US1256032A - Catalytic agent. - Google Patents
Catalytic agent. Download PDFInfo
- Publication number
- US1256032A US1256032A US84302314A US1914843023A US1256032A US 1256032 A US1256032 A US 1256032A US 84302314 A US84302314 A US 84302314A US 1914843023 A US1914843023 A US 1914843023A US 1256032 A US1256032 A US 1256032A
- Authority
- US
- United States
- Prior art keywords
- nickel
- catalytic agent
- aluminate
- silicate
- catalytic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003197 catalytic effect Effects 0.000 title description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 34
- 239000003795 chemical substances by application Substances 0.000 description 23
- 229910052759 nickel Inorganic materials 0.000 description 16
- 239000010457 zeolite Substances 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 10
- PGZIKUPSQINGKT-UHFFFAOYSA-N dialuminum;dioxido(oxo)silane Chemical compound [Al+3].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O PGZIKUPSQINGKT-UHFFFAOYSA-N 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- -1 alkali metal aluminate-silicate Chemical class 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 150000002815 nickel Chemical class 0.000 description 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052908 analcime Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052674 natrolite Inorganic materials 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
Definitions
- aluminatesilicate containin water such as a natural zeolite, or an artificial zeolite
- nickel replacing a part, or the whole of the alkali metal or alkaline earth metal contained therein, by nickel.
- the product obtained can be subjected to further treatment, without departing from ohr invention; for instance, it may be heated and reduced, and this reduction is desirable, if the catalytic agent is to be employed for the hydrogenization of organic compounds. After such reduction, the catalytic agent contains metallic nickel and the elements of an aluminate-silicate.
- the introduction of the nickel into the aluminate-silicate can be effected, for instance, by digesting the alkali metal aluminate-silicate, or other aluminate-silicate, with a solution of a nickel salt.
- the zeo lite can either direct, or after being gently heated, so that some of the water is driven off, be soaked in a solution of a nickel salt, so that the nickel salt enters the zeolite, and some replacement of the alkali metal or alkaline earth metal by nickel-takes place, al-
- C htalytic agents in accordance with this invention are very easily produced and are characterized by excellent activity, and by their use, the most varied operations, such, for instance, as hydrogenization, reduction and oxidation can be carried out.
- zeolite for instance, commercial granular sodium permutite
- nickel for instance, commercial granular sodium permutite
- the catalytic agent is to be used for hydrogenization purposes, dry the granular mass which contains, for instance, about 10% of nickel and reduce it with hyrogen at from 350 to 400 C.
- the catalytic agent so produced contains metallic nickel and is excellently suited for hydrogenizing various oils of either animal, vegetable, or mineral, origin, either by shaking or stirring the oil with the catalytic agent in the presence of hydrogen, or by passing the mixed hydrogen and oil through a stationary layer of the catalytic agent.
- potassium permutite or other alumihate-silicates containing a replaceable base, or more than one replaceable base
- natural zeolites can be used, such as analcime, natrolite and chaba- Site.
- aluminate-silicate in addition to the nickel compounds.
- other compounds can be introduced into the aluminate-silicate, in addition to the nickel compounds.
- nickel nitrate solution employed according to the foregoing example, small quantities of aluminium nitrate or of cobalt nitrate can be added, so that alumina or cobalt oxid at 150 0., and then soaking it with a solution of nickel nitrate drying the whole and reducing it.
- a catalytic agent containmg the elements of nickel and of a zeolite.
- a catalytic agent containing the elements of nickel and of an alkali metal aluminate-silicate in a reduced form is provided.
- a catalytic agent containing the elements of nickel and of a zeolite in a reduced form is provided.
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Description
WIN MITTASOH, CHRISTIAN SCHNEIDER, AND HUGO MORAWITZ, 0F LUDWIGSHAFEN- on-rnn-nnmn,
ERMANY, ASSIGN'ORS TO BADISGHE ANILIN & SODA FABRIK, OF
LUDWIGSHAFEN- N-THE-RHINE, GERMANY, A CORPORATION.
CATALYTIC AGENT.
No Drawing.
by means of which catalytic reactions can be carried out in a very advantageous manner. Our new catalytic agents contain the elements of nickel and an aluminate-silicate,
and can be obtained by'taking an aluminatesilicate containin water, such as a natural zeolite, or an artificial zeolite, and replacing a part, or the whole of the alkali metal or alkaline earth metal contained therein, by nickel. The product obtained can be subjected to further treatment, without departing from ohr invention; for instance, it may be heated and reduced, and this reduction is desirable, if the catalytic agent is to be employed for the hydrogenization of organic compounds. After such reduction, the catalytic agent contains metallic nickel and the elements of an aluminate-silicate.
The introduction of the nickel into the aluminate-silicate can be effected, for instance, by digesting the alkali metal aluminate-silicate, or other aluminate-silicate, with a solution of a nickel salt. Or, the zeo lite can either direct, or after being gently heated, so that some of the water is driven off, be soaked in a solution of a nickel salt, so that the nickel salt enters the zeolite, and some replacement of the alkali metal or alkaline earth metal by nickel-takes place, al-
though the alkali remains in the mass. Artificial zeolites are put on to the market under the name of permutite, and are described in British Patent No. 23.706/12 and also in the article On artificial zeolites by Dr. Siedler on page 202 of the report of section 2 of the Seventh International Congress of Ap lied Chemistry held in London in 1909.
C htalytic agents in accordance with this invention are very easily produced and are characterized by excellent activity, and by their use, the most varied operations, such, for instance, as hydrogenization, reduction and oxidation can be carried out.
During the employment of our catalytic agents, they may undergo physical and Specification of Letters Patent.
A; lication flied June 4, 1914. Serial N 0. 843,023.
Patented Feb. t0, TQM.
chemical changes, and we wish to be understood as claiming the new catalytic agents, as above defined whether they may have undergone these changes or not.
The following example illustrates how one of our new catalytic agents can be prepared, but the invention is not limited to this example. The parts are by weight.
Example.
Treat a zeolite (for instance, commercial granular sodium permutite) several times with a warm 10% solution of nickel nitrate, washing Well after each treatment, whereby the sodium, or potassium, or other strong replaceable base, is replaced by nickel. If the catalytic agent is to be used for hydrogenization purposes, dry the granular mass which contains, for instance, about 10% of nickel and reduce it with hyrogen at from 350 to 400 C. The catalytic agent so produced contains metallic nickel and is excellently suited for hydrogenizing various oils of either animal, vegetable, or mineral, origin, either by shaking or stirring the oil with the catalytic agent in the presence of hydrogen, or by passing the mixed hydrogen and oil through a stationary layer of the catalytic agent.
In this example instead of sodium permutite, potassium permutite, or other alumihate-silicates containing a replaceable base, or more than one replaceable base, can be employed, for instance, natural zeolites can be used, such as analcime, natrolite and chaba- Site.
If desired, other compounds can be introduced into the aluminate-silicate, in addition to the nickel compounds. For instance, to the nickel nitrate solution employed according to the foregoing example, small quantities of aluminium nitrate or of cobalt nitrate can be added, so that alumina or cobalt oxid at 150 0., and then soaking it with a solution of nickel nitrate drying the whole and reducing it.
Now what we claim is 1. A catalytic agent containing the elements of nickel and of an aluminate-sihcate.
2. A catalytic agent containing the elements of nickel and of an alkali metal aluminate-silicate.
3. A catalytic agent containmg the elements of nickel and of a zeolite.
4. A catalytic agent containing the elements of nickel and of an aluminate-silicate in a reduced form.
5. A catalytic agent containing the elements of nickel and of an alkali metal aluminate-silicate in a reduced form.
6. A catalytic agent containing the elements of nickel and of a zeolite in a reduced form.
7. The process of producing a catalytic agent by causing nickel to replace the whole or a part of the replaceable base of an aluminate-silicate containing water.
8. The process of producing a catalytic agent by causing nickel to replace the whole or a part of the alkali metal of an alkali metal illuminate-silicate containing water.
9. The process of producing a catalytic agent by causing nickel to replace the whole or part of the alkali metal of an artificial zeolite.
10. The process of producing a catalytic agent by causing nickel to replace the whole or a part of the replaceable base on an aluminate-silicate containing water and then treating the product with a reducing agent. I
11. The process of producing a catalytic agent by causing nickel to replace the whole or a part of the alkali metal of an alkali metal aluminate-silicate containing water and then treating the product with a reducing agent.
In testimony whereof we have hereunto set our hands in the presence of two subscribing witnesses. a
' ALWIN MITTASCH.
CHRISTIAN SCHNEIDER. HUGO MORAWITZ. Witnesses:
CH. BECK, J. ALEG. LLOYD.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US84302314A US1256032A (en) | 1914-06-04 | 1914-06-04 | Catalytic agent. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US84302314A US1256032A (en) | 1914-06-04 | 1914-06-04 | Catalytic agent. |
Publications (1)
Publication Number | Publication Date |
---|---|
US1256032A true US1256032A (en) | 1918-02-12 |
Family
ID=3323725
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US84302314A Expired - Lifetime US1256032A (en) | 1914-06-04 | 1914-06-04 | Catalytic agent. |
Country Status (1)
Country | Link |
---|---|
US (1) | US1256032A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2470092A (en) * | 1944-10-09 | 1949-05-17 | Koppers Co Inc | Dehydrogenation process |
US2472831A (en) * | 1947-02-28 | 1949-06-14 | Standard Oil Dev Co | Process for the preparation of a silica-metal oxide hydrogel catalyst |
US2472833A (en) * | 1947-02-28 | 1949-06-14 | Standard Oil Dev Co | Process for the preparation of a silica-group vill metal oxide catalyst |
US2472832A (en) * | 1947-02-28 | 1949-06-14 | Standard Oil Dev Co | Process for the preparation of a silica-group iv metal oxide catalyst |
US2566362A (en) * | 1947-11-01 | 1951-09-04 | Lever Brothers Ltd | Hardening and decolorizing glyceride oils with nickel-alumina-silica catalysts |
US2575324A (en) * | 1946-05-18 | 1951-11-20 | Hercules Powder Co Ltd | Nickel-magnesia-zirconium silicate catalyst |
US2589189A (en) * | 1949-08-17 | 1952-03-11 | Atlantic Refining Co | Silica-alumina-group vill metal catalyst |
US2606940A (en) * | 1945-06-15 | 1952-08-12 | Phillips Petroleum Co | Catalytic polymerization of olefins |
US3012860A (en) * | 1958-03-17 | 1961-12-12 | Shell Oil Co | Hydrogen peroxide purification |
-
1914
- 1914-06-04 US US84302314A patent/US1256032A/en not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2470092A (en) * | 1944-10-09 | 1949-05-17 | Koppers Co Inc | Dehydrogenation process |
US2606940A (en) * | 1945-06-15 | 1952-08-12 | Phillips Petroleum Co | Catalytic polymerization of olefins |
US2575324A (en) * | 1946-05-18 | 1951-11-20 | Hercules Powder Co Ltd | Nickel-magnesia-zirconium silicate catalyst |
US2472831A (en) * | 1947-02-28 | 1949-06-14 | Standard Oil Dev Co | Process for the preparation of a silica-metal oxide hydrogel catalyst |
US2472833A (en) * | 1947-02-28 | 1949-06-14 | Standard Oil Dev Co | Process for the preparation of a silica-group vill metal oxide catalyst |
US2472832A (en) * | 1947-02-28 | 1949-06-14 | Standard Oil Dev Co | Process for the preparation of a silica-group iv metal oxide catalyst |
US2566362A (en) * | 1947-11-01 | 1951-09-04 | Lever Brothers Ltd | Hardening and decolorizing glyceride oils with nickel-alumina-silica catalysts |
US2589189A (en) * | 1949-08-17 | 1952-03-11 | Atlantic Refining Co | Silica-alumina-group vill metal catalyst |
US3012860A (en) * | 1958-03-17 | 1961-12-12 | Shell Oil Co | Hydrogen peroxide purification |
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