US10851678B2 - Thermal energy recovery device and startup operation method for the same - Google Patents

Thermal energy recovery device and startup operation method for the same Download PDF

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US10851678B2
US10851678B2 US16/464,696 US201716464696A US10851678B2 US 10851678 B2 US10851678 B2 US 10851678B2 US 201716464696 A US201716464696 A US 201716464696A US 10851678 B2 US10851678 B2 US 10851678B2
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working fluid
flow path
temperature
circulation flow
fluid
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US20190383177A1 (en
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Kazuo Takahashi
Haruyuki Matsuda
Shigeto Adachi
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Kobe Steel Ltd
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Kobe Steel Ltd
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Assigned to KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD.) reassignment KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD.) ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ADACHI, SHIGETO, MATSUDA, HARUYUKI, TAKAHASHI, KAZUO
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K25/00Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
    • F01K25/08Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
    • F01K25/10Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D17/00Regulating or controlling by varying flow
    • F01D17/10Final actuators
    • F01D17/12Final actuators arranged in stator parts
    • F01D17/14Final actuators arranged in stator parts varying effective cross-sectional area of nozzles or guide conduits
    • F01D17/141Final actuators arranged in stator parts varying effective cross-sectional area of nozzles or guide conduits by means of shiftable members or valves obturating part of the flow path
    • F01D17/145Final actuators arranged in stator parts varying effective cross-sectional area of nozzles or guide conduits by means of shiftable members or valves obturating part of the flow path by means of valves, e.g. for steam turbines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • F01K13/02Controlling, e.g. stopping or starting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/16Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being hot liquid or hot vapour, e.g. waste liquid, waste vapour
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B35/00Control systems for steam boilers
    • F22B35/001Controlling by flue gas dampers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22DPREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
    • F22D1/00Feed-water heaters, i.e. economisers or like preheaters

Definitions

  • the present invention relates to a thermal energy recovery device and a startup operation method for the same.
  • patent literature 1 discloses a power generation device (thermal energy recovery device) with an evaporator, a preheater, an expander, a power generator, a condenser, a working fluid pump and a circulation flow path.
  • the evaporator heats a working fluid with a heating medium supplied from an external heat source.
  • the preheater heats the working fluid before flowing into the evaporator with the heating medium flowing out from the evaporator.
  • the expander expands the working fluid flowing out from the evaporator.
  • the power generator is connected to the expander.
  • the condenser condenses the working fluid flowing out from the expander.
  • the working fluid pump feeds the working fluid condensed in the condenser to the preheater.
  • the circulation flow path connects the preheater, the evaporator, the expander, the condenser and the pump.
  • the temperature of the evaporator suddenly increases at the time of starting the operation of this recovery device, whereby a thermal stress generated in the evaporator may suddenly increase.
  • the temperature of the evaporator is relatively low, whereas thermal energy of the heating medium such as steam is very large.
  • the high-temperature heating medium flows into the evaporator at the time of starting the operation, the temperature of the evaporator may suddenly increase.
  • Patent Literature 1 Japanese Unexamined Patent Publication No. 2014-47632
  • An object of the present invention is to provide a thermal energy recovery device capable of suppressing a sudden increase of a thermal stress generated in an evaporator at the time of starting an operation and a startup operation method for the same.
  • a thermal energy recovery device includes a working fluid circulation flow path for circulating a working fluid, a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state, an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path, and a control unit for controlling a startup operation of the thermal energy recovery device.
  • the control unit executes a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation.
  • a startup operation method for thermal energy recovery device is a startup operation method for thermal recovery device with an evaporation unit for evaporating a working fluid flowing in a working fluid circulation flow path by heat of a heating fluid flowing in a thermal fluid circulation flow path, wherein a suppression control for suppressing a temperature of the working fluid in the evaporation unit is executed in a startup operation of the thermal energy recovery device.
  • FIG. 1 is a diagram showing a schematic configuration of a thermal energy recovery device according to a first embodiment of the present invention
  • FIG. 2 is a graph showing temperature transitions of a working fluid and hot water in the thermal energy recovery device
  • FIG. 3 is a chart showing a control operation of a startup operation of the thermal energy recovery device
  • FIG. 4 is a chart showing a control operation of a stop operation of the thermal energy recovery device
  • FIG. 5 is a diagram showing a schematic configuration of a thermal energy recovery device according to a modification of the first embodiment of the present invention
  • FIG. 6 is a diagram showing a schematic configuration of a thermal energy recovery device according to a second embodiment of the present invention.
  • FIG. 7 is a graph showing temperature transitions of a working fluid and hot water in the thermal energy recovery device
  • FIG. 8 is a chart showing a control operation of a normal operation of the thermal energy recovery device
  • FIG. 9 is a diagram showing a schematic configuration of a thermal energy recovery device as a reference example.
  • FIG. 10 is a graph showing temperature transitions of a working fluid and hot water in the reference example.
  • thermal energy recovery device according to a first embodiment of the present invention is described with reference to the drawings.
  • the thermal energy recovery device 1 includes a working fluid circulation flow path for circulating a working fluid while being accompanied by a phase change (hereinafter, merely referred to as a “circulation flow path”) 22 , a thermal fluid circulation flow path 30 for circulating hot water serving as a pressurized heating fluid in a liquid state, and a control unit 50 .
  • a heater 32 is provided in the thermal fluid circulation flow path 30 .
  • This heater 32 includes a heating medium flow path 32 a in which a heating medium (high-temperature gas such as corrosive gas) in a gas phase flows and a thermal fluid flow path 32 b in which hot water flows.
  • the heating medium in the heating medium flow path 32 a and the hot water in the thermal fluid flow path 32 b exchange heat in the heater 32 . In this way, the hot water is heated.
  • the thermal energy recovery device 1 recovers thermal energy of the heating medium. In the recovery device 1 , this thermal energy of the heating medium is temporarily recovered in the hot water of the thermal fluid circulation flow path 30 .
  • the thermal fluid circulation flow path 30 is interposed between a pipe 34 in which the heating medium flows and the circulation flow path 22 in which the working fluid is circulated, the heating medium does not flow into later-described evaporator 10 and preheater 12 provided in the circulation flow path 22 . Thus, even if the heating medium is corrosive gas, the corrosion of the evaporator 10 and the preheater 12 can be prevented.
  • the heating medium flow path 32 a is connected to a heating pipe 35 branched from the pipe 34 in which the heating medium flows.
  • a flow rate of the heating medium flowing into the heater 32 can be adjusted by changing an opening of a flow rate control value Va 1 provided in the heating pipe 35 .
  • the flow rate control valve Va 1 may be arranged upstream of the heater 32 in the heating pipe 35 or may be arranged downstream of the heater 32 .
  • the evaporator 10 , the preheater 12 , an energy recovery unit 13 , a condenser 18 and a pump 20 are provided in the circulation flow path 22 .
  • the evaporator 10 includes a first flow path 10 a in which the working fluid flows and a second flow path 10 b in which the hot water flows.
  • the evaporator 10 performs heat exchange between the hot water in the thermal fluid circulation flow path 30 and the working fluid (HFC245fa or the like) in the circulation flow path 22 . In this way, the working fluid evaporates.
  • a brazing plate type heat exchanger is used as the evaporator 10 .
  • a so-called shell-and-tube type heat exchanger may be used as the evaporator 10 .
  • the preheater 12 is arranged between the evaporator 10 and the pump 20 in the circulation flow path 22 .
  • the preheater 12 includes a first flow path 12 a in which the working fluid flows and a second flow path 12 b in which the hot water flows.
  • the preheater 12 performs heat exchange between the hot water flowing out from the evaporator 10 and the working fluid before flowing into the evaporator 10 . In this way, the working fluid is heated.
  • a brazing plate type heat exchanger is used also as the preheater 12 .
  • a so-called shell-and-tube heat exchanger may be used as the preheater 12 as in the case of the evaporator 10 .
  • an evaporation unit for evaporating the working fluid includes the evaporator 10 and the preheater 12 provided separately from the evaporator 10 .
  • the evaporator 10 functioning as the evaporation unit may be provided, whereas the preheater may be omitted.
  • the energy recovery unit 13 includes an expander 14 and a power recovery device 16 .
  • the expander 14 is provided in a part of the circulation flow path 22 downstream of the evaporator 10 .
  • the preheater 12 , the evaporator 10 , the expander 14 , the condenser 18 and the pump 20 are connected to the circulation flow path 22 in this order.
  • the expander 14 expands the working fluid in a gas phase flowing out from the evaporator 10 .
  • a positive displacement screw expander including a rotor to be rotationally driven by expansion energy of the working fluid in a gas phase flowing out from the evaporator 10 is used as the expander 14 .
  • the expander 14 includes a pair of male and female screw rotors.
  • the power recovery device 16 is connected to the expander 14 .
  • a power generator is used as the power recovery device 16 .
  • This power recovery device 16 includes a rotary shaft connected to one of the pair of screw rotors of the expander 14 .
  • the power recovery device 16 generates power as the rotary shaft rotates according to the rotation of the screw rotor.
  • a compressor or the like may be used as the power recovery device 16 .
  • An isolation valve V- 1 is provided in a part of the circulation flow path 22 between the evaporator 10 and the expander 14 . Further, a bypass flow path 24 bypassing the isolation valve V- 1 and the expander 14 is provided in the circulation flow path 22 . An on-off valve V- 2 is provided in the bypass flow path 24 .
  • the condenser 18 is provided in a part of the circulation flow path 22 downstream of the expander 14 .
  • the condenser 18 condenses (liquefies) the working fluid flowing out from the expander 14 by cooling the working fluid with a cooling medium (cooling water or the like) supplied from outside.
  • the cooling medium is supplied through a cooling medium flow path 37 , for example, from a cooling tower connected to the cooling medium flow path 37 .
  • the pump 20 is provided in a part of the circulation flow path 22 downstream of the condenser 18 (part between the condenser 18 and the preheater 12 ).
  • the pump 20 pressurizes the working fluid in a liquid phase to a predetermined pressure and feeds the pressurized working fluid to the preheater 12 .
  • a centrifugal pump including an impeller as a rotor, a gear pump including a rotor composed of a pair of gears, a screw pump, a trochoid pump or the like is used as the pump 20 .
  • the heating fluid is sealed in a pressurized state in the thermal fluid circulation flow path 30 .
  • the hot water is sealed in a pressurized state in the thermal fluid circulation flow path 30 .
  • the evaporator 10 , the preheater 12 , a buffer tank 38 , a fluid pump 40 and the heater 32 are arranged in this order in the thermal fluid circulation flow path 30 .
  • the hot water successively flows through the evaporator 10 , the preheater 12 , the buffer tank 38 , the fluid pump 40 and the heater 32 .
  • the buffer tank 38 is provided on a suction side of the fluid pump 40 . By providing the buffer tank 38 , a predetermined pressure (head pressure) can be applied to the suction side of the fluid pump 40 .
  • the thermal energy recovery device 1 is provided with an inlet-side working fluid temperature sensor Tr 1 , an outlet-side working fluid temperature sensor Tr 2 , an inlet-side hot water temperature sensor Tw 1 and an outlet-side hot water temperature sensor Tw 2 .
  • the inlet-side working fluid temperature sensor Tr 1 detects a temperature of the working fluid on an inlet side of the evaporation unit, i.e. the preheater 12 and outputs a signal indicative of a detection value.
  • the outlet-side working fluid temperature sensor Tr 2 detects a temperature of the working fluid on an outlet side of the evaporation unit, i.e. the evaporator 10 and outputs a signal indicative of a detection value.
  • the inlet-side hot water temperature sensor Tw 1 detects a temperature of the hot water on an inlet side of the evaporation unit, i.e. the evaporator 10 and outputs a signal indicative of a detection value.
  • the outlet-side hot water temperature sensor Tw 2 detects a temperature of the hot water on an outlet side of the evaporation unit, i.e. the preheater 12 and outputs a signal indicative of a detection value.
  • the signals output from these sensors Tr 1 , Tr 2 , Tw 1 and Tw 2 are input to the control unit 50 .
  • the control unit 50 executes a suppression control for suppressing a temperature difference between the hot water and the working fluid in the evaporator 10 and the preheater 12 during a startup operation of the thermal energy recovery device 1 .
  • the temperature of the working fluid increases from a temperature tr 1 on the inlet side of the preheater 12 to a temperature tr 3 by being heated by the hot water in the preheater 12 and the evaporator 10 .
  • the working fluid evaporated in the evaporator 10 is further heated in the evaporator 10 to reach a temperature tr 2 .
  • the temperature of the hot water gradually decreases from a temperature tw 1 on the inlet side of the evaporator 10 and reaches a temperature tw 2 on the outlet side of the preheater 12 . Since the working fluid undergoes a phase change in the evaporator 10 , a temperature change amount is small. In contrast, a temperature change amount of the working fluid is large in the preheater 12 . Thus, a temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side of the preheater 12 and the temperature tr 1 of the working fluid on the inlet side of the preheater 12 increases. Particularly, since the temperature of the working fluid is low in some cases during the startup operation, the temperature difference ⁇ t tends to increase and a thermal stress generated in the preheater 12 possibly becomes problematic.
  • control unit 50 executes the suppression control for suppressing the temperature difference between the hot water and the working fluid in the evaporator 10 and the preheater 12 during the startup operation.
  • Step ST 1 an operator first confirms that the flow rate control valve Va 1 is closed, the isolation valve V- 1 is closed and the on-off valve V- 2 in the bypass flow path 24 is open (Step ST 1 ). Then, the operator operates an unillustrated start button. In this way, the pump 20 and the fluid pump 40 start operating (Step ST 2 ). Further, the operation of the cooling tower is started, whereby the cooling medium is supplied to the condenser 18 through the cooling medium flow path 37 (Step ST 3 ).
  • the control unit 50 controls to slightly open the flow rate control valve Va 1 (Step ST 4 ). At this time, the opening is set at a value set in advance such as ⁇ %.
  • the control unit 50 controls to gradually increase the opening of the flow rate control valve Va 1 (Step ST 5 ). In this way, the temperature of the hot water gradually increases. At this time, the temperature tw 1 of the hot water on the inlet side of the evaporator 10 is monitored by the inlet-side hot water temperature sensor Tw 1 .
  • the control unit 50 gradually increases the opening of the flow rate control valve Va 1 until the temperature reaches an operation start temperature (e.g. 90° C.) set in advance. However, the operation start temperature is not limited to 90° C.
  • Step ST 6 the control unit 50 opens the isolation valve V- 1 and closes the on-off valve V- 2 in the bypass flow path 24 .
  • the expander 14 is driven to start power recovery by the power recovery device 16 (Step ST 6 ).
  • Step ST 7 it is confirmed whether or not the operation (power generation) has been continuously stably performed for a given time.
  • the control unit 50 controls to gradually increases the opening of the flow rate control valve Va 1 with the temperatures monitored by the respective temperature sensors Tr 1 , Tr 2 , Tw 1 and Tw 2 (Step ST 8 ).
  • a rate of increasing the opening of the flow rate control valve Va 1 is so set that a temperature increase rate ⁇ T (C°/min) of the temperature tw 1 of the hot water on the inlet side of the evaporator 10 is larger than a temperature increase rate when the temperature is below the operation start temperature.
  • Step ST 8 the temperature tw 1 of the hot water on the inlet side of the evaporator 10 is monitored and, if the temperature tw 1 of the hot water is below a temperature set in advance, the control unit 50 gradually increases the opening of the flow rate control valve Va 1 as described above. If the temperature tw 1 of the hot water is equal to or higher than the temperature set in advance, the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side of the preheater 12 and the temperature tr 1 of the working fluid on the inlet side of the preheater 12 is also monitored.
  • the control unit 50 executes the suppression control to gradually increase the opening of the flow rate control valve Va 1 in such a range where the temperature difference ⁇ t does not exceed a value set in advance.
  • the temperature tw 1 of the hot water on the inlet side of the evaporator 10 gradually increases and the temperature tw 2 of the hot water on the outlet side of the preheater 12 also gradually increases.
  • the temperature difference ⁇ t between the temperature tw 2 and the temperature tr 1 is suppressed to be equal to or lower than a predetermined temperature and does not become excessive. Specifically, an input heat quantity increase rate from the hot water in the evaporator 10 and the preheater 12 is suppressed.
  • a rotation speed of the fluid pump 40 may also be adjusted in association with an opening adjustment of the flow rate control valve Va 1 . Specifically, the rotation speed of the fluid pump 40 may be adjusted to further finely adjust the temperature by the flow rate control valve Va 1 .
  • the control unit 50 judges whether or not the temperature tw 1 of the hot water on the inlet side of the evaporator 10 has reached an operating temperature (e.g. 130° C.) set in advance (Step ST 9 ) and the startup operation transitions to a normal operation by an automatic operation when the temperature tw 1 reaches the operating temperature (Step ST 10 ).
  • an operating temperature e.g. 130° C.
  • the temperature tw 1 of the hot water on the inlet side of the evaporator 10 is, for example, about 130° C.
  • the temperature of the hot water on the outlet side of the evaporator 10 is, for example, about 115° C.
  • the temperature tw 2 of the hot water on the outlet side of the preheater 12 is, for example, about 100° C.
  • the temperature of the working fluid on the inlet side of the preheater 12 is, for example, about 20° C. at the start of the operation, but reaches, for example, about 40° C. during the normal operation.
  • the temperature of the working fluid on the outlet side of the evaporator 10 is, for example, about 120° C.
  • FIG. 4 shows a stop flow during the automatic operation.
  • the control unit 50 closes the isolation valve V- 1 and opens the on-off valve V- 2 in the bypass flow path 24 (Step ST 22 ). In this way, the working fluid bypasses the expander 14 , wherefore power generation is stopped. Then, the flow rate control valve Va 1 is closed (Step ST 23 ). Since the temperature of the hot water circulating in the thermal fluid circulation flow path 30 decreases in this way, the input heat quantities to the evaporator 10 and the preheater 12 decrease. Then, the pump 20 and a hot water pump are stopped (Step ST 24 ). At this time, the operation of the cooling tower is maintained (Step ST 25 ).
  • heat exchange is performed between the hot water introduced from the thermal fluid circulation flow path 30 and the working fluid introduced from the circulation flow path 22 in the evaporator 10 and the preheater 12 . Since the pressurized hot water in a liquid state flows into the evaporator 10 and the preheater 12 , thermal energy introduced to the evaporator 10 and the preheater 12 is large. Thus, in the startup operation in which the temperature of the working fluid is relatively low, the suppression control is executed to suppress the temperature difference between the hot water and the working fluid in the evaporator 10 and the preheater 12 . Therefore, it can be suppressed that large thermal stresses are generated in the evaporator 10 and the preheater 12 during the startup operation.
  • the input heat quantities in the evaporator 10 and the preheater 12 are suppressed such that the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side of the preheater 12 and the temperature tr 1 of the working fluid on the inlet side of the preheater 12 is equal to or lower than the predetermined temperature.
  • the thermal stresses in the evaporator 10 and the preheater 12 become excessive at the start of the operation.
  • the temperature difference between the temperature tw 2 of the hot water on the outlet side and the temperature tr 1 of the working fluid on the inlet side is largest in the preheater 12 .
  • the suppression control on the basis of this temperature difference between the both, it can be reliably suppressed that the terminal stress in the preheater 12 becomes excessive.
  • control unit 50 adjusts the opening of the flow rate control valve Va 1 in the startup operation, whereby the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side and the temperature tr 1 of the working fluid on the inlet side is maintained to be equal to or lower than the predetermined temperature.
  • the control unit 50 adjusts the opening of the flow rate control valve Va 1 in the startup operation, whereby the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side and the temperature tr 1 of the working fluid on the inlet side is maintained to be equal to or lower than the predetermined temperature.
  • the suppression control is executed to control the temperature difference ⁇ t between the hot water and the working fluid in the startup operation.
  • FIG. 6 shows a second embodiment of the present invention. Note that the same constituent elements as in the first embodiment are denoted by the same reference signs and the detailed description thereof is omitted here.
  • a cooler 53 is provided in a thermal fluid circulation flow path 30 and a temperature difference ⁇ t between a temperature tw 2 of hot water on an outlet side of a preheater 12 and a temperature tr 1 of a working fluid on an inlet side of the preheater 12 is reduced by operating the cooler 53 .
  • the cooler 53 is for reducing the temperature of the hot water through heat exchange between a cooling medium (air, water or the like) and the hot water. If air is used as the cooling medium, a fan 54 for generating an air flow is provided. By driving the fan 54 , the cooler 53 operates. In this way, the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side of the preheater 12 and the temperature tr 1 of the working fluid on the inlet side is controlled to or below a predetermined temperature. Note that if water is used as the cooling medium, an unillustrated pump is provided and the cooler 53 operates by driving the pump.
  • a cooling medium air, water or the like
  • a temperature tw 4 of the hot water on an inlet side of the preheater 12 becomes lower than a temperature tw 3 of the hot water on an outlet side of the evaporator 10 as shown in FIG. 7 by operating the cooler 53 .
  • the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side of the preheater 12 and the temperature tr 1 of the working fluid on the inlet side of the preheater 12 is suppressed to be equal to or lower than the predetermined temperature.
  • the temperature of the hot water exhibits a temperature transition shown in FIG. 2 in a state where the cooler 53 is not operated.
  • Step ST 31 whether or not the temperature difference ⁇ t between the temperature tw 2 of the hot water on the outlet side of the preheater 12 and the temperature tr 1 of the working fluid on the inlet side of the preheater 12 is equal to or lower than the temperature set in advance during the normal operation is monitored by the control unit 50 (Step ST 31 ) as shown in FIG. 8 . If the temperature difference ⁇ t is judged to have exceeded the temperature set in advance, the control unit 50 operates the cooler 53 (Step ST 32 ).
  • the control unit 50 stops the cooler 53 (Step ST 54 ).
  • the control unit 50 operates the cooler 53 if the temperature difference ⁇ t between the hot water and the working fluid exceeds the predetermined temperature. In this way, the temperature of the hot water flowing in the thermal fluid circulation flow path 30 decreases. Thus, the temperature difference ⁇ t between the hot water and the working fluid in the preheater 12 can be reduced.
  • a regenerator 58 is provided between a pump 20 and the preheater 12 in a circulation flow path 22 .
  • This regenerator 58 heats the working fluid flowing from the pump 20 toward the preheater 12 by the working fluid discharged from an expander 14 and flowing toward a condenser 18 .
  • the temperature difference ⁇ t in the preheater 12 can be reduced by increasing the temperature of the working fluid before flowing into the preheater 12 .
  • a thermal energy recovery device of the above embodiment includes a working fluid circulation flow path for circulating a working fluid, a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state, an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path, and a control unit for controlling a startup operation of the thermal energy recovery device.
  • the control unit executes a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation.
  • the pressurized heating fluid in a liquid state flows into the evaporation unit, thermal energy introduced to the evaporation unit is large.
  • heat exchange is performed between the heating fluid in a liquid state introduced from the thermal fluid circulation flow path and the working fluid introduced from the working fluid circulation flow path.
  • the suppression control is executed to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit. Therefore, it can be suppressed that a large thermal stress is generated in the evaporation unit during the startup operation.
  • the suppression control may be a control for setting a temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit equal to or lower than a predetermined temperature set in advance when the temperature of the heating fluid flowing into the evaporation unit is equal to or higher than a temperature set in advance.
  • an input heat quantity in the evaporation unit is so suppressed that a temperature difference between the temperature of the heating fluid on an outlet side of the evaporation unit and the temperature of the working fluid on an inlet side of the evaporation unit becomes equal to or lower than the predetermined temperature when the temperature of the heating fluid is equal to or higher than the predetermined temperature set in advance.
  • the thermal stress in the evaporation unit becomes excessive during the startup operation.
  • the temperature difference between the temperature of the heating fluid on the outlet side and the temperature of the working fluid on the inlet side is largest in the evaporation unit.
  • the above thermal energy recovery device may include a heater provided in the thermal fluid circulation flow path for heating the heating fluid with heat of a heating medium in a gas state and a flow rate control valve for adjusting a flow rate of the heating medium introduced into the heater.
  • the control unit may adjust an opening of the flow rate control valve such that the temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit is maintained to be equal to or lower than the predetermined temperature in the startup operation.
  • the temperature difference is maintained to be equal to or lower than the predetermined temperature by the control unit adjusting the opening of the flow rate control valve in the startup operation.
  • the control unit adjusting the opening of the flow rate control valve in the startup operation.
  • the above thermal energy recovery device may include a cooler for cooling the heating fluid flowing in the thermal fluid circulation flow path with a cooling medium.
  • the control unit may operate the cooler to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit.
  • control unit operates the cooler, for example, when the temperature difference between the heating fluid and the working fluid in the evaporation unit exceeds the predetermined temperature. In this way, the temperature of the heating fluid flowing in the thermal fluid circulation flow path decreases. Thus, the temperature difference between the heating fluid and the working fluid in the evaporation unit can be reduced.
  • the evaporation unit may include an evaporator for evaporating the working fluid by the heat of the heating fluid flowing in the thermal fluid circulation flow path and a preheater for heating the working fluid before flowing into the evaporator by the heat of the heating fluid flowing in the thermal fluid circulation flow path.
  • thermal energy introduced to the preheater may increase, but the suppression control for suppressing the temperature difference between the heating fluid and the working fluid is executed in the startup operation.
  • the suppression control for suppressing the temperature difference between the heating fluid and the working fluid is executed in the startup operation.
  • a startup operation method for thermal energy recovery device of the above embodiment is a startup operation method for thermal energy recovery device with an evaporation unit for evaporating working fluid flowing in a working fluid circulation flow path by heat of a heating fluid flowing in a thermal fluid circulation flow path, wherein a suppression control for suppressing a temperature of the working fluid in the evaporation unit is executed in a startup operation of the thermal energy recovery device.
  • a heater for heating the heating fluid by heat of a heating medium in a gas state may be provided in the thermal fluid circulation flow path.
  • an opening of a flow rate control valve for adjusting a flow rate of the heating medium introduced into the heater may be adjusted such that a temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit is maintained to be equal to or lower than the predetermined temperature.
  • a cooler for cooling the heating fluid flowing in the thermal fluid circulation flow path by a cooling medium may be provided.
  • the above startup operation method for thermal energy recovery device may include operating the cooler to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit if the temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit exceeds a temperature set in advance.

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Abstract

A thermal energy recovery device includes a circulation flow path for circulating a working fluid, a thermal fluid circulation flow path for circulating hot water, an evaporator for evaporating the working fluid flowing in the circulation flow path by heat of the hot water flowing in the thermal fluid circulation flow path, a preheater for heating the working fluid before flowing into the evaporator by the heat of the hot water flowing in the thermal fluid circulation flow path, and a control unit for controlling a startup operation of the thermal energy recovery device. The control unit executes a suppression control for suppressing a temperature difference between the hot water and the working fluid in the preheater.

Description

TECHNICAL FIELD
The present invention relates to a thermal energy recovery device and a startup operation method for the same.
BACKGROUND ART
Conventionally, a thermal energy recovery device is known which recovers power from a heating medium such as exhaust gas discharged from various facilities such as factories. For example, patent literature 1 discloses a power generation device (thermal energy recovery device) with an evaporator, a preheater, an expander, a power generator, a condenser, a working fluid pump and a circulation flow path. The evaporator heats a working fluid with a heating medium supplied from an external heat source. The preheater heats the working fluid before flowing into the evaporator with the heating medium flowing out from the evaporator. The expander expands the working fluid flowing out from the evaporator. The power generator is connected to the expander. The condenser condenses the working fluid flowing out from the expander. The working fluid pump feeds the working fluid condensed in the condenser to the preheater. The circulation flow path connects the preheater, the evaporator, the expander, the condenser and the pump.
In the thermal energy recovery device described in the above literature 1, if the high-temperature heating medium is supplied to the evaporator, the temperature of the evaporator suddenly increases at the time of starting the operation of this recovery device, whereby a thermal stress generated in the evaporator may suddenly increase. Specifically, before the operation of the recovery device is started, the temperature of the evaporator is relatively low, whereas thermal energy of the heating medium such as steam is very large. Thus, if the high-temperature heating medium flows into the evaporator at the time of starting the operation, the temperature of the evaporator may suddenly increase.
CITATION LIST Patent Literature
Patent Literature 1: Japanese Unexamined Patent Publication No. 2014-47632
SUMMARY OF INVENTION
An object of the present invention is to provide a thermal energy recovery device capable of suppressing a sudden increase of a thermal stress generated in an evaporator at the time of starting an operation and a startup operation method for the same.
To achieve the above object, a thermal energy recovery device according to one aspect of the present invention includes a working fluid circulation flow path for circulating a working fluid, a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state, an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path, and a control unit for controlling a startup operation of the thermal energy recovery device. The control unit executes a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation.
A startup operation method for thermal energy recovery device according to one aspect of the present invention is a startup operation method for thermal recovery device with an evaporation unit for evaporating a working fluid flowing in a working fluid circulation flow path by heat of a heating fluid flowing in a thermal fluid circulation flow path, wherein a suppression control for suppressing a temperature of the working fluid in the evaporation unit is executed in a startup operation of the thermal energy recovery device.
BRIEF DESCRIPTION OF DRAWINGS
FIG. 1 is a diagram showing a schematic configuration of a thermal energy recovery device according to a first embodiment of the present invention,
FIG. 2 is a graph showing temperature transitions of a working fluid and hot water in the thermal energy recovery device,
FIG. 3 is a chart showing a control operation of a startup operation of the thermal energy recovery device,
FIG. 4 is a chart showing a control operation of a stop operation of the thermal energy recovery device,
FIG. 5 is a diagram showing a schematic configuration of a thermal energy recovery device according to a modification of the first embodiment of the present invention,
FIG. 6 is a diagram showing a schematic configuration of a thermal energy recovery device according to a second embodiment of the present invention,
FIG. 7 is a graph showing temperature transitions of a working fluid and hot water in the thermal energy recovery device,
FIG. 8 is a chart showing a control operation of a normal operation of the thermal energy recovery device,
FIG. 9 is a diagram showing a schematic configuration of a thermal energy recovery device as a reference example, and
FIG. 10 is a graph showing temperature transitions of a working fluid and hot water in the reference example.
DESCRIPTION OF EMBODIMENTS First Embodiment
A thermal energy recovery device according to a first embodiment of the present invention is described with reference to the drawings.
As shown in FIG. 1, the thermal energy recovery device 1 includes a working fluid circulation flow path for circulating a working fluid while being accompanied by a phase change (hereinafter, merely referred to as a “circulation flow path”) 22, a thermal fluid circulation flow path 30 for circulating hot water serving as a pressurized heating fluid in a liquid state, and a control unit 50.
A heater 32 is provided in the thermal fluid circulation flow path 30. This heater 32 includes a heating medium flow path 32 a in which a heating medium (high-temperature gas such as corrosive gas) in a gas phase flows and a thermal fluid flow path 32 b in which hot water flows. The heating medium in the heating medium flow path 32 a and the hot water in the thermal fluid flow path 32 b exchange heat in the heater 32. In this way, the hot water is heated. The thermal energy recovery device 1 recovers thermal energy of the heating medium. In the recovery device 1, this thermal energy of the heating medium is temporarily recovered in the hot water of the thermal fluid circulation flow path 30. Since the thermal fluid circulation flow path 30 is interposed between a pipe 34 in which the heating medium flows and the circulation flow path 22 in which the working fluid is circulated, the heating medium does not flow into later-described evaporator 10 and preheater 12 provided in the circulation flow path 22. Thus, even if the heating medium is corrosive gas, the corrosion of the evaporator 10 and the preheater 12 can be prevented.
The heating medium flow path 32 a is connected to a heating pipe 35 branched from the pipe 34 in which the heating medium flows. A flow rate of the heating medium flowing into the heater 32 can be adjusted by changing an opening of a flow rate control value Va1 provided in the heating pipe 35. Note that the flow rate control valve Va1 may be arranged upstream of the heater 32 in the heating pipe 35 or may be arranged downstream of the heater 32.
The evaporator 10, the preheater 12, an energy recovery unit 13, a condenser 18 and a pump 20 are provided in the circulation flow path 22.
The evaporator 10 includes a first flow path 10 a in which the working fluid flows and a second flow path 10 b in which the hot water flows. The evaporator 10 performs heat exchange between the hot water in the thermal fluid circulation flow path 30 and the working fluid (HFC245fa or the like) in the circulation flow path 22. In this way, the working fluid evaporates. In this embodiment, a brazing plate type heat exchanger is used as the evaporator 10. However, a so-called shell-and-tube type heat exchanger may be used as the evaporator 10.
The preheater 12 is arranged between the evaporator 10 and the pump 20 in the circulation flow path 22. The preheater 12 includes a first flow path 12 a in which the working fluid flows and a second flow path 12 b in which the hot water flows. The preheater 12 performs heat exchange between the hot water flowing out from the evaporator 10 and the working fluid before flowing into the evaporator 10. In this way, the working fluid is heated. In this embodiment, a brazing plate type heat exchanger is used also as the preheater 12. However, a so-called shell-and-tube heat exchanger may be used as the preheater 12 as in the case of the evaporator 10.
In the first embodiment, an evaporation unit for evaporating the working fluid includes the evaporator 10 and the preheater 12 provided separately from the evaporator 10. However, there is no limitation to this. As shown in FIG. 5, the evaporator 10 functioning as the evaporation unit may be provided, whereas the preheater may be omitted.
The energy recovery unit 13 includes an expander 14 and a power recovery device 16. The expander 14 is provided in a part of the circulation flow path 22 downstream of the evaporator 10. Thus, the preheater 12, the evaporator 10, the expander 14, the condenser 18 and the pump 20 are connected to the circulation flow path 22 in this order. The expander 14 expands the working fluid in a gas phase flowing out from the evaporator 10. In this embodiment, a positive displacement screw expander including a rotor to be rotationally driven by expansion energy of the working fluid in a gas phase flowing out from the evaporator 10 is used as the expander 14. Specifically, the expander 14 includes a pair of male and female screw rotors.
The power recovery device 16 is connected to the expander 14. In this embodiment, a power generator is used as the power recovery device 16. This power recovery device 16 includes a rotary shaft connected to one of the pair of screw rotors of the expander 14. The power recovery device 16 generates power as the rotary shaft rotates according to the rotation of the screw rotor. Note that, instead of the power generator, a compressor or the like may be used as the power recovery device 16.
An isolation valve V-1 is provided in a part of the circulation flow path 22 between the evaporator 10 and the expander 14. Further, a bypass flow path 24 bypassing the isolation valve V-1 and the expander 14 is provided in the circulation flow path 22. An on-off valve V-2 is provided in the bypass flow path 24.
The condenser 18 is provided in a part of the circulation flow path 22 downstream of the expander 14. The condenser 18 condenses (liquefies) the working fluid flowing out from the expander 14 by cooling the working fluid with a cooling medium (cooling water or the like) supplied from outside. The cooling medium is supplied through a cooling medium flow path 37, for example, from a cooling tower connected to the cooling medium flow path 37.
The pump 20 is provided in a part of the circulation flow path 22 downstream of the condenser 18 (part between the condenser 18 and the preheater 12). The pump 20 pressurizes the working fluid in a liquid phase to a predetermined pressure and feeds the pressurized working fluid to the preheater 12. A centrifugal pump including an impeller as a rotor, a gear pump including a rotor composed of a pair of gears, a screw pump, a trochoid pump or the like is used as the pump 20.
The heating fluid is sealed in a pressurized state in the thermal fluid circulation flow path 30. Specifically, the hot water is sealed in a pressurized state in the thermal fluid circulation flow path 30. Further, the evaporator 10, the preheater 12, a buffer tank 38, a fluid pump 40 and the heater 32 are arranged in this order in the thermal fluid circulation flow path 30. The hot water successively flows through the evaporator 10, the preheater 12, the buffer tank 38, the fluid pump 40 and the heater 32. The buffer tank 38 is provided on a suction side of the fluid pump 40. By providing the buffer tank 38, a predetermined pressure (head pressure) can be applied to the suction side of the fluid pump 40.
The thermal energy recovery device 1 is provided with an inlet-side working fluid temperature sensor Tr1, an outlet-side working fluid temperature sensor Tr2, an inlet-side hot water temperature sensor Tw1 and an outlet-side hot water temperature sensor Tw2. The inlet-side working fluid temperature sensor Tr1 detects a temperature of the working fluid on an inlet side of the evaporation unit, i.e. the preheater 12 and outputs a signal indicative of a detection value. The outlet-side working fluid temperature sensor Tr2 detects a temperature of the working fluid on an outlet side of the evaporation unit, i.e. the evaporator 10 and outputs a signal indicative of a detection value. The inlet-side hot water temperature sensor Tw1 detects a temperature of the hot water on an inlet side of the evaporation unit, i.e. the evaporator 10 and outputs a signal indicative of a detection value. The outlet-side hot water temperature sensor Tw2 detects a temperature of the hot water on an outlet side of the evaporation unit, i.e. the preheater 12 and outputs a signal indicative of a detection value.
The signals output from these sensors Tr1, Tr2, Tw1 and Tw2 are input to the control unit 50. The control unit 50 executes a suppression control for suppressing a temperature difference between the hot water and the working fluid in the evaporator 10 and the preheater 12 during a startup operation of the thermal energy recovery device 1. As shown in FIG. 2, the temperature of the working fluid increases from a temperature tr1 on the inlet side of the preheater 12 to a temperature tr3 by being heated by the hot water in the preheater 12 and the evaporator 10. Then, the working fluid evaporated in the evaporator 10 is further heated in the evaporator 10 to reach a temperature tr2. In contrast, the temperature of the hot water gradually decreases from a temperature tw1 on the inlet side of the evaporator 10 and reaches a temperature tw2 on the outlet side of the preheater 12. Since the working fluid undergoes a phase change in the evaporator 10, a temperature change amount is small. In contrast, a temperature change amount of the working fluid is large in the preheater 12. Thus, a temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 increases. Particularly, since the temperature of the working fluid is low in some cases during the startup operation, the temperature difference Δt tends to increase and a thermal stress generated in the preheater 12 possibly becomes problematic.
Accordingly, the control unit 50 executes the suppression control for suppressing the temperature difference between the hot water and the working fluid in the evaporator 10 and the preheater 12 during the startup operation.
Next, a control operation of the startup operation is described with reference to FIG. 3. During the startup operation for starting the thermal energy recovery device 1, an operator first confirms that the flow rate control valve Va1 is closed, the isolation valve V-1 is closed and the on-off valve V-2 in the bypass flow path 24 is open (Step ST1). Then, the operator operates an unillustrated start button. In this way, the pump 20 and the fluid pump 40 start operating (Step ST2). Further, the operation of the cooling tower is started, whereby the cooling medium is supplied to the condenser 18 through the cooling medium flow path 37 (Step ST3).
Subsequently, the control unit 50 controls to slightly open the flow rate control valve Va1 (Step ST4). At this time, the opening is set at a value set in advance such as α %. The control unit 50 controls to gradually increase the opening of the flow rate control valve Va1 (Step ST5). In this way, the temperature of the hot water gradually increases. At this time, the temperature tw1 of the hot water on the inlet side of the evaporator 10 is monitored by the inlet-side hot water temperature sensor Tw1. The control unit 50 gradually increases the opening of the flow rate control valve Va1 until the temperature reaches an operation start temperature (e.g. 90° C.) set in advance. However, the operation start temperature is not limited to 90° C. and, for example, a range of about ±5° C. is allowed. When the temperature tw1 of the hot water on the inlet side of the evaporator 10 reaches the operation start temperature, the control unit 50 opens the isolation valve V-1 and closes the on-off valve V-2 in the bypass flow path 24. In this way, the expander 14 is driven to start power recovery by the power recovery device 16 (Step ST6). Then, it is confirmed whether or not the operation (power generation) has been continuously stably performed for a given time (Step ST7).
After the drive of the expander 14 is started, the control unit 50 controls to gradually increases the opening of the flow rate control valve Va1 with the temperatures monitored by the respective temperature sensors Tr1, Tr2, Tw1 and Tw2 (Step ST8). At this time, a rate of increasing the opening of the flow rate control valve Va1 is so set that a temperature increase rate ΔT (C°/min) of the temperature tw1 of the hot water on the inlet side of the evaporator 10 is larger than a temperature increase rate when the temperature is below the operation start temperature.
In Step ST8, the temperature tw1 of the hot water on the inlet side of the evaporator 10 is monitored and, if the temperature tw1 of the hot water is below a temperature set in advance, the control unit 50 gradually increases the opening of the flow rate control valve Va1 as described above. If the temperature tw1 of the hot water is equal to or higher than the temperature set in advance, the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 is also monitored. Then, the control unit 50 executes the suppression control to gradually increase the opening of the flow rate control valve Va1 in such a range where the temperature difference Δt does not exceed a value set in advance. In this way, the temperature tw1 of the hot water on the inlet side of the evaporator 10 gradually increases and the temperature tw2 of the hot water on the outlet side of the preheater 12 also gradually increases. On the other hand, the temperature difference Δt between the temperature tw2 and the temperature tr1 is suppressed to be equal to or lower than a predetermined temperature and does not become excessive. Specifically, an input heat quantity increase rate from the hot water in the evaporator 10 and the preheater 12 is suppressed. Thus, a thermal stress by the thermal expansion of the preheater 12 does not become excessive. Note that a rotation speed of the fluid pump 40 may also be adjusted in association with an opening adjustment of the flow rate control valve Va1. Specifically, the rotation speed of the fluid pump 40 may be adjusted to further finely adjust the temperature by the flow rate control valve Va1.
The control unit 50 judges whether or not the temperature tw1 of the hot water on the inlet side of the evaporator 10 has reached an operating temperature (e.g. 130° C.) set in advance (Step ST9) and the startup operation transitions to a normal operation by an automatic operation when the temperature tw1 reaches the operating temperature (Step ST10). In the normal operation, the temperature tw1 of the hot water on the inlet side of the evaporator 10 is, for example, about 130° C., and the temperature of the hot water on the outlet side of the evaporator 10 is, for example, about 115° C. Further, the temperature tw2 of the hot water on the outlet side of the preheater 12 is, for example, about 100° C. On the other hand, the temperature of the working fluid on the inlet side of the preheater 12 is, for example, about 20° C. at the start of the operation, but reaches, for example, about 40° C. during the normal operation. The temperature of the working fluid on the outlet side of the evaporator 10 is, for example, about 120° C.
FIG. 4 shows a stop flow during the automatic operation. As shown in FIG. 4, when an emergency stop signal is issued (Step ST21), the control unit 50 closes the isolation valve V-1 and opens the on-off valve V-2 in the bypass flow path 24 (Step ST22). In this way, the working fluid bypasses the expander 14, wherefore power generation is stopped. Then, the flow rate control valve Va1 is closed (Step ST23). Since the temperature of the hot water circulating in the thermal fluid circulation flow path 30 decreases in this way, the input heat quantities to the evaporator 10 and the preheater 12 decrease. Then, the pump 20 and a hot water pump are stopped (Step ST24). At this time, the operation of the cooling tower is maintained (Step ST25).
As described above, in this embodiment, heat exchange is performed between the hot water introduced from the thermal fluid circulation flow path 30 and the working fluid introduced from the circulation flow path 22 in the evaporator 10 and the preheater 12. Since the pressurized hot water in a liquid state flows into the evaporator 10 and the preheater 12, thermal energy introduced to the evaporator 10 and the preheater 12 is large. Thus, in the startup operation in which the temperature of the working fluid is relatively low, the suppression control is executed to suppress the temperature difference between the hot water and the working fluid in the evaporator 10 and the preheater 12. Therefore, it can be suppressed that large thermal stresses are generated in the evaporator 10 and the preheater 12 during the startup operation.
Further, in this embodiment, if the temperature of the hot water is equal to or higher than the predetermined temperature set in advance, the input heat quantities in the evaporator 10 and the preheater 12 are suppressed such that the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 is equal to or lower than the predetermined temperature. Thus, it can be reliably suppressed that the thermal stresses in the evaporator 10 and the preheater 12 become excessive at the start of the operation. Specifically, the temperature difference between the temperature tw2 of the hot water on the outlet side and the temperature tr1 of the working fluid on the inlet side is largest in the preheater 12. Thus, by executing the suppression control on the basis of this temperature difference between the both, it can be reliably suppressed that the terminal stress in the preheater 12 becomes excessive.
Further, in this embodiment, the control unit 50 adjusts the opening of the flow rate control valve Va1 in the startup operation, whereby the temperature difference Δt between the temperature tw2 of the hot water on the outlet side and the temperature tr1 of the working fluid on the inlet side is maintained to be equal to or lower than the predetermined temperature. Thus, it can be suppressed that the thermal stress in the preheater 12 becomes excessive by a simple operation of adjusting the opening of the flow rate control valve Va1.
Further, in this embodiment, the suppression control is executed to control the temperature difference Δt between the hot water and the working fluid in the startup operation. Thus, even if the temperature of the preheater 12 is relatively low before the startup operation, a sudden temperature increase of the preheater 12 can be suppressed. Therefore, it can be suppressed that the thermal stress generated in the preheater 12 suddenly increases at the start of the operation.
Second Embodiment
FIG. 6 shows a second embodiment of the present invention. Note that the same constituent elements as in the first embodiment are denoted by the same reference signs and the detailed description thereof is omitted here.
In the second embodiment, a cooler 53 is provided in a thermal fluid circulation flow path 30 and a temperature difference Δt between a temperature tw2 of hot water on an outlet side of a preheater 12 and a temperature tr1 of a working fluid on an inlet side of the preheater 12 is reduced by operating the cooler 53.
The cooler 53 is for reducing the temperature of the hot water through heat exchange between a cooling medium (air, water or the like) and the hot water. If air is used as the cooling medium, a fan 54 for generating an air flow is provided. By driving the fan 54, the cooler 53 operates. In this way, the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side is controlled to or below a predetermined temperature. Note that if water is used as the cooling medium, an unillustrated pump is provided and the cooler 53 operates by driving the pump.
In the second embodiment, a temperature tw4 of the hot water on an inlet side of the preheater 12 becomes lower than a temperature tw3 of the hot water on an outlet side of the evaporator 10 as shown in FIG. 7 by operating the cooler 53. In this way, the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 is suppressed to be equal to or lower than the predetermined temperature. Note that the temperature of the hot water exhibits a temperature transition shown in FIG. 2 in a state where the cooler 53 is not operated.
In the thermal energy recovery device 1 according to the second embodiment, whether or not the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 is equal to or lower than the temperature set in advance during the normal operation is monitored by the control unit 50 (Step ST31) as shown in FIG. 8. If the temperature difference Δt is judged to have exceeded the temperature set in advance, the control unit 50 operates the cooler 53 (Step ST32). In this way, the temperature on the inlet side of the preheater 12 decreases to reduce the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12. If the temperature difference Δt is further monitored and judged to be within the temperature set in advance, the control unit 50 stops the cooler 53 (Step ST54).
As just described, in the second embodiment, the control unit 50 operates the cooler 53 if the temperature difference Δt between the hot water and the working fluid exceeds the predetermined temperature. In this way, the temperature of the hot water flowing in the thermal fluid circulation flow path 30 decreases. Thus, the temperature difference Δt between the hot water and the working fluid in the preheater 12 can be reduced.
Note that the other configurations, functions and effects are not described, but are the same as in the first embodiment.
Here, a reference example for reducing the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 is mentioned. As shown in FIG. 9, a regenerator 58 is provided between a pump 20 and the preheater 12 in a circulation flow path 22. This regenerator 58 heats the working fluid flowing from the pump 20 toward the preheater 12 by the working fluid discharged from an expander 14 and flowing toward a condenser 18. In this way, the temperature difference Δt in the preheater 12 can be reduced by increasing the temperature of the working fluid before flowing into the preheater 12. Specifically, as shown in FIG. 10, if the temperature of the working fluid discharged from the pump 20 is tr0, this temperature reaches a temperature tr1 since the working fluid is heated by the regenerator 58 before flowing into the preheater 12. As a result, the temperature difference Δt between the temperature tw2 of the hot water on the outlet side of the preheater 12 and the temperature tr1 of the working fluid on the inlet side of the preheater 12 is reduced.
SUMMARY OF EMBODIMENTS
Here, the above embodiments are outlined.
(1) A thermal energy recovery device of the above embodiment includes a working fluid circulation flow path for circulating a working fluid, a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state, an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path, and a control unit for controlling a startup operation of the thermal energy recovery device. The control unit executes a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation.
In the above recovery device, since the pressurized heating fluid in a liquid state flows into the evaporation unit, thermal energy introduced to the evaporation unit is large. In the evaporation unit, heat exchange is performed between the heating fluid in a liquid state introduced from the thermal fluid circulation flow path and the working fluid introduced from the working fluid circulation flow path. Thus, in the startup operation in which the temperature of the working fluid is relatively low, the suppression control is executed to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit. Therefore, it can be suppressed that a large thermal stress is generated in the evaporation unit during the startup operation.
(2) The suppression control may be a control for setting a temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit equal to or lower than a predetermined temperature set in advance when the temperature of the heating fluid flowing into the evaporation unit is equal to or higher than a temperature set in advance.
In this mode, an input heat quantity in the evaporation unit is so suppressed that a temperature difference between the temperature of the heating fluid on an outlet side of the evaporation unit and the temperature of the working fluid on an inlet side of the evaporation unit becomes equal to or lower than the predetermined temperature when the temperature of the heating fluid is equal to or higher than the predetermined temperature set in advance. Thus, it can be reliably suppressed that the thermal stress in the evaporation unit becomes excessive during the startup operation. Specifically, the temperature difference between the temperature of the heating fluid on the outlet side and the temperature of the working fluid on the inlet side is largest in the evaporation unit. Thus, by executing the suppression control on the basis of this temperature difference between the both, it can be reliably suppressed that the thermal stress in the evaporation unit becomes excessive.
(3) The above thermal energy recovery device may include a heater provided in the thermal fluid circulation flow path for heating the heating fluid with heat of a heating medium in a gas state and a flow rate control valve for adjusting a flow rate of the heating medium introduced into the heater. In this case, the control unit may adjust an opening of the flow rate control valve such that the temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit is maintained to be equal to or lower than the predetermined temperature in the startup operation.
In this mode, the temperature difference is maintained to be equal to or lower than the predetermined temperature by the control unit adjusting the opening of the flow rate control valve in the startup operation. Thus, it can be suppressed that the thermal stress in the evaporation unit becomes excessive by a simple operation of adjusting the opening of the flow rate control valve.
(4) The above thermal energy recovery device may include a cooler for cooling the heating fluid flowing in the thermal fluid circulation flow path with a cooling medium. In this case, the control unit may operate the cooler to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit.
In this mode, the control unit operates the cooler, for example, when the temperature difference between the heating fluid and the working fluid in the evaporation unit exceeds the predetermined temperature. In this way, the temperature of the heating fluid flowing in the thermal fluid circulation flow path decreases. Thus, the temperature difference between the heating fluid and the working fluid in the evaporation unit can be reduced.
(5) The evaporation unit may include an evaporator for evaporating the working fluid by the heat of the heating fluid flowing in the thermal fluid circulation flow path and a preheater for heating the working fluid before flowing into the evaporator by the heat of the heating fluid flowing in the thermal fluid circulation flow path.
In this mode, thermal energy introduced to the preheater may increase, but the suppression control for suppressing the temperature difference between the heating fluid and the working fluid is executed in the startup operation. Thus, even if the temperature of the working fluid in the preheater is relatively low before the startup operation, a sudden temperature increase of the preheater can be suppressed. Therefore, a sudden increase of a thermal stress generated in the preheater at the start of the operation can be suppressed.
(6) A startup operation method for thermal energy recovery device of the above embodiment is a startup operation method for thermal energy recovery device with an evaporation unit for evaporating working fluid flowing in a working fluid circulation flow path by heat of a heating fluid flowing in a thermal fluid circulation flow path, wherein a suppression control for suppressing a temperature of the working fluid in the evaporation unit is executed in a startup operation of the thermal energy recovery device.
(7) A heater for heating the heating fluid by heat of a heating medium in a gas state may be provided in the thermal fluid circulation flow path. In this case, in the above startup operation method for thermal energy recovery device, an opening of a flow rate control valve for adjusting a flow rate of the heating medium introduced into the heater may be adjusted such that a temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit is maintained to be equal to or lower than the predetermined temperature.
(8) A cooler for cooling the heating fluid flowing in the thermal fluid circulation flow path by a cooling medium may be provided. In this case, the above startup operation method for thermal energy recovery device may include operating the cooler to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit if the temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit exceeds a temperature set in advance.
As described above, a sudden increase of a thermal stress generated in the evaporation unit at the start of the operation can be suppressed.

Claims (4)

The invention claimed is:
1. A thermal energy recovery device, comprising:
a working fluid circulation flow path for circulating a working fluid;
a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state;
an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path; and
a control unit for controlling a startup operation of the thermal energy recovery device;
the control unit executing a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation,
wherein the suppression control is a control for setting a temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit equal to or lower than a predetermined temperature set in advance when the temperature of the heating fluid flowing into the evaporation unit is equal to or higher than a temperature set in advance.
2. A thermal energy recovery device according to claim 1, wherein the evaporation unit includes an evaporator for evaporating the working fluid by the heat of the heating fluid flowing in the thermal fluid circulation flow path and a preheater for heating the working fluid before flowing into the evaporator by the heat of the heating fluid flowing in the thermal fluid circulation flow path.
3. A thermal energy recovery device comprising:
a working fluid circulation flow path for circulating a working fluid;
a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state;
an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path;
a control unit for controlling a startup operation of the thermal energy recovery device, the control unit executing a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation;
a heater provided in the thermal fluid circulation flow path for heating the heating fluid with heat of a heating medium in a gas state; and
a flow rate control valve for adjusting a flow rate of the heating medium introduced into the heater;
wherein the control unit adjusts an opening of the flow rate control valve such that the temperature difference between the heating fluid flowing out from the evaporation unit and the working fluid flowing into the evaporation unit is maintained to be equal to or lower than the predetermined temperature in the startup operation.
4. A thermal energy recovery device comprising
a working fluid circulation flow path for circulating a working fluid;
a thermal fluid circulation flow path for circulating a pressurized heating fluid in a liquid state;
an evaporation unit for evaporating the working fluid flowing in the working fluid circulation flow path by heat of the heating fluid flowing in the thermal fluid circulation flow path;
a control unit for controlling a startup operation of the thermal energy recovery device, the control unit executing a suppression control for suppressing a temperature difference between the heating fluid and the working fluid in the evaporation unit in the startup operation; and
a cooler for cooling the heating fluid flowing in the thermal fluid circulation flow path with a cooling medium,
wherein the control unit operates the cooler to suppress the temperature difference between the heating fluid and the working fluid in the evaporation unit.
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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5799223A (en) 1980-12-10 1982-06-19 Chiyoda Chem Eng & Constr Co Ltd Power collector device from lng by rankin cycle and its start-up method
JPS5865917A (en) 1981-10-15 1983-04-19 Takuma Sogo Kenkyusho:Kk Power generating device of exhaust heat recovery in diesel engine
JPS58104401A (en) 1981-12-17 1983-06-21 株式会社東芝 Method and device for controlling quantity of ventilation of steam generator
JPS6296704A (en) 1985-10-23 1987-05-06 Toshiba Corp Hot water turbine plant
JPH01237309A (en) 1988-03-16 1989-09-21 Hitachi Ltd Generating equipment using lng cryogenic heat
US20120031096A1 (en) 2010-08-09 2012-02-09 Uop Llc Low Grade Heat Recovery from Process Streams for Power Generation
DE102011004263A1 (en) 2011-02-17 2012-08-23 Siemens Aktiengesellschaft Method for operating a solar-heated waste heat steam generator and solar thermal waste heat steam generator
US20120285167A1 (en) * 2006-11-15 2012-11-15 Jon Horek Heat recovery system and method
US20130047614A1 (en) 2010-05-13 2013-02-28 Turboden S.R.L. High temperature orc system
JP2014047632A (en) 2012-08-29 2014-03-17 Kobe Steel Ltd Power generation device and method of controlling power generation device
US20150013335A1 (en) * 2013-07-09 2015-01-15 Volkswagen Aktiengesellschaft Heat exchange device and drive unit for a motor vehicle
US20160047540A1 (en) 2010-11-17 2016-02-18 Technische Universitaet Muenchen Method and Apparatus For Evaporating Organic Working Media
US20170284230A1 (en) * 2007-03-02 2017-10-05 Victor Juchymenko Controlled organic rankine cycle system for recovery and conversion of thermal energy
US20190226364A1 (en) * 2016-06-27 2019-07-25 Fives Stein Method and facility for recovering thermal energy on a furnace with tubular side members and for converting same into electricity by means of a turbine producing the electricity by implementing a rankine cycle

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL114123A (en) * 1994-06-14 2004-07-25 Ormat Ind Ltd Gas turbine system with heat recovery cycle and method for using the same
JP2007327661A (en) * 2006-06-06 2007-12-20 Babcock Hitachi Kk Exhaust heat recovery boiler
EP2224164A1 (en) * 2008-11-13 2010-09-01 Siemens Aktiengesellschaft Method of operating a waste heat steam generator
IT1402363B1 (en) * 2010-06-10 2013-09-04 Turboden Srl ORC PLANT WITH SYSTEM TO IMPROVE THE HEAT EXCHANGE BETWEEN THE SOURCE OF WARM FLUID AND WORK FLUID
US20130160449A1 (en) * 2011-12-22 2013-06-27 Frederick J. Cogswell Cascaded organic rankine cycle system
JP6194274B2 (en) * 2014-04-04 2017-09-06 株式会社神戸製鋼所 Waste heat recovery system and waste heat recovery method

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5799223A (en) 1980-12-10 1982-06-19 Chiyoda Chem Eng & Constr Co Ltd Power collector device from lng by rankin cycle and its start-up method
JPS5865917A (en) 1981-10-15 1983-04-19 Takuma Sogo Kenkyusho:Kk Power generating device of exhaust heat recovery in diesel engine
JPS58104401A (en) 1981-12-17 1983-06-21 株式会社東芝 Method and device for controlling quantity of ventilation of steam generator
JPS6296704A (en) 1985-10-23 1987-05-06 Toshiba Corp Hot water turbine plant
JPH01237309A (en) 1988-03-16 1989-09-21 Hitachi Ltd Generating equipment using lng cryogenic heat
US20120285167A1 (en) * 2006-11-15 2012-11-15 Jon Horek Heat recovery system and method
US20170284230A1 (en) * 2007-03-02 2017-10-05 Victor Juchymenko Controlled organic rankine cycle system for recovery and conversion of thermal energy
US20130047614A1 (en) 2010-05-13 2013-02-28 Turboden S.R.L. High temperature orc system
US20120031096A1 (en) 2010-08-09 2012-02-09 Uop Llc Low Grade Heat Recovery from Process Streams for Power Generation
US20160047540A1 (en) 2010-11-17 2016-02-18 Technische Universitaet Muenchen Method and Apparatus For Evaporating Organic Working Media
DE102011004263A1 (en) 2011-02-17 2012-08-23 Siemens Aktiengesellschaft Method for operating a solar-heated waste heat steam generator and solar thermal waste heat steam generator
JP2014047632A (en) 2012-08-29 2014-03-17 Kobe Steel Ltd Power generation device and method of controlling power generation device
US20150013335A1 (en) * 2013-07-09 2015-01-15 Volkswagen Aktiengesellschaft Heat exchange device and drive unit for a motor vehicle
US20190226364A1 (en) * 2016-06-27 2019-07-25 Fives Stein Method and facility for recovering thermal energy on a furnace with tubular side members and for converting same into electricity by means of a turbine producing the electricity by implementing a rankine cycle

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
International Preliminary Report on Patentability and Written Opinion issued in PCT/JP2017/041132; dated Jun. 13, 2019.
The extended European search report issued by the European Patent Office on May 27, 2020, which corresponds to European Patent Application No. 17875253.1-1008 and is related to U.S. Appl. No. 16/464,696.

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EP3536915A1 (en) 2019-09-11
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WO2018101043A1 (en) 2018-06-07
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