US1003806A - Article composed of titanium and nickel alloyed together and method of producing the same. - Google Patents
Article composed of titanium and nickel alloyed together and method of producing the same. Download PDFInfo
- Publication number
- US1003806A US1003806A US60116511A US1911601165A US1003806A US 1003806 A US1003806 A US 1003806A US 60116511 A US60116511 A US 60116511A US 1911601165 A US1911601165 A US 1911601165A US 1003806 A US1003806 A US 1003806A
- Authority
- US
- United States
- Prior art keywords
- nickel
- titanium
- alloy
- producing
- same
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title description 54
- 229910052759 nickel Inorganic materials 0.000 title description 26
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title description 17
- 239000010936 titanium Substances 0.000 title description 17
- 229910052719 titanium Inorganic materials 0.000 title description 17
- 238000000034 method Methods 0.000 title description 7
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 239000004411 aluminium Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 229910000990 Ni alloy Inorganic materials 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910002056 binary alloy Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- -1 slags Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
Definitions
- the ferric metal and also the" nickel contain impurities, being undesired elements and compounds including slags, etc, which it is desirable should if possible be climinat'ed.
- Titanium in quantity proportioned to satisfy the chemical atlinities of such undesired elements and compounds is as l have heretofore discovcrtal etlicient to insure their removal when added to the ferric hath containing them as an alloy of titanium with ferric metal; I have now discovered that: the etticiency of titanium in the particular mentioned is not. impaired by its association with nickel in'alloy therewith, and therefore my said novel alloy is of important utility in attain these ob-.
- My novel alloy of titanium with nickcl'l produce as follows :-I charge into a graphite crucible or other container properly tttltlptltl. nickel, titanic acid, and preferably an oxid of nickel, also such an amount of aluminium (preferably in shots or the like so as to melt more rapidly) as is chemically sutlicient to decompose the oxid of titanium and also the oxid of nickel, and reduce their respective titanium and nickel contents to their metallic states.
- This mixture is then heated, as preferably in any of the well known forms of so called electric furnaces, or otherwise, to a temperature sutliciently high to insure the melting of the .n'ietallic element of the charge and the taking place of the required reactions as hereinafter noted.
- the molten product on being withdrawn and cooled will be found to'be an alloy of titanium with nickel, the percentage of the former being proportional to the amounts of titanic i acid and aluminium charged, the reactions being as per the following formula,-assuming that the oxid of nickel designated as NiO is employed.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
UNITED OFFICE.
AUGUSTE J. 30581, 01? NIAGARA FALLS, NEW YORK, ASSIGNOR TO Tl-IE TITANIUM ALLOY MANUFACTURING COMPANY, OF NEW YORK. N. Y., A CORPORATION OF MAINE.
. ARTICLE COMPOSED OF TITANIUM AND NICKEL ALLOYEID TOGETHER AND METHOD OF PRODUCING THE SAME.
No Drawing.
T 0 all whom it may concern:
lie it known. that I, Arctsrn J. ltossi, a citizen of the t uited States, and a resident of Niagara Falls, in the county of Niagara and State of New York, have in vented a ccrtain new and useful Article Composed of 'litanium. and Nickel Alloyed 'llogetlnaf and Method of lroducing the Same, of which the following is a specification.
[t has heretofore been regarded as in'ipossible to produce'the binary alloy of titanium with nickel, and the object of my invention is to produce such alloy and to provide meth- .ods for its prtuluction so simple. economical and reliable as to justify manufacture thereof on industrial scales. jects as hereinafter described.
It has been asserted heretofore that because of the much higher melting-point of titanium as compared with that of nickel itwas impossible to produce a binary alloy of said metals since titanium added to molten nickel would chill and segregate. I have discovered lu'nvevcr that the binary alloy of titanium and nickel is producible provided the titanium is brought in nascent state into the presence of the nickel previously reduced to molten state so as to constitute a hath forthe reception of the titanimn on its reduction from an oxid thereof.
Alto of ferric metals, 1'. c. iron and steel with nickel have by now, as well known, at; tained a position of recognized high utility in the. arts as for instance under the designation of. nickel steels. Such alloys are produced by adding to a ferric metal any th sired percentage of nickel and melting the two together.
The ferric metal and also the" nickel contain impurities, being undesired elements and compounds including slags, etc, which it is desirable should if possible be climinat'ed. Titanium in quantity proportioned to satisfy the chemical atlinities of such undesired elements and compounds is as l have heretofore discovcrtal etlicient to insure their removal when added to the ferric hath containing them as an alloy of titanium with ferric metal; I have now discovered that: the etticiency of titanium in the particular mentioned is not. impaired by its association with nickel in'alloy therewith, and therefore my said novel alloy is of important utility in attain these ob-.
Specification of Letters Patent.
Application filed January 6, 1911. Serial No. 601,165.
Patented Sept. 19, 1911.
that by its addition to baths ofmoltcn ferric metalnot only is nickel alloyed with the latter but also both metals and their resulting allpy sinmltaneoi'lsly purified by the tita nium. Moreover my novel alloy is also particularly useful to so purify molten nickel intended for use by itself alone for other applications in the arts.
My novel alloy of titanium with nickcl'l produce as follows :-I charge into a graphite crucible or other container properly tttltlptltl. nickel, titanic acid, and preferably an oxid of nickel, also such an amount of aluminium (preferably in shots or the like so as to melt more rapidly) as is chemically sutlicient to decompose the oxid of titanium and also the oxid of nickel, and reduce their respective titanium and nickel contents to their metallic states. This mixture is then heated, as preferably in any of the well known forms of so called electric furnaces, or otherwise, to a temperature sutliciently high to insure the melting of the .n'ietallic element of the charge and the taking place of the required reactions as hereinafter noted. The molten product on being withdrawn and cooled will be found to'be an alloy of titanium with nickel, the percentage of the former being proportional to the amounts of titanic i acid and aluminium charged, the reactions being as per the following formula,-assuming that the oxid of nickel designated as NiO is employed.
Whil in this instance the n-esence of an ()Xtl of nickel is not absolutely essential it nevertheless promotes considerably the reactions desired in the charge and accelerates its fusion into a homogeneous metallic alloy, the heat of the formation ot such oxid being so much less than that. of the oxid of titanium as to leave available a considerable excess of heat due exothermally to the cmnbination of its oxygen with part of the aluminium of the bath. In this manner an alloy of nickel with ti tanium containing any (lLrdlPtl percent-age of titanium may be prot luced. Moreover such use of an oxid of nickel, or even its substitution entirely for the metal in said process, is st.nnetimes economically desirable, the cost of such oxid being usually less than that of the metal, and such entire substitution being possible in the produc-' tion of my said alloy by my said process. I have also discovered that my said alloy of nickel with titanium may, in some instances, be advantageously produced by substituting carbon for aluminium as the reducing agent, in which. case it is essential in industrial practice to employ the higher temperatures derivable for instance from some of the now well known forms of so-called electric furnaces, such for example as illustrated and described in Letters Patent No. 802,941 granted to me October 4, 1905. In this case o-xid of nickel, oxid of titanium, and carbon are mixed together as for instance as per the formula 01' the ingredients used in the charge will be varied according to the percentage of the respective metals desired in the alloy according to the formulas above given and as experience and test in each case will readily demonstrate to those skilled in the metallurgical art.
What I claim as new and desire to secure by Letters Patent is the following, viz
1. As a new article an alloy of titanium with nickel.
2. The process of producing an alloy of titanium with nickel which comprises in corporating titanic acid into a bath' of molten nickel in presence of a reducing agent, subjecting the bath to a temperature sufiicient' to insure reduction of said titanic acid by said agent, and withdrawing and cooling the resulting metallic product.
3. The method of producing an alloy of nickel with titanium which comprises incorporating titanic acid into a bath comprising molten nickel and molten aluminium, subjecting the bath to a temperature sutlicient to insure reduction of said titanic acld by said aluminium and withdrawing and cooling the resulting metallic product.
AUGUSTE J. RossI. WVitnesses WALTER D. EDMONDS, GEORGE G. MEAsUREs.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60116511A US1003806A (en) | 1911-01-06 | 1911-01-06 | Article composed of titanium and nickel alloyed together and method of producing the same. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US60116511A US1003806A (en) | 1911-01-06 | 1911-01-06 | Article composed of titanium and nickel alloyed together and method of producing the same. |
Publications (1)
Publication Number | Publication Date |
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US1003806A true US1003806A (en) | 1911-09-19 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US60116511A Expired - Lifetime US1003806A (en) | 1911-01-06 | 1911-01-06 | Article composed of titanium and nickel alloyed together and method of producing the same. |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3529958A (en) * | 1966-11-04 | 1970-09-22 | Buehler William J | Method for the formation of an alloy composed of metals reactive in their elemental form with a melting container |
-
1911
- 1911-01-06 US US60116511A patent/US1003806A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3529958A (en) * | 1966-11-04 | 1970-09-22 | Buehler William J | Method for the formation of an alloy composed of metals reactive in their elemental form with a melting container |
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