TWM536673U - Glued glass recovery apparatus - Google Patents
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本創作係有關於一種膠合玻璃回收裝置，尤其是指一種能將廢棄之ＰＶＢ膠合玻璃經回收後，予以分離出完整的整片玻璃與ＰＶＢ溶液，且將該ＰＶＢ溶液進行乾燥為ＰＶＢ粉體，以能分別再次利用該分離後的玻璃及ＰＶＢ粉體，使得該廢棄之ＰＶＢ膠合玻璃不會產生污染環境之情況，以能符合環保概念，而在其整體施行使用上更增實用功效特性的膠合玻璃回收裝置創新設計者。The present invention relates to a glued glass recycling device, in particular to a method for recovering a waste PVB glued glass, separating a complete whole glass and a PVB solution, and drying the PVB solution into a PVB powder. In order to re-use the separated glass and PVB powder separately, the discarded PVB glued glass does not cause environmental pollution, and can be adhered to the environmental protection concept, and the utility model has more practical utility characteristics. Innovative designer of glass recycling equipment.
按，由於現在科技迅速發展及人們對生活品質要求日益提高，使得玻璃不僅被廣泛應用在建築工藝以及人們的日常生活中，更進一步發展成為最新科技產品所不可缺少之新材料；但這也造成了大量廢棄玻璃的產生，每天在一般生活垃圾中及玻璃工廠皆會有各式廢玻璃與工業玻璃廢料大量產生。而於近年來，隨著人們對節能環保要求的提高，膠合玻璃因著其節能、安全、隔音的特性，使得人類對膠合玻璃的需求也越來越高，大大的提升膠合玻璃之使用率。According to the rapid development of science and technology and the increasing demand for quality of life, glass is not only widely used in construction technology and people's daily life, but also further developed into a new material that is indispensable for the latest technology products; A large amount of waste glass is produced, and various types of waste glass and industrial glass waste are produced in large quantities in general household garbage and glass factories every day. In recent years, with the improvement of people's requirements for energy conservation and environmental protection, due to its energy-saving, safe and sound-proof characteristics, the demand for glued glass has become higher and higher, and the utilization rate of glued glass has been greatly improved.
其中，該ＰＶＢ［聚乙烯醇縮丁醛］是一種常用的支撐物，其具有強結合力、高光學清晰度，且易黏於各種不同的表面，係為高韌性和高彈性的樹脂，而由於該ＰＶＢ具有良好的耐老化及防紫外線等性能，使得ＰＶＢ膠合玻璃廣為受到青睞；但，該膠合玻璃的使用卻也相對會導致有更多的廢棄膠合玻璃產生，這些廢膠合玻璃，不僅只有廢玻璃，更還有許多封裝材料［ＰＶＢ黏合膜］的產生。Among them, the PVB [polyvinyl butyral] is a commonly used support, which has strong binding force, high optical clarity, and is easy to adhere to various surfaces, and is a resin with high toughness and high elasticity, and Due to the good anti-aging and anti-UV properties of PVB, PVB glued glass is widely favored; however, the use of the glued glass will also lead to more waste glued glass, and these waste glued glass not only Only waste glass, but also a lot of packaging materials [PVB adhesive film].
於是，即有相關人員研發出一種公開於２００３年１０月７日之日本特開２００３－２８５０４２號「廢結合玻璃的處理方法及夾層ＰＶＢ樹脂的再生方法」，其係先將結合玻璃予以粉碎，以取得結合玻璃中間的ＰＶＢ層，再以有機溶劑溶解該ＰＶＢ層。Therefore, there has been a related person who has developed a method for recycling waste glass and a method for regenerating a laminated PVB resin disclosed in Japanese Patent Laid-Open No. 2003-285042, which is issued on October 7, 2003. The PVB layer in the middle of the bonded glass is obtained, and the PVB layer is dissolved in an organic solvent.
另，請再一併參閱公開於２０１４年１０月２０日之韓國專利第２０１４０１２２４５２號「自汽車及建築之強化玻璃中提取ＰＶＢ及回收強化玻璃之方法」，其係先將汽車或建築用之強化玻璃予以粉碎，分離出強化玻璃中的ＰＶＢ層，將ＰＶＢ層溶於甲醇、乙醇或甲乙酮等溶劑中，以取得ＰＶＢ溶液。In addition, please refer to Korean Patent No. 20140122452 published on October 20, 2014, "Method for extracting PVB from tempered glass from automobiles and buildings and recycling tempered glass", which is the first to strengthen automobiles or buildings. The glass is pulverized, the PVB layer in the tempered glass is separated, and the PVB layer is dissolved in a solvent such as methanol, ethanol or methyl ethyl ketone to obtain a PVB solution.
然而，上述「廢結合玻璃的處理方法及夾層ＰＶＢ樹脂的再生方法」或「自汽車及建築之強化玻璃中提取ＰＶＢ及回收強化玻璃之方法」，雖皆可達到回收結合玻璃中之ＰＶＢ樹脂的預期功效，但也在其實際施行使用過程中發現，上述方法皆需先將結合玻璃予以進行粉碎，再由粉碎後之結合玻璃中取得ＰＶＢ層，使得其不僅需另行花費人工、機具、時間對該結合玻璃進行粉碎作業，相對增加其成本支出，且由於需對該結合玻璃進行粉碎作業，即會造成無法將該結合玻璃整片回收再次使用，致令其在整體操作施行上仍存在有改進之空間。However, the above-mentioned "method for treating waste bonded glass and method for regenerating laminated PVB resin" or "method for extracting PVB from tempered glass for automobiles and buildings and for recovering tempered glass" can achieve recovery of PVB resin in bonded glass. Expected efficacy, but also found in the actual application process, the above methods need to first comminute the bonded glass, and then obtain the PVB layer from the fused glass, so that it not only costs labor, equipment, time The tempering operation of the combined glass increases the cost of the comminution, and the comminution of the conjugated glass may result in the inability to recycle the conjugated glass and reuse it, so that there is still improvement in the overall operation. Space.
緣是，創作人有鑑於此，秉持多年該相關行業之豐富設計開發及實際製作經驗，針對現有之缺失予以研究改良，提供一種膠合玻璃回收裝置，以期達到更佳實用價值性之目的者。The reason is that the creators have made a lot of research and development and practical production experience in the relevant industries for many years, and researched and improved the existing defects to provide a glued glass recycling device, in order to achieve better practical value.
本創作之主要目的在於提供一種膠合玻璃回收裝置，其主要係能將廢棄之ＰＶＢ膠合玻璃經回收後，予以分離出完整的整片玻璃與ＰＶＢ溶液，且將該ＰＶＢ溶液進行乾燥為ＰＶＢ粉體，以能分別再次利用該分離後的玻璃及ＰＶＢ粉體，使得該廢棄之ＰＶＢ膠合玻璃不會產生污染環境之情況，以能符合環保概念，而在其整體施行使用上更增實用功效特性者。The main purpose of this creation is to provide a glued glass recovery device, which is mainly capable of separating the discarded PVB glued glass and separating the whole whole glass and PVB solution, and drying the PVB solution into PVB powder. In order to re-use the separated glass and PVB powder separately, the discarded PVB glued glass does not pollute the environment, so as to conform to the environmental protection concept, and the utility model is more effective in its overall application. .
本創作膠合玻璃回收裝置之主要目的與功效，係由以下具體技術手段所達成：The main purpose and effect of the creative glued glass recycling device are achieved by the following specific technical means:
其主要係包括有清洗單元、超音波震盪單元、回收單元、脫色單元、ＰＶＢ液體析出單元、乾燥單元、第一蒸餾單元及第二蒸餾單元；其中：The utility model mainly comprises a cleaning unit, an ultrasonic vibration unit, a recovery unit, a decolorization unit, a PVB liquid deposition unit, a drying unit, a first distillation unit and a second distillation unit; wherein:
該清洗單元，其供對完整之ＰＶＢ［聚乙烯醇縮丁醛］膠合玻璃進行清洗作業；The cleaning unit for cleaning the complete PVB [polyvinyl butyral] glued glass;
該超音波震盪單元，其與該清洗單元連結，以能將清洗後的該ＰＶＢ［聚乙烯醇縮丁醛］膠合玻璃置入，且加入乙醇溶液後予以進行震盪，將ＰＶＢ膠合玻璃中之ＰＶＢ樹脂予以溶解；The ultrasonic oscillating unit is coupled to the cleaning unit to insert the cleaned PVB [polyvinyl butyral] glued glass, and after adding an ethanol solution, oscillating, and PVB in the PVB glued glass The resin is dissolved;
該回收單元，其與該超音波震盪單元連結，該回收單元供回收去除ＰＶＢ樹脂後之完整玻璃；The recovery unit is coupled to the ultrasonic oscillating unit for recovering the complete glass after removing the PVB resin;
該脫色單元，其與該超音波震盪單元連結，該脫色單元供對該超音波震盪單元所輸出溶解有ＰＶＢ樹脂之乙醇溶液混合液體，於加入脫色劑後進行加熱脫色；The decolorizing unit is coupled to the ultrasonic oscillating unit, and the decolorizing unit is configured to output a mixed liquid of the ethanol solution in which the PVB resin is dissolved in the ultrasonic oscillating unit, and perform heating and decolorizing after adding the decolorizing agent;
該ＰＶＢ液體析出單元，其與該脫色單元連結，該ＰＶＢ液體析出單元供對該脫色單元所輸出之ＰＶＢ樹脂與乙醇溶液之混合液體，於加入水和沉澱劑後析出ＰＶＢ液體；The PVB liquid deposition unit is coupled to the decolorizing unit, and the PVB liquid deposition unit supplies a mixed liquid of the PVB resin and the ethanol solution outputted by the decolorizing unit, and precipitates the PVB liquid after adding water and a precipitating agent;
該乾燥單元，其與該ＰＶＢ液體析出單元連結，該乾燥單元供對該ＰＶＢ液體析出單元所析出之ＰＶＢ液體進行加熱乾燥，而獲得ＰＶＢ粉體；The drying unit is connected to the PVB liquid precipitation unit for heating and drying the PVB liquid precipitated by the PVB liquid deposition unit to obtain PVB powder;
該第一蒸餾單元，其與該ＰＶＢ液體析出單元連結，該第一蒸餾單元供對該ＰＶＢ液體析出單元所輸出之乙醇溶液混合液體進行蒸餾作業，以回收乙醇溶液；The first distillation unit is connected to the PVB liquid precipitation unit, and the first distillation unit is configured to perform a distillation operation on the ethanol solution mixed liquid outputted by the PVB liquid deposition unit to recover the ethanol solution;
該第二蒸餾單元，其與該第一蒸餾單元連結，該第二蒸餾單元供對該第一蒸餾單元所輸出之混合液體再次蒸餾分離出脫色劑及增塑劑。The second distillation unit is coupled to the first distillation unit, and the second distillation unit is configured to re-distill the mixed liquid outputted from the first distillation unit to separate the decolorizing agent and the plasticizer.
本創作膠合玻璃回收裝置的較佳實施例，其中，該超音波震盪單元內建有加熱器，該加熱器供對該乙醇溶液進行加溫。A preferred embodiment of the inventive glued glass recovery device, wherein the ultrasonic oscillating unit has a heater built therein for heating the ethanol solution.
本創作膠合玻璃回收裝置的較佳實施例，其中，該回收單元連結有光學性質檢測單元，該光學性質檢測單元供對該回收單元所回收之完整玻璃進行光學性質的檢測，確認該完整玻璃之堪用性。A preferred embodiment of the present invention relates to a recycling glass unit, wherein the recycling unit is coupled with an optical property detecting unit for detecting the optical properties of the intact glass recovered by the recycling unit, and confirming the integrity of the glass. Usability.
為令本創作所運用之技術內容、創作目的及其達成之功效有更完整且清楚的揭露，茲於下詳細說明之，並請一併參閱所揭之圖式及圖號：In order to make the technical content, creative purpose and the effect achieved by this creation more complete and clear, please elaborate below, and please refer to the drawings and drawings:
首先，本創作為找出最佳的膠合玻璃回收裝置，希望能將ＰＶＢ溶解使玻璃分離，進而使玻璃及ＰＶＢ同時被回收利用，便可得到完整玻璃及ＰＶＢ，因此分別以下列兩種方式進行實驗：First of all, in order to find the best glued glass recovery device, it is hoped that PVB can be dissolved to separate the glass, and then the glass and PVB can be recycled at the same time, and the complete glass and PVB can be obtained. experiment:
方法一：膨潤，選用適當的溶劑，將ＰＶＢ膠合玻璃置入溶劑中，利用不同的方式加速滲透，待其ＰＶＢ膨潤，導致附著性變差進而分離膠合玻璃。Method 1: Swelling, using appropriate solvent, PVB glued glass is placed in the solvent, and the penetration is accelerated by different methods, and the PVB is swollen, resulting in poor adhesion and separation of the bonded glass.
方法二：溶解，選用適當的溶劑，利用不同方式加速ＰＶＢ溶解，分離膠合玻璃，再利用Ｍｏｎｔｅ Ｃａｒｌｏ Ｍｅｔｈｏｄ來求出ＰＶＢ被溶解的面積。Method 2: Dissolve, select appropriate solvent, accelerate PVB dissolution by different methods, separate the glued glass, and then use Monte Carlo Method to find the area where PVB is dissolved.
而依據ＰＶＢ的性質來選擇溶劑，將其ＰＶＢ放入各溶劑中，靜置一天並記錄其變化，請參閱下表一所示：The solvent is selected according to the nature of the PVB, and the PVB is placed in each solvent, allowed to stand for one day and the change is recorded, as shown in the following Table 1:
表一 各溶劑與ＰＶＢ反應的結果表 <TABLE border="1" borderColor="#000000" width="_0001"><TBODY><tr><td> 溶劑 </td></tr><tr><td> 甲苯 </td><td><b>⊙</b></td></tr><tr><td> 二甲苯 </td><td><b>⊙</b></td></tr><tr><td> 乙酸苯酯 </td><td><b>╳</b></td></tr><tr><td> 乙酸甲酯 </td><td><b>╳</b></td></tr><tr><td> 乙酸乙酯 </td><td><b>╳</b></td></tr><tr><td> 碳酸二甲酯 </td><td><b>╳</b></td></tr><tr><td> 硫酸 </td><td><b>╳</b></td></tr><tr><td> 氫氧化鈉 </td><td><b>╳</b></td></tr><tr><td> 丁酮 </td><td><b>⊕</b></td></tr><tr><td> 丙酮 </td><td><b>╳</b></td></tr><tr><td> 乙酮 </td><td><b>╳</b></td></tr><tr><td> 甲酮 </td><td><b>╳</b></td></tr><tr><td> 乙醇 </td><td><b>⊕</b></td></tr><tr><td> 異丙醇 </td><td><b>╳</b></td></tr></TBODY></TABLE>⊙膨潤；⊕溶解；╳無變化 Table 1 Table of results of reaction of each solvent with PVB <TABLE border="1" borderColor="#000000" width="_0001"><TBODY><tr><td> Solvent</td></tr><tr><td> Toluene</td><td ><b>⊙</b></td></tr><tr><td> xylene</td><td><b>⊙</b></td></tr><tr ><td> phenyl acetate</td><td><b>╳</b></td></tr><tr><td> methyl acetate</td><td><b>╳ </b></td></tr><tr><td> ethyl acetate</td><td><b>╳</b></td></tr><tr><td> Dimethyl carbonate</td><td><b>╳</b></td></tr><tr><td> sulfuric acid</td><td><b>╳</b>< /td></tr><tr><td> Sodium Hydroxide</td><td><b>╳</b></td></tr><tr><td> Butanone</td ><td><b>⊕</b></td></tr><tr><td> Acetone</td><td><b>╳</b></td></tr> <tr><td> ethyl ketone</td><td><b>╳</b></td></tr><tr><td> ketone</td><td><b>╳ </b></td></tr><tr><td> ethanol</td><td><b>⊕</b></td></tr><tr><td> isopropyl Alcohol</td><td><b>╳</b></td></tr></TBODY></TABLE>⊙ swell; ⊕ dissolve; ╳ no change
在各溶劑反應的結果，得知ＰＶＢ會因吸收甲苯及二甲苯導致體積增大產生膨潤的現象，而甲苯膨潤的現象最為明顯，因此可以利用此特性，讓ＰＶＢ的附著力變差，進而分離膠合玻璃，而另外可以發現玻璃中的ＳｉＯＨ和ＰＶＢ的Ｈｙｄｒｏｘｙｌ ｇｒｏｕｐ之間產生氫键，可以形成黏著力與玻璃建結合，因此可以利用極性較大的溶劑去爭奪ＰＶＢ的Ｈｙｄｒｏｘｙｌ ｇｒｏｕｐ破壞和ＳｉＯＨ的结合，而乙醇和丁酮都能溶解，但乙醇溶解的速度最快且成本較低。As a result of the reaction in each solvent, it was found that PVB caused swelling due to absorption of toluene and xylene, and toluene swelling was the most obvious phenomenon. Therefore, this property can be utilized to deteriorate the adhesion of PVB and further separate. Glued glass, and it can be found that the hydrogen bond between the SiOH in the glass and the Hydroxyl group of PVB can form a bond with the glass. Therefore, a solvent with a higher polarity can be used to compete for the combination of the Hydroxyl group and the SiOH of the PVB. Both ethanol and methyl ethyl ketone are soluble, but ethanol dissolves at the fastest and at a lower cost.
令方法一：膨潤，使用的溶劑為甲苯。Let Method 1: Swell, the solvent used is toluene.
令方法二：溶解，使用的溶劑為乙醇。Let Method 2: Dissolve, the solvent used is ethanol.
令ＰＶＢ膠合玻璃單純以溶劑浸泡：甲苯可使ＰＶＢ膠產生膨潤效果，因膨潤可以改變ＰＶＢ對玻璃之附著力，確實可以讓ＰＶＢ膠與玻璃分離，但所需時間至少須１０天。而乙醇可以溶解ＰＶＢ但因無法有效地滲透玻璃的縫隙中，因此大約花的時間為１６０天。但反應所花的時間太長，所以針對這兩種方法進行縮短時間的改善。The PVB glued glass is simply soaked in solvent: toluene can make the PVB glue swell, and the swelling can change the adhesion of PVB to the glass. It can really separate the PVB glue from the glass, but it takes at least 10 days. While ethanol can dissolve PVB but cannot penetrate the gap of the glass effectively, it takes about 160 days. However, the time taken for the reaction is too long, so the shortening time is improved for the two methods.
令ＰＶＢ膠合玻璃置入溶劑中加熱：Put the PVB glued glass in the solvent and heat it:
方法一：膨潤，加熱加速甲苯對ＰＶＢ滲透，但是時間也需要１０天，因此並無法縮短時間。Method 1: Swelling, heating accelerates the infiltration of toluene to PVB, but the time also takes 10 days, so the time cannot be shortened.
方法二：溶解，利用加熱，增加熱對流以加速與ＰＶＢ的反應，將完整ＰＶＢ膠合玻璃放入玻璃燒杯中，再倒入乙醇置入熱浴中，溫度設定為６５度，每六小時取出ＰＶＢ膠合玻璃拍照記錄並利用Ｍｏｎｔｅ Ｃａｒｌｏ Ｍｅｔｈｏｄ模擬出ＰＶＢ被溶解的面積，此方法所花的時間為５２小時。Method 2: Dissolve, use heat, increase heat convection to accelerate the reaction with PVB, put the complete PVB glued glass into a glass beaker, then pour the ethanol into a hot bath, set the temperature to 65 degrees, and take out the PVB every six hours. Glued glass was photographed and Monte Carlo Method was used to simulate the area in which PVB was dissolved. This method took 52 hours.
令ＰＶＢ膠合玻璃置入超音波清洗器浸泡：Put PVB glued glass into the ultrasonic cleaner to soak:
方法一：膨潤，利用超音波震盪加速甲苯滲透到ＰＶＢ膠合玻璃，所需時間為４天。Method 1: Swelling, using ultrasonic vibration to accelerate the penetration of toluene into PVB glued glass, the time required is 4 days.
方法二：溶解，利用超音波震盪經由加快流速可以增加溶劑的滲透，將完整ＰＶＢ膠合玻璃放入玻璃燒杯中，再倒入乙醇溶劑置入超音波清洗器，震盪的頻率設定為２０Ｈｚ，並每三小時取出ＰＶＢ膠合玻璃拍照記錄並利用Ｍｏｎｔｅ Ｃａｒｌｏ Ｍｅｔｈｏｄ模擬出ＰＶＢ被溶解的面積，此方法時間為１５小時。Method 2: Dissolve, use ultrasonic vibration to increase the penetration of the solvent by accelerating the flow rate, put the complete PVB glued glass into a glass beaker, and then pour the ethanol solvent into the ultrasonic cleaner. The frequency of the oscillation is set to 20 Hz, and each The PVB glued glass was taken for three hours to take a photo record and the area where PVB was dissolved was simulated using Monte Carlo Method. The method took 15 hours.
請再一併下表二及第一圖ＰＶＢ溶解實驗面積數據圖所示，可得知利用超音波震盪加速乙醇溶解ＰＶＢ的速度最快，只需要１５個小時而且乙醇可以再次回收利用，成本較低、效率高，符合回收效益。 表二 實驗所需時間表 <TABLE border="1" borderColor="#000000" width="_0002"><TBODY><tr><td></td><td><b>溶劑浸泡</b></td><td><b>加熱</b></td><td><b>超音波震盪</b></td></tr><tr><td><b>(</b><b>方法一：膨潤)</b></td><td> 10天 </td><td> 10天 </td><td> 4天 </td></tr><tr><td><b>(</b><b>方法二：溶解)</b></td><td> 160天 </td><td> 52小時 </td><td> 15小時 </td></tr></TBODY></TABLE>Please also show the PVB dissolution test area data shown in Table 2 and Figure 1 below. It can be seen that the use of ultrasonic vibration to accelerate the dissolution of PVB by ethanol is the fastest. It takes only 15 hours and the ethanol can be recycled again. Low, high efficiency and consistent with recycling benefits. Table 2 Timetable for the experiment <TABLE border="1" borderColor="#000000" width="_0002"><TBODY><tr><td></td><td><b>solvent soak</b></td><td ><b>Heating</b></td><td><b>Supersonic shock</b></td></tr><tr><td><b>(</b><b >Method 1: Swelling)</b></td><td> 10 days</td><td> 10 days</td><td> 4 days</td></tr><tr><td ><b>(</b><b>Method 2: Dissolution)</b></td><td> 160 days</td><td> 52 hours</td><td> 15 hours</ Td></tr></TBODY></TABLE>
因此，請參閱第二圖本創作之結構示意圖所示，本創作主要係包括有清洗單元（１）、超音波震盪單元（２）、回收單元（３）、脫色單元（４）、ＰＶＢ液體析出單元（５）、乾燥單元（６）、第一蒸餾單元（７）及第二蒸餾單元（８）；其中：Therefore, please refer to the second diagram of the schematic diagram of the creation of this creation, this creation mainly includes cleaning unit (1), ultrasonic oscillation unit (2), recovery unit (3), decolorization unit (4), PVB liquid precipitation a unit (5), a drying unit (6), a first distillation unit (7) and a second distillation unit (8); wherein:
該清洗單元（１），其供對完整之ＰＶＢ［聚乙烯醇縮丁醛］膠合玻璃進行清洗作業。The cleaning unit (1) is for cleaning a complete PVB [polyvinyl butyral] glued glass.
該超音波震盪單元（２），其與該清洗單元（１）連結，以能將清洗後的該ＰＶＢ［聚乙烯醇縮丁醛］膠合玻璃置入，且加入乙醇溶液後予以進行震盪，並於該超音波震盪單元（２）內建有加熱器（２１），該加熱器（２１）可對該乙醇溶液進行加溫。The ultrasonic oscillating unit (2) is coupled to the cleaning unit (1) to insert the cleaned PVB [polyvinyl butyral] glued glass, and is oscillated after adding an ethanol solution, and A heater (21) is built in the ultrasonic oscillating unit (2), and the heater (21) can warm the ethanol solution.
該回收單元（３），其與該超音波震盪單元（２）連結，該回收單元（３）供回收去除ＰＶＢ樹脂後之完整玻璃，於該回收單元（３）可連結有光學性質檢測單元（３１），該光學性質檢測單元（３１）可供對該回收單元（３）所回收之完整玻璃進行光學性質的檢測，確認該完整玻璃之堪用性。The recovery unit (3) is coupled to the ultrasonic oscillating unit (2) for recovering the complete glass after removing the PVB resin, and the optical unit detecting unit (3) can be coupled to the recycling unit (3) 31) The optical property detecting unit (31) is capable of detecting the optical properties of the intact glass recovered by the recycling unit (3), confirming the usability of the complete glass.
該脫色單元（４），其與該超音波震盪單元（２）連結，該脫色單元（４）供對該超音波震盪單元（２）所輸出溶解有ＰＶＢ樹脂之乙醇溶液混合液體，於加入脫色劑後進行加熱脫色。The decolorizing unit (4) is coupled to the ultrasonic oscillating unit (2), and the decolorizing unit (4) is configured to output a mixed liquid of the ethanol solution in which the PVB resin is dissolved in the ultrasonic oscillating unit (2), and add the discoloration The agent is then decolorized by heating.
該ＰＶＢ液體析出單元（５），其與該脫色單元（４）連結，該ＰＶＢ液體析出單元（５）供對該脫色單元（４）所輸出之ＰＶＢ樹脂與乙醇溶液之混合液體，於加入水和沉澱劑後析出ＰＶＢ液體。The PVB liquid deposition unit (5) is coupled to the decolorizing unit (4) for supplying a mixed liquid of the PVB resin and the ethanol solution outputted to the decolorizing unit (4) to the water. The PVB liquid is precipitated after the precipitant.
該乾燥單元（６），其與該ＰＶＢ液體析出單元（５）連結，該乾燥單元（６）供對該ＰＶＢ液體析出單元（５）所析出之ＰＶＢ液體進行加熱乾燥，而獲得ＰＶＢ粉體。The drying unit (6) is connected to the PVB liquid deposition unit (5) for heating and drying the PVB liquid deposited in the PVB liquid deposition unit (5) to obtain PVB powder.
該第一蒸餾單元（７），其與該ＰＶＢ液體析出單元（５）連結，該第一蒸餾單元（７）供對該ＰＶＢ液體析出單元（５）所輸出之乙醇溶液混合液體進行蒸餾作業，以可回收乙醇溶液。The first distillation unit (7) is coupled to the PVB liquid deposition unit (5) for performing a distillation operation on the ethanol solution mixed liquid output from the PVB liquid deposition unit (5). Recoverable ethanol solution.
該第二蒸餾單元（８），其與該第一蒸餾單元（７）連結，該第二蒸餾單元（８）供對該第一蒸餾單元（７）所輸出之混合液體再次蒸餾分離出脫色劑及增塑劑。The second distillation unit (8) is coupled to the first distillation unit (7), and the second distillation unit (8) is used for re-distilling the mixed liquid outputted from the first distillation unit (7) to separate the decolorizing agent. And plasticizers.
使得本創作於操作使用上，請再一併參閱第三圖本創作之回收流程示意圖所示，其回收步驟係為：To make this creation work, please refer to the third diagram. The recycling process diagram of this creation is as follows:
A.先令完整之ＰＶＢ［聚乙烯醇縮丁醛］膠合玻璃於該清洗單元（１）中進行清洗作業；A. Sampling complete PVB [polyvinyl butyral] glued glass is cleaned in the cleaning unit (1);
B.將清洗後的該ＰＶＢ［聚乙烯醇縮丁醛］膠合玻璃置入該超音波震盪單元（２）中，同時加入乙醇溶液，令該超音波震盪單元（２）進行震盪作業，且利用該超音波震盪單元（２）內建之該加熱器（２１）進行加溫，將該乙醇溶液加溫至５０℃，以利用加溫後之乙醇溶液搭配該超音波震盪單元（２）之震盪，而將該ＰＶＢ膠合玻璃中之ＰＶＢ樹脂予以溶解，並為能加速ＰＶＢ樹脂之溶解，而可將乙醇溶液另行以該加熱器（２１）加溫至其沸點以下；B. The cleaned PVB [polyvinyl butyral] glued glass is placed in the ultrasonic oscillating unit (2), and an ethanol solution is added to cause the ultrasonic oscillating unit (2) to oscillate and utilize The heater (21) built in the ultrasonic oscillating unit (2) is heated, and the ethanol solution is heated to 50 ° C to oscillate with the warmed ethanol solution and the ultrasonic oscillating unit (2). And dissolving the PVB resin in the PVB glued glass, and in order to accelerate the dissolution of the PVB resin, the ethanol solution may be separately heated by the heater (21) to below its boiling point;
C.於該超音波震盪單元（２）內待ＰＶＢ樹脂完全被乙醇溶液溶解後，即可利用該回收單元（３）回收完整玻璃；C. After the PVB resin is completely dissolved in the ethanol solution in the ultrasonic oscillation unit (2), the recovery unit (3) can be used to recover the complete glass;
D.利用該回收單元（３）所連結之光學性質檢測單元（３１）對所回收之玻璃進行光學性質檢測，以確認其堪用性；D. Using the optical property detecting unit (31) connected to the recycling unit (3) to perform optical property detection on the recovered glass to confirm its usability;
E.該超音波震盪單元（２）內溶解有ＰＶＢ樹脂之乙醇溶液混合液體則輸送至該脫色單元（４），同時加入脫色劑，利用該脫色單元（４）予以進行加熱，讓脫色劑產生作用，令ＰＶＢ樹脂還原為原色；E. The mixed solution of the ethanol solution in which the PVB resin is dissolved in the ultrasonic oscillating unit (2) is sent to the decolorizing unit (4), and the decolorizing agent is added, and the decolorizing unit (4) is used to heat the decolorizing agent. Function to restore PVB resin to primary color;
F.待該乙醇溶液混合液體中之ＰＶＢ樹脂還原為原色後，予以輸送至該ＰＶＢ液體析出單元（５），同時予以加入水和沉澱劑後，以析出ＰＶＢ液體；F. After the PVB resin in the mixed liquid of the ethanol solution is reduced to a primary color, it is sent to the PVB liquid precipitation unit (5), and water and a precipitant are added to precipitate the PVB liquid;
G.將所析出之ＰＶＢ液體利用該乾燥單元（６）予以加熱乾燥，即可得到ＰＶＢ粉體；G. The precipitated PVB liquid is heated and dried by the drying unit (6) to obtain PVB powder;
H.而該ＰＶＢ液體析出單元（５）內之乙醇溶液混合液體則輸送至該第一蒸餾單元（７），以利用該第一蒸餾單元（７）對該乙醇溶液混合液體進行蒸餾作業，以回收乙醇溶液；H. The ethanol solution mixed liquid in the PVB liquid precipitation unit (5) is sent to the first distillation unit (7) to perform the distillation operation on the ethanol solution mixed liquid by the first distillation unit (7). Recovering the ethanol solution;
I.該回收之乙醇溶液可供用來加入該超音波震盪單元（２）中，以溶解ＰＶＢ膠合玻璃中之ＰＶＢ樹脂；I. The recovered ethanol solution is available for addition to the ultrasonic oscillating unit (2) to dissolve the PVB resin in the PVB glued glass;
J.經該第一蒸餾單元（７）所蒸餾後之混合液體則可輸送至該第二蒸餾單元（８），利用該第二蒸餾單元（８）再次進行蒸餾，而分離出脫色劑及增塑劑；J. The mixed liquid distilled by the first distillation unit (7) can be sent to the second distillation unit (8), and the second distillation unit (8) is used for distillation again to separate the decolorizing agent and increase Plasticizer
K.該第二蒸餾單元（８）所蒸餾分離出之脫色劑，其可供用來加入該該脫色單元（４）中，令ＰＶＢ樹脂還原為原色。K. The decolorizing agent separated by distillation by the second distillation unit (8), which is available for addition to the decolorizing unit (4) to reduce the PVB resin to a primary color.
如此一來，使得本創作於使用上，即能將廢棄之ＰＶＢ膠合玻璃回收予以分離出玻璃與ＰＶＢ粉體，使得經回收分離後之玻璃與ＰＶＢ粉體皆能再次利用，以能解決廢棄之ＰＶＢ膠合玻璃所產生的環保問題。In this way, the original PVB glued glass can be recycled to separate the glass and PVB powder, so that the recovered and separated glass and PVB powder can be reused to solve the waste. Environmental problems caused by PVB glued glass.
藉由以上所述，本創作結構之組成與使用實施說明可知，本創作與現有結構相較之下，本創作主要係能將廢棄之ＰＶＢ膠合玻璃經回收後，予以分離出完整的整片玻璃與ＰＶＢ溶液，且將該ＰＶＢ溶液進行乾燥為ＰＶＢ粉體，以能分別再次利用該分離後的玻璃及ＰＶＢ粉體，使得該廢棄之ＰＶＢ膠合玻璃不會產生污染環境之情況，以能符合環保概念，而在其整體施行使用上更增實用功效特性者。From the above, the composition and use of the creation structure can be seen that, compared with the existing structure, this creation mainly can recycle the discarded PVB glued glass and separate the whole whole glass. And the PVB solution is dried to PVB powder, so that the separated glass and PVB powder can be reused again, so that the discarded PVB glued glass does not pollute the environment, so as to be environmentally friendly. The concept, but in its overall implementation, the use of more practical features.
前述之實施例或圖式並非限定本創作之結構樣態，任何所屬技術領域中具有通常知識者之適當變化或修飾，皆應視為不脫離本創作之專利範疇。The above-mentioned embodiments or drawings are not intended to limit the structure of the present invention, and any suitable variations or modifications of those skilled in the art should be considered as not departing from the scope of the invention.
綜上所述，本創作實施例確能達到所預期之使用功效，又其所揭露之具體構造，不僅未曾見於同類產品中，亦未曾公開於申請前，誠已完全符合專利法之規定與要求，爰依法提出新型專利之申請，懇請惠予審查，並賜准專利，則實感德便。In summary, the present embodiment can achieve the expected use efficiency, and the specific structure disclosed is not only found in similar products, nor has it been disclosed before the application, and has fully complied with the requirements and requirements of the Patent Law.爰Proposing an application for a new type of patent in accordance with the law, and pleading for a review and granting a patent, it is really sensible.
（１）‧‧‧清洗單元(1)‧‧‧cleaning unit
（２）‧‧‧超音波震盪單元(2) ‧‧‧Supersonic oscillation unit
（２１）‧‧‧加熱器(21)‧‧‧ heater
（３）‧‧‧回收單元(3) ‧‧‧Recycling unit
（３１）‧‧‧光學性質檢測單元(31)‧‧‧ Optical property detection unit
（４）‧‧‧脫色單元(4) ‧‧‧Decolorization unit
（５）‧‧‧ＰＶＢ液體析出單元(5) ‧‧‧PVB liquid precipitation unit
（６）‧‧‧乾燥單元(6) ‧‧‧ drying unit
（７）‧‧‧第一蒸餾單元(7) ‧‧‧First distillation unit
（８）‧‧‧第二蒸餾單元(8)‧‧‧Second distillation unit
第一圖：ＰＶＢ溶解實驗面積數據圖The first picture: PVB dissolution test area data map
第二圖：本創作之結構示意圖Second picture: Schematic diagram of the creation
第三圖：本創作之回收流程示意圖The third picture: schematic diagram of the recycling process of this creation
(1)‧‧‧清洗單元 (1)‧‧‧cleaning unit
(2)‧‧‧超音波震盪單元 (2) ‧‧‧Supersonic oscillation unit
(21)‧‧‧加熱器 (21)‧‧‧ heater
(3)‧‧‧回收單元 (3) ‧‧‧Recycling unit
(31)‧‧‧光學性質檢測單元 (31)‧‧‧ Optical property detection unit
(4)‧‧‧脫色單元 (4) ‧‧‧Decolorization unit
(5)‧‧‧PVB液體析出單元 (5) ‧‧‧PVB liquid precipitation unit
(6)‧‧‧乾燥單元 (6) ‧‧‧ drying unit
(7)‧‧‧第一蒸餾單元 (7) ‧‧‧First distillation unit
(8)‧‧‧第二蒸餾單元 (8)‧‧‧Second distillation unit
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| Application Number | Priority Date | Filing Date | Title |
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| TW105217677U TWM536673U (en) | 2016-11-18 | 2016-11-18 | Glued glass recovery apparatus |
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| TWM536673U true TWM536673U (en) | 2017-02-11 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113600547A (en) * | 2021-07-28 | 2021-11-05 | 映利科技股份有限公司 | Soaking and separating glass equipment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113600547A (en) * | 2021-07-28 | 2021-11-05 | 映利科技股份有限公司 | Soaking and separating glass equipment |
| CN113600547B (en) * | 2021-07-28 | 2023-08-22 | 映利科技股份有限公司 | Glass soaking and separating equipment |
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