TWM246204U - Hydrocarbon fuel reformer capable of automatic operation mode switching - Google Patents
Hydrocarbon fuel reformer capable of automatic operation mode switching Download PDFInfo
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- TWM246204U TWM246204U TW92221267U TW92221267U TWM246204U TW M246204 U TWM246204 U TW M246204U TW 92221267 U TW92221267 U TW 92221267U TW 92221267 U TW92221267 U TW 92221267U TW M246204 U TWM246204 U TW M246204U
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M246204 9、創作說明(1) 【技術領域】 t創作係有關於一種可自動切換操作模式之碳氫燃料 重組器’特別是指一種感測重組器内觸媒層出口之溫度變 化—,刀別控制加熱塞、空氣供應系統、燃料供應系統及 水洛i供應系統作動,自動調整產生出不同之加熱功率。 【先前技術】 按 燃料電池係為一種南效率且低污染之發電設備, 在見5 切構究環保要求之規定下’燃料電池則為極具潛 力的選擇’值得大力推廣,可預見未來燃料電池將被廣泛 使用於汽、機車等交通工具上,例如有新型公告第5 0 3丨9 i 號「燃料電池式四輪汽車」、第49 6376號「電動機車燃料 電池儲氫裝置」及第476333號「以燃料電池為能源系統之 電動機車配置構造」等專利所示,足見燃料電池之功效性 及便利性;而燃料電池之燃料—氫氣的產生方式,最方便 者乃為車載型之重組器’其主要係设有一儲存有液態燃料 之燃料槽,其係利用氣體輔助而加以霧化,其次,&態燃 料再經過重組器内之加熱器加熱而進一步汽化,該汽化後 之燃料再經過觸媒轉換器之轉化作用,而可以使之轉化成 為富氫氣體〔Hydrogen Rich Gas〕,以及二氧化碳 〔C〇2〕等生成物,其中該氫氣最後係可被送到燃料電池之 陽極與陰極空氣中之氧氣產生電化學反應而產生'電能,/並 且可用來儲存在燃料電池產生之電力的輔助電池者;b在此 轉化過程中,該液態燃料於需經過重組器均勻的分佈加 熱’才可以使轉化後之氫氣產生效果達到最佳,但由於現M246204 9. Creation Instructions (1) [Technical Field] t creation is about a hydrocarbon fuel reformer that can automatically switch the operation mode, especially a sensor that senses the temperature change of the catalyst layer outlet in the reformer—, knife type Control the operation of the heating plug, air supply system, fuel supply system and water supply system, and automatically adjust to produce different heating power. [Previous technology] According to the fuel cell system is a kind of power generation equipment with low efficiency and low pollution. Under the requirements of 5 environmental protection requirements, 'the fuel cell is a potential choice' is worth promoting vigorously, and it is foreseeable that the future fuel cell Will be widely used in vehicles such as automobiles and locomotives, for example, new announcement No. 5 03 丨 9 i "Fuel Cell Four-Wheel Vehicle", No. 49 6376 "Electric Locomotive Fuel Cell Hydrogen Storage Device" and No. 476333 As shown in patents such as "Configuration configuration of electric locomotive using fuel cell as energy system", it shows the efficiency and convenience of fuel cell; and the most convenient way of generating fuel-hydrogen for fuel cell is vehicle-mounted reorganizer 'It is mainly provided with a fuel tank storing liquid fuel, which is atomized with the aid of gas. Secondly, the & state fuel is further heated by the heater in the reformer to further vaporize, and the vaporized fuel passes through The conversion effect of the catalyst converter, which can be converted into hydrogen-rich gas [Hydrogen Rich Gas], and carbon dioxide [C02], etc. Among them, the hydrogen can be finally sent to the anode of the fuel cell and the oxygen in the cathode air to produce an electrochemical reaction to generate 'electricity', and / or can be used to store the auxiliary battery's power generated by the fuel cell; b during this conversion process In order to achieve the best hydrogen production after conversion, the liquid fuel needs to be heated through the uniform distribution of the reformer.
第6頁 013571 M246204 四、創作說明(2) 今習知重組器内之加熱方式係有採用火星塞之定時點火爆 炸後’而燃燒產生加熱作用,或者是於重組器上包覆有熱 層’以產生加熱之效果者,但由於該等加熱方式所產生之 溫度並無法均勻,以致於加熱效果並不甚理想,而無法達 到使其可完全加熱汽化之目的,以致富氫氣體之產生不 足’而造成能源上之浪費。 爰此,本創作人係有鑑於習知重組器之加熱結構,係 具有上述種種之缺失,因此乃潛心加以研究, 作及改良,遂得以首創出本創作。 、丄夕-人忒 【内容】 本創 變化,以 熱,毋庸 ,及攔截 應的可自 其特 貫穿連接 ,其係將 至加熱室 路提供液 體之攜行 供連接至 組,其係 層出口之 作之目 控制調 使用點 較大顆 動切換 徵係在 至加熱 空氣輪 ,其係 態燃料 ,而將 加熱室 於觸媒 溫度變 的係在 整出多 火系統 粒之液 操作模 於:該 室内; 入至加 設有第 ,係將 其輸入 ,其係 層出口 化,而 提供一 種加熱 ,而可 態燃料 式之碳 重組器 空氣供 熱室内 一管路 其共同 至加妖 將水蒸 言支入有 分別控 種可根據觸 功率;又利 藉由蓄熱層 ’以防止過 氫燃料重組 之外緣係接 應糸統,係 ;燃料供應 提供低壓氣 先行霧化後 室内;水蒸 汽輪入至加 溫度感測器 制加熱塞、 媒層出 用加熱 以提昇 多的燃 器。 設有力口 供連接 系統, 體,以 ,再利 汽供應 熱室内 ,藉由 空氣供 口之溫度 塞進行加 加熱效率 料局部反 熱塞,並 至加熱室 係供連接 及第二管 用低壓氣 系統,係 ;控制模 感測觸媒 應系統、Page 6 013571 M246204 IV. Creation instructions (2) The heating method in the conventional recombiner today is to use a spark plug to ignite and explode at regular time, and then the combustion will generate heating effect, or the recombiner is covered with a thermal layer. Those who produce heating effects, but because the temperatures generated by these heating methods are not uniform, the heating effect is not ideal, and the purpose of making them fully heated and vaporized cannot be achieved, so that the generation of hydrogen-rich gas is insufficient. This results in waste of energy. At this point, in view of the heating structure of the conventional reorganizer, the creator has the above-mentioned shortcomings. Therefore, he concentrated on researching, making and improving, and was able to create this creation for the first time. 、 丄 夕-人 忒 [Content] Innovative changes to heat, needless, and interception should be through its special through connection, which is to connect to the heating chamber to provide liquid for the connection to the group, and its system exit The purpose of the control is to use a larger point to switch the heating system to the heating air wheel, which is the state of fuel, and the heating chamber at the catalyst temperature change is tied to the liquid operating mode of the multi-fire system pellets: The interior of the room is provided with a tube, which is input, and the layer is exported, and provides a heating, and a state of fuel-type carbon recombiner air heating room, a pipe, which is common to the demon to steam the water The language support can be controlled separately according to the contact power; it also uses the thermal storage layer to prevent the reorganization of the hydrogen fuel. The outer edge is connected to the system; the fuel supply provides low-pressure gas to be atomized first and then indoor; Add a temperature sensor to make a glow plug and heat the medium layer to heat up a large number of burners. It is equipped with a power supply connection system, so as to supply steam to the heating chamber, and use the temperature plug of the air supply port to increase the heating efficiency, and locally reheat the plug, and connect the heating chamber to the low-pressure gas system for the second pipe. System; control mold sensing catalyst response system,
$ 7頁 013572 M246204 、創作說明(3) 燃料供應系統及水蒸汽供應系統 之加熱功率。 亍死作動,以調整產生出不同 【實施方式】 首先,請參閱第一圖所示,士仏 (I) 、空氣供應系統(2 )、燃料供麻糸:主要係°又一由重組态 系統(4)及控制模組(5)所組合而g,,、其中3)·、水蒸汽供應 重組器(1),其内部係設有加熱室πι)·,而 之外緣係接設有若干之加敎塞(1 2 ) ♦ ' . * …、巷w㈠而貫穿連接至加埶室 (II) 内,又加熱室(11)之一端係連i …至 媒層U3)係設有一出口 (14),觸媒層(13)’該觸 ..^ ru , U4; U供輸出反應後所產生之富 虱軋體〔Hydrogen Rich Gas〕。 右暗H供應系統(2),係供連接至加熱室⑴),其係設 有喷嘴(21)可將空氣輸入至加熱室(11)内。 燃料供應系統(3),係供連接至加熱室(11),其係設 有第-管路^31)提供低壓之氣體,該氣體係可為氣氣 .〔2〕,或空氣,以及第二管路(3 2)提供液態燃料,該液態 燃料係可為甲醇及水所組成,或是其他種類之燃料等能源 係將其共同先行霧化後,再由喷嘴(3 3)將霧化後之燃料 ,利用低壓氣體之攜行,而將其喷入於加熱室(丨丨)内。 水蒸A供應系統(4 ),係供連接至加熱室(11 ),其係 設有噴嘴(41)可將水蒸汽輸入至加熱室(11)内。 ^ 控制模組(5 ),其係於觸媒層(1 3 )内接近出口( 1 4)處 =入有一溫度感測器(5 1 ),藉由感測觸媒層(1 3 )内之溫度 變化’而分別控制加熱塞(丨2 )、空氣供應系統(2 )、燃料$ 7 pages 013572 M246204, Creative Instructions (3) Heating power of fuel supply system and water vapor supply system. Action to adjust to make a difference [Embodiment] First, please refer to the first picture, Shi Jie (I), air supply system (2), fuel supply mochi: mainly by the reconfiguration system ( 4) and control module (5) combined with g ,, of which 3) ·, water vapor supply recombiner (1), the interior of which is equipped with a heating chamber π) ·, and the outer edge is provided with a number of The plus plug (1 2) ♦ '. *…, The lane w㈠ is connected to the plus chamber (II), and one end of the heating chamber (11) is connected to i ... to the media layer U3). An outlet ( 14), the catalyst layer (13) 'the touch .. ^ ru, U4; U is for the genus genus [Hydrogen Rich Gas] produced after the output reaction. The right dark H supply system (2) is connected to the heating chamber ⑴) and is provided with a nozzle (21) to input air into the heating chamber (11). The fuel supply system (3) is for connecting to the heating chamber (11), and it is provided with a first line-31) to provide a low-pressure gas, and the gas system may be gas. [2], or air, and the first The second pipeline (3 2) provides liquid fuel. The liquid fuel can be composed of methanol and water, or other types of fuel and other energy systems can be atomized together, and then atomized by the nozzle (3 3). The latter fuel is carried into the heating chamber (丨 丨) by carrying it with low-pressure gas. The water-steaming A supply system (4) is connected to the heating chamber (11), and is provided with a nozzle (41) to input water vapor into the heating chamber (11). ^ The control module (5) is located near the outlet (1 4) in the catalyst layer (1 3) = a temperature sensor (5 1) is inserted into the catalyst layer (1 3) Temperature change 'to control the glow plug (丨 2), air supply system (2), fuel
第8頁 M246204Page 8 M246204
供應系統(3 )及水蒸汽供應系統(4 )作動。 使用日可㊂重組器(1 )之加熱室(1 1 )位於常溫時,則 启^動電源進行「加熱一冷啟動」,該控制模組(5)係會根 據溫度感測器(51)所測得觸媒層(13)出口(14)處之溫度, 在觸媒層(13)未達到工作溫度時,而啟動加熱塞(12)開始 加,,並,制空氣供應系統(2)透過喷嘴(21),而輸入大 流置之空氣進入加熱室(11)内,將加熱塞(12)所產生之熱 里傳遞至觸媒層(1 3 ),以加快溫度之提昇,同時控制模組 (5)亦控制燃料供應系統(3),透過喷嘴(33)輸入大量霧化 ^液悲燃料進入加熱室(丨丨)内,利用加熱塞(丨2 )所產生之 咼,,使液態燃料與高溫之空氣產生氧化作用,並釋放出 大:E的反應熱’促使觸媒層(i 3 )快速提昇到工作溫度,此 冷啟動之階段稱為「部份氧化反應模式」。 而在冷啟動初期之「部份氧化反應模式」當中,其反 應作用係利用加熱塞(1 2 )直接與液態燃料中之曱醇形成氧 化反應’在雙重釋出熱量的狀況下,觸媒層3 )可在極短 的時間中達到工作溫度而進行反應作用,由於其反應後所 轉化之氣體係為昌氫氣體〔H2,Hydrogen Rich Gas〕 ,以 及一氧化石反〔C〇2〕等生成物,由於在反應作用中,一旦溫 度過高或濕度過低時,則富氫氣體及二氧化碳係會轉換成 一氧化碳及水〔H2 + C02 c〇 + H20〕,如此,則會造 成富氫氣體之數量大幅減少,而增加無用的一氧化碳及水 ’因此控制模組(5 )係藉由溫度感測器(5丨)隨時監控觸媒The supply system (3) and the water vapor supply system (4) operate. When the heating chamber (1 1) of the Japanese reorganizer (1) is located at normal temperature, the power supply is turned on for "heating and cold start", and the control module (5) is based on the temperature sensor (51) The measured temperature at the outlet (14) of the catalyst layer (13), when the catalyst layer (13) has not reached the operating temperature, the heating plug (12) is started to start adding, and the air supply system (2) is made Through the nozzle (21), the air flowing into the heating chamber (11) is transferred into the heating chamber (11), and the heat generated by the heating plug (12) is transferred to the catalyst layer (1 3) to accelerate the temperature increase and control The module (5) also controls the fuel supply system (3), and inputs a large amount of atomized fuel through the nozzle (33) into the heating chamber (丨 丨), and uses the 咼 generated by the heating plug (丨 2) to make The oxidation of liquid fuel and high-temperature air produces a large: E's reaction heat 'prompts the catalyst layer (i 3) to quickly rise to the working temperature. This stage of cold start is called "partial oxidation reaction mode". In the "partial oxidation reaction mode" in the early stage of cold start, the reaction function is to use a glow plug (1 2) to directly form an oxidation reaction with methanol in liquid fuel. Under the condition of dual heat release, the catalyst layer 3) The reaction can be carried out at the operating temperature in a very short time, because the gas system converted after the reaction is a hydrogen gas [H2, Hydrogen Rich Gas], and a monolithic reaction [C0]. In the reaction, once the temperature is too high or the humidity is too low, the hydrogen-rich gas and carbon dioxide will be converted into carbon monoxide and water [H2 + C02 c0 + H20], so it will cause the hydrogen-rich gas. The quantity is greatly reduced, and the useless carbon monoxide and water are increased. Therefore, the control module (5) monitors the catalyst at any time through the temperature sensor (5 丨).
第9頁 M246204 創作說明(5) 層ίίίίΐ溫度變化,當溫度感測器(51)測得觸媒層(13)出 口 )處之溫度已到達可供反應之工作溫度時,則控制模 =(5)自/動降低空^供應系統(2)之空氣供應量,並調節燃 料供應系統(3 )液態燃料之適當供應量;如工作溫产過高 時,則控制模組⑸會關閉空氣供應系統(空皿又冋 ,及減少加熱塞(⑴啟動之數目,藉以降低加熱 =度’以及耗電功率’同時控制模組(5)會開始啟動水 洛π供應系統(4),透過噴嘴(41)將水蒸汽輸入至加孰室 (11)内,以增加加熱室(11)内之濕度,而可維持正常之工 作溫度,藉此降低-氧化碳的濃度及產生,而相對增加舍 氫氣?的產量,此時則可由「部份氧化反應模式」轉變: 「水瘵汽重組反應模式」;又如果當工作溫度降低時,則 控制模組(5)再自動控制加熱塞(12)開始加熱,並控制調 整空,供應系統(2)及燃料供應系統(3)之空氣及液態燃料 之流量,並關閉水蒸汽供應系統(4 ),而再由「水蒸汽重 組反應模式」切換到「部份氧化反應模式」,藉以達到完 全自動化控制加熱,如此,則可根據溫度之不同,而調= 出各種不同之加熱功率,以提昇氫氣體之產量。 正 本創作另一實施例,如第二圖所示,係可於重組器 (1)之加熱室(11)内壁環設有一蓄熱層(15),該蓄熱層 (1 5)係由蓄熱材料所製成,並可供加熱塞(丨2)穿設於其中 ,以供加熱塞(12)在加熱的過程中,可以蓄積熱量,^有 效緩和冷啟動時液態燃料之反應狀況,以提昇加熱時之 度及效率。 、Page 9 M246204 Creation instructions (5) Layer temperature changes, when the temperature at the temperature of the catalyst layer (13) measured by the temperature sensor (51) has reached the working temperature available for reaction, then the control mode = ( 5) Automatically reduce the air supply of the air supply system (2) and adjust the fuel supply system (3) the appropriate supply of liquid fuel; if the operating temperature is too high, the control module will turn off the air supply The system (empty dishes again, and reducing the number of heating plugs (⑴), so as to reduce heating = degrees 'and power consumption' At the same time, the control module (5) will start to start the water π supply system (4), through the nozzle ( 41) Water vapor is input into the heating chamber (11) to increase the humidity in the heating chamber (11) while maintaining the normal operating temperature, thereby reducing the concentration and production of carbon oxides, and relatively increasing the hydrogen content. At this time, the output can be changed from the "partial oxidation reaction mode": "water vapor reforming reaction mode"; and if the operating temperature is reduced, the control module (5) automatically controls the glow plug (12) to start Heating and control adjustment empty, supply system (2) and the fuel supply system (3), the air and liquid fuel flow, and the water vapor supply system (4) is closed, and then the "water vapor recombination reaction mode" is switched to the "partial oxidation reaction mode" to achieve Fully automatic heating control. In this way, according to different temperatures, different heating power can be adjusted to increase the production of hydrogen gas. Another embodiment of the original creation, as shown in the second figure, can be used in the reformer (1) The inner wall of the heating chamber (11) is provided with a heat storage layer (15). The heat storage layer (15) is made of a heat storage material and can be inserted through the heating plug (丨 2) for The heating plug (12) can accumulate heat during the heating process, effectively alleviating the reaction condition of the liquid fuel during cold start, so as to improve the degree and efficiency during heating.
013575 M246204 3、創作說明(6) 本創作又 之如端處設有 入觸媒層(1 3 ) 擔’並由網中 燃料顆料進入 部反應,而釋 故由以上 優點: 1 ·本創作 根據觸媒層之 燃料供應系統 化反應模式」 率,而達到最 2·本創作 供應系統,使 霧化效果。 3·加熱室 ’除而可供方 進行加熱,毋 度。 4 ·係於加 加快加熱速度 5·另於觸 之顆粒燃料, 一實施例,如第 一濾網(1 6 ),該 時,將其液體中 蓄存的熱量,協 至觸媒層(1 3 )中 放大量熱能傷害 說明可知,本創 之控制模組藉由 溫度變化,以控 及水蒸汽供應系 及「水蒸汽重組 佳之加熱效果, 之燃料重組器, 燃料的霧化不需 内係可由重組器 便拆裝、更換及 庸使用點火系統 熱室内設有蓄熱 ’以提昇加熱效 媒層之前端設有 以防止過多的燃 三圖所示,係於觸媒層(1 3 ) 濾網(1 6 )係可在液態燃料進 較大之燃料顆粒將其攔截阻 助燃料的霧化,以防止大的 ,以防止過多燃料顆粒之局 到觸媒層(1 3 )。 作之實施例確實具有下列之 溫度感測器之偵測作用,而 制加熱塞、空氣供應系統、 統作動,自動切換「部份氧 反應模式」等多種加熱功 以提高富氫氣體之產量。 係採用氣體輔助霧化之燃料 額外加熱’即可獲得良好的 之外緣設入有若干之加敎 易於維修,同時利用加埶ς 進行加熱,*可提高加熱ς 材料所製成之蓄熱層,藉以 率。 9 濾網,藉以攔戴液態燃料中 料局部反應,而釋放大量的013575 M246204 3. Creation instructions (6) This creation is similar to the entry catalyst layer (1 3) at the end, which is reacted by the entrance of the fuel particles in the net, and the reasons are explained by the above advantages: 1 · This creation According to the rate of the fuel supply systematized reaction mode of the catalyst layer, the maximum supply of this creative supply system is achieved and the atomization effect is achieved. 3. Heating chamber ′ except for heating. 4. It is to increase the heating speed. 5. It is also to contact the granular fuel. An embodiment, such as the first filter (16), at this time, the heat stored in the liquid is associated with the catalyst layer (1 3) The thermal energy damage description of the medium-magnification amount shows that the control module of the invention controls the water vapor supply system and the "heating effect of water vapor reformation, the fuel reformer, and the atomization of fuel without internal system by temperature change. It can be disassembled, reassembled, and used by the reorganizer. The heat storage chamber is equipped with heat storage to improve the heating efficiency. The front end is provided to prevent excessive combustion. It is attached to the catalyst layer (1 3). (16) The liquid fuel can be fed into larger fuel particles to intercept the fuel and prevent the atomization of the fuel to prevent the large ones from preventing excessive fuel particles from reaching the catalyst layer (1 3). It does have the detection function of the following temperature sensors, and makes heating plugs, air supply systems, and integrated operations, automatically switching "partial oxygen reaction mode" and other heating functions to increase the production of hydrogen-rich gas. It uses gas-assisted atomized fuel for additional heating to get a good outer edge. There are a few pluses for easy maintenance, and at the same time, it can be heated with pluses, which can improve the heat storage layer made of heating materials. Take the rate. 9 Strainer to stop local reaction of liquid fuel ingredients and release a large amount of
第11頁 013576 M246204 四、創作說明(7) 熱能傷害觸媒層。 綜上所述,本創作確實可達到預期之使用目的及功效 ,且於同類產品中更未見有相同創作特徵公知、公用在先 者,故本創作當能符合新型專利之申請要件,爰依法提出 專利申請5懇請早曰審結’並賜准專利’貫深任感荷。Page 11 013576 M246204 Fourth, creation instructions (7) Thermal energy hurts the catalyst layer. In summary, this creation can indeed achieve the intended use purpose and effect, and it has not seen the same creative characteristics and common antecedents in similar products. Therefore, this creation should meet the application requirements for new patents, according to law Filed a patent application 5 I would like to ask for the conclusion of the 'and quasi-patent' as early as possible.
第頁 013577 M246204 圖式簡單說明 第一圖係為本創作之結構示意圖。 第二圖係為本創作另一實施例蓄熱層結構之示意圖。 第三圖係為本創作又一實施例濾網結構之示意圖。 【元件符號說明】 (1) 重組器 (11) 加熱室 (12) 加熱塞 (13) 觸媒層 (14) 出〇 (15) 蓄熱層 (16) 濾網 (2) 空氣供應系統 (21) 喷嘴 (3) 燃料供應糸統 (31) 第一管路 (32) 第二管路 (33) 喷嘴 (4) 水蒸汽供應系統 (41) 喷嘴 (5) 控制模組 (51) 溫度感測器Page 013577 M246204 Brief description of the drawings The first picture is a schematic diagram of the structure of this creation. The second figure is a schematic diagram of a heat storage layer structure according to another embodiment of the present invention. The third diagram is a schematic diagram of the filter structure of another embodiment of the creation. [Description of component symbols] (1) Reassembler (11) Heating chamber (12) Heating plug (13) Catalyst layer (14) Out 0 (15) Heat storage layer (16) Strainer (2) Air supply system (21) Nozzle (3) Fuel supply system (31) First line (32) Second line (33) Nozzle (4) Water vapor supply system (41) Nozzle (5) Control module (51) Temperature sensor
第13頁 013578Page 13 013578
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