TWI789132B - Living clay fiber, fabric and producing method thereof - Google Patents
Living clay fiber, fabric and producing method thereof Download PDFInfo
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一種纖維的製造方法，特別是一種活性黏土纖維及其織物與製造方法。 A fiber manufacturing method, especially an activated clay fiber, its fabric and its manufacturing method.
近年來由於低勞力成本國家崛起以及區域經濟優惠關稅政策興起，使得台灣紡織工業中低附加價值以及技術層次較低之產品逐漸被式微。為求創意以及高經濟之效益以及配合長照觀念的重視，具備差異化或是特殊功能的纖維產品也隨之開發。 In recent years, due to the rise of countries with low labor costs and the rise of preferential tariff policies for regional economies, products with low added value and low technical levels in Taiwan's textile industry have gradually declined. In order to seek creativity and high economic benefits and to match the emphasis on the concept of long-term care, fiber products with differentiation or special functions are also developed accordingly.
然而，配合現代人生活形態以及保健意識的高漲以及社會人口高齡化的發展，具能量保健且抗紫外線的衣物也隨之熱門的應用於生活當中。然而具能量保健且抗紫外線的特殊功能纖維在製作過程中，除了需要長時間的研發還需要冗長的化學反應時間，配合未來市售以及生產等發展方向考量，可以快速量產並節省製作步驟的具能量保健且抗紫外線纖維成為相關產業急欲發展之目標。 However, in line with the rising lifestyle of modern people and the awareness of health care, as well as the development of the aging population, clothing with energy, health care and anti-ultraviolet rays is also popularly used in daily life. However, in the production process of special functional fibers with energy health care and anti-ultraviolet rays, in addition to long-term research and development, lengthy chemical reaction time is required. Considering the development direction of future commercial sales and production, it can be mass-produced quickly and save the cost of production steps. Fibers with energy, health care and anti-ultraviolet rays have become the targets that related industries are eager to develop.
為了發展一種快速量產並節省製作步驟的具能量保健且抗紫外線纖維，本發明提供一種活性黏土纖維製造方法，其步驟包含： 製備一複合漿料：將一天然黏土經由濕式研磨並均勻的分散於一遠紅外線粉體中，形成該複合漿料，其中，該複合粉體的粒徑大小為D50<400nm、D99<800nm；製備一PA6/Clay複合切片：將該複合漿料定量的加入到一己內醯胺(ε-caprolactam,CPL)溶液中形成一複合混料，透過的一原位聚合法使得該己內醯胺經由攝氏190度2小時的一開環反應以及攝氏250度一聚合反應生成該PA6/Clay複合切片，其中，添加一磷鎢酸(Tungstophosphoric acid,TPA)催化劑以及聚丙二醇(Polypropylene glycol)分散劑，且該PA6/Clay複合切片的固含量為3wt%；以及形成一PA6/Clay複合纖維：經由一熔融紡絲法，將該PA6/Clay複合切片製成該PA6/Clay複合纖維。 In order to develop an energy-healthy and anti-ultraviolet fiber that can be quickly mass-produced and saves manufacturing steps, the present invention provides a method for manufacturing activated clay fibers, the steps of which include: Preparation of a composite slurry: A natural clay is wet-milled and uniformly dispersed in a far-infrared powder to form the composite slurry, wherein the particle size of the composite powder is D50<400nm, D99<800nm ; Preparation of a PA6/Clay composite slice: quantitatively adding the composite slurry to a caprolactam (ε-caprolactam, CPL) solution to form a composite mixture, through an in-situ polymerization method to make the caprolactam The PA6/Clay composite chip is generated through a ring-opening reaction at 190 degrees Celsius for 2 hours and a polymerization reaction at 250 degrees Celsius, wherein a phosphotungstic acid (Tungstopphosphoric acid, TPA) catalyst and a polypropylene glycol (Polypropylene glycol) dispersant are added, And the solid content of the PA6/Clay composite chip is 3wt%; and forming a PA6/Clay composite fiber: making the PA6/Clay composite chip into the PA6/Clay composite fiber through a melt spinning method.
其中，該天然黏土為奈米級無機層狀矽酸鹽材料，該天然黏土可選為一高嶺石、一蒙脫石、一鈣基膨潤土或是一綠土黏土。 Wherein, the natural clay is a nano-scale inorganic layered silicate material, and the natural clay can be selected from a kaolinite, a montmorillonite, a calcium-based bentonite or a smectite clay.
其中，該遠紅外線粉體可以是以金屬或非金屬化合物所組成，該遠紅外線粉體之成分可自選自天然礦石、陶瓷粉末、三氧化二鋁(Al2O3)、二氧化矽(SiO2)或是上述之混合。 Wherein, the far-infrared powder can be composed of metal or non-metallic compounds, and the components of the far-infrared powder can be selected from natural ore, ceramic powder, aluminum oxide (Al 2 O 3 ), silicon dioxide (SiO 2 ) or a mixture of the above.
其中，於該原位聚合法反應時添加一改質劑或是一插層劑。 Wherein, a modifying agent or an intercalation agent is added during the in-situ polymerization reaction.
其中，該複合粉體的一組成份包含矽、鋁、鉀、鐵、鈣、鈦元素，該複合粉體的粒徑大小為D50=351nm、D99=627nm。 Wherein, one component of the composite powder includes silicon, aluminum, potassium, iron, calcium, and titanium elements, and the particle size of the composite powder is D50=351nm, D99=627nm.
本發明更提供一種活性黏土纖維及其織物，其中，該PA6/Clay複合纖維配比介於27%~81%之間；以及該複合粉體之一表面電位為-36.45mV。 The present invention further provides an activated clay fiber and its fabric, wherein the proportion of the PA6/Clay composite fiber is between 27% and 81%; and the surface potential of one of the composite powders is -36.45mV.
其中，該織物包含一蠶絲蛋白紗，該蠶絲蛋白紗與該PA6/Clay複合纖維比例為1：1。 Wherein, the fabric includes a silk protein yarn, and the ratio of the silk protein yarn to the PA6/Clay composite fiber is 1:1.
本發明之活性黏土纖維織物具備改善人體保健、血液循環、新陳代謝與吸附汙物等功能。成品將推廣於長照用品、秋冬季襯衫、長短褲、運動衣、運動褲、帽子、鞋材、襪子、內衣、內褲、襯墊、袖套、床套、寢具、絲巾、座墊填充材及生技產品之面膜、濕巾、化妝用棉等應用領域為主。 The activated clay fiber fabric of the present invention has the functions of improving human health care, blood circulation, metabolism and absorbing dirt. The finished product will be promoted in long-term photo products, autumn and winter shirts, long shorts, sportswear, sports pants, hats, shoe materials, socks, underwear, underwear, pads, sleeve covers, bed covers, bedding, silk scarves, seat cushion filling Materials and biotechnology products are mainly used in facial masks, wet wipes, and cosmetic cotton.
圖1為本發明較佳實施例製造方法流程圖 Fig. 1 is the flow chart of manufacturing method of preferred embodiment of the present invention
圖2為本發明較佳實施例XRD繞射圖 Fig. 2 is the XRD diffraction figure of preferred embodiment of the present invention
圖3為本發明較佳實施例SEM電子影像圖 Fig. 3 is the SEM electronic image figure of the preferred embodiment of the present invention
請參考圖1，其為本發明所提供的活性黏土纖維製造方法較佳實施例，其步驟包含： Please refer to Fig. 1, it is the preferred embodiment of the activated clay fiber manufacturing method provided by the present invention, and its steps include:
步驟S1，製備一複合漿料：利用一天然黏土(Clay)為基本材料，使其經由濕式研磨並均勻的分散於一遠紅外線粉體中，形成該複合漿料。該天然黏土是一種常見奈米級無機層狀矽酸鹽材料，具有良好的機械強度以及熱穩定性。該天然黏土可選一高嶺石、一蒙脫石或是該蒙脫石家族之一鈣基膨潤土或一綠土黏土。 Step S1, preparing a composite slurry: using a natural clay (Clay) as a basic material, wet grinding it and uniformly dispersing it in a far-infrared powder to form the composite slurry. The natural clay is a common nanoscale inorganic layered silicate material with good mechanical strength and thermal stability. The natural clay can be a kaolinite, a montmorillonite, or a calcium-based bentonite or a smectite clay of the montmorillonite family.
本實施例中，該天然黏土選為該鈣基膨潤土，該鈣基膨潤土因其特殊的層型晶體結構，使得該膨潤土具備有良好的吸水性而展現其獨特的膨脹性。由於該鈣基膨潤土所具備的功能性基團，使得該鈣基膨潤土於吸水膨脹的同時可以吸收帶有正電的之離子，另該鈣基膨潤土更具備有優秀的陽離子吸附與交換之特性。除此之外，該鈣基膨潤土還具備分散懸浮性、可塑性、滑潤性 以及，使其於後續流程可以較佳的進行化學反應。較佳的，該天然黏土包含有該綠土黏土，該綠土黏土具備絕佳的陽離子吸附與交換之特性，是其具備獨特的吸附和吸收毒素的能力。 In this embodiment, the natural clay is selected as the calcium-based bentonite. The calcium-based bentonite exhibits unique expansibility due to its special layered crystal structure, which enables the bentonite to have good water absorption. Due to the functional groups of the calcium-based bentonite, the calcium-based bentonite can absorb positively charged ions while absorbing water and expand, and the calcium-based bentonite has excellent cation adsorption and exchange properties. In addition, the calcium-based bentonite also has dispersion suspension, plasticity, lubricity And, it can better carry out chemical reaction in the subsequent process. Preferably, the natural clay contains the smectite clay, and the smectite clay has excellent cation adsorption and exchange properties, and it has a unique ability to absorb and absorb toxins.
該遠紅外線粉體可以是以金屬或非金屬化合物所組成，該遠紅外線粉體之成分可自選自天然礦石、陶瓷粉末、三氧化二鋁(Al2O3)、二氧化矽(SiO2)、或是上述之混合，依據所需，該遠紅外線粉體和可以添加可抗靜電之ZnO或MgO、抗X射線之BaSO 4 或CaO、抗電磁波之Sb2O3、抗紫外線之TiO2或是具阻燃效果的B2O3、Fe2O3等。由於該鈣基膨潤土的添加，該複合漿料具備有高濃度的礦物離子，例如：矽離子、鐵離子、鈣離子以及鉀離子等等。綜合該天然黏土以及該遠紅外線粉體之原料特性，該複合漿料可以具備有能量保健以及抗UV之功能，而相關效果之測驗將後續說明； The far-infrared powder can be composed of metal or non-metallic compounds, and the components of the far-infrared powder can be selected from natural ore, ceramic powder, aluminum oxide (Al 2 O 3 ), silicon dioxide (SiO 2 ) , or a mixture of the above, according to the needs, the far-infrared powder can be added with antistatic ZnO or MgO, anti-X-ray BaSO 4 or CaO, anti-electromagnetic wave Sb 2 O 3 , anti-ultraviolet TiO 2 or It is B 2 O 3 , Fe 2 O 3 , etc. with flame retardant effect. Due to the addition of the calcium-based bentonite, the composite slurry has a high concentration of mineral ions, such as silicon ions, iron ions, calcium ions, and potassium ions. Combining the raw material characteristics of the natural clay and the far-infrared powder, the composite slurry can have the functions of energy health care and anti-UV, and the test of related effects will be explained later;
步驟S2，製備一PA6/Clay複合切片：將該複合漿料定量的加入到一己內醯胺(ε-caprolactam,CPL)溶液中形成一複合混料，接著透過一原位聚合法中該己內醯胺可以經由一開環反應以及一聚合反應生成的一聚醯胺(polyamide 6,PA6)，使得將該複合混料可以透過該原位聚合法製成該PA6/Clay複合切片。 Step S2, preparing a PA6/Clay composite chip: quantitatively adding the composite slurry to a caprolactam (ε-caprolactam, CPL) solution to form a composite mixture, and then through an in-situ polymerization method. Amide can generate a polyamide (polyamide 6, PA6) through a ring-opening reaction and a polymerization reaction, so that the composite mixture can be made into the PA6/Clay composite chip through the in-situ polymerization method.
於該原位聚合法的過程中，添加一磷鎢酸(Tungstophosphoric acid,TPA)催化劑以及聚丙二醇(Polypropylene glycol)分散劑，使得該複合漿料有效地均勻分散於該CPL溶液中，並經由攝氏190度2小時的該開環反應以及攝氏250度的該聚合反應，使得該複合漿料可均勻分散於該CPL溶液中。接著經由冷卻固化以及乾燥破碎形成一複合粉體，並且將該複合粉體經由攝氏100度2小時的一沸水純化流程以及攝氏120度24小時的一真空乾燥流程於形成該PA6/Clay複合切片。經由該原位聚合法合成後的該PA6/Clay複合切片，其固含量為3wt%。 In the process of the in-situ polymerization method, a phosphotungstic acid (Tungstopphosphoric acid, TPA) catalyst and a polypropylene glycol (Polypropylene glycol) dispersant are added, so that the composite slurry is effectively uniformly dispersed in the CPL solution, and passed through the Celsius The ring-opening reaction at 190°C for 2 hours and the polymerization reaction at 250°C allow the composite slurry to be uniformly dispersed in the CPL solution. Then, a composite powder is formed by cooling, solidification, drying and crushing, and the composite powder is subjected to a boiling water purification process at 100 degrees Celsius for 2 hours and a vacuum drying process at 120 degrees Celsius for 24 hours to form the PA6/Clay composite chip. The PA6/Clay composite chip synthesized by the in-situ polymerization method has a solid content of 3wt%.
較佳的，由於該鈣基膨潤土具備有親水性，是其與大部分具殊水性的該高分子材料相容性低，可以進一步的添加一改質劑或是一插層劑於其中，如：氨基已酸(Aminocaproic Acid)或是已二酸已二胺鹽(Hexamethylene diamine adipate,Nylon-66 salt)。使得該鈣基膨潤土便可以無須憑藉機器剪切力的應用，並且經由一插層技術、一脫層技術或是一陽離子交換技術而更完善的分散於該聚醯胺(polyamide 6,PA 6)中。 Preferably, since the calcium-based bentonite has hydrophilicity, it has low compatibility with most of the high-molecular materials with special water properties, and a modifier or an intercalation agent can be further added therein, such as : Aminocaproic Acid or Hexamethylene diamine adipate (Nylon-66 salt). So that the calcium-based bentonite can be dispersed in the polyamide (polyamide 6, PA 6) more perfectly through an intercalation technology, a delamination technology or a cation exchange technology without the application of machine shear force middle.
步驟S3，形成一PA6/Clay複合纖維：經由一熔融紡絲法，將該PA6/Clay複合切片製成該PA6/Clay複合纖維，該PA6/Clay複合纖維可以依據所需製程不同型態之長纖絲或是短纖絲。透過該熔融紡絲法使得該PA6/Clay複合切片加熱至呈現熔融狀態，隨後經過導管引導至一紡絲唧筒，並經由該紡絲唧筒將熔融狀的該PA6/Clay複合切片擠出並經過冷卻、延伸並捲取成該PA6/Clay複合纖維。本實施例中，該PA6/Clay複合纖維為40d/24f全延伸絲(FDY)。 Step S3, forming a PA6/Clay composite fiber: through a melt spinning method, the PA6/Clay composite chip is made into the PA6/Clay composite fiber, and the PA6/Clay composite fiber can have different lengths according to the required process. filaments or short filaments. Through the melt spinning method, the PA6/Clay composite chip is heated to a molten state, and then guided to a spinning pump through a catheter, and the molten PA6/Clay composite chip is extruded through the spinning pump and cooled , stretched and coiled into the PA6/Clay composite fiber. In this embodiment, the PA6/Clay composite fiber is 40d/24f fully extended yarn (FDY).
步驟S4，形成一PA6/Clay纖維織物：以42G之圓編針織機製造各種不同結構與規格之該PA6/Clay纖維織物。 Step S4, forming a PA6/Clay fiber fabric: using a 42G circular knitting machine to manufacture the PA6/Clay fiber fabric with various structures and specifications.
於步驟S2後，該複合粉體的粒徑大小為D50<400nm、D99<800nm，較佳的該複合粉體的粒徑大小為D50=351nm；D99=627nm。接著，本發明進一步的，檢測該複合粉體的一脫色率、一表面電位值、一組成份。 After step S2, the particle size of the composite powder is D50<400nm, D99<800nm, preferably the particle size of the composite powder is D50=351nm; D99=627nm. Next, the present invention further detects a decolorization rate, a surface potential value, and a composition of the composite powder.
脫色率測驗：脫色率測驗是為了的測試該複合粉體吸收一色素的能力。本發明以羅丹明B(RHB)作為脫色率測驗的脫色染料，將該複合粉體加入於一羅丹明B染料溶液中，並置於暗室攪拌1小時，最後利用一紫外可見光譜儀分析並計算該複合粉體之該脫色率(%)，於常規中，該脫色率應大於等於65%。其中，該脫色率(%)的計算公式如下：(原羅丹明B染料溶液濃度-脫色後羅丹明B染料溶液濃度)/原羅丹明B染料溶液濃度x 100% Decolorization rate test: The decolorization rate test is to test the ability of the composite powder to absorb a pigment. In the present invention, Rhodamine B (RHB) is used as the decolorizing dye for the decolorization rate test, and the composite powder is added into a rhodamine B dye solution, and placed in a dark room for stirring for 1 hour, and finally, an ultraviolet-visible spectrometer is used to analyze and calculate the composite powder. The decolorization rate (%) of the powder, conventionally, the decolorization rate should be greater than or equal to 65%. Wherein, the calculation formula of the decolorization rate (%) is as follows: (concentration of the former Rhodamine B dye solution-decolorized back Rhodamine B dye solution concentration)/former Rhodamine B dye solution concentration x 100%
經由脫色率測驗，該複合粉體之該脫色率介於80%~90%之間。 After the decolorization rate test, the decolorization rate of the composite powder is between 80% and 90%.
表面電位值測驗：本發明利用Brookhaven之NanoBrook 90Plus PALS分析儀，配合該分析儀的動態光散射(DLS)原理進行該複合粉體之粒度和分佈，並且利用都卜勒速測法(電泳光散射，ELS)進行該表面電位值測量，於常規中，該表面電位值應大於絕對值30mV。本發明該複合粉體經由該表面電位為-36.45mV，該複合粉體呼應了前段落所敘述之具備有該天然黏土可以吸收及交換陽離子之能力。 Surface potential value test: the present invention utilizes the NanoBrook 90Plus PALS analyzer of Brookhaven, cooperates the dynamic light scattering (DLS) principle of this analyzer to carry out the particle size and the distribution of this composite powder, and utilizes Doppler speed measurement method (electrophoretic light scattering , ELS) to measure the surface potential value, in the conventional, the surface potential value should be greater than the absolute value of 30mV. The potential of the composite powder of the present invention is -36.45mV through the surface, and the composite powder echoes the ability of the natural clay to absorb and exchange cations as described in the previous paragraph.
X射線繞射儀(X-ray diffractometer，XRD)以及X射線螢光分析儀(X-Ray Fluorescence Spectrometer,XRF)分析：利用X射線繞射原理進一步的生成繞射圖譜以確認該複合粉體的內部結構，並且利用X射線照射至該複合粉體上，激發該複合粉體中的元素訊號，進行該複合粉體所含之該組成份。請參考圖2以及表1，經由X射線繞射儀(X-ray diffractometer，XRD)以及X射線螢光分析儀(X-Ray Fluorescence Spectrometer,XRF)分析，可以該複合粉體的該組成份主要含有矽、鋁、鉀，以及較少量的鐵、鈣、鈦等元素。 X-ray diffractometer (XRD) and X-ray fluorescence analyzer (X-Ray Fluorescence Spectrometer, XRF) analysis: use the principle of X-ray diffraction to further generate diffraction patterns to confirm the composition of the composite powder internal structure, and use X-rays to irradiate the composite powder to excite elemental signals in the composite powder to carry out the components contained in the composite powder. Please refer to Figure 2 and Table 1, through X-ray diffractometer (X-ray diffractometer, XRD) and X-ray fluorescence analyzer (X-Ray Fluorescence Spectrometer, XRF) analysis, the composition of the composite powder can be mainly Contains silicon, aluminum, potassium, and lesser amounts of iron, calcium, titanium and other elements.
於步驟S2後，本發明檢測該PA6/Clay複合切片的一壓昇測試為△P=0.5bar/kg，並且透過一掃描式電子顯微鏡(Scanning Electron Microscope,SEM)以及該X射線螢光分析儀(X-Ray Fluorescence Spectrometer,XRF)分析該PA6/Clay複合切片。請配合參考圖3，其為該PA6/Clay複合切片經由該掃描式電子顯微鏡利用電子束在高倍率下生成該PA6/Clay複合切片的一電子影像圖。表2 為該PA6/Clay複合切片經由X射線繞射儀(X-ray diffractometer，XRD)測驗後該組成份分析表，可以知道該PA6/Clay複合切片的該組成份主要含有鈦(Ti)以及矽(Si)，以及較少量的鐵(Fe)、鈣(Ca)、鉀(K)等元素，可以與該複合粉體之組成份相互對應。 After step S2, the present invention detects that a pressure rise test of the PA6/Clay composite slice is ΔP=0.5bar/kg, and through a scanning electron microscope (Scanning Electron Microscope, SEM) and the X-ray fluorescence analyzer (X-Ray Fluorescence Spectrometer, XRF) analysis of the PA6/Clay composite slice. Please refer to FIG. 3 , which is an electronic image of the PA6/Clay composite slice generated by the scanning electron microscope using an electron beam at high magnification. Table 2 The composition analysis table of the PA6/Clay composite slice after the X-ray diffractometer (XRD) test shows that the composition of the PA6/Clay composite slice mainly contains titanium (Ti) and silicon ( Si), and a small amount of iron (Fe), calcium (Ca), potassium (K) and other elements can correspond to the composition of the composite powder.
請參考表3，於步驟S3後，本發明將所得之該PA6/Clay複合纖維(40d/24f全延伸絲)，與常規的一聚醯胺6纖維(40d/34f)及一涼感纖維(40d/24f全延伸絲)進行各物理性能比較。可以知道該PA6/Clay複合纖維仍然具備了聚醯胺6的柔軟性能以及彈性。值得注意的是，該PA6/Clay複合纖維的均勻度明顯的大於常規的該聚醯胺6纖維及該涼感纖維，表示該PA6/Clay複合纖維的物理性能較為優異，有利於後續加工的應用。 Please refer to Table 3, after step S3, the present invention combines the resulting PA6/Clay composite fiber (40d/24f fully extended yarn) with a conventional polyamide 6 fiber (40d/34f) and a cooling fiber (40d /24f full extension wire) to compare the physical properties. It can be known that the PA6/Clay composite fiber still has the softness and elasticity of polyamide 6. It is worth noting that the uniformity of the PA6/Clay composite fiber is significantly greater than that of the conventional polyamide 6 fiber and the cooling fiber, indicating that the PA6/Clay composite fiber has excellent physical properties and is conducive to the application of subsequent processing.
請配合參考表4，該PA6/Clay複合纖維經由該步驟S4織成幅寬60英寸(inch)以及布重約179gsm的該PA6/Clay纖維織物後，分別依循規範AATCC 61、AATCC 112、OEKO-TEX、ASTM D737以及AATCC 183測試方法，測驗一 耐洗染色堅牢度、一游離甲醛含量、一10項重金屬含量、一透氣度以及一抗UV性能。可以知道，該PA6/Clay纖維織物皆達到了各項測驗之標準值。值得注意的是，該PA6/Clay纖維織物的該抗UV性能明顯的高於標準值7倍以上。 Please refer to Table 4. After the PA6/Clay composite fiber is woven into the PA6/Clay fiber fabric with a width of 60 inches (inch) and a cloth weight of about 179gsm through the step S4, it follows the specifications of AATCC 61, AATCC 112, and OEKO- TEX, ASTM D737 and AATCC 183 Test Methods, Quiz 1 Dyeing fastness to washing, free formaldehyde content, 10 heavy metal content, air permeability and UV resistance. It can be known that the PA6/Clay fiber fabric has reached the standard values of various tests. It is worth noting that the UV resistance of the PA6/Clay fiber fabric is significantly higher than the standard value by more than 7 times.
請配合參考表5.，本發明進一步的將該PA6/Clay複合纖維分別與一一般紗線以及/或一蠶絲蛋白紗共同編織成針數42G、幅寬60英寸(inch)以及布重約179gsm的該PA6/Clay纖維織物。並觀察經由不同比例與其他材質之紗線共同織成的該PA6/Clay纖維織物的各項性能。其中，布號A以及布號D為將該PA6/Clay複合纖維分別以81%以及40%的配比與該一般紗線編織成的該PA6/Clay纖維織物；而布號B以及布號C則為該PA6/Clay複合纖維與該蠶絲蛋白紗以1比1的比率下編織成的該PA6/Clay纖維織物。 Please refer to Table 5. The present invention further knits the PA6/Clay composite fiber with a common yarn and/or a silk protein yarn into a needle number of 42G, a width of 60 inches (inch) and a cloth weight of about 179gsm The PA6/Clay fiber fabric. And observe the various properties of the PA6/Clay fiber fabric woven together with yarns of other materials in different proportions. Among them, cloth number A and cloth number D are the PA6/Clay fiber fabrics woven into the PA6/Clay composite fiber at a ratio of 81% and 40% respectively with the general yarn; and cloth number B and cloth number C Then it is the PA6/Clay fiber fabric woven into the PA6/Clay composite fiber and the silk protein yarn at a ratio of 1:1.
可以看到布號A至D的該PA6/Clay纖維織物於不管是在一熱影像溫差測試、一遠紅外線放射測試、一保溫率測試以及一熱焓測試中，皆展現了優異的數據結果，即使僅含有27%的該PA6/Clay複合纖維配比下，該PA6/Clay纖維織物不僅可以呈現具保溫效果，還具備散發一遠紅外線熱能的效果，有助於幫助人體微血管擴張、促進血液循環且提高養分的吸收與傳遞、排除毒素並降低發炎反應的產生。 It can be seen that the PA6/Clay fiber fabrics of cloth numbers A to D have shown excellent data results in a thermal image temperature difference test, a far-infrared radiation test, a heat retention rate test, and a heat enthalpy test. Even if it only contains 27% of the PA6/Clay composite fiber ratio, the PA6/Clay fiber fabric can not only show a thermal insulation effect, but also have the effect of emitting a far-infrared heat energy, which helps to expand the microvessels of the human body and promote blood circulation. And improve the absorption and delivery of nutrients, eliminate toxins and reduce inflammation.
而在一吸水面積測試中，同樣的也可以看到布號A至D的該PA6/Clay纖維織物相較於標準值中，皆具備了強大的吸水效果，這代表該PA6/Clay纖維織物具備良好的吸濕性，作為一衣物時可以展現乾爽舒適之穿著效果。 In a water absorption area test, it can also be seen that the PA6/Clay fiber fabrics with cloth numbers A to D have a strong water absorption effect compared with the standard value, which means that the PA6/Clay fiber fabric has Good hygroscopicity, when used as a garment, it can show a dry and comfortable wearing effect.
其中布號B以及布號C的該PA6/Clay纖維織物中，該PA6/Clay複合纖維中與該蠶絲蛋白紗皆以1比1的比率，分別以40%以及27%的配比與該一般紗線編織成該PA6/Clay纖維織物。該蠶絲蛋白紗主要成分為蛋白質及胺基酸，對人體皮膚具有極佳親和性、無刺激性及過敏反應，且具備了透水性、透氣性佳、抗紫外線、抗菌等功能。在一保濕率測試中也可以明顯的看出，布號B以及布號C的該PA6/Clay纖維織物具有良好的保濕效果，可以應用於敏感皮膚區域或是嬰兒用衣物，展現親膚滑潤特性。 Among them, in the PA6/Clay fiber fabrics of cloth number B and cloth number C, the PA6/Clay composite fiber and the silk protein yarn are all in a ratio of 1 to 1, respectively 40% and 27% with the general Yarn is woven into this PA6/Clay fiber fabric. The main components of the silk protein yarn are proteins and amino acids, which have excellent affinity to human skin, no irritation and allergic reactions, and have functions such as water permeability, good air permeability, anti-ultraviolet radiation, and antibacterial. It can also be clearly seen in a moisture retention rate test that the PA6/Clay fiber fabrics of cloth number B and cloth number C have a good moisturizing effect, and can be applied to sensitive skin areas or baby clothes, showing skin-friendly and smooth properties .
進一步的利用，布號A的該PA6/Clay纖維織物證實其對於人體的影響效果，經由財團法人紡織產業綜合研究所-人體穿著性能試驗驗證結果中，一受測者穿著布號A的該PA6/Clay纖維織物後一血流速度提升17.3%、一血流量提升16.5%以及一血氧含量提升2.0%，呼應了前段落所述的該PA6/Clay纖維織物有助於人體的能量保健效果。 For further use, the PA6/Clay fiber fabric of cloth number A confirmed its effect on the human body. According to the verification results of the Textile Industry Research Institute-Human Body Wearing Performance Test, a subject wearing the PA6 fabric of cloth number A After the /Clay fiber fabric, the blood flow velocity is increased by 17.3%, the blood flow rate is increased by 16.5%, and the blood oxygen content is increased by 2.0%, echoing the energy health care effect of the PA6/Clay fiber fabric mentioned in the previous paragraph.
本發明之活性黏土纖維及其織物製造方法步驟簡單，有助於於相關產業的快速量產，且該天然黏土於地殼中含量豐富，工業成本低。透過該聚醯胺6於形成時使將具有該天然黏土的該複合漿料均勻分散於其中，使得該PA6/Clay纖維可以展現結合有該聚醯胺6優秀之機械性能、耐化學性、柔軟性、耐磨性並具備該天然黏土滑潤性以及能量保健以及抗UV等特性。進一步的該PA6/Clay纖維還可以依據所需與其他如蠶絲蛋白紗的功能型紗線共同編織，使得本發明之活性黏土纖維及其織物可以再不影響該PA6/Clay纖維特性下展現其他功能型紗線之功能，強化了該聚醯胺6的應用，也拓展台灣紡織工業的應用。 The manufacturing method of the active clay fiber and the fabric thereof of the present invention has simple steps, is conducive to the rapid mass production of related industries, and the natural clay is abundant in the earth's crust, and the industrial cost is low. When the polyamide 6 is formed, the composite slurry with the natural clay is uniformly dispersed in it, so that the PA6/Clay fiber can exhibit the excellent mechanical properties, chemical resistance, and softness combined with the polyamide 6 resistance, wear resistance and has the lubricity of this natural clay as well as energy health and UV resistance properties. Further, the PA6/Clay fiber can also be woven together with other functional yarns such as silk protein yarn according to requirements, so that the activated clay fiber and its fabric of the present invention can exhibit other functional types without affecting the properties of the PA6/Clay fiber. The function of the yarn strengthens the application of polyamide 6 and expands the application of Taiwan's textile industry.
本發明之活性黏土纖維織物具備人體保健、改善血液循環、加速新陳代謝以及陽離子吸附汙物等功能。PA6/Clay纖維可以應用於長照用品、秋冬季襯衫、長短褲、運動衣、運動褲、帽子、鞋材、襪子、內衣、內褲、襯墊、袖套、床套、寢具、絲巾、座墊填充材及生技產品之面膜、濕巾、化妝用棉等領域。 The active clay fiber fabric of the present invention has the functions of human health care, improvement of blood circulation, acceleration of metabolism and cation adsorption of dirt. PA6/Clay fiber can be used in long-term photo products, autumn and winter shirts, long shorts, sportswear, sports pants, hats, shoe materials, socks, underwear, underwear, pads, sleeve covers, bed covers, bedding, silk scarves, Cushion filling materials and biotechnology products such as facial masks, wet wipes, and cosmetic cotton.
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| JP2021110071A (en) * | 2020-01-14 | 2021-08-02 | 日本製紙株式会社 | Assembly of fiber and inorganic particle |
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| TW201333111A (en) * | 2011-11-14 | 2013-08-16 | Honeywell Int Inc | Polyamide composition for low temperature applications |
| CN104211955A (en) * | 2013-05-31 | 2014-12-17 | 骏马化纤股份有限公司 | Halogen-free flame-retardation nylon 6 montmorillonite nanocomposite and preparation method thereof |
| US20190048491A1 (en) * | 2016-06-08 | 2019-02-14 | Nantong Qiangsheng Graphene Technology Co., Ltd. | Method for Preparing Graphene-Polyamide Nanocomposite Fiber |
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