TWI787323B - Measuring device, measurement method, and plasma processing device - Google Patents

Measuring device, measurement method, and plasma processing device Download PDF

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TWI787323B
TWI787323B TW107128150A TW107128150A TWI787323B TW I787323 B TWI787323 B TW I787323B TW 107128150 A TW107128150 A TW 107128150A TW 107128150 A TW107128150 A TW 107128150A TW I787323 B TWI787323 B TW I787323B
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electrostatic capacitance
measurement
mentioned
electrode
frequency power
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TW201921417A (en
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佐藤雅紀
樫村龍成
綱本哲
大﨑良規
荒金俊行
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日商東京威力科創股份有限公司
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R19/00Arrangements for measuring currents or voltages or for indicating presence or sign thereof
    • G01R19/0046Arrangements for measuring currents or voltages or for indicating presence or sign thereof characterised by a specific application or detail not covered by any other subgroup of G01R19/00
    • G01R19/0061Measuring currents of particle-beams, currents from electron multipliers, photocurrents, ion currents; Measuring in plasmas
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R29/00Arrangements for measuring or indicating electric quantities not covered by groups G01R19/00 - G01R27/00
    • G01R29/24Arrangements for measuring quantities of charge
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32532Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32715Workpiece holder

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  • Plasma & Fusion (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Drying Of Semiconductors (AREA)
  • Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)
  • Measurement Of Current Or Voltage (AREA)
  • Plasma Technology (AREA)
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  • Control And Other Processes For Unpacking Of Materials (AREA)
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Abstract

A measuring device includes a switch that switches a connection of an electrode to which high frequency electric power is applied, wherein the electrode is within an electrostatic chuck disposed in a plasma processing device; a component provided with electrostatic capacitance, wherein the component is connected to the switch; and a measuring unit that measures a value corresponding to an electric charge amount accumulated in the component provided with the electrostatic capacitance.

Description

測定裝置、測定方法及電漿處理裝置Measuring device, measuring method and plasma treatment device

本發明係關於一種測定裝置、測定方法及電漿處理裝置。 The invention relates to a measuring device, a measuring method and a plasma processing device.

於在電漿處理裝置內進行之蝕刻或成膜等電漿處理中,為了控制蝕刻速率或成膜速率,關鍵在於掌握電漿之狀態。因此,為了測定電漿之狀態而提出有測定自給偏壓電壓Vdc之方法(例如,參照專利文獻1、2)。 In the plasma treatment such as etching or film formation in the plasma treatment equipment, in order to control the etching rate or film formation rate, the key is to grasp the state of the plasma. Therefore, a method of measuring the self-bias voltage Vdc has been proposed in order to measure the state of the plasma (for example, refer to Patent Documents 1 and 2).

專利文獻1中,藉由不與電漿直接接觸之器件間接地測定自給偏壓電壓Vdc。於專利文獻1中,器件係設置於處理容器壁內,測定對器件內之由介電體絕緣之電極施加之電壓,根據該測定電壓考慮各寄生電容而算出自給偏壓電壓Vdc。 In Patent Document 1, the self-bias voltage Vdc is indirectly measured by a device not in direct contact with the plasma. In Patent Document 1, the device is installed in the wall of the processing container, the voltage applied to electrodes insulated by a dielectric in the device is measured, and the self-bias voltage Vdc is calculated by considering each parasitic capacitance from the measured voltage.

專利文獻2中,將自給偏壓電壓Vdc之測定電路組入至匹配器,並將測定電路之輸入電阻設為充分地大於簇射頭之電阻值之值,藉由測定電路進行自給偏壓電壓Vdc之測定。 In Patent Document 2, a measurement circuit for the self-sufficient bias voltage Vdc is incorporated into the matcher, and the input resistance of the measurement circuit is set to a value sufficiently larger than the resistance value of the shower head, and the self-supply bias voltage is performed by the measurement circuit. Determination of Vdc.

[先前技術文獻] [Prior Art Literature] [專利文獻] [Patent Document]

[專利文獻1]日本專利特開2001-148374號公報 [Patent Document 1] Japanese Patent Laid-Open No. 2001-148374

[專利文獻2]日本專利特開2006-93342號公報 [Patent Document 2] Japanese Patent Laid-Open No. 2006-93342

然而,上述方法必須變更裝置或電路之設計,無法簡易地進行自給偏壓電壓Vdc之測定。例如,於專利文獻1中,為了將器件設置於處理容器壁內而對處理容器壁進行機械加工。又,由於測定用探針位於遠離作為測定對象之電漿之位置,故而測定之感度及精度降低。於專利文獻2中,必須將自給偏壓電壓Vdc之測定電路組入至匹配器,而必須變更電漿處理裝置之設計。 However, the above-mentioned method needs to change the design of the device or the circuit, and cannot easily measure the self-sufficient bias voltage Vdc. For example, in Patent Document 1, the processing container wall is machined in order to install the device in the processing container wall. Also, since the measuring probe is located away from the plasma which is the measurement object, the sensitivity and accuracy of the measurement are lowered. In Patent Document 2, a measurement circuit for the self-sufficient bias voltage Vdc must be incorporated into the matching unit, and the design of the plasma processing device must be changed.

根據上述情況,於專利文獻1、2中,為了將用以進行自給偏壓電壓Vdc之測定之探針或測定電路組入,必須進行電漿處理裝置之機械設計之變更、高頻電路(匹配器)之變更,存在缺乏測定之通用性及簡易性之情形。 In view of the above, in Patent Documents 1 and 2, in order to incorporate a probe or a measurement circuit for measuring the self-sufficient bias voltage Vdc, it is necessary to change the mechanical design of the plasma processing device, high-frequency circuit (matching instrument) changes, there is a lack of versatility and simplicity of measurement.

針對上述問題,於一態樣中,本發明之目的在於簡易地進行電漿之自給偏壓電壓Vdc之測定。 In view of the above problems, in one aspect, the purpose of the present invention is to simply measure the plasma self-bias voltage Vdc.

為了解決上述問題,根據一態樣,提供一種測定裝置,其包含:切換部,其係配置於電漿處理裝置內之靜電吸盤內之電極,且切換被施加直流電壓之上述電極之連接;具有靜電電容之構件,其連接於上述切換部;及測定部,其測定相當於上述具有靜電電容之構件所儲存之電荷量之值。 In order to solve the above problems, according to one aspect, a measurement device is provided, which includes: a switching unit, which is an electrode disposed in an electrostatic chuck in a plasma processing device, and switches the connection of the electrode to which a DC voltage is applied; A member with electrostatic capacitance connected to the switching unit; and a measurement unit for measuring a value corresponding to the amount of charge stored in the member with electrostatic capacitance.

根據一態樣,可簡易地進行電漿之自給偏壓電壓Vdc之測定。 According to one aspect, the measurement of the plasma self-bias voltage Vdc can be easily performed.

1:氣體簇射頭 1: Gas shower head

1a:氣體導入口 1a: Gas inlet

1b:擴散室 1b: Diffusion chamber

1c:供給孔 1c: Supply hole

2:載台 2: carrier

2a:靜電吸盤 2a: Electrostatic Chuck

2b:基台 2b: Abutment

3:第1高頻電源 3: The first high-frequency power supply

3a:匹配器 3a: Matcher

4:第2高頻電源 4: The second high-frequency power supply

4a:匹配器 4a: Matcher

5:氣體供給部 5: Gas supply part

6:繼電器箱 6: Relay box

6a:開關 6a: switch

7:直流電源 7: DC power supply

8:聚焦環 8: Focus ring

9:排氣裝置 9: Exhaust device

10:測定裝置 10: Measuring device

11:濾波器 11: filter

12:銅圓板 12: Copper round plate

13:銅板 13: copper plate

14:丙烯酸系樹脂板 14: Acrylic resin board

15:探針 15: Probe

16:表面電位計 16: Surface potentiometer

17:信號記錄裝置 17: Signal recording device

18:電位測定系統 18: Potential measurement system

21:吸附電極 21: Adsorption electrode

22:介電層 22: Dielectric layer

22a:凸部 22a: convex part

100:電漿處理裝置 100: Plasma treatment device

200:控制部 200: control department

205:CPU 205:CPU

210:ROM 210:ROM

215:RAM 215: RAM

A:電極 A: electrode

bdot:面積 b dot : area

ddot:高度 d dot : height

C:處理容器 C: process container

C1:靜電電容 C 1 : Electrostatic capacitance

C2:靜電電容 C 2 : Electrostatic capacitance

C3:靜電電容 C 3 : Electrostatic capacitance

C11:靜電電容 C 11 : Electrostatic capacitance

C12:靜電電容 C 12 : Electrostatic capacitance

C13:靜電電容 C 13 : Electrostatic capacitance

CB:隔直流電容器 C B : DC blocking capacitor

G:閘閥 G: gate valve

HF:第1高頻電力 HF: 1st high frequency power

K:電極 K: electrode

LF:第2高頻電力 LF: 2nd high frequency power

q1:電荷 q 1 : charge

q2:電荷 q 2 : charge

q3:電荷 q 3 : charge

R:沈積物 R: sediment

RF:高頻電源 RF: High frequency power supply

S1~S6:步驟 S1~S6: steps

S10~S20:步驟 S10~S20: steps

T:高度 T: height

Th1:閾值 Th 1 : Threshold

Th2:閾值 Th 2 : Threshold

V1:電壓 V 1 : Voltage

V2:電壓 V 2 : voltage

Vdc:自給偏壓電壓 V dc : Self-sufficient bias voltage

W:晶圓 W: Wafer

圖1(a)、(b)係用以說明自給偏壓電壓之圖。 Fig. 1(a), (b) are diagrams used to illustrate the self-sufficient bias voltage.

圖2係表示一實施形態之電漿處理裝置及測定裝置之一例之圖。 Fig. 2 is a diagram showing an example of a plasma processing device and a measuring device according to an embodiment.

圖3係用以對一實施形態之自給偏壓電壓之測定時機進行說明之圖。 Fig. 3 is a diagram for explaining the timing of measuring the self-bias voltage in one embodiment.

圖4(a)、(b)係表示一實施形態之自給偏壓電壓之測定序列之一例之圖。 4( a ), ( b ) are diagrams showing an example of a measurement sequence of a self-bias voltage in one embodiment.

圖5(a)~(c)係表示一實施形態之自給偏壓電壓之測定序列之一例之圖。 5( a ) to ( c ) are diagrams showing an example of the measurement sequence of the self-bias voltage in one embodiment.

圖6係表示一實施形態之自給偏壓電壓之計算所使用之模型之一例之圖。 FIG. 6 is a diagram showing an example of a model used for calculation of self-bias voltage in one embodiment.

圖7係表示一實施形態之模型之等效電路之一例之圖。 Fig. 7 is a diagram showing an example of an equivalent circuit of a model of an embodiment.

圖8係表示一實施形態之自給偏壓電壓之測定結果之一例之圖。 Fig. 8 is a diagram showing an example of the measurement results of the self-bias voltage in one embodiment.

圖9係表示一實施形態之自給偏壓電壓與沈積時間之相關資訊之一例之圖。 FIG. 9 is a diagram showing an example of information related to self-bias voltage and deposition time in one embodiment.

圖10(a)~(i)係表示為了收集圖9之相關資訊而預先執行之測定之一例之圖。 FIGS. 10( a ) to ( i ) are diagrams showing examples of measurements performed in advance to collect the relevant information in FIG. 9 .

圖11係表示一實施形態之測定方法之一例之流程圖。 Fig. 11 is a flow chart showing an example of a measuring method in one embodiment.

以下,參照圖式對用以實施本發明之形態進行說明。再者,於本說明書及圖式中,對於實質上相同之構成,藉由標註相同符號而省略重複之說明。 Hereinafter, modes for implementing the present invention will be described with reference to the drawings. In addition, in this specification and drawing, about the structure which is substantially the same, the description which overlaps is abbreviate|omitted by attaching the same code|symbol.

[自給偏壓電壓] [Self Bias Voltage]

首先,一面參照圖1,一面對電漿之直流自給偏壓電壓(以下,稱為「自給偏壓電壓Vdc」)進行說明。圖1(a)中模式性地表示將電極A與電極K對向地配置而成之對向電極之一部分。電極A係接地之接地電極,電極K係經由隔直流電容器CB連接於高頻電源(RF(Radio Frequency,射頻)電源)之高頻電極。又,電極K之面積小於電極A之面積。 First, the DC self-bias voltage (hereinafter referred to as "self-bias voltage Vdc") of plasma will be described with reference to FIG. 1 . FIG. 1( a ) schematically shows a part of the counter electrode in which the electrode A and the electrode K are arranged to face each other. Electrode A is a ground electrode that is grounded, and electrode K is a high-frequency electrode that is connected to a high-frequency power supply (RF (Radio Frequency, radio frequency) power supply) via a DC blocking capacitor C B . Also, the area of the electrode K is smaller than the area of the electrode A.

對電極K施加高頻電力RF而使氣體游離及解離,從而產生電漿。由於對電極K施加正弦曲線之正負對稱之高頻電力RF,故電極K之電位總計為零。自所產生之電漿產生電子及陽離子,且如圖1(b)所示,於電極K相對於電漿處於正電位時,電子流入至電極K,處於負電位時,陽離子流入至電極K。 A high-frequency electric power RF is applied to the electrode K to dissociate and dissociate the gas, thereby generating plasma. Since the sinusoidal positive and negative symmetrical high-frequency power RF is applied to the electrode K, the potential of the electrode K is zero in total. Electrons and cations are generated from the generated plasma, and as shown in FIG. 1( b ), electrons flow into the electrode K when the electrode K is at a positive potential relative to the plasma, and cations flow into the electrode K when it is at a negative potential.

此時,電子由於質量較小,故而可追隨電極K之高速之電位變動。其 結果,電子流入至電極K。另一方面,陽離子由於質量較大,故而無法追隨電極K之高速之電位變動,於平均電場中遵循慣性定律而移動。因此,離子向電極K之流入量固定且極小。 At this time, electrons can follow the high-speed potential change of the electrode K due to their small mass. That As a result, electrons flow into the electrode K. On the other hand, the positive ions cannot follow the high-speed potential change of the electrode K due to their large mass, and move in the average electric field according to the law of inertia. Therefore, the inflow of ions to the electrode K is constant and extremely small.

由於電極K藉由隔直流電容器CB而自接地浮動,故而流入至電極K之電子不流動於接地。由此,於電極K之表面相對於電漿處於正電位之週期(半循環)中,電子流入並儲存於電極K。然而,電極K之表面因所儲存之電子而帶負電,從而對電漿產生負偏壓。由於該負偏壓,陽離子流入至電極K之表面。藉此,於電極K之表面形成鞘層。 Since the electrode K is floating from the ground by the DC blocking capacitor C B , the electrons flowing into the electrode K do not flow to the ground. Thus, electrons flow into and are stored in the electrode K during the period (half cycle) in which the surface of the electrode K is at a positive potential relative to the plasma. However, the surface of electrode K is negatively charged by the stored electrons, thereby negatively biasing the plasma. Due to the negative bias, cations flow into the surface of the electrode K. Thereby, a sheath layer is formed on the surface of the electrode K.

最終,電極K之表面以1個循環中之非常短之時間相對於電漿成為正電位。此時流入之電子與因負偏壓而穩定地流入之陽離子達到平衡時之電極K之電位差之DC(Direct Current,直流)成分為自給偏壓電壓Vdc。 Finally, the surface of the electrode K becomes a positive potential with respect to the plasma in a very short time in one cycle. At this time, the DC (Direct Current) component of the potential difference of the electrode K when the electrons flowing in and the positive ions stably flowing in due to the negative bias are in balance is the self-bias voltage Vdc.

為了控制表示電漿處理之特性之蝕刻速率或成膜速率等,必須掌握電漿之狀態。因此,於本實施形態中,為了掌握電漿處理裝置100內之電漿之狀態而測定自給偏壓電壓Vdc。 In order to control the etching rate or film formation rate, etc., which represent the characteristics of plasma processing, it is necessary to grasp the state of the plasma. Therefore, in this embodiment, in order to grasp the state of the plasma in the plasma processing apparatus 100, the self-bias voltage Vdc is measured.

[電漿處理裝置之構成] [Structure of plasma treatment device]

圖2所示之本實施形態之電漿處理裝置100具有裝置本體、繼電器箱6及測定裝置10。測定裝置10對配置於電漿處理裝置100之處理容器C內之靜電吸盤2a內之吸附電極21之電壓進行測定。繼電器箱6於直流電源7與測定裝置10之間切換吸附電極21之連接目標。若將吸附電極21與測定裝 置10連接,則測定裝置10測定銅圓板12與銅板13之間之電壓V2作為靜電吸盤2a之吸附電極21之電位差之DC成分,並基於測定結果算出自給偏壓電壓Vdc,上述電壓V2表示相當於夾持於銅圓板12與銅板13之間之丙烯酸系樹脂板14中儲存之電荷量之值。藉此,於本實施形態中,藉由對既有之電漿處理裝置100附加繼電器箱6及測定裝置10便可簡易且精度良好地進行自給偏壓電壓Vdc之測定。以下,對本實施形態之電漿處理裝置100及測定裝置10之構成之一例進行說明。 The plasma processing apparatus 100 of this embodiment shown in FIG. 2 has the apparatus main body, the relay box 6, and the measuring apparatus 10. The measurement device 10 measures the voltage of the adsorption electrode 21 in the electrostatic chuck 2 a arranged in the processing container C of the plasma processing device 100 . The relay box 6 switches the connection destination of the adsorption electrode 21 between the DC power supply 7 and the measurement device 10 . If the adsorption electrode 21 is connected to the measuring device 10, the measuring device 10 measures the voltage V2 between the copper circular plate 12 and the copper plate 13 as the DC component of the potential difference of the adsorption electrode 21 of the electrostatic chuck 2a, and calculates the self-bias based on the measurement result. The voltage Vdc, the above - mentioned voltage V2 represents a value corresponding to the amount of charge stored in the acrylic resin plate 14 sandwiched between the copper circular plate 12 and the copper plate 13. Therefore, in this embodiment, by adding the relay box 6 and the measuring device 10 to the existing plasma processing apparatus 100, the measurement of the self-bias voltage Vdc can be performed simply and accurately. Hereinafter, an example of the configuration of the plasma processing apparatus 100 and the measurement apparatus 10 of this embodiment will be described.

(電漿處理裝置之構成) (Structure of plasma treatment device)

本實施形態之電漿處理裝置100係電容耦合型平行平板電漿處理裝置,且具有大致圓筒形之處理容器C。對處理容器C之內面實施氧化鋁膜處理(陽極氧化處理)。處理容器C之內部成為藉由電漿進行蝕刻處理或成膜處理等電漿處理之處理室。於處理容器C內設置有載台2。 The plasma processing device 100 of this embodiment is a capacitively coupled parallel plate plasma processing device, and has a substantially cylindrical processing container C. The inner surface of the processing container C is subjected to aluminum oxide film treatment (anodizing treatment). The inside of the processing container C serves as a processing chamber for plasma processing such as etching processing or film forming processing using plasma. In the processing container C, the stage 2 is installed.

載台2中,於基台2b上設置有用以對晶圓W進行靜電吸附之靜電吸盤2a。基台2b例如由鋁(Al)或鈦(Ti)、碳化矽(SiC)等形成。載台2亦作為下部電極發揮功能。 In the stage 2, an electrostatic chuck 2a for electrostatically adsorbing the wafer W is provided on the base 2b. The base 2 b is formed of, for example, aluminum (Al), titanium (Ti), silicon carbide (SiC), or the like. The stage 2 also functions as a lower electrode.

靜電吸盤2a成為於介電層22內具有吸附電極21之構造。於靜電吸盤2a之表面形成有點狀之凸部22a。吸附電極21連接於繼電器箱6。若將繼電器箱6之開關6a切換至直流電源7,自直流電源7向吸附電極21供給直流電壓,則作為基板之一例之晶圓W由庫侖力吸附並保持於靜電吸盤2a。 The electrostatic chuck 2 a has a structure having an adsorption electrode 21 in a dielectric layer 22 . Dot-shaped protrusions 22a are formed on the surface of the electrostatic chuck 2a. The adsorption electrode 21 is connected to the relay box 6 . When the switch 6a of the relay box 6 is switched to the DC power supply 7, and a DC voltage is supplied from the DC power supply 7 to the chucking electrode 21, the wafer W as an example of a substrate is sucked and held by the electrostatic chuck 2a by Coulomb force.

於靜電吸盤2a之外周側之上部,以包圍晶圓W之外緣部之方式載置有圓環狀之聚焦環8。聚焦環8例如由矽形成,且以使電漿朝向晶圓W之表面收斂而提高電漿處理效率之方式發揮功能。 An annular focus ring 8 is placed on the upper portion of the outer peripheral side of the electrostatic chuck 2 a so as to surround the outer edge of the wafer W. The focus ring 8 is formed of silicon, for example, and functions to converge the plasma toward the surface of the wafer W to improve plasma processing efficiency.

對於載台2,自第1高頻電源3施加第1頻率之電漿產生用之第1高頻電力(HF),且自第2高頻電源4施加作為較第1頻率低之頻率之第2頻率的偏壓電壓產生用之第2高頻電力(LF)。第1高頻電源3經由匹配器3a電性連接於載台2。第2高頻電源4經由匹配器4a電性連接於載台2。第1高頻電源3例如對載台2施加40MHz之高頻電力HF。第2高頻電源4例如對載台2施加13.56MHz之高頻電力LF。再者,於本實施形態中,將第1高頻電力施加至載台2,但第1高頻電力亦可施加至氣體簇射頭1。 To the stage 2, the first high-frequency power (HF) for plasma generation of the first frequency is applied from the first high-frequency power supply 3, and the second high-frequency power (HF) which is a frequency lower than the first frequency is applied from the second high-frequency power supply 4. The second high-frequency power (LF) is used for generating the bias voltage of 2 frequencies. The first high-frequency power supply 3 is electrically connected to the stage 2 through a matching device 3a. The second high-frequency power supply 4 is electrically connected to the stage 2 through a matching device 4a. The first high-frequency power supply 3 applies, for example, high-frequency power HF of 40 MHz to the stage 2 . The second high-frequency power supply 4 applies, for example, high-frequency power LF of 13.56 MHz to the stage 2 . In addition, in the present embodiment, the first high-frequency power is applied to the stage 2 , but the first high-frequency power may be applied to the gas shower head 1 .

匹配器3a使負載阻抗與第1高頻電源3之內部(或輸出)阻抗匹配。匹配器4a使負載阻抗與第2高頻電源4之內部(或輸出)阻抗匹配。 The matching unit 3 a matches the load impedance with the internal (or output) impedance of the first high-frequency power supply 3 . The matching unit 4a matches the load impedance with the internal (or output) impedance of the second high-frequency power supply 4 .

氣體簇射頭1係以經由被覆其外緣部之屏蔽環封閉處理容器C之頂壁部開口之方式進行安裝。氣體簇射頭1接地。氣體簇射頭1可由矽形成。氣體簇射頭1作為與載台2(下部電極)對向之對向電極(上部電極)發揮功能。 The gas shower head 1 is installed so as to close the opening of the ceiling wall of the processing container C through a shield ring covering the outer edge thereof. The gas shower head 1 is grounded. The gas shower head 1 can be formed of silicon. The gas shower head 1 functions as a counter electrode (upper electrode) facing the stage 2 (lower electrode).

於氣體簇射頭1形成有導入氣體之氣體導入口1a。於氣體簇射頭1之內部設置有用以使氣體擴散之擴散室1b。自氣體供給部5輸出之氣體經由氣體導入口1a供給至擴散室1b,並於擴散室1b內擴散而自多個氣體供給孔1c導入至處理容器C內。 In the gas shower head 1, a gas introduction port 1a for introducing gas is formed. Inside the gas shower head 1, a diffusion chamber 1b for diffusing gas is provided. The gas output from the gas supply part 5 is supplied to the diffusion chamber 1b through the gas introduction port 1a, diffuses in the diffusion chamber 1b, and is introduced into the processing container C from the plurality of gas supply holes 1c.

於處理容器C之底面形成有排氣口,藉由連接於排氣口之排氣裝置9對處理容器C內進行排氣。藉此,可將處理容器C內維持於特定之真空度。於處理容器C之側壁設置有閘閥G。閘閥G於自處理容器C進行晶圓W之搬入及搬出時開閉。 An exhaust port is formed on the bottom surface of the processing container C, and the inside of the processing container C is exhausted by an exhaust device 9 connected to the exhaust port. Thereby, the inside of the processing container C can be maintained at a specific vacuum degree. A gate valve G is provided on the side wall of the processing container C. The gate valve G is opened and closed when carrying in and carrying out the wafer W from the processing container C.

若自氣體供給部5向處理容器C內供給處理氣體並自第1高頻電源3及第2高頻電源4對載台2施加第1及第2高頻電力,則產生電漿,對晶圓W實施特定之電漿處理。尤其是,若自第2高頻電源4對載台2施加第2高頻電力,則電漿中之離子被引向晶圓W側。 When the processing gas is supplied from the gas supply unit 5 into the processing container C and the first and second high-frequency powers are applied to the stage 2 from the first high-frequency power supply 3 and the second high-frequency power supply 4, plasma is generated, and the crystal Circle W is subjected to specific plasma treatment. In particular, when the second high-frequency power is applied to the stage 2 from the second high-frequency power supply 4, ions in the plasma are drawn toward the wafer W side.

電漿處理後,自直流電源7對吸附電極21供給正負與晶圓W之吸附時相反之直流電壓,從而去除晶圓W之電荷。藉此,晶圓W自靜電吸盤2a剝落,並自閘閥G搬出至處理容器C之外部。 After the plasma treatment, the DC power supply 7 supplies the adsorption electrode 21 with a DC voltage opposite to that of the wafer W during adsorption, thereby removing the charge of the wafer W. Thereby, the wafer W is peeled off from the electrostatic chuck 2a, and carried out from the gate valve G to the outside of the processing container C. As shown in FIG.

於電漿處理裝置100設置有控制裝置整體之動作之控制部200。控制部200具有CPU(Central Processing Unit,中央處理單元)205、ROM(Read Only Memory,唯讀記憶體)210及RAM(Random Access Memory,隨機存取記憶體)215。CPU205依據RAM215等記憶區域中儲存之製程配方執行蝕刻等所需處理。製程配方中設定有對程序條件之裝置之控制資訊即程序時間、壓力(氣體之排氣)、高頻電力或電壓、各種氣體流量、處理容器內溫度(上部電極溫度、處理容器之側壁溫度、晶圓W溫度、靜電吸盤溫度等)、冷媒之溫度等。 The control part 200 which controls the operation of the whole apparatus is provided in the plasma processing apparatus 100. The control unit 200 has a CPU (Central Processing Unit, central processing unit) 205 , a ROM (Read Only Memory, read only memory) 210 and a RAM (Random Access Memory, random access memory) 215 . The CPU 205 executes required processes such as etching according to the recipes stored in memory areas such as the RAM 215 . In the process recipe, the control information of the device for the process conditions is set, namely, the program time, pressure (gas exhaust), high-frequency power or voltage, various gas flow rates, and the temperature in the processing container (the temperature of the upper electrode, the temperature of the side wall of the processing container, Wafer W temperature, electrostatic chuck temperature, etc.), refrigerant temperature, etc.

又,控制部200於特定之時機切換繼電器箱6之開關6a,將吸附電極21連接至測定裝置10。測定裝置10所測定之電壓V2被發送至控制部200,藉此,控制部200基於電壓V2算出自給偏壓電壓Vdc。 In addition, the control unit 200 switches the switch 6 a of the relay box 6 at a specific timing to connect the adsorption electrode 21 to the measurement device 10 . The voltage V 2 measured by the measuring device 10 is sent to the control unit 200 , whereby the control unit 200 calculates the self-bias voltage Vdc based on the voltage V 2 .

再者,表示用以執行該等動作之程式或處理條件之製程配方亦可記憶於硬碟或半導體記憶體。又,製程配方亦可以收容於CD-ROM(compact disc read only memory,唯讀記憶光碟)、DVD(Digital Versatile Disc,數位多功能光碟)等可攜性之可由電腦讀取之記憶媒體的狀態設置於特定位置並被讀出。 Furthermore, a recipe representing a program or processing conditions for executing these operations can also be stored in a hard disk or a semiconductor memory. In addition, the process recipe can also be stored in CD-ROM (compact disc read only memory, CD-ROM), DVD (Digital Versatile Disc, digital versatile disc) and other portable storage media that can be read by the computer. at a specific location and read out.

(測定裝置之構成) (Configuration of measuring device)

其次,對測定裝置10之構成之一例進行說明。測定裝置10具有濾波器11、銅圓板12、銅板13、丙烯酸系樹脂板14、探針15、表面電位計16及信號記錄裝置17。探針15及表面電位計16構成電位測定系統18。 Next, an example of the configuration of the measurement device 10 will be described. The measurement device 10 has a filter 11 , a copper disc 12 , a copper plate 13 , an acrylic resin plate 14 , a probe 15 , a surface potentiometer 16 , and a signal recording device 17 . The probe 15 and the surface potentiometer 16 constitute a potential measurement system 18 .

又,於圖2中,為了便於說明,繼電器箱6係與測定裝置10分開地進行圖示,但測定裝置10具有繼電器箱6。繼電器箱6於直流電源7與測定裝置10之具有靜電電容之構件之間切換吸附電極21之連接。繼電器箱6於測定自給偏壓電壓Vdc之時機將繼電器箱6之開關6a連接至測定裝置10。繼電器箱6係將被施加高頻電力之吸附電極21之連接切換至具有靜電電容之構件的切換部之一例。具有將丙烯酸系樹脂板14夾於銅圓板12與銅板13之間之構成之構件係具有靜電電容之構件之一例。具有靜電電容之構件並 不限於銅圓板12、銅板13及丙烯酸系樹脂板14之構成,可由經絕緣之導體構成。 In addition, in FIG. 2 , for convenience of description, the relay box 6 is shown separately from the measurement device 10 , but the measurement device 10 has the relay box 6 . The relay box 6 switches the connection of the adsorption electrode 21 between the DC power supply 7 and the components having electrostatic capacitance of the measurement device 10 . The relay box 6 connects the switch 6 a of the relay box 6 to the measurement device 10 at the timing of measuring the self-sufficient bias voltage Vdc. The relay box 6 is an example of a switching unit that switches the connection of the adsorption electrode 21 to which high-frequency power is applied to a member having electrostatic capacitance. A member having a structure in which an acrylic resin plate 14 is sandwiched between the copper circular plate 12 and the copper plate 13 is an example of a member having an electrostatic capacitance. Components with electrostatic capacitance and It is not limited to the composition of the copper circular plate 12, the copper plate 13, and the acrylic resin plate 14, and may be composed of insulated conductors.

於電位測定系統18中,使用與銅圓板12之表面非接觸地設置之探針15藉由表面電位計16測定產生於銅圓板12與銅板13之間之丙烯酸系樹脂板14之電位。電位測定系統18係測定相當於具有靜電電容之構件中儲存之電荷量之值的測定部之一例。只要可測定銅圓板12與銅板13之間之電位差,則探針15可與銅圓板12接觸,亦可不接觸。 In the potential measuring system 18 , the potential of the acrylic resin plate 14 generated between the copper circular plate 12 and the copper plate 13 is measured by the surface potentiometer 16 using the probe 15 provided in non-contact with the surface of the copper circular plate 12 . The potential measuring system 18 is an example of a measuring unit that measures a value corresponding to the amount of charge stored in a member having electrostatic capacitance. As long as the potential difference between the copper circular plate 12 and the copper plate 13 can be measured, the probe 15 may be in contact with the copper circular plate 12 or not.

於繼電器箱6與具有靜電電容之構件之間設置有去除高頻電力之濾波器11,防止高頻電力傳播至測定裝置10側。若繼電器箱6之開關6a自與直流電源7連接之一側切換至與測定裝置10之具有靜電電容之構件連接之一側,則可進行產生於具有靜電電容之構件之電壓V2之測定、即浮動狀態之吸附電極21之電壓V2之測定。 A filter 11 for removing high-frequency power is provided between the relay box 6 and components having electrostatic capacitance to prevent the high-frequency power from propagating to the measuring device 10 side. If the switch 6a of the relay box 6 is switched from the side connected to the DC power supply 7 to the side connected to the component with the electrostatic capacity of the measuring device 10 , the measurement of the voltage V2 generated in the component with the electrostatic capacity can be performed, That is, the measurement of the voltage V2 of the adsorption electrode 21 in the floating state.

具體而言,銅板13接地,使用與銅圓板12之表面非接觸地設置之探針15藉由表面電位計16測定出之電位成為浮動狀態之吸附電極21之電壓V2。再者,銅圓板12之直徑例如可為100mm左右,但並不限於此。 Specifically, the copper plate 13 is grounded, and the potential measured by the surface potentiometer 16 using the probe 15 provided in non-contact with the surface of the copper circular plate 12 becomes the voltage V 2 of the adsorption electrode 21 in a floating state. Furthermore, the diameter of the copper circular plate 12 may be, for example, about 100 mm, but it is not limited thereto.

藉由表面電位計16測定出之電壓V2係保存於連接於表面電位計16之信號記錄裝置17。信號記錄裝置17可為PC(Personal Computer,個人電腦)或平板終端等具有記憶體之電子機器,亦可為設置於雲端上之雲電腦。信號記錄裝置17所記錄之測定電壓V2被發送至控制部200,由控制部 200使用於電漿處理裝置100之蝕刻速率或成膜速率等之控制。 The voltage V 2 measured by the surface potentiometer 16 is stored in the signal recording device 17 connected to the surface potentiometer 16 . The signal recording device 17 can be an electronic machine with a memory such as a PC (Personal Computer) or a tablet terminal, or can be a cloud computer installed on the cloud. The measurement voltage V2 recorded by the signal recording device 17 is sent to the control unit 200, and is used by the control unit 200 to control the etching rate or film formation rate of the plasma processing device 100, etc.

具有靜電電容之構件所儲存之電荷量會因水分而受到影響。因此,銅圓板12、銅板13、丙烯酸系樹脂板14及探針15較佳為設置於真空容器內。藉由將銅圓板12、銅板13、丙烯酸系樹脂板14及探針15置於真空環境下,可不受環境之干擾之影響而精度良好地測定電壓V2The amount of charge stored in components with electrostatic capacitance will be affected by moisture. Therefore, the copper circular plate 12, the copper plate 13, the acrylic resin plate 14 and the probe 15 are preferably arranged in a vacuum container. By placing the copper circular plate 12, the copper plate 13, the acrylic resin plate 14, and the probe 15 in a vacuum environment, the voltage V 2 can be accurately measured without being affected by environmental disturbances.

[測定時機] [measurement timing]

圖3表示於電漿處理裝置100中對晶圓W進行處理之處理循環之一例。當處理開始時,首先,將晶圓W自電漿處理裝置100之閘閥G搬入(步驟S1)。其次,自直流電源7對吸附電極21供給特定之直流電壓,使晶圓W靜電吸附於靜電吸盤2a(步驟S2)。其次,對載台2(吸附電極21)施加高頻電力,將自氣體供給部5供給之程序氣體電漿化,從而對晶圓W進行蝕刻處理等電漿處理(步驟S3)。蝕刻處理係利用電漿進行之基板處理之一例。高頻電力可為自第1高頻電源3輸出之高頻電力HF或自第2高頻電源4輸出之高頻電力LF之任一者,亦可為兩者。 FIG. 3 shows an example of a processing cycle for processing a wafer W in the plasma processing apparatus 100 . When the process starts, first, the wafer W is carried in from the gate valve G of the plasma processing apparatus 100 (step S1). Next, a specific DC voltage is supplied to the adsorption electrode 21 from the DC power supply 7 to electrostatically adsorb the wafer W to the electrostatic chuck 2a (step S2). Next, high-frequency power is applied to the stage 2 (adsorption electrode 21 ), and the process gas supplied from the gas supply unit 5 is plasma-formed to perform plasma processing such as etching on the wafer W (step S3 ). Etching treatment is an example of substrate treatment using plasma. The high-frequency power may be either the high-frequency power HF output from the first high-frequency power supply 3 or the high-frequency power LF output from the second high-frequency power supply 4 , or both.

其次,對吸附電極21供給與步驟S2中施加至吸附電極21之直流電壓正負相反且大小相同之直流電壓,使晶圓W自靜電吸盤2a脫離(步驟S4),且將晶圓W自電漿處理裝置100之閘閥G搬出(步驟S5)。其次,進行清洗處理(步驟S6)。 Next, supply the DC voltage opposite to the DC voltage applied to the adsorption electrode 21 in step S2 and the same magnitude to the adsorption electrode 21, so that the wafer W is detached from the electrostatic chuck 2a (step S4), and the wafer W is removed from the plasma. The gate valve G of the processing device 100 is carried out (step S5). Next, cleaning processing is performed (step S6).

於該時間點,一個晶圓W之處理結束,完成一個處理循環。再次開 始下一晶圓W之處理循環時,進行靜電吸盤2a之表面處理(處理劑等之清洗)(步驟S6),搬入下一晶圓W(步驟S1),重複步驟S1之後之處理。 At this point in time, the processing of one wafer W ends, and one processing cycle is completed. open again When the processing cycle of the next wafer W is started, the surface treatment of the electrostatic chuck 2a (cleaning of processing agent, etc.) is carried out (step S6), the next wafer W is loaded (step S1), and the processing after step S1 is repeated.

於以上循環之(1)清洗處理(S6)及(2)蝕刻處理(S3)中,繼電器箱6將吸附電極21之連接切換至測定裝置10。即,繼電器箱6於執行利用電漿之晶圓W之處理或清洗處理之過程中之時機,將吸附電極21之連接切換至測定裝置10,於電位測定系統18中測定浮動狀態之吸附電極21之電壓V2In the above cycle (1) cleaning treatment ( S6 ) and (2) etching treatment ( S3 ), the relay box 6 switches the connection of the adsorption electrode 21 to the measuring device 10 . That is, the relay box 6 switches the connection of the adsorption electrode 21 to the measurement device 10 at a timing during the processing or cleaning process of the wafer W using plasma, and the adsorption electrode 21 in a floating state is measured in the potential measurement system 18 The voltage V 2 .

[測定序列] [measurement sequence]

其次,一面參照圖4及圖5之測定序列圖,一面對(1)清洗處理及(2)蝕刻處理之測定序列之一例進行說明。圖4表示清洗處理之測定序列之一例。圖5表示蝕刻處理之測定序列之一例。清洗處理及蝕刻處理之測定序列之控制係由控制部200進行。 Next, an example of the measurement sequence of (1) cleaning treatment and (2) etching treatment will be described with reference to the measurement sequence diagrams of FIGS. 4 and 5 . Fig. 4 shows an example of a measurement sequence for cleaning treatment. FIG. 5 shows an example of a measurement sequence of etching processing. Control of the measurement sequence of the cleaning process and the etching process is performed by the control unit 200 .

(1)清洗處理之測定序列 (1) Determination sequence of cleaning treatment

圖4所示之清洗處理之測定序列係於無晶圓乾洗(WLDC)或無晶圓處理(WLT)中進行。開始本測定序列時,吸附電極21為斷開、即未連接於直流電源7而連接於接地(基準電位)之狀態。 The measured sequence of cleaning processes shown in FIG. 4 was performed in either wafer-less dry cleaning (WLDC) or wafer-less processing (WLT). At the start of this measurement sequence, the adsorption electrode 21 is in a state of being disconnected, that is, not connected to the DC power supply 7 but connected to the ground (reference potential).

於該狀態下於圖4之I開始測定序列,於II將繼電器箱6之開關6a切換至與測定裝置10連接之側。藉此,將吸附電極21之連接切換至測定裝置10,吸附電極21成為浮動狀態。 In this state, the measurement sequence is started at I in FIG. 4 , and the switch 6 a of the relay box 6 is switched to the side connected to the measurement device 10 at II. Thereby, the connection of the adsorption electrode 21 is switched to the measurement device 10, and the adsorption electrode 21 becomes a floating state.

其後,於III接通高頻電力,於電位測定系統18中使用探針15藉由表面電位計16測定銅圓板12之電壓V2,並記錄於信號記錄裝置17。其次,於IV斷開高頻電力,於V將繼電器箱6之開關6a切換至與直流電源7連接之側,結束測定序列。重複進行以上之測定序列。 Afterwards, turn on the high-frequency power in III, use the probe 15 in the potential measurement system 18 to measure the voltage V 2 of the copper disc 12 through the surface potentiometer 16, and record it in the signal recording device 17. Next, disconnect the high-frequency power at IV, switch the switch 6a of the relay box 6 to the side connected to the DC power supply 7 at V, and end the measurement sequence. The above measurement sequence was repeated.

(2)蝕刻處理之測定序列 (2) Determination sequence of etching treatment

圖5所示之蝕刻處理之測定序列係將晶圓W載置於靜電吸盤2a,於蝕刻等電漿處理中進行。開始本測定序列時,吸附電極21為接通、即連接於直流電源7之狀態。 The measurement sequence of the etching process shown in FIG. 5 is performed by placing the wafer W on the electrostatic chuck 2 a and performing plasma processing such as etching. At the start of this measurement sequence, the adsorption electrode 21 is turned on, that is, connected to the DC power supply 7 .

於該狀態下於圖5之I開始測定序列,於II將繼電器箱6之開關6a切換至與測定裝置10連接之側。藉此,將吸附電極21之連接切換至測定裝置10,吸附電極21成為浮動狀態。 In this state, the measurement sequence is started at I in FIG. 5 , and the switch 6 a of the relay box 6 is switched to the side connected to the measurement device 10 at II. Thereby, the connection of the adsorption electrode 21 is switched to the measurement device 10, and the adsorption electrode 21 becomes a floating state.

其後,於III接通高頻電力,於電位測定系統18中使用探針15藉由表面電位計16測定銅圓板12之電壓V2,並記錄於信號記錄裝置17。其次,於IV斷開高頻電力,並於V將繼電器箱6之開關6a切換至與直流電源7連接之一側,而測定序列結束。重複進行以上之測定序列時,若處於電漿處理中,則於VI對吸附電極21施加直流電壓HV,使晶圓W靜電吸附於載台2,其後執行VII~XI之測定序列,並於XII截止對吸附電極21施加直流電壓HV,從而停止晶圓W之吸附。VII~XI之測定序列與上述說明之II~V之測定序列相同。 Afterwards, turn on the high-frequency power at III, use the probe 15 in the potential measurement system 18 to measure the voltage V 2 of the copper disc 12 through the surface potentiometer 16, and record it in the signal recording device 17. Next, disconnect the high-frequency power at IV, and switch the switch 6a of the relay box 6 to the side connected to the DC power supply 7 at V, and the measurement sequence ends. When the above measurement sequence is repeated, if it is in the process of plasma treatment, apply a direct current voltage HV to the adsorption electrode 21 at VI, so that the wafer W is electrostatically adsorbed on the stage 2, and then perform the measurement sequence of VII~XI, and at XII cuts off the application of the DC voltage HV to the adsorption electrode 21, thereby stopping the adsorption of the wafer W. The determination sequences of VII~XI are the same as those of II~V described above.

如此,繼電器箱6於直流電源7與測定裝置10之間切換吸附電極21之連接。若將繼電器箱6之開關6a切換至測定裝置10,則吸附電極21成為浮動狀態,其後,施加高頻電力,氣體於電漿處理裝置100之電漿處理空間內電漿化。 In this way, the relay box 6 switches the connection of the adsorption electrode 21 between the DC power supply 7 and the measurement device 10 . When the switch 6a of the relay box 6 is switched to the measurement device 10, the adsorption electrode 21 will be in a floating state, and then high-frequency power is applied to plasmaize the gas in the plasma processing space of the plasma processing device 100.

施加高頻電力之後,表面電位計16使用探針15測定銅圓板12之電壓V2,控制部200基於測定出之電壓V2算出自給偏壓電壓Vdc。以下,對基於測定出之電壓V2算出自給偏壓Vdc之方法進行說明。 After the high-frequency power is applied, the surface potentiometer 16 uses the probe 15 to measure the voltage V 2 of the copper disc 12 , and the control unit 200 calculates the self-bias voltage Vdc based on the measured voltage V 2 . Hereinafter, a method of calculating the self - bias voltage Vdc based on the measured voltage V2 will be described.

[自給偏壓Vdc之算出方法] [Calculation method of self-bias voltage Vdc]

將本實施形態之自給偏壓Vdc之計算所使用之模型之一例示於圖6。如圖6之靜電吸盤2a之表面之一部分之放大圖所示,將形成於靜電吸盤2a之表面之點狀凸部22a之上表面之面積設為bdot,且將凸部22a之高度設為ddot。又,將吸附電極21至點之上表面之高度設為T,且將凸部22a之上表面之面積相對於靜電吸盤2a之表面之面積的面積比設為aelAn example of the model used for the calculation of the self-bias voltage Vdc of this embodiment is shown in FIG. 6 . As shown in the enlarged view of a part of the surface of the electrostatic chuck 2a in FIG. d dot . Also, let T be the height from the adsorption electrode 21 to the upper surface of the dot, and let a el be the area ratio of the upper surface area of the protrusion 22a to the surface area of the electrostatic chuck 2a.

將靜電吸盤2a之點狀凸部22a間之空間部分之靜電電容設為C11,將凸部22a間之空間下方與吸附電極21之間之靜電電容設為C12,且將凸部22a之上表面與吸附電極21之間之靜電電容設為C13Let the electrostatic capacitance of the space between the point-shaped convex parts 22a of the electrostatic chuck 2a be C11, set the electrostatic capacitance between the space below the convex parts 22a and the adsorption electrode 21 as C12, and set the capacitance of the convex part 22a The capacitance between the upper surface and the adsorption electrode 21 is set as C 13 .

靜電電容C11係由以下之(1)式算出。 The capacitance C11 is calculated by the following formula ( 1 ).

[數式1]

Figure 107128150-A0305-02-0018-1
[Formula 1]
Figure 107128150-A0305-02-0018-1

靜電電容C12係由以下之(2)式算出。 The capacitance C12 is calculated by the following formula (2).

Figure 107128150-A0305-02-0018-2
Figure 107128150-A0305-02-0018-2

靜電電容C13係由以下之(3)式算出。 The capacitance C13 is calculated by the following formula (3).

Figure 107128150-A0305-02-0018-3
Figure 107128150-A0305-02-0018-3

於(1)式~(3)式中,ε0表示真空之介電常數,εr表示比介電常數、即靜電吸盤2a之介電層22之介電常數ε與真空之介電常數ε0之比(=ε/ε0),且S表示吸附電極21之面積。 In formulas (1) to (3), ε 0 represents the dielectric constant of vacuum, and ε r represents the specific permittivity, that is, the dielectric constant ε of the dielectric layer 22 of the electrostatic chuck 2a and the dielectric constant ε of vacuum 0 (=ε/ε 0 ), and S represents the area of the adsorption electrode 21 .

由於靜電電容C11、C12、C13為根據設計參數求出之固定值,故靜電吸盤2a之靜電電容C1係藉由將靜電電容C11、C12、C13代入至以下之(4)式而以固定值之形式算出。 Since the electrostatic capacitances C 11 , C 12 , and C 13 are fixed values obtained according to the design parameters, the electrostatic capacitance C 1 of the electrostatic chuck 2a is obtained by substituting the electrostatic capacitances C 11 , C 12 , and C 13 into the following (4 ) formula and calculated in the form of a fixed value.

[數式4]

Figure 107128150-A0305-02-0019-4
[Formula 4]
Figure 107128150-A0305-02-0019-4

使用所算出之靜電吸盤2a之靜電電容C1、對作為圖6之模型之等效電路之圖7所示之靜電吸盤2a所施加之電壓V1及儲存於靜電吸盤2a之電荷q1,根據庫侖定律,以下之(5)式之關係成立。 Using the calculated electrostatic capacitance C 1 of the electrostatic chuck 2a, the voltage V 1 applied to the electrostatic chuck 2a shown in FIG. 7 as the equivalent circuit of the model in FIG. Coulomb's law, the relationship of the following formula (5) is established.

C1V1=q1‧‧‧(5) C 1 V 1 =q 1 ‧‧‧(5)

將銅圓板12與銅板13(接地)之間之靜電電容設為C2,將濾波器11之靜電電容設為C3,且將施加至銅圓板12與銅板13之間及濾波器11之電壓設為V2。又,若將分別儲存於銅圓板12與銅板13之間及濾波器11之電荷設為q2、q3,則根據庫侖定律,以下之(6)式之關係成立。 Set the electrostatic capacitance between the copper round plate 12 and the copper plate 13 (ground) as C 2 , set the electrostatic capacitance of the filter 11 as C 3 , and apply it between the copper round plate 12 and the copper plate 13 and the filter 11 The voltage is set to V 2 . Also, if the charges stored between the copper circular plate 12 and the copper plate 13 and the filter 11 are respectively q 2 and q 3 , then the relationship of the following formula (6) holds true according to Coulomb's law.

再者,靜電電容C2係由銅圓板12、銅板13與丙烯酸系樹脂板14之構成所決定之根據設計參數求出之固定值。同樣,靜電電容C3係由濾波器11之構成所決定之根據設計參數求出之固定值。再者,靜電電容C1、C2、C3不僅可為由設計參數決定之固定值,當然亦可由測定所得之實測值決定。 Furthermore, the electrostatic capacitance C2 is a fixed value determined by the configuration of the copper circular plate 12, the copper plate 13, and the acrylic resin plate 14 and obtained according to design parameters. Similarly, the capacitance C3 is a fixed value obtained from design parameters determined by the configuration of the filter 11 . Furthermore, the electrostatic capacitances C 1 , C 2 , and C 3 can not only be fixed values determined by design parameters, but also be determined by actual measured values obtained through measurement.

(C2+C3)V2=q2+q3‧‧‧(6) (C 2 +C 3 )V 2 =q 2 +q 3 ‧‧‧(6)

對於儲存於靜電吸盤2a之電荷q1、儲存於銅圓板12與銅板13之間之電荷q2、及儲存於濾波器11之電荷q3,以下之(7)式之關係成立。 For the charge q 1 stored in the electrostatic chuck 2a, the charge q 2 stored between the copper circular plate 12 and the copper plate 13, and the charge q 3 stored in the filter 11 , the relationship of the following formula (7) holds true.

q1-(q2+q3)=0‧‧‧(7) q 1 -(q 2 +q 3 )=0‧‧‧(7)

若對式(7)進行變形,則 q1=(q2+q3)‧‧‧(8) If the formula (7) is transformed, then q 1 =(q 2 +q 3 )‧‧‧(8)

若將(5)式及(6)式代入至(8)式中,則C1V1=(C2+C3)V2‧‧‧(9) If formula (5) and formula (6) are substituted into formula (8), then C 1 V 1 =(C 2 +C 3 )V 2 ‧‧‧(9)

若對(9)式進行變形,則V1=V2×(C2+C3)/C1‧‧‧(10) If formula (9) is transformed, then V 1 =V 2 ×(C 2 +C 3 )/C 1 ‧‧‧(10)

V2=V1×C1/(C2+C3)‧‧‧(11) V 2 =V 1 ×C 1 /(C 2 +C 3 )‧‧‧(11)

圖7之自給偏壓電壓Vdc係根據(10)式及(11)式藉由(12)式算出。 The self-sufficient bias voltage V dc in Fig. 7 is calculated by formula (12) according to formula (10) and formula (11).

Vdc=V1+V2‧‧‧(12) V dc =V 1 +V 2 ‧‧‧(12)

若將(10)式代入至(12)式,則Vdc=V2×(C2+C3)/C1+V2‧‧‧(13) If formula (10) is substituted into formula (12), then V dc =V 2 ×(C 2 +C 3 )/C 1 +V 2 ‧‧‧(13)

若將利用測定裝置10測定出之電壓V2、及固定值之靜電電容C1、C2、C3代入至(13)式,則算出自給偏壓電壓Vdc。靜電電容C1為由(4)式求出之C11、C12、C13之合成電容值。靜電電容C1、C2、C3係由設計參數決定之固定值。 By substituting the voltage V 2 measured by the measuring device 10 and the fixed capacitances C 1 , C 2 , and C 3 into the formula (13), the self-bias voltage V dc is calculated. Capacitance C 1 is the composite capacitance value of C 11 , C 12 , and C 13 obtained from formula (4). The electrostatic capacitances C 1 , C 2 , and C 3 are fixed values determined by design parameters.

如以上所說明般,根據本實施形態之測定方法,自給偏壓電壓Vdc可基於(13)式由表面電位計16之測定值即電壓V2、靜電吸盤2a之靜電電容C1、具有靜電電容之構件之靜電電容C2、及濾波器11之靜電電容C3簡易且精度良好地導出。 As explained above, according to the measurement method of this embodiment, the self-sufficient bias voltage V dc can be based on the formula (13) from the measured value of the surface potentiometer 16, that is, the voltage V 2 , the capacitance C 1 of the electrostatic chuck 2a, and the electrostatic capacity C 1 of the electrostatic chuck 2a. The electrostatic capacitance C 2 of the capacitance component and the electrostatic capacitance C 3 of the filter 11 are derived easily and accurately.

[測定結果] [The measurement results]

圖8表示本實施形態之測定裝置10所得之電壓V2之測定結果、及由電壓V2算出之自給偏壓電壓Vdc之一例。圖8之橫軸表示電漿處理裝置100之 處理容器C內之壓力。於圖8中,將使處理容器C內之壓力變化並藉由測定裝置10測定出之電壓V2表示為測定值。又,將基於(13)式由靜電電容C1、C2、C3及測定值之電壓V2換算而得之自給偏壓電壓Vdc表示為換算值。 FIG. 8 shows the measurement results of the voltage V2 obtained by the measurement device 10 of this embodiment, and an example of the self - bias voltage Vdc calculated from the voltage V2. The horizontal axis of FIG. 8 represents the pressure in the processing container C of the plasma processing apparatus 100 . In FIG. 8 , the voltage V2 measured by the measuring device 10 by changing the pressure in the processing container C is shown as a measured value. Also, the self-bias voltage V dc converted from the capacitances C 1 , C 2 , and C 3 and the measured voltage V 2 based on the formula (13) is expressed as a converted value.

藉此,無論處理容器C內之壓力如何變化,3點之測定值與換算值均一對一地對應。即,明白可藉由電位測定系統18使用具有靜電電容之構件測定浮動狀態之吸附電極21之電壓,並使用測定出之電壓V2精度良好地算出自給偏壓電壓Vdc。又,根據(13)式,具有靜電電容之構件之靜電電容C2及濾波器11之靜電電容C3越小,測定出之電壓V2(測定值)與自給偏壓電壓Vdc(換算值)越接近。 Thereby, no matter how the pressure in the processing container C changes, the measured values at the three points correspond to the converted values in a one-to-one correspondence. That is, it is understood that the potential measurement system 18 can measure the voltage of the adsorption electrode 21 in a floating state using a member having electrostatic capacitance, and calculate the self-bias voltage V dc with high accuracy using the measured voltage V 2 . Also, according to formula (13), the smaller the electrostatic capacitance C2 of the member with electrostatic capacitance and the electrostatic capacitance C3 of the filter 11 , the smaller the measured voltage V2 ( measured value) and the self-supply bias voltage Vdc (converted value) ) is closer.

如以上所說明般,根據本實施形態,無須變更電漿處理裝置之設計,僅藉由將切換部及測定裝置設置於電漿處理裝置便可簡易地進行電漿之自給偏壓電壓Vdc之測定。 As explained above, according to this embodiment, the self-bias voltage V dc of the plasma can be easily adjusted by simply installing the switching unit and the measuring device in the plasma processing apparatus without changing the design of the plasma processing apparatus. Determination.

[測定方法] [test methods]

晶圓W之偏移或破裂係由殘留於靜電吸盤2a之表面之電荷所引起。可藉由上述測定裝置10測定電壓V2並基於(13)式算出自給偏壓電壓Vdc,上述電壓V2表示導致該晶圓W之偏移或破裂之靜電吸盤2a表面之殘留吸附狀態、即電荷之儲存容易度或帶電狀態。 The deflection or cracking of the wafer W is caused by the charge remaining on the surface of the electrostatic chuck 2a. The self-bias voltage V dc can be calculated by measuring the voltage V 2 by the measuring device 10 based on the formula (13). The above voltage V 2 represents the residual adsorption state on the surface of the electrostatic chuck 2a that causes the wafer W to shift or break, That is, the ease of storage of charge or the state of charge.

該電壓V2之測定及自給偏壓電壓Vdc之算出係於搬入晶圓W前之靜電吸盤2a之狀態下進行。而且,根據算出之自給偏壓電壓Vdc,判斷該時間 點之靜電吸盤2a表面之殘留吸附狀態,控制靜電吸盤2a之清洗處理時間或控制是否執行打開處理容器C而進行之靜電吸盤2a之維護等。以此方式,藉由不載置晶圓W而基於算出之自給偏壓電壓Vdc預先判定靜電吸盤2a表面之殘留吸附狀態,可消除因搬出晶圓W時之推桿銷之上升而導致晶圓W破裂之風險。 The measurement of the voltage V 2 and the calculation of the self-bias voltage V dc are performed in the state of the electrostatic chuck 2 a before the wafer W is loaded. Moreover, according to the calculated self-sufficient bias voltage V dc , the residual adsorption state on the surface of the electrostatic chuck 2a at that time point is judged, and the cleaning treatment time of the electrostatic chuck 2a is controlled or whether the maintenance of the electrostatic chuck 2a performed by opening the processing container C is performed. Wait. In this way, by pre-determining the residual adsorption state on the surface of the electrostatic chuck 2a based on the calculated self-bias voltage V dc without placing the wafer W, it is possible to eliminate the possibility of causing the wafer W to rise due to the lift of the pusher pin when the wafer W is unloaded. Risk of circle W breaking.

即,先前係觀察於搬出晶圓W時使推桿銷上升時之銷轉矩之大小而確認殘留吸附,或者將探針或感測器***而測定靜電吸盤2a之表面電位。相對於此,根據上述測定方法,可防止晶圓W破裂之風險,並且根據自給偏壓電壓Vdc之值判斷靜電吸盤2a表面之殘留吸附狀態而判定是否執行維護。藉此,可基於判定結果,根據自給偏壓電壓Vdc獲得所執行之清洗之頻度或清洗處理時間、其他維護之執行時機等運用方法之最佳化及運用改善之方針。 That is, conventionally, the magnitude of the pin torque when the pusher pin is raised when the wafer W is unloaded was checked to confirm the residual suction, or a probe or a sensor was inserted to measure the surface potential of the electrostatic chuck 2a. On the other hand, according to the above measuring method, the risk of cracking of the wafer W can be prevented, and the residual adsorption state on the surface of the electrostatic chuck 2a can be judged based on the value of the self-bias voltage V dc to judge whether to perform maintenance. In this way, based on the judgment result, the guidelines for optimizing and improving the operation method such as the frequency of cleaning performed, the cleaning processing time, and the execution timing of other maintenance can be obtained according to the self-sufficient bias voltage V dc .

例如,參照圖9~圖11,對包含上述判定之一實施形態之測定方法之一例進行說明。圖9係表示一實施形態之自給偏壓電壓Vdc與沈積時間之相關資訊之一例之曲線圖。圖10係表示為了收集圖9之曲線圖中示出一例之相關資訊而預先進行之製程之一例之圖。圖11係表示一實施形態之測定方法之一例之流程圖。 For example, an example of a measurement method including an embodiment of the above determination will be described with reference to FIGS. 9 to 11 . FIG. 9 is a graph showing an example of information related to self-bias voltage V dc and deposition time in one embodiment. FIG. 10 is a diagram showing an example of a preliminarily performed process for collecting information related to an example shown in the graph of FIG. 9 . Fig. 11 is a flow chart showing an example of a measuring method in one embodiment.

圖9係基於測定出之銅圓板12與銅板13之間之電壓V2導出橫軸之沈積時間之累積值與縱軸之自給偏壓電壓Vdc之相關資訊。橫軸之沈積物之沈積時間之累積值與供給沈積性氣體而施加之高頻電力之施加時間之累積值 相等,且與沈積於靜電吸盤2a表面之沈積物之厚度成比例。橫軸之沈積時間之累積值係表示靜電吸盤2a之殘留吸附狀態之值之一例。但是,表示靜電吸盤2a之殘留吸附狀態之值並不限於沈積時間之累積值,亦可為靜電吸盤2a上之沈積物之厚度之測定值,還可為高頻電力之施加時間之累積值。 FIG. 9 is based on the measured voltage V 2 between the copper circular plate 12 and the copper plate 13 to derive the cumulative value of the deposition time on the horizontal axis and the relevant information on the self-bias voltage V dc on the vertical axis. The cumulative value of the deposition time of the deposit on the horizontal axis is equal to the cumulative value of the application time of the high-frequency power applied for supplying the deposition gas, and is proportional to the thickness of the deposit deposited on the surface of the electrostatic chuck 2a. The cumulative value of the deposition time on the horizontal axis is an example of the value representing the residual adsorption state of the electrostatic chuck 2a. However, the value indicating the residual adsorption state of the electrostatic chuck 2a is not limited to the cumulative value of the deposition time, but may also be a measured value of the thickness of the deposit on the electrostatic chuck 2a, or a cumulative value of the application time of high-frequency power.

又,縱軸之自給偏壓電壓Vdc係相當於測定出之上述電荷量之值之一例。相當於測定出之上述電荷量之值並不限於由電壓V2算出之自給偏壓電壓Vdc,亦可為測定出之電壓V2In addition, the self-bias voltage V dc on the vertical axis is an example of a value corresponding to the above-mentioned measured charge amount. The value corresponding to the measured charge amount is not limited to the self-bias voltage V dc calculated from the voltage V 2 , and may be the measured voltage V 2 .

於本實施形態中,藉由圖10之(a)~(i)之製程導出圖9之沈積時間之累積值與自我偏壓電壓Vdc之相關資訊。但是,表示相當於測定出之上述電荷量之值與表示靜電吸盤2a之殘留吸附狀態之值的相關關係之曲線並不限於直線。 In this embodiment, the accumulation value of the deposition time in FIG. 9 and the relevant information of the self-bias voltage V dc are derived from the process of (a) to (i) in FIG. 10 . However, the curve representing the correlation between the value corresponding to the measured charge amount and the value representing the residual adsorption state of the electrostatic chuck 2a is not limited to a straight line.

例如,於圖10(a)之製程中,測定裝置10將晶圓W載置於表面不存在沈積物之狀態(即沈積時間0秒)之靜電吸盤2a上,產生氧氣之電漿,並測定銅圓板12與銅板13之間之電壓V2。繼而,基於(13)式,由測定結果之電壓V2算出表示初始時之靜電吸盤2a表面之殘留吸附狀態之自給偏壓電壓Vdc。此時之資料係圖9之沈積時間為0(s)時之Vdc(=-70V),將該資料記憶於控制部200之RAM215等記憶部。 For example, in the process shown in Figure 10(a), the measurement device 10 places the wafer W on the electrostatic chuck 2a in a state where no deposits exist on the surface (that is, the deposition time is 0 seconds), generates a plasma of oxygen, and measures The voltage V 2 between the copper circular plate 12 and the copper plate 13 . Then, based on the formula (13), the self-bias voltage Vdc representing the residual adsorption state on the surface of the electrostatic chuck 2a at the initial stage was calculated from the voltage V2 of the measurement result. The data at this time is V dc (=-70V) when the deposition time in FIG.

其次,於圖10(b)之製程中,將晶圓W搬出後,藉由一面供給作為沈積性氣體之一例之CF系氣體、一面以特定時間(本實施形態中為30秒)施加 高頻電力而產生CF系氣體之電漿,使CF系之聚合物即沈積物R沈積於靜電吸盤2a之表面。 Next, in the process of FIG. 10(b), after the wafer W is unloaded, a CF-based gas as an example of a deposition gas is supplied and applied for a predetermined time (30 seconds in this embodiment) while the wafer W is unloaded. The high-frequency power generates the plasma of the CF-based gas, so that the CF-based polymer, that is, the deposit R, is deposited on the surface of the electrostatic chuck 2a.

其次,於圖10(c)之製程中,將晶圓W載置於靜電吸盤2a上,產生氧氣之電漿,並測定銅圓板12與銅板13之間之電壓V2。繼而,基於(13)式,由測定結果之電壓V2算出表示該時間點之靜電吸盤2a表面之殘留吸附狀態之自給偏壓電壓Vdc。此時之資料係圖9之沈積時間為30秒時之Vdc(=-68V),將該資料記憶於控制部200之RAM215等記憶部。 Next, in the manufacturing process of FIG. 10(c), the wafer W is placed on the electrostatic chuck 2a to generate oxygen plasma, and the voltage V 2 between the copper circular plate 12 and the copper plate 13 is measured. Then, based on the formula (13), the self-bias voltage Vdc representing the residual adsorption state on the surface of the electrostatic chuck 2a at that point in time was calculated from the voltage V2 of the measurement result. The data at this time is V dc (=-68V) when the deposition time in FIG.

其次,於圖10(d)之製程中,搬出晶圓W後,藉由一面供給CF系氣體一面以特定時間(本實施形態中為進而30秒)施加高頻電力而產生CF系氣體之電漿,使CF系之聚合物之沈積物R進而沈積於靜電吸盤2a之表面。 Next, in the process shown in FIG. 10( d ), after unloading the wafer W, the CF-based gas is generated by applying high-frequency power for a specific period of time (30 seconds in this embodiment) while supplying the CF-based gas. slurry, so that the deposit R of the CF-based polymer is further deposited on the surface of the electrostatic chuck 2a.

其次,於圖10(e)之製程中,將晶圓W載置於靜電吸盤2a上,產生氧氣之電漿,並測定銅圓板12與銅板13之間之電壓V2。繼而,基於(13)式,由測定結果之電壓V2算出表示該時間點之靜電吸盤2a表面之殘留吸附狀態之自給偏壓電壓Vdc(=-66V)。此時之資料係圖9之沈積時間為60秒(=30+30)時之Vdc,將該資料記憶於控制部200之RAM215等記憶部。 Next, in the manufacturing process of FIG. 10( e ), the wafer W is placed on the electrostatic chuck 2 a to generate oxygen plasma, and the voltage V 2 between the copper circular plate 12 and the copper plate 13 is measured. Then, based on the formula (13), the self-bias voltage Vdc (= -66V ) representing the residual adsorption state on the surface of the electrostatic chuck 2a at that point in time was calculated from the voltage V2 of the measurement result. The data at this time is the V dc when the deposition time in FIG. 9 is 60 seconds (=30+30), and this data is stored in the RAM215 of the control part 200 and other memory parts.

於圖10(f)及(g)、圖10(h)及(i)之製程中,將與圖10(c)及圖10(d)之製程相同之動作重複進行2次。即,於圖10(g)之測定中,算出圖9之沈積時間為90秒時之Vdc(=-64V),於圖10(h)之測定中,算出圖9之沈積時間為120秒時之Vdc(=-62V),將該等資料記憶於控制部200之RAM215等記憶 部。 In the process of Fig. 10(f) and (g), Fig. 10(h) and (i), the same operation as that of Fig. 10(c) and Fig. 10(d) is repeated twice. That is, in the measurement of Fig. 10(g), the V dc (=-64V) when the deposition time of Fig. 9 is calculated as 90 seconds, and in the measurement of Fig. 10(h), the deposition time of Fig. 9 is calculated as 120 seconds When V dc (=-62V), these data are memorized in memory parts such as RAM215 of the control part 200 .

藉由預先進行該測定,於記憶部中儲存於圖9中示出一例之表示沈積時間與自給偏壓電壓Vdc之相關關係的相關資訊。再者,圖9之表示沈積時間與自給偏壓電壓Vdc之相關關係之相關資訊為表示相當於預先測定之電荷量之值與表示靜電吸盤2a之殘留吸附狀態之值之相關關係的相關資訊之一例。 By performing this measurement in advance, relevant information showing the correlation between the deposition time and the self-bias voltage V dc shown as an example in FIG. 9 is stored in the memory unit. Furthermore, the relevant information showing the correlation between the deposition time and the self-bias voltage V dc in FIG. 9 is the relevant information showing the correlation between the value corresponding to the amount of charge measured in advance and the value showing the residual adsorption state of the electrostatic chuck 2a. One example.

以此方式儲存之圖9之相關資訊係供圖11所示之一實施形態之測定方法參照。圖11所示之測定方法係於搬入晶圓W前由控制部200執行,包含是否執行清洗處理等維護之判定製程。藉此,根據本實施形態之測定方法,由於在特定之情形時於搬入晶圓W前執行清洗處理等維護,故而可防止靜電吸盤2a表面之殘留吸附所導致之晶圓W之偏移或破裂。 The relevant information in FIG. 9 stored in this way is for reference by the measurement method of an embodiment shown in FIG. 11 . The measurement method shown in FIG. 11 is executed by the control unit 200 before loading the wafer W, and includes a process of determining whether to perform maintenance such as cleaning processing. Thus, according to the measurement method of this embodiment, since maintenance such as cleaning treatment is performed before loading the wafer W in a specific case, it is possible to prevent the wafer W from shifting or cracking due to residual adsorption on the surface of the electrostatic chuck 2a. .

當圖11之處理開始時,控制部200切換繼電器箱6之開關6a,將吸附電極21連接至測定裝置10。測定裝置10測定電壓V2(步驟S10)。將測定出之電壓V2發送至控制部200,藉此,控制部200基於電壓V2算出自給偏壓電壓Vdc(步驟S12)。 When the process in FIG. 11 starts, the control unit 200 switches the switch 6 a of the relay box 6 to connect the adsorption electrode 21 to the measurement device 10 . The measuring device 10 measures the voltage V 2 (step S10). The measured voltage V2 is sent to the control unit 200 , whereby the control unit 200 calculates the self-bias voltage Vdc based on the voltage V2 (step S12).

其次,控制部200判定算出之自給偏壓電壓Vdc之絕對值是否超過預先規定之閾值Th1(步驟S14)。控制部200若判定算出之Vdc之絕對值未超過預先規定之閾值Th1,則判定靜電吸盤2a之殘留吸附狀態並非於晶圓W之去靜電及搬出時產生晶圓之破裂之程度,從而結束本處理。 Next, the control unit 200 judges whether or not the calculated absolute value of the self-bias voltage V dc exceeds a predetermined threshold Th 1 (step S14). If the control unit 200 determines that the calculated absolute value of V dc does not exceed the predetermined threshold Th 1 , it determines that the residual adsorption state of the electrostatic chuck 2a is not to the extent that wafer cracks occur when the wafer W is destaticized and unloaded, thereby End this processing.

另一方面,若於步驟S14中,控制部200判定算出之自給偏壓電壓Vdc之絕對值超過預先規定之閾值Th1,則判定自給偏壓電壓Vdc之絕對值是否超過預先規定之閾值Th2(步驟S16)。 On the other hand, if in step S14, the control unit 200 determines whether the absolute value of the calculated self-bias voltage V dc exceeds the predetermined threshold Th 1 , then it is determined whether the absolute value of the self-bias voltage V dc exceeds the predetermined threshold Th 2 (step S16).

例如,如圖11所示,閾值Th1及閾值Th2具有閾值Th1之絕對值小於閾值Th2之絕對值之關係。例如,閾值Th1係表示如下情況之指標之一例,即,於自給偏壓電壓Vdc之絕對值大於閾值Th1時,推桿銷之銷轉矩提高,處於去靜電時有時會於晶圓W產生破裂之程度之殘留吸附狀態。 For example, as shown in FIG. 11 , the threshold Th1 and the threshold Th2 have a relationship in which the absolute value of the threshold Th1 is smaller than the absolute value of the threshold Th2. For example, the threshold Th1 is an example of an index indicating that when the absolute value of the self-supplied bias voltage V dc is greater than the threshold Th1, the pin torque of the push rod pin is increased, and the crystal may sometimes be damaged during destaticization. Circle W is the residual adsorption state to the extent that rupture occurs.

又,例如,閾值Th2係表示如下情況之指標之一例,即,於自給偏壓電壓Vdc之絕對值大於閾值Th2時,處於去靜電時於晶圓W產生破裂之可能性較高之殘留吸附狀態,必須打開處理容器C進行維護。 Also, for example, the threshold value Th2 is an example of an index indicating that when the absolute value of the self - bias voltage Vdc is greater than the threshold value Th2, there is a high possibility of cracks occurring on the wafer W during destaticization. The adsorption state remains, and the processing container C must be opened for maintenance.

由此,若於步驟S16中,控制部200判定自給偏壓電壓Vdc之絕對值超過預先規定之閾值Th2,則以打開處理容器C對靜電吸盤2a之表面進行醇擦拭等維護之方式進行控制,並結束本處理。 Therefore, if in step S16, the control unit 200 determines that the absolute value of the self-sufficient bias voltage V dc exceeds the predetermined threshold value Th 2 , it will open the processing container C and perform maintenance such as alcohol wiping on the surface of the electrostatic chuck 2a. Control, and end this process.

另一方面,若於步驟S16中,控制部200判定自給偏壓電壓Vdc之絕對值未超過預先規定之閾值Th2,則以使清洗處理時間較通常情況長而進行無晶圓乾洗之方式進行控制,並結束本處理。作為使清洗處理時間較通常情況長之一例,例如可列舉於通常之清洗處理時間為20秒之情形時延長至80秒左右之控制。 On the other hand, if in step S16, the control unit 200 determines that the absolute value of the self-sufficient bias voltage V dc does not exceed the predetermined threshold value Th 2 , then the method of making the cleaning process longer than usual and performing dry cleaning without wafers Control is performed, and this process ends. As an example of making the cleaning processing time longer than usual, for example, when the normal cleaning processing time is 20 seconds, control to extend it to about 80 seconds is exemplified.

藉此,參照記憶有自給偏壓電壓Vdc與沈積時間之相關資訊之記憶部,基於由測定出之電壓V2算出之自給偏壓電壓Vdc執行判定靜電吸盤2a表面之殘留吸附狀態之判定製程。繼而,於判定製程中,參照上述記憶部,測定出之算出之自給偏壓電壓Vdc之絕對值超過預先規定之閾值Th1或閾值Th2之至少一者時,控制部200判定執行靜電吸盤2a或處理容器C內之清洗處理或其他維護。再者,於判定製程中,亦可基於測定出之電壓V2判定靜電吸盤2a表面之殘留吸附狀態。 In this way, the determination of the residual adsorption state on the surface of the electrostatic chuck 2a is performed based on the self - bias voltage Vdc calculated from the measured voltage V2 by referring to the memory portion storing information about the self-bias voltage Vdc and the deposition time. Process. Then, in the determination process, when the absolute value of the measured and calculated self - bias voltage V dc exceeds at least one of the predetermined threshold value Th1 or threshold value Th2 with reference to the above-mentioned memory unit, the control unit 200 determines that the electrostatic chuck is to be executed. 2a or cleaning treatment or other maintenance in the treatment container C. Furthermore, in the determination process, the residual adsorption state on the surface of the electrostatic chuck 2a can also be determined based on the measured voltage V2.

藉此,可根據算出之自給偏壓電壓Vdc,獲得清洗之頻度或清洗時間、是否為執行靜電吸盤2a之維護等之時機等運用方法之最佳化及運用改善之方針。 In this way, based on the calculated self-bias voltage V dc , guidelines for optimizing and improving the operation method can be obtained, such as cleaning frequency or cleaning time, whether it is the timing for performing maintenance of the electrostatic chuck 2a, etc.

以上,藉由上述實施形態對測定裝置、測定方法及電漿處理裝置進行了說明,但本發明之測定裝置、測定方法及電漿處理裝置並不限定於上述實施形態,可於本發明之範圍內進行各種變化及改良。上述複數個實施形態中記載之事項可於不矛盾之範圍內進行組合。 Above, the measuring device, measuring method and plasma processing device have been described by the above-mentioned embodiment, but the measuring device, measuring method and plasma processing device of the present invention are not limited to the above-mentioned embodiment, and can be used within the scope of the present invention. Various changes and improvements have been made. The matters described in the above-mentioned plural embodiments can be combined within the range that does not contradict.

本發明之基板處理裝置可應用於電容耦合電漿(CCP,Capacitively Coupled Plasma)、感應耦合電漿(ICP,Inductively Coupled Plasma)、放射狀線槽孔天線、電子迴旋共振式電漿(ECR,Electron Cyclotron Resonance Plasma)、螺旋微波電漿(HWP,Helicon Wave Plasma)之任一類型。 The substrate processing device of the present invention can be applied to capacitively coupled plasma (CCP, Capacitively Coupled Plasma), inductively coupled plasma (ICP, Inductively Coupled Plasma), radial line slot antenna, electron cyclotron resonance plasma (ECR, Electron Any type of Cyclotron Resonance Plasma), Helicon Microwave Plasma (HWP, Helicon Wave Plasma).

於本說明書中,列舉晶圓W作為基板之一例而進行了說明。然而,基板並不限於此,亦可為用於LCD(Liquid Crystal Display,液晶顯示器)、FPD(Flat Panel Display,平板顯示器)之各種基板、或光罩、CD(Compact Disc,光碟)基板、印刷基板等。 In this specification, a wafer W has been described as an example of a substrate. However, the substrate is not limited thereto, and may also be various substrates for LCD (Liquid Crystal Display), FPD (Flat Panel Display, flat panel display), or a photomask, CD (Compact Disc, optical disc) substrate, printed Substrate etc.

1‧‧‧氣體簇射頭 1‧‧‧Gas shower head

1a‧‧‧氣體導入口 1a‧‧‧Gas inlet

1b‧‧‧擴散室 1b‧‧‧diffusion chamber

1c‧‧‧供給孔 1c‧‧‧Supply hole

2‧‧‧載台 2‧‧‧carrier

2a‧‧‧靜電吸盤 2a‧‧‧Electrostatic chuck

2b‧‧‧基台 2b‧‧‧abutment

3‧‧‧第1高頻電源 3‧‧‧The first high-frequency power supply

3a‧‧‧匹配器 3a‧‧‧Matcher

4‧‧‧第2高頻電源 4‧‧‧The second high frequency power supply

4a‧‧‧匹配器 4a‧‧‧Matcher

5‧‧‧氣體供給部 5‧‧‧Gas Supply Unit

6‧‧‧繼電器箱 6‧‧‧Relay box

6a‧‧‧開關 6a‧‧‧Switch

7‧‧‧直流電源 7‧‧‧DC power supply

8‧‧‧聚焦環 8‧‧‧Focus ring

9‧‧‧排氣裝置 9‧‧‧exhaust device

10‧‧‧測定裝置 10‧‧‧measurement device

11‧‧‧濾波器 11‧‧‧Filter

12‧‧‧銅圓板 12‧‧‧copper round plate

13‧‧‧銅板 13‧‧‧copper plate

14‧‧‧丙烯酸系樹脂板 14‧‧‧Acrylic resin board

15‧‧‧探針 15‧‧‧Probe

16‧‧‧表面電位計 16‧‧‧Surface potentiometer

17‧‧‧信號記錄裝置 17‧‧‧Signal recording device

18‧‧‧電位測定系統 18‧‧‧potential measurement system

21‧‧‧吸附電極 21‧‧‧Adsorption electrode

22‧‧‧介電層 22‧‧‧dielectric layer

22a‧‧‧凸部 22a‧‧‧convex part

100‧‧‧電漿處理裝置 100‧‧‧plasma treatment device

200‧‧‧控制部 200‧‧‧Control Department

205‧‧‧CPU 205‧‧‧CPU

210‧‧‧ROM 210‧‧‧ROM

215‧‧‧RAM 215‧‧‧RAM

C‧‧‧處理容器 C‧‧‧Disposal container

G‧‧‧閘閥 G‧‧‧gate valve

HF‧‧‧第1高頻電力 HF‧‧‧The first high-frequency power

LF‧‧‧第2高頻電力 LF‧‧‧The second high-frequency power

V2‧‧‧電壓 V 2 ‧‧‧voltage

W‧‧‧晶圓 W‧‧‧Wafer

Claims (14)

一種測定裝置,其包含:切換部,其係配置於電漿處理裝置內之靜電吸盤內之電極,且切換被施加直流電壓之上述電極之連接;具有靜電電容之構件,其連接於上述切換部;及測定部,其測定相當於上述具有靜電電容之構件所儲存之電荷量之值;且於藉由電漿執行基板處理之過程中,上述切換部將上述電極之上述連接切換至上述具有靜電電容之構件;於執行上述基板處理之過程中,上述測定部測定相當於上述具有靜電電容之構件所累積之上述電荷量之上述值。 A measurement device comprising: a switching unit, which is an electrode arranged in an electrostatic chuck in a plasma processing device, and switches the connection of the electrode to which a DC voltage is applied; a member having an electrostatic capacitance, which is connected to the switching unit and a measuring section that measures a value corresponding to the amount of charge stored in the above-mentioned member with electrostatic capacitance; Capacitive member; during the process of performing the above-mentioned substrate processing, the above-mentioned measurement unit measures the above-mentioned value corresponding to the above-mentioned electric charge accumulated on the above-mentioned member with electrostatic capacitance. 如請求項1之測定裝置,其中上述切換部係於上述直流電源與上述具有靜電電容之構件之間切換上述電極之連接。 The measurement device according to claim 1, wherein the switching unit switches the connection of the electrodes between the DC power supply and the member having electrostatic capacitance. 如請求項1或2之測定裝置,其於上述切換部與上述具有靜電電容之構件之間具有去除高頻電力之濾波器。 The measuring device according to claim 1 or 2, which has a filter for removing high-frequency power between the switching unit and the member having the electrostatic capacitance. 如請求項1或2之測定裝置,其中上述切換部於執行清洗處理之過程中將上述電極之連接切換至上述具有靜電電容之構件,且 上述測定部於執行上述清洗處理之過程中測定相當於上述具有靜電電容之構件所儲存之電荷量之值。 The measurement device according to claim 1 or 2, wherein the switching unit switches the connection of the electrodes to the member having electrostatic capacitance during the cleaning process, and The measurement unit measures a value corresponding to the amount of charge stored in the member having the electrostatic capacitance during the cleaning process. 如請求項1或2之測定裝置,其中上述切換部將上述電極之連接切換至上述具有靜電電容之構件之後,施加高頻電力。 The measuring device according to claim 1 or 2, wherein the switching unit applies high-frequency power after switching the connection of the electrodes to the member having an electrostatic capacitance. 如請求項1或2之測定裝置,其基於上述測定出之相當於電荷量之值,測定電漿之自給偏壓電壓。 The measuring device according to claim 1 or 2, which measures the self-bias voltage of the plasma based on the measured value corresponding to the electric charge. 如請求項1或2之測定裝置,其中上述測定部具有與上述具有靜電電容之構件之表面非接觸或接觸地設置之探針,且上述具有靜電電容之構件及上述探針係設置於真空容器內。 The measuring device according to claim 1 or 2, wherein the measuring unit has a probe provided in non-contact or contact with the surface of the member having electrostatic capacitance, and the member having electrostatic capacitance and the probe are arranged in a vacuum container Inside. 一種測定方法,其包括:切換製程,其切換配置於電漿處理裝置內之靜電吸盤內之電極之連接;施加製程,其對上述靜電吸盤施加高頻電力;及測定製程,其測定相當於藉由上述切換製程而連接至上述電極之具有靜電電容之構件所儲存之電荷量之值;且於藉由電漿執行基板處理之過程中,上述切換製程將上述電極之上述連接切換至上述具有靜電電容之構件; 於執行上述基板處理之過程中,上述測定製程測定相當於上述具有靜電電容之構件所累積之上述電荷量之上述值。 A measurement method, which includes: switching process, which switches the connection of electrodes arranged in the electrostatic chuck in the plasma processing device; applying process, which applies high-frequency power to the above-mentioned electrostatic chuck; and measuring the process, the measurement is equivalent to using The value of the amount of charge stored in the member with electrostatic capacitance connected to the above-mentioned electrode by the above-mentioned switching process; components of capacitors; In the course of performing the above-mentioned substrate processing, the above-mentioned measurement process measures the above-mentioned value corresponding to the above-mentioned charge amount accumulated by the above-mentioned member having the electrostatic capacitance. 如請求項8之測定方法,其中上述切換製程係於直流電源與上述具有靜電電容之構件之間切換上述電極之連接。 The measuring method according to claim 8, wherein the switching process is to switch the connection of the electrodes between the DC power supply and the above-mentioned member with electrostatic capacitance. 如請求項8或9之測定方法,其中於上述切換製程將上述電極之連接切換至上述具有靜電電容之構件之後,上述施加製程施加高頻電力。 The measuring method according to claim 8 or 9, wherein after the switching process switches the connection of the electrode to the member having the electrostatic capacitance, the applying process applies high-frequency power. 如請求項10之測定方法,其中上述切換製程於執行清洗處理之過程中將上述電極之連接切換至上述具有靜電電容之構件,且上述測定製程於執行上述清洗處理之過程中測定相當於上述具有靜電電容之構件所儲存之電荷量之值。 The measurement method according to claim 10, wherein the switching process switches the connection of the electrode to the above-mentioned member with electrostatic capacitance during the cleaning process, and the measurement process measures the equivalent of the above-mentioned capacitance during the cleaning process. The value of the amount of charge stored by a component of an electrostatic capacitance. 如請求項8或9之測定方法,其包含判定製程,該判定製程係參照記憶有預先測定出之上述相當於電荷量之值、與表示上述靜電吸盤之殘留吸附狀態之值的相關資訊之記憶部,基於測定出之上述相當於電荷量之值而判定基板之殘留吸附狀態。 The measurement method of Claim 8 or 9, which includes a determination process, the determination process refers to the memory with the previously measured value corresponding to the amount of charge and the relevant information indicating the value of the residual adsorption state of the electrostatic chuck The unit determines the residual adsorption state of the substrate based on the measured value corresponding to the amount of charge. 如請求項12之測定方法,其中 上述判定製程於參照上述記憶部而判定測定出之上述相當於電荷量之值之絕對值超過預先規定之閾值時,判定執行清洗處理或靜電吸盤之維護。 Such as the determination method of claim item 12, wherein The determination process determines to perform cleaning or maintenance of the electrostatic chuck when the absolute value of the measured value corresponding to the electric charge exceeds a predetermined threshold with reference to the memory unit. 一種電漿處理裝置,其包含:高頻電源,其施加高頻電力;切換部,其係配置於電漿處理裝置內之靜電吸盤內之電極,且切換被施加直流電壓之上述電極之連接;具有靜電電容之構件,其連接於上述切換部;及測定部,其測定相當於上述具有靜電電容之構件所儲存之電荷量之值;且於藉由電漿執行基板處理之過程中,上述切換部將上述電極之上述連接切換至上述具有靜電電容之構件;於執行上述基板處理之過程中,上述測定部測定相當於上述具有靜電電容之構件所累積之上述電荷量之上述值。 A plasma processing device, which includes: a high-frequency power supply, which applies high-frequency power; a switching unit, which is an electrode arranged in an electrostatic chuck in the plasma processing device, and switches the connection of the electrode to which a DC voltage is applied; A member with electrostatic capacitance connected to the switching unit; and a measurement unit that measures a value corresponding to the amount of charge stored in the member with electrostatic capacitance; and during the process of performing substrate processing by plasma, the switching unit The unit switches the connection of the electrode to the member with electrostatic capacitance; and the measurement unit measures the value corresponding to the amount of charge accumulated on the member with electrostatic capacitance during the process of performing the substrate processing.
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