TWI767450B - Surfactant composition for controlling or preventing insects and method using the same - Google Patents

Surfactant composition for controlling or preventing insects and method using the same Download PDF

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TWI767450B
TWI767450B TW109144213A TW109144213A TWI767450B TW I767450 B TWI767450 B TW I767450B TW 109144213 A TW109144213 A TW 109144213A TW 109144213 A TW109144213 A TW 109144213A TW I767450 B TWI767450 B TW I767450B
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surfactant composition
alkyl
insects
insect
sulfosuccinate
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TW109144213A
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TW202224560A (en
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江豐明
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江豐明
台界化學工業股份有限公司
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof

Abstract

The present invention relates to a surfactant composition for controlling or preventing insects and a method using the same, wherein the surfactant composition comprises an alkyl sulfosuccinate and a specific humectant. The surfactant composition is applied to insects in an appropriate dosage and manner to quickly reduce or eliminate the activity of insects, alleviate insect damage to agriculture, or crop and economic losses. In addition, the present invention can avoid the abuse of chemical insecticides, the use of unauthorized insecticides, the pollution of certain toxins, or the enhancement of insect resistance. Moreover, the surfactant composition of the present invention also does not contain volatile chemical substances, any fluorine, silicon or phosphorus compound, or any aromatic compound. Thus, the present invention can reduce environmental pollution and deterioration, or adverse effects on human and animal health.

Description

控制或防治昆蟲之界面活性劑組成物及其使用方法 Surfactant composition for controlling or controlling insects and method of using the same

本發明係關於一種控制或防治昆蟲之界面活性劑組成物及其使用方法。 The present invention relates to a surfactant composition for controlling or controlling insects and a method of using the same.

蟑螂是一種有著數億年演化歷史的雜食性昆蟲,其繁殖力強,且身上藏有細菌,因此被普遍認為是一種害蟲。蟻類會危害農作物、保護害蟲,舉例來說,紅火蟻會以大顎啃咬,並由腹部末端分泌蟻酸(甲酸)刺激被叮咬傷口,造成患部紅腫疼痛。天牛為一種鞘翅目昆蟲,其幼體於樹皮下取食,待齡期增大後會鑽入並蛀食木材,造成林木與木造建築的腐朽,因而對於人類居住環境造成危害。金龜子為金龜子科昆蟲的總稱,成蟲採食果樹嫩芽、新葉及花朵,造成栽種或復育之花卉、果樹及農作物的經濟損失。 Cockroaches are omnivorous insects with a history of hundreds of millions of years of evolution. They are highly fertile and harbor bacteria, so they are generally considered to be pests. Ants will harm crops and protect pests. For example, RIFA will bite with its big jaws and secrete formic acid (formic acid) from the end of the abdomen to stimulate the bite wound, causing redness, swelling and pain in the affected area. Longhorn beetle is a coleopteran insect. Its larvae feed under the bark. When the age increases, it will burrow into and eat wood, causing the decay of forest trees and wooden buildings, thus causing harm to the human living environment. Scarabs is a general term for insects of the family Scarabidae. Adults feed on the buds, new leaves and flowers of fruit trees, causing economic losses to planted or rehabilitated flowers, fruit trees and crops.

此外,蚊子則會在吸食過程中將疾病(諸如登革熱、瘧疾、黃熱病、茲卡病毒、絲蟲病、日本腦炎、西尼羅河病毒、基孔肯雅熱等)從一個宿主體內傳播到另一個宿主體內,因此每年約有7億人被蚊子傳染各種疾病,且每17人中就有1人死於被蚊子傳染的各種疾病,故蚊子被評為世界上最危險的動物之一。黃蜂於春季時從冬眠中甦醒,常叮咬經過其巢穴附近的人類,由於其毒 液會觸發被叮咬者的神經系統,造成患部腫脹、疼痛和搔癢等皮膚過敏反應。跳蚤為小型、無翅及善跳躍的寄生性昆蟲,寄生於人體常造成過敏性皮炎和叮咬性皮炎,使人類皮膚產生大小不同且奇癢難耐的丘疹。蜘蛛屬於節肢動物門,嚴格來說並不是昆蟲,惟多數蜘蛛都具有毒腺,從而可能影響人類的健康,且少數蜘蛛的毒腺更有致命的風險。 In addition, mosquitoes transmit diseases (such as dengue, malaria, yellow fever, Zika, filariasis, Japanese encephalitis, West Nile virus, chikungunya, etc.) from one host to another during feeding. In one host, about 700 million people are infected with various diseases by mosquitoes every year, and 1 in 17 people die from various diseases caused by mosquitoes, so mosquitoes are rated as one of the most dangerous animals in the world. The wasp emerges from hibernation in spring and often stings humans passing by near its nest, due to its venomous nature. The fluid triggers the nervous system of the bitten person, causing allergic skin reactions such as swelling, pain and itching in the affected area. Fleas are small, wingless parasitic insects that are good at jumping. They often cause allergic dermatitis and biting dermatitis when parasitic on the human body. Spiders belong to the phylum Arthropoda, and are not strictly insects, but most spiders have venom glands, which may affect human health, and the venom glands of a few spiders are more deadly.

其次,蝗蟲為一種危害相當大的昆蟲,蝗蟲成群快速飛行而往往造成大面積農作物之損害,影響農作物資源與糧食。《自然》期刊(Nature,volume 584,p.584-588,2020)的最新研究發表指出,觸發蝗蟲群聚的因子稱為4-乙烯基苯甲醚「4-vinylanisole」(4VA)的信息素(pheromone),僅需4~5隻蝗蟲群聚,就會產生並釋放4VA,其特別引起蝗蟲刺槐觸角上的鹼度感官反應,吸引周圍蝗蟲群聚。《科學進步》期刊(Science Advances,Jan.23,2019)的最新研究發表指出,經化學分析,可以在群居蝗蟲的所有組織和體液中檢測到苯乙腈(Phenylacetonitrile,PAN),但卻不存在於孤群蝗蟲中,因此群居蝗蟲藉由PAN減少鳥類的捕食,並在蝗蟲防禦中充當作嗅覺特有訊號。 Secondly, locusts are quite harmful insects. Locusts fly fast in swarms and often cause damage to large areas of crops, affecting crop resources and food. A new study published in the journal Nature (Nature, volume 584, p.584-588, 2020) points out that the factor that triggers locust swarms is a pheromone called 4-vinylanisole (4-vinylanisole) (4VA). (pheromone), it only takes 4 to 5 locusts to swarm to generate and release 4VA, which especially causes the alkalinity sensory response on the antennae of the locust locust, attracting the surrounding locusts to swarm. A new study published in the journal Science Advances (Jan.23, 2019) pointed out that phenylacetonitrile (PAN) can be detected in all tissues and body fluids of gregarious locusts by chemical analysis, but not in In solitary locusts, gregarious locusts therefore reduce bird predation by PAN and serve as an olfactory-specific signal in locust defense.

由此可知,昆蟲對於人類生活安全、糧食資源或是居住環境上可能造成諸多影響,但是長期以來,各地多使用傳統的化學農藥或殺蟲劑等有害物質施用於昆蟲,部分昆蟲已對這些物質產生抗性,而大大降低施用後的效果。此外,為了快速接觸昆蟲表面,傳統的化學農藥或殺蟲劑經常含有大量揮發性化學物質/有機溶劑,容易造成環境污染,更可能危害人體和家禽健康,所以難以且無法大量施用於群居或群飛之昆蟲。 It can be seen that insects may have many impacts on human life safety, food resources or living environment. However, for a long time, traditional chemical pesticides or insecticides and other harmful substances have been applied to insects in various places, and some insects have already affected these substances. resistance, while greatly reducing the effect after application. In addition, in order to quickly contact the surface of insects, traditional chemical pesticides or insecticides often contain a large amount of volatile chemicals/organic solvents, which are easy to cause environmental pollution and are more likely to endanger human and poultry health. Flying insects.

因此,為解決上述問題,亟需發展一種控制或防治昆蟲之界面活性劑組成物及其使用方法,以消除或緩和上述問題。 Therefore, in order to solve the above-mentioned problems, there is an urgent need to develop a surfactant composition for controlling or controlling insects and a method of using the same, so as to eliminate or alleviate the above-mentioned problems.

有鑑於此,本發明提出一種控制或防治昆蟲之界面活性劑組成物,其可不含有毒物質、不含揮發性化學物質/有機溶劑、不含任何基於氟、矽或磷類化合物或不含任何芳香族化合物,或對於環境友善及人畜安全,並針對有害昆蟲具有廣譜性。 In view of this, the present invention proposes a surfactant composition for controlling or preventing insects, which may not contain toxic substances, volatile chemical substances/organic solvents, any fluorine, silicon or phosphorus-based compounds or any Aromatic compounds, or are environmentally friendly and safe for humans and animals, and have a broad spectrum against harmful insects.

為達成上述目的,根據本發明的一種觀點,提出一種控制或防治昆蟲之界面活性劑組成物,包括0.01至5重量百分比之烷基磺基琥珀酸酯、0.01至1重量百分比之保濕劑、以及餘量為水。在此,所使用之水無特別限制,較佳為純淨水、蒸餾水、去離子水或超純水。 In order to achieve the above object, according to an aspect of the present invention, a surfactant composition for controlling or preventing insects is provided, comprising 0.01 to 5 weight percent of alkyl sulfosuccinate, 0.01 to 1 weight percent of a moisturizing agent, and The remainder is water. Here, the water used is not particularly limited, preferably purified water, distilled water, deionized water or ultrapure water.

於本發明之界面活性劑組成物中,烷基磺基琥珀酸酯可為單烷基磺基琥珀酸酯、二烷基磺基琥珀酸酯、多烷基磺基琥珀酸酯或其組合,其中單烷基磺基琥珀酸酯可具有1至18個碳鏈烷基,較佳具有4至18個碳鏈烷基,更佳具有4至12個碳鏈烷基,最佳具有6至8個碳鏈烷基;二烷基磺基琥珀酸酯可具有兩個相同或不同的1至18個碳鏈烷基,較佳為4至18個碳鏈烷基,更佳為4至12個碳鏈烷基,最佳為6至8個碳鏈烷基;以及多烷基磺基琥珀酸酯可具有多個相同或不同的1至18個碳鏈烷基,較佳為4至18個碳鏈烷基,更佳為4至12個碳鏈烷基,最佳為6至8個碳鏈烷基,但本發明不限於此。 In the surfactant composition of the present invention, the alkyl sulfosuccinate can be monoalkyl sulfosuccinate, dialkyl sulfosuccinate, polyalkyl sulfosuccinate or a combination thereof, Among them, the monoalkyl sulfosuccinate may have 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups carbon chain alkyl groups; dialkyl sulfosuccinates may have two identical or different carbon chain alkyl groups of 1 to 18, preferably 4 to 18 carbon alkyl groups, more preferably 4 to 12 carbon chain alkyl groups carbon chain alkyl groups, preferably 6 to 8 carbon chain alkyl groups; and polyalkyl sulfosuccinates may have a plurality of the same or different 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups The carbon chain alkyl group is more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups, but the present invention is not limited thereto.

於本發明之界面活性劑組成物中,烷基磺基琥珀酸酯可為具有下列化學式之烷基磺基琥珀酸酯: In the surfactant composition of the present invention, the alkyl sulfosuccinate can be an alkyl sulfosuccinate having the following chemical formula:

Figure 109144213-A0101-12-0003-2
Figure 109144213-A0101-12-0003-2
Figure 109144213-A0101-12-0004-3
Figure 109144213-A0101-12-0004-3

其中,R1及R2可分別為一烷基,但本發明不限於此。此外,R1及R2可分別為1至18個碳鏈烷基,較佳為4至18個碳鏈烷基,更佳為4至12個碳鏈烷基,最佳為6至8個碳鏈烷基,但本發明不限於此。此外,R1及R2可為相同或不同的烷基,且較佳為相同的烷基。 Wherein, R 1 and R 2 may each be an alkyl group, but the present invention is not limited thereto. In addition, R 1 and R 2 can each be 1 to 18 carbon chain alkyl groups, preferably 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups carbon chain alkyl group, but the present invention is not limited thereto. In addition, R 1 and R 2 may be the same or different alkyl groups, and preferably the same alkyl groups.

於本發明之界面活性劑組成物中,保濕劑可為烷基一元醇、烷基二元醇、烷基多元醇或其組合,其中烷基可為1至18個碳鏈烷基,較佳為4至18個碳鏈烷基,更佳為4至12個碳鏈烷基,最佳為6至8個碳鏈烷基,但本發明不限於此。 In the surfactant composition of the present invention, the humectant can be an alkyl monohydric alcohol, an alkyl dihydric alcohol, an alkyl polyhydric alcohol or a combination thereof, wherein the alkyl group can be 1 to 18 carbon chain alkyl groups, preferably is 4 to 18 carbon chain alkyl groups, more preferably 4 to 12 carbon chain alkyl groups, and most preferably 6 to 8 carbon chain alkyl groups, but the present invention is not limited thereto.

於本發明之界面活性劑組成物中,界面活性劑組成物可不含任何揮發性化合物之有機溶劑、不含任何氟、矽或磷類化合物、不含任何芳香族化合物或可不含傳統農藥或殺蟲劑,但本發明不限於此。 In the surfactant composition of the present invention, the surfactant composition may not contain any organic solvent of volatile compounds, not contain any fluorine, silicon or phosphorus compounds, not contain any aromatic compounds, or may not contain traditional pesticides or sterilizers. insecticide, but the present invention is not limited to this.

根據本發明的另一種觀點,提出一種控制或防治昆蟲界面活性劑組成物之使用方法,包括以下步驟:(a)配製如前所述的界面活性劑組成物;以及(b)將(a)所得之界面活性劑組成物施用於昆蟲。藉由本發明之界面活性劑組成物的優秀溶解能力,可清除及阻斷昆蟲的揮發物性化合物信息素之傳播,以減輕或防止昆蟲群居或群飛。 According to another aspect of the present invention, a method for controlling or controlling an insect surfactant composition is provided, comprising the steps of: (a) formulating the aforementioned surfactant composition; and (b) mixing (a) The resulting surfactant composition is applied to insects. The excellent dissolving ability of the surfactant composition of the present invention can remove and block the spread of the volatile compound pheromone of insects, so as to reduce or prevent the swarming or flying of insects.

此外,由於多數昆蟲以體內之氣管系統進行呼吸,氣管系統遍佈全身,由氣門(spiracle)與大氣相通,空氣依靠擴散作用經氣門進入氣管(trachea)、逐級分支的支氣管和微氣管(tracheole)中,最後進入組織細胞。由此可知,若能影響昆蟲身體上氣門之開閉,就可以影響昆蟲之呼吸系統。如果能夠影響昆蟲 呼吸系統,就可以控制昆蟲之飛行,甚至是影響其生存。因此,亦可透過向昆蟲施用本發明的界面活性劑組成物,而濕潤昆蟲,造成昆蟲呼吸困難或重量增加,以降低其活動力或飛行能力。 In addition, because most insects breathe through the trachea system in the body, the trachea system is all over the body, and is communicated with the atmosphere by the spiracle. , and finally enter the tissue cells. It can be seen from this that if the opening and closing of the air valve on the insect body can be affected, the respiratory system of the insect can be affected. If it can affect insects The respiratory system can control the flight of insects and even affect their survival. Therefore, by applying the surfactant composition of the present invention to the insects, wetting the insects, causing difficulty in breathing or increasing the weight of the insects, reduces their mobility or flight ability.

於本發明之方法中,昆蟲可為具有氣孔、氣管、氣囊或其組合而成呼吸系統的任何昆蟲,例如可為蝗蟲、飛蟻、天牛、蜘蛛、黃蜂、飛蟲、蒼蠅、蟑螂、或鼠婦(潮蟲)等,但本發明不限於此。 In the method of the present invention, the insect can be any insect having a respiratory system with stomata, trachea, air sacs, or a combination thereof, such as locusts, flying ants, beetles, spiders, wasps, flying insects, flies, cockroaches, or Rat woman (fluid worm), etc., but the present invention is not limited to this.

於本發明之方法中,昆蟲可為靜態或動態之任何爬行或飛行昆蟲,但本發明不限於此。 In the method of the present invention, the insect can be any crawling or flying insect, static or dynamic, but the present invention is not limited thereto.

於本發明之方法中,昆蟲可為散居或群居之任何昆蟲,但本發明不限於此。 In the method of the present invention, the insects may be any insects that are scattered or gregarious, but the present invention is not limited thereto.

於本發明之方法中,其中此方法可施用於阻止或遏制前述昆蟲之群居或群飛,但本發明不限於此。 In the method of the present invention, wherein the method can be applied to prevent or suppress the colony or swarm flying of the aforementioned insects, but the present invention is not limited thereto.

於本發明之方法中,其中此方法可用以控制或防治昆蟲之蟲卵、幼蟲或成蟲,但本發明不限於此。 In the method of the present invention, wherein the method can be used to control or control the eggs, larvae or adults of insects, but the present invention is not limited thereto.

於本發明之方法中,可使用噴霧、泡沫、氣溶膠、塗抹、覆蓋、灌注或其組合的形式將前述的界面活性劑組成物直接施用於前述昆蟲,但本發明不限於此。 In the method of the present invention, the aforementioned surfactant composition can be directly applied to the aforementioned insects in the form of spraying, foaming, aerosol, smearing, covering, pouring or a combination thereof, but the present invention is not limited thereto.

下文將配合圖式並詳細說明,使本發明的其他目的、優點、及新穎特徵更明顯。 The accompanying drawings and detailed descriptions will hereinafter make other objects, advantages, and novel features of the present invention more apparent.

1:界面活性劑組成物 1: Surfactant composition

2:裝置 2: Device

3:昆蟲 3: Insects

S1、S2、S3:步驟 S1, S2, S3: Steps

圖1顯示本發明之界面活性劑組成物之配製流程圖。 FIG. 1 shows a flow chart of the preparation of the surfactant composition of the present invention.

圖2顯示本發明之界面活性劑組成物之使用方法示意圖。 FIG. 2 shows a schematic diagram of the use method of the surfactant composition of the present invention.

以下提供本發明的不同實施例。這些實施例是用於說明本發明的技術內容,而非用於限制本發明的權利範圍。一實施例的一特徵可透過合適的修飾、置換、組合、分離以應用於其他實施例。 Various embodiments of the present invention are provided below. These embodiments are used to illustrate the technical content of the present invention, but not to limit the scope of the right of the present invention. A feature of one embodiment can be applied to other embodiments by suitable modification, substitution, combination, isolation.

在本文中,除了特別指明者之外,所謂的特徵甲「或」(or)或「及/或」(and/or)特徵乙,是指甲單獨存在、乙單獨存在、或甲與乙同時存在;所謂的特徵甲「及」(and)或「與」(and)或「且」(and)特徵乙,是指甲與乙同時存在;所謂的「包括」、「包含」、「具有」、「含有」,是指包括但不限於此。 In this article, unless otherwise specified, the so-called feature A "or" (or) or "and/or" (and/or) feature B, refers to the existence of nail alone, the existence of B alone, or the coexistence of A and B ; The so-called feature A "and" (and) or "and" (and) or "and" (and) feature B, is that nail and B exist at the same time; the so-called "include", "include", "have", " "Contain" means including but not limited to.

圖1顯示本發明之界面活性劑組成物之配製流程圖。 FIG. 1 shows a flow chart of the preparation of the surfactant composition of the present invention.

如圖1所示,本發明之界面活性劑組成物的配製流程包括以下步驟:(步驟S1)混合烷基磺基琥珀酸酯與保濕劑,形成混合物;(步驟S2)於前述混合物中加入純淨水;以及(步驟S3)形成界面活性劑組成物。 As shown in Figure 1, the preparation process of the surfactant composition of the present invention includes the following steps: (step S1) mixing alkyl sulfosuccinate and humectant to form a mixture; (step S2) adding pure water to the aforementioned mixture water; and (step S3) forming a surfactant composition.

圖2顯示本發明之界面活性劑組成物之使用方法示意圖。 FIG. 2 shows a schematic diagram of the use method of the surfactant composition of the present invention.

如圖2所示,將上述配製所得的界面活性劑組成物1裝填於適當裝置2內,在此,裝置2為噴霧瓶,透過裝置2以噴灑的方式將界面活性劑組成物1施用於昆蟲3,並實施於不同種的昆蟲3以測試本發明之界面活性劑組成物1對於控制或防治昆蟲3之效用,下文中的實施例1至實施例10均使用與上文相似的方 式進行測試,差異僅在於界面活性劑組成物1之各成分比例、噴灑秒數、單次噴灑量以及實施於不同種的昆蟲3。 As shown in FIG. 2, the surfactant composition 1 prepared above is loaded into a suitable device 2, where the device 2 is a spray bottle, and the surfactant composition 1 is applied to the insects through the device 2 by spraying 3, and implemented in different species of insects 3 to test the effect of the surfactant composition 1 of the present invention for controlling or preventing insects 3, the following examples 1 to 10 all use methods similar to those above. The difference is only in the ratio of each component of the surfactant composition 1, the number of spraying seconds, the amount of single spraying, and the implementation of different species of insects 3.

本發明所提供的界面活性劑組成物的具體實施例如下: The specific embodiment of the surfactant composition provided by the present invention is as follows:

實施例1 (小蝗蟲,尺寸約30mm) Embodiment 1 (small locust, size about 30mm)

將下表1的實施例1的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之小蝗蟲。 The surfactant composition 1 of Example 1 in Table 1 below is uniformly stirred into an aqueous solution, and is applied to static small locusts by means of spraying or spraying with a suitable device 2 (as shown in Figure 2).

表1 實施例1之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0007-4
Table 1 Composition, implementation and results of the surfactant composition of Example 1
Figure 109144213-A0101-12-0007-4

實施例2 (蝗蟲,尺寸約45mm) Example 2 (locusts, about 45mm in size)

將下表2的實施例2的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於動態之蝗蟲。 The surfactant composition 1 of Example 2 in Table 2 below is uniformly stirred into an aqueous solution, and is applied to the dynamic locusts by means of spraying or spraying using a suitable device 2 (as shown in Figure 2).

表2 實施例2之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0007-5
Table 2 Composition, embodiment and results of the surfactant composition of Example 2
Figure 109144213-A0101-12-0007-5

實施例3 (飛蟻,尺寸約10mm) Example 3 (flying ants, about 10mm in size)

將下表3的實施例3的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之飛蟻。 The surfactant composition 1 of Example 3 in Table 3 below is uniformly stirred into an aqueous solution, and is applied to the static flying ants by spraying or spraying with a suitable device 2 (as shown in FIG. 2 ).

表3 實施例3之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0008-6
Table 3 Composition, implementation and results of the surfactant composition of Example 3
Figure 109144213-A0101-12-0008-6

實施例4 (天牛,尺寸約13mm) Example 4 (Berlin, about 13mm in size)

將下表4的實施例4的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之天牛。 The surfactant composition 1 of Example 4 in Table 4 below is uniformly stirred into an aqueous solution, and is applied to the static beetle by spraying or spraying with a suitable device 2 (as shown in FIG. 2 ).

表4 實施例4之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0008-7
Table 4 Composition, implementation and results of the surfactant composition of Example 4
Figure 109144213-A0101-12-0008-7

實施例5 (蜘蛛,尺寸約20mm) Example 5 (spider, about 20mm in size)

將下表5的實施例5的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於動態之蜘蛛。 The surfactant composition 1 of Example 5 in Table 5 below was uniformly stirred into an aqueous solution, and was applied to the dynamic spider by means of spraying or spraying with a suitable device 2 (as shown in FIG. 2 ).

表5 實施例5之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0008-8
Table 5 Composition, implementation and results of the surfactant composition of Example 5
Figure 109144213-A0101-12-0008-8

Figure 109144213-A0101-12-0009-9
Figure 109144213-A0101-12-0009-9

實施例6 (黃蜂,尺寸約30mm) Example 6 (Wasp, about 30mm in size)

將下表6的實施例6的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之黃蜂。 The surfactant composition 1 of Example 6 in Table 6 below was uniformly stirred into an aqueous solution, and was applied to the static wasps by spraying or spraying with a suitable device 2 (as shown in FIG. 2 ).

表6 實施例6之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0009-10
Table 6 Composition, implementation and results of the surfactant composition of Example 6
Figure 109144213-A0101-12-0009-10

實施例7 (小飛蟲,尺寸約3mm) Example 7 (small flying insects, about 3mm in size)

將下表7的實施例7的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之小飛蟲。 The surfactant composition 1 of Example 7 in Table 7 below is uniformly stirred into an aqueous solution, and is applied to static small flying insects by means of spraying or spraying using a suitable device 2 (as shown in Figure 2).

表7 實施例7之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0009-11
Table 7 Composition, implementation and results of the surfactant composition of Example 7
Figure 109144213-A0101-12-0009-11

實施例8 (蒼蠅,尺寸約12mm) Example 8 (fly, about 12mm in size)

將下表8的實施例8的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之蒼蠅。 The surfactant composition 1 of Example 8 in Table 8 below was uniformly stirred into an aqueous solution, and was applied to static flies by spraying or spraying with a suitable device 2 (as shown in FIG. 2 ).

表8 實施例8之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0010-12
Table 8 Composition, implementation and results of the surfactant composition of Example 8
Figure 109144213-A0101-12-0010-12

實施例9 (蟑螂,尺寸約15mm) Example 9 (cockroaches, about 15mm in size)

將下表9的實施例9的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於靜態之蟑螂。由於蟑螂體型較大,因此噴灑量必須足夠。 The surfactant composition 1 of Example 9 in Table 9 below was uniformly stirred into an aqueous solution, and was applied to static cockroaches by spraying or spraying with a suitable device 2 (as shown in FIG. 2 ). Due to the large size of cockroaches, the amount of spraying must be sufficient.

表9 實施例9之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0010-13
Table 9 Composition, implementation and results of the surfactant composition of Example 9
Figure 109144213-A0101-12-0010-13

實施例10 (鼠婦,尺寸約40mm) Example 10 (mouse, size about 40mm)

將下表10的實施例10的界面活性劑組成物1均勻攪拌成水溶液,並利用適當裝置2(如圖2所示)以噴霧或噴灑的方式施用於動態之鼠婦(潮蟲)。 雖鼠婦並不屬於昆蟲,但是亦可以使用本發明之界面活性劑組成物進行控制或防治。 The surfactant composition 1 of Example 10 in the following table 10 was uniformly stirred into an aqueous solution, and was applied to the dynamic rat woman (fluid worm) by spraying or spraying with a suitable device 2 (as shown in FIG. 2 ). Although ratwolves are not insects, they can also be controlled or prevented by using the surfactant composition of the present invention.

表10 實施例10之界面活性劑組成物的組成、實施方式與結果

Figure 109144213-A0101-12-0011-14
Table 10 Composition, implementation and results of the surfactant composition of Example 10
Figure 109144213-A0101-12-0011-14

由上述實施例1至實施例10的結果顯示,本發明的界面活性劑組成物具有協同作用可以使各類昆蟲快速進入濕潤狀態,且保持深度濕潤狀態,進而達到立即有效控制或防治昆蟲之功效。 From the results of the above-mentioned examples 1 to 10, it is shown that the surfactant composition of the present invention has a synergistic effect, which can make all kinds of insects quickly enter a wet state, and maintain a deep wet state, thereby achieving the effect of immediate and effective control or prevention of insects. .

將本發明的界面活性劑組成物以適當的劑量與實施方式,經由水溶液噴霧、泡沫、氣溶膠、塗抹、灌注或其組合的方式直接或間接施用於散居或群居之昆蟲,能夠影響昆蟲之呼吸系統、阻擾群飛昆蟲信息素之傳播、遏止群飛昆蟲之飛行,甚至是影響其生存,達到快速有效控制或防治昆蟲之目的。本發明之控制或防治昆蟲之界面活性劑組成物及其使用方法與現有控制或防治昆蟲的技術相比,具有以下優點: The surfactant composition of the present invention is directly or indirectly applied to scattered or gregarious insects by means of aqueous solution spraying, foaming, aerosol, smearing, infusion or a combination thereof in an appropriate dosage and embodiment, and can affect the respiration of insects. The system can prevent the spread of pheromone of flying insects, prevent the flight of flying insects, and even affect their survival, so as to achieve the purpose of fast and effective control or prevention of insects. Compared with the existing technology for controlling or preventing insects, the surfactant composition for controlling or preventing and controlling insects and its using method have the following advantages:

1.不含任何揮發性化合物之有機溶劑,不會危害人畜健康。此外,使用時不會產生異味,可保持室內清新的空氣。 1. It does not contain any organic solvents of volatile compounds, and will not harm human and animal health. In addition, there is no odor during use, which can keep indoor fresh air.

2.不含任何芳香族化合物,具有優秀的安全性。 2. Does not contain any aromatic compounds, with excellent safety.

3.不含任何基於氟、矽或磷類之化合物,具有生物降解性,避免造成環境汙染。氟類之化合物是可能影響生態環境及動物的無形污染物,磷類之化 合物已經確認會汙染水資源。有報告稱,甲基環矽氧烷會在水生動物體累積,所以可能是影響水資源的污染物。 3. Does not contain any compounds based on fluorine, silicon or phosphorus, and is biodegradable to avoid environmental pollution. Fluorine compounds are invisible pollutants that may affect the ecological environment and animals. Phosphorus compounds Compounds have been identified as contaminating water resources. Methylcyclosiloxane has been reported to accumulate in aquatic animals, so it may be a contaminant affecting water resources.

4.不含傳統農藥或殺蟲劑,具有優秀的環保性。 4. Does not contain traditional pesticides or insecticides, with excellent environmental protection.

5.使用水配製為包含本發明界面活性劑組成物的特定濃度之水溶液,可以以噴霧、泡沫、氣溶膠、塗抹、覆蓋、灌注或其組合直接或間接施用於散居或群居之昆蟲。 5. Use water to prepare an aqueous solution containing a specific concentration of the surfactant composition of the present invention, which can be directly or indirectly applied to scattered or gregarious insects by spraying, foaming, aerosol, smearing, covering, pouring, or a combination thereof.

6.經噴灑或灌注本發明之界面活性劑組成物可以讓地下蟲卵高度濕潤化,導致其窒息、腐爛或泡壞,而無法孵化成蟲。 6. By spraying or pouring the surfactant composition of the present invention, the subterranean eggs can be highly humidified, causing them to suffocate, rot or foam, and cannot hatch into adults.

7.可以施用於阻止或遏制昆蟲幼蟲之成長或是成蟲之群居或群飛。 7. Can be applied to prevent or restrain the growth of insect larvae or the colony or flock of adults.

8.可依照昆蟲之種類、體型、棲居型態調整實施方式與劑量,具有高度彈性與方便性。 8. The embodiment and dosage can be adjusted according to the species, body shape and habitat type of insects, with high flexibility and convenience.

9.可免除昆蟲對於傳統殺蟲劑或農藥所產生抗藥性之問題。 9. The problem of insect resistance to traditional pesticides or pesticides can be eliminated.

綜上所述,本發明之界面活性劑組成物的特點為使用量小、成效快、實施便利性高、安全無毒、無異味、環境友善、無抗藥性或具經濟性等。 To sum up, the surfactant composition of the present invention is characterized by small usage amount, quick effect, high implementation convenience, safety, non-toxicity, no peculiar smell, environmental friendliness, no drug resistance or economy, and the like.

儘管本發明已透過多個實施例來說明,應理解的是,只要不背離本發明的精神及申請專利範圍所主張者,可作出許多其他可能的修飾及變化。 Although this invention has been described in terms of several embodiments, it should be understood that many other possible modifications and changes can be made without departing from the spirit of the invention and the claimed scope of the invention.

Figure 109144213-A0101-11-0002-1
Figure 109144213-A0101-11-0002-1

S1、S2、S3:步驟 S1, S2, S3: Steps

Claims (16)

一種界面活性劑組成物的用途,用於控制或防治昆蟲上,其中該界面活性劑組成物包括:0.01至5重量百分比之烷基磺基琥珀酸酯;0.01至1重量百分比之保濕劑;以及餘量為水;其中,該烷基磺基琥珀酸酯具有1至18個碳鏈烷基;該保濕劑為烷基一元醇、烷基二元醇、烷基多元醇或其組合,其中該保濕劑之烷基為1至18個碳鏈烷基。 A use of a surfactant composition for controlling or preventing insects, wherein the surfactant composition comprises: 0.01 to 5 weight percent of alkylsulfosuccinate; 0.01 to 1 weight percent of a moisturizing agent; and The balance is water; wherein, the alkyl sulfosuccinate has 1 to 18 carbon chain alkyl groups; the humectant is an alkyl monohydric alcohol, an alkyl dihydric alcohol, an alkyl polyhydric alcohol or a combination thereof, wherein the The alkyl groups of the humectants are 1 to 18 carbon chain alkyl groups. 如請求項1所述的用途,其中該烷基磺基琥珀酸酯為單烷基磺基琥珀酸酯、二烷基磺基琥珀酸酯、多烷基磺基琥珀酸酯或其組合。 The use of claim 1, wherein the alkyl sulfosuccinate is a monoalkyl sulfosuccinate, a dialkyl sulfosuccinate, a polyalkyl sulfosuccinate, or a combination thereof. 如請求項1所述的用途,其中該烷基磺基琥珀酸酯為具有下列化學式之烷基磺基琥珀酸酯:
Figure 109144213-A0305-02-0016-1
其中,R1及R2分別為一1至18個碳鏈烷基。
The use as claimed in claim 1, wherein the alkyl sulfosuccinate is an alkyl sulfosuccinate having the following chemical formula:
Figure 109144213-A0305-02-0016-1
Wherein, R 1 and R 2 are respectively a 1 to 18 carbon chain alkyl group.
如請求項3所述的用途,其中R1及R2分別為4至18個碳鏈烷基。 The use according to claim 3, wherein R 1 and R 2 are respectively 4 to 18 carbon chain alkyl groups. 如請求項1所述的用途,其中該保濕劑為烷基多元醇。 The use of claim 1, wherein the humectant is an alkyl polyol. 如請求項1所述的用途,其中該界面活性劑組成物不含任何揮發性化合物之有機溶劑。 The use as claimed in claim 1, wherein the surfactant composition does not contain any organic solvent of volatile compounds. 如請求項1所述的用途,其中該界面活性劑組成物不含任何氟、矽或磷類化合物。 The use according to claim 1, wherein the surfactant composition does not contain any fluorine, silicon or phosphorus compounds. 如請求項1所述的用途,其中該界面活性劑組成物不含任何芳香族化合物。 The use as claimed in claim 1, wherein the surfactant composition does not contain any aromatic compounds. 如請求項1所述的用途,其中該界面活性劑組成物不含傳統農藥或殺蟲劑。 The use as claimed in claim 1, wherein the surfactant composition does not contain conventional pesticides or insecticides. 一種控制或防治昆蟲之方法,包括以下步驟:(a)配製一界面活性劑組成物,該界面活性劑組成物包括:0.01至5重量百分比之烷基磺基琥珀酸酯;0.01至1重量百分比之保濕劑;以及餘量為水;其中該烷基磺基琥珀酸酯具有1至18個碳鏈烷基;該保濕劑為烷基一元醇、烷基二元醇、烷基多元醇或其組合,其中該保濕劑之烷基為1至18個碳鏈烷基;以及(b)將(a)所得之界面活性劑組成物施用於一昆蟲。 A method for controlling or controlling insects, comprising the following steps: (a) formulating a surfactant composition, the surfactant composition comprising: 0.01 to 5 weight percent of alkyl sulfosuccinate; 0.01 to 1 weight percent and the balance is water; wherein the alkyl sulfosuccinate has 1 to 18 carbon chain alkyl groups; the humectant is an alkyl monohydric alcohol, an alkyl dihydric alcohol, an alkyl polyhydric alcohol or its A combination, wherein the alkyl group of the humectant is from 1 to 18 carbon chain alkyl groups; and (b) applying the resulting surfactant composition of (a) to an insect. 如請求項10所述的方法,其中該昆蟲為具有氣孔、氣管、氣囊或其組合而成呼吸系統的任何昆蟲。 The method of claim 10, wherein the insect is any insect having a respiratory system with stomata, trachea, air sacs, or a combination thereof. 如請求項10所述的方法,其中該昆蟲為靜態或動態之任何爬行或飛行昆蟲。 The method of claim 10, wherein the insect is any crawling or flying insect, static or dynamic. 如請求項10所述的方法,其中該昆蟲為散居或群居之任何昆蟲。 The method of claim 10, wherein the insect is any insect that is scattered or gregarious. 如請求項10所述的方法,其中該方法是施用於阻止或遏制昆蟲之群居或群飛。 The method of claim 10, wherein the method is applied to prevent or deter insect colonies or swarms. 如請求項10所述的方法,其中該方法是用以控制或防治昆蟲之蟲卵、幼蟲或成蟲。 The method of claim 10, wherein the method is for controlling or controlling eggs, larvae or adults of insects. 如請求項10至請求項15中任一項所述的方法,其中使用噴霧、泡沫、氣溶膠、塗抹、覆蓋、灌注或其組合的形式將該界面活性劑組成物直接施用於昆蟲。 The method of any one of claims 10 to 15, wherein the surfactant composition is applied directly to the insect using a spray, foam, aerosol, spread, drape, infusion, or a combination thereof.
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