TWI758844B - Circular and economical system and method for regenerating energy from industrial waste resources - Google Patents
Circular and economical system and method for regenerating energy from industrial waste resources Download PDFInfo
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本發明係有關於一種循環經濟之事業廢棄物資源能源再製造系統與方法，尤其是指一種能將事業廢棄物資源完全再生為有用能源，且系統設備之所需能源皆不需額外使用耗費其他資源，利用形成閉路循環，減少資源之耗費，並可實現零排放，讓生態環境更為優化，而在其整體施行使用上更增實用功效特性者。The present invention relates to a system and method for remanufacturing industrial waste resources and energy in a circular economy, in particular to a system and method that can completely regenerate industrial waste resources into useful energy, and the energy required by the system equipment does not require additional use and consumption of other energy sources. The utilization of resources forms a closed loop, which reduces the consumption of resources, and can achieve zero emissions, optimize the ecological environment, and increase the practical performance characteristics in its overall implementation and use.
按，隨著科技發展，電子業、印刷電路板業或電鍍業於製造處理過程中，常會產生含有大量重金屬的廢棄污泥。該重金屬污泥主要來源為工業製程中所排放廢水經絮凝沉澱而來，早期對於重金屬污泥處理方式主要為經燒結或減量後固化掩埋，固化掩埋法雖能處理重金屬污泥，但處理成本昂貴，掩埋場土地取得困難，及該土地長期未能再使用；且於掩埋過程中若未妥善處理，易造成環境污染及生態破壞，且以固化掩埋法處理重金屬污泥，該重金屬污泥中所合大量金屬等物質未將其回收再利用，對物料資源使用上亦是極大浪費。Press, with the development of science and technology, the electronic industry, printed circuit board industry or electroplating industry often produces waste sludge containing a large amount of heavy metals in the manufacturing process. The main source of the heavy metal sludge is the flocculation and precipitation of the wastewater discharged in the industrial process. In the early stage, the treatment method of heavy metal sludge was mainly sintering or reduction followed by solidification and burial. Although the solidification and burial method can treat heavy metal sludge, the treatment cost is expensive. , landfill land is difficult to obtain, and the land cannot be reused for a long time; and if it is not properly handled during the burial process, it is easy to cause environmental pollution and ecological damage, and the heavy metal sludge is treated by the solidification burial method, and the heavy metal sludge contains A large amount of metals and other substances are not recycled and reused, which is also a great waste of material resources.
也因此，即研發出公告於102年9月21日之第M462153號「重金屬污泥全資源化處理系統」，係於酸溶反應槽將重金屬污泥溶於酸溶液中，再以分子震盪裂解器將溶於酸溶液之重金屬污泥化合物全離子化，繼由連續分離機分離出酸不溶物及溶有重金屬離子之酸溶液，又使酸溶液經鹽酸回收器蒸發回收獲取高純度鹽酸，再將溶於酸溶液之重金屬離子經酸鹼值調整，分別取出高含量之貴金屬後，續經中和反應及分子穩定器磁化整序後形成複合鐵氧體及氯化鉀混合液，以分離出複合鐵氧體，又使氯化鉀混合液過濾後濃縮結晶成氯化鉀粉末，另使酸不溶物經矽溶膠反應器，生成活性矽酸膠。據此，利用本創作之重金屬污泥全資源化處理系統即可將重金屬污泥等廢棄物內所含諸多有用成分有效分離取出，以使該諸多成分可再為其他產業之原料再利用，達到將重金屬污泥全資源化實質效果。Therefore, the company developed the No. M462153 "Heavy Metal Sludge Total Resource Treatment System" announced on September 21, 102, which is to dissolve the heavy metal sludge in an acid solution in an acid-dissolving reaction tank, and then use molecular vibration to crack it. The device fully ionizes the heavy metal sludge compounds dissolved in the acid solution, and then separates the acid insoluble matter and the acid solution dissolved in heavy metal ions by a continuous separator, and then evaporates the acid solution through a hydrochloric acid recovery device to obtain high-purity hydrochloric acid. The heavy metal ions dissolved in the acid solution are adjusted by the pH value, and the high content of precious metals are taken out respectively, and then the mixed solution of composite ferrite and potassium chloride is formed after the neutralization reaction and the magnetization sequence of the molecular stabilizer. To compound ferrite, the potassium chloride mixture is filtered and then concentrated and crystallized into potassium chloride powder, and the acid-insoluble matter is passed through a silica sol reactor to generate active silicic acid gel. Accordingly, the use of the heavy metal sludge full resource treatment system of this creation can effectively separate and take out many useful components contained in heavy metal sludge and other wastes, so that these components can be reused as raw materials for other industries. Substantial effect of the full resource utilization of heavy metal sludge.
然而，上述「重金屬污泥全資源化處理系統」雖可達到將重金屬污泥全資源化之預期功效，但也在其實際操作施行使用上發現，該系統於施行過程中仍需額外使用到電能及其他資源，造成其仍有需要消耗其他能源之問題，致令其在整體結構組成上仍存在有改進之空間。However, although the above-mentioned "heavy metal sludge full resource treatment system" can achieve the expected effect of full resource recycling of heavy metal sludge, it is also found in its actual operation and use that the system still needs to use additional electricity during the implementation process. and other resources, it still needs to consume other energy, so there is still room for improvement in its overall structure.
緣是，發明人有鑑於此，秉持多年該相關行業之豐富設計開發及實際製作經驗，再予以研究改良，提供一種循環經濟之事業廢棄物資源能源再製造系統與方法，以期達到更佳實用價值性之目的者。The reason is that in view of this, the inventor, adhering to the rich experience in design, development and actual production for many years in the related industry, further researches and improves, and provides a recycling economy business waste resource energy remanufacturing system and method, in order to achieve better practical value. sexual purpose.
本發明之主要目的在於提供一種循環經濟之事業廢棄物資源能源再製造系統與方法，其主要係能將事業廢棄物資源完全再生為有用能源，且系統設備之所需能源皆不需額外使用耗費其他資源，利用形成閉路循環，減少資源之耗費，並可實現零排放，讓生態環境更為優化，而在其整體施行使用上更增實用功效特性者。The main purpose of the present invention is to provide a recycling economy industrial waste resource energy remanufacturing system and method, which can completely regenerate commercial waste resources into useful energy, and the energy required by the system equipment does not require additional use and consumption Other resources can be utilized to form a closed loop, reduce resource consumption, and achieve zero emissions, optimize the ecological environment, and increase the utility of their overall implementation and use.
本發明循環經濟之事業廢棄物資源能源再製造系統之主要目的與功效，係由以下具體技術手段所達成：The main purpose and effect of the recycling economy industrial waste resource energy remanufacturing system of the present invention are achieved by the following specific technical means:
其主要係包括有發電裝置及重金屬污泥處理裝置；其中：Its main systems include power generation devices and heavy metal sludge treatment devices; among which:
該發電裝置，其設有產氫器，於該產氫器電性連接有太陽能發電器，且於該產氫器以管路連接有氣體過濾器，於該氣體過濾器則連接有氫燃料發電器，該氫燃料發電器與該重金屬污泥處理裝置電性連接，以能進行發電供給該發電裝置本身及該重金屬污泥處理裝置所需用電；The power generation device is provided with a hydrogen generator, a solar generator is electrically connected to the hydrogen generator, a gas filter is connected to the hydrogen generator through a pipeline, and a hydrogen fuel is connected to the gas filter to generate electricity The hydrogen fuel generator is electrically connected to the heavy metal sludge treatment device, so as to generate electricity and supply the power required by the power generation device itself and the heavy metal sludge treatment device;
該重金屬污泥處理裝置，其分別設有污泥均質機及酸液均質機，令該污泥均質機及該酸液均質機皆以管路連接至酸溶反應槽，該酸溶反應槽以管路連接有分子震盪裂解器，該分子震盪裂解器以管路連接有連續分離機，該連續分離機以管路與該污泥均質機連接，且於該連續分離機以管路連接有分子穩定器，該分子穩定器以管路連接有過濾器，該過濾器以管路連接有乾燥單元，另於該過濾器以管路連接有真空薄膜濃縮［Vacuum membrane concentration，VMC］分離器，該真空薄膜濃縮分離器以管路連接有電解器，該電解器以管路與該分子穩定器連接，並令該電解器以管路連接合成槽，該合成槽以管路與該酸溶反應槽連接。The heavy metal sludge treatment device is provided with a sludge homogenizer and an acid solution homogenizer respectively, so that the sludge homogenizer and the acid solution homogenizer are connected to the acid solution reaction tank by pipelines, and the acid solution reaction tank is connected to the acid solution reaction tank. The pipeline is connected with a molecular vibration cracker, the molecular vibration cracker is connected with a continuous separator by a pipeline, the continuous separator is connected with the sludge homogenizer by a pipeline, and the continuous separator is connected with a molecule by a pipeline A stabilizer, the molecular stabilizer is connected with a filter by a pipeline, the filter is connected with a drying unit by a pipeline, and a vacuum membrane concentration [Vacuum membrane concentration, VMC] separator is connected with the filter by a pipeline, the The vacuum membrane concentration separator is connected with an electrolyzer by a pipeline, and the electrolyzer is connected with the molecular stabilizer by a pipeline, and the electrolyzer is connected with a pipeline by a synthesis tank, and the synthesis tank is connected with the acid-dissolving reaction tank by a pipeline. connect.
本發明循環經濟之事業廢棄物資源能源再製造系統的較佳實施例，其中，該發電裝置之該產氫器電性連接有太陽能發電器，以利用該太陽能發電器所產生的電能供給該產氫器作動使用。A preferred embodiment of the recycling economy industrial waste resource energy remanufacturing system of the present invention, wherein the hydrogen generator of the power generation device is electrically connected with a solar generator, so as to utilize the electric energy generated by the solar generator to supply the generator The hydrogen generator is used in action.
本發明循環經濟之事業廢棄物資源能源再製造系統的較佳實施例，其中，該發電裝置於該氣體過濾器另連接有微藻養殖裝置，該微藻養殖裝置則可利用由該氣體過濾器所分離出之二氧化碳氣體進行微藻養殖。A preferred embodiment of the recycling economy industrial waste resource energy remanufacturing system of the present invention, wherein the power generation device is further connected with a microalgae cultivation device to the gas filter, and the microalgae cultivation device can utilize the gas filter. The separated carbon dioxide gas is used for microalgae cultivation.
本發明循環經濟之事業廢棄物資源能源再製造方法之主要目的與功效，係由以下具體技術手段所達成：The main purpose and effect of the recycling economy industrial waste resource energy remanufacturing method of the present invention are achieved by the following specific technical means:
其主要係於發電裝置以有機生物質廢棄物輸入進行產氫程序，令該有機生物質廢棄物以電漿氣化技術產生氫及二氧化碳合成氣，該氫及二氧化碳合成氣經由進行純化，而分別分離出氫氣與二氧化碳氣體，該氫氣即可進行發電，以供給該發電裝置本身及重金屬污泥處理裝置所需用電；It is mainly based on the input of organic biomass waste in the power generation device to carry out the hydrogen production process, so that the organic biomass waste is produced by plasma gasification technology to generate hydrogen and carbon dioxide synthesis gas. After separating hydrogen and carbon dioxide gas, the hydrogen can generate electricity to supply the electricity required by the power generation device itself and the heavy metal sludge treatment device;
令電鍍污泥及廢酸洗液分別輸入該重金屬污泥處理裝置進行均質處理，將經過均質處理後的電鍍污泥及廢酸洗液進行酸溶程序，令該電鍍污泥溶解於酸溶液中，使該電鍍污泥中之化合物完全離子化，而該離子化之電鍍污泥中化合物係概分有可溶於酸溶液之重金屬離子及不溶於酸溶液之酸不溶物，再使不溶於酸溶液之酸不溶物及溶於酸溶液之重金屬離子分離，而分離形成酸不溶物及溶有重金屬離子之酸溶液；The electroplating sludge and the waste pickling liquid are respectively input into the heavy metal sludge treatment device for homogenization treatment, and the electroplating sludge and the waste pickling liquid after the homogenization treatment are subjected to an acid dissolution process, so that the electroplating sludge is dissolved in the acid solution. , so that the compounds in the electroplating sludge are completely ionized, and the compounds in the ionized electroplating sludge are roughly divided into heavy metal ions that are soluble in acid solution and acid-insoluble substances that are insoluble in acid solution. The acid-insoluble matter of the solution and the heavy metal ions dissolved in the acid solution are separated, and the acid-insoluble matter and the acid solution with the heavy metal ions dissolved are formed by separation;
所分離出之溶有重金屬離子之酸溶液則進行鐵氧體程序，加入已調好濃度之鹼溶液供進行中和反應，即可形成複合鐵氧體，將該沉澱有複合鐵氧體之酸鹼溶液進行過濾分離，分別分離出酸鹼溶液與複合鐵氧體，該複合鐵氧體經乾燥後，即形成複合鐵氧體粉末；The separated acid solution dissolved with heavy metal ions is subjected to a ferrite procedure, and an alkali solution with a adjusted concentration is added for neutralization reaction to form composite ferrite, and the acid precipitated with composite ferrite The alkaline solution is filtered and separated, and the acid-base solution and the composite ferrite are respectively separated, and the composite ferrite is dried to form a composite ferrite powder;
所過濾分離出的該酸鹼溶液則以真空薄膜進行膜過濾濃縮分離出純水，而無法通過該真空薄膜之該酸鹼溶液則進行電解處理，經電解處理後產生電解鹼及氯離子，該氯離子則進行合成反應，以合成鹽酸。The acid-base solution separated by filtration is subjected to membrane filtration and concentrated separation with a vacuum membrane to separate pure water, and the acid-base solution that cannot pass through the vacuum membrane is subjected to electrolysis treatment, and electrolytic alkali and chloride ions are generated after electrolysis treatment. Chloride ions undergo a synthesis reaction to synthesize hydrochloric acid.
本發明循環經濟之事業廢棄物資源能源再製造方法的較佳實施例，其中，該有機生物質廢棄物以電漿氣化技術產氫，其過程中會產生微量固體廢棄物，該微量固體廢棄物可供輸送至該重金屬污泥處理裝置再次經過均質處理及進行後續程序。A preferred embodiment of the method for reproducing energy from commercial waste in a circular economy of the present invention, wherein the organic biomass waste is produced by plasma gasification technology, and a trace amount of solid waste will be generated in the process, and the trace amount of solid waste will be produced. The material can be transported to the heavy metal sludge treatment device for homogenization treatment and subsequent procedures.
本發明循環經濟之事業廢棄物資源能源再製造方法的較佳實施例，其中，該有機生物質廢棄物於產氫發電後，其過程中所產生的水，即導入再生水系統。In a preferred embodiment of the recycling-economy business waste resource energy recycling method of the present invention, after the organic biomass waste produces hydrogen to generate electricity, the water produced in the process is introduced into the reclaimed water system.
本發明循環經濟之事業廢棄物資源能源再製造方法的較佳實施例，其中，該氫及二氧化碳合成氣經由進行純化，而分別分離出氫氣與二氧化碳氣體，該二氧化碳氣體可供進行微藻養殖。In a preferred embodiment of the method for reproducing commercial waste resources and energy in a circular economy of the present invention, the hydrogen and carbon dioxide synthesis gas are purified to separate hydrogen and carbon dioxide gas respectively, and the carbon dioxide gas can be used for microalgae cultivation.
本發明循環經濟之事業廢棄物資源能源再製造方法的較佳實施例，其中，該電鍍污泥進行均質處理過程中能利用氣旋脫水方式進行均質及脫水處理，並可予以加熱提高脫水效率。In a preferred embodiment of the recycling-economy business waste resource energy remanufacturing method of the present invention, the electroplating sludge can be homogenized and dehydrated by cyclone dehydration during the homogenization process, and can be heated to improve dehydration efficiency.
本發明循環經濟之事業廢棄物資源能源再製造方法的較佳實施例，其中，電解處理後之該電解鹼可提供進行鐵氧體程序之中和反應。In a preferred embodiment of the recycling-economy business waste resource energy remanufacturing method of the present invention, the electrolytic alkali after the electrolytic treatment can be used for neutralization reaction of ferrite process.
本發明循環經濟之事業廢棄物資源能源再製造方法的較佳實施例，其中，該發電裝置與該重金屬污泥處理裝置操作使用過程中所產生的熱能可利用儲熱槽進行儲熱，且將所儲存的熱能以梯式熱傳導方式依照所需熱能大小，依序傳導至該發電裝置與該重金屬污泥處理裝置操作使用過程中需使用到熱能之步驟，令熱能呈閉路循環狀態。In a preferred embodiment of the method for reproducing energy from commercial waste in a circular economy of the present invention, the heat energy generated during the operation and use of the power generation device and the heavy metal sludge treatment device can be stored in a heat storage tank, and the heat is stored in a heat storage tank. The stored heat energy is transferred to the power generation device and the heavy metal sludge treatment device in sequence according to the required heat energy in a ladder heat conduction mode, so that the heat energy is in a closed circuit state.
為令本發明所運用之技術內容、發明目的及其達成之功效有更完整且清楚的揭露，茲於下詳細說明之，並請一併參閱所揭之圖式及圖號：In order to make the technical content used in the present invention, the purpose of the invention and the effect achieved by the present invention more completely and clearly disclosed, it is explained in detail below, and please refer to the disclosed drawings and drawing numbers together:
首先，請參閱第一圖本發明之架構示意圖所示，本發明主要係包括有發電裝置(1)及重金屬污泥處理裝置(2)；其中：First of all, please refer to the schematic diagram of the structure of the present invention in Figure 1. The present invention mainly includes a power generation device (1) and a heavy metal sludge treatment device (2); wherein:
該發電裝置(1)，其設有產氫器(11)，於該產氫器(11)電性連接有太陽能發電器(12)，以利用該太陽能發電器(12)所產生的電能供給該產氫器(11)作動使用，且於該產氫器(11)以管路連接有氣體過濾器(13)，該氣體過濾器(13)以分子篩方式進行氫氣純化，於該氣體過濾器(13)則分別連接有氫燃料發電器(14)及微藻養殖裝置(15)，該氫燃料發電器(14)與該重金屬污泥處理裝置(2)電性連接，以能進行發電供給該發電裝置(1)本身及該重金屬污泥處理裝置(2)所需用電，而該微藻養殖裝置(16)則可進行微藻養殖，另於該產氫氣(11)亦以管路連接有再生水系統(3)。The power generation device (1) is provided with a hydrogen generator (11), and a solar generator (12) is electrically connected to the hydrogen generator (11), so as to utilize the electric energy generated by the solar generator (12) to supply electricity The hydrogen generator (11) is in operation, and a gas filter (13) is connected to the hydrogen generator (11) with a pipeline, and the gas filter (13) is used for hydrogen purification by molecular sieve. (13) are respectively connected with a hydrogen fuel generator (14) and a microalgae cultivation device (15), and the hydrogen fuel generator (14) is electrically connected with the heavy metal sludge treatment device (2) to enable power generation and supply The power generation device (1) itself and the heavy metal sludge treatment device (2) need electricity, and the microalgae cultivation device (16) can be used for microalgae cultivation, and the hydrogen production (11) is also connected by pipelines. A reclaimed water system (3) is connected.
該重金屬污泥處理裝置(2)，其分別設有污泥均質機(21)及酸液均質機(22)，令該污泥均質機(21)及該酸液均質機(22)皆以管路連接至酸溶反應槽(23)，該酸溶反應槽(23)以管路連接有分子震盪裂解器(231)，該分子震盪裂解器(231)以管路連接有連續分離機(24)，該連續分離機(24)以管路與該污泥均質機(21)連接，且於該連續分離機(24)以管路連接有分子穩定器(25)，該分子穩定器(25)以管路連接有過濾器(251)，該過濾器(251)以管路連接有乾燥單元(26)，另於該過濾器(251)以管路連接有真空薄膜濃縮［Vacuum membrane concentration，VMC］分離器(27)，該真空薄膜濃縮分離器(27)以管路連接有電解器(28)，該電解器(28)以管路與該分子穩定器(25)連接，並令該電解器(28)以管路連接合成槽(29)，該合成槽(29)以管路與該酸溶反應槽(23)連接，另於該真空薄膜濃縮分離器(27)亦與該再生水系統(3)以管路連接。The heavy metal sludge treatment device (2) is provided with a sludge homogenizer (21) and an acid liquid homogenizer (22) respectively, so that the sludge homogenizer (21) and the acid liquid homogenizer (22) are both The pipeline is connected to the acid-dissolving reaction tank (23), and the acid-dissolving reaction tank (23) is connected with a molecular oscillation cracker (231) with a pipeline, and the molecular oscillation cracker (231) is connected with a continuous separator (231) with a pipeline. 24), the continuous separator (24) is connected to the sludge homogenizer (21) with a pipeline, and a molecular stabilizer (25) is connected to the continuous separator (24) with a pipeline, and the molecular stabilizer ( 25) A filter (251) is connected with a pipeline, the filter (251) is connected with a drying unit (26) with a pipeline, and a vacuum membrane concentration (Vacuum membrane concentration) is connected with the filter (251) with a pipeline. , VMC] separator (27), the vacuum membrane concentration separator (27) is connected with an electrolyzer (28) by a pipeline, and the electrolyzer (28) is connected with the molecular stabilizer (25) by a pipeline, and makes The electrolyzer (28) is connected to the synthesis tank (29) by a pipeline, the synthesis tank (29) is connected to the acid dissolution reaction tank (23) by a pipeline, and the vacuum membrane concentration separator (27) is also connected to the The reclaimed water system (3) is connected by pipeline.
如此一來，使得本發明於操作施行上，請再一併參閱第二圖本發明之發電裝置施行狀態流程示意圖所示，其係令有機生物質廢棄物［如：農作廢棄物、城市污泥、食品工業污泥、造紙工業污泥、廢塑膠膜、菇類廢太空包、中藥提煉藥渣等］輸入該發電裝置(1)之該產氫器(11)進行產氫程序，而該產氫器(11)受該太陽能發電器(12)所產生的電能進行作動，令該有機生物質廢棄物於該產氫器(11)內以電漿氣化技術產生氫及二氧化碳合成氣、微量固體廢棄物，該微量固體廢棄物可供輸送至該重金屬污泥處理裝置(2)之該污泥均質機(21)中，而該氫及二氧化碳合成氣則經由該氣體過濾器(13)進行純化，而分別分離出氫氣與二氧化碳氣體，該氫氣可輸送至該氫燃料發電器(14)進行發電或將多餘氫氣進行市場販售，以供給該發電裝置(1)本身及該重金屬污泥處理裝置(2)所需用電，且該利用有機生物質廢棄物產氫，所產生的水會導入該再生水系統(3)，能供給整體系統使用或進行市場販售，而該二氧化碳氣體則可輸送至該微藻養殖裝置(15)，以進行微藻養殖，並產生微藻粉供市場販售。In this way, in the operation of the present invention, please refer to Fig. 2 again, as shown in the schematic flow chart of the implementation state of the power generation device of the present invention, which is an organic biomass waste [such as agricultural waste, municipal sludge]. , food industry sludge, paper industry sludge, waste plastic film, mushroom waste space bag, traditional Chinese medicine extraction dregs, etc.] are input into the hydrogen generator (11) of the power generation device (1) to carry out the hydrogen production process, and the product The hydrogen generator (11) is actuated by the electrical energy generated by the solar power generator (12), so that the organic biomass waste generates hydrogen and carbon dioxide syngas, trace amounts of hydrogen and carbon dioxide in the hydrogen generator (11) by plasma gasification technology Solid waste, which can be transported to the sludge homogenizer (21) of the heavy metal sludge treatment device (2), and the hydrogen and carbon dioxide syngas are processed through the gas filter (13) Purification to separate out hydrogen gas and carbon dioxide gas respectively, the hydrogen can be sent to the hydrogen fuel generator (14) for power generation or the excess hydrogen can be sold in the market to supply the power generation device (1) itself and the heavy metal sludge treatment The electricity required by the device (2) and the use of organic biomass waste to produce hydrogen, the water produced will be introduced into the reclaimed water system (3), which can be supplied to the overall system for use or sold in the market, and the carbon dioxide gas can be transported to the microalgae cultivation device (15), so as to carry out microalgae cultivation and produce microalgae powder for sale in the market.
請再一併參閱第三圖本發明之重金屬污泥處理裝置施行狀態流程示意圖所示，其係令電鍍污泥輸入該重金屬污泥處理裝置(2)之該污泥均質機(21)進行均質處理，且於電鍍污泥進行均質處理過程中能利用氣旋脫水方式以氣體噴射、衝擊流進行均質及再進行脫水處理，並可予以加熱提高脫水效率，同時亦令廢酸洗液輸入該酸液均質機(22)進行均質處理，將經過均質處理後的電鍍污泥及廢酸洗液進行酸溶程序，令均質處理後的電鍍污泥及廢酸洗液皆輸入該酸溶反應槽(23)中，令電鍍污泥溶解於酸溶液中，且將溶有電鍍污泥之酸溶液輸入該分子震盪裂解器(231)，以利用不同波長之超音波協同相乘作用將溶於酸溶液之電鍍污泥中化合物分子鏈結打斷形成游離狀態的離子，以使該電鍍污泥中之化合物完全離子化，而該離子化之電鍍污泥中化合物係概分有可溶於酸溶液之重金屬離子及不溶於酸溶液之矽、鈣等酸不溶物，再使分子震盪裂解器(231)將電鍍污泥中化合物完全離子化之酸溶液輸往該連續分離機(24)，以由該連續分離機(24)將不溶於酸溶液之酸不溶物及溶於酸溶液之重金屬離子分離，而分離形成酸不溶物及溶有重金屬離子之酸溶液，該不溶於酸溶液之酸不溶物則會再輸送到該污泥均質機(21)，以持續進行處理，防止存在有重金屬離子，以使其更為純化，達到零排放及資源完全回收再生。Please also refer to Figure 3, which is a schematic flow diagram of the operation state of the heavy metal sludge treatment device of the present invention, which is to make the electroplating sludge input into the sludge homogenizer (21) of the heavy metal sludge treatment device (2) for homogenization. In the process of homogenization treatment of electroplating sludge, cyclone dehydration can be used for homogenization and dehydration treatment by gas jet and impingement flow, and it can be heated to improve the dehydration efficiency, and at the same time, waste pickling solution can be input into the acid solution. The homogenizer (22) performs homogenization treatment, and performs an acid-dissolving procedure on the electroplating sludge and the waste pickling solution after the homogenization treatment, so that the electroplating sludge and the waste pickling solution after the homogenization treatment are all input into the acid-dissolving reaction tank (23). ), the electroplating sludge is dissolved in the acid solution, and the acid solution dissolved in the electroplating sludge is input into the molecular oscillation cracker (231), so as to utilize the synergistic effect of ultrasonic waves of different wavelengths to dissolve the acid solution dissolved in the acid solution. The molecular chains of the compounds in the electroplating sludge are broken to form free ions, so that the compounds in the electroplating sludge are completely ionized, and the compounds in the ionized electroplating sludge are roughly divided into heavy metals soluble in acid solutions. ions and acid-insoluble substances such as silicon and calcium that are insoluble in the acid solution, and then the molecular oscillatory cracker (231) is used to transport the acid solution in which the compounds in the electroplating sludge are completely ionized to the continuous separator (24), so that the continuous The separator (24) separates the acid-insoluble matter that is insoluble in the acid solution and the heavy metal ions that dissolve in the acid solution, and separates the acid-insoluble matter and the acid solution that dissolves heavy metal ions. The acid-insoluble matter that is insoluble in the acid solution will It is then transported to the sludge homogenizer (21) for continuous treatment to prevent the presence of heavy metal ions, so as to make it more purified and achieve zero discharge and complete resource recovery and regeneration.
而由該連續分離機(24)所分離出之溶有重金屬離子之酸溶液則係輸入該分子穩定器(25)中進行鐵氧體程序，且能予以加熱以提高該鐵氧體程序之效能，於該分子穩定器(25)內計量加入已調好濃度之鹼溶液供進行中和反應，利用該酸鹼值［PH值］控制即可形成複合鐵氧體，其主要係將其酸鹼值［PH值］調整至PH 9以沉澱形成複合鐵氧體，再由該分子穩定器(25)導入壓縮空氣進行氧化，以於該中和之酸鹼溶液中形成有複合鐵氧體沉澱，並發出規劃之磁力線，通過磁化反應，將該複合鐵氧體整序排列，使複合鐵氧體錯合物穩定，再令該分子穩定器(25)將該沉澱有複合鐵氧體之酸鹼溶液輸入該過濾器(251)中，以將該酸鹼溶液與該複合鐵氧體進行過濾分離，該複合鐵氧體係再經該乾燥單元(26)乾燥後，即形成複合鐵氧體粉末。And the acid solution dissolved with heavy metal ions separated by the continuous separator (24) is input into the molecular stabilizer (25) for the ferrite process, and can be heated to improve the efficiency of the ferrite process , in the molecular stabilizer (25), metered alkaline solution with adjusted concentration for the neutralization reaction, and the composite ferrite can be formed by controlling the pH value [PH value], which is mainly composed of acid and alkali. The value [PH value] is adjusted to PH 9 to form composite ferrite by precipitation, and then compressed air is introduced into the molecular stabilizer (25) for oxidation, so that composite ferrite precipitate is formed in the neutralized acid-base solution, And send out the planned magnetic lines of force, through the magnetization reaction, the composite ferrites are arranged in order, so that the composite ferrite complex is stabilized, and then the molecular stabilizer (25) is precipitated with the acid-base of the composite ferrite. The solution is input into the filter (251) to filter and separate the acid-base solution and the composite ferrite, and the composite ferrite system is dried by the drying unit (26) to form composite ferrite powder.
而經由該過濾器(251)所過濾分離出的該酸鹼溶液則輸送入該真空薄膜濃縮分離器(27)，該真空薄膜濃縮分離器(27)僅能通過水分子，使得能由該真空薄膜濃縮分離器(27)膜過濾濃縮分離出純水，所產生的純水即導入該再生水系統(3)，使其能供給整體系統使用或進行市場販售，且該真空薄膜濃縮分離器(27)之真空薄膜能經由溫差降低壓力以進行多級膜過濾，且真空薄膜可回收再使用，減少資源的耗費，而無法通過該真空薄膜濃縮分離器(27)之該酸鹼溶液則輸入該電解器(28)中進行電解處理，經該電解器(28)電解處理後之電解鹼可供輸入該分子穩定器(25)中之鐵氧體程序，以提供進行中和反應，而電解處理後之氯離子則輸入該合成槽(29)進行合成反應，以合成鹽酸，所合成的鹽酸可輸入該酸溶反應槽(23)中進行酸溶程序或進行市場販售。And the acid-base solution filtered and separated by the filter (251) is transported into the vacuum membrane concentrating separator (27), and the vacuum membrane concentrating separator (27) can only pass water molecules, so that the Membrane concentration separator (27) membrane filtration concentrates and separates pure water, and the produced pure water is introduced into the regeneration water system (3), so that it can be supplied to the whole system for use or sold in the market, and the vacuum membrane concentration separator ( The vacuum membrane of 27) can reduce the pressure through the temperature difference to perform multi-stage membrane filtration, and the vacuum membrane can be recycled and reused to reduce the consumption of resources, and the acid-base solution that cannot pass through the vacuum membrane concentration separator (27) is input into the The electrolytic treatment is carried out in the electrolyzer (28), and the electrolytic alkali after the electrolytic treatment of the electrolyzer (28) can be supplied to the ferrite procedure in the molecular stabilizer (25) to provide a neutralization reaction, and the electrolytic treatment is carried out. Afterwards, chloride ions are input into the synthesis tank (29) for synthesis reaction to synthesize hydrochloric acid, and the synthesized hydrochloric acid can be input into the acid dissolution reaction tank (23) for acid dissolution procedure or for sale in the market.
而整體系統於操作使用過程中，由於該太陽能發電器(12)發電、該氫燃料發電器(15)發電、及各化學反應過程中，皆會產生熱能，使得能將所產生的熱能利用儲熱槽進行儲熱，且將所儲存的熱能以梯式熱傳導方式依照所需熱能大小，依序傳導至該乾燥單元(26)進行複合鐵氧體粉末之乾燥、該污泥均質機(21)進行電鍍污泥之脫水乾燥、該微藻養殖裝置(16)進行微藻粉之乾燥、該分子穩定器(25)增加鐵氧體程序之效能、該真空薄膜濃縮分離器(27)對真空薄膜加溫以利用溫差降低壓力而進行多級膜過濾，以令熱能呈閉路循環狀態，防止熱能的浪費。During the operation and use of the overall system, heat energy will be generated due to the power generation of the solar power generator (12), the power generation of the hydrogen fuel power generator (15), and each chemical reaction process, so that the generated heat energy can be utilized for storage. The heat tank is used for heat storage, and the stored heat energy is transferred to the drying unit (26) in order to dry the composite ferrite powder according to the required heat energy in a ladder-type heat conduction mode, and the sludge homogenizer (21) The dehydration and drying of electroplating sludge, the drying of microalgae powder by the microalgae cultivation device (16), the increase of the efficiency of the ferrite process by the molecular stabilizer (25), the concentration and separation of the vacuum membrane by the vacuum membrane (27) Heating to use the temperature difference to reduce the pressure and perform multi-stage membrane filtration, so that the heat energy is in a closed circuit state and prevent the waste of heat energy.
藉由以上所述，本發明之使用實施說明可知，本發明與現有技術手段相較之下，本發明主要係具有下列優點：From the above, the use and implementation description of the present invention shows that compared with the prior art means, the present invention mainly has the following advantages:
1.本發明係於發電裝置以有機生物質廢棄物產氫進行發電，以供給該發電裝置本身及重金屬污泥處理裝置所需用電，且於重金屬污泥處理裝置處理過程中所產生的鹼、鹽酸等有用成份，亦予以應用在該重金屬污泥處理裝置之處理步驟中，使得不需額外使用耗費其他資源，而在其整體施行使用上更增實用功效特性者。1. The present invention uses organic biomass waste to generate hydrogen for power generation in a power generation device to supply the power required by the power generation device itself and the heavy metal sludge treatment device, and the alkali, Useful ingredients such as hydrochloric acid are also used in the treatment steps of the heavy metal sludge treatment device, so that additional resources are not required to be used, and the utility properties are enhanced in the overall implementation and use.
2.本發明於發電裝置與重金屬污泥處理裝置操作過程中，能令水、熱、酸、鹼等資源皆形成閉路循環，以減少資源之耗費。2. During the operation of the power generation device and the heavy metal sludge treatment device, the present invention can make water, heat, acid, alkali and other resources form a closed-circuit cycle, so as to reduce the consumption of resources.
3.本發明於發電裝置與重金屬污泥處理裝置操作過程中，能生成再生能源、氫能源、二氧化碳微藻養殖等，以形成零排放，而讓生態環境更為優化。3. During the operation of the power generation device and the heavy metal sludge treatment device, the present invention can generate renewable energy, hydrogen energy, carbon dioxide microalgae cultivation, etc., so as to form zero emissions and optimize the ecological environment.
然而前述之實施例或圖式並非限定本發明之產品結構或使用方式，任何所屬技術領域中具有通常知識者之適當變化或修飾，皆應視為不脫離本發明之專利範疇。However, the foregoing embodiments or drawings do not limit the product structure or usage of the present invention, and any appropriate changes or modifications made by those with ordinary knowledge in the technical field should be regarded as not departing from the scope of the present invention.
綜上所述，本發明實施例確能達到所預期之使用功效，又其所揭露之具體構造，不僅未曾見諸於同類產品中，亦未曾公開於申請前，誠已完全符合專利法之規定與要求，爰依法提出發明專利之申請，懇請惠予審查，並賜准專利，則實感德便。To sum up, the embodiment of the present invention can indeed achieve the expected use effect, and the specific structure disclosed is not only not seen in similar products, but also has not been disclosed before the application, which fully complies with the provisions of the patent law In accordance with the requirements, I would like to file an application for an invention patent in accordance with the law, and I sincerely request that it be reviewed and granted the patent.
1:發電裝置1: Power generation device
11:產氫器11: Hydrogen generator
12:太陽能發電器12: Solar generator
13:氣體過濾器13: Gas filter
14:氫燃料發電器14: Hydrogen Fuel Generator
15:微藻養殖裝置15: Microalgae cultivation device
2:重金屬污泥處理裝置2: Heavy metal sludge treatment device
21:污泥均質機21: Sludge homogenizer
22:酸液均質機22: Acid homogenizer
23:酸溶反應槽23: Acid dissolution reaction tank
231:分子震盪裂解器231: Molecular oscillatory cracker
24:連續分離機24: Continuous Separator
25:分子穩定器25: Molecular Stabilizer
251:過濾器251: Filter
26:乾燥單元26: Drying unit
27:真空薄膜濃縮分離器27: Vacuum Membrane Concentration Separator
28:電解器28: Electrolyzer
29:合成槽29: Synthesis slot
3:再生水系統3: Reclaimed water system
第一圖：本發明之架構示意圖Figure 1: Schematic diagram of the structure of the present invention
第二圖：本發明之發電裝置施行狀態流程示意圖The second figure: a schematic diagram of the implementation state of the power generation device of the present invention
第三圖：本發明之重金屬污泥處理裝置施行狀態流程示意圖Figure 3: Schematic diagram of the implementation state of the heavy metal sludge treatment device of the present invention
1:發電裝置 11:產氫器 12:太陽能發電器 13:氣體過濾器 14:氫燃料發電器 15:微藻養殖裝置 2:重金屬污泥處理裝置 21:污泥均質機 22:酸液均質機 23:酸溶反應槽 231:分子震盪裂解器 24:連續分離機 25:分子穩定器 251:過濾器 26:乾燥單元 27:真空薄膜濃縮分離器 28:電解器 29:合成槽 3:再生水系統 1: Power generation device 11: Hydrogen generator 12: Solar generator 13: Gas filter 14: Hydrogen Fuel Generator 15: Microalgae cultivation device 2: Heavy metal sludge treatment device 21: Sludge homogenizer 22: Acid homogenizer 23: Acid dissolution reaction tank 231: Molecular oscillatory cracker 24: Continuous Separator 25: Molecular Stabilizer 251: Filter 26: Drying unit 27: Vacuum Membrane Concentration Separator 28: Electrolyzer 29: Synthesis slot 3: Reclaimed water system
Claims (10)
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| CN101041831A (en) * | 2007-02-25 | 2007-09-26 | 汕头大学 | Activated sludge hydrogen production and application for power generation |
| CN101717790A (en) * | 2009-12-10 | 2010-06-02 | 同济大学 | Method for promoting sludge anaerobic fermentation to produce hydrogen in sewage plant |
| CN102329006A (en) * | 2011-07-28 | 2012-01-25 | 西安交通大学 | Microbial photoelectrochemical system for simultaneously generating electricity and hydrogen and treating sewage |
| CN102766661A (en) * | 2012-07-04 | 2012-11-07 | 中国环境科学研究院 | Algal residue and livestock/poultry feces coupled anaerobic fermentation method for producing hydrogen |
| CN203833780U (en) * | 2013-05-31 | 2014-09-17 | 台湾押花事业股份有限公司 | Heavy metal sludge full-recycling treatment system |
| CN104141147A (en) * | 2014-08-01 | 2014-11-12 | 太原理工大学 | Method for making microorganism electrolytic cell generate and store hydrogen through microbial fuel cells in self-driven mode |
| TWM605131U (en) * | 2020-09-03 | 2020-12-11 | 擁泉科技股份有限公司 | Cycle economy industrial waste resources and energy resources remanufacturing system |
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| CN101041831A (en) * | 2007-02-25 | 2007-09-26 | 汕头大学 | Activated sludge hydrogen production and application for power generation |
| CN101717790A (en) * | 2009-12-10 | 2010-06-02 | 同济大学 | Method for promoting sludge anaerobic fermentation to produce hydrogen in sewage plant |
| CN102329006A (en) * | 2011-07-28 | 2012-01-25 | 西安交通大学 | Microbial photoelectrochemical system for simultaneously generating electricity and hydrogen and treating sewage |
| CN102766661A (en) * | 2012-07-04 | 2012-11-07 | 中国环境科学研究院 | Algal residue and livestock/poultry feces coupled anaerobic fermentation method for producing hydrogen |
| CN203833780U (en) * | 2013-05-31 | 2014-09-17 | 台湾押花事业股份有限公司 | Heavy metal sludge full-recycling treatment system |
| CN104141147A (en) * | 2014-08-01 | 2014-11-12 | 太原理工大学 | Method for making microorganism electrolytic cell generate and store hydrogen through microbial fuel cells in self-driven mode |
| TWM605131U (en) * | 2020-09-03 | 2020-12-11 | 擁泉科技股份有限公司 | Cycle economy industrial waste resources and energy resources remanufacturing system |
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