TWI746873B - Wrapper for non-burning heating type smoking article, non-buring heating type smoking article and electrically heating type smoking system - Google Patents

Wrapper for non-burning heating type smoking article, non-buring heating type smoking article and electrically heating type smoking system Download PDF

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TWI746873B
TWI746873B TW107126504A TW107126504A TWI746873B TW I746873 B TWI746873 B TW I746873B TW 107126504 A TW107126504 A TW 107126504A TW 107126504 A TW107126504 A TW 107126504A TW I746873 B TWI746873 B TW I746873B
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paper
heating type
smoking article
type smoking
roll paper
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TW107126504A
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TW202007287A (en
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櫻井亨
大澤徳子
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日商日本煙草產業股份有限公司
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Abstract

The present invention provides a wrapper for non-burning heating type smoking article which has a white part, the white part having a discrimination score obtained by substituting the color difference value in the CIELab color system before and after heating at 230℃ for 3 minutes in the following formula (1) showing a numerical value lower than 0.62, and a ISO whiteness degree of 83% or more. Discrimination score (y) y = -0.18 × △L * + 0.08 × △a * + 0.13 × △b * -2.36 (1)
(In the formula (1), the color difference value in the CIELab color system before and after heating means the value obtained by subtracting the L*, a*, b* values before heating from the L*, a*, b* values after heating. △L* represents the difference in lightness L* after and before heating the wrapper, △a * represents the difference in chromaticity a * after and before heating the wrapper, and △b * represents the difference in chromaticity b * after and before heating the wrapper).

Description

非燃燒加熱型吸煙物品用捲紙、非燃燒加熱型吸煙物品及電加熱型吸煙系統 Non-combustion heating type smoking article roll paper, non-combustion heating type smoking article and electric heating type smoking system

本發明係關於非燃燒加熱型吸煙物品用捲紙、非燃燒加熱型吸煙物品及電加熱型吸煙系統。 The present invention relates to a non-combustion heating type smoking article roll paper, a non-combustion heating type smoking article and an electric heating type smoking system.

從包含煙草絲之煙草桿的周圍進行加熱,以將揮發成分傳送至使用者之形式的非燃燒加熱型吸煙物品乃為人所知。非燃燒加熱型吸煙物品中,係將以捲紙所捲裝之煙草桿加熱,但與先前的香煙不同,使用後(加熱後)煙草桿亦不會燃燒而殘留。 A non-combustion heating type smoking article in the form of heating from a tobacco rod containing tobacco shreds to deliver volatile components to the user is known. In non-combustion heating smoking articles, tobacco rods wrapped in paper are heated, but unlike previous cigarettes, the tobacco rods will not burn and remain after use (after heating).

先前的香煙中,用以捲裝煙草絲之捲紙,雖有時附有商標等,但一般是使用白色(無色)紙。 In previous cigarettes, the paper used to wrap the tobacco shreds was sometimes accompanied by a trademark, but white (colorless) paper was generally used.

非燃燒加熱型吸煙物品中,已知當使用先前的香煙所使用之捲紙來作為捲裝煙草絲之捲紙時,會因 使用時的加熱,有時會產生對使用者而言為不適之變色之情形。相對於此課題,雖有使用特定的有色紙使變色變得較不醒目之方法,但可得知使用泛用性高的白色紙時仍需另外耗費心力。 Among non-combustion heating smoking articles, it is known that when the paper used in previous cigarettes is used as the paper for wrapping tobacco shreds, the heating during use may sometimes cause discomfort to the user. Discoloration. In contrast to this problem, although there is a method of using specific colored paper to make the discoloration less noticeable, it can be seen that additional effort is required to use white paper with high generality.

因此,本發明中,係以提供一種不會產生可能因加熱而產生之外觀上的不適感之非燃燒加熱型吸煙物品用捲紙者為課題。 Therefore, the subject of the present invention is to provide a non-combustion heating type smoking article roll that does not cause discomfort in appearance that may be caused by heating.

為了解決上述課題,本發明者係著眼於:藉由具有白色部之捲紙,該白色部於加熱前具有特定的白色度且於加熱後具備特定範圍的變色區域,以使該不適的變色變得較不醒目。 In order to solve the above-mentioned problems, the present inventors focused on: using a roll paper with a white part that has a specific whiteness before heating and a specific range of discoloration area after heating, so as to make the uncomfortable discoloration and discoloration It's less eye-catching.

以紙漿為主材料之紙,當以一定以上的溫度來加熱時會焦化而變色為茶色系,其原因是紙漿或紙之構成成分因熱分解所造成之物理性現象,所以無法簡單地防止此變色。然而經發現,即使因焦化而產生變色,若可將紙原本的色彩及後續的之變色程度縮小為一定範圍內,則不容易被辨識成不適的焦黑感。 Paper made of pulp as the main material will scorch and change color to brown when heated at a certain temperature or higher. The reason is that the pulp or paper constituents are caused by physical phenomena caused by thermal decomposition, so this cannot be simply prevented. Discoloration. However, it has been found that even if the discoloration occurs due to scorching, if the original color of the paper and the subsequent discoloration can be reduced to a certain range, it is not easy to be recognized as an uncomfortable feeling of burnt black.

本發明人發現,以數學式來表示此視覺上可容許變色程度之色差變化的區域,且發現在將加熱前後之L*、a*、b*的各值代入於該數學式時會顯示特定的數值,並且使用加熱前具有特定白色度的白色部之紙作為捲紙,藉此可解決有關非燃燒加熱型吸煙物品所特有之不適的變色之問題。 The inventor found that the visually allowable color difference area of the degree of discoloration is expressed by a mathematical formula, and found that when the values of L*, a*, and b* before and after heating are substituted into the mathematical formula, the specific The value of, and the use of white paper with a specific whiteness before heating as the roll paper can solve the problem of discomfort and discoloration unique to non-combustion heating smoking articles.

具體而言,本發明人發現,若使用具有加熱前的ISO白色度為83%以上且加熱前後的色差小之白色部之紙,則可解決上述不適的變色之問題。 Specifically, the present inventors found that if a paper having a white portion with an ISO whiteness before heating of 83% or more and a small color difference before and after heating is used, the above-mentioned uncomfortable discoloration problem can be solved.

本發明之課題為被電加熱型裝置加熱之非燃燒加熱型吸煙物品所特有者,其係於先前的吸煙物品(香煙等)中不會產生之課題。 The subject of the present invention is a non-combustion heating type smoking article that is heated by an electric heating device, and it is a problem that does not occur in conventional smoking articles (cigarettes, etc.).

亦即,本發明係如以下所述。 That is, the present invention is as described below.

[1]一種非燃燒加熱型吸煙物品用捲紙,其具有白色部,該白色部之將以230℃加熱3分鐘前與後之CIELab表色系中的色差值代入於下式(1)所得到之判別分數顯示低於0.62之數值,且ISO白色度為83%以上者。 [1] A non-combustion heating type smoking article roll paper, which has a white part, the white part will be heated at 230 ℃ for 3 minutes before and after the color difference in the CIELab color system is substituted into the following formula (1) The obtained discriminant score shows a value lower than 0.62, and the ISO whiteness is 83% or more.

判別分數(y)y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1) Discriminant score (y) y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1)

(式(1)中,所謂加熱前與後之CIELab表色系中的色差值,為從加熱後的L*、a*、b*值減去加熱前的L*、a*、b*值後之值;△L*表示前述捲紙加熱後與加熱前之亮度L*的差,△a*表示前述捲紙加熱後與加熱前之色度a*的差,△b*表示前述捲紙加熱後與加熱前之色度b*的差) (In formula (1), the so-called color difference value in the CIELab color system before and after heating is the value of L*, a*, b* after heating minus L*, a*, b* before heating Value after the value; △L* represents the difference between the brightness L* of the aforementioned roll paper after heating and before heating, △a* represents the difference between the chromaticity a* of the aforementioned roll paper after heating and before heating, △b* represents the aforementioned roll (The difference between the chromaticity b* of the paper after heating and before heating)

[2]如[1]所述之非燃燒加熱型吸煙物品用捲紙,其中,前述非燃燒加熱型吸煙物品用捲紙含有填料,填料的含量為15至45重量%,前述非燃燒加熱型吸煙物品用捲紙的基重為25至45gsm,基重為25gsm以上35gsm以下時,填料為15至45重量%,基重超過35gsm且為45gsm以下時,填料為25至45重量%。 [2] The non-combustion heating type smoking article roll paper according to [1], wherein the non-combustion heating type smoking article roll paper contains a filler, and the content of the filler is 15 to 45% by weight, and the non-combustion heating type The basis weight of the smoking article roll paper is 25 to 45 gsm. When the basis weight is 25 gsm or more and 35 gsm or less, the filler is 15 to 45% by weight, and when the basis weight exceeds 35 gsm and is less than 45 gsm, the filler is 25 to 45% by weight.

[3]如[1]或[2]所述之非燃燒加熱型吸煙物品用捲紙,其中,拉伸強度為8N/15mm以上。 [3] The non-combustion heating type smoking article roll paper according to [1] or [2], wherein the tensile strength is 8N/15mm or more.

[4]如[2]或[3]所述之非燃燒加熱型吸煙物品用捲紙,其中,前述填料為碳酸鈣,前述捲紙的不透明度為60%以上。 [4] The non-combustion heating type smoking article roll paper according to [2] or [3], wherein the filler is calcium carbonate, and the opacity of the roll paper is 60% or more.

[5]如[1]至[4]中任一項所述之非燃燒加熱型吸煙物品用捲紙,其中,前述白色部的判別分數未達0。 [5] The non-combustion heating type smoking article roll paper according to any one of [1] to [4], wherein the discrimination score of the white part does not reach 0.

[6]如[1]至[5]所述之非燃燒加熱型吸煙物品用捲紙,其中,前述捲紙不含助燃劑。 [6] The non-combustion heating type smoking article roll paper described in [1] to [5], wherein the roll paper does not contain a combustion enhancer.

[7]一種非燃燒加熱型吸煙物品,係具有煙草桿部、及構成與該煙草桿部為相反側之端部之煙嘴部,該煙草桿部為包含煙草絲與霧氣(aerosol;又稱氣溶膠)生成基材之填充物經用以捲裝該填充物之第一捲紙所捲裝而成者;前述煙草桿部與前述煙嘴部係使用與捲裝前述填充物之捲紙為相同或不同的第二捲紙而連結,且第一捲紙及第二捲紙的至少一者為如[1]至[6]中任一項所述之非燃燒加熱型吸煙物品用捲紙。 [7] A non-combustion heating type smoking article, which has a tobacco stem and a mouthpiece that forms an end opposite to the tobacco stem. The tobacco stem contains tobacco shreds and mist (aerosol; also known as gas). Sol) The filler for generating the substrate is rolled by the first roll of paper used to wrap the filler; the tobacco rod and the mouthpiece are the same or the roll paper used for packaging the filler Different second paper rolls are connected, and at least one of the first paper roll and the second paper roll is the non-combustion heating type smoking article roll paper as described in any one of [1] to [6].

[8]一種電加熱型吸煙系統,係由電加熱型裝置、及以接觸於下述傳熱構件之方式嵌合之如[7]所述之非燃燒加熱型吸煙物品所構成,該電加熱型裝置係具備:加熱器構件、傳導來自該加熱器構件的熱之傳熱構件、成為該加熱器構件的電力源之電池單元、及用以控制該加熱器構件之控制單元。 [8] An electric heating type smoking system consisting of an electric heating type device and a non-combustion heating type smoking article as described in [7] fitted in contact with the following heat transfer member, the electric heating The type device includes a heater member, a heat transfer member that conducts heat from the heater member, a battery unit that becomes a power source of the heater member, and a control unit for controlling the heater member.

根據本發明,可提供一種不會產生可能因加熱而產生之外觀上的不適感之非燃燒加熱型吸煙物品用捲紙。 According to the present invention, it is possible to provide a non-combustion heating type smoking article roll paper which does not cause discomfort in appearance that may be caused by heating.

10‧‧‧非燃燒加熱型吸煙物品 10‧‧‧Non-combustion heating type smoking articles

11‧‧‧填充物 11‧‧‧Filling

12‧‧‧第一捲紙 12‧‧‧The first roll of paper

13‧‧‧第二捲紙(外層紙) 13‧‧‧The second roll of paper (outer paper)

14‧‧‧紙管部 14‧‧‧Paper Tube Department

15‧‧‧濾嘴部 15‧‧‧Filter

16‧‧‧煙嘴部 16‧‧‧Cigarette holder

17‧‧‧中空區段部 17‧‧‧Hollow section

20‧‧‧電加熱型裝置 20‧‧‧Electric heating device

21‧‧‧電池單元 21‧‧‧Battery unit

22‧‧‧控制單元 22‧‧‧Control Unit

23‧‧‧軀體 23‧‧‧Body

24‧‧‧加熱器構件 24‧‧‧Heater components

25‧‧‧傳熱構件 25‧‧‧Heat transfer components

30‧‧‧電加熱型吸煙系統 30‧‧‧Electric heating type smoking system

第1圖為顯示非燃燒加熱型吸煙物品的一樣態之概略圖。 Figure 1 is a schematic diagram showing the same state of a non-combustion heating type smoking article.

第2圖為顯示非燃燒加熱型吸煙物品的其他一樣態之概略圖。 Figure 2 is a schematic diagram showing other aspects of the non-combustion heating smoking article.

第3圖為顯示電加熱型吸煙系統的一樣態之概略圖。 Figure 3 is a schematic diagram showing the same state of the electrically heated smoking system.

第4圖A為顯示各紙樣本之加熱前後的△L*值與外觀印象之關係之圖。 Figure 4A is a graph showing the relationship between the △L* value before and after heating and the appearance impression of each paper sample.

第4圖B為顯示各紙樣本之加熱前後的△a*值與外觀印象之關係之圖。 Figure 4B is a graph showing the relationship between the Δa* value before and after heating and the appearance impression of each paper sample.

第4圖C為顯示各紙樣本之加熱前後的△b*值與外觀印象之關係之圖。 Figure 4C is a graph showing the relationship between the Δb* value before and after heating and the appearance impression of each paper sample.

第5圖為顯示使用加熱前後之各紙樣本的L*、a*、b*之△值與外觀印象之關係進行判別分析的結果之圖。 Figure 5 is a graph showing the results of discriminant analysis of the relationship between the △ value of L*, a*, b* and the appearance impression of each paper sample before and after heating.

第6圖為顯示加熱前後之各紙樣本的△a*值與△b*值之關係之圖。 Figure 6 is a graph showing the relationship between the △a* value and the △b* value of each paper sample before and after heating.

第7圖為對捲紙中之填料的含量與判別分數之關係依不同基重進行點繪(plot)而得之圖。 Figure 7 is a graph obtained by plotting the relationship between the filler content in the roll paper and the discriminant score according to different basis weights.

以下係表示實施形態及例示物等來詳細說明本發明,但本發明並不限定於以下實施形態及例示物等,在不脫離本發明的主旨之範圍內,可任意地變更而實施。 Hereinafter, the present invention will be explained in detail by showing embodiments and exemplified materials. However, the present invention is not limited to the following embodiments and exemplified materials, and can be implemented with arbitrarily changed without departing from the gist of the present invention.

〈非燃燒加熱型吸煙物品用捲紙〉 〈Roll paper for non-combustion heating type smoking articles〉

本說明書中,所謂「非燃燒加熱型吸煙物品用捲紙」為使用在後述非燃燒加熱型吸煙物品之捲紙。以下亦僅稱為本發明的實施形態之捲紙。對於本發明的實施形態之捲紙的用途,所謂「非燃燒加熱型吸煙物品用」意指使用於用以將包含煙草絲之填充物捲裝而製作煙草桿,或是為了連結與煙草桿鄰接之構件而使用於用以捲裝此等的外周面之情況。 In this manual, the "roll paper for non-combustion heating type smoking articles" refers to the roll paper used for non-combustion heating type smoking articles described later. Hereinafter, it is also only referred to as the roll paper of the embodiment of the present invention. Regarding the use of the roll paper of the embodiment of the present invention, the so-called "non-combustion heating type smoking article" means to be used to wrap fillers containing tobacco shreds to make tobacco rods, or to connect adjacent tobacco rods The component is used for the case of the outer peripheral surface of the package.

本發明的實施形態之捲紙係具有白色部,該白色部之以230℃加熱3分鐘前與後(亦僅稱為加熱前後)分別測定L*、a*、b*並將加熱前後之各值的差(將加熱後的值減去加熱前的值後之值)分別表視為△L*、△a*、△b*再將此等值代入於下式(1)所得到之y(判別分數)係具有小於0.62之值,並且ISO白色度為83%以上者。 The roll paper of the embodiment of the present invention has a white part. Before and after heating the white part at 230°C for 3 minutes (also referred to as before and after heating), respectively, L*, a*, b* are measured and each of the before and after heating The difference between the values (the value after heating minus the value before heating) is expressed as △L*, △a*, △b*, and then substituting these values into the following formula (1) to obtain y (Discrimination score) is a value less than 0.62, and the ISO whiteness is 83% or more.

判別分數(y)y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1) Discriminant score (y) y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1)

本發明的實施形態之捲紙若具有將△L*、△a*、△b*的各值代入於上述式(1)所得到之判別分數顯示小於0.62之值之白色部,則加熱前之L*、a*、b*的各值並無特別限制。 If the roll paper of the embodiment of the present invention has a white portion where the discriminant score obtained by substituting the values of △L*, △a*, and △b* into the above formula (1) shows a value less than 0.62, the value before heating The values of L*, a*, and b* are not particularly limited.

具有上述判別分數之白色部可存在於本發明的實施形態之捲紙的整面,或是可為至少存在於受熱之部分(藉由 後述電加熱型裝置所進行之加熱)之樣態。 The white part having the above-mentioned discrimination score may exist on the entire surface of the roll paper of the embodiment of the present invention, or may exist at least in the heated part (heated by an electric heating type device described later).

ISO白色度可藉由以下方法來求取。 ISO whiteness can be obtained by the following method.

依據JIS 8148:2001紙、紙板及紙漿之ISO白色度(擴散藍色光反射率)的測定方法,使用白色度/不透明度測定機(製造者:村上色彩技術研究所,型號:WMS-1)來測定。 According to JIS 8148:2001 ISO whiteness (diffuse blue light reflectance) measurement method of paper, paperboard and pulp, use whiteness/opacity measuring machine (manufacturer: Murakami Color Technology Research Institute, model: WMS-1) Determination.

上述白色部之加熱前的L*值較高者(較亮且色彩較淺者),有ISO白色度成為83%以上之傾向。一形態的捲紙中,白色部之加熱前的L*值可列舉出95%以上者。 The higher L* value of the white part before heating (brighter and lighter color) tends to be above 83% in ISO whiteness. In one form of roll paper, the L* value of the white part before heating can be listed as 95% or more.

如後述實施例所示,藉由上述式(1)所得到之y(判別分數)若小於0.62,則不會產生可能因加熱而產生之外觀上的不適感。藉由上述式(1)所得到之y(判別分數)未達0時,可更確實地包含不會在加熱前後損及外觀者。 As shown in the following examples, if the y (discrimination score) obtained by the above formula (1) is less than 0.62, there will be no discomfort in appearance that may be caused by heating. When the y (discrimination score) obtained by the above formula (1) is less than 0, it is possible to more reliably include those that do not impair the appearance before and after heating.

本發明的實施形態之捲紙中,加熱前後之L*、a*、b*的各值係對作為試樣之紙之白色部的5點進行測定,並採用其單純的平均值。測定對象為紙之白色部的任意點,但在紙上存在有商標等之文字或圖樣時,係以不存在該文字或商標之白色部的部分為對象。L*、a*、b*的各值可使用分光光度計來測定。 In the roll paper of the embodiment of the present invention, the values of L*, a*, and b* before and after heating are measured at 5 points of the white part of the paper as a sample, and their simple average values are used. The measurement target is an arbitrary point on the white part of the paper, but when there are characters or drawings such as a trademark on the paper, the part where the white part of the character or the trademark does not exist is the target. The values of L*, a*, and b* can be measured using a spectrophotometer.

具體而言可使用分光光度計(X-Rite公司製,品名SpectroEye)。測量係在光源D65、無光源濾片、視角2°的條件下,將1片試樣放置在ISO白色度92%的紙上並將分光光度計的測定部壓抵於其上方而實施。 Specifically, a spectrophotometer (manufactured by X-Rite, product name SpectroEye) can be used. The measurement was carried out under the conditions of light source D65, no light source filter, and viewing angle of 2°. One sample was placed on a paper with an ISO whiteness of 92% and the measurement part of the spectrophotometer was pressed against it.

用以得到具有藉由上述式(1)所得到之判別分數顯示小於0.62之值且ISO白色度為83%以上之白色部 之紙(亦稱為具有上述特性之紙)之手段並無特別限制,可使用一般所知的方法。當捲紙的整面具有判別分數顯示小於0.62之值且ISO白色度為83%以上之白色部時,藉由在製紙的階段中調整紙漿及填料的種類及含量,可製造該捲紙。具體可列舉出增加後述填料的含量或是極力避免使用有色材料的量。 There are no special restrictions on the means for obtaining paper with a white portion with a discriminant score obtained by the above formula (1) showing a value less than 0.62 and an ISO whiteness of 83% or more (also referred to as paper with the above characteristics) , You can use generally known methods. When the entire surface of the roll paper has a white portion with a discriminant score of less than 0.62 and an ISO whiteness of 83% or more, the roll paper can be manufactured by adjusting the types and contents of pulp and fillers in the papermaking stage. Specific examples include increasing the content of fillers described later or avoiding the use of colored materials.

另一方面,於捲紙的一部分,在不會損及加熱後的外觀印象之範圍內具有有色部時,例如藉由施以印刷,可賦予顯示期望的色相之有色部。印刷的方法並無特別限制,例如可列舉出凹版印刷及平版印刷。有色部是指ISO白色度未達83%之部分。 On the other hand, when a part of the roll paper has a colored portion within a range that does not impair the appearance impression after heating, for example, by applying printing, a colored portion showing a desired hue can be provided. The printing method is not particularly limited, and examples include gravure printing and offset printing. The colored part refers to the part where the ISO whiteness is less than 83%.

當藉由印刷將商標或部分性圖樣作為有色部附加於原紙時,並不將該印刷面(印刷處)當作藉由分光光度計所進行之測色的對象。此外,藉由印刷將有色部賦予至捲紙時,其面積的比率可列舉出10%以下,較佳為5%以下,尤佳為3%以下。相反而言,本發明的實施形態之捲紙中,上述白色部之面積的比率可列舉出90%以上,較佳為95%以上,尤佳為97%以上。另一方面,當賦予規則性圖樣作為有色部且於加熱前後不會對外觀印象造成影響時,白色部之面積的比率有時只要為50%以上即可。 When a trademark or partial pattern is attached to the base paper as a colored part by printing, the printing surface (printing place) is not regarded as the object of color measurement by a spectrophotometer. In addition, when the colored portion is applied to the roll paper by printing, the area ratio thereof may be 10% or less, preferably 5% or less, and particularly preferably 3% or less. On the contrary, in the roll paper of the embodiment of the present invention, the ratio of the area of the white part may be 90% or more, preferably 95% or more, and particularly preferably 97% or more. On the other hand, when a regular pattern is provided as a colored portion and does not affect the appearance impression before and after heating, the ratio of the area of the white portion may be 50% or more.

於捲紙的表面上,至少被加熱之部分(經電加熱型裝置受熱之部分)較佳係藉由上述式(1)所得到之判別分數小於0.62且ISO白色度為83%以上者。於捲紙的表面中,藉由使經後述電加熱型裝置受熱之部分具有上述特性,可防止 加熱後之外觀印象的惡化。 On the surface of the roll paper, at least the heated part (the part heated by the electric heating device) is preferably the one with the discriminant score obtained by the above formula (1) less than 0.62 and the ISO whiteness above 83%. On the surface of the roll paper, by making the portion heated by the electric heating type device described later have the above-mentioned characteristics, it is possible to prevent the deterioration of the appearance after heating.

本發明的實施形態之捲紙原紙的基重,例如通常為20gsm以上,較佳為25gsm以上。另一方面,基重通常為65gsm以下,較佳為50gsm以下,更佳為45gsm以下。基重與填料的含量之關係如後述。 The basis weight of the roll base paper of the embodiment of the present invention is, for example, usually 20 gsm or more, preferably 25 gsm or more. On the other hand, the basis weight is usually 65 gsm or less, preferably 50 gsm or less, and more preferably 45 gsm or less. The relationship between the basis weight and the filler content will be described later.

具有上述特性之捲紙的厚度並無特別限定,從剛性、透氣性以及製紙時的調整容易性之觀點來看,通常為10μm以上,較佳為20μm以上,尤佳為30μm以上,此外,通常為100μm以下,較佳為75μm以下,尤佳為50μm以下。 The thickness of the roll paper having the above characteristics is not particularly limited. From the viewpoints of rigidity, air permeability, and ease of adjustment during papermaking, it is usually 10 μm or more, preferably 20 μm or more, and particularly preferably 30 μm or more. In addition, usually It is 100 μm or less, preferably 75 μm or less, and particularly preferably 50 μm or less.

非燃燒加熱型吸煙物品用捲紙,該形狀可列舉出正方形或長方形。當被利用作為用以捲裝煙草絲(用以製作煙草桿)之捲紙時,其一邊的長度可列舉出約15至70mm,另一邊的長度可列舉出約15至26.5mm,另一邊之較佳的長度可列舉出24mm。 Non-combustion heating type smoking article roll paper, the shape can be a square or a rectangle. When used as a roll paper for rolling tobacco shreds (to make tobacco rods), the length of one side can be about 15 to 70 mm, the length of the other side can be about 15 to 26.5 mm, and the length of the other side is about 15 to 26.5 mm. A preferred length can be 24 mm.

如外層紙(tipping paper)般,在連結煙草桿及與煙草桿鄰接之其他構件進行捲裝時,一邊的長度可列舉出20至60mm,另一邊的長度可列舉出約15至26.5mm。 Like tipping paper, when the tobacco rod and other components adjacent to the tobacco rod are connected and packaged, the length of one side can be 20 to 60 mm, and the length of the other side can be about 15 to 26.5 mm.

具有上述特性之捲紙可列舉出以紙漿為主成分者。紙漿除了藉由針葉樹紙漿或闊葉樹紙漿等之木漿來抄製之外,亦可與亞麻紙漿、***紙漿、劍麻紙漿、蘆葦等之一般使用在吸煙物品用捲紙之非木漿混抄而製得。 The roll paper having the above-mentioned characteristics can be exemplified by pulp as the main component. In addition to making pulp from conifer pulp or hardwood pulp, it can also be made by mixing non-wood pulp with flax pulp, hemp pulp, sisal pulp, reed, etc., which are commonly used in smoking articles. have to.

紙漿的種類,可使用藉由硫酸鹽蒸解法、酸性或中性或鹼性亞硫酸鹽蒸解法、鈉鹽蒸解法等所得到之化學紙漿、碎木紙漿、化學碎木紙漿、熱機械紙漿等。 The types of pulp can be chemical pulp, wood pulp, chemical wood pulp, thermomechanical pulp, etc. obtained by kraft digestion, acid or neutral or alkaline sulfite digestion, sodium salt digestion, etc. .

在使用上述紙漿並藉由長網抄紙機、圓網抄紙機、圓短複合抄紙機等所進行之抄紙步驟中,係使質地達到一致而均一地製造捲紙。此外,可視需要添加上述濕潤紙力增強劑以將耐水性賦予至捲紙,或是添加上漿劑以調整捲紙的印刷程度。再者,可添加硫酸鋁、各種陰離子性、陽離子性、非離子性或兩性之良率提升劑、濾水性提升劑,以及紙力增強劑等抄紙用內添加輔助劑,以及染料、pH調整劑、消泡劑、間距控制劑,以及黏泥控制劑等之製紙用添加劑。 In the papermaking process using the above-mentioned pulp and by the Fourdrinier paper machine, the cylinder paper machine, the round and short composite paper machine, etc., the roll paper is made uniform and uniform in texture. In addition, the above-mentioned wet paper strength enhancer may be added as needed to impart water resistance to the roll paper, or a sizing agent may be added to adjust the printing degree of the roll paper. In addition, aluminum sulfate, various anionic, cationic, nonionic, or amphoteric yield enhancers, drainage enhancers, and paper strength enhancers can be added as internal additives for papermaking, as well as dyes and pH adjusters. , Antifoaming agent, spacing control agent, and slime control agent and other additives for paper making.

除了上述紙漿之外,本發明的實施形態之捲紙亦可含有填料。相對於本發明的實施形態之捲紙的全重量,填料的含量可列舉出10重量%以上且未達60重量%,較佳為15至45重量%。 In addition to the above-mentioned pulp, the roll paper of the embodiment of the present invention may also contain a filler. The content of the filler relative to the total weight of the roll paper of the embodiment of the present invention may be 10% by weight or more and less than 60% by weight, preferably 15 to 45% by weight.

本發明的實施形態之捲紙中,於較佳的基重範圍(25至45gsm)中,填料較佳為15至45重量%。 In the roll paper of the embodiment of the present invention, in the preferred basis weight range (25 to 45 gsm), the filler is preferably 15 to 45% by weight.

再者,基重為25gsm以上35gsm以下時,填料較佳為15至45重量%,基重超過35gsm且為45gsm以下時,填料較佳為25至45重量%。 Furthermore, when the basis weight is 25 gsm or more and 35 gsm or less, the filler is preferably 15 to 45% by weight, and when the basis weight exceeds 35 gsm and is less than 45 gsm, the filler is preferably 25 to 45% by weight.

填料可使用碳酸鈣、二氧化鈦、高嶺土等,從提高吸嚐味或白色度等觀點來看,較佳係使用碳酸鈣。 As the filler, calcium carbonate, titanium dioxide, kaolin, etc. can be used. From the viewpoint of improving the taste and whiteness, it is preferable to use calcium carbonate.

含有此填料之紙通常呈現白色系的明亮色彩,可恆久地保持白色。藉由大量地含有此填料,可將捲紙的ISO白色度設為83%。 Paper containing this filler usually presents a bright white color, which can be kept white for a long time. By containing a large amount of this filler, the ISO whiteness of the roll paper can be set to 83%.

本發明的實施形態之捲紙之藉由下述測定 法所測定之拉伸強度為8N/15mm以上者,從利用作為非燃燒加熱型吸煙物品的捲紙之實用上的觀點來看為佳。 The tensile strength of the roll paper of the embodiment of the present invention measured by the following measuring method is 8N/15mm or more, from the practical point of view of using the roll paper as a non-combustion heating type smoking article.

此拉伸強度可藉由減少填料的含量而提高。具體而言,藉由使填料的含量低於上述所例示之各基重的範圍內所示之填料的含量上限,可提高拉伸強度。 This tensile strength can be increased by reducing the filler content. Specifically, by making the content of the filler lower than the upper limit of the content of the filler shown in the ranges of the respective basis weights exemplified above, the tensile strength can be improved.

〈拉伸強度的測定法〉 <Measurement method of tensile strength>

依據P8113:2006(ISO1924-2:1994)紙及板紙-拉伸特性的試驗方法-第2部:依據定速拉伸法並使用東洋精機製作所公司製的Strograph E-L來測定。 According to P8113:2006 (ISO1924-2:1994) Paper and Board Paper-Test Method for Tensile Properties-Part 2: Measured according to the constant speed drawing method and using Strograph E-L manufactured by Toyo Seiki Seisakusho.

本發明的實施形態之捲紙之藉由下述測定法所測定之不透明度較佳為60%以上。不透明度可藉由增加捲紙中之填料的含量而提高。具體而言,藉由使填料的含量高於上述所例示之各基重的範圍內所示之填料的含量下限,可提高不透明度。 The opacity of the roll paper of the embodiment of the present invention measured by the following measurement method is preferably 60% or more. Opacity can be increased by increasing the filler content in the roll paper. Specifically, by making the content of the filler higher than the lower limit of the content of the filler shown in the range of each basis weight exemplified above, the opacity can be improved.

〈不透明度的測定法〉 <Measurement method of opacity>

不透明度為使用白色度/不透明度測定機(製造者:村上色彩技術研究所,型號:WMS-1)並依據ISO2471所測定之值。所謂不透明度,為藉由算出式:單一薄片視感反射率係數(R0)/固有視感反射率係數(R∞)×100(%)所算出之值。此算出式的固有視感反射率係數(R∞)為使用規定的反射率計與光源,在有效波長457nm、半值寬44nm之分光條件下進行測定時之白色度的固有反射率係數。 The opacity is a value measured in accordance with ISO2471 using a whiteness/opacity measuring machine (manufacturer: Murakami Color Technology Research Institute, model: WMS-1). The so-called opacity is the value calculated by the calculation formula: single sheet visual reflectance coefficient (R0)/intrinsic visual reflectance coefficient (R∞)×100(%). The intrinsic visual reflectance coefficient (R∞) of this calculation formula is the intrinsic reflectance coefficient of the whiteness when measured under the spectroscopic conditions with an effective wavelength of 457nm and a half-value width of 44nm using a predetermined reflectance meter and light source.

本發明的實施形態之捲紙中,為了滿足上述判別分數,較佳係不含先前煙草桿用捲紙所含有之助燃 劑。本發明的實施形態之捲紙可用作為後述非燃燒加熱型吸煙物品所使用之第一捲紙,或用作為第二捲紙。 In order to satisfy the above-mentioned discriminant score in the roll paper of the embodiment of the present invention, it is preferable that the combustion-supporting agent contained in the conventional tobacco rod roll paper is not included. The roll paper of the embodiment of the present invention can be used as the first roll paper used in the non-combustion heating type smoking article described later, or as the second roll paper.

〈非燃燒加熱型吸煙物品〉 <Non-combustion heating type smoking article>

本發明的實施形態之非燃燒加熱型吸煙物品,例如可列舉出具有第1圖的構成者。 Examples of the non-combustion heating type smoking article of the embodiment of the present invention include those having the configuration shown in Fig. 1.

第1圖的非燃燒加熱型吸煙物品10,具有:填充物11,由捲裝填充物11之第一捲紙12所構成之煙草桿部,以及構成與該煙草桿部為相反側之端部之煙嘴部16;前述煙草桿部與前述煙嘴部係使用與捲裝前述填充物之捲紙為相同或不同的其他第二捲紙13(第1圖中為外層紙)來連結。本發明的實施形態中,即使第一捲紙及第二捲紙分別僅由一片來構成,亦不會因加熱而燒毀。分別僅由一片來構成者,可降低成本。 The non-combustion heating type smoking article 10 of Figure 1 has: a filler 11, a tobacco rod formed by the first roll of paper 12 of the roll filler 11, and an end formed on the opposite side of the tobacco rod The mouthpiece part 16; the tobacco rod part and the mouthpiece part are connected by using another second roll paper 13 (the outer layer paper in the first figure) that is the same as or different from the roll paper that wraps the filler. In the embodiment of the present invention, even if the first roll paper and the second roll paper are each composed of only one sheet, they will not be burnt due to heating. If only one piece is used, the cost can be reduced.

第一捲紙及第二捲紙的至少一者為上述所說明之本發明的實施形態之捲紙。較佳係至少第一捲紙為本發明的實施形態之捲紙。此外,第一捲紙12及第二捲紙兩者為上述所說明之本發明的實施形態之捲紙者亦佳。 At least one of the first roll paper and the second roll paper is the roll paper of the embodiment of the present invention described above. Preferably, at least the first roll of paper is the roll of paper according to the embodiment of the present invention. In addition, it is also preferable that both the first roll paper 12 and the second roll paper are the roll papers of the embodiment of the present invention described above.

第1圖所示之樣態中,煙嘴部16具備紙管部14及濾嘴部15。此外,並具備外層紙13作為用以連結此等之第二捲紙。第1圖中,煙嘴部16是由2個區段所構成,但煙嘴部16亦可由單一區段所構成或是由3個以上的區段所構成。此外,構成煙嘴部之區段,可構成為包含紙管部與濾嘴部兩者或是僅由任一者所構成。 In the aspect shown in FIG. 1, the mouthpiece portion 16 includes a paper tube portion 14 and a filter portion 15. In addition, an outer layer paper 13 is provided as a second roll of paper for connecting these. In Figure 1, the mouthpiece portion 16 is composed of two segments, but the mouthpiece portion 16 may be composed of a single segment or be composed of three or more segments. In addition, the section constituting the mouthpiece portion may be constituted to include both the paper tube portion and the filter portion or to be constituted by only any one of them.

於第2圖中記載煙嘴部16由3個區段所構成者。第2圖的實施形態係於第1圖的紙管部14及濾嘴部15之間具有中空區段17。中空區段17是由具有1個或複數個中空通道之填充層及包覆填充層之栓塞包材所構成。關於填充層,例如可構成:以高密度填充有乙酸纖維素纖維,且相對於乙酸纖維素的重量添加含有三乙酸甘油酯之塑化劑6至20重量%並使其硬化而成之內徑為

Figure 107126504-A0202-12-0013-15
4.5至
Figure 107126504-A0202-12-0013-16
1.0mm的桿。由於填充層之纖維的填充密度高,所以於吸嚐時空氣或霧氣(aerosol)僅流通通道部,幾乎不流通填充層內。非燃燒加熱型吸煙物品中,在欲降低因濾嘴部15中之霧氣成分的過濾所導致之減少時,可縮短濾嘴部15的長度並以中空區段17來取代,此對於增大霧氣成分輸送量而言為有效。由於中空區段17內部的填充層為纖維填充層,所以於使用時從外側接觸的觸感比起紙管部14更接近於濾嘴部,因此帶給使用者的差異感較少。 In FIG. 2, it is described that the mouthpiece portion 16 is composed of three segments. The embodiment in FIG. 2 has a hollow section 17 between the paper tube portion 14 and the filter portion 15 in FIG. 1. The hollow section 17 is composed of a filling layer with one or more hollow channels and a plug packing material covering the filling layer. Regarding the filling layer, for example, it can be composed of a high density filled with cellulose acetate fibers, and an inner diameter formed by adding 6 to 20% by weight of a plasticizer containing triacetin relative to the weight of the cellulose acetate and hardening it. for
Figure 107126504-A0202-12-0013-15
4.5 to
Figure 107126504-A0202-12-0013-16
1.0mm rod. Due to the high packing density of the fibers in the packing layer, air or mist (aerosol) only flows through the channel portion during inhalation, and hardly circulates in the packing layer. In the non-combustion heating type smoking article, when it is desired to reduce the reduction caused by the filtration of the mist components in the filter portion 15, the length of the filter portion 15 can be shortened and replaced with a hollow section 17, which is useful for increasing the mist. It is effective in terms of component delivery amount. Since the filling layer inside the hollow section 17 is a fiber filling layer, the tactile touch from the outside during use is closer to the filter part than the paper tube part 14, so it brings less sense of difference to the user.

第1圖及第2圖所示之實施形態中,非燃燒加熱型吸煙物品10之長度方向的長度較佳為40mm至90mm,尤佳為50mm至75mm,更佳為50mm至60mm。此外,非燃燒加熱型吸煙物品的圓周較佳為15mm至25mm,尤佳為17mm至24mm,更佳為20mm至22mm。此外,第2圖所示之實施形態中,可列舉出煙草桿部的長度為20mm,紙管部的長度為20mm,中空區段部的長度為8mm,濾嘴部的長度為7mm之樣態,但此等個別的區段長度可因應製造適性、要求品質等來適當地變更。 In the embodiments shown in Figs. 1 and 2, the length of the non-combustion heating smoking article 10 in the longitudinal direction is preferably 40 mm to 90 mm, more preferably 50 mm to 75 mm, and more preferably 50 mm to 60 mm. In addition, the circumference of the non-combustion heating type smoking article is preferably 15 mm to 25 mm, more preferably 17 mm to 24 mm, and more preferably 20 mm to 22 mm. In addition, in the embodiment shown in Figure 2, the length of the tobacco stem portion is 20mm, the length of the paper tube portion is 20mm, the length of the hollow section portion is 8mm, and the length of the filter portion is 7mm. , But these individual section lengths can be changed appropriately according to manufacturing suitability and required quality.

藉由加熱前述煙草桿所產生之含有霧氣生成基材與煙草香味成分之蒸氣,會隨著通過紙管部14,與紙管內的空氣相互接觸而冷卻並液化而生成霧氣。 The vapor containing the mist generating substrate and tobacco flavor components generated by heating the tobacco rod will cool and liquefy to generate mist as it passes through the paper tube portion 14 and contacts the air in the paper tube.

此外,非燃燒加熱型吸煙物品10亦可於紙管部14與包覆紙管部14的周圍之第二捲紙13(外層紙)的一部分,具有用以從外部擷取空氣之微小孔(圖中未顯示)。藉由該微小孔的存在,於使用時可從外部使空氣流入於紙管部14的內部,使藉由加熱前述煙草桿所產生之含有霧氣生成基材與煙草香味成分之蒸氣與來自外部的空氣接觸而降低溫度進而液化,可更確實地生成霧氣。 In addition, the non-combustion heating type smoking article 10 may also have a part of the second roll paper 13 (outer paper) around the paper tube portion 14 and the coated paper tube portion 14 with tiny holes for extracting air from the outside ( Not shown in the figure). Due to the existence of these tiny holes, air can flow from the outside into the inside of the paper tube portion 14 during use, so that the steam containing the mist generating base material and the tobacco flavor components generated by heating the tobacco rod and the steam from the outside Contact with air reduces the temperature and liquefies, so that mist can be generated more reliably.

紙管部14例如可列舉出將厚紙加工為圓筒狀者。 Examples of the paper tube portion 14 include those processed into a cylindrical shape by thick paper.

濾嘴部15例如可列舉出使用乙酸酯絲束作為材料者。乙酸酯絲束的單絲纖度、總纖度並無特別限定。 For the filter part 15, for example, one using acetate tow as a material can be cited. The monofilament fineness and total fineness of the acetate tow are not particularly limited.

第1圖中,濾嘴部15是由單一區段所構成,但亦可由複數個區段所構成。由複數個區段所構成時,例如可列舉出於上游側配置中空的區段,且下游側(使用者的吸口端側)的區段為吸口剖面被乙酸酯絲束所填充之樣態。根據此樣態,可防止所生成之霧氣的無謂損失,同時可使非燃燒加熱型吸煙物品的外觀達到良好。 In Figure 1, the filter portion 15 is composed of a single segment, but it may also be composed of a plurality of segments. When composed of a plurality of segments, for example, a hollow segment is arranged on the upstream side, and the segment on the downstream side (user's mouth end side) is a state where the mouth section is filled with acetate tow . According to this aspect, the unnecessary loss of the generated mist can be prevented, and at the same time, the appearance of the non-combustion heating type smoking article can be improved.

此外,於濾嘴的製造時,可適當地設定透氣阻力的調整或添加物(一般所知的吸附劑或香料、香料保持材料等)的添加。 In addition, during the manufacture of the filter, the adjustment of the air permeability resistance or the addition of additives (commonly known adsorbents, fragrances, fragrance-retaining materials, etc.) can be appropriately set.

第二捲紙13(外層紙)的材料並無特別限制,可於一部分或全部使用本發明的實施形態之捲紙。第二捲紙13例如 可列舉出使用乙酸乙烯酯系的黏膠將上述煙草桿、紙管部14、濾嘴部15的周圍捲裝後加以固定之樣態。 The material of the second roll paper 13 (outer layer paper) is not particularly limited, and the roll paper according to the embodiment of the present invention can be used in part or all. For example, the second roll paper 13 may include a form in which the tobacco rod, the paper tube portion 14, and the filter portion 15 are wound and fixed using vinyl acetate-based glue.

煙草桿係含有煙草絲作為填充物11,該煙草絲的材料並無特別限定,可使用葉片(lamina)或主脈等之一般所知者。煙草桿中之填充物的含量範圍,於圓周22mm、長度20mm的煙草桿時,可列舉出200至400mg/桿,較佳為250至320mg/桿。填充物的水分含量可列舉出10至15重量%,較佳為11至13重量%。為此水分含量時,可抑制捲取滲出的產生,使煙草桿之製造時的捲取適性達到良好。 The tobacco rod system contains tobacco shreds as the filler 11, and the material of the tobacco shreds is not particularly limited, and generally known ones such as lamina or main vein can be used. The content range of the filler in the tobacco rod is 200 to 400 mg/bar, preferably 250 to 320 mg/bar for a tobacco rod with a circumference of 22 mm and a length of 20 mm. The water content of the filler may be 10 to 15% by weight, preferably 11 to 13% by weight. Therefore, when the moisture content is used, the occurrence of winding exudation can be suppressed, and the winding suitability during the manufacture of the tobacco rod can be improved.

對於用作為填充物之煙草絲的大小及其調製法並無特別限制。例如可使用將乾燥後的煙草葉切絲為寬0.8至1.2mm者。 There are no special restrictions on the size of the tobacco shreds used as fillers and the preparation method. For example, the tobacco leaf after drying can be shredded to a width of 0.8 to 1.2 mm.

此外,亦可使用:將乾燥後的煙草葉粉碎為平均粒徑約20至200μm並使其均一化,再對此進行薄片加工,並切絲為寬0.8至1.2mm者。 In addition, it can also be used: the dried tobacco leaves are crushed to an average particle diameter of about 20 to 200 μm and homogenized, and then processed into thin sheets, and shredded to a width of 0.8 to 1.2 mm.

再者,亦可不對經上述薄片加工者進行切絲而是經皺褶加工,以此作為填充物使用。 In addition, it is also possible to use crease processing instead of shredding the above-mentioned sheet processing, and use it as a filler.

填充物係包含生成霧氣煙之霧氣生成基材。該霧氣生成基材的種類並無特別限定,可因應用途而選擇來自各種天然物之萃取物質及/或此等的構成成分。霧氣生成基材可列舉出甘油、丙二醇、三乙酸甘油酯、1,3-丁二醇及此等之混合物。 The filler includes a mist generating base material that generates mist and smoke. The type of the mist generating substrate is not particularly limited, and extracts from various natural products and/or these constituent components can be selected according to the application. Examples of the mist generating substrate include glycerin, propylene glycol, glycerol triacetate, 1,3-butanediol, and mixtures thereof.

填充物中之霧氣生成基材的含量並無特別限定,從可 充分地生成霧氣且同時賦予良好的吸嚐味之觀點來看,通常為5重量%以上,較佳為10重量%以上,此外,通常為50重量%以下,較佳為20重量%以下。 The content of the mist generating substrate in the filler is not particularly limited. From the viewpoint of sufficient mist generation and good taste, it is usually 5% by weight or more, preferably 10% by weight or more. , Usually 50% by weight or less, preferably 20% by weight or less.

填充物亦可含有香料。該香料的種類並無特別限定,從可賦予良好的吸嚐味之觀點來看,可列舉出對甲氧基苯乙酮(Acetanisole)、苯乙酮、乙醯基吡嗪、2-乙醯基噻唑、紫花苜蓿萃取物(Alfalfa Extract)、戊醇、丁酸戊酯、反式大茴香腦(trans-Anethole)、大茴香油(Star Anise Oil)、蘋果汁、秘魯香精油(Peru Balsam Oil)、蜜蠟原精、苯甲醛、安息香精油(Benzoin Resinoid)、苯甲醇、苯甲酸苯甲酯、苯基乙酸苯甲酯、丙酸苯甲酯、2,3-丁烷二酮、2-丁醇、丁酸丁酯、丁酸、焦糖、小豆蔻油(Cardamon Oil)、刺槐豆原精(Carob absolute)、β-胡蘿蔔素、胡蘿蔔汁、左旋香旱芹酮(L-Carvone)、β-石竹烯(β-Caryophyllene)、桂皮油、雪松木油(Cedarwood oil)、芹菜籽油、甘菊油(Chamomile Oil)、桂皮醛(Cinnamaldehyde)、桂皮酸、桂皮醇、桂皮酸桂皮酯、香茅油、右旋左旋香茅醇、鼠尾草萃取物(Clary sage extract)、可可、咖啡、葡萄渣油(Cognac Oil)、胡荽子油(Coriander Oil)、茴香甲醛(Cuminaldehyde)、印蒿油(Davana Oil)、δ-癸內酯、γ-癸內酯、癸酸、蒔蘿油(Dill herb oil)、3,4-二甲基-1,2-環戊烷二酮、4,5-二甲基-3-羥基-2,5-二氫呋喃-2-酮、3,7-二甲基-6-辛烯酸、2,3-二甲基吡嗪、2,5-二甲基吡嗪、2,6-二甲基吡嗪、2-甲基丁酸乙酯、乙酸乙酯、丁酸乙酯、己酸乙酯、異戊酸乙酯、乳酸 乙酯、月桂酸乙酯、乙醯丙酸乙酯、乙基麥芽醇、辛酸乙酯、油酸乙酯、棕櫚酸乙酯、苯基乙酸乙酯、丙酸乙酯、硬脂酸乙酯、戊酸乙酯、乙基香蘭素、乙基香蘭素葡萄糖苷(Ethyl Vanillin Glucoside)、2-乙基-3,(5或6)-二甲基吡嗪、5-乙基-3-羥基-4-甲基-2(5H)-呋喃酮、2-乙基-3-甲基吡嗪、桉樹油(Eucalyptol)、葫蘆巴原精(Fenugreek absolute)、金雀花原精(Genet absolute)、龍膽根浸劑(Gentian root infusion)、香葉草醇(Geraniol)、乙酸香葉草酯、葡萄汁、癒創木酚(Guaiacol)、番石榴萃取物、γ-庚內酯、γ-己內酯、己酸、順式-3-己烯-1-醇、乙酸己酯、己醇、苯基乙酸己酯、蜂蜜、4-羥基-3-戊烯酸內酯、4-羥基-4-(3-羥基-1-丁烯基)-3,5,5-三甲基-2-環己烯-1-酮、4-(對羥基苯基)-2-丁酮、4-羥基十一烷酸鈉、不凋花(Immortelle)原精(Immortelle absolute)、β-紫羅酮(β-Ionone)、乙酸異戊酯、丁酸異戊酯、苯基乙酸異戊酯、乙酸異丁酯、苯基乙酸異丁酯、茉莉原精、可樂果酊劑(Kolanut tincture)、勞丹油、無萜檸檬油(Lemon oil terpeneless)、甘草萃取物、沉香醇(Linalool)、乙酸沉香酯、圓葉當歸根油(Lovage root oil)、麥芽醇、楓糖漿、薄荷醇、薄荷酮(Menthone)、左旋乙酸薄荷酯、對甲氧基苯甲醛、甲基-2-吡咯基酮、鄰胺苯甲酸甲酯、苯基乙酸甲酯、柳酸甲酯、4'-甲基苯乙酮、甲基環戊二酮、3-甲基戊酸、含羞草原精(Mimosa absolute)、糖蜜、肉豆蔻酸、橙花醇(Nerol)、橙花叔醇(Nerolidol)、γ-壬內酯、肉豆蔻油(Nutmeg Oil)、δ-辛內酯、辛醛(Octanal)、辛酸、橙 花油(Orange flower oil)、橙油、昌蒲根油(Orris Root Oil)、棕櫚酸、ω-十五內酯、辣薄荷油、巴拉圭苦橙葉油(Petitgrain Paraguay Oil)、苯乙醇、苯基乙酸苯乙酯、苯基乙酸、向日葵醛(Piperonal)、梅萃取物、丙烯基鄰乙氧苯酚(Propenylguaethol)、乙酸丙酯、3-丙基茚苯酞(3-Propylidenephthalide)、乾果李果汁、丙酮酸、葡萄乾萃取物、玫瑰油、萊姆酒、鼠尾草油、檀香油、綠薄荷油、蘇合香萃取物(Styrax absolute)、萬壽菊油(Marigold Oil)、茶餾出物、α-松油醇、乙酸萜烯酯、5,6,7,8-四氫喹喔啉、1,5,5,9-四甲基-13-氧雜環(8.3.0.0(4.9))十三烷、2,3,5,6-四甲基吡嗪、瑞香草油(Thyme Oil)、番茄萃取物、2-十三酮、檸檬酸三乙酯、4-(2,6,6-三甲基-1-環己烯基)2-丁烯-4-酮、2,6,6-三甲基-2-環己烯-1,4-二酮、4-(2,6,6-三甲基-1,3-環己二烯基)2-丁烯-4-酮、2,3,5-三甲基吡嗪、γ-十一內酯、γ-戊內酯、香草萃取物、香蘭素、藜蘆醛(Veratraldehyde)、紫羅蘭葉原精,特佳為薄荷醇。此外,此等香料可單獨使用1種或併用2種以上。 The filling may also contain fragrance. The type of fragrance is not particularly limited. From the viewpoint of imparting a good tasting taste, examples include p-methoxyacetophenone (Acetanisole), acetophenone, acetylpyrazine, and 2-acetyl pyrazine. Thiazole, Alfalfa Extract, Amyl Alcohol, Amyl Butyrate, Trans-Anethole, Star Anise Oil, Apple Juice, Peru Balsam Oil ), beeswax essence, benzaldehyde, benzoin essential oil (Benzoin Resinoid), benzyl alcohol, benzyl benzoate, benzyl phenylacetate, benzyl propionate, 2,3-butanedione, 2- Butanol, Butyl Butyrate, Butyric Acid, Caramel, Cardamon Oil, Carob absolute, β-Carotene, Carrot Juice, L-Carvone, β-Caryophyllene, Cinnamon Bark Oil, Cedarwood Oil, Celery Seed Oil, Chamomile Oil, Cinnamaldehyde, Cinnamic Acid, Cinnamyl Alcohol, Cinnamyl Cinnamate , Citronella oil, D-L-citronellol, Clary sage extract, Cocoa, Coffee, Cognac Oil, Coriander Oil, Cuminaldehyde, Artemisia annua Davana Oil, δ-decanolide, γ-decanolide, capric acid, Dill herb oil, 3,4-dimethyl-1,2-cyclopentanedione, 4, 5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one, 3,7-dimethyl-6-octenoic acid, 2,3-dimethylpyrazine, 2,5- Dimethylpyrazine, 2,6-Dimethylpyrazine, ethyl 2-methylbutyrate, ethyl acetate, ethyl butyrate, ethyl caproate, ethyl isovalerate, ethyl lactate, laurel Ethyl Acetate, Ethyl Acetate Propionate, Ethyl Maltol, Ethyl Caprylate, Ethyl Oleate, Ethyl Palmitate, Ethyl Phenylacetate, Ethyl Propionate, Ethyl Stearate, Valeric Acid Ethyl, ethyl vanillin, ethyl vanillin glucoside (Ethyl Vanillin Glucoside), 2-ethyl-3, (5 or 6)-dimethylpyrazine, 5-ethyl-3-hydroxy-4- Methyl-2(5H)-furanone, 2-ethyl-3-methylpyrazine, Eucalyptus oil (Eucalyptol), Fenugreek absolute, Genugreek absolute, Genet absolute, Gentian Root infusion (Gentian root infusion), geraniol (Geraniol), geraniol acetate, grape juice, guaiacol (Guaiacol ), guava extract, γ-heptanolide, γ-caprolactone, hexanoic acid, cis-3-hexen-1-ol, hexyl acetate, hexanol, phenylhexyl acetate, honey, 4 -Hydroxy-3-pentenoic acid lactone, 4-hydroxy-4-(3-hydroxy-1-butenyl)-3,5,5-trimethyl-2-cyclohexen-1-one, 4 -(P-hydroxyphenyl)-2-butanone, sodium 4-hydroxyundecanoate, Immortelle absolute, β-ionone, isoamyl acetate , Isoamyl butyrate, isoamyl phenylacetate, isobutyl acetate, isobutyl phenylacetate, jasmine essence, kolanut tincture (Kolanut tincture), labdan oil, lemon oil (Lemon oil) terpeneless), licorice extract, linalool (Linalool), linalyl acetate, Lovage root oil (Lovage root oil), maltol, maple syrup, menthol, menthone (Menthone), menthyl acetate, right Methoxybenzaldehyde, methyl-2-pyrrolyl ketone, methyl anthranilate, methyl phenylacetate, methyl salicylate, 4'-methylacetophenone, methylcyclopentadione, 3 -Methyl valeric acid, Mimosa absolute, molasses, myristic acid, nerol (Nerol), nerolidol, γ-nonanolactone, nutmeg oil, δ -Caprolactone, Octanal, Caprylic acid, Orange flower oil, Orange oil, Orris Root Oil, Palmitic acid, Omega-pentalactone, Peppermint oil, Paraguay Petitgrain Paraguay Oil, Phenyl Alcohol, Phenyl Ethyl Phenyl Acetate, Phenyl Acetic Acid, Piperonal, Plum Extract, Propenylguaethol, Propyl Acetate, 3- Propylidenephthalide (3-Propylidenephthalide), dried fruit plum juice, pyruvic acid, raisin extract, rose oil, lime wine, sage oil, sandalwood oil, spearmint oil, styrax absolute, 10,000 Marigold oil, tea distillate, α-terpineol, terpene acetate, 5,6,7,8-tetrahydroquinoxaline, 1,5,5,9-tetramethyl- 13-oxygen heterocycle (8.3.0.0(4.9)) tridecane, 2,3,5,6-tetramethylpyrazine, Thyme Oil, tomato extract, 2-tridecone, lemon Triethyl ester, 4-(2,6,6-trimethyl-1-cyclohexenyl)2-butene-4-one, 2,6,6-trimethyl-2-cyclohexene- 1,4-Dione, 4-(2,6,6-trimethyl-1,3-cyclohexadiene Base) 2-butene-4-one, 2,3,5-trimethylpyrazine, γ-undecanolide, γ-valerolactone, vanilla extract, vanillin, Veratraldehyde, Violet leaf extract, particularly preferably menthol. Moreover, these fragrances can be used individually by 1 type or in combination of 2 or more types.

填充物中之香料的含量並無特別限定,從賦予良好的吸嚐味之觀點來看,通常為10000ppm以上,較佳為20000ppm以上,尤佳為25000ppm以上,此外,通常為50000ppm以下,較佳為40000ppm以下,尤佳為33000ppm以下。 The content of the flavor in the filler is not particularly limited. From the viewpoint of imparting a good taste, it is usually 10,000 ppm or more, preferably 20,000 ppm or more, particularly preferably 25,000 ppm or more, and usually 50,000 ppm or less, preferably It is 40,000 ppm or less, and particularly preferably 33,000 ppm or less.

填充物的填充密度並無特別限定,從可確保非燃燒加熱型吸煙物品的性能並賦予良好的吸嚐味之觀 點來看,通常為250mg/cm3以上,較佳為320mg/cm3以上,此外,通常為520mg/cm3以下,較佳為420mg/cm3以下。 The filling density of the filler is not particularly limited. From the viewpoint of ensuring the performance of the non-combustion heating smoking article and imparting a good taste, it is usually 250 mg/cm 3 or more, preferably 320 mg/cm 3 or more. In addition, it is usually 520 mg/cm 3 or less, preferably 420 mg/cm 3 or less.

於本發明的實施形態之非燃燒加熱型吸煙物品的製造中,可使用上述本發明的實施形態之捲紙。具體而言,可使包含煙草絲與霧氣生成基材之填充物成形,然後使用本發明的實施形態之捲紙,將成形後之填充物捲裝而得到煙草桿。並且,藉由使用外層紙(或本發明的實施形態之捲紙)將該煙草桿與構成煙嘴部之構件捲裝,可得到非燃燒加熱型吸煙物品。捲裝時可使用一般所知的捲取裝置。 In the manufacture of the non-combustion heating type smoking article of the embodiment of the present invention, the roll paper of the embodiment of the present invention described above can be used. Specifically, a filler including tobacco shreds and a mist generating base material can be shaped, and then the shaped filler can be wound using the roll paper of the embodiment of the present invention to obtain a tobacco rod. In addition, by using the outer layer paper (or the roll paper of the embodiment of the present invention) to wrap the tobacco rod and the member constituting the mouthpiece portion, a non-combustion heating type smoking article can be obtained. The generally known winding device can be used for the package.

於非燃燒加熱型吸煙物品的製造時,藉由使用本發明的實施形態之捲紙作為煙草桿的捲紙及/或外層紙,可提供一種於使用後(加熱後)不會損及外觀印象之非燃燒加熱型吸煙物品。 In the manufacture of non-combustion heating smoking articles, by using the roll paper of the embodiment of the present invention as the roll paper and/or outer layer of the tobacco rod, it is possible to provide a method that does not impair the appearance impression after use (after heating) The non-combustion heating type smoking article.

本發明的一實施形態之非燃燒加熱型吸煙物品10係具備:填充物11、由捲紙12(本發明的實施形態之捲紙)所構成之煙草桿部、紙管部14及濾嘴部15、及用以連接此等之第二捲紙13。此外,非燃燒加熱型吸煙物品10亦可於紙管部14與包覆紙管部14的周圍之第二捲紙13的一部分,具有用以從外部擷取空氣之微小孔(圖中未顯示)。藉由該微小孔的存在,於使用時可從外部使空氣流入於紙管部14的內部,使藉由加熱前述煙草桿所產生之含有霧氣生成基材與煙草香味成分之蒸氣,與來自外部的空氣接觸而降低溫度進而液化,可更確實地生成霧氣。 A non-combustion heating type smoking article 10 according to an embodiment of the present invention is provided with a filler 11, a tobacco rod portion composed of a rolled paper 12 (rolled paper in an embodiment of the present invention), a paper tube portion 14 and a filter portion 15. And the second roll paper 13 used to connect these. In addition, the non-combustion heating smoking article 10 may also have a part of the second roll paper 13 around the paper tube portion 14 and the wrapped paper tube portion 14 with tiny holes for extracting air from the outside (not shown in the figure) ). Due to the existence of these tiny holes, air can flow from the outside into the inside of the paper tube portion 14 during use, so that the vapor containing the mist generating substrate and tobacco flavor components generated by heating the tobacco rod can be compared with the vapor from the outside. The air is contacted to lower the temperature and liquefy, and the mist can be generated more reliably.

〈電加熱型吸煙系統〉 〈Electric heating type smoking system〉

第3圖係圖示電加熱型吸煙系統的一樣態。電加熱型吸煙系統30係以使上述所說明之非燃燒加熱型吸煙物品10接觸於傳熱構件25之方式嵌裝而使用,該傳熱構件25係配置在電加熱型裝置20的內部且與加熱器24接觸者。 Figure 3 shows the same state of the electrically heated smoking system. The electric heating type smoking system 30 is embedded and used in such a way that the non-combustion heating type smoking article 10 described above is in contact with the heat transfer member 25, which is arranged inside the electric heating device 20 and is in contact with Heater 24 contacts.

電加熱型裝置20,例如於樹脂性之軀體23的內部具有電池單元21與控制單元22。 The electric heating device 20 has, for example, a battery unit 21 and a control unit 22 inside a resin body 23.

如上述般,非燃燒加熱型吸煙物品係具有:填充物11,由捲裝填充物11之第一捲紙12所構成之煙草桿部,以及構成與該煙草桿部為相反側之端部之煙嘴部16;前述煙草桿部與前述煙嘴部係使用與捲裝前述填充物之捲紙為相同或不同的其他第二捲紙來連結。非燃燒加熱型吸煙物品的煙嘴部16,如第1圖所示般可由紙管部14及濾嘴部15所構成,或是如第2圖所示般可於紙管部14及濾嘴部15之間具有由填充層17所構成之中空區段。 As described above, the non-combustion heating type smoking article has: a filler 11, a tobacco rod portion formed by the first roll of paper 12 of the roll filler 11, and an end portion that constitutes the opposite side of the tobacco rod portion. The mouthpiece part 16; the tobacco stem part and the mouthpiece part are connected by using another second paper that is the same as or different from the paper used to wrap the filler. The cigarette holder part 16 of the non-combustion heating smoking article may be composed of a paper tube part 14 and a filter part 15 as shown in Fig. 1, or may be formed in a paper tube part 14 and a filter part as shown in Fig. 2 There is a hollow section formed by the filling layer 17 between 15.

當將非燃燒加熱型吸煙物品嵌裝於電加熱型裝置時,該煙草桿的外周面,與由連接該煙草桿與紙管部14之第二捲紙(外層紙13)所構成之外周面的一部分,係與電加熱型裝置20內部的傳熱構件25接觸。 When the non-combustion heating type smoking article is embedded in the electric heating device, the outer peripheral surface of the tobacco rod and the outer peripheral surface formed by the second roll of paper (outer paper 13) connecting the tobacco rod and the paper tube portion 14 A part of it is in contact with the heat transfer member 25 inside the electric heating device 20.

電加熱型裝置20內部的加熱器24係藉由依據控制單元22所進行之控制而發熱。該熱經由傳熱構件25傳遞至非燃燒加熱型吸煙物品的煙草桿,而使煙草桿的填充物11所含有之霧氣生成基材與香味成分一同揮發。 The heater 24 inside the electric heating device 20 generates heat by the control performed by the control unit 22. The heat is transferred to the tobacco rod of the non-combustion heating smoking article via the heat transfer member 25, so that the mist generating base material contained in the filler 11 of the tobacco rod is volatilized together with the flavor components.

藉由依據加熱器構件24所進行之加熱,前述煙草桿被加熱至大致150至250℃為止。 By the heating performed by the heater member 24, the tobacco rod is heated to approximately 150 to 250°C.

在測定上述L*、a*、b*時,將捲紙的加熱溫度設為230℃並將其時間設為3分鐘乙事,係以使用本發明的實施形態之電加熱型吸煙系統為前提而設定者。 When measuring the above L*, a*, b*, the heating temperature of the roll paper is set to 230°C and the time is set to 3 minutes, and it is assumed that the electrically heated smoking system of the embodiment of the present invention is used. And the setter.

藉由加熱所產生之含有霧氣生成基材與香味成分之蒸氣,係藉由前述所說明之機制而於紙管部14的內部霧氣化,並通過非燃燒加熱型吸煙物品10的濾嘴部15而到達使用者的口腔內。 The vapor containing the mist generating base material and flavor components generated by heating is atomized inside the paper tube portion 14 by the mechanism described above, and passes through the filter portion 15 of the non-combustion heating smoking article 10 And reach the user's mouth.

[實施例] [Example]

以下藉由實施例來更具體說明本發明,惟本發明在未超出該主旨的情況下,並不限定於以下實施例之記載。 The following examples illustrate the present invention in more detail, but the present invention is not limited to the description of the following examples as long as it does not exceed the gist.

〈加熱前後之紙樣本的製備〉 <Preparation of paper samples before and after heating>

對於CIELab表色系中的亮度L*、色度a*、色度b*,製備具有各種數值之紙。作為有色紙,例如製備凹版印刷品、將未漂白紙漿抄製於白色的一般紙漿之混抄品、抄製有細微的煙草葉之煙草薄片等。作為完全未著色之紙樣本,係製備使用100%原生紙漿之一般外層紙與捲紙以作為對照。全部製備26種紙。 For the brightness L*, chromaticity a*, and chromaticity b* in the CIELab color system, papers with various values are prepared. As colored paper, for example, gravure printing is prepared, a mixture of unbleached pulp made from white general pulp, and a tobacco sheet made with fine tobacco leaves. As a completely uncolored paper sample, general outer layer paper and roll paper using 100% virgin pulp were prepared as a control. All 26 types of paper were prepared.

Figure 107126504-A0202-12-0022-1
Figure 107126504-A0202-12-0022-1

〈加熱條件〉 <Heating conditions>

將回熱爐(品名:Muffle Furnace F0410型,Yamato Scientific公司製)預先調整至230℃。開啟爐門並將紙樣本載置於家庭用鋁箔紙(材質:鋁箔厚度:11μm),然後放入於回熱爐內並關閉爐門。迅速進行前述動作(3秒以內)以將回熱爐內的溫度降低抑制在最低限度。在本實施例中的加熱條件(回熱爐溫度設定230℃、紙樣本加熱時間3分鐘)下,實際上紙的溫度,在關閉爐門後的最慢1分鐘後,係與回熱爐設定溫度相同樣為約230℃。此係使用色變色溫度試驗紙(Thermolabel 5E-170/Thermolabel 5E-210)(日油技研工業公司製)得到確認者。 The reheat furnace (product name: Muffle Furnace F0410 model, manufactured by Yamato Scientific) was adjusted to 230°C in advance. Open the furnace door and place the paper sample on household aluminum foil paper (material: aluminum foil thickness: 11μm), then put it in the reheat furnace and close the furnace door. Perform the aforementioned actions quickly (within 3 seconds) to minimize the temperature drop in the reheat furnace. Under the heating conditions in this embodiment (the temperature of the reheat furnace is set to 230°C, and the heating time of the paper sample is 3 minutes), the actual paper temperature is set at the slowest 1 minute after the furnace door is closed. The temperature phase is also about 230°C. This system has been confirmed by using color change temperature test paper (Thermolabel 5E-170/Thermolabel 5E-210) (manufactured by NOF Corporation).

〈色差測定〉 <Color difference measurement>

使用分光光度計(X-Rite公司製,品名SpectroEye)對加熱前後的各樣本測量色相。測量係在光源D65、無光源濾片、視角2°的條件下,將1片試樣放置在ISO白色度92%的紙上,並於其上方壓抵分光光度計的測定部而實施。 A spectrophotometer (manufactured by X-Rite, product name SpectroEye) was used to measure the hue of each sample before and after heating. The measurement was performed under the conditions of a light source D65, no light source filter, and a viewing angle of 2°. One sample was placed on a paper with an ISO whiteness of 92%, and the measurement section of the spectrophotometer was pressed above it.

測定係對5處重複進行並將平均值用於解析中。L*、a*、b*係直接測定而求取,而△L*、△a*、△b*係將加熱變色後的值減去加熱變色前的值來求取。 The measurement system was repeated for 5 locations and the average value was used in the analysis. L*, a*, and b* are obtained by direct measurement, and ΔL*, Δa*, and Δb* are obtained by subtracting the value after heating and discoloration from the value before heating and discoloration.

色調評估中有各種評估、分類系統,CIELab表色系為CIE(國際照明委員會)所訂定之表色系,並且為JIS Z 8781-4、ISO 11664-4的基礎。此表色系近似於人類的感覺而被普遍地使用,且係可將色調三維方式數值化之便利的 分類系。L*為代表亮度之軸,a*為代表藍至黃之軸,b*為代表藍綠至紅紫之軸,L*值愈高則愈亮,a*、b*愈接近於0,彩度愈低。例如,L*、a*、b*=100,0,0時為白,0,0,0時為黑。 There are various evaluation and classification systems in hue evaluation. The CIELab color system is the color system set by CIE (International Commission on Illumination) and is the basis of JIS Z 8781-4 and ISO 11664-4. This color system is similar to human perception and is widely used, and it is a convenient classification system that can digitize the color tone in a three-dimensional manner. L* is the axis representing brightness, a* is the axis representing blue to yellow, b* is the axis representing blue-green to red-violet, the higher the L* value, the brighter, the closer a* and b* are to 0, the chroma Lower. For example, L*, a*, b*=100,0,0 is white, and 0,0,0 is black.

〈官能評估〉 <Sensory Evaluation>

讓20位測試員每一位觀看加熱前後的紙樣本,並詢問從該色調所觀察之外觀的污損,當20位測試員中回答看起來污損而覺得不適之人數為11人以上時,將該樣本的外觀印象判定為×,未達11人時,將該樣本的外觀印象判定為○,並將此等結果使用在解析中。 Let each of 20 testers look at the paper samples before and after heating and ask about the stains observed from the hue. When the number of 20 testers who said they looked stained and felt uncomfortable was more than 11, The appearance impression of the sample was judged to be ×, and when there were less than 11 people, the appearance impression of the sample was judged to be ○, and these results were used in the analysis.

〈解析〉 <Analysis>

加熱前後的△L*、△a*、△b*值與外觀印象的優劣之間並未觀察到關聯性(第4圖A至第4圖C)。 No correlation was observed between the ΔL*, Δa*, and Δb* values before and after heating and the quality of the appearance impression (Figure 4A to Figure 4C).

由於無法從以色相單體之值的差所構成之單純圖式中來推測加熱後的紙之色調的優劣,故探討使用色差資料來進行判別分析之作法,進行判別分析,以瞭解複雜因素的關聯性。該結果可得到如以下般之將能夠以判別率96.2%的高機率來判定外觀印象之△L*、△a*、△b*值作為參數之函數。判別式的P值小於0.001,統計上為高度有效,一般而言,若判別率超過75%,則可使用在推測,故判別率為96.2%係意指幾乎可完全推測之水準。 Since it is impossible to infer the quality of the hue of the heated paper from the simple diagram formed by the difference in the value of the hue monomers, the method of discriminant analysis using the color difference data is explored, and the discriminant analysis is performed to understand the complex factors. Relevance. This result can be obtained as a function of the following parameters that can determine the appearance impression with a high probability of 96.2%. The P value of the discriminant is less than 0.001, which is statistically highly effective. Generally speaking, if the discriminant rate exceeds 75%, it can be used for estimation. Therefore, the discriminant rate of 96.2% means that the level can be almost completely estimated.

判別分數y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1) Discriminant score y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1)

判別分數為0.62以上:×(差) The discriminant score is 0.62 or more: × (bad)

判別分數未達0.62:○(良好) The discriminant score did not reach 0.62: ○ (good)

式(1)意指加熱後的外觀印象幾乎可藉由加熱前的紙樣本與加熱後的紙樣本之色差之△L*、△a*、△b*來決定,例如△L*愈低,△a*、△b*之值愈高,則判別分數上升。亦即該紙之加熱後的印象位於較差之方向。 Equation (1) means that the appearance impression after heating can almost be determined by the color difference between the paper sample before heating and the paper sample after heating △L*, △a*, △b*, for example, the lower the △L*, The higher the value of △a* and △b*, the higher the discrimination score. That is, the impression of the paper after heating is in a poor direction.

第5圖為彙總該結果之圖。 Figure 5 is a graph summarizing the results.

判別分析係使用Bell Curve公司製Excel統計Ver.2.15多變量解析的判別分析2群,並在以下的條件下進行分析。 The discriminant analysis is based on the discriminant analysis of two groups of multivariate analysis using Excel Statistics Ver.2.15 manufactured by Bell Curve, and the analysis is performed under the following conditions.

(1)增減法P值:投入0.2去除0.2 (1) P value of increase and decrease method: 0.2 investment and 0.2 removal (2)扣除線性結合之變數進行分析 (2) Analysis by deducting the linear combination of variables

第6圖係為了更詳細說明而表示此次調查之紙樣本的△a*與△b*之關係之圖。 Figure 6 is a diagram showing the relationship between △a* and △b* of the paper sample of this survey for more detailed explanation.

由於無法三維地明確表示,所以△L*之值簡便上以-10予以二值化,對於該值低於-10(變得較暗)者,以黑圓或粗字的×來表示。 Since it cannot be clearly expressed in three dimensions, the value of △L* is simply binarized with -10. For those whose value is lower than -10 (it becomes darker), it is expressed with a black circle or a thick ×.

評估中外觀印象差者以「×」來表示,△a*、△b*之值皆位於較高之處。此係意指因加熱而往紅紫或黃色或是此等混合之茶色方向大幅地變色,此外,亦相對大量地觀察到△L*較低者。亦即,此等樣本在視覺上為所謂的從淺焦色接近於濃焦色之樣本群,直覺上亦可理解為外觀印象差之群。 Those with poor appearance impression in the evaluation are indicated by "×", and the values of △a* and △b* are all located at higher places. This refers to a large change in color to red-purple, yellow, or a mixed brown color due to heating. In addition, relatively large amounts of those with lower ΔL* are also observed. In other words, these samples are visually a so-called group of samples with a light focus color close to a deep focus color, and intuitively can also be understood as a group with poor appearance impression.

此等樣本群中,於加熱前L*值相對較高且a*值、b* 值亦低,亦即大多為明亮且彩度低者。咸認此明亮且色相淺的樣本會因加熱而使茶色的變化變得明顯,導致外觀印象的惡化。 In these sample groups, the L* value before heating is relatively high and the a* value and b* value are also low, that is, most of them are bright and low chroma. It is believed that this bright and light hue sample will change the brown color obviously due to heating, resulting in the deterioration of the appearance impression.

相反的,對於外觀印象良好之「○」的樣本,△a*、△b*之值皆位於較低之處。此係意指因加熱而往藍或綠色或是此等混合之藍綠色方向大幅地變色,其中,即使△L*相對較低亦即亮度小且較暗,但亦觀看到為○者。此等樣本群與×的情形相反,於加熱前L*值相對較低且a*值與b*值亦高,亦即大多為偏暗且彩度高者。咸認此偏濃色相的樣本不易因加熱而使變化變得明顯,有利於維持外觀印象的良好。 On the contrary, for the samples with good appearance impression "○", the values of △a* and △b* are all located at a lower position. This means that the color is greatly changed to blue or green or the mixed blue-green direction due to heating. Among them, even if ΔL* is relatively low, that is, the brightness is small and dark, it is still observed as ○. These sample groups are contrary to the situation of ×, the L* value is relatively low and the a* value and b* value are also high before heating, that is, most of them are dark and high chroma. The samples with this denser hue are not easy to change significantly due to heating, which helps to maintain a good appearance impression.

當整體地觀看點繪時,於△a*為±20、△b*為±30的廣範圍內分布有點繪,所以可得知此實驗並非部分性,而是涵蓋形成各種色相的變化之樣本。 When viewing the stipple as a whole, the dots are distributed in a wide range of △a* of ±20 and △b* of ±30, so it can be seen that this experiment is not partial, but covers samples that form various hue changes. .

本發明中,係著眼於紙於加熱前後之色彩的變化程度,並將其區域以數值來掌握藉此規定出有效的範圍。 In the present invention, the color change degree of the paper before and after heating is focused on, and the area is grasped with numerical values to define the effective range.

原先以為,會容易想到對此參數化單純以加熱前的色相來規定區域,但在此次的統計性手法中,僅從非色差之加熱前之紙的L*、a*、b*之值中,並無法得到有用的數學式。咸認此仍因為色彩中所含有之顏料或染料等有色成分各自具有不同的熱分解行為,而使加熱後的變色程度亦因色成分的不同而有所不同之故。因此,不僅是紙原本的色彩,可藉由變色程度來正確地推測外觀印象之本發明的思考方式亦為合理。 I originally thought that it would be easy to think of this parameterization simply using the hue before heating to specify the area, but in this statistical method, only the values of L*, a*, and b* of the paper before heating without color difference In, no useful mathematical formula can be obtained. It is believed that this is still because the colored components such as pigments or dyes contained in the color have different thermal decomposition behaviors, and the degree of discoloration after heating is also different due to the different color components. Therefore, not only the original color of the paper, but also the way of thinking of the present invention that can accurately estimate the appearance impression based on the degree of discoloration is also reasonable.

而且,根據上述的試驗結果,可得知具有判別分數未達0.62的數值之紙,於加熱前後之變色的程度少,且相對於進行觀察之人不會賦予不適的印象。 Furthermore, according to the above-mentioned test results, it can be seen that paper with a discriminant score of less than 0.62 has a small degree of discoloration before and after heating, and does not give an impression of discomfort to the person performing the observation.

根據以上內容,進一步調製以下第2表所示之實驗例1至18所示之配方的捲紙。具體而言,實驗例1至18中,將基重與填料的含量變更如第1表所記載者。此等實驗例中,係使用木漿作為紙漿並使用碳酸鈣(白石工業公司製)作為填料。抄紙係以手抄來進行,方法則依據JIS P-8222「紙漿-試驗用手抄紙的調製方法」。此外,準備一般香煙用捲紙。實驗例1至18的捲紙中不含助燃劑,另一方面,一般香煙用捲紙中含有1.0重量%的助燃劑(檸檬酸鈉)。 Based on the above content, the paper rolls with the recipes shown in Experimental Examples 1 to 18 shown in Table 2 below were further prepared. Specifically, in Experimental Examples 1 to 18, the basis weight and filler content were changed as described in Table 1. In these experimental examples, wood pulp was used as pulp and calcium carbonate (manufactured by Shiraishi Kogyo Co., Ltd.) was used as filler. Papermaking is done by hand, and the method is based on JIS P-8222 "Pulp-Test Method for Preparing Handmade Paper". In addition, prepare rolling paper for general cigarettes. The papers of Experimental Examples 1 to 18 did not contain a combustion enhancer. On the other hand, a general cigarette paper contains 1.0% by weight of the combustion enhancer (sodium citrate).

對於此等捲紙,係將以230℃加熱3分鐘後之L*、a*、b*的各值減去加熱前預先測定之L*、a*、b*的各值,求取△值,然後將各值代入於算出上述判別分數之式中以求取判別分數。加熱的方式與上述樣本1至26相同。 For these paper rolls, the values of L*, a*, and b* after heating at 230°C for 3 minutes are subtracted from the values of L*, a*, and b* measured in advance before heating to obtain the delta value , And then substitute each value into the formula for calculating the above discriminant score to obtain the discriminant score. The heating method is the same as the above-mentioned samples 1 to 26.

此外,對於此等捲紙測定加熱前的ISO白色度。然後依據上述所說明之P8113:2006(ISO1924-2:1994),使用東洋精機製作所公司製的Strograph E-L作為測定裝置來測定拉伸強度。該結果如第2表所示。 In addition, the ISO whiteness before heating was measured for these roll papers. Then, in accordance with P8113:2006 (ISO1924-2:1994) described above, a Strograph E-L manufactured by Toyo Seiki Seisakusho Co., Ltd. was used as a measuring device to measure the tensile strength. The results are shown in Table 2.

Figure 107126504-A0202-12-0028-2
Figure 107126504-A0202-12-0028-2

從第2表的結果來看,加熱前的ISO白色度未達83%之實驗例1、7、13,其判別分數大於0.62,加熱後的外觀印象變差。另一方面,對於加熱前的ISO白色度為83%以上且基重與填料的含量為既定值者,雖然加熱前的色彩為白色,亦即L*值較高而被認為加熱後的外觀印象容易變差者,加熱後的外觀印象卻未受損。此外,含有助燃劑之一般香煙用捲紙的判別分數大於0.62,加熱後的外觀印象變差。此外,不論為何種基重,當填料的含量超過45重量%時,可觀察到捲紙的拉伸強度降低之傾向。此外,填料的含量過多之捲紙,煙草桿的高速捲取特性惡化。 Judging from the results in Table 2, in Experimental Examples 1, 7, and 13, in which the ISO whiteness before heating did not reach 83%, the discriminant score was greater than 0.62, and the appearance impression after heating was deteriorated. On the other hand, if the ISO whiteness before heating is 83% or more and the content of basis weight and filler is a predetermined value, although the color before heating is white, that is, the L* value is high and it is considered as the appearance impression after heating For those who are prone to deterioration, the appearance impression after heating is not impaired. In addition, the discriminant score of general cigarette paper containing a combustion enhancer is greater than 0.62, and the appearance impression after heating becomes poor. In addition, regardless of the basis weight, when the filler content exceeds 45% by weight, a tendency to decrease the tensile strength of the roll paper can be observed. In addition, the high-speed winding characteristics of the tobacco rod will deteriorate if the content of the filler is too high.

接著根據第2表的結果,依不同基重,於 橫軸點繪出填料的含量,於縱軸點繪出判別分數而製作圖式(第7圖)。從第7圖的結果來看,可觀察到基重愈小且填料的含量愈多時,判別分數有愈小之傾向。 Then, according to the results of Table 2, draw the filler content on the horizontal axis and the discriminant score on the vertical axis according to different basis weights to make a graph (Figure 7). From the results in Figure 7, it can be observed that the smaller the basis weight and the higher the filler content, the smaller the discriminative score tends to be.

接著對於第2表的結果,為了更容易了解填料的含量及基重與判別分數之關係,將第3表彙整如以下所示。 Next, for the results of the second table, in order to more easily understand the relationship between the filler content and basis weight and the discriminant score, the third table is summarized as shown below.

Figure 107126504-A0202-12-0029-4
Figure 107126504-A0202-12-0029-4

根據第7圖及第3表的記載,從外觀印象之觀點來看,可得知捲紙的基重為25gsm以上35gsm以下時,填料較佳為15至45重量%,基重超過35gsm且為45gsm以下時,填料較佳為25至45重量%。於上述各基重的範圍內,填料的含量為各下限值以下時,不透明度較小,使用作為捲紙時會有內容物的煙草絲被看透之傾向。此外,可得知即使基重及填料的含量位於上述範圍內,含有助燃劑者從外觀印象之觀點來看亦不佳。 According to the description in Figure 7 and Table 3, from the viewpoint of appearance impression, it can be known that when the basis weight of the roll paper is 25 gsm or more and 35 gsm or less, the filler is preferably 15 to 45% by weight, and the basis weight exceeds 35 gsm and is When 45 gsm or less, the filler is preferably 25 to 45% by weight. Within the ranges of the above-mentioned basis weights, when the filler content is below each lower limit, the opacity is small, and the tobacco shreds of the contents tend to be seen through when used as a roll paper. In addition, it can be seen that even if the basis weight and the content of the filler are within the above-mentioned ranges, those containing the combustion enhancer are not good from the viewpoint of appearance impression.

10‧‧‧非燃燒加熱型吸煙物品 10‧‧‧Non-combustion heating type smoking articles

11‧‧‧填充物 11‧‧‧Filling

12‧‧‧第一捲紙 12‧‧‧The first roll of paper

13‧‧‧第二捲紙(外層紙) 13‧‧‧The second roll of paper (outer paper)

14‧‧‧紙管部 14‧‧‧Paper Tube Department

15‧‧‧濾嘴部 15‧‧‧Filter

16‧‧‧煙嘴部 16‧‧‧Cigarette holder

Claims (8)

一種非燃燒加熱型吸煙物品用捲紙,其具有白色部,該白色部之將以230℃加熱3分鐘前與後之CIELab表色系中的色差值代入於下式(1)所得到之判別分數係顯示低於0.62之數值,且ISO白色度為83%以上,前述非燃燒加熱型吸煙物品用捲紙含有填料,填料的含量為15至45重量%,前述非燃燒加熱型吸煙物品用捲紙的基重為25至45gsm,判別分數(y)y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1)式(1)中,所謂加熱前與後之CIELab表色系中的色差值,為從加熱後的L*、a*、b*值減去加熱前的L*、a*、b*值後之值;△L*表示前述捲紙加熱後與加熱前之亮度L*的差,△a*表示前述捲紙加熱後與加熱前之色度a*的差,△b*表示前述捲紙加熱後與加熱前之色度b*的差。 A non-combustion heating type smoking article roll paper, which has a white part, the white part will be heated at 230 ℃ for 3 minutes before and after the color difference in the CIELab color system is substituted into the following formula (1) The discriminant score shows a value lower than 0.62, and the ISO whiteness is 83% or more. The aforementioned non-combustion heating type smoking article roll paper contains filler, and the content of the filler is 15 to 45% by weight. The aforementioned non-combustion heating type smoking article uses The basis weight of the roll paper is 25 to 45gsm, and the discrimination score (y) y=-0.18×△L*+0.08×△a*+0.13×△b*-2.36 (1) In formula (1), the so-called before heating and The color difference value in the CIELab color system is the value obtained by subtracting the L*, a*, b* values before heating from the L*, a*, b* values after heating; △L* represents the aforementioned volume The difference between the brightness L* of the paper after heating and before heating, △a* represents the difference between the chromaticity a* of the aforementioned roll paper after heating and before heating, △b* represents the chromaticity b* of the aforementioned roll paper after heating and before heating The difference. 如申請專利範圍第1項所述之非燃燒加熱型吸煙物品用捲紙,其中,前述非燃燒加熱型吸煙物品用捲紙的基重為25gsm以上35gsm以下時,填料的含量為15至45重量%,前述非燃燒加熱型吸煙物品用捲紙的基重超過35gsm且為45gsm以下時,填料的含量為25至45重量%。 The non-combustion heating type smoking article roll paper described in the first item of the scope of patent application, wherein, when the basis weight of the aforementioned non-combustion heating type smoking article roll paper is 25 gsm or more and 35 gsm or less, the filler content is 15 to 45 weight %, when the basis weight of the aforementioned non-combustion heating type smoking article roll paper exceeds 35 gsm and is 45 gsm or less, the filler content is 25 to 45% by weight. 如申請專利範圍第1或2項所述之非燃燒加熱型吸煙物品用捲紙,其中,拉伸強度為8N/15mm以上。 The non-combustion heating type smoking article roll paper described in item 1 or 2 of the scope of patent application has a tensile strength of 8N/15mm or more. 如申請專利範圍第1或2項所述之非燃燒加熱型吸煙物品用捲紙,其中,前述填料為碳酸鈣,前述捲紙的不透明度為60%以上。 The non-combustion heating type smoking article roll paper described in item 1 or 2 of the scope of patent application, wherein the filler is calcium carbonate, and the opacity of the roll paper is 60% or more. 如申請專利範圍第1或2項所述之非燃燒加熱型吸煙物品用捲紙,其中,前述白色部的判別分數未達0。 The non-combustion heating type smoking article roll paper described in item 1 or 2 of the scope of patent application, wherein the discrimination score of the white part does not reach 0. 如申請專利範圍第1或2項所述之非燃燒加熱型吸煙物品用捲紙,其中,前述捲紙不含助燃劑。 The non-combustion heating type smoking article roll paper described in item 1 or 2 of the scope of patent application, wherein the aforementioned roll paper does not contain a combustion-supporting agent. 一種非燃燒加熱型吸煙物品,係具有煙草桿部、及構成與該煙草桿部為相反側之端部之煙嘴部,該煙草桿部為包含煙草絲與霧氣生成基材之填充物經用以捲裝該填充物之第一捲紙所捲裝而成者;前述煙草桿部與前述煙嘴部係使用與捲裝前述填充物之捲紙為相同或不同的第二捲紙而連結,且第一捲紙及第二捲紙的至少一者為如申請專利範圍第1或2項所述之非燃燒加熱型吸煙物品用捲紙。 A non-combustion heating type smoking article is provided with a tobacco stem and a mouthpiece that forms an end on the opposite side of the tobacco stem. The tobacco stem is a filler containing tobacco shreds and a mist generating substrate. Rolled by the first roll of the filler; the tobacco stem and the mouthpiece are connected by using a second roll of paper that is the same or different from the roll of the filler, and the first At least one of the first roll of paper and the second roll of paper is the non-combustion heating type smoking article roll as described in item 1 or 2 of the scope of patent application. 一種電加熱型吸煙系統,係由電加熱型裝置、及以接觸於下述傳熱構件之方式嵌合之如申請專利範圍第7項所述之非燃燒加熱型吸煙物品所構成,該電加熱型裝置係具備:加熱器構件、傳導來自該加熱器構件的熱之傳熱構件、成為該加熱器構件的電力源之電池單元、及用以控制該加熱器構件之控制單元。 An electric heating type smoking system is composed of an electric heating type device and a non-combustion heating type smoking article as described in item 7 of the scope of patent application that is fitted in a manner of contacting the following heat transfer member. The electric heating The type device includes a heater member, a heat transfer member that conducts heat from the heater member, a battery unit that becomes a power source of the heater member, and a control unit for controlling the heater member.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013523094A (en) * 2010-03-26 2013-06-17 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム Smoking articles containing heat-resistant sheet material
CN106368069A (en) * 2016-10-19 2017-02-01 中烟摩迪(江门)纸业有限公司 Heating non-combustible cigarette paper and preparation method thereof
CN106998798A (en) * 2014-12-24 2017-08-01 菲利普莫里斯生产公司 Aerosol generation product including transparent pipe

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013523094A (en) * 2010-03-26 2013-06-17 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム Smoking articles containing heat-resistant sheet material
CN106998798A (en) * 2014-12-24 2017-08-01 菲利普莫里斯生产公司 Aerosol generation product including transparent pipe
CN106368069A (en) * 2016-10-19 2017-02-01 中烟摩迪(江门)纸业有限公司 Heating non-combustible cigarette paper and preparation method thereof

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