TWI695859B - 組成物、含有其之熱可塑性樹脂組成物及其成形品 - Google Patents
組成物、含有其之熱可塑性樹脂組成物及其成形品 Download PDFInfo
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- TWI695859B TWI695859B TW108131244A TW108131244A TWI695859B TW I695859 B TWI695859 B TW I695859B TW 108131244 A TW108131244 A TW 108131244A TW 108131244 A TW108131244 A TW 108131244A TW I695859 B TWI695859 B TW I695859B
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- ABTNKPAZMOYEAS-UHFFFAOYSA-N oxo-bis(prop-2-enoxy)phosphanium Chemical compound C=CCO[P+](=O)OCC=C ABTNKPAZMOYEAS-UHFFFAOYSA-N 0.000 description 1
- ACMVLJBSYFHILY-UHFFFAOYSA-N oxo-di(tridecoxy)phosphanium Chemical compound CCCCCCCCCCCCCO[P+](=O)OCCCCCCCCCCCCC ACMVLJBSYFHILY-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
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- MWFNQNPDUTULBC-UHFFFAOYSA-N phosphono dihydrogen phosphate;piperazine Chemical compound C1CNCCN1.OP(O)(=O)OP(O)(O)=O MWFNQNPDUTULBC-UHFFFAOYSA-N 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
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- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
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- 229910052623 talc Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000001017 thiazole dye Substances 0.000 description 1
- WXBXVVIUZANZAU-CMDGGOBGSA-N trans-2-decenoic acid Chemical compound CCCCCCC\C=C\C(O)=O WXBXVVIUZANZAU-CMDGGOBGSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- UWHZIFQPPBDJPM-BQYQJAHWSA-N trans-vaccenic acid Chemical compound CCCCCC\C=C\CCCCCCCCCC(O)=O UWHZIFQPPBDJPM-BQYQJAHWSA-N 0.000 description 1
- 239000001003 triarylmethane dye Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- MZHULIWXRDLGRR-UHFFFAOYSA-N tridecyl 3-(3-oxo-3-tridecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCC MZHULIWXRDLGRR-UHFFFAOYSA-N 0.000 description 1
- BWPNIANVWARHPR-UHFFFAOYSA-N tridecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCOP(O)O BWPNIANVWARHPR-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- CENHPXAQKISCGD-UHFFFAOYSA-N trioxathietane 4,4-dioxide Chemical compound O=S1(=O)OOO1 CENHPXAQKISCGD-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- DECPGQLXYYCNEZ-UHFFFAOYSA-N tris(6-methylheptyl) phosphite Chemical compound CC(C)CCCCCOP(OCCCCCC(C)C)OCCCCCC(C)C DECPGQLXYYCNEZ-UHFFFAOYSA-N 0.000 description 1
- QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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Abstract
提供可對熱可塑性樹脂賦予優良之透明性與物性的組成物、含有其之熱可塑性樹脂組成物及其成形品。
一種含有下述(A)~(D)之組成物,其中相對於(A)~(D)之合計量而言,各成分之比例為(A)35~75質量%、(B)10~40質量%、(C)0~20質量%、(D)5~35質量%,(A)係以通式(1)
表示,通式(1)中,R
1~R
4係各自獨立地表示氫原子等,R
5表示碳原子數1~4之亞烷基,m為1時,M
1表示鋰,m為2時,M
1為羥基鋁之芳香族磷酸酯金屬鹽,
(B)為羧酸鈉,(C)係以通式(2)
表示,通式(2)中,R
6為導入於碳原子數10~30之脂肪族有機酸之基,M
2表示n價金屬原子等,n為1~3之整數。
Description
本發明係關於組成物、含有其之熱可塑性樹脂組成物(以下亦僅稱為「樹脂組成物」)及其成形品,詳而言之,係關於可對熱可塑性樹脂賦予優良之透明性與物性的流動性優良之組成物、含有其之熱可塑性樹脂組成物及其成形品。
熱可塑性樹脂,特別是聚乙烯、聚丙烯及聚丁烯-1等之烯烴系樹脂,由於價格便宜,且成形加工性、衛生性、耐熱性、耐藥品性、力學特性、低比重等之優良性質,而廣為被利用於建材、汽車材料、家電機/電子用材料、纖維材料、包裝用資材、農業用資材、家電製品之外殼材料、生活雜貨用品、醫療器具、食品容器、飲料容器、薄膜、薄片及構造零件等之各種成形品。
但是,烯烴系樹脂由於成形後之結晶化速度慢,因此成形循環性低,又,由於加熱成形後之結晶化進行,而有生成大的結晶,透明性或強度不足之缺點。此等之缺點均為來自烯烴系樹脂之結晶性者,已知若能夠提高烯烴系樹脂之結晶化溫度,使微細的結晶急速地生成,則會解決上述問題。
因此,已知添加核劑,作為核劑,例如已知有苯甲酸鈉、4-tert-丁基苯甲酸鋁鹽、己二酸鈉及2鈉雙環[2.2.1]庚烷-2,3-二羧酸鹽等之羧酸金屬鹽;鈉雙(4-tert-丁基苯基)磷酸酯、鈉2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯、鋰-2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯等之環狀有機磷酸酯金屬鹽;二亞苄基山梨醇、雙(甲基亞苄基)山梨醇、雙(3,4-二甲基亞苄基)山梨醇、雙(p-乙基亞苄基)山梨醇,及雙(二甲基亞苄基)山梨醇等之多元醇衍生物;N,N’,N”-參[2-甲基環己基]-1,2,3-丙烷三羧醯胺、N,N’,N”-三環己基-1,3,5-苯三羧醯胺、N,N’-二環己基萘二羧醯胺、1,3,5-三(2,2-二甲基丙烷醯胺)苯等之醯胺化合物等。
此等化合物之中,尤已知環狀有機磷酸酯金屬鹽,作為烯烴系樹脂之透明性與物性的改良效果大之核劑。例如,專利文獻1中,提出有使結晶性合成樹脂含有環狀有機磷酸酯鹼性鋁鹽及硬脂酸鈉之樹脂組成物。又,專利文獻2中,提出有使結晶性合成樹脂含有環狀有機磷酸酯鹼性多價金屬鹽及鹼金屬羧酸鹽之樹脂組成物。
進一步地,專利文獻3中,係有核劑較佳為自2,2’-亞甲基-雙(4,6-二-tert-丁基苯氧基)磷酸酯鈉、二(4-tert-丁基-苯氧基)磷酸酯鈉、羥基雙[2,2-亞甲基雙(4,6-二-tert-丁基苯氧基)磷酸酯]鋁、雙(2-烷基、4-烷基苯氧基)磷酸酯、雙環[2,2,1]庚烷二羧酸鈉或雙環[2,2,1]庚烷二羧酸鈣當中一種以上之其中的二種以上之混合物的記載,且於實施例記載添加該核劑與苯甲酸鈉之樹脂組成物。又進一步,專利文獻4中,提出有混合了p-tert-丁基苯甲酸羥基鋁及/或苯甲酸鈉,與鋁羥基雙[2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯]的組成物。又,專利文獻5中,提出有含有取代二芳基磷酸之多價金屬鹽與一元脂肪酸之鹼金屬鹽的聚丙烯用透明化劑。
[先前技術文獻]
[專利文獻]
[專利文獻1]日本特開平8-120116號公報
[專利文獻2]日本特開平5-156078號公報
[專利文獻3]中國公開專利102344609號公報
[專利文獻4]中國公開專利101845171號公報
[專利文獻5]中國公開專利101265347號公報
[發明所欲解決之課題]
但是,專利文獻1、2中,雖記載鋁羥基雙[2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯]與硬脂酸鈉之組合,但此等核劑效果尚未充分,要求進一步改善。又,專利文獻3中,雖顯示改善潛變耐性,但並未對摻合鋁羥基雙[2,2-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯]進行評估,關於透明性與物性之評估並不充分。進一步地,專利文獻4中,雖記載摻合了苯甲酸鈉或苯甲酸鈉及p-tert-羥基苯甲酸羥基鋁,與鋁羥基雙[2,2-亞甲基雙(4,6-二-tert-丁基苯氧基)磷酸酯]之組成物,但其餘並未提及,又,未對摻合於樹脂中進行評估,故關於對透明性及物性之影響,尚有探討的餘地。又進一步,專利文獻5中,雖揭示含有鋁羥基雙[2,2-亞甲基雙(4,6-二-tert-丁基苯氧基)磷酸酯],與硬脂酸鈉或松香酸鈉等之羧酸鈉,及/或羥基硬脂酸鋰等之一元脂肪酸之鹼金屬鹽的樹脂組成物,但關於其效果,則尚未能夠滿足,要求進一步改善。
又,芳香族磷酸酯金屬鹽,係有缺乏作為粉體之流動性的缺點,就輸送性、作業性、計量性之觀點,係要求流動性的改善。
因而,本發明之目的,為提供可對熱可塑性樹脂賦予優良之透明性與物性的流動性優良之組成物、含有其之熱可塑性樹脂組成物及其成形品。
[用以解決課題之手段]
本發明者等為了解決上述課題而重複深入探討的結果,發現藉由將芳香族磷酸酯金屬鹽、羧酸鈉、脂肪酸金屬鹽及脂肪酸調整至特定範圍,可解決上述課題,而完成本發明。
亦即,本發明之組成物,為一種組成物,其係含有下述(A)、(B)、(C)及(D)之組成物,其特徵為相對於(A)+(B)+(C)+(D)之合計量而言,各成分之比例,為
(A)35~75質量%、
(B)10~40質量%、
(C)0~20質量%、
(D)5~35質量%;
(A)芳香族磷酸酯金屬鹽,其係以通式(1)表示,通式(1)中,R
1~R
4係各自獨立地表示氫原子或碳原子數1~9之直鏈或具有分支之烷基,R
5表示碳原子數1~4之亞烷基,m表示1或2之數,m為1時,M
1表示鋰,m為2時,M
1為羥基鋁;
(B)羧酸鈉;
(C)脂肪酸金屬鹽,其係以通式(2)表示,通式(2)中,R
6表示導入於碳原子數10~30之脂肪族有機酸之基,M
2表示n價金屬原子(惟,鈉原子及鈣原子除外)或Al(OH)
3-n,n為1~3之整數;
(D)脂肪酸。
又,本發明之組成物中,較佳含有選自由酚系抗氧化劑、磷系抗氧化劑、硫醚系抗氧化劑、其他抗氧化劑、受阻胺化合物、紫外線吸收劑、與通式(1)表示之構造相異之核劑、難燃劑、難燃助劑、潤滑劑、填充劑、水滑石類、脂肪酸金屬鹽、抗靜電劑、螢光增白劑、顏料、染料所成之群的1種以上之添加劑。進一步地,本發明之組成物中,前述(B)羧酸鈉,較佳為芳香族羧酸鈉或脂肪酸鈉。又進一步,本發明之組成物中,較佳為(A)35~55質量%、(B)20~40質量%、(C)5~20質量%、(D)5~35質量%。
本發明之熱可塑性樹脂組成物,其特徵為以相對於熱可塑性樹脂100質量份而言,通式(1)表示之芳香族磷酸酯金屬鹽(A)成為0.001~10質量份的方式,含有本發明之組成物。
本發明之熱可塑性樹脂組成物中,前述熱可塑性樹脂,係以烯烴系樹脂、特別是聚丙烯為佳。
本發明之成形品,其特徵為使用本發明之熱可塑性樹脂組成物而成。
[發明之效果]
依照本發明,可提供可對熱可塑性樹脂賦予優良之透明性與物性的流動性優良之組成物、含有其之熱可塑性樹脂組成物及其成形品。特別是對聚丙烯使用了本發明之組成物的本發明之成形品,不僅改善透明性或物性,且可提高衝擊強度,或抑制成形品之著色。
以下,詳細說明本發明之實施形態。
本發明之組成物,為含有下述(A)、(B)、(C)及(D)之組成物,相對於(A)+(B)+(C)+(D)之合計量而言,各成分之比例,為(A)35~75質量%、(B)10~40質量%、(C)0~20質量%、(D)5~35質量%。此處,(A)為下述通式(1)、
表示之芳香族磷酸酯金屬鹽,通式(1)中,R
1~R
4係各自獨立地表示氫原子或碳原子數1~9之直鏈或具有分支之烷基,R
5表示碳原子數1~4之亞烷基。m表示1或2之數,m為1時,M
1表示鋰,m為2時,M
1為羥基鋁之芳香族磷酸酯金屬鹽。又,(B)為羧酸鈉,(C)為通式(2)
表示之脂肪酸金屬鹽,通式(2)中,R
6表示導入於碳原子數10~30之脂肪族有機酸之基,M
2表示n價金屬原子(惟,鈉原子及鈣原子除外)或Al(OH)
3-n,n表示1~3之整數。進一步地,(D)為脂肪酸。
首先,說明(A)通式(1)表示之芳香族磷酸酯金屬鹽(以下亦稱為(A)成分)。通式(1)中,R
1~R
4係各自獨立地表示氫原子或直鏈或具有分支之碳原子數1~9之烷基,R
5表示碳原子數1~4之亞烷基,m表示1或2之數,m為1時,M
1表示鋰,m為2時,M
1表示羥基鋁。
通式(1)中之R
1~R
4表示之碳原子數1~9之直鏈或具有分支之烷基,例如可列舉甲基、乙基、丙基、異丙基、丁基、sec-丁基、tert-丁基、異丁基、戊基、tert-戊基、己基、庚基、辛基、異辛基、tert-辛基、2-乙基己基、壬基、異壬基等,本發明之組成物中,特佳為tert-丁基。
通式(1)中之R
5表示之碳原子數1~4之亞烷基,例如可列舉亞甲基、亞乙基、亞丙基、亞丁基等,本發明之組成物中,較佳為亞甲基。
本發明之組成物的(A)成分之製造方法,例如可列舉使對應構造之環狀磷酸,與鋁或鋰之氫氧化物、氧化物、鹵化物、硫酸鹽、硝酸鹽、烷氧化物化合物等之化合物,使用依需要使用的鹼性化合物等之反應劑來進行反應的方法,或使對應構造之芳香族磷酸酯之鹼金屬鹽,與鋁氫氧化物、鋁氧化物、鋁鹵化物、鋁硫酸鹽、鋁硝酸鹽、烷氧化鋁化合物等之鋁化合物,使用依需要使用的反應劑來進行鹽交換反應的方法、以環狀***為起始物質,藉由水解而生成環狀磷酸,並與金屬化合物反應的方法等。
(A)成分之具體例子,可列舉下述之化合物。惟,本發明之組成物不限定於此等化合物。
本發明之組成物中,(A)成分並不被粒子徑或粒度分布等之粒子狀態所限定,但已知粒子徑若為微細,則對樹脂中之分散性變佳,體積平均粒子徑較佳為100μm以下、更佳為30μm以下、又更佳為20μm以下。再者,體積平均粒子徑,係表示藉由雷射繞射/散射式粒度測定裝置(MicrotracBEL股份有限公司製Microtrac MT3000II),以體積加權的平均粒子徑。
本發明之組成物中,(A)成分之摻合量,相對於(A)成分~(D)成分之合計量而言,係35~75質量%、較佳為35~55質量%、更佳為38~50質量%之範圍。(A)成分未達35質量%,或超過75質量%時,不僅得不到本發明之效果,成形品之著色有變多的情況。
(A)成分對於熱可塑性樹脂之摻合量,相對於熱可塑性樹脂100質量份而言,係0.001~10質量份、更佳為0.006~5質量份。摻合量未達0.001質量份時,有得不到核劑效果的情況,超過10質量份時,對熱可塑性樹脂中之分散變得困難,有對成形品之物性或外觀造成不良影響的情況。
接著,說明(B)羧酸鈉(以下亦稱為(B)成分)。羧酸鈉(B)可列舉芳香族羧酸鈉及脂肪酸鈉。
芳香族羧酸,可列舉苯甲酸、tert-丁基苯甲酸、甲氧基苯甲酸、二甲氧基苯甲酸、三甲氧基苯甲酸、氯苯甲酸、二氯苯甲酸、三氯苯甲酸、乙醯氧基苯甲酸、聯苯羧酸、萘羧酸、蒽羧酸、呋喃羧酸、噻吩甲酸等。本發明之組成物中,係以苯甲酸、tert-丁基苯甲酸,由於本發明之效果顯著故較佳。
脂肪酸可列舉導入有碳原子數9~29之烷基、烯基、2個以上之不飽和鍵的脂肪酸,脂肪酸之氫原子可經羥基取代,亦可具有分支。脂肪酸之具體例子,可列舉癸酸、2-乙基己酸、十一酸、月桂酸、十三酸、肉豆蔻酸、十五酸、棕櫚酸、十七酸、硬脂酸、12-羥基硬脂酸、十九酸、花生酸、二十一酸、二十二酸、二十三酸、二十四酸、蟲蠟酸、二十八酸、蜜蠟酸等之飽和脂肪酸;4-癸烯酸、4-十二烯酸、棕櫚油酸、α-次亞麻油酸、亞麻油酸、γ-次亞麻油酸、硬脂四烯酸、芹子酸、油酸、反油酸、異油酸(vaccenic acid)、二十碳五烯酸、二十二碳五烯酸、二十二碳六烯酸等之直鏈不飽和脂肪酸等。本發明之組成物中,較佳為碳原子數10~21之脂肪酸、更佳為碳原子數12~18。特別以月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、12-羥基硬脂酸、油酸、亞麻油酸,由於本發明之效果顯著故特佳。
本發明之組成物中,(B)成分之摻合量,相對於(A)成分~(D)成分之合計量而言,係10~40質量%、較佳為15~40質量%、更佳為20~40質量%、又更佳為22~35質量%之範圍。(B)成分未達10質量%,或超過40質量%時,有得不到本發明之效果的情況。
其次,說明(C)通式(2)表示之脂肪酸金屬鹽(以下亦稱為(C)成分)。通式(2)中,R
6表示導入於碳原子數10~30之脂肪族有機酸之基,M
2表示n價金屬原子(惟,鈉原子及鈣原子除外)或Al(OH)
3-n,n為1~3之整數。M
2之n價金屬原子,可列舉鋰、鉀、鎂、鋇、鋅、鋁,本發明之組成物中,M
2較佳為鋰、鉀、鋅、鋁、羥基鋁;更佳為鋰、鉀、鋅。
通式(2)中,R
6表示之導入於碳原子數10~30之脂肪族有機酸之基,可列舉碳原子數9~29之烷基、烯基、導入有2個以上之不飽和鍵的烴基,烷基、烯基亦可具有分支,烴基之氫原子亦可經羥基取代。脂肪酸金屬鹽(C)之具體例子,可列舉於羧酸鈉所例示之脂肪酸之鋰鹽、鉀鹽、鎂鹽、鋇鹽、鋅鹽、鋁鹽、羥基鋁鹽。
本發明之組成物中,(C)成分之脂肪酸,較佳為碳原子數10~21之脂肪酸、更佳為碳原子數12~18。特別以月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、12-羥基硬脂酸、油酸、亞麻油酸,由於本發明之效果顯著故特佳。再者,本發明之組成物中,(C)成分可單獨使用一種化合物、亦可合併使用2種以上之化合物。
本發明之組成物中,(C)成分之摻合量,相對於(A)成分~(D)成分之合計量而言,係0~20質量%、較佳為5~20質量%、更佳為7~18質量%之範圍。超過20質量%時,有自成形品滲出的情況。
接著說明(D)脂肪酸(以下亦稱為(D)成分)。本發明之組成物中,脂肪酸(D)例如可列舉丁酸、戊酸、己酸、庚酸、辛酸、壬酸、2-乙基己基酸、癸酸、月桂酸、肉豆蔻酸、十五酸、棕櫚酸、十七酸、異硬脂酸、硬脂酸、12-羥基硬脂酸、花生酸、二十一酸、二十二酸、二十四酸、二十八酸等之等之飽和脂肪酸;巴豆酸、肉豆蔻油酸、棕櫚油酸、十六烯酸(sapienic acid)、油酸、反油酸、異油酸、鱈油酸、二十烯酸、芥子酸、二十四烯酸等之單不飽和脂肪酸;亞麻油酸、二十碳二烯酸、二十二碳二烯酸等之二不飽和脂肪酸;次亞麻油酸、松子油酸、油硬脂酸、米德酸(mead acid)、二十碳三烯酸、硬脂四烯酸、花生四烯酸、二十碳四烯酸、腎上腺酸、二十二碳六烯酸等之不飽和鍵為3以上之不飽和脂肪酸。
本發明之組成物中,較佳為碳原子數10~21之脂肪酸、更佳為碳原子數12~18。特別以肉豆蔻酸、棕櫚酸、硬脂酸,由於發明效果顯著故較佳。
本發明之組成物中,(D)成分之摻合量,相對於(A)成分~(D)成分之合計量而言,係(D)5~35質量%、較佳為7~28質量%之範圍內。未達5質量%時,有得不到本發明之效果的情況,超過35質量%時,有成形品之透明性降低、著色增加,或自成形品滲出的情況。
本發明之組成物,在不損及本發明之效果的範圍內,可使用其他添加劑。其他添加劑例如可列舉酚系抗氧化劑、磷系抗氧化劑、硫醚系抗氧化劑、其他抗氧化劑、受阻胺化合物、紫外線吸收劑、與通式(1)表示之構造相異之核劑、難燃劑、難燃助劑、潤滑劑、填充劑、水滑石類、抗靜電劑、螢光增白劑、顏料、染料等。其他添加劑之含量並無特殊限制,較佳為將本發明之組成物摻合於熱可塑性樹脂時,其他添加劑於熱可塑性樹脂中以適度的濃度存在之量。
酚系抗氧化劑,例如可列舉2,6-二-tert-丁基-4-乙基酚、2-tert-丁基-4,6-二甲基酚、苯乙烯化酚、2,2’-亞甲基雙(4-乙基-6-tert-丁基酚)、2,2’-硫雙-(6-tert-丁基-4-甲基酚)、2,2’-硫二伸乙基雙[3-(3,5-二-tert-丁基-4-羥基苯基)丙酸酯]、2-甲基-4,6-雙(辛基氫硫基甲基)酚、2,2’-異亞丁基雙(4,6-二甲基酚)、異辛基-3-(3,5-二-tert-丁基-4-羥基苯基)丙酸酯、N,N’-己烷-1,6-二基雙[3-(3,5-二-tert-丁基-4-羥基苯基)丙醯胺]、2,2’-草醯胺-雙[乙基-3-(3,5-二-tert-丁基-4-羥基苯基)丙酸酯]、2-乙基己基-3-(3’,5’-二-tert-丁基-4’-羥基苯基)丙酸酯、2,2’-伸乙基雙(4,6-二-tert-丁基酚)、3,5-二-tert-丁基-4-羥基-苯丙酸及C13-15烷基之酯、2,5-二-tert-戊基氫醌、受阻酚之聚合物(ADEKA POLYMER ADDITIVES EUROPE SAS公司製商品名「AO.OH.98」)、2,2’-亞甲基雙[6-(1-甲基環己基)-p-甲酚]、丙烯酸2-tert-丁基-6-(3-tert-丁基-2-羥基-5-甲基苄基)-4-甲基苯酯、丙烯酸2-[1-(2-羥基-3,5-二-tert-戊基苯基)乙基]-4,6-二-tert-戊基苯酯、6-[3-(3-tert-丁基-4-羥基-5-甲基)丙氧基]-2,4,8,10-四-tert-丁基苯并[d,f][1,3,2]-二氧雜磷雜庚英(dioxaphosphepin)、六亞甲基雙[3-(3,5-二-tert-丁基-4-羥基苯基)丙酸酯、雙[單乙基(3,5-二-tert-丁基-4-羥基苄基)膦酸酯]鈣鹽、5,7-雙(1,1-二甲基乙基)-3-羥基-2(3H)-苯并呋喃酮與o-二甲苯之反應生成物、2,6-二-tert-丁基-4-(4,6-雙(辛硫基)-1,3,5-三嗪-2-基胺基)酚、DL-a-生育酚(維生素E)、2,6-雙(α-甲基苄基)-4-甲基酚、雙[3,3-雙-(4’-羥基-3’-tert-丁基-苯基)丁酸]二醇酯、2,6-二-tert-丁基-p-甲酚、2,6-二苯基-4-十八烷氧基酚、硬脂基(3,5-二-tert-丁基-4-羥基苯基)丙酸酯、二硬脂基(3,5-二-tert-丁基-4-羥基苄基)膦酸酯、十三烷基-3,5-tert-丁基-4-羥基苄基硫乙酸酯、硫二伸乙基雙[(3,5-二-tert-丁基-4-羥基苯基)丙酸酯]、4,4’-硫雙(6-tert-丁基-m-甲酚)、2-辛硫基-4,6-二(3,5-二-tert-丁基-4-羥基苯氧基)-s-三嗪、2,2’-亞甲基雙(4-甲基-6-tert-丁基酚)、雙[3,3-雙(4-羥基-3-tert-丁基苯基)丁酸]二醇酯、4,4’-亞丁基雙(2,6-二-tert-丁基酚)、4,4’-亞丁基雙(6-tert-丁基-3-甲基酚)、2,2’-亞乙基雙(4,6-二-tert-丁基酚)、1,1,3-參(2-甲基-4-羥基-5-tert-丁基苯基)丁烷、雙[2-tert-丁基-4-甲基-6-(2-羥基-3-tert-丁基-5-甲基苄基)苯基]對苯二甲酸酯、1,3,5-參(2,6-二甲基-3-羥基-4-tert-丁基苄基)異三聚氰酸酯、1,3,5-參(3,5-二-tert-丁基-4-羥基苄基)異三聚氰酸酯、1,3,5-參(3,5-二-tert-丁基-4-羥基苄基)-2,4,6-三甲基苯、1,3,5-參[(3,5-二-tert-丁基-4-羥基苯基)丙醯氧基乙基]異三聚氰酸酯、肆[亞甲基-3-(3’,5’-tert-丁基-4’-羥基苯基)丙酸酯]甲烷、2-tert-丁基-4-甲基-6-(2-丙烯醯氧基-3-tert-丁基-5-甲基苄基)酚、3,9-雙[2-(3-tert-丁基-4-羥基-5-甲基氫桂皮醯氧基)-1,1-二甲基乙基]-2,4,8,10-四氧雜螺[5.5]十一烷、三乙二醇雙[β-(3-tert-丁基-4-羥基-5-甲基苯基)丙酸酯]、硬脂基-3-(3,5-二-tert-丁基-4-羥基苯基)丙酸醯胺、棕櫚基-3-(3,5-二-tert-丁基-4-羥基苯基)丙酸醯胺、肉豆蔻基-3-(3,5-二-tert-丁基-4-羥基苯基)丙酸醯胺、月桂基-3-(3,5-二-tert-丁基-4-羥基苯基)丙酸醯胺等之3-(3,5-二烷基-4-羥基苯基)丙酸衍生物等。摻合酚系抗氧化劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.001~5質量份、更佳為0.03~3質量份。
磷系抗氧化劑,例如可列舉亞磷酸三苯酯、亞磷酸二異辛酯、柒(二丙二醇)三亞磷酸酯、亞磷酸三異癸酯、亞磷酸二苯基異辛酯、亞磷酸二異辛基苯酯、亞磷酸二苯基十三烷酯、亞磷酸三異辛酯、亞磷酸三月桂酯、亞磷酸二苯酯、參(二丙二醇)亞磷酸酯、二油基氫亞磷酸酯、三月桂基三硫亞磷酸酯、雙(十三烷基)亞磷酸酯、參(異癸基)亞磷酸酯、參(十三烷基)亞磷酸酯、亞磷酸二苯基癸酯、二壬基苯基雙(壬基苯基)亞磷酸酯、聚(二丙二醇)苯基亞磷酸酯、四苯基二丙基二醇二亞磷酸酯、亞磷酸參壬基苯酯、參(2,4-二-tert-丁基苯基)亞磷酸酯、參(2,4-二-tert-丁基-5-甲基苯基)亞磷酸酯、參[2-tert-丁基-4-(3-tert-丁基-4-羥基-5-甲基苯硫基)-5-甲基苯基]亞磷酸酯、三(癸基)亞磷酸酯、亞磷酸辛基二苯酯、亞磷酸二(癸基)單苯酯、二硬脂基季戊四醇與硬脂酸鈣鹽之混合物、烷基(C10)雙酚A亞磷酸酯、四苯基-四(十三烷基)季戊四醇四亞磷酸酯、亞磷酸雙(2,4-二-tert-丁基-6-甲基苯基)乙酯、四(十三烷基)異亞丙基二酚二亞磷酸酯、四(十三烷基)-4,4’-n-亞丁基雙(2-tert-丁基-5-甲基酚)二亞磷酸酯、六(十三烷基)-1,1,3-參(2-甲基-4-羥基-5-tert-丁基苯基)丁烷三亞磷酸酯、肆(2,4-二-tert-丁基苯基)伸聯苯基二亞膦酸酯、9,10-二氫-9-氧雜-10-磷雜菲-10-氧化物、亞磷酸(1-甲基-1-丙烯基-3-亞基)參(1,1-二甲基乙基)-5-甲基-4,1-伸苯基)六-十三烷酯、亞磷酸2,2’-亞甲基雙(4,6-二-tert-丁基苯基)-2-乙基己酯、亞磷酸2,2’-亞甲基雙(4,6-二-tert-丁基苯基)-十八烷酯、2,2’-亞乙基雙(4,6-二-tert-丁基苯基)氟亞磷酸酯、4,4’-亞丁基雙(3-甲基-6-tert-丁基苯基二-十三烷基)亞磷酸酯、參(2-[(2,4,8,10-肆-tert-丁基二苯并[d,f][1,3,2]二氧雜磷雜庚英-6-基)氧基]乙基)胺、3,9-雙(4-壬基苯氧基)-2,4,8,10-四氧雜-3,9-二磷雜螺[5,5]十一烷、2,4,6-三-tert-丁基苯基-2-丁基-2-乙基-1,3-丙二醇亞磷酸酯、聚4,4’-異亞丙基二酚C12-15醇亞磷酸酯、雙(二異癸基)季戊四醇二亞磷酸酯、雙(十三烷基)季戊四醇二亞磷酸酯、雙(十八烷基)季戊四醇二亞磷酸酯、雙(壬基苯基)季戊四醇二亞磷酸酯、雙(2,4-二-tert-丁基苯基)季戊四醇二亞磷酸酯、雙(2,4,6-三-tert-丁基苯基)季戊四醇二亞磷酸酯、雙(2,6-二-tert-丁基-4-甲基苯基)季戊四醇二亞磷酸酯、雙(2,4-二異丙苯基苯基)季戊四醇二亞磷酸酯等。摻合磷系抗氧化劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.001~10質量份、更佳為0.01~0.5質量份。
硫醚系抗氧化劑,例如可列舉肆[亞甲基-3-(月桂硫基)丙酸酯]甲烷、雙(甲基-4-[3-n-烷基(C12/C14)硫基丙醯氧基]5-tert-丁基苯基)硫醚、二-十三烷基-3,3’-硫二丙酸酯、二月桂基-3,3’-硫二丙酸酯、二肉豆蔻基-3,3’-硫二丙酸酯、二硬脂基-3,3’-硫二丙酸酯、月桂基/硬脂基硫二丙酸酯、4,4’-硫雙(6-tert-丁基-m-甲酚)、2,2’-硫雙(6-tert-丁基-p-甲酚)、二硬脂基-二硫醚。摻合硫醚系抗氧化劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.001~10質量份、更佳為0.01~0.5質量份。
其他抗氧化劑,可列舉N-苄基-α-苯基硝酮、N-乙基-α-甲基硝酮、N-辛基-α-庚基硝酮、N-月桂基-α-十一烷基硝酮、N-十四烷基-α-十三烷基硝酮、N-十六烷基-α-十五烷基硝酮、N-辛基-α-十七烷基硝酮、N-十六烷基-α-十七烷基硝酮、N-十八烷基-α-十五烷基硝酮、N-十七烷基-α-十七烷基硝酮、N-十八烷基-α-十七烷基硝酮等之硝酮化合物、3-芳基苯并呋喃-2(3H)-酮、3-(烷氧基苯基)苯并呋喃-2-酮、3-(醯氧基苯基)苯并呋喃-2(3H)-酮、5,7-二-tert-丁基-3-(3,4-二甲基苯基)-苯并呋喃-2(3H)-酮、5,7-二-tert-丁基-3-(4-羥基苯基)-苯并呋喃-2(3H)-酮、5,7-二-tert-丁基-3-{4-(2-羥基乙氧基)苯基}-苯并呋喃-2(3H)-酮、6-(2-(4-(5,7-二-tert-2-側氧-2,3-二氫苯并呋喃-3-基)苯氧基)乙氧基)-6-側氧己基-6-((6-羥基己醯基)氧基)己酸酯、5-二-tert-丁基-3-(4-((15-羥基-3,6,9,13-四氧雜十五烷基)氧基)苯基)苯并呋喃-2(3H)酮等之苯并呋喃化合物等。摻合其他抗氧化劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳為0.001~20質量份、更佳為0.01~5質量份。
紫外線吸收劑,例如可列舉2,4-二羥基二苯甲酮、5,5’-亞甲基雙(2-羥基-4-甲氧基二苯甲酮)等之2-羥基二苯甲酮類;2-(2-羥基-5-甲基苯基)苯并***、2-(2-羥基-5-tert-辛基苯基)苯并***、2-(2-羥基-3,5-二-tert-丁基苯基)-5-氯苯并***、2-(2-羥基-3-tert-丁基-5-甲基苯基)-5-氯苯并***、2-(2-羥基-3,5-二異丙苯基苯基)苯并***、2,2’-亞甲基雙(4-tert-辛基-6-苯并***基酚)、2-(2-羥基-3-tert-丁基-5-羧基苯基)苯并***之聚乙二醇酯、2-[2-羥基-3-(2-丙烯醯氧基乙基)-5-甲基苯基]苯并***、2-[2-羥基-3-(2-甲基丙烯醯氧基乙基)-5-tert-丁基苯基]苯并***、2-[2-羥基-3-(2-甲基丙烯醯氧基乙基)-5-tert-辛基苯基]苯并***、2-[2-羥基-3-(2-甲基丙烯醯氧基乙基)-5-tert-丁基苯基]-5-氯苯并***、2-[2-羥基-5-(2-甲基丙烯醯氧基乙基)苯基]苯并***、2-[2-羥基-3-tert-丁基-5-(2-甲基丙烯醯氧基乙基)苯基]苯并***、2-[2-羥基-3-tert-戊基-5-(2-甲基丙烯醯氧基乙基)苯基]苯并***、2-[2-羥基-3-tert-丁基-5-(3-甲基丙烯醯氧基丙基)苯基]-5-氯苯并***、2-[2-羥基-4-(2-甲基丙烯醯氧基甲基)苯基]苯并***、2-[2-羥基-4-(3-甲基丙烯醯氧基-2-羥基丙基)苯基]苯并***、2-[2-羥基-4-(3-甲基丙烯醯氧基丙基)苯基]苯并***等之2-(2-羥基苯基)苯并***類;水楊酸苯酯、間苯二酚單苯甲酸酯、苯甲酸2,4-二-tert-丁基苯基-3,5-二-tert-丁基-4-羥酯、辛基(3,5-二-tert-丁基-4-羥基)苯甲酸酯、十二烷基(3,5-二-tert-丁基-4-羥基)苯甲酸酯、十四烷基(3,5-二-tert-丁基-4-羥基)苯甲酸酯、十六烷基(3,5-二-tert-丁基-4-羥基)苯甲酸酯、十八烷基(3,5-二-tert-丁基-4-羥基)苯甲酸酯、二十二烷基(3,5-二-tert-丁基-4-羥基)苯甲酸酯等之苯甲酸酯類;2-乙基-2’-乙氧基草醯苯胺、2-乙氧基-4’-十二烷基草醯苯胺等之取代草醯苯胺類;丙烯酸乙基-α-氰基-β,β-二苯酯、甲基-2-氰基-3-甲基-3-(p-甲氧基苯基)丙烯酸酯等之氰基丙烯酸酯類;2-(4,6-二苯基-1,3,5-三嗪-2-基)-5-己氧基酚、2-(2-羥基-4-辛氧基苯基)-4,6-雙(2,4-二甲基苯基)-1,3,5-三嗪、三辛基-2,2’,2”-((1,3,5-三嗪-2,4,6-三基)參(3-羥基苯-4-,1-二基)三丙酸酯)、2-(4,6-二苯基-1,3,5-三嗪-2-基)-5-[2-(2-乙基己醯基氧基)乙氧基]酚、2,4,6-參(2-羥基-4-己氧基-3-甲基苯基)-1,3,5-三嗪、1,12-雙[2-[4-(4,6-二苯基-1,3,5-三嗪-2-基)-3-羥基苯氧基]乙基]十二烷二酸酯等之三嗪類;各種金屬鹽,或金屬鉗合物、特別是鎳、鉻之鹽,或鉗合物類等。摻合紫外線吸收劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.001~10質量份、更佳為0.01~0.5質量份。
受阻胺化合物,例如可列舉硬脂酸2,2,6,6-四甲基-4-哌啶酯、硬脂酸1,2,2,6,6-五甲基-4-哌啶酯、苯甲酸2,2,6,6-四甲基-4-哌啶酯、雙(2,2,6,6-四甲基-4-哌啶基)癸二酸酯、肆(2,2,6,6-四甲基-4-哌啶基)-1,2,3,4-丁烷四羧酸酯、肆(1,2,2,6,6-五甲基-4-哌啶基)-1,2,3,4-丁烷四羧酸酯、雙(2,2,6,6-四甲基-4-哌啶基)・二(十三烷基)-1,2,3,4-丁烷四羧酸酯、雙(1,2,2,6,6-五甲基-4-哌啶基)-二(十三烷基)-1,2,3,4-丁烷四羧酸酯、雙(1,2,2,4,4-五甲基-4-哌啶基)-2-丁基-2-(3,5-二-tert-丁基-4-羥基苄基)丙二酸酯、1-(2-羥基乙基)-2,2,6,6-四甲基-4-哌啶醇/琥珀酸二乙酯聚縮合物、1,6-雙(2,2,6,6-四甲基-4-哌啶基胺基)己烷/2,4-二氯-6-嗎啉基-s-三嗪聚縮合物、1,6-雙(2,2,6,6-四甲基-4-哌啶基胺基)己烷/2,4-二氯-6-tert-辛基胺基-s-三嗪聚縮合物、1,5,8,12-肆[2,4-雙(N-丁基-N-(2,2,6,6-四甲基-4-哌啶基)胺基)-s-三嗪-6-基]-1,5,8,12-四氮雜十二烷、1,5,8,12-肆[2,4-雙(N-丁基-N-(1,2,2,6,6-五甲基-4-哌啶基)胺基)-s-三嗪-6-基]-1,5,8-12-四氮雜十二烷、1,6,11-參[2,4-雙(N-丁基-N-(2,2,6,6-四甲基-4-哌啶基)胺基)-s-三嗪-6-基]胺基十一烷、1,6,11-參[2,4-雙(N-丁基-N-(1,2,2,6,6-五甲基-4-哌啶基)胺基)-s-三嗪-6-基]胺基十一烷、雙{4-(1-辛氧基-2,2,6,6-四甲基)哌啶基}癸二酸酯、雙{4-(2,2,6,6-四甲基-1-十一烷氧基)哌啶基)碳酸酯等。摻合受阻胺化合物時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.001~10質量份、更佳為0.01~0.5質量份。
與通式(1)表示之構造相異之核劑,例如可列舉苯甲酸鈉、4-tert-丁基苯甲酸鋁鹽、己二酸鈉及2鈉雙環[2.2.1]庚烷-2,3-二羧酸鹽等之羧酸金屬鹽;二亞苄基山梨醇、雙(甲基亞苄基)山梨醇、雙(3,4-二甲基亞苄基)山梨醇、雙(p-乙基亞苄基)山梨醇,及雙(二甲基亞苄基)山梨醇等之多元醇衍生物;N,N’,N”-參[2-甲基環己基]-1,2,3-丙烷三羧醯胺、N,N’,N”-三環己基-1,3,5-苯三羧醯胺、N,N’-二環己基萘二羧醯胺、1,3,5-三(二甲基異丙基胺基)苯等之醯胺化合物等。摻合與通式(1)表示之構造相異之核劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.03~10質量份、更佳為0.05~0.5質量份。
難燃劑例如可列舉磷酸三苯酯、磷酸三甲苯酚酯、磷酸三-二甲苯酯、磷酸甲苯酚基二苯酯、磷酸甲苯酚基-2,6-二-二甲苯酯、間苯二酚雙(二苯基磷酸酯)、(1-甲基亞乙基)-4,1-伸苯基四苯基二磷酸酯、1,3-伸苯基肆(2,6-二甲基苯基)磷酸酯、ADEKA股份有限公司製商品名「Adeka Stab FP-500」、「Adeka Stab FP-600」、「Adeka Stab FP-800」之芳香族磷酸酯;苯基膦酸二乙烯酯、苯基膦酸二烯丙酯、苯基膦酸(1-丁烯基)等之膦酸酯;二苯基次磷酸苯酯、二苯基次磷酸甲酯、9,10-二氫-9-氧雜-10-磷雜菲-10-氧化物衍生物等之次磷酸酯;雙(2-烯丙基苯氧基)磷腈、二甲苯酚基磷腈等之磷腈化合物;磷酸三聚氰胺、焦磷酸三聚氰胺、多磷酸三聚氰胺、多磷酸蜜白胺、多磷酸銨、磷酸哌嗪、焦磷酸哌嗪、多磷酸哌嗪、含有磷之乙烯基苄基化合物及紅磷等之磷系難燃劑;氫氧化鎂、氫氧化鋁等之金屬氫氧化物;溴化雙酚A型環氧樹脂、溴化酚酚醛清漆型環氧樹脂、六溴苯、五溴甲苯、伸乙基雙(五溴苯基)、伸乙基雙四溴鄰苯二甲醯亞胺、1,2-二溴-4-(1,2-二溴乙基)環己烷、四溴環辛烷、六溴環十二烷、雙(三溴苯氧基)乙烷、溴化聚苯醚、溴化聚苯乙烯及2,4,6-參(三溴苯氧基)-1,3,5-三嗪、三溴苯基馬來醯亞胺、丙烯酸三溴苯酯、甲基丙烯酸三溴苯酯、四溴雙酚A型二甲基丙烯酸酯、丙烯酸五溴苄酯,及溴化苯乙烯等之溴系難燃劑等。此等難燃劑較佳與氟樹脂等之滴落防止劑或多元醇、水滑石等之難燃助劑合併使用。摻合難燃劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為1~100質量份、更佳為10~70質量份。
潤滑劑係以對成形品表面賦予潤滑性,提高損傷防止效果為目的而添加。潤滑劑例如可列舉油酸醯胺、芥子酸醯胺等之不飽和脂肪酸醯胺;二十二酸醯胺、硬脂酸醯胺等之飽和脂肪酸醯胺;硬脂酸丁酯、硬脂醇、硬脂酸單甘油酯、山梨醇酐單棕櫚酸酯、山梨醇酐單硬脂酸酯、甘露醇、硬脂酸、硬化蓖麻油、硬脂酸醯胺、油酸醯胺、伸乙基雙硬脂酸醯胺等。此等可1種單獨使用、亦可合併使用2種以上。摻合潤滑劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.01~2質量份、更佳為0.03~0.5質量份。
填充劑例如可列舉滑石、雲母、碳酸鈣、氧化鈣、氫氧化鈣、碳酸鎂、氫氧化鎂、氧化鎂、硫酸鎂、氫氧化鋁、硫酸鋇、玻璃粉末、玻璃纖維、黏土、白雲石、雲母、二氧化矽、氧化鋁、鈦酸鉀鬚晶、矽灰石、纖維狀硫氧鎂(fibrous magnesium oxysulfate)等,可適當選擇粒子徑(纖維狀時係纖維徑或纖維長及長寬比)來使用。又,填充劑可使用依需要而經表面處理者。摻合填充劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳為0.01~80質量份、更佳為1~50質量份。
水滑石類為作為天然物或合成物已知的含有鎂、鋁、羥基、碳酸基及任意之結晶水的複合鹽化合物,可列舉鎂或鋁之一部分經鹼金屬或鋅等其他金屬取代者或羥基、碳酸基經其他陰離子基取代者,具體而言,例如可列舉下述通式(4)表示之水滑石之金屬取代為鹼金屬者。又,Al-Li系之水滑石類,亦可使用下述通式(5)表示之化合物。
又,此等水滑石類中之碳酸陰離子,一部分亦可經其他陰離子取代。
水滑石類亦可為結晶水經脫水者,亦可為經硬脂酸等之高級脂肪酸、油酸鹼金屬鹽等之高級脂肪酸金屬鹽、十二烷基苯磺酸鹼金屬鹽等之有機磺酸金屬鹽、高級脂肪酸醯胺、高級脂肪酸酯或蠟等被覆者。
水滑石類可為天然物、又亦可為合成品。此等水滑石類之合成方法,可列舉日本特公昭46-2280號公報、日本特公昭50-30039號公報、日本特公昭51-29129號公報、日本特公平3-36839號公報、日本特開昭61-174270號公報、日本特開平5-179052號公報等記載之公知方法。又,此等水滑石類,可不限制於其結晶構造、結晶粒子等地使用。摻合水滑石類時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.001~5質量份、更佳為0.01~3質量份。
抗靜電劑例如可列舉脂肪酸四級銨離子鹽、多胺四級鹽等之陽離子系抗靜電劑;高級醇磷酸酯鹽、高級醇EO加成物、聚乙二醇脂肪酸酯、陰離子型之烷基磺酸鹽、高級醇硫酸酯鹽、高級醇環氧乙烷加成物硫酸酯鹽、高級醇環氧乙烷加成物磷酸酯鹽等之陰離子系抗靜電劑;多元醇脂肪酸酯、聚乙二醇磷酸酯、聚氧乙烯烷基烯丙基醚等之非離子系抗靜電劑;烷基二甲基胺基乙酸甜菜鹼等之兩性型烷基甜菜鹼、咪唑啉型兩性活性劑等之兩性抗靜電劑、聚醚酯醯胺等之高分子型抗靜電劑。此等抗靜電劑可單獨使用,又,亦可組合使用2種以上之抗靜電劑。摻合抗靜電劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.03~2質量份、更佳為0.1~0.8質量份。
顏料亦可使用市售之顏料,例如可列舉顏料紅1、2、3、9、10、17、22、23、31、38、41、48、49、88、90、97、112、119、122、123、144、149、166、168、169、170、171、177、179、180、184、185、192、200、202、209、215、216、217、220、223、224、226、227、228、240、254;顏料橙13、31、34、36、38、43、46、48、49、51、52、55、59、60、61、62、64、65、71;顏料黃1、3、12、13、14、16、17、20、24、55、60、73、81、83、86、93、95、97、98、100、109、110、113、114、117、120、125、126、127、129、137、138、139、147、148、150、151、152、153、154、166、168、175、180、185;顏料綠7、10、36;顏料藍15、15:1、15:2、15:3、15:4、15:5、15:6、22、24、29、56、60、61、62、64;顏料紫1、15、19、23、27、29、30、32、37、40、50等。
螢光增白劑,係指吸收太陽光或人工光之紫外線,藉由將其變為紫~藍色之可見光線並輻射之螢光作用,而助長成形品之白色度或藍色度之化合物。螢光增白劑,可列舉苯并噁唑系化合物C.I.Fluorescent Brightner184;香豆素系化合物C.I.Fluorescent Brightner52;二胺基二苯乙烯二磺酸系化合物C.I.Fluorescent Brightner24、85、71等。使用螢光增白劑時之摻合量,相對於熱可塑性樹脂100質量份而言,較佳調整為0.00001~0.1質量份、更佳為0.00005~0.05質量份。
染料可列舉偶氮染料、蒽醌染料、靛藍類染料、三芳基甲烷染料、氧雜蒽(xanthene)染料、茜素染料、吖啶染料、二苯乙烯染料、噻唑染料、萘酚染料、喹啉染料、硝基染料、吲達胺染料、噁嗪染料、酞青素染料、花青染料等之染料等,此等亦可混合複數種使用。
接著,說明本發明之熱可塑性樹脂組成物。
本發明之熱可塑性樹脂組成物中可利用之樹脂,只要係熱可塑性樹脂則無限制,就本發明之效果變得顯著之觀點,較佳為聚烯烴系樹脂、苯乙烯系樹脂、聚酯系樹脂、聚醚系樹脂、聚碳酸酯系樹脂、聚醯胺系樹脂、含鹵素樹脂;更佳為聚烯烴系樹脂。
聚烯烴系樹脂,例如可列舉聚乙烯、低密度聚乙烯、直鏈狀低密度聚乙烯、高密度聚乙烯、交聯聚乙烯、超高分子量聚乙烯、聚丙烯、均聚丙烯、隨機共聚物聚丙烯、嵌段共聚物聚丙烯、同排聚丙烯、對排聚丙烯、半同排聚丙烯、聚丁烯、環烯烴聚合物、立體嵌段聚丙烯、聚-3-甲基-1-丁烯、聚-3-甲基-1-戊烯、聚-4-甲基-1-戊烯等之α-烯烴聚合物;乙烯-丙烯之嵌段或隨機共聚物、衝擊共聚物聚丙烯、乙烯-甲基丙烯酸甲酯共聚物、乙烯-丙烯酸甲酯共聚物、乙烯-丙烯酸乙酯共聚物、乙烯-丙烯酸丁酯共聚物、乙烯-乙酸乙烯酯共聚物等之α-烯烴共聚物、聚氟烯烴、進而聚烯烴系熱可塑性彈性體,亦可為此等之2種以上的共聚物。
苯乙烯系樹脂例如可列舉含有乙烯基之芳香族烴單獨,及含有乙烯基之芳香族烴與其他單體(例如馬來酸酐、苯基馬來醯亞胺、(甲基)丙烯酸酯、丁二烯、(甲基)丙烯腈等)之共聚物,例如,可列舉聚苯乙烯(PS)樹脂、耐衝擊性聚苯乙烯(HIPS)、丙烯腈-苯乙烯(AS)樹脂、丙烯腈-丁二烯-苯乙烯(ABS)樹脂、甲基丙烯酸甲酯-丁二烯-苯乙烯(MBS)樹脂、耐熱ABS樹脂、丙烯酸酯-苯乙烯-丙烯腈(ASA)樹脂、丙烯腈-丙烯酸橡膠-苯乙烯(AAS)樹脂、苯乙烯-馬來酸酐(SMA)樹脂、甲基丙烯酸酯-苯乙烯(MS)樹脂、苯乙烯-異戊二烯-苯乙烯(SIS)樹脂、丙烯腈-乙烯丙烯橡膠-苯乙烯(AES)樹脂、苯乙烯-丁二烯-丁烯-苯乙烯(SBBS)樹脂、甲基丙烯酸甲酯-丙烯腈-丁二烯-苯乙烯(MABS)樹脂等之熱可塑性樹脂,以及此等之丁二烯或異戊二烯之雙鍵經氫化的苯乙烯-乙烯-丁烯-苯乙烯(SEBS)樹脂、苯乙烯-乙烯-丙烯-苯乙烯(SEPS)樹脂、苯乙烯-乙烯-丙烯(SEP)樹脂、苯乙烯-乙烯-乙烯-丙烯-苯乙烯(SEEPS)樹脂等之氫化苯乙烯系彈性體樹脂。
聚酯系樹脂例如可列舉聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚對苯二甲酸環己烷二甲酯等之聚對苯二甲酸烷二酯;聚萘二甲酸乙二酯、聚萘二甲酸丁二酯等之聚萘二甲酸烷二酯等之芳香族聚酯;聚對苯二甲酸四亞甲二酯等之直鏈聚酯;及聚羥基丁酸酯、聚己內酯、聚琥珀酸丁二酯、聚琥珀酸乙二酯、聚乳酸、聚蘋果酸、聚乙二醇酸、聚二噁烷、聚(2-氧雜環丁酮)等之分解性脂肪族聚酯等。
聚醚系樹脂可列舉聚縮醛、聚苯醚、聚醚酮、聚醚醚酮、聚醚酮酮、聚醚醚酮酮、聚醚碸、聚醚醯亞胺等。
聚碳酸酯系樹脂可列舉聚碳酸酯、聚碳酸酯/ABS樹脂、聚碳酸酯/ASA樹脂、聚碳酸酯/AES樹脂、分支聚碳酸酯等。
聚醯胺系樹脂例如可列舉ε-己內醯胺(耐綸6)、十一內醯胺(耐綸11)、月桂內醯胺(耐綸12)、胺基己酸、庚內醯胺(enantholactam)、7-胺基庚酸、11-胺基十一酸、9-胺基壬酸、α-吡咯啶酮、α-哌啶酮等之聚合物;使六亞甲二胺、壬二胺、壬烷亞甲二胺、甲基戊二胺、十一烷亞甲二胺、十二烷亞甲二胺、間二甲苯二胺等之二胺,與己二酸、癸二酸、對苯二甲酸、間苯二甲酸、十二烷二羧酸、戊二酸等之二羧酸等之羧酸化合物共聚合而得的共聚物,或此等聚合物或共聚物之混合物等。又,可列舉杜邦公司製商品名“Kevlar”、杜邦公司製商品名“Nomex”、帝人股份有限公司製商品名“Twaron”、“Conex”等之聚芳醯胺系樹脂。
含鹵素樹脂可列舉聚氯乙烯、聚偏二氯乙烯、氯化聚乙烯、氯化聚丙烯、聚偏二氟乙烯、氯化橡膠、氯乙烯-乙酸乙烯酯共聚物、氯乙烯-乙烯共聚物、氯乙烯-偏二氯乙烯共聚物、氯乙烯-偏二氯乙烯-乙酸乙烯酯三元共聚物、氯乙烯-丙烯酸酯共聚物、氯乙烯-馬來酸酯共聚物、氯乙烯-環己基馬來醯亞胺共聚物等。
進一步列舉熱可塑性樹脂之例子時,例如可使用石油樹脂、香豆酮樹脂、聚乙酸乙烯酯、丙烯酸樹脂、聚甲基丙烯酸甲酯、聚乙烯醇、聚乙烯甲醛、聚乙烯縮丁醛、聚苯硫醚、聚胺基甲酸酯、纖維素系樹脂、聚醯亞胺樹脂、聚碸、液晶聚合物等之熱可塑性樹脂及此等之摻合物。
又,熱可塑性樹脂,可為異戊二烯橡膠、丁二烯橡膠、丙烯腈-丁二烯共聚合橡膠、苯乙烯-丁二烯共聚合橡膠、氟橡膠、聚矽氧橡膠、聚酯系彈性體、腈系彈性體、耐綸系彈性體、氯乙烯系彈性體、聚醯胺系彈性體、聚胺基甲酸酯系彈性體等之彈性體,亦可合併使用。
本發明之樹脂組成物中,此等之熱可塑性樹脂,可單獨使用,亦可合併使用2種以上。又,亦可經合金化。再者,此等之熱可塑性樹脂,能夠與分子量、聚合度、密度、軟化點、對溶劑之不溶成分之比例、立體規則性之程度、觸媒殘渣之有無、作為原料的單體之種類或摻合比率、聚合觸媒之種類(例如戚格勒觸媒、二茂金屬觸媒等)等無關地使用。
本發明之熱可塑性樹脂組成物中,由於發明之效果顯著,較佳使用聚烯烴系樹脂。
將本發明之組成物摻合於熱可塑性樹脂之方法並不受特殊限制,可列舉一般所使用的方法,例如可列舉將熱可塑性樹脂粉末或丸粒,與本發明之組成物進行乾摻合之方法,或製成含高濃度本發明之組成物的母料,將其添加於熱可塑性樹脂之方法、將本發明之組成物加工為丸粒形狀,添加於熱可塑性樹脂之方法。
加工為丸粒形狀之方法,可將本發明之組成物,與酚系抗氧化劑、高分子化合物、石油樹脂等之黏合劑及依需要任意含有的添加劑之混合物予以加熱,在熔解狀態之黏合劑存在下混合,藉以製造。加工條件、加工機器等無任何限定,可使用周知一般的加工方法、加工機器。具體的製造方法,可列舉盤式製粒機(disk pelleter)法、擠出法等。
本發明之熱可塑性樹脂組成物,為於熱可塑性樹脂組成物中含有本發明之組成物者。本發明之組成物之摻合量,係以相對於熱可塑性樹脂100質量份而言,通式(1)表示之芳香族磷酸酯金屬鹽成為0.001~10質量份的方式摻合者,較佳為0.01~0.5質量份。摻合量未達0.001質量份時,有得不到透明性改良效果之情況,超過10質量份時,自成形品滲出,或得不到添加效果,其係不經濟。
本發明之熱可塑性樹脂組成物,在不顯著損及發明之效果之範圍,亦可任意含有公知之添加劑(例如酚系抗氧化劑、磷系抗氧化劑、硫醚系抗氧化劑、其他抗氧化劑、受阻胺化合物、紫外線吸收劑、核劑、難燃劑、難燃助劑、潤滑劑、填充劑、水滑石類、抗靜電劑、螢光增白劑、顏料、染料等)。其摻合量可列舉與上述相同者。
本發明之樹脂組成物,可使用公知之成形方法成形。例如可使用射出成形法、擠出成形法、吹塑成形法、真空成形法、吹脹成形法、壓延成形法、凝塑成形法、浸漬成形法、發泡成形法等來得到成形品。
本發明之樹脂組成物之用途,可列舉保險桿、控制面板、儀表板等汽車材料;冷藏庫、洗衣機、吸塵器等之外殼用途;食器、水桶、入浴用品等之家庭用品;玩具等之雜貨品;儲存槽類等之儲存、保存用容器等之成形品,或薄膜、纖維等。
[實施例]
以下列舉實施例,以更具體說明本發明,但本發明不受以下實施例等的任何限制。
[實施例1-1~1-3、比較例1-1~1-3]
對於作為熱可塑性樹脂之均聚丙烯(熔流速率8g/10min;根據ISO規格1133,2.16kg×230℃)100質量份,摻合酚系抗氧化劑(肆[亞甲基-3-(3’,5’-二-tert-丁基-4’-羥基苯基)丙酸酯]甲烷)0.05質量份、磷系抗氧化劑(參(2,4-二-tert-丁基苯基)亞磷酸酯)0.1質量份、硬脂酸鈣0.05質量份,及表1記載之組成物,以亨舍爾混合機1000rpm×1min混合後,使用二軸擠出機,於230℃之擠出溫度造粒。將所造粒之丸粒,於60℃乾燥8小時後,以下述記載之條件,測定霧度、彎曲彈性率、拉伸彈性率、伊左得衝擊強度(Izod impact strength)及試驗片之黃色度(Y.I.)。所得結果分別示於表1。再者,表中之各成分之單位為質量份。
<霧度>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製作試驗片。實施例1-1~1-3、比較例1-1~1-3中,係製作尺寸60mm×60mm×2mm之試驗片。將試驗片成形後,立即於23℃之恆溫機靜置48小時以上後,使用Haze Gard 2[BYK Additives&Instruments製],根據ISO 14782測定霧度(%)。
<彎曲彈性率(MPa)>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製作尺寸80mm×10mm×4mm之試驗片,於23℃之恆溫機靜置48小時以上後,使用島津製作所股份有限公司製彎曲試驗機「AG-IS」,根據ISO178,測定彎曲彈性率(MPa)。
<拉伸彈性率(MPa)>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製作1A形啞鈴狀試驗片,於23℃之恆溫機靜置48小時以上後,使用島津製作所股份有限公司製彎曲試驗機「AG-IS」,根據ISO527-2測定拉伸彈性率(MPa)。
<伊左得衝擊強度(kJ/m
2)>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製作80mm×10mm×4mm之試驗片,於23℃之恆溫機靜置48小時以上後,根據ISO180測定伊左得衝擊強度(kJ/m
2)。
<Y.I.>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製成60mm×60mm×2mm之試驗片,於23℃之恆溫機靜置48小時以上後,使用Suga Test Instruments股份有限公司製「多光源分光測色計」,藉由反射法測定試驗片之Y.I.。
由比較例1-1及比較例1-2,得知未摻合脂肪酸(D)之成形品,未得到衝擊強度之改善效果。又,由比較例1-3,可確認到脂肪酸(D)相對於組成物之比例超過30質量%時,物性或透明性之改善效果降低,進而霧度或成形品之著色增強,損及外觀。
相對於此等,由實施例1-1~1-3,可確認到使用本發明之組成物的成形品,物性或透明性之平衡優良,進一步地,具有優良的衝擊強度,成形品之著色少。
[實施例2-1~實施例2-4及比較例2-1、2-2]
對於下述表2記載之組成物,以下述順序進行旋轉安息角及凝集度之評估。再者,實施例2-4之組成物,係由以下之組成來調製。
鋁羥基雙[2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯]:45質量%、
硬脂酸鈉:28質量%、
肉豆蔻酸鋰:15質量%、
硬脂酸:12質量%
<旋轉安息角(度)>
於圓筒型容器(500mL)中投入表2記載之組成物,使成為圓筒容器一半的容量,蓋上蓋子,使用筒井理化學器械股份有限公司製安息角測定器(Revolving Cylinder Test),以2.4rpm之速度等速旋轉,評估試樣之流動性。圓筒型容器旋轉時,試樣係沿著旋轉的容器***,但試樣會由高的位置崩落。由該崩落的試樣所形成的斜面成為一定的狀態時,測定試樣的斜面與水平面所成的角度,作為安息角。此等結果分別示於表2。
<凝集度(%)>
使用粉體測定評估裝置(SEISHIN企業公司製、Multi Tester MT-02),以篩孔徑355μm(上段)、220μm(中段)、150μm(下段)、樣品重量2g、振幅1mm、振動時間100秒之條件將樣品分級,以下式的總和為凝集度。此等結果分別示於表2。
(上段之篩上樣品重量/全部樣品重量)×100=(a)之值(%)
(中段之篩上樣品重量/全部樣品重量)×(3/5)×100=(b)之值(%)
(下段之篩上樣品重量/全部樣品重量)×(1/5)×100=(c)之值(%)
凝集度(%)=(a)之值(%)+(b)之值(%)+(c)之值(%)
由比較例2-1,得知未摻合(D)成分之組成物的情況時,流動性不佳。又,由比較例2-2,得知(D)成分之比例超過約35質量%之組成物的情況時,流動性不佳。相對於此等,由實施例2-1~實施例2-4,可確認到(D)成分之比例為3~35質量%之範圍內的本發明之組成物,流動性優良。
[實施例3-1~3-15、比較例3-1~3-12]
對於作為熱可塑性樹脂之均聚丙烯(熔流速率8g/10min;根據ISO規格1133,2.16kg×230℃)100質量份,摻合酚系抗氧化劑(肆[亞甲基-3-(3’,5’-二-tert-丁基-4’-羥基苯基)丙酸酯]甲烷)0.05質量份、磷系抗氧化劑(參(2,4-二-tert-丁基苯基)亞磷酸酯)0.1質量份、硬脂酸鈣0.05質量份,及表3~6記載之組成物,以亨舍爾混合機1000rpm× 1min混合後,使用二軸擠出機,以230℃之擠出溫度進行造粒。惟,比較例3-12係未摻合組成物即進行造粒。將經造粒之丸粒於60℃乾燥8小時後,以下述記載之條件,測定結晶化溫度、彎曲彈性率及荷重變形溫度(HDT)。所得之結果分別示於表3~6。再者,表中之各成分之單位表示質量份。
<結晶化溫度>
使用所得之丸粒,使用示差掃描熱量測定器(裝置;PerkinElmer公司製Diamond)測定結晶化溫度(℃)。測定方法係以50℃/min之速度由室溫昇溫至230℃,保持10分鐘後,以-10℃/min冷卻至50℃,將所得之圖中吸熱反應成為峰頂時的溫度作為結晶化溫度(℃)。
<彎曲彈性率(MPa)>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製作尺寸80mm×10mm×4mm之試驗片,於23℃之恆溫機靜置48小時以上後,使用島津製作所股份有限公司製彎曲試驗機「AG-IS」,根據ISO178測定彎曲彈性率(MPa)。
<HDT>
使用所得之丸粒,藉由射出成形機(EC100-2A;東芝機械股份有限公司製),以模具溫度50℃、樹脂溫度200℃之條件進行射出成形,製作尺寸80mm×10mm×4mm之試驗片,於23℃之恆溫機靜置48小時以上後,使用東洋精機製作所股份有限公司製HDT試驗機「AUTO HDT Tester 3A-2」,根據ISO75測定HDT(℃)。
(A)-2:鋰(2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯)
(B)-2:硬脂酸鈉
(C)-2:硬脂酸鋅
(C)-3:硬脂酸鎂
(C)-4:硬脂酸鉀
(a)-1:鈉(2,2’-亞甲基雙(4,6-二-tert-丁基苯基)磷酸酯)
(b)-1:苯甲酸鉀
由比較例3-1~3-5,得知(A)、(B)、(C)、(D)之組成落在本發明之範圍外的組成物,缺乏結晶化溫度之改善效果。又,由比較例3-6及比較例3-7,得知(A)成分或(B)成分與本發明之組成物相異時,結晶化溫度、彎曲彈性率及HDT非為可滿足者。又,由比較例3-8~比較例3-11,得知若為缺乏(A)、(B)、(C)、(D)成分之一部分的組成物時,缺乏結晶化溫度、結晶化溫度及彎曲彈性率之改善效果。
相對於此等,由實施例3-1~3-15,可確認到使用本發明之組成物的成形品,結晶化溫度之改善效果顯著,可得到彎曲彈性率或HDT優良的成形品。
Claims (10)
- 一種組成物,其係含有下述(A)、(B)、(C)及(D)之組成物,其特徵為,相對於(A)+(B)+(C)+(D)之合計量而言,各成分之比例,為(A)35~75質量%、(B)10~40質量%、(C)0~20質量%、(D)5~35質量%;(A)芳香族磷酸酯金屬鹽,其係以通式(1)表示,通式(1)中,R1~R4係各自獨立地表示氫原子或碳原子數1~9之直鏈或具有分支之烷基,R5表示碳原子數1~4之亞烷基,m表示1或2之數,m為1時,M1表示鋰,m為2時,M1為羥基鋁;
- 如請求項1之組成物,其中通式(2)中之M2為鋰、鉀、鎂、鋅、鋁或羥基鋁。
- 如請求項1或2之組成物,其含有選自由酚系抗氧化劑、磷系抗氧化劑、硫醚系抗氧化劑、其他抗氧化劑、受阻胺化合物、紫外線吸收劑、與通式(1)表示之構造相異之核劑、難燃劑、難燃助劑、潤滑劑、填充劑、水滑石類、抗靜電劑、螢光增白劑、顏料、染料所成之群的1種以上之添加劑。
- 如請求項1或2之組成物,其中前述(B)羧酸鈉,為芳香族羧酸鈉或脂肪酸鈉。
- 如請求項1或2之組成物,其中(A)35~55質量%、(B)20~40質量%、(C)5~20質量%、(D)5~35質量%。
- 一種熱可塑性樹脂組成物,其特徵為含有如請求項1~6中任一項之組成物,使相對於熱可塑性樹脂100質量份而言,通式(1)表示之芳香族磷酸酯金屬鹽(A)成為0.001~10質量份。
- 如請求項7之熱可塑性樹脂組成物,其中前述熱可塑性樹脂為烯烴系樹脂。
- 如請求項8之熱可塑性樹脂組成物,其中前述烯烴系樹脂為聚丙烯。
- 一種成形品,其特徵為使用如請求項7~9中任一項之熱可塑性樹脂組成物而成。
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