TWI688005B - Heat treatment method and heat treatment apparatus - Google Patents

Heat treatment method and heat treatment apparatus Download PDF

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TWI688005B
TWI688005B TW106145087A TW106145087A TWI688005B TW I688005 B TWI688005 B TW I688005B TW 106145087 A TW106145087 A TW 106145087A TW 106145087 A TW106145087 A TW 106145087A TW I688005 B TWI688005 B TW I688005B
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chamber
pressure
heat treatment
flash
semiconductor wafer
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TW201812920A (en
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青山敬幸
河原崎光
古川雅志
布施和彥
谷村英昭
加藤慎一
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日商思可林集團股份有限公司
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    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
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    • H01L21/28518—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table the conductive layers comprising silicides
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Abstract

本發明提供一種能夠抑制矽化物之高電阻化之熱處理方法及熱處理裝置。 本發明於矽之半導體晶圓之表面成膜有金屬膜。於將該半導體晶圓收容於腔室內之後，將腔室內減壓至較大氣壓低之氣壓P1。其後，對腔室內供給氮氣而使之恢復壓力至常壓Ps，對半導體晶圓之表面照射閃光而形成金屬膜與矽之化合物即矽化物。由於將腔室內暫時減壓至較大氣壓低之氣壓P1之後再恢復壓力，故而可顯著地降低執行矽化物形成處理時之腔室內之氧濃度，從而可抑制因腔室內氛圍氣體中之氧進入至金屬膜與基材之界面附近之缺陷所導致的矽化物之高電阻化。The invention provides a heat treatment method and a heat treatment device capable of suppressing the increase of silicide resistance. In the present invention, a metal film is formed on the surface of the silicon semiconductor wafer. After the semiconductor wafer is housed in the chamber, the chamber is depressurized to an atmospheric pressure P1 with a relatively large atmospheric pressure. Thereafter, nitrogen gas is supplied into the chamber to restore the pressure to the normal pressure Ps, and the surface of the semiconductor wafer is irradiated with flash to form a silicide, which is a compound of a metal film and silicon. Since the pressure in the chamber is temporarily reduced to a higher pressure P1 and then the pressure is restored, the oxygen concentration in the chamber when the silicide formation process is performed can be significantly reduced, so that the oxygen in the atmosphere in the chamber can be suppressed from entering The high resistance of the silicide caused by defects near the interface between the metal film and the substrate.

Description

熱處理方法及熱處理裝置Heat treatment method and heat treatment device

本發明係關於一種對半導體晶圓等矽或矽鍺之薄板狀精密電子基板(以下簡稱為「基板」)照射閃光而形成矽化物或鍺化物之熱處理方法及熱處理裝置。The invention relates to a heat treatment method and a heat treatment device for forming a silicide or a germanium compound by irradiating a thin plate-shaped precision electronic substrate (hereinafter referred to as "substrate") of silicon or silicon germanium such as a semiconductor wafer.

於半導體器件之製造製程中，以極短時間加熱半導體晶圓之閃光燈退火(FLA)引人注目。閃光燈退火係藉由使用氙氣閃光燈(以下於簡稱為「閃光燈」時意指氙氣閃光燈)對半導體晶圓之表面照射閃光而僅使半導體晶圓之表面於極短時間(數毫秒以下)升溫之熱處理技術。 氙氣閃光燈之輻射分光分佈係自紫外區域至近紅外區域，且波長較先前之鹵素燈短，與矽半導體晶圓之基礎吸收帶大致一致。由此，於自氙氣閃光燈對半導體晶圓照射閃光時，透過光較少而能夠使半導體晶圓急速地升溫。又，亦判明若為數毫秒以下之極短時間之閃光照射，則可僅將半導體晶圓之表面附近選擇性地升溫。 此種閃光燈退火用於必需極短時間之加熱之處理，例如典型而言用於注入至半導體晶圓之雜質之活化。若自閃光燈對利用離子注入法注入有雜質之半導體晶圓之表面照射閃光，則可使該半導體晶圓之表面僅升溫至活化溫度極短時間，從而可不使雜質較深地擴散而僅執行雜質活化。 又，亦在研究於場效電晶體(FET)之矽化物形成中應用閃光燈退火。矽化物形成係用於場效電晶體之高性能化而形成金屬與矽之化合物(矽化物)之技術。藉由形成矽化物，而降低閘極及源極/汲極區域之電阻從而實現場效電晶體之高速動作。作為用於形成矽化物之金屬，研究鎳(Ni)、鈷(Co)、鈦(Ti)等，但鎳作為最適於微細化之材料而較有前途。 矽化物形成係藉由於半導體晶圓之源極/汲極區域成膜鎳等之金屬膜，且對該半導體晶圓實施加熱處理而實現。此時，若進行長時間之加熱處理則產生如下問題，即，矽化物於橫向(自源極/汲極區域朝向閘極之方向)異常成長而穿破源極/汲極之接面，漏電流急速地增大。因此，例如於專利文獻1中揭示對成膜有金屬膜之半導體晶圓之表面照射閃光而進行短時間之加熱處理。 [先前技術文獻] [專利文獻] [專利文獻1]日本專利特開2013-84901號公報In the manufacturing process of semiconductor devices, flash lamp annealing (FLA) that heats semiconductor wafers in a very short time is noticeable. Flash lamp annealing is a heat treatment that uses a xenon flash lamp (hereinafter referred to as a "flash lamp" to mean a xenon flash lamp) to irradiate the surface of the semiconductor wafer to flash only the temperature of the semiconductor wafer surface for a very short time (less than a few milliseconds) technology. The radiation spectral distribution of the xenon flash lamp is from the ultraviolet region to the near infrared region, and the wavelength is shorter than that of the previous halogen lamp, which is roughly consistent with the basic absorption band of the silicon semiconductor wafer. Thus, when the semiconductor wafer is irradiated with flash light from the xenon flash lamp, the transmitted light is small, and the semiconductor wafer can be rapidly heated. In addition, it was also found that if the flash irradiation is performed for a very short time of several milliseconds or less, only the vicinity of the surface of the semiconductor wafer can be selectively heated. Such flash lamp annealing is used for a treatment that requires a very short time for heating, for example, it is typically used for activation of impurities implanted into a semiconductor wafer. If the surface of the semiconductor wafer with impurities implanted by the ion implantation method is irradiated with flash from the flash lamp, the surface of the semiconductor wafer can be heated to the activation temperature for a very short time, so that the impurities can be carried out without deep diffusion of the impurities activation. In addition, flash lamp annealing has also been studied in the formation of silicides for field-effect transistors (FETs). Silicide formation is a technique used to improve the performance of field effect transistors to form a compound of metal and silicon (silicide). By forming silicide, the resistance of the gate and source/drain regions is reduced to achieve high-speed operation of the field effect transistor. As a metal for forming silicide, nickel (Ni), cobalt (Co), titanium (Ti), etc. are studied, but nickel is promising as a material most suitable for miniaturization. Silicide formation is achieved by forming a metal film such as nickel on the source/drain regions of the semiconductor wafer, and applying heat treatment to the semiconductor wafer. At this time, if the heat treatment is performed for a long time, the following problem occurs, that is, the silicide grows abnormally in the lateral direction (from the source/drain region toward the gate) and breaks through the source/drain junction. The current increased rapidly. Therefore, for example, Patent Document 1 discloses that the surface of a semiconductor wafer on which a metal film is formed is irradiated with a flash to perform a short-time heating process. [Prior Art Literature] [Patent Literature] [Patent Literature 1] Japanese Patent Laid-Open No. 2013-84901

[發明所欲解決之問題] 然而，如專利文獻1所揭示般，判明了若僅係對成膜有金屬膜之半導體晶圓簡單地照射閃光而進行極短時間之閃光加熱處理，則矽化物與基層之矽之界面特性劣化而導致高電阻化。於今後之微細化更進展之器件中，矽化物之膜厚變薄而更易受到氧之影響。又，矽化物本身亦容易被氧化，亦必須抑制矽化物形成後之矽化物之氧化。 矽化物之界面特性之劣化及矽化物本身之氧化係起因於在氧存在之狀態下進行加熱處理。成為該等諸問題之原因之氧主要有腔室內之殘留氧、及吸附於半導體晶圓之表面之氧(典型而言以水分之方式吸附)。尤其是，於閃光加熱處理時殘留於腔室內之氧成為矽氧化膜之膜厚增大之較大之主因。一般而言，於閃光燈退火裝置中，由於在常壓下將半導體晶圓搬入搬出腔室內，故而此時流入之大氣中之氧殘留於腔室內而使氧濃度變高。 本發明係鑒於上述課題而完成者，其目的在於提供一種能夠抑制矽化物等之高電阻化之熱處理方法及熱處理裝置。 [解決問題之技術手段] 為了解決上述課題，技術方案1之發明係對基板照射閃光而形成矽化物或鍺化物之熱處理方法，其特徵在於包括：搬入步驟，其將成膜有金屬膜之基板搬入至腔室內；減壓步驟，其將上述腔室內減壓至較大氣壓低之第1壓力；恢復壓力步驟，其將上述腔室內自第1壓力恢復壓力至較第1壓力高之第2壓力；及照射步驟，其一面將上述腔室內維持為第2壓力，一面自閃光燈對上述基板之表面照射閃光。 又，技術方案2之發明係如技術方案1之發明之熱處理方法，其中第2壓力高於第1壓力且低於大氣壓。 又，技術方案3之發明係如技術方案1之發明之熱處理方法，其中第2壓力為大氣壓。 又，技術方案4之發明係如技術方案1之發明之熱處理方法，其中第2壓力高於大氣壓。 又，技術方案5之發明係如技術方案1之發明之熱處理方法，其中於上述減壓步驟中，使自上述腔室之排氣流量隨時間增加。 又，技術方案6之發明係如技術方案1之發明之熱處理方法，其中於上述恢復壓力步驟中，使向上述腔室之供氣流量隨時間增加。 又，技術方案7之發明係如技術方案1之發明之熱處理方法，其中於上述照射步驟之後，使上述腔室內為大氣壓並以50升/分鐘以上100升/分鐘以下之流量將惰性氣體流入至上述腔室內。 又，技術方案8之發明係如技術方案1之發明之熱處理方法，其中於上述搬入步驟中，一面將上述腔室之搬送開口部開放，一面對上述腔室內供給惰性氣體。 又，技術方案9之發明係對基板照射閃光而形成矽化物或鍺化物之熱處理方法，其特徵在於包括：搬入步驟，其將成膜有金屬膜之基板搬入至腔室內；減壓步驟，其將上述腔室內減壓至較大氣壓低之第1壓力；及照射步驟，其一面將上述腔室內維持為第1壓力，一面自閃光燈對上述基板之表面照射閃光。 又，技術方案10之發明係對基板照射閃光而形成矽化物或鍺化物之熱處理裝置，其特徵在於具備：腔室，其收容成膜有金屬膜之基板；閃光燈，其對收容於上述腔室之上述基板照射閃光；排氣部，其將上述腔室內之氛圍氣體排氣；氣體供給部，其對上述腔室供給特定之處理氣體；及控制部，其以如下方式控制上述排氣部及上述氣體供給部，即，於使上述腔室內減壓至較大氣壓低之第1壓力之後，於恢復壓力至較第1壓力高之第2壓力之狀態下自上述閃光燈對上述基板之表面照射閃光。 又，技術方案11之發明係如技術方案10之發明之熱處理裝置，其中第2壓力高於第1壓力且低於大氣壓。 又，技術方案12之發明係如技術方案10之發明之熱處理裝置，其中第2壓力為大氣壓。 又，技術方案13之發明係如技術方案10之發明之熱處理裝置，其中第2壓力高於大氣壓。 又，技術方案14之發明係如技術方案10之發明之熱處理裝置，其中上述控制部以於將上述腔室內減壓至第1壓力時自上述腔室之排氣流量隨時間增加之方式控制上述排氣部。 又，技術方案15之發明係如技術方案10之發明之熱處理裝置，其中上述控制部以於使上述腔室內自第1壓力恢復壓力至第2壓力時向上述腔室之供氣流量隨時間增加之方式控制上述氣體供給部。 又，技術方案16之發明係如技術方案10之發明之熱處理裝置，其中上述控制部以如下方式控制上述排氣部及上述氣體供給部，即，於上述閃光之照射後，使上述腔室內為大氣壓並以50升/分鐘以上100升/分鐘以下之流量將惰性氣體流入至上述腔室內。 又，技術方案17之發明係對基板照射閃光而形成矽化物或鍺化物之熱處理裝置，其特徵在於具備：腔室，其收容成膜有金屬膜之基板；閃光燈，其對收容於上述腔室之上述基板照射閃光；排氣部，其將上述腔室內之氛圍氣體排出；氣體供給部，其對上述腔室供給特定之處理氣體；及控制部，其以如下方式控制上述排氣部及上述氣體供給部，即，於將上述腔室內減壓至較大氣壓低之第1壓力之後，一面維持為第1壓力一面自上述閃光燈對上述基板之表面照射閃光。 [發明之效果] 根據技術方案1至技術方案8之發明，由於將腔室內於減壓至較大氣壓低之第1壓力之後恢復壓力至較其高之第2壓力，故而可降低照射閃光時之腔室內之氧濃度，從而可抑制因腔室內之氧進入至金屬膜與基材之界面附近之缺陷所導致的矽化物或鍺化物之高電阻化。 尤其是，根據技術方案2之發明，由於第2壓力高於第1壓力且低於大氣壓，故而恢復壓力所需之時間變短，從而可提高產量。 尤其是，根據技術方案4之發明，由於第2壓力高於大氣壓，故而可抑制自腔室放出之氧之擴散速度變慢而到達基板。 尤其是，根據技術方案5之發明，由於使自腔室之排氣流量隨時間增加，故而可防止伴隨著自腔室之排氣之微粒之捲起。 尤其是，根據技術方案6之發明，由於使向腔室之供氣流量隨時間增加，故而可防止伴隨著向腔室之供氣之微粒之捲起。 尤其是，根據技術方案7之發明，由於使腔室內為大氣壓並以50升/分鐘以上100升/分鐘以下之流量使惰性氣體流入至腔室內，故而可將閃光照射時產生之微粒衝出至腔室外。 尤其是，根據技術方案8之發明，由於在搬入步驟中一面將腔室之搬送開口部開放一面對腔室內供給惰性氣體，故而可防止基板搬入時向腔室流入空氣。 根據技術方案9之發明，由於使腔室內減壓至較大氣壓低之第1壓力，且一面維持為該第1壓力一面對基板之表面照射閃光，故而可降低照射閃光時之腔室內之氧濃度，從而可抑制因腔室內之氧進入至金屬膜與基材之界面附近之缺陷所導致的矽化物或鍺化物之高電阻化。 根據技術方案10至技術方案16之發明，由於將腔室內在減壓至較大氣壓低之第1壓力之後，恢復壓力至較第1壓力高之第2壓力，故而可降低照射閃光時之腔室內之氧濃度，從而可抑制因腔室內之氧進入至金屬膜與基材之界面附近之缺陷所導致的矽化物之高電阻化。 尤其是，根據技術方案11之發明，由於第2壓力高於第1壓力且低於大氣壓，故而恢復壓力所需之時間變短，從而可提高產量。 尤其是，根據技術方案13之發明，由於第2壓力高於大氣壓，故而可抑制自腔室放出之氧之擴散速度變慢而到達基板。 尤其是，根據技術方案14之發明，由於以自腔室之排氣流量隨時間增加之方式控制排氣部，故而可防止伴隨著來自腔室之排氣之微粒之捲起。 尤其是，根據技術方案15之發明，由於以向腔室之供氣流量隨時間增加之方式控制氣體供給部，故而可防止伴隨著向腔室之供氣之微粒之捲起。 尤其是，根據技術方案16之發明，由於使腔室內為大氣壓並以50升/分鐘以上100升/分鐘以下之流量使惰性氣體流入至腔室內，故而可將閃光照射時產生之微粒衝出至腔室外。 根據技術方案17之發明，由於使腔室內減壓至較大氣壓低之第1壓力，且一面維持為該第1壓力一面對基板之表面照射閃光，故而可降低照射閃光時之腔室內之氧濃度，從而可抑制因腔室內之氧進入至金屬膜與基材之界面附近之缺陷所導致的矽化物或鍺化物之高電阻化。[Problems to be Solved by the Invention] However, as disclosed in Patent Document 1, it has been found that if the semiconductor wafer formed with a metal film is simply irradiated with flash light and flash heat treatment is performed for a very short time, the silicide The interface characteristic with the silicon of the base layer deteriorates, resulting in higher resistance. In future devices that are more miniaturized and more advanced, the thickness of the silicide becomes thinner and more susceptible to oxygen. In addition, the silicide itself is easily oxidized, and the oxidation of the silicide after the formation of the silicide must also be suppressed. The deterioration of the interface characteristics of the silicide and the oxidation of the silicide itself are caused by heat treatment in the presence of oxygen. The oxygen causing these problems mainly includes residual oxygen in the chamber and oxygen adsorbed on the surface of the semiconductor wafer (typically adsorbed by moisture). In particular, the oxygen remaining in the chamber during the flash heating process becomes the main reason for the larger thickness of the silicon oxide film. Generally, in the flash lamp annealing apparatus, since the semiconductor wafer is carried into and out of the chamber under normal pressure, the oxygen in the atmosphere that flows in at this time remains in the chamber, thereby increasing the oxygen concentration. The present invention has been completed in view of the above-mentioned problems, and its object is to provide a heat treatment method and a heat treatment apparatus that can suppress the increase in resistance of silicides and the like. [Technical Means for Solving the Problem] In order to solve the above-mentioned problems, the invention of claim 1 is a heat treatment method for forming a silicide or germanide by shining a flash on a substrate, which is characterized by including a carrying-in step, which forms a substrate with a metal film Carried into the chamber; the decompression step, which decompresses the chamber to a first pressure with a larger atmospheric pressure; the pressure recovery step, which restores the pressure in the chamber from the first pressure to a second pressure higher than the first pressure And the irradiating step, while maintaining the second pressure in the chamber while irradiating the flash from the flash on the surface of the substrate. Furthermore, the invention of claim 2 is the heat treatment method of the invention of claim 1, wherein the second pressure is higher than the first pressure and lower than atmospheric pressure. In addition, the invention of claim 3 is the heat treatment method according to the invention of claim 1, wherein the second pressure is atmospheric pressure. Furthermore, the invention of claim 4 is the heat treatment method of the invention of claim 1, wherein the second pressure is higher than atmospheric pressure. Furthermore, the invention of claim 5 is the heat treatment method of the invention of claim 1, wherein in the depressurization step, the flow rate of the exhaust gas from the chamber is increased with time. In addition, the invention of claim 6 is the heat treatment method of the invention of claim 1, wherein in the pressure recovery step, the gas supply flow rate to the chamber is increased with time. Furthermore, the invention of claim 7 is the heat treatment method of the invention of claim 1, wherein after the irradiation step, the chamber is brought to atmospheric pressure and an inert gas is flowed into at a flow rate of 50 liters/minute or more and 100 liters/minute or less to Inside the chamber. Furthermore, the invention of claim 8 is the heat treatment method of the invention of claim 1, wherein in the carrying-in step, while opening the conveying opening of the chamber, an inert gas is supplied facing the chamber. Furthermore, the invention of claim 9 is a heat treatment method for irradiating the substrate with flash to form a silicide or germanide, which is characterized by including: a carrying-in step, which carries the film-formed metal substrate into the chamber; a decompression step, which Depressurizing the chamber to a first pressure with a relatively low atmospheric pressure; and an irradiation step, while maintaining the chamber at the first pressure while irradiating the surface of the substrate with a flash from a flash. In addition, the invention of claim 10 is a heat treatment device for irradiating the substrate with flash to form a silicide or germanide, which is characterized by comprising: a chamber that houses the substrate with a metal film formed thereon; and a flash lamp, which is housed in the chamber The substrate is irradiated with flash light; an exhaust portion that exhausts the atmospheric gas in the chamber; a gas supply portion that supplies a specific processing gas to the chamber; and a control portion that controls the exhaust portion and The gas supply part, that is, after depressurizing the chamber to a first pressure lower than a larger atmospheric pressure, irradiates the surface of the substrate from the flash lamp with the pressure restored to a second pressure higher than the first pressure . Furthermore, the invention of claim 11 is the heat treatment device of the invention of claim 10, wherein the second pressure is higher than the first pressure and lower than atmospheric pressure. In addition, the invention of claim 12 is the heat treatment device of the invention of claim 10, wherein the second pressure is atmospheric pressure. Furthermore, the invention of claim 13 is the heat treatment device of the invention of claim 10, wherein the second pressure is higher than atmospheric pressure. Also, the invention of claim 14 is the heat treatment device of the invention of claim 10, wherein the control section controls the exhaust gas flow rate from the chamber to increase with time when the chamber is decompressed to the first pressure. Exhaust. Also, the invention of claim 15 is the heat treatment device of the invention of claim 10, wherein the control unit increases the flow rate of the gas supplied to the chamber with time when the pressure in the chamber is restored from the first pressure to the second pressure To control the gas supply unit. In addition, the invention of claim 16 is the heat treatment apparatus of the invention of claim 10, wherein the control unit controls the exhaust unit and the gas supply unit in such a manner that after the irradiation of the flash, the chamber is Atmospheric pressure and flow of inert gas into the chamber at a flow rate of 50 liters/minute or more and 100 liters/minute or less. In addition, the invention of claim 17 is a heat treatment device for irradiating the substrate with flash to form a silicide or germanide, which is characterized by comprising: a chamber for accommodating the metal film-formed substrate; and a flash lamp for accommodating the chamber The substrate is irradiated with flash light; an exhaust portion that exhausts the atmospheric gas in the chamber; a gas supply portion that supplies a specific processing gas to the chamber; and a control portion that controls the exhaust portion and the above in the following manner The gas supply unit, that is, after depressurizing the chamber to a first pressure with a relatively large atmospheric pressure and low pressure, radiates flash light from the flash lamp to the surface of the substrate while maintaining the first pressure. [Effects of the invention] According to the inventions of claim 1 to claim 8, since the pressure in the chamber is reduced to the first pressure with a larger atmospheric pressure and lower, the pressure is restored to the second pressure with a higher pressure. The oxygen concentration in the chamber can suppress the high resistance of the silicide or germanide caused by the oxygen in the chamber entering the defect near the interface between the metal film and the substrate. In particular, according to the invention of claim 2, since the second pressure is higher than the first pressure and lower than the atmospheric pressure, the time required to restore the pressure becomes shorter, and the yield can be improved. In particular, according to the invention of claim 4, since the second pressure is higher than atmospheric pressure, the diffusion rate of oxygen released from the chamber can be suppressed from slowing down and reaching the substrate. In particular, according to the invention of claim 5, since the flow rate of the exhaust gas from the chamber is increased over time, it is possible to prevent the particles accompanying the exhaust gas from the chamber from being rolled up. In particular, according to the invention of claim 6, since the flow rate of the air supply to the chamber is increased over time, it is possible to prevent the particles accompanying the air supply to the chamber from being rolled up. In particular, according to the invention of claim 7, since the chamber is at atmospheric pressure and the inert gas flows into the chamber at a flow rate of 50 liters/minute or more and 100 liters/minute or less, the particles generated during flash irradiation can be flushed out to Outside the chamber. In particular, according to the invention of claim 8, since the transfer opening of the chamber is opened and the inert gas is supplied to the chamber during the loading step, it is possible to prevent the inflow of air into the chamber when the substrate is loaded. According to the invention of claim 9, since the pressure in the chamber is reduced to the first pressure with a relatively large atmospheric pressure, and the first pressure is maintained while the first pressure is applied to the surface of the substrate, the flash is irradiated, so the oxygen in the chamber when the flash is irradiated The concentration can suppress the increase in resistance of silicide or germanide caused by the oxygen in the chamber entering the defects near the interface between the metal film and the substrate. According to the inventions of claim 10 to claim 16, after the pressure in the chamber is reduced to the first pressure which is lower than the larger pressure, the pressure is restored to the second pressure which is higher than the first pressure, so that the chamber when irradiating the flash can be reduced The concentration of oxygen can suppress the increase in resistance of the silicide caused by the oxygen in the chamber entering the defects near the interface between the metal film and the substrate. In particular, according to the invention of claim 11, since the second pressure is higher than the first pressure and lower than the atmospheric pressure, the time required to restore the pressure becomes shorter, and the output can be improved. In particular, according to the invention of claim 13, since the second pressure is higher than atmospheric pressure, it is possible to suppress the diffusion rate of oxygen released from the chamber from slowing down and reaching the substrate. In particular, according to the invention of claim 14, since the exhaust portion is controlled so that the flow rate of exhaust gas from the chamber increases with time, it is possible to prevent the particles accompanying the exhaust gas from the chamber from being rolled up. In particular, according to the invention of claim 15, since the gas supply portion is controlled so that the flow rate of the gas supply to the chamber increases with time, it is possible to prevent the particles accompanying the gas supply to the chamber from being rolled up. In particular, according to the invention of claim 16, since the chamber is at atmospheric pressure and the inert gas flows into the chamber at a flow rate of 50 liters/minute or more and 100 liters/minute or less, the particles generated during flash irradiation can be flushed out to Outside the chamber. According to the invention of claim 17, since the pressure in the chamber is reduced to the first pressure with a relatively large pressure and the first pressure is maintained while the first pressure is irradiated to the surface of the substrate, the oxygen in the chamber when irradiating the flash can be reduced The concentration can suppress the increase in resistance of silicide or germanide caused by the oxygen in the chamber entering the defects near the interface between the metal film and the substrate.

以下，一面參照圖式一面對本發明之實施形態詳細地進行說明。 ＜第1實施形態＞ 圖1係表示本發明之熱處理裝置1之構成之縱剖視圖。本實施形態之熱處理裝置1係藉由對作為基板之圓板形狀之半導體晶圓W進行閃光照射而加熱該半導體晶圓W之閃光燈退火裝置。成為處理對象之半導體晶圓W之尺寸並無特別限定，例如為

Figure 02_image001
300 mm或
Figure 02_image001
450 mm。於搬入至熱處理裝置1之前之半導體晶圓W成膜有鎳等之金屬膜，藉由利用熱處理裝置1之加熱處理而形成並成長該金屬與矽之化合物即矽化物。再者，於圖1及以後之各圖中，為了容易理解，視需要對各部分之尺寸或數量進行誇張或者簡化而描繪。 熱處理裝置1具備：腔室6，其收容半導體晶圓W；閃光加熱部5，其內置複數個閃光燈FL；及鹵素加熱部4，其內置複數個鹵素燈HL。於腔室6之上側設置有閃光加熱部5，並且於下側設置有鹵素加熱部4。又，熱處理裝置1於腔室6之內部具備將半導體晶圓W保持為水平姿勢之保持部7、及於保持部7與裝置外部之間進行半導體晶圓W之交付之移載機構10。進而，熱處理裝置1具備控制部3，該控制部3控制鹵素加熱部4、閃光加熱部5及設置於腔室6之各動作機構而使其等執行半導體晶圓W之熱處理。 腔室6係於筒狀之腔室側部61之上下安裝石英製之腔室窗而構成。腔室側部61具有上下開口之概略筒形狀，於上側開口安裝上側腔室窗63而將其封閉，於下側開口安裝下側腔室窗64而將其封閉。構成腔室6之頂壁之上側腔室窗63係由石英形成之圓板形狀構件，且作為使自閃光加熱部5出射之閃光透過至腔室6內之石英窗發揮功能。又，構成腔室6之地板部之下側腔室窗64亦係由石英形成之圓板形狀構件，且作為使來自鹵素加熱部4之光透過至腔室6內之石英窗發揮功能。上側腔室窗63及下側腔室窗64之厚度例如為約28 mm。 又，於腔室側部61之內側之壁面之上部安裝有反射環68，於下部安裝有反射環69。反射環68、69均形成為圓環狀。上側之反射環68藉由自腔室側部61之上側嵌入而安裝。另一方面，下側之反射環69藉由自腔室側部61之下側嵌入且利用省略圖示之螺絲固定而安裝。即，反射環68、69均裝卸自如地安裝於腔室側部61。腔室6之內側空間、即由上側腔室窗63、下側腔室窗64、腔室側部61及反射環68、69包圍之空間被界定為熱處理空間65。 藉由於腔室側部61安裝反射環68、69，而於腔室6之內壁面形成凹部62。即，形成由腔室側部61之內壁面中未安裝反射環68、69之中央部分、反射環68之下端面、及反射環69之上端面包圍之凹部62。凹部62於腔室6之內壁面沿著水平方向形成為圓環狀而圍繞保持半導體晶圓W之保持部7。 腔室側部61及反射環68、69係利用強度及耐熱性優異之金屬材料(例如不鏽鋼)形成。又，反射環68、69之內周面係藉由電解鍍鎳而成為鏡面。 又，於腔室側部61設置有用以相對於腔室6進行半導體晶圓W之搬入及搬出之搬送開口部(爐口)66。搬送開口部66設為能夠藉由閘閥185進行開閉。搬送開口部66連通連接於凹部62之外周面。因此，於閘閥185將搬送開口部66開放時，可進行自搬送開口部66通過凹部62向熱處理空間65搬入半導體晶圓W及自熱處理空間65搬出半導體晶圓W。又，若閘閥185將搬送開口部66閉鎖，則腔室6內之熱處理空間65設為密閉空間。 又，於腔室6之內壁上部設置有氣體供給孔81，該氣體供給孔81對熱處理空間65供給處理氣體(本實施形態中為氮氣(N2 ))。氣體供給孔81設置於較凹部62更靠上側位置，亦可設置於反射環68。氣體供給孔81經由呈圓環狀形成於腔室6之側壁內部之緩衝空間82而連通連接於氣體供給管83。氣體供給管83連接於氣體供給源85。氣體供給源85於控制部3之控制下將氮氣作為處理氣體送給至氣體供給管83。又，於氣體供給管83之路徑中途介插有閥84及流量調整閥90。若將閥84開放，則自氣體供給源85將處理氣體送給至緩衝空間82。流經氣體供給管83而送給至緩衝空間82之處理氣體之流量由流量調整閥90調整。流量調整閥90規定之處理氣體之流量藉由控制部3之控制而可變。流入至緩衝空間82之處理氣體以於流體阻力較氣體供給孔81小之緩衝空間82內擴散之方式流動而自氣體供給孔81供給至熱處理空間65內。再者，處理氣體並不限定於氮氣，亦可為氬(Ar)、氦(He)等惰性氣體、或氫(H2 )、氨(NH3 )、氯(Cl2 )、氯化氫(HCl)等反應性氣體。 另一方面，於腔室6之內壁下部設置有將熱處理空間65內之氣體排氣之氣體排氣孔86。氣體排氣孔86設置於較凹部62更靠下側位置，亦可設置於反射環69。氣體排氣孔86經由呈圓環狀形成於腔室6之側壁內部之緩衝空間87而連通連接於氣體排氣管88。氣體排氣管88連接於排氣部190。又，於氣體排氣管88之路徑中途介插有閥89。若將閥89開放，則熱處理空間65之氣體自氣體排氣孔86經由緩衝空間87而排出至氣體排氣管88。再者，氣體供給孔81及氣體排氣孔86可沿著腔室6之圓周方向設置複數個，亦可為狹縫狀者。 圖8係表示排氣部190之構成之圖。排氣部190具備排氣泵191、流量調整閥196、3條旁通路線197、198、199、及3個排氣閥192、193、194。引導來自腔室6之排氣之氣體排氣管88與排氣泵191藉由3條旁通路線197、198、199而連接。3條旁通路線197、198、199並列設置。3條旁通路線197、198、199之配管直徑彼此不同。旁通路線197之直徑最小，旁通路線199之直徑最大，旁通路線198之直徑為其等之間。藉此，能夠通過之氣體之流量按旁通路線197、198、199之順序變大。 3個排氣閥192、193、194分別設置於3條旁通路線197、198、199。即，於旁通路線197介插排氣閥192，於旁通路線198介插排氣閥193，於旁通路線199介插排氣閥194。若一面使排氣泵191作動一面將3個排氣閥192、193、194開放，則藉由氣體排氣管88而引導之來自腔室6之排氣通過對應的旁通路線197、198、199而被抽吸至排氣泵191。 由於3條旁通路線197、198、199之配管直徑不同，故而排氣能力不同。配管直徑越大則排氣能力亦越大，排氣能力按照旁通路線197、198、199之順序變大。因此，可藉由將3個排氣閥192、193、194中之任一者開閉而控制來自腔室6之排氣流量。可僅將3個排氣閥192、193、194之任一者開放，亦可將2個或3個開放。例如，於將排氣閥193、194關閉而僅將排氣閥192開放之情形時，以最小之排氣流量進行排氣。又，於將3個排氣閥192、193、194全部開放之情形時，以最大之排氣流量進行排氣。 又，於3條旁通路線197、198、199之合流部分與排氣泵191之間介插有流量調整閥196。氣體排氣管88之排氣流量亦能夠藉由流量調整閥196而調整。流量調整閥196規定之排氣流量藉由控制部3之控制而可變。3條旁通路線197、198、199係不連續且多段地調整排氣流量之機構，相對於此，流量調整閥196係連續地無階段地調整排氣流量之機構。 氣體供給管83、氣體排氣管88、及3條旁通路線197、198、199係由強度及耐蝕性優異之不鏽鋼構成。又，於腔室6內設置有測定熱處理空間65之壓力之壓力計180。作為壓力計180較佳為將約5 Pa～0.2 MPa設為測定範圍者。 圖2係表示保持部7之整體外觀之立體圖。又，圖3係自上表面觀察保持部7之俯視圖，圖4係自側方觀察保持部7之側視圖。保持部7具備基台環71、連結部72及基座74而構成。基台環71、連結部72及基座74均由石英形成。即，保持部7之整體由石英形成。 基台環71係圓環形狀之石英構件。基台環71藉由載置於凹部62之底面而被支持於腔室6之壁面(參照圖1)。於具有圓環形狀之基台環71之上表面，沿著其圓周方向豎立設置有複數個連結部72(本實施形態中為4個)。連結部72亦係石英之構件，且藉由焊接而固定於基台環71。再者，基台環71之形狀亦可為自圓環形狀缺損一部分而成之圓弧狀。 平板狀之基座74由設置於基台環71之4個連結部72支持。基座74係由石英形成之大致圓形之平板狀構件。基座74之直徑大於半導體晶圓W之直徑。即，基座74具有較半導體晶圓W大之平面尺寸。於基座74之上表面豎立設置有複數個(本實施形態中為5個)導銷76。5個導銷76沿著與基座74之外周圓為同心圓之圓周上設置。配置有5個導銷76之圓之直徑略大於半導體晶圓W之直徑。各導銷76亦由石英形成。再者，導銷76可與基座74一體地自石英錠加工，亦可將另行加工者藉由焊接等安裝於基座74。 豎立設置於基台環71之4個連結部72與基座74之周緣部之下表面藉由焊接而固定。即，基座74與基台環71藉由連結部72而固定地連結，保持部7成為石英之一體成形構件。此種保持部7之基台環71支持於腔室6之壁面，藉此，將保持部7安裝於腔室6。於將保持部7安裝於腔室6之狀態下，大致圓板形狀之基座74成為水平姿勢(法線與鉛垂方向一致之姿勢)。搬入至腔室6之半導體晶圓W以水平姿勢載置並保持於安裝於腔室6之保持部7之基座74上。半導體晶圓W載置於由5個導銷76形成之圓之內側，藉此，防止水平方向之位置偏移。再者，導銷76之個數並不限定於5個，只要為可防止半導體晶圓W之位置偏移之個數即可。 又，如圖2及圖3所示，於基座74上下貫通地形成有開口部78及缺口部77。缺口部77係用於供使用熱電偶之接觸式溫度計130之探針前端部通過而設置。另一方面，開口部78係用於輻射溫度計120接收自保持於基座74之半導體晶圓W之下表面輻射之輻射光(紅外光)而設置。進而，於基座74穿設有下述之移載機構10之頂起銷12為交付半導體晶圓W而貫通之4個貫通孔79。 圖5係移載機構10之俯視圖。又，圖6係移載機構10之側視圖。移載機構10具備2條移載臂11。移載臂11設為如沿著大致圓環狀之凹部62般之圓弧形狀。於各個移載臂11豎立設置有2根頂起銷12。各移載臂11設為能夠藉由水平移動機構13而旋動。水平移動機構13使一對移載臂11於相對於保持部7進行半導體晶圓W之移載之移載動作位置(圖5之實線位置)與和保持於保持部7之半導體晶圓W於俯視下不重疊之退避位置(圖5之二點鏈線位置)之間水平移動。作為水平移動機構13，可為藉由個別之馬達而分別使各移載臂11旋動者，亦可為使用連桿機構藉由1個馬達使一對移載臂11連動地旋動者。 又，一對移載臂11藉由升降機構14而與水平移動機構13一同升降移動。若升降機構14使一對移載臂11於移載動作位置上升，則共4根頂起銷12通過穿設於基座74之貫通孔79(參照圖2、3)且頂起銷12之上端自基座74之上表面突出。另一方面，若升降機構14使一對移載臂11於移載動作位置下降而將頂起銷12自貫通孔79抽出，且水平移動機構13使一對移載臂11以打開之方式移動，則各移載臂11移動至退避位置。一對移載臂11之退避位置係保持部7之基台環71之正上方。由於基台環71載置於凹部62之底面，故而移載臂11之退避位置成為凹部62之內側。 返回圖1，設置於腔室6之上方之閃光加熱部5於殼體51之內側具備包含複數根(本實施形態中為30根)氙氣閃光燈FL之光源、及以覆蓋該光源之上方之方式設置之反射器52而構成。又，於閃光加熱部5之殼體51之底部安裝有燈光輻射窗53。構成閃光加熱部5之地板部之燈光輻射窗53係由石英形成之板狀之石英窗。閃光加熱部5設置於腔室6之上方，藉此，成為燈光輻射窗53與上側腔室窗63相對向。閃光燈FL自腔室6之上方經由燈光輻射窗53及上側腔室窗63對熱處理空間65照射閃光。 複數個閃光燈FL係分別具有長條之圓筒形狀之棒狀燈，且以各自之長邊方向沿著保持於保持部7之半導體晶圓W之主面(即沿著水平方向)相互平行之方式呈平面狀排列。由此，藉由閃光燈FL之排列而形成之平面亦為水平面。 氙氣閃光燈FL具備：棒狀之玻璃管(放電管)，其內部封入有氙氣且其兩端部配設有與電容器連接之陽極及陰極；及觸發電極，其附設於該玻璃管之外周面上。氙氣為電性絕緣體，因此，即便於電容器儲存有電荷，於通常之狀態下電亦不會流入至玻璃管內。然而，於對觸發電極施加高電壓而破壞絕緣之情形時，儲存於電容器之電瞬時流入至玻璃管內，藉由此時之氙原子或分子之激發而放出光。於此種氙氣閃光燈FL中，預先儲存於電容器之靜電能量轉換為0.1毫秒至100毫秒之極短之光脈衝，因此，與如鹵素燈HL般連續點亮之光源相比具有能夠照射極強之光之特徵。即，閃光燈FL係以未達1秒之極短之時間瞬間發光之脈衝發光燈。再者，閃光燈FL之發光時間可藉由對閃光燈FL進行電力供給之燈電源之線圈常數來調整。 又，反射器52於複數個閃光燈FL之上方以覆蓋其等全體之方式設置。反射器52之基本功能係將自複數個閃光燈FL出射之閃光向熱處理空間65之側反射。反射器52係由鋁合金板形成，其表面(面向閃光燈FL之側之面)係藉由噴砂處理而實施粗糙面化加工。 設置於腔室6之下方之鹵素加熱部4於殼體41之內側內置有複數根(本實施形態中為40根)鹵素燈HL。鹵素加熱部4係藉由複數個鹵素燈HL進行自腔室6之下方經由下側腔室窗64向熱處理空間65之光照射而加熱半導體晶圓W之光照射部。 圖7係表示複數個鹵素燈HL之配置之俯視圖。40根鹵素燈HL分為上下2段而配置。於靠近保持部7之上段配設20根鹵素燈HL，並且於較上段更遠離保持部7之下段亦配設有20根鹵素燈HL。各鹵素燈HL係具有長條之圓筒形狀之棒狀燈。上段、下段均20根鹵素燈HL以各自之長邊方向沿著保持於保持部7之半導體晶圓W之主面(亦即沿著水平方向)相互平行之方式排列。由此，上段、下段均係藉由鹵素燈HL之排列而形成之平面為水平面。 又，如圖7所示，上段、下段均係較與保持於保持部7之半導體晶圓W之中央部對向之區域，而與周緣部對向之區域中之鹵素燈HL之配設密度變高。即，上下段均係較燈排列之中央部，而周緣部之鹵素燈HL之配設間距更短。因此，於利用來自鹵素加熱部4之光照射之加熱時，可對容易產生溫度降低之半導體晶圓W之周緣部進行更多之光量之照射。 又，由上段之鹵素燈HL所構成之燈群與由下段之鹵素燈HL所構成之燈群以呈格子狀交叉之方式排列。即，以配置於上段之20根鹵素燈HL之長邊方向與配置於下段之20根鹵素燈HL之長邊方向相互正交之方式配設有共40根鹵素燈HL。 鹵素燈HL係藉由對配設於玻璃管內部之燈絲通電而使燈絲白熱化並發光之燈絲方式之光源。於玻璃管之內部封入有於氮氣或氬等惰性氣體微量導入鹵素元素(碘、溴等)而成之氣體。藉由導入鹵素元素，能夠抑制燈絲之折損並且將燈絲之溫度設定為高溫。因此，鹵素燈HL與通常之白熾燈泡相比具有壽命長且能夠連續地照射強光之特性。即，鹵素燈HL係至少1秒以上連續發光之連續照明燈。又，鹵素燈HL係棒狀燈，因此壽命長，藉由使鹵素燈HL沿著水平方向配置，成為向上方之半導體晶圓W之輻射效率優異者。 又，於鹵素加熱部4之殼體41內，亦於2段鹵素燈HL之下側設置有反射器43(圖1)。反射器43將自複數個鹵素燈HL出射之光向熱處理空間65之側反射。 控制部3控制設置於熱處理裝置1之上述各種動作機構。作為控制部3之硬體之構成係與一般之電腦同樣。即，控制部3具備作為進行各種運算處理之電路之CPU(Central Processing Unit，中央處理單元)、作為記憶基本程式之讀出專用之記憶體之ROM(Read Only Memory，唯讀記憶體)、作為記憶各種資訊之讀寫自如之記憶體之RAM(Random Access Memory，隨機存取記憶體)及記憶控制用軟體或資料等之磁碟。控制部3之CPU藉由執行特定之處理程式而進行熱處理裝置1之處理。又，控制部3控制閥84、閥89、流量調整閥90、流量調整閥196、排氣泵191、及3個排氣閥192、193、194而調整腔室6內之熱處理空間65之壓力、供氣流量及排氣速率。 除上述構成以外，熱處理裝置1為了防止於半導體晶圓W之熱處理時因自鹵素燈HL及閃光燈FL產生之熱能導致之鹵素加熱部4、閃光加熱部5及腔室6的過度之溫度上升，亦具備各種冷卻用構造。例如，於腔室6之壁體設置有水冷管(省略圖示)。又，鹵素加熱部4及閃光加熱部5設為於內部形成氣體流而進行排熱之空冷構造。又，對於上側腔室窗63與燈光輻射窗53之間隙亦供給空氣，從而將閃光加熱部5及上側腔室窗63冷卻。 其次，對在熱處理裝置1之半導體晶圓W之處理順序進行說明。此處成為處理對象之半導體晶圓W係於矽基材上成膜有金屬膜之半導體基板。藉由熱處理裝置1對該半導體晶圓W照射閃光進行加熱而進行矽化物形成。 圖9係表示於半導體晶圓W成膜有金屬膜之構造之圖。於半導體晶圓W之矽基材101上形成有矽氧化膜(SiO2 )102。矽氧化膜102係作為矽基材101與高介電率膜103之間之界面層膜必需之層。矽氧化膜102之膜厚極薄，例如為約1 nm。作為矽氧化膜102之形成方法，例如可採用熱氧化法等公知之各種方法。 於矽氧化膜102上形成有作為閘極絕緣膜之高介電率膜103。作為高介電率膜103，例如可使用HfO2 、ZrO2 、Al2 O3 、La2 O3 等高介電率材料(本實施形態中為HfO2 )。高介電率膜103例如藉由利用ALD(Atomic Layer Deposition，原子層沈積)使高介電率材料沈積於矽氧化膜102上而成膜。沈積於矽氧化膜102上之高介電率膜103之膜厚為數nm，但該矽氧化膜換算膜厚(EOT：Equivalent oxide thickness)為1 nm左右。高介電率膜103之形成方法並不限定於ALD，例如可採用MOCVD(Metal Organic Chemical Vapor Deposition，金屬有機氣相沈積)等公知之方法。 於高介電率膜103上形成有閘極電極105。本實施形態之閘極電極105係由鈦(Ti)或鈦之氮化物(TiN)形成之所謂金屬閘極電極。再者，作為閘極電極105，亦可代替金屬閘極電極而使用多晶矽。又，於閘極電極105之兩側方形成有SiN之側牆104。該側牆104於後閘極製程中先於高介電率膜103形成。 矽基材101之上表面中之閘極電極105之兩側方成為源極/汲極區域(圖9之以虛線區分之區域)。於該源極/汲極區域藉由離子注入裝置而注入離子。 而且，於該源極/汲極區域上成膜有金屬膜108。矽化物技術中使用之金屬材料例如為鎳(Ni)、鈷(Co)、鈦(Ti)、鎢(W)等(本實施形態中為鎳)。金屬膜108之成膜可藉由濺鍍或真空蒸鍍等公知之成膜技術進行。 對如圖9所示之於矽基材101之源極/汲極區域上成膜有金屬膜108之半導體晶圓W之熱處理係藉由熱處理裝置1進行。以下，對熱處理裝置1中之動作順序進行說明。熱處理裝置1中之動作順序係藉由控制部3控制熱處理裝置1之各動作機構而進行。 首先，將成膜有金屬膜108之半導體晶圓W搬入至熱處理裝置1之腔室6。於半導體晶圓W之搬入時，閘閥185打開而將搬送開口部66開放，藉由裝置外部之搬送機器人經由搬送開口部66而將成膜有金屬膜108之半導體晶圓W搬入至腔室6內之熱處理空間65。此時，腔室6之內外同為大氣壓，因此，伴隨著半導體晶圓W之搬入，而將空氣捲入至腔室6內之熱處理空間65。因此，亦可藉由將閥84開放自氣體供給源85對腔室6內持續供給氮氣而使氮氣流自開放之搬送開口部66流出，從而將裝置外部之氛圍氣體向腔室6內之流入抑制於最小限度。又，較佳為於閘閥185開放時，使氮氣之供給流量較半導體晶圓W之熱處理時增大(例如，若於熱處理時通常為30升/分鐘，則於閘閥185開放時設為120升/分鐘)。進而，較佳為使氮氣之供給流量增大，並且將閥89關閉而停止自腔室6之排氣。藉此，供給至腔室6內之氮氣僅自搬送開口部66流出，因此，可更有效地防止外部空氣之流入。 藉由搬送機器人搬入之半導體晶圓W前進至保持部7之正上方位置為止而停止。然後，移載機構10之一對移載臂11自退避位置水平移動至移載動作位置並上升，藉此，頂起銷12通過貫通孔79自基座74之上表面突出而接收半導體晶圓W。 半導體晶圓W載置於頂起銷12之後，搬送機器人自熱處理空間65退出，藉由閘閥185將搬送開口部66閉鎖。然後，一對移載臂11下降，藉此，半導體晶圓W自移載機構10交付至保持部7之基座74並保持為水平姿勢。將半導體晶圓W以成膜有金屬膜108之表面為上表面而保持於基座74。又，半導體晶圓W於基座74之上表面被保持於5個導銷76之內側。下降至基座74之下方為止之一對移載臂11藉由水平移動機構13而退避至退避位置、即凹部62之內側。 將半導體晶圓W收容於腔室6且藉由閘閥185將搬送開口部66閉鎖之後，將腔室6內減壓至較大氣壓低之氣壓。具體而言，藉由將搬送開口部66閉鎖，腔室6內之熱處理空間65成為密閉空間。於此狀態下，將用於供氣之閥84關閉並且將用於排氣之閥89開放。又，控制部3使排氣泵191作動並且將設置於3條旁通路線197、198、199中之配管直徑最小之旁通路線197之排氣閥192開放。將其他排氣閥193、194關閉。藉此，不對腔室6內進行氣體供給而進行排氣，從而將腔室6內之熱處理空間65減壓。 圖10係表示第1實施形態中之腔室6內之壓力變化之圖。於該圖之橫軸表示時刻，於縱軸表示腔室6內之壓力。於將半導體晶圓W收容於腔室6且將搬送開口部66閉鎖之時點，腔室6內之壓力為常壓Ps(＝大氣壓＝約101325 Pa)。然後，於時刻t1開始腔室6內之減壓。於減壓之初始階段僅使用3條旁通路線197、198、199中之配管直徑最小之旁通路線197，因此，排氣流量小且排氣速度亦較慢。 其次，於時刻t2，控制部3將3個排氣閥192、193、194全部開放。藉此，來自腔室6之排氣流量增大，排氣速度亦變快。然後，於時刻t3腔室6之壓力(真空度)到達至氣壓P1。氣壓P1例如為約100 Pa。即，於減壓之初始階段以小排氣流量進行排氣之後，切換為較其更大之排氣流量進行排氣。再者，於第1實施形態中，流量調整閥196之流量固定。 若自減壓開始時以大排氣流量急速地進行排氣，則有於腔室6內產生大氣流變化而捲起附著於腔室6之構造物(例如下側腔室窗64)的微粒並使之再附著於半導體晶圓W而造成污染之虞。若於減壓之初始階段以較小之排氣流量平靜地進行排氣之後，切換為大排氣流量進行排氣，則可防止此種腔室6內之微粒之捲起。 於腔室6內之壓力到達至氣壓P1之時刻t3，將用於排氣之閥89關閉且將用於供氣之閥84開放，自氣體供給源85對腔室6內之熱處理空間65供給氮氣。其結果為，於腔室6內於保持於保持部7之半導體晶圓W之周邊形成氮氣氛圍氣體。再者，亦可於對腔室6供給氮氣之期間進行僅使用配管直徑最小之旁通路線197之自腔室6之排氣。於此情形時，當然處理氣體之供給流量大於排氣流量。 藉由對腔室6內供給氮氣，腔室6內之壓力自氣壓P1上升並於時刻t4恢復壓力至常壓Ps。於第1實施形態中，由於將腔室6內暫時先減壓至氣壓P1為止之後恢復壓力至常壓Ps，故而可使恢復壓力至常壓Ps後之腔室6內之氮氣氛圍氣體中之氧濃度為約200 ppb以下。 於將腔室6內之壓力恢復壓力至常壓Ps之時刻t4以後，使對腔室6之氮氣之供給流量與自腔室6之排氣流量相等從而將腔室6內之壓力維持為常壓Ps。 又，於將腔室6內之壓力恢復壓力至常壓Ps之時刻t4，將鹵素加熱部4之40根鹵素燈HL同時點亮，開始半導體晶圓W之預加熱(輔助加熱)。自鹵素燈HL出射之鹵素光透過由石英形成之下側腔室窗64及基座74而自半導體晶圓W之背面照射。所謂半導體晶圓W之背面係與成膜有金屬膜108之表面為相反側之主面。藉由接受來自鹵素燈HL之光照射而使半導體晶圓W之溫度上升。再者，由於移載機構10之移載臂11退避至凹部62之內側，故而不會成為利用鹵素燈HL之加熱之障礙。 於進行利用鹵素燈HL之預加熱時，半導體晶圓W之溫度係利用接觸式溫度計130測定。即，內置熱電偶之接觸式溫度計130經由缺口部77接觸於被保持於基座74之半導體晶圓W的下表面而測定升溫中之晶圓溫度。測定之半導體晶圓W之溫度被傳達至控制部3。控制部3一面監控藉由自鹵素燈HL之光照射而升溫之半導體晶圓W之溫度是否到達至特定之預加熱溫度T1，一面控制鹵素燈HL之輸出。即，控制部3基於接觸式溫度計130之測定值，以半導體晶圓W之溫度成為預加熱溫度T1之方式對鹵素燈HL之輸出進行反饋控制。預加熱溫度T1為室溫以上300℃以下，於本實施形態中為200℃。再者，於藉由來自鹵素燈HL之光照射而使半導體晶圓W升溫時，不進行利用輻射溫度計120之溫度測定。其原因在於：自鹵素燈HL照射之鹵素光作為環境光而入射至輻射溫度計120，無法進行準確之溫度測定。 於半導體晶圓W之溫度到達至預加熱溫度T1之後，控制部3將半導體晶圓W暫時維持為該預加熱溫度T1。具體而言，於藉由接觸式溫度計130測定之半導體晶圓W之溫度到達至預加熱溫度T1之時點，控制部3調整鹵素燈HL之輸出，將半導體晶圓W之溫度維持為大致預加熱溫度T1。 藉由進行此種利用鹵素燈HL之預加熱，使包含金屬膜108之半導體晶圓W之整體均勻升溫至預加熱溫度T1。於利用鹵素燈HL之預加熱之階段，更容易產生散熱之半導體晶圓W之周緣部之溫度有較中央部更降低之傾向，但鹵素加熱部4之鹵素燈HL之配設密度係較與半導體晶圓W之中央部對向之區域，而與周緣部對向之區域較高。因此，對容易產生散熱之半導體晶圓W之周緣部照射之光量變多，可使預加熱階段之半導體晶圓W之面內溫度分佈均勻。進而，由於安裝於腔室側部61之反射環69之內周面設為鏡面，故而藉由該反射環69之內周面朝向半導體晶圓W之周緣部反射之光量變多，從而可使預加熱階段之半導體晶圓W之面內溫度分佈更均勻。再者，預加熱時之腔室6內之壓力維持為常壓Ps。 其次，於半導體晶圓W之溫度到達預加熱溫度T1且經過特定時間之時刻t5，執行藉由自閃光燈FL照射閃光之閃光加熱處理。此時，自閃光燈FL輻射之閃光之一部分直接射向腔室6內，另一部分暫時藉由反射器52反射後射向腔室6內，藉由該等閃光之照射而進行半導體晶圓W之閃光加熱。 閃光加熱係藉由來自閃光燈FL之閃光(閃光)照射而進行，因此，可使半導體晶圓W之表面溫度於較短時間上升。即，自閃光燈FL照射之閃光係將預先儲存於電容器之靜電能量轉換為極短之光脈衝之照射時間為0.1毫秒以上100毫秒以下左右之極短且較強之閃光。藉由自閃光燈FL對成膜有金屬膜108之半導體晶圓W之表面照射閃光而使源極/汲極區域之矽與金屬膜108反應，從而形成矽化物(本實施形態中為鎳矽化物)。 藉由閃光照射而半導體晶圓W之表面到達之最高溫度(峰值溫度)即處理溫度T2係矽化物成長之600℃以上1100℃以下，於本實施形態中設為900℃。再者，由於自閃光燈FL之照射時間為0.1毫秒以上100毫秒以下左右之短時間，故而半導體晶圓W之表面溫度自預加熱溫度T1升溫至處理溫度T2為止所需之時間亦為未達1秒之極短時間。閃光照射後之半導體晶圓W之表面溫度自處理溫度T2立即急速地下降。 於閃光加熱處理結束之後，經過特定時間之後鹵素燈HL亦熄滅。藉此，半導體晶圓W自預加熱溫度T1亦降溫。降溫中之半導體晶圓W之溫度係藉由接觸式溫度計130或輻射溫度計120而測定，其測定結果被傳達至控制部3。控制部3係自測定結果監控半導體晶圓W之溫度是否降溫至特定溫度為止。而且，於半導體晶圓W之溫度降溫至特定以下之後，移載機構10之一對移載臂11再次自退避位置水平移動至移載動作位置並上升，藉此，頂起銷12自基座74之上表面突出而自基座74接收熱處理後之半導體晶圓W。繼而，將藉由閘閥185而閉鎖之搬送開口部66開放，藉由裝置外部之搬送機器人將載置於頂起銷12上之半導體晶圓W搬出，於熱處理裝置1之半導體晶圓W之加熱處理結束。 於第1實施形態中，將腔室6內暫時減壓至較大氣壓低之氣壓P1之後供給氮氣而恢復壓力至常壓Ps，因此，可使恢復壓力後之腔室6內之氧濃度為約200 ppb以下。於不對腔室6內進行減壓而於維持常壓之狀態下進行自大氣向氮氣之氛圍氣體置換之情形時，可降低腔室6內之氧濃度之極限為約2 ppm。即，藉由如本實施形態般將腔室6內暫時減壓至氣壓P1之後恢復壓力至常壓Ps，與不進行減壓之情形相比，可將腔室6內之氧濃度降低至十分之一左右。 於矽基材101之源極/汲極區域上成膜金屬膜108之後，於未進行特別之處理之狀態下，於金屬膜108與矽基材101之界面附近存在多個缺陷。若於半導體晶圓W之周邊之氧濃度較高之狀態下進行矽化物形成之熱處理，則氛圍氣體中之氧進入至金屬膜108與基材101之界面附近之缺陷，其結果為，界面附近劣化而成為高電阻。又，亦存在鎳之矽化物本身被氧化之情況。作為此種氧化之原因，尤其成為問題者係殘留於腔室6內之氧。如本實施形態般，於在常壓下將半導體晶圓W搬入至腔室6內之情形時，來自外部之空氣之捲入較大，其會提高腔室6之殘留氧濃度。因此，較佳為對成膜有金屬膜108之半導體晶圓W進行加熱而形成矽化物時之氛圍氣體中之氧濃度儘可能地降低。 於第1實施形態中，藉由將腔室6內暫時減壓至較大氣壓低之氣壓P1之後恢復壓力至常壓Ps，而使形成矽化物時之腔室6內之熱處理空間65之氧濃度降低至約200 ppb以下。因此，可抑制於矽化物形成處理中熱處理空間65之氧進入至金屬膜108與基材101之界面附近之缺陷所導致的矽化物之高電阻化。又，亦可防止矽化物本身之氧化。 又，要求矽化物儘可能地形成得較薄，但於第1實施形態中，自閃光燈FL以未達1秒之照射時間對半導體晶圓W之表面照射閃光而以極短時間將晶圓表面升溫至處理溫度T2，因此，可抑制矽化物之膜厚過度地增大。 又，若於向腔室6搬入半導體晶圓W時使氮氣之供給流量增大而使其自搬送開口部66流出，則可防止晶圓搬入時之外部空氣之流入而降低處理前之腔室6內之氧濃度之初始值。藉此，即便對腔室6內進行減壓時之到達壓力即氣壓P1較高，亦可充分地降低殘留氧濃度。 進而，如上所述，於對腔室6內進行減壓時，於減壓開始時以較小之排氣流量進行排氣之後，切換為較大之排氣流量進行排氣，因此，可防止腔室6內之微粒之捲起。 ＜第2實施形態＞ 其次，對本發明之第2實施形態進行說明。第2實施形態之熱處理裝置1之構成與第1實施形態完全相同。又，第2實施形態之熱處理裝置1中之半導體晶圓W之處理順序亦與第1實施形態大致相同。第2實施形態與第1實施形態不同之處係於將腔室6內暫時減壓之後恢復壓力時之壓力。 圖11係表示第2實施形態中之腔室6內之壓力變化之圖。於圖11中，亦與圖10同樣地，於橫軸表示時刻，於縱軸表示腔室6內之壓力。又，圖11中虛線所示者係將第1實施形態中之腔室6內恢復壓力至常壓Ps為止時之壓力變化圖案(圖10之圖案)。 與第1實施形態同樣地，於將成膜有金屬膜108之半導體晶圓W收容於腔室6並將搬送開口部66閉鎖之時點，腔室6內之壓力為常壓Ps(＝大氣壓＝約101325 Pa)。然後，於時刻t1開始腔室6內之減壓。與第1實施形態相同，於減壓之初始階段以較小之排氣流量進行排氣之後，於時刻t2切換為較其更大之排氣流量進行排氣。藉此，可防止腔室6內之微粒之捲起。 於腔室6內之壓力到達氣壓P1之時刻t3，將用於排氣之閥89關閉且開放用於供氣之閥84，自氣體供給源85對腔室6內之熱處理空間65供給氮氣。至此為止係與第1實施形態相同。再者，氣壓P1例如為約100 Pa。 於第2實施形態中，未使腔室6內之壓力恢復壓力至常壓Ps為止，而藉由供給氮氣於時刻t6使腔室6內之壓力恢復壓力至氣壓P2為止。氣壓P2高於氣壓P1，且低於常壓Ps，例如為約5000 Pa。於第2實施形態中亦使腔室6內暫時減壓至氣壓P1之後恢復壓力至較其更高之氣壓P2，因此，可使恢復壓力後之腔室6內之氧濃度為約200 ppb以下。 於腔室6內之壓力恢復壓力至氣壓P2之時刻t6以後，使對腔室6之氮氣之供給流量與自腔室6之排氣流量相等而將腔室6內之壓力維持為氣壓P2。然後，一面將腔室6內之壓力維持為氣壓P2，一面進行利用鹵素燈HL之半導體晶圓W之預加熱，進而，其後於時刻t7自閃光燈FL對半導體晶圓W之表面照射閃光而進行閃光加熱。預加熱及閃光加熱處理之內容係與第1實施形態相同。藉由自閃光燈FL對成膜有金屬膜108之半導體晶圓W之表面照射閃光而使源極/汲極區域之矽與金屬膜108反應從而形成矽化物。 於閃光加熱處理結束後，於經過特定時間後將用於排氣之閥89關閉且將用於供氣之閥84開放，自氣體供給源85對腔室6內供給氮氣而恢復壓力至常壓Ps為止。又，鹵素燈HL亦熄滅，藉此半導體晶圓W亦自預加熱溫度T1降溫。其後，將降溫至特定溫度為止之半導體晶圓W自熱處理裝置1之腔室6搬出之順序係與第1實施形態相同。 此外，作為於腔室6內捲起微粒之主要原因，除對腔室6之供氣排氣以外，閃光照射亦為原因。於自閃光燈FL之閃光照射時，半導體晶圓W之表面瞬間升溫，另一方面背面並未自預加熱溫度T1那般升溫，因此，於正背面產生較大之溫度差，僅表面熱膨脹而半導體晶圓W急遽地變形。其結果為，因半導體晶圓W於基座74上振動而產生微粒並於腔室6內捲起。 為了將此種起因於閃光照射之微粒有效地自腔室6排出，於第2實施形態中，於閃光加熱處理結束並對腔室6內供給氮氣而恢復壓力至常壓Ps時，將用於排氣之閥89開放並且以50升/分鐘以上100升/分鐘以下之流量使氮氣流入至腔室6內，藉此，將起因於閃光照射之微粒衝出。藉此，可防止起因於閃光照射之微粒附著於半導體晶圓W而造成污染。 再者，於閃光加熱結束後對腔室6內供給氮氣而恢復壓力至常壓Ps時，亦可於將用於排氣之閥89開放之狀態下將用於供氣之閥84亦開放而對腔室6內供給氮氣。若如此，則可將起因於閃光照射之微粒更有效地自腔室6排氣。 於第2實施形態中，由於在將腔室6內暫時減壓至較大氣壓低之氣壓P1之後供給氮氣而恢復壓力至氣壓P2，故而可與第1實施形態同樣地使執行矽化物形成之熱處理時之腔室6內之熱處理空間65之氧濃度為約200 ppb以下。因此，可抑制因矽化物形成處理中熱處理空間65之氧進入至金屬膜108與基材101之界面附近之缺陷所導致的矽化物之高電阻化。又，亦可防止矽化物本身之氧化。 又，與第1實施形態同樣地，自閃光燈FL以未達1秒之照射時間對半導體晶圓W之表面照射閃光而以極短時間使晶圓表面升溫至處理溫度T2，因此，可抑制矽化物之膜厚過度地增大。 又，若於減壓下進行熱處理，則可促進金屬膜108中所包含之雜質之脫離。藉由將此種脫離之雜質元素自腔室6排出，可防止該雜質再附著於半導體晶圓W之表面而造成污染。其結果為，可防止器件性能之劣化及良率之降低。 又，由於利用腔室6內之氛圍氣體氣體之鹵素燈光及閃光之吸光變少，故而可提高預加熱時及閃光加熱時之升溫效率。其結果為，可提高閃光加熱時之半導體晶圓W之表面到達溫度。 又，藉由於減壓下進行半導體晶圓W之加熱處理，可減少腔室6內之對流之影響，且可提高半導體晶圓W之面內溫度分佈之均一性。 進而，於第2實施形態中，於使腔室6內之壓力自氣壓P1恢復壓力時，未恢復壓力至常壓Ps為止而恢復壓力至較大氣壓低之氣壓P2。因此，與如第1實施形態般將腔室6內之壓力恢復壓力至常壓Ps相比，若如第2實施形態般恢復壓力至氣壓P2，則可縮短恢復壓力所需之時間。而且，可將閃光照射之時間提前有縮短恢復壓力所需之時間之量(如圖11所示，第2實施形態中之閃光照射之時刻t7早於第1實施形態中之閃光照射之時刻t5)。其結果為，如第2實施形態般將腔室6內之壓力恢復壓力至較大氣壓低之氣壓P2可提高熱處理裝置1之產量。 ＜第3實施形態＞ 其次，對本發明之第3實施形態進行說明。第3實施形態之熱處理裝置1之構成係與第1實施形態完全相同。又，第3實施形態之熱處理裝置1中之半導體晶圓W之處理順序亦與第1實施形態大致相同。第3實施形態與第1實施形態不同之處係腔室6內之壓力變化。 圖12係表示第3實施形態中之腔室6內之壓力變化之圖。於圖12中，亦與圖10同樣地，於橫軸表示時刻，於縱軸表示腔室6內之壓力。 與第1實施形態同樣地，於將成膜有金屬膜108之半導體晶圓W收容於腔室6並將搬送開口部66閉鎖之時點，腔室6內之壓力為常壓Ps(＝大氣壓＝約101325 Pa)。然後，於時刻t1開始腔室6內之減壓。於第3實施形態中，使利用3條旁通路線197、198、199之排氣流量固定，並且藉由流量調整閥196使自腔室6之排氣流量隨時間連續地增加。即，於減壓之初始階段以相對小之排氣流量開始排氣，且逐漸連續地使排氣流量增加。若如此，則可與第1實施形態同樣地防止腔室6內之微粒之捲起。又，藉由使排氣流量無階段地連續地增加，亦可防止因排氣流量之急遽之變化導致之微粒的捲起。 於腔室6內之壓力到達氣壓P1之時刻t3，將用於排氣之閥89關閉且將用於供氣之閥84開放，自氣體供給源85對腔室6內之熱處理空間65供給氮氣而將腔室6內恢復壓力。再者，氣壓P1例如為約100 Pa。 於第3實施形態中，藉由流量調整閥90使向腔室6之處理氣體之供氣流量隨時間連續地增加。即，於恢復壓力之初始階段以相對小之供氣流量開始供氣，且逐漸連續地使供氣流量增加。與減壓時同樣地，若自恢復壓力之開始時以較大之供氣流量急速地進行供氣，則有附著於腔室6之構造物之微粒被捲起之虞。藉由於恢復壓力之初始階段以較小之供氣流量平靜地開始供氣，且逐漸增大排氣流量，可防止此種腔室6內之微粒之捲起。又，藉由使供氣流量無階段地連續地增加，亦可防止因供氣流量之急遽之變化導致的微粒之捲起。 又，於第3實施形態中，藉由對腔室6供給氮氣而於時刻t8使腔室6內之壓力恢復壓力至超過常壓Ps之氣壓P3。氣壓P3高於大氣壓，例如為約0.12 MPa。於第3實施形態中，亦將腔室6內暫時減壓至氣壓P1為止後恢復壓力至較其更高之氣壓P3，因此，可使恢復壓力後之腔室6內之氧濃度為約200 ppb以下。 於腔室6內之壓力恢復壓力至氣壓P3之時刻t8以後，使對腔室6之氮氣之供給流量與自腔室6之排氣流量相等而將腔室6內之壓力維持為氣壓P3。然後，一面將腔室6內之壓力維持為氣壓P3，一面進行利用鹵素燈HL之半導體晶圓W之預加熱，進而，其後於時刻t9自閃光燈FL對半導體晶圓W之表面照射閃光而進行閃光加熱。預加熱及閃光加熱處理之內容係與第1實施形態相同。藉由自閃光燈FL對成膜有金屬膜108之半導體晶圓W之表面照射閃光而使源極/汲極區域之矽與金屬膜108反應從而形成矽化物。 於閃光加熱處理結束後，自氣體排氣管88將腔室6內之氣體排出而使腔室6內為常壓Ps。又，鹵素燈HL亦熄滅，藉此，半導體晶圓W亦自預加熱溫度T1降溫。其後，將降溫至特定溫度為止之半導體晶圓W自熱處理裝置1之腔室6搬出之順序係與第1實施形態相同。 於第3實施形態中，於將腔室6內暫時減壓至較大氣壓低之氣壓P1之後供給氮氣而恢復壓力至氣壓P3，因此，可與第1實施形態同樣地使執行矽化物形成之熱處理時之腔室6內之熱處理空間65之氧濃度為約200 ppb以下。因此，可抑制因矽化物形成處理中熱處理空間65之氧進入至金屬膜108與基材101之界面附近之缺陷所導致的矽化物之高電阻化。又，亦可防止矽化物本身之氧化。 又，與第1實施形態同樣地，自閃光燈FL以未達1秒之照射時間對半導體晶圓W之表面照射閃光而於極短時間使晶圓表面升溫至處理溫度T2，因此，可抑制矽化物之膜厚過度地增大。 又，於第3實施形態中，於腔室6內之壓力較大氣壓高之氣壓P3下，亦即於加壓下對半導體晶圓W之表面照射閃光而進行加熱處理。只要於加壓下進行熱處理，則可抑制自腔室側部61等放出之氧之擴散速度變慢而到達半導體晶圓W。 進而，於第3實施形態中，於腔室6內之減壓時及恢復壓力時，使排氣流量及供氣流量無階段地連續變化。藉此，可防止因供氣排氣之急遽之變化導致的微粒之捲起。 ＜第4實施形態＞ 其次，對本發明之第4實施形態進行說明。第4實施形態之熱處理裝置1之構成係與第1實施形態完全相同。又，第4實施形態之熱處理裝置1中之半導體晶圓W之處理順序亦與第1實施形態大致相同。第4實施形態與第1實施形態不同之處係腔室6內之壓力變化。 圖13係表示第4實施形態中之腔室6內之壓力變化之圖。於圖13中亦與圖10同樣地，於橫軸表示時刻，於縱軸表示腔室6內之壓力。 與第1實施形態同樣地，於將成膜有金屬膜108之半導體晶圓W收容於腔室6並將搬送開口部66閉鎖之時點，腔室6內之壓力為常壓Ps(＝大氣壓＝約101325 Pa)。然後，於時刻t1開始腔室6內之減壓。與第1實施形態同樣地，於減壓之初始階段以較小之排氣流量進行排氣之後，於時刻t2切換為較其更大之排氣流量進行排氣。藉此，可防止腔室6內之微粒之捲起。 於腔室6內之壓力到達氣壓P1之時刻t3，將用於排氣之閥89關閉。而且，於第4實施形態中，未將氮氣導入於腔室6內而將腔室6內之壓力維持為氣壓P1。再者，為了將腔室6內之壓力維持為氣壓P1，亦可將閥89開放而持續排氣。 於第4實施形態中，將腔室6內減壓至氣壓P1為止，其後亦維持為氣壓P1，因此，可使腔室6內之殘留氧濃度為約200 ppb以下。然後，一面將腔室6內之壓力維持為氣壓P1，一面進行利用鹵素燈HL之半導體晶圓W之預加熱，進而，其後於時刻t10自閃光燈FL對半導體晶圓W之表面照射閃光而進行閃光加熱。預加熱及閃光加熱處理之內容係與第1實施形態相同。藉由自閃光燈FL對成膜有金屬膜108之半導體晶圓W之表面照射閃光而使源極/汲極區域之矽與金屬膜108反應從而形成矽化物。 於閃光加熱處理結束後，於經過特定時間後將用於供氣之閥84開放，自氣體供給源85將氮氣供給至腔室6內而使之恢復壓力至常壓Ps為止。又，鹵素燈HL亦熄滅，藉此，半導體晶圓W亦自預加熱溫度T1降溫。其後，將降溫至特定溫度之半導體晶圓W自熱處理裝置1之腔室6搬出之順序係與第1實施形態相同。 於第4實施形態中，將腔室6內減壓至較大氣壓低之氣壓P1之後就這樣維持為氣壓P1，因此，可與第1實施形態同樣地使執行矽化物形成之熱處理時之腔室6內之熱處理空間65之氧濃度為約200 ppb以下。因此，可抑制因矽化物形成處理中熱處理空間65之氧進入至金屬膜108與基材101之界面附近之缺陷所導致的矽化物之高電阻化。又，亦可防止矽化物本身之氧化。 又，與第1實施形態同樣地自閃光燈FL以未達1秒之照射時間對半導體晶圓W之表面照射閃光而於極短時間使晶圓表面升溫至處理溫度T2，因此，可抑制矽化物之膜厚過度地增大。 又，藉由於減壓下進行半導體晶圓W之熱處理，可獲得與第2實施形態同樣之效果。進而，於金屬膜108為鈦之情形時，即便於氮氣氛圍中進行熱處理亦有金屬膜108被氮化之虞，但若如第4實施形態般於極低壓下進行半導體晶圓W之熱處理則可抑制金屬膜108之氮化。 ＜變化例＞ 以上，對本發明之實施形態進行了說明，但本發明於不脫離其主旨之範圍內可於除上述者以外進行各種變更。例如，於上述各實施形態中，使對腔室6內進行減壓時之到達壓力即氣壓P1為約100 Pa，但並不限定於此，可設為適當之值。為了將腔室6內之到達氧濃度降低至10分之1左右，只要使對腔室6內進行減壓時之到達壓力即氣壓P1為大氣壓之約10分之1(約10000 Pa)即可。若使氣壓P1為更低壓(亦即，若減壓至更高真空)，則可更降低恢復壓力後殘留於腔室6內之氧濃度，但至到達氣壓P1為止之減壓時間變長。因此，較佳為自執行矽化物形成之熱處理時所必需之氧濃度與產量之平衡來設定氣壓P1。 又，於上述各實施形態中，藉由設置3條旁通路線197、198、199而控制自腔室6之排氣流量，但旁通路線之條數只要為2條以上即可。又，亦可代替設置複數條旁通路線197、198、199而藉由設置節流閥或氣體鎮流器來控制自腔室6之排氣流量。又，亦可代替流量調整閥90、196而使用質量流量控制器。 於第1及第2實施形態中將減壓時之自腔室6之排氣流量以2階段切換，於第3實施形態中使排氣流量無階段地連續增加，但並不限定於該等，例如，亦可將排氣流量多階段地切換。即，只要為對腔室6內進行減壓時之排氣流量隨時間增加之形態即可。 同樣地，關於恢復壓力時之向腔室6之供氣流量，亦於第3實施形態中使供氣流量無階段地連續增加，但亦可將其以2階段或多階段切換而增加。即，只要為使腔室6內恢復壓力時之供氣流量亦隨時間增加之形態即可。 又，於進行腔室6內之減壓及恢復壓力時，控制部3可基於自減壓開始時(時刻t1)之經過時間而控制各種閥等，亦可基於利用壓力計180之熱處理空間65之壓力之測定結果而對各種閥等進行反饋控制。於基於經過時間而進行控制之情形時，藉由實驗或模擬求出經過時間與腔室6內之壓力之關係即可。 又，於上述各實施形態中，於矽基材101上成膜金屬膜108而形成矽化物，但基材101之材質並不限定於矽，亦可為鍺(Ge)或矽鍺。尤其是，於製造PMOS(P-channel metal oxide semiconductor，P型金氧半導體)電晶體之情形時，使用矽鍺作為基材101。於基材101為鍺或矽鍺之情形時，於基材101上成膜金屬膜108，使鍺與金屬反應而形成鍺化物。即便基材101為鍺或矽鍺，對半導體晶圓W之處理亦與上述各實施形態相同。 又，上述各實施形態係抑制矽化物之高電阻化者，但本發明之技術亦可應用於Fin構造中之接觸電阻之降低。於Fin構造中，於基材101之一部分區域(接觸孔之開口部)沈積用於形成接觸之金屬膜(例如TiN膜)。藉由於形成該金屬膜與基材101之接觸(歐姆性接觸)中應用本發明之技術進行極低氧濃度下之熱處理，可降低接觸電阻。 又，於上述各實施形態中，於閃光加熱部5具備30根閃光燈FL，但並不限定於此，閃光燈FL之根數可設為任意數。又，閃光燈FL並不限定於氙氣閃光燈，亦可為氪氣閃光燈。又，鹵素加熱部4所具備之鹵素燈HL之根數亦並不限定於40根，只要為於上段及下段配置複數根之形態則可設為任意數。 又，於上述實施形態中，藉由來自鹵素燈HL之鹵素光照射而對半導體晶圓W進行預加熱，但預加熱之方法並不限定於此，亦可藉由載置於加熱板而對半導體晶圓W進行預加熱。Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings. <First Embodiment> Fig. 1 is a longitudinal sectional view showing the configuration of a heat treatment apparatus 1 of the present invention. The heat treatment apparatus 1 of the present embodiment is a flash lamp annealing apparatus that heats the semiconductor wafer W by flashing the disk-shaped semiconductor wafer W as a substrate. The size of the semiconductor wafer W to be processed is not particularly limited, for example
Figure 02_image001
300 mm or
Figure 02_image001
450 mm. The semiconductor wafer W before being carried into the heat treatment device 1 is formed with a metal film of nickel or the like, and a silicide, which is a compound of the metal and silicon, is formed and grown by heat treatment using the heat treatment device 1. In addition, in FIG. 1 and subsequent drawings, the size or number of each part is exaggerated or simplified as necessary for easy understanding. The heat treatment apparatus 1 includes: a chamber 6 that houses a semiconductor wafer W; a flash heating unit 5 that includes a plurality of flash lamps FL; and a halogen heating unit 4 that includes a plurality of halogen lamps HL. A flash heater 5 is provided above the chamber 6 and a halogen heater 4 is provided below. In addition, the heat treatment apparatus 1 includes a holding portion 7 that holds the semiconductor wafer W in a horizontal posture inside the chamber 6, and a transfer mechanism 10 that delivers the semiconductor wafer W between the holding portion 7 and the outside of the device. Furthermore, the heat treatment apparatus 1 includes a control unit 3 that controls the halogen heating unit 4, the flash heating unit 5, and each operating mechanism provided in the chamber 6 to perform heat treatment of the semiconductor wafer W and the like. The chamber 6 is configured by attaching a quartz chamber window to the cylindrical chamber side portion 61 above and below. The chamber side portion 61 has a generally cylindrical shape that opens up and down. The upper chamber window 63 is attached to the upper opening to close it, and the lower chamber window 64 is attached to the lower opening to close it. The upper chamber window 63 constituting the top wall of the chamber 6 is a disc-shaped member formed of quartz, and functions as a quartz window that transmits the flash light emitted from the flash heating unit 5 into the chamber 6. In addition, the lower chamber window 64 constituting the floor of the chamber 6 is also a disk-shaped member formed of quartz, and functions as a quartz window that transmits light from the halogen heating section 4 into the chamber 6. The thickness of the upper chamber window 63 and the lower chamber window 64 is, for example, about 28 mm. In addition, a reflection ring 68 is attached to the upper part of the inner wall surface of the chamber side 61, and a reflection ring 69 is attached to the lower part. The reflection rings 68 and 69 are both formed in a circular ring shape. The upper reflection ring 68 is installed by being fitted from the upper side of the chamber side 61. On the other hand, the lower reflection ring 69 is fitted by being fitted from the lower side of the chamber side 61 and fixed with screws not shown. In other words, the reflection rings 68 and 69 are detachably attached to the chamber side 61. The inner space of the chamber 6, that is, the space surrounded by the upper chamber window 63, the lower chamber window 64, the chamber side 61 and the reflection rings 68 and 69 is defined as the heat treatment space 65. Since the reflection rings 68 and 69 are installed on the side portion 61 of the chamber, a concave portion 62 is formed on the inner wall surface of the chamber 6. That is, a recess 62 surrounded by the central portion of the inner wall surface of the chamber side 61 where the reflection rings 68 and 69 are not mounted, the lower end surface of the reflection ring 68, and the upper end surface of the reflection ring 69 is formed. The recess 62 is formed in an annular shape along the horizontal direction on the inner wall surface of the chamber 6 and surrounds the holding portion 7 that holds the semiconductor wafer W. The chamber side portion 61 and the reflection rings 68 and 69 are formed of a metal material (for example, stainless steel) excellent in strength and heat resistance. In addition, the inner peripheral surfaces of the reflection rings 68 and 69 become mirror surfaces by electrolytic nickel plating. In addition, a transport opening (furnace opening) 66 is provided in the chamber side portion 61 to carry in and out the semiconductor wafer W with respect to the chamber 6. The transport opening 66 is opened and closed by the gate valve 185. The transport opening 66 is connected to the outer peripheral surface of the recess 62. Therefore, when the gate valve 185 opens the transport opening 66, the semiconductor wafer W can be carried into the heat treatment space 65 from the transport opening 66 through the recess 62 and the semiconductor wafer W can be carried out from the heat treatment space 65. When the gate valve 185 closes the transport opening 66, the heat treatment space 65 in the chamber 6 is a closed space. In addition, a gas supply hole 81 is provided in the upper portion of the inner wall of the chamber 6, and the gas supply hole 81 supplies a processing gas (nitrogen (N in this embodiment) 2 )). The gas supply hole 81 is provided above the recess 62, and may be provided in the reflection ring 68. The gas supply hole 81 is connected to the gas supply pipe 83 via a buffer space 82 formed in a ring shape inside the side wall of the chamber 6. The gas supply pipe 83 is connected to the gas supply source 85. The gas supply source 85 supplies nitrogen gas as a processing gas to the gas supply pipe 83 under the control of the control unit 3. In addition, a valve 84 and a flow rate adjustment valve 90 are interposed in the middle of the path of the gas supply pipe 83. When the valve 84 is opened, the processing gas is sent to the buffer space 82 from the gas supply source 85. The flow rate of the processing gas flowing through the gas supply pipe 83 and sent to the buffer space 82 is adjusted by the flow rate adjustment valve 90. The flow rate of the processing gas specified by the flow rate adjustment valve 90 is variable under the control of the control unit 3. The processing gas flowing into the buffer space 82 flows through the buffer space 82 having a fluid resistance smaller than that of the gas supply hole 81 and flows into the heat treatment space 65 from the gas supply hole 81. Furthermore, the processing gas is not limited to nitrogen, but may be inert gas such as argon (Ar), helium (He), or hydrogen (H 2 ), ammonia (NH 3 ), chlorine (Cl 2 ), hydrogen chloride (HCl) and other reactive gases. On the other hand, a gas exhaust hole 86 for exhausting the gas in the heat treatment space 65 is provided in the lower part of the inner wall of the chamber 6. The gas exhaust hole 86 is provided on the lower side of the recess 62, and may also be provided in the reflection ring 69. The gas exhaust hole 86 is connected to the gas exhaust pipe 88 via a buffer space 87 formed in an annular shape inside the side wall of the chamber 6. The gas exhaust pipe 88 is connected to the exhaust portion 190. In addition, a valve 89 is inserted in the middle of the path of the gas exhaust pipe 88. When the valve 89 is opened, the gas in the heat treatment space 65 is discharged from the gas exhaust hole 86 through the buffer space 87 to the gas exhaust pipe 88. Furthermore, the gas supply hole 81 and the gas exhaust hole 86 may be provided in plural along the circumferential direction of the chamber 6 or may be slit-shaped. FIG. 8 is a diagram showing the configuration of the exhaust unit 190. The exhaust unit 190 includes an exhaust pump 191, a flow rate adjustment valve 196, three bypass lines 197, 198, 199, and three exhaust valves 192, 193, 194. The gas exhaust pipe 88 that guides the exhaust gas from the chamber 6 and the exhaust pump 191 are connected by three bypass lines 197, 198, and 199. Three bypass lines 197, 198, and 199 are arranged in parallel. The piping diameters of the three bypass lines 197, 198, and 199 are different from each other. The diameter of the bypass line 197 is the smallest, the diameter of the bypass line 199 is the largest, and the diameter of the bypass line 198 is between them. As a result, the flow rate of the gas that can pass increases in the order of the bypass lines 197, 198, and 199. The three exhaust valves 192, 193, and 194 are provided on the three bypass lines 197, 198, and 199, respectively. That is, the exhaust valve 192 is inserted into the bypass passage line 197, the exhaust valve 193 is inserted into the bypass passage line 198, and the exhaust valve 194 is inserted into the bypass passage line 199. If the three exhaust valves 192, 193, 194 are opened while the exhaust pump 191 is actuated, the exhaust gas from the chamber 6 guided by the gas exhaust pipe 88 passes through the corresponding bypass lines 197, 198, 199 is sucked to the exhaust pump 191. The three bypass paths 197, 198, and 199 have different pipe diameters, so the exhaust capacity is different. The larger the pipe diameter, the larger the exhaust capacity, and the exhaust capacity increases in the order of the bypass lines 197, 198, and 199. Therefore, the flow rate of the exhaust gas from the chamber 6 can be controlled by opening or closing any of the three exhaust valves 192, 193, and 194. Only one of the three exhaust valves 192, 193, and 194 may be opened, or two or three may be opened. For example, when the exhaust valves 193 and 194 are closed and only the exhaust valve 192 is opened, exhaust is performed at the minimum exhaust flow rate. In addition, when all three exhaust valves 192, 193, and 194 are opened, exhaust is performed at the maximum exhaust flow rate. In addition, a flow regulating valve 196 is interposed between the junction of the three bypass lines 197, 198, and 199 and the exhaust pump 191. The exhaust flow rate of the gas exhaust pipe 88 can also be adjusted by the flow adjustment valve 196. The exhaust gas flow rate specified by the flow rate adjustment valve 196 is variable under the control of the control unit 3. The three by-pass lines 197, 198, and 199 are discontinuous and multi-stage mechanisms for adjusting the exhaust flow rate. In contrast, the flow adjustment valve 196 is a mechanism for continuously adjusting the exhaust flow rate in stages. The gas supply pipe 83, the gas exhaust pipe 88, and the three bypass lines 197, 198, and 199 are made of stainless steel having excellent strength and corrosion resistance. In addition, a pressure gauge 180 for measuring the pressure of the heat treatment space 65 is provided in the chamber 6. As the pressure gauge 180, those having a measurement range of about 5 Pa to 0.2 MPa are preferred. FIG. 2 is a perspective view showing the overall appearance of the holding portion 7. 3 is a plan view of the holding portion 7 viewed from the upper surface, and FIG. 4 is a side view of the holding portion 7 viewed from the side. The holding portion 7 includes a base ring 71, a coupling portion 72 and a base 74. The abutment ring 71, the connecting portion 72, and the base 74 are all made of quartz. That is, the entire holding portion 7 is formed of quartz. The abutment ring 71 is a ring-shaped quartz member. The abutment ring 71 is supported on the wall surface of the chamber 6 by being placed on the bottom surface of the recess 62 (refer to FIG. 1 ). On the upper surface of the abutment ring 71 having a ring shape, a plurality of connecting portions 72 (four in the present embodiment) are erected along its circumferential direction. The connecting portion 72 is also a member of quartz, and is fixed to the abutment ring 71 by welding. In addition, the shape of the abutment ring 71 may be a circular arc shape formed by partially missing a ring shape. The plate-shaped base 74 is supported by the four connecting portions 72 provided on the base ring 71. The base 74 is a substantially circular flat plate member formed of quartz. The diameter of the base 74 is larger than the diameter of the semiconductor wafer W. That is, the susceptor 74 has a larger plane size than the semiconductor wafer W. A plurality of (five in this embodiment) guide pins 76 are erected on the upper surface of the base 74. The five guide pins 76 are provided along a circumference concentric with the outer circumference of the base 74. The diameter of the circle provided with the five guide pins 76 is slightly larger than the diameter of the semiconductor wafer W. Each guide pin 76 is also formed of quartz. Furthermore, the guide pin 76 may be processed from the quartz ingot integrally with the base 74, or a separately processed person may be attached to the base 74 by welding or the like. The four lower surface of the four connection portions 72 of the abutment ring 71 and the peripheral edge portion of the base 74 are fixed by welding. That is, the base 74 and the abutment ring 71 are fixedly connected by the connecting portion 72, and the holding portion 7 becomes a quartz body forming member. The abutment ring 71 of such a holding portion 7 is supported on the wall surface of the chamber 6, whereby the holding portion 7 is attached to the chamber 6. In a state where the holding portion 7 is attached to the chamber 6, the base 74 having a substantially disc shape takes a horizontal posture (posture whose normal line coincides with the vertical direction). The semiconductor wafer W carried into the chamber 6 is placed in a horizontal posture and held on the base 74 mounted on the holding portion 7 of the chamber 6. The semiconductor wafer W is placed inside the circle formed by the five guide pins 76, thereby preventing the positional deviation in the horizontal direction. In addition, the number of the guide pins 76 is not limited to five, as long as it can prevent the positional deviation of the semiconductor wafer W. As shown in FIGS. 2 and 3, an opening 78 and a notch 77 are formed vertically through the base 74. The notch 77 is provided for passing the tip of the probe of the contact thermometer 130 using a thermocouple. On the other hand, the opening 78 is provided for the radiation thermometer 120 to receive radiation (infrared light) radiated from the lower surface of the semiconductor wafer W held on the base 74. Furthermore, the base 74 is provided with four through holes 79 through which the jack pin 12 of the transfer mechanism 10 described below penetrates to deliver the semiconductor wafer W. FIG. 5 is a top view of the transfer mechanism 10. 6 is a side view of the transfer mechanism 10. The transfer mechanism 10 includes two transfer arms 11. The transfer arm 11 has a circular arc shape along the substantially circular recess 62. Two lifting pins 12 are erected on each transfer arm 11. Each transfer arm 11 is set to be rotatable by the horizontal movement mechanism 13. The horizontal movement mechanism 13 causes the pair of transfer arms 11 to transfer the semiconductor wafer W with respect to the holding portion 7 (the solid line position in FIG. 5) and the semiconductor wafer W held in the holding portion 7. Move horizontally between retreat positions (two-dot chain line position in Figure 5) that do not overlap in a plan view. The horizontal movement mechanism 13 may be one that individually rotates each transfer arm 11 by a separate motor, or may use a link mechanism to rotate a pair of transfer arms 11 by one motor. In addition, the pair of transfer arms 11 are moved up and down together with the horizontal moving mechanism 13 by the lifting mechanism 14. If the lifting mechanism 14 raises the pair of transfer arms 11 at the transfer operation position, a total of four jacking pins 12 pass through the through holes 79 (see FIGS. The upper end protrudes from the upper surface of the base 74. On the other hand, if the lifting mechanism 14 lowers the pair of transfer arms 11 at the transfer operation position, the jacking pin 12 is drawn out from the through hole 79, and the horizontal movement mechanism 13 moves the pair of transfer arms 11 open , Each transfer arm 11 moves to the retreat position. The retracted position of the pair of transfer arms 11 is directly above the abutment ring 71 of the holding portion 7. Since the abutment ring 71 is placed on the bottom surface of the recess 62, the retreat position of the transfer arm 11 becomes the inside of the recess 62. Returning to FIG. 1, the flash heating unit 5 provided above the chamber 6 is provided with a light source including a plurality of (30 in this embodiment) xenon flash lamp FL inside the housing 51, and in a manner to cover the light source above The reflector 52 is provided. In addition, a light radiation window 53 is installed at the bottom of the casing 51 of the flash heater 5. The light radiation window 53 constituting the floor portion of the flash heater 5 is a plate-shaped quartz window formed of quartz. The flash heating part 5 is provided above the chamber 6, thereby becoming a light radiation window 53 facing the upper chamber window 63. The flash lamp FL irradiates the heat treatment space 65 through the light radiation window 53 and the upper chamber window 63 from above the chamber 6. The plurality of flash lamps FL are rod-shaped lamps each having a long cylindrical shape, and are parallel to each other along the main surface of the semiconductor wafer W held in the holding portion 7 (that is, along the horizontal direction) with their respective longitudinal directions The way is arranged in a plane. Therefore, the plane formed by the arrangement of the flash lamps FL is also a horizontal plane. The xenon flash lamp FL includes: a rod-shaped glass tube (discharge tube) in which xenon gas is enclosed and an anode and a cathode connected to the capacitor are arranged at both ends thereof; and a trigger electrode which is attached to the outer peripheral surface of the glass tube . Xenon gas is an electrical insulator. Therefore, even if electric charges are stored in the capacitor, electricity will not flow into the glass tube under normal conditions. However, when a high voltage is applied to the trigger electrode to break the insulation, the electricity stored in the capacitor flows into the glass tube instantaneously, and light is emitted by the excitation of the xenon atoms or molecules at this time. In this xenon flash lamp FL, the electrostatic energy pre-stored in the capacitor is converted into an extremely short light pulse of 0.1 ms to 100 ms. Therefore, compared with a light source that is continuously lit like a halogen lamp HL, it has an extremely strong irradiance Characteristics of light. That is, the flash lamp FL is a pulse light emitting lamp that emits light instantly in an extremely short time of less than 1 second. Furthermore, the lighting time of the flash lamp FL can be adjusted by the coil constant of the lamp power supply that supplies power to the flash lamp FL. In addition, the reflector 52 is provided above the plurality of flash lamps FL so as to cover the entirety thereof. The basic function of the reflector 52 is to reflect the flash light emitted from the plurality of flash lamps FL toward the side of the heat treatment space 65. The reflector 52 is formed of an aluminum alloy plate, and its surface (the surface facing the side of the flash lamp FL) is roughened by sandblasting. The halogen heating part 4 provided below the chamber 6 contains a plurality of (40 in this embodiment) halogen lamps HL inside the housing 41. The halogen heating portion 4 is a light irradiation portion that heats the semiconductor wafer W by irradiating light from the lower portion of the chamber 6 to the heat treatment space 65 through the lower chamber window 64 through a plurality of halogen lamps HL. 7 is a plan view showing the arrangement of a plurality of halogen lamps HL. The 40 halogen lamps HL are arranged in two sections, upper and lower. 20 halogen lamps HL are arranged on the upper section close to the holding portion 7, and 20 halogen lamps HL are also arranged on the lower section farther from the holding section 7 than the upper section. Each halogen lamp HL is a rod-shaped lamp having a long cylindrical shape. The 20 halogen lamps HL in the upper stage and the lower stage are arranged in such a manner that their respective longitudinal directions are parallel to each other along the main surface (that is, along the horizontal direction) of the semiconductor wafer W held by the holding portion 7. Therefore, the upper and lower sections are formed by the arrangement of the halogen lamps HL as horizontal planes. Furthermore, as shown in FIG. 7, the upper and lower stages are arranged at a density opposite to the central portion of the semiconductor wafer W held in the holding portion 7, and the density of halogen lamps HL in the area opposed to the peripheral portion Becomes high. In other words, the upper and lower segments are all shorter than the central part of the lamp arrangement, and the arrangement interval of the halogen lamps HL in the peripheral part is shorter. Therefore, when heating by the light irradiation from the halogen heating portion 4, a larger amount of light can be irradiated to the peripheral portion of the semiconductor wafer W that is prone to temperature reduction. In addition, the lamp group constituted by the halogen lamp HL in the upper stage and the lamp group constituted by the halogen lamp HL in the lower stage are arranged in a grid-like manner. That is, a total of 40 halogen lamps HL are arranged so that the longitudinal direction of the 20 halogen lamps HL arranged in the upper stage and the longitudinal direction of the 20 halogen lamps HL arranged in the lower stage are orthogonal to each other. The halogen lamp HL is a filament-type light source that causes the filament to heat up and emit light by energizing the filament arranged inside the glass tube. Inside the glass tube, a gas obtained by introducing a small amount of halogen elements (iodine, bromine, etc.) into an inert gas such as nitrogen or argon is sealed. By introducing halogen elements, it is possible to suppress the breakage of the filament and set the temperature of the filament to a high temperature. Therefore, the halogen lamp HL has a characteristic that it has a longer life and can continuously irradiate strong light than a conventional incandescent bulb. That is, the halogen lamp HL is a continuous lighting lamp that continuously emits light for at least 1 second or more. In addition, since the halogen lamp HL is a rod-shaped lamp, it has a long life. By arranging the halogen lamp HL in a horizontal direction, it is excellent in the radiation efficiency of the semiconductor wafer W upward. Also, in the housing 41 of the halogen heating section 4, a reflector 43 is provided below the two-stage halogen lamp HL (FIG. 1). The reflector 43 reflects the light emitted from the plurality of halogen lamps HL toward the side of the heat treatment space 65. The control unit 3 controls the above-mentioned various operating mechanisms provided in the heat treatment apparatus 1. The configuration of the hardware as the control unit 3 is the same as that of a general computer. That is, the control unit 3 includes a CPU (Central Processing Unit) as a circuit that performs various arithmetic processes, and a ROM (Read Only Memory) as a memory dedicated for reading basic programs, as RAM (Random Access Memory) and disks for memory control software or data, etc. The CPU of the control unit 3 executes the processing of the heat treatment device 1 by executing a specific processing program. In addition, the control unit 3 controls the valve 84, the valve 89, the flow adjustment valve 90, the flow adjustment valve 196, the exhaust pump 191, and the three exhaust valves 192, 193, and 194 to adjust the pressure of the heat treatment space 65 in the chamber 6 , Air supply flow rate and exhaust rate. In addition to the above configuration, the heat treatment apparatus 1 prevents excessive temperature rise of the halogen heating unit 4, the flash heating unit 5, and the chamber 6 due to the heat energy generated from the halogen lamp HL and the flash lamp FL during the heat treatment of the semiconductor wafer W, It also has various cooling structures. For example, a water cooling pipe (not shown) is provided on the wall of the chamber 6. In addition, the halogen heating unit 4 and the flash heating unit 5 have an air-cooling structure in which a gas flow is formed inside to discharge heat. In addition, air is also supplied to the gap between the upper chamber window 63 and the light radiation window 53 to cool the flash heater 5 and the upper chamber window 63. Next, the processing procedure of the semiconductor wafer W in the heat treatment apparatus 1 will be described. The semiconductor wafer W to be processed here is a semiconductor substrate with a metal film formed on a silicon substrate. The semiconductor wafer W is irradiated with flash and heated by the heat treatment device 1 to form silicide. 9 is a diagram showing a structure in which a metal film is formed on a semiconductor wafer W. FIG. A silicon oxide film (SiO) is formed on the silicon substrate 101 of the semiconductor wafer W 2 )102. The silicon oxide film 102 is a necessary layer for the interface layer between the silicon substrate 101 and the high-dielectric film 103. The thickness of the silicon oxide film 102 is extremely thin, for example, about 1 nm. As a method of forming the silicon oxide film 102, for example, various known methods such as a thermal oxidation method can be used. On the silicon oxide film 102, a high-dielectric film 103 as a gate insulating film is formed. As the high dielectric constant film 103, for example, HfO can be used 2 , ZrO 2 , Al 2 O 3 , La 2 O 3 High-dielectric materials (HfO in this embodiment) 2 ). The high-dielectric film 103 is formed by depositing a high-dielectric material on the silicon oxide film 102 by using ALD (Atomic Layer Deposition). The thickness of the high-dielectric film 103 deposited on the silicon oxide film 102 is several nm, but the equivalent thickness of the silicon oxide film (EOT: Equivalent oxide thickness) is about 1 nm. The method for forming the high-dielectric film 103 is not limited to ALD. For example, a well-known method such as MOCVD (Metal Organic Chemical Vapor Deposition) can be used. A gate electrode 105 is formed on the high-dielectric film 103. The gate electrode 105 of this embodiment is a so-called metal gate electrode formed of titanium (Ti) or titanium nitride (TiN). In addition, as the gate electrode 105, polysilicon may be used instead of the metal gate electrode. In addition, sidewall spacers 104 of SiN are formed on both sides of the gate electrode 105. The sidewall 104 is formed before the high-dielectric film 103 in the rear gate process. Both sides of the gate electrode 105 in the upper surface of the silicon substrate 101 become source/drain regions (regions separated by broken lines in FIG. 9). In the source/drain region, ions are implanted by an ion implantation device. Furthermore, a metal film 108 is formed on the source/drain region. The metal materials used in the silicide technology are, for example, nickel (Ni), cobalt (Co), titanium (Ti), tungsten (W), etc. (nickel in this embodiment). The metal film 108 can be formed by a well-known film forming technique such as sputtering or vacuum evaporation. The heat treatment of the semiconductor wafer W with the metal film 108 formed on the source/drain regions of the silicon substrate 101 as shown in FIG. 9 is performed by the heat treatment device 1. Hereinafter, the operation sequence in the heat treatment apparatus 1 will be described. The operation sequence in the heat treatment apparatus 1 is performed by the control unit 3 controlling each operation mechanism of the heat treatment apparatus 1. First, the semiconductor wafer W on which the metal film 108 is formed is carried into the chamber 6 of the heat treatment apparatus 1. When the semiconductor wafer W is carried in, the gate valve 185 is opened to open the transport opening 66, and the semiconductor wafer W with the metal film 108 formed thereon is transported into the chamber 6 by the transport robot outside the apparatus through the transport opening 66 Within the heat treatment space 65. At this time, both inside and outside of the chamber 6 are at atmospheric pressure, so as the semiconductor wafer W is carried in, air is drawn into the heat treatment space 65 in the chamber 6. Therefore, by opening the valve 84 from the gas supply source 85 and continuously supplying nitrogen gas into the chamber 6, the nitrogen gas flow can be flowed out from the opened transport opening 66, so that the atmosphere gas outside the device can flow into the chamber 6. Suppressed to a minimum. Further, it is preferable to increase the supply flow rate of nitrogen when the gate valve 185 is opened compared with the heat treatment of the semiconductor wafer W (for example, if the heat treatment is usually 30 liters/min, it is set to 120 liters when the gate valve 185 is opened /minute). Furthermore, it is preferable to increase the supply flow rate of nitrogen and close the valve 89 to stop the exhaust from the chamber 6. As a result, the nitrogen gas supplied into the chamber 6 only flows out from the transfer opening 66, so that the inflow of outside air can be prevented more effectively. The semiconductor wafer W carried in by the transfer robot advances to the position directly above the holding portion 7 and stops. Then, one of the transfer mechanisms 10 moves the pair of transfer arms 11 horizontally from the retreat position to the transfer operation position and rises, whereby the jacking pin 12 protrudes from the upper surface of the base 74 through the through hole 79 to receive the semiconductor wafer W. After the semiconductor wafer W is placed on the jacking pin 12, the transfer robot exits from the heat treatment space 65, and the transfer opening 66 is closed by the gate valve 185. Then, the pair of transfer arms 11 is lowered, whereby the semiconductor wafer W is transferred from the transfer mechanism 10 to the pedestal 74 of the holding portion 7 and held in a horizontal posture. The semiconductor wafer W is held on the base 74 with the surface on which the metal film 108 is formed as an upper surface. In addition, the semiconductor wafer W is held inside the five guide pins 76 on the upper surface of the base 74. The pair of transfer arms 11 descending below the base 74 are retracted by the horizontal movement mechanism 13 to the retracted position, that is, inside the recess 62. After the semiconductor wafer W is housed in the chamber 6 and the transfer opening 66 is closed by the gate valve 185, the inside of the chamber 6 is depressurized to a high atmospheric pressure. Specifically, by closing the transport opening 66, the heat treatment space 65 in the chamber 6 becomes a closed space. In this state, the valve 84 for air supply is closed and the valve 89 for air discharge is opened. Furthermore, the control unit 3 activates the exhaust pump 191 and opens the exhaust valve 192 of the bypass line 197 having the smallest piping diameter among the three bypass lines 197, 198, and 199. Close the other exhaust valves 193 and 194. Thereby, without supplying gas to the chamber 6 and exhausting, the heat treatment space 65 in the chamber 6 is decompressed. FIG. 10 is a diagram showing pressure changes in the chamber 6 in the first embodiment. In the figure, the horizontal axis represents time, and the vertical axis represents the pressure in the chamber 6. When the semiconductor wafer W is housed in the chamber 6 and the transport opening 66 is closed, the pressure in the chamber 6 is normal pressure Ps (=atmospheric pressure=about 101325 Pa). Then, the decompression in the chamber 6 starts at time t1. In the initial stage of decompression, only the three bypass passage lines 197, 198, and 199 are used with the smallest bypass passage line 197. Therefore, the exhaust flow rate is small and the exhaust speed is also slow. Next, at time t2, the control unit 3 opens all three exhaust valves 192, 193, and 194. As a result, the flow rate of the exhaust gas from the chamber 6 increases, and the exhaust speed also becomes faster. Then, at time t3, the pressure (vacuum degree) of the chamber 6 reaches the air pressure P1. The air pressure P1 is, for example, about 100 Pa. That is, after exhausting at a small exhaust gas flow rate at the initial stage of decompression, the exhaust gas is switched to a larger exhaust gas flow rate. Furthermore, in the first embodiment, the flow rate of the flow rate adjustment valve 196 is fixed. If the exhaust is rapidly exhausted at a large exhaust flow rate from the start of decompression, large airflow changes occur in the chamber 6 and particles of the structure attached to the chamber 6 (for example, the lower chamber window 64) are rolled up. It may be attached to the semiconductor wafer W again and cause contamination. If the exhaust gas is calmly exhausted at a small exhaust flow rate at the initial stage of decompression, the exhaust gas is switched to a large exhaust flow rate, so that the particles in the chamber 6 can be prevented from being rolled up. At the time t3 when the pressure in the chamber 6 reaches the air pressure P1, the valve 89 for exhaust is closed and the valve 84 for gas supply is opened, and the heat treatment space 65 in the chamber 6 is supplied from the gas supply source 85 Nitrogen. As a result, a nitrogen atmosphere is formed in the chamber 6 around the semiconductor wafer W held by the holding portion 7. In addition, during the supply of nitrogen to the chamber 6, the exhaust from the chamber 6 may be performed using only the bypass line 197 having the smallest piping diameter. In this case, of course, the supply flow rate of the process gas is greater than the exhaust flow rate. By supplying nitrogen gas into the chamber 6, the pressure in the chamber 6 rises from the air pressure P1 and returns to the normal pressure Ps at time t4. In the first embodiment, since the pressure in the chamber 6 is temporarily reduced to the pressure P1 and then the pressure is restored to the normal pressure Ps, the nitrogen atmosphere in the chamber 6 after the pressure is restored to the normal pressure Ps The oxygen concentration is about 200 ppb or less. After the time t4 at which the pressure in the chamber 6 is restored to the normal pressure Ps, the supply flow rate of nitrogen to the chamber 6 is equal to the exhaust flow rate from the chamber 6 to maintain the pressure in the chamber 6 constant Press Ps. At the time t4 when the pressure in the chamber 6 is restored to the normal pressure Ps, the 40 halogen lamps HL of the halogen heating unit 4 are simultaneously turned on to start preheating (auxiliary heating) of the semiconductor wafer W. The halogen light emitted from the halogen lamp HL is irradiated from the back surface of the semiconductor wafer W through the lower chamber window 64 and the base 74 formed of quartz. The back surface of the semiconductor wafer W is the main surface opposite to the surface on which the metal film 108 is formed. The temperature of the semiconductor wafer W is increased by receiving light from the halogen lamp HL. Furthermore, since the transfer arm 11 of the transfer mechanism 10 is retracted to the inside of the recess 62, it does not become an obstacle to heating by the halogen lamp HL. During the preheating using the halogen lamp HL, the temperature of the semiconductor wafer W is measured by the contact thermometer 130. That is, the contact thermometer 130 with a built-in thermocouple is in contact with the lower surface of the semiconductor wafer W held by the susceptor 74 via the notch 77 to measure the temperature of the wafer that is rising. The measured temperature of the semiconductor wafer W is transmitted to the control unit 3. The control unit 3 controls the output of the halogen lamp HL while monitoring whether the temperature of the semiconductor wafer W heated up by the light irradiation from the halogen lamp HL reaches a specific preheating temperature T1. That is, the control unit 3 performs feedback control on the output of the halogen lamp HL so that the temperature of the semiconductor wafer W becomes the preheating temperature T1 based on the measurement value of the contact thermometer 130. The preheating temperature T1 is not less than room temperature and not more than 300°C, and in this embodiment is 200°C. Furthermore, when the temperature of the semiconductor wafer W is increased by the irradiation of light from the halogen lamp HL, the temperature measurement by the radiation thermometer 120 is not performed. The reason is that the halogen light irradiated from the halogen lamp HL enters the radiation thermometer 120 as ambient light, and accurate temperature measurement cannot be performed. After the temperature of the semiconductor wafer W reaches the preheating temperature T1, the control unit 3 temporarily maintains the semiconductor wafer W at the preheating temperature T1. Specifically, when the temperature of the semiconductor wafer W measured by the contact thermometer 130 reaches the preheating temperature T1, the control unit 3 adjusts the output of the halogen lamp HL to maintain the temperature of the semiconductor wafer W to approximately preheating Temperature T1. By performing such preheating using the halogen lamp HL, the entire semiconductor wafer W including the metal film 108 is uniformly heated to the preheating temperature T1. At the stage of preheating using the halogen lamp HL, the temperature of the peripheral portion of the semiconductor wafer W that is more likely to generate heat tends to be lower than that of the central portion, but the density of the halogen lamp HL of the halogen heating portion 4 is The area facing the central portion of the semiconductor wafer W is higher than the area facing the peripheral portion. Therefore, the amount of light irradiated to the peripheral portion of the semiconductor wafer W that easily generates heat is increased, and the in-plane temperature distribution of the semiconductor wafer W in the preheating stage can be made uniform. Furthermore, since the inner peripheral surface of the reflection ring 69 mounted on the side portion 61 of the chamber is set to a mirror surface, the amount of light reflected by the inner peripheral surface of the reflection ring 69 toward the peripheral portion of the semiconductor wafer W increases, so that The temperature distribution in the surface of the semiconductor wafer W in the preheating stage is more uniform. Furthermore, the pressure in the chamber 6 during preheating is maintained at normal pressure Ps. Next, at the time t5 when the temperature of the semiconductor wafer W reaches the preheating temperature T1 and a specific time elapses, the flash heating process by irradiating the flash from the flash lamp FL is performed. At this time, a part of the flash light radiated from the flash lamp FL is directly directed into the chamber 6, and the other part is temporarily reflected by the reflector 52 and then is directed into the chamber 6, the semiconductor wafer W is irradiated by the flash light Flash heating. Flash heating is performed by flash (flash) irradiation from the flash lamp FL, and therefore, the surface temperature of the semiconductor wafer W can be raised in a short time. That is, the flash light irradiated from the flash lamp FL converts the electrostatic energy stored in the capacitor in advance into an extremely short light pulse and the irradiation time is 0. Very short and strong flashes of about 1 ms to 100 ms. By illuminating the surface of the semiconductor wafer W with the metal film 108 formed thereon from the flash lamp FL, the silicon in the source/drain region reacts with the metal film 108 to form a silicide (in this embodiment, nickel silicide) ). The maximum temperature (peak temperature) reached by the flash irradiation on the surface of the semiconductor wafer W, that is, the processing temperature T2 is 600°C or more and 1100°C or less for silicide growth, which is 900°C in this embodiment. Furthermore, since the irradiation time from the flash FL is 0. A short time of 1 ms or more and 100 ms or less, so the time required for the surface temperature of the semiconductor wafer W to rise from the preheating temperature T1 to the processing temperature T2 is also an extremely short time of less than 1 second. The surface temperature of the semiconductor wafer W immediately after the flash irradiation drops rapidly from the processing temperature T2. After the flash heating process ends, the halogen lamp HL also goes out after a certain period of time. As a result, the semiconductor wafer W also cools down from the preheating temperature T1. The temperature of the semiconductor wafer W during cooling is measured by the contact thermometer 130 or the radiation thermometer 120, and the measurement result is transmitted to the control unit 3. The control unit 3 monitors whether the temperature of the semiconductor wafer W has decreased to a specific temperature from the measurement result. Moreover, after the temperature of the semiconductor wafer W drops below a certain level, one of the transfer mechanisms 10 moves the pair of transfer arms 11 horizontally again from the retreat position to the transfer operation position and rises, thereby lifting the pin 12 from the base The upper surface of 74 protrudes and receives the heat-treated semiconductor wafer W from the base 74. Then, the transfer opening 66 closed by the gate valve 185 is opened, and the semiconductor wafer W placed on the jacking pin 12 is carried out by the transfer robot outside the device, and the semiconductor wafer W heated by the heat treatment device 1 is heated Processing ends. In the first embodiment, the pressure in the chamber 6 is temporarily reduced to the atmospheric pressure P1 with a relatively large atmospheric pressure and low pressure, and then nitrogen is supplied to restore the pressure to the normal pressure Ps. Therefore, the oxygen concentration in the chamber 6 after the restoration of pressure can be approximately Below 200 ppb. In the case where the atmospheric gas is replaced from the atmosphere to nitrogen without depressurizing the chamber 6 while maintaining the atmospheric pressure, the limit of the oxygen concentration in the chamber 6 can be reduced to about 2 ppm. That is, by temporarily depressurizing the chamber 6 to the atmospheric pressure P1 and restoring the pressure to the normal pressure Ps as in the present embodiment, the oxygen concentration in the chamber 6 can be reduced to 10 compared with the case without decompression Around one-half. After the metal film 108 is formed on the source/drain regions of the silicon substrate 101, there are many defects near the interface between the metal film 108 and the silicon substrate 101 without special treatment. If the heat treatment for silicide formation is performed in a state where the oxygen concentration around the semiconductor wafer W is high, oxygen in the atmosphere enters the defect near the interface between the metal film 108 and the substrate 101, and as a result, near the interface It deteriorates and becomes high resistance. In addition, the nickel silicide itself is oxidized. As a cause of such oxidation, the problem particularly is the oxygen remaining in the chamber 6. As in this embodiment, when the semiconductor wafer W is carried into the chamber 6 under normal pressure, the air from the outside is greatly involved, which increases the residual oxygen concentration in the chamber 6. Therefore, it is preferable to reduce the oxygen concentration in the atmosphere gas when the semiconductor wafer W formed with the metal film 108 is heated to form a silicide as much as possible. In the first embodiment, the oxygen concentration in the heat treatment space 65 in the chamber 6 when the silicide is formed is obtained by temporarily depressurizing the chamber 6 to the atmospheric pressure P1 with a larger atmospheric pressure and then returning the pressure to the normal pressure Ps Reduced to below about 200 ppb. Therefore, it is possible to suppress the increase in resistance of the silicide caused by the oxygen entering the heat treatment space 65 in the silicide formation process near the interface between the metal film 108 and the substrate 101. Also, it can prevent the oxidation of the silicide itself. In addition, the silicide is required to be formed as thin as possible, but in the first embodiment, the surface of the semiconductor wafer W is irradiated with flash light from the flash lamp FL with an irradiation time of less than 1 second, and the wafer surface is irradiated in a very short time Since the temperature is raised to the processing temperature T2, the silicide film thickness can be suppressed from increasing excessively. In addition, when the semiconductor wafer W is loaded into the chamber 6, the supply flow rate of nitrogen gas is increased to flow out from the transfer opening 66, thereby preventing the inflow of outside air when the wafer is carried in and reducing the chamber before processing The initial value of the oxygen concentration in 6. With this, even if the pressure P1, which is the reaching pressure when the pressure in the chamber 6 is decompressed, is high, the residual oxygen concentration can be sufficiently reduced. Furthermore, as described above, when the chamber 6 is decompressed, after the decompression is started with a smaller exhaust flow rate, the exhaust flow is switched to a larger exhaust flow rate. Therefore, it can be prevented The particles in the chamber 6 are rolled up. <Second Embodiment> Next, a second embodiment of the present invention will be described. The configuration of the heat treatment apparatus 1 of the second embodiment is completely the same as that of the first embodiment. In addition, the processing sequence of the semiconductor wafer W in the heat treatment apparatus 1 of the second embodiment is also substantially the same as that of the first embodiment. The second embodiment differs from the first embodiment in the pressure when the pressure in the chamber 6 is temporarily reduced and the pressure is restored. Fig. 11 is a diagram showing pressure changes in the chamber 6 in the second embodiment. In FIG. 11, as in FIG. 10, the horizontal axis indicates the time, and the vertical axis indicates the pressure in the chamber 6. The broken line in FIG. 11 is a pressure change pattern (pattern in FIG. 10) when the pressure in the chamber 6 in the first embodiment is restored to the normal pressure Ps. As in the first embodiment, when the semiconductor wafer W formed with the metal film 108 is housed in the chamber 6 and the transport opening 66 is closed, the pressure in the chamber 6 is normal pressure Ps (=atmospheric pressure= About 101325 Pa). Then, the decompression in the chamber 6 starts at time t1. As in the first embodiment, after the exhaust is performed with a smaller exhaust flow rate at the initial stage of decompression, the exhaust gas is switched to a larger exhaust flow rate at time t2. Thereby, the particles in the chamber 6 can be prevented from being rolled up. At time t3 when the pressure in the chamber 6 reaches the air pressure P1, the valve 89 for exhaust is closed and the valve 84 for gas supply is opened, and nitrogen is supplied from the gas supply source 85 to the heat treatment space 65 in the chamber 6. This is the same as the first embodiment. In addition, the air pressure P1 is about 100 Pa, for example. In the second embodiment, the pressure in the chamber 6 is not restored to the normal pressure Ps, but by supplying nitrogen gas at time t6, the pressure in the chamber 6 is restored to the atmospheric pressure P2. The air pressure P2 is higher than the air pressure P1 and lower than the normal pressure Ps, for example, about 5000 Pa. In the second embodiment, the pressure in the chamber 6 is temporarily reduced to the pressure P1 and the pressure is restored to a higher pressure P2. Therefore, the oxygen concentration in the chamber 6 after the pressure restoration can be about 200 ppb or less . After the time t6 at which the pressure in the chamber 6 returns to the pressure P2, the supply flow rate of nitrogen to the chamber 6 is equal to the exhaust flow rate from the chamber 6 to maintain the pressure in the chamber 6 at the pressure P2. Then, while maintaining the pressure in the chamber 6 at the air pressure P2, preheating of the semiconductor wafer W using the halogen lamp HL is performed, and thereafter, the surface of the semiconductor wafer W is irradiated with flash light from the flash lamp FL at time t7. Perform flash heating. The contents of the preheating and flash heat treatment are the same as in the first embodiment. The surface of the semiconductor wafer W on which the metal film 108 is formed is irradiated with flash light from the flash lamp FL to cause the silicon in the source/drain region to react with the metal film 108 to form silicide. After the flash heating process is completed, after a certain period of time, the valve 89 for exhaust is closed and the valve 84 for gas supply is opened, and nitrogen is supplied to the chamber 6 from the gas supply source 85 to restore the pressure to normal pressure Ps. In addition, the halogen lamp HL is also turned off, whereby the semiconductor wafer W is also cooled down from the preheating temperature T1. Thereafter, the order in which the semiconductor wafer W cooled down to a specific temperature is carried out from the chamber 6 of the heat treatment apparatus 1 is the same as in the first embodiment. In addition, as the main reason for the particles to be rolled up in the chamber 6, in addition to the air supply and exhaust to the chamber 6, flash irradiation is also a cause. During the flash irradiation from the flash lamp FL, the surface of the semiconductor wafer W heats up instantaneously, and on the other hand, the back surface does not heat up from the preheating temperature T1. Therefore, a large temperature difference occurs between the front and back surfaces, and only the surface thermally expands and Wafer W is rapidly deformed. As a result, the semiconductor wafer W vibrates on the susceptor 74 to generate fine particles and is rolled up in the chamber 6. In order to effectively discharge such particles caused by flash irradiation from the chamber 6, in the second embodiment, when the flash heating process is completed and nitrogen is supplied to the chamber 6 to restore the pressure to the normal pressure Ps, it will be used The exhaust valve 89 is opened and nitrogen flows into the chamber 6 at a flow rate of 50 liters/minute or more and 100 liters/minute or less, thereby flushing out particles caused by flash irradiation. With this, it is possible to prevent particles caused by flash irradiation from adhering to the semiconductor wafer W and causing contamination. Furthermore, when nitrogen gas is supplied into the chamber 6 after the flash heating is completed and the pressure is restored to the normal pressure Ps, the valve 84 for air supply may be opened while the valve 89 for exhaust is opened Nitrogen gas is supplied into the chamber 6. If so, the particles caused by the flash irradiation can be exhausted from the chamber 6 more efficiently. In the second embodiment, after temporarily depressurizing the chamber 6 to the atmospheric pressure P1 with a relatively large atmospheric pressure and low pressure, nitrogen is supplied to restore the pressure to the atmospheric pressure P2, so that the heat treatment for silicide formation can be performed in the same manner as the first embodiment The oxygen concentration of the heat treatment space 65 in the chamber 6 at that time is about 200 ppb or less. Therefore, it is possible to suppress the increase in the resistance of the silicide caused by the oxygen entering the heat treatment space 65 in the silicide formation process near the interface between the metal film 108 and the substrate 101. Also, it can prevent the oxidation of the silicide itself. In addition, as in the first embodiment, since the flash lamp FL irradiates the surface of the semiconductor wafer W with an irradiation time of less than 1 second to raise the wafer surface to the processing temperature T2 in a very short time, silicidation can be suppressed The film thickness of the object increases excessively. In addition, heat treatment under reduced pressure can promote the detachment of impurities contained in the metal film 108. By discharging such detached impurity elements from the chamber 6, it is possible to prevent the impurities from adhering to the surface of the semiconductor wafer W and causing contamination. As a result, it is possible to prevent the deterioration of device performance and the decrease of yield. In addition, since the absorption of halogen light and flash light using the atmospheric gas in the chamber 6 is reduced, the temperature increase efficiency during pre-heating and flash heating can be improved. As a result, the surface temperature of the semiconductor wafer W during flash heating can be increased. Moreover, by heating the semiconductor wafer W under reduced pressure, the influence of convection in the chamber 6 can be reduced, and the uniformity of the in-plane temperature distribution of the semiconductor wafer W can be improved. Furthermore, in the second embodiment, when the pressure in the chamber 6 is restored from the air pressure P1, the pressure is not restored to the normal pressure Ps, but the pressure is restored to the atmospheric pressure P2, which is lower than the atmospheric pressure. Therefore, as compared with restoring the pressure in the chamber 6 to the normal pressure Ps as in the first embodiment, if the pressure is restored to the atmospheric pressure P2 as in the second embodiment, the time required to restore the pressure can be shortened. Moreover, the flash irradiation time can be advanced by the amount of time required to shorten the pressure recovery (as shown in FIG. 11, the flash irradiation time t7 in the second embodiment is earlier than the flash irradiation time t5 in the first embodiment ). As a result, as in the second embodiment, the pressure in the chamber 6 is restored to the pressure P2 that is larger than the atmospheric pressure, and the output of the heat treatment apparatus 1 can be increased. <Third Embodiment> Next, a third embodiment of the present invention will be described. The configuration of the heat treatment apparatus 1 of the third embodiment is completely the same as that of the first embodiment. In addition, the processing sequence of the semiconductor wafer W in the heat treatment apparatus 1 of the third embodiment is also substantially the same as that of the first embodiment. The third embodiment differs from the first embodiment in that the pressure in the chamber 6 changes. Fig. 12 is a diagram showing pressure changes in the chamber 6 in the third embodiment. In FIG. 12, as in FIG. 10, the horizontal axis represents the time, and the vertical axis represents the pressure in the chamber 6. As in the first embodiment, when the semiconductor wafer W formed with the metal film 108 is housed in the chamber 6 and the transport opening 66 is closed, the pressure in the chamber 6 is normal pressure Ps (=atmospheric pressure= About 101325 Pa). Then, the decompression in the chamber 6 starts at time t1. In the third embodiment, the exhaust gas flow rate using the three bypass lines 197, 198, and 199 is fixed, and the exhaust gas flow rate from the chamber 6 is continuously increased with time by the flow rate adjustment valve 196. That is, exhaust gas is started at a relatively small exhaust gas flow rate in the initial stage of decompression, and the exhaust gas flow rate is gradually increased continuously. If this is the case, the particles in the chamber 6 can be prevented from being rolled up as in the first embodiment. In addition, by continuously increasing the exhaust gas flow rate steplessly, it is also possible to prevent the particles from being rolled up due to the rapid change of the exhaust gas flow rate. At the time t3 when the pressure in the chamber 6 reaches the air pressure P1, the valve 89 for exhaust is closed and the valve 84 for gas supply is opened, and the heat treatment space 65 in the chamber 6 is supplied with nitrogen from the gas supply source 85 The pressure in the chamber 6 is restored. In addition, the air pressure P1 is about 100 Pa, for example. In the third embodiment, the flow rate of the processing gas supplied to the chamber 6 is continuously increased with time by the flow rate adjustment valve 90. That is, in the initial stage of recovering the pressure, the air supply is started with a relatively small air supply flow rate, and the air supply flow rate is gradually increased continuously. As in the case of decompression, if the air is supplied rapidly at a large air supply flow rate from the beginning of the pressure recovery, the particles adhering to the structure of the chamber 6 may be rolled up. Since the initial stage of recovering the pressure starts the air supply calmly with a smaller air supply flow rate and gradually increases the exhaust gas flow rate, such particles in the chamber 6 can be prevented from being rolled up. In addition, by continuously increasing the air supply flow rate steplessly, it is also possible to prevent the particles from being rolled up due to a sudden change in the air supply flow rate. In addition, in the third embodiment, by supplying nitrogen gas to the chamber 6, the pressure in the chamber 6 is restored to the atmospheric pressure P3 that exceeds the normal pressure Ps at time t8. Air pressure P3 is higher than atmospheric pressure, for example, about 0. 12 MPa. In the third embodiment, the pressure in the chamber 6 is temporarily reduced to the pressure P1 and then the pressure is restored to a higher pressure P3. Therefore, the oxygen concentration in the chamber 6 after the pressure restoration can be about 200 Below ppb. After the time t8 at which the pressure in the chamber 6 returns to the pressure P3, the supply flow rate of nitrogen to the chamber 6 is equal to the exhaust flow rate from the chamber 6 to maintain the pressure in the chamber 6 at the pressure P3. Then, while maintaining the pressure in the chamber 6 at the air pressure P3, preheating of the semiconductor wafer W using the halogen lamp HL is performed, and thereafter, the surface of the semiconductor wafer W is irradiated with flash light from the flash lamp FL at time t9. Perform flash heating. The contents of the preheating and flash heat treatment are the same as in the first embodiment. The surface of the semiconductor wafer W on which the metal film 108 is formed is irradiated with flash light from the flash lamp FL to cause the silicon in the source/drain region to react with the metal film 108 to form silicide. After the flash heating process is completed, the gas in the chamber 6 is exhausted from the gas exhaust pipe 88 to make the inside of the chamber 6 at normal pressure Ps. In addition, the halogen lamp HL is also turned off, whereby the semiconductor wafer W is also cooled down from the preheating temperature T1. Thereafter, the order in which the semiconductor wafer W cooled down to a specific temperature is carried out from the chamber 6 of the heat treatment apparatus 1 is the same as in the first embodiment. In the third embodiment, after temporarily depressurizing the chamber 6 to the atmospheric pressure P1 with a relatively large atmospheric pressure and low pressure, nitrogen is supplied to restore the pressure to the atmospheric pressure P3. Therefore, the heat treatment for silicide formation can be performed in the same manner as in the first embodiment. The oxygen concentration of the heat treatment space 65 in the chamber 6 at that time is about 200 ppb or less. Therefore, it is possible to suppress the increase in the resistance of the silicide caused by the oxygen entering the heat treatment space 65 in the silicide formation process near the interface between the metal film 108 and the substrate 101. Also, it can prevent the oxidation of the silicide itself. Also, as in the first embodiment, since the flash lamp FL irradiates the surface of the semiconductor wafer W with an irradiation time of less than 1 second and the wafer surface is heated to the processing temperature T2 in a very short time, silicidation can be suppressed The film thickness of the object increases excessively. Furthermore, in the third embodiment, the surface of the semiconductor wafer W is irradiated with flash light under the pressure P3 in the chamber 6 that is larger than the pressure and high in pressure, that is, under pressure, to perform heat treatment. As long as the heat treatment is performed under pressure, the diffusion rate of oxygen released from the chamber side 61 and the like can be suppressed from slowing down and reaching the semiconductor wafer W. Furthermore, in the third embodiment, the exhaust gas flow rate and the air supply flow rate are continuously changed steplessly during decompression and pressure recovery in the chamber 6. By this, it is possible to prevent the particles from being rolled up due to the sudden change of the air supply and exhaust. <Fourth Embodiment> Next, a fourth embodiment of the present invention will be described. The configuration of the heat treatment apparatus 1 of the fourth embodiment is completely the same as that of the first embodiment. In addition, the processing sequence of the semiconductor wafer W in the heat treatment apparatus 1 of the fourth embodiment is also substantially the same as that of the first embodiment. The fourth embodiment differs from the first embodiment in that the pressure in the chamber 6 changes. Fig. 13 is a diagram showing pressure changes in the chamber 6 in the fourth embodiment. In FIG. 13, as in FIG. 10, the horizontal axis represents time, and the vertical axis represents pressure in the chamber 6. As in the first embodiment, when the semiconductor wafer W formed with the metal film 108 is housed in the chamber 6 and the transport opening 66 is closed, the pressure in the chamber 6 is normal pressure Ps (=atmospheric pressure= About 101325 Pa). Then, the decompression in the chamber 6 starts at time t1. As in the first embodiment, after exhausting with a smaller exhaust flow rate at the initial stage of decompression, the exhaust gas is switched to a larger exhaust flow rate at time t2. Thereby, the particles in the chamber 6 can be prevented from being rolled up. At the time t3 when the pressure in the chamber 6 reaches the air pressure P1, the valve 89 for exhaust is closed. In addition, in the fourth embodiment, the pressure in the chamber 6 is maintained at the air pressure P1 without introducing nitrogen gas into the chamber 6. In addition, in order to maintain the pressure in the chamber 6 at the air pressure P1, the valve 89 may be opened to continue the exhaust. In the fourth embodiment, the pressure in the chamber 6 is reduced to the gas pressure P1 and thereafter the gas pressure P1 is maintained. Therefore, the residual oxygen concentration in the chamber 6 can be reduced to about 200 ppb or less. Then, while maintaining the pressure in the chamber 6 at the atmospheric pressure P1, preheating of the semiconductor wafer W by the halogen lamp HL is performed, and thereafter, the surface of the semiconductor wafer W is irradiated with flash light from the flash lamp FL at time t10. Perform flash heating. The contents of the preheating and flash heat treatment are the same as in the first embodiment. The surface of the semiconductor wafer W on which the metal film 108 is formed is irradiated with flash light from the flash lamp FL to cause the silicon in the source/drain region to react with the metal film 108 to form silicide. After the end of the flash heating process, the valve 84 for gas supply is opened after a certain period of time, and nitrogen gas is supplied into the chamber 6 from the gas supply source 85 to restore the pressure to the normal pressure Ps. In addition, the halogen lamp HL is also turned off, whereby the semiconductor wafer W is also cooled down from the preheating temperature T1. Thereafter, the order in which the semiconductor wafer W cooled down to a specific temperature is carried out from the chamber 6 of the heat treatment apparatus 1 is the same as in the first embodiment. In the fourth embodiment, after the pressure in the chamber 6 is reduced to the atmospheric pressure P1 of a relatively large atmospheric pressure, it is maintained at the atmospheric pressure P1. Therefore, the chamber when performing the heat treatment for silicide formation can be performed in the same manner as the first embodiment The oxygen concentration of the heat treatment space 65 in 6 is about 200 ppb or less. Therefore, it is possible to suppress the increase in the resistance of the silicide caused by the oxygen entering the heat treatment space 65 in the silicide formation process near the interface between the metal film 108 and the substrate 101. Also, it can prevent the oxidation of the silicide itself. In addition, as in the first embodiment, the surface of the semiconductor wafer W is irradiated with flash light from the flash lamp FL for less than 1 second, and the wafer surface is heated to the processing temperature T2 in a very short time. Therefore, silicide can be suppressed The film thickness increases excessively. In addition, by performing the heat treatment of the semiconductor wafer W under reduced pressure, the same effect as the second embodiment can be obtained. Furthermore, in the case where the metal film 108 is titanium, the metal film 108 may be nitrided even if the heat treatment is performed in a nitrogen atmosphere. However, if the heat treatment of the semiconductor wafer W is performed under extremely low pressure as in the fourth embodiment Nitriding of the metal film 108 can be suppressed. <Variation> The embodiment of the present invention has been described above, but the present invention can be modified in various ways other than those described above without departing from the gist of the invention. For example, in each of the above-mentioned embodiments, the pressure P1, which is the reaching pressure when the pressure inside the chamber 6 is decompressed, is about 100 Pa, but it is not limited to this and can be set to an appropriate value. In order to reduce the arrival oxygen concentration in the chamber 6 to about 1/10, it is sufficient to make the arrival pressure when the chamber 6 is depressurized, that is, the pressure P1 is about 1/10 of the atmospheric pressure (about 10000 Pa) . If the gas pressure P1 is lowered (that is, if the pressure is reduced to a higher vacuum), the oxygen concentration remaining in the chamber 6 after the recovery pressure can be further reduced, but the decompression time until the gas pressure P1 is reached becomes longer. Therefore, it is preferable to set the gas pressure P1 by balancing the oxygen concentration and the output necessary when performing the heat treatment for silicide formation. In addition, in each of the above-mentioned embodiments, the exhaust flow rate from the chamber 6 is controlled by providing three bypass lines 197, 198, and 199, but the number of bypass lines may be two or more. In addition, instead of providing a plurality of bypass lines 197, 198, 199, the flow rate of the exhaust gas from the chamber 6 may be controlled by providing a throttle valve or a gas ballast. In addition, a mass flow controller may be used instead of the flow adjustment valves 90 and 196. In the first and second embodiments, the exhaust gas flow rate from the chamber 6 during decompression is switched in two stages, and in the third embodiment, the exhaust gas flow rate is continuously increased steplessly, but it is not limited to these For example, the exhaust gas flow rate may be switched in multiple stages. That is, it may be a form in which the flow rate of exhaust gas when the pressure in the chamber 6 is decompressed increases with time. Similarly, regarding the gas supply flow rate to the chamber 6 when the pressure is restored, the gas supply flow rate is continuously increased steplessly in the third embodiment, but it may be increased by switching between two or more stages. That is, it is sufficient if the air supply flow rate when the pressure is restored in the chamber 6 also increases with time. In addition, when performing decompression and restoration of pressure in the chamber 6, the control unit 3 may control various valves and the like based on the elapsed time from the start of decompression (time t1 ), or may be based on the heat treatment space 65 using the pressure gauge 180 The pressure measurement results are used to feedback control various valves. In the case of controlling based on the elapsed time, the relationship between the elapsed time and the pressure in the chamber 6 may be obtained by experiment or simulation. In the above embodiments, a metal film 108 is formed on the silicon substrate 101 to form a silicide. However, the material of the substrate 101 is not limited to silicon, and may be germanium (Ge) or silicon germanium. In particular, in the case of manufacturing a PMOS (P-channel metal oxide semiconductor, P-type metal oxide semiconductor) transistor, silicon germanium is used as the substrate 101. When the substrate 101 is germanium or silicon germanium, a metal film 108 is formed on the substrate 101 to react germanium with metal to form germanide. Even if the substrate 101 is germanium or silicon germanium, the processing of the semiconductor wafer W is the same as in the above embodiments. In addition, the above embodiments suppress the increase of silicide resistance, but the technique of the present invention can also be applied to the reduction of the contact resistance in the Fin structure. In the Fin structure, a metal film (such as a TiN film) for contact formation is deposited on a part of the region of the base material 101 (the opening of the contact hole). By forming the contact (ohmic contact) between the metal film and the substrate 101 by applying the technique of the present invention for heat treatment at an extremely low oxygen concentration, the contact resistance can be reduced. In addition, in each of the above-mentioned embodiments, the flash heater 5 is provided with 30 flash lamps FL, but it is not limited to this, and the number of flash lamps FL may be any number. In addition, the flash FL is not limited to the xenon flash, but may be a krypton flash. In addition, the number of halogen lamps HL included in the halogen heating unit 4 is not limited to 40, and any number may be used as long as the plurality of halogen lamps HL are arranged in the upper and lower stages. Furthermore, in the above-mentioned embodiment, the semiconductor wafer W is preheated by the halogen light irradiation from the halogen lamp HL, but the method of preheating is not limited to this, and it may be The semiconductor wafer W is preheated.

1‧‧‧熱處理裝置3‧‧‧控制部4‧‧‧鹵素加熱部5‧‧‧閃光加熱部6‧‧‧腔室7‧‧‧保持部10‧‧‧移載機構11‧‧‧移載臂12‧‧‧頂起銷13‧‧‧水平移動機構14‧‧‧升降機構41‧‧‧殼體43‧‧‧反射器51‧‧‧殼體52‧‧‧反射器53‧‧‧燈光輻射窗61‧‧‧腔室側部62‧‧‧凹部63‧‧‧上側腔室窗64‧‧‧下側腔室窗65‧‧‧熱處理空間66‧‧‧搬送開口部68‧‧‧反射環69‧‧‧反射環71‧‧‧基台環72‧‧‧連結部74‧‧‧基座76‧‧‧導銷77‧‧‧缺口部78‧‧‧開口部79‧‧‧貫通孔81‧‧‧氣體供給孔82‧‧‧緩衝空間83‧‧‧氣體供給管84‧‧‧閥85‧‧‧氣體供給源86‧‧‧氣體排氣孔87‧‧‧緩衝空間88‧‧‧氣體排氣管89‧‧‧閥90、196‧‧‧流量調整閥101‧‧‧基材102‧‧‧矽氧化膜103‧‧‧高介電率膜104‧‧‧側牆105‧‧‧閘極電極108‧‧‧金屬膜120‧‧‧輻射溫度計130‧‧‧接觸式溫度計180‧‧‧壓力計185‧‧‧閘閥190‧‧‧排氣部191‧‧‧排氣泵192、193、194‧‧‧排氣閥197、198、199‧‧‧旁通路線D FL‧‧‧閃光燈G HL‧‧‧鹵素燈P1‧‧‧氣壓P2‧‧‧氣壓P3‧‧‧氣壓Ps‧‧‧常壓S t1‧‧‧時刻t2‧‧‧時刻t3‧‧‧時刻t4‧‧‧時刻t5‧‧‧時刻t6‧‧‧時刻t7‧‧‧時刻t8‧‧‧時刻t9‧‧‧時刻t10‧‧‧時刻W‧‧‧半導體晶圓1‧‧‧Heat treatment device 3‧‧‧Control part 4‧‧‧ Halogen heating part 5‧‧‧Flash heating part 6‧‧‧ Chamber 7‧‧‧ Holding part 10‧‧‧Transfer mechanism 11‧‧‧ Carrier arm 12‧‧‧Push up pin 13‧‧‧Horizontal movement mechanism 14‧‧‧ Lifting mechanism 41‧‧‧‧case 43‧‧‧‧reflector 51‧‧‧case 52‧‧‧‧reflector 53‧‧‧ Light radiation window 61‧‧‧Chamber side part 62‧‧‧Concave part 63‧‧‧ Upper chamber window 64‧‧‧‧Lower chamber window 65‧‧‧ Heat treatment space 66‧‧‧Transport opening 68‧‧‧ Reflective ring 69‧‧‧Reflective ring 71‧‧‧Abutment ring 72‧‧‧Connecting part 74‧‧‧‧Base 76‧‧‧Guide pin 77‧‧‧Notch 78‧‧‧Opening 79‧‧‧ through Hole 81‧‧‧Gas supply hole 82‧‧‧Buffer space 83‧‧‧Gas supply pipe 84‧‧‧Valve 85‧‧‧Gas supply source 86‧‧‧Gas exhaust hole 87‧‧‧Buffer space 88‧‧ ‧Gas exhaust pipe 89‧‧‧Valve 90, 196‧‧‧Flow regulating valve 101‧‧‧Base material 102‧‧‧Silicon oxide film 103‧‧‧High dielectric rate film 104‧‧‧Side wall 105‧‧ ‧Gate electrode 108‧‧‧Metal film 120‧‧‧Radiation thermometer 130‧‧‧Contact thermometer 180‧‧‧Pressure gauge 185‧‧‧Gate valve 190‧‧‧Exhaust part 191‧‧‧Exhaust pump 192, 193, 194‧‧‧ Exhaust valves 197, 198, 199‧‧‧ Bypass line D FL‧‧‧Flash G HL‧‧‧ Halogen lamp P1‧‧‧Air pressure P2‧‧‧Air pressure P3‧‧‧Air pressure Ps‧ ‧‧Normal pressure S t1‧‧‧Time t2‧‧‧Time t3‧‧‧Time t4‧‧‧Time t5‧‧‧Time t6‧‧‧Time t7‧‧‧Time t8‧‧‧‧Time t9‧‧‧ t10‧‧‧w W‧‧‧semiconductor wafer

圖1係表示本發明之熱處理裝置之構成之縱剖視圖。 圖2係表示保持部之整體外觀之立體圖。 圖3係自上表面觀察保持部之俯視圖。 圖4係自側方觀察保持部之側視圖。 圖5係移載機構之俯視圖。 圖6係移載機構之側視圖。 圖7係表示複數個鹵素燈之配置之俯視圖。 圖8係表示排氣部之構成之圖。 圖9係表示於半導體晶圓成膜有金屬膜之構造之圖。 圖10係表示第1實施形態中之腔室內之壓力變化之圖。 圖11係表示第2實施形態中之腔室內之壓力變化之圖。 圖12係表示第3實施形態中之腔室內之壓力變化之圖。 圖13係表示第4實施形態中之腔室內之壓力變化之圖。FIG. 1 is a longitudinal cross-sectional view showing the structure of the heat treatment apparatus of the present invention. 2 is a perspective view showing the overall appearance of the holding portion. Fig. 3 is a plan view of the holding portion viewed from the upper surface. Fig. 4 is a side view of the holding portion viewed from the side. 5 is a top view of the transfer mechanism. 6 is a side view of the transfer mechanism. 7 is a plan view showing the arrangement of a plurality of halogen lamps. FIG. 8 is a diagram showing the configuration of the exhaust section. 9 is a diagram showing a structure in which a metal film is formed on a semiconductor wafer. Fig. 10 is a diagram showing pressure changes in the chamber in the first embodiment. Fig. 11 is a diagram showing pressure changes in the chamber in the second embodiment. Fig. 12 is a diagram showing pressure changes in the chamber in the third embodiment. Fig. 13 is a diagram showing pressure changes in the chamber in the fourth embodiment.

Ps‧‧‧常壓 Ps‧‧‧Normal pressure

P1‧‧‧氣壓 P1‧‧‧Air pressure

t1‧‧‧時刻 t1‧‧‧ moment

t2‧‧‧時刻 t2‧‧‧ moment

t3‧‧‧時刻 t3‧‧‧ moment

t4‧‧‧時刻 t4‧‧‧ moment

t5‧‧‧時刻 t5‧‧‧

Claims (11)

一種熱處理方法，其特徵在於：其係對基板照射閃光而形成接觸(contact)者，且包括：搬入步驟，其將成膜有TiN膜之基板搬入至腔室內；減壓步驟，其將上述腔室內減壓至較大氣壓低之第1壓力；恢復壓力步驟，其將上述腔室內自第1壓力恢復壓力至較第1壓力高之第2壓力；及照射步驟，其一面將上述腔室內維持為第2壓力，一面自閃光燈對上述基板之表面照射閃光，其中第2壓力高於第1壓力且低於大氣壓。 A heat treatment method, which is characterized in that it irradiates the substrate with flash to form a contact, and includes: a carrying-in step, which carries the TiN film-formed substrate into the chamber; a decompression step, which applies the above-mentioned chamber The chamber is depressurized to a first pressure with a larger atmospheric pressure; a pressure recovery step, which restores the pressure in the chamber from the first pressure to a second pressure higher than the first pressure; and an irradiation step, which maintains the chamber as The second pressure illuminates the surface of the substrate from the flash lamp, and the second pressure is higher than the first pressure and lower than atmospheric pressure. 一種熱處理方法，其特徵在於：其係對基板照射閃光而形成接觸(contact)者，且包括：搬入步驟，其將成膜有TiN膜之基板搬入至腔室內；減壓步驟，其將上述腔室內減壓至較大氣壓低之第1壓力；恢復壓力步驟，其將上述腔室內自第1壓力恢復壓力至較第1壓力高之第2壓力；及照射步驟，其一面將上述腔室內維持為第2壓力，一面自閃光燈對上述基板之表面照射閃光，其中第2壓力高於大氣壓。 A heat treatment method, which is characterized in that it irradiates the substrate with flash to form a contact, and includes: a carrying-in step, which carries the TiN film-formed substrate into the chamber; a decompression step, which applies the above-mentioned chamber The chamber is depressurized to a first pressure with a larger atmospheric pressure; a pressure recovery step, which restores the pressure in the chamber from the first pressure to a second pressure higher than the first pressure; and an irradiation step, which maintains the chamber as The second pressure illuminates the surface of the substrate from the flash lamp, and the second pressure is higher than atmospheric pressure. 如請求項1之熱處理方法，其中於上述減壓步驟中，使自上述腔室之 排氣流量隨時間而增加。 The heat treatment method according to claim 1, wherein in the above decompression step, the Exhaust gas flow increases with time. 如請求項1之熱處理方法，其中於上述恢復壓力步驟中，使向上述腔室之供氣流量隨時間而增加。 The heat treatment method according to claim 1, wherein in the pressure recovery step, the gas supply flow rate to the chamber is increased with time. 如請求項1之熱處理方法，其中於上述照射步驟之後，使上述腔室內為大氣壓並以50升/分鐘以上100升/分鐘以下之流量使惰性氣體流入至上述腔室內。 The heat treatment method according to claim 1, wherein after the irradiation step, the inside of the chamber is brought to atmospheric pressure and an inert gas is flowed into the chamber at a flow rate of 50 liters/minute or more and 100 liters/minute or less. 如請求項1之熱處理方法，其中於上述搬入步驟中，一面將上述腔室之搬送開口部開放，一面對上述腔室內供給惰性氣體。 The heat treatment method according to claim 1, wherein in the carrying-in step, while opening the conveying opening of the chamber, an inert gas is supplied facing the chamber. 一種熱處理裝置，其特徵在於：其係對基板照射閃光而形成接觸者，且具備：腔室，其收容成膜有TiN膜之基板；閃光燈，其對收容於上述腔室之上述基板照射閃光；排氣部，其將上述腔室內之氛圍氣體排氣；氣體供給部，其對上述腔室供給特定之處理氣體；及控制部，其以如下方式控制上述排氣部及上述氣體供給部，即，於將上述腔室內減壓至較大氣壓低之第1壓力之後，於恢復壓力至較第1壓力高之第2壓力之狀態下自上述閃光燈對上述基板之表面照射閃光，其中第2壓力高於第1壓力且低於大氣壓。 A heat treatment device, characterized in that it irradiates the substrate with flash to form a contact, and is provided with: a chamber that houses the substrate with the TiN film formed thereon; a flash lamp that radiates flash to the substrate contained in the chamber; An exhaust part that exhausts the atmospheric gas in the chamber; a gas supply part that supplies a specific processing gas to the chamber; and a control part that controls the exhaust part and the gas supply part as follows, namely After depressurizing the chamber to a first pressure lower than the larger pressure, irradiate the flash from the flash lamp on the surface of the substrate with the pressure restored to a second pressure higher than the first pressure, wherein the second pressure is high At the first pressure and below atmospheric pressure. 一種熱處理裝置，其特徵在於：其係對基板照射閃光而形成接觸者，且具備：腔室，其收容成膜有TiN膜之基板；閃光燈，其對收容於上述腔室之上述基板照射閃光；排氣部，其將上述腔室內之氛圍氣體排氣；氣體供給部，其對上述腔室供給特定之處理氣體；及控制部，其以如下方式控制上述排氣部及上述氣體供給部，即，於將上述腔室內減壓至較大氣壓低之第1壓力之後，於恢復壓力至較第1壓力高之第2壓力之狀態下自上述閃光燈對上述基板之表面照射閃光，其中第2壓力高於大氣壓。 A heat treatment device, characterized in that it irradiates the substrate with flash to form a contact, and is provided with: a chamber that houses the substrate with the TiN film formed thereon; a flash lamp that radiates flash to the substrate contained in the chamber; An exhaust part that exhausts the atmospheric gas in the chamber; a gas supply part that supplies a specific processing gas to the chamber; and a control part that controls the exhaust part and the gas supply part as follows, namely After depressurizing the chamber to a first pressure lower than the larger pressure, irradiate the flash from the flash lamp on the surface of the substrate with the pressure restored to a second pressure higher than the first pressure, wherein the second pressure is high At atmospheric pressure. 如請求項7之熱處理裝置，其中上述控制部以如下方式控制上述排氣部，即，於將上述腔室內減壓至第1壓力時，自上述腔室之排氣流量隨時間而增加。 The heat treatment apparatus according to claim 7, wherein the control section controls the exhaust section in such a manner that when the chamber is decompressed to the first pressure, the flow rate of the exhaust gas from the chamber increases with time. 如請求項7之熱處理裝置，其中上述控制部以如下方式控制上述氣體供給部，即，於將上述腔室內自第1壓力恢復壓力至第2壓力時，向上述腔室之供氣流量隨時間而增加。 The heat treatment apparatus according to claim 7, wherein the control section controls the gas supply section in such a manner that, when the pressure in the chamber is restored from the first pressure to the second pressure, the flow rate of the gas supplied to the chamber over time And increase. 如請求項7之熱處理裝置，其中上述控制部以如下方式控制上述排氣部及上述氣體供給部，即，於上述閃光照射後，使上述腔室內為大氣壓並以50升/分鐘以上100升/分鐘以下之流量使惰性氣體流入至上述腔室內。 The heat treatment apparatus according to claim 7, wherein the control section controls the exhaust section and the gas supply section in such a manner that, after the flash irradiation, the chamber is brought to atmospheric pressure at 50 liters/minute or more and 100 liters/minute A flow rate of less than a minute allows the inert gas to flow into the chamber.
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