TWI685372B - Filter material preparation method, filter material and water purification system - Google Patents

Filter material preparation method, filter material and water purification system Download PDF

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TWI685372B
TWI685372B TW107118417A TW107118417A TWI685372B TW I685372 B TWI685372 B TW I685372B TW 107118417 A TW107118417 A TW 107118417A TW 107118417 A TW107118417 A TW 107118417A TW I685372 B TWI685372 B TW I685372B
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filter material
filter
silicon
active
nano
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TW107118417A
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TW201916932A (en
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李東峯
徐盟貴
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友達晶材股份有限公司
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Priority to US16/169,316 priority Critical patent/US20190126178A1/en
Priority to JP2018201841A priority patent/JP6783841B2/en
Priority to CN201811258173.8A priority patent/CN109718602B/en
Priority to EP18202955.3A priority patent/EP3476458B1/en
Priority to KR1020180129700A priority patent/KR20200068031A/en
Publication of TW201916932A publication Critical patent/TW201916932A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02—Types of fibres, filaments or particles, self-supporting or supported materials
    • B01D2239/0258—Types of fibres, filaments or particles, self-supporting or supported materials comprising nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Filtering Materials (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

一種濾材的製備方法，包含下列步驟：(1)提供一個包含活性成分及黏結材的混合材，其中，該活性成分包含過濾材料及奈米矽，且該黏結材用於黏結過濾材料與奈米矽；及(2) 燒結壓合該混合材，得到該濾材。以本發明製備方法所製得的濾材作為淨水系統之濾心時，不易有濾心阻塞及所製得氫水的氫氣含量與矽酸含量下降的問題。A method for preparing a filter material includes the following steps: (1) A mixed material including an active ingredient and a binding material is provided, wherein the active ingredient includes a filtering material and nano-silicon, and the binding material is used to bond the filtering material and the nano-material Silicon; and (2) sintering and pressing the mixed material to obtain the filter material. When the filter material prepared by the preparation method of the present invention is used as a filter element of a water purification system, the problems of clogging of the filter element and the decrease of the hydrogen content and the silicic acid content of the prepared hydrogen water are less likely to occur.

Description

濾材的製備方法、濾材及淨水系統Filter material preparation method, filter material and water purification system

本發明是有關於一種濾材的製備方法、濾材及淨水系統，特別是指一種含有奈米矽的濾材的製備方法、濾材及淨水系統。The invention relates to a method for preparing a filter material, a filter material and a water purification system, in particular to a method for preparing a filter material containing nano-silicon, a filter material and a water purification system.

氫水(hydrogen water)為含有氫氣的純水，其在飲用後，能助於除去存在人體內的自由基，因而成為熱門的保健飲品。Hydrogen water (hydrogen water) is pure water containing hydrogen. After drinking, it can help to remove free radicals present in the human body, so it has become a popular health drink.

目前市面上所販售的氫水，大多是將高純度氫氣直接溶於純水中，或是透過鎂粉或鎂錠與純水反應而使純水產成氫氣所製得。但是，前者方法存在著高純度氫氣取得不易、氫氣溶解困難及具有危險性等問題；後者方法則會於純水中殘留部分與心血管疾病藥品衝突的氫氧化鎂，因而飲用後易引發急性藥物中毒、急性腎衰竭或高血鎂症等問題。Most of the hydrogen water currently on the market is made by dissolving high-purity hydrogen directly in pure water, or by reacting pure water with magnesium powder or magnesium ingots to make pure water into hydrogen. However, the former method has problems such as difficulty in obtaining high-purity hydrogen, difficulty in dissolving hydrogen, and danger; the latter method may leave some magnesium hydroxide in pure water that conflicts with cardiovascular disease drugs, so it is easy to cause acute drugs after drinking. Problems such as poisoning, acute kidney failure, or hypermagnesemia.

因此，本發明的第一目的，即在提供一種濾材的製備方法。Therefore, the first object of the present invention is to provide a method for preparing a filter material.

於是，本發明濾材的製備方法，包含下列步驟： (1) 提供一個包含活性成分及黏結材的混合材，其中，該活性成分包含過濾材料及奈米矽，且該黏結材用於黏結過濾材料與奈米矽；及 (2) 燒結壓合該混合材，得到該濾材。Therefore, the preparation method of the filter material of the present invention includes the following steps: (1) Provide a mixed material containing an active ingredient and a binding material, wherein the active ingredient includes a filter material and nano silicon, and the bonding material is used to bond the filter material And nano silicon; and (2) sintering and pressing the mixed material to obtain the filter material.

因此，本發明還有一第二目的，即在提供一種濾材。Therefore, the present invention has a second object, namely to provide a filter material.

於是，本發明濾材包含至少一個矽濾層。Therefore, the filter material of the present invention includes at least one silicon filter layer.

該矽濾層包括活性成分及黏結材，其中，該活性成分包含過濾材料及奈米矽，且該黏結材黏結過濾材料與奈米矽。The silicon filter layer includes an active component and a bonding material, wherein the active component includes a filter material and nano silicon, and the bonding material bonds the filter material and the nano silicon.

此外，本發明還有一第三目的，即在提供一種淨水系統。In addition, the present invention has a third object, namely to provide a water purification system.

於是，本發明淨水系統包含一個濾水管路及一個濾芯裝置。Therefore, the water purification system of the present invention includes a water filtering pipeline and a filter element device.

該濾水管路包括一個入水口與一個出水口。The water filtering pipeline includes a water inlet and a water outlet.

該濾芯裝置與該濾水管路相連通且設置在該入水口與該出水口間，並包括前述的濾材。The filter element device communicates with the water filtration pipeline and is disposed between the water inlet and the water outlet, and includes the aforementioned filter material.

本發明的功效在於：本發明製備方法由於步驟(1)中還混合了黏結材，所以在經壓合燒結步驟後所製得的濾材，其活性成分中的奈米矽能藉由該黏結材與該過濾材料黏結在一起而不易與該過濾材料分離，因此以本發明的濾材作為淨水系統之濾心時，不易有濾心阻塞及所製得氫水的氫氣含量與矽酸含量下降的問題。The effect of the present invention lies in that, in the preparation method of the present invention, since the bonding material is also mixed in step (1), the nano-silicon in the active ingredient of the filter material obtained after the compression and sintering step can pass through the bonding material The filter material sticks together and is not easy to separate from the filter material. Therefore, when the filter material of the present invention is used as a filter element of a water purification system, the filter element is unlikely to be blocked and the hydrogen content and silicic acid content of the prepared hydrogen water decrease problem.

以下將就本發明內容進行詳細說明：The content of the present invention will be described in detail below:

[[ 濾材的製備方法Preparation method of filter material ]]

＜＜ 步驟step (1)＞(1)＞

特別說明的是，該黏結材除了能用於黏結過濾材料與奈米矽外，也能用於黏結過濾材料中的每個粒子，以過濾材料為活性碳為例，該黏結材能用於黏結每個活性碳粒子。較佳地，該黏結材選自於聚乙烯(polyethylene, PE)、聚丙烯(polypropylene, PP)或前述的組合。更佳地，該黏結材為聚乙烯。聚乙烯例如但不限於是高密度聚乙烯(high density polyethylene, HDPE)、線性低密度聚乙烯(linear low-density polyethylene, LLDPE)、超高分子量聚乙烯(ultra high molecular weight polyethylene, UHMWPE)或前述的組合。又更佳地，該黏結材為超高分子量聚乙烯。又更佳地，該超高分子量聚乙烯的平均重量分子量範圍為1.5×106 ~5×106 g/mol，密度範圍為0.92~0.95 g/cm3 。又更佳地，該黏結材除了上述的黏結功能外，自身還可以成型為多孔性結構，詳言之，該黏結材是由數個黏結材粒子所形成，在預定的溫度及壓力下，各個黏結材粒子彼此會相互連結形成該黏結材，因而使得該黏結材具有多孔性結構。In particular, the bonding material can be used not only to bond the filter material and the nano silicon, but also to bond each particle in the filter material. Taking the filter material as activated carbon as an example, the bonding material can be used to bond Each activated carbon particle. Preferably, the bonding material is selected from polyethylene (PE), polypropylene (PP) or a combination of the foregoing. More preferably, the bonding material is polyethylene. Polyethylene such as, but not limited to, high density polyethylene (HDPE), linear low-density polyethylene (LLDPE), ultra high molecular weight polyethylene (UHMWPE) or the foregoing The combination. Even more preferably, the bonding material is ultra-high molecular weight polyethylene. Even more preferably, the ultra-high molecular weight polyethylene has an average weight molecular weight ranging from 1.5×10 6 to 5×10 6 g/mol and a density ranging from 0.92 to 0.95 g/cm 3 . Even better, in addition to the above-mentioned bonding function, the bonding material itself can also be formed into a porous structure. In detail, the bonding material is formed of several bonding material particles, each of which is under a predetermined temperature and pressure. The particles of the bonding material are connected to each other to form the bonding material, so that the bonding material has a porous structure.

該過濾材料為現有能用於過濾水的材料。該過濾材料可為多孔性材料、非多孔性材料或前述的組合。該多孔性材料例如但不限於是活性碳、多孔性陶瓷、沸石、多孔性二氧化矽、竹炭、麥飯石或前述的組合。該非多孔性材料例如但不限於是石英砂。較佳地，該過濾材料為多孔性材料。更佳地，該過濾材料為粉狀多孔性材料(例如粉狀活性碳)或顆粒狀多孔性材料(例如顆粒狀活性碳)。又更佳地，該過濾材料為顆粒狀多孔性材料。The filter material is an existing material that can be used to filter water. The filter material may be a porous material, a non-porous material, or a combination of the foregoing. The porous material is, for example but not limited to, activated carbon, porous ceramics, zeolite, porous silica, bamboo charcoal, maifanite, or a combination of the foregoing. The non-porous material is, for example but not limited to, quartz sand. Preferably, the filter material is a porous material. More preferably, the filter material is a powdery porous material (such as powdered activated carbon) or a particulate porous material (such as granular activated carbon). Even more preferably, the filter material is a granular porous material.

需先說明的是，本發明中所提及「第一過濾材料」與「第二過濾材料」的定義與「過濾材料」的定義並無差異，其詳細說明皆同於前段與後段關於「過濾材料」的詳細說明。It should be noted that the definitions of "first filter material" and "second filter material" mentioned in the present invention are not different from the definition of "filter material", and their detailed descriptions are the same as the "filter" Detailed description of "Materials".

較佳地，該過濾材料的平均粒徑範圍為20~400 µm 。在某些特定實施例中，該過濾材料的平均粒徑範圍為20~100 µm。在某些特定實施例中，該過濾材料的平均粒徑範圍為30~100 µm。更佳地，該過濾材料的平均粒徑範圍為40~80 µm。在某些特定實施例中，該過濾材料的平均粒徑範圍為100~400 µm。更佳地，該過濾材料的平均粒徑範圍為150~250 µm。Preferably, the average particle size of the filter material ranges from 20 to 400 µm. In some specific embodiments, the average particle size of the filter material ranges from 20 to 100 µm. In some specific embodiments, the average particle size of the filter material ranges from 30 to 100 µm. More preferably, the average particle size of the filter material ranges from 40 to 80 µm. In some specific embodiments, the average particle size of the filter material ranges from 100 to 400 µm. More preferably, the average particle size of the filter material ranges from 150 to 250 µm.

較佳地，該奈米矽的平均粒徑範圍為50~300 nm。更佳地，該奈米矽的平均粒徑範圍為100~250 nm。Preferably, the average particle size of the nano-silicon is in the range of 50-300 nm. More preferably, the nano-silicon has an average particle size ranging from 100 to 250 nm.

較佳地，該奈米矽具有至少二種不同的粒徑。更佳地，任二種不同的粒徑差介於50 nm至150 nm間。Preferably, the nano-silicon has at least two different particle sizes. More preferably, any two different particle size differences are between 50 nm and 150 nm.

較佳地，該步驟(1)的活性成分包含至少一種過濾材料，該過濾材料係先與奈米矽混合之後，再一同與該黏結材及另一個相同或相異的過濾材料混合。Preferably, the active ingredient in the step (1) includes at least one filter material. The filter material is first mixed with nano-silicon, and then mixed together with the binding material and another filter material that is the same or different.

較佳地，以該混合材的總重為100 wt%計，該過濾材料與該奈米矽的總重量範圍為55~85 wt%，該黏結材的重量範圍為15~45 wt%。在某些特定實施例中，該過濾材料與該奈米矽的總重量範圍為55~65 wt%，該黏結材的重量範圍為35~45 wt%。Preferably, based on the total weight of the mixed material being 100 wt%, the total weight range of the filter material and the nano-silicon is 55-85 wt%, and the weight range of the bonding material is 15-45 wt%. In some specific embodiments, the total weight range of the filter material and the nano-silicon is 55~65 wt%, and the weight range of the bonding material is 35~45 wt%.

較佳地，該活性成分包含有多個活性粒子，每個活性粒子包含一個由過濾材料所組成的核心，及多個吸附於該核心上的奈米矽。更佳地，以該等活性粒子的總重量為100 wt%計，該等活性粒子之奈米矽的重量範圍為10~40 wt%。又更佳地，該等活性粒子中之奈米矽的重量範圍為15~40 wt%。在某些特定實施例中，該等活性粒子中之奈米矽的重量範圍為30~40 wt%。Preferably, the active ingredient includes a plurality of active particles, each active particle includes a core composed of a filter material, and a plurality of nano-silicon adsorbed on the core. More preferably, based on the total weight of the active particles being 100 wt%, the weight range of the nanosilicon of the active particles is 10-40 wt%. Even more preferably, the weight range of nano-silicon in the active particles is 15-40 wt%. In some specific embodiments, the weight range of the nano-silicon in the active particles is 30-40 wt%.

更佳地，該等活性粒子的過濾材料為第一過濾材料，該步驟(1)的混合材還包含第二過濾材料，且是利用下列步驟(A)及(B)所得到： (A) 混合該等活性粒子與該黏結材，得到第一混合物，以及混合該第二過濾材料與該黏結材，得到第二混合物； (B) 混合該第一混合物與該第二混合物，得到該混合材。More preferably, the filter material of the active particles is the first filter material, and the mixed material of step (1) further includes the second filter material, and is obtained by using the following steps (A) and (B): (A) Mixing the active particles and the binder to obtain a first mixture, and mixing the second filter material and the binder to obtain a second mixture; (B) mixing the first mixture and the second mixture to obtain the mixture .

又更佳地，在該步驟(B)中，該第一混合物與該第二混合物的重量比值為1.5~2.5。Even more preferably, in the step (B), the weight ratio of the first mixture to the second mixture is 1.5-2.5.

較佳地，該步驟(1)的混合材是利用下列步驟(a)及(b)所得到： (a) 混合該活性成分及該黏結材，形成一個活性混合層；及 (b) 混合該過濾材料及該黏結材並部分或完全覆蓋該活性混合層，而於該活性混合層表面形成至少一個過濾混合層。Preferably, the mixed material of step (1) is obtained by the following steps (a) and (b): (a) mixing the active ingredient and the binding material to form an active mixing layer; and (b) mixing the The filter material and the binding material partially or completely cover the active mixing layer, and at least one filter mixing layer is formed on the surface of the active mixing layer.

更佳地，該步驟(1)的過濾材料包含第一過濾材料及第二過濾材料，且該步驟(a)的活性成分包含第一過濾材料及奈米矽，以及該步驟(b)的過濾材料為第二過濾材料，該第一過濾材料與該第二過濾材料為相同或不相同的過濾材料。需說明的是，該第一過濾材料與該第二過濾材料的詳細說明分別與前述該過濾材料的詳細說明相同。More preferably, the filter material of the step (1) includes a first filter material and a second filter material, and the active ingredient of the step (a) includes the first filter material and nanosilica, and the filter of the step (b) The material is a second filter material, and the first filter material and the second filter material are the same or different filter materials. It should be noted that the detailed descriptions of the first filter material and the second filter material are the same as the aforementioned detailed description of the filter material.

較佳地，該步驟(1)的混合材是利用下列步驟(I)及(II)所得到： (I) 混合該活性成分及該黏結材，形成多個活性混合層； 及 (II) 使兩個相鄰的活性混合層間形成一個由該黏結材所組成的黏結層。Preferably, the mixed material of step (1) is obtained by the following steps (I) and (II): (I) mixing the active ingredient and the binding material to form a plurality of active mixed layers; and (II) A bonding layer composed of the bonding material is formed between two adjacent active mixed layers.

＜＜ 步驟step (2)＞(2)＞

較佳地，是以一預定的壓力及溫度於一模具中壓合燒結該混合材。Preferably, the mixed material is pressed and sintered in a mold at a predetermined pressure and temperature.

較佳地，該混合材是於160~250℃下進行燒結。更佳地，是於180~200℃下進行燒結。Preferably, the mixed material is sintered at 160-250°C. More preferably, it is sintered at 180~200℃.

更佳地，該混合材是先於50~70分鐘內升溫至180~200℃後，再於180~200℃下進行燒結50~70分鐘。More preferably, the mixed material is first heated to 180-200°C within 50-70 minutes, and then sintered at 180-200°C for 50-70 minutes.

[[ 濾材Filter ]]

較佳地，該黏結材具有多孔性黏結材。Preferably, the bonding material has a porous bonding material.

較佳地，該過濾材料為多孔性材料。Preferably, the filter material is a porous material.

較佳地，該活性成分含有多個活性粒子，每個活性粒子包含一個由過濾材料所組成的核心，及多個吸附於該核心上的奈米矽。Preferably, the active ingredient contains a plurality of active particles, each active particle includes a core composed of a filter material, and a plurality of nano-silicon adsorbed on the core.

更佳地，該等活性粒子的過濾材料為第一過濾材料，且該濾材還包含第二過濾材料，該等活性粒子與該第二過濾材料經由該黏結材黏結在一起。需說明的是，該第一過濾材料與該第二過濾材料可為相同或不同種類的過濾材料。又更佳地，該第一過濾材料與該第二過濾材料為相同的過濾材料。More preferably, the filter material of the active particles is a first filter material, and the filter material further includes a second filter material, and the active particles and the second filter material are bonded together via the bonding material. It should be noted that the first filter material and the second filter material may be the same or different types of filter materials. Even more preferably, the first filter material and the second filter material are the same filter material.

更佳地，該等活性粒子的過濾材料為第一過濾材料，且該活性成分還包含第二過濾材料。又更佳地，該第二過濾材料上吸附多個奈米矽，並且吸附於該第二過濾材料上的奈米矽數量會少於該等活性粒子中的奈米矽數量。又更佳地，該第一過濾材料與該第二過濾材料為相同的過濾材料。More preferably, the filter material of the active particles is a first filter material, and the active ingredient further includes a second filter material. Even more preferably, a plurality of nano-silicons are adsorbed on the second filter material, and the amount of nano-silicon adsorbed on the second filter material is less than the amount of nano-silicon in the active particles. Even more preferably, the first filter material and the second filter material are the same filter material.

較佳地，本發明的濾材還包含兩個分別覆蓋於該矽濾層的兩相反表面上的過濾層。Preferably, the filter material of the present invention further includes two filter layers respectively covering two opposite surfaces of the silicon filter layer.

較佳地，本發明的濾材還包含一個部份或完全覆蓋於該矽濾層表面上的過濾層。更佳地，該過濾層包括過濾材料及黏結材。Preferably, the filter material of the present invention further includes a filter layer partially or completely covering the surface of the silicon filter layer. More preferably, the filter layer includes filter material and bonding material.

較佳地，該至少一個矽濾層為數個，且彼此相間隔，並該濾材還包含至少一個由黏結材所組成的連接層，每兩個相鄰的矽濾層會透過一個連接層黏接在一起。Preferably, the at least one silicon filter layer is a plurality of and spaced apart from each other, and the filter material further includes at least one connection layer composed of a bonding material, and every two adjacent silicon filter layers will be bonded through a connection layer Together.

特別說明的是，本發明濾材的活性成分、黏結材、過濾材料、奈米矽、活性粒子之詳細說明同前面[濾材的製備方法]之＜步驟(1)＞中關於活性成分、黏結材、過濾材料、奈米矽、活性粒子的說明，而該第一過濾材料與該第二過濾材料的詳細說明也與該過濾材料的詳細說明相同。In particular, the detailed description of the active ingredient, the binding material, the filter material, the nanosilica, and the active particles of the filter material of the present invention is the same as the active ingredient, the binding material, The description of the filter material, nanosilicon, and active particles, and the detailed description of the first filter material and the second filter material are also the same as the detailed description of the filter material.

在本發明被詳細描述前，應當注意在以下的說明內容中，類似的元件是以相同的編號來表示。Before the present invention is described in detail, it should be noted that in the following description, similar elements are denoted by the same number.

＜＜ 物品來源Item source ＞＞

Figure 107118417-A0304-0001
Figure 107118417-A0304-0001

＜＜ 製備例Preparation example 1~5＞1~5＞

製備矽碳粉Preparation of silicon carbon powder (( 含有活性粒子Contains active particles ))

製備例1~5的矽碳粉是分別依據下列步驟所製得：步驟 (i)- 製備奈米矽漿料： 將奈米矽粉加入純度為99.5%(v/v)的酒精中並均勻攪拌，使奈米矽粉分散於酒精中，以製得固含量為15 wt%的奈米矽漿料。其中，以該奈米矽粉的總重為100 wt%計，平均粒徑為100 nm的奈米矽粉重量為40 wt%，平均粒徑為150 nm的奈米矽粉重量為40 wt%，平均粒徑為250 nm的奈米矽粉重量為20 wt%。值得一提的是，在其他實施例中，亦可使用具有二種不同粒徑的奈米矽粉，且二種粒徑的差距介於50~150nm間；當然，在另一個實施例中，亦可只使用單一種粒徑，例如平均粒徑介於100 nm至220 nm間的奈米矽粉。步驟 (ii)- 製備矽碳粉： 取前述步驟(i)所製得的奈米矽漿料，於攪拌下先加入椰殼活性碳粉(過濾材料)，再利用真空烘箱(廠商:柏沅；型號:OVV-125)烘乾後，製得該矽碳粉。其中，製備例1~5之步驟(ii)中，該奈米矽漿料與椰殼活性碳粉的添加量、椰殼活性碳的平均粒徑，以及最終所製得矽碳粉中的奈米矽含量整理於下表1中。 表1

Figure 107118417-A0304-0002
The silicon carbon powders of Preparation Examples 1 to 5 are prepared according to the following steps: Step (i) -Preparation of nano-silicon slurry: Add the nano-silicon powder to alcohol with a purity of 99.5% (v/v) and homogenize Stir to disperse the nano-silica powder in alcohol to prepare a nano-silica slurry with a solid content of 15 wt%. Where the total weight of the nano-silica powder is 100 wt%, the weight of the nano-silica powder with an average particle size of 100 nm is 40 wt%, and the weight of the nano-silica powder with an average particle size of 150 nm is 40 wt% The weight of nano-silica powder with an average particle size of 250 nm is 20 wt%. It is worth mentioning that in other embodiments, nano silicon powder with two different particle sizes can also be used, and the difference between the two particle sizes is between 50-150 nm; of course, in another embodiment, It is also possible to use only a single particle size, for example, nano-silica powder with an average particle size between 100 nm and 220 nm. Step (ii) -Preparation of silicon carbon powder: Take the nano silicon slurry prepared in the previous step (i), add coconut shell activated carbon powder (filter material) under stirring, and then use a vacuum oven (manufacturer: Bai Yuan) ; Model: OVV-125) After drying, the silicon carbon powder is prepared. Among them, in step (ii) of Preparation Examples 1 to 5, the addition amount of the nano-silica slurry and coconut shell activated carbon powder, the average particle size of coconut shell activated carbon, and the nano-particles in the finally prepared silicon carbon powder The content of rice and silicon is summarized in Table 1 below. Table 1
Figure 107118417-A0304-0002

特別說明的是，參閱圖1A及圖1B，製備例1~5所製得的矽碳粉分別含有多個活性粒子113，每個活性粒子113包含一個由過濾材料111(椰殼活性碳粉)所組成的核心114，及多個吸附於該核心114上的奈米矽112。In particular, referring to FIGS. 1A and 1B, the silicon carbon powders prepared in Preparation Examples 1 to 5 respectively contain a plurality of active particles 113, and each active particle 113 includes a filter material 111 (coconut shell activated carbon powder). The composed core 114 and a plurality of nano silicon 112 adsorbed on the core 114.

＜＜ 實施例Examples 1＞1＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 奈米矽粉與椰殼活性碳粉；黏結材Nanometer silicon powder and coconut shell activated carbon powder; bonding material :: GUR2122)GUR2122)

實施例1的濾材是依據下列步驟所製得：步驟 (1)- 製備混合材： 混合15 g平均粒徑大小為40~80 µm的椰殼活性碳粉(過濾材料)、15 g平均粒徑大小為200 nm的奈米矽粉(活性成分)及20 g超高分子量聚乙烯(黏結材GUR2122)後，製得一個混合材。步驟 (2)- 壓合燒結： 將前述步驟(1)所製得的混合材填入不銹鋼模具中進行壓合燒結後，亦即先於60分鐘內升溫至190℃，接著再於190℃下進行燒結60分鐘後，製得實施例1的濾材。The filter material of Example 1 is prepared according to the following steps: Step (1) -Preparation of a mixed material: mixing 15 g of coconut shell activated carbon powder (filter material) with an average particle size of 40 to 80 µm, and an average particle size of 15 g A nanometer silicon powder (active ingredient) with a size of 200 nm and 20 g of ultra-high molecular weight polyethylene (bonding material GUR2122) were prepared to produce a mixed material. Step (2) -Pressing and sintering: After the mixed material prepared in the previous step (1) is filled in a stainless steel mold for pressing and sintering, it is first heated to 190°C within 60 minutes, and then at 190°C After sintering for 60 minutes, the filter material of Example 1 was prepared.

特別說明的是，參閱圖2，實施例1所製得的濾材即為一個矽濾層1，該矽濾層1包括活性成分11及黏結材12(超高分子量聚乙烯)。該活性成分11含有過濾材料111(椰殼活性碳粉)及奈米矽112。該黏結材12黏結過濾材料111與奈米矽112，且具有多孔性結構(圖2省略繪示出黏結材12的孔洞)。In particular, referring to FIG. 2, the filter material prepared in Example 1 is a silicon filter layer 1. The silicon filter layer 1 includes an active ingredient 11 and a bonding material 12 (ultra-high molecular weight polyethylene). The active ingredient 11 contains a filter material 111 (coconut shell activated carbon powder) and nano silicon 112. The bonding material 12 bonds the filter material 111 and the nano-silicon 112, and has a porous structure (the holes of the bonding material 12 are omitted in FIG. 2).

＜＜ 實施例Examples 2＞2＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 奈米矽粉與椰殼活性碳粉；黏結材Nanometer silicon powder and coconut shell activated carbon powder; bonding material :XM-220):XM-220)

實施例2之濾材及其製備方法與實施例1類似，其差別在於，實施例2的黏結材12及其於步驟(1)中所添加的黏結材是使用廠商為三井且型號為XM-220的超高分子量聚乙烯。The filter material of Example 2 and its preparation method are similar to those of Example 1, except that the bonding material 12 of Example 2 and the bonding material added in step (1) use the manufacturer Mitsui and model XM-220 Of UHMWPE.

＜＜ 實施例Examples 3＞3＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 矽Silicon 碳粉；黏結材Toner; bonding material :GUR2122):GUR2122)

實施例3的製備方法與實施例1類似，其差別在於，實施例3的步驟(1)是依據下列方法製得該混合材：混合30 g製備例1所製得的矽碳粉(活性成分)及20 g超高分子量聚乙烯(黏結材GUR2122)後，製得該混合材。The preparation method of Example 3 is similar to Example 1, except that the step (1) of Example 3 is to prepare the mixed material according to the following method: mixing 30 g of the silicon carbon powder (active ingredient) prepared in Preparation Example 1 ) And 20 g of ultra-high molecular weight polyethylene (bonding material GUR2122), the mixed material was prepared.

特別說明的是，參閱圖3，實施例3所製得的濾材即為一個矽濾層1。該矽濾層1包括活性成分11及黏結材12(超高分子量聚乙烯)。該活性成分11為矽碳粉，該活性成分11(矽碳粉)含有多個活性粒子113，每個活性粒子113具有一個由過濾材料111 (椰殼活性碳)所組成的核心114，及多個吸附於該核心114上的奈米矽112。該黏結材12用於黏結該等活性粒子113。In particular, referring to FIG. 3, the filter material obtained in Example 3 is a silicon filter layer 1. The silicon filter layer 1 includes an active ingredient 11 and a bonding material 12 (ultra-high molecular weight polyethylene). The active ingredient 11 is silicon carbon powder, the active ingredient 11 (silicon carbon powder) contains a plurality of active particles 113, each active particle 113 has a core 114 composed of a filter material 111 (coconut shell activated carbon), and more A nano-silicon 112 adsorbed on the core 114. The bonding material 12 is used to bond the active particles 113.

值得一提的是，在其它實施例中，係可於實施例3的混合材中進一步加入另一個相同(例如活性碳)或相異(例如多孔性陶瓷)的過濾材料。如此一來，矽濾層中會同時存在吸附較多奈米矽的過濾材料(即活性粒子113)與相對吸附少很多甚至無吸附奈米矽的過濾材料。It is worth mentioning that, in other embodiments, another same (for example, activated carbon) or different (for example, porous ceramic) filter material may be further added to the mixed material of Example 3. As a result, there will be both a filter material that adsorbs more nanosilicon (ie, active particles 113) and a filter material that adsorbs much less or no nanosilicon in the silicon filter layer.

＜＜ 實施例Examples 4＞4＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 矽Silicon 碳粉；黏結材Toner; bonding material :: GUR2122)GUR2122)

實施例4之濾材及其製備方法與實施例3類似，其差別在於，實施例4的步驟(1)中，是以製備例2的矽碳粉與超高分子量聚乙烯(黏結材GUR2122)混合而製得該混合材。The filter material of Example 4 and its preparation method are similar to Example 3, the difference is that in step (1) of Example 4, the silicon carbon powder of Preparation Example 2 is mixed with ultra-high molecular weight polyethylene (bonding material GUR2122) And the mixed material is prepared.

＜＜ 實施例Examples 5＞5＞

製備濾材 ( 活性成分 : 矽 碳粉；黏結材 : GUR2122) 步驟 (1)- 製備混合材： 混合3 g椰殼活性碳粉(過濾材料)及2 g超高分子量聚乙烯(黏結材GUR2122)，得到一個第一過濾混合層；接著在該第一過濾混合層上填入6 g製備例1所製得的矽碳粉(活性成分)及4 g超高分子量聚乙烯(黏結材GUR2122)，得到一個活性混合層；最後在該活性混合層上填入1.2 g椰殼活性碳(過濾材料)及0.8 g超高分子量聚乙烯(黏結材GUR2122)，得到一個第二過濾混合層後，製得該混合材。步驟 (2)- 壓合燒結： 將前述步驟(1)所製得的混合材於不銹鋼模具中進行壓合燒結，例如先於60分鐘內升溫至190℃，接著再於190℃下進行燒結60分鐘後，製得實施例5的濾材。 Preparation of filter material ( active ingredient : silicon carbon powder; bonding material : GUR2122) Step (1) -Preparation of mixing material: mixing 3 g coconut shell activated carbon powder (filter material) and 2 g ultra-high molecular weight polyethylene (bonding material GUR2122), A first filtration and mixing layer was obtained; then the first filtration and mixing layer was filled with 6 g of the silicon carbon powder (active ingredient) prepared in Preparation Example 1 and 4 g of ultra-high molecular weight polyethylene (bonding material GUR2122) to obtain An active mixed layer; finally, 1.2 g coconut shell activated carbon (filter material) and 0.8 g ultra-high molecular weight polyethylene (bonding material GUR2122) are filled on the active mixed layer to obtain a second filter mixed layer Mixed wood. Step (2) -Pressing and sintering: The mixed material prepared in the previous step (1) is pressed and sintered in a stainless steel mold, for example, first heated to 190°C within 60 minutes, and then sintered at 190°C for 60 After 5 minutes, the filter material of Example 5 was prepared.

特別說明的是，參閱圖4，實施例5所製得的濾材包含一個矽濾層1，及兩個分別覆蓋於該矽濾層1的兩相反表面上的過濾層2。該矽濾層1是由前述步驟(1)中的活性混合層所形成；該等過濾層2是分別由前述步驟(1)中的第一過濾混合層與第二過濾混合層所形成。In particular, referring to FIG. 4, the filter material prepared in Example 5 includes a silicon filter layer 1 and two filter layers 2 respectively covering two opposite surfaces of the silicon filter layer 1. The silicon filter layer 1 is formed by the active mixing layer in the aforementioned step (1); the filter layers 2 are respectively formed by the first filter mixing layer and the second filter mixing layer in the aforementioned step (1).

該矽濾層1包括活性成分11及黏結材12(超高分子量聚乙烯)。該活性成分11為矽碳粉，該活性成分11(矽碳粉)含有多個活性粒子113，每個活性粒子113包含一個由過濾材料111(椰殼活性碳粉)所組成的核心114，及多個吸附於該核心114上的奈米矽112。該黏結材12黏結該等活性粒子113。當然，在其他實施例中，該矽濾層也可以替換為實施例1所述之矽濾層。The silicon filter layer 1 includes an active ingredient 11 and a bonding material 12 (ultra-high molecular weight polyethylene). The active ingredient 11 is silicon carbon powder, the active ingredient 11 (silicon carbon powder) contains a plurality of active particles 113, each active particle 113 includes a core 114 composed of a filter material 111 (coconut shell activated carbon powder), and A plurality of nano silicon 112 adsorbed on the core 114. The bonding material 12 bonds the active particles 113. Of course, in other embodiments, the silicon filter layer can also be replaced with the silicon filter layer described in Embodiment 1.

每個過濾層2包括過濾材料111(椰殼活性碳粉)及黏結材12(超高分子量聚乙烯)。值得一提的是，在其他實施例中，該過濾層2的數量可以只有一個，例如單獨設置於該矽濾層之出水側的表面上。此外，在其他衍生實施例中，該等過濾層2也可以完全包覆該矽濾層1表面。Each filter layer 2 includes a filter material 111 (coconut shell activated carbon powder) and a binding material 12 (ultra-high molecular weight polyethylene). It is worth mentioning that, in other embodiments, the number of the filter layer 2 may be only one, for example, it is separately provided on the surface of the silicon filter layer on the water outlet side. In addition, in other derivative embodiments, the filter layers 2 can also completely cover the surface of the silicon filter layer 1.

＜＜ 實施例Examples 6~7＞6~7＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 矽Silicon 碳粉；黏結材Toner; bonding material :: GUR2122)GUR2122)

實施例6~7的濾材分別是依據下列步驟所製得：步驟 (1)- 製備混合材： 先於不銹鋼模具中混合製備例3的矽碳粉及超高分子量聚乙烯(黏結材GUR2122)，得到一個第一活性混合層；接著於該第一活性混合層上填入一層超高分子量聚乙烯(黏結材GUR2122)，得到一個第一黏結層；接著於該第一黏結層上混合製備例3的矽碳粉及超高分子量聚乙烯(黏結材GUR2122)，得到一個第二活性混合層；接著於該第二活性混合層上填入一層超高分子量聚乙烯(黏結材GUR2122) ，得到一個第二黏結層；接著於該第二黏結層上混合製備例3的矽碳粉及超高分子量聚乙烯(黏結材GUR2122)，得到一個第三活性混合層後，製得該混合材。步驟 (2)- 壓合燒結： 將前述步驟(1)所製得的混合材於該不銹鋼模具中進行壓合燒結，例如先於60分鐘內升溫至190℃，接著再於190℃下進行燒結60分鐘後，分別製得實施例6~7的濾材。 其中，前述步驟(1)中，該實施例6的該第一至第三活性混合層的總重為235 g，該第一與該第二黏結層的重量分別為6 g；而該實施例7的該第一至第三活性混合層的總重為375 g，該第一與第二黏結層的重量分別為8 g；此外，不論是實施例6或7，分別以該第一至第三活性混合層的總重為100 wt%計，其矽碳粉的含量分別為20 wt%，而超高分子量聚乙烯的含量分別為80 wt%。The filter materials of Examples 6 to 7 are respectively prepared according to the following steps: Step (1) -Preparation of mixed materials: the silicon carbon powder and ultra-high molecular weight polyethylene (bonded material GUR2122) of Preparation Example 3 are mixed in a stainless steel mold, A first active mixed layer was obtained; then a layer of ultra-high molecular weight polyethylene (adhesive material GUR2122) was filled on the first active mixed layer to obtain a first adhesive layer; then, the first adhesive layer was mixed with Preparation Example 3 Silicon carbide powder and ultra-high molecular weight polyethylene (bonding material GUR2122) to obtain a second active mixed layer; then fill a layer of ultra-high molecular weight polyethylene (bonding material GUR2122) on the second active mixed layer to obtain a first Two adhesive layers; then mix the silicon carbon powder and ultra-high molecular weight polyethylene (adhesive material GUR2122) of Preparation Example 3 on the second adhesive layer to obtain a third active mixed layer, and then prepare the mixed material. Step (2) -Pressing and sintering: The mixed material prepared in the previous step (1) is pressed and sintered in the stainless steel mold, for example, firstly heated to 190°C within 60 minutes, and then sintered at 190°C After 60 minutes, the filter materials of Examples 6 to 7 were prepared respectively. Wherein, in the aforementioned step (1), the total weight of the first to third active mixed layers of the embodiment 6 is 235 g, and the weights of the first and second adhesive layers are 6 g respectively; and the embodiment The total weight of the first to third active mixed layers of 7 is 375 g, and the weights of the first and second adhesive layers are 8 g; in addition, regardless of Embodiment 6 or 7, the first to third The total weight of the three active mixed layers is 100 wt%, the content of silicon carbon powder is 20 wt%, and the content of ultra-high molecular weight polyethylene is 80 wt%.

特別說明的是，參閱圖5，實施例6與7所製得的濾材分別包含一個第一矽濾層31、一個第二矽濾層32、一個第三矽濾層33、一個位於該第一與第二矽濾層31,32間且用於黏接該第一與該第二矽濾層31,32的第一連接層34、一個位於該第二與第三矽濾層32,33間且用於黏接該第二與第三矽濾層32,33的第二連接層35，及一個貫穿該第一至第三矽濾層31,32,33及該第一與第二連接層34,35的中心穿孔36，該第一至第三矽濾層31,32,33是分別是由前述步驟(1)中的第一至第三活性混合層所形成，該第一與第二連接層34,35分別是由該第一與第二黏結層所形成，而該第一至第三矽濾層31,32,33的描述與實施例5的矽濾層描述相同。其中，實施例6所製得之濾材的高度d1為239 mm，外徑d2為46.5 mm，內徑d3為20 mm；實施例7所製得之濾材的高度d1為237 mm，外徑d2為64 mm，內徑d3為34 mm。In particular, referring to FIG. 5, the filter materials prepared in Examples 6 and 7 respectively include a first silicon filter layer 31, a second silicon filter layer 32, a third silicon filter layer 33, and one located in the first Between the second silicon filter layers 31, 32 and for connecting the first and second silicon filter layers 31, 32 to the first connection layer 34, and between the second and third silicon filter layers 32, 33 And a second connection layer 35 for bonding the second and third silicon filter layers 32, 33, and a first through third silicon filter layers 31, 32, 33 and the first and second connection layers The central through holes 36 of 34, 35, the first to third silicon filter layers 31, 32, 33 are respectively formed by the first to third active mixed layers in the aforementioned step (1), the first and second The connection layers 34 and 35 are respectively formed by the first and second adhesion layers, and the description of the first to third silicon filter layers 31, 32 and 33 is the same as the description of the silicon filter layer of Embodiment 5. Among them, the height d1 of the filter material obtained in Example 6 is 239 mm, the outer diameter d2 is 46.5 mm, and the inner diameter d3 is 20 mm; the height d1 of the filter material obtained in Example 7 is 237 mm, and the outer diameter d2 is 64 mm, the inner diameter d3 is 34 mm.

＜＜ 實施例Examples 8＞8＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 矽Silicon 碳粉；黏結材Toner; bonding material :: GUR2122)GUR2122)

實施例8的製備方法與實施例3類似，其差別在於，實施例8的步驟(1)中，是以製備例3的矽碳粉與超高分子量聚乙烯(黏結材GUR2122)混合而製得該混合材，且以該混合材的總重為100 wt%計，該矽碳粉的重量為77.5 wt%，該超高分子量聚乙烯的重量為22.5 wt%。The preparation method of Example 8 is similar to that of Example 3, except that step (1) of Example 8 is prepared by mixing the silicon carbide powder of Preparation Example 3 with ultra-high molecular weight polyethylene (bonding material GUR2122) For the mixed material, based on the total weight of the mixed material being 100 wt%, the weight of the silicon carbon powder is 77.5 wt%, and the weight of the ultra-high molecular weight polyethylene is 22.5 wt%.

特別說明的是，參閱圖6，實施例8所製得的濾材即為一個矽濾層1，但其與實施例3所製得之濾材的差異在於，實施例8的該矽濾層1被一個中心穿孔13貫穿。其中，水可經由外側向中心流過該矽濾層1，再由該中心穿孔13流出。In particular, referring to FIG. 6, the filter material obtained in Example 8 is a silicon filter layer 1, but the difference from the filter material obtained in Example 3 is that the silicon filter layer 1 of Example 8 is A central perforation 13 penetrates. Wherein, water can flow through the silicon filter layer 1 from the outside to the center, and then flow out from the center perforation 13.

＜＜ 實施例Examples 9＞9＞

製備濾材Preparation of filter material (( 活性成分Active ingredient :: 矽Silicon 碳粉；黏結材Toner; bonding material :: GUR2122)GUR2122)

實施例9的濾材是依據下列步驟所製得：步驟 (1)- 製備混合材： 先混合製備例4的矽碳粉(所包含的椰殼活性碳粉相當於第一過濾材料)及超高分子量聚乙烯(黏結材GUR2122)後，得到第一混合物，同時混合椰殼活性碳粉(相當於第二過濾材料)及超高分子量聚乙烯(黏結材GUR2122)後，得到第二混合物，且以該第一混合物的總重為100 wt%計，其矽碳粉的含量為75 wt%，而超高分子量聚乙烯的含量為25 wt%，以該第二混合物的總重為100 wt%計，其椰殼活性碳粉的含量為75 wt%，而超高分子量聚乙烯的含量為25 wt%。接著，混合該第一混合物及該第二混合物(重量比為2：1)後，得到該混合材。步驟 (2)- 壓合燒結： 將前述步驟(1)所製得的混合材於該不銹鋼模具中進行壓合燒結，例如先於60分鐘內升溫至190℃，接著再於190℃下進行燒結60分鐘後，分別製得實施例9的濾材。The filter material of Example 9 is prepared according to the following steps: Step (1) -Preparation of the mixed material: firstly mix the silicon carbon powder of the preparation example 4 (contained coconut shell activated carbon powder is equivalent to the first filter material) and ultra-high After molecular weight polyethylene (bonding material GUR2122), the first mixture is obtained, and after mixing coconut shell activated carbon powder (equivalent to the second filter material) and ultra-high molecular weight polyethylene (bonding material GUR2122), a second mixture is obtained, and The total weight of the first mixture is 100 wt%, the content of silicon carbon powder is 75 wt%, and the content of ultra-high molecular weight polyethylene is 25 wt%, based on the total weight of the second mixture is 100 wt% The content of coconut shell activated carbon powder is 75 wt%, and the content of ultra-high molecular weight polyethylene is 25 wt%. Next, after mixing the first mixture and the second mixture (the weight ratio is 2:1), the mixed material is obtained. Step (2) -Pressing and sintering: The mixed material prepared in the previous step (1) is pressed and sintered in the stainless steel mold, for example, firstly heated to 190°C within 60 minutes, and then sintered at 190°C After 60 minutes, the filter material of Example 9 was prepared separately.

參閱圖6，實施例9所製得濾材的結構與實施例8相同，且該矽濾層1包括活性成分、第二過濾材料及黏結材(超高分子量聚乙烯)，該活性成分為矽碳粉。該活性成分(矽碳粉)包含多個活性粒子，每個活性粒子包含一個由第一過濾材料所組成的核心，及多個吸附於該核心上的奈米矽，該等活性粒子與該第二過濾材料經由該黏結材黏結在一起。需說明的是，在本實施例中，該第一與第二過濾材料皆為椰殼活性碳粉。Referring to FIG. 6, the structure of the filter material prepared in Example 9 is the same as that in Example 8, and the silicon filter layer 1 includes an active ingredient, a second filter material, and a binding material (ultra-high molecular weight polyethylene). The active ingredient is silicon carbon powder. The active ingredient (silicon carbon powder) contains a plurality of active particles, each active particle includes a core composed of a first filter material, and a plurality of nano-silicon adsorbed on the core, the active particles and the first The two filter materials are bonded together through the bonding material. It should be noted that, in this embodiment, both the first and second filter materials are coconut shell activated carbon powder.

此外，參閱圖7，本實施例9的濾材也可為另一種實施態樣，該濾材即為一矽濾層4，該矽濾層4包含一界定出一中心穿孔41且是由第二混合物所形成的第一混合層42、一環繞在該第二混合層42外圍且是由第一混合物所形成的活性層43，及一環繞在該活性層43外圍且是由第二混合物所形成的第二混合層44。其中，該第一混合物與該第二混合物的成分及比例與該實施例9之步驟(1)中的該第一混合物與該第二混合物相同。另特別一提的是，前述實施例5的濾材也可以是以本實施例的結構態樣呈現；更具體來說，圖4的兩個過濾層2即可以分別是本實施例的第一與第二混合層42、44，圖4的矽濾層1即可以是本實施例的活性層43。In addition, referring to FIG. 7, the filter material of the present embodiment 9 can also be another embodiment, the filter material is a silicon filter layer 4, the silicon filter layer 4 includes a central perforation 41 defined by the second mixture The first mixed layer 42 formed, an active layer 43 surrounding the second mixed layer 42 and formed by the first mixture, and an active layer 43 surrounding the active layer 43 and formed by the second mixture Second mixing layer 44. The components and ratios of the first mixture and the second mixture are the same as those of the first mixture and the second mixture in step (1) of Example 9. Another special mention is that the filter material of the foregoing embodiment 5 can also be presented in the structural form of this embodiment; more specifically, the two filter layers 2 of FIG. 4 can be the first and The second mixed layers 42 and 44 and the silicon filter layer 1 of FIG. 4 may be the active layer 43 of this embodiment.

特別說明的是，本實施例9之步驟(1)中的第一混合物也可以是以該製備例5的矽碳粉與該超高分子量聚乙烯混合，即該矽碳粉中的奈米矽含量可降至15 wt%，使得該濾材穩固性更佳。In particular, the first mixture in step (1) of Example 9 may also be the silicon carbide powder of the preparation example 5 mixed with the ultra-high molecular weight polyethylene, that is, the nano silicon in the silicon carbide powder The content can be reduced to 15 wt%, making the filter material more stable.

＜＜ 應用例Application examples ＞＞

淨水系統Water purification system

參閱圖8，為本發明的一個淨水系統，用以產製含有矽酸及氫氣的生物用水組成，其沿一水流方向依序包含一個第一濾芯裝置51、一個第二濾芯裝置52、一個第三濾芯裝置53、一個紫外光殺菌燈組54，及一個連通該該第一、第二與第三濾芯裝置51,52,53的濾水管路55。Referring to FIG. 8, it is a water purification system of the present invention for producing biological water containing silicic acid and hydrogen, which sequentially includes a first filter element device 51, a second filter element device 52, and a The third filter element device 53, an ultraviolet sterilization lamp group 54, and a water filter pipeline 55 connecting the first, second and third filter element devices 51, 52, 53.

該濾水管路55包括一個供水進入的入水口551及一個供水排出的出水口552。The water filtering pipeline 55 includes a water inlet 551 for entering water and a water outlet 552 for exiting water.

該第一濾芯裝置51設置於該入水口551與該第二濾芯裝置52間，且其內部裝設有第一濾材511。該第一濾材511是選自前述實施例1~9中的任何一種濾材。特別值得一提的是，該實施例6~9的濾材分別也可以在其中心穿孔中設置中空絲膜，且該第一濾芯裝置51的數量不限定為一個，本發明的淨水系統也可以包含兩個以上的該第一濾芯裝置51，如此可使得品質更佳更穩定。The first filter element device 51 is disposed between the water inlet 551 and the second filter element device 52, and a first filter material 511 is installed inside. The first filter material 511 is any filter material selected from the foregoing embodiments 1-9. It is particularly worth mentioning that the filter materials of Examples 6 to 9 can also be provided with hollow fiber membranes in their central perforations, and the number of the first filter element device 51 is not limited to one, and the water purification system of the present invention can also Including more than two first filter element devices 51, this can make the quality better and more stable.

該第二濾芯裝置52設置於該第一濾芯裝置51與該第三濾芯裝置53間，且其內部裝設有第二濾材521。該第二濾材521為現有能用於過濾水的材料。在本應用例中，該第二濾材521為添加有奈米銀的活性碳濾芯。The second filter element device 52 is disposed between the first filter element device 51 and the third filter element device 53, and a second filter material 521 is installed therein. The second filter material 521 is a material that can be used to filter water. In this application example, the second filter material 521 is an activated carbon filter added with nano silver.

該第三濾芯裝置53設置於該第二濾芯裝置52與該紫外光殺菌燈組54間，且其內部裝設有第三濾材531。該第三濾材531為現有能用於過濾水的材料。在本應用例中，該第三濾材531為中空絲膜。較佳地，該中空絲膜的孔徑大小為0.1 µm。補充說明的是，若該實施例6~9的濾材已在其中心穿孔中設置中空絲膜時，則可選擇性地省去作為該第三濾材531的中空絲膜。The third filter element device 53 is disposed between the second filter element device 52 and the ultraviolet sterilization lamp group 54, and a third filter material 531 is installed inside. The third filter material 531 is a material that can be used to filter water. In this application example, the third filter 531 is a hollow fiber membrane. Preferably, the pore size of the hollow fiber membrane is 0.1 µm. It is added that, if the filter materials of Examples 6 to 9 have been provided with hollow fiber membranes in the center perforations, the hollow fiber membranes as the third filter materials 531 can be selectively omitted.

該紫外光殺菌燈組54設置於該第三濾芯裝置53與該出水口552間，且是用於對該經第三濾芯裝置53過濾後所產生的矽氫水進行紫外光殺菌。The ultraviolet sterilization lamp group 54 is disposed between the third filter element device 53 and the water outlet 552, and is used to sterilize the silicon hydrogen water generated by the third filter element device 53 after being filtered.

需說明的是，本應用例的淨水系統還可以包含一設置於該第二濾芯裝置52與該第三濾芯裝置53間且可以定期排水或排氣的自動定期排水/氣管路56，或者在另一態樣中，本應用例的淨水系統還可以包含一個設置於該第一濾芯裝置51與該入水口551間且供量測水流量的流量計57。另一提的是，在其他實施例中，水可以自該第三濾芯裝置53的上端流入，並從下端流出，以利氣體更易排出。It should be noted that the water purification system of this application example may further include an automatic periodic drainage/air line 56 provided between the second filter element device 52 and the third filter element device 53 and capable of regular drainage or exhaust, or in In another aspect, the water purification system of this application example may further include a flow meter 57 disposed between the first filter element device 51 and the water inlet 551 and configured to measure water flow. It is also mentioned that in other embodiments, water may flow in from the upper end of the third filter element device 53 and flow out from the lower end, so that the gas is more easily discharged.

＜ 實施例 1 之濾材 的氫氣含量及矽酸含量分析 ＞ a. 分析方法： 將4.13 g實施例1所製得的濾材加入裝有1升純水的容器中後靜置，每隔一段時間，量測水的氧化還電位(mV)及矽酸含量(mg/L)，所得結果如圖5所示。其中，氧化還原電位是以電極(廠商:JAQUA；型號:EO221)與氧化還原電位分析主機(廠商:Horiba)量測，矽酸含量是以Merck比色法藥品量測。特別說明的是，水中的氫氣含量越高時，所測得的氧化還原電位就越低。b. 結果與討論： 由圖9可以發現，隨著時間增加，所測得的氧化還原電位會逐漸下降(即氫氣含量逐漸升高)，矽酸含量則會逐漸升高，說明以本發明製備方法所製得的濾材作為濾心時，不易發生濾心阻塞，同時也能穩定提升氫水中的氫氣含量及矽酸含量。 < Analysis of the hydrogen content and silicic acid content of the filter material of Example 1 > a. Analysis method: add 4.13 g of the filter material prepared in Example 1 to a container containing 1 liter of pure water and let it stand, every once in a while, Measure the redox potential (mV) and silicic acid content (mg/L) of water. The results are shown in Figure 5. Among them, the redox potential is measured with an electrode (manufacturer: JAQUA; model: EO221) and a redox potential analysis host (manufacturer: Horiba), and the silicic acid content is measured with Merck colorimetric method. In particular, the higher the hydrogen content in the water, the lower the measured redox potential. b. Results and discussion: It can be found from FIG. 9 that as the time increases, the measured redox potential will gradually decrease (that is, the hydrogen content gradually increases), and the silicic acid content will gradually increase, indicating that the preparation of the present invention When the filter material prepared by the method is used as a filter element, the filter element is less likely to be blocked, and at the same time, the hydrogen content and the silicic acid content in the hydrogen water can be steadily increased.

＜ 實施例 4 、 7 與 9 之濾材 的氧化還原電位及矽酸含量分析 ＞ a. 分析方法： 量測實施例4、7與9所製得的濾材應用於前述應用例之淨水設備時，所產生之過濾水的氧化還電位(mV)及矽酸含量(mg/L)，所得結果整理於下表2。其中，氧化還原電位是以電極(廠商:JAQUA；型號:EO221)與氧化還原電位分析主機(廠商:Horiba)量測，矽酸含量是以Merck比色法藥品量測。 表2

Figure 107118417-A0304-0003
b. 結果與討論： 由表2可以發現，實施例4、7與9所測得的氧化還原電位皆於-500 mV以下，表示水中的氫氣含量高，此外，由表2也可以發現，所測得水中的矽酸含量也很高。由前述結果說明以本發明製備方法所製得的濾材作為濾心時，不易發生濾心阻塞，同時也能穩定提升氫水中的氫氣含量及矽酸含量。 < Analysis of oxidation-reduction potential and silicic acid content of the filter materials of Examples 4 , 7 and 9 > a. Analysis method: When the filter materials prepared in Examples 4, 7 and 9 are applied to the water purification equipment of the aforementioned application example, The redox potential (mV) and silicic acid content (mg/L) of the filtered water produced are summarized in Table 2 below. Among them, the redox potential is measured with an electrode (manufacturer: JAQUA; model: EO221) and a redox potential analysis host (manufacturer: Horiba), and the silicic acid content is measured with Merck colorimetric method. Table 2
Figure 107118417-A0304-0003
 b. Results and discussion: It can be found from Table 2 that the redox potentials measured in Examples 4, 7 and 9 are all below -500 mV, indicating that the hydrogen content in the water is high. In addition, it can also be found from Table 2 that The measured silicic acid content in water is also very high. The foregoing results indicate that when the filter material prepared by the preparation method of the present invention is used as a filter element, clogging of the filter element is unlikely to occur, and at the same time, the hydrogen content and the silicic acid content in the hydrogen water can be increased steadily.

綜上所述，本發明製備方法由於步驟(1)中還混合了黏結材，所以在經壓合燒結步驟後所製得的濾材，其活性成分中的奈米矽能藉由該黏結材與該過濾材料黏結在一起而不易與該過濾材料分離，且奈米矽被固定於壓製成型的濾材中而可於固定的濾道中與水穩定反應，因而以本發明的濾材作為造水設備之濾心時，不易有濾心阻塞及所製得氫水的氫氣含量與矽酸含量下降的問題，故確實能達成本發明的目的。In summary, since the preparation method of the present invention also mixes the bonding material in step (1), the nano-silicon in the active ingredient of the filter material obtained after the compression and sintering step can be used by the bonding material and The filter material sticks together and is not easy to separate from the filter material, and the nano silicon is fixed in the press-shaped filter material and can react stably with water in the fixed filter channel. Therefore, the filter material of the present invention is used as a filter for water-making equipment In the heart, there is no problem of clogging of the filter and the decrease of the hydrogen content and the silicic acid content of the prepared hydrogen water, so it can indeed achieve the purpose of the invention.

惟以上所述者，僅為本發明的實施例而已，當不能以此限定本發明實施的範圍，凡是依本發明申請專利範圍及專利說明書內容所作的簡單的等效變化與修飾，皆仍屬本發明專利涵蓋的範圍內。However, the above are only examples of the present invention, and the scope of implementation of the present invention cannot be limited by this, any simple equivalent changes and modifications made according to the scope of the patent application of the present invention and the content of the patent specification are still classified as Within the scope of the invention patent.

1,4‧‧‧矽濾層 11‧‧‧活性成分 111‧‧‧過濾材料 112‧‧‧奈米矽 113‧‧‧活性粒子 114‧‧‧核心 12‧‧‧黏結材 13,36,41‧‧‧中心穿孔 2‧‧‧過濾層 31‧‧‧第一矽濾層 32‧‧‧第二矽濾層 33‧‧‧第三矽濾層 34‧‧‧第一連接層 35‧‧‧第二連接層 42‧‧‧第一混合層 43‧‧‧活性層 44‧‧‧第二混合層 51‧‧‧第一濾芯裝置 511‧‧‧第一濾材 52‧‧‧第二濾芯裝置 521‧‧‧第二濾材 53‧‧‧第三濾芯裝置 531‧‧‧第三濾材 54‧‧‧紫外光殺菌燈組 55‧‧‧濾水管路 551‧‧‧入水口 552‧‧‧出水口 56‧‧‧自動定期排水/氣管路 57‧‧‧流量計 1,4‧‧‧Silicon filter layer 11‧‧‧Active ingredients 111‧‧‧ Filter material 112‧‧‧Nanosilicon 113‧‧‧active particles 114‧‧‧Core 12‧‧‧bond material 13,36,41‧‧‧‧Perforated 2‧‧‧Filter layer 31‧‧‧The first silicon filter 32‧‧‧Second silicon filter layer 33‧‧‧The third silicon filter layer 34‧‧‧First connection layer 35‧‧‧Second connection layer 42‧‧‧First mixed layer 43‧‧‧Active layer 44‧‧‧second mixed layer 51‧‧‧First filter element device 511‧‧‧ First filter 52‧‧‧Second filter element device 521‧‧‧Second filter material 53‧‧‧The third filter element device 531‧‧‧The third filter material 54‧‧‧UV germicidal lamp set 55‧‧‧Water filter pipe 551‧‧‧ water inlet 552‧‧‧Water outlet 56‧‧‧Automatic regular drainage/air line 57‧‧‧Flowmeter

本發明的其他的特徵及功效，將於參照圖式的實施方式中清楚地呈現，其中： 　圖1A是一示意圖，說明製備例1所製得的矽碳粉； 圖1B是一顯微圖，說明製備例1所製得的矽碳粉； 　圖2是一示意圖，說明實施例1所製得的濾材； 　圖3是一示意圖，說明實施例3所製得的濾材； 　圖4是一示意圖，說明實施例5所製得的濾材； 圖5是一立體示意圖，說明實施例6與7所製得的濾材； 圖6是一立體示意圖，說明實施例8所製得的濾材； 圖7是一立體示意圖，說明實施例9所製得濾材的另一種態樣； 圖8 是一示意圖，說明應用例1的淨水系統；及 圖9是一曲線圖，說明實施例1所製得濾材置於水中時，水的氧化還原電位(mV)及矽酸含量(mg/L)隨著時間之變化情況。Other features and effects of the present invention will be clearly presented in the embodiment with reference to the drawings, in which: 　 FIG. 1A is a schematic diagram illustrating the silicon carbon powder prepared in Preparation Example 1; FIG. 1B is a micrograph, Description of the silicon carbon powder prepared in Preparation Example 1; 　 FIG. 2 is a schematic diagram illustrating the filter material prepared in Example 1; 　 FIG. 3 is a schematic diagram illustrating the filter material prepared in Example 3; 　 FIG. 4 is a schematic diagram, Explain the filter material prepared in Example 5; Fig. 5 is a schematic perspective view illustrating the filter material prepared in Examples 6 and 7; Fig. 6 is a schematic perspective view illustrating the filter material prepared in Example 8; Fig. 7 is a A three-dimensional schematic diagram illustrating another aspect of the filter material prepared in Example 9; FIG. 8 is a schematic diagram illustrating the water purification system of Application Example 1; and FIG. 9 is a graph illustrating that the filter material produced in Example 1 is placed in In water, the redox potential (mV) and silicic acid content (mg/L) of water change with time.

1‧‧‧矽濾層 1‧‧‧Silicon filter layer

11‧‧‧活性成分 11‧‧‧Active ingredients

111‧‧‧過濾材料 111‧‧‧ Filter material

112‧‧‧奈米矽 112‧‧‧Nanosilicon

12‧‧‧黏結材 12‧‧‧bond material

Claims (30)

一種濾材的製備方法，包含下列步驟： (1) 提供一個包含活性成分及黏結材的混合材，其中，該活性成分包含過濾材料及奈米矽，且該黏結材用於黏結過濾材料與奈米矽；及 (2) 燒結壓合該混合材，得到該濾材。A method for preparing a filter material includes the following steps: (1) Provide a mixed material including an active ingredient and a binding material, wherein the active ingredient includes a filtering material and nano silicon, and the binding material is used to bond the filtering material and the nano material Silicon; and (2) sintering and pressing the mixed material to obtain the filter material. 如請求項1所述的濾材的製備方法，其中，該活性成分包含多個活性粒子，每個活性粒子包含一個由過濾材料所組成的核心，及多個吸附於該核心上的奈米矽。The method for preparing a filter material according to claim 1, wherein the active ingredient includes a plurality of active particles, each active particle includes a core composed of a filter material, and a plurality of nano-silicon adsorbed on the core. 如請求項1所述的濾材的製備方法，其中，該步驟(1)的混合材是利用下列步驟(a)及(b)所得到： (a) 混合該活性成分及該黏結材，形成一個活性混合層；及 (b) 混合該過濾材料及該黏結材並部分或完全覆蓋該活性混合層，而於該活性混合層表面形成至少一個過濾混合層。The method for preparing a filter material according to claim 1, wherein the mixed material in step (1) is obtained by the following steps (a) and (b): (a) The active ingredient and the binding material are mixed to form a An active mixing layer; and (b) mixing the filter material and the binding material and covering the active mixing layer partially or completely, and forming at least one filter mixing layer on the surface of the active mixing layer. 如請求項1所述的濾材的製備方法，其中，該步驟(1)的混合材是利用下列步驟(I)及(II)所得到： (I) 混合該活性成分及該黏結材，形成多個活性混合層；及 (II) 使兩個相鄰的活性混合層間形成一個由該黏結材所組成的黏結層。The method for preparing the filter material according to claim 1, wherein the mixed material in step (1) is obtained by the following steps (I) and (II): (I) the active ingredient and the binding material are mixed to form Active mixing layers; and (II) forming a bonding layer composed of the bonding material between two adjacent active mixing layers. 如請求項2所述的濾材的製備方法，其中，該等活性粒子的過濾材料為第一過濾材料，該步驟(1)的混合材還包含第二過濾材料，且是利用下列步驟(A)及(B)所得到： (A) 混合該等活性粒子與該黏結材，得到第一混合物，以及混合該第二過濾材料與該黏結材，得到第二混合物； (B) 混合該第一混合物與該第二混合物，得到該混合材。The method for preparing a filter material according to claim 2, wherein the filter material of the active particles is the first filter material, the mixed material of step (1) further includes the second filter material, and the following step (A) is used And (B) obtained: (A) mixing the active particles and the binding material to obtain a first mixture, and mixing the second filter material and the binding material to obtain a second mixture; (B) mixing the first mixture With the second mixture, the mixed material is obtained. 如請求項1至4中任一項所述的濾材的製備方法，其中，該奈米矽的平均粒徑範圍為50~300 nm。The method for preparing a filter material according to any one of claims 1 to 4, wherein the average particle size of the nano-silicon is in the range of 50 to 300 nm. 如請求項1至4中任一項所述的濾材的製備方法，其中，該過濾材料的平均粒徑範圍為20~400 µm。The method for preparing a filter material according to any one of claims 1 to 4, wherein the average particle size of the filter material ranges from 20 to 400 µm. 如請求項1所述的濾材的製備方法，其中，在步驟(2)中，該混合材是於180~200℃下進行燒結。The method for preparing a filter material according to claim 1, wherein in step (2), the mixed material is sintered at 180 to 200°C. 如請求項3所述的濾材的製備方法，其中，該步驟(1)的過濾材料包含第一過濾材料及第二過濾材料，且該步驟(a)的活性成分包含第一過濾材料及奈米矽，以及該步驟(b)的過濾材料為第二過濾材料，該第一過濾材料與該第二過濾材料為相同或不相同的過濾材料。The method for preparing a filter material according to claim 3, wherein the filter material in step (1) includes a first filter material and a second filter material, and the active ingredient in step (a) includes the first filter material and nanometer The silicon and the filter material in step (b) are second filter materials, and the first filter material and the second filter material are the same or different filter materials. 如請求項1所述的濾材的製備方法，其中，該步驟(1)的活性成分包含至少一種過濾材料，該過濾材料係先與奈米矽混合之後，再一同與該黏結材及另一相同或相異的過濾材料混合。The method for preparing the filter material according to claim 1, wherein the active ingredient in step (1) includes at least one filter material, the filter material is first mixed with nano silicon, and then the same as the bonding material and the other Or mix different filter materials. 如請求項1所述的濾材的製備方法，其中，該奈米矽具有至少二種不同的粒徑。The method for preparing a filter material according to claim 1, wherein the nano-silicon has at least two different particle sizes. 如請求項11所述的濾材的製備方法，其中，任二種不同的粒徑差介於50 nm至150 nm間。The method for preparing a filter material according to claim 11, wherein any two different particle size differences are between 50 nm and 150 nm. 一種濾材，包含至少一個矽濾層，該矽濾層包括活性成分及黏結材，其中，該活性成分包含過濾材料及奈米矽，且該黏結材黏結該過濾材料與該奈米矽。A filter material includes at least one silicon filter layer, the silicon filter layer includes an active ingredient and a bonding material, wherein the active ingredient includes a filter material and nano silicon, and the bonding material bonds the filter material and the nano silicon. 如請求項13所述的濾材，其中，該過濾材料為多孔性材料。The filter material according to claim 13, wherein the filter material is a porous material. 如請求項13所述的濾材，其中，該黏結材為多孔性黏結材。The filter material according to claim 13, wherein the bonding material is a porous bonding material. 如請求項13所述的濾材，其中，該活性成分包含多個活性粒子，每個活性粒子包含一個由過濾材料所組成的核心，及多個吸附於該核心上的奈米矽。The filter material according to claim 13, wherein the active ingredient includes a plurality of active particles, each active particle includes a core composed of a filter material, and a plurality of nano-silicon adsorbed on the core. 如請求項13所述的濾材，還包含兩個分別覆蓋於該矽濾層的兩相反表面上的過濾層。The filter material according to claim 13, further comprising two filter layers respectively covering two opposite surfaces of the silicon filter layer. 如請求項13所述的濾材，還包含一個部份或完全覆蓋於該矽濾層表面上的過濾層。The filter material according to claim 13, further comprising a filter layer partially or completely covering the surface of the silicon filter layer. 如請求項17或18所述的濾材，其中，該過濾層包括過濾材料及黏結材。The filter material according to claim 17 or 18, wherein the filter layer includes a filter material and a binding material. 如請求項13所述的濾材，其中，該至少一個矽濾層為數個，且彼此相間隔，並該濾材還包含至少一個由黏結材所組成的連接層，每兩個相鄰的矽濾層會透過一個連接層黏接在一起。The filter material according to claim 13, wherein the at least one silicon filter layer is a plurality of and spaced apart from each other, and the filter material further comprises at least one connection layer composed of a bonding material, and each two adjacent silicon filter layers Will be glued together through a connection layer. 如請求項13所述的濾材，其中，該奈米矽具有至少二種不同的粒徑。The filter material according to claim 13, wherein the nanosilicon has at least two different particle sizes. 如請求項21所述的濾材，其中，任二種不同的粒徑差介於50 nm至150 nm間。The filter material according to claim 21, wherein any two different particle size differences are between 50 nm and 150 nm. 如請求項16所述的濾材，其中，以該等活性粒子的總重量為100 wt%計，該等活性粒子之奈米矽的重量範圍為10~40 wt%。The filter material according to claim 16, wherein the weight range of the nano-silicon of the active particles is 10 to 40 wt% based on the total weight of the active particles being 100 wt%. 如請求項23所述的濾材，其中，該等活性粒子之奈米矽的重量範圍為15~40 wt%。The filter material according to claim 23, wherein the weight range of the nanoparticles of the active particles is 15-40 wt%. 如請求項16所述的濾材，其中，該等活性粒子的過濾材料為第一過濾材料，且該濾材還包含第二過濾材料，該等活性粒子與該第二過濾材料經由該黏結材黏結在一起。The filter material according to claim 16, wherein the filter material of the active particles is a first filter material, and the filter material further includes a second filter material, and the active particles and the second filter material are bonded to each other via the bonding material together. 如請求項25所述的濾材，其中，該第一過濾材料與該第二過濾材料為相同的過濾材料。The filter material according to claim 25, wherein the first filter material and the second filter material are the same filter material. 如請求項16所述的濾材，其中，該等活性粒子的過濾材料為第一過濾材料，且該活性成分還包含第二過濾材料。The filter material according to claim 16, wherein the filter material of the active particles is a first filter material, and the active component further includes a second filter material. 如請求項27所述的濾材，其中，該第二過濾材料上吸附多個奈米矽，且吸附於該第二過濾材料上的奈米矽數量會少於該等活性粒子中的奈米矽數量。The filter material according to claim 27, wherein the second filter material adsorbs a plurality of nano-silicons, and the amount of nano-silicon adsorbed on the second filter material is less than the nano-silicon in the active particles Quantity. 如請求項27所述的濾材，其中，該第一過濾材料與該第二過濾材料為相同的過濾材料。The filter material according to claim 27, wherein the first filter material and the second filter material are the same filter material. 一種淨水系統，包含： 一個濾水管路，包括一個入水口與一個出水口；及 一個濾芯裝置，與該濾水管路相連通且設置在該入水口與該出水口間，並包括如請求項13所述的濾材。A water purification system, comprising: a water filtration pipeline, including a water inlet and a water outlet; and a filter element device, connected to the water filtration pipeline and disposed between the water inlet and the water outlet, and including items as requested 13 The filter material.
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CN102649592A (en) * 2012-05-02 2012-08-29 平湖美嘉保温容器工业有限公司 Filter medium for removing macrolide antibiotics from drinking water and preparation method thereof
JP2017104848A (en) * 2015-12-04 2017-06-15 小林　光 Silicon nanoparticles and/or aggregate thereof, hydrogen generating material for organism and production method for the same, and hydrogen water and production method and production apparatus for the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102649592A (en) * 2012-05-02 2012-08-29 平湖美嘉保温容器工业有限公司 Filter medium for removing macrolide antibiotics from drinking water and preparation method thereof
JP2017104848A (en) * 2015-12-04 2017-06-15 小林　光 Silicon nanoparticles and/or aggregate thereof, hydrogen generating material for organism and production method for the same, and hydrogen water and production method and production apparatus for the same

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