TWI627910B - Non-burning type heated smoking article - Google Patents
Non-burning type heated smoking article Download PDFInfo
- Publication number
- TWI627910B TWI627910B TW105116860A TW105116860A TWI627910B TW I627910 B TWI627910 B TW I627910B TW 105116860 A TW105116860 A TW 105116860A TW 105116860 A TW105116860 A TW 105116860A TW I627910 B TWI627910 B TW I627910B
- Authority
- TW
- Taiwan
- Prior art keywords
- taste
- tobacco
- mass
- smoking article
- acid
- Prior art date
Links
Landscapes
- Manufacture Of Tobacco Products (AREA)
Abstract
本發明之目的在於提供一種非燃燒型加熱吸煙物品用之煙草填充物，其係在加熱含有煙草絲之填充物的形態之非燃燒型加熱吸煙物品中可抑制香吸嚐味成分的蒸發量之降低，同時並可抑制「香吸嚐味阻礙感」。藉由於煙草填充物中添加第一酸解離常數為1.0以下之3或4價之酸的二氫鹽，可抑制香吸嚐味成分之蒸發量的降低，並可抑制「香吸嚐味阻礙感」。 An object of the present invention is to provide a tobacco filler for a non-combustion type heated smoking article, which is capable of suppressing evaporation of a flavor-absorbing component in a non-combustion type heated smoking article in a form of heating a filler containing tobacco silk. It can reduce the "scent of taste and taste". By adding a dihydrogen salt of a third or tetravalent acid having a first acid dissociation constant of 1.0 or less to the tobacco filler, the decrease in the evaporation amount of the flavoring component can be suppressed, and the "sweet taste and taste inhibition" can be suppressed. "."
Description
本發明係關於一種填充於非燃燒型加熱吸煙物品而使用之非燃燒型加熱吸煙物品用的煙草填充物。 The present invention relates to a tobacco filler for use in a non-combustion type heated smoking article for use in a non-combustion type heated smoking article.
近年，已開發出不使煙草燃燒，吸嚐香吸嚐味之非燃燒型加熱吸煙物品取代香菸，代表性者已知有於罐狀容器內部填充香吸嚐味成分及產生氣溶膠之成分而使用之形態者、或於前端具備熱源者等。 In recent years, non-combustion-type heated smoking articles that do not burn tobacco and taste taste have been developed to replace cigarettes. Representatives are known to fill the interior of a can-shaped container with a flavor-absorbing component and an aerosol-generating component. The form to be used, or the heat source at the front end.
又，亦已報告出在如此之非燃燒型加熱吸煙物品中，於填充物中添加酸之技術或添加內包酸之膠囊的技術(參照專利文獻1至5。)。 In addition, a technique of adding an acid to a filler or a capsule containing an acid-containing capsule in such a non-combustion type heated smoking article has been reported (see Patent Documents 1 to 5).
[專利文獻1]國際公開第2014/190079號 [Patent Document 1] International Publication No. 2014/190079
[專利文獻2]美國專利申請案公開第2015/0020820號說明書 [Patent Document 2] US Patent Application Publication No. 2015/0020820
[專利文獻3]美國專利申請案公開第2014/0345631號 說明書 [Patent Document 3] U.S. Patent Application Publication No. 2014/0345631 Instruction manual
[專利文獻4]國際公開第2015/101651號 [Patent Document 4] International Publication No. 2015/101651
[專利文獻5]國際公開第2015/000974號 [Patent Document 5] International Publication No. 2015/000974
在使用非燃燒型加熱吸煙物品之吸煙時，香吸嚐味成分之蒸發量與香菸比較，有時為不充分，或感覺到所謂之「香吸嚐味阻礙感」。 When smoking is carried out using a non-combustion type heated smoking article, the evaporation amount of the fragrant taste taste component may be insufficient compared with the cigarette, or the so-called "sweet taste taste barrier" may be felt.
本發明之目的在於提供一種非燃燒型加熱吸煙物品，特別是非燃燒型加熱吸煙物品用之煙草填充物，其係在加熱含有煙草絲之填充物的形態中可抑制香吸嚐味成分的蒸發量之降低，同時並抑制「香吸嚐味阻礙感」。 It is an object of the present invention to provide a non-combustion type heated smoking article, particularly a tobacco filler for a non-combustion type heated smoking article, which is capable of suppressing evaporation of a flavor-absorbing component in a form of heating a filler containing tobacco silk. The reduction is at the same time, and the "sweet taste is hindered".
本發明人等係為解決前述課題，累積精心研究之結果，發現藉由於煙草填充物中添加滿足特定條件之鹽，可抑制香吸嚐味成分之蒸發量的降低，並可抑制「香吸嚐味阻礙感」，終完成本發明。 In order to solve the above problems, the present inventors have accumulated intensive studies and found that by adding a salt satisfying specific conditions to the tobacco filler, it is possible to suppress a decrease in the evaporation amount of the flavor-absorbing component, and to suppress the "fragrance taste". The taste is hindered, and the present invention is finally completed.
亦即，本發明係如以下。 That is, the present invention is as follows.
<1>一種煙草填充物，係含有煙草絲、及產生氣溶膠之液體的非燃燒型加熱吸煙物品用之煙草填充物，其中，包含第一酸解離常數為1.0以下之3或4價的酸之二氫鹽。 <1> A tobacco filler comprising a tobacco filler for a non-combustion type heated smoking article containing tobacco silk and an aerosol-generating liquid, wherein the acid having a first acid dissociation constant of 1.0 or less is 1.0 or less Dihydrogen salt.
<2>如申請專利範圍第1項所述之煙草填充物，其中，前述二氫鹽為焦磷酸之二氫鹽。 <2> The tobacco filler according to claim 1, wherein the dihydrogen salt is a dihydrogen salt of pyrophosphoric acid.
<3>如<1>或<2>所述之煙草填充物，其中，前述二 氫鹽之含量為全部煙草填充物之0.1質量%以上10質量%以下。 <3> The tobacco filler according to <1> or <2>, wherein the aforementioned two The content of the hydrogen salt is 0.1% by mass or more and 10% by mass or less of the total tobacco filler.
<4>如<1>至<3>中任一項所述之煙草填充物，其中，產生前述氣溶膠之液體包含丙二醇。 The tobacco filler according to any one of <1> to <3> wherein the liquid in which the aerosol is produced contains propylene glycol.
<5>如<1>至<4>中任一項所述之煙草填充物，其中，水之含量為全部煙草填充物之5.0質量%以上30質量%以下。 The tobacco filler according to any one of <1> to <4> wherein the content of water is 5.0% by mass or more and 30% by mass or less of the total tobacco filler.
若依據本發明，在加熱含有煙草絲之填充物的形態之非燃燒型加熱吸煙物品中，可抑制香吸嚐味成分的蒸發量之降低，同時並可抑制「香吸嚐味阻礙感」。 According to the present invention, in the non-combustion type heated smoking article in which the filler containing the tobacco yarn is heated, the decrease in the evaporation amount of the flavor-absorbing component can be suppressed, and the "smell-sucking taste-suppressing feeling" can be suppressed.
10‧‧‧非燃燒型加熱吸煙物品 10‧‧‧Non-burning heated smoking articles
101‧‧‧電池 101‧‧‧Battery
102‧‧‧填充物 102‧‧‧Filling
103‧‧‧罐 103‧‧‧ cans
104‧‧‧加熱器 104‧‧‧heater
105‧‧‧吸嘴 105‧‧ ‧ nozzle
第1圖係表示非燃燒型加熱吸煙物品之例的剖面圖。 Fig. 1 is a cross-sectional view showing an example of a non-combustion type heated smoking article.
第2圖係表示構成鹽之共軛酸的第一酸解離常數及香吸嚐味成分之蒸發量的關係之圖表。 Fig. 2 is a graph showing the relationship between the first acid dissociation constant of the conjugate acid constituting the salt and the evaporation amount of the savory taste component.
第3圖係表示構成鹽之共軛酸的第一酸解離常數及香吸嚐味阻礙感的關係之圖表。 Fig. 3 is a graph showing the relationship between the first acid dissociation constant of the conjugate acid constituting the salt and the feeling of odor absorption.
第4圖係表示焦磷酸二氫二鈉之含量及香吸嚐味阻礙感之關係的圖表。 Fig. 4 is a graph showing the relationship between the content of disodium dihydrogen pyrophosphate and the feeling of odor absorption.
當說明本發明時，雖舉出具體例而說明，但只要不超出本發明之旨意，不限定於以下之內容，而可適宜變更而實施。 In the description of the present invention, a specific example will be described. However, the present invention is not limited to the following, and may be modified as appropriate without departing from the scope of the invention.
本發明之一態樣的非燃燒型加熱吸煙物品用之煙草填充物(以下，有時簡稱為「本發明之煙草填充物」。)係包含煙草絲及產生氣溶膠之液體的煙草填充物，其中，含有第一酸解離常數為1.0以下之3或4價的酸之二氫鹽。 A tobacco filler for a non-combustion type heated smoking article (hereinafter sometimes simply referred to as "tobacco filler of the present invention") is a tobacco filler containing tobacco silk and an aerosol-generating liquid. Among them, a dihydrogen salt containing an acid having a first acid dissociation constant of 1.0 or less and a valence of 1.0 or less.
本發明人等係對於非燃燒型加熱吸煙物品、尤其加熱含有煙草絲之填充物的形態之吸煙物品，闡明各種之問題點。 The inventors of the present invention have clarified various problems with respect to a non-combustion type heated smoking article, in particular, a smoking article in a form in which a filler containing tobacco silk is heated.
例如若於含有煙草絲之填充物(通常，含有產生氣溶膠之液體。)中添加酸，有時香吸嚐味成分之蒸發量會降低。認為此係所添加之與酸產生氣溶膠之液體滲透至煙草絲之內部，與煙草絲內之香吸嚐味成分形成鹽之故。在加熱溫度高之非燃燒型加熱吸煙物品中，係藉由加熱而將鹽解離，或藉由高溫度而抑制香吸嚐味成分之蒸發量之降低，但認為在加熱溫度低之非燃燒型加熱吸煙物品中其影響很顯著。又，將酸內包於膠囊而添加者，就製造成本之觀點為不佳。 For example, when an acid is added to a filler containing tobacco silk (generally, a liquid containing an aerosol), the evaporation amount of the flavoring component may be lowered. It is considered that the liquid added with the acid-generating aerosol in this system penetrates into the inside of the tobacco yarn to form a salt with the flavor-absorbing component in the tobacco yarn. In a non-combustion type heated smoking article having a high heating temperature, the salt is dissociated by heating, or the evaporation amount of the flavoring component is suppressed by a high temperature, but it is considered to be a non-combustion type having a low heating temperature. The effect of heating smoking articles is significant. Further, when the acid is contained in a capsule and added, the viewpoint of the production cost is not preferable.
其他，使用非燃燒型加熱吸煙物品之吸煙中，有時受到與煙草相異之刺激，或感覺產生「嗆」等之生理性自發動作的「香吸嚐味阻礙感」。認為此係於填充物內含有阻礙香吸嚐味之成分之故，此成分與如丙二醇之溶劑一起揮發，感覺「香吸嚐味阻礙感」。 Others, in the case of smoking using non-combustion-type heated smoking articles, may be stimulated by tobacco, or may feel a "sweet taste and taste" caused by physiological spontaneous movements such as "呛". It is considered that this component contains a component which hinders the taste of the scent, and this component volatilizes together with a solvent such as propylene glycol, and it feels "sweet taste and taste sensation".
本發明人等發現，不直接添加酸，而添加於填充物所 含之水分等進行解離而形成酸之鹽，則酸不與煙草絲中之香吸嚐味成分形成鹽，發揮其效果者。又，為了要避免所解離之酸及香吸嚐味成分形成鹽，當酸鹽之水解時，必須引起酸之熱蒸發。又，明顯可知以藉由解離而形成之酸成為強酸，進一步鹽藉由強酸之共軛鹼而構成者為較佳。亦即，發現藉由將「第一酸解離常數為1.0以下之3或4價之酸的二氫鹽」添加於煙草填充物，可抑制香吸嚐味成分之蒸發量的降低，同時並抑制「香吸嚐味阻礙感」。 The present inventors have found that it is added to the filler without directly adding an acid. When the water or the like is dissociated to form an acid salt, the acid does not form a salt with the flavor-absorbing component in the tobacco yarn, and the effect is exhibited. Further, in order to prevent the dissociated acid and the fragrant taste component from forming a salt, when the acid salt is hydrolyzed, it is necessary to cause the heat of the acid to evaporate. Further, it is apparent that the acid formed by dissociation is a strong acid, and further the salt is preferably constituted by a conjugate base of a strong acid. In other words, it has been found that by adding a "dihydrogen salt of an acid having a first acid dissociation constant of 1.0 or less to a value of 1.0 or less" to the tobacco filler, the decrease in the evaporation amount of the flavoring component can be suppressed while suppressing "Sweet taste tastes bad."
又，所謂「第一酸解離常數」係意指在常溫(25℃)中對水之酸解離常數。 Further, the "first acid dissociation constant" means an acid dissociation constant for water at normal temperature (25 ° C).
以下，詳細說明有關「非燃燒型加熱吸煙物品」、「煙草絲」、「產生氣溶膠之液體」、「第一酸解離常數為1.0以下之3或4價之酸的二氫鹽」等。 Hereinafter, the "non-combustion type heated smoking article", "tobacco silk", "liquid generating aerosol", and "dihydrogen salt of an acid having a first acid dissociation constant of 1.0 or less of 1.0 or less" will be described in detail.
本發明之煙草填充物係包含煙草絲及產生氣溶膠之液體的非燃燒型加熱吸煙物品用之煙草填充物，但填充有本發明之煙草填充物的非燃燒型加熱吸煙物品之具體構造等係無特別限定，而可適宜採用公知者。以下，舉出具體例而進行說明。 The tobacco filler of the present invention is a tobacco filler for a non-combustion type heated smoking article comprising tobacco silk and an aerosol-generating liquid, but the specific structure of the non-combustion type heated smoking article filled with the tobacco filler of the present invention is It is not particularly limited, and a known one can be suitably used. Hereinafter, a specific example will be described.
非燃燒型加熱吸煙物品係可舉出具有第1圖所示之非燃燒型加熱吸煙物品10之構造者。第1圖係將圓筒形之非燃燒型加熱吸煙物品裁切其長方向時之剖面圖，具有電池101及置入填充物102之罐103以及加熱器104與吸嘴105之構造。將本發明之煙草填充物填充於罐103，藉加熱產生氣溶膠。 The non-combustion type heated smoking article is a structure having the non-combustion type heated smoking article 10 shown in Fig. 1 . Fig. 1 is a cross-sectional view showing a cylindrical non-combustion type heated smoking article cut in a long direction, and has a structure of a battery 101 and a can 103 in which a filler 102 is placed, and a heater 104 and a suction nozzle 105. The tobacco filler of the present invention is filled in a can 103 to generate an aerosol by heating.
非燃燒型加熱吸煙物品中之煙草填充物之加熱溫度通常為22℃以上，較佳係100℃以上，更佳係150℃以上，通常為350℃以下，較佳係300℃以下，更佳係250℃以下。煙草填充物之加熱溫度為上述範圍內之非燃燒型加熱吸煙物品時，易產生「香吸嚐味阻礙感」之問題，可更有效地活用本發明之煙草填充物之特性。 The heating temperature of the tobacco filler in the non-combustion type heated smoking article is usually 22 ° C or higher, preferably 100 ° C or higher, more preferably 150 ° C or higher, usually 350 ° C or lower, preferably 300 ° C or lower, and more preferably Below 250 °C. When the heating temperature of the tobacco filler is a non-combustion type heated smoking article within the above range, the problem of "sweet taste and taste inhibition" is apt to occur, and the characteristics of the tobacco filler of the present invention can be more effectively utilized.
煙草絲之種類係可舉例如黃色種、白勒(Burley)種、在來種、再生煙草等，使用之部位係可舉例如葉(緩和絲)、莖、葉脈(中骨絲)、根、花等。 Examples of the type of the tobacco yarn include a yellow species, a Burley species, a seed, a reconstituted tobacco, and the like, and the parts to be used include, for example, leaves (tempered silk), stems, veins (medium bone), roots, and Flowers, etc.
煙草絲之尺寸係無限定，但以使用投影剖面積之測定方法(例如使用Camsizer(Retsch公司)等之方法)，相當球之徑通常為1.5mm以下，較佳係0.5mm以下，通常為0.01mm以上。 The size of the tobacco yarn is not limited, but the measurement method using the projected sectional area (for example, using a method such as Camsizer (Retsch)), the diameter of the equivalent sphere is usually 1.5 mm or less, preferably 0.5 mm or less, usually 0.01. Mm or more.
本發明之煙草填充物之煙草絲之含量通常為20質量%以上，較佳係30質量%以上，更佳係40質量%以上，通常為80質量%以下，較佳係70質量%以下，更佳係60質量%以下。若為上述範圍內，容易更抑制香吸嚐味成分之蒸發量之降低，以及可更有效地抑制「香吸嚐味阻礙感」。 The content of the tobacco yarn of the tobacco filler of the present invention is usually 20% by mass or more, preferably 30% by mass or more, more preferably 40% by mass or more, usually 80% by mass or less, preferably 70% by mass or less, more preferably The best quality is 60% by mass or less. When it is in the above range, it is easy to suppress the decrease in the evaporation amount of the flavoring component, and it is possible to more effectively suppress the "sweet taste and taste inhibition".
產生氣溶膠之液體係可舉例如甘油、丙二醇、三乙二醇、四乙二醇等多元醇；硬脂酸酸甲酯、十二碳二酸二甲酯、十四碳二酸二甲酯等之羧酸脂肪族酯。又，液體係不限定於1種類，亦可組合2種類以上而使用。 Examples of the liquid system for generating an aerosol include polyhydric alcohols such as glycerin, propylene glycol, triethylene glycol, and tetraethylene glycol; methyl stearate, dimethyl dodecanoate, and dimethyl tetradecanoate. A carboxylic acid aliphatic ester. Further, the liquid system is not limited to one type, and may be used in combination of two or more types.
產生氣溶膠之液體係以含有丙二醇為較佳。丙二醇係 安全性高之溶液，可使用於食品、醫療品，因沸點低，具有易氣化之性質，故可容易生成可見煙。另一方面，丙二醇係因蒸氣壓高，故具有在口腔內容易揮發之性質。因此，認為阻礙氣溶膠中所含之香吸嚐味的成分易揮發之氛圍，結果易產生「香吸嚐味阻礙感」之問題。因此，可更有效地活用本發明之煙草填充物之特性。 The liquid system for generating an aerosol preferably contains propylene glycol. Propylene glycol The highly safe solution can be used for foods and medical products, and has a low boiling point and is easy to vaporize, so that visible smoke can be easily generated. On the other hand, since propylene glycol has a high vapor pressure, it has a property of being easily volatilized in the oral cavity. Therefore, it is considered that the atmosphere which hinders the taste of the fragrance contained in the aerosol is easily volatilized, and as a result, it is easy to cause a problem of "sweet taste and taste inhibition". Therefore, the characteristics of the tobacco filler of the present invention can be utilized more effectively.
本發明之產生煙草填充物之氣溶膠的液體之含量通常為20質量%以上，較佳係30質量%以上，更佳係40質量%以上，通常為80質量%以下，較佳係70質量%以下，更佳係60質量%以下。上述範圍內時，可更容易地抑制香吸嚐味成分之蒸發量之降低，且可更有效地抑制「香吸嚐味阻礙感」。 The content of the liquid of the aerosol for producing a tobacco filler of the present invention is usually 20% by mass or more, preferably 30% by mass or more, more preferably 40% by mass or more, usually 80% by mass or less, and preferably 70% by mass or less. Hereinafter, it is more preferably 60% by mass or less. When it is in the above range, the decrease in the evaporation amount of the flavoring component can be more easily suppressed, and the "sweet taste and taste inhibition" can be more effectively suppressed.
本發明之煙草填充物其特徵係含有第一酸解離常數為1.0以下之3或4價之酸的二氫鹽(以下，有時簡稱為「二氫鹽」。)，但若為滿足條件者，具體之二氫鹽無特別限定，可依目的需要而適宜採用公知者。以下，舉出具體例而說明。又，所謂「二氫鹽」係指含有2個氫離子(H+)作為陽離子之鹽，其他之陽離子無特別限定。 The tobacco filler of the present invention is characterized in that it contains a dihydrogen salt (hereinafter sometimes abbreviated as "dihydrogen salt") having an acid having a first acid dissociation constant of 1.0 or less and a valence of 1.0 or less, but if it satisfies the condition, The specific dihydrogen salt is not particularly limited, and a known one can be suitably used according to the purpose. Hereinafter, a specific example will be described. In addition, the "dihydrogen salt" means a salt containing two hydrogen ions (H + ) as a cation, and other cations are not particularly limited.
構成二氫鹽之共軛酸的第一酸解離常數較佳為0.8以下，通常為-1.0以上。 The first acid dissociation constant of the conjugate acid constituting the dihydrogen salt is preferably 0.8 or less, and usually is -1.0 or more.
構成二氫鹽之共軛酸的價數為3或4價，但較佳為3。 The valence of the conjugate acid constituting the dihydrogen salt is 3 or 4, but is preferably 3.
構成二氫鹽之氫離子以外之陽離子可舉例如鋰離子、鈉離子、鉀離子等鹼金屬離子；鎂離子、鈣離子等鹼土族金屬離子；銨離子、四甲基銨等之銨離子。 The cations other than the hydrogen ion constituting the dihydrogen salt may, for example, be an alkali metal ion such as a lithium ion, a sodium ion or a potassium ion; an alkaline earth metal ion such as a magnesium ion or a calcium ion; or an ammonium ion such as an ammonium ion or a tetramethylammonium.
構成二氫鹽之共軛酸可舉例如焦磷酸鹽等。 The conjugate acid constituting the dihydrogen salt may, for example, be pyrophosphate or the like.
如上述者，更容易抑制香吸嚐味成分之蒸發量的降低，同時並可更有效地抑制「香吸嚐味阻礙感」。 As described above, it is easier to suppress the decrease in the evaporation amount of the flavor-absorbing component, and at the same time, it is possible to more effectively suppress the "sweet taste and taste barrier".
構成二氫鹽之共軛酸的分子量通常為90以上，較佳為120以上，更佳為170以上，通常為300以下，較佳為250以下，更佳為200以下。上述範圍內時，所解離之二氫鹽的強酸可抑制適度之蒸發量的降低，可貯存於氣溶膠中。強酸係作為酸之機能較高，故即使少量，若可存在於氣溶膠中，即可發揮效果。 The molecular weight of the conjugate acid constituting the dihydrogen salt is usually 90 or more, preferably 120 or more, more preferably 170 or more, usually 300 or less, preferably 250 or less, and more preferably 200 or less. Within the above range, the strong acid of the dissociated dihydrogen salt can suppress a moderate decrease in the amount of evaporation and can be stored in the aerosol. The strong acid system has a high function as an acid, so even if it is present in a small amount, it can exert an effect.
二氫鹽可舉例如焦磷酸二氫二鈉、焦磷酸二氫二鉀等。 The dihydrogen salt may, for example, be disodium dihydrogen pyrophosphate or dipotassium dihydrogen pyrophosphate.
若為上述者，可更容易地抑制香吸嚐味成分之蒸發量之降低，以及可更有效地抑制「香吸嚐味阻礙感」。 According to the above, it is possible to more easily suppress the decrease in the evaporation amount of the flavoring component and to more effectively suppress the "sweet taste and taste inhibition".
本發明之煙草填充物之二氫鹽之含量通常為0.1質量%以上，較佳係0.25質量%以上，更佳係1質量%以上，通常為10質量%以下，較佳為5質量%以下。上述範圍內時，可更容易地抑制香吸嚐味成分之蒸發量之降低，以及可更有效地抑制「香吸嚐味阻礙感」。 The content of the dihydrogen salt of the tobacco filler of the present invention is usually 0.1% by mass or more, preferably 0.25 mass% or more, more preferably 1% by mass or more, usually 10% by mass or less, and preferably 5% by mass or less. When it is in the above range, it is possible to more easily suppress the decrease in the evaporation amount of the flavoring component and to more effectively suppress the "sweet taste and taste inhibition".
本發明之煙草填充物係包含煙草絲及產生氣溶膠之液體者，但通常於煙草絲係含有水分，可謂本發明之煙草填充物係亦含有水者。 The tobacco filler of the present invention contains tobacco silk and an aerosol-generating liquid, but usually contains water in the tobacco silk system, and it can be said that the tobacco filler of the present invention also contains water.
本發明之煙草填充物之水的含量通常係全部煙草填充物之5質量%以上，較佳係7.5質量%以上，更佳係10質量%以上，通常為30質量%以下，較佳係25質量%以下， 更佳係20質量%以下。上述範圍內時，更容易地抑制香吸嚐味成分之蒸發量之降低，以及可更有效地抑制「香吸嚐味阻礙感」。 The content of water in the tobacco filler of the present invention is usually 5% by mass or more, preferably 7.5 mass% or more, more preferably 10 mass% or more, usually 30 mass% or less, and preferably 25 mass% of the total tobacco filler. %the following, More preferably, it is 20% by mass or less. When it is in the above range, it is easier to suppress the decrease in the evaporation amount of the flavoring component and to more effectively suppress the "sweet taste and taste inhibition".
以下，舉出實施例而更具體說明本發明，但只要不超出本發明之旨意，可適宜變更。 Hereinafter, the present invention will be specifically described by way of examples, but it should be modified as appropriate without departing from the scope of the invention.
相對於黃色絲(日本產)100mg，添加丙二醇及甘醇以1：1(重量比)混合而成之液體100mg，表1所示之酸以組成物全部之質量換算為添加5質量%，製作試樣。又，煙草絲係預先以家庭用混和機粉碎之後，以篩網(AS200，Retch公司製)條件：amplitude-1.5mm/“g”中振動2分鐘，使用篩網目徑0.5mm以下者。 100 mg of a liquid obtained by mixing propylene glycol and glycol in a ratio of 1:1 (weight ratio) to 100 mg of yellow silk (manufactured in Japan), and the acid shown in Table 1 was added in an amount of 5% by mass based on the total mass of the composition. Sample. In addition, the tobacco silk system was pulverized in advance by a household mixer, and then vibrated for 2 minutes in a mesh (AS200, manufactured by Retch) conditions: amplitude-1.5 mm/"g", and a mesh size of 0.5 mm or less was used.
所製作之試樣係以貼附於由日本煙草產業股份公司發售之商品名「Ploom(註冊商標)」專用之pod上之方式設置，以2日以上22℃、濕度60%之條件藏置。又，使用Ploom時之煙草絲的加熱溫度(安定作働時)係藉由使用熱電偶之前的計測，確認為160℃至170℃左右。又，煙草絲因含有13質量%之水分，故認為所製作之試樣係含有約6.0質量%左右之水分者。 The sample to be produced is placed on a pod dedicated to the trade name "Ploom (registered trademark)" sold by Japan Tobacco Industry Co., Ltd., and is stored at a temperature of 2 days or more and 22 degrees C and a humidity of 60%. Further, the heating temperature of the tobacco yarn when the Ploom was used (when it was stabilized) was confirmed to be about 160 ° C to 170 ° C by measurement before the use of the thermocouple. In addition, since the tobacco yarn contains 13% by mass of water, it is considered that the sample to be produced contains about 6.0% by mass of water.
吸煙試驗係使用吸煙機(Borgwaldt，RM-26)，並安裝有Ploom製作之墊(pod)，在規定之吸煙條件(55ml/2S、吸煙間 隔30s)之下，測定初期10次吸吐(puff)之香吸嚐味成分的蒸發量。又，本實驗係選擇香吸嚐味成分容易測定之尼古丁作為成分指標。煙捕集係使用Cambridge Filter pod，將被濾嘴捕集之煙以甲醇溶劑振動萃取40分鐘，以GC-FID定量出尼古丁。 The smoking test used a smoking machine (Borgwaldt, RM-26) and was fitted with a pod made by Ploom under the prescribed smoking conditions (55ml/2S, smoking room). Below 30 s), the amount of evaporation of the taste component of the initial 10 puffs was measured. In addition, this experiment selects nicotine which is easy to measure as a component index. The smoke trapping system uses a Cambridge Filter pod to extract the smoke trapped by the filter with a methanol solvent for 40 minutes, and quantify the nicotine by GC-FID.
吸煙試驗之官能評價係以4名實施，就「香吸嚐味阻礙感」及以1至7之7階段評價來實施。本實施例之結果中，香吸嚐味阻礙感之評價值為2以下時，就評價者而言，為可充分識別差異之值，作為效果優異之區域。評價中，7之值係顯示人吸菸之後，感覺阻礙，對吸煙造成影響之程度，評估係以吸菸中所感受到之感覺記載的值。 The sensory evaluation of the smoking test was carried out in four places, and it was carried out in the "sweet taste taste barrier" and the 7-stage evaluation of 1 to 7. In the result of the present example, when the evaluation value of the scent taste sensation is 2 or less, the evaluator can sufficiently recognize the value of the difference and is an area excellent in the effect. In the evaluation, the value of 7 indicates the degree to which the person feels obstructed after smoking, and the degree of influence on smoking is evaluated as the value recorded by the feeling felt in smoking.
茲將鹽之物性值、香吸嚐味成分之蒸發量、官能評價之結果分別表示於表1中。 The physical properties of the salt, the evaporation amount of the flavoring component, and the results of the sensory evaluation are shown in Table 1, respectively.
將表示構成鹽之共軛酸的第一酸解離常數與香吸嚐味成分之蒸發量的關係之圖表表示於第2圖。從第2圖中，可知添加二氫鹽時與不添加時，香吸嚐味成分量為同程度。一氫鹽或不含氫之鹽可確認香吸嚐味成分量會變動。從本結果，可知以添加二氫鹽，香吸嚐味成分之蒸發量成為一定。 A graph showing the relationship between the first acid dissociation constant of the conjugate acid constituting the salt and the evaporation amount of the savory taste component is shown in Fig. 2 . From Fig. 2, it is understood that the amount of the flavoring taste component is the same when the dihydrogen salt is added or not. A monohydrogen salt or a salt containing no hydrogen can confirm that the amount of the flavoring taste component changes. From the results, it was found that the amount of evaporation of the fragrant taste component was constant by the addition of the dihydrogen salt.
其次，將表示構成鹽之共軛酸的第一酸解離常數及香吸嚐味阻礙感之關係的圖表表示於第3圖。確認出構成鹽之共軛酸的第一酸解離常數愈低，香吸嚐味阻礙感愈降低。本實施例所使用之鹽中，焦磷酸鹽二氫二鈉之效果最高，推測此理由係因構成鹽之共軛酸的酸之強度所造成。 Next, a graph showing the relationship between the first acid dissociation constant of the conjugate acid constituting the salt and the odor absorption feeling is shown in Fig. 3. It was confirmed that the lower the first acid dissociation constant of the conjugate acid constituting the salt, the lower the scent absorption resistance. Among the salts used in the examples, the effect of pyrophosphate dihydrogen disodium was the highest, and the reason was presumed to be caused by the strength of the acid constituting the conjugate acid of the salt.
從以上之結果可知，添加構成鹽之共軛酸的第一酸解離常數為1.0以下之二氫鹽，維持香吸嚐味成分之蒸發量後，可解決香吸嚐味阻礙感。 From the above results, it is understood that the dihydrogen salt having a first acid dissociation constant of 1.0 or less is added to the conjugate acid constituting the salt, and the evaporation amount of the savory taste component is maintained, whereby the odor absorption feeling can be solved.
除了將先前之實施例之焦磷酸鹽二氫二鈉的含量從5質量%變更為3質量%、1質量%以外，其餘係以與先前之實施例同樣之方法實施。又，在本評價中，香吸嚐味成分量係相同，故僅著眼於對香吸嚐味阻礙感之效果。 The same procedure as in the previous examples was carried out except that the content of pyrophosphate disodium disodium in the previous examples was changed from 5% by mass to 3% by mass and 1% by mass. Moreover, in this evaluation, since the amount of the flavor taste component is the same, only the effect of the taste of the flavor is suppressed.
茲將表示焦磷酸鹽二氫二鈉之含量及香吸嚐味阻礙感之關係的圖表表示於第4圖中。從第4圖中，可確認將含量降低至1質量%時，酸之效果亦高。推想強酸係作為酸之效果高，即使為少量，若存在氣溶膠中，亦可發揮效果。認為構成鹽之共軛酸愈為強酸愈佳。 A graph showing the relationship between the content of pyrophosphate dihydrogen disodium and the feeling of odor absorption is shown in Fig. 4. From Fig. 4, it was confirmed that the effect of the acid was also high when the content was lowered to 1% by mass. It is assumed that the strong acid system has a high effect as an acid, and even if it is in a small amount, it can exert an effect in the presence of an aerosol. It is considered that the stronger the conjugate acid constituting the salt, the better.
本發明之煙草填充物係可利用於填充在非燃燒型加熱吸煙物品而吸煙者。 The tobacco filler of the present invention can be utilized for filling a non-combustible heated smoking article with a smoker.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105116860A TWI627910B (en) | 2016-05-27 | 2016-05-27 | Non-burning type heated smoking article |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105116860A TWI627910B (en) | 2016-05-27 | 2016-05-27 | Non-burning type heated smoking article |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201740825A TW201740825A (en) | 2017-12-01 |
| TWI627910B true TWI627910B (en) | 2018-07-01 |
Family
ID=61229989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105116860A TWI627910B (en) | 2016-05-27 | 2016-05-27 | Non-burning type heated smoking article |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TWI627910B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120055494A1 (en) * | 2010-09-07 | 2012-03-08 | Rj Reynolds Tobacco Company | Smokeless Tobacco Product Comprising Effervescent Composition |
| CN102754913A (en) * | 2012-07-31 | 2012-10-31 | 龙功运 | Blended additive for atomizing smoke after heating tobacco, using method thereof and tobacco composite thereof |
| US20130152953A1 (en) * | 2011-12-14 | 2013-06-20 | R. J. Reynolds Tobacco Company | Smokeless tobacco product comprising effervescent composition |
| CN103564658A (en) * | 2013-11-22 | 2014-02-12 | 上海烟草集团有限责任公司 | Electric heating smoking device and tobacco heating structure thereof |
| CN104770885A (en) * | 2015-02-13 | 2015-07-15 | 深圳市合元科技有限公司 | Smoke suction device |
-
2016
- 2016-05-27 TW TW105116860A patent/TWI627910B/en active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120055494A1 (en) * | 2010-09-07 | 2012-03-08 | Rj Reynolds Tobacco Company | Smokeless Tobacco Product Comprising Effervescent Composition |
| US20130152953A1 (en) * | 2011-12-14 | 2013-06-20 | R. J. Reynolds Tobacco Company | Smokeless tobacco product comprising effervescent composition |
| CN102754913A (en) * | 2012-07-31 | 2012-10-31 | 龙功运 | Blended additive for atomizing smoke after heating tobacco, using method thereof and tobacco composite thereof |
| CN103564658A (en) * | 2013-11-22 | 2014-02-12 | 上海烟草集团有限责任公司 | Electric heating smoking device and tobacco heating structure thereof |
| CN104770885A (en) * | 2015-02-13 | 2015-07-15 | 深圳市合元科技有限公司 | Smoke suction device |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201740825A (en) | 2017-12-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2910681C (en) | Vaporisable material | |
| JP2019532671A (en) | Vaporizable tobacco wax composition and container thereof | |
| WO2018016069A1 (en) | Tobacco filler for non-combustion type heat smoking article | |
| GB2555355A (en) | Vaporisable material | |
| JP7457069B2 (en) | Composition | |
| US20190090531A1 (en) | Tobacco filling for non-combustion-type heating smoking article | |
| US20220408784A1 (en) | Tobacco filling for non-combustion-type heating smoking article | |
| TWI627910B (en) | Non-burning type heated smoking article | |
| JP7087136B2 (en) | Tobacco filling for non-combustible heated smoking articles | |
| TWI629006B (en) | Tobacco packing for non-combustion type heated smoking article | |
| TWI650082B (en) | Tobacco packing for non-burning type heated smoking article | |
| EA040319B1 (en) | TOBACCO FILLER FOR HEATING SMOKING PRODUCT OF NON-COMBUSTIBLE TYPE |