TWI597389B - Electrolysis Device - Google Patents
Electrolysis Device Download PDFInfo
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- TWI597389B TWI597389B TW105118046A TW105118046A TWI597389B TW I597389 B TWI597389 B TW I597389B TW 105118046 A TW105118046 A TW 105118046A TW 105118046 A TW105118046 A TW 105118046A TW I597389 B TWI597389 B TW I597389B
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Description
本發明是一種電解設備，尤指一種具有兩種電解槽、並將冷卻管路及陰極板直接浸入電解液中的電解設備。The invention relates to an electrolysis device, in particular to an electrolysis device having two kinds of electrolysis cells and directly immersing the cooling pipe and the cathode plate in the electrolyte.
一般的電解裝置是在陰極與陽極之間設置一可讓離子通透的隔膜，以形成不同的電解室並將電解裝置的陽極板與陰極板隔開，但是，當出現問題時，由於電極往往位於槽體內部而難以觀察，使得維修時往往必須將整套設備分解，再一一尋找原因，且對於電極的設計，往往是將電極直接固定在設備上，於拆解時也須花費一定功夫及時間，使得出問題時，設備的維修時間與維修難度往往造成使用者的在設備成本與時間成本上的沉重負擔。A general electrolysis device is provided with a membrane for allowing ions to pass through between the cathode and the anode to form different electrolysis chambers and to separate the anode plate of the electrolysis device from the cathode plate, but when a problem occurs, the electrode is often It is located inside the tank and is difficult to observe. Therefore, it is often necessary to disassemble the whole set of equipment during maintenance, and then find the cause one by one. For the design of the electrode, the electrode is often directly fixed on the equipment, and it takes a certain amount of effort to disassemble. Time, when the problem occurs, the maintenance time and maintenance difficulty of the equipment often cause a heavy burden on the equipment cost and time cost of the user.
而為了解決這樣的問題，過去以有前人提出一種可插卡式之隔膜電解裝置，該專利提出一種插卡式的隔膜電解設，使得裝備出問題時，可以快速的拆解陽極板與隔膜，使得使用者快速將可能損害的零件快速卸下檢查更換，以節省大量的人力維修成本與維修時所佔用的時間成本。但是這樣的設計，陰極板是設計成與介於陰極室與冷卻槽之間，並將兩者區隔開來。In order to solve such problems, in the past, a plug-in type diaphragm electrolysis device has been proposed by the prior art, and the patent proposes a plug-in type diaphragm electrolysis device, which can quickly disassemble the anode plate and the diaphragm when the equipment is in trouble. This allows the user to quickly remove and repair the parts that may be damaged, saving a lot of manpower maintenance costs and the time cost of maintenance. However, in such a design, the cathode plate is designed to be interposed between the cathode chamber and the cooling bath and to separate the two.
另外，由於電解時，電極板與電解液之間的接觸面積大小會影響電解的品質，而在前述設計中該設備的陰極板與陰極室中電解液的接觸面積僅侷限於陰極板的其中一面，這樣的設計會由於表面所產生的氣泡影響，會使得接觸電解液的電極的總表面積，僅侷限於陰極板的其中一面，使得反應製程中仍然具有可以改良的餘地。In addition, since the contact area between the electrode plate and the electrolyte affects the quality of the electrolysis during electrolysis, in the foregoing design, the contact area of the electrolyte between the cathode plate and the cathode chamber of the device is limited to one side of the cathode plate. Such a design may cause the total surface area of the electrode contacting the electrolyte to be limited to one side of the cathode plate due to the influence of bubbles generated on the surface, so that there is still room for improvement in the reaction process.
此外，由於電解時，於電極處會生氣泡，進而影響電極與電解液的接觸面積，所以為了提高電解效率，如何排除附著於產生在電極上的氣泡也是一重要課題，而在過去的習之技術中，有些是利用電極的形狀設計、將一導電桿連接一放電往以利氣泡排除，但這樣的設計，除了整個陽極的電流會匯集在單一導電桿外而使得該導電桿溫度較高外，在單一導電桿與放電網之間連結時，因為彼此間的接觸面積不夠大，而使得兩元件間的接觸介面的電阻因此而較高，使得該處溫度容易上升，提高了電解裝置的能量消耗，並因此降低了電解的品質，故也有必要再這部分進行改良。In addition, since bubbles are generated at the electrodes during electrolysis, which affects the contact area between the electrodes and the electrolyte, it is also an important subject to eliminate the adhesion of bubbles generated on the electrodes in order to improve the electrolysis efficiency. In the technology, some use the shape design of the electrode to connect a conductive rod to a discharge to facilitate the bubble elimination, but such a design, except that the current of the entire anode is collected outside the single conductive rod, so that the temperature of the conductive rod is higher. When the single conductive rod and the discharge net are connected, the contact area between the two elements is not high enough, so that the resistance of the contact interface between the two elements is higher, so that the temperature at the place is easily increased, and the energy of the electrolysis device is increased. Consumption, and thus reduced the quality of the electrolysis, it is necessary to improve this part.
扣掉上述的電極的設計部分，從其他方面的設計來說，因為電解液在電解反應中，其中的成分與溶液濃度會因參與電化學反應而產生化學變化，使得電解槽內的電解液產生不均勻的問題，進而影響到電解的品質；因此，為了提高電解品質，必須不斷的補充新的電解液進電解槽中，並將舊的電解液排出電解槽。Deducting the design part of the above electrode, from other aspects of the design, because the electrolyte in the electrolysis reaction, the composition and solution concentration will cause chemical changes due to participation in the electrochemical reaction, so that the electrolyte in the electrolytic cell is generated. The problem of unevenness, which in turn affects the quality of electrolysis; therefore, in order to improve the quality of electrolysis, it is necessary to continuously replenish a new electrolyte into the electrolysis cell and discharge the old electrolyte out of the electrolysis cell.
另外，又因為電解時會於電解槽中，電極處的氧化還原反應而產生不必要的雜質，或是會降低電極與電解液間接觸的氧化層，或是因為其他如槽體本身接觸槽內化學反應物而產生的各種雜質，使得為維持槽內電解效率的最大化，而必須定期清洗電解槽設備，所以對於能簡單的進行電解液補充，及電解槽清洗的設備，也有一定的需求。In addition, because electrolysis occurs in the electrolytic cell, the oxidation-reduction reaction at the electrode generates unnecessary impurities, or the oxide layer which reduces the contact between the electrode and the electrolyte, or because other cells such as the groove itself contact the groove. The various impurities generated by the chemical reactants make it necessary to periodically clean the electrolytic cell equipment in order to maximize the electrolysis efficiency in the tank. Therefore, there is a certain demand for a device capable of simply performing electrolyte replenishment and electrolytic cell cleaning.
最後，因電極本身會放熱而使得電極本身及電解液的溫度過度提高，而使得電解的效益降低，更甚者，由於電解時溫度的變化，更可能造成電極的老化而使得設備壽命降低，而造成額外的生產成本，所以過去有些設計是在電解槽上裝備散熱風扇以降低電解槽的溫度，或在電解反應時產生熱的陰極板旁設計一水冷槽，藉由水冷槽與陰極板的接觸而降低陰極板的溫度。Finally, because the electrode itself exotherms, the temperature of the electrode itself and the electrolyte is excessively increased, so that the efficiency of electrolysis is lowered. Moreover, due to the temperature change during electrolysis, the aging of the electrode is more likely to cause the life of the device to decrease, and Incurs additional production costs, so in the past some designs were designed to equip the cell with a cooling fan to reduce the temperature of the cell, or to design a water-cooled cell next to the cathode plate that generates heat during the electrolysis reaction, by contact of the water-cooled cell with the cathode plate. The temperature of the cathode plate is lowered.
但是，以上這些散熱設備，利用風扇散熱是藉由氣體分子的運動將散熱槽所散發的熱量帶走，在降溫的功能上，因為必須先將熱傳遞給電解槽體外槽，然後再由氣體分子將外槽所散發的熱量帶走的方法的效率較低；而利用水冷槽的接觸陰極板這種手段降溫陰極則僅侷限於所接觸陰極板部分，且僅與陰極板的一面作接觸，使得以上先前技術對於降低電解液的溫度，仍具有改善的空間。However, in these heat dissipating devices, the heat dissipation by the fan is carried away by the movement of gas molecules to remove the heat dissipated from the heat dissipating groove. In the function of cooling, the heat must be transferred to the outer tank of the electrolyzer, and then by the gas molecules. The method of taking away the heat dissipated from the outer tank is less efficient; and the means for lowering the temperature by using the contact cathode plate of the water-cooling tank is limited to the portion of the cathode plate that is contacted, and only makes contact with one side of the cathode plate, so that The above prior art still has room for improvement in reducing the temperature of the electrolyte.
本發明之主要目的在於提供一種使電解設備的陰極與冷卻管路具有與電解液較大接觸面積的電解設備，針對陰極與冷卻管路的裝配方式及裝配位置進行改良，使電解槽設備具有較大的陰極面積及吸熱面積以提高設備的電解品質。The main object of the present invention is to provide an electrolysis device having a cathode and a cooling pipe having a large contact area with an electrolyte, and improving the assembly mode and assembly position of the cathode and the cooling pipe, so that the electrolyzer device has a comparative Large cathode area and heat absorption area to improve the electrolysis quality of the equipment.
本發明之次要目的在於提供一種電解設備的輸液改良結構，使電解設備在使用時不需經過拆解，即可對電解設備中各槽體中補充電解液，或是灌入清洗液以進行清洗。A secondary object of the present invention is to provide an infusion improving structure of an electrolysis device, so that the electrolysis device can be replenished with electrolyte in each tank of the electrolysis device without being disassembled, or can be filled with a cleaning liquid. Cleaning.
本發明之次要目的在於提供一種電解設備的陽極改良結構，針對陽極的部分進行結構改良，以提高陽極部分的散熱能力，以及增加陽極與電解液間的接觸面積。A secondary object of the present invention is to provide an anode-improved structure of an electrolysis apparatus, which is structurally modified for the portion of the anode to improve the heat dissipation capability of the anode portion and to increase the contact area between the anode and the electrolyte.
為達到上述目的，本發明電解設備，包含：一電解槽以及一冷卻裝置，其中，上述電解槽設有一內槽以及一安裝於上述內槽外部的外槽，上述內槽具有一第一電解空間，且上述第一電解空間中設有一陽極以及一陽極電解液，而上述外槽與內槽之間形成有一第二電解空間，且上述第二電解空間中設有一陰極以及一陰極電解液，又上述第一電解空間與第二電解空間之間設有至少一隔膜單元。In order to achieve the above object, the electrolysis apparatus of the present invention comprises: an electrolytic cell and a cooling device, wherein the electrolytic cell is provided with an inner groove and an outer groove mounted outside the inner groove, the inner groove has a first electrolysis space And an anode and an anolyte are disposed in the first electrolysis space, and a second electrolysis space is formed between the outer tank and the inner tank, and a cathode and a catholyte are disposed in the second electrolysis space, and At least one diaphragm unit is disposed between the first electrolysis space and the second electrolysis space.
其特徵在於：上述內槽與外槽共同將第二電解空間封閉，且上述內槽與外槽的其中一者形成一供上述陰極***的通道；上述冷卻裝置具有安裝於上述第二電解空間中的冷卻管路，使上述冷卻管路直接接觸上述陰極電解液，使得陰極與冷卻管路兩者和電解液之間具有較大的接觸面積。The inner groove and the outer groove together seal the second electrolysis space, and one of the inner and outer grooves forms a passage for the cathode to be inserted; the cooling device has a second electrolysis space. The cooling pipe is such that the cooling pipe directly contacts the catholyte, so that the cathode and the cooling pipe have a large contact area with the electrolyte.
針對上述內槽槽體與上述陰極的設計，其中，上述內槽具有一槽體，上述槽體設有至少一將上述第二電解空間與外部空間互相間隔的隔板，且上述隔板上形成有上述通道。The inner groove body and the cathode are designed, wherein the inner groove has a groove body, and the groove body is provided with at least one partition plate separating the second electrolysis space from the outer space, and the partition plate is formed There are the above channels.
再來是關於上述管路，在本發明一實施例中，上述冷卻管路是由單一管體構成，上述單一管路具有複數個並排陳列的直線部以及複數個連接於兩直接部之間的彎曲部。Referring to the above-mentioned pipeline, in an embodiment of the invention, the cooling pipeline is composed of a single pipe body, and the single pipe has a plurality of straight portions arranged side by side and a plurality of wires connected between the two direct portions. Curved part.
另外，上述電解槽設有複數個一輸入管以及複數個輸出管，上述輸入管將一外部空間與上述第一電解空間相互連通，而上述輸出管將上述第一電解空間與上述外部空間相互連通。In addition, the electrolytic cell is provided with a plurality of input tubes and a plurality of output tubes, wherein the input tube communicates an external space with the first electrolysis space, and the output tube connects the first electrolysis space and the external space .
其中，上述輸入管穿過上述外槽的第二電解空間，並將一液體由一外部空間輸入至上述第一電解空間中，而上述輸出管穿過上述外槽的第二電解空間，並將上述液體由上述第一電解空間輸出至上述外部空間。Wherein the input pipe passes through the second electrolysis space of the outer tank, and a liquid is input into the first electrolysis space from an outer space, and the output pipe passes through the second electrolysis space of the outer tank, and The liquid is discharged from the first electrolysis space to the outer space.
為了更精確的定義上述各輸入、輸出管的位置，其中，上述電解槽於一第一端位置具有一上輸入管以及一下輸入管，並於一位於相反側的第二端位置具有一上輸出管以及一下輸出管。In order to more precisely define the positions of the input and output tubes, the electrolytic cell has an upper input tube and a lower input tube at a first end position, and has an upper output at a second end position on the opposite side. Tube and the next output tube.
而關於上述內槽、上述外槽與上述各輸入、輸出管的連接方式，上述內槽外側具有複數個外接頭連通內部的第一電解空間，而上述外槽內側具有複數個內接頭連通外部的外部空間，上述複數個輸入管及複數個輸出管分別安裝於對應位置的上述外接頭與內接頭之間。The inner tank and the outer tank are connected to the input and output tubes, and the outer side of the inner tank has a plurality of outer joints communicating with the first inner electrolysis space, and the inner side of the outer tank has a plurality of inner joints communicating with the outer portion. In the external space, the plurality of input tubes and the plurality of output tubes are respectively installed between the outer joint and the inner joint at corresponding positions.
除此之外，上述電解槽還進一步設有複數輔助管，上述複數輔助管分別由將上述外部空間與上述第二電解空間連通。In addition, the electrolytic cell is further provided with a plurality of auxiliary tubes, and the plurality of auxiliary tubes are connected to the second electrolytic space by the external space.
最後，關於本發明陽極的部分，上述陽極設有複數個間隔並排的導電桿，且上述複數導電桿共同連接一導電網罩；其中，上述導電網罩圍繞於上述複數導電桿外側，並形成有一導電空間增加與陽極電解液的接觸面積；上述複數導電桿依據上述導電網罩的長度分別連接在上述導電空間的均分位置。Finally, in the anode portion of the present invention, the anode is provided with a plurality of electrically conductive rods arranged side by side, and the plurality of conductive rods are commonly connected to a conductive mesh cover; wherein the conductive mesh cover surrounds the outer side of the plurality of conductive rods and is formed with The conductive space is increased in contact area with the anolyte; the plurality of conductive rods are respectively connected to the equally spaced positions of the conductive spaces according to the length of the conductive mesh cover.
由以上說明可知，本發明電解設備的特點在於藉由在內槽上設計出一凸出的隔板來在內槽外壁與外槽內壁間固定陰極板；並將冷卻管入直接設置於裝有電解液的槽中；並在內槽與外槽上的上下位置設置複數個輸入及輸出管路；並針對陽極的導電桿數量進行增加，使得本發明電解設備具有較大的陰極及陽極面積，除了強化陰、陽兩極的散熱能力，還藉由增加冷卻管的吸熱面積以提高設備的電解品質，並使得電解設備在使用時不需經過拆解，即可對電解設備中各槽體補充電解液，或是灌入清洗液以進行清洗。It can be seen from the above description that the electrolysis device of the present invention is characterized in that a cathode plate is fixed between the outer wall of the inner groove and the inner wall of the outer groove by designing a protruding partition on the inner groove; and the cooling pipe is directly installed in the installation. a tank having an electrolyte; and a plurality of input and output lines disposed at upper and lower positions on the inner tank and the outer tank; and an increase in the number of conductive rods for the anode, so that the electrolysis apparatus of the present invention has a larger cathode and anode area In addition to strengthening the heat dissipation capacity of the anode and the cathode, the electrolyte quality of the equipment is increased by increasing the heat absorption area of the cooling tube, and the electrolysis equipment can be replenished to each tank in the electrolysis equipment without disassembling. The electrolyte is either poured into the cleaning solution for cleaning.
茲為便於更進一步對本發明之構造、使用及其特徵有更深一層明確、詳實的認識與瞭解，爰舉出較佳實施例，配合圖式詳細說明如下：In order to further clarify and understand the structure, the use and the features of the present invention, the preferred embodiment is described in detail with reference to the following drawings:
請參照圖1、2、3、4所示，本發明電解設備，具有一電解槽10及一冷卻裝置17，上述電解槽10包含一外槽11、複數條管路、一內槽13、一第一電解空間14、一第二電解空間15、一蓋板16、連結上述冷卻裝置17的兩冷卻管171、兩陰極板18、一陽極19及兩隔膜單元20；上述外槽11內部包含一容置空間110，上述複數管路包括組合時安裝在上述外槽11的上述容置空間110中的一第一端位置111，連接用來輸入一陽極電解液21及陽極清洗液211(圖1至4中為方便表示未畫出)至上述內槽13中的一上輸入管121及一下輸入管122(圖2中為方便觀察，將上述上輸入管121與上述輸入管122先行連結在上述內槽13上)，於上述第一端位置111相反側的一第二端位置112連接用來輸出上述內槽13中液體的一上輸出管123及一下輸出管124，以及裝設在上述第一端位置111裝設的複數個用來輸入一陰極電解液22的輸入輔助管125，另外，還包含安裝在上述第二端位置112的上、下位置所分別設有複數個用來輸出上述陰極電解液22的上輸出輔助管126、及下輸出輔助管127；其中，為了更換上的方便，組合時，上述上輸入管121、上述下輸入管122、上述上輸出管123及上述下輸出管124分別是透過設置於上述外槽11上的複數個內接頭113及上述內槽13上的複數個外接頭132連結在上述外槽11與上述內槽13之間。Referring to Figures 1, 2, 3 and 4, the electrolysis apparatus of the present invention has an electrolytic cell 10 and a cooling device 17, and the electrolytic cell 10 includes an outer tank 11, a plurality of tubes, an inner tank 13, and a a first electrolytic space 14, a second electrolytic space 15, a cover plate 16, two cooling tubes 171 connecting the cooling device 17, two cathode plates 18, an anode 19 and two diaphragm units 20; the outer tank 11 includes a The accommodating space 110 includes a first end position 111 installed in the accommodating space 110 of the outer tank 11 when combined, and is connected for inputting an anolyte 21 and an anode cleaning liquid 211 (FIG. 1). An upper input pipe 121 and a lower input pipe 122 to the inner groove 13 are conveniently shown in FIG. 4 (the upper input pipe 121 and the input pipe 122 are connected in advance in FIG. 2 for convenience of observation). a second end position 112 on the opposite side of the first end position 111 is connected to an upper output tube 123 and a lower output tube 124 for outputting the liquid in the inner tank 13, and is mounted on the inner tank 13 a plurality of inputs for inputting a catholyte 22 at one end position 111 The auxiliary tube 125 further includes a plurality of upper output auxiliary tubes 126 and lower output auxiliary tubes 127 for outputting the catholyte 22 respectively at upper and lower positions of the second end position 112; For the convenience of replacement, the upper input pipe 121, the lower input pipe 122, the upper output pipe 123, and the lower output pipe 124 are respectively transmitted through a plurality of inner joints 113 provided on the outer groove 11 and A plurality of outer joints 132 on the inner tank 13 are coupled between the outer tank 11 and the inner tank 13.
上述內槽13內部具有上述第一電解空間14，上述內槽13殼體上設置有供組合時由上述隔膜單元20從兩側所覆蓋的開口131以及對應上述上輸入管121，上述下輸入管122、上述上輸出管123、上述下輸出管124位置的複數個上述外接頭132，使得上述陽極電解液21能藉由上述下輸入管122注入至上述第一電解空間14，並藉由上述上輸出管123排出反應後的上述陽極電解液21；此外，上述內槽13兩側還設有一具有通道133的隔板134，上述隔板134為一突出上述內槽13槽外表面的片體，上述隔板134上面還各自設有一供電解時所產生氣體排出的第二排氣口135。The inner tank 13 has the first electrolytic space 14 therein, and the inner tank 13 is provided with an opening 131 for covering from both sides of the diaphragm unit 20 when combined, and corresponding to the upper input pipe 121, the lower input pipe 122, the plurality of outer joints 132 at the position of the upper output tube 123 and the lower output tube 124, so that the anolyte 21 can be injected into the first electrolytic space 14 by the lower input tube 122, and The output tube 123 discharges the anolyte 21 after the reaction; further, a partition 134 having a passage 133 is formed on both sides of the inner groove 13, and the partition 134 is a sheet protruding from the outer surface of the inner groove 13. The partition plate 134 is also provided with a second exhaust port 135 for discharging the gas generated when the power is supplied.
請參考圖1及圖4所示，在本實施例中，為了更加穩固上述內槽13與上述外槽11間的組接，上述內槽13的兩側還有組接橫跨上述隔板134兩側的固定板136，上述固定版136上具有用來供上述冷卻管171穿過並固定的複數個開孔137，並在其邊緣具有一藉由高低差，而能夠接觸覆蓋上述隔板134，使上述隔板134與上述固定板136之間組接更加準確的凸緣138，使得上述內槽13與上述外槽11在組合時，除了藉由上述隔板134與上述外槽11透過一做為鎖固件的螺絲(圖上未畫出)組合時外，還藉由上述固定板136與上述外槽11組接而更加穩固，並在上述內槽13置入上述容置空間110時，由上述固定板136與上述隔板134共同在上述外槽11與上述內槽13間形成封閉的上述第二電解空間15與外部空間產生互相間隔，以方便使用者藉由上述第二排氣口135收集/排出電解時所產生的氣體。Referring to FIG. 1 and FIG. 4, in the embodiment, in order to further stabilize the assembly between the inner groove 13 and the outer groove 11, the two sides of the inner groove 13 are further assembled across the partition 134. The fixing plate 136 on the two sides has a plurality of openings 137 for the passage and fixing of the cooling tube 171, and has a height difference on the edge thereof to contact and cover the partition plate 134. Between the partition plate 134 and the fixing plate 136, a more accurate flange 138 is assembled, so that the inner groove 13 and the outer groove 11 are combined, except that the partition plate 134 and the outer groove 11 are passed through. When the screws (not shown) of the fastener are combined, the fixing plate 136 is further assembled with the outer groove 11 to be more stable, and when the inner groove 13 is placed in the accommodating space 110, The fixing plate 136 and the partition plate 134 are spaced apart from each other by the second electrolytic space 15 which is closed between the outer groove 11 and the inner groove 13 so as to be spaced apart from each other by the fixing plate 136 for facilitating the user to pass the second exhaust port 135. The gas generated during electrolysis is collected/discharged.
而針對上述冷卻管171，請參考圖5所示，在本實施例中，上述冷卻管171的材質為鈦金屬，形狀為單一管路，並具有複數個並排陳列的直線部172以及複數個連接於兩直接部之間的彎曲部173，而使上述冷卻管171呈現出複數個U字型的外觀；上述冷卻管171內部具有一冷卻流體174流通於管路中，使得上述冷卻管171能藉由熱交換作用，讓上述冷卻管171所接觸吸收的熱量能由上述冷卻流體174帶離上述電解槽10中。For the cooling tube 171, please refer to FIG. 5. In the embodiment, the cooling tube 171 is made of titanium metal and has a single tube shape, and has a plurality of straight portions 172 and a plurality of connections arranged side by side. The cooling tube 171 has a plurality of U-shaped appearances on the curved portion 173 between the two direct portions; the cooling tube 171 has a cooling fluid 174 flowing therein through the pipeline, so that the cooling tube 171 can be borrowed The heat absorbed by the cooling tube 171 can be carried away from the electrolytic cell 10 by the heat transfer agent 174 by heat exchange.
但在本發明的另一實施例中，請參考圖6所示，上述冷卻管171可設為其他形狀，如圖6中包含一入口管175、一出口管176以及複數個介於上述入口管175與出口管176之間的分歧管177而呈現出的柵欄狀樣態，使上述冷卻管171與上述陰極電解液22之間的接觸面積增加；但要特別說明的是，上述兩種對於冷卻管171設計的實施例僅是為了說明而非加以限制，任何藉由彎折或分岔上述冷卻管171管路而使得上述冷卻管171的表面積增加的設計，對於本領域述人員來說應是簡單變化，使得類似的設計也應屬於本發明所揭示之範疇。However, in another embodiment of the present invention, please refer to FIG. 6 , the cooling tube 171 can be set to other shapes, as shown in FIG. 6 , an inlet tube 175 , an outlet tube 176 , and a plurality of inlet tubes 175 and the outlet pipe 176 between the branch pipe 177 to present a fence-like state, so that the contact area between the cooling pipe 171 and the catholyte 22 is increased; but particularly, the above two for cooling The embodiment of the tube 171 design is for purposes of illustration and not limitation, and any design that increases the surface area of the cooling tube 171 by bending or dividing the conduit of the cooling tube 171 described above should be Simple variations such that similar designs are also within the scope of the present invention.
關於陰極板18的部分，請參考圖2及圖3所示，上述陰極板18依照功能而分成用來一固定上述陰極板18位置而設置在上述陰極板18頂面的支撐部181以及一與上述陰極電解液22接觸的反應部182，並在上述支撐部181上進一步設置一用來與電源供應源連接的通電部183以及一絕緣部184，上述絕緣部184連接於上述支撐部181，而上述通電部183穿設於上述絕緣部184，並與上述支撐部181相互連接；上述反應部182的厚度小於上述通道133的寬度，而能夠穿過上述通道133並與上述陰極電解液22相接觸，而上述支撐部181的厚度大於上述通道133的寬度，無法穿過上述通道133而使得上述陰極板18被固定在上述隔板134上，使得本實施例的電解設備，使用者在更換維修或檢查時，只要直接將上述陰極板18由上述通道133中抽出，並在上述通道133中放入新的上述陰極板18即可完成更換。With respect to the portion of the cathode plate 18, as shown in FIG. 2 and FIG. 3, the cathode plate 18 is divided into a support portion 181 which is provided on the top surface of the cathode plate 18 for fixing the position of the cathode plate 18, and a portion thereof. The reaction portion 182 in contact with the catholyte 22 is further provided with a conducting portion 183 for connecting to a power supply source and an insulating portion 184, and the insulating portion 184 is connected to the supporting portion 181. The conducting portion 183 is disposed in the insulating portion 184 and is connected to the supporting portion 181. The thickness of the reaction portion 182 is smaller than the width of the channel 133, and can pass through the channel 133 and be in contact with the catholyte 22 The thickness of the support portion 181 is larger than the width of the passage 133, and the passage 133 cannot pass through the passage 133, so that the cathode plate 18 is fixed on the partition plate 134, so that the electrolysis device of the embodiment is replaced by a user or At the time of inspection, the cathode plate 18 is directly withdrawn from the above-mentioned passage 133, and a new one of the cathode plates 18 is placed in the passage 133 to complete the replacement.
在本實施例中，設置於上述隔板134上的上述通道133形狀是一矩形，以配合上述陰極板18的形狀，並使上述陰極板18介設於上述內槽13外側面與上述外槽11的內側面之間，讓上述陰極板18的兩相反側皆能接觸上述陰極電解液22，以增加面積；此外，詳細的上述通道133的位置在設置時是比較接近上述內槽13外面，而使得上述陰極板18與上述隔膜單元20之間的一第一間隔距離185小於上述陰極板18與上述外槽11內側面之間的一第二間隔距離186，盡可能的減少上陽極19與上述陰極板18之間的距離，以提升電解品質。In the embodiment, the passage 133 disposed on the partition plate 134 has a rectangular shape to match the shape of the cathode plate 18, and the cathode plate 18 is disposed on the outer surface of the inner groove 13 and the outer groove. Between the inner side surfaces of the first and second sides of the cathode plate 18, the catholyte 22 can be contacted to increase the area; moreover, the position of the channel 133 in detail is relatively close to the outer groove 13 when disposed. The first spacing distance 185 between the cathode plate 18 and the diaphragm unit 20 is smaller than a second spacing distance 186 between the cathode plate 18 and the inner surface of the outer groove 11 to reduce the upper anode 19 as much as possible. The distance between the above cathode plates 18 is to improve the electrolysis quality.
另外，本發明並沒有對上述通道133的數量進行限制，使得本領域技術人員可在上述隔板134上在不同位置同時設置複數個上述通道133，並在設置上述陰極板18時，隨電解需求調整上述陰極板18與上述陽極19的距離，並藉由一或複數個蓋件如橡皮塞等，將不使用的上述通道133封閉，即可保持上述第二電解空間15封閉。In addition, the present invention does not limit the number of the above-mentioned channels 133, so that those skilled in the art can simultaneously provide a plurality of the above-mentioned channels 133 at different positions on the above-mentioned partition plate 134, and when the above-mentioned cathode plates 18 are provided, with the electrolysis demand The distance between the cathode plate 18 and the anode 19 is adjusted, and the unused passage 133 is closed by one or a plurality of cover members such as rubber stoppers or the like to keep the second electrolytic space 15 closed.
而針對上述陽極19的部分，請參考圖2及圖7所示；在本實施例中，上述陽極19由兩導電桿191，及一導電網罩192所組成；在本實施例中，上述導電桿191安裝在上述蓋板16上，並被上述蓋板16分隔為一通電部193與一反應部194，上述導電桿191在外型上為一圓柱，上述導電網罩192是為了增加上述陽極19的表面積，而在上述反應部19距離上述蓋板16一間隔距離195處的位置裝設上述導電網罩192，For the portion of the anode 19, please refer to FIG. 2 and FIG. 7; in the embodiment, the anode 19 is composed of two conductive rods 191 and a conductive mesh cover 192; in the embodiment, the conductive The rod 191 is mounted on the cover plate 16 and is divided by the cover plate 16 into an electric conducting portion 193 and a reaction portion 194. The conductive rod 191 is a cylinder on the outer shape, and the conductive mesh cover 192 is for adding the anode 19 The surface area of the conductive mesh cover 192 is disposed at a position of the reaction portion 19 at a distance 195 from the cover plate 16 .
上述導電網罩192圍繞於上述兩導電桿191外側，並形成有一導電空間196增加與陽極電解液21的接觸面積，其中要特別說明的是，在本實施例中，為了降低上述導電網罩192與上述導電桿191間的電阻，上述導電桿191的直徑等同於上述導電空間196的寬度，且上述導電桿191數量設為複數個；此外，為了分散在電解反應時上述導電空間196中的溫度，上述兩導電桿191穿設於上述導電網罩192中1/3及2/3的位置，而將上述導電空間196均分為3等分。The conductive mesh cover 192 surrounds the outer sides of the two conductive rods 191, and a conductive space 196 is formed to increase the contact area with the anolyte 21, wherein, in particular, in the embodiment, the conductive mesh cover 192 is lowered. The electric resistance between the conductive rod 191 and the conductive rod 191 is equal to the width of the conductive space 196, and the number of the conductive rods 191 is plural; in addition, the temperature in the conductive space 196 is dispersed in the electrolytic reaction. The two conductive rods 191 are disposed at positions 1/3 and 2/3 of the conductive mesh cover 192, and the conductive spaces 196 are equally divided into three equal parts.
通電時，上述兩導電桿191、上述導電網罩192分別分散陽極19所產生的溫度，並透過上述導電網罩192增加上述陽極19與上述陽極電解液21的接觸面積，並且利用網體結構方便電解反應時，產生於上述導電網罩192及上述導電桿191的氣泡排出，並由設置於上述蓋板16上的一第一排氣口161由上述第一電解空間14內排出電解反應所產生之氣體，並收集；When the current is applied, the two conductive rods 191 and the conductive mesh cover 192 respectively disperse the temperature generated by the anode 19, and increase the contact area between the anode 19 and the anolyte 21 through the conductive mesh cover 192, and the mesh structure is convenient. During the electrolysis reaction, the bubbles generated in the conductive mesh cover 192 and the conductive rod 191 are discharged, and are discharged from the first electrolytic space 14 by the first exhaust port 161 provided on the cover plate 16 to generate an electrolytic reaction. Gas and collect;
最後關於隔膜單元20，本發明並沒有對隔膜單元20進行任何限制，採用現有技術即可。Finally, regarding the diaphragm unit 20, the present invention does not impose any limitation on the diaphragm unit 20, and the prior art can be employed.
請參考圖2及圖3所示，組合時，上述陽極19組裝於上述蓋板16；上述蓋板16組裝於上述內槽13，並讓上述陽極19設置於上述第一電解空間14中；上述兩隔膜單元20分別藉由複數個螺絲與螺帽(圖上未畫出)，鎖固在裝在上述內槽13兩側，上述兩陰極板18分別裝設於上述隔板134的上述通道133中，並藉由上述支撐部181將上述陰極板18扣在上述隔板134上，而不會從上述通道133中掉出；上述內槽13則置入上述容置空間110中，然後藉由複數個螺絲(圖1、2中螺絲未畫出)與上述固定板136一起固定在上述外槽11上，並在上述內槽13與上述外槽11之間形成上述第二電解空間15；上述冷卻管171組裝於上述第二電解空間15中並分別設置於上述第二電解空間15中兩側的第一區域151及第二區域152，然後再透過上述開孔137穿出上述二電解空間15中。Referring to FIG. 2 and FIG. 3, in combination, the anode 19 is assembled to the cover plate 16; the cover plate 16 is assembled to the inner groove 13, and the anode 19 is disposed in the first electrolytic space 14; The two diaphragm units 20 are respectively locked on the two sides of the inner groove 13 by a plurality of screws and nuts (not shown), and the two cathode plates 18 are respectively mounted on the passage 133 of the partition plate 134. And the cathode plate 18 is fastened to the partition plate 134 by the support portion 181 without falling out of the passage 133; the inner groove 13 is placed in the accommodating space 110, and then a plurality of screws (not shown in FIGS. 1 and 2) are fixed to the outer groove 11 together with the fixing plate 136, and the second electrolytic space 15 is formed between the inner groove 13 and the outer groove 11; The cooling tubes 171 are assembled in the second electrolysis space 15 and are respectively disposed in the first region 151 and the second region 152 on both sides of the second electrolysis space 15, and then pass through the openings 137 to pass through the second electrolysis space 15 in.
另外，要特別說明的是，關於上述各元件間的結合方法，僅是為了說明而非加以限定，使得利用其他元件結合上述外槽11、上述內槽13、上述蓋板16的方法，或是其他將上述陰極板18固定在內槽13與外槽11內壁面之間的方法，皆應屬於本發明的範疇。In addition, it is to be noted that the bonding method between the above-mentioned elements is merely for the purpose of illustration and not limitation, so that the other elements may be used in combination with the outer groove 11, the inner groove 13, and the cover plate 16, or Other methods of fixing the above-described cathode plate 18 between the inner groove 13 and the inner wall surface of the outer groove 11 are all within the scope of the present invention.
請參考圖2及圖3所示，更精確地來說，由上述內槽13與上述外槽11組合後所形成的上述第二電解空間15之中，由上述內槽13往外排序分別包含上述隔膜單元20、上述陰極板18及上述冷卻管171；其中，要特別說明的是，上述陰極板18在組裝後與上述隔膜單元20、上述冷卻管171互相平行，而使得上述電解槽10使用時，由上述輸入輔助管125所注入，並填充於上述第二電解空間15中的上述陰極電解液22 (圖2中未畫出)能直接與上述陰極板18的兩對側版面互相接觸；上述冷卻管171，不與上述陰極板18、上述外槽11互相接觸，使得上述電解槽10使用時，上述冷卻管171直接與上述陰極電解液22接觸，並達到上述冷卻管171接觸上述陰極電解液22時所能具有的最大的接觸面積。Referring to FIG. 2 and FIG. 3, more precisely, the second electrolytic space 15 formed by combining the inner groove 13 and the outer groove 11 is sequentially sorted by the inner groove 13 to include the above. The diaphragm unit 20, the cathode plate 18, and the cooling tube 171; wherein, in particular, the cathode plate 18 is parallel to the diaphragm unit 20 and the cooling tube 171 after assembly, so that the electrolytic cell 10 is used. The catholyte 22 (not shown in FIG. 2) injected by the input auxiliary tube 125 and filled in the second electrolysis space 15 can directly contact the opposite side plates of the cathode plate 18; The cooling tube 171 is not in contact with the cathode plate 18 and the outer tank 11, so that when the electrolytic cell 10 is used, the cooling tube 171 is directly in contact with the catholyte 22, and the cooling tube 171 is brought into contact with the catholyte. The maximum contact area that can be obtained at 2200 hours.
以上所舉的冷卻管171的安裝位置，僅是本發明多種實施例的其中一種，使得上述冷卻管171不一定被限制於安裝於上述第二電解空間15中，而在其他實施例中，可以安裝在上述第一電解空間14中，或是同時安裝在上述第一電解空間14及上述第二電解空間15中，且上述冷卻管171不一定被限制要安裝在上述陰極板18與上述外槽11之間，亦可裝置於上述陰極板18及上述隔膜單元20之間或是其他位置，只要上述冷卻管171浸在電解液中直接冷卻電解液之設計，皆應屬於本發明之範疇。The mounting position of the cooling tube 171 mentioned above is only one of the various embodiments of the present invention, so that the cooling tube 171 is not necessarily limited to being installed in the second electrolysis space 15, but in other embodiments, Mounted in the first electrolytic space 14 or simultaneously installed in the first electrolytic space 14 and the second electrolytic space 15, and the cooling tube 171 is not necessarily limited to be mounted on the cathode plate 18 and the outer tank 11 may be disposed between the cathode plate 18 and the diaphragm unit 20 or at other positions. As long as the cooling tube 171 is immersed in the electrolyte to directly cool the electrolyte, it is within the scope of the present invention.
關於上述電解槽10的在電解時的實際使用方式，請參考圖1、圖7及圖8所示；當電解時，首先，封閉上述上輸入管121及上述下輸出管124並由開通後的上述下輸入管122於上述第一電解空間14中填入上述陽極電解液21，並藉由開通後的上述輸入輔助管125於上述第二電解空間15中填入上述陰極電解液22，上述陽極電解液21與上述陰極電解液22透過上述隔膜單元20分隔，並在電解時透過上述隔膜單元20交換上述陽極電解液21與上述陰極電解液22的離子；上述陽極19、上述兩陰極板18連接一外部電源，而共同形成一電解回路，進行電解反應而形成一反應狀態。Regarding the actual use mode of the electrolytic cell 10 at the time of electrolysis, please refer to FIG. 1, FIG. 7 and FIG. 8; when electrolyzing, first, the upper input pipe 121 and the lower output pipe 124 are closed and opened. The lower input pipe 122 fills the anolyte 21 in the first electrolytic space 14, and fills the catholyte 22 in the second electrolytic space 15 by the opened input auxiliary pipe 125. The electrolyte solution 21 is separated from the catholyte 22 by the separator unit 20, and exchanges ions of the anolyte 21 and the catholyte 22 through the separator unit 20 during electrolysis; the anode 19 and the two cathode plates 18 are connected. An external power source forms an electrolytic circuit together to perform an electrolytic reaction to form a reaction state.
其中，反應過的上述陽極電解液21在上述步驟補充新的上述陽極電解液21時，是透過開通後的上述上輸出管123排出上述第一電解空間14中，而使得上述第一電解空間14中的電解液體積保持不變；同樣，反應後的上述陰極電解液22是透過開通上述上輸出輔助管126排出上述第二電解空間15；而使得上述第二電解空間15中的電解液體積保持不變。When the anolyte 21 that has been reacted is replenished with the new anolyte 21 in the above step, the upper electrolysis chamber 123 is discharged through the upper discharge tube 123, so that the first electrolysis space 14 is caused. The volume of the electrolyte remains unchanged; likewise, the catholyte 22 after the reaction is discharged through the upper output auxiliary pipe 126 to discharge the second electrolytic space 15; and the volume of the electrolyte in the second electrolytic space 15 is maintained. constant.
請參考圖9所示，在反應狀態時，過程中一來自陰極板18所產生的熱23，則是傳遞到上述陰極電解液22後，藉由上述冷卻管171吸收，並由上述冷卻流體174將陰極板18所產生的熱23帶離上述第二電解空間15，並進入上述冷卻裝置17進行冷卻。Referring to FIG. 9, in the reaction state, a heat 23 generated from the cathode plate 18 during the process is transferred to the catholyte 22, absorbed by the cooling pipe 171, and the cooling fluid 174 is used. The heat 23 generated by the cathode plate 18 is carried away from the second electrolysis space 15 and enters the above-described cooling device 17 for cooling.
請參考圖10及圖11所示，為了維持上述電解槽10的電解品質而必須清洗上述電解設備時，是由開通上述上輸入管121及上述下輸出管124，並封閉上述下輸入管122來注入一陽極清洗液211於上述第一電解空間14中，並將上述陽極清洗液211與其他反應中所產生的雜物由開通後的上述下輸出管124排出上述第一電解空間14；而上述第二電解空間15的清洗方式，則是由上述輸入輔助管125將一陰極清洗液221注入上述第二電解空間15中，並將廢水及雜質由上述下輸出輔助管127排出而成為一沖洗狀態；上述陽極清洗液211、上述陰極清洗液221在本實施例中皆是水，但是，本發明並沒有特別去限制上述陰、陽極清洗液221、211的種類，使得使用者可配合需求選擇上述陰、陽極清洗液221、211。Referring to FIGS. 10 and 11, in order to maintain the electrolysis quality of the electrolytic cell 10, it is necessary to clean the electrolysis device by opening the upper input tube 121 and the lower output tube 124, and closing the lower input tube 122. An anode cleaning solution 211 is injected into the first electrolytic space 14, and the anode cleaning liquid 211 and the impurities generated in the other reactions are discharged from the opened lower output tube 124 to the first electrolytic space 14; In the cleaning method of the second electrolytic space 15, a cathode cleaning liquid 221 is injected into the second electrolytic space 15 by the input auxiliary pipe 125, and waste water and impurities are discharged from the lower output auxiliary pipe 127 to become a flushing state. The above-mentioned anode cleaning liquid 211 and the above-mentioned cathode cleaning liquid 221 are all water in the present embodiment. However, the present invention does not particularly limit the types of the above-mentioned anode and anode cleaning liquids 221 and 211, so that the user can select the above-mentioned requirements. Anion and anode cleaning solutions 221, 211.
此外，本發明也沒有特別去限制如何封閉上述上、下輸入管121、122，上述上、下輸出管123、124、上述輸入輔助管125及上述上、下輸出輔助管126、127的封閉方式，使得本領域技術人員可在上述元件所涉及的流道中的任一位置設置一可開關的閥、單向閥或是其他任意可封閉流道中流體移動方向的元件，來改變管路的流通狀態。In addition, the present invention does not particularly limit how to close the upper and lower input tubes 121 and 122, and to close the upper and lower output tubes 123 and 124, the input auxiliary tube 125, and the upper and lower output auxiliary tubes 126 and 127. Therefore, a person skilled in the art can set a switchable valve, a check valve or any other element in the direction of fluid movement in the closable flow path at any position in the flow path involved in the above-mentioned component to change the flow state of the pipeline. .
上述所舉實施例，僅用為方便說明本發明並非加以限制，在不離本發明精神範疇，熟悉此一行業技藝人士依本發明申請專利範圍及發明說明所作之各種簡易變形與修飾，均仍應含括於以下申請專利範圍中。The above-mentioned embodiments are merely intended to be illustrative of the present invention and are not intended to limit the scope of the invention, and the various modifications and modifications made by those skilled in the art in accordance with the scope of the invention and the description of the invention are still It is included in the scope of the following patent application.
10‧‧‧電解裝置10‧‧‧Electrolytic device
11‧‧‧外槽11‧‧‧ outer trough
110‧‧‧容置空間110‧‧‧ accommodating space
111‧‧‧第一端位置111‧‧‧First end position
112‧‧‧第二端位置112‧‧‧second end position
113‧‧‧內接頭113‧‧‧Internal joint
121‧‧‧上輸入管121‧‧‧Upper input tube
122‧‧‧下輸入管122‧‧‧ lower input tube
123‧‧‧上輸出管123‧‧‧Upper output tube
124‧‧‧下輸出管124‧‧‧ lower output tube
125‧‧‧輸入輔助管125‧‧‧Input auxiliary tube
126‧‧‧上輸出輔助管126‧‧‧Up output auxiliary tube
127‧‧‧下輸出輔助管127‧‧‧ output auxiliary tube
13‧‧‧內槽13‧‧‧Inner slot
131‧‧‧開口131‧‧‧ openings
132‧‧‧外接頭132‧‧‧Outer joint
133‧‧‧通道133‧‧‧ channel
134‧‧‧隔板134‧‧ ‧ partition
135‧‧‧第二排氣口135‧‧‧Second vent
136‧‧‧固定板136‧‧‧ fixed plate
137‧‧‧開孔137‧‧‧ openings
138‧‧‧凸緣138‧‧‧Flange
14‧‧‧第一電解空間14‧‧‧First Electrolytic Space
15‧‧‧第二電解空間15‧‧‧Second Electrolysis Space
151‧‧‧第一區域151‧‧‧First area
152‧‧‧第二區域152‧‧‧Second area
16‧‧‧蓋板16‧‧‧ Cover
161‧‧‧第一排氣口161‧‧‧first exhaust
17‧‧‧冷卻裝置17‧‧‧Cooling device
171‧‧‧冷卻管171‧‧‧ Cooling tube
172‧‧‧直線部172‧‧‧ Straight line
173‧‧‧彎曲部173‧‧‧Bend
174‧‧‧冷卻流體174‧‧‧Cooling fluid
175‧‧‧入口管175‧‧‧Inlet pipe
176‧‧‧出口管176‧‧‧Export tube
177‧‧‧分歧管177‧‧‧Different pipe
18‧‧‧陰極板18‧‧‧ cathode plate
181‧‧‧支撐部181‧‧‧Support
182‧‧‧反應部182‧‧‧Response
183‧‧‧通電部183‧‧‧Electricity Department
184‧‧‧絕緣部184‧‧‧Insulation
185‧‧‧第一間隔距離185‧‧‧first separation distance
186‧‧‧第一間隔距離186‧‧‧First separation distance
19‧‧‧陽極19‧‧‧Anode
191‧‧‧導電桿191‧‧‧ Conducting rod
192‧‧‧導電網罩192‧‧‧ Conductive mesh cover
193‧‧‧通電部193‧‧‧Electricity Department
194‧‧‧反應部194‧‧‧Response
195‧‧‧間隔距離195‧‧‧ separation distance
196‧‧‧導電空間196‧‧‧ conductive space
20‧‧‧隔膜單元20‧‧‧Separator unit
21‧‧‧陽極電解液21‧‧‧Anodic electrolyte
211‧‧‧陽極清洗液211‧‧‧Anode cleaning solution
22‧‧‧陰極電解液22‧‧‧Catholyte
221‧‧‧陰極清洗液221‧‧‧Cathodic cleaning solution
23‧‧‧熱23‧‧‧Hot
圖1為本發明電解設備的示意圖； 圖2為本發明電解設備的分解圖； 圖3為本發明電解設備的剖面圖； 圖4為本發明電解設備中固定板的示意圖； 圖5為本發明電解設備的冷卻管在一實施例的示意圖； 圖6為本發明電解設備的冷卻管在另一實施例的示意圖； 圖7為本發明電解設備針對第一電解空間注入陽極電解液的示意圖； 圖8為本發明電解設備針對第二電解空間注入陰極電解液的示意圖； 圖9為本發明電解設備在反應狀態時冷卻管路作用的示意圖； 圖10為本發明電解設備針對第一電解空間注入陽極清洗液的示意圖； 圖11為本發明電解設備針對第二電解空間注入陽極清洗液的示意圖。1 is a schematic view of an electrolysis apparatus of the present invention; FIG. 2 is an exploded view of the electrolysis apparatus of the present invention; FIG. 3 is a cross-sectional view of the electrolysis apparatus of the present invention; BRIEF DESCRIPTION OF THE DRAWINGS FIG. 6 is a schematic view of another embodiment of a cooling tube of an electrolysis apparatus according to the present invention; FIG. 7 is a schematic view of an electrolysis apparatus according to the present invention for injecting an anolyte into a first electrolysis space; 8 is a schematic view of the electrolysis device injecting catholyte into the second electrolysis space according to the present invention; FIG. 9 is a schematic view showing the action of the cooling pipe in the reaction state of the electrolysis device of the present invention; Schematic diagram of the cleaning liquid; Figure 11 is a schematic view of the electrolysis apparatus of the present invention for injecting the anode cleaning liquid into the second electrolysis space.
10‧‧‧電解槽 10‧‧‧electrolyzer
11‧‧‧外槽 11‧‧‧ outer trough
124‧‧‧下輸出管 124‧‧‧ lower output tube
127‧‧‧下輸出輔助管 127‧‧‧ output auxiliary tube
13‧‧‧內槽 13‧‧‧Inner slot
133‧‧‧通道 133‧‧‧ channel
134‧‧‧隔板 134‧‧ ‧ partition
14‧‧‧第一電解空間 14‧‧‧First Electrolytic Space
15‧‧‧第二電解空間 15‧‧‧Second Electrolysis Space
151‧‧‧第一區域 151‧‧‧First area
152‧‧‧第二區域 152‧‧‧Second area
16‧‧‧蓋板 16‧‧‧ Cover
171‧‧‧冷卻管 171‧‧‧ Cooling tube
18‧‧‧陰極板 18‧‧‧ cathode plate
181‧‧‧支撐部 181‧‧‧Support
182‧‧‧反應部 182‧‧‧Response
183‧‧‧通電部 183‧‧‧Electricity Department
184‧‧‧絕緣部 184‧‧‧Insulation
185‧‧‧第一間隔距離 185‧‧‧first separation distance
186‧‧‧第一間隔距離 186‧‧‧First separation distance
19‧‧‧陽極 19‧‧‧Anode
191‧‧‧導電桿 191‧‧‧ Conducting rod
192‧‧‧導電網罩 192‧‧‧ Conductive mesh cover
20‧‧‧隔膜單元 20‧‧‧Separator unit
Claims (10)
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|---|---|---|---|
| TW105118046A TWI597389B (en) | 2016-06-07 | 2016-06-07 | Electrolysis Device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105118046A TWI597389B (en) | 2016-06-07 | 2016-06-07 | Electrolysis Device |
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| Publication Number | Publication Date |
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| TW201742955A TW201742955A (en) | 2017-12-16 |
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| CN110902767A (en) * | 2019-08-06 | 2020-03-24 | 无锡小天鹅电器有限公司 | Electrolytic component and clothes treatment equipment |
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