TWI585190B - Nematic liquid crystal composition and liquid crystal display element using the same - Google Patents

Nematic liquid crystal composition and liquid crystal display element using the same Download PDF

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TWI585190B
TWI585190B TW101148564A TW101148564A TWI585190B TW I585190 B TWI585190 B TW I585190B TW 101148564 A TW101148564 A TW 101148564A TW 101148564 A TW101148564 A TW 101148564A TW I585190 B TWI585190 B TW I585190B
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liquid crystal
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carbon atoms
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TW201333172A (en
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栗山毅
須藤豪
平田真一
川上正太郎
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迪愛生股份有限公司
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Description

向列型液晶組成物及使用其之液晶顯示元件 Nematic liquid crystal composition and liquid crystal display element using same

本發明係關於作為液晶顯示材料而有效用之介電常數各向異性(△ε)顯示負值的向列型液晶組成物及使用其之液晶顯示元件。 The present invention relates to a nematic liquid crystal composition exhibiting a negative value of dielectric anisotropy (??) which is effective as a liquid crystal display material, and a liquid crystal display element using the same.

液晶顯示元件係使用於以時鐘、電子計算機為首之家庭用各種電器、測定機器、汽車用面板、文字處理器、電子記事本、印表機、電腦、電視等。作為液晶顯示方式，其代表者中可舉出TN(扭曲向列)型、STN(超扭曲向列)型、DS(動態光散射)型、GH(賓主(guest host))型、IPS(平面內切換)型、OCB(光學補償雙折射)型、ECB(電壓控制雙折射)型、VA(垂直配向)型、CSH(彩色超垂面(color super-homeotropic))型、或FLC(強介電性液晶)等。又，作為驅動方式亦可舉出靜態驅動、多工(multiplex)驅動、單純矩陣方式、藉由TFT(薄膜電晶體)或TFD(薄膜二極體)等所驅動的主動矩陣(AM)方式。 The liquid crystal display element is used in various household appliances, measurement equipment, automobile panels, word processors, electronic notebooks, printers, computers, televisions, and the like, which are clocks and electronic computers. Examples of the liquid crystal display method include a TN (twisted nematic) type, an STN (super twisted nematic) type, a DS (dynamic light scattering) type, a GH (guest host) type, and an IPS (plane). Internal switching) type, OCB (optical compensation birefringence) type, ECB (voltage controlled birefringence) type, VA (vertical alignment) type, CSH (color super-homeotropic) type, or FLC (strong Electrical liquid crystal) and the like. Further, examples of the driving method include static driving, multiplex driving, a simple matrix method, and an active matrix (AM) method driven by a TFT (Thin Film Transistor) or a TFD (Thin Film Diode).

在該等顯示方式中，IPS型、ECB型、VA型、或CSH型等具有使用△ε顯示負值之液晶材料的特徵。在該等之中特別是藉由AM驅動的VA型顯示方式，係使用於被要求高速且廣角的顯示元件、例如電視等的用途。 Among these display modes, the IPS type, the ECB type, the VA type, or the CSH type or the like has a feature of using a liquid crystal material having a negative value of Δ ε. Among these, the VA type display system driven by AM is used for applications requiring high-speed and wide-angle display elements such as televisions.

對於使用於VA型等之顯示方式的向列型液晶組成物，係被要求有低電壓驅動、高速應答及寬廣的動作溫度範圍。即，被要求△ε為負且絕對值大、低黏度、高的向列相-各向同性液體相轉移溫度(Tni)。又，必須從折射 率各向異性(refractivity anisotropy,△n)與晶胞間隙(cell gap,d)之乘積△n×d的設定，將液晶材料的△n調節於符合晶胞間隙的適當範圍內。此外當應用液晶顯示元件於電視等時，由於重視高速應答性，故要求黏度(η)低的液晶材料。 A nematic liquid crystal composition used for a display mode such as a VA type is required to have a low voltage drive, a high speed response, and a wide operating temperature range. That is, a nematic phase-isotropic liquid phase transition temperature (T ni ) which is required to have a negative Δ ε and a large absolute value and a low viscosity and a high viscosity is required. Further, it is necessary to adjust the Δn of the liquid crystal material to an appropriate range in accordance with the cell gap from the setting of the product of the refractive index anisotropy (Δn) and the cell gap (d) Δn×d. Inside. Further, when a liquid crystal display element is applied to a television or the like, a liquid crystal material having a low viscosity (η) is required because of high speed responsiveness.

迄今，藉由各種研究△ε為負且其絕對值大的化合物而改善液晶組成物的特性。 Heretofore, the characteristics of the liquid crystal composition have been improved by various compounds in which Δε is negative and its absolute value is large.

作為△ε為負的液晶材料，已揭示使用具有如下之2,3-二氟伸苯基骨架之液晶化合物(A)及(B)(參照專利文獻1)的液晶組成物。 As a liquid crystal material having a negative Δ ε, a liquid crystal composition using liquid crystal compounds (A) and (B) having the following 2,3-difluorophenylene skeleton (see Patent Document 1) has been disclosed.

該液晶組成物雖使用液晶化合物(C)及(D)作為△ε幾乎為0的化合物，但該液晶組成物係未能達成在液晶電視等之要求高速應答的液晶組成物中實現足夠低的黏性。 In the liquid crystal composition, the liquid crystal compounds (C) and (D) are used as a compound having a Δ ε of almost 0. However, the liquid crystal composition is not sufficiently low in a liquid crystal composition which requires a high-speed response such as a liquid crystal television. Sticky.

另外，在專利文獻2或專利文獻3中，雖亦已揭示使用具有被氟取代之聯三苯(terphenyl)結構之化合物的液晶組成物，但為了對應於快速之影像或3D影像，從現在起更加要求高速應答性能。此外，雖有發展配合用於改善應答之窄幅晶胞(narrow cell)對應品而使用之液晶組成物的高△n化，但亦產生在低溫之溶解性的問題，故尋 求即使在用於高速應答的低黏性與低溫下亦兼顧穩定穩定地保持液晶相之溶解性的液晶組成物。 Further, in Patent Document 2 or Patent Document 3, a liquid crystal composition using a compound having a terphenyl structure substituted by fluorine has been disclosed, but in order to correspond to a fast image or a 3D image, from now on More demand for high-speed response performance. In addition, although there has been a problem of high Δn formation of a liquid crystal composition used for improving a response of a narrow cell counterpart, it also causes a problem of solubility at a low temperature, so Even in the low viscosity and low temperature for high-speed response, a liquid crystal composition which stably and stably maintains the solubility of the liquid crystal phase is obtained.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特開平8-104869號 [Patent Document 1] Japanese Patent Laid-Open No. 8-104869

[專利文獻2]日本特開2003-327965號 [Patent Document 2] Japanese Patent Laid-Open No. 2003-327965

[專利文獻3]WO2007/077872 [Patent Document 3] WO2007/077872

本發明所欲解決之課題係在於提供具有寬廣溫度範圍之液晶相、黏性小、△ε為負且其絕對值大、在低溫下之溶解性佳的液晶組成物，進一步提供使用其之顯示品質優異的VA型或PSVA型等的液晶顯示元件。 The problem to be solved by the present invention is to provide a liquid crystal composition having a wide liquid crystal phase, a small viscosity, a negative Δ ε and a large absolute value, and a good solubility at a low temperature, and further providing a display using the same. A liquid crystal display element such as a VA type or a PSVA type excellent in quality.

本發明者研究各種液晶化合物，發現藉由組合特定的化合物而可解決前述課題，致完成本發明。 The inventors of the present invention have studied various liquid crystal compounds and found that the above problems can be solved by combining specific compounds, and the present invention has been completed.

本發明係提供含有1種或2種以上選自以通式(I)表示之化合物群組中的化合物作為第一成分，且含有1種或2種以上選自以通式(II)表示之化合物群組中的化合物作為第二成分的液晶組成物，再者，提供使用該液晶組成物的液晶顯示元件。 The present invention provides a compound containing one or more compounds selected from the group consisting of the compounds represented by the formula (I) as a first component, and one or more compounds selected from the group consisting of the formula (II) A compound in the compound group is used as a liquid crystal composition of the second component, and a liquid crystal display element using the liquid crystal composition is further provided.

(通式中，R11及R12各別獨立地表示碳原子數為1至10的烷 基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基；存在於R11及R12中之1個-CH2-或未相鄰之2個以上的-CH2-可各別獨立地被取代成-O-及/或-S-，又存在於R11及R12中之1個或2個以上的氫原子可各別獨立地被取代成氟原子或氯原子；p表示0或1。) (In the formula, R 11 and R 12 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or carbon atoms alkenyloxy having 2 to 10; in the presence of 12 1 -CH 2 R 11, and R - -CH above or adjacent two of the 2 - groups independently may be substituted with -O- And/or -S-, and one or more hydrogen atoms present in R 11 and R 12 may be independently substituted with a fluorine atom or a chlorine atom; p represents 0 or 1.

(通式中，R21及R22各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基；存在於R21及R22中之1個-CH2-或未相鄰之2個以上的-CH2-可各別獨立地被取代成-O-及/或-S-，又存在於R21及R22中之1個或2個以上的氫原子各可別獨立地被取代成氟原子或氯原子；環A、環B及環C雖各別獨立地表示1,4-伸苯基、2-氟-1,4-伸苯基、3-氟-1,4-伸苯基或2,3-二氟-1,4-伸苯基，但至少一個表示2,3-二氟-1,4-伸苯基)。 (In the formula, R 21 and R 22 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or carbon atoms alkenyloxy having 2 to 10; in the presence of a -CH 2 R 21 and R 22 in the - or more than two of the adjacent -CH 2 - groups independently may be substituted with -O- And/or -S-, and one or more hydrogen atoms which are present in R 21 and R 22 may be independently substituted with a fluorine atom or a chlorine atom; and ring A, ring B and ring C are each Also independently means 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,3-difluoro-1,4-phenylene , but at least one represents 2,3-difluoro-1,4-phenylene).

本發明之△ε為負的液晶組成物可獲得大幅降低的黏性，又，由於在低溫下的溶解性變好，製品的實用性高且使用其之VA型或PSVA型等的液晶顯示元件可達成高速應答，故可抑制顯示不佳而非常地有效用。 The liquid crystal composition having a negative Δ ε of the present invention can be remarkably reduced in viscosity, and the solubility at a low temperature is improved, the practicality of the product is high, and a liquid crystal display element such as a VA type or a PSVA type using the same is used. A high-speed response can be achieved, so that the display can be suppressed and used very effectively.

[實施發明之形態] [Formation of the Invention]

在本發明中的液晶組成物中，在使用作為第一成分 之以通式(I)表示的化合物中， In the liquid crystal composition of the present invention, in the compound represented by the general formula (I) as the first component,

R11及R12較佳為各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基(亦包含存在於該等基中之1個-CH2-或未相鄰之2個以上之-CH2-被取代成-O-及/或-S-者、或存在於該等基中之1個或2個以上之氫原子各別獨立地被取代成氟原子或氯原子者)，更佳為表示碳數為1至10的直鏈狀烷基、碳數為1至10的直鏈狀烷氧基或碳數為2至10的烯基，特佳為表示碳數為1至8之直鏈狀烷基或碳數為1至8的烷氧基；p表示0或1。在本案發明的液晶組成物中，雖含有1種或2種以通式(I)表示的化合物，但較佳為含有1種至5種；其含量較佳為5至70質量%，更佳為5至60質量%。 R 11 and R 12 preferably each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon number. alkenyloxy having 2 to 10 (these are also included in the present of a group -CH 2 - or more than two of the adjacent -CH 2 - is substituted with -O- and / or -S- by Or one or two or more hydrogen atoms present in the groups are independently substituted with a fluorine atom or a chlorine atom, and more preferably a linear alkyl group having a carbon number of 1 to 10, a linear alkoxy group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, particularly preferably a linear alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms Base; p represents 0 or 1. In the liquid crystal composition of the present invention, one or two kinds of compounds represented by the formula (I) are contained, but it is preferably one to five kinds; and the content thereof is preferably from 5 to 70% by mass, more preferably It is 5 to 60% by mass.

在使用作為第二成分之以通式(II)表示的化合物中， In the compound represented by the general formula (II) as the second component,

R21及R22較佳為各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基(亦包含存在於該等基中之1個-CH2-或未相鄰之2個以上之-CH2-被取代成-O-及/或-S-者、或存在於該等基中之1個或2個以上之氫原子被取代成氟原子或氯原子者)，更佳為表示碳數為1 至10之直鏈狀烷基、碳數為1至10之直鏈狀烷氧基或碳數為2至10之烯基，特佳為表示碳數為1至8之直鏈狀烷基或碳數為1至8之烷氧基；環A、環B及環C雖各別獨立地表示1,4-伸苯基、2-氟-1,4-伸苯基、3-氟-1,4-伸苯基或2,3-二氟-1,4-伸苯基，但至少一個表示2,3-二氟-1,4-伸苯基。 R 21 and R 22 preferably each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon number. alkenyloxy having 2 to 10 (these are also included in the present of a group -CH 2 - or more than two of the adjacent -CH 2 - is substituted with -O- and / or -S- by Or one or two or more hydrogen atoms present in the group are substituted with a fluorine atom or a chlorine atom, and more preferably a linear alkyl group having a carbon number of 1 to 10 and a carbon number of 1 a linear alkoxy group to 10 or an alkenyl group having 2 to 10 carbon atoms, particularly preferably a linear alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; And ring B and ring C each independently represent 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,3-difluoro -1,4-phenylene, but at least one represents 2,3-difluoro-1,4-phenylene.

以通式(II)表示之化合物，更具體而言，較佳為下述以通式(II-A)至通式(II-H)表示的化合物。 The compound represented by the formula (II), more specifically, the compound represented by the following formula (II-A) to the formula (II-H) is preferred.

(通式中，R21及R22各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基，存在於R21及R22中之1個-CH2-或未相鄰之2個以上之-CH2-可各別獨立地被取代成-O-及/或-S-，又存在於R21及R22中之1個或2個以上之氫原子可各別獨立地被取代成氟原子或氯原子。) (In the formula, R 21 and R 22 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or carbon The alkenyloxy group having an atomic number of 2 to 10, one of -CH 2 - or two or more of -CH 2 - present in R 21 and R 22 may be independently substituted into -O- And/or -S-, and one or more hydrogen atoms which are present in R 21 and R 22 may be independently substituted into a fluorine atom or a chlorine atom.)

以通式(II-A)至通式(II-H)表示的化合物中，更佳為通式(II-A)、通式(II-B)、通式(II-C)、通式(II-E)、通式(II-F)、通式(II-G)。 Among the compounds represented by the formula (II-A) to the formula (II-H), more preferably the formula (II-A), the formula (II-B), the formula (II-C), and the formula (II-E), general formula (II-F), and general formula (II-G).

在本案發明中雖含有至少一種以通式(II)表示的化合物，但較佳為含有1種至10種，特佳為含有1種至8種，其含量較佳為2至30質量%，更佳為2至20質量%。 In the present invention, at least one compound represented by the formula (II) is contained, but it is preferably one to ten, particularly preferably one to eight, and the content thereof is preferably from 2 to 30% by mass. More preferably 2 to 20% by mass.

本案發明的液晶組成物雖可進一步含有1種或2種以上選自以通式(III-A)至通式(III-J)表示之化合物群組的化合物作為第三成分， The liquid crystal composition of the present invention may further contain one or more compounds selected from the group consisting of compounds represented by the general formulae (III-A) to (III-J) as a third component.

但更佳為含有2種至10種選自通式(III-A)、(III-D)、(III-F)、(III-G)及(III-H)的化合物。且，R31及R32雖各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基，但較佳為碳原子數為1至10的烷基、碳原子數為1至10的烷氧基或碳原子數為2至10的烯基，更佳為碳原子數1至5的烷基、碳原子數為1至5的烷氧基或碳原子數為2至5的烯基。 More preferably, it contains 2 to 10 compounds selected from the group consisting of the formulae (III-A), (III-D), (III-F), (III-G) and (III-H). Further, R 31 and R 32 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon number. Is an alkenyloxy group of 2 to 10, preferably an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, more preferably An alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms.

在本案發明中以通式(III)表示之化合物的含量係以10至90質量%為佳，較佳為20至80質量%，更佳為25至70質量%，特佳為30至65質量%。 The content of the compound represented by the formula (III) in the invention of the present invention is preferably from 10 to 90% by mass, preferably from 20 to 80% by mass, more preferably from 25 to 70% by mass, particularly preferably from 30 to 65% by mass. %.

本案發明的液晶組成物較佳為同時含有以通式(I)表示之化合物、以通式(II)表示之化合物、及選自以通式(III-A)至通式(III-J)表示之化合物群組的化合物，更佳為同時含有通式(I)、通式(II)及通式(III-A)。 The liquid crystal composition of the present invention preferably contains a compound represented by the formula (I), a compound represented by the formula (II), and a compound of the formula (III-A) to (III-J). The compound represented by the group of compounds preferably further contains the formula (I), the formula (II) and the formula (III-A).

本案發明的液晶組成物雖然在25℃的△ε為-2.0至-6.0，但較佳為-2.5至-5.5，特佳為-2.5至-5.0。在25℃的△n雖為0.08至0.13，但較佳為0.09至0.13，特佳為0.09至0.12。若更詳細說明，當對應於薄的晶胞間隙時，較佳為0.10至0.13，當對應厚的晶胞間隙時，較佳為0.08至0.10。在20℃的η雖為10至30mPa‧s，但較佳為10至25mPa‧s，特佳為10至20mPa‧s。Tni雖為60℃至120℃，但較佳為70℃至100℃，特佳為70℃至85℃。 The liquid crystal composition of the present invention has a Δ ε at 25 ° C of -2.0 to -6.0, preferably -2.5 to -5.5, particularly preferably -2.5 to -5.0. Although Δn at 25 ° C is from 0.08 to 0.13, it is preferably from 0.09 to 0.13, particularly preferably from 0.09 to 0.12. More specifically, when it corresponds to a thin cell gap, it is preferably 0.10 to 0.13, and when it corresponds to a thick cell gap, it is preferably 0.08 to 0.10. Although η at 20 ° C is 10 to 30 mPa ‧ s, it is preferably 10 to 25 mPa ‧ s, and particularly preferably 10 to 20 mPa ‧ s. Although T ni is from 60 ° C to 120 ° C, it is preferably from 70 ° C to 100 ° C, particularly preferably from 70 ° C to 85 ° C.

本案發明的液晶組成物在除了上述的化合物以外，亦可含有通常之向列型液晶、層列型(smectic)液晶、膽固醇型(cholesteric)液晶、抗氧化劑、紫外線吸收劑、聚合性單體等。 The liquid crystal composition of the present invention may contain, in addition to the above-mentioned compounds, a normal nematic liquid crystal, a smectic liquid crystal, a cholesteric liquid crystal, an antioxidant, an ultraviolet absorber, a polymerizable monomer, or the like. .

在本案發明的液晶組成物中，為了提升其保存穩定性，亦可添加穩定劑。作為可使用的穩定劑，可列舉例如氫醌類、氫醌一烷基醚類、第三丁基兒茶酚類、五倍子酚類、苯硫酚類、硝基化合物類、β-萘胺類、β-萘酚類、亞硝基化合物等。 In the liquid crystal composition of the present invention, in order to improve the storage stability, a stabilizer may be added. Examples of stabilizers that can be used include hydroquinones, hydroquinone monoalkyl ethers, tert-butylcatechols, gallic phenols, thiophenols, nitro compounds, and β-naphthylamines. , β-naphthols, nitroso compounds, and the like.

在本案發明的液晶組成物中，為了製作PS模式、PSA模式或PSVA模式等的液晶顯示元件，可含有聚合性化合物。作為可使用之聚合性化合物，可舉出以光等之能量線進行聚合的光聚合性單體等，作為結構，可列舉例如 聯苯衍生物、聯三苯衍生物等之具有六環複數連結之液晶骨架的聚合性化合物等。更具體而言，較佳為以通式(IV)表示的化合物。 In the liquid crystal composition of the present invention, a polymerizable compound may be contained in order to produce a liquid crystal display element such as a PS mode, a PSA mode or a PSVA mode. Examples of the polymerizable compound that can be used include a photopolymerizable monomer which is polymerized by an energy ray such as light, and examples of the structure include, for example, a structure. A polymerizable compound having a six-ring complex-bonded liquid crystal skeleton such as a biphenyl derivative or a terphenyl derivative. More specifically, a compound represented by the formula (IV) is preferred.

(通式中，R41及R42各別獨立地表示以下的通式(R-1)至通式(R-15)之任意者， (In the formula, R 41 and R 42 each independently represent any of the following formula (R-1) to formula (R-15),

X1至X12各別獨立地表示三氟甲基、三氟甲氧基、氟原子、氫原子或碳原子數為1至3的烷基，S1及S2係互相獨立地表示碳原子數為1至8的伸烷基或單鍵，該伸烷基中的1個-CH2-或未相鄰的2個以上之-CH2-可被取代成-O-、-COO-、-OCO-或-OCOO-，q表示0或1。) X 1 to X 12 each independently represent a trifluoromethyl group, a trifluoromethoxy group, a fluorine atom, a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and S 1 and S 2 each independently represent a carbon atom. a number of 1 to 8 alkyl or single bonds, one of -CH 2 - or two or more of -CH 2 - which are not adjacent to each other may be substituted into -O-, -COO-, -OCO- or -OCOO-, q means 0 or 1. )

再者，化合物中之R41及R42較佳為互相獨立地為通式(R-1)或(R-2)，X1至X12較佳為各別獨立地為氟原子、氫原子或甲基，S1及S2較佳為互相獨立地為碳原子數為1至4的伸烷基、烷氧伸(alkoxylene)基或單鍵，S1及S2更佳為各別係單鍵。 Further, R 41 and R 42 in the compound are preferably each independently of the formula (R-1) or (R-2), and X 1 to X 12 are preferably independently a fluorine atom or a hydrogen atom. Or a methyl group, S 1 and S 2 are preferably independently an alkylene group having an alkyl group of 1 to 4, an alkoxy group or a single bond, and S 1 and S 2 are more preferably each other. single bond.

較佳為含有1種或2種以上之聚合性化合物，該含量較佳為0.01質量%至2質量%。 It is preferred to contain one or two or more kinds of polymerizable compounds, and the content is preferably from 0.01% by mass to 2% by mass.

含有上述聚合性化合物的液晶組成物，即使在不存在聚合起始劑的情況下亦進行聚合，但為了促進聚合，亦可含有聚合起始劑。作為聚合起始劑，可舉出安息香醚類、二苯基酮類、苯乙酮類、芐基縮酮類、氧化醯基膦(acyl phosphine oxide)類等。 The liquid crystal composition containing the above polymerizable compound is polymerized even in the absence of a polymerization initiator, but may contain a polymerization initiator in order to promote polymerization. Examples of the polymerization initiator include benzoin ethers, diphenyl ketones, acetophenones, benzyl ketals, and acyl phosphine oxides.

使用本發明之液晶組成物的液晶顯示元件係兼具高速應答與抑制顯示不佳的有效用者，特別是有效用於主動矩陣驅動用液晶顯示元件，可適用於VA模式、PSVA模式、PSA模式、IPS模式或ECB模式用。 The liquid crystal display element using the liquid crystal composition of the present invention is effective for both high-speed response and suppression of display, and is particularly effective for active matrix drive liquid crystal display elements, and is applicable to VA mode, PSVA mode, and PSA mode. , IPS mode or ECB mode.

[實施例] [Examples]

以下雖舉出實施例而更詳細地說明本發明，但本發明係不受該等實施例所限制。又，在以下之實施例及比較例之組成物中的「%]係意味著『質量%』。 The present invention is described in more detail below by way of examples, but the invention is not limited by the examples. Moreover, "%" in the composition of the following examples and comparative examples means "% by mass".

實施例中，所測定之特性係如下。 In the examples, the properties measured were as follows.

Tni：向列相-各向同性液體相轉移溫度(℃) T ni : nematic phase-isotropic liquid phase transfer temperature (°C)

△n：在25℃之折射率各向異性 △n: refractive index anisotropy at 25 ° C

△ε：在25℃之介電常數各向異性 △ ε: dielectric anisotropy at 25 ° C

η：在20℃之黏度(mPa‧s) η: viscosity at 20 ° C (mPa ‧ s)

(實施例1) (Example 1)

以下顯示所調製之液晶組成物與其物性值。 The liquid crystal composition prepared and its physical property values are shown below.

顯示於實施例1之向列型液晶組成物的物性值為Tni：75.6℃、△n：0.116、△ε：-2.8、η：15.3mPa‧s。又，測定使用本液晶組成物之液晶顯示元件的應答速度時，其為7.6msec。再者，測定電壓保持率(VHR)，則可確認具有高VHR。且，晶胞厚度為3.5μm、垂直配向膜為JALS2096，應答速度的測定條件係Von為5.5V、Voff為1.0V、測定溫度為20℃，使用AUTRONIC-MELCHERS公 司的DMS301。VHR的測定條件係電壓為5V、頻率為60Hz、溫度為60℃，使用TOYO Technica股份有限公司的VHR-1。 The physical properties of the nematic liquid crystal composition shown in Example 1 were T ni : 75.6 ° C, Δn: 0.116, Δ ε: -2.8, and η: 15.3 mPa ‧ s. Further, when the response speed of the liquid crystal display element using the liquid crystal composition was measured, it was 7.6 msec. Further, when the voltage holding ratio (VHR) was measured, it was confirmed that the voltage VHR was high. Further, the cell thickness was 3.5 μm, the vertical alignment film was JALS 2096, and the response rate was measured by Von of 5.5 V, Voff of 1.0 V, and measurement temperature of 20 ° C, and DMS301 of AUTRONIC-MELCHERS Co., Ltd. was used. The measurement conditions of VHR were a voltage of 5 V, a frequency of 60 Hz, and a temperature of 60 ° C, and VHR-1 of TOYO Technica Co., Ltd. was used.

又，即使改變晶胞注入的條件(壓力及ODF法)亦未發現物性值變化，為無散亂、均一且顯示品質良好者。 Further, even if the conditions for the cell injection (pressure and ODF method) were changed, no change in the physical property value was observed, and there was no disorder, uniformity, and good display quality.

(比較例1) (Comparative Example 1)

以下顯示所調製之液晶組成物及其物性值。 The liquid crystal composition prepared and its physical property values are shown below.

顯示於比較例1的向列型液晶組成物係不包含本發明之通式(I)，為Tni：76.0℃、△n：0.117、△ε：-2.9、η：18.5mPa‧s。當不使用以通式(I)表示之化合物而調整成與實施例1同樣的Tni、△n、△ε時，黏度變得比實施例1 高。又，測定使用本液晶組成物之液晶顯示元件的應答速度時，其為10.1msec。 The nematic liquid crystal composition shown in Comparative Example 1 does not contain the general formula (I) of the present invention and has T ni : 76.0 ° C, Δn: 0.117, Δ ε: -2.9, and η: 18.5 mPa ‧ s. When Tni , Δn, and Δε similar to those in Example 1 were used without using the compound represented by the formula (I), the viscosity was higher than that of Example 1. Further, when the response speed of the liquid crystal display element using the liquid crystal composition was measured, it was 10.1 msec.

(比較例2) (Comparative Example 2)

相較於比較例1中顯示不使用以通式(I)表示之化合物的液晶組成物之事例，調製不使用以通式(II)表示之化合物的液晶組成物。 The liquid crystal composition of the compound represented by the general formula (II) was not prepared as compared with the case where the liquid crystal composition of the compound represented by the general formula (I) was not used in Comparative Example 1.

其物性值為Tni：76.3℃、△n：0.119、△ε：-2.8、η：17.8mPa‧s。當不使用以通式(II)表示之化合物而調整成與實施例1同樣的Tni、△n、△ε時，黏度變得比實施例1高。 The physical property values were T ni : 76.3 ° C, Δn: 0.119, Δ ε: -2.8, and η: 17.8 mPa ‧ s. When Tni , Δn, and Δε similar to those in Example 1 were used without using the compound represented by the formula (II), the viscosity was higher than that of Example 1.

藉此得知含有如本案發明之以通式(I)及通式(II)表示之化合物的液晶組成物可改善η。 From this, it is understood that the liquid crystal composition containing the compound represented by the general formula (I) and the general formula (II) according to the present invention can improve η.

再者，進行實施例1、比較例1及比較例2之低溫保存測試時，相對於在-30℃及-20℃下實施例1可維持向列型狀態2週，比較例1及比較例2則僅1週而無法維持向列型狀態，在第2週時則確認析出。因此，可確認實施例1在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 Further, in the low-temperature storage test of Example 1, Comparative Example 1, and Comparative Example 2, the nematic state was maintained for 2 weeks with respect to Example 1 at -30 ° C and -20 ° C, and Comparative Example 1 and Comparative Example In 2, the nematic type state could not be maintained for only one week, and the precipitation was confirmed on the second week. Therefore, it was confirmed that Example 1 maintains a nematic state over a wide temperature range, and can be a very practical liquid crystal composition when used.

(實施例2) (Example 2)

以下顯示所調製之液晶組成物及其物性值。 The liquid crystal composition prepared and its physical property values are shown below.

顯示於實施例2之向列型液晶組成物的物性值為Tni：78.1℃、△n：0.104、△ε：-2.9、η：15.5mPa‧s。該液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The physical properties of the nematic liquid crystal composition shown in Example 2 were T ni : 78.1 ° C, Δn: 0.104, Δ ε: -2.9, and η: 15.5 mPa ‧ s. The liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

(實施例3) (Example 3)

以下顯示所調製之液晶組成物及其物性值。 The liquid crystal composition prepared and its physical property values are shown below.

顯示於實施例3之向列型液晶組成物的物性值為Tni：76.9℃、△n：0.098、△ε：-3.0、η：14.7mPa‧s。該液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The physical properties of the nematic liquid crystal composition shown in Example 3 were T ni : 76.9 ° C, Δn: 0.098, Δ ε: -3.0, and η: 14.7 mPa ‧ s. The liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

(實施例4) (Example 4)

以下顯示所調製之液晶組成物及其物性值。 The liquid crystal composition prepared and its physical property values are shown below.

顯示於實施例4之向列型液晶組成物的物性值為Tni：77.4℃、△n：0.100、△ε：-2.9、η：14.9mPa‧s。該液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The physical properties of the nematic liquid crystal composition shown in Example 4 were T ni : 77.4 ° C, Δn: 0.100, Δ ε: -2.9, and η: 14.9 mPa ‧ s. The liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

(實施例5) (Example 5)

藉由相對於99.7%之顯示於實施例1的向列型液晶組成物，添加0.3%之以通式(IV-a)表示的聚合性化合物並 使其均勻溶解而調製聚合性液晶組成物CLC-1。 By adding 0.3% of the polymerizable compound represented by the general formula (IV-a) with respect to 99.7% of the nematic liquid crystal composition shown in Example 1 The polymerizable liquid crystal composition CLC-1 was prepared by uniformly dissolving it.

CLC-1的物性係與顯示於實施例1之向列型液晶組成物的物性大致相同。以真空注入法將CLC-1注入晶胞間隙為3.5μm且已塗布有誘發垂面(homeotropic)配向之聚醯亞胺配向膜之附有ITO的晶胞。測定該晶胞的預傾角(晶體旋轉法)後，以頻率為1kHz施加1.8V的矩形波，同時經由隔絕320nm以下紫外線的濾光片，以高壓水銀燈照射紫外線於晶胞。將晶胞表面的照射強度調整為10mW/cm2並照射600秒，獲得已將聚合性液晶組成物中的聚合性化合物聚合的垂直配向性液晶顯示元件。藉由聚合性化合物之聚合，可確認已產生對於液晶化合物之配向強制力。又，可確認垂直配向性液晶顯示元件具有優異的光學特性及高速應答性。 The physical properties of CLC-1 are substantially the same as those of the nematic liquid crystal composition shown in Example 1. CLC-1 was injected into the cell gap with a cell gap of 3.5 μm by vacuum injection and coated with a ITO-attached cell of a polyimide-aligned polyimide film. After measuring the pretilt angle of the unit cell (crystal rotation method), a rectangular wave of 1.8 V was applied at a frequency of 1 kHz, and ultraviolet rays were irradiated to the unit cell by a high pressure mercury lamp through a filter that shields ultraviolet rays of 320 nm or less. The irradiation intensity of the surface of the unit cell was adjusted to 10 mW/cm 2 and irradiated for 600 seconds to obtain a vertical alignment liquid crystal display element in which the polymerizable compound in the polymerizable liquid crystal composition was polymerized. By the polymerization of the polymerizable compound, it was confirmed that the alignment force for the liquid crystal compound was generated. Further, it was confirmed that the vertical alignment liquid crystal display element has excellent optical characteristics and high-speed response.

該聚合性液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The polymerizable liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

(實施例6) (Example 6)

藉由相對於99.7%之顯示於實施例2的向列型液晶組成物，添加0.3%之以通式(IV-b)表示的聚合性化合物並使其均勻溶解而調製聚合性液晶組成物CLC-2。 The polymerizable liquid crystal composition CLC was prepared by adding 0.3% of the polymerizable compound represented by the formula (IV-b) to the nematic liquid crystal composition of Example 2, and uniformly dissolving it. -2.

CLC-2的物性係與顯示於實施例1之向列型液晶組 成物的物性大致相同。以真空注入法將CLC-2注入晶胞間隙為3.5μm且已塗布有誘發垂面配向之聚醯亞胺配向膜之附有ITO的晶胞。測定該晶胞的預傾角(晶體旋轉法)後，以頻率為1kHz施加1.8V的矩形波，同時經由隔絕320nm以下紫外線的濾光片，以高壓水銀燈照射紫外線於晶胞。將晶胞表面的照射強度調整為10mW/cm2並照射600秒，獲得已將聚合性液晶組成物中的聚合性化合物聚合的垂直配向性液晶顯示元件。藉由聚合性化合物之聚合，可確認已產生對於液晶化合物之配向強制力。又，可確認垂直配向性液晶顯示元件具有優異的光學特性及高速應答性。 The physical properties of CLC-2 were substantially the same as those of the nematic liquid crystal composition shown in Example 1. The CLC-2 was injected into the cell gap with a cell gap of 3.5 μm by a vacuum injection method and coated with an ITO-attached unit cell which induces a vertical alignment of the polyimide film. After measuring the pretilt angle of the unit cell (crystal rotation method), a rectangular wave of 1.8 V was applied at a frequency of 1 kHz, and ultraviolet rays were irradiated to the unit cell by a high pressure mercury lamp through a filter that shields ultraviolet rays of 320 nm or less. The irradiation intensity of the surface of the unit cell was adjusted to 10 mW/cm 2 and irradiated for 600 seconds to obtain a vertical alignment liquid crystal display element in which the polymerizable compound in the polymerizable liquid crystal composition was polymerized. By the polymerization of the polymerizable compound, it was confirmed that the alignment force for the liquid crystal compound was generated. Further, it was confirmed that the vertical alignment liquid crystal display element has excellent optical characteristics and high-speed response.

該聚合性液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The polymerizable liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

(實施例7) (Example 7)

藉由相對於99.7%之顯示於實施例2的向列型液晶組成物，添加0.3%之以通式(IV-c)表示的聚合性化合物並均勻溶解而調製聚合性液晶組成物CLC-3。 The polymerizable liquid crystal composition CLC-3 was prepared by adding 0.3% of the polymerizable compound represented by the general formula (IV-c) to 99.7% of the nematic liquid crystal composition shown in Example 2 and uniformly dissolving it. .

CLC-3的物性係與顯示於實施例1之向列型液晶組成物的物性大致相同。以真空注入法將CLC-3注入晶胞間隙為3.5μm且已塗布有誘發垂面配向之聚醯亞胺配向膜之附有ITO的晶胞。測定該晶胞的預傾角(晶體旋轉法)後，以頻率為1kHz施加1.8V的矩形波，同時經由隔絕 320nm以下紫外線的濾光片，以高壓水銀燈照射紫外線於晶胞。將晶胞表面的照射強度調整為10mW/cm2並照射600秒，獲得已將聚合性液晶組成物中的聚合性化合物聚合的垂直配向性液晶顯示元件。藉由聚合性化合物之聚合，可確認已產生對於液晶化合物之配向強制力。又，可確認垂直配向性液晶顯示元件具有優異的光學特性及高速應答性。 The physical properties of CLC-3 were substantially the same as those of the nematic liquid crystal composition shown in Example 1. CLC-3 was injected into the cell gap with a cell gap of 3.5 μm by a vacuum injection method and coated with a ITO-attached cell of a polyimide film which induces a vertical alignment. After measuring the pretilt angle of the unit cell (crystal rotation method), a rectangular wave of 1.8 V was applied at a frequency of 1 kHz, and ultraviolet rays were irradiated to the unit cell by a high pressure mercury lamp through a filter that shields ultraviolet rays of 320 nm or less. The irradiation intensity of the surface of the unit cell was adjusted to 10 mW/cm 2 and irradiated for 600 seconds to obtain a vertical alignment liquid crystal display element in which the polymerizable compound in the polymerizable liquid crystal composition was polymerized. By the polymerization of the polymerizable compound, it was confirmed that the alignment force for the liquid crystal compound was generated. Further, it was confirmed that the vertical alignment liquid crystal display element has excellent optical characteristics and high-speed response.

該聚合性液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The polymerizable liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

(實施例8) (Example 8)

藉由相對於99.7%之顯示於實施例2的向列型液晶組成物，添加0.3%之以通式(IV-d)表示的聚合性化合物並均勻溶解而調製聚合性液晶組成物CLC-4。 The polymerizable liquid crystal composition CLC-4 was prepared by adding 0.3% of the polymerizable compound represented by the general formula (IV-d) to 99.7% of the nematic liquid crystal composition shown in Example 2 and uniformly dissolving it. .

CLC-4的物性係與顯示於實施例1之向列型液晶組成物的物性大致相同。以真空注入法將CLC-4注入晶胞間隙為3.5μm且已塗布有誘發垂面配向之聚醯亞胺配向膜之附有ITO的晶胞。測定該晶胞的預傾角(晶體旋轉法)後，以頻率為1kHz施加1.8V的矩形波，同時經由隔絕320nm以下紫外線的濾光片，以高壓水銀燈照射紫外線於晶胞。將晶胞表面的照射強度調整為10mW/cm2並照射600秒，獲得已將聚合性液晶組成物中的聚合性化合物聚合的垂直配向性液晶顯示元件。藉由將聚合性化合物進 行聚合，可確認已產生對於液晶化合物之配向強制力。又，可確認垂直配向性液晶顯示元件具有優異的光學特性及高速應答性。 The physical properties of CLC-4 were substantially the same as those of the nematic liquid crystal composition shown in Example 1. The CLC-4 was injected into the cell gap with a cell gap of 3.5 μm by a vacuum injection method and coated with a ITO-attached cell of a polyimide film which induces a vertical alignment. After measuring the pretilt angle of the unit cell (crystal rotation method), a rectangular wave of 1.8 V was applied at a frequency of 1 kHz, and ultraviolet rays were irradiated to the unit cell by a high pressure mercury lamp through a filter that shields ultraviolet rays of 320 nm or less. The irradiation intensity of the surface of the unit cell was adjusted to 10 mW/cm 2 and irradiated for 600 seconds to obtain a vertical alignment liquid crystal display element in which the polymerizable compound in the polymerizable liquid crystal composition was polymerized. By polymerizing the polymerizable compound, it was confirmed that the alignment force for the liquid crystal compound was generated. Further, it was confirmed that the vertical alignment liquid crystal display element has excellent optical characteristics and high-speed response.

該聚合性液晶組成物在-30℃及-20℃下維持向列型狀態2週。因此，可確認在寬廣的溫度範圍下維持向列型狀態，當使用時可為非常實用的液晶組成物。 The polymerizable liquid crystal composition was maintained in a nematic state at -30 ° C and -20 ° C for 2 weeks. Therefore, it was confirmed that the nematic state was maintained over a wide temperature range, and it was a very practical liquid crystal composition when used.

Claims (12)

一種液晶組成物，其含有1種或2種以上選自以通式(I-1)表示之化合物群組中的化合物作為第一成分，含有1種或2種以上選自以通式(II-A)、通式(II-E)表示之化合物群組中的化合物作為第二成分，且含有以通式(III-A)表示之化合物、與1種或2種以上從包含以通式(III-F)及通式(III-H)表示之化合物的群組中所選出者作為第三成分， (式中，R11及R12各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基；p表示1)， (式中，R21及R22各別獨立地表示碳原子數為1至10的烷基或碳原子數為1至10的烷氧基)， (上述式中，R31及R32中之任一者係碳原子數為1至10的烷基，另一者表示碳原子數為2的烯基)， (式中，R31及R32各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基)，其中不包括下述化合物， (式中，R3及R4獨立為碳數1至12烷基、碳數1至12烷氧基、碳數2至12烯基、碳數2至11烯氧基、或任意氫被氟取代的碳數2至12烯基；環A及環B獨立為1,4-伸環己基、1,4-伸苯基、2-氟-1,4-伸苯基、3-氟-1,4-伸苯基或四氫吡喃-2,5-二基；Z1及Z2獨立為單鍵、伸乙基、亞甲氧基或羰氧基；k及m獨立為0、1或2，且k與m之和在3以下)。 A liquid crystal composition containing one or more compounds selected from the group consisting of the compounds represented by the formula (I-1) as a first component, and one or more selected from the group consisting of the formula (II) -A), a compound represented by the formula (II-E) as a second component, and a compound represented by the formula (III-A), and one or more compounds from the formula The selected one of (III-F) and the compound represented by the general formula (III-H) is selected as the third component. (wherein R 11 and R 12 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon atom; a number of 2 to 10 alkenyloxy groups; p represents 1), (wherein R 21 and R 22 each independently represent an alkyl group having 1 to 10 carbon atoms or an alkoxy group having 1 to 10 carbon atoms), (In the above formula, any one of R 31 and R 32 is an alkyl group having 1 to 10 carbon atoms, and the other represents an alkenyl group having 2 carbon atoms), (wherein R 31 and R 32 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon atom; a number of 2 to 10 alkenyloxy groups, which do not include the following compounds, (wherein R 3 and R 4 are independently a C 1 to 12 alkyl group, a C 1 to 12 alkoxy group, a C 2 to 12 alkenyl group, a C 2 to 11 alkenyloxy group, or an arbitrary hydrogen group. Substituted carbon number 2 to 12 alkenyl; ring A and ring B are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1 , 4-phenylene or tetrahydropyran-2,5-diyl; Z 1 and Z 2 are independently a single bond, an extended ethyl group, a methyleneoxy group or a carbonyloxy group; k and m are independently 0, 1 Or 2, and the sum of k and m is 3 or less). 如申請專利範圍第1項之液晶組成物，其中第一成分的含量為5至60質量%，第二成分的含量為2至30質量%。 The liquid crystal composition of claim 1, wherein the content of the first component is 5 to 60% by mass, and the content of the second component is 2 to 30% by mass. 如申請專利範圍第1或2項之液晶組成物，其中含有1種或2種以上選自以通式(I-2)表示之化合物群組中的化合物作為該第一成分， (式中，R11及R12各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基；p表示0)。 The liquid crystal composition according to claim 1 or 2, which contains one or more compounds selected from the group consisting of compounds represented by the general formula (I-2) as the first component, (wherein R 11 and R 12 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon atom; The number is an alkenyloxy group of 2 to 10; p represents 0). 如申請專利範圍第1或2項之液晶組成物，其中進一步含有1種或2種以上選自以通式(III-B)、通式(III-C)、通式(III-D)、通式(III-E)、通式(III-G)、通式(III-I)及通式(III-J)表示之化合物群組的化合物作為第三成分， (式中，R31及R32各別獨立地表示碳原子數為1至10的烷基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基)。 The liquid crystal composition according to claim 1 or 2, wherein one or more of them are selected from the group consisting of the formula (III-B), the formula (III-C), and the formula (III-D). a compound of the group of compounds represented by the formula (III-E), the formula (III-G), the formula (III-I) and the formula (III-J) as a third component, (wherein R 31 and R 32 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon atom; The number 2 to 10 of the alkenyloxy group). 如申請專利範圍第4項之液晶組成物，其中進一步含有1種或2種以上選自以式(III-A’)表示之化合物群組的化合物作為第三成分， (式中，R31及R32各別獨立地表示碳原子數為1至10的烷 基、碳原子數為1至10的烷氧基、碳原子數為2至10的烯基或碳原子數為2至10的烯氧基)。 The liquid crystal composition of claim 4, further comprising one or more compounds selected from the group consisting of compounds represented by formula (III-A') as a third component, (wherein R 31 and R 32 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or a carbon atom; The number 2 to 10 of the alkenyloxy group). 如申請專利範圍第1或2項之液晶組成物，其中第三成分的含量為10至90質量%。 The liquid crystal composition according to claim 1 or 2, wherein the content of the third component is from 10 to 90% by mass. 如申請專利範圍第1或2項之液晶組成物，其中在25℃之介電常數各向異性△ε為-2.0至-6.0的範圍，在25℃之折射率各向異性△n為0.08至0.13的範圍，向列型相-各向同性液體相轉移溫度(Tni)為60℃至120℃的範圍。 The liquid crystal composition according to claim 1 or 2, wherein the dielectric anisotropy Δ ε at 25 ° C is in the range of -2.0 to -6.0, and the refractive index anisotropy Δn at 25 ° C is 0.08 to In the range of 0.13, the nematic phase-isotropic liquid phase transition temperature (T ni ) is in the range of 60 ° C to 120 ° C. 如申請專利範圍第1或2項之液晶組成物，其中含有聚合性化合物。 A liquid crystal composition according to claim 1 or 2, which contains a polymerizable compound. 如申請專利範圍第8項之液晶組成物，其中聚合性化合物為以通式(IV)表示之化合物， (式中，R41及R42各別獨立地表示下述通式(R-1)至式(R-15)的任意者， X1至X12各別獨立地表示三氟甲基、三氟甲氧基、 氟原子、氫原子或碳原子數為1至3的烷基，q表示0或1)。 The liquid crystal composition of claim 8, wherein the polymerizable compound is a compound represented by the formula (IV), (wherein R 41 and R 42 each independently represent any of the following formulas (R-1) to (R-15), X 1 to X 12 each independently represent a trifluoromethyl group, a trifluoromethoxy group, a fluorine atom, a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and q represents 0 or 1). 一種液晶顯示元件，其使用如申請專利範圍第1至9項中任一項之液晶組成物。 A liquid crystal display element using the liquid crystal composition according to any one of claims 1 to 9. 一種主動矩陣驅動用液晶顯示元件，其使用如申請專利範圍第1至9項中任一項之液晶組成物。 A liquid crystal display element for active matrix driving, which uses the liquid crystal composition according to any one of claims 1 to 9. 一種VA模式、PSA模式、PSVA模式、IPS模式或ECB模式用液晶顯示元件，其使用如申請專利範圍第1至9項中任一項之液晶組成物。 A liquid crystal display element for a VA mode, a PSA mode, a PSVA mode, an IPS mode, or an ECB mode, which uses the liquid crystal composition according to any one of claims 1 to 9.
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