TWI558879B - Synthetic paper manufacturing method and the synthetic paper system Caused by type device - Google Patents

Synthetic paper manufacturing method and the synthetic paper system Caused by type device Download PDF

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TWI558879B
TWI558879B TW103142054A TW103142054A TWI558879B TW I558879 B TWI558879 B TW I558879B TW 103142054 A TW103142054 A TW 103142054A TW 103142054 A TW103142054 A TW 103142054A TW I558879 B TWI558879 B TW I558879B
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composition
unit
synthetic paper
sheet
stretching
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TW201621115A (en
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geng-xian Lin
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合成紙之製造方法及該合成紙之製 造成型裝置 Method for producing synthetic paper and system for producing synthetic paper Causing device

本發明是有關於一種合成紙之製造方法,特別是指一種將一組合物板片使用一紅外線燈照射的合成紙製造成型裝置。 The present invention relates to a method for producing synthetic paper, and more particularly to a synthetic paper manufacturing and molding apparatus for irradiating a composition sheet with an infrared lamp.

二十世紀末期出現以聚烯烴為主要材料的合成紙,因其具備了紙張和塑料的兩種性能,具有比重輕、剛性佳等優點,可在許多特殊領域取代天然紙張,例如在印刷出版方面,合成紙可以印刷耐水報刊、書籍、地圖、日曆、卡片;在商業包裝方面,可用於製造禮品袋、西裝袋、購物袋、包裝容器盒,也可用於食品、藥品、化妝品的外包裝;而在建築方面,可用於做彩色貼面紙等。 At the end of the twentieth century, synthetic paper with polyolefin as the main material appeared. Because of its two properties of paper and plastic, it has the advantages of light weight and good rigidity, and can replace natural paper in many special fields, for example, in printing and publishing. Synthetic paper can print water-resistant newspapers, books, maps, calendars, cards; in commercial packaging, it can be used to make gift bags, suit bags, shopping bags, packaging containers, and also for the packaging of food, medicine, cosmetics; In terms of construction, it can be used as a color overlay paper.

合成紙發展至今主要生產方法有壓延法、流延法、吹膜法、雙向拉伸法。其中,壓延法是生產以PP為基材的合成紙,也就是通過配料、混料、在線密煉、擠出造料、開煉至壓延,最後再分切為合成紙產品。再以雙向拉伸法來說,其基材也是PP,且其原料混配與壓延法大致相同,差異在於使用雙向拉伸機的設備,而在雙向拉伸過程中,塑料的分子鏈縱橫分布比較一致,因此,合成紙縱橫向的物理機械性能也基本相同。 The main production methods of synthetic paper have been calendering, casting, blown film and biaxial stretching. Among them, the calendering method is to produce synthetic paper with PP as a base material, that is, by batching, mixing, in-line mixing, extrusion, materializing, rolling to calendering, and finally slitting into a synthetic paper product. In the biaxial stretching method, the substrate is also PP, and the raw material mixing and rolling method are substantially the same, the difference is the equipment using the biaxial stretching machine, and the molecular chain distribution of the plastic in the biaxial stretching process More consistent, therefore, the physical and mechanical properties of the synthetic paper in the vertical and horizontal directions are basically the same.

另外,基材塑料與填充料CaCO3之間會形成一些小間隙,從而降低了合成紙的比重及成本,而形成的小間隙與光產生折射作用,使得合成紙具有珠光效果,所以在包裝、印刷、廣告等領域得到了廣泛的應用。雖然雙向拉伸法合成紙的設備昂貴,且工藝與配方技術也較為 複雜,但其製品應用範圍是最廣泛的,從而成為目前的發展主流,因此,業者無不極研發,以滿足市場的的多元需求。 In addition, some small gaps are formed between the substrate plastic and the filler CaCO3, thereby reducing the specific gravity and cost of the synthetic paper, and the formed small gap and the light refraction, so that the synthetic paper has a pearlescent effect, so in packaging, printing , advertising and other fields have been widely used. Although the biaxial stretching method is expensive, the process and formulation techniques are relatively high. It is complex, but its range of products is the most extensive, and thus it has become the mainstream of current development. Therefore, the industry has no research and development to meet the diverse needs of the market.

參閱圖1,為中華民國發明第197686號專利「雙軸延伸聚丙烯珠光合成紙提升產量產速製造方法」,該專利案揭露一種提升珠光合成紙產量、產速的製造方法,是將均勻攪拌後之樹脂層或紙面層、發泡中間層、和樹脂層或紙面層組成之組合物配方,分別擠入押出機裝置11之T型模頭內,進行共擠壓成型而形成三層樹脂組合物,並由T型模頭之出口流道流出,再經由冷卻成型裝置12、縱向延伸裝置13、橫向延伸裝置14和電暈處理裝置15和捲取裝置16,而製成產量可提升一倍以上之具有三層結構之疊層珠光合成紙。 Referring to Fig. 1, a method for manufacturing a biaxially stretched polypropylene pearlescent synthetic paper to increase the yield and production speed is disclosed in the Patent No. 197686 of the Republic of China. The patent discloses a method for improving the yield and production rate of pearlescent synthetic paper, which is to uniformly agitate. The composition of the resin layer or the paper surface layer, the foaming intermediate layer, and the resin layer or the paper surface layer are respectively extruded into the T-die of the extruder device 11 to perform co-extrusion molding to form a three-layer resin combination. And output from the outlet flow path of the T-die, and then through the cooling forming device 12, the longitudinal stretching device 13, the lateral stretching device 14 and the corona treatment device 15 and the winding device 16, the production can be doubled The above laminated pearlescent synthetic paper having a three-layer structure.

經由以上之敘述,可知習知的雙軸延伸聚丙烯珠光合成紙提升產量產速製造方法於實際使用時仍然有以下的缺點產生: From the above description, it is known that the conventional biaxially stretched polypropylene pearlescent synthetic paper manufacturing method for increasing the yield and production speed still has the following disadvantages in practical use:

一、混料不均勻 First, the mixing is uneven

習知的組合物配方僅利用押出機裝置11進行攪拌與混鍊後,即透過冷卻成型裝置12將組合物配方冷卻成型為三層疊層板片,然而,三層疊層板片僅利用單一螺桿之冷卻成型裝置12擠壓成型,恐將導致所製作之疊層珠光合成紙有混料不均勻而衍生不易上色之困擾。 The conventional composition formulation is cooled and formed into a three-layer laminate by the cooling molding device 12 only after stirring and mixing by the extruder device 11, however, the three-layer laminate uses only a single screw. Extrusion molding of the cooling forming device 12 may result in unevenness of the mixed laminated pearlescent synthetic paper and derivation of coloring.

二、效率不佳 Second, the efficiency is not good

習知利用電暈處理裝置15作高週波電暈處理,以提高珠光合成紙的表面張力,惟經過電暈處理裝置15之珠光合成紙僅用以改變被印體表面的附著能量,以符合印刷油墨的附著或塗佈,但是當製造較厚之珠光合成紙,或是使用不同組合物配方時,恐因完全乾燥的時間不同,而延長 作業人員及預留等候乾燥作業時間之降低製程效率的問題。 It is conventional to use the corona treatment device 15 for high-frequency corona treatment to increase the surface tension of the pearlescent synthetic paper, but the pearlescent synthetic paper passing through the corona treatment device 15 is only used to change the adhesion energy of the surface of the substrate to conform to the printing. Adhesion or coating of ink, but when making thicker pearlescent synthetic paper, or using different composition formulas, it may be delayed due to different drying time. The operator and the problem of waiting for the drying time to reduce the process efficiency.

三、產量不佳 Third, the output is not good

習知雖可藉由在珠光合成紙製程中,先將無機粉末預製成M1B(複合粒),以改進習知的珠光合成紙製程中因為無機物本身受潮的因素,或表面處理劑受熱揮發產生氣體的因素,而影響產品品質與產量無法提高的問題,但是,無機粉末在押出機裝置11產速提高以及與聚丙烯混合時分散性仍有造成押出機裝置11過濾網壽命縮短,而影響生產效率與無法提高產量之目標。 Although it is known in the pearly synthetic paper process that the inorganic powder is first formed into M1B (composite particles) to improve the moisture content of the inorganic material itself in the conventional pearlescent synthetic paper process, or the surface treatment agent is heated and volatilized. The gas factor affects the problem that the product quality and the yield cannot be improved. However, the increase in the production rate of the inorganic powder in the extruder device 11 and the dispersibility when mixed with the polypropylene still cause the life of the filter device of the extruder device 11 to be shortened, which affects the production. Efficiency and the goal of not increasing production.

上述缺點都顯現習知的雙軸延伸聚丙烯珠光合成紙提升產量產速製造方法在使用上所衍生的種種問題,如能設計出可有效改善現有之合成紙製程缺點,研發出一種縮短製程時間與提升生產效率之設計,必定能達到提高效能之目標,為業者創造更大的商機,進而提升市場上的競爭力。 The above disadvantages all show various problems arising from the use of the conventional biaxially stretched polypropylene pearlescent synthetic paper to increase the yield and production speed. For example, it can be designed to effectively improve the shortcomings of the existing synthetic paper process, and develop a shortening process time. With the design of improving production efficiency, it is sure to achieve the goal of improving efficiency, creating greater business opportunities for the industry, and thus enhancing competitiveness in the market.

因此,本發明之一目的,即在提供一種合成紙之製造方法,包含一混合提煉步驟、一押出步驟、一成型步驟、一持溫步驟,及一裁切捲收步驟。 Accordingly, it is an object of the present invention to provide a method of making a synthetic paper comprising a mixing and refining step, an extruding step, a forming step, a holding step, and a cutting and winding step.

首先,進行該混合提煉步驟,將一塑膠原料組合物進行混料後提煉,使其膠化並均勻分散,以得到一充分混合後之膠化組合物,接著,進行該押出步驟,將該膠化組合物作定量之擠壓輸出,然後,進行該成型步驟,將該膠化組合物作定量之擠壓輸出,接著,進行該持溫步驟,使用一紅外線燈照射該組合物板片,以使該組合物板片維持一定溫度,最後,進行該裁切捲收步驟,對該組合物板片取適當長度進行裁切並捲收,以得到一合成紙。 First, the mixing and refining step is carried out, and a plastic raw material composition is mixed and refined, gelatinized and uniformly dispersed to obtain a fully mixed gelled composition, and then the extruding step is performed, the glue is applied. The composition is subjected to quantitative extrusion output, and then the molding step is performed, and the gelled composition is subjected to quantitative extrusion output, and then the temperature holding step is performed, and the composition sheet is irradiated with an infrared lamp to The composition sheet is maintained at a certain temperature. Finally, the cutting and winding step is carried out, and the composition sheet is cut to an appropriate length and wound up to obtain a synthetic paper.

本發明的另一技術手段,是在於上述合成紙之製造方法更包括一介於該持溫步驟與該裁切捲收步驟間之拉伸步驟,在該拉伸步驟中,是對該組合物板片進行拉伸延展,以得到一變薄之組合物延伸片,再對該組合物延伸片取適當長度進行裁切與捲收。 Another technical means of the present invention is that the method for manufacturing the synthetic paper further comprises a stretching step between the temperature holding step and the cutting and winding step, in which the composition sheet is The sheet is stretched to obtain a thinned stretch of the composition, and the stretched sheet of the composition is cut to length and wound.

本發明的又一技術手段,是在於上述合成紙之製造方法更包括一介於該拉伸步驟與該裁切捲收步驟間之表面處理步驟,在該表面處理步驟中,是對該組合物延伸片進行壓花或鏡面處置,以於其表面上成型出預定圖樣或光滑度。 A further technical means of the present invention is that the method for producing the synthetic paper further comprises a surface treatment step between the stretching step and the cutting and winding step, in which the composition is extended The sheet is embossed or mirrored to form a predetermined pattern or smoothness on its surface.

本發明的再一技術手段,是在於上述合成紙之製造方法更包括一介於該拉伸步驟與該表面處理步驟間之後段加熱步驟,在該後段加熱步驟中,是使用該紅外線燈照射該組合物延伸片,以使其維持一定溫度。 A further technical means of the present invention is that the method for manufacturing the synthetic paper further comprises a step of heating between the stretching step and the surface treating step, and in the heating step of the latter stage, the combination is irradiated with the infrared lamp. Extend the sheet to maintain it at a certain temperature.

本發明的另一技術手段,是在於上述合成紙之製造方法更包括一介於該混合提煉步驟與該押出步驟間之前段加熱步驟,在該前段加熱步驟中,是使用該紅外線燈照射該膠化組合物以使其維持一定溫度。 Another technical means of the present invention is that the method for manufacturing the synthetic paper further comprises a step of heating between the mixing and refining step and the step of ejecting, in the step of heating, the gel is irradiated with the infrared lamp. The composition is allowed to maintain a certain temperature.

本發明的又一技術手段,是在於上述之混合提煉步驟中,該塑膠原料組合物是選自於聚丙烯、高密度聚乙烯、低密度聚乙烯、線性低密度聚乙烯,及此等之組合。 Another technical means of the present invention is that in the above mixing and refining step, the plastic raw material composition is selected from the group consisting of polypropylene, high density polyethylene, low density polyethylene, linear low density polyethylene, and the like. .

本發明之另一目的,即在提供一種合成紙之製造成型裝置,包含一混料單元、一押出單元、一成型單元、一加熱單元,及一裁切捲收單元。 Another object of the present invention is to provide a manufacturing and molding apparatus for synthetic paper comprising a mixing unit, an extrusion unit, a molding unit, a heating unit, and a cutting and retracting unit.

該混料單元包括一圍繞界定出一混合空間之混料機、一位於該混料機上方之入料口,及一位於該混料機下方之出料口,該塑膠原料組合物是由該入料口進入該混合空間中,攪拌並使其膠化均勻分散,以得到一膠化組合物,再由該出料口流出該混料機。該押出單元包括一 位於該混料單元後端且圍繞界定出一押出空間之押出機、一位於該押出機上方之押入口,及一位於該押出機下方之押出口,該押入口是接收該出料口流出之膠化組合物,並存放於該押出空間中,再由該押出口自該押出空間將該膠化組合物定量向外擠出。 The mixing unit comprises a mixing machine defining a mixing space, a receiving port located above the mixing machine, and a discharging port located below the mixing machine, wherein the plastic raw material composition is The feed port enters the mixing space, is stirred and gelled uniformly to obtain a gelled composition, and the discharge port is discharged from the mixer. The extruding unit includes a An extruder located at a rear end of the mixing unit and defining an extrusion space, an entrance located above the extruder, and an exit port located below the extruder, the entrance is to receive the outlet The composition is gelled and stored in the extrusion space, and the gelled composition is quantitatively extruded outward from the extrusion space.

該成型單元包括一位於該押出單元後端之壓延機,其具有二對向且間隔設置之螺桿,該二螺桿圍繞界定出一壓延空間,自該押出口壓出之膠化組合物會由該二螺桿上方進入該壓延空間中進行壓延,再由該二螺桿下方輸出,以得到一組合物板片。該加熱單元包括一設置於該組合物板片旁以對該組合物板片進行加熱之第一加熱件。該裁切捲收單元包括一用以裁切預定長度之組合物板片的裁切機,以及一用以將經裁切後之組合物板片捲收之捲取機。 The molding unit includes a calender located at the rear end of the extruding unit, and has two oppositely spaced and spaced apart screws, the two screws defining a calendering space, and the gelled composition extruded from the outlet is The second screw enters the calendering space for calendering, and then is outputted from below the two screws to obtain a composite sheet. The heating unit includes a first heating member disposed adjacent to the sheet of the composition to heat the sheet of the composition. The cutting and retracting unit includes a cutter for cutting a predetermined length of the composition sheet, and a coiler for winding the cut sheet of the composition.

本發明的另一技術手段,是在於上述合成紙之製造成型裝置更包含一位於該加熱單元與該裁切捲收單元間之拉伸單元,該拉伸單元具有複數間隔設置之輥壓輪,該複數輥壓輪圍繞界定出一拉伸空間,自該二螺桿下方輸出之組合物板片會由該複數輥壓輪前端進入該拉伸空間中進行延展拉伸,再由該複數輥壓輪後端輸出,以得到一組合物延伸片,再用以該裁切機與該捲取機對該組合物延伸片進行裁切與捲收。 Another technical means of the present invention is that the manufacturing and molding apparatus of the synthetic paper further comprises a stretching unit located between the heating unit and the cutting and retracting unit, the stretching unit having a plurality of roller pressing wheels arranged at intervals. The plurality of roller presses define a stretching space, and the composition plate outputted from the bottom of the two screws enters the stretching space by the front end of the plurality of roller pressing wheels for stretching and stretching, and then the plurality of roller pressing rollers The back end is output to obtain a set of stretched pieces, and the cutting piece and the winder are used for cutting and winding the composition extension piece.

本發明的又一技術手段,是在於上述合成紙之製造成型裝置更包含一位於該拉伸單元與該裁切捲收單元間之表面處理單元,該表面處理單元包括一用以對該組合物延伸片進行表面壓花或鏡面處置之表面處理機。 Another technical means of the present invention is that the manufacturing and molding apparatus of the synthetic paper further comprises a surface treatment unit located between the stretching unit and the cutting and retracting unit, the surface treatment unit comprising a composition for the composition A surface treatment machine for surface embossing or mirror treatment of the extension sheet.

本發明的再一技術手段,是在於上述合成紙之製造成型裝置更包含一後段加熱單元,及一前段加熱單元,該後段加熱單元位於該拉伸單元與該表面處理單元間,並包括一用以對該組合物延伸片進行表面加熱處理之 第二加熱件,該前段加熱單元位於該混料單元與該押出單元間,並包括一用以對該膠化組合物進行加熱處理之第三加熱件,其中,該第一、二、三加熱件為一紅外線燈。 A further technical means of the present invention is that the manufacturing and molding apparatus for synthetic paper further comprises a rear heating unit and a front heating unit, the rear heating unit is located between the stretching unit and the surface treatment unit, and includes a Surface heat treatment of the stretched sheet of the composition a second heating member, the front heating unit is located between the mixing unit and the extruding unit, and includes a third heating member for heating the gelling composition, wherein the first, second, and third heating The piece is an infrared lamp.

本發明之有益功效在於,藉由該第一、二、三加熱件的設置,可大大降低製程中硬化、表面壓花變型、捲收黏持等困擾,以降低產品之不良率,再者,利用該二螺桿之設置,可使壓延之膠化組合物混料均勻、該組合物板片表面平整,而可提高該合成紙的品質。 The beneficial effect of the invention is that, by the arrangement of the first, second and third heating elements, the problems of hardening, surface embossing, shrinkage and adhesion, etc. in the process can be greatly reduced, so as to reduce the defect rate of the product, By using the arrangement of the two screws, the calendered composition of the calendered composition can be uniformly mixed, and the surface of the sheet of the composition can be flat, and the quality of the synthetic paper can be improved.

21‧‧‧塑膠原料組合物 21‧‧‧Plastic raw material composition

22‧‧‧膠化組合物 22‧‧‧gelling composition

23‧‧‧組合物板片 23‧‧‧Composition sheets

24‧‧‧組合物延伸片 24‧‧‧Composition extension

25‧‧‧合成紙 25‧‧‧Synthetic paper

51‧‧‧混料單元 51‧‧‧Mixed unit

510‧‧‧混合空間 510‧‧‧ mixed space

511‧‧‧混料機 511‧‧‧ Mixer

512‧‧‧入料口 512‧‧‧Inlet

513‧‧‧出料口 513‧‧‧Outlet

52‧‧‧前段加熱單元 52‧‧‧Front heating unit

521‧‧‧第三加熱件 521‧‧‧ Third heating element

53‧‧‧押出單元 53‧‧‧Exit unit

530‧‧‧押出空間 530‧‧‧Exit space

531‧‧‧押出機 531‧‧‧Exporting machine

532‧‧‧押入口 532‧‧‧ entrance

533‧‧‧押出口 533‧‧‧Exit

54‧‧‧成型單元 54‧‧‧Molding unit

540‧‧‧壓延空間 540‧‧‧Depression space

541‧‧‧壓延機 541‧‧‧Caulding machine

542‧‧‧螺桿 542‧‧‧ screw

55‧‧‧加熱單元 55‧‧‧heating unit

551‧‧‧第一加熱件 551‧‧‧First heating element

56‧‧‧拉伸單元 56‧‧‧Stretching unit

560‧‧‧拉伸空間 560‧‧‧ stretching space

561‧‧‧延伸機 561‧‧‧Extension machine

562‧‧‧輥壓輪 562‧‧‧ Roller wheel

57‧‧‧後段加熱單元 57‧‧‧ Rear heating unit

571‧‧‧第二加熱件 571‧‧‧second heating element

58‧‧‧表面處理單元 58‧‧‧Surface treatment unit

581‧‧‧表面處理機 581‧‧‧ surface treatment machine

59‧‧‧裁切捲收單元 59‧‧‧Cropping unit

591‧‧‧裁切機 591‧‧‧ cutting machine

592‧‧‧捲取機 592‧‧‧Winding machine

91~99‧‧‧步驟 91~99‧‧‧Steps

圖1是一立體示意圖,說明習知台灣發明第197686號一種雙軸延伸聚丙烯珠光合成紙提升產量產速製造方法; 圖2是一示意圖,說明本發明合成紙之製造方法的第一較佳實施例; 圖3是一示意圖,說明該第一較佳實施例之製造成型裝置配置示意; 圖4是一示意圖,說明本發明合成紙之製造方法的第二較佳實施例;及 圖5是一示意圖,說明該第二較佳實施例之製造成型裝置配置示意。 1 is a perspective view showing a manufacturing method for increasing the yield and production speed of a biaxially stretched polypropylene pearlescent synthetic paper of the Japanese Patent No. 197686; Figure 2 is a schematic view showing a first preferred embodiment of the method for producing the synthetic paper of the present invention; Figure 3 is a schematic view showing the configuration of the manufacturing molding apparatus of the first preferred embodiment; Figure 4 is a schematic view showing a second preferred embodiment of the method of manufacturing the synthetic paper of the present invention; Figure 5 is a schematic view showing the configuration of the manufacturing molding apparatus of the second preferred embodiment.

有關本發明之相關申請專利特色與技術內容,在以下配合參考圖式之較佳實施例的詳細說明中,將可清楚的呈現。 The detailed description of the preferred embodiments of the present invention will be apparent from the detailed description of the preferred embodiments.

參閱圖2,為本發明合成紙之製造方法的第一較佳實施例,包含一混合提煉步驟91、一前段加熱步驟92、一押出步驟93、一成型步驟94、一持溫步驟95、一拉伸步驟96、一後段加熱步驟97、一表面處理步驟98,及一裁切捲收步驟99。 2 is a first preferred embodiment of a method for manufacturing a synthetic paper according to the present invention, comprising a mixing and refining step 91, a front heating step 92, an extruding step 93, a forming step 94, a temperature holding step 95, and a The stretching step 96, a subsequent heating step 97, a surface treatment step 98, and a cutting and winding step 99 are performed.

首先,進行該混合提煉步驟91,將一塑膠原料組合物21進行混料後提煉,使其膠化並均勻分散,以得到一充分混合後之膠化組合物22。 First, the mixing and refining step 91 is carried out, and a plastic raw material composition 21 is mixed and refined, gelled and uniformly dispersed to obtain a sufficiently mixed gelled composition 22.

其中,在該混合提煉步驟91中,該塑膠原料組合物21是選自於聚丙烯、高密度聚乙烯、低密度聚乙烯、線性低密度聚乙烯,及此等之組合,實際實施時,可依使用需求選擇不同材質之聚烯類的塑膠原料組合物21,亦或是增加其他的添加劑,不應以此為限。 Wherein, in the mixing and refining step 91, the plastic raw material composition 21 is selected from the group consisting of polypropylene, high density polyethylene, low density polyethylene, linear low density polyethylene, and the like, and in actual implementation, The plastic raw material composition 21 of different materials may be selected according to the use requirements, or other additives may be added, and should not be limited thereto.

接著,進行該前段加熱步驟92,是使用一紅外線燈或一烘箱照射該膠化組合物22,以使其維持一定溫度,使用者可隨該膠化組合物22之材質,調整該紅外線燈或該烘箱的照射溫度,以避免該膠化組合物22在過程中產生硬化之困擾。 Next, the front heating step 92 is performed by irradiating the gelling composition 22 with an infrared lamp or an oven to maintain a certain temperature, and the user can adjust the infrared lamp according to the material of the gelling composition 22. The irradiation temperature of the oven avoids the hardening of the gelled composition 22 during the process.

然後,進行該押出步驟93,將該膠化組合物22作定量之擠壓輸出。 Then, the extruding step 93 is performed, and the gelled composition 22 is subjected to a quantitative extrusion output.

接著,進行該成型步驟94,將押出之膠化組合物22進行壓延成片狀,以得到一組合物板片23。 Next, the molding step 94 is carried out, and the extruded gelled composition 22 is calendered into a sheet shape to obtain a composition sheet 23 .

然後,進行該持溫步驟95,使用該紅外線燈或該烘箱照射該組合物板片23,以使該組合物板片23維持一定溫度。 Then, the temperature holding step 95 is performed, and the composition sheet 23 is irradiated with the infrared lamp or the oven to maintain the composition sheet 23 at a constant temperature.

接著,進行該拉伸步驟96,對該組合物板片23進行拉伸延展,以得到一變薄之組合物延伸片24。 Next, the stretching step 96 is performed to stretch and stretch the composition sheet 23 to obtain a thinned composition extending sheet 24.

然後,進行該後段加熱步驟97,是使用該紅外線燈或該烘箱照射該組合物延伸片24,以使其維持一定溫度。 Then, the subsequent heating step 97 is performed by irradiating the composition extension sheet 24 with the infrared lamp or the oven to maintain a certain temperature.

接著,進行該表面處理步驟98,是對該組合物延伸片24進行壓花或鏡面處置,以於其表面上成型出預定圖樣或光滑度。 Next, the surface treatment step 98 is performed by subjecting the composition extension sheet 24 to embossing or mirror treatment to form a predetermined pattern or smoothness on the surface thereof.

最後,進行該裁切捲收步驟99,對該組合物延伸片24取適當長度進行裁切並捲收,以得到一合成紙 25。 Finally, the cutting and winding step 99 is performed, and the composition extending sheet 24 is cut to an appropriate length and wound up to obtain a synthetic paper. 25.

配合參閱圖3,依據上述合成紙之製造方法所組成之合成紙製造成型裝置,包含一混料單元51、一前段加熱單元52、一押出單元53、一成型單元54、一加熱單元55、一拉伸單元56、一後段加熱單元57、一表面處理單元58,及一裁切捲收單元59。 Referring to FIG. 3, a synthetic paper manufacturing molding apparatus comprising the above synthetic paper manufacturing method comprises a mixing unit 51, a front heating unit 52, an extruding unit 53, a molding unit 54, a heating unit 55, and a The stretching unit 56, a rear heating unit 57, a surface treatment unit 58, and a cutting and retracting unit 59.

該混料單元51包括一圍繞界定出一混合空間510之混料機511、一位於該混料機511上方入料口512,及一位於該混料機511下方之出料口513。 The mixing unit 51 includes a mixer 511 surrounding a mixing space 510, an inlet 512 located above the mixer 511, and a discharge port 513 located below the mixer 511.

該塑膠原料組合物21是由該入料口512進入該混合空間510中,經該混料機511高速混合、攪拌、冷卻,使其膠化並均勻分散,以得到該膠化組合物22,再由該出料口513流出該混料機511。 The plastic raw material composition 21 enters the mixing space 510 from the inlet port 512, is mixed, stirred, cooled, and gelled and uniformly dispersed by the mixer 511 to obtain the gelled composition 22, The mixer 511 is again discharged from the discharge port 513.

該前段加熱單元52包括一用以對該膠化組合物22進行加熱處理之第三加熱件521。由於該膠化組合物22之耐溫性不佳,透過該第三加熱件521之設置,可減少該膠化組合物22硬化而無法使用之困擾。 The front stage heating unit 52 includes a third heating member 521 for heat-treating the gelled composition 22. Since the temperature resistance of the gelled composition 22 is not good, the setting of the third heating member 521 can reduce the problem that the gelled composition 22 is hardened and cannot be used.

再者,經由該第三加熱件521之加熱處理的膠化組合物22,可將多餘水分蒸發,以避免該膠化組合物22於後續程序中,衍生表面產生氣泡之困擾,進而降低產品之不良率。 Furthermore, the heat-treated gelled composition 22 of the third heating member 521 can evaporate excess water to avoid the problem that the gelled composition 22 generates bubbles in the subsequent process, thereby reducing the product. Bad rate.

在該第一較佳實施例中,是用以該紅外線燈作為加熱、持溫該膠化組合物22之用,該紅外線燈的最高加熱溫度可達180℃,該紅外線燈使用於該膠化組合物22之照射距離約為45cm,溫度則是控制在50℃~60℃間,於此所揭露之照射距離與溫度僅為舉例說明,實際實施時,仍需依材質而決定,不應以此為限。 In the first preferred embodiment, the infrared lamp is used for heating and holding the gelled composition 22, and the infrared lamp has a maximum heating temperature of up to 180 ° C, and the infrared lamp is used for the gelation. The irradiation distance of the composition 22 is about 45 cm, and the temperature is controlled between 50 ° C and 60 ° C. The irradiation distance and temperature disclosed herein are only examples, and in actual implementation, it is still determined according to the material, and should not be determined by the material. This is limited.

該押出單元53包括一位於該混料單元51後端且圍繞界定出一押出空間530之押出機531、一位於該押出機531上方之押入口532,及一位於該押出機531 下方之押出口533。 The extruding unit 53 includes an extruder 531 located at the rear end of the mixing unit 51 and surrounding an extruding space 530, an entrance 532 located above the extruder 531, and one of the extruders 531. Below the exit 533.

該押入口532是接收該出料口513流出之膠化組合物22,並存放於該押出空間530中,再由該押出口533自該押出空間530將該膠化組合物22定量向外擠出。 The inlet 532 is a gelled composition 22 that receives the discharge port 513 and is stored in the extrusion space 530. The extrusion outlet 533 then quantitatively squeezes the gelled composition 22 from the extrusion space 530. Out.

特別說明的是,該押出機531可視材質需求使用雙螺桿的押出機型態,並在該雙螺桿中盛裝熱水或冷水等進行加熱或冷卻,以使該膠化組合物22充份膠化、混合,亦或是在該押出口533設置一過濾網,以過濾欲自該押出口533向外擠出的膠化組合物22,避免影響該合成紙的表面平整度。 In particular, the extruder 531 can use a twin-screw extruder type depending on the material requirements, and heat or cool the hot water or cold water in the twin screw to make the gelled composition 22 fully gelatinized. A filter is also provided, or a filter is provided at the outlet 533 to filter the gelled composition 22 to be extruded outwardly from the outlet 533 to avoid affecting the surface flatness of the synthetic paper.

該成型單元54包括一位於該押出單元53後端之壓延機541,其具有二對向且間隔設置之螺桿542,該二螺桿542圍繞界定出一壓延空間540。 The forming unit 54 includes a calender 541 at the rear end of the extruding unit 53 having two opposing and spaced apart screws 542 that define a calendering space 540.

自該押出口533壓出之膠化組合物22會由該二螺桿542上方進入該壓延空間540中進行壓延,再由該二螺桿542下方輸出,以得到該組合物板片23,透過該二螺桿542之設置,可使壓延之膠化組合物22混料均勻,且該組合物板片23表面平整,將可有效提升該合成紙25的品質,實際實施時,該二螺桿542之間隙可調整,以得到不同厚度之組合物板片23。 The gelled composition 22 extruded from the outlet 533 is rolled into the calendering space 540 from above the second screw 542, and then outputted from the lower portion of the second screw 542 to obtain the composition sheet 23, through which the two The screw 542 is arranged to make the calendered composition 22 uniform, and the surface of the composition sheet 23 is flat, which can effectively improve the quality of the synthetic paper 25. In actual implementation, the gap between the two screws 542 can be Adjustment is made to obtain a composite sheet 23 of varying thickness.

該加熱單元55包括一設置於該組合物板片23旁以對該組合物板片23進行加熱之第一加熱件551,同樣地,該第一加熱件551亦為該紅外線燈,於此不再贅述其功效。 The heating unit 55 includes a first heating member 551 disposed adjacent to the composition sheet 23 to heat the composition sheet 23. Similarly, the first heating member 551 is also the infrared lamp. Then describe its efficacy.

該拉伸單元56包括一位於該成型單元54後端之延伸機561,其具有複數間隔設置之輥壓輪562,該複數輥壓輪562圍繞界定出一拉伸空間560。 The stretching unit 56 includes an extension 561 at the rear end of the molding unit 54 having a plurality of spaced apart roller pressers 562 that define a stretch space 560.

自該二螺桿542下方輸出之組合物板片23會由該複數輥壓輪562前端進入該拉伸空間560中進行延 展拉伸,再由該複數輥壓輪562後端輸出,以得到該組合物延伸片24。 The composition sheet 23 outputted from the second screw 542 is extended by the front end of the plurality of roller pressing wheels 562 into the stretching space 560. The stretch is stretched and then output from the rear end of the plurality of roller pressers 562 to obtain the composition stretch sheet 24.

通常該輥壓輪562的數量可為4~6支,而其排列可為L型、逆L型、Z型,或逆Z型,端視材質之分散、膠化,或是厚度而定,溫度則依所用之塑膠原料組合物21之不同而定。 Generally, the number of the roller pressers 562 may be 4-6, and the arrangement may be L-shaped, reverse-L-shaped, Z-shaped, or reverse-Z-shaped, depending on the dispersion, gelation, or thickness of the material. The temperature depends on the plastic material composition 21 used.

該後段加熱單元57包括一用以對該組合物延伸片24進行表面加熱處理之第二加熱件571,且該第一加熱件551亦為該紅外線燈。 The rear heating unit 57 includes a second heating member 571 for surface heating the composition extending sheet 24, and the first heating member 551 is also the infrared lamp.

該表面處理單元58包括一用以對該組合物延伸片24進行表面壓花或鏡面處置之表面處理機581,以於其表面上成型出客戶預定的圖樣,或不同光滑度等客製化需求。 The surface treatment unit 58 includes a surface treatment machine 581 for surface embossing or mirror treatment of the composition extension sheet 24 to form a predetermined pattern on the surface thereof, or a customized requirement such as different smoothness. .

該裁切捲收單元59包括一用以裁切預定長度之組合物延伸片24的裁切機591,以及一用以將經裁切後之組合物延伸片24捲收之捲取機592,以得到該合成紙25。 The cutting and retracting unit 59 includes a cutter 591 for cutting a predetermined length of the composition extension piece 24, and a reeling machine 592 for winding the cut composition extension piece 24, The synthetic paper 25 is obtained.

透過在該表面處理單元58前先對該組合物延伸片24進行表面加熱處理,可避免未完全乾燥之組合物延伸片24產生表面壓花變型之疑慮,再者,未完全乾燥之組合物延伸片24捲收後恐相互黏持,而不利於後續使用。 By subjecting the composition extension sheet 24 to surface heat treatment prior to the surface treatment unit 58, it is possible to avoid the occurrence of surface embossing variations of the composition stretch sheet 24 which is not completely dried, and further, the composition which is not completely dried is extended. After 24 rolls, the film may stick to each other, which is not conducive to subsequent use.

參閱圖4、5,為本發明合成紙之製造方法及該合成紙之製造成型裝置的第二較佳實施例,該第二較佳實施例與該第一較佳實施例大致相同,相同之處於此不再贅述,不同之處在於,該合成紙之製造方法是省略該拉伸步驟96,而該合成紙製造成型裝置則是省略該拉伸單元56。 4 and 5 are a second preferred embodiment of the method for manufacturing a synthetic paper of the present invention and a manufacturing apparatus for the synthetic paper. The second preferred embodiment is substantially the same as the first preferred embodiment. This will not be described again, except that the synthetic paper is manufactured by omitting the stretching step 96, and the synthetic paper manufacturing molding apparatus omits the stretching unit 56.

實際實施時,是將進行該持溫步驟95後之組合物板片23,送至該表面處理機581進行表面壓花或鏡面處置,之後即進行該裁切捲收步驟99,以符合不同使用 狀態之需求。 In actual implementation, the composition sheet 23 after the temperature holding step 95 is sent to the surface treatment machine 581 for surface embossing or mirror surface treatment, and then the cutting and winding step 99 is performed to meet different uses. The need for status.

經由上述說明可知,本發明合成紙之製造方法及該合成紙之製造成型裝置確實具有以下優點: As apparent from the above description, the manufacturing method of the synthetic paper of the present invention and the manufacturing and molding apparatus of the synthetic paper do have the following advantages:

一、混料均勻且平整 First, the mixture is even and flat

自該押出口533壓出之膠化組合物22會透過該成型單元54之二螺桿542進入該壓延空間540中壓延,再由該二螺桿542下方輸出,如此一來,將可使受該二螺桿542壓延之膠化組合物22成為混料均勻且表面平整之組合物板片23,進而提升該合成紙25的品質。 The gelled composition 22 extruded from the outlet 533 will be rolled into the calendering space 540 through the two screws 542 of the molding unit 54 and then outputted from the lower portion of the second screw 542, so that the second The gelled composition 22 which is rolled by the screw 542 becomes a composition sheet 23 which is uniformly mixed and has a smooth surface, thereby improving the quality of the synthetic paper 25.

二、提升製程效率 Second, improve process efficiency

透過在該表面處理單元58前對該組合物延伸片24進行表面加熱處理,可減少作業人員等候乾燥時間,以提升製程效率。 By subjecting the composition extending sheet 24 to surface heat treatment before the surface treatment unit 58, the drying time of the worker can be reduced to improve the process efficiency.

三、減少產品不良率 Third, reduce product defect rate

透過該第一、二、三加熱件551、571、521之設置,可大大降低製程中硬化、表面壓花變型、捲收黏持等困擾,以降低產品之不良率。 Through the arrangement of the first, second and third heating elements 551, 571, 521, the problems of hardening, surface embossing, and retraction in the process can be greatly reduced, so as to reduce the defect rate of the product.

綜上所述,本發明合成紙之製造方法及該合成紙之製造成型裝置,藉由該混料單元51、該前段加熱單元52、該押出單元53、該成型單元54、該加熱單元55、該拉伸單元56、該後段加熱單元57、該表面處理單元58,及該裁切捲收單元59間相互設置,透過該第一、二、三加熱件551、571、521的設置,可大大降低製程中硬化、表面壓花變型、捲收黏持等困擾,再者,利用該二螺桿542之設置,可使壓延之膠化組合物22混料均勻、該組合物板片23表面平整,不僅可降低產品之不良率,亦可有效提升該合成紙25的品質,故確實可以達成本發明之目的。 In summary, the manufacturing method of the synthetic paper of the present invention and the manufacturing and molding apparatus of the synthetic paper, the mixing unit 51, the front heating unit 52, the extruding unit 53, the molding unit 54, the heating unit 55, The stretching unit 56, the rear heating unit 57, the surface treatment unit 58, and the cutting and retracting unit 59 are disposed to each other, and the setting of the first, second, and third heating members 551, 571, and 521 can be greatly increased. The process of hardening, surface embossing, shrinkage and the like are reduced, and further, by using the two screws 542, the calendered composition 22 can be uniformly mixed, and the surface of the composition sheet 23 is flat. Not only can the defect rate of the product be lowered, but also the quality of the synthetic paper 25 can be effectively improved, so that the object of the present invention can be achieved.

惟以上所述者,僅為本發明之二個較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依 本發明申請專利範圍及發明說明內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。 However, the above description is only two preferred embodiments of the present invention, and the scope of the present invention cannot be limited thereto. The simple equivalent changes and modifications made by the scope of the invention and the description of the invention are still within the scope of the invention.

91~95‧‧‧步驟 91~95‧‧‧Steps

97~99‧‧‧步驟 97~99‧‧‧Steps

Claims (10)

一種合成紙之製造方法,包含下列步驟:一混合提煉步驟,將一塑膠原料組合物進行混料後提煉,使其膠化並均勻分散,以得到一充分混合後之膠化組合物;一押出步驟,將該膠化組合物作定量之擠壓輸出;一成型步驟,將押出之膠化組合物進行壓延成片狀,以得到一組合物板片;一持溫步驟,使用一紅外線燈照射該組合物板片,以使該組合物板片維持一定溫度;及一裁切捲收步驟,對該組合物板片取適當長度進行裁切並捲收,以得到一合成紙。 A method for producing synthetic paper, comprising the steps of: mixing and refining step, mixing a plastic raw material composition, refining it, gelling and uniformly dispersing to obtain a fully mixed gelled composition; Step, the gelled composition is subjected to quantitative extrusion output; in a molding step, the extruded gelled composition is calendered into a sheet form to obtain a composition plate; a temperature holding step is irradiated with an infrared lamp The composition sheet is used to maintain the composition sheet at a certain temperature; and a cutting and taking step, the composition sheet is cut to an appropriate length and wound to obtain a synthetic paper. 依據申請專利範圍第1項所述合成紙之製造方法,更包括一介於該持溫步驟與該裁切捲收步驟間之拉伸步驟,在該拉伸步驟中,是對該組合物板片進行拉伸延展,以得到一變薄之組合物延伸片,再對該組合物延伸片取適當長度進行裁切與捲收。 The method for manufacturing a synthetic paper according to claim 1, further comprising a stretching step between the temperature holding step and the cutting and winding step, wherein in the stretching step, the composition sheet is Stretching is carried out to obtain a thinned stretch of the composition, and the stretched sheet of the composition is cut to a suitable length for cutting and winding. 依據申請專利範圍第2項所述合成紙之製造方法,更包括一介於該拉伸步驟與該裁切捲收步驟間之表面處理步驟,在該表面處理步驟中,是對該組合物延伸片進行壓花或鏡面處置,以於其表面上成型出預定圖樣或光滑度。 The method for producing a synthetic paper according to claim 2, further comprising a surface treatment step between the stretching step and the cutting and winding step, wherein in the surface treatment step, the composition is extended Embossing or mirroring is performed to form a predetermined pattern or smoothness on the surface. 依據申請專利範圍第3項所述合成紙之製造方法,更包括一介於該拉伸步驟與該表面處理步驟間之後段加熱步驟,在該後段加熱步驟中,是使用該紅外線燈照射該組合物延伸片,以使其維持一定溫度。 The method for producing a synthetic paper according to claim 3, further comprising a step of heating between the stretching step and the surface treating step, wherein in the subsequent heating step, the composition is irradiated with the infrared lamp Extend the sheet to maintain it at a certain temperature. 依據申請專利範圍第4項所述合成紙之製造方法,更包括一介於該混合提煉步驟與該押出步驟間之前段加熱步驟,在該前段加熱步驟中,是使用該紅外線燈照射該膠化組合物以使其維持一定溫度。 The method for manufacturing a synthetic paper according to claim 4, further comprising a step of heating between the mixing and refining step and the step of ejecting, in the step of heating, using the infrared lamp to illuminate the gelled combination To maintain it at a certain temperature. 依據申請專利範圍第5項所述合成紙之製造方法,其中,在該混合提煉步驟中,該塑膠原料組合物是選自於聚丙烯、高密度聚乙烯、低密度聚乙烯、線性低密度聚乙烯,及此等之組合。 The method for producing a synthetic paper according to claim 5, wherein in the mixing and refining step, the plastic raw material composition is selected from the group consisting of polypropylene, high density polyethylene, low density polyethylene, and linear low density poly Ethylene, and combinations of these. 一種合成紙之製造成型裝置,包含:一混料單元,包括一圍繞界定出一混合空間之混料機、一位於該混料機上方之入料口,及一位於該混料機下方之出料口,該塑膠原料組合物是由該入料口進入該混合空間中,攪拌並使其膠化均勻分散,以得到一膠化組合物,再由該出料口流出該混料機;一押出單元,包括一位於該混料單元後端且圍繞界定出一押出空間之押出機、一位於該押出機上方之押入口,及一位於該押出機下方之押出口,該押入口是接收該出料口流出之膠化組合物,並存放於該押出空間中,再由該押出口自該押出空間將該膠化組合物定量向外擠出; 一成型單元,包括一位於該押出單元後端之壓延機,其具有二對向且間隔設置之螺桿,該二螺桿圍繞界定出一壓延空間,自該押出口壓出之膠化組合物會由該二螺桿上方進入該壓延空間中進行壓延,再由該二螺桿下方輸出,以得到一組合物板片;一加熱單元,包括一設置於該組合物板片旁以對該組合物板片進行加熱之第一加熱件;及一裁切捲收單元,包括一用以裁切預定長度之組合物板片的裁切機,以及一用以將經裁切後之組合物板片捲收之捲取機。 A manufacturing and molding apparatus for synthetic paper, comprising: a mixing unit comprising a mixing machine defining a mixing space, an inlet opening above the mixing machine, and an outlet located below the mixing machine a material port, the plastic material composition enters the mixing space from the feed port, stirs and gels and uniformly disperses to obtain a gelled composition, and then flows out of the mixer through the discharge port; The extruding unit includes an extruding machine located at a rear end of the mixing unit and surrounding an extruding space, an ejecting port located above the extruding machine, and an ejecting port located below the extruding machine, the ejecting port receiving the The gelled composition flowing out of the discharge port is stored in the extrusion space, and the gelled composition is quantitatively extruded outward from the extrusion space by the outlet; a molding unit comprising a calender located at the rear end of the extruding unit, having two oppositely spaced and spaced apart screws, the two screws defining a calendering space, and the gelled composition extruded from the outlet is The two screws enter the calendering space for calendering, and then are outputted from the lower side of the two screws to obtain a composite sheet; a heating unit includes a set beside the sheet of the composition to carry out the sheet of the composition. a heated first heating member; and a cutting and retracting unit comprising a cutting machine for cutting a predetermined length of the composition sheet, and a method for winding the cut composition sheet Coiler. 依據申請專利範圍第7項所述合成紙之製造成型裝置,更包含一位於該加熱單元與該裁切捲收單元間之拉伸單元,該拉伸單元具有複數間隔設置之輥壓輪,該複數輥壓輪圍繞界定出一拉伸空間,自該二螺桿下方輸出之組合物板片會由該複數輥壓輪前端進入該拉伸空間中進行延展拉伸,再由該複數輥壓輪後端輸出,以得到一組合物延伸片,再用以該裁切機與該捲取機對該組合物延伸片進行裁切與捲收。 The manufacturing molding apparatus of the synthetic paper according to claim 7 further comprising a stretching unit between the heating unit and the cutting and retracting unit, the stretching unit having a plurality of roller pressing wheels arranged at intervals, a plurality of roller presses define a stretching space, and the composition sheet outputted from the bottom of the two screws enters the stretching space by the front end of the plurality of roller pressing rollers for stretching and stretching, and then the plurality of rollers are pressed and stretched The end is output to obtain a set of extension sheets, which are then cut and retracted by the cutter and the reel. 依據申請專利範圍第8項所述合成紙之製造成型裝置,更包含一位於該拉伸單元與該裁切捲收單元間之表面處理單元,該表面處理單元包括一用以對該組合物延伸片進行表面壓花或鏡面處置之表面處理機。 The manufacturing and molding apparatus for synthetic paper according to claim 8 further comprising a surface treatment unit between the stretching unit and the cutting and retracting unit, the surface treatment unit comprising a unit for extending the composition A surface treatment machine for surface embossing or mirror treatment. 依據申請專利範圍第9項所述合成紙之製造成型裝置,更包含一後段加熱單元,及一前段加熱單元,該後段加熱單元位於該拉伸單元與該表面處理單元間,並包括一用以對該組合物延伸片進行表面加熱處理之第二加熱件,該前段加熱單元位於該混料單元與該押出單元間,並包括一用以對該膠化組合物進行加熱處理之第三加熱件,其中,該第一、二、三加熱件為一紅外線燈。 The manufacturing and molding apparatus for synthetic paper according to claim 9 further comprising a rear heating unit and a front heating unit, wherein the rear heating unit is located between the stretching unit and the surface treatment unit, and includes a a second heating member for surface heat treatment of the composition extension sheet, the front stage heating unit being located between the mixing unit and the extruding unit, and comprising a third heating member for heat-treating the gelled composition Wherein the first, second and third heating elements are an infrared lamp.
TW103142054A 2014-12-03 2014-12-03 Synthetic paper manufacturing method and the synthetic paper system Caused by type device TWI558879B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW575614B (en) * 2001-07-20 2004-02-11 Nanya Plastics Corp Manufacturing method for improving the yield and production rate of a biaxial-oriented polypropylene pearly synthetic paper
TWM429717U (en) * 2012-01-17 2012-05-21 Jerboa Electronic Co Ltd Heated quilt bag for quilt-heating machine
CN103009647A (en) * 2011-09-28 2013-04-03 陈博彦 Integrated processing device of in-plant production of surface-coated and modified BOPP (Biaxially Oriented Polypropylene) synthetic paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW575614B (en) * 2001-07-20 2004-02-11 Nanya Plastics Corp Manufacturing method for improving the yield and production rate of a biaxial-oriented polypropylene pearly synthetic paper
CN103009647A (en) * 2011-09-28 2013-04-03 陈博彦 Integrated processing device of in-plant production of surface-coated and modified BOPP (Biaxially Oriented Polypropylene) synthetic paper
TWM429717U (en) * 2012-01-17 2012-05-21 Jerboa Electronic Co Ltd Heated quilt bag for quilt-heating machine

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