TWI542631B - Silane compound, method for preparing the same, and polycarbonate resin composition including the same - Google Patents

Silane compound, method for preparing the same, and polycarbonate resin composition including the same Download PDF

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TWI542631B
TWI542631B TW103112763A TW103112763A TWI542631B TW I542631 B TWI542631 B TW I542631B TW 103112763 A TW103112763 A TW 103112763A TW 103112763 A TW103112763 A TW 103112763A TW I542631 B TWI542631 B TW I542631B
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polycarbonate resin
decane compound
integer
formula
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TW201500449A (en
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裵洙學
安盛熙
韓弦周
羅哈納
李炫虎
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第一毛織股份有限公司
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/04—Aromatic polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates

Description

矽烷化合物、其製備方法及含有其的聚碳酸酯樹脂組成物 Decane compound, preparation method thereof and polycarbonate resin composition containing same

本發明涉及矽烷化合物、用於製備其的方法及包括其的聚碳酸酯樹脂組成物。更具體地，本發明涉及具有新穎的結構的矽烷化合物、用於製備其的方法、以及藉由使用其具有優異的外觀、剛性等而沒有劣化流動性的聚碳酸酯樹脂組成物。 The present invention relates to a decane compound, a process for preparing the same, and a polycarbonate resin composition comprising the same. More specifically, the present invention relates to a decane compound having a novel structure, a method for producing the same, and a polycarbonate resin composition which has excellent appearance, rigidity, and the like without deteriorating fluidity.

當將熱塑性樹脂或熱固性樹脂與無機填料如玻璃纖維、二氧化矽、滑石(talc)等摻混時，由於無機填料的固有性質使得樹脂可以具有改善的抗撕強度(tearing strength)、拉伸強度、彎曲強度、彎曲模量(flexural modulus)等。通常在製備需要高剛性的模製品(molded article)的過程中進行熱塑性樹脂如聚碳酸酯等與無機填料的摻混。具體地，摻混物被用作用於汽車以及電氣和電子產品的內部/外部材料。 When a thermoplastic resin or a thermosetting resin is blended with an inorganic filler such as glass fiber, cerium oxide, talc or the like, the resin can have improved tearing strength and tensile strength due to the intrinsic properties of the inorganic filler. , bending strength, flexural modulus, and the like. The blending of a thermoplastic resin such as polycarbonate or the like with an inorganic filler is usually carried out in the process of preparing a molded article requiring high rigidity. In particular, blends are used as internal/external materials for automotive and electrical and electronic products.

然而，當將樹脂與無機填料摻混時，由於降低的模塑性(moldability)，使得樹脂可能具有注射成型(injection molding)方面的問題。具體地，當樹脂注射成型時，存在無機填料如玻璃纖維等可能從模製品的表面突出的可能性，其導致外觀劣化。因此，實際上，樹脂局限於用於生產室內製品。 However, when the resin is blended with the inorganic filler, the resin may have problems in injection molding due to reduced moldability. Specifically, when the resin is injection-molded, there is a possibility that an inorganic filler such as glass fiber or the like may protrude from the surface of the molded article, which causes deterioration in appearance. Therefore, in practice, the resin is limited to use in the production of interior articles.

此外，當改善與無機填料如玻璃纖維等摻混的熱塑性樹脂組成物的流動性時，可以增強外觀，但是存在的問題在於隨著流動性的增加會降低樹脂組成物的力學(機械)和熱學性能。 Further, when the fluidity of the thermoplastic resin composition blended with an inorganic filler such as glass fiber or the like is improved, the appearance can be enhanced, but there is a problem in that the mechanical (mechanical) and thermal properties of the resin composition are lowered as the fluidity increases. performance.

韓國專利公開號10-2012-0075813A公開了包含玻璃纖維增強的聚碳酸酯樹脂、金屬鹽阻燃劑、氟化聚烯烴樹脂、以及矽氧烷化合物和矽酮樹脂組成物的混合物並且具有優異阻燃性的玻璃纖維增強的聚碳酸酯樹脂組成物。此外，韓國專利公開號10-2012-0057276A公開了在高溫下具有增強的顏色穩定性的玻璃纖維增強的聚碳酸酯樹脂組成物。藉由玻璃纖維增強物，這些樹脂組成物可以增強剛性和阻燃性(flame retardancy)。然而，由於隨著時間的推移外觀快速劣化，使得這些樹脂較差地地適用于外部應用。 Korean Patent Publication No. 10-2012-0075813A discloses a glass fiber reinforced polycarbonate resin, a metal salt flame retardant, a fluorinated polyolefin resin, and a mixture of a siloxane compound and an oxime resin composition and has excellent resistance. A flammable glass fiber reinforced polycarbonate resin composition. Further, Korean Patent Publication No. 10-2012-0057276A discloses a glass fiber reinforced polycarbonate resin composition having enhanced color stability at a high temperature. These resin compositions can enhance rigidity and flame retardancy by means of glass fiber reinforcement. However, these resins are poorly suitable for external applications due to rapid deterioration in appearance over time.

為了增強外觀，可以使用注射成型如快速熱迴圈注射成型(rapid heat cycle molding，RHCM)等。然而，此方法需要昂貴的注射機和引起生產率劣化的長週期的成型週期。 In order to enhance the appearance, injection molding such as rapid heat cycle molding (RHCM) or the like can be used. However, this method requires an expensive injection machine and a long cycle molding cycle that causes productivity deterioration.

本發明的一個態樣提供了新穎的矽烷化合物、用於製備其的方法及藉由使用該矽烷化合物具有優異的剛性和外觀而沒有劣化流動性的聚碳酸酯樹脂組成物。 One aspect of the present invention provides a novel decane compound, a method for producing the same, and a polycarbonate resin composition which has excellent rigidity and appearance without deteriorating fluidity by using the decane compound.

本發明的一個態樣涉及矽烷化合物。該矽烷化合物由式1表示： 其中，R1是單鍵、醚基、羰基、硫醚基、磺基(碸基，sulfone group)、或者經取代或未經取代的C1至C20烴基，R2和R3各自獨立地是經取代或未經取代的C1至C20烴基，R4是氫原子或C1至C5烴基，X是鹵素原子、羥基、或C1至C20烷氧基，Y是單鍵、醯胺基、硫酯基、羥基伸乙基(hydroxyethylene group)、羰基、芳香基或酯基，a和b各自獨立地是從1至3的整數，a+b是4，m是從0至5的整數，n是從5至50的整數，並且p和q各自獨立地是從0至4的整數。 One aspect of the invention relates to a decane compound. The decane compound is represented by Formula 1: Wherein R 1 is a single bond, an ether group, a carbonyl group, a thioether group, a sulfone group, or a substituted or unsubstituted C 1 to C 20 hydrocarbon group, and R 2 and R 3 are each independently Is a substituted or unsubstituted C 1 to C 20 hydrocarbon group, R 4 is a hydrogen atom or a C 1 to C 5 hydrocarbon group, X is a halogen atom, a hydroxyl group, or a C 1 to C 20 alkoxy group, and Y is a single bond, Amidino, thioester, hydroxyethylene group, carbonyl, aryl or ester group, a and b are each independently an integer from 1 to 3, a+b is 4, and m is from 0 to An integer of 5, n is an integer from 5 to 50, and p and q are each independently an integer from 0 to 4.

在一個實施例中，Y可以是單鍵、醯胺基、或羥基伸乙基。 In one embodiment, Y can be a single bond, a guanamine group, or a hydroxyethyl group.

在一個實施例中，矽烷化合物可以具有從2,000g/mol至17,000g/mol的重量平均分子量。 In one embodiment, the decane compound may have a weight average molecular weight of from 2,000 g/mol to 17,000 g/mol.

本發明的另一個態樣涉及用於製備矽烷化合物的方法。 該製備方法包括：將由式2表示的矽烷化合物與由式3表示的芳香族碳酸酯化合物反應。 Another aspect of the invention relates to a process for the preparation of a decane compound. The preparation method comprises reacting a decane compound represented by Formula 2 with an aromatic carbonate compound represented by Formula 3.

其中，R4、a、b以及m如在式1中限定的，Z是鹵素原子、異氰酸酯基、硫氰酸酯基、環氧基、羧基、或鹵代羰基。 Wherein R 4 , a, b and m are as defined in Formula 1, and Z is a halogen atom, an isocyanate group, a thiocyanate group, an epoxy group, a carboxyl group, or a halogenated carbonyl group.

其中，R1、R2、R3、X、n、p以及q如在式1中限定的。 Wherein R 1 , R 2 , R 3 , X, n, p and q are as defined in Formula 1.

在一個實施例中，可以在有機溶劑的存在下，藉由在30℃至110℃下加熱並攪拌進行該反應。 In one embodiment, the reaction can be carried out by heating and stirring at 30 ° C to 110 ° C in the presence of an organic solvent.

本發明的又一態樣涉及聚碳酸酯樹脂組成物。聚碳酸酯樹脂組成物包含：聚碳酸酯樹脂、由式1表示的矽烷化合物、以及無機填料。 Still another aspect of the invention relates to a polycarbonate resin composition. The polycarbonate resin composition contains a polycarbonate resin, a decane compound represented by Formula 1, and an inorganic filler.

在一個實施例中，基於100重量份的聚碳酸酯樹脂，矽烷化合物可以以1重量份至20重量份的量存在，並且無機填料可以以5重量份至50重量份的量存在。 In one embodiment, the decane compound may be present in an amount of from 1 part by weight to 20 parts by weight based on 100 parts by weight of the polycarbonate resin, and the inorganic filler may be present in an amount of from 5 parts by weight to 50 parts by weight.

矽烷化合物和無機填料可以以1：4至1：30的重量比存在。 The decane compound and the inorganic filler may be present in a weight ratio of 1:4 to 1:30.

在一個實施例中，無機填料可以包括二氧化矽、滑石、玻璃纖維、雲母、矽灰石、玄武岩纖維、以及晶鬚(whisker)中的至少一種。 In one embodiment, the inorganic filler may include at least one of cerium oxide, talc, glass fiber, mica, ash stone, basalt fiber, and whisker.

在一個實施例中，可以將一部分或整個矽烷化合物化學鍵結至無機填料。 In one embodiment, a portion or the entire decane compound can be chemically bonded to the inorganic filler.

在一個實施例中，聚碳酸酯樹脂組成物可以具有根據ASTM D638的800kgf/cm2至1,500kgf/cm2的拉伸強度，根據ASTM D790的1,200kgf/cm2至2,000kgf/cm2的彎曲強度，30,000kgf/cm2至110,000kgf/cm2的彎曲模量、根據ASTM D256對1/8"厚的試樣測量的5kgf．cm/cm至16kgf．cm/cm的落錘衝擊強度(Izod impact strength)，根據杜邦落錘試驗方法(Dupont drop test method)對1mm厚的試樣測量的10 J至40 J的FDI(falling dart impact，落鏢衝擊)強度，以及根據ASTM D1238測量的10g/10min至80g/10min的熔體流動指數(melt flow index，MI)。 In one embodiment, the polycarbonate resin composition may have 2 to 1,500kgf according to ASTM D638 tensile strength of 800kgf / cm / cm 2 is, / cm 2 according to ASTM D790 bending of 1,200kgf / cm 2 to 2,000kgf Strength, flexural modulus of 30,000 kgf/cm 2 to 110,000 kgf/cm 2 , drop impact strength of 5 kgf.cm/cm to 16 kgf.cm/cm measured according to ASTM D256 for 1/8" thick specimens (Izod Impact strength), 10 D to 40 J FDI (falling dart impact) strength measured according to the Dupont drop test method for a 1 mm thick specimen, and 10 g/ measured according to ASTM D1238 Melt flow index (MI) from 10 min to 80 g/10 min.

圖1是在製備實例1中製備的矽烷化合物的1H-NMR光譜。 1 is a 1 H-NMR spectrum of a decane compound prepared in Preparation Example 1.

圖2描繪使用光學顯微鏡在實例和比較實例中製備的聚碳酸酯組成物的注塑試樣(injection molded specimen)(6cm×6cm)的中心表面區域(2cm×2cm)捕捉的試樣的顯微照片(micrograph)，其中每個試樣的外觀按1至10的等級分級。 2 depicts a photomicrograph of a sample captured by a central surface area (2 cm × 2 cm) of an injection molded specimen (6 cm × 6 cm) of a polycarbonate composition prepared by an optical microscope in an example and a comparative example. (micrograph), wherein the appearance of each sample is graded on a scale of 1 to 10.

在下文中，將詳細描述本發明的實施例。 Hereinafter, embodiments of the invention will be described in detail.

本發明的矽烷化合物由式1表示： 其中，R1是單鍵、醚基(-O-)、羰基(-CO-)、硫醚基(-S-)、磺基(-SO2-)、或者經取代或未經取代的C1至C20烴基，例如，C1至C15伸烷基或亞烷基、或C5至C15亞環烷基(cycloalkylidene group)；R2和R3各自獨立地是經取代或未經取代的C1至C20烴基，例如，C1至C15烷基或烷氧基、C3至C15環烷基或環烷氧基、或者C6至C15芳基或芳氧基，例如，甲基、乙基、甲氧基、或乙氧基；R4是氫原子或C1至C5烴基如甲基、乙基、丙基、丁基等；X是鹵素原子如氯原子(Cl)、溴原子(Br)等，羥基、或C1至C20烷氧基如C1至C15烷氧基；Y是單鍵、醯胺基(-NH-CO-)、硫酯基(-S-CO-)、羥基伸乙基(-C(OH)-CH2-)、羰基(-CO-)、芳香基或酯基(-O-CO-)等；a和b各自獨立地是從1至3的整數，a+b是4，例如，a可以是3，b可以是1；m是從0至5的整數；n是從5至50的整數如7至30、尤其為10至25；p和q各自獨立地是從0至4的整數。 The decane compound of the present invention is represented by Formula 1: Wherein R 1 is a single bond, an ether group (-O-), a carbonyl group (-CO-), a thioether group (-S-), a sulfo group (-SO 2 -), or a substituted or unsubstituted C a 1 to C 20 hydrocarbon group, for example, a C 1 to C 15 alkyl or alkylene group, or a C 5 to C 15 cycloalkylidene group; R 2 and R 3 are each independently substituted or not a substituted C 1 to C 20 hydrocarbon group, for example, a C 1 to C 15 alkyl or alkoxy group, a C 3 to C 15 cycloalkyl or cycloalkoxy group, or a C 6 to C 15 aryl or aryloxy group, For example, a methyl group, an ethyl group, a methoxy group, or an ethoxy group; R 4 is a hydrogen atom or a C 1 to C 5 hydrocarbon group such as a methyl group, an ethyl group, a propyl group, a butyl group or the like; and X is a halogen atom such as a chlorine atom. (Cl), a bromine atom (Br) or the like, a hydroxyl group, or a C 1 to C 20 alkoxy group such as a C 1 to C 15 alkoxy group; Y is a single bond, a guanamine group (-NH-CO-), a thioester (-S-CO-), hydroxyethyl (-C(OH)-CH 2 -), carbonyl (-CO-), aryl or ester (-O-CO-), etc.; Independently an integer from 1 to 3, a+b is 4, for example, a may be 3, b may be 1; m is an integer from 0 to 5; n is an integer from 5 to 50, such as 7 to 30, Especially 10 to 25; p and q are each independently from 0 to 4 .

如在本文中使用的，術語“經取代的”是指用選自由鹵素基團、C1至C30烷基、C1至C30鹵烷基、C6至C30芳基、C2至C30雜芳基、C1至C20烷氧基、或它們的組合所組成的族群中的取代基取代氫原子。 As used herein, the term "substituted" means selected from a halogen group, a C 1 to C 30 alkyl group, a C 1 to C 30 haloalkyl group, a C 6 to C 30 aryl group, a C 2 to A substituent in a group consisting of a C 30 heteroaryl group, a C 1 to C 20 alkoxy group, or a combination thereof, is substituted for a hydrogen atom.

在一個實施例中，矽烷化合物具有藉由凝膠滲透色譜法(gel permeation chromatography，GPC)測量的2,000g/mol至17,000g/mol的重均分子量(Mw)，但不限於此。 In one embodiment, the decane compound has a weight average molecular weight (Mw) of 2,000 g/mol to 17,000 g/mol as measured by gel permeation chromatography (GPC), but is not limited thereto.

用於製備根據本發明的矽烷化合物的方法包括：將由式2表示的矽烷化合物與由式3表示的芳香族碳酸酯化合物反應。 The method for producing a decane compound according to the present invention comprises reacting a decane compound represented by Formula 2 with an aromatic carbonate compound represented by Formula 3.

其中，R4、a、b以及m如在式1中限定的，Z是鹵素原子如氯原子(Cl)、溴原子(Br)等、異氰酸酯基(-N=C=O)、硫氰酸酯基(-S=C=O)、環氧基、羧基(-CO-OH)、鹵代碳基(-CO-R'：R'=鹵素原子)等。 Wherein R 4 , a, b and m are as defined in formula 1, Z is a halogen atom such as a chlorine atom (Cl), a bromine atom (Br) or the like, an isocyanate group (-N=C=O), thiocyanate Ester group (-S=C=O), epoxy group, carboxyl group (-CO-OH), halogenated carbon group (-CO-R': R'=halogen atom), and the like.

其中，R1、R2、R3、X、n、p以及q如在式1中限定的。 Wherein R 1 , R 2 , R 3 , X, n, p and q are as defined in Formula 1.

在一個實施例中，可以在有機溶劑的存在下，藉由在30℃至110℃，例如在60℃至100℃下加熱並攪拌進行反應1小時至48小時。 In one embodiment, the reaction may be carried out by heating and stirring at 30 ° C to 110 ° C, for example, at 60 ° C to 100 ° C for 1 hour to 48 hours in the presence of an organic solvent.

有機溶劑的實例可以包括四氫呋喃(THF)、1,4-二氧六環、二氯甲烷(CH2Cl2)、三氯甲烷(氯仿，trichloromethane)(CHCl3)、氯苯等。例如，四氫呋喃或1,4-二氧六環可以用作有機溶劑。基於100重量份的由式2表示的矽烷化合物和由式3表示的芳香族碳酸酯化合物，可以以200重量份至1,000重量份的量使用有機溶劑，但不限於此。 Examples of the organic solvent may include tetrahydrofuran (THF), 1,4-dioxane, dichloromethane (CH 2 Cl 2 ), chloroform (CHCl 3 ), chlorobenzene, and the like. For example, tetrahydrofuran or 1,4-dioxane can be used as the organic solvent. The organic solvent may be used in an amount of from 200 parts by weight to 1,000 parts by weight based on 100 parts by weight of the decane compound represented by Formula 2 and the aromatic carbonate compound represented by Formula 3, but is not limited thereto.

此外，如果需要，反應可以在催化劑的存在下進行。催化劑可以包括，例如，胺催化劑如吡啶、三乙胺、二乙胺等，但不限於此。基於100重量份的由式2表示的矽烷化合物和由式3表示的芳香族碳酸酯化合物，可以以0.1重量份至30重量份的量使用催化劑，但不限於此。 Further, if necessary, the reaction can be carried out in the presence of a catalyst. The catalyst may include, for example, an amine catalyst such as pyridine, triethylamine, diethylamine or the like, but is not limited thereto. The catalyst may be used in an amount of 0.1 part by weight to 30 parts by weight based on 100 parts by weight of the decane compound represented by Formula 2 and the aromatic carbonate compound represented by Formula 3, but is not limited thereto.

在一個實施例中，由式2表示的化合物與由式3表示的芳香族碳酸酯化合物的莫耳比可以取決於矽烷化合物的量。例如，莫耳比可以是1：1至1：10。 In one embodiment, the molar ratio of the compound represented by Formula 2 to the aromatic carbonate compound represented by Formula 3 may depend on the amount of the decane compound. For example, the molar ratio can be from 1:1 to 1:10.

根據本發明的聚碳酸酯樹脂組成物可以包含聚碳酸酯樹脂、由式1表示的矽烷化合物、以及無機填料。 The polycarbonate resin composition according to the present invention may comprise a polycarbonate resin, a decane compound represented by Formula 1, and an inorganic filler.

在本文中，聚碳酸酯樹脂是典型的熱塑性聚碳酸酯樹脂。例如，藉由將二酚(二醇化合物)與光氣、鹵甲酸酯(halogen formate)或碳酸二酯反應製備的芳香族聚碳酸酯樹脂可以用作該 聚碳酸酯樹脂。 Herein, the polycarbonate resin is a typical thermoplastic polycarbonate resin. For example, an aromatic polycarbonate resin prepared by reacting a diphenol (diol compound) with phosgene, a halogen formate or a carbonic acid diester can be used as the Polycarbonate resin.

二酚的實例可以包括4,4'-二羥基聯苯(4,4'-biphenol)、2,2-雙(4-羥苯基)丙烷、2,4-雙(4-羥苯基)-2-甲基丁烷、1,1-雙(4-羥苯基)環己烷、2,2-雙(3-氯-4-羥苯基)丙烷、2,2-雙(3,5-二氯-4-羥苯基)丙烷等。例如，二酚可以是2,2-雙(4-羥苯基)丙烷、2,2-雙(3,5-二氯-4-羥苯基)丙烷、或1,1-雙(4-羥苯基)環己烷，尤其是可以稱為雙酚A的2,2-雙(4-羥苯基)丙烷。 Examples of the diphenol may include 4,4'-dihydroxybiphenyl (4,4'-biphenol), 2,2-bis(4-hydroxyphenyl)propane, 2,4-bis(4-hydroxyphenyl) -2-methylbutane, 1,1-bis(4-hydroxyphenyl)cyclohexane, 2,2-bis(3-chloro-4-hydroxyphenyl)propane, 2,2-bis (3, 5-Dichloro-4-hydroxyphenyl)propane and the like. For example, the diphenol can be 2,2-bis(4-hydroxyphenyl)propane, 2,2-bis(3,5-dichloro-4-hydroxyphenyl)propane, or 1,1-bis(4- Hydroxyphenyl)cyclohexane, especially 2,2-bis(4-hydroxyphenyl)propane, which may be referred to as bisphenol A.

聚碳酸酯樹脂可以具有支鏈，並且可以藉由如加入0.05mol%至2mol%的三或更多多官能化合物如具有三個或更多個酚基的化合物製備。 The polycarbonate resin may have a branch and may be prepared by, for example, adding 0.05 mol% to 2 mol% of three or more polyfunctional compounds such as a compound having three or more phenol groups.

可以以均聚碳酸酯樹脂(homo polycarbonate resin)、共聚碳酸酯樹脂、或它們的摻混物的形式使用聚碳酸酯樹脂。 The polycarbonate resin may be used in the form of a homo polycarbonate resin, a copolycarbonate resin, or a blend thereof.

此外，可以用在酯前體如雙官能羧酸的存在下藉由聚合獲得的芳香族聚酯-碳酸酯樹脂部分或完全置換聚碳酸酯樹脂。 Further, the polycarbonate resin may be partially or completely replaced with an aromatic polyester-carbonate resin obtained by polymerization in the presence of an ester precursor such as a difunctional carboxylic acid.

聚碳酸酯樹脂可以具有10,000g/mol至200,000g/mol、例如，15,000g/mol至80,000g/mol的重均分子量(Mw)，但不限於此。 The polycarbonate resin may have a weight average molecular weight (Mw) of from 10,000 g/mol to 200,000 g/mol, for example, from 15,000 g/mol to 80,000 g/mol, but is not limited thereto.

在本發明中，由式1表示的矽烷化合物可以用作提高聚碳酸酯和無機填料之間的介面粘附力同時增加剛性而沒有劣化流動性的聚碳酸酯樹脂組成物中的增容劑或偶聯劑。 In the present invention, the decane compound represented by Formula 1 can be used as a compatibilizer in a polycarbonate resin composition which improves the interfacial adhesion between the polycarbonate and the inorganic filler while increasing the rigidity without deteriorating the fluidity. Coupling agent.

在一個實施例中，基於100重量份的聚碳酸酯樹脂，矽烷化合物可以以1重量份至20重量份、例如，2重量份至10重量 份的量存在。在此範圍內，聚碳酸酯樹脂組成物可以表現出優異的剛性而沒有劣化流動性。 In one embodiment, the decane compound may be from 1 part by weight to 20 parts by weight, for example, 2 parts by weight to 10 parts by weight based on 100 parts by weight of the polycarbonate resin. The amount of serving exists. Within this range, the polycarbonate resin composition can exhibit excellent rigidity without deteriorating fluidity.

在本文中，無機填料是指能夠藉由與矽烷化合物的羥基縮合形成化學鍵的材料。無機填料的實例可以包括二氧化矽、滑石、玻璃纖維、雲母、矽灰石、玄武岩纖維、晶鬚、以及它們的混合物。例如，無機填料可以是二氧化矽、滑石、玻璃纖維、雲母、玄武岩纖維、以及它們的混合物。 As used herein, an inorganic filler refers to a material capable of forming a chemical bond by condensation with a hydroxyl group of a decane compound. Examples of the inorganic filler may include cerium oxide, talc, glass fiber, mica, apatite, basalt fiber, whisker, and a mixture thereof. For example, the inorganic filler may be cerium oxide, talc, glass fiber, mica, basalt fiber, and mixtures thereof.

在一個實施例中，無機填料可以具有如50nm至100μm的平均粒徑，但不限於此。 In one embodiment, the inorganic filler may have an average particle diameter of, for example, 50 nm to 100 μm, but is not limited thereto.

在一個實施例中，玻璃纖維可以指其中用上漿劑(sizing agent)如環氧樹脂、胺甲酸乙酯、矽烷等塗覆的玻璃絲形成纖維的玻璃纖維增強劑。玻璃絲可以具有5μm至20μm的平均直徑(D)(縱橫比(L/D)：約5至約60)。玻璃纖維增強劑可以具有10μm至13μm的平均直徑(D)(縱橫比(L/D)：約5至約60)，但不限於此。此外，基於100重量份的玻璃絲，上漿劑可以以0.05重量份至0.1重量份的量存在。 In one embodiment, the glass fiber may refer to a glass fiber reinforcement in which a glass filament coated with a sizing agent such as an epoxy resin, urethane, decane, or the like is used to form a fiber. The glass filaments may have an average diameter (D) of 5 μm to 20 μm (aspect ratio (L/D): about 5 to about 60). The glass fiber reinforcing agent may have an average diameter (D) (aspect ratio (L/D): about 5 to about 60) of 10 μm to 13 μm, but is not limited thereto. Further, the sizing agent may be present in an amount of from 0.05 part by weight to 0.1 part by weight based on 100 parts by weight of the glass strand.

在一個實施例中，基於100重量份的聚碳酸酯樹脂，無機填料可以以5重量份至50重量份、例如，10重量份至30重量份的量存在。在此範圍內，樹脂組成物可以表現出優異的外觀和剛性而沒有劣化流動性。 In one embodiment, the inorganic filler may be present in an amount of from 5 parts by weight to 50 parts by weight, for example, from 10 parts by weight to 30 parts by weight, based on 100 parts by weight of the polycarbonate resin. Within this range, the resin composition can exhibit excellent appearance and rigidity without deteriorating fluidity.

此外，矽烷化合物與無機填料的重量比(矽烷化合物：無機填料)可以是1：4至1：30、例如，1：4至1：20。在此範圍內，樹 脂組成物可以表現出進一步增強的剛性、流動性、外觀等。 Further, the weight ratio of the decane compound to the inorganic filler (decane compound: inorganic filler) may be 1:4 to 1:30, for example, 1:4 to 1:20. Within this range, the tree The lipid composition can exhibit further enhanced rigidity, fluidity, appearance, and the like.

根據需要，根據本發明的熱塑性樹脂組成物可以進一步包含添加劑如阻燃助劑、滑潤劑、可塑劑、熱穩定劑、抗滴落劑(anti-dripping agent)、抗氧化劑、增容劑、光穩定劑、顏料、染料等。可以單獨使用或以其組合使用這些添加劑。例如，基於100重量份的基礎樹脂，可以以0.1重量份至10重量份的量使用添加劑，但不限於此。 The thermoplastic resin composition according to the present invention may further contain additives such as a flame retardant aid, a lubricant, a plasticizer, a heat stabilizer, an anti-dripping agent, an antioxidant, a compatibilizer, and light, as needed. Stabilizers, pigments, dyes, etc. These additives may be used singly or in combination thereof. For example, the additive may be used in an amount of 0.1 part by weight to 10 parts by weight based on 100 parts by weight of the base resin, but is not limited thereto.

在本發明的聚碳酸酯樹脂組成物中，可以將一部分或整個矽烷化合物化學鍵結至無機填料。例如，可以藉由混合組分並且在200℃至280℃、例如，250℃至260℃下在典型的雙螺杆擠出機中熔融擠出混合物獲得團塊形式(pellet form)的聚碳酸酯樹脂組成物。在此擠出溫度下，矽烷化合物的矽烷基和無機填料的羥基進行縮合以在無機填料的表面上形成共價鍵，隨後在擠出和乾燥過程中進行脫水縮合。 In the polycarbonate resin composition of the present invention, a part or the entire decane compound may be chemically bonded to the inorganic filler. For example, a polycarbonate resin in a pellet form can be obtained by mixing the components and melt-extruding the mixture in a typical twin-screw extruder at 200 ° C to 280 ° C, for example, 250 ° C to 260 ° C. Composition. At this extrusion temperature, the decyl group of the decane compound and the hydroxyl group of the inorganic filler are condensed to form a covalent bond on the surface of the inorganic filler, followed by dehydration condensation during extrusion and drying.

藉由多種模塑方法如注射成型、擠出成型、真空成型、鑄塑成型(cast molding)等，團塊狀樹脂組成物可以用於生產多種模製品。本領域技術人員熟知這些方法。 The agglomerated resin composition can be used for producing a plurality of molded articles by various molding methods such as injection molding, extrusion molding, vacuum molding, cast molding, and the like. These methods are well known to those skilled in the art.

在一個實施例中，聚碳酸酯樹脂組成物可以具有根據ASTM D638的800kgf/cm2至1,500kgf/cm2、例如，800kgf/cm2至1,200kgf/cm2、尤其是900kgf/cm2至1,000kgf/cm2的拉伸強度，根據ASTM D790的1,200kgf/cm2至2,000kgf/cm2、例如，1,300kgf/cm2至1,800kgf/cm2的彎曲強度，30,000kgf/cm2至 110,000kgf/cm2、例如，40,000kgf/cm2至75,000kgf/cm2的彎曲模量。 In one embodiment, the polycarbonate resin may have a composition in accordance with ASTM D638 of 800kgf / cm 2 to 1,500kgf / cm 2, e.g., 800kgf / cm 2 to 1,200kgf / cm 2, in particular 900kgf / cm 2 to 1,000 kgf / cm 2 in a tensile strength, according to ASTM D790 of 1,200kgf / cm 2 to 2,000kgf / cm 2, e.g., 1,300kgf / cm 2 to 1,800kgf / cm 2, bending strength, 30,000kgf / cm 2 to 110,000kgf /cm 2 , for example, a flexural modulus of 40,000 kgf/cm 2 to 75,000 kgf/cm 2 .

此外，聚碳酸酯樹脂組成物可以具有根據ASTM D256對1/8"厚的試樣測量的5kgf/cm2至16kgf/cm2的落錘衝擊強度。 Further, the polycarbonate resin may have a composition in accordance with ASTM D256 5kgf to 1/8 "thick specimen measured in / cm 2 to 16kgf / cm 2 falling weight impact strength.

聚碳酸酯樹脂組成物可以具有根據杜邦落錘試驗方法使用2kg的鏢對1mm厚的試樣(10cm×10cm×1mm)測量的10 J至40 J、例如，20 J至30 J的FDI(落鏢衝擊)強度。在此FDI強度試驗中，具有預定重量的鏢從調節的高度降落至1mm厚的試樣上以用肉眼觀察出現的裂縫。測量不出現裂縫的最大高度以計算位能(杜邦落錘試驗方法)。 The polycarbonate resin composition may have a FDI (falling) of 10 J to 40 J, for example, 20 J to 30 J, measured according to the DuPont drop weight test method using a 2 kg dart to a 1 mm thick sample (10 cm × 10 cm × 1 mm). Dart impact) strength. In this FDI strength test, a dart having a predetermined weight was dropped from the adjusted height onto a 1 mm thick sample to visually observe the crack that occurred. The maximum height at which cracks do not occur is measured to calculate the potential energy (DuPont drop test method).

此外，聚碳酸酯樹脂組成物可以具有根據ASTM D1238測量的10g/10min至80g/10min、例如，20g/10min至50g/10min的熔體流動指數(MI)。 Further, the polycarbonate resin composition may have a melt flow index (MI) of 10 g/10 min to 80 g/10 min, for example, 20 g/10 min to 50 g/10 min, measured according to ASTM D1238.

接下來，將參照一些實施例更詳細地說明本發明。然而，應當理解的是，提供的這些實施例僅用於說明而不以任何方式解釋為限制本發明。在本文中，將省去對本領域技術人員顯而易見的細節的描述。 Next, the present invention will be explained in more detail with reference to some embodiments. However, it is to be understood that the examples are provided for illustration only and are not to be construed as limiting the invention. In this document, a description of details that will be apparent to those skilled in the art will be omitted.

實施例Example 製備實例1：矽烷化合物的製備Preparation Example 1: Preparation of a decane compound

將240g(1.0mol)由式2a表示的矽烷化合物和760g(0.3mol)由式3a表示的芳香族碳酸酯化合物(n=10)溶解在 1,4-二氧六環溶劑中，並在100℃下攪拌24小時以製備由式1a表示的矽烷化合物(n=10)(產率：99%，重均分子量(由GPC測量)：5,300g/mol)。測量製備的由式1a表示的矽烷化合物的1H-NMR光譜並將結果顯示在圖1中。 240 g (1.0 mol) of a decane compound represented by Formula 2a and 760 g (0.3 mol) of an aromatic carbonate compound represented by Formula 3a (n = 10) were dissolved in a 1,4-dioxane solvent at 100 The mixture was stirred at ° C for 24 hours to prepare a decane compound (n = 10) represented by the formula 1a (yield: 99%, weight average molecular weight (measured by GPC): 5,300 g/mol). The 1 H-NMR spectrum of the prepared decane compound represented by Formula 1a was measured and the results are shown in Fig. 1.

在式1a和3a中，X是如在式1中限定的。 In Formulas 1a and 3a, X is as defined in Formula 1.

製備實例2：矽烷化合物的製備Preparation Example 2: Preparation of decane compound

除了使用760g(0.15mol)由式3a表示的芳香族碳酸酯化合物(n=20)代替760g(0.3mol)由式3a表示的芳香族碳酸酯化合物(n=10)之外，以與製備實例1中相同的方法製備由式 1a表示的矽烷化合物(n=20)(產率：98%，重均分子量：10,300g/mol)。 In addition to using 760 g (0.15 mol) of the aromatic carbonate compound represented by Formula 3a (n=20) instead of 760 g (0.3 mol) of the aromatic carbonate compound represented by Formula 3a (n=10), The same method of preparation in 1 The decane compound (n = 20) represented by 1a (yield: 98%, weight average molecular weight: 10,300 g/mol).

製備實例3：矽烷化合物的製備Preparation Example 3: Preparation of decane compound

除了使用760g(0.1mol)由式3a表示的芳香族碳酸酯化合物(n=30)代替760g(0.3mol)由式3a表示的芳香族碳酸酯化合物(n=10)之外，以與製備實例1中相同的方法製備由式1a表示的矽烷化合物(n=30)(產率：96%，重均分子量：15,300g/mol)。 In addition to using 760 g (0.1 mol) of the aromatic carbonate compound represented by Formula 3a (n=30) instead of 760 g (0.3 mol) of the aromatic carbonate compound represented by Formula 3a (n=10), The decane compound represented by Formula 1a (n = 30) was prepared by the same method in 1 (yield: 96%, weight average molecular weight: 15,300 g/mol).

用於實施例和比較例的組分的詳細情況如下。 The details of the components used in the examples and comparative examples are as follows.

(A)聚碳酸酯樹脂 (A) Polycarbonate resin

使用雙酚A聚碳酸酯(SC-1190，第一毛織株式會社，熔體指數(MI，在300℃下，根據ISO 1133在1.2kg的負荷下測量)：20g/10min)。 Bisphenol A polycarbonate (SC-1190, First Wool Co., Ltd., Melt Index (MI, measured at 300 ° C according to ISO 1133 under a load of 1.2 kg): 20 g/10 min) was used.

(B)矽烷化合物 (B) decane compound

使用在製備實例1至3中製備的矽烷化合物((B1)~(B3))。 The decane compound ((B1) to (B3))) prepared in Preparation Examples 1 to 3 was used.

(C)無機填料 (C) inorganic filler

(C1)滑石(KC-3000，高起股份有限公司，Coach Co.Ltd.) (C1) Talc (KC-3000, Gaoqi Co., Ltd., Coach Co. Ltd.)

(C2)雲母(200-HK，Suzolite) (C2) Mica (200-HK, Suzolite)

(C3)玻璃纖維：環氧樹脂塗覆的玻璃纖維增強劑(CS321,KCC) (C3) Glass Fiber: Epoxy Resin Coated Glass Fiber Reinforcer (CS321, KCC)

實例1至8和比較實例1至6Examples 1 to 8 and Comparative Examples 1 to 6

以表1和表2中列出的量混合組分，隨後在200℃至280℃下擠出混合物以製備團塊。將具有45mm直徑且L/D=36的雙螺杆擠出機用於擠出。將製備的團塊在70℃下乾燥2小時並在6盎斯(Oz)的注模機(模塑溫度：290℃，模具溫度：60℃)中注射成型以製備試樣。對製備的試樣進行如下物理性能的評估。結果顯示在表1和表2中。 The components were mixed in the amounts listed in Tables 1 and 2, followed by extruding the mixture at 200 ° C to 280 ° C to prepare agglomerates. A twin screw extruder having a diameter of 45 mm and L/D = 36 was used for extrusion. The prepared pellet was dried at 70 ° C for 2 hours and injection-molded in an injection molding machine of 6 oz (Oz) (molding temperature: 290 ° C, mold temperature: 60 ° C) to prepare a sample. The prepared samples were evaluated for the following physical properties. The results are shown in Tables 1 and 2.

[物理性能的測量][Measurement of physical properties]

(1)落錘衝擊強度(單位：kgf．cm/cm)：根據ASTM D256對1/8"厚的缺口落錘試樣測量的落錘衝擊強度。 (1) Drop weight impact strength (unit: kgf.cm/cm): Drop hammer impact strength measured according to ASTM D256 for a 1/8" thick notched weight drop specimen.

(2)FDI(落鏢衝擊)強度(單位：J)：根據杜邦落錘試驗方法，藉由將2kg的鏢降落至1mm厚的試樣(10cm×10cm×1mm)上並測量不會出現裂縫的鏢的高度以計算位能來測量FDI強度。 (2) FDI (Dart Dart Impact) Strength (Unit: J): According to the DuPont Drop Hammer Test method, a 2 kg dart was dropped onto a 1 mm thick sample (10 cm × 10 cm × 1 mm) and no crack was measured. The height of the dart is calculated to calculate the FDI intensity.

(3)拉伸強度(單位：kgf/cm2)：根據ASTM D638，以5mm/min測量拉伸強度。 (3) Tensile strength (unit: kgf/cm 2 ): The tensile strength was measured at 5 mm/min according to ASTM D638.

(4)彎曲模量和彎曲強度(單位：kgf/cm2)：根據ASTM D790，以2.8mm/min測量彎曲模量和彎曲強度。 (4) Flexural modulus and flexural strength (unit: kgf/cm 2 ): The flexural modulus and flexural strength were measured at 2.8 mm/min according to ASTM D790.

(5)熔體流動指數(MI，單位：g/10min)：在300℃下，根據ASTM D1238在5kg的負荷下測量熔體流動指數。 (5) Melt Flow Index (MI, unit: g/10 min): The melt flow index was measured at 300 ° C under a load of 5 kg according to ASTM D1238.

(6)外觀評估：使用光學顯微鏡觀察注塑試樣(6cm×6 cm)的中心表面區域(2cm×2cm)。圖2描述了其中拍攝在實例和比較實例中製備的聚碳酸酯組成物的注塑試樣(6cm×6cm)的中心表面區域(2cm×2cm)並且按1至10的等級對外觀進行評估(1是最佳(優異)而10是最差(不佳))的試樣的照片。 (6) Appearance evaluation: observation of injection molded samples using an optical microscope (6 cm × 6 The central surface area of cm) (2 cm x 2 cm). Fig. 2 depicts a central surface area (2 cm × 2 cm) of an injection molded sample (6 cm × 6 cm) in which polycarbonate compositions prepared in Examples and Comparative Examples were taken and the appearance was evaluated on a scale of 1 to 10 (1) A photograph of a sample that is optimal (excellent) and 10 is the worst (poor).

單位：重量份 Unit: parts by weight

從以上結果中可以看出，包含本發明的矽烷化合物的聚碳酸酯樹脂組成物表現出優異的剛性、流動性、以及具有1至5等級的外觀。 As can be seen from the above results, the polycarbonate resin composition containing the decane compound of the present invention exhibits excellent rigidity, fluidity, and appearance of 1 to 5 grades.

相反地，與本發明的聚碳酸酯樹脂組成物相比，不包含矽烷化合物的比較實例的聚碳酸酯樹脂組成物具有低落錘衝擊強度和FDI強度(比較實例1和2)或低拉伸強度、彎曲強度或彎曲模量(比較實例5和6)。此外，當將玻璃纖維(C3)用作無機填料時，組成物具有降低的FDI強度、流動性和外觀(比較實例3和4)。 In contrast, the polycarbonate resin composition of the comparative example containing no decane compound has low drop impact strength and FDI strength (Comparative Examples 1 and 2) or low tensile strength as compared with the polycarbonate resin composition of the present invention. , bending strength or flexural modulus (Comparative Examples 5 and 6). Further, when glass fiber (C3) was used as the inorganic filler, the composition had reduced FDI strength, fluidity, and appearance (Comparative Examples 3 and 4).

應當理解的是，在沒有背離本發明的精神和範圍的情況下，本領域技術人員可以設計多種修改、變化、變更及等同的實施方式。 It will be appreciated that various modifications, changes, variations and equivalents may be made by those skilled in the art without departing from the spirit and scope of the invention.

Claims (10)

一種矽烷化合物，由式1表示： 其中，R1是單鍵、醚基、羰基、硫醚基、磺基、或者經取代或未經取代的C1至C20烴基，R2和R3各自獨立地是經取代或未經取代的C1至C20烴基，R4是氫原子或C1至C5烴基，X是鹵素原子、羥基、或C1至C20烷氧基，Y是單鍵、醯胺基或羥基伸乙基，a和b各自獨立地是從1至3的整數，a+b是4，m是從0至5的整數，n是從5至50的整數，並且p和q各自獨立地是從0至4的整數。 A decane compound represented by Formula 1: Wherein R 1 is a single bond, an ether group, a carbonyl group, a thioether group, a sulfo group, or a substituted or unsubstituted C 1 to C 20 hydrocarbon group, and R 2 and R 3 are each independently substituted or unsubstituted. a C 1 to C 20 hydrocarbon group, R 4 is a hydrogen atom or a C 1 to C 5 hydrocarbon group, X is a halogen atom, a hydroxyl group, or a C 1 to C 20 alkoxy group, and Y is a single bond, a guanamine group or a hydroxyl group. The bases, a and b are each independently an integer from 1 to 3, a+b is 4, m is an integer from 0 to 5, n is an integer from 5 to 50, and p and q are each independently from 0. An integer of up to 4. 如申請專利範圍第1項所述的矽烷化合物，其中所述矽烷化合物具有從2,000g/mol至17,000g/mol的重量平均分子量。 The decane compound according to claim 1, wherein the decane compound has a weight average molecular weight of from 2,000 g/mol to 17,000 g/mol. 一種用於製備式1的矽烷化合物的方法，包括：將由式2表示的矽烷化合物與由式3表示的芳香族碳酸酯化合物進行反應， 其中，R1是單鍵、醚基、羰基、硫醚基、磺基、或者經取代或未經取代的C1至C20烴基，R2和R3各自獨立地是經取代或未經 取代的C1至C20烴基，R4是氫原子或C1至C5烴基，X是鹵素原子、羥基、或C1至C20烷氧基，Y是單鍵、醯胺基或羥基伸乙基，a和b各自獨立地是從1至3的整數，a+b是4，m是從0至5的整數，n是從5至50的整數，並且p和q各自獨立地是從0至4的整數； 其中，R4、a、b以及m如在式1中限定的，Z是鹵素原子、異氰酸酯基、硫氰酸酯基、環氧基、羧基、或鹵代羰基； 其中，R1、R2、R3、X、n、p以及q如在式1中限定的。 A method for producing a decane compound of Formula 1, comprising: reacting a decane compound represented by Formula 2 with an aromatic carbonate compound represented by Formula 3, Wherein R 1 is a single bond, an ether group, a carbonyl group, a thioether group, a sulfo group, or a substituted or unsubstituted C 1 to C 20 hydrocarbon group, and R 2 and R 3 are each independently substituted or unsubstituted. a C 1 to C 20 hydrocarbon group, R 4 is a hydrogen atom or a C 1 to C 5 hydrocarbon group, X is a halogen atom, a hydroxyl group, or a C 1 to C 20 alkoxy group, and Y is a single bond, a guanamine group or a hydroxyl group. The bases, a and b are each independently an integer from 1 to 3, a+b is 4, m is an integer from 0 to 5, n is an integer from 5 to 50, and p and q are each independently from 0. An integer of up to 4; Wherein R 4 , a, b and m are as defined in formula 1, Z is a halogen atom, an isocyanate group, a thiocyanate group, an epoxy group, a carboxyl group, or a halogenated carbonyl group; Wherein R 1 , R 2 , R 3 , X, n, p and q are as defined in Formula 1. 如申請專利範圍第3項所述的用於製備式1的矽烷化合物的方法，其中在有機溶劑的存在下，藉由在30℃至110℃下加熱並攪拌進行所述反應。 The method for producing a decane compound of the formula 1, as described in claim 3, wherein the reaction is carried out by heating and stirring at 30 ° C to 110 ° C in the presence of an organic solvent. 一種聚碳酸酯樹脂組成物，包含：聚碳酸酯樹脂；式1的矽烷化合物；以及無機填料，其中所述式1的矽烷化合物： 其中，R1是單鍵、醚基、羰基、硫醚基、磺基、或者經取代或未經取代的C1至C20烴基，R2和R3各自獨立地是經取代或未經取代的C1至C20烴基，R4是氫原子或C1至C5烴基，X是鹵素原子、羥基、或C1至C20烷氧基，Y是單鍵、醯胺基或羥基伸乙基，a和b各自獨立地是從1至3的整數，a+b是4，m是從0至5的整數，n是從5至50的整數，並且p和q各自獨立地是從0至4的整數。 A polycarbonate resin composition comprising: a polycarbonate resin; a decane compound of the formula 1; and an inorganic filler, wherein the decane compound of the formula 1: Wherein R 1 is a single bond, an ether group, a carbonyl group, a thioether group, a sulfo group, or a substituted or unsubstituted C 1 to C 20 hydrocarbon group, and R 2 and R 3 are each independently substituted or unsubstituted. a C 1 to C 20 hydrocarbon group, R 4 is a hydrogen atom or a C 1 to C 5 hydrocarbon group, X is a halogen atom, a hydroxyl group, or a C 1 to C 20 alkoxy group, and Y is a single bond, a guanamine group or a hydroxyl group. The bases, a and b are each independently an integer from 1 to 3, a+b is 4, m is an integer from 0 to 5, n is an integer from 5 to 50, and p and q are each independently from 0. An integer of up to 4. 如申請專利範圍第5項所述的聚碳酸酯樹脂組成物，包含：基於100重量份的聚碳酸酯樹脂，1重量份至20重量份的所述矽烷化合物以及5重量份至50重量份的所述無機填料。 The polycarbonate resin composition according to claim 5, comprising: 1 part by weight to 20 parts by weight of the decane compound and 5 parts by weight to 50 parts by weight based on 100 parts by weight of the polycarbonate resin; The inorganic filler. 如申請專利範圍第6項所述的聚碳酸酯樹脂組成物，其中所述矽烷化合物和所述無機填料以1：4至1：30的重量比存在。 The polycarbonate resin composition according to claim 6, wherein the decane compound and the inorganic filler are present in a weight ratio of 1:4 to 1:30. 如申請專利範圍第5項所述的聚碳酸酯樹脂組成物，其中所述無機填料包括二氧化矽、滑石、玻璃纖維、雲母、矽灰石、玄武岩纖維、以及晶鬚中的至少一種。 The polycarbonate resin composition according to claim 5, wherein the inorganic filler comprises at least one of cerium oxide, talc, glass fiber, mica, apatite, basalt fiber, and whiskers. 如申請專利範圍第5項所述的聚碳酸酯樹脂組成物，其中一部分或整個所述矽烷化合物化學鍵結至所述無機填料。 The polycarbonate resin composition according to claim 5, wherein a part or the whole of the decane compound is chemically bonded to the inorganic filler. 如申請專利範圍第6項所述的聚碳酸酯樹脂組成物，其 中所述聚碳酸酯樹脂組成物具有根據ASTM D638的800kgf/cm2至1,500kgf/cm2的拉伸強度、根據ASTM D790的1,200kgf/cm2至2,000kgf/cm2的彎曲強度、30,000kgf/cm2至110,000kgf/cm2的彎曲模量、根據ASTM D256對1/8"厚的試樣測量的5kgf．cm/cm至16kgf．cm/cm的落錘衝擊強度、根據杜邦落錘試驗方法對1mm厚的試樣測量的10J至40J的落鏢衝擊強度、以及根據ASTM D1238測量的10g/10min至80g/10min的熔體流動指數。 The patentable scope of application as in item 6 of the polycarbonate resin composition, wherein said polycarbonate resin composition having from 2 to 1,500kgf / cm in accordance with ASTM D638 Tensile strength of 800kgf / cm 2 according to ASTM D790 1,200kgf / cm 2 to 2,000kgf / cm 2, bending strength, 30,000kgf / cm 2 to 110,000kgf / cm 2 flexural modulus according to ASTM D256 5kgf.cm/cm specimen measurement 1/8 "thick of Drop hammer impact strength up to 16 kgf.cm/cm, dart impact strength of 10J to 40J measured on a 1 mm thick specimen according to the DuPont drop weight test method, and melting from 10 g/10 min to 80 g/10 min measured according to ASTM D1238 Body flow index.
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