TWI498646B - Image display system employing a liquid crystal device and method for fabricating the liquid crystal device - Google Patents

Image display system employing a liquid crystal device and method for fabricating the liquid crystal device Download PDF

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TWI498646B
TWI498646B TW101103027A TW101103027A TWI498646B TW I498646 B TWI498646 B TW I498646B TW 101103027 A TW101103027 A TW 101103027A TW 101103027 A TW101103027 A TW 101103027A TW I498646 B TWI498646 B TW I498646B
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liquid crystal
photoisomerization
display device
crystal display
polymer
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TW101103027A
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TW201331680A (en
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Hung Ming Shen
Wan Ling Huang
Kai Neng Yang
Tsau Hua Hsieh
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Innocom Tech Shenzhen Co Ltd
Innolux Corp
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Priority to EP20130152528 priority patent/EP2624047A3/en
Priority to JP2013015375A priority patent/JP2013156634A/en
Priority to US13/753,784 priority patent/US20130194533A1/en
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具有液晶顯示裝置之影像顯示系統及液晶顯示裝置之製造方法Image display system with liquid crystal display device and method of manufacturing liquid crystal display device

本發明係有關於一種影像顯示系統,特別是關於一種具有液晶顯示裝置的影像顯示系統。The present invention relates to an image display system, and more particularly to an image display system having a liquid crystal display device.

液晶顯示裝置利用薄型、輕量及低電力消耗之特長,而應用於範圍較廣之領域中。液晶顯示裝置可具備一對基板,基板上設置電極且基板間設置一液晶層,當對設置於基板上的電極適當地施加電壓時,可控制液晶層中所含有之液晶分子的旋轉方向。液晶顯示裝置通常具有設置於基板之液晶層側之表面的液晶配向膜以控制液晶分子之配向方向。The liquid crystal display device is used in a wide range of fields by utilizing the advantages of thinness, light weight, and low power consumption. The liquid crystal display device may include a pair of substrates, and an electrode is provided on the substrate, and a liquid crystal layer is provided between the substrates. When a voltage is appropriately applied to the electrodes provided on the substrate, the rotation direction of the liquid crystal molecules contained in the liquid crystal layer can be controlled. The liquid crystal display device usually has a liquid crystal alignment film provided on the surface of the liquid crystal layer side of the substrate to control the alignment direction of the liquid crystal molecules.

液晶配向膜主要是由聚合材料製成。液晶配向膜扮演導引液晶分子之引向器。當藉由電場之影響移動液晶分子以呈現影像時,液晶配向膜使這些分子在預定方向上定向。一般而言,需要均勻配向液晶分子以便為液晶裝置提供均勻亮度以及高對比率。The liquid crystal alignment film is mainly made of a polymeric material. The liquid crystal alignment film acts as a director for guiding the liquid crystal molecules. When the liquid crystal molecules are moved by the influence of the electric field to present an image, the liquid crystal alignment film orients the molecules in a predetermined direction. In general, it is necessary to uniformly align liquid crystal molecules in order to provide uniform brightness and high contrast ratio to the liquid crystal device.

配向液晶之習知方法包含將諸如聚醯亞胺(polyimide)之聚合物膜塗覆於玻璃基板上,以及用諸如尼龍(nylon)或聚酯之纖維(polyester)在某一方向上摩擦基板之表面。然而,摩擦方法在利用纖維摩擦聚合物膜時所產生之粉塵或靜電放電(electrostatic discharge,ESD)而引起嚴重問題。Conventional methods for aligning liquid crystals include coating a polymer film such as polyimide on a glass substrate, and rubbing the surface of the substrate in a certain direction with a polyester such as nylon or polyester. . However, the rubbing method causes serious problems in dust or electrostatic discharge (ESD) generated when the fiber is rubbed against the polymer film.

為了解決摩擦方法引起之問題,近來業界已研究光輻射配向方法(簡稱光配向),藉由在膜上照射光來誘導聚合物膜之各向異性,以便將液晶分子配向。已提出之光配向方法係利用具有光官能基之聚合物作為配向膜材料。藉由用偏振光照射使這些聚合物各向異性地光異構化、光交聯或光裂解,以便對表面提供各向異性,從而使其能夠誘導液晶分子在某一方向上配向。In order to solve the problems caused by the rubbing method, the optical radiation alignment method (referred to as photoalignment) has recently been studied in the industry, and the anisotropy of the polymer film is induced by irradiating light on the film to align the liquid crystal molecules. A photoalignment method has been proposed which utilizes a polymer having a photofunctional group as an alignment film material. These polymers are anisotropically photoisomerized, photocrosslinked, or photolyzed by irradiation with polarized light to provide anisotropy to the surface, thereby enabling it to induce alignment of the liquid crystal molecules in a certain direction.

用於液晶配向膜之材料應具有光學穩定性及熱穩定性,以便使其適用於液晶顯示裝置。然而,就此點而言,習知光配向材料所形成之配向膜光學穩定性及熱穩定性不佳,導致配向力不穩定。此外,一般來說,光配向處理法所形成之配向膜其錨定能小於利用摩擦法所形成之配向膜,如此一來會導致回應速度(response speed)的下降或是造成影像留痕。The material used for the liquid crystal alignment film should have optical stability and thermal stability so as to be suitable for use in a liquid crystal display device. However, in this regard, the alignment film formed by the conventional light alignment material has poor optical stability and thermal stability, resulting in unstable alignment force. In addition, in general, the alignment film formed by the photo-alignment processing method has an anchoring energy smaller than that of the alignment film formed by the rubbing method, which may cause a decrease in the response speed or cause image sticking.

基於上述,目前業界亟需一種新穎的光配向方法,來形成具有高穩定性及錨定效果的配向膜,來解決習知技術所目臨的問題。Based on the above, there is a need in the industry for a novel photo-alignment method to form an alignment film having high stability and anchoring effect to solve the problems posed by the prior art.

有鑑於此,本發明提供一種具有液晶顯示裝置之影像顯示系統,其具有改良的光異構化配向層,與傳統光異構化配向法相比,具有較高的配向效果及光學穩定性。此外,本發明亦提供一種影像顯示系統的製造方法,可減少光異構化高分子層的照光時間,並增加配向膜穩定性及錨定效果,達到降低成本以及提高產能的目的。In view of the above, the present invention provides an image display system having a liquid crystal display device, which has an improved photoisomerization alignment layer, which has higher alignment effect and optical stability than the conventional photo isomerization alignment method. In addition, the present invention also provides a method for manufacturing an image display system, which can reduce the illumination time of the photoisomerization polymer layer, increase the stability and anchoring effect of the alignment film, and achieve the purpose of reducing cost and increasing productivity.

本發明所述之影像顯示系統包括一液晶顯示裝置,而該液晶顯示裝置包含:一上基板與一下基板,其中該上基板與該下基板係相互平行設置;一第一光異構化配向層配置於該下基板之上表面,以及一第二光異構化配向層配置於該上基板之下表面,其中該第一光異構化配向層及該第二光異構化配向層表面具有複數之突起,且該突起係由一非極性單體經聚合反應所形成,其中該非極性單體具有2或3個丙烯酸酯官能基;以及,一橫向電場切換(In-Plane Switching)液晶層配置於該第一光異構化配向層及該第二光異構化配向層之間。根據本發明一實施例,該液晶顯示裝置係為一橫向電場切換液晶顯示裝置。The image display system of the present invention comprises a liquid crystal display device, and the liquid crystal display device comprises: an upper substrate and a lower substrate, wherein the upper substrate and the lower substrate are arranged in parallel with each other; a first photoisomerization alignment layer And disposed on the upper surface of the lower substrate, and a second photoisomerization alignment layer disposed on the lower surface of the upper substrate, wherein the first photo isomerization alignment layer and the second photo isomerization alignment layer have a surface a plurality of protrusions formed by polymerization of a non-polar monomer having 2 or 3 acrylate functional groups; and a transverse electric field switching (In-Plane Switching) liquid crystal layer configuration And between the first photo-isomerization alignment layer and the second photo-isomerization alignment layer. According to an embodiment of the invention, the liquid crystal display device is a lateral electric field switching liquid crystal display device.

本發明亦提供上述液晶顯示裝置之製造方法,包括:提供一上基板與一下基板,其中該上基板與該下基板係相互平行設置;在上基板之下表面塗佈一第一光異構化高分子層,以及在該下基板之上表面塗佈一第二光異構化高分子層;對該第一光異構化高分子層及該第二光異構化高分子層施以一第一能量,分別形成一第一光異構化配向層及一第二光異構化配向層;注入一液晶組合物於該第一光異構化配向層及該第二光異構化配向層之間,其中該液晶組合物包含一橫向電場切換(In-Plane Switching)液晶以及一非極性單體,且該非極性單體具有2或3個丙烯酸酯官能基;以及,對該液晶組合物施以一第二能量,以在該第一光異構化配向層及該第二光異構化配向層之表面形成複數個突起,其中該突起係為該非極性單體經聚合反應所形成。The present invention also provides a method for fabricating the above liquid crystal display device, comprising: providing an upper substrate and a lower substrate, wherein the upper substrate and the lower substrate are disposed in parallel with each other; and coating a first photo isomerization on a lower surface of the upper substrate a polymer layer, and coating a second photoisomerization polymer layer on the upper surface of the lower substrate; applying a first photoisomerization polymer layer and the second photo isomerization polymer layer a first energy, respectively forming a first photoisomerization alignment layer and a second photo isomerization alignment layer; injecting a liquid crystal composition in the first photo isomerization alignment layer and the second photo isomerization alignment Between the layers, wherein the liquid crystal composition comprises a transverse electric field switching (In-Plane Switching) liquid crystal and a non-polar monomer, and the non-polar monomer has 2 or 3 acrylate functional groups; and, the liquid crystal composition Applying a second energy to form a plurality of protrusions on the surface of the first photoisomerization alignment layer and the second photo isomerization alignment layer, wherein the protrusions are formed by polymerization of the non-polar monomer.

為使本發明之上述目的、特徵能更明顯易懂,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下:In order to make the above objects and features of the present invention more comprehensible, the following detailed description of the preferred embodiments and the accompanying drawings

請參照第1圖,其顯示本發明一實施例所述之液晶顯示裝置100,該液晶顯示裝置100包含:一下基板12與一上基板14,其中該上基板14與該下基板12係相互平行設置。該下基板12與上基板14可為透明基板,例如為一玻璃基板。一第一光異構化配向層16配置於該下基板12之上表面11之上,以及一第二光異構化配向層18配置於該上基板14之下表面13之上。該第一光異構化配向層16及第二光異構化配向層18係藉由對一光異構化高分子施以一第一能量後所形成之膜層,其中該光異構化高分子可為偶氮高分子,例如芳香族偶氮高分子。舉例來說,該光異構化高分子可為一具有丙烯酸酯基的偶氮苯(azobenzene)單體經聚合反應所形得,其中該具有丙烯酸酯基的偶氮苯(azobenzene)單體可例如具有以下結構:(其中R1 係為氫、或C1-6 烷基)。值得注意的是,請參照第2圖,係為第1圖所示區域2的局部放大示意圖,該第一光異構化配向層16的上表面15(以及該第二光異構化配向層18的下表面17)係具有複數的突起22(該突起可具有一高度不大於20nm、以及一寬度不大於200nmnm)。其中,該突起22係由一非極性單體經施以一第二能量後藉由聚合反應所形成,其中該非極性單體具有2或3個丙烯酸酯官能基。舉例來說,該非極性單體可具有以下結構:Referring to FIG. 1 , a liquid crystal display device 100 according to an embodiment of the present invention includes a lower substrate 12 and an upper substrate 14 , wherein the upper substrate 14 and the lower substrate 12 are parallel to each other. Settings. The lower substrate 12 and the upper substrate 14 may be transparent substrates, such as a glass substrate. A first photoisomerization alignment layer 16 is disposed on the upper surface 11 of the lower substrate 12, and a second photo isomerization alignment layer 18 is disposed on the lower surface 13 of the upper substrate 14. The first photoisomerization alignment layer 16 and the second photoisomerization alignment layer 18 are formed by applying a first energy to a photoisomerization polymer, wherein the photoisomerization is performed. The polymer may be an azo polymer such as an aromatic azo polymer. For example, the photoisomerization polymer can be formed by polymerization of an azobenzene monomer having an acrylate group, wherein the azobenzene monomer having an acrylate group can be used. For example, it has the following structure: (wherein R 1 is hydrogen or C 1-6 alkyl). It should be noted that, referring to FIG. 2, it is a partially enlarged schematic view of the region 2 shown in FIG. 1, the upper surface 15 of the first photoisomerization alignment layer 16 (and the second photoisomerization alignment layer). The lower surface 17) of 18 has a plurality of protrusions 22 (which may have a height of no more than 20 nm and a width of no more than 200 nm nm). Wherein, the protrusion 22 is formed by a polymerization reaction by applying a second energy to a non-polar monomer, wherein the non-polar monomer has 2 or 3 acrylate functional groups. For example, the non-polar monomer can have the following structure:

(其中m及m’係各自獨立的整數並介於1-7之間,n係為一整數介於1-5之間)。該複數的突起22可發揮錨定效果,穩定並提昇該第一光異構化配向層16及第二光異構化配向層18的配向力。 (where m and m' are independent integers and are between 1 and 7, and n is an integer between 1 and 5). The plurality of protrusions 22 can exert an anchoring effect to stabilize and enhance the alignment force of the first photoisomerization alignment layer 16 and the second photo isomerization alignment layer 18.

仍請參照第1圖,一橫向電場切換(In-Plane Switching)液晶層20配置於該第一光異構化配向層16及該第二光異構化配向層18之間。根據本發明一實施例,該液晶顯示裝置係為一橫向電場切換液晶顯示裝置。Still referring to FIG. 1 , an In-Plane Switching liquid crystal layer 20 is disposed between the first photo-isomerization alignment layer 16 and the second photo-isomerization alignment layer 18 . According to an embodiment of the invention, the liquid crystal display device is a lateral electric field switching liquid crystal display device.

請參照第3圖,係為上述第1圖所示之液晶顯示裝置100的製程步驟流程圖,該液晶顯示裝置的製造方法,可包含以下步驟:首先,提供一上基板與一下基板,其中該上基板與該下基板係相互平行設置(步驟101)。接著,在上基板之下表面塗佈一第一光異構化高分子層,以及在該下基板之上表面塗佈一第二光異構化高分子層(步驟102)。該光異構化高分子可為偶氮高分子,例如芳香族偶氮高分子。舉例來說,該光異構化高分子可為一具有丙烯酸酯基的偶氮苯(azobenzene)單體經聚合反應所形得,其中該具有丙烯酸酯基的偶氮苯(azobenzene)單體可例如具有以下結構:(其中R1 係為氫、或C1-6 烷基)。接著,在完成上述光異構化高分子層的塗佈後,對該第一光異構化高分子層及該第二光異構化高分子層施以一第一能量,以分別形成一第一光異構化配向層及一第二光異構化配向層(步驟103)。值得注意的是,該第一能量可為具有365nm波長的紫外線(可為一般UV光或線性偏極光),而對該第一光異構化高分子層及該第二光異構化高分子層施以該第一能量的時間可為1-10秒(UV強度強)、照度可介於10~80mW、而總照射量可為至0.01J~0.8J。在形成該第一光異構化配向層及一第二光異構化配向層後,可注入一液晶組合物於該第一光異構化配向層及該第二光異構化配向層之間(步驟104),其中,該液晶組合物可包含一橫向電場切換(In-Plane Switching)液晶以及一非極性單體,且該非極性單體具有2或3個丙烯酸官能基。舉例來說,該非極性單體可具有以下結構:Referring to FIG. 3 , it is a flowchart of a process of the liquid crystal display device 100 shown in FIG. 1 . The method for manufacturing the liquid crystal display device may include the following steps: first, providing an upper substrate and a lower substrate, wherein the method The upper substrate and the lower substrate are disposed in parallel with each other (step 101). Next, a first photoisomerization polymer layer is coated on the lower surface of the upper substrate, and a second photoisomerization polymer layer is coated on the upper surface of the lower substrate (step 102). The photoisomerized polymer may be an azo polymer such as an aromatic azo polymer. For example, the photoisomerization polymer can be formed by polymerization of an azobenzene monomer having an acrylate group, wherein the azobenzene monomer having an acrylate group can be used. For example, it has the following structure: (wherein R 1 is hydrogen or C 1-6 alkyl). Next, after the coating of the photoisomerization polymer layer is completed, a first energy is applied to the first photoisomerization polymer layer and the second photoisomerization polymer layer to form a first energy The first photoisomerization alignment layer and a second photoisomerization alignment layer (step 103). It should be noted that the first energy may be ultraviolet light having a wavelength of 365 nm (which may be general UV light or linear polarized light), and the first photoisomerized polymer layer and the second photoisomerized polymer The layer may apply the first energy for 1-10 seconds (high UV intensity), the illuminance may be between 10 and 80 mW, and the total exposure may be from 0.01 J to 0.8 J. After forming the first photo-isomerization alignment layer and a second photo-isomerization alignment layer, a liquid crystal composition may be injected into the first photo-isomerization alignment layer and the second photo-isomerization alignment layer. (Step 104), wherein the liquid crystal composition may comprise a transverse electric field switching (In-Plane Switching) liquid crystal and a non-polar monomer, and the non-polar monomer has 2 or 3 acrylic functional groups. For example, the non-polar monomer can have the following structure:

(其中m及m’係各自獨立的整數並介於1-7之間,n係為一整數介於1-5之間)。在該液晶組合物中,該非極性單體具有一重量百分比介於0.05-3wt%,例如:0.3 wt %、0.5 wt %、1 wt %、1.5 wt %、或3 wt %(該重量百分比係以該液晶組合物之總重為基準)。當非極性單體之重量百分比小於0.05wt%時,可能造成光配向能力不足的問題;而當非極性單體之重量百分比大於3wt%時,過多的非極性單體又可能造成液晶分子排列時的紊亂。此外,該液晶組合物的注入方式可為液晶滴入製程(One Drop Filling、ODF)。最後,在注入該液晶組合物之後,對該液晶組合物施以一第二能量(步驟105),以使液晶組合物內的非極性單體進行聚合反應,並附著於該第一光異構化配向層及第二光異構化配向層上,以在該第一光異構化配向層及該第二光異構化配向層之表面上形成複數個突起,得到該液晶顯示裝置。該第二能量可為具有310-400nm波長的紫外線(可為一般UV光或線性偏極光),而對該液晶組合物施以該第二能量的時間可為100-1800秒、照度可介於5~10mW、而總照射量可為0.5J~18J。 (where m and m' are independent integers and are between 1 and 7, and n is an integer between 1 and 5). In the liquid crystal composition, the non-polar monomer has a weight percentage of 0.05 to 3 wt%, for example, 0.3 wt%, 0.5 wt%, 1 wt%, 1.5 wt%, or 3 wt% (the weight percentage is The total weight of the liquid crystal composition is based on the basis). When the weight percentage of the non-polar monomer is less than 0.05% by weight, the problem of insufficient photo-alignment ability may be caused; and when the weight percentage of the non-polar monomer is more than 3% by weight, excessive non-polar monomers may cause alignment of the liquid crystal molecules. Disorder. Further, the liquid crystal composition may be injected into a One Drop Filling (ODF) process. Finally, after injecting the liquid crystal composition, the liquid crystal composition is subjected to a second energy (step 105) to polymerize the non-polar monomer in the liquid crystal composition and adhere to the first photo-isomerization. The alignment layer and the second photoisomerization alignment layer are formed with a plurality of protrusions on the surface of the first photoisomerization alignment layer and the second photo isomerization alignment layer to obtain the liquid crystal display device. The second energy may be ultraviolet light having a wavelength of 310-400 nm (which may be general UV light or linear polarized light), and the time for applying the second energy to the liquid crystal composition may be 100-1800 seconds, and the illuminance may be between 5~10mW, and the total exposure can be 0.5J~18J.

為了讓本發明之上述和其他目的、特徵、和優點能更明顯易懂,下文特舉實施例,來說明本發明所述之液晶顯示裝置的製備方法。The above and other objects, features and advantages of the present invention will become more apparent and understood.

實施例Example

首先,取兩片透明玻璃基板在其上分別塗佈光異構化高分子層並且將兩基板平行設置,以使兩基板塗佈光異構化高分子層的表面對向。其中該光異構化高分子層係由具有以下結構的單體經聚合而成,厚度可為400~800mm。接著,以365nm波長的紫外線照射該光異構化高分子層,照射時間為10~500秒、照度為10~80mW、而總照射量可為0.8~5J,得到上下兩層光異構化配向層。接著,將一液晶組合物(由IPS液晶(由Merck製造販售)與一非極性單體(具有以下結構:)所混合,其中該非極性單體具有一重量百分比為0.3wt%,以該液晶組合物總重為基準)以液晶滴入製程(One Drop Filling、ODF)注入兩基板間,使液晶組合物與上下光異構化配向層接觸。最後,對該液晶組合物照射一波長含蓋310-400nm波長的紫外線,以使液晶組合物內的非極性單體進行聚合反應,並附著於一上下光異構化配向層上,以形成複數個突起。該310-400nm波長紫外線的照射時間為100-1800秒、照度為5~10mW、而總照射量可為0.5~18J。請參照第5圖,係為實施例所得之具有複數突起之光異構化配向層的SEM(掃描式電子顯微鏡)光譜圖。First, two transparent glass substrates are coated thereon with a photoisomerization polymer layer, and the two substrates are placed in parallel so that the surfaces of the two substrates coated with the photoisomerization polymer layer face each other. Wherein the photoisomerized polymer layer is polymerized from a monomer having the following structure The thickness can be 400~800mm. Next, the photoisomerization polymer layer is irradiated with ultraviolet light having a wavelength of 365 nm, and the irradiation time is 10 to 500 seconds, the illuminance is 10 to 80 mW, and the total irradiation amount is 0.8 to 5 J, and the upper and lower layers of photoisomerization alignment are obtained. Floor. Next, a liquid crystal composition (sold by IPS liquid crystal (sold by Merck) and a non-polar monomer (having the following structure: Mixing, wherein the non-polar monomer has a weight percentage of 0.3% by weight based on the total weight of the liquid crystal composition) and is injected between the two substrates by a One Drop Filling (ODF) process to cause the liquid crystal composition to The upper and lower photoisomerization alignment layer is in contact. Finally, the liquid crystal composition is irradiated with ultraviolet light having a wavelength of 310-400 nm at a wavelength to polymerize the non-polar monomer in the liquid crystal composition, and adhered to an upper and lower photoisomerization alignment layer to form a plurality Protrusions. The irradiation time of the 310-400 nm ultraviolet light is 100-1800 seconds, the illuminance is 5-10 mW, and the total irradiation amount is 0.5-18 J. Referring to Fig. 5, there is shown a SEM (scanning electron microscope) spectrum of the photoisomerization alignment layer having a plurality of protrusions obtained in the examples.

基於上述,本發明所述之液晶顯示裝置及其製造方法,除了使用光異構化配向層外,進一步使用一具有非極性單體的液晶組合物與光異構化配向層接觸,並施加一能量使非極性單體在光異構化配向層表面聚合。由於非極性單體聚合後所形成的複數突起可發揮錨定效果,增強配向力及穩定性,可進一步減少在形成光異構化配向膜步驟時,對該光異構化高分子層施加紫外線(波長365nm)的時間。由於波長為365nm的紫外線設備動輒上億元,因此減少該設備的時用時間除了可降低成本外,亦可達到提高產能的目的。Based on the above, the liquid crystal display device and the method of manufacturing the same according to the present invention, in addition to using a photoisomerization alignment layer, further use a liquid crystal composition having a non-polar monomer to contact the photoisomerization alignment layer, and apply a The energy causes the non-polar monomer to polymerize on the surface of the photoisomerization alignment layer. Since the complex protrusion formed by the polymerization of the non-polar monomer can exert an anchoring effect, enhance the alignment force and stability, and further reduce the application of ultraviolet rays to the photoisomerization polymer layer in the step of forming the photoisomerization alignment film Time (wavelength 365 nm). Since the ultraviolet equipment with a wavelength of 365 nm is hundreds of millions of dollars, reducing the time of use of the equipment can not only reduce the cost, but also achieve the purpose of increasing the production capacity.

第4圖係顯示根據本發明實施例包含液晶顯示裝置100之影像顯示系統200之的方塊示意圖。影像顯示系統 200可更具有一控制單元50耦接至液晶顯示裝置100。控制單元50包括一微處理器,用以將訊號輸入至液晶顯示裝置100,經處理後顯示影像。影像顯示系統200包括例如個人數位理(PDA)、攜帶式手機(mobile phone)、筆記型電腦、手提電腦或其他可攜式電子裝置。4 is a block diagram showing an image display system 200 including a liquid crystal display device 100 in accordance with an embodiment of the present invention. Image display system The control unit 50 can be coupled to the liquid crystal display device 100. The control unit 50 includes a microprocessor for inputting signals to the liquid crystal display device 100, and processing the images to display images. Image display system 200 includes, for example, a personal digital device (PDA), a mobile phone, a notebook computer, a laptop computer, or other portable electronic device.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為基準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope is based on the definition of the scope of the patent application attached.

2‧‧‧區域2‧‧‧ Area

11‧‧‧下基板之上表面11‧‧‧ Upper surface of the lower substrate

12‧‧‧下基板12‧‧‧ Lower substrate

13‧‧‧上基板之下表面13‧‧‧Under the lower surface of the substrate

14‧‧‧上基板14‧‧‧Upper substrate

15‧‧‧第一光異構化配向層上表面15‧‧‧First photoisomerization alignment layer upper surface

16‧‧‧第一光異構化配向層16‧‧‧First photoisomerization alignment layer

17‧‧‧第二光異構化配向層下表面17‧‧‧Second photoisomerization alignment layer lower surface

18‧‧‧第二光異構化配向層18‧‧‧Second photoisomerization alignment layer

20‧‧‧橫向電場切換液晶層20‧‧‧Transverse electric field switching liquid crystal layer

22‧‧‧突起22‧‧‧ Protrusion

50‧‧‧控制單元50‧‧‧Control unit

100‧‧‧液晶顯示裝置100‧‧‧Liquid crystal display device

101-105‧‧‧步驟101-105‧‧‧Steps

200‧‧‧影像顯示系統200‧‧‧Image Display System

第1圖顯示根據本發明之一實施例所繪示的液晶顯示裝置剖面示意圖。1 is a cross-sectional view showing a liquid crystal display device according to an embodiment of the invention.

第2圖顯示第1圖區域2的局部放大示意圖。Fig. 2 is a partially enlarged schematic view showing a region 2 of Fig. 1.

第3圖係根據本發明一實施例所述之液晶顯示裝置製造方法之步驟流程圖。3 is a flow chart showing the steps of a method of fabricating a liquid crystal display device according to an embodiment of the invention.

第4圖係繪示根據本發明一實施例之影像顯示系統方塊示意圖。4 is a block diagram showing an image display system according to an embodiment of the invention.

第5圖係為實施例所得之具有複數突起之光異構化配向層的SEM(掃描式電子顯微鏡)光譜圖。Fig. 5 is a SEM (Scanning Electron Microscope) spectrum of the photoisomerization alignment layer having a plurality of protrusions obtained in the examples.

2...區域2. . . region

11...下基板之上表面11. . . Upper surface of lower substrate

12...下基板12. . . Lower substrate

13...上基板之下表面13. . . Lower surface of the upper substrate

14...上基板14. . . Upper substrate

15...第一光異構化配向層上表面15. . . First photoisomerization alignment layer upper surface

16...第一光異構化配向層16. . . First photoisomerization alignment layer

17...第二光異構化配向層下表面17. . . Second photoisomerization alignment layer lower surface

18...第二光異構化配向層18. . . Second photoisomerization alignment layer

20...橫向電場切換液晶層20. . . Transverse electric field switching liquid crystal layer

100...液晶顯示裝置100. . . Liquid crystal display device

Claims (18)

一種具有液晶顯示裝置之影像顯示系統,包含:一液晶顯示裝置,其中該液晶顯示裝置包含:一第一基板與一第二基板,其中該第一基板之第一表面與該第二基板之第三表面係相互平行設置;一第一光異構化配向層配置於該第二基板之第三表面,以及一第二光異構化配向層配置於該第一基板之第一表面,其中該第一光異構化配向層及該第二光異構化配向層表面及具有複數之突起,且該突起係由一非極性單體經聚合反應所形成,其中該非極性單體具有以下結構: ,其中m及m’係各自獨立的整數並介於1-7之間,n係為一整數介於1-5之間;以及一橫向電場切換(In-Plane Switching)液晶層配置於該第一光異構化配向層及該第二光異構化配向層之間。An image display system having a liquid crystal display device, comprising: a liquid crystal display device, wherein the liquid crystal display device comprises: a first substrate and a second substrate, wherein the first surface of the first substrate and the second substrate The third surface is disposed in parallel with each other; a first photoisomerization alignment layer is disposed on the third surface of the second substrate, and a second photoisomerization alignment layer is disposed on the first surface of the first substrate, wherein the The first photoisomerization alignment layer and the surface of the second photoisomerization alignment layer and having a plurality of protrusions, and the protrusions are formed by polymerization of a non-polar monomer having the following structure: Wherein m and m' are each an independent integer and are between 1 and 7, and n is an integer between 1 and 5; and a transverse electric field switching (In-Plane Switching) liquid crystal layer is disposed in the first A photoisomerization alignment layer and the second photoisomerization alignment layer. 如申請專利範圍第1項所述之具有液晶顯示裝置之影像顯示系統,其中該第一光異構化配向層及第二光異構化配向層係一光異構化高分子經施以一第一能量後所形成。 The image display system with a liquid crystal display device according to claim 1, wherein the first photoisomerization alignment layer and the second photoisomerization alignment layer-photoisomerization polymer are subjected to After the first energy is formed. 如申請專利範圍第2項所述之具有液晶顯示裝置之影像顯示系統,其中該光異構化高分子係為偶氮高分子。 An image display system having a liquid crystal display device according to claim 2, wherein the photoisomerization polymer is an azo polymer. 如申請專利範圍第2項所述之具有液晶顯示裝置之影像顯示系統,其中該光異構化高分子係為芳香族偶氮高分子。 An image display system having a liquid crystal display device according to claim 2, wherein the photoisomerization polymer is an aromatic azo polymer. 如申請專利範圍第2項所述之具有液晶顯示裝置之影像顯示系統,其中該光異構化高分子係由以下單體經聚合反應而得: ,其中R1 係為氫、或C1-6 烷基。An image display system having a liquid crystal display device according to claim 2, wherein the photoisomerization polymer is obtained by polymerization of the following monomers: Wherein R 1 is hydrogen or C 1-6 alkyl. 如申請專利範圍第1項所述之具有液晶顯示裝置之影像顯示系統,其中突起係由對該非極性單體經施以一第二能量後所形成。 An image display system having a liquid crystal display device according to claim 1, wherein the protrusion is formed by applying a second energy to the non-polar monomer. 如申請專利範圍第1項所述之具有液晶顯示裝置之影像顯示系統,其中該液晶顯示裝置係為一橫向電場切換液晶顯示裝置。 An image display system having a liquid crystal display device according to claim 1, wherein the liquid crystal display device is a lateral electric field switching liquid crystal display device. 一種液晶顯示裝置之製造方法,包含:提供一第一基板與一第二基板,其中該第一基板之第一表面與該第二基板之第三表面係相互平行設置;在第一基板之第一表面塗佈一第一光異構化高分子層,以及在該第二基板之第三表面塗佈一第二光異構化高分子層;對該第一光異構化高分子層及該第二光異構化高分子層施以一第一能量,分別形成一第一光異構化配向層及一第二光異構化配向層;注入一液晶組合物於該第一光異構化配向層及該第二光異構化配向層之間,其中該液晶組合物包含一橫向電場切換(In-Plane Switching)液晶以及一非極性單體,且該非極性單體具有以下結構: ,其中m及m’係各自獨立的整數並介於1-7之間,n係為一整數介於1-5之間;以 及對該液晶組合物施以一第二能量,以在該第一光異構化配向層及該第二光異構化配向層之表面形成複數個突起,其中該突起係為該非極性單體經聚合反應所形成。A method for manufacturing a liquid crystal display device includes: providing a first substrate and a second substrate, wherein a first surface of the first substrate and a third surface of the second substrate are disposed in parallel with each other; Coating a first photoisomerization polymer layer on a surface, and coating a second photoisomerization polymer layer on the third surface of the second substrate; the first photoisomerization polymer layer and The second photoisomerization polymer layer applies a first energy to form a first photoisomerization alignment layer and a second photo isomerization alignment layer, respectively; and injecting a liquid crystal composition into the first photo-distribution layer Between the alignment layer and the second photoisomerization alignment layer, wherein the liquid crystal composition comprises a transverse electric field switching (In-Plane Switching) liquid crystal and a non-polar monomer, and the non-polar monomer has the following structure: Wherein m and m' are each an independent integer and are between 1 and 7, and n is an integer between 1 and 5; and a second energy is applied to the liquid crystal composition to A plurality of protrusions are formed on a surface of the photoisomerization alignment layer and the second photoisomerization alignment layer, wherein the protrusions are formed by polymerization of the non-polar monomer. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該第一光異構化高分子層及第二光異構化高分子層包含偶氮高分子。 The method for producing a liquid crystal display device according to claim 8, wherein the first photoisomerization polymer layer and the second photoisomerization polymer layer comprise an azo polymer. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該第一光異構化高分子層及第二光異構化高分子層包含芳香族偶氮高分子。 The method for producing a liquid crystal display device according to claim 8, wherein the first photoisomerization polymer layer and the second photoisomerization polymer layer comprise an aromatic azo polymer. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該第一光異構化高分子層及第二光異構化高分子層係由以下單體經聚合反應而得: ,其中R1 係為氫、或C1-6 烷基。The method for manufacturing a liquid crystal display device according to claim 8, wherein the first photoisomerization polymer layer and the second photoisomerization polymer layer are obtained by polymerization of the following monomers: Wherein R 1 is hydrogen or C 1-6 alkyl. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該非極性單體具有一重量百分比介於0.05-3wt%,該重量百分比係以該液晶組合物之總重為基準。 The method of manufacturing a liquid crystal display device according to claim 8, wherein the non-polar monomer has a weight percentage of 0.05 to 3% by weight based on the total weight of the liquid crystal composition. 如申請專利範圍第8項所述之液晶顯示裝置之製 造方法,其中該第一能量係為具有365nm波長的紫外線。 The system for liquid crystal display device as described in claim 8 The method, wherein the first energy system is ultraviolet light having a wavelength of 365 nm. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中施以該第一能量的時間係為1-10秒。 The method of manufacturing a liquid crystal display device according to claim 8, wherein the time for applying the first energy is 1-10 seconds. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該第二能量係為具有310-400nm波長的紫外線。 The method of manufacturing a liquid crystal display device according to claim 8, wherein the second energy system is ultraviolet light having a wavelength of 310 to 400 nm. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中施以該第二能量的時間係為100-1800秒。 The method of manufacturing a liquid crystal display device according to claim 8, wherein the time for applying the second energy is 100 to 1800 seconds. 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該第一光異構化高分子層包含偶氮高分子以及第二光異構化高分子層包含芳香族偶氮高分子。 The method of manufacturing a liquid crystal display device according to claim 8, wherein the first photoisomerization polymer layer comprises an azo polymer and the second photoisomerization polymer layer comprises an aromatic azo polymer. . 如申請專利範圍第8項所述之液晶顯示裝置之製造方法,其中該第二光異構化高分子層包含偶氮高分子以及第一光異構化高分子層包含芳香族偶氮高分子。 The method for producing a liquid crystal display device according to claim 8, wherein the second photoisomerization polymer layer comprises an azo polymer and the first photoisomerization polymer layer comprises an aromatic azo polymer. .
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