TWI498089B - Cigarette - Google Patents
Cigarette Download PDFInfo
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- TWI498089B TWI498089B TW101127938A TW101127938A TWI498089B TW I498089 B TWI498089 B TW I498089B TW 101127938 A TW101127938 A TW 101127938A TW 101127938 A TW101127938 A TW 101127938A TW I498089 B TWI498089 B TW I498089B
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/17—Filters specially adapted for simulated smoking devices
Description
本發明係關於具備含有香料膠囊之香煙用濾嘴的香煙。The present invention relates to a cigarette having a filter for a cigarette containing a fragrance capsule.
以往以來，將香料膠囊組裝入香煙用濾嘴，在使用時壓壞香料膠囊並在吸煙時品嚐內容液之香味，並進行消化後之煙蒂之味道的遮蔽(專利文獻1及2)。有關香料膠囊之詳細內容，係例如記載於專利文獻3。In the past, the flavor capsules were placed in a filter for cigarettes, and the flavor capsules were crushed during use, and the flavor of the content liquid was tasted during smoking, and the taste of the cigarette butts after digestion was masked (Patent Documents 1 and 2). The details of the flavor capsule are described, for example, in Patent Document 3.
外層紙(tipping paper)及插件捲取紙係使濾嘴與煙草棒之連接處不被看見，因吸煙使焦油附著於濾嘴之濾材，為了擔當使焦油顏色不被看見之遮蓋角色，一般係使用不透明紙。木炭濾嘴之情形，除了上述功能，不透明外層紙及插件捲取紙也擔當使活性碳顏色不被看見的角色。The tipping paper and the insert paper take-up paper make the connection between the filter and the tobacco rod not visible. Because the smoking causes the tar to adhere to the filter material of the filter, in order to protect the role of the tar color from being seen, the general system is Use opaque paper. In the case of the charcoal filter, in addition to the above functions, the opaque outer paper and the insert take-up paper also function as a role in which the activated carbon color is not seen.
另一方面，使用透明之外層紙及透明之插件捲取紙，並進行濾嘴內部之可視化(專利文獻4至6)。On the other hand, paper is taken up using a transparent outer layer paper and a transparent insert, and the inside of the filter is visualized (Patent Documents 4 to 6).
為了使濾嘴內部為可視化，專利文獻4揭示使用透明材料作為外層紙及插件捲取紙，並在外層紙一部份實施不透明塗佈而賦予遮掩功能。專利文獻4中，透明材料係例示有聚丙烯、聚氯乙烯、纖維素乙酸酯膜、聚對苯二甲酸乙二酯、聚氧乙烯、聚乙烯、賽璐玢(cellophane)、Natureflex(註冊商標)及聚醋酸。此外，專利文獻4揭示若可使濾嘴內部可視化，則為了提供濾嘴之美觀效果，外層紙及插件捲取紙也可藉由著色而為半透明。In order to visualize the inside of the filter, Patent Document 4 discloses that a transparent material is used as the outer layer paper and the insert paper is taken up, and opaque coating is applied to a part of the outer paper to impart a masking function. In Patent Document 4, the transparent material is exemplified by polypropylene, polyvinyl chloride, cellulose acetate film, polyethylene terephthalate, polyoxyethylene, polyethylene, cellophane, and natureflex (registered Trademark) and polyacetic acid. Further, Patent Document 4 discloses that if the inside of the filter can be visualized, in order to provide an aesthetic effect of the filter, the outer paper and the insert take-up paper can be translucent by coloring.
專利文獻5揭示使用透明薄膜材料作為外層紙(tip paper)及濾嘴捲紙，而可目視到濾嘴內之香料粒子，透明膜的材料例示有聚丙烯、聚氯乙烯及纖維素乙酸酯膜。Patent Document 5 discloses the use of a transparent film material as a tip paper and a filter roll paper, and the fragrance particles in the filter can be visually observed. The materials of the transparent film are exemplified by polypropylene, polyvinyl chloride and cellulose acetate. membrane.
專利文獻6揭示為了使有害物質之萃取效果可視化，而使用透明材料作為外層紙及插件捲取紙。Patent Document 6 discloses that a transparent material is used as the outer layer paper and the insert winding paper in order to visualize the extraction effect of the harmful substance.
(專利文獻)(Patent Literature)
專利文獻1：日本特開平7-250665號公報Patent Document 1: Japanese Patent Laid-Open No. Hei 7-250665
專利文獻2：日本特表2007-520204號公報Patent Document 2: Japanese Patent Publication No. 2007-520204
專利文獻3：日本特表2008-546400號公報Patent Document 3: Japanese Patent Publication No. 2008-546400
專利文獻4：國際公開第2009/106374號小冊Patent Document 4: International Publication No. 2009/106374
專利文獻5：日本實公平5-45198號公報Patent Document 5: Japanese Real Fair No. 5-45198
專利文獻6：國際公開第2004/068975號公報Patent Document 6: International Publication No. 2004/068975
本發明者們係著眼於在濾嘴部份含有香料膠囊之香煙中，若以不透明插件捲取紙及不透明外層紙捲包，則吸煙者壓壞香料膠囊時會有難以知道香料膠囊位置之問題，以及，膠囊破碎後不知道膠囊內容液在濾嘴內擴展之問題。The present inventors focused on cigarettes containing a fragrance capsule in a filter portion. If an opaque insert is used to take up the paper and the opaque outer paper roll, it is difficult for the smoker to know the position of the fragrance capsule when the smoker crushes the fragrance capsule. And, after the capsule is broken, the problem that the capsule content liquid expands in the filter is not known.
為了使濾嘴內之香料膠囊可視化而使用透明外層紙及透明插件捲取紙時，會損及上述遮掩功能(亦即，使濾嘴與煙草棒之連接處不被看見、使附著於濾嘴之濾材的焦油顏色不被看見之機能)。此外，使用透明外層紙及透明插件捲取紙而使香料膠囊可視化時，即使可確認膠囊的破 壞，因膠囊內容液係微量，故難以視覺而確認內容液於中空部內充分擴展。In order to visualize the flavor capsules in the filter and use the transparent outer paper and the transparent insert to take up the paper, the above hiding function is damaged (that is, the connection between the filter and the tobacco rod is not seen, and the filter is attached to the filter. The color of the tar of the filter material is not seen.) In addition, when the transparent capsule paper and the transparent insert are used to take up the paper to visualize the flavor capsule, even if the capsule is broken In the case of a small amount of liquid in the capsule, it is difficult to visually confirm that the content liquid is sufficiently expanded in the hollow portion.
在此，本發明目的為提供一種具有外層紙及插件捲取紙的香煙，其具有以下特徵：(a)外層紙及插件捲取紙維持遮掩功能、(b)吸煙者壓壞濾嘴內之香料膠囊時，透過外層紙及插件捲取紙，而可以視覺確認膠囊位置、且(c)膠囊破碎後，透過外層紙及插件捲取紙，而可以視覺確認膠囊內容液在濾嘴內擴展。Here, the object of the present invention is to provide a cigarette having an outer layer paper and a card take-up paper, which has the following features: (a) the outer paper and the insert take-up paper maintain the masking function, and (b) the smoker crushes the filter. In the case of the fragrance capsule, the paper can be visually confirmed by the outer paper and the insert, and (c) the capsule is broken, and the outer paper and the insert are taken up to visually confirm that the capsule content liquid expands in the filter.
至今為止，含有香料膠囊之香煙，係以使破壞膠囊而釋出之膠囊內容液不會於插件捲取紙及外層紙產生滲染為目的，例如使用親油性溶媒作為膠囊內容液時，較佳為使用耐油紙作為插件捲取紙。相反地，本發明者們在半透明之插件捲取紙附著膠囊內容液，於插件捲取紙產生具有更高透明度之滲染，藉此而完成本發明。Heretofore, the cigarette containing the flavor capsule is preferably such that the capsule content liquid released by the destruction of the capsule does not cause bleeding on the insert take-up paper and the outer layer paper. For example, when a lipophilic solvent is used as the capsule content liquid, it is preferred. To take up paper with oil-resistant paper as a plug-in. On the contrary, the inventors of the present invention completed the present invention by attaching a capsule content liquid to a translucent inserting paper to produce a bleeding having higher transparency in the insert winding paper.
亦即，根據本發明而提供一種香煙，包括：煙草棒，係包括煙草填充材及捲包該煙草填充材周圍之煙草捲紙；濾嘴，係包括互相間隔配置之複數個濾嘴插件；插件捲取紙，係以在前述濾嘴插件間形成中空部之方式捲包前述濾嘴插件周圍；以及位於前述中空部內，並將含有香料 之內容液維持於皮膜內的香料膠囊；以及外層紙，係以連接前述煙草棒與前述濾嘴之方式捲包於該煙草棒與該濾嘴上；前述插件捲取紙對於內容液具有不穿透性，前述插件捲取紙及前述外層紙所構成之積層紙的不透明度係(i)在香料膠囊破壞前為70%以下、(ii)在破壞香料膠囊而釋出之內容液附著於插件捲取紙時，降低5%以上。That is, a cigarette according to the present invention includes: a tobacco rod comprising a tobacco filler and a tobacco roll wrapped around the tobacco filler; and a filter comprising a plurality of filter inserts arranged at a distance from each other; Rolling up the paper around the filter insert in such a manner as to form a hollow portion between the filter inserts; and in the hollow portion, and containing the fragrance a fragrance capsule in which the content liquid is maintained in the film; and an outer layer paper wrapped around the tobacco rod and the filter in a manner of connecting the tobacco rod and the filter; the insert winding paper does not wear the content liquid The opacity of the laminated paper comprising the insert take-up paper and the outer layer paper is (i) 70% or less before the fragrance capsule is broken, and (ii) the content liquid released by destroying the fragrance capsule is attached to the insert. When taking up paper, reduce it by 5% or more.
根據本發明之香煙，其具有以下特徵：(a)外層紙及插件捲取紙維持遮掩功能、(b)吸煙者壓壞濾嘴內之香料膠囊時，透過外層紙及插件捲取紙，而可以視覺確認膠囊位置、且(c)膠囊破碎後，膠囊內容液於插件捲取紙產生滲染，藉此而可以視覺確認膠囊內容液在濾嘴內擴展。The cigarette according to the present invention has the following features: (a) the outer paper and the insert take-up paper maintain the masking function, and (b) when the smoker crushes the spice capsule in the filter, the outer paper and the insert take up the paper, and After the capsule position can be visually confirmed and (c) the capsule is broken, the capsule content liquid is infiltrated on the insert take-up paper, whereby the capsule content liquid can be visually confirmed to expand in the filter.
以下參照圖式而說明本發明，但以下說明之目的為詳細說明本發明，而並非限定本發明。The invention is described below with reference to the drawings, but the following description is intended to illustrate the invention and not to limit the invention.
第1A圖及第1B圖係表示本發明香煙之一部分的截面圖。第1A圖表示壓壞香料膠囊23前之香煙，第1B圖表示壓壞香料膠囊23後之香煙。1A and 1B are cross-sectional views showing a part of the cigarette of the present invention. Fig. 1A shows the cigarette before the fragrance capsule 23 is crushed, and Fig. 1B shows the cigarette after the fragrance capsule 23 is crushed.
第1A圖及第1B圖所示之香煙，係具有煙草棒10、在兩個濾嘴插件21a、21b及插件捲取紙22所形成之中空部收容有香料膠囊23之濾嘴20，且煙草棒10與濾嘴20係 藉由外層紙30而連接。與一般附有濾嘴之香煙相同地，第1A圖及第1B圖所示之香煙整體而言具有圓柱形狀。The cigarettes shown in FIGS. 1A and 1B have a tobacco rod 10, a filter 20 in which a fragrance capsule 23 is accommodated in a hollow portion formed by the two filter inserts 21a and 21b and the insert take-up paper 22, and tobacco Stick 10 and filter 20 Connected by the outer paper 30. Similarly to the cigarettes generally having a filter, the cigarettes shown in Figs. 1A and 1B have a cylindrical shape as a whole.
與一般香煙同樣地，煙草棒10係由煙草填充材11與捲包其周圍之煙草捲紙12所構成，例如可具有5至10mm之直徑及40至80mm之長度。Like the conventional cigarette, the tobacco rod 10 is composed of the tobacco filler 11 and the tobacco roll paper 12 wrapped around it, and may have, for example, a diameter of 5 to 10 mm and a length of 40 to 80 mm.
濾嘴20含有：互相間隔並隔著中空部而配置之2個濾嘴插件21a、21b；插件捲取紙22，其係以在濾嘴插件21a、21b間形成中空部之方式而捲包濾嘴插件周圍；膠囊23，其係收容於濾嘴插件間之中空部，並將含有香料之內容液維持於皮膜內。濾嘴20具有略與煙草棒10相同之直徑，長度係與一般濾嘴相同，例如可為15至40mm。The filter 20 includes two filter inserts 21a and 21b which are disposed to be spaced apart from each other with a hollow portion interposed therebetween, and an insert take-up paper 22 which is formed by winding a hollow portion between the filter inserts 21a and 21b. Around the mouth insert; the capsule 23 is received in the hollow portion between the filter inserts, and the content liquid containing the fragrance is maintained in the film. The filter 20 has the same diameter as the tobacco rod 10 and has the same length as a general filter, for example, 15 to 40 mm.
第1A圖及第1B圖之香煙中，2個濾嘴插件21a、21b係隔著一個中空部而配置，但n個(n為2以上之整數)濾嘴插件隔著(n-1)個中空部而配置亦可，例如n為2至4，較佳為n為2至3，更佳為n為2。In the cigarettes of Figs. 1A and 1B, the two filter inserts 21a and 21b are arranged with one hollow portion interposed therebetween, but n (n is an integer of 2 or more) filter inserts are interposed (n-1) It is also possible to arrange the hollow portion, for example, n is 2 to 4, preferably n is 2 to 3, and more preferably n is 2.
與一般附有濾嘴之香煙相同地，濾嘴插件21a、21b係可藉由纖維素乙酸酯纖維等纖維狀濾嘴材所構成。濾嘴插件可僅以纖維狀濾嘴材所構成，也可以纖維狀濾嘴材與捲包該周圍之素材紙所構成。細絲側之濾嘴插件21a與吸口側之濾嘴插件21b可具有相同素材及構造，也可具有不同之素材及構造。The filter inserts 21a and 21b can be composed of a fibrous filter material such as cellulose acetate fibers, similarly to a cigarette generally having a filter. The filter insert may be composed only of a fibrous filter material, or may be composed of a fibrous filter material and a material paper wrapped around the fiber. The filter insert 21a on the filament side and the filter insert 21b on the suction side may have the same material and structure, and may have different materials and configurations.
插件捲取紙22係捲包2個濾嘴插件21之周圍，結果2個濾嘴插件21a、21b同時形成中空部。插件捲取紙22為半透明，並具有可以視覺確認位於中空部內之香料膠囊 23之程度的不透明度。亦即，插件捲取紙22具有在吸煙者壓壞濾嘴內之香料膠囊時，可以視覺確認香料膠囊位置之程度的不透明度。因此，插件捲取紙22也具有遮蓋機能，而使得濾嘴內部之構造不被看見。此外，插件捲取紙22若附著破壞香料膠囊所釋出之膠囊內容液，其不透明度會降低並使香料膠囊之視認度增加。亦即，插件捲取紙22在附著膠囊內容液之位置其透明性會增加，被破壞之香料膠囊的輪廓變得明顯可見。「視認度增加」即被破壞之香料膠囊的輪廓變得明顯可見，具體來說，係代表依照後述表1所記載之評價基準所評價的評價點會增大。藉此使得吸煙者可以視覺確認膠囊內容液在中空部內之擴展。The insert take-up paper 22 is wrapped around the two filter inserts 21, and as a result, the two filter inserts 21a and 21b simultaneously form a hollow portion. The insert take-up paper 22 is translucent and has a fragrance capsule that can visually confirm the inside of the hollow portion. The degree of opacity of 23. That is, the insert take-up paper 22 has an opacity that allows visual confirmation of the position of the perfume capsule when the smoker crushes the perfume capsule in the filter. Therefore, the insert take-up paper 22 also has a covering function, so that the structure inside the filter is not seen. In addition, if the insert take-up paper 22 adheres to the capsule content liquid released by the fragrance capsule, the opacity thereof is lowered and the visibility of the fragrance capsule is increased. That is, the transparency of the insert take-up paper 22 at the position where the capsule content liquid is attached is increased, and the outline of the damaged flavor capsule becomes apparent. The "increased visibility", that is, the outline of the damaged flavor capsule is clearly visible. Specifically, the evaluation points evaluated in accordance with the evaluation criteria described in Table 1 below will increase. Thereby, the smoker can visually confirm the expansion of the capsule content liquid in the hollow portion.
如此，於本發明中，使膠囊內容液附著於半透明之插件捲取紙，並使插件捲取紙產生具有更高透明度之滲染，藉由該滲染的擴大，而可以視覺確認膠囊內容液在中空部內之擴展。藉此使得吸煙者可以確認膠囊內容液在中空部內充分擴展，更可品嚐香味。Thus, in the present invention, the capsule content liquid is attached to the translucent insert-wound paper, and the insert-wound paper is produced to have a higher transparency, and the capsule content can be visually confirmed by the enlargement of the bleeding. The expansion of the liquid in the hollow. Thereby, the smoker can confirm that the capsule content liquid is fully expanded in the hollow portion, and the flavor can be tasted.
為了發揮上述效果，本發明中插件捲取紙22具體來說係具有以下3個要件：In order to exert the above effects, the insert take-up paper 22 of the present invention specifically has the following three requirements:
(1)插件捲取紙具有對於膠囊內容液之不穿透性。(1) The insert take-up paper has a non-penetration property to the capsule content liquid.
(2)插件捲取紙及外層紙所構成之積層紙，係具有70%以下之不透明度。(2) The laminated paper composed of the insert take-up paper and the outer paper has an opacity of 70% or less.
(3)插件捲取紙及外層紙所構成之積層紙附著有破壞香料膠囊所釋出之膠囊內容液時，與膠囊破壞前相比，具有5%以上之低不透明度。(3) When the laminated paper composed of the insert take-up paper and the outer paper adheres to the capsule content liquid released by the fragrance capsule, it has a low opacity of 5% or more as compared with that before the capsule is broken.
本發明中外層紙較佳為透明，外層紙為透明時不透明度一般為0.5至3%。作為透明外層紙，例如可使用NatureFlex 23μ(Innovia公司)、NatureFlex 42μ(Innovia公司)作為外層紙用之基底膜。因此，外層紙為透明時，外層片紙不會對積層紙之不透明度造成實質上的影響。因此，外層紙為透明時係表現(2)之要件「插件捲取紙具有70%以下之不透明度」，並表現(3)之要件「插件捲取紙附著有破壞香料膠囊所釋出之膠囊內容液時，與膠囊破壞前相比，具有5%以上之低的不透明度」。In the present invention, the outer layer paper is preferably transparent, and when the outer layer paper is transparent, the opacity is generally from 0.5 to 3%. As the transparent outer layer paper, for example, NatureFlex 23μ (Innovia), NatureFlex 42μ (Innovia) can be used as the base film for the outer layer paper. Therefore, when the outer paper is transparent, the outer paper does not substantially affect the opacity of the laminated paper. Therefore, when the outer paper is transparent, the requirement of (2) is "the entanglement of the insert take-up paper has 70% or less", and the requirement of (3) "the insert roll paper is attached with the capsule released by the damaging capsule. When the content liquid is used, it has a lower opacity of 5% or more than before the capsule is destroyed.
本說明書全文中，不透明度係指依照JIS P8138A(1976年)所測定的值。Throughout the specification, opacity means a value measured in accordance with JIS P8138A (1976).
插件捲取紙是否滿足(1)之要件，具體來說係可以下方式判斷。亦即，重疊插件捲取紙與試驗紙並形成積層紙，由試驗紙側測定積層紙之不透明度，由插件捲取紙側滴下膠囊內容液，並由試驗紙側測定積層紙之不透明度，由滴下膠囊內容液前之不透明度減去滴下膠囊內容液後之不透明度，藉此求出不透明度差，前述差在10%以下時，插件捲取紙係評價為具有對於膠囊內容液之不穿透性，前述差超過10%時，插件捲取紙係評價為不具有對於膠囊內容液之不穿透性(參照後述實施例2)。因此，本發明中「具有不穿透性」除了具有完全不穿透性之情形以外，亦包括具有不穿透性但觀察到極些 微的浸透性之情形(參照後述表3)。此處不透明度之測定亦依照JIS P8138A(1976年)而進行。此處所使用之「試驗紙」係不透明紙，其具有作為在液體穿透插件捲取紙時可吸收該液體之濾紙的功能，例如可使用不透明度80以上之厚度33至53μm的紙，例如可舉出37白原紙(日本製紙papylia股份有限公司)。Whether the plug-in roll-to-roll paper meets the requirements of (1), specifically, it can be judged in the following manner. That is, the overlapping insert takes up the paper and the test paper to form a laminated paper, the opacity of the laminated paper is measured from the test paper side, the capsule content liquid is dropped from the side of the inserting paper, and the opacity of the laminated paper is measured from the side of the test paper. The opacity after dropping the capsule liquid is subtracted from the opacity before dropping the capsule content liquid, thereby obtaining the opacity difference. When the difference is less than 10%, the insert winding paper is evaluated as having no liquid for the capsule content. When the difference is more than 10%, the insert winding paper is evaluated as having no penetration property with respect to the capsule content liquid (see Example 2 to be described later). Therefore, in the present invention, "having non-penetration" includes non-penetrability but is observed to be extremely non-penetrative. The case of micro-permeability (refer to Table 3 below). The measurement of opacity here is also carried out in accordance with JIS P8138A (1976). The "test paper" used herein is an opaque paper having a function as a filter paper which can absorb the liquid when the liquid penetrates the insert, for example, a paper having a thickness of 33 to 53 μm having an opacity of 80 or more can be used, for example, Take 37 white base paper (Japan Paper Papylia Co., Ltd.).
插件捲取紙及外層紙所構成之積層紙是否滿足(2)之要件，具體來說係可以下方式判斷。亦即，將插件捲取紙與外層紙重疊形成積層紙，並由外層紙側測定積層紙之不透明度(參照後述實施例3)。此處不透明度之測定亦依照JIS P8138A(1976年)而進行。本發明中，如此所測定之不透明度(亦即附著膠囊內容液前之不透明度)為70%以下，較佳為5至70%，更佳為10至40%，又更佳為15至40%。若不透明度超過70%，則難以視覺通過插件捲取紙與外層紙而確認香料膠囊。Whether the laminated paper composed of the insert take-up paper and the outer paper satisfies the requirements of (2), specifically, can be judged in the following manner. That is, the laminated paper is overlapped with the outer paper to form a laminated paper, and the opacity of the laminated paper is measured from the outer paper side (see Example 3 to be described later). The measurement of opacity here is also carried out in accordance with JIS P8138A (1976). In the present invention, the opacity thus measured (i.e., the opacity before attaching the capsule content liquid) is 70% or less, preferably 5 to 70%, more preferably 10 to 40%, still more preferably 15 to 40. %. If the opacity exceeds 70%, it is difficult to visually confirm the perfume capsule by taking up the paper and the outer paper through the insert.
插件捲取紙及外層紙所構成之積層紙是否滿足(3)之要件，具體來說係可以下方式判斷。亦即，重疊插件捲取紙與外層紙並形成積層紙，由外層紙側測定積層紙之不透明度，由插件捲取紙側滴下膠囊內容液，並由外層紙側測定積層紙之不透明度，由滴下膠囊內容液前之不透明度減去滴下膠囊內容液後之不透明度，藉此求出不透明度差(參照後述實施例3)，此處不透明度之測定亦依照JIS P8138A(1976年)而 進行。本發明中，如此所求得之不透明差為5%以上，較佳為5至30%，更佳為10至30%。不透明度未達5%時，積層紙之不透明度的降低並不充分，難以確認到破壞膠囊所釋出之膠囊內容液於濾嘴中空部內擴展。Whether the laminated paper composed of the insert roll paper and the outer paper meets the requirements of (3), specifically, it can be judged in the following manner. That is, the overlapping insert winds up the paper and the outer paper to form a laminated paper, the opacity of the laminated paper is measured from the outer paper side, the capsule content liquid is dropped from the side of the paper taken by the insert, and the opacity of the laminated paper is measured from the outer paper side. The opacity after dropping the capsule content liquid is subtracted from the opacity before dropping the capsule content liquid, thereby obtaining the opacity difference (refer to Example 3 described later), where the opacity is also measured in accordance with JIS P8138A (1976). get on. In the present invention, the opacity difference thus obtained is 5% or more, preferably 5 to 30%, more preferably 10 to 30%. When the opacity is less than 5%, the decrease in the opacity of the laminated paper is not sufficient, and it is difficult to confirm that the capsule content liquid released from the broken capsule spreads in the hollow portion of the filter.
有關(2)及(3)之要件，可在製造香煙前測定插件捲取紙與外層紙重疊形成之積層紙的不透明度，並可在製造香煙後，從中空部的位置切取插件捲取紙與外層紙為接著狀態之積層紙，並測定該積層紙之不透明度。後者之情形，積層紙雖含有接著劑，但插件捲取紙與外層紙之接著一般使用透明之接著劑(例如乳劑系接著劑)，故接著劑不會對透明度造成影響，而可以忽略。For the requirements of (2) and (3), the opacity of the laminated paper formed by the overlap of the insert take-up paper and the outer paper may be measured before the cigarette is manufactured, and the insert take-up paper may be cut from the position of the hollow portion after the cigarette is manufactured. The laminated paper is in a state of being attached to the outer layer paper, and the opacity of the laminated paper is measured. In the latter case, although the laminated paper contains an adhesive, the insert take-up paper and the outer paper are generally followed by a transparent adhesive (for example, an emulsion-based adhesive), so that the adhesive does not affect the transparency and can be ignored.
更具體來說，插件捲取紙22可使用具有5至40%之不透明度、500至2500sec之平滑度以及0至5%之灰份的紙。插件捲取紙22較佳可使用具有20至40%之不透明度、500至2500sec之平滑度以及0至5%之灰份的紙。更具體來說，插件捲取紙22可使用滿足上述條件之玻璃紙(glassine paper)、羊皮紙(parchment paper)。插件捲取紙22較佳可使用滿足上述條件之玻璃紙。若不透明度超過30%，則從視覺確認香料膠囊之觀點來說較不佳。此外，若平滑度未滿500sec，則從對於膠囊內容液之不穿透性的觀點來看較為不佳。此外，灰份超過5%，則以不透明度上升之觀點來看較為不佳。插件捲取紙22例如可為40至80μm之厚度。More specifically, the insert take-up paper 22 may use paper having an opacity of 5 to 40%, a smoothness of 500 to 2500 sec, and an ash of 0 to 5%. The insert take-up paper 22 preferably uses paper having an opacity of 20 to 40%, a smoothness of 500 to 2500 sec, and an ash of 0 to 5%. More specifically, the insert take-up paper 22 can use glassine paper or parchment paper which satisfies the above conditions. It is preferable to use the cellophane paper 22 which satisfies the above conditions. If the opacity exceeds 30%, it is less preferred from the viewpoint of visually confirming the flavor capsule. Further, if the smoothness is less than 500 sec, it is not preferable from the viewpoint of the non-penetration of the capsule content liquid. In addition, when the ash content exceeds 5%, it is not preferable from the viewpoint of an increase in opacity. The insert take-up paper 22 may have a thickness of, for example, 40 to 80 μm.
插件捲取紙22可實施以下處理，於其內側表面(中 空部側之表面)設置具有撥水性或撥油性之特定形狀的區域，藉此在破壞香料膠囊所釋出之內容液附著時，使前述特定形狀浮出。可藉由塗佈石蠟、矽等而形成具有撥水性區域，並可藉由塗佈蠟、石蠟、羧甲基纖維素、膠乳等而形成具有撥油性之區域。可利用印刷技術將該等物質塗佈於插件捲取紙上，藉此而塗佈。特定的形狀可為記號；圓圈、三角、四角、星形等圖形；字母等文字等任意形狀。The insert take-up paper 22 can perform the following treatment on the inner side surface thereof The surface of the empty portion side is provided with a region having a specific shape of water repellency or oil repellency, whereby the specific shape is floated when the content liquid released by the fragrance capsule is broken. A water-repellent region can be formed by coating paraffin, ruthenium or the like, and a oil-repellent region can be formed by coating wax, paraffin, carboxymethylcellulose, latex or the like. These materials can be applied to the insert take-up paper by printing techniques and coated. The specific shape may be a mark; a circle, a triangle, a square, a star, or the like; an arbitrary shape such as a letter or the like.
第1A圖及第1B圖之香煙中，香料膠囊23係收容於濾嘴插件間之中空部。每一個中空部可收納一個香料膠囊，也可收納複數個(例如2至10個)香料膠囊。In the cigarettes of Figs. 1A and 1B, the fragrance capsule 23 is housed in a hollow portion between the filter inserts. Each hollow portion can accommodate one spice capsule, and can also accommodate a plurality of (for example, 2 to 10) perfume capsules.
香料膠囊23係由皮膜23a與含有香料之內容液23b所構成。皮膜23a例如可使用澱粉、糊精、多醣類、寒天、結蘭膠(gellan gum)、明膠、各種天然膠化劑、甘油等，復可含有香料或著色料。即使以具有不透明度之插件捲取紙所包圍著，香料膠囊較佳為著色使壓壞香料膠囊時使用者可確認，皮膜23a較佳為含有著色料，例如藍色1號等。內容液23b之香料例如可使用薄荷醇、植物精油等。內容液23b之溶媒可使用適合於香料之溶媒，可使用中鏈脂肪酸三酸甘油酯(MCT)(具體來說，辛酸/癸酸三酸甘油酯(caprylic/cabric triglyceride))、丙二醇、水、乙醇等。內容液可復含有其他溶媒、色素、乳化劑、增黏劑等其他添加劑。The fragrance capsule 23 is composed of a film 23a and a content liquid 23b containing a fragrance. The film 23a may, for example, be starch, dextrin, polysaccharide, cold weather, gellan gum, gelatin, various natural gelling agents, glycerin or the like, and may contain a perfume or a coloring material. Even if it is surrounded by the insert paper having the opacity, the fragrance capsule is preferably colored so that the user can confirm that the film 23a is crushed, and the film 23a preferably contains a coloring material such as Blue No. 1. As the fragrance of the content liquid 23b, for example, menthol, plant essential oil or the like can be used. As the solvent of the content liquid 23b, a solvent suitable for the fragrance can be used, and a medium chain fatty acid triglyceride (MCT) (specifically, caprylic/cabric triglyceride), propylene glycol, water, or the like can be used. Ethanol and the like. The content liquid may contain other additives such as other solvents, pigments, emulsifiers, and tackifiers.
香料膠囊之製造方法並無特別限定，但若例如使用滴下法則可製造具有無縫皮膜之香料膠囊。該方法中使用雙 重噴嘴，並由內側噴嘴將內容液、由外側噴嘴將液狀皮膜物質同時地吐出，藉此可使皮膜液無接縫地包住內容液。香料膠囊直徑例如可為1.5至7.0mm。The method for producing the flavor capsule is not particularly limited, but a flavor capsule having a seamless film can be produced, for example, by using a dropping method. Double in the method The liquid nozzle is discharged from the inner nozzle by the inner nozzle, and the liquid film material is simultaneously discharged from the outer nozzle, thereby allowing the coating liquid to wrap the content liquid without seams. The fragrance capsule may have a diameter of, for example, 1.5 to 7.0 mm.
製造本發明香煙時，首先決定香煙所含有之香料，並根據香料種類而選擇適合於溶解香料之溶媒，可對於此溶媒而選擇滿足上述(1)至(3)要件之插件捲取紙。例如香煙含有薄荷醇時，溶媒可選擇中鏈脂肪酸三酸甘油酯，對於該溶媒而滿足上述(1)至(3)要件之紙，例如可選擇40.0白色特厚Glassine(日本製紙papylia股份有限公司：玻璃紙)、25.8白色薄Glassine(日本製紙papylia股份有限公司：玻璃紙)、DREEP W34.9(王子特殊紙有限股份公司：羊皮紙)、JT高透明Glassine 40(日本製紙papylia股份有限公司：玻璃紙)等(參照表4及表6)。When the cigarette of the present invention is produced, the flavor contained in the cigarette is first determined, and the solvent suitable for dissolving the fragrance is selected according to the type of the fragrance, and the insert-wound paper satisfying the above requirements (1) to (3) can be selected for the solvent. For example, when the cigarette contains menthol, the solvent may be selected from medium chain fatty acid triglyceride, and the paper satisfying the above requirements (1) to (3) for the solvent, for example, 40.0 white thick Glassis (Japan Paper Papylia Co., Ltd.) may be selected. : cellophane), 25.8 white thin Glassine (Japan Paper Papylia Co., Ltd.: cellophane), DREEP W34.9 (Prince Special Paper Co., Ltd.: parchment), JT High Transparent Glassine 40 (Japan Paper Papylia Co., Ltd.: cellophane) (Refer to Table 4 and Table 6).
第1A圖及第1B圖之香煙中，外層紙30較佳為內容液不穿透性。此外，外層紙較佳為透明。如此外層紙可使用透明之賽璐玢。In the cigarettes of Figs. 1A and 1B, the outer layer paper 30 is preferably impervious to the content liquid. Further, the outer layer paper is preferably transparent. Such a layer of paper can be used in transparent celluloid.
外層紙30係以覆蓋插件捲取紙22整體與香煙捲紙12之一部分之方式而以接著劑接著。接著劑較佳為無色透明而不會影響香料膠囊之試認度，例如可使用乳劑系接著劑。外層紙30係例如煙草棒的軸方向長度(寬)可為20至50mm、厚度可為10至100μm。與一般附有濾嘴之香煙同樣地，外層紙可沿著香煙圓周方向而大量穿設一列、複數列或不規則之通氣用小開孔(通氣孔)。外層紙30係可於中空部以外之區域實施塗佈，例如白底印刷。The outer layer paper 30 is followed by an adhesive in such a manner as to cover the entire portion of the card take-up paper 22 and the portion of the cigarette paper 12. The subsequent agent is preferably colorless and transparent without affecting the testability of the perfume capsule, and for example, an emulsion-based adhesive can be used. The outer paper 30 such as a tobacco rod may have an axial length (width) of 20 to 50 mm and a thickness of 10 to 100 μm. As with the cigarettes generally having a filter, the outer layer of paper can be provided with a large number of rows, a plurality of rows or irregular small openings for ventilation (vent holes) along the circumferential direction of the cigarette. The outer layer paper 30 can be applied in a region other than the hollow portion, for example, printed on a white background.
(實施例1：膠囊之視認性)(Example 1: Visibility of capsules)
本實施例中，評價在將本發明香煙之香料膠囊壓壞前及壓壞後，香料膠囊是否可以視覺確認。In the present example, it was evaluated whether the fragrance capsule can be visually confirmed before and after crushing the flavor capsule of the cigarette of the present invention.
1.材料Material
濾嘴A至F之插件捲取紙係使用下述商品名之紙，括號內表示取得來源、紙之種類。For the inserts of the filters A to F, the paper of the following trade name is used, and the source and the type of paper are indicated in parentheses.
濾嘴A：40.0白色特厚Glassine(日本製紙papylia股份有限公司：玻璃紙)；不透明度30至35%、平滑度800至1000sec、灰份0至5%。Filter A: 40.0 white extra thick Glassine (Japan Paper Papylia Co., Ltd.: cellophane); opacity 30 to 35%, smoothness 800 to 1000 sec, ash 0 to 5%.
濾嘴B：25.8白色薄Glassine(日本製紙papylia股份有限公司：玻璃紙)；不透明度20至25%、平滑度1000至1200sec、灰份0至5%。Filter B: 25.8 White Thin Glassine (Japan Paper Papylia Co., Ltd.: cellophane); opacity 20 to 25%, smoothness 1000 to 1200 sec, ash 0 to 5%.
濾嘴C：50NFB(耐油紙)(日本製紙papylia股份有限公司：耐油紙)；不透明度75至80%、平滑度30至130sec、灰份1至2%。Filter C: 50NFB (oil resistant paper) (Japan Paper Papylia Co., Ltd.: oil resistant paper); opacity 75 to 80%, smoothness 30 to 130 sec, ash 1 to 2%.
濾嘴D：GLAFAN 35gsm(王子特殊紙股份有限公司：玻璃紙)；不透明度5至15%、平滑度1500至2000sec、灰份0至5%。Filter D: GLAFAN 35gsm (Prince Special Paper Co., Ltd.: cellophane); opacity 5 to 15%, smoothness 1500 to 2000 sec, ash 0 to 5%.
濾嘴E：P-10000C(高通氣不織布)(日本製紙papylia 股份有限公司：高通氣不織布)；不透明度40至50%、平滑度8至10sec、灰份0至3%。Filter E: P-10000C (high ventilation non-woven fabric) (Japanese paper papylia Co., Ltd.: High-ventilation non-woven fabric); opacity 40 to 50%, smoothness 8 to 10 sec, ash 0 to 3%.
濾嘴F：NatureFlex 42μ(透明膜)(Innovia公司：透明賽璐玢)；不透明度1.0至2.0%、平滑度3500至4000sec。Filter F: NatureFlex 42μ (transparent film) (Innovia: transparent celluloid); opacity 1.0 to 2.0%, smoothness 3500 to 4000 sec.
濾嘴G：JT高透明Glassine(日本製紙papylia股份有限公司：玻璃紙)；不透明度15至25%、平滑度1500sec以上、灰份0至5%。Filter G: JT high transparent Glassine (Japan Paper Papylia Co., Ltd.: cellophane); opacity 15 to 25%, smoothness 1500 sec or more, ash content 0 to 5%.
2.濾嘴之製造2. Manufacture of filters
使用上述插件捲取紙而製造第2圖所示之濾嘴。濾嘴係由細絲側(左側)之濾嘴插件21a、吸口側(右側)之濾嘴插件21b、插件捲取紙22及香料膠囊23所構成。The filter shown in Fig. 2 was produced by winding the paper using the above-mentioned insert. The filter is composed of a filter insert 21a on the filament side (left side), a filter insert 21b on the suction side (right side), a plug-in take-up paper 22, and a fragrance capsule 23.
「細絲側之濾嘴插件21a」係由Non-Wrap-Acetate(ATK2010-02)之濾材所構成(不含素材紙)，其長度L1為11mm、圓周為24.1mm。「吸口側之濾嘴插件21b」係由Acetate tow(2.8Y35000)之濾材與P10000C之素材紙所構成，其長度L2為10mm、圓周為24.1mm。該等2個濾嘴插件與插件捲紙所形成之中空部長度(S)為6mm。香料膠囊23係由含有中鏈脂肪酸三酸甘油酯(辛酸/癸酸三酸甘油酯)與香料(薄荷醇及植物精油)之內容液23b、以及以多醣類(澱粉)為基底之皮膜23a所構成，香料膠囊之直徑D為4.5mm。將作為皮膜物質之澱粉(20重量%)與 內容液(80重量%)混合，並藉由滴下法而調製香料膠囊。所製造濾嘴之全長(Lf)為27mm。The "filament plug 21a" on the filament side is composed of a filter material of Non-Wrap-Acetate (ATK2010-02) (excluding material paper), and has a length L1 of 11 mm and a circumference of 24.1 mm. The "filter inlet side plug 21b" is composed of an Acetate tow (2.8Y35000) filter material and a P10000C material paper, and has a length L2 of 10 mm and a circumference of 24.1 mm. The length (S) of the hollow portion formed by the two filter inserts and the insert roll paper was 6 mm. The fragrance capsule 23 is composed of a content liquid 23b containing a medium chain fatty acid triglyceride (octanoic acid/capric triglyceride) and a fragrance (menthol and plant essential oil), and a film 23a based on a polysaccharide (starch). The capsule D has a diameter D of 4.5 mm. Starch (20% by weight) as a film substance The content liquid (80% by weight) was mixed, and the flavor capsule was prepared by dropping. The total length (Lf) of the manufactured filter was 27 mm.
使用FLR捲包機(ND-5RC、三條機械製作所股份有限公司)，將2個濾嘴插件與香料膠囊如第2圖所示般以插件捲取紙22捲包。Using the FLR roll wrapping machine (ND-5RC, Sanjo Machinery Co., Ltd.), the two filter inserts and the fragrance capsules were wrapped in the insert take-up paper 22 as shown in Fig. 2 .
3.香煙之製造3. Manufacture of cigarettes
使用如上述製造之濾嘴而製造第3圖所示之香煙。香煙係由「煙草棒10」、「濾嘴20」及「外層紙30」所構成。The cigarette shown in Fig. 3 was produced using the filter manufactured as described above. The cigarette is composed of "tobacco stick 10", "filter 20" and "outer paper 30".
「煙草棒」係使用本公司製造販售之品牌Mild Seven之煙草棒。煙草棒具有長度(Lr)57mm、圓周24.8mm之尺寸。「濾嘴」係如第2圖所示，其全長(Lf)為27mm。「外層紙」係使用使用NatureFlex 23μ(Innovia公司)作為基底膜，並以TANNPAPIER GmbH將其外層紙之兩端各白底印刷10mm而於外層紙加工者。外層紙長度(Lt)為32mm、白底部分長度(Lt1及Lt2)為10mm。"Tobacco Stick" is a tobacco rod made by Mild Seven, a brand sold by the company. The tobacco rod has a size of (Lr) 57 mm and a circumference of 24.8 mm. The "filter" is shown in Fig. 2, and its total length (Lf) is 27 mm. For the "outer paper", NatureFlex 23μ (Innovia) was used as the base film, and the white paper on both ends of the outer paper was printed by TANNPAPIER GmbH to a thickness of 10 mm for the outer paper processor. The outer paper length (Lt) was 32 mm, and the white base portion length (Lt1 and Lt2) was 10 mm.
外層糊可使用EVA系乳劑。由濾嘴A及B使用煙草捲包機(HAUNI公司ProtosM5)而製作香煙A及B。此外，由濾嘴C至G以手捲包而製作香煙C至G。An EVA emulsion can be used for the outer layer paste. Cigarettes A and B were produced from the filters A and B using a tobacco wrapping machine (HAUNI Protos M5). Further, cigarettes C to G were produced by hand wrapping from the filters C to G.
4.評價結果4. Evaluation results
以目視評價香煙膠囊之視認性(視認度)。在23℃、濕度50%、標準光源下實施評價。The visibility (visibility) of the cigarette capsule was visually evaluated. The evaluation was carried out under a standard light source at 23 ° C, a humidity of 50%.
(1)將香煙A至G分別準備2隻。(1) Two cigarettes A to G were prepared separately.
(2)於2支中的1支，使用尖嘴鉗壓壞膠囊。(2) In one of the two, the capsule is crushed using a needle-nosed pliers.
(3)將壓壞膠囊之香煙置於桌上放置5分鐘。(3) Place the cigarette with the crushed capsule on the table for 5 minutes.
(4)將經放置之香煙置於市售咖啡用紙上，以目視評分膠囊之視認性。(4) Place the placed cigarette on a commercially available coffee paper to visually score the visibility of the capsule.
以下表為基準進行評分。The table below is a benchmark for scoring.
(5)壓壞前之香煙也以相同方式評價。由該評分與(4)所得之評分的差，而算出「視認性之變化」。(5) Cigarettes before crushing were also evaluated in the same manner. From the difference between the score and the score obtained in (4), the "change in visibility" is calculated.
(6)以5位評價者進行評價，以目視之評價結果係如以下所示。下表係將目視之評價結果與不透明度之測定結果合併表示。不透明度之測定結果係將後述實施例3(表 6)所得之結果記錄於此。(6) Evaluation was performed by five evaluators, and the results of the visual evaluation were as follows. The table below shows the visual evaluation results combined with the opacity measurement results. The measurement result of opacity is the following Example 3 (Table 6) The results obtained are recorded here.
香煙C中，壓壞前無法以視覺確認膠囊，故50NFB(耐油紙)不適合於插件捲取紙。香煙F中，壓壞前壓壞後皆可以視覺清晰地確認膠囊，故NatureFlex 42μ不具有遮蓋功能，而不適合於插件捲取紙。另一方面，香煙A、B、D、E及G中，壓壞前可以視覺確認膠囊(評分2至3)，若將膠囊壓壞則膠囊內之內容液附著於插件捲取紙，使得膠囊可更清楚地以視覺確認。In cigarette C, the capsule cannot be visually confirmed before crushing, so 50NFB (oil resistant paper) is not suitable for the insert winding paper. In the cigarette F, the capsule can be visually and clearly confirmed after being crushed before crushing, so the NatureFlex 42μ does not have a covering function, and is not suitable for the insert winding paper. On the other hand, in cigarettes A, B, D, E and G, the capsule can be visually confirmed before the crushing (score 2 to 3), and if the capsule is crushed, the content liquid in the capsule is attached to the insert take-up paper, so that the capsule It can be confirmed visually more clearly.
本實施例中評價各種插件捲取紙之液體不穿透性。In the present embodiment, the liquid impermeability of the various insert take-up sheets was evaluated.
1.材料Material
使用下述紙作為插件捲取紙。括號內表示商品名、獲得來源、紙之種類。Use the paper described below as the insert roll. The name of the product, the source of the source, and the type of paper are indicated in parentheses.
(1)普通紙24(普通紙24.0gsm：日本製紙papylia股份有限公司；普通紙)；不透明度65至75%、平滑度80至140sec、灰份8至12%。(1) Plain paper 24 (plain paper 24.0 gsm: Nippon Paper Papylia Co., Ltd.; plain paper); opacity 65 to 75%, smoothness 80 to 140 sec, ash 8 to 12%.
(2)N250(N250：日本製紙papylia股份有限公司；普通紙)；不透明度40至50%、平滑度100至140sec、灰份5%以下。(2) N250 (N250: Nippon Paper Papylia Co., Ltd.; plain paper); opacity 40 to 50%, smoothness 100 to 140 sec, ash 5% or less.
(3)NPWS(NPWS-OLL：日本製紙papylia股份有限公司；普通紙)；不透明度45至55%、平滑度150至190sec、灰份5%以下。(3) NPWS (NPWS-OLL: Nippon Paper Papylia Co., Ltd.; plain paper); opacity of 45 to 55%, smoothness of 150 to 190 sec, and ash content of 5% or less.
(4)P10000C(P-10000C：日本製紙papylia股份有限公司；高通氣度不織布)；不透明度40至50%、平滑度8至10sec、灰份0至3%。(4) P10000C (P-10000C: Nippon Paper Papylia Co., Ltd.; high air permeability non-woven fabric); opacity 40 to 50%, smoothness 8 to 10 sec, ash 0 to 3%.
(5)P20000C(P-2000C：日本製紙papylia股份有限公司；高通氣度不織布)；不透明度35至45%、平滑度1至4sec、灰份0至3%。(5) P20000C (P-2000C: Nippon Paper Papylia Co., Ltd.; high air permeability non-woven fabric); opacity 35 to 45%, smoothness 1 to 4 sec, ash 0 to 3%.
(6)NatureFlex 23μ(NatureFlex 23μ：Innovia；透明賽璐玢)；不透明度1.0至2.0%、平滑度3500至4000sec。(6) NatureFlex 23μ (NatureFlex 23μ: Innovia; transparent celluloid); opacity 1.0 to 2.0%, smoothness 3500 to 4000 sec.
(7)50NFB(50NFB：日本製紙papylia股份有限公司；耐油紙)；不透明度75至80%、平滑度30至130sec、灰份1至2%。(7) 50NFB (50NFB: Nippon Paper Papylia Co., Ltd.; oil resistant paper); opacity of 75 to 80%, smoothness of 30 to 130 sec, and ash content of 1 to 2%.
(8)DREEP W34.9(DREEP W34.9：王子特殊紙股份有限公司；羊皮紙)；不透明度30至50%、平滑度3000sec以上、灰份0至5%。(8) DREEP W34.9 (DREEP W34.9: Prince Special Paper Co., Ltd.; parchment); opacity 30 to 50%, smoothness 3000 sec or more, ash 0 to 5%.
(9)GLAFAN(GLAFAN 35gsm：王子特殊紙股份有限公司；玻璃紙)；不透明度5至15%、平滑度1500至2000sec、灰份0至5%。(9) GLAFAN (GLAFAN 35gsm: Prince Special Paper Co., Ltd.; cellophane); opacity 5 to 15%, smoothness 1500 to 2000 sec, ash 0 to 5%.
(10)Glassine 25.8(25.8白色薄Glassine：日本製紙papylia股份有限公司；玻璃紙)；不透明度20至25%、平滑度1000至1200sec、灰份0至5%。(10) Glassine 25.8 (25.8 white thin Glassine: Nippon Paper Papylia Co., Ltd.; cellophane); opacity 20 to 25%, smoothness 1000 to 1200 sec, ash 0 to 5%.
(11)Glassine40(40.0白色特厚Glassine：日本製紙papylia股份有限公司；玻璃紙)；不透明度30至35%、平滑度800至1000sec、灰份0至5%。(11) Glassine 40 (40.0 white extra thick Glassine: Nippon Paper Papylia Co., Ltd.; cellophane); opacity 30 to 35%, smoothness 800 to 1000 sec, ash 0 to 5%.
(12)高透明Glassine 40(JT高透明Glassine 40： 日本製紙papylia股份有限公司；玻璃紙)；不透明度15至25%、平滑度1500sec以上、灰份0至5%。(12) Highly transparent Glassine 40 (JT High Transparent Glassine 40: Nippon Paper Papylia Co., Ltd.; cellophane); opacity 15 to 25%, smoothness 1500 sec or more, ash 0 to 5%.
2.評價方法2. Evaluation method
使用中鏈脂肪酸三酸甘油酯(MCT)(辛酸/癸酸三酸甘油酯)、丙二醇(PG)以及水。Medium chain fatty acid triglycerides (MCT) (caprylic/capric triglyceride), propylene glycol (PG) and water are used.
在23℃、濕度50%、標準光源下實施評價。The evaluation was carried out under a standard light source at 23 ° C, a humidity of 50%.
(1)滴下液體前(1) before dropping the liquid
將插件捲取紙與外層紙(37白原紙：日本製紙papylia股份有限公司)(試驗紙)重疊，由外層紙側以Hunter法(JIS P 8138A)測定所得積層紙之不透明度(%)。The insert take-up paper was overlapped with the outer paper (37 white paper: Nippon Paper Papylia Co., Ltd.) (test paper), and the opacity (%) of the obtained laminated paper was measured by the Hunter method (JIS P 8138A) from the outer paper side.
(2)滴下液體後(2) After dropping the liquid
於上述積層紙之插件紙側滴下液體70μl。滴下液體2分鐘後，擦拭插件捲取紙表面所殘留之液體。之後由外層紙側以Hunter法(JIS P 8138A)測定不透明度(%)。70 μl of the liquid was dropped on the side of the insert paper of the above laminated paper. After the liquid was dropped for 2 minutes, the plug was swept to take up the liquid remaining on the surface of the paper. The opacity (%) was then measured by the Hunter method (JIS P 8138A) from the outer paper side.
由滴下液體後之不透明度(%)與滴下液體前之不透明度(%)的差算出「不透明度之變化量」。不穿透性係根據「不透明度之變化量」，而如以下表而評價。The "change in opacity" was calculated from the difference between the opacity (%) after dropping the liquid and the opacity (%) before dropping the liquid. The non-penetration system is evaluated according to the following table according to the "change in opacity".
液體為水時因會經時乾燥而無法測定不透明度，不穿透性係依照表3之評價基準而瞬間地評價之外觀。When the liquid was water, the opacity could not be measured because it was dried over time, and the non-penetrability was evaluated instantaneously according to the evaluation criteria of Table 3.
以下表示各種插件捲取紙之「不透明度之變化量」及「不穿透性之評價」。The following shows the "change in opacity" and "evaluation of non-penetration" of various plug-in rolls.
普通紙24、N250、NPWS、P10000C、P20000C皆顯示對於液體之穿透性，故不適合使用於插件捲取紙。NatureFlex 23μ、50NFB、DREEP W34.9、GLAFAN、高透明Glassine 40皆具有對於液體之不穿透性。Glassine 25.8對於中鏈脂肪酸三酸甘油酯顯示些許不穿透性，但認為使 用作為插件捲取紙應沒有問題。因Glassine 25.8顯示對於水之穿透性，故不可使用水作為香料膠囊之溶媒。Glassine 40具有對於水以外之所有液體之不穿透性。Plain paper 24, N250, NPWS, P10000C, and P20000C all show transparency to liquids, so they are not suitable for use in insert winding paper. NatureFlex 23μ, 50NFB, DREEP W34.9, GLAFAN, and highly transparent Glassine 40 all have non-penetration properties to liquids. Glassine 25.8 shows some non-penetration for medium chain fatty acid triglycerides, but thinks There should be no problem with taking paper as a plug-in. Since Glassine 25.8 shows penetration into water, water cannot be used as a solvent for perfume capsules. Glassine 40 has non-penetration to all liquids other than water.
1.評價方法Evaluation method
本實施例中將實施例2所使用之插件捲取紙與透明外層紙NatureFlex 23μ重疊，並藉由附著液體而評價不透明度之變化。滴下與實施例2所使用液體相同之液體，以與實施例2相同之手法進行評價。In the present embodiment, the insert take-up paper used in Example 2 was overlapped with the transparent outer layer NatureFlex 23μ, and the change in opacity was evaluated by attaching a liquid. The liquid which was the same as the liquid used in Example 2 was dropped, and evaluated in the same manner as in Example 2.
由滴下液體後之不透明度(%)與滴下液體前之不透明度(%)的差，而算出「不透明度之變化」。如下表般一起評價相關之「外觀(透明性)」。The "change in opacity" was calculated from the difference between the opacity (%) after dropping the liquid and the opacity (%) before dropping the liquid. The related "appearance (transparency)" is evaluated together as shown in the following table.
如表5所示般，不透明度之變化量在5%以上時，可以視覺確認透明性之增加。As shown in Table 5, when the amount of change in opacity is 5% or more, the increase in transparency can be visually confirmed.
2.評價結果2. Evaluation results
以下表示各種插件捲取紙之「不透明度之變化量」及「評價」。The following shows the "change in opacity" and "evaluation" of various plug-in rolls.
普通紙24、N250、NPWS、P10000C、P20000C皆在滴下液體後不透明度大幅變化，但根據實施例2之結果，該等皆顯示對於液體之穿透性，故不適合作為插件捲取紙。The plain papers 24, N250, NPWS, P10000C, and P20000C all changed greatly in opacity after dropping the liquid, but according to the results of Example 2, these all showed transparency to liquids, and thus were not suitable as a card take-up paper.
NatureFlex 23μ未顯示5%以上之不透明度的變化量，故不適合作為插件捲取紙。NatureFlex 23μ does not show a change in opacity of more than 5%, so it is not suitable as a plug-in take-up paper.
50NFB為不透明，故使用該紙時無法確認香料膠囊之位置，因此不適合作為插件捲取紙。Since 50NFB is opaque, the position of the fragrance capsule cannot be confirmed when the paper is used, and therefore it is not suitable as a card to take up the paper.
DREEP W34.9在滴下前之不透明度為37.2%，且滴下任何液體後皆顯示5%以上之不透明度之變化量，並可以視覺確認透明度之增加。此外，DREEP W34.9顯示對任何液體之不穿透性(參考實施例2之結果)。由此來看，DREEP W34.9可使用作為插件捲取紙。The opacity of DREEP W34.9 before dripping was 37.2%, and the amount of change in opacity of more than 5% was observed after dropping any liquid, and the increase in transparency was visually confirmed. In addition, DREEP W34.9 showed non-penetration to any liquid (see the results of Example 2). From this point of view, DREEP W34.9 can be used as a plug-in to take paper.
GLAFAN未顯示5%以上之不透明度的變化量，故不適合作為插件捲取紙。GLAFAN does not show a change in opacity of more than 5%, so it is not suitable as a plug-in take-up paper.
Glassine 25.8在滴下前之不透明度為20.9%，且滴下中鏈脂肪酸三酸甘油酯(MCT)及丙二醇(PG)後顯示5%以上之不透明度之變化量，並可以視覺確認透明度之增加。此外，Glassine 25.8顯示對中鏈脂肪酸三酸甘油酯(MCT)及丙二醇(PG)之不穿透性(參考實施例2之結果)。由此來看，使用該等液體作為香料含有液時，Glassine 25.8可使用作為插件捲取紙。The opacity of Glassine 25.8 before dropping was 20.9%, and the amount of change in opacity of 5% or more after dropping the medium chain fatty acid triglyceride (MCT) and propylene glycol (PG), and visually confirming the increase in transparency. In addition, Glassine 25.8 showed non-penetration of the medium chain fatty acid triglyceride (MCT) and propylene glycol (PG) (see the results of Reference Example 2). From this point of view, when using these liquids as perfume-containing liquids, Glassine 25.8 can be used as a plug-in take-up paper.
Glassine 40在滴下前之不透明度為31.2%，且滴下中鏈脂肪酸三酸甘油酯(MCT)、丙二醇(PG)及水後顯示5%以上之不透明度之變化量，並可以視覺確認透明度之增加。此外，Glassine 40顯示對中鏈脂肪酸三酸甘油酯(MCT)、丙二醇(PG)及水之不穿透性(參考實施例2之結果)。由此來看，使用該等液體作為香料含有液時，Glassine 40可使用作為插件捲取紙。The opacity of Glassine 40 before dripping was 31.2%, and the amount of change in opacity after 5% or more of the medium chain fatty acid triglyceride (MCT), propylene glycol (PG) and water was observed, and the increase in transparency was visually confirmed. . Further, Glassine 40 showed non-penetration of the medium chain fatty acid triglyceride (MCT), propylene glycol (PG), and water (the results of Reference Example 2). From this point of view, when these liquids are used as the fragrance-containing liquid, the Glassine 40 can be used as a card to take up the paper.
高透明Glassine 40在滴下前之不透明度為16.2%， 且滴下中鏈脂肪酸三酸甘油酯(MCT)後顯示5%以上之不透明度之變化量，並可以視覺確認透明度之增加。此外，高透明Glassine 40顯示對任何液體之不穿透性(參考實施例2之結果)。由此來看，高透明Glassine 40可使用作為插件捲取紙。The high transparency Glassine 40 has an opacity of 16.2% before dripping. Further, after the medium chain fatty acid triglyceride (MCT) was dropped, the amount of change in opacity of 5% or more was observed, and the increase in transparency was visually confirmed. In addition, the highly transparent Glassine 40 shows impermeability to any liquid (see the results of Example 2). From this point of view, the highly transparent Glassine 40 can be used as a plug-in to take up paper.
10‧‧‧煙草棒10‧‧‧Tobacco stick
11‧‧‧煙草填充材11‧‧‧Tobacco filler
12‧‧‧煙草捲紙12‧‧‧Tobacco roll paper
20‧‧‧濾嘴20‧‧‧ filter
21a‧‧‧濾嘴插件(細絲側)21a‧‧‧Filter insert (filament side)
21b‧‧‧濾嘴插件(吸口側)21b‧‧‧Filter plug (suck side)
22‧‧‧插件捲取紙22‧‧‧Insert roll-up paper
23‧‧‧香料膠囊23‧‧‧ Spice Capsules
23a‧‧‧皮膜23a‧‧ ‧ film
23b‧‧‧內容液23b‧‧‧Content liquid
30‧‧‧外層紙30‧‧‧ outer paper
D‧‧‧膠囊直徑D‧‧‧ capsule diameter
L1‧‧‧濾嘴插件21a之長度Length of L1‧‧‧ filter insert 21a
L2‧‧‧濾嘴插件21b之長度Length of L2‧‧‧ filter insert 21b
Lf‧‧‧濾嘴之全長Lf‧‧‧ filter full length
Lr‧‧‧煙草棒長度Lr‧‧‧Tobacco rod length
Lt‧‧‧外層紙長度Lt‧‧‧ outer paper length
Lt1、Lt2‧‧‧白底部分長度Lt1, Lt2‧‧‧ part length of white background
S‧‧‧中空部長度S‧‧‧ hollow length
第1A圖係表示本發明香煙之一部分在香煙膠囊壓壞前的截面圖。Figure 1A is a cross-sectional view showing a portion of the cigarette of the present invention before the cigarette capsule is crushed.
第1B圖係表示本發明香煙之一部分在香煙膠囊壓壞後的截面圖。Fig. 1B is a cross-sectional view showing a portion of the cigarette of the present invention after the cigarette capsule is crushed.
第2圖係表示本發明實施例之濾嘴的說明圖。Fig. 2 is an explanatory view showing a filter of an embodiment of the present invention.
第3圖係表示本發明實施例之香煙的說明圖。Fig. 3 is an explanatory view showing a cigarette of an embodiment of the present invention.
10‧‧‧煙草棒10‧‧‧Tobacco stick
11‧‧‧煙草填充材11‧‧‧Tobacco filler
12‧‧‧煙草捲紙12‧‧‧Tobacco roll paper
20‧‧‧濾嘴20‧‧‧ filter
21a‧‧‧濾嘴插件(細絲側)21a‧‧‧Filter insert (filament side)
21b‧‧‧濾嘴插件(吸口側)21b‧‧‧Filter plug (suck side)
22‧‧‧插件捲取紙22‧‧‧Insert roll-up paper
23‧‧‧香料膠囊23‧‧‧ Spice Capsules
23a‧‧‧皮膜23a‧‧ ‧ film
23b‧‧‧內容液23b‧‧‧Content liquid
30‧‧‧外層紙30‧‧‧ outer paper
Claims (7)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011172153 | 2011-08-05 |
Publications (2)
| Publication Number | Publication Date |
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| TW201318571A TW201318571A (en) | 2013-05-16 |
| TWI498089B true TWI498089B (en) | 2015-09-01 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101127938A TWI498089B (en) | 2011-08-05 | 2012-08-03 | Cigarette |
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| EP (1) | EP2740370B1 (en) |
| JP (1) | JP5728581B2 (en) |
| KR (1) | KR101589390B1 (en) |
| CN (1) | CN103702577B (en) |
| ES (1) | ES2570567T3 (en) |
| RU (1) | RU2544158C1 (en) |
| TW (1) | TWI498089B (en) |
| WO (1) | WO2013021863A1 (en) |
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- 2012-07-31 ES ES12822517T patent/ES2570567T3/en active Active
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- 2012-07-31 JP JP2013527972A patent/JP5728581B2/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2740370A1 (en) | 2014-06-11 |
| CN103702577B (en) | 2015-04-29 |
| ES2570567T3 (en) | 2016-05-19 |
| TW201318571A (en) | 2013-05-16 |
| EP2740370B1 (en) | 2016-04-20 |
| JPWO2013021863A1 (en) | 2015-03-05 |
| JP5728581B2 (en) | 2015-06-03 |
| EP2740370A4 (en) | 2015-06-17 |
| KR20140029536A (en) | 2014-03-10 |
| RU2544158C1 (en) | 2015-03-10 |
| CN103702577A (en) | 2014-04-02 |
| WO2013021863A1 (en) | 2013-02-14 |
| KR101589390B1 (en) | 2016-01-27 |
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