TWI461526B - Cleaner composition - Google Patents
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本發明係關於一種潔淨劑組合物，且特別關於一種潔淨劑組合物，其具有親水性與環保特性，且適用於各種硬及/或光滑表面之清潔。This invention relates to a cleansing composition, and more particularly to a cleansing composition which is hydrophilic and environmentally friendly and which is suitable for cleaning various hard and/or smooth surfaces.
空氣污染與酸雨現象等問題，使得大樓玻璃與金屬帷幕外牆易產生水垢斑漬、塵垢、金屬鏽垢與矽膠老化垂流現象，並導致大樓外觀快速醜化，進而影響都市建築之美觀。而目前一般市面上所使用之清潔劑多以陰/陽離子型或非離子型界面活性劑材料為主成分，但此類型之清潔劑並無法有效去除附著玻璃或建築外牆表面之上之水垢與填縫矽膠老化之垂流等污垢。為了有效處理大樓外牆表面問題，有一些大樓清潔業者甚至會以稀(氟)酸洗劑來進行處理，然此不但對人體有害，且對玻璃表面與環境亦具破壞性。Air pollution and acid rain phenomenon make the building glass and metal curtain exterior wall prone to scale stains, dust, metal rust and tantalum aging, and lead to rapid appearance of the building, which in turn affects the aesthetics of urban buildings. At present, most of the cleaning agents used in the market mainly contain anionic/cationic or nonionic surfactant materials, but this type of cleaning agent cannot effectively remove the scale on the surface of the attached glass or building exterior wall. Filling the aging of the aging rubber and other dirt. In order to effectively deal with the problem of the exterior wall surface of the building, some building cleaners even use dilute (fluorine) pickling agents for treatment, which is not only harmful to the human body, but also destructive to the glass surface and environment.
中華民國專利公告號170733揭示一種玻璃清潔劑組合物，其含有精細切割之矽石、輕微磨料、潤濕劑、水與酒精，其中精細切割之矽石的粒子大小為5-40毫微米，輕微磨料粒子為粒子大小為3-14微米之碳酸鈣，而潤濕劑為1,2-丙二醇-乙二醇脂醇類聚合物。美國專利公告號4,690,779(Baker等人)揭示一種硬表面清潔之組成物，包含10-14個碳之氧化胺(amine oxide)或甜菜鹼(betaine)界面活性劑、聚乙二醇、乙二胺四乙酸鈉鹽、丁氧基乙醇溶劑與水。E.P. 0393772與E.P. 0428816教示一硬表面清潔劑，其包括具有銨離子之陰離子界面活性劑和其他添加劑。又，G.B. 2,160,887揭露一種清潔系統，於其中合併使用非離子和陰離子界面活性劑(包括烷醇胺鹽烷基硫酸鹽)，以加強清潔效果。而WO 91/11505則描述一種玻璃清潔劑，其含有作為溶劑/緩衝劑之兩性離子界面活性劑、單乙醇胺及/或β-胺基烷醇以改善清潔效果與降低薄膜斑點的形成作用。中華民國專利公告號327649提供一種具有明顯改善殘留物清除效果之水性硬表面清潔劑，該清潔劑包含非離子界面活性劑、含氮緩衝劑、烷醇類溶劑與水。又中華民國專利公告號425427揭示一種水性、液態玻璃清潔用清潔劑組合物，其包含直鏈烷基硫酸鹽界面活性劑、疏水性溶劑、鹼性緩衝劑、非水性極性溶劑與會增加玻璃親水性之多羧酸鹽聚合體。The Republic of China Patent Publication No. 170733 discloses a glass cleaner composition comprising finely cut vermiculite, a slight abrasive, a wetting agent, water and alcohol, wherein the finely cut vermiculite has a particle size of 5-40 nm, slightly The abrasive particles are calcium carbonate having a particle size of 3 to 14 microns, and the wetting agent is a 1,2-propylene glycol-ethylene glycol fatty alcohol polymer. U.S. Patent No. 4,690,779 (Baker et al.) discloses a hard surface cleansing composition comprising 10-14 carbon amine oxide or betaine surfactant, polyethylene glycol, ethylene diamine Sodium tetraacetate, butoxyethanol solvent and water. E.P. 0 393 772 and E.P. 0428816 teach a hard surface cleaner comprising an anionic surfactant having ammonium ions and other additives. Further, G.B. 2,160,887 discloses a cleaning system in which a nonionic and anionic surfactant (including an alkanolamine salt alkyl sulfate) is used in combination to enhance the cleaning effect. WO 91/11505, on the other hand, describes a glass cleaner comprising a zwitterionic surfactant as a solvent/buffer, monoethanolamine and/or beta-aminoalkanol to improve the cleaning effect and reduce the formation of film spots. The Republic of China Patent Publication No. 327649 provides an aqueous hard surface cleaner having a significant improvement in residue removal, which comprises a nonionic surfactant, a nitrogen-containing buffer, an alkanol solvent and water. Also, the Republic of China Patent Publication No. 425427 discloses an aqueous, liquid glass cleaning detergent composition comprising a linear alkyl sulfate surfactant, a hydrophobic solvent, an alkaline buffer, a non-aqueous polar solvent, and an increase in glass hydrophilicity. Polycarboxylate polymer.
而由上述可知，目前大多硬表面之清潔劑仍以具有不同鹼性程度之無機或有機氮鹽做為清潔表面之主要組成，並於成份中添加醇類或烷醇類材料，來降低表面條紋與斑點的產生，或者採用多羧酸鹽聚合體增加玻璃之親水性，以增加清潔效果。然而，此類含氮材成之清潔劑並無法有效清除水垢、塵垢、金屬鏽垢與矽膠老化垂流等之附著物，而上述中華民國專利公告號170733所揭露之摩擦式玻璃清潔劑，雖可利用研磨切削之作用清除玻璃表面之附著物，但若處理不慎，則易使玻璃表面殘留研磨粒子，而導致需耗用較多之水來去除殘留之研磨粒子。As can be seen from the above, most of the hard surface cleaning agents still use inorganic or organic nitrogen salts with different basicity as the main components of the clean surface, and add alcohol or alkanol materials to the components to reduce surface streaks. The production of spots or the use of polycarboxylate polymers increases the hydrophilicity of the glass to increase the cleaning effect. However, such a nitrogen-containing detergent does not effectively remove the deposits of scale, grime, metal scale and tantalum aging, and the friction type glass cleaner disclosed in the above-mentioned Republic of China Patent Publication No. 170733, though The adhesion of the glass surface can be removed by the action of the grinding and cutting. However, if the treatment is inadvertent, the abrasive particles are likely to remain on the surface of the glass, which results in the consumption of more water to remove the remaining abrasive particles.
因此目前亟需一種新穎之潔淨劑組合物，其具有良好之親水性與環保之特性，且可有效去除表面附著物，並具有易沖洗與節能省水的功效。Therefore, there is a need for a novel detergent composition which has good hydrophilicity and environmental protection properties, and can effectively remove surface adhering substances, and has the advantages of easy washing, energy saving and water saving.
本發明提供一種潔淨劑組合物，其成分包括：一無機粉體；一可分解之高分子材料；一保濕劑；以及一溶劑。The present invention provides a cleansing composition comprising: an inorganic powder; a decomposable polymeric material; a humectant; and a solvent.
為了讓本發明之上述和其他目的、特徵、和優點能更明顯易懂，下文特舉較佳實施例，並配合所附圖示，作詳細說明如下：The above and other objects, features and advantages of the present invention will become more apparent from
本發明提供一潔淨劑組合物，其有良好之親水性與環保特性，並具有可有效去除表面附著物、易沖洗之優點，進而可達成節能省水之功效。且，本發明之潔淨劑組合物適用於一表面之清潔。The invention provides a cleansing agent composition which has good hydrophilicity and environmental protection characteristics, and has the advantages of effectively removing surface adhering substances and being easy to be washed, thereby achieving energy saving and water saving effect. Moreover, the cleansing composition of the present invention is suitable for cleaning a surface.
上述本發明之潔淨劑組合物，可包括，但不限於，一無機粉體、一可分解之高分子材料、一保濕劑與一溶劑。在一實施例中，於上述潔淨劑組合物中，無機粉體可為約1-75重量份，較佳為10-50重量份、可分解之高分子材料可為約0.05-5重量份，較佳為0.2-2.0重量份、保濕劑可為約0.1-50重量份，較佳為5-40重量份，且溶劑可為約10-90重量份，較佳為20-60重量份。The above cleansing agent composition of the present invention may include, but is not limited to, an inorganic powder, a decomposable polymer material, a humectant and a solvent. In one embodiment, the inorganic powder may be from about 1 to 75 parts by weight, preferably from 10 to 50 parts by weight, and the decomposable polymer material may be from about 0.05 to 5 parts by weight in the detergent composition. It is preferably 0.2 to 2.0 parts by weight, the humectant may be from about 0.1 to 50 parts by weight, preferably from 5 to 40 parts by weight, and the solvent may be from about 10 to 90 parts by weight, preferably from 20 to 60 parts by weight.
上述無機粉體具有研磨及/或拋光之作用，其例子可包括氧化矽、氧化鋁、氧化鈰、碳酸鈣、氧化鎂、氧化鐵、氧化鈦、氧化鋯或碳化矽，但不限於此。而上述無機粉體之粒徑大小可為約0.05-10 μm，在一實施例中為約0.1-3 μm。The above inorganic powder has a function of grinding and/or polishing, and examples thereof may include cerium oxide, aluminum oxide, cerium oxide, calcium carbonate, magnesium oxide, iron oxide, titanium oxide, zirconium oxide or cerium carbide, but are not limited thereto. The above inorganic powder may have a particle size of about 0.05 to 10 μm, and in one embodiment, about 0.1 to 3 μm.
上述可分解之高分子材料具有粒子穩定分散劑之功效，並具有增稠劑或黏度調整劑之作用以調整本發明之潔淨劑組合物之黏度而避免使用時產生嚴重垂流之問題。此外，上述可分解之高分子材料符合生物可分解度的要求，因此具有環保性。上述可分解之高分子材料可包括，但不限於羥基乙基纖維素(HEC)、羥基丙基纖維素(HPC)、羧基甲基纖維素鈉(NaCMC)、聚乙烯醇(PVA)或海藻萃取物。海藻萃取物的例子可包括三仙膠、洋菜等，但不限於此。The above decomposable polymer material has the effect of a particle-stabilizing dispersant and has the function of a thickener or a viscosity modifier to adjust the viscosity of the detergent composition of the present invention to avoid the problem of severe sag when used. In addition, the above-mentioned decomposable polymer material meets the requirements of biodegradability and is therefore environmentally friendly. The above decomposable polymer material may include, but is not limited to, hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), sodium carboxymethyl cellulose (NaCMC), polyvinyl alcohol (PVA) or seaweed extraction. Things. Examples of the seaweed extract may include, but are not limited to, Sanxian gum, Chinese cabbage, and the like.
而在使用本發明潔淨組合物清潔一待清潔之表面之時，於本發明潔淨組合物中之保濕劑搭配上述無機粉體對此表面所進行的研磨，而可使得此表面具親水特性而易形成水膜披覆，進而達成容易去除表面之污垢與殘留於此表面上之無機粉體的效果。保濕劑可包括一多羥結構分子，例如一多元醇。於本發明潔淨組合物中，適合之多元醇的例子，可包括，但不限於乙二醇、丙二醇、丙三醇、丁二醇、己二醇、己六醇、木糖醇、聚乙二醇(polyethylene glycol,PEG)與聚丙二醇(polypropylene glycol,PPG)等。在一實施例中，上述聚乙二醇的例子可為聚乙二醇200，但不限於此。在另一實施例中，上述聚丙二醇的例子可為聚丙二醇400，但不限於此。When the surface to be cleaned is cleaned by using the cleansing composition of the present invention, the moisturizing agent in the cleansing composition of the present invention is ground with the inorganic powder to make the surface hydrophilic, and the surface is hydrophilic. The formation of a water film is carried out, and the effect of easily removing the dirt on the surface and the inorganic powder remaining on the surface is achieved. The humectant can include a polyhydroxy structural molecule, such as a polyol. Examples of suitable polyols in the cleansing compositions of the present invention may include, but are not limited to, ethylene glycol, propylene glycol, glycerol, butylene glycol, hexanediol, hexahexaol, xylitol, polyethylene. Polyethylene glycol (PEG) and polypropylene glycol (PPG). In one embodiment, an example of the above polyethylene glycol may be polyethylene glycol 200, but is not limited thereto. In another embodiment, an example of the above polypropylene glycol may be polypropylene glycol 400, but is not limited thereto.
於本發明潔淨組合物中，上述溶劑可包括水、酒精、異丙醇或丙酮，但不限於此。In the cleansing composition of the present invention, the above solvent may include water, alcohol, isopropanol or acetone, but is not limited thereto.
此外，本發明之潔淨劑組合物，除上述成分外，還可更包括一界面活性劑。在一實施例中，於本發明潔淨劑組合物中，界面活性劑可為約0.05-5重量份，較佳為0.1-2重量份。界面活性劑可包括陰離子界面活性劑、陽離子界面活性劑或非離子型界面活性劑。陰離子界面活性劑的例子可包括，但不限於烷基羧酸酯鹽、烷基硫酸酯鹽等。陽離子界面活性劑的例子可包括，但不限於烷基四級胺鹽、胺基化合物等。非離子型界面活性劑的例子可包括，但不限於烷基醇醯胺、多元醇脂肪酸酯等。在一實施例中，界面活性劑為屬於陰離子界面活性劑之月桂醇聚醚硫酸酯鈉鹽(sodium laureth sulfate)。Further, the cleansing composition of the present invention may further comprise a surfactant in addition to the above components. In one embodiment, the surfactant may be from about 0.05 to about 5 parts by weight, preferably from 0.1 to 2 parts by weight, in the cleansing composition of the present invention. Surfactants can include anionic surfactants, cationic surfactants, or nonionic surfactants. Examples of anionic surfactants may include, but are not limited to, alkyl carboxylate salts, alkyl sulfate salts, and the like. Examples of the cationic surfactant may include, but are not limited to, an alkyl quaternary ammonium salt, an amine compound, and the like. Examples of the nonionic surfactant may include, but are not limited to, alkyl decylamine, polyhydric alcohol fatty acid ester, and the like. In one embodiment, the surfactant is sodium laureth sulfate which is an anionic surfactant.
再者，如前所述，本發明之潔淨劑組合物適用於一表面之清潔。在一實施例中，上述表面可為一硬/及或光滑之表面。而經本發明潔淨劑組合物處理後，上述表面在以本發明之潔淨劑組合物處理後之接觸角相較於處理前可降低約25°以上，較佳為可降低約55°以上。上述表面之例子可包括，但不限於玻璃、金屬、塑膠、石材與陶瓷等之表面。在一實施例中，本發明之潔淨劑組合物所處理之表面為玻璃之表面，而經本發明之潔淨劑組合物處理後，此玻璃之表面之接觸角可達約10度以下。Further, as described above, the cleansing composition of the present invention is suitable for cleaning a surface. In one embodiment, the surface may be a hard/and or smooth surface. After treatment with the cleansing composition of the present invention, the contact angle of the surface after treatment with the cleansing composition of the present invention can be reduced by about 25 or more, preferably by about 55 or more, before treatment. Examples of such surfaces may include, but are not limited to, surfaces of glass, metal, plastic, stone, ceramic, and the like. In one embodiment, the surface treated by the cleansing composition of the present invention is the surface of the glass, and after treatment with the cleansing composition of the present invention, the surface of the glass has a contact angle of up to about 10 degrees.
又，將本發明之潔淨劑組合物以摩擦擦拭之方式來清潔上述表面時，由於其中之無機粒子摩擦研磨此表面，並搭配保濕劑於此表面上形成一水膜，而使得表面上之附著物，例如水垢、垂流矽油、鏽垢…等不易去除之附著物，可輕易被去除，並且不易殘留無機粒子與此表面上，而易於沖洗，進而可達成成節能省水之功效。Further, when the cleansing agent composition of the present invention is used to clean the surface by rubbing, the inorganic particles are rubbed and rubbed on the surface, and a water film is formed on the surface with a moisturizing agent to cause adhesion on the surface. The deposits, such as scale, sloping oil, rust, etc., which are difficult to remove, can be easily removed, and the inorganic particles are not easily left on the surface, and are easy to rinse, thereby achieving energy saving and water saving effects.
【實施例】[Examples]
1. 本發明潔淨劑組合物之各實施例的製備與比較例的製備1. Preparation of Comparative Examples of the Cleaner Composition of the Invention and Preparation of Comparative Examples
(1) 實施例1(1) Example 1
在實施例1中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表1所示。將各成分分別加入製備容器內，並持續以攪拌器充分攪拌，使所有成分混合均勻，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約100-500 nm(廠商：Almatis，商品編號P10F)。In Example 1, the components of the composition and their contents are shown in Table 1 on the basis of 100 g as the total weight of the composition. Each component is separately added to the preparation vessel, and is continuously stirred with a stirrer to uniformly mix all the components to obtain a stably dispersed detergent composition. The inorganic powder has a particle diameter of about 100 to 500 nm (manufacturer: Almatis, product number P10F).
表1、實施例1之組合物的成分配方Table 1, composition formula of the composition of Example 1
(2) 實施例2(2) Example 2
在實施例2中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表2所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約100-500 nm(廠商：Almatis，商品編號P10F)。In Example 2, the components of the composition and their contents are shown in Table 2 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The inorganic powder has a particle diameter of about 100 to 500 nm (manufacturer: Almatis, product number P10F).
表2、實施例2之組合物的成分配方Table 2, ingredient formulation of the composition of Example 2
(3) 實施例3(3) Example 3
在實施例3中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表3所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約1-5 μm(廠商：Almatis，商品編號PSG300)。In Example 3, the components of the composition and their contents are shown in Table 3 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The particle size of the inorganic powder is about 1-5 μm (manufacturer: Almatis, product number PSG300).
表3、實施例3之組合物的成分配方Table 3, the composition of the composition of the composition of Example 3
(4) 實施例4(4) Example 4
在實施例4中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表4所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約100-500 nm(廠商：Almatis，商品編號P10F)。In Example 4, the components of the composition and their contents are shown in Table 4 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The inorganic powder has a particle diameter of about 100 to 500 nm (manufacturer: Almatis, product number P10F).
表4、實施例4之組合物的成分配方Table 4, the composition of the composition of the composition of Example 4
(5) 實施例5(5) Example 5
在實施例5中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表5所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約1-10 μm(廠商：American Tripoli，商品名稱TRIPOLI CLAY)。In Example 5, the components of the composition and their contents are shown in Table 5 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The inorganic powder has a particle size of about 1-10 μm (manufacturer: American Tripoli, trade name TRIPOLI CLAY).
表5、實施例5之組合物的成分配方Table 5, the composition of the composition of the composition of Example 5
(6) 實施例6(6) Example 6
在實施例6中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表6所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約50-100 nm(廠商：景明化工，商品編號TG-020-000000-93NL)。In Example 6, the components of the composition and their contents are shown in Table 6 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The particle size of the inorganic powder is about 50-100 nm (manufacturer: Jing Ming Chemical, trade number TG-020-000000-93NL).
表6、實施例6之組合物的成分配方Table 6. Formulations of the compositions of Example 6
(7) 實施例7(7) Example 7
在實施例7中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表7所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約200-500 nm(廠商：Aldrich，商品編號Aldrich #239216)。In Example 7, the components of the composition and their contents are shown in Table 7 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The particle size of the inorganic powder is about 200-500 nm (manufacturer: Aldrich, trade number Aldrich #239216).
表7、實施例7之組合物的成分配方Table 7. Formulation of the composition of the composition of Example 7
(8) 實施例8(8) Example 8
在實施例8中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表8所示。配製方法可參見實施例1所述，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約100-500 nm(廠商：Almatis，商品編號P10F)。In Example 8, the components of the composition and their contents are shown in Table 8 on the basis of 100 g as the total weight of the composition. The preparation method can be as described in Example 1, to obtain a stable dispersion of the cleansing composition. The inorganic powder has a particle diameter of about 100 to 500 nm (manufacturer: Almatis, product number P10F).
表8、實施例8之組合物的成分配方Table 8. Formulation of the composition of the composition of Example 8.
(9) 比較例1(9) Comparative example 1
在比較例1中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表9所示。將各成分分別加入製備容器內，並持續以攪拌器充分攪拌，使所有成分混合均勻，即可獲得一穩定分散之潔淨劑組合物。無機粉體之粒徑為約100-500 nm(廠商：Almatis，商品編號P10F)。In Comparative Example 1, the components of the composition and their contents are shown in Table 9 on the basis of 100 g as the total weight of the composition. Each component is separately added to the preparation vessel, and is continuously stirred with a stirrer to uniformly mix all the components to obtain a stably dispersed detergent composition. The inorganic powder has a particle diameter of about 100 to 500 nm (manufacturer: Almatis, product number P10F).
表9、比較例1之組合物的成分配方Table 9. Formulation of the composition of the composition of Comparative Example 1.
(10) 比較例2(10) Comparative Example 2
在比較例2中，以100 g做為組合物之總重的基準，組合物之各成分與其含量如表10所示。將各成分分別加入製備容器內，並持續以攪拌器充分攪拌，使所有成分混合均勻，即可獲得一穩定分散之潔淨劑組合物。In Comparative Example 2, each component of the composition and its content are shown in Table 10 on the basis of 100 g as the total weight of the composition. Each component is separately added to the preparation vessel, and is continuously stirred with a stirrer to uniformly mix all the components to obtain a stably dispersed detergent composition.
表10、比較例2之組合物的成分配方Table 10, composition formula of the composition of Comparative Example 2
(11) 比較例3(11) Comparative Example 3
以市售商品3M玻璃油膜拔除劑為比較例3，其主要成份如表11所示。The commercially available 3M glass oil film extracting agent was Comparative Example 3, and the main components thereof are shown in Table 11.
表11、比較例3之主要成份Table 11, the main components of Comparative Example 3
(12) 比較例4(12) Comparative Example 4
以市售商品石原(ISK) ST-K253為比較例4，其主要成份如表12所示。Commercially available product Ishihara (ISK) ST-K253 was used as Comparative Example 4, and its main components are shown in Table 12.
表12、比較例4之主要成份Table 12, the main components of Comparative Example 4
(13) 比較例5(13) Comparative Example 5
以市售泡舒洗潔劑為比較例5，其主要成份如表13所示。A commercially available bubble-washing detergent was used as Comparative Example 5, and the main components thereof are shown in Table 13.
表13、比較例5之主要成份Table 13, the main components of Comparative Example 5
(14) 比較例6(14) Comparative Example 6
以市售穩潔玻璃清潔劑為比較例6，其主要成份如表14所示。A commercially available stable glass cleaner was used as Comparative Example 6, and the main components thereof are shown in Table 14.
表14、比較例6之主要成份Table 14, the main components of Comparative Example 6
2. 以各實施例或比較例之組合物處理前與處理後之表面的親水特性測定(接觸角測量)2. Determination of hydrophilicity of the surface before and after treatment of the compositions of the respective examples or comparative examples (contact angle measurement)
接觸角測量方法Contact angle measurement method
表面之親水特性乃藉由一表面於清潔前、後的接觸角改變做為判定，依ASTM D7334之測試方法進行接觸角量測。首先以布或紙巾擦拭一表面之灰塵，並以自動定量滴水器垂滴0.5 μl之純水於此表面上，並以攝影機擷取畫面，再以軟體分析水滴與此表面之接觸角。接著以各實施例或比較例之組合物使用於此表面上，經磨擦處理洗淨後，以接觸角量測儀進行上述表面接觸角量測。The hydrophilic character of the surface is determined by the change of the contact angle of a surface before and after cleaning, and the contact angle measurement is performed according to the test method of ASTM D7334. First, wipe the dust on a surface with a cloth or paper towel, and drop 0.5 μl of pure water on the surface with an automatic quantitative dripper, and take a picture with a camera, and then analyze the contact angle of the water drop with the surface by software. Next, the composition of each of the examples or the comparative examples was used on the surface, and after washing by a rubbing treatment, the surface contact angle measurement was performed by a contact angle measuring instrument.
(1) 以實施例1之組合物處理前與處理後之表面的接觸角測量(1) Measurement of contact angle of the surface before and after treatment with the composition of Example 1.
(i) 以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表15所示。(i) A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 15.
表15、以實施例1之組合物處理前及處理後之玻璃平板的接觸角測量Table 15. Measurement of contact angle of glass plates before and after treatment with the composition of Example 1.
此外，經霧度測量後，測得以實施例1之組合物處理前與處理後之表面的霧度分別為0.3%與0.2%。而實施例1之組合物處理前與處理後之表面的穿透度測量結果如第1圖所示。Further, after the haze measurement, the haze of the surface before and after the treatment of the composition of Example 1 was 0.3% and 0.2%, respectively. The measurement results of the transmittance of the surface before and after the treatment of the composition of Example 1 are shown in Fig. 1.
(ii) 以厚度1 mm之不鏽鋼平板為測試表面，依照前述接觸角測量方法進行測量，結果如表16所示。(ii) A stainless steel plate having a thickness of 1 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 16.
表16、以實施例1之組合物處理前及處理後之不鏽鋼平板的接觸角測量Table 16. Contact angle measurement of stainless steel plates before and after treatment with the composition of Example 1.
(iii) 以厚度1 mm之鋁板為測試表面，依照前述接觸角測量方法進行測量，結果如表17所示。(iii) Using an aluminum plate having a thickness of 1 mm as a test surface, the measurement was carried out in accordance with the aforementioned contact angle measurement method, and the results are shown in Table 17.
表17、以實施例1之組合物處理前及處理後之鋁板的接觸角測量Table 17. Contact angle measurement of aluminum sheets before and after treatment with the composition of Example 1.
(iv) 以厚度10 mm之平面大理石材一為測試表面，依照前述接觸角測量方法進行測量，結果如表18所示。(iv) A flat marble material having a thickness of 10 mm was used as the test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 18.
表18、以實施例1之組合物處理前及處理後之平面大理石材一(廠商：力豐石材有限公司，商品名稱：印度紅)的接觸角測量Table 18: Contact angle measurement of a flat marble material (manufacturer: Lifeng Stone Co., Ltd., trade name: Indian red) before and after treatment with the composition of Example 1.
(v) 以厚度10 mm之平面大理石材二(廠商：力豐石材有限公司，商品名稱：帝諾石)為測試表面，依照前述接觸角測量方法進行測量，結果如表19所示。(v) The surface of the marble material 2 (manufacturer: Lifeng Stone Co., Ltd., trade name: Dino Stone) having a thickness of 10 mm was used as the test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 19.
表19、以實施例1之組合物處理前及處理後之平面大理石材二的接觸角測量Table 19. Measurement of contact angle of planar marble 2 before and after treatment with the composition of Example 1.
(2) 以實施例2之組合物處理前與處理後之表面的接觸角測量(2) Measurement of contact angle of the surface before and after treatment with the composition of Example 2
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表20所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 20.
表20、以實施例2之組合物處理前及處理後之玻璃平板的接觸角測量Table 20, Measurement of contact angle of glass plates before and after treatment with the composition of Example 2
(3) 以實施例3之組合物處理前與處理後之表面的接觸角測量(3) Measurement of contact angle of the surface before and after treatment with the composition of Example 3
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表21所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 21.
表21、以實施例3之組合物處理前及處理後之玻璃平板的接觸角測量Table 21, Measurement of contact angle of glass plates before and after treatment with the composition of Example 3.
(4) 以實施例4之組合物處理前與處理後之表面的接觸角測量(4) Measurement of contact angle of the surface before and after treatment with the composition of Example 4
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表22所示。A glass plate having a thickness of 3 mm was used as a test surface, and measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 22.
表22、以實施例4之組合物處理前及處理後之玻璃平板的接觸角測量Table 22, Measurement of contact angle of glass plates before and after treatment with the composition of Example 4
(5) 以實施例5之組合物處理前與處理後之表面的接觸角測量(5) Measurement of contact angle of the surface before and after treatment with the composition of Example 5
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表23所示。A glass plate having a thickness of 3 mm was used as a test surface, and measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 23.
表23、以實施例5之組合物處理前及處理後之玻璃平板的接觸角測量Table 23, Measurement of contact angle of glass plates before and after treatment with the composition of Example 5
(6) 以實施例6之組合物處理前與處理後之表面的接觸角測量(6) Measurement of contact angle of the surface before and after treatment with the composition of Example 6
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表24所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 24.
表24、以實施例6之組合物處理前及處理後之玻璃平板的接觸角測量Table 24, Measurement of contact angle of glass plates before and after treatment with the composition of Example 6
(7) 以實施例7之組合物處理前與處理後之表面的接觸角測量(7) Measurement of contact angle of the surface before and after treatment with the composition of Example 7
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表25所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 25.
表25、以實施例7之組合物處理前及處理後之玻璃平板的接觸角測量Table 25. Measurement of contact angle of glass plates before and after treatment with the composition of Example 7
(8) 以實施例8之組合物處理前與處理後之表面的接觸角測量(8) Measurement of contact angle of the surface before and after treatment with the composition of Example 8
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表26所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 26.
表26、以實施例8之組合物處理前及處理後之玻璃平板的接觸角測量Table 26. Measurement of contact angle of glass plates before and after treatment with the composition of Example 8.
(9) 以比較例1之組合物處理前與處理後之表面的接觸角測量(9) Measurement of contact angle of the surface before and after treatment of the composition of Comparative Example 1
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表27所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 27.
表27、以比較例1之組合物處理前及處理後之玻璃平板的接觸角測量Table 27. Measurement of contact angle of glass plates before and after treatment with the composition of Comparative Example 1.
(10) 以比較例2之組合物處理前與處理後之表面的接觸角測量(10) Measurement of contact angle of the surface before and after treatment of the composition of Comparative Example 2
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表28所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 28.
表28、以比較例2之組合物處理前及處理後之玻璃平板的接觸角測量Table 28, Measurement of contact angle of glass plates before and after treatment with the composition of Comparative Example 2
(11) 以比較例3之組合物處理前與處理後之表面的接觸角測量(11) Measurement of contact angle of the surface before and after treatment of the composition of Comparative Example 3
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表29所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 29.
表29、以比較例3之組合物處理前及處理後之玻璃平板的接觸角測量Table 29, Measurement of contact angle of glass plates before and after treatment with the composition of Comparative Example 3
(12) 以比較例4之組合物處理前與處理後之表面的接觸角測量(12) Measurement of contact angle of the surface before and after treatment of the composition of Comparative Example 4
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表30所示。A glass plate having a thickness of 3 mm was used as a test surface, and measurement was carried out in accordance with the aforementioned contact angle measurement method, and the results are shown in Table 30.
表30、以比較例4之組合物處理前及處理後之玻璃平板的接觸角測量Table 30, Measurement of contact angle of glass plates before and after treatment with the composition of Comparative Example 4
(13) 以比較例5之組合物處理前與處理後之表面的接觸角測量(13) Measurement of contact angle of the surface before and after treatment of the composition of Comparative Example 5
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表31所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 31.
表31、以比較例5之組合物處理前及處理後之玻璃平板的接觸角測量Table 31, Measurement of contact angle of glass plates before and after treatment with the composition of Comparative Example 5
(14) 以比較例6之組合物處理前與處理後之表面的接觸角測量(14) Measurement of contact angle of the surface before and after treatment of the composition of Comparative Example 6
以厚度3 mm之玻璃平板為測試表面，依照前述接觸角測量方法進行測量，結果如表32所示。A glass plate having a thickness of 3 mm was used as a test surface, and the measurement was carried out in accordance with the aforementioned contact angle measurement method. The results are shown in Table 32.
表32、以比較例6之組合物處理前及處理後之玻璃平板的接觸角測量Table 32. Measurement of contact angle of glass plates before and after treatment with the composition of Comparative Example 6
由上示結果可以得知，對於處理玻璃平面而言，相較於各比較例，經本發明之潔淨劑組合物之各實施例處理後之玻璃皆可測得較小之接觸角。且經各實施例處理後之玻璃的接觸角皆為10°以下，甚至為10°以下，而此清楚顯示本發明之潔淨劑組合物對於玻璃具有超親水性。As can be seen from the above results, for the treated glass plane, the glass treated by each of the examples of the cleansing composition of the present invention can measure a small contact angle as compared with each comparative example. Further, the contact angle of the glass treated by each of the examples was 10 or less, or even 10 or less, and it was clearly shown that the cleansing composition of the present invention is superhydrophilic to the glass.
又，根據上述結果也可得知，相較於本發明各實施例，組合物中缺乏無機粉體或保濕劑任一者(參見比較例1與2)，皆會導致經其處理後之玻璃表面的接觸角的下降程度不如本發明各實施例所處理之玻璃表面。Further, based on the above results, it is also known that any of the lack of inorganic powder or humectant in the composition (see Comparative Examples 1 and 2) causes the treated glass to be compared with the examples of the present invention. The degree of contact of the surface is not reduced as much as the surface of the glass treated in accordance with various embodiments of the present invention.
另外，由上述結果也可得知，除玻璃表面外，經本發明之潔淨劑組合物處理其他材料表面，例如不鏽鋼平板、鋁板、大理石材，其接觸角也大幅降低，而此也代表本發明之潔淨劑組合物對於其他材料之表面也具有良好之親水性。In addition, as can be seen from the above results, in addition to the surface of the glass, the surface of other materials treated by the detergent composition of the present invention, such as stainless steel flat plate, aluminum plate, marble material, the contact angle thereof is also greatly reduced, and this also represents the present invention. The cleansing composition also has good hydrophilicity to the surface of other materials.
雖然本發明已以較佳實施例揭露如上，然其並非用以限定本發明，任何熟習此技藝者，在不脫離本發明之精神和範圍內，當可作些許之更動與潤飾，因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application.
第1圖顯示以實施例1之組合物處理前與處理後之玻璃表面的穿透度測量結果。Fig. 1 shows the results of measurement of the transmittance of the glass surface before and after the treatment with the composition of Example 1.
Claims (23)
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| WO2011130460A1 (en) * | 2010-04-14 | 2011-10-20 | Lubrizol Advanced Materials, Inc. | Thickened amino acid surfactant compositions and methods therefor |
| US20110262371A1 (en) * | 2010-04-21 | 2011-10-27 | Geert Andre Deleersnyder | Liquid cleaning and/or cleansing composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205509A (en) * | 2006-12-22 | 2008-06-25 | 苏伟光 | Inorganic abradant cleaning paste |
| CN101392213B (en) * | 2008-03-17 | 2012-04-18 | 蒋暾 | Washing paste for removing paint |
| CN101993795A (en) * | 2010-11-18 | 2011-03-30 | 林琳 | Leather sneaker cleaning paste and preparation method thereof |
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- 2012-04-17 TW TW101113569A patent/TWI461526B/en active
- 2012-05-25 CN CN2012101657276A patent/CN103374476A/en active Pending
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| WO1998013457A1 (en) * | 1996-09-27 | 1998-04-02 | The Procter & Gamble Company | Cleaning compositions comprising a mycodextranase |
| US6342473B1 (en) * | 1999-01-20 | 2002-01-29 | The Procter & Gamble Company | Hard surface cleaning compositions comprising modified alkylbenzene sulfonates |
| US20050130873A1 (en) * | 2002-02-21 | 2005-06-16 | Cheung Tak W. | Hard surface cleaning compositions |
| US20050124519A1 (en) * | 2003-12-03 | 2005-06-09 | Sherry Alan E. | Method, articles and compositions for cleaning bathroom surfaces |
| WO2011130460A1 (en) * | 2010-04-14 | 2011-10-20 | Lubrizol Advanced Materials, Inc. | Thickened amino acid surfactant compositions and methods therefor |
| US20110262371A1 (en) * | 2010-04-21 | 2011-10-27 | Geert Andre Deleersnyder | Liquid cleaning and/or cleansing composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103374476A (en) | 2013-10-30 |
| TW201343906A (en) | 2013-11-01 |
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