TWI403353B - Carbon dioxide resolve/decompose and c4+nm state carbon recycle device and method - Google Patents

Carbon dioxide resolve/decompose and c4+nm state carbon recycle device and method Download PDF

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TWI403353B
TWI403353B TW097126060A TW97126060A TWI403353B TW I403353 B TWI403353 B TW I403353B TW 097126060 A TW097126060 A TW 097126060A TW 97126060 A TW97126060 A TW 97126060A TW I403353 B TWI403353 B TW I403353B
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carbon dioxide
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hydrogen
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TW201002412A (en
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Shu Chin Chen
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Shu Chin Chen
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Abstract

uv+CO2+&Dgr;nM+2H2+4e-&rerr;C+2H2O+∇nM; That equation can let Carbon Dioxide be broken. In this proposal, we provide a highly original solution to resolve/decompose carbon dioxide into useful by-products thus providing industrial values to businesses around world with which carbon emission control is of utmost importance. Thus far, as we know it, only plants and few blue and green bacteria are able to perform photo-synthesis, which is, removing carbon from CO2 using photon. The electrons, which are excited by photons, escape from their orbit, and with ATP (Adenosine triphosphate) as bio-catalyses medium turns carbon into carbo-hydrate. The chemical equation is 6CO2+6H2O&rerr;C6H12O6+6O2↑, and is the only efficient way to reduce/remove carbon dioxide, the green house gas, from earth until now. This proposal brings an idea based on nanotechnology. With this technology, we build a nano-material which is structured as a tree with the branches and leaves being tentacles. When the temperature is between 100 DEG C and 200 DEG C, those tentacles will shape themselves into nanometer holes to catch ion or water. The chemical equation: uv+CO2+&Dgr;nM+2H2+4e-&rerr;C+2H2O+∇nM. Those two chemical equations have one common subject, that's they both take high energy light particles from sun to break the quantum effect of electron bond between carbon and oxygen.

Description

二氧化碳分解及(C4+nM)狀態碳回收裝置及方法 Carbon dioxide decomposition and (C4+nM) state carbon recovery device and method

近200年來人類大量使用石化能源來支持產業及科技的發展，我們將這兩個世紀的世界文明稱之為碳的文明或碳的世代實不為過，大量使用石化能源造成了今日大氣中二氧化碳溫室氣體不斷上升的不良後果，由公元1800年的280ppm.升高到目前的380ppm.左右；設若人類依然不針對二氧化碳溫室氣體加以有效的控制，預計到本世紀中葉的2050年左右，地球上二氧化碳溫室氣體的濃度，將上升至危險的500ppm.以上的水準，這將是地球無可承受的重。 In the past 200 years, human beings have used petrochemical energy to support the development of industry and science and technology. We have called the world civilization of these two centuries a carbon civilization or a generation of carbon. The massive use of petrochemical energy has caused carbon dioxide in the atmosphere today. The adverse consequences of rising greenhouse gases have risen from 280 ppm in 1800 to about 380 ppm today; if humans still do not effectively control carbon dioxide greenhouse gases, it is expected that carbon dioxide on Earth will be around 2050 in the middle of this century. The concentration of greenhouse gases will rise to a dangerous level of 500 ppm. This will be an unbearable weight for the Earth.

據媒體報導，2007年12月聯合國主要國家的專家代表們在印尼的巴里島達成了氣候變遷協商，希望在2050年之前將地球二氧化碳溫室氣體的濃度控制在440ppm.，這意味著人類未來半個世紀的每一天，都必須減少二氧化碳溫室氣體的排放量約30%而不影響經濟發展及生活的品質；由此看來，未來二氧化碳溫室氣體減量的工程確實浩大，而且所必需投入的成本更是驚人，但地球只有一個，有能力挽救地球的生物又只有人類，我們實在責無旁貸。 According to media reports, in December 2007, expert representatives from major UN countries reached a climate change consultation in Bali, Indonesia, hoping to control the concentration of greenhouse carbon dioxide greenhouse gases at 440 ppm by 2050, which means that the future of humans will be half. Every day of the century, it is necessary to reduce carbon dioxide greenhouse gas emissions by about 30% without affecting the economic development and quality of life. From this point of view, the future project of carbon dioxide greenhouse gas reduction is indeed huge, and the cost of the necessary investment is Amazing, but there is only one planet, the ability to save the earth's creatures and only humans, we are really duty-bound.

本發明二氧化碳分解回收裝置係利用一個奈米尺度的突觸狀導電結構體(nM)，外表有很多呈現鬆散突觸狀的觸鬚，這些觸鬚在溫度150℃~180℃時會糾結形成奈米孔洞，可以捕捉碳離子，成為(C4+nM)狀態碳，在溫度降低至90℃~30℃時，這些糾結的奈米觸鬚又回復為鬆散的突觸狀，可釋出由(C4+nM)狀態碳還原為碳(C)之顆粒，然後等待下次加溫再進行另一個循環的利用，本發明利用這個奈米體(nM)所具備的電子鍵結代償特 性、溫變調控特性以及可伸縮變異的機械特性等集三種性能於一體的神奇特性，使本發明能一舉破解二氧化碳〝碳--氧〞間化學鍵結牢不可破的迷失；利用分階段的工序，創造出這個全球首創的二氧化碳分解回收裝置，本發明除了能分解二氧化碳，使之能被回收為碳(C)與水(H2O)之外，又兼有燃料電池的功能，可彌補分解與回收二氧化碳時所需的能源消耗量，更可回收高純度的奈米級純碳等多重實用效果。 The carbon dioxide decomposition recovery device of the invention utilizes a nano-scale synaptic conductive structure (nM), and has many tentacles which are loosely synaptic, and the tentacles are entangled to form nanopores at a temperature of 150 ° C to 180 ° C. It can capture carbon ions and become (C 4+ nM) state carbon. When the temperature is lowered to 90 ° C ~ 30 ° C, these entangled nano-touchers return to loose synapses, which can be released by (C 4+ nM) state carbon is reduced to carbon (C) particles, and then waiting for the next heating and then another cycle of utilization, the present invention utilizes the electronic bond compensating property and temperature-regulating characteristics of the nano-body (nM) And the mechanical properties of the scalable variability, the magical characteristics of the three properties, so that the invention can solve the unbreakable loss of carbon dioxide 〝 carbon-oxygen enthalpy chemical bond; use the staged process to create the world's first carbon dioxide when the required decomposition of recovery, in addition to the present invention can decompose carbon dioxide, so as to be recovered as a carbon (C) and water (H 2 O) beyond, and both the function of the fuel cell, can make up the decomposition and recovery of carbon dioxide Energy consumption, high purity recycled more pure carbon, such as multiple nanoscale practical effect.

過去雖有些技術與能力可暫時將二氧化碳吸附並侷限於特定材質中，例如氫氧化鈉(sodium hydroxide)(NaOH)，其方程式為：NaOH+CO2→NaHCO3，但當該材質吸附達飽和時，所有的反應即已無以為繼，如同當年美國太空船阿波羅13號所曾經面對的狀況，因此使用特定吸附材料，雖可有限度的處理二氧化碳濃度太高的狀況，但對於大量溫室氣體二氧化碳減量的工程，並無多大的應用價值；最近亦有人試圖採用〝藍綠菌〞(cyanobacteria)光合作用的能力，用來對付工廠所排放的高濃度二氧化碳，但藍綠菌受陽光、溫度、及光合作用效率的限制，以及需要佔用大量的土地面積，而有實施上的瓶頸，亦非溫室氣體減量工程的優良方法。 In the past, although some technologies and capabilities temporarily adsorbed carbon dioxide and limited it to specific materials, such as sodium hydroxide (NaOH), the equation is: NaOH + CO 2 → NaHCO 3 , but when the material is saturated to saturation All the reactions are unsustainable. Just like the situation that the American spacecraft Apollo 13 once faced, the use of specific adsorbent materials, although limited treatment of carbon dioxide concentration is limited, but for a large number of greenhouse gases The project of carbon dioxide reduction has little application value. Recently, some people have tried to use the ability of cyanobacteria photosynthesis to deal with the high concentration of carbon dioxide emitted by the factory, but the blue-green bacteria are exposed to sunlight, temperature, And the limitation of photosynthesis efficiency, as well as the need to occupy a large amount of land area, and the implementation of bottlenecks, is not an excellent method of greenhouse gas reduction engineering.

本發明所採用的二氧化碳分解回收方法，是人類首次以工業製程的概念，達到裂解二氧化碳強固電子鍵結的效果，可以全天候進行，比植物光合作用消費二氧化碳的機制，多出一倍以上的時間效率；沒有污染，也沒有規模上的限制，更沒有地區性的差別，例如可以建造在沙漠、海上、南北極地或地底洞穴內，均無所限制，不 像植物行光合作用，必須考量太陽光照多寡、溫度高低、雲層厚薄以及有無霾害等等。 The method for decomposing and recovering carbon dioxide used in the invention is the first time that the concept of industrial process is used for human beings to achieve the effect of cracking carbon dioxide strong electronic bond, which can be carried out all the time, and more than double the time efficiency of plant carbon dioxide consumption by photosynthesis. There is no pollution, no scale restrictions, and no regional differences. For example, it can be built in deserts, seas, north and south poles or underground caves. There are no restrictions, no For photosynthesis in plants, it is necessary to consider the amount of sunlight, the temperature, the thickness of the clouds, and the presence or absence of damage.

長久以來本發明團隊就一直在尋找一種能將二氧化碳(CO2)解離成碳(C)及氧(O2)的方法，但一直苦於沒有適當的工具，而且也不免陷入專業的盲點，固執的輕信二氧化碳分子〝碳--氧〞間的電子鍵結非常強固，是牢不可破的化學結構，也因此就將這個構想束之高閣而未予聞問；及至日前，忽然頓悟植物在億萬年以前早已演化出光合作用的二氧化碳解離機制，即反應式：6CO2+6H2O→C6H12O6+6O2↑；能有效的分解二氧化碳，使二氧化碳成為植物自身有用的碳水化合物(C6H12O6)，以及對植物而言係屬無用的氧氣(O2)排出；我們這才跳出專業的迷障，體認到二氧化碳分子〝碳--氧〞間的電子化學鍵結，並非想像中的牢不可破，所謂牢不可破的現象，只是人類尚未找到有效的解離二氧化碳及固碳的方法而已，因此我們重新燃起希望，認真投入精神與努力，尋找可以將二氧化碳解離成碳(C)及氧(O2)的方法，終於得到一個重要的推論，亦即人類若要解離二氧化碳，絕對無法像植物一樣，僅利用光合作用即能使二氧化碳成功解離；但我們可以參考植物光合作用的原理，利用光觸媒uv紫外光的量子效應，使二氧化碳〝碳--氧〞鍵結間的電子，利用量子穿隧(quantum tunneling)效應，使自由電子進入外部的導電迴路，做為燃料電池的起電作用加以消耗，即可讓二氧化碳暫時解離成為(C4+nM)狀態碳及氧(O2)；續前所述，因為接受uv紫外光激發而暫時脫離二氧化碳鍵結軌道的電子，一旦外加的能量消失，立刻會回到原先的軌道(能階)繞行，致使暫時處於解離狀態的(C4+nM)狀態碳及氧(O2)非常不穩定，隨時可能重新鍵結，回復為二氧化碳(CO2)的穩固 狀態；如何維持(C4+nM)狀態碳，並及時將氧(O2)抽離，使兩者無法重新發生鍵結，就是本發明首要解決的技術重點。 The team of the invention has long been looking for a way to dissociate carbon dioxide (CO 2 ) into carbon (C) and oxygen (O 2 ), but has been suffering from the lack of proper tools, and can not fall into professional blind spots, stubborn Evidence of carbon dioxide, carbon and carbon - the electron bond between the oxygen is very strong, and it is an unbreakable chemical structure. Therefore, this concept has been shelved and not heard; and until now, suddenly the plant has evolved light hundreds of millions of years ago. Cooperative carbon dioxide dissociation mechanism, ie, reaction formula: 6CO 2 +6H 2 O→C 6 H 12 O 6 +6O 2 ↑; can effectively decompose carbon dioxide, make carbon dioxide a useful carbohydrate for plants (C 6 H 12 O 6 ), and the use of oxygen (O 2 ) for plant excretion; we have jumped out of the professional obstacles, recognizing the electron-chemical bond between carbon dioxide and carbon - oxygen, not unimaginable The so-called unbreakable phenomenon is that human beings have not yet found an effective way to dissociate carbon dioxide and carbon sequestration. Therefore, we rekindle hope and earnestly invest in our spirit and efforts. Looking for a way to dissociate carbon dioxide into carbon (C) and oxygen (O 2 ), and finally get an important inference, that is, if humans want to dissociate carbon dioxide, they can never use photosynthesis to make carbon dioxide successfully dissociated. However, we can refer to the principle of plant photosynthesis, using the quantum effect of photocatalyst uv ultraviolet light to make the electrons between carbon dioxide and carbon-oxygen bonds, using quantum tunneling effect, to make free electrons enter the outside. The conductive loop, which is consumed as a fuel cell, allows the carbon dioxide to be temporarily dissociated into (C 4+ nM) state carbon and oxygen (O 2 ); as described above, it is temporarily detached due to uv ultraviolet excitation. The electrons in the carbon dioxide-bonded orbital, once the applied energy disappears, immediately return to the original orbit (energy level), causing the carbon and oxygen (O 2 ) in the (C 4+ nM) state that is temporarily dissociated. , it is possible to re-bond at any time, returning to the stable state of carbon dioxide (CO 2 ); how to maintain the carbon in (C 4+ nM) state, and withdraw oxygen (O 2 ) in time so that the two cannot reoccur Bonding is the technical focus of the present invention.

有了以上的認知，本發明即採用分兩階段的方法，解離二氧化碳強固的〝碳--氧〞電子鍵結，使成為(C4+nM)狀態碳及氧(O2)，即：uv+CO2+△(nM)+2H2+4e-↑→C+2H2O+▽(nM)+4e-↓ With the above recognition, the present invention adopts a two-stage method to dissociate carbon dioxide-rich carbon-oxygen-electron bond, so as to become (C 4+ nM) state carbon and oxygen (O 2 ), namely: uv +CO 2 +△(nM)+2H 2 +4e - ↑→C+2H 2 O+▽(nM)+4e - ↓

uv+CO2+△(nM)→(C4+nM)+O2+4e-↑；並於二氧化碳(CO2)解離後，立刻使暫時處於游離狀態的氧(O2)與來自於氫燃料電池(H2 Fuel Cell)解離出來的質子(H+)發生鍵結，成為水(H2O)，而多出來的4個自由電子(4e-)，則由外部電路加以消費，即反應式O2+4H++4e-↓→2H2O，迫使氧無法重新與(C4+nM)狀態碳發生鍵結，因此能將碳離子(C4+)暫時固持在奈米觸鬚所糾結成的奈米孔洞內，成為(C4+nM)狀態碳，等待次一階段再將(C4+nM)狀態碳還原為碳，其反應式為：(C4+nM)+4e-↓→C+▽(nM)。 Uv+CO 2 +△(nM)→(C 4+ nM)+O 2 +4e - ↑; and immediately after the dissociation of carbon dioxide (CO 2 ), temporarily release oxygen (O 2 ) from the free state and from hydrogen The protons (H + ) dissociated from the fuel cell (H 2 Fuel Cell) are bonded to become water (H 2 O), and the extra 4 free electrons (4e - ) are consumed by external circuits, that is, the reaction The formula O 2 +4H + +4e - ↓→2H 2 O, forcing oxygen to re-bond with the (C 4+ nM) state carbon, thus temporarily holding the carbon ion (C 4+ ) in the entanglement of the nanowhiskers In the nano-holes, it becomes a (C 4+ nM) state carbon, waiting for the next stage to reduce the (C 4+ nM) state carbon to carbon, and its reaction formula is: (C 4+ nM)+4e - ↓ →C+▽(nM).

首先本發明利用uv紫外光所射出的高能粒子(光子)隨機撞擊(激發)二氧化碳(CO2)分子外圍的電子，強迫二氧化碳電子鍵結的能階由基態躍入激發態，使〝碳--氧〞原子間的鍵結力減弱，讓二氧化碳的4個自由電子(4e-)藉此開啟量子隧道而逸出，使該4個電子(4e-)脫離原本繞行的軌道而自由移動，即所謂的量子穿隧(quantum tunneling)效應；該效應可以讓失去4個自由電子(4e-)的二氧化碳鍵結束縛力暫時減弱，使二氧化碳暫時成為(C4+nM)狀態碳和游離狀態的氧，此時由外部電路強迫消費該脫離軌道的4個自由電子(4e-)的能量，即可使(C4+nM)狀態碳的能階，因為失去自由電子(4e-)而處於基態；此時游離中的氧(O2)因與4個質子(H+)進行鍵 結，並由外部電子迴路獲得4個填補電洞的自由電子(4e-)而反應生成水(2H2O)，即反應式：O2+4H++4e-↓→2H2O；至此，氧(O2)已無法重新與被侷限於奈米糾結孔洞中的碳離子(C4+)發生鍵結，此時的碳離子(C4+)因已失去4個自由電子(4e-)而與奈米觸鬚較弱的靜電力結合，而以(C4+nM)狀態碳的形式存在，並使能階回復為基態，因此我們利用氫燃料電池(H2 Fuel Cell)提供4個質子(H+)予二氧化碳電極(CO2 pole)所生成的氧(O2)，順利將二氧化碳解離成為(C4+nM)狀態碳，並使游離而出的氧(O2)與該4個質子(H+)反應成為水(2H2O)，反應程序如下列方程式所示：(H2 pole) 2H2→4H++4e-↑(CO2 pole) uv+CO2+△(nM)→(C4+nM)+O2+4e-↑(H2O pole) O2+4H++4e-↓→2H2O Firstly, the present invention utilizes high-energy particles (photons) emitted by uv ultraviolet light to randomly impinge (excite) electrons on the periphery of carbon dioxide (CO 2 ) molecules, forcing the energy level of carbon dioxide electron bonding from the ground state to the excited state, so that carbon is-- The bonding force between the oxygen atoms is weakened, and the four free electrons (4e - ) of carbon dioxide are opened by opening the quantum tunnel, so that the four electrons (4e - ) are free to move away from the originally orbiting, that is, The so-called quantum tunneling effect; this effect can temporarily weaken the carbon dioxide bond end-binding force of the four free electrons (4e - ), making the carbon dioxide temporarily become the (C 4+ nM) state carbon and the free state oxygen. At this time, the external circuit forcibly consumes the energy of the four free electrons (4e - ) of the off-track, so that the energy level of the carbon in the (C 4+ nM) state is in the ground state because the free electron (4e - ) is lost; At this time, the free oxygen (O 2 ) is bonded to the four protons (H + ), and four free electrons (4e − ) filling the holes are obtained from the external electronic circuit to generate water (2H 2 O). , that is, the reaction formula: O 2 + 4H + + 4e - ↓ → 2H 2 O; at this point, oxygen (O 2 ) has It is impossible to re-bond with the carbon ions (C 4+ ) confined to the nano-entangled holes. At this time, the carbon ions (C 4+ ) are lost to the four free electrons (4e - ) and compared with the nano tentacles. The weak electrostatic force combines and exists in the form of (C 4+ nM) state carbon, and the energy level returns to the ground state. Therefore, we use hydrogen fuel cell (H 2 Fuel Cell) to provide 4 protons (H + ) to carbon dioxide. The oxygen (O 2 ) generated by the electrode (CO 2 pole) smoothly dissociates the carbon dioxide into a (C 4+ nM) state carbon, and reacts the free oxygen (O 2 ) with the four protons (H + ). Become water (2H 2 O), the reaction procedure is as shown in the following equation: (H 2 pole) 2H 2 → 4H + + 4e - ↑ (CO 2 pole) uv + CO 2 + △ (nM) → (C 4 + nM )+O 2 +4e - 2 (H 2 O pole) O 2 +4H + +4e - ↓→2H 2 O

上述氫燃料電池與二氧化碳電極之間的持續互補反應，可在設於外部的雙電子迴路產生電壓與電流，可以輕易的回收利用或支援其他用途之消費，即係一雙迴路的燃料電池(Double-loop Fuel Cell)，當雙迴路燃料電池的輸出能力降低至額定80%時，即可推定二氧化碳極(CO2 pole)的效能因奈米孔洞即將塞滿(C4+nM)狀態碳而降低，必須進行次一階段的化學反應，即(C4+nM)狀態碳的還原程序，亦即利用靜電產生器，將4個電子(4e-)的純能量歸還予(C4+nM)狀態碳的逆反應程序，即(C4+nM)+4e-↓→C+▽(nM)。 The continuous complementary reaction between the hydrogen fuel cell and the carbon dioxide electrode can generate voltage and current in the external two-electron circuit, and can be easily recycled or used for other purposes, that is, a dual-circuit fuel cell (Double -loop Fuel Cell), when the output capacity of the dual-loop fuel cell is reduced to 80% of the rated value, it is presumed that the performance of the CO 2 pole is reduced due to the carbon to be filled (C 4+ nM) state. The next stage of the chemical reaction, that is, the reduction process of the (C 4+ nM) state carbon, that is, the electrostatic energy of the four electrons (4e - ) is returned to the (C 4+ nM) state. The reverse reaction process of carbon, namely (C 4+ nM) + 4e - ↓ → C + ▽ (nM).

誠如上述化學反應式(C4+nM)+4e-↓→C+▽(nM)的程序，吾人給予被侷限於奈米糾結中的(C4+nM)狀態碳增加4個電子(4e-)的純能量，使之脫離該奈米糾結的靜電 力束縛，於此同時，將該奈米體的溫度，由形成糾結狀態的150℃~180℃調降至90℃~30℃，俾使該奈米糾結觸鬚回復為鬆散的突觸狀態，以利已還原為顆粒狀的碳(C)脫離該奈米糾結的侷限；而該奈米體則回復到原有的功能及狀態，等待另一循環的加溫及再利用。 As in the above chemical reaction formula (C 4+ nM) + 4e - ↓ → C + ▽ (nM), we give 4 electrons (4e - in the (C 4+ nM) state carbon limited to the nano tangles. Pure energy, so as to get rid of the electrostatic force binding of the nano entanglement, at the same time, the temperature of the nano-body is reduced from 150 ° C ~ 180 ° C in the entangled state to 90 ° C ~ 30 ° C, so that The nano tangled tentacle returns to a loose synaptic state, in order to facilitate the reduction of the granular carbon (C) from the limitation of the nano-tangling; and the nano-body returns to its original function and state, waiting for another A cycle of heating and reuse.

其次，前述雙迴路燃料電池的二氧化碳極板(CO2 pole)與氫氧燃料電池的氫極板(H2 pole)之間，係各自透過一層絕緣滲透膜的隔離，與具有水(H2O)還原功能之氧極板(O2 pole)組裝在一起，而成為一雙迴路燃料電池；最後在該雙迴路燃料電池的外部建立兩組導電迴路，使該氫極板(H2 pole)與二氧化碳極板(CO2 pole)兩者，於進行催化解離2個氫氣分子(2H2)與1個二氧化碳分子(CO2)時，各自產生4個自由電子(4e-)，並在各自的導電迴路之間發生起電作用加以消費，使原本處於激發態，脫離原軌道游離而出的4個自由電子(4e-)能順利填補各自的電洞，以產生電壓與電流。 Secondly, the carbon dioxide plate (CO 2 pole) of the aforementioned dual-circuit fuel cell and the hydrogen plate of the hydrogen-oxygen fuel cell (H 2 pole) are each separated by an insulating permeable membrane and have water (H 2 O). The reduction function of the oxygen plates (O 2 poles) are assembled together to form a dual-circuit fuel cell; finally, two sets of conductive circuits are established outside the dual-circuit fuel cell to make the hydrogen plate (H 2 pole) Both carbon dioxide plates (CO 2 poles), when catalytically dissociating two hydrogen molecules (2H 2 ) and one carbon dioxide molecule (CO 2 ), each generate four free electrons (4e − ) and are electrically conductive at each The electrification between the loops is consumed, so that the four free electrons (4e - ) that are originally in the excited state and free from the original orbit can smoothly fill their respective holes to generate voltage and current.

由於氫極板(H2 pole)解離出來的質子(H+)，與來自二氧化碳極板(CO2 pole)解離出來的氧(O2)，雙雙係穿透各自的絕緣滲透膜後，彼此在氧極板(O2 pole)發生碰觸而啟動還原程序，最終以水的狀態排出，即O2+4H++4e-↓→2H2O；而失去氧的二氧化碳則因失去4個自由電子(4e-)，暫時以(C4+nM)狀態碳的型態儲存於奈米觸鬚所糾結孔洞之間；上述二氧化碳的解離效果，與植物葉片的光合作用有相似之處，也有不同之點；兩者都有依賴高能光粒子的量子作用力，將構成二氧化碳鍵結力的電子撞離原軌道，使成為自由電子，達到削弱二氧化碳電子鍵結力的效果；兩者都能將碳暫時解離出來，其中相當重要的差別，是植物不需要利用氫離子去捕捉氧，而是利用葉綠素分解水分子的光合作用 6CO2+6H2O→C6H12O6+6O2↑，使碳與水相結合而成為碳水化合物(C6H12O6)，並直接排出氧，這是植物利用脫離軌道的自由電子與酵素ATP共振，使二氧化碳與水合成為碳水化合物及氧。植物利用葉面的葉綠體，使葉綠素α、葉綠素β、類胡蘿菠素、其他小分子以及蛋白質等所組成的光合系統(photosystem)同步共振，利用分層降低能階的方式消耗自由電子的能量，讓水裂解成為氫與副產物氧，而氫則進一步解離成為質子與電子，以合成具有高能量的ATP以及還原劑NADPH，作用在二氧化碳分子，將二氧化碳分子中的碳原子還原合成為碳水化合物，就能使二氧化碳中的碳與氧分離，不需額外給予碳離子純能量，就能使碳離子與水結合成為碳水化合物，這是植物演化上高明而有效率的地方，而本發明卻必須分二階段才能完成將二氧化碳分解及回收為碳和水的工程，即方程式：uv+CO2+△(nM)+2H2+4e-↑→C+2H2O+▽(nM)+4e-↓。 Due to the dissociation of protons (H + ) from the hydrogen plate (H 2 pole) and the oxygen (O 2 ) dissociated from the carbon dioxide plate (CO 2 pole), the double pairs penetrate the respective insulating permeable membranes and The oxygen plate (O 2 pole) touches and initiates the reduction process, and finally discharges in the state of water, that is, O 2 +4H + +4e - ↓→2H 2 O; and the carbon dioxide that loses oxygen loses 4 free electrons. (4e - ), temporarily stored in the (C 4+ nM) state of carbon between the entangled pores of the nanowhiskers; the dissociation effect of the above carbon dioxide is similar to the photosynthesis of plant leaves, and there are also differences Both have quantum forces that rely on high-energy light particles, and the electrons that make up the carbon dioxide bonding force are knocked away from the original orbit, making them free electrons, which can weaken the electron-bonding force of carbon dioxide; both can temporarily dissociate carbon. Out of it, the most important difference is that plants do not need to use hydrogen ions to capture oxygen, but use chlorophyll to break down the photosynthesis of water molecules 6CO 2 +6H 2 O→C 6 H 12 O 6 +6O 2 ↑ to make carbon and combined aqueous phase becomes carbohydrate (C 6 H 12 O 6) And directly discharging oxygen, which is a plant from orbit using the enzyme ATP resonance free electrons, the carbon dioxide becomes hydrated carbohydrates and oxygen. Plants use the chloroplasts of the foliage to synchronize the photosystems of chlorophyll alpha, chlorophyll beta, carotenoids, other small molecules, and proteins, and consume the energy of free electrons by stratification and energy reduction. , the water is cleaved into hydrogen and by-product oxygen, and the hydrogen is further dissociated into protons and electrons to synthesize high-energy ATP and reducing agent NADPH, acting on carbon dioxide molecules, and reducing carbon atoms in carbon dioxide molecules into carbohydrates. The carbon in the carbon dioxide can be separated from the oxygen, and the carbon ion can be combined with water to form a carbohydrate without additional energy of the carbon ion, which is a place where the plant evolution is high and efficient, but the invention must The project of decomposing and recovering carbon dioxide into carbon and water can be completed in two stages, that is, the equation: uv+CO 2 + △(nM)+2H 2 +4e - ↑→C+2H 2 O+▽(nM)+4e - ↓ .

相對於自然界運作機制的奧妙，誠令人嘆服；本發明當然不是摹仿植物光合作用的機制來達成固碳的效果，本發明只是藉由植物光合作用的機制，來思考打破二氧化碳(CO2)電子鍵結的方法，因此本發明是一個非生物機制的二氧化碳(CO2)解離與還原方法，操作過程中沒有污染的疑慮，反而有化學電能以及奈米純碳可資回收的額外利益，是一個解決地球溫室氣體的絕佳方案。 It is awesome compared to the mystery of the operation mechanism of nature; the invention is of course not a mechanism for plant photosynthesis to achieve carbon fixation. The present invention only considers the mechanism of plant photosynthesis to break carbon dioxide (CO 2 ) electrons. The method of bonding, so the present invention is a non-biological mechanism for the separation and reduction of carbon dioxide (CO 2 ), which has no pollution concerns during operation, but has the additional benefit of chemical power and the recovery of nano pure carbon. An excellent solution to the global greenhouse gas.

續前所敘，因為二氧化碳的鍵結強固，過去縱然有方法暫時將二氧化碳的鍵結力切斷，但瞬間即又結合，這是全世界千百萬挑戰二氧化碳解離技術的專家所共同面對的難題；假設他們所採用的材料特性只有電子鍵結 代償特性一種，其實無法達成將二氧化碳解離成碳及氧的結果，因為當〝碳--氧〞的鍵結力瞬間被削弱時，若無其他力量取代〝碳--氧〞間原先的鍵結力，例如提供質子(H+)與氧發生新的鍵結，並消費多出來的自由電子，使(C4+nM)狀態碳的量子狀態暫時處於基態，則氧將立刻重新與(C4+nM)狀態碳中的碳結合成為穩定的二氧化碳。但是我們利用本發明奈米體的電子鍵結代償特性、溫變調控特性，以及可伸縮變異的機械特性來達成將二氧化碳分解回收的工作；因此本發明所建構的非生物性、工業量產式的光量子作用解離機制，勢將成為解決全球溫室氣體的具體可行方法，因為吾人可以輕易改變奈米體的溫度，將塞滿(C4+nM)狀態碳的奈米糾結觸鬚伸展開來，順利地將(C4+nM)狀態碳中的碳釋放還原為顆粒狀的碳，使該奈米體所構成的二氧化碳極板(CO2 pole)回復原狀，方便重複使用。重點是建造這種工業量產等級的二氧化碳分解回收裝置，並無體積與容量的限制，只要是一個密閉的空間就可以進行裝設，組裝後的成品可以像室內足球場般的巨大，也可以像烤麵包機一般嬌小。 As mentioned above, because of the strong bond of carbon dioxide, even though there is a way to temporarily cut off the binding force of carbon dioxide, it is combined in an instant, which is the face of millions of experts around the world who challenge carbon dioxide dissociation technology. Difficulty; assuming that the material properties they use are only one of the electronic bond compensatory properties, in fact, the result of dissociating carbon dioxide into carbon and oxygen cannot be achieved, because when the bonding force of the carbon-oxygen enthalpy is instantly weakened, if there is no other The power replaces the carbon--the original bonding force between the oxygen, such as providing a new bond between the proton (H + ) and oxygen, and consuming the excess free electrons, making the quantum state of the (C 4+ nM) state carbon Temporarily in the ground state, oxygen will immediately recombine with carbon in the (C 4+ nM) state carbon to become stable carbon dioxide. However, we use the electronic bond compensatory properties, temperature-regulating properties of the nano-body of the present invention, and the mechanical properties of the scalable mutation to achieve the work of decomposing and recovering carbon dioxide; therefore, the abiotic, industrial mass production method constructed by the present invention The photo-quantity dissociation mechanism will become a concrete and feasible method for solving global greenhouse gases, because we can easily change the temperature of the nano-body, and spread the nano-tangled tentacles filled with (C 4+ nM) state carbon. The carbon in the (C 4+ nM) state carbon is released and reduced to granular carbon, and the carbon dioxide plate (CO 2 pole) composed of the nano body is returned to the original state, which is convenient for repeated use. The focus is on the construction of this industrial mass production grade carbon dioxide decomposition and recovery unit. There is no limit on volume and capacity. As long as it is a closed space, it can be installed. The assembled product can be as large as an indoor soccer field. It is petite like a toaster.

本發明二氧化碳分解回收裝置的未來發展無可限量，目前已知的最佳應用方向即有下列數種： The future development of the carbon dioxide decomposition recovery device of the present invention is limitless, and the best known application directions are as follows:

(1).將按照本發明所組裝的巨型二氧化碳分解回收裝置，以複數個串接的方式，裝設於火力發電廠、煉鋼廠或水泥廠的排煙口，處理經過靜電除塵、水洗的高濃度二氧化碳排氣，將能有效的把二氧化碳分解回收為碳及純水，可以做為環保減碳甚或達成零碳目標的執行工具之一，本發明二氧化碳分解回收裝置在此處的應用重點，在於把二氧化碳分解回收為碳及純水，成為未來環保碳交易世代的穫利工具，讓原本屬於碳交易的買方， 搖身一變成為賣方，可以將減碳的額度，出售給技術上無法減碳的產業，例如航空、運輸、煤氣瓦斯、煉油等產業，除可獲取一筆額外的收益外，兼可為地球的未來盡一份心力；本發明當然無法一舉將大氣中的二氧化碳溫室氣體，立刻減量到公元1800年的280ppm.左右水準，但只要能有效地將二氧化碳溫室氣體控制於不再增加的水準上，目前地球上早已超量的二氧化碳溫室氣體，可留待地球上尚存的森林以及海洋珊瑚礁的自淨能力去慢慢消化，相信在兩個世紀之內，地球將逐漸找回自己的健康；重點是若無本發明二氧化碳分解回收裝置的協助，地球二氧化碳溫室氣體減量的艱鉅工程與任務，勢將耗時費日，而且將需付出數十倍或數百倍的代價。 (1) The giant carbon dioxide decomposition and recovery device assembled according to the present invention is installed in a ventilating port of a thermal power plant, a steelmaking plant or a cement plant in a plurality of serial connection manners, and is treated by electrostatic dust removal and water washing. The high concentration of carbon dioxide exhaust gas will effectively decompose and recycle carbon dioxide into carbon and pure water. It can be used as an implementation tool for environmentally friendly carbon reduction or even zero carbon target. The application of the carbon dioxide decomposition and recovery device of the present invention is emphasized here. It is to decompose and recycle carbon dioxide into carbon and pure water, which will become a profitable tool for the future generation of environmentally friendly carbon trading, so that it is originally a buyer of carbon trading. By turning into a seller, you can sell the amount of carbon reduction to industries that cannot be carbon-reduced technically, such as aviation, transportation, gas gas, oil refining, etc. In addition to obtaining an additional income, it can also be used for the future of the planet. The invention is of course unable to reduce the greenhouse gas carbon dioxide in the atmosphere to about 280 ppm in the year 1800, but as long as it can effectively control the greenhouse gas of carbon dioxide to a level that is no longer increasing, the earth is already on the earth. Excessive carbon dioxide greenhouse gases can be reserved for the remaining forests on the earth and the self-purification capacity of marine coral reefs. It is believed that within two centuries, the earth will gradually recover its own health; the key point is that without the carbon dioxide of the present invention With the assistance of the decomposition and recovery device, the arduous project and task of reducing the greenhouse gas emissions of the earth's carbon dioxide will take time and will cost tens or hundreds of times.

(2).將按照本發明所生產的小型二氧化碳分解回收裝置按裝在載人的太空船上，利用太陽高能光子的光電發電能力來電解分離水，製造氫氣(H2)和氧氣(O2)，作為本發明另一項應用特點(CO2)燃料電池的燃料來源；讓本發明在太空船的艙內不斷的過濾循環，一方面產生水，以備再次利用太陽光電效應來電解水，製造氫氣和氧氣備用；氧氣可供太空人呼吸之用，氫氣則可供本發明二氧化碳分解裝置(CO2燃料電池)氫極燃料之需，太空艙內二氧化碳濃度則因二氧化碳分解回收裝置之持續運作而可避免過高；本發明二氧化碳分解回收裝置在此處的應用，主要係在於發電供太空艙使用，以及控制艙內二氧化碳的濃度，兩者同等重要；雖然平常太空船艙內的二氧化碳濃度可能不是很高，但本裝置因係屬經常性之循環操作，依然可以有效的將太空船艙內的二氧化碳濃度控制在正常標準值之下，自然可以避免人類當年登月探險過程中所面對的意外及風險，亦即阿波羅 13號太空艙二氧化碳吸收裝置飽和，導致太空人經歷二氧化碳濃度逼近極限值的危機事件重演，兼有燃料電池發電的附帶利益。 (2) The small carbon dioxide decomposition and recovery device produced according to the present invention is installed on a manned spacecraft, and uses the photovoltaic power generation capability of the solar high-energy photon to electroly separate water to produce hydrogen (H 2 ) and oxygen (O 2 ). As a fuel source of another application characteristic (CO 2 ) fuel cell of the present invention; let the present invention continuously filter the circulation in the spacecraft cabin, and generate water on the one hand, in order to re-use the solar photovoltaic effect to electrolyze water, manufacturing Hydrogen and oxygen are reserved; oxygen can be used by astronauts for breathing, and hydrogen can be used for the hydrogenation fuel of the carbon dioxide decomposition unit (CO 2 fuel cell) of the present invention, and the carbon dioxide concentration in the capsule is continuously operated by the carbon dioxide decomposition recovery unit. Avoid excessively high; the application of the carbon dioxide decomposition recovery device of the present invention here mainly depends on the use of power generation for the capsule and the concentration of carbon dioxide in the control cabin, both of which are equally important; although the carbon dioxide concentration in the usual space cabin may not be very high. High, but this device can effectively convert carbon dioxide in the space cabin due to the regular cyclic operation. The degree of control is below the normal standard value, naturally avoiding the accidents and risks faced by humans during the moon landing expedition, that is, the saturation of the Apollo 13 capsule carbon dioxide absorption device, causing the astronauts to experience the carbon dioxide concentration approaching the limit value. The recurrence of the crisis has both the fringe benefits of fuel cell power generation.

(3).將按照本發明所生產的中型二氧化碳分解回收裝置按裝在軍用或民用的潛水艇之內，足可確保潛水艇內操作人員日常生活呼吸不必擔憂二氧化碳濃度過高的問題，設若潛水艇發生意外，裝有中型二氧化碳分解回收裝置的潛水艇，將有更長的等待救援時間，在那種狀況之下，本發明將是提供潛水艇成員活命希望的珍貴設備；本二氧化碳分解回收裝置在此處的應用，主要係在於控制二氧化碳的濃度。 (3) The medium-sized carbon dioxide decomposition and recovery device produced according to the present invention is installed in a military or civilian submarine to ensure that the daily life of the submarine operator does not have to worry about excessive carbon dioxide concentration. In the event of a boat accident, a submarine equipped with a medium-sized carbon dioxide decomposition recovery unit will have a longer waiting time for rescue. Under such circumstances, the present invention will be a precious device for providing submarine members with a life expectancy; the present carbon dioxide decomposition recovery device The application here is mainly to control the concentration of carbon dioxide.

(4).前述二氧化碳分解回收裝置所回收的碳(C)，係屬奈米級的純碳，既無雜質又粒徑均質化，其應用範圍廣泛；可用於製造人造鑽石之原料，大幅提升人造鑽石結晶的成功率，降低製造成本，提高品質。而回收的奈米碳又可用於製造高品級的碳纖維，作為打造飛機結構等的高級材料；更可製成奈米碳管或奈米碳網，應用在燃料電池極板上。本裝置所回收的奈米碳可有效排除碳晶圓製程所面對的良率問題，加速下一世代碳晶圓產品的面世進程，用以取代目前已接近摩爾定律極限的矽晶圓世代，讓未來採用碳製程的資訊產品更輕巧、省電、快速且功能大幅提升。 (4) The carbon (C) recovered by the carbon dioxide decomposition and recovery device is a pure carbon of nanometer grade, which has no impurities and homogenization of particle size, and has a wide range of applications; it can be used for manufacturing raw materials of artificial diamonds, and is greatly improved. The success rate of synthetic diamond crystals reduces manufacturing costs and improves quality. The recovered nanocarbon can be used to manufacture high-grade carbon fiber as a high-grade material for aircraft structure, and can be made into a carbon nanotube or nano carbon mesh for use on a fuel cell plate. The nanocarbon recovered by this device can effectively eliminate the yield problem faced by the carbon wafer process and accelerate the process of the next generation of carbon wafer products to replace the current generation of wafers that are close to the limits of Moore's Law. The information products that will adopt the carbon process in the future will be lighter, more energy-efficient, faster and more powerful.

本發明二氧化碳分解回收裝置(CO2燃料電池)係使用一組傳統的氫燃料電池(H2 Fuel Cell)作為正極的架構，催化2個氫氣分子(2H2)產生4個當量的質子(4H+)與4個當量的電子(4e-)；而在燃料電池負極原本提供氧氣的介面之外側，增設一個二氧化碳催化電極(CO2 pole)，做為氧氣分子(O2)的產生器；而切斷二氧化碳分子〝碳--氧〞間鍵結力的量子作用力，係採用uv紫外燈的高能光子，作為解離催化的驅動力量，使二氧化碳(CO2)解離為(C4+nM)狀態碳及氧氣分子(O2)，並產生4個當量的電子(4e-)；而該由二氧化碳(CO2)解離出來的氧氣分子(O2)則配合氫極板(H2 pole)解離出來的4個當量的質子(4H+)及4個當量的電子(4e-)，還原為2個水分子(2H2O)；請參閱第一圖所示，將這些元件組合在一個密閉的反應空間，即成為一個雙迴路燃料電池(1)，然後在該雙迴路燃料電池(1)的外側，裝設一氫氣儲存槽(2)、一二氧化碳儲存槽(3)、一電源供應器(4)、一電子負載器(5)及一靜電產生器(6)，即構成本企劃案的二氧化碳分解回收裝置(CO2燃料電池)，可有效分解二氧化碳，減少地球的溫室氣體，兼可回收奈米等級的純碳以及產生直流電能量；再請參考第一圖，首先在雙迴路燃料電池(1)內部，靠近氫氣儲存槽(2)之一側，裝置一片以碳纖維為導電材質所編織而成的碳布，在碳布上壓接有氫極輸出電路(52)，透過二極體(54)與電子負載器(5)相接，做為燃料電池氫觸媒催化極(22)之輸出相；而構成氫觸媒催化極的碳布表面，則塗佈尺度為奈米規格之碳管，該奈米碳管上濺鍍有白金鉑(Pt)或鈀(Pd)的分子顆粒，做為氫燃料接觸、質子產生、電子傳導的三接點膜，亦即氫觸媒催化極(22)；其次在雙迴路燃料電池(1)的內部，靠近二氧化碳儲存槽(3)之一側，裝置一片以銀絲線作為導電材質所編織而成的銀網，在銀網上壓接有二氧化碳極輸出電路 (51)，透過二極體(54)與電子負載器(5)相接，做為燃料電池二氧化碳奈米(nM)反應極(32)之輸出相；而構成二氧化碳奈米(nM)反應極(32)的銀網表面上，則塗佈上奈米體(nM)，做為二氧化碳接觸、光觸媒催化、碳--氧解離、電子傳導的四接點膜，並作為(C4+nM)狀態碳的暫時鍵結處所，亦即是本發明的二氧化碳奈米(nM)反應極(32)；本發明二氧化碳奈米(nM)反應極(32)，在uv紫外燈(43)照射所及之範圍，係採多皺褶方式處理，以盡量增加二氧化碳(CO2)接觸及催化面積；將按裝於氫氣儲存槽(2)頂端之氫氣連接管(21)上的氫氣控制閥(25)開啟，使氫氣流入並接觸氫觸媒催化極(22)，使氫氣在氫觸媒催化極(22)的三接點上，被解離成為質子(H+)與電子(e-)；該電子(e-)則經由氫極輸出電路(52)及二極體(54)之傳導，與電子負載器(5)相接而被消費利用；而該氫氣於三接點膜解離時所產生的質子(H+)，則被導入氫氧反應極(24)，使之與來自二氧化碳奈米(nM)反應極(32)所解離之(O2)接觸，發生還原反應而生成水(H2O)，由設於底部之排水管(7)經排水閥(71)排出；此時該二氧化碳奈米(nM)反應極(32)所產生之電子(e-)，係經由二氧化碳極輸出電路(51)及二極體(54)之傳導，與電子負載器(5)相接而被消費利用；利用電子負載器(5)消費由二氧化碳奈米(nM)反應極(32)所產生的電子(e-)，其主要的目的，係能因而讓二氧化碳的碳--氧鍵結，因暫時失去電子(e-)而被打斷，否則二氧化碳即不可能被分解為(C4+nM)狀態碳和自由游離的氧；以上所敘述的質子(H+)，則透過氫極絕緣滲透膜(23)之絕緣，與透過氧極絕緣滲透膜(33)絕緣之氧分子，在 氫氧反應極(24)接觸，而反應還原成水，並由設於底部之排水管(7)經排水閥(71)排出；該氫極絕緣滲透膜(23)與氧極絕緣滲透膜(33)之功能，係讓質子(H+)及氧分子(O2)自由滲透，但必須使自由電子之電性處於絕緣狀態之下，方能構成電子--電洞對，使雙迴路燃料電池(1)發生起電反應，尤其重要的是在於消費二氧化碳奈米(nM)反應極(32)所產生之電子(e-)，使二氧化碳強固之鍵結暫時崩解，方能達到本發明二氧化碳分解回收之主要目的。 The carbon dioxide decomposition recovery device (CO 2 fuel cell) of the present invention uses a conventional hydrogen fuel cell (H 2 Fuel Cell) as a positive electrode structure to catalyze two hydrogen molecules (2H 2 ) to generate four equivalent protons (4H + And 4 equivalents of electrons (4e - ); and on the outside of the interface where the fuel cell anode originally provides oxygen, a carbon dioxide catalytic electrode (CO 2 pole) is added as a generator of oxygen molecules (O 2 ); The quantum force of the carbon dioxide-based carbon-oxygen bond interaction force is the high-energy photon of the uv ultraviolet lamp, which acts as the driving force for the dissociation catalysis to dissociate the carbon dioxide (CO 2 ) into the (C 4+ nM) state carbon. And an oxygen molecule (O 2 ), and produces 4 equivalents of electrons (4e - ); and the oxygen molecule (O 2 ) dissociated by carbon dioxide (CO 2 ) is dissociated from the hydrogen plate (H 2 pole) 4 equivalents of protons (4H + ) and 4 equivalents of electrons (4e - ), reduced to 2 water molecules (2H 2 O); see the first figure, combining these elements in a closed reaction space That becomes a dual-circuit fuel cell (1) and then outside the dual-circuit fuel cell (1) , a hydrogen storage tank (2), a carbon dioxide storage tank (3), a power supply (4), an electronic loader (5) and an electrostatic generator (6), which constitute the carbon dioxide of the plan Decomposition and recovery device (CO 2 fuel cell) can effectively decompose carbon dioxide, reduce the earth's greenhouse gases, and recover nano-grade pure carbon and generate DC energy; then please refer to the first figure, first in the dual-loop fuel cell (1 Inside, near one side of the hydrogen storage tank (2), a carbon cloth woven from carbon fiber is used as a conductive material, and a hydrogen electrode output circuit (52) is crimped on the carbon cloth to pass through the diode (54). ) is connected to the electronic loader (5) as the output phase of the hydrogen catalyst catalytic electrode (22) of the fuel cell; and the surface of the carbon cloth constituting the catalytic end of the hydrogen catalyst is coated with a carbon tube of a nanometer size The carbon nanotubes are sputtered with platinum platinum (Pt) or palladium (Pd) molecular particles as a three-contact film for hydrogen fuel contact, proton generation, and electron conduction, that is, a hydrogen catalyst catalytic electrode (22). ); secondly, inside the dual-circuit fuel cell (1), close to one side of the carbon dioxide storage tank (3), A silver mesh woven from a silver wire as a conductive material, a carbon dioxide pole output circuit (51) is crimped on the silver mesh, and is connected to the electronic loader (5) through the diode (54) as a fuel. The output phase of the battery carbon dioxide nano (nM) reaction electrode (32); and the surface of the silver mesh constituting the carbon dioxide nano (nM) reaction electrode (32), coated with nano-body (nM) as carbon dioxide contact Photocatalyst catalyzed, carbon-oxygen dissociation, electron-conducting four-contact film, and as a temporary bonding site for carbon in the (C 4+ nM) state, that is, the carbon dioxide nano (nM) reactor of the present invention (32) The carbon dioxide nano (nM) reaction electrode (32) of the present invention is treated in a multi-pleated manner in the range of irradiation of the uv ultraviolet lamp (43) to maximize carbon dioxide (CO 2 ) contact and catalytic area; The hydrogen control valve (25) installed on the hydrogen connecting pipe (21) at the top of the hydrogen storage tank (2) is opened, so that hydrogen flows into and contacts the hydrogen catalyst catalytic electrode (22) to make hydrogen in the hydrogen catalyst catalytic electrode. (22) three contacts is dissociated into protons (H +) and electron (e -); the electron (e -) the hydrogen electrode through an output circuit (52) and two Conductor (54), the load of the electronic device (5) is in contact with the consumer use; in which hydrogen protons (H +) dissociative triple points membrane produced, were introduced into the hydrogen electrode reaction (24) In contact with (O 2 ) dissociated from the carbon dioxide nano (nM) reaction electrode (32), a reduction reaction occurs to generate water (H 2 O), and the drain pipe (7) provided at the bottom passes through the drain valve. (71) Discharge; at this time, the electron (e - ) generated by the carbon dioxide nano (nM) reaction electrode (32) is conducted through the carbon dioxide electrode output circuit (51) and the diode (54), and the electronic load (5) is in contact with the consumer use; electronics using an electronic load (5) consumption pole (32) is produced by carbon dioxide nm (nM) in the reaction (e -), the main object, therefore, it can be carbon-based The carbon-oxygen bond is interrupted by the temporary loss of electrons (e - ), otherwise carbon dioxide cannot be decomposed into (C 4+ nM) state carbon and free free oxygen; the protons described above (H +), the gate insulating film hydrogen permeation through (23) of insulation, with a gate insulating film permeation (33) through the insulating oxygen molecules of oxygen, the reaction in hydrogen electrode (24) contacting, reduced to water while the reaction Provided by the drain pipe (7) pass through a discharge valve (71) of the bottom; the hydrogen permeable electrode insulating film (23) with the oxygen permeable gate insulating film (33) function, so that based proton (H +) and oxygen molecules (O 2 ) is free to infiltrate, but the electrical properties of the free electrons must be insulated to form an electron-hole pair, which causes the dual-circuit fuel cell (1) to react electrically, especially when it is consumed. The electron (e - ) generated by the carbon dioxide nano (nM) reaction electrode (32) temporarily disintegrates the carbon dioxide strong bond to achieve the main purpose of the carbon dioxide decomposition and recovery of the present invention.

本發明分解二氧化碳之操作方法；首先使電源供應器(4)迴路上的電源開關(41)成為導通之閉路狀態，使裝置於二氧化碳奈米(nM)反應極(32)上的電熱加溫器(42)開始加溫，於此同時，設於雙迴路燃料電池(1)內部的uv紫外燈(43)亦同時點亮，當二氧化碳奈米(nM)反應極(32)的溫度上升至150℃~180℃時，開啟氫氣控制閥(25)及二氧化碳控制閥(34)，使氫氣儲存槽(2)內的氫透過氫氣連接管(21)注入氫觸媒催化極(22)之一側；同時讓二氧化碳儲存槽(3)內的二氧化碳注入靠近二氧化碳奈米(nM)反應極(32)之一側； 此時uv紫外燈(43)所發出的高能光子，將隨機撞擊附著於二氧化碳奈米(nM)反應極(32)上的二氧化碳，使二氧化碳分子鍵結間的電子因吸收光能量而處於激發狀態，讓鍵結間之電子，因能階躍遷而產生量子穿隧效應，遂使二氧化碳分子的碳--氧鍵結暫時鬆動，此時游離而出的氧，即可輕易的與來自於氫觸媒催化極(22)的質子(H+)產生反應而生成水，而使二氧化碳分子中的碳暫時與奈米體(nM)發生鍵結，成為(C4+nM)狀態碳。 The method for decomposing carbon dioxide according to the present invention; firstly, the power switch (41) on the circuit of the power supply (4) is turned into a closed state, and the electric heater is installed on the carbon dioxide nanometer (nM) reactor (32). (42) At the same time, the uv UV lamp (43) inside the dual-circuit fuel cell (1) is also lit at the same time, when the temperature of the carbon dioxide nano (nM) reaction electrode (32) rises to 150. At °C~180°C, the hydrogen control valve (25) and the carbon dioxide control valve (34) are turned on, so that the hydrogen in the hydrogen storage tank (2) is injected into the side of the hydrogen catalyst catalytic electrode (22) through the hydrogen connecting tube (21). At the same time, the carbon dioxide in the carbon dioxide storage tank (3) is injected near one side of the carbon dioxide nanometer (nM) reaction electrode (32); at this time, the high-energy photon emitted by the uv ultraviolet lamp (43) will randomly adhere to the carbon dioxide. The carbon dioxide on the (nM) reaction pole (32) causes the electrons between the carbon dioxide molecules to be excited by the absorption of light energy, allowing the electrons between the bonds to undergo quantum tunneling due to energy level transitions. The carbon-oxygen bond of the carbon dioxide molecule is temporarily loosened, and the oxygen released at this time Can easily and protons (H +) from the hydrogen catalytic electrode catalyst (22) to react to produce water, carbon dioxide molecules in the carbon body is temporarily bonded to the nanometer (nM), which serve as (C 4 + nM) State carbon.

當雙迴路燃料電池的輸出能力降低至額定80%時， 即可推定二氧化碳催化極(CO2 pole)的效能因奈米孔洞即將塞滿(C4+nM)狀態碳而降低，必須進行次一階段的化學反應程序，即(C4+nM)狀態碳的還原程序，亦即利用靜電產生器(6)將4個自由電子(4e-)的純能量，歸還予(C4+nM)狀態碳的逆反應程序，即本發明(C4+nM)+4e-↓→C+▽(nM)之還原反應程序。 When the output capacity of the dual-circuit fuel cell is reduced to 80% of the rated value, it can be presumed that the performance of the CO 2 pole is lowered due to the carbon to be filled (C 4+ nM) state, and the second must be performed. The chemical reaction procedure of the stage, that is, the reduction procedure of the (C 4+ nM) state carbon, that is, the pure energy of the four free electrons (4e - ) is returned to the (C 4+ nM) state by the electrostatic generator (6). The reverse reaction procedure of carbon, that is, the reduction reaction procedure of the present invention (C 4+ nM) + 4e - ↓ → C + ▽ (nM).

本發明還原(C4+nM)狀態碳為碳之操作方法；首先關閉氫氣控制閥(25)及二氧化碳控制閥(34)以及設於底部之排水閥(71)，使雙迴路燃料電池(1)內部回復初始狀態；其次切斷電源供應器(4)迴路上的電源開關(41)，使迴路成為不導通之開路狀態，讓二氧化碳奈米(nM)反應極(32)之溫度下降至90℃~30℃，而uv紫外燈(43)亦因電路不導通而熄滅； 最後請參考第二圖所示，使靜電產生器(6)啟動，讓靜電產生器(6)利用摩擦生電之原理，製造正負極性相反之靜電能量，其中帶有反電子之能量，可經由靜電放電迴路(61)之導通，將4個反電子導引至靜電放電梳(63)之尖端，利用尖端放電之原理釋放至大氣中；而該靜電產生器(6)所相對生成的4個電子(4e-)，則經由靜電充電迴路(62)之傳導，將能量回充至二氧化碳奈米(nM)反應極(32)之極板上，使暫時鍵結於二氧化碳奈米(nM)反應極(32)上的(C4+nM)狀態碳，因獲得額外的4個電子(4e-)能量而還原為碳原子，此時的二氧化碳奈米(nM)反應極(32)，因為溫度已下降至90℃~30℃而回復為鬆散的突觸狀態，即可利用高頻震盪的機械力，順利的將奈米碳顆粒釋出；然後二氧化碳奈米(nM)反應極(32)經重新加溫，即可進行另一個循環的再利用。 The invention reduces the (C 4+ nM) state carbon as a carbon operation method; firstly, the hydrogen control valve (25) and the carbon dioxide control valve (34) and the drain valve (71) provided at the bottom are closed to make the dual-circuit fuel cell (1) The internal return to the initial state; secondly, the power switch (41) on the circuit of the power supply (4) is cut off, so that the circuit becomes a non-conducting open state, and the temperature of the carbon dioxide nanometer (nM) reactor (32) is lowered to 90. °C~30°C, and the UV UV lamp (43) is also extinguished due to the non-conduction of the circuit; finally, please refer to the second figure to start the electrostatic generator (6) and let the static electricity generator (6) use the friction generating electricity. The principle is to manufacture electrostatic energy with opposite positive and negative polarities, with anti-electron energy, which can be turned on by the electrostatic discharge circuit (61) to guide the four counter-electrodes to the tip of the electrostatic discharge comb (63), using the tip discharge The principle is released into the atmosphere; and the four electrons (4e - ) generated by the static electricity generator (6) are recharged to the carbon dioxide nanometer (nM) reactor by conduction through the electrostatic charging circuit (62). (32) on the plate, temporarily bonded to the carbon dioxide nano (nM) reactor (32) (C 4+ nM) state carbon, which is reduced to carbon atoms by obtaining an additional 4 electrons (4e - ) energy, at this time the carbon dioxide nano (nM) reaction pole (32), because the temperature has dropped to 90 ° C ~ At 30 ° C and return to a loose synaptic state, the high-frequency shock mechanical force can be used to smoothly release the nano carbon particles; then the carbon dioxide nano (nM) reaction pole (32) can be reheated. Carry out another cycle of reuse.

1‧‧‧雙迴路燃料電池 1‧‧‧Double-loop fuel cell

2‧‧‧氫氣儲存槽 2‧‧‧ Hydrogen storage tank

21‧‧‧氫氣連接管 21‧‧‧ Hydrogen connection tube

22‧‧‧氫觸媒催化極 22‧‧‧ Hydrogen catalytic catalyst

23‧‧‧氫極絕緣滲透膜 23‧‧‧Hydrogen permeable membrane

24‧‧‧氫氧反應極 24‧‧‧Hydrogen Oxygen Reaction

25‧‧‧氫氣控制閥 25‧‧‧ Hydrogen control valve

3‧‧‧二氧化碳儲存槽 3‧‧‧CO2 storage tank

31‧‧‧二氧化碳連接管 31‧‧‧CO2 connecting tube

32‧‧‧二氧化碳奈米(nM)反應極 32‧‧‧Carbon Nanotube (nM) Reactance

33‧‧‧氧極絕緣滲透膜 33‧‧‧Oxygen insulated insulating membrane

34‧‧‧二氧化碳控制閥 34‧‧‧CO2 control valve

4‧‧‧電源供應器 4‧‧‧Power supply

41‧‧‧電源開關 41‧‧‧Power switch

42‧‧‧電熱加溫器 42‧‧‧Electrical heater

43‧‧‧uv紫外燈 43‧‧‧uv UV lamp

5‧‧‧電子負載器 5‧‧‧Electronic loader

51‧‧‧二氧化碳極輸出電路 51‧‧‧CO2 pole output circuit

52‧‧‧氫極輸出電路 52‧‧‧ Hydrogen electrode output circuit

53‧‧‧共同迴路 53‧‧‧Common circuit

54‧‧‧二極體 54‧‧‧ diode

6‧‧‧靜電產生器 6‧‧‧Electrostatic generator

61‧‧‧靜電放電迴路 61‧‧‧Electrostatic discharge circuit

62‧‧‧靜電充電迴路 62‧‧‧Electrostatic charging circuit

63‧‧‧放電梳 63‧‧‧Discharge comb

7‧‧‧排水管 7‧‧‧Drainage pipe

71‧‧‧排水閥 71‧‧‧Drain valve

第一圖：(CO2)二氧化碳分解裝置及實施示意圖。 First figure: (CO 2 ) carbon dioxide decomposition apparatus and implementation diagram.

第二圖：(C4+nM)狀態碳還原裝置及實施示意圖。 Second: (C 4+ nM) state carbon reduction device and implementation diagram.

Claims (8)

一種二氧化碳分解及(C4+nM)狀態碳回收裝置，其包括：一雙迴路燃料電池，該內部包含：一氫觸媒催化極、一氫極絕緣滲透膜、一氫氧反應極、一氧極絕緣滲透膜、一二氧化碳奈米(nM)反應極、一電熱加溫器及一uv紫外燈；一氫氣儲存槽，設於該雙迴路燃料電池之外側，其兩者之間用氫氣連接管及氫氣控制閥做一連接；一二氧化碳儲存槽，設於該雙迴路燃料電池之外側，其兩者之間用二氧化碳連接管及二氧化碳控制閥做一連接；一電源供應器，設於該雙迴路燃料電池之外側，與該電熱加溫器及uv紫外燈透過電源開關做一連接；一電子負載器，設於雙迴路燃料電池之外側，一端藉由該二氧化碳極輸出電路及二極體與雙迴路燃料電池之二氧化碳奈米(nM)反應極做一連接，另一端藉由該氫極輸出電路及二極體與雙迴路燃料電池之氫觸媒催化極做一連接，且設有一共同迴路連接至雙迴路燃料電池之氫氧反應極做一連接；一靜電產生器，設於該雙迴路燃料電池之外側，一端連接靜電放電迴路，並再連接至放電梳，另一端為靜電充電迴路，並與雙迴路燃料電池之二氧化碳奈米(nM)反應極相連接； 一排水管，設於雙迴路燃料電池氫氧反應極之下方，該排水管上設有一排水閥。 A carbon dioxide decomposition and (C 4+ nM) state carbon recovery device comprises: a dual-circuit fuel cell, the interior comprising: a hydrogen catalyst catalytic electrode, a hydrogen-polar insulating permeable membrane, a hydrogen-oxygen reaction pole, and an oxygen a pole insulating permeable membrane, a carbon dioxide nanometer (nM) reaction pole, an electric heating warmer and a uv ultraviolet lamp; a hydrogen storage tank disposed on the outer side of the dual circuit fuel cell, wherein the hydrogen pipe is connected between the two And a hydrogen control valve is connected; a carbon dioxide storage tank is disposed on the outer side of the dual-circuit fuel cell, and a carbon dioxide connecting tube and a carbon dioxide control valve are connected between the two; a power supply is disposed in the double circuit On the outer side of the fuel cell, the electric heating heater and the uv ultraviolet lamp are connected through the power switch; an electronic load device is disposed on the outer side of the dual-circuit fuel cell, and one end is connected to the carbon dioxide electrode output circuit and the diode and the double The carbon dioxide nanometer (nM) reaction pole of the loop fuel cell is connected, and the other end is connected by the hydrogen electrode output circuit and the hydrogen catalyst catalytic pole of the dual-circuit fuel cell. A common circuit is connected to the hydrogen-oxygen reaction pole of the dual-circuit fuel cell to make a connection; an electrostatic generator is disposed on the outer side of the dual-circuit fuel cell, one end is connected to the electrostatic discharge circuit, and then connected to the discharge comb, and the other end is electrostatic The charging circuit is connected to the carbon dioxide nano (nM) reaction pole of the dual-circuit fuel cell; a drain pipe is disposed below the hydrogen-oxygen reaction pole of the dual-circuit fuel cell, and the drain pipe is provided with a drain valve. 如申請專利範圍第1項所述之「二氧化碳分解及(C4+nM)狀態碳回收裝置」，其中，該氫觸媒催化極的碳布表面，塗佈奈米規格之碳管，該奈米碳管上濺鍍有白金鉑(Pt)或鈀(Pd)的分子顆粒。 The carbon dioxide decomposition and (C 4+ nM) state carbon recovery device according to the first aspect of the invention, wherein the carbon catalyst surface of the hydrogen catalyst catalyst is coated with a carbon tube of a nano specification, the nai The carbon nanotubes are sputtered with molecular particles of platinum (Pt) or palladium (Pd). 如申請專利範圍第1項所述之「二氧化碳分解及(C4+nM)狀態碳回收裝置」，其中，二氧化碳奈米(nM)反應極的銀網表面上，塗佈上奈米體(nM)。 The "carbon dioxide decomposition and (C 4+ nM) state carbon recovery device" described in the first paragraph of the patent application, wherein the surface of the silver mesh of the carbon dioxide nanometer (nM) reaction electrode is coated with a nano-body (nM) ). 如申請專利範圍第1項所述之「二氧化碳分解及(C4+nM)狀態碳回收裝置」，其中，該電子負載器之二氧化碳極輸出電路及二極體係接於雙迴路燃料電池之二氧化碳奈米(nM)反應極。 The carbon dioxide decomposition and (C 4+ nM) state carbon recovery device according to the first aspect of the patent application, wherein the carbon dioxide output circuit of the electronic loader and the two-pole system are connected to the carbon dioxide of the dual-circuit fuel cell. Rice (nM) reaction pole. 如申請專利範圍第1項所述之「二氧化碳分解及(C4+nM)狀態碳回收裝置」，其中，該電子負載器之氫極輸出電路及二極體係接於雙迴路燃料電池之氫觸媒催化極。 The "carbon dioxide decomposition and (C 4+ nM) state carbon recovery device" as described in the first aspect of the patent application, wherein the hydrogen electrode output circuit of the electronic loader and the hydrogen barrier of the two-pole system are connected to the dual-circuit fuel cell Catalytic electrode. 如申請專利範圍第1項所述之「二氧化碳分解及(C4+nM)狀態碳回收裝置」，其中，該電子負載器之共同迴路係接於雙迴路燃料電池內之氫氧反應極。 The "carbon dioxide decomposition and (C 4+ nM) state carbon recovery device" according to claim 1, wherein the common circuit of the electronic loader is coupled to a hydrogen-oxygen reaction electrode in the dual-circuit fuel cell. 一種二氧化碳分解及(C4+nM)狀態碳回收方法，首先將二氧化碳分解裝置之電源供應器迴路上的電源開關設成導通之閉路狀態，使裝置於二氧化碳奈米(nM)反應極上的電熱加溫器開始加溫，於此同時，設於雙迴路燃料電池內部的uv紫外燈亦開始點亮，當二氧化碳奈米(nM)反應極的溫度上升至150℃~180℃時，開啟氫氣控制閥及二氧化碳控制閥，使氫氣儲存 槽內的氫透過氫氣連接管注入氫觸媒催化極之一側，同時讓二氧化碳儲存槽內的二氧化碳注入靠近二氧化碳奈米(nM)反應極之一側；此時uv紫外燈所發出的高能光子，將隨機撞擊附著於二氧化碳奈米(nM)反應極上二氧化碳分子外圍的電子，強迫二氧化碳電子鍵結的能階由基態躍入激發態，使〝碳--氧〞原子間的鍵結力減弱，讓二氧化碳的4個自由電子(4e-)藉此開啟量子隧道而逸出，讓失去4個自由電子(4e-)的二氧化碳鍵結束縛力暫時減弱成為(C4+nM)狀態碳和游離狀態的氧(O2)；此時藉由外部電路強迫消費該脫離軌道的4個自由電子(4e-)的能量，即可使(C4+nM)狀態碳的能階，因為失去自由電子(4e-)而處於基態；此時游離中的氧(O2)因與4個質子(H+)進行鍵結，並由外部電子迴路獲得4個填補電洞的自由電子(4e-)而反應生成水(2H2O)；本裝置利用氫燃料電池提供4個質子(H+)予二氧化碳電極所生成的氧(O2)，並使該氧(O2)與4個質子(H+)反應成為水(2H2O)，完整反應方程式：(H2 pole) 2H2→4H++4e-↑(CO2 pole) uv+CO2+△(nM)→(C4+nM)+O2+4e-↑(H2O pole) O2+4H++4e-↓→2H2O A method for carbon dioxide decomposition and (C 4+ nM) state carbon recovery, firstly setting a power switch on a power supply circuit of a carbon dioxide decomposition device to a closed state of conduction, and heating the device on a carbon dioxide nanometer (nM) reaction electrode The heater starts to warm up. At the same time, the UV UV lamp inside the dual-circuit fuel cell also starts to light up. When the temperature of the carbon dioxide nanometer (nM) reaction temperature rises to 150 ° C ~ 180 ° C, the hydrogen control valve is opened. And a carbon dioxide control valve, so that hydrogen in the hydrogen storage tank is injected into one side of the catalytic end of the hydrogen catalyst through the hydrogen connecting tube, and the carbon dioxide in the carbon dioxide storage tank is injected into one side of the reaction pole of the carbon dioxide nanometer (nM); The high-energy photons emitted by the UV lamp will randomly impact the electrons attached to the periphery of the carbon dioxide molecules on the carbon dioxide nano (nM) reaction pole, forcing the energy level of the carbon dioxide electron bond from the ground state to the excited state, so that the carbon-oxygen bonding force between atoms weakened, so that four free electrons of carbon dioxide (4e -) whereby the quantum tunneling escape opening, so that the loss of four free electrons (4e -) dioxide Carbon bonded temporarily weaken the binding force becomes (C 4+ nM) state carbon and oxygen free state (O 2); case by forced consumption of the external circuit from orbit four free electrons (4e -) energy, i.e. The energy level of the carbon in the (C 4+ nM) state can be in the ground state because the free electron (4e - ) is lost; at this time, the free oxygen (O 2 ) is bonded to the four protons (H + ), and Four free electrons (4e - ) filling the holes are obtained from the external electronic circuit to generate water (2H 2 O); the device uses hydrogen fuel cells to provide four protons (H + ) to the oxygen generated by the carbon dioxide electrode (O 2 ), and react the oxygen (O 2 ) with 4 protons (H + ) into water (2H 2 O), the complete reaction equation: (H 2 pole) 2H 2 → 4H + + 4e - ↑ (CO 2 pole Uv+CO 2 +△(nM)→(C 4+ nM)+O 2 +4e - ↑(H 2 O pole) O 2 +4H + +4e - ↓→2H 2 O 一種二氧化碳分解及(C4+nM)狀態碳回收方法，當雙迴路燃料電池的輸出能力降低至額定的80%時，即可推定二氧化碳極(CO2 pole)的效能因奈米孔洞即將塞滿(C4+nM)狀態碳而降低，必須進行次一階段的化學反應，即(C4+nM)狀態碳的還原程序，亦即利用靜電產生器，將4個電子(4e-)的純能量，歸還予(C4+nM)狀態碳的逆反應程序，即反應程式： (C4+nM)+4e-↓→C+▽(nM)；續前，由二氧化碳分解所產生的(C4+nM)狀態碳還原為碳之操作方法，首先關閉氫氣控制閥及二氧化碳控制閥以及設於底部之排水閥，使雙迴路燃料電池內部回復初始狀態；其次將電源供應器迴路上的電源開關設成不導通之開路狀態，使二氧化碳奈米(nM)反應極溫度降至90℃~30℃間，而uv紫外燈亦因電源不導通而熄滅；使靜電產生器啟動，讓靜電產生器利用摩擦生電之原理，製造正負極性相反之靜電能量，其中帶有反電子之能量，可經由靜電放電迴路之導通，將4個反電子導引至靜電放電梳之尖端，利用尖端放電之原理釋放至大氣中；而該靜電產生器所相對生成的4個電子(4e-)，則經由靜電充電迴路之傳導，將能量回充至二氧化碳奈米(nM)反應極之極板上，使暫時鍵結於二氧化碳奈米(nM)反應極上的(C4+nM)狀態碳，因獲得額外的4個電子(4e-)能量而還原為碳原子，此時的二氧化碳奈米(nM)反應極，因為溫度已下降至90℃~30℃而回復為鬆散的突觸狀態，即可利用高頻震盪的機械力，順利的將奈米碳顆粒釋出；然後二氧化碳奈米(nM)反應極經重新加溫，即可進行另一個循環的再利用。 A carbon dioxide decomposition and (C 4+ nM) state carbon recovery method, when the output capacity of a dual-circuit fuel cell is reduced to 80% of the rated value, the performance of the carbon dioxide pole (CO 2 pole) is estimated to be filled with nanometer pores. (C 4+ nM) state carbon is reduced, and the next stage of chemical reaction, that is, the reduction process of carbon in the (C 4+ nM) state, that is, the use of an electrostatic generator, the purity of four electrons (4e - ) Energy, returning to the (C 4+ nM) state of the reverse reaction process of carbon, ie the reaction formula: (C 4+ nM) + 4e - ↓ → C + ▽ (nM); continued, produced by decomposition of carbon dioxide (C 4+ nM) state carbon reduction to carbon operation method, first shut down the hydrogen control valve and carbon dioxide control valve and the bottom drain valve, so that the interior of the dual-circuit fuel cell returns to the initial state; secondly, the power switch on the power supply circuit is set to The non-conducting open state causes the carbon dioxide nanometer (nM) reaction temperature to drop to between 90 ° C and 30 ° C, and the UV UV lamp is also extinguished due to the non-conduction of the power source; the electrostatic generator is activated to allow the electrostatic generator to utilize the friction The principle of electricity, the manufacture of static electricity with the opposite polarity Energy, with anti-electron energy, can be conducted through the electrostatic discharge circuit, guiding four counter-electrodes to the tip of the electrostatic discharge comb, and releasing it to the atmosphere by the principle of tip discharge; and the electrostatic generator is relatively generated The four electrons (4e - ) are then recharged to the plate of the carbon dioxide nano (nM) reactor via the conduction of the electrostatic charging circuit to temporarily bond to the carbon dioxide nano (nM) reactor ( C 4+ nM) state carbon, which is reduced to carbon atoms by obtaining an additional 4 electrons (4e - ) energy. At this time, the carbon dioxide nanometer (nM) reacts extremely, because the temperature has dropped to 90 ° C ~ 30 ° C and replies For the loose synaptic state, the high-frequency oscillating mechanical force can be used to smoothly release the nano carbon particles; then the carbon dioxide nano (nM) reaction is reheated, and another cycle can be reused. .
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JPH0668854A (en) * 1991-12-25 1994-03-11 Toshimi Yoshida Miniature solar lamp
CN1956917A (en) * 2004-05-25 2007-05-02 学校法人东洋大学 Method of decomposing carbon dioxide and method of forming carbon-particle structure

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Publication number Priority date Publication date Assignee Title
JPH0668854A (en) * 1991-12-25 1994-03-11 Toshimi Yoshida Miniature solar lamp
CN1956917A (en) * 2004-05-25 2007-05-02 学校法人东洋大学 Method of decomposing carbon dioxide and method of forming carbon-particle structure

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