TWI387464B - Makeup remover - Google Patents
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Description
本發明係有關於一種卸妝製劑，尤關於一種用以除去化妝品及/或達到清潔效果之卸妝油。The present invention relates to a makeup remover preparation, and more particularly to a cleansing oil for removing cosmetics and/or achieving a cleaning effect.
為避免接觸汗水、口水等而被去除、弄花，彩妝、防曬油、口紅等化妝品或保養品中常添加有大量疏水性的油酯、高分子、矽油、矽油衍生物等成分。通常使用一般液皂難以去除。In order to avoid contact with sweat, saliva, etc., it is removed, and flowers, makeup, sunscreen, lipstick, and other cosmetics or skin care products are often added with a large number of hydrophobic oil esters, polymers, eucalyptus oil, eucalyptus oil and other ingredients. It is usually difficult to remove using a general liquid soap.
既有卸妝製劑產品之中，以卸妝油之清潔效果較佳，亦即既有卸妝油得以自皮膚表面有效地去除化妝品或保養品。例如U.S. Patent No.4921874、U.S. Patent No.4707293、U.S. Patent No.3795624、U.S. Patent No.5462691、U.S. Patent No.5653450、U.S. Patent No.5653988，U.S. Patent No.5527488，U.S. Patent No.6620773，U.S. Patent No.4529605，U.S. Patent No.6132738、U.S. Patent No.4963535等美國專利，即揭露有關於既有卸妝油之先前技術。Among the cleansing preparation products, the cleansing effect of the cleansing oil is better, that is, the cleansing oil can effectively remove the cosmetic or skin care products from the skin surface. For example, US Patent No. 4,921,874, US Patent No. 4,074,293, US Patent No. 3,759,624, US Patent No. 5,462,691, US Patent No. 5,653,450, US Patent No. 5,565,988, US Patent No. 5,527, 488, US Patent No. 6620773, US U.S. Patent No. 4, 925, 960, U.S. Patent No. 4, 316, 738, and U.S. Patent No. 4, 963, 535, the disclosure of which is incorporated herein by reference.
卸妝油之主要成分為油及乳化劑所組成，其清潔機構，是利用組成裡的油來降低與彩妝上疏水成分之界面張力，進而溶解臉上的彩妝及污垢，當此卸妝油遇到水之後，利用組成裡的乳化劑形成乳液，所形成的乳液為水包油(oil-in-water)的狀態，將皮膚上的彩妝、污垢裡的油污，包在水內，再沖水將其去除。The main component of cleansing oil is oil and emulsifier. The cleaning mechanism uses the oil in the composition to reduce the interfacial tension with the hydrophobic component on the makeup, and then dissolve the makeup and dirt on the face. When the cleansing oil meets the water Then, the emulsion is formed by using the emulsifier in the composition, and the formed emulsion is in an oil-in-water state, and the makeup on the skin and the oil in the dirt are wrapped in water, and then the water is poured into water. Remove.
然而，由於既有卸妝油含有大量的油酯。使用此既有卸妝油後，常常導致油膩感而令使用者不舒服，進而讓使用者必需再使用諸如洗面乳或面皂等清潔劑來清洗皮膚表面，以消除該油膩感。However, since both cleansing oils contain large amounts of oil esters. The use of this cleansing oil often results in a greasy feel that is uncomfortable for the user, and the user must then use a cleaning agent such as a facial cleanser or a facial soap to clean the surface of the skin to eliminate the greasy feel.
另一方面，當卸妝油溶解臉上的彩妝、污垢，接著遇水之後，所形成乳液的粒徑若不夠小，雖能溶解油污，卻無法將毛孔內溶解的油污乳化並攜出，因乳滴粒徑大於毛孔，所以無法於毛孔內乳化，自然無法將毛孔內溶解的油污攜出。另外，進入毛孔內大量的卸妝油酯，若無法乳化時，殘留於毛孔內，也是產生油膩之因素。On the other hand, when the cleansing oil dissolves the makeup and dirt on the face, and then the water, the particle size of the formed emulsion is not small enough, although it can dissolve the oil, it cannot emulsifie and carry out the oil dissolved in the pores, because of the milk. Since the droplet size is larger than the pores, it cannot be emulsified in the pores, and naturally it is impossible to carry out the oil dissolved in the pores. In addition, a large amount of cleansing oil ester entering the pores, if not emulsified, remains in the pores, which is also a factor of greasy.
因此，遂有形成為微乳化狀態之清潔產品。既有微乳化清潔產品具有可於毛孔內乳化之微小乳滴，以強化清潔效果。諸如U.S. Patent No.6342469、U.S. Patent No.7399479、U.S. Patent No.5858954、U.S. Patent No.5571459、U.S. published Application number 2003/0095990等美國專利或專利申請公開案所揭露之既有微乳化清潔產品，亦具有良好清潔效果。Therefore, the crucible has a cleaning product formed in a microemulsified state. Both micro-emulsified cleaning products have tiny emulsion droplets that can be emulsified in the pores to enhance the cleaning effect. A microemulsified cleaning product, such as disclosed in US Patent No. 6,342,469, US Patent No. 7,399,479, US Patent No. 5, 858, 954, US Patent No. 5, 571, 459, US Published Application No. 2003/0095990, and the like. It also has a good cleaning effect.
此外，通常乳液之粒徑大小可略由外觀判斷，亦即當乳液透明度越高粒徑則越小。準此，卸妝油的乳化狀態，可以由卸妝油加水後所乳化而成乳液之外觀予以初步判別。當乳液呈現澄清或低濁度時，該乳液即為微乳化型乳液，其乳滴粒徑約在100nm以下；若乳液呈現乳白色而不透光時，該乳液即非微乳化乳液，其乳滴粒徑約800nm以上。In addition, usually, the particle size of the emulsion can be judged slightly by the appearance, that is, the particle size is smaller as the emulsion transparency is higher. Therefore, the emulsified state of the cleansing oil can be preliminarily determined by the appearance of the emulsion emulsified by the cleansing oil and water. When the emulsion exhibits a clear or low turbidity, the emulsion is a microemulsified emulsion having a droplet size of about 100 nm or less; if the emulsion is milky white and does not transmit light, the emulsion is a non-microemulsified emulsion, and the emulsion droplet The particle size is about 800 nm or more.
查U.S. Patent No.5571459使用硫酸鹽陰離子界面活性劑(anionic sulfate surfactant)、聚氧乙烯甘油酯(ethoxylated glycerol)、碳鏈3~9之醇類或醇醚作為共界面活性劑(co-surfactant)、和水不相溶之碳氫化合物或芳香物、水等，調配成萬用型的微乳化液體清潔劑。U.S. Patent No. 5,571,459 uses an anionic sulfate surfactant, an ethoxylated glycerol, an alcohol or carbon ether of a carbon chain 3-9 as a co-surfactant. And water-incompatible hydrocarbons or aromas, water, etc., formulated into a universal micro-emulsified liquid cleaner.
U.S. Patent No.6306410以部分聚氧乙烯化甘油酯(ethoxylated partial glycerides)和油酯為其組成，做為皮膚清潔之用途。雖然U.S. Patent No.6306410之記載宣稱其提供之卸妝油外觀透明、清潔效果佳、易沖洗，但未說明該卸妝油或該卸妝油之成分能形成水在油或油在水之微乳化狀態。U.S. Patent No. 6306410 is composed of ethoxylated partial glycerides and oil esters for use as a skin cleansing agent. Although the description of U.S. Patent No. 6,306,410 claims that the cleansing oil provided is transparent, cleansing, and easy to rinse, it does not mean that the cleansing oil or the cleansing oil component can form water in a microemulsified state of oil or oil in water.
然而，由於既有微乳化清潔產品含有大量界面活性劑，使用既有微乳化清潔產品時將導致厚重、黏膩之感覺。此外，為令前述既有微乳化清潔產品形成為微乳化狀態，必須添加大量有機溶劑，從而對眼睛、皮膚具有刺激性。又因該既有微乳化清潔產品過度地排除皮膚表面之油酯，亦導致使用既有微乳化清潔產品後皮膚乾燥之問題。However, since the microemulsified cleaning product contains a large amount of surfactant, the use of a microemulsified cleaning product results in a thick, sticky feeling. Further, in order to form the aforementioned microemulsified cleaning product into a microemulsified state, it is necessary to add a large amount of an organic solvent to be irritating to eyes and skin. Moreover, the excessive micro-emulsified cleaning product excessively eliminates the oil ester on the skin surface, and also causes the problem of dry skin after using the micro-emulsified cleaning product.
有鑒於前述既有卸妝製劑產品之缺點，本發明之目的在於提供一種具有良好卸妝效果及良好復脂效果，且使用後無油膩感之卸妝油。In view of the above disadvantages of the prior art makeup remover preparation, it is an object of the present invention to provide a cleansing oil which has a good makeup removal effect and a good liposuction effect, and which has no greasy feel after use.
為達到前述目的，本發明所採取之技術手段係令本發明所提供之卸妝油包括有含量為20~60重量百分比之油酯、含量為20~50重量百分比之聚氧乙烯化甘油酯、含量為5~20重量百分比之聚氧乙烯月桂基醚、含量為5~25重量百分比之月桂醇聚醚-13羧酸鈉、以及含量為3~20重量百分比之水。In order to achieve the above object, the technical means adopted by the present invention is such that the cleansing oil provided by the present invention comprises an oil ester having a content of 20 to 60% by weight, a polyoxyethylene glyceride having a content of 20 to 50% by weight, and a content thereof. It is 5 to 20% by weight of polyoxyethylene lauryl ether, 5 to 25 parts by weight of sodium laureth-13 carboxylate, and 3 to 20% by weight of water.
由於本發明所提供之卸妝油具有上述特定比例之成分，從而得以令本發明形成為一種油包水狀態之微乳化卸妝油，能有效地溶解臉上的彩妝、污垢，且不刺激眼睛皮膚。又由於本發明之卸妝油在受水沖洗後可轉變為水包油之微乳化形態，因此易於沖洗，且沖洗後不會導致油膩感。由上述可知該卸妝油確可改良既有卸妝油及既有微乳化清潔產品之缺點而能夠達到本發明之目的。Since the cleansing oil provided by the present invention has the above specific proportion of components, the present invention can be formed into a water-in-oil microemulsion cleansing oil, which can effectively dissolve makeup and dirt on the face without irritating the skin of the eyes. Moreover, since the cleansing oil of the present invention can be converted into a microemulsified form of oil-in-water after being washed by water, it is easy to rinse, and does not cause greasy feeling after rinsing. From the above, it can be seen that the cleansing oil can improve the disadvantages of the existing cleansing oil and the existing micro-emulsified cleaning product, and can achieve the object of the present invention.
以下藉由具體之實施例進一步說明本發明之實施形態。應注意該等實施例係用以說明本發明之技術內容，而非用以在任何方面限制本發明之範疇者。Embodiments of the present invention will be further described below by way of specific examples. It should be noted that the embodiments are intended to illustrate the technical aspects of the invention and are not intended to limit the scope of the invention in any way.
【實施例1】[Example 1]
本發明配方組成1之卸妝油主要包括有下列成分：The cleansing oil of the formula 1 of the present invention mainly comprises the following components:
1.油酯：20~60重量百分比(%w/w)；該油酯，係與水不互溶、皮膚可接受之液體碳氫化合物。較佳的是，該油酯係選擇自下列各油酯之一、或者自下列所選擇複數油酯所混合組成者：1. Oil ester: 20~60 weight percent (% w/w); the oil ester is a liquid hydrocarbon which is immiscible with water and acceptable to the skin. Preferably, the oil ester is selected from one of the following oil esters or a mixture of the following oil esters:
a.白礦油(paraffin)或支鏈礦油(isoparaffin)a. white mineral oil (paraffin) or branched mineral oil (isoparaffin)
b.揮發性矽油(0.6~10 cSt)、二甲基矽氧烷(dimethicone)、四矽環矽油(cyclotetrasiloxane)或五矽環矽油(cyclopentasiloxane)b. Volatile eucalyptus oil (0.6~10 cSt), dimethicone, cyclotetrasiloxane or cyclopentasiloxane
c.脂肪酸(碳鏈12~18)烷基(碳鏈1~4)酯。c. Fatty acid (carbon chain 12-18) alkyl (carbon chain 1-4) ester.
2.聚氧乙烯化甘油酯(ethoxylated glycerides)：聚氧乙烯-7椰子油甘油酯(PEG-7 glyceryl cocoate)含量20~50重量百分比。該聚氧乙烯-7椰子油甘油酯是一種復脂劑，在本發明之卸妝油中係做為主要之界面活性劑。該聚氧乙烯-7椰子油甘油酯不僅對於人體無刺激性，且能降低其他界面活性劑之刺激性。2. ethoxylated glycerides: PEG-7 glyceryl cocoate content of 20-50% by weight. The polyoxyethylene-7 coconut oil glyceride is a re-lipiding agent and is used as a main surfactant in the cleansing oil of the present invention. The polyoxyethylene-7 coconut oil glyceride is not only non-irritating to the human body, but also can reduce the irritation of other surfactants.
3.聚氧乙烯月桂基醚(polyoxyethylene lauryl ether)：聚氧乙烯1~4月桂基醚(laureth-1~4)含量5~20重量百分比。3. Polyoxyethylene lauryl ether: polyoxyethylene 1~4 lauryl ether (laureth-1~4) content of 5-20% by weight.
4.月桂醇聚醚-13羧酸鈉(sodium Laureth-13 carboxylate)：含量5~25重量百分比。4. Sodium laureth-13 carboxylate: content 5 to 25 weight percent.
5.水：3~20重量百分比。藉著在配方組成1中添加水而形成澄清透明油包水(water-in-oil，W/O)微乳化卸妝油，添加水，可減少配置成本，也可藉調整水之含量來調整卸妝油之黏度。5. Water: 3 to 20 weight percent. By adding water to the formulation 1 to form a clear water-in-oil (W/O) micro-emulsified cleansing oil, adding water can reduce the cost of the configuration, and can also adjust the makeup by adjusting the water content. The viscosity of the oil.
此外，亦可於配方組成1之中加入含量在1重量百分比以下之芳香精油。Further, an aromatic essential oil having a content of 1% by weight or less may be added to the formulation 1.
上述配方組成1可用以配製卸妝油如下：The above formula 1 can be used to formulate a cleansing oil as follows:
將表1成分1~5混合，拌均勻，即成透明之卸妝油。取此卸妝油1ml以水稀釋成100ml形成乳液後，其乳滴粒徑分佈如第一圖所示。Mix the ingredients 1 to 5 in Table 1 and mix them evenly to form a clear cleansing oil. After taking 1 ml of the cleansing oil and diluting it with water to 100 ml to form an emulsion, the particle size distribution of the emulsion droplets is as shown in the first figure.
反觀諸如U.S. Patent No.6306410等先前技術文獻所揭露之卸妝油具有如下表2所示之成分。In contrast, the cleansing oil disclosed in the prior art documents such as U.S. Patent No. 6,306,410 has the components shown in Table 2 below.
將上表2之組成混合，拌均勻，即成略為霧狀，非透明之卸妝油。取此U.S. Patent No.6306410所提供卸妝油1ml以水稀釋成100ml而形成乳液後，該乳滴粒徑分佈如第三圖。Mix the ingredients of Table 2 above and mix well to form a slightly misty, non-transparent cleansing oil. After the emulsion of the cleansing oil provided by U.S. Patent No. 6306410 was diluted with water to 100 ml to form an emulsion, the droplet size distribution was as shown in the third figure.
藉由前述關於本案技術內容之記載以及與U.S. Patent No.6306410所揭露之卸妝油相互比較，可知本發明所提供之卸妝油為一油包水(W/O)微乳化卸妝油，外觀透明澄清，沖水稀釋後轉變為水包油(oil-in-water，O/W)微乳液，具不刺激皮膚、清潔效果好、易沖洗、沖洗後無油膩感等特性。The above-mentioned cleansing oil provided by the present invention is a water-in-oil (W/O) micro-emulsified cleansing oil, and the appearance is transparent and clarified by the above description of the technical contents of the present invention and the cleansing oil disclosed in US Patent No. 6306410. After dilution with water, it is converted into oil-in-water (O/W) microemulsion, which has the characteristics of no irritating skin, good cleaning effect, easy rinsing, no greasy feeling after rinsing.
【實施例2】[Example 2]
本發明卸妝油之配方組成2包括有前述實施例1配方所有成分，並進一步包括有聚氧乙烯月桂基硫酸鈉(Sodium Lauryl Ether Sulfate)及丙二醇，因此，當依配方組成2製得之卸妝油被沖水稀釋而形成乳液後，該乳液較前述配方組成1之卸妝油形成之乳液的更加透明，從而可知配方組成2之卸妝油所形成之乳液具有更小的乳化粒徑其乳滴粒徑分佈如第三圖所示。The formula 2 of the cleansing oil of the present invention comprises all the components of the formula of the foregoing embodiment 1, and further comprises sodium sulphate sodium sulphate (Sodium Lauryl Ether Sulfate) and propylene glycol, and therefore, the cleansing oil prepared according to the formula 2 After being diluted with water to form an emulsion, the emulsion is more transparent than the emulsion formed by the cleansing oil of Formulation 1 described above, and it is known that the emulsion formed by the cleansing oil of Formulation 2 has a smaller emulsified particle size and a droplet size thereof. The distribution is shown in the third figure.
本發明配方組成2之卸妝油主要包括有下列成分：The cleansing oil of formula 2 of the present invention mainly comprises the following components:
1.油酯：20~60重量百分比。1. Oil ester: 20~60% by weight.
2.聚氧乙烯化甘油酯：聚氧乙烯-7椰子油甘油酯含量20~50重量百分比。2. Polyoxyethylene glyceride: Polyoxyethylene-7 coconut oil glyceride content 20~50% by weight.
3.聚氧乙烯月桂基醚：聚氧乙烯1~4月桂基醚含量5~15重量百分比。3. Polyoxyethylene lauryl ether: polyoxyethylene 1~4 lauryl ether content 5~15 weight percent.
4.月桂醇聚醚-13羧酸鈉(Sodium Laureth-13 Carboxylate)：含量5~25重量百分比。4. Sodium Laureth-13 Carboxylate: content 5 to 25 weight percent.
5.聚氧乙烯月桂基硫酸鈉：含量2~15重量百分比。5. Polyoxyethylene sodium lauryl sulfate: content of 2 to 15% by weight.
6.丙二醇：含量5~20重量百分比6. Propylene glycol: content 5~20% by weight
7.水：3~20重量百分比。7. Water: 3 to 20 weight percent.
此外，亦可於配方組成2之中加入含量在1重量百分比以下之芳香精油。Further, an aromatic essential oil having a content of 1% by weight or less may be added to the formulation 2.
上述配方組成2可以如下表3具體製成卸妝油，其乳滴粒徑分佈如第二圖。The above formula 2 can be specifically made into a cleansing oil as shown in Table 3 below, and the droplet size distribution is as shown in the second figure.
如上述實施例1及2之配方組成1及2所例示可知本發明所提供卸妝油之具體組成，並可知本發明之卸妝油具有下列特點：The specific compositions of the cleansing oil provided by the present invention can be seen as exemplified by the formulation compositions 1 and 2 of the above Examples 1 and 2. It is also known that the cleansing oil of the present invention has the following characteristics:
1.本發明為油包水(W/O)透明澄清之微乳化卸妝油，沖水稀釋後則轉變為水包油(O/W)之微乳液。1. The present invention is a water-in-oil (W/O) transparent clarified micro-emulsified cleansing oil which is converted into an oil-in-water (O/W) microemulsion after dilution with water.
2.含水量可達20重量百分比。2. The water content can reach 20% by weight.
3.可藉由水含量來調整產品之黏度。3. The viscosity of the product can be adjusted by the water content.
4.因沖水後轉變為水包油(O/W)之微乳液，乳滴粒徑小(約20~60奈米)，所以將能深入毛孔的油污攜出。4. The microemulsion is converted into oil-in-water (O/W) after flushing, and the droplet size is small (about 20~60 nm), so the oil which can penetrate into the pores can be carried out.
5.含聚氧乙烯-7椰子油甘油酯表面活性劑，因其兼具復脂作用，洗後皮膚無乾燥感。5. Polyoxyethylene-7 coconut oil glyceride surfactant, because it has a re-fatting effect, the skin does not have a dry feeling after washing.
6.油酯若選擇包含揮發性矽油對於彩妝、防曬、口紅等添加矽油或矽油衍生物疏水性難清洗物之產品，則有很好的去除效果。6. If the oil ester is selected to contain volatile eucalyptus oil, it will have a good removal effect for products such as makeup, sunscreen, lipstick, etc., which add hydrophobic or difficult-to-clean substances such as eucalyptus oil or eucalyptus oil derivatives.
7.不刺激眼睛皮膚。7. Does not irritate the eyes and skin.
8.易沖洗，沖洗後不留油感。8. Easy to rinse, no oily feeling after washing.
9.清潔處有些濕，也能有好的清潔效果。9. The cleaning area is a little wet and can also have a good cleaning effect.
10.卸妝洗淨，一次完成，無需在卸妝後再度以清潔劑清洗。10. Remove makeup and wash it once, no need to clean it with detergent after removing makeup.
由於本發明之卸妝油具有上述特點，可知該卸妝油確可改良既有卸妝油及既有微乳化清潔產品之缺點而能夠達到本發明之目的。Since the cleansing oil of the present invention has the above characteristics, it can be understood that the cleansing oil can improve the disadvantages of the existing cleansing oil and the existing microemulsified cleaning product, and can achieve the object of the present invention.
第一圖係本發明實施例1所例示卸妝油之乳滴粒徑分佈圖表。The first figure is a graph of the droplet size distribution of the cleansing oil exemplified in Example 1 of the present invention.
第二圖係本發明實施例2所例示卸妝油之乳滴粒徑分佈圖表。The second graph is a graph of the droplet size distribution of the cleansing oil exemplified in Example 2 of the present invention.
第三圖係既有卸妝油之乳滴粒徑分佈圖表。The third chart is a graph of the droplet size distribution of both cleansing oils.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW99111041A TWI387464B (en) | 2010-04-09 | 2010-04-09 | Makeup remover |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW99111041A TWI387464B (en) | 2010-04-09 | 2010-04-09 | Makeup remover |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201134498A TW201134498A (en) | 2011-10-16 |
| TWI387464B true TWI387464B (en) | 2013-03-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW99111041A TWI387464B (en) | 2010-04-09 | 2010-04-09 | Makeup remover |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TWI387464B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6792738B1 (en) * | 2019-08-19 | 2020-11-25 | 株式会社ファンケル | Transparent cleansing fee |
| CN111529432A (en) * | 2020-04-20 | 2020-08-14 | 上海舒彩网络科技有限公司 | Reversed micelle solubilizing cleansing oil and preparation method thereof |
-
2010
- 2010-04-09 TW TW99111041A patent/TWI387464B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TW201134498A (en) | 2011-10-16 |
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