TWI339219B

TWI339219B - High-performance hardmetal materials

Info

Publication number: TWI339219B
Application number: TW94108009A
Authority: TW
Inventors: Scott Liu Shaiw-Rong
Original assignee: Genius Metal Inc
Priority date: 2004-03-17
Filing date: 2005-03-16
Publication date: 2011-03-21
Also published as: TW200535255A

Description

1339219 九、發明說明：【發明所屬之技術領域】本發明係有關於硬金屬組合物及其製作技術，以及相關的應用。【先前技術】硬金屬（hardmetals)包括各種的複合材料，而特別設計成具有硬與耐火之特性，並且展現非常強的耐磨耗特性。在許多常用的硬金屬中，係包括有燒結或接合的碳化物、碳氮化物或其組合。許多硬金屬被稱作陶瓷金屬 (cermets) ’該陶瓷金屬所具有的組合物係可包括與黏結劑金屬粒子互相黏結之陶瓷粒子（例如Tic^在一些技術文獻中已經有揭示-些既定的硬金屬組合物。例如，硬金屬組合物的综合的編輯物係發表於Br〇〇kes的世界辭典以及硬金屬手冊（Handbook of Hardmetals，sixth edition，1339219 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to hard metal compositions and their fabrication techniques, as well as related applications. [Prior Art] Hardmetals include various composite materials, and are specifically designed to have hard and fire resistant characteristics and exhibit very strong wear resistance characteristics. Among many commonly used hard metals are sintered or joined carbides, carbonitrides or combinations thereof. Many hard metals are called ceramics (cermets). The ceramic metal has a composition that can include ceramic particles bonded to the metal particles of the binder (for example, Tic^ has been disclosed in some technical literature - some established hard Metal compositions. For example, a comprehensive editorial of hard metal compositions is published in Br〇〇kes' World Dictionary and Handbook of Hardmetals, sixth edition,

International Carbide Data, United Kindom 1996)中。硬金屬有許多的應用，例如可應用於切割金屬、石頭與其他硬材料的切割工具，拉金屬線的鋼膜，刀具，切割煤炭、礦石和岩石的切割研磨工具’以及鑽油田或其他的工具。除此之外，可根據元件的特別需要，而作成構造用的外罩、外表面或一些層而符合元件在某些環境下的操作應用。許夕硬金屬可以先將硬且耐火的碳化物或碳氮化物的粒子散佈於黏結基質（bindermatrix)中，然後將此混合物熱壓和燒結。這燒結製程使黏結基質與上述粒子黏結並使該International Carbide Data, United Kindom 1996). There are many applications for hard metals, such as cutting tools for cutting metals, stones and other hard materials, steel films for pulling metal wires, cutting tools, cutting and grinding tools for cutting coal, ore and rock, and drilling oil fields or other tools. . In addition, depending on the particular needs of the component, the outer cover, outer surface or layers of the construction may be constructed to conform to the operational application of the component under certain circumstances. The Xuxi hard metal may first disperse hard and refractory carbide or carbonitride particles in a binder matrix, and then heat and sinter the mixture. This sintering process bonds the bonding matrix to the particles and causes the

1057D-6939-PF 339219 混合物緻密化，而形成硬全盈 _ _.s 屬。廷些硬粒子係主要貢獻於硬金屬的硬特性與耐火特性：【發明内容】本發明的目的在於提供— 作技術。，、種新的硬金屬組合物及其製本發明的硬金屬組合物的特徵係：具有第—材料的硬粒子以及具有與第一材料不 _ 疋第一材枓之~黏結劑基質加^猶丨小其中，上述硬粒子係以實質均勻的佈於該黏結劑基質中。其中，式散一材料可以包括下列材料，例如成述硬粒子的該第材料WC基的材料、TiC基的一 T丨C基混合的材料或其他碳化物、氮化物、物以及上述材料的組合。其中，用以構成該黏屬質之該第二材料係可以包括下列材料，例如：以 -素、Re和Co的混合物、Ni基超合金、州基超合金盘1057D-6939-PF 339219 The mixture is densified to form a hard full _ _.s genus. The hard particle system mainly contributes to the hard and fire resistant properties of the hard metal: SUMMARY OF THE INVENTION The object of the present invention is to provide a technique. , a novel hard metal composition and the hard metal composition of the invention are characterized by: hard particles having a first material and a matrix of a binder having a first material and a first material In the case of the crucible, the hard particles are substantially uniformly distributed in the binder matrix. Wherein, the material may include the following materials, such as WC-based material of the first material forming a hard particle, a TC-based mixed material of TiC-based or other carbides, nitrides, and combinations of the above materials. . Wherein, the second material for constituting the adhesive substance may include the following materials, for example: a mixture of -, Re and Co, a Ni-based superalloy, a state-based superalloy disk

Re的混合物、Ni基超合金的混合物、州和c〇的混人物，以及上述材料與其他材料之混合物也可當作硬金°屬材料的黏結劑基質。還有’該Ni基超合金可以在”，相卜本發明的硬金屬組合物的组成例如是：該第二材料係佔該硬金屬組合物總體積的3〜4〇體積％。在一些應用例中’該黏結劑基質可以包括有銖（Re)元素’且銖元㈣佔該硬金屬組合物黏結劑基質該硬金屬組合物總重量的25 重量％以上。在其他應用例中’該第二材料可以包括川基超合金，該Ni基超合金可包括Ni與其他元素(例如叫，而應用於既定應用例中。A mixture of Re, a mixture of Ni-based superalloys, a mixed character of the state and c〇, and a mixture of the above materials and other materials can also be used as a binder matrix for hard gold. Also, 'the Ni-based superalloy may be in the same', the composition of the hard metal composition of the present invention is, for example, that the second material accounts for 3 to 4% by volume of the total volume of the hard metal composition. In some applications. In the example, the binder matrix may include a bismuth (Re) element and the bismuth (four) accounts for more than 25% by weight of the total weight of the hard metal composition of the hard metal composition binder matrix. In other applications, the The two materials may include a Kawasaki superalloy, which may include Ni and other elements (for example, for use in a given application).

1057D-6939'PF 6 339219 :製造上述硬金屬材料方面，其中一種製程包括：⑴在真 ”下於固相中燒結該材料混合物，以及（2)在具有壓力的情性氣氛中，進行固相掠社,. . 4丁 u 相 ^結（sohd-phase sintering)。也可以利用熱喷塗法Λ # 宽沄在表面上形成硬金屬塗層或硬金屬结構0 ，根據上述硬金屬材料不同的實施方式，可有至少下述優點：具有非常好的硬度、提升在高溫下的硬度，以及改善對腐蝕及氧化的抵抗性。在本應用中多種特別的實施方式將概述如下第一類 265種實施方式如下： !· 一種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素，且銖元素係佔該硬金屬組合物總重量的2 5 %以上；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 2·如第1項或第14項所述之硬金屬組合物，該第一材料包括一含鎢的碳化物。 3.如第2項所述之硬金屬組合物，其中該碳化物為 WC。 4‘如第3項所述之硬金屬組合物，其中該第一材料更進一步包括另一種含不同於W的金屬元素之破化物。 5. 如第4項所述之硬金屬組合物，其中該金屬為Ti。 6. 如第4項所述之硬金屬組合物，其中該金屬為Ta。 1057D-6939-PF 7 1339219 7·如第4項所述之硬金屬組合物，其中該金屬為Nb。 8.如第4項所述之硬金屬組合物，其中該金屬為v。 9·如第4項所述之硬金屬組合物，其中該金屬為Cr。 1〇.如第4項所述之硬金屬組合物，其中該金屬為Hf。 U·如第4項所述之硬金屬組合物，其中該金屬為M〇。 12. 如第2項所述之硬金屬組合物，其中該第—材料更進—步包括氮化物。 13. 如第2項或第12項所述之硬金屬組合物，其中該籲氮化物包括丁iN、 ZrN、 VN、NbN、 TaN 或 HfN。 14，一種硬金屬組合物，包括：具有包括氮化物的第一材料之硬粒子；以及具有與第一材料不同之第二材料之毒占結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括鍊 (Re)元素，其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 15. 如第14項所述之硬金屬組合物，其中該氮化物包籲括 TiN、ZrN、VN、NbN、TaN 或 HfN。 16. 如第1項所述之硬金屬組合物，其中黏結劑基質更進一步包括Co ^ 17· —種硬金屬組合物’包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中’該黏結劑基質包括銖（Re)和鎳（Νι:) 元素’其中’上述硬粒子係以實質均勻的方式散佈於該黏 1057D-6939-PF 8 1339219 結劑基質中。 18. —種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第_材料不同之第二材料之一黏結劑基質 (binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40。/。；其中’該黏結劑基質包括銖（Re)和鉬（M〇) 几素，其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 19. 一種硬金屬組合物，包括：具有包括氮化物第一 •材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質（bindermatrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇%;其中，該黏結劑基質包括銖（Re) 和鐵（Fe)元素，其中，上述硬粒子係以實質均勾的方式散佈於該黏結劑基質中。 20. -種硬金屬組合物’包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之-黏結劑基質巋W她⑻；其中，該第二材料係佔該硬金屬組合物總 •體積的3〜4〇% ;其中，嗜赴处如w _ 該黏結劑基質包括銖（Re)和鉻（Cr) 元素’其中，上述硬粒子係以夸拼认“ 係以貫貝均勻的方式散佈於該黏結劑基質中。 21 . •裡峴金屬組合物，包括. ^ 匕括‘具有第一材料的硬啦子，以及具有與第一材料不同 ,u. ^ ^ < 弟一材料之一黏結劑基f (binder matnx);其中，該第 __ 胁ο] 材抖係佔該硬金屬組合物鲜體積的3〜40% ;其中，該黏結入▲一本^ . %丞貝包括銖（Re)和Ni基南合金7L素，其中，上述硬粒子 ' 乂實貝均勻的方式散佈灰1057D-6939'PF 6 339219: In the manufacture of the above hard metal materials, one of the processes includes: (1) sintering the material mixture in a solid phase under a true ", and (2) performing a solid phase in a pressure atmosphere Sweeping society, . . 4 sou d-phase sintering. You can also use the thermal spray method # 沄形成 on the surface to form a hard metal coating or hard metal structure 0, according to the above hard metal materials Embodiments may have at least the following advantages: having very good hardness, increasing hardness at high temperatures, and improving resistance to corrosion and oxidation. In this application, various special embodiments will be summarized as follows: The embodiment is as follows: a hard metal composition comprising: hard particles having a first material; and a binder matrix having a second material different from the first material; wherein the second material system 3% to 40% of the total volume of the hard metal composition; wherein the binder matrix comprises bismuth (Re) element, and the lanthanum element accounts for more than 25 % of the total weight of the hard metal composition; The sub-system is dispersed in the binder matrix in a substantially uniform manner. The hard metal composition according to item 1 or claim 14, wherein the first material comprises a tungsten-containing carbide. The hard metal composition of the present invention, wherein the carbide is WC. The hard metal composition according to Item 3, wherein the first material further comprises another compound containing a metal element different from W. 5. The hard metal composition according to item 4, wherein the metal is Ti. 6. The hard metal composition according to item 4, wherein the metal is Ta. 1057D-6939-PF 7 1339219 7· The hard metal composition according to the item 4, wherein the metal is Nb. The hard metal composition according to item 4, wherein the metal is v. 9. The hard metal combination according to item 4. The hard metal composition according to the item 4, wherein the metal is Hf. The metal is Hf. The metal is M〇. 12. The hard metal composition of item 2, wherein the first material further comprises a nitride. 13. As described in item 2 or item 12. a hard metal composition, wherein the nitrogen compound comprises butyl iN, ZrN, VN, NbN, TaN or HfN. 14. A hard metal composition comprising: hard particles having a first material comprising a nitride; a second material of a different material is a binder matrix; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix comprises a chain (Re) An element wherein the above hard particles are dispersed in the binder matrix in a substantially uniform manner. 15. The hard metal composition of clause 14, wherein the nitride comprises TiN, ZrN, VN, NbN, TaN or HfN. 16. The hard metal composition of item 1, wherein the binder matrix further comprises a Co ^ 17· hard metal composition 'comprising: hard particles having a first material; and having a different texture than the first material a binder matrix of the second material; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein 'the binder matrix comprises bismuth (Re) and nickel (Νι: The element 'where' the above hard particles are dispersed in the viscous 1057D-6939-PF 8 1339219 binder matrix in a substantially uniform manner. 18. A hard metal composition comprising: hard particles having a first material; and a binder matrix having a second material different from the first material; wherein the second material accounts for the hard The total volume of the metal composition is from 3 to 40. /. Wherein the binder matrix comprises bismuth (Re) and molybdenum (M〇), wherein the above hard particles are dispersed in the binder matrix in a substantially uniform manner. 19. A hard metal composition comprising: a hard particle having a first material comprising a nitride; and a binder matrix having a second material different from the first material; wherein the second material is The total volume of the hard metal composition is 3 to 4% by weight; wherein the binder matrix comprises bismuth (Re) and iron (Fe) elements, wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. in. 20. A hard metal composition 'comprising: a hard particle having a first material; and a binder matrix 她W (8) having a second material different from the first material; wherein the second material occupies the hard 3~4〇% of the total volume of the metal composition; wherein, the place where the object is like w _ the binder matrix includes bismuth (Re) and chromium (Cr) elements, wherein the above hard particles are labeled as " The scallop is evenly distributed in the matrix of the binder. 21. The metal composition of the lining, including: ^ includes a hard-clip with a first material, and has a different color than the first material, u. ^ ^ &lt a binder material base f (binder matnx); wherein, the first __ threat ο] material shakes account for 3 to 40% of the fresh volume of the hard metal composition; wherein, the bond into ▲ a ^ % mussels include ruthenium (Re) and Ni-based alloys 7L, in which the above-mentioned hard particles' 乂贝均匀均匀均匀均匀均匀均匀

1057D-6939-PF 1339219 該黏結劑基質中。 2 2.如第2 1項所述之硬金屬組合物，其中該黏結劑基質材料更進一步包括Co 23. —種硬金屬組合物，包括：具有第一材料的硬粒子，其中該第一材料具有至少一下列混合物：（1 )Wc，Tic 與TaC的混合物，（2)WC，Tic與NbC的混合物，（3)wc，Tic 與至少TaC與；KbC中之一的混合物，（4)WC，TiC與至少 HfC與NbC中之一的混合物；以及具有與第—材料不同之籲第一材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40°/。；其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 24. —種硬金屬組合物’包括：具有第一材料的硬粒子，其中該第一材料具有至少一下列混合物：（1)wc, TiC 與TaC的混合物，（2)WC，TiC與NbC的混合物，（3)wc，Tic 與至少TaC與NbC中之一的混合物，（4)WC，TiC與至少鲁HfC與NbC中之一的混合物；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素及Ni基超合金；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 25. —種硬金屬組合物，包括：具有第一材料的硬粒子’其中該第一材料具有M〇2C與TiC的混合物；以及具有與第一材料不同之第二材料之一黏結劑基質（bin£jer 1057D-6939-PF 10 1339219 matrix);其中’該第二材料係佔該硬金屬組合物總體積的 3〜40體積％ ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 26·—種硬金屬組合物，包括：具有包括TiN、Mo2C 與TiC第一材料的硬粒子；以及具有與第一材料不同之第材料之.黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇D/。：其中，該黏結劑基質包括鍊（Re)元素；其中，上述硬粒子係以實質均勻的方 Φ 式散佈於該黏結劑基質中。 27. —種硬金屬組合物，包括：具有包括m〇2c與Tic 的第一材料之硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)元素及Ni基超合金：其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 28. —種硬金屬組合物的成形方法，包括下列步驟：鲁經由混合具有硬粒子的粉末與包括有鍊（Re)的一點結劑基質材料，而形成一階段性的粒子；以及利用該黏結劑基質材料黏結該等硬粒子，而進行一製程使上述階段性的粒子被製造成一固態的硬金屬材料；其中該製程包括：⑴在真空條件下，於固相中燒結該階段性的粒子，以及⑺在具有壓力的惰性氣氛中，於固相中燒結該階段性的粒子。” “9.如第28項所述之硬金屬組合物的成形方法，其中該黏結劑基質係更包括鎳基超合金。、1057D-6939-PF 1339219 The binder matrix. 2. The hard metal composition of item 2, wherein the binder matrix material further comprises a Co 23. hard metal composition comprising: hard particles having a first material, wherein the first material Having at least one of the following mixtures: (1) Wc, a mixture of Tic and TaC, (2) WC, a mixture of Tic and NbC, (3) wc, a mixture of Tic and at least TaC and one of KbC, (4) WC a mixture of TiC and at least one of HfC and NbC; and a binder matrix having a first material different from the first material; wherein the second material accounts for the total volume of the hard metal composition 3~40°/. Wherein the binder matrix comprises a ruthenium (Re) element; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 24. A hard metal composition 'comprising: hard particles having a first material, wherein the first material has at least one of the following: (1) wc, a mixture of TiC and TaC, (2) WC, TiC and NbC a mixture, (3) wc, a mixture of Tic and at least one of TaC and NbC, (4) a mixture of WC, TiC and at least one of Luf and NbC; and one of a second material different from the first material a binder matrix; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix comprises a ruthenium (Re) element and a Ni-based superalloy; The hard particles are dispersed in the binder matrix in a substantially uniform manner. 25. A hard metal composition comprising: a hard particle having a first material wherein the first material has a mixture of M〇2C and TiC; and a binder matrix having a second material different from the first material ( Bin£jer 1057D-6939-PF 10 1339219 matrix); wherein the second material accounts for 3 to 40% by volume of the total volume of the hard metal composition; wherein the binder matrix comprises a ruthenium (Re) element; The above hard particles are dispersed in the binder matrix in a substantially uniform manner. 26. A hard metal composition comprising: a hard particle having a first material comprising TiN, Mo2C and TiC; and a binder matrix having a first material different from the first material; wherein the second The material is 3 to 4 Å D/ of the total volume of the hard metal composition. Wherein the binder base comprises a chain (Re) element; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 27. A hard metal composition comprising: a hard particle having a first material comprising m〇2c and Tic; and a binder matrix having a second material different from the first material; wherein The second material accounts for 3 to 4% by weight of the total volume of the hard metal composition; wherein the binder matrix comprises a bismuth (Re) element and a Ni-based superalloy: wherein the hard particles are dispersed in a substantially uniform manner The binder is in the matrix. 28. A method of forming a hard metal composition comprising the steps of: forming a staged particle by mixing a powder having a hard particle with a one-point binder matrix material comprising a chain (Re); and utilizing the bond The matrix material is bonded to the hard particles, and a process is performed to prepare the above-mentioned staged particles into a solid hard metal material; wherein the process comprises: (1) sintering the staged particles in a solid phase under vacuum conditions, And (7) sintering the staged particles in a solid phase in a pressurized inert atmosphere. The method of forming a hard metal composition according to item 28, wherein the binder matrix further comprises a nickel-based superalloy. ,

1057D-6939-PF 11 1339219 1 ^ ' 、 30. 如第29項所述之硬金屬組合物的成形方去盆中該黏結劑基質係更包括鈷（Co)。 31. 如第28項所述之硬金屬組合物的成形方法其中該黏結劑基質係更包括鈷（Co)。 ^ 32‘如第28項所述之硬金屬組合物的成形方法，其中上述每一步驟的燒結製程係在低於該等硬粒子盥 /、路黏結劑基質的共炫（eutectic)溫度下進行。 33. —種硬金屬組合物，包括：具有第—持料的硬粒 •子：以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 34. 如第33項或第47項所述之硬金屬組合物，其中該第一材料係包括含有鎢的碳化物。 35. 如第34項所述之硬金屬組合物，其中該碳化物係包括單原子的碳化鎢（WC)。 36. 如第34項所述之硬金屬組合物，其中該第一材料 •更包括含有不同於鎢的金屬之碳化物。 37. 如第36項所述之硬金屬組合物，其中該金屬係鈦 (Ti) 〇 ’、 38·如第36項所述之硬金屬組合物，其中該金屬係鈕 (Ta)。 39·如第36項所述之硬金屬組合物，其中該金屬係鈮 (Nb)。 40.如第36項所述之硬金屬組合物’其中該金屬係釩1057D-6939-PF 11 1339219 1 ^ ' 30. The forming of the hard metal composition as described in item 29 is in the basin. The binder matrix further comprises cobalt (Co). The method of forming a hard metal composition according to item 28, wherein the binder matrix further comprises cobalt (Co). The method of forming a hard metal composition according to item 28, wherein the sintering process of each of the above steps is performed at a eutectic temperature lower than the hard particle/rubber matrix. . 33. A hard metal composition comprising: a hard particle having a first holding material: and a binder matrix having a second material different from the first material, the second material comprising nickel a base super alloy; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. The hard metal composition according to Item 33 or 47, wherein the first material comprises a carbide containing tungsten. 35. The hard metal composition of clause 34, wherein the carbide comprises monoatomic tungsten carbide (WC). 36. The hard metal composition of clause 34, wherein the first material further comprises a carbide comprising a metal other than tungsten. The hard metal composition according to the item 36, wherein the metal is titanium (Ti) ’ ', 38. The hard metal composition according to item 36, wherein the metal button (Ta). 39. The hard metal composition of clause 36, wherein the metal is niobium (Nb). 40. The hard metal composition of item 36, wherein the metal is vanadium

1057D-6939-PF 12 1339219 '、命 * (v) 〇 41. 如第36項所述之硬金屬組合物，其中該金屬係鉻 (Cr) 〇 42. 如第36項所述之硬金屬組合物，其中該金屬係給 (Hf) 〇 43. 如第36項所述之硬金屬組合物，其中該金屬係鉬 (Mo) 〇 44. 如第34項所述之硬金屬組合物，其中該第一材料 _更包括一氮化物。 45. 如第44項所述之硬金屬組合物，其中該氮化物係包括 ZrN，HfN ' VN、NbN、TaN 及 TiN。 46_如第44項所述之硬金屬組合物，其中該氮化物係包括HfN。 47.如第33項所述之硬金屬組合物，其中該第一材料更包括一氮化物。 4 8.如第4 7項所述之硬金屬組合物，其中該氮化物係春包括至少 ZrN、VN、NbN、TaN TiN 及 HfN 之一。 49. 如第33項所述之硬金屬組合物，其中該鎳基超合金係主要包括鎮元素以及更包括其他元素。 50. 如第49項所述之硬金屬組合物，其中該其他元素係包括 Co, Cr，Al，Ti，Mo, Nb, W 與 Zr。 51. 如第33項所述之硬金屬組合物，其中該黏結劑基質更包括不同於鎳（Ni)基超合金的一第二超合金。 5 2 ·如第5 1項所述之硬金屬組合物，其中該黏結劑基 1057D-6939-PF 13 1339219 質係更包括銖（Re)。 53.如申請專利範圍第52項所述之硬金屬組合物其中該黏結劑基質係更包括鈷（c〇)。 54·如申請專利範圍第33項所述之硬金屬組合物其中該黏結劑基質係更包括銖（尺£)。、 55. -種硬金屬組合物’包括：具有第一材料的硬粒子：以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括錦基超合金、鍊㈣及㈣Q)元素；H上述硬粒子係、以實質均句的方式散佈於該黏結劑基質中。 56 一種硬金屬組合物，包括. I祜.具有第一材料的硬粒子；以及具有與第一材料不同之笛_ 之第一材料之一黏結劑基質 (binder matrix)，該第二材料係台匕何Ή係包括鎳基超合金及鈷（c〇)元素；其中，上述硬粒子係以實皙的耳買均勾的方式散佈於該黏結劑基質中。 57. —種硬金屬組合物，包妊. L括.具有第一材料的硬粒子；以及具有與第-材料不同之第二材料之一黏結劑基質 W -叫，該第二材料係包括錄基超合金及鎳⑽元素；其中，上述硬粒子係以實暂仏灵買均勻的方式散佈於該黏結劑基質中。具有第一材料的硬粒 58. —種硬金屬組合物，包括. 子；以及具有與第一材料不同之笛_ 〜乐二材料之一黏結劑基質 (binder matrix)，該第二材料传治上，叶係包括鎳基超合金及鐵（Fe)元素；其中，上述硬粒子係以實暂仏 M句勻的方式散佈於該黏結 1057D-6939-PF 14 1339219 劑基質中。 59. -種硬金屬組合物，包括：子；以及具有與第一材料二第-材料的硬粒 •^弟—材料之一逢上会士；^丨# (binder matrix) ’該第二材料係，.·。劑基質1057D-6939-PF 12 1339219 ', life* (v) 〇41. The hard metal composition according to item 36, wherein the metal is chromium (Cr) 〇42. The hard metal combination as described in item 36 The hard metal composition according to the item 36, wherein the metal is molybdenum (Mo) 〇44. The hard metal composition according to item 34, wherein The first material _ further includes a nitride. The hard metal composition according to item 44, wherein the nitride system comprises ZrN, HfN 'VN, NbN, TaN and TiN. The hard metal composition according to item 44, wherein the nitride system comprises HfN. 47. The hard metal composition of clause 33, wherein the first material further comprises a nitride. 4. The hard metal composition according to item 4, wherein the nitride system spring comprises at least one of ZrN, VN, NbN, TaN TiN and HfN. The hard metal composition according to item 33, wherein the nickel-based superalloy system mainly comprises a town element and further includes other elements. 50. The hard metal composition of clause 49, wherein the other elements are Co, Cr, Al, Ti, Mo, Nb, W and Zr. 51. The hard metal composition of clause 33, wherein the binder matrix further comprises a second superalloy different from the nickel (Ni) based superalloy. The hard metal composition according to item 51, wherein the binder base 1057D-6939-PF 13 1339219 further comprises ruthenium (Re). 53. The hard metal composition of claim 52, wherein the binder matrix further comprises cobalt (c). 54. The hard metal composition of claim 33, wherein the binder matrix further comprises ruthenium (foot). 55. - a hard metal composition 'comprising: a hard particle having a first material: and a binder matrix having a second material different from the first material, the second material comprising a Alloy, chain (4) and (4) Q) elements; H above hard particle system, dispersed in the matrix of the binder in a substantially uniform manner. A hard metal composition comprising: I. a hard particle having a first material; and a binder matrix having a first material different from the first material, the second material system The cerium includes a nickel-based superalloy and a cobalt (c〇) element; wherein the hard particles are dispersed in the binder matrix in a manner that is sturdy. 57. A hard metal composition comprising: a hard particle having a first material; and a binder matrix W having a second material different from the first material, the second material comprising a base super alloy and a nickel (10) element; wherein the hard particles are dispersed in the binder matrix in a manner that is uniformly bought. a hard particle having a first material 58. a hard metal composition comprising: a sub-material; and a binder matrix having a flute material different from the first material, the second material is passed on The leaf system comprises a nickel-based superalloy and an iron (Fe) element; wherein the hard particles are dispersed in the bond 1057D-6939-PF 14 1339219 matrix in a manner that is uniform. 59. - a hard metal composition comprising: a sub-material; and a hard particle having a first material - a material - a material of a material - a blister matrix - a second material system,.·. Agent matrix

Tt-f ; JL ^ » _L 4v, jz. ’、，、土超合金及鉬（Mo) 兀京，/、宁，上述硬粒子係以實質 } 結劑基質中。、_ _ 式散佈於該黏 60. —種硬金屬組合物，包括.1 子；以及具有與第-材料不同之第：材材料的硬粒 a.」材抖之—黏結劑基質 (bmdei· matrix)，該第二材料係貝丰.甘士 u + 叶伟。括鎳基超合金及鉻(Cr)元素，其中，上述硬粒子係以實質均㈣所由勾的方式散佈於該黏結劑基質中。 61_如第33項所述之硬金屈細人榀更I屬組合物，其中該黏結劑基質係更包括不同於鎳基超合金的其他合金。 62. -種硬金層組合物’包括：具有第—材料的硬粒子，其中該第一材料具有加與TiN;以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix)，該第二材料係包括至少Ni、Mo與MhC之一；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 63. —種硬金屬組合物，包括：具有第一材料的硬粒子’其中該第一材料具有TiC與TiN;以及具有與第—材料不同之第二材料之一黏結劑基質（binder matrix)，該具有鍊（Re)元素的第一材料係包括至少Ni、Mo與Mo2C2 — · 其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 1057D-6939-PF 15 1339219 64. 如第63項所述之硬金屬組合物，其中該黏結劑基質係更包括鈷（Co)。 65. 如第64項所述之硬金屬組合物，其中該黏結劑基質係更包括鎳基超合金。 66. 如第63項所述之硬金屬組合物，其中該黏結劑基質係更包括鎳基超合金。 67. —種硬金屬組合物，包括··具有第一材料的硬粒子，其中該第一材料具有Tic與丁iN;以及具有與第一材料不同之第二材料之__黏結劑基f (bindef福叫，該具有鎳（N!)基超合金的第二材料係包括至少與之 :其ϋΓ上述硬粒子係以實質均勾的方式散佈於該黏結劑基質中。 TJS. m *屬一 D仍〜紙叩万法，包括下列基=有：！子的粉末與包括有錄基超合金的經劑基質材料，而开彡赤一 b —。巧祥丞超甘金的一黏也成一階段性的粒子.Tt-f ; JL ^ » _L 4v, jz. ', ,, soil superalloy and molybdenum (Mo) 兀, /, 宁, the above hard particles are in the matrix of the substance. , _ _ is dispersed in the viscous 60. A hard metal composition, including .1; and a hard particle having a material other than the first material a." Material shake - binder matrix (bmdei· Matrix), the second material is Befeng. Gansu u + Ye Wei. A nickel-based superalloy and a chromium (Cr) element, wherein the hard particles are dispersed in the binder matrix in such a manner as to be substantially (4). 61. The hard gold ferrule as described in item 33, wherein the binder matrix further comprises other alloys other than the nickel-based superalloy. 62. A hard gold layer composition 'comprising: a hard particle having a first material, wherein the first material has a TiN added; and a binder matrix having a second material different from the first material The second material comprises at least one of Ni, Mo and MhC; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 63. A hard metal composition comprising: a hard particle having a first material, wherein the first material has TiC and TiN; and a binder matrix having a second material different from the first material, The first material having a chain (Re) element includes at least Ni, Mo, and Mo2C2 - wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. The hard metal composition of item 63, wherein the binder matrix further comprises cobalt (Co). 65. The hard metal composition of clause 64, wherein the binder matrix further comprises a nickel based superalloy. 66. The hard metal composition of clause 63, wherein the binder matrix further comprises a nickel based superalloy. 67. A hard metal composition comprising: hard particles having a first material, wherein the first material has a Tic and a di-nN; and a binder base f (having a second material different from the first material) The second material of the nickel (N!)-based superalloy includes at least the same: the hard particles are dispersed in the binder matrix in a substantially uniform manner. TJS. m * is a D is still ~ paper 叩 Wanfa, including the following base = there are:! The powder of the child and the matrix material including the recording base super alloy, and the opening of the red one b -. Qiaoxiang 丞 super ganjin's stick is also one Staged particles.

基質材料黏結該等硬粒子，一制：及利用該黏結粒子被製造成一固製耘使上述階段性口心、的硬金屬材料。 69.如第68項所述之硬金該製程係連續地〇物的成形方法，其進仃下列步驟： (1) 一衝壓製程· (2) 一第—繞結製程； (3) -成形製程；以及 (4) 一第二繞結製程。 70·如第68項私、+ 、所述之硬金屬級合物的成形方法，在該 1057D-6939*-pf 16 339219 退合步驟之前，更包括使該黏結劑基質更包括有錁（Re)之一預備製程。 71.如第68項所述之硬金屬組合物的成形方法，在該混合步驟之前，更包括使該黏結劑基質更包括有鈷（c〇)之一預備製程。 72·如第68項所述之硬金屬組合物的成形方法，其令該製程包括在一熱均壓製程中的一固相燒結。The matrix material is bonded to the hard particles, and the bonded particles are fabricated into a solid metal material which is solidified to form the above-mentioned periodic core. 69. The hard gold process as described in item 68 is a method for forming a continuous smash, which comprises the following steps: (1) a stamping process, (2) a first-wound process; (3) - forming Process; and (4) a second winding process. 70. The method of forming a hard metal hexahydrate according to item 68, prior to the step of decomposing 1057D-6939*-pf 16 339219, further comprising including the ruthenium (Re) One of the preparatory processes. 71. The method of forming a hard metal composition according to item 68, further comprising, prior to the mixing step, a preparatory process for further including the cobalt matrix. The method of forming a hard metal composition according to item 68, which comprises subjecting the process to solid phase sintering in a heat homogenization process.

73.如第68項所述之硬金屬組合物的成形方法，其中該製程包括：（1)在真空條件下，於固相粒子，以及（2)在具有壓力的惰性氣氛中階段性的粒子。中燒結該階段性的 ’於固相中燒結該 —一，一 ^ 取少乃沃，在為二合步：之前，更包括使該等硬粒子具有小於。.一子徑，用以降低該等燒結製程的溫度。 π 合物1以當作是具有的元件的構成材料，該耐磨部分用以去除一物品的= 該对磨部分的構成材料包括：具㈣及具有與第一材料不同之第二材料之一：：子，以 —X)，該第二材料係包括銖與鎳基超人：.二(b-e 硬粒Γ::Γ的方式—劑基ί:，質係包=。:。所述之硬金屬組合物’其中該黏結》 77· 一種硬金屬組合物，材料’該财磨元件的構成材料用以當作是耐磨包括：具有第一元件的構成材料的硬粒73. The method of forming a hard metal composition according to item 68, wherein the process comprises: (1) solid phase particles under vacuum, and (2) staged particles in an inert atmosphere having pressure . The sintering of the staged 'sintering in the solid phase is one-to-one, taking less Naiwo, before including the second step: further including making the hard particles less than. A sub-path to reduce the temperature of the sintering process. The π compound 1 is considered to be a constituent material of the component, and the wear-resistant portion is for removing an article. The constituent material of the pair of grinding portions includes: (4) and one of the second materials having a different material from the first material. ::Sub, to -X), the second material consists of bismuth and nickel-based superman: two (be hard Γ:: Γ way - agent base ί:, 质包包 =.:. Metal composition 'where the bond>> 77. A hard metal composition, the material of which is used as a wear resistant material comprising: a hard grain having a constituent material of the first element

1057D-6939-PF 17 1339219 'Λ % 子；以及具有與第—材料不同之第二材料之一黏結劑基質 (binder matrix)’該第二材料係包括鎳基超合金；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 78. —種硬金屬組合物，包括：具有第一材料的硬粒子’其中該第一材料具有至少一下列混合物：（丨）Wc, Tic 與TaC的固溶體，（2)WC, TiC與NbC的固溶體，（3)WC, TiC 與至少TaC與NbC中之一的固溶體，（4)WC, TiC與至少 HfC與NbC中之一的固溶體；以及具有與第一材料不同之 _ 第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 79. 如第78項所述之硬金屬組合物，其中該等硬粒子包括WC，TiC與TaC的固溶體，且該黏結劑基質係由純銶 (Re)元素所構成。 80. 如第79項所述之硬金屬組合物，其中該固溶體係鲁佔該硬金屬組合物總體積的72%’而該係銖（Re)元素佔該硬金屬組合物總體積的28%。 81. 如第79項所述之硬金屬組合物，其中該固溶體係佔該硬金屬組合物總體積的85體積％ ’而該銖（Re)元素係佔該硬金屬組合物總體積的1 5 %。 82. 如第79項所述之硬金屬組合物，其中TiC與丁aC 係約等量，且TiC與TaC的總量係少於WC的量。 83·如第78項所述之硬金屬組合物’其中該硬粒子包 1057D-6939-PF 18 1339219 括WC，TiC與Tac的固溶體。 84.如第83項所述之硬金屬組合物，其中Tic係佔該硬金屬組合物總重量的3至6%，TaC係佔該硬金屬組合物總重量的3至6%，而WC佔該硬金屬組合物總重量的78 至 89%。 8 5 .如第8 3項所述之硬金屬組合物’其中該黏結劑基質更包括Co。 86. 如第83項所述之硬金屬組合物，其中該鎳基超合 # 金係主要包括鎳以及其他元素，上述其他元素包括Co, Cr,1057D-6939-PF 17 1339219 'Λ% sub; and a binder matrix having a second material different from the first material', the second material comprising a nickel-based superalloy; wherein the hard particle system Dispersed in the binder matrix in a substantially uniform manner. 78. A hard metal composition comprising: hard particles having a first material, wherein the first material has at least one of the following: (丨) Wc, a solid solution of Tic and TaC, (2) WC, TiC and a solid solution of NbC, (3) WC, a solid solution of TiC and at least one of TaC and NbC, (4) a solid solution of WC, TiC and at least one of HfC and NbC; and having a first material a binder matrix of a second material; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix comprises a ruthenium (Re) element; Wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 79. The hard metal composition of clause 78, wherein the hard particles comprise WC, a solid solution of TiC and TaC, and the binder matrix is composed of pure ruthenium (Re) elements. The hard metal composition according to item 79, wherein the solid solution system accounts for 72% of the total volume of the hard metal composition and the 铢 (Re) element accounts for 28% of the total volume of the hard metal composition. %. The hard metal composition according to item 79, wherein the solid solution system accounts for 85% by volume of the total volume of the hard metal composition, and the ruthenium (Re) element accounts for 1% of the total volume of the hard metal composition. 5 %. 82. The hard metal composition of item 79, wherein TiC is about the same as diced aC, and the total amount of TiC and TaC is less than the amount of WC. 83. The hard metal composition as described in item 78 wherein the hard particle package 1057D-6939-PF 18 1339219 comprises WC, a solid solution of TiC and Tac. The hard metal composition according to item 83, wherein the Tic is from 3 to 6% by weight based on the total weight of the hard metal composition, and the TaC is from 3 to 6% by weight based on the total weight of the hard metal composition, and the WC is The hard metal composition has a total weight of from 78 to 89%. 8. The hard metal composition as described in item 83, wherein the binder matrix further comprises Co. 86. The hard metal composition of item 83, wherein the nickel-based superabsorbent # gold system mainly comprises nickel and other elements, and the other elements include Co, Cr,

Al, Ti，Mo, Nb，W，Zr，B，C 與 V。 87. —種硬金屬組合物，包括：具有第一材料的硬粒子’其中該第一材料具有至少一下列混合物：（1)wc, Tic 與TaC的固溶體’（2)WC，TiC與NbC的固溶體，（3)WC, TiC 與至少TaC與NbC中之一的固溶體，（4)WC，TiC與至少 HfC與NbC中之一的固溶體；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材籲料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 8 8 ·如申請專利範圍第21項所述之硬金屬組合物，其中該鎳基超合金包括Re。 89·如第24項所述之硬金屬組合物，其中該鎳基超合金包括Re。 90.如第27項所述之硬金屬組合物，其中該鎳基超合 1057D-6939-PF 19 1339219 金包括Re。 91. 一種硬金屬組合物，包括：有八方禾何枓的硬子；以及具有與第一材料不同之第二 $，·0劑基質 (bmder matrix)，該第二材料係包括鎳基超合金；其中，述硬粒子係以實質均勻的方式散佈於該黏結劑基質中，1 中該鎳基超合金含有Re。 ' '、Al, Ti, Mo, Nb, W, Zr, B, C and V. 87. A hard metal composition comprising: hard particles having a first material, wherein the first material has at least one of the following: (1) wc, a solid solution of Tic and TaC' (2) WC, TiC and a solid solution of NbC, (3) WC, a solid solution of TiC and at least one of TaC and NbC, (4) a solid solution of WC, TiC and at least one of HfC and NbC; and having a first material a binder matrix different from the second material; wherein the second material is 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix comprises bismuth (Re) element Wherein the above hard particles are dispersed in the binder matrix in a substantially uniform manner. 8. The hard metal composition of claim 21, wherein the nickel-based superalloy comprises Re. The hard metal composition of item 24, wherein the nickel-based superalloy comprises Re. 90. The hard metal composition of clause 27, wherein the nickel based super 1057D-6939-PF 19 1339219 gold comprises Re. 91. A hard metal composition comprising: a hardened one having a square; and a second $bmder matrix different from the first material, the second material comprising a nickel based superalloy Wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner, and the nickel-based superalloy contains Re. ' ',

92. -種硬金屬組合物’包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金；其中=上述硬粒子係以貫質均勻的方式散佈於該黏結劑基質中，其中該錄基超合金在γ-γ’相中。 93. —種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金係主要包括鎳以及其他元素’上述其他元素包括c〇，Cr, Al，Ti，Mo，Nb W，Zr 與 Re。 94. 如第17項所述之硬金屬組合物，其中該第一材料包括一蝴化物。 95. 如第94項所述之硬金屬組合物，其中該硼化物為 TiB2, ZrB2, HfB2 ' TaB2 ' VB2 ' M〇B2 ' WB 及 W2B 其中之一0 96. 如第17項所述之硬金屬組合物，其中該第一材料包括一珍化物。 97. 如第96項所述之硬金屬組合物，其中該矽化物為 1057D-6939-PF 20 133921992. A hard metal composition 'comprising: a hard particle having a first material; and a binder matrix having a second material different from the first material, the second material comprising a nickel-based superalloy Wherein = the above hard particles are dispersed in the binder matrix in a uniform manner, wherein the recording superalloy is in the γ-γ' phase. 93. A hard metal composition comprising: hard particles having a first material; and a binder matrix having a second material different from the first material, the second material comprising a nickel-based superalloy The system mainly includes nickel and other elements. 'The other elements mentioned above include c〇, Cr, Al, Ti, Mo, Nb W, Zr and Re. 94. The hard metal composition of clause 17, wherein the first material comprises a blister. 95. The hard metal composition according to item 94, wherein the boride is TiB2, ZrB2, HfB2 'TaB2 'VB2 'M〇B2 'WB and W2B one of them 0 96. Hard as described in item 17 a metal composition wherein the first material comprises a mineral. 97. The hard metal composition of clause 96, wherein the telluride is 1057D-6939-PF 20 1339219

TaSi2、Wsi2、NbSi2 及 MoSi2 其中之一。 98. 如第17項所述之硬金屬組合物，其中該第一材料包括一碳化物。 99. 如第98項所述之硬金屬組合物，其中該碳化物為 TiC, ZrC, HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC 其中之一。 100. 如第17項所述之硬金屬組合物，其中該第一材料更進一步包括一 II化物。 • 101.如第100項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 102. 如第100項所述之硬金屬組合物，其中第一材料更進一步包括一碳化物。 103. 如第102項所述之硬金屬組合物、其中碳化物包One of TaSi2, Wsi2, NbSi2 and MoSi2. 98. The hard metal composition of clause 17, wherein the first material comprises a carbide. 99. The hard metal composition according to item 98, wherein the carbide is one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and WC. The hard metal composition of item 17, wherein the first material further comprises an II compound. The hard metal composition according to item 100, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN and TaN. The hard metal composition of item 100, wherein the first material further comprises a carbide. 103. The hard metal composition of item 102, wherein the carbide package

括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 104. 如第102項所述之硬金屬組合物、其中氮化物包 # 括至少 TiN、ZrN、HfN、VN、NbN 及 TaN 其中之一 105. 如第18項所述之硬金屬組合物，其中該第一材料包括一棚化物。 106. 如第105項所述之硬金屬組合物，其中硼化物包括 TiB2、ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一 107. 如第18項所述之硬金屬組合物，其中該第一材料包括一碎化物。 1057D-6939-PF 21 1339219 108.如第107項所述之硬金屬組合物，其中該石夕化物為 TaSi2、Wsi2、NbSi2 及 MoSi2 其中之一 109·如第18項所述之硬金屬組合物，其中該第一材料包括一碳化物。 110. 如第109項所述之硬金屬組合物，其中該碳化物包括 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC其中之一 111. 如第18項所述之硬金屬組合物，其中該第一材 # 料包括一氮化物。 112. 如第111項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 113. 如第111項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 114. 如第113項所述之硬金屬組合物，其中該碳化物Including at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and we. The hard metal composition according to the item 102, wherein the nitride package comprises at least one of TiN, ZrN, HfN, VN, NbN and TaN. The hard metal composition according to Item 18, wherein The first material includes a shed. The hard metal composition according to item 105, wherein the boride comprises one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB and W2B. 107. The hard metal composition according to item 18, Wherein the first material comprises a fragment. The hard metal composition according to the item 107, wherein the alumite is one of TaSi2, Wsi2, NbSi2 and MoSi2. 109. The hard metal composition according to item 18. Wherein the first material comprises a carbide. 110. The hard metal composition according to item 109, wherein the carbide comprises one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and WC. 111. The hard metal according to item 18. a composition wherein the first material comprises a nitride. The hard metal composition according to item 111, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN and TaN. 113. The hard metal composition of clause 111, wherein the first material further comprises a carbide. 114. The hard metal composition of item 113, wherein the carbide

包括至少 TiC、ZrC、HfC、VC、NbC、TaC ' Cr2C3、Mo2C 及 WC其中之一。 • Π5.如第113項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 116. 如第19項所述之硬金屬組合物，其中該第一材料包括一碳化物。It includes at least one of TiC, ZrC, HfC, VC, NbC, TaC 'Cr2C3, Mo2C and WC. The hard metal composition according to item 113, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN and TaN. 116. The hard metal composition of clause 19, wherein the first material comprises a carbide.

117. 如第116項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC其中之一。 118•如第19項所述之硬金屬組合物，其中該第一材 1057D-6939-PF 22 339219 •j* * 料包括一棚化物。 1 1 9.如第1 1 8項所述之硬金屬組合物，其中該蝴化物為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一 e 120.如第19項所述之硬金屬組合物，其中該第一材料包括一 *夕化物。 121•如第120項所述之硬金屬組合物，其中該矽化物為 TaSi、Wsi2、NbSi2 及 MoSi2 其中之一。 • 122.如第19項所述之硬金屬組合物，其中該第一材料包括一氮化物。 123•如第122項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 I24·如第122項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 125. 如第124項所述之硬金屬組合物，其中該碳化物117. The hard metal composition of item 116, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 118. The hard metal composition of clause 19, wherein the first material 1057D-6939-PF 22 339219 •j** comprises a shed. The hard metal composition according to item 1 18, wherein the compound is one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB and W2B e 120. a hard metal composition, wherein the first material comprises an oxime compound. The hard metal composition according to item 120, wherein the telluride is one of TaSi, Wsi2, NbSi2 and MoSi2. The hard metal composition of item 19, wherein the first material comprises a nitride. 123. The hard metal composition of clause 122, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. The hard metal composition of item 122, wherein the first material further comprises a carbide. 125. The hard metal composition of item 124, wherein the carbide

包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C •及we其中之一。 126. 如第125項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之_。 127. 如第20項所述之硬金屬組合物，其中該第一材料包括一棚化物。 128. 如第127項所述之硬金屬組合物，其中該侧化物為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 w B 其中之一。 1057D-6939-PF 23 129. 如第20項所述之硬金屬組合物，其中該第一材料包括一 $夕化物。 130. 如第129項所述之硬金屬組合物，其中該矽化物為 TaSi、\Vsi2、NbSi2 及 MoSi2 其中之一。 131. 如第20項所述之硬金屬組合物，其中該第一材料包括一碳化物。 ]32.如第131項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 133. 如第20項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 134. 如第133項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 135. 如第133項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 136. 如第135項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及wc其中之一。 137. 如第135項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 138. 如第21項所述之硬金屬組合物，其中該第一材料包括一碳化物。It includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and we. 126. The hard metal composition of item 125, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 127. The hard metal composition of clause 20, wherein the first material comprises a shed. The hard metal composition according to item 127, wherein the side compound is one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB and wB. 129. The hard metal composition of item 20, wherein the first material comprises an oxime compound. 130. The hard metal composition of item 129, wherein the telluride is one of TaSi, \Vsi2, NbSi2, and MoSi2. The hard metal composition of item 20, wherein the first material comprises a carbide. The hard metal composition according to item 131, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and WC. 133. The hard metal composition of clause 20, wherein the first material further comprises a nitride. 134. The hard metal composition of clause 133, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 135. The hard metal composition of clause 133, wherein the first material further comprises a carbide. 136. The hard metal composition of clause 135, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and wc. 137. The hard metal composition of clause 135, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 138. The hard metal composition of clause 21, wherein the first material comprises a carbide.

139. 如第138項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 1057D-6939-PF 24 及 wc其中之一。 140. 如第21項所述之硬金屬組合物，其中該第一材料包括一棚化物。 141. 如第140項所述之硬金屬組合物，其中該硼化物為 ΉΒ2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 w2B 其中之一。 142. 如第21項所述之硬金屬組合物，其中該第一材料包括一矽化物。 143. 如第142項所述之硬金屬組合物，其中該石夕化物為 TaSi、Wsi2、NbSi2 及 MoSi2 其中之一。 144. 如第21項所述之硬金屬組合物，其中該第一材料包括一氮化物。 145. 如第144項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 146. 如第144項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 147. 如第146項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、M〇2C 及WC其中之一。 148. 如第147項所述之硬金屬組合物，其中該氣化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 149. 如第22項所述之硬金屬組合物，其中該第一材料包括一硼化物。 150. 如第127項所述之硬金屬組合物，其中該蝴化物 25139. The hard metal composition of clause 138, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C 1057D-6939-PF 24 and wc. 140. The hard metal composition of clause 21, wherein the first material comprises a shed. 141. The hard metal composition of item 140, wherein the boride is one of ΉΒ2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and w2B. 142. The hard metal composition of clause 21, wherein the first material comprises a telluride. 143. The hard metal composition of item 142, wherein the cerium compound is one of TaSi, Wsi2, NbSi2, and MoSi2. 144. The hard metal composition of clause 21, wherein the first material comprises a nitride. 145. The hard metal composition of clause 144, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 146. The hard metal composition of clause 144, wherein the first material further comprises a carbide. 147. The hard metal composition of clause 146, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, M〇2C, and WC. 148. The hard metal composition of clause 147, wherein the vapor comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 149. The hard metal composition of clause 22, wherein the first material comprises a boride. 150. The hard metal composition of item 127, wherein the wafer 25

1057D-6939-PF 為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一。 151. 如第22項所述之硬金屬組合物，其中該第一材料包括一石夕化物。 152. 如第151項所述之硬金屬組合物，其中該矽化物為 TaSi ' Wsi2、NbSi2 及 MoSi2 其中之一。 153. 如第22項所述之硬金屬組合物’其中該第一材料包括一碳化物。 154. 如第153項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 155. 如第20項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 156. 如第155項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 157. 如第155項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 158. 如第157項所述之硬金屬組合物，其中該碳化物1057D-6939-PF is one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB and W2B. 151. The hard metal composition of clause 22, wherein the first material comprises a lithium compound. 152. The hard metal composition of item 151, wherein the telluride is one of TaSi 'Wsi2, NbSi2, and MoSi2. 153. The hard metal composition of item 22, wherein the first material comprises a carbide. 154. The hard metal composition of clause 153, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 155. The hard metal composition of clause 20, wherein the first material further comprises a nitride. 156. The hard metal composition of clause 155, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 157. The hard metal composition of clause 155, wherein the first material further comprises a carbide. 158. The hard metal composition of item 157, wherein the carbide

包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 159. 如第l57項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 1 60.如第24項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 1057D-6939-PF 26 1339219 ， 161.如第160項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 162·如第24項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Co。 1 63.如第24項所述之硬金屬組合物，其中Re約佔誃硬金屬組合物總重量的K5%至24·4% '該鎳基超合金約佔該硬金屬組合物總重量的0.86%至4.88%以及其中包括 TiC的第一材料約佔該硬金屬組合物總重量的^^至147 • %、含TaC的該第一材料約佔該硬金屬組合物總重量的3 %至0‘2%而含WC的該第一材料所佔該硬金屬組合物绝重量百分比約高於64%約低於88%。 164.如第23項所述之硬金屬組合物，其中該黏結劑基質更進一步包括一鎳基超合金。 1 65.如第1 64項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Co。 166. 如第27項所述之硬金屬組合物，其中該點結劑 φ 基質更進一步包括Co。 167. 如第27項所述之硬金屬組合物，其中Re約佔該硬金屬組合物總重量的8.8%至23.8%、鎳基超合金約佔該硬金屬組合物總重量的3%至10.3%，且其中M〇2c約佔該硬金屬組合物總重量的13_8%至15.2%，而TiC約佔該硬金屬組合物總重量的59.4%至65.7%。 168. 如第47項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 1057D-6939-PF 27 1339219 169.如第168項所述之硬金屬組合物，其中該碳化物It includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and we. 159. The hard metal composition of item 157, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. The hard metal composition of item 24, wherein the first material further comprises a nitride. 161. The hard metal composition of item 160, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 162. The hard metal composition of clause 24, wherein the binder matrix further comprises Co. The hard metal composition of claim 24, wherein Re is from about K5% to 24.4% by weight based on the total weight of the hard metal composition. The nickel-based superalloy accounts for about the total weight of the hard metal composition. 0.86% to 4.88% and the first material including TiC thereof accounts for about 147% of the total weight of the hard metal composition, and the first material containing TaC accounts for about 3% of the total weight of the hard metal composition. 0'2% and the first material containing WC accounts for an absolute weight percentage of the hard metal composition of more than about 64% and less than about 88%. 164. The hard metal composition of clause 23, wherein the binder matrix further comprises a nickel based superalloy. The hard metal composition of item 1, wherein the binder matrix further comprises Co. 166. The hard metal composition of item 27, wherein the point φ matrix further comprises Co. 167. The hard metal composition of item 27, wherein Re comprises from about 8.8% to 23.8% by weight of the total of the hard metal composition, and the nickel-based superalloy comprises from about 3% to 10.3 of the total weight of the hard metal composition. %, and wherein M 〇 2c accounts for about 13-8% to 15.2% of the total weight of the hard metal composition, and TiC accounts for about 59.4% to 65.7% of the total weight of the hard metal composition. 168. The hard metal composition of clause 47, wherein the first material further comprises a carbide. 169. The hard metal composition of item 168, wherein the carbide

包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2c3、m〇2C 及Wc其中之^一。 170，如第168項所述之硬金屬組合物，其中該氣化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 171. 如第49項所述之硬金屬組合物，其中該其他元素包括 Cr、Co、Fe、Al、Ti、Mo、W、Nb、Ta、Hf、Zr、B、 C 及 Re。 172. 如第51項所述之硬金屬組合物，其中該第一材料包括一碳化物。 173. 如第172項所述之硬金屬組合物，其中該第一材料更進—步包括一氮化物。 174·.如第50項所述之硬金屬組合物，其中該其他元素更進一步包括Fe、Ti、Hf、C及Re。 175.如第51項所述之硬金屬組合物，其中該第一材料包括一氮化物。 1 76.如第55項所述之硬金屬組合物，其中Re約佔該硬金屬組合物總重量的0.4%至1.8%、該鎳基超合金約佔該硬金屬組合物總重量的2.7%至4·5%、Co約佔該硬金屬紐·合物總重量的3%至4.8% ’以及其中含WC的該第一材料約佔該硬金屬組合物總重量的90.4%至9 1.5 %而VC約佔該硬金屬組合物總重量的0.3%至0.6%。 177.如第55項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 1057D-6939-PF 28 1339219 17 8.如第55項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 179. 如第56項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 180. 如第179項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物 181. 如第56項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 182. 如第5項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 183. 如第182項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 184. 如第57項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 185. 如第58項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 18 6.如第185項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 18 7.如第58項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 188. 如第59項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 189. 如第188項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 1057D-6939-PF 29 1339219 « * 190.如第59項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 191. 如第60項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 192. 如第191項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 193. 如第60項所述之硬金屬組合物，其中該第—材料更進一步包括一碳化物。 % 194.如第75項所述之硬金屬組合物，其中該第—材料包括一碳化物。 195·如第194項所述之硬金屬組合物，其中該碳化物It includes at least TiC, ZrC, HfC, VC, NbC, TaC, Cr2c3, m〇2C and Wc. 170. The hard metal composition of clause 168, wherein the vapor comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 171. The hard metal composition of clause 49, wherein the other elements comprise Cr, Co, Fe, Al, Ti, Mo, W, Nb, Ta, Hf, Zr, B, C, and Re. 172. The hard metal composition of clause 51, wherein the first material comprises a carbide. 173. The hard metal composition of clause 172, wherein the first material further comprises a nitride. The hard metal composition according to item 50, wherein the other element further comprises Fe, Ti, Hf, C and Re. 175. The hard metal composition of clause 51, wherein the first material comprises a nitride. The hard metal composition of item 55, wherein Re is from about 0.4% to 1.8% by weight based on the total weight of the hard metal composition, and the nickel-based superalloy comprises about 2.7% of the total weight of the hard metal composition. Up to 4.5%, Co accounts for about 3% to 4.8% of the total weight of the hard metal ruthenium and the first material containing WC thereof accounts for about 90.4% to 9.15% of the total weight of the hard metal composition. And VC accounts for about 0.3% to 0.6% of the total weight of the hard metal composition. 177. The hard metal composition of clause 55, wherein the first material further comprises a nitride. 8. The hard metal composition of item 55, wherein the first material further comprises a carbide. 179. The hard metal composition of clause 56, wherein the first material further comprises a nitride. 180. The hard metal composition of claim 179, wherein the first material further comprises a carbide 181. The hard metal composition of item 56, wherein the first material further comprises a carbide . 182. The hard metal composition of item 5, wherein the first material further comprises a nitride. 183. The hard metal composition of clause 182, wherein the first material further comprises a carbide. 184. The hard metal composition of clause 57, wherein the first material further comprises a carbide. 185. The hard metal composition of clause 58, wherein the first material further comprises a nitride. The hard metal composition of item 185, wherein the first material further comprises a carbide. The hard metal composition of item 58, wherein the first material further comprises a carbide. 188. The hard metal composition of clause 59, wherein the first material further comprises a nitride. 189. The hard metal composition of clause 188, wherein the first material further comprises a carbide. The hard metal composition of item 59, wherein the first material further comprises a carbide. 191. The hard metal composition of clause 60, wherein the first material further comprises a nitride. 192. The hard metal composition of clause 191, wherein the first material further comprises a carbide. 193. The hard metal composition of clause 60, wherein the first material further comprises a carbide. The hard metal composition of item 75, wherein the first material comprises a carbide. 195. The hard metal composition of item 194, wherein the carbide

包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 196.如第75項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 197•如第196項所述之硬金屬組合物，其中該氮化物 Φ 包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 198.如第196項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 199•如第198項所述之硬金屬組合物，其中該第一材料包括WC、TiC、TaC以及Mo2C。 200.如第198項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 1057D-6939-PF 30 ⑧ 1339219 201. 如第198項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 202. 如第75項所述之硬金屬組合物，其中該第一材料更進一步包括一棚化物。 203. 如第202項所述之硬金屬組合物，其中該第一材料至少包括 TiBj，ZrB:、HfB2、TaB2、VB2、M0B2、WB 及 W2B其中之一。 204. 如第75項所述之硬金屬組合物，其中該第一材 φ 料更進一步包括至少一硼化物及至少一碳化物。 205. 如第2〇4項所述之硬金屬組合物，其中該第一材料包括 WC、TiC、TaC 及 B4C。 206. 如第75項所述之硬金屬組合物，其中該第一材料包括一石夕化物。 207.如第75項所述之硬金屬組合物，其中該石夕化物為 TaSi2、WSi2、NbSi2 及 MoSi2 其中之—。 2〇8.如第75項所述之硬金屬組合物，1 士丹甲Re約佔該硬金屬組合物總重量的9.04%至9.32%、# μ w 琢錦基超合金約佔該硬金屬組合物總重量的3.53%至3 640/ 4 ’以及其中含 W C的該第一材料約佔該硬金屬組合物蝻舌θ 、心更®的67,24%至 6 9.4 0 %、T i C約佔該硬金屬組合物總重鲁从 μ 的 6·35% 至 6.55 %、TaC約佔該硬金屬組合物總重量的6 /至 6,44%、It includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and WC. 196. The hard metal composition of clause 75, wherein the first material further comprises a nitride. 197. The hard metal composition of clause 196, wherein the nitride Φ comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 198. The hard metal composition of clause 196, wherein the first material further comprises a carbide. 199. The hard metal composition of clause 198, wherein the first material comprises WC, TiC, TaC, and Mo2C. 200. The hard metal composition of clause 198, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. The hard metal composition of claim 198, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. The hard metal composition of item 75, wherein the first material further comprises a shed. 203. The hard metal composition of clause 202, wherein the first material comprises at least one of TiBj, ZrB:, HfB2, TaB2, VB2, M0B2, WB, and W2B. 204. The hard metal composition of clause 75, wherein the first material further comprises at least one boride and at least one carbide. 205. The hard metal composition of clause 2, wherein the first material comprises WC, TiC, TaC, and B4C. 206. The hard metal composition of clause 75, wherein the first material comprises a lithium compound. 207. The hard metal composition of clause 75, wherein the alumite is TaSi2, WSi2, NbSi2, and MoSi2. 2〇8. The hard metal composition according to item 75, wherein the amount of the striation of the hard metal composition is from 9.04% to 9.32%, and the #μw 琢基超 superalloy accounts for the hard metal. The total weight of the composition is from 3.53% to 3 640 / 4 ' and the first material containing WC therein accounts for about 67, 24% to 6 9.4 0% of the hard metal composition tongue θ, Xingen®, T i C The total weight of the hard metal composition is from 6.35% to 6.55% of μ, and TaC is about 6/6,44% of the total weight of the hard metal composition.

TiB2約佔該硬金屬組合物總重量的〇4〇yTiB2 accounts for about 〇4〇y of the total weight of the hard metal composition

至 7.399^^0 R C 約佔該硬金屬組合物總重量的〇·22%至4 ) ° 4 * Z 5 % 〇 2〇9.如第75項所述之硬金屬組合物，其中Re約佔該To 7.399^^0 RC, which accounts for about 22% to 4% of the total weight of the hard metal composition. 4 * Z 5 % 〇2〇9. The hard metal composition according to item 75, wherein Re accounts for The

1057D-6939-PF 31 ⑧ 1339219 硬金屬組合物總重量的8.96%至9.37%、該鎳基超合金約佔該硬金屬組合物總重量的3.50%至3.66%，以及其中含 WC的該第一材料約佔該硬金屬組合物總重量的58.61%至 66.67%、TiC約佔該硬金屬組合物總重量的14.69%至 15.3 7%、TaC約佔該硬金屬組合物總重量的6.19%至6.47 %而M02C約佔該硬金屬組合物總重量的〇%至6.1 5 %。 2 1 0.如第7 5項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Ni。瞻 2 1 1.如第75項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Fe。 2 1 2.如第7 5項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Mo。 2 1 3 .如第7 5項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Cr。 214. 如第83項所述之硬金屬組合物，其中該錄基超合金係主要包括鎳以及其他元素，上述其他元素包括Co, φ Cr，Al，Ti，Mo, Nb，W，Zr 與 Re。 215. 如第91項所述之硬金屬組合物，其中該第一材料包括一碳化物。 216. 如第215項所述之硬金屬組合物，其中該碳化物包括至少丁iC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 217·如第91項所述之硬金屬組合物，其中該第一材料更進一步包括一氣化物。 1057D-6939-PF 32 ⑧ 1339219 218. 如第217項所述之硬金屬組合物，其中該氮化物包括至少ΉΝ、ZrN、HfN、VN、NbN及 TaN其中之一。 219. 如第217項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 220. 如第219項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及Wc其中之一。 221. 如第91項所述之硬金屬組合物，其中該第一材料更進一步包括一棚化物。 222. 如第221項所述之硬金屬組合物，其中該第一材料至少包括 TiB2, ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 w2b其中之一。 223·如第91項所述之硬金屬組合物，其中該第一材料更進一步包括至少一硼化物及至少一碳化物。 224.如第223項所述之硬金屬組合物，其中該第一材料包括WC、TiC、TaC以及Mo2C。 _ 225.如第91項所述之硬金屬組合物，其中該第一材料包括矽化物。 226.如第225項所述之硬金屬組合物，其中該石夕化物至少包括TaSi2、WSi2、NbSi2及MoSi2其中之一。 22 7.如第9 1項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Ni。 2 2 8.如第91項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Fe。 1057D-6939-PF 33 ⑧ 1339219 229.如第91項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Mo。 23 0.如第91項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Cr。 231.如第92項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 23 2.如第231項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C φ 及wc其中之一。 233·如第92項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 234.如第233項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 23 5.如第233項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 23 6.如第235項所述之硬金屬組合物，其中該碳化物 # 包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 237.如第235項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 23 8.如第92項所述之硬金屬組合物，其中該第一材料更進一步包括一硼化物。 239.如第238項所述之硬金屬組合物，其中該第一材料包括至少 TiB2, ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 1057D-6939-PF 34 1339219 • 4 W2B其中之一。 240·如第92項所述之硬金屬組合物，其中該第一材料包括一碎化物。 241. 如第92項所述之硬金屬組合物，其中該第一材料包括至少TaSi、Wsi2、NbSi2及M〇Si2其中之一。 242. 如第92項所述之硬金屬組合物，其中該第二材料更進一步包括至少Re、Ni、Co、Fe、Mo及Cr其中之一。 2斗3 ·如第92項所述之硬金屬組合物，其中該第二材 φ 料更進一步包括至少另一種不同的鎳基超合金。 244.如第92項所述之硬金屬組合物，其中含WC的該第一材料約佔該硬金屬組合物總重量的9 1.9%至92.5 %、VC約佔該硬金屬組合物總重量的0.3%至0.6%，以及其中該錄基超合金約佔該硬金屬組合物總重量的7.2 %至 7.5%。 245·如第92項所述之硬金屬組合物，其中含丁丨匚及 M〇2C的該第一材料分別約佔該硬金屬組合物總重量的鲁69.44%及1 6.09% ’以及其中該鎳基超合金約佔該硬金屬組合物總重量的7.2%至7.5%。 246. 如第93項所述之硬金屬組合物，其中該第一材料包括一碳化物。 247. 如第246項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及wc其中之一。 248. 如第93項所述之硬金屬組合物，其中該第一材 1057D-6939-PF 35 1339219 料包括一氮化物。 249.如第248項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 250·如第249項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 251.如第250項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 • 252·如第25〇項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 25 3.如第93項所述之硬金屬組合物，其中該第一材料更進一步包括一硼化物。 254. 如第253項所述之硬金屬組合物，其中該第一材料包括至少 TiB2, ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B其中之一。 255. 如第93項所述之硬金屬組合物，其中該第一材 Φ料更進一步包括一矽化物。 256. 如第93項所述之硬金屬組合物，其中該第一材料包括至少TaSi、Wsi2、NbSi2及MoSi2其中之一。 2 5 7.如第93項所述之硬金屬組合物’其中該第二材料更進一步包括至少Re、N卜Co、Fe、Mo及Cr其中之一。 25 8.如第93項所述之硬金屬組合物，其中該第二材料更進一步包括至少另一種不同的鎮基超合金。 2 5 9.如第93項所述之硬金屬組合物，其中該鎳基超 1057D-6939-PF 36 1339219 合金的其他元素更進一步包括卜、^、^、B及c。1057D-6939-PF 31 8 1339219 8.96% to 9.37% of the total weight of the hard metal composition, the nickel-based superalloy accounts for about 3.50% to 3.66% of the total weight of the hard metal composition, and the first of which contains WC The material accounts for 58.61% to 66.67% of the total weight of the hard metal composition, TiC accounts for 14.69% to 15.37% of the total weight of the hard metal composition, and TaC accounts for about 6.19% to 6.47 of the total weight of the hard metal composition. % and M02C accounts for about 〇5% of the total weight of the hard metal composition to 6.15%. The hard metal composition of item 7, wherein the binder matrix further comprises Ni. The hard metal composition of item 75, wherein the binder matrix further comprises Fe. 2. The hard metal composition of item 7, wherein the binder matrix further comprises Mo. The hard metal composition of item 7, wherein the binder matrix further comprises Cr. 214. The hard metal composition according to item 83, wherein the base superalloy system mainly comprises nickel and other elements, and the other elements include Co, φ Cr, Al, Ti, Mo, Nb, W, Zr and Re . 215. The hard metal composition of clause 91, wherein the first material comprises a carbide. 216. The hard metal composition of clause 215, wherein the carbide comprises at least one of butyl iC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. The hard metal composition of item 91, wherein the first material further comprises a vapor. 218. The hard metal composition of item 217, wherein the nitride comprises at least one of lanthanum, ZrN, HfN, VN, NbN, and TaN. 219. The hard metal composition of clause 217, wherein the first material further comprises a carbide. The hard metal composition according to item 219, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and Wc. 221. The hard metal composition of item 91, wherein the first material further comprises a shed. 222. The hard metal composition of clause 221, wherein the first material comprises at least one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and w2b. The hard metal composition of item 91, wherein the first material further comprises at least one boride and at least one carbide. 224. The hard metal composition of clause 223, wherein the first material comprises WC, TiC, TaC, and Mo2C. The hard metal composition of item 91, wherein the first material comprises a telluride. 226. The hard metal composition of clause 225, wherein the alexandry comprises at least one of TaSi2, WSi2, NbSi2, and MoSi2. The hard metal composition of item 9, wherein the binder matrix further comprises Ni. The hard metal composition of item 91, wherein the binder matrix further comprises Fe. 229. The hard metal composition of item 91, wherein the binder matrix further comprises Mo. The hard metal composition of item 91, wherein the binder matrix further comprises Cr. 231. The hard metal composition of clause 92, wherein the first material further comprises a carbide. The hard metal composition according to item 231, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C φ and wc. 233. The hard metal composition of clause 92, wherein the first material further comprises a nitride. 234. The hard metal composition of clause 233, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. The hard metal composition of item 233, wherein the first material further comprises a carbide. The hard metal composition according to item 235, wherein the carbide # comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and WC. 237. The hard metal composition of clause 235, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. The hard metal composition of item 92, wherein the first material further comprises a boride. 239. The hard metal composition of clause 238, wherein the first material comprises at least one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and 1057D-6939-PF 34 1339219 • 4 W2B. The hard metal composition of item 92, wherein the first material comprises a fragment. 241. The hard metal composition of clause 92, wherein the first material comprises at least one of TaSi, Wsi2, NbSi2, and M〇Si2. 242. The hard metal composition of clause 92, wherein the second material further comprises at least one of Re, Ni, Co, Fe, Mo, and Cr. The hard metal composition of item 92, wherein the second material further comprises at least one other different nickel-based superalloy. The hard metal composition according to item 92, wherein the first material containing WC accounts for about 9.9% to 92.5% of the total weight of the hard metal composition, and VC accounts for about the total weight of the hard metal composition. 0.3% to 0.6%, and wherein the recording base superalloy accounts for about 7.2% to 7.5% of the total weight of the hard metal composition. 245. The hard metal composition of item 92, wherein the first material comprising butyl sulfonium and M 〇 2C respectively comprises about 69.44% and 16.09% of the total weight of the hard metal composition, and wherein The nickel-based superalloy accounts for about 7.2% to 7.5% of the total weight of the hard metal composition. 246. The hard metal composition of clause 93, wherein the first material comprises a carbide. 247. The hard metal composition of clause 246, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and wc. 248. The hard metal composition of clause 93, wherein the first material 1057D-6939-PF 35 1339219 comprises a nitride. 249. The hard metal composition of clause 248, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. The hard metal composition of item 249, wherein the first material further comprises a carbide. 251. The hard metal composition of clause 250, wherein the carbide comprises at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. The hard metal composition of item 25, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN and TaN. The hard metal composition of item 93, wherein the first material further comprises a boride. 254. The hard metal composition of clause 253, wherein the first material comprises at least one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B. 255. The hard metal composition of clause 93, wherein the first material further comprises a telluride. 256. The hard metal composition of clause 93, wherein the first material comprises at least one of TaSi, Wsi2, NbSi2, and MoSi2. The hard metal composition as described in item 93, wherein the second material further comprises at least one of Re, N, Co, Fe, Mo and Cr. The hard metal composition of item 93, wherein the second material further comprises at least one other different town-based superalloy. The hard metal composition according to item 93, wherein the other elements of the nickel-based super 1057D-6939-PF 36 1339219 alloy further include Bu, ^, ^, B and c.

260. —種硬金屬組合物的製造方法包括：預備一金屬表面，接著進行-熱喷塗製程將—層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子; 以及具有與第一材料不同之第：材料之一黏结劑基質 (binder matrix);其中’該第二材料係佔該硬金屬組合物總體積的3〜40%;其中，該黏結劑基質包括銖（Re)元素且銖元素係佔該硬金屬組合物總重量的25%以上；其中上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 261_ —種硬金屬組合物的製造方法，包括：預備一金屬表面，接著進行一熱噴塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子，其中該第一材料具有至少一下列混合物：（丨）wc，丁丨[與 TaC的混合物，（2)wc，Tic與Nbc的混合物，（3)wc，Tic 與至少TaC與NbC中之一的混合物，（4)WC, TiC與至少 HfC與NbC中之一的混合物；以及具有與第—材料不同之第一材料之一黏結劑基質（binder matrix);其中，該第_材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏纟士劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 262.—種硬金屬組合物的製造方法，包括：預備一金屬表面，接著進行一熱喷塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子具有M〇2C及TiC的混和物；以及具有與第—材料不同之260. A method of making a hard metal composition comprising: preparing a metal surface, followed by a thermal spray process to coat a hard metal layer on a metal surface, wherein the hard metal layer comprises: having a first material a hard particle; and a binder matrix having a material different from the first material; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder The matrix comprises a bismuth (Re) element and the lanthanum element is more than 25% by weight of the total of the hard metal composition; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 261_ A method for producing a hard metal composition, comprising: preparing a metal surface, and then performing a thermal spraying process to coat a layer of a hard metal on the metal surface, wherein the hard metal layer comprises: hard particles having the first material Wherein the first material has at least one of the following: (丨) wc, butadiene [mixture with TaC, (2) wc, a mixture of Tic and Nbc, (3) wc, Tic and at least one of TaC and NbC a mixture of (4) WC, TiC and at least one of HfC and NbC; and a binder matrix having a first material different from the first material; wherein the first material is The total volume of the hard metal composition is from 3 to 4% by weight; wherein the binder base comprises a bismuth (Re) element; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 262. A method of making a hard metal composition comprising: preparing a metal surface, followed by performing a thermal spray process to coat a layer of hard metal on the metal surface, wherein the hard metal layer comprises: having a first material Hard particles have a mixture of M〇2C and TiC; and have a different texture than the first material

1057D-6939-PF 37 1339219 第二材料之一黏結劑基質（binder· matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 263· —種硬金屬組合物的製造方法，包括：預備一金屬表面’接著進行一熱噴塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 • (binder matrix) ’該第二材料係包括一鎳基超合金；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 264. —種硬金屬組合物的製造方法，包括：預備一金屬表面’接著進行一熱喷塗製程將一層硬金屬層塗佈在金屬表面上’其中該硬金屬層包括：具有第一材料的硬粒子包括’其中該第一材料具有TiC與TiN ;以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix)，該第二材料係包括至少Ni，Mo與Mo2C之一；其中，上述硬粒籲子係以實質均勻的方式散佈於該黏結劑基質中。 265· —種硬金屬組合物的製造方法，包括：預備一金屬表面，接著進行一熱噴塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子包括’其中該第一材料具有至少一下列混合物：（1)WC，TiC 與TaC的混合物’（2)WC，TiC與NbC的混合物，（3)WC, TiC 與至少TaC與NbC中之一的混合物，（4)WC，TiC與至少 HfC與NbC中之一的混合物；以及具有與第一材料不同之1057D-6939-PF 37 1339219 A binder matrix of a second material; wherein the second material accounts for 3 to 4% by weight of the total volume of the hard metal composition; wherein the binder matrix comprises a bismuth (Re) element; wherein the above hard particles are dispersed in the binder matrix in a substantially uniform manner. 263. A method for producing a hard metal composition, comprising: preparing a metal surface, and then performing a thermal spraying process to coat a layer of hard metal on the metal surface, wherein the hard metal layer comprises: a hard material having a first material a binder; and a binder matrix having a second material different from the first material, the second material comprising a nickel-based superalloy; wherein the hard particles are dispersed in a substantially uniform manner In the matrix of the binder. 264. A method of making a hard metal composition comprising: preparing a metal surface 'and subsequently performing a thermal spray process to coat a layer of hard metal on the metal surface' wherein the hard metal layer comprises: having a first material The hard particles include 'where the first material has TiC and TiN; and a binder matrix having a second material different from the first material, the second material comprising at least one of Ni, Mo and Mo2C; Wherein, the above-mentioned hard particles are dispersed in the binder matrix in a substantially uniform manner. 265. A method of making a hard metal composition comprising: preparing a metal surface, followed by performing a thermal spray process to coat a layer of hard metal on the metal surface, wherein the hard metal layer comprises: a hard material having a first material The particles include 'where the first material has at least one of the following: (1) WC, a mixture of TiC and TaC '(2) WC, a mixture of TiC and NbC, (3) WC, TiC and at least one of TaC and NbC a mixture of (4) WC, TiC and at least one of HfC and NbC; and having a different texture than the first material

1057D-6939-PF 38 Ϊ339219 第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該點結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。此外，本應用中第二類288項實施方法敘述如下 1· 一種硬金屬組合物包括：其中硬粒子包括至少一種碳化物’該碳化物擇自由至少WC、TiC及HfC其中之—；以及一包括Re且用來黏結硬粒子的黏結劑基質，其中該硬 • 粒子低於該硬金屬組合物總重量的75%，而Re高於該硬金屬組合物總重量的25%。 2. 如第1項所述之硬金屬組合物，其中該碳化物為 TiC且南於約該硬金屬組合物總重量的26%，而Re低於約該硬金屬組合物總重量的74%。 3. 如第1項所述之硬金屬組合物，其中該碳化物為 WC且馬於約該硬金屬組合物總重量的5 3 %，而Re低於約該硬金屬組合物總重量的47%。 _ 4.如第】項所述之硬金屬組合物，其中該碳化物為1057D-6939-PF 38 Ϊ339219 A binder matrix of a second material; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the point preparation matrix comprises ruthenium a (Re) element; wherein the above hard particles are dispersed in the binder matrix in a substantially uniform manner. In addition, the second type of 288 implementation methods in this application are described as follows: 1. A hard metal composition comprising: wherein the hard particles include at least one carbide 'the carbide is selected from at least WC, TiC and HfC - and one comprises Re and a binder matrix for bonding hard particles, wherein the hard particles are less than 75% of the total weight of the hard metal composition, and Re is higher than 25% of the total weight of the hard metal composition. 2. The hard metal composition of item 1, wherein the carbide is TiC and is about 26% of the total weight of the hard metal composition, and Re is less than about 74% of the total weight of the hard metal composition. . 3. The hard metal composition according to item 1, wherein the carbide is WC and the horse is about 53% by weight of the total of the hard metal composition, and Re is less than about 47% of the total weight of the hard metal composition. %. 4. The hard metal composition according to the item, wherein the carbide is

HfC且高於約該硬金屬組合物總重量的48%，而Re低於約該硬金屬組合物總重量的52%。 5·—種硬金屬組合物包括：包括至少一種碳化物的硬粒子’其中該碳化物擇自由元素週期表中IVb、Vb及VIb 族70素所形成的碳化物，不包括WC、TiC及HfC ;以及一黏結硬粒子的黏結劑基質包括Re，其中該硬粒子低於該硬金屬組合物總重量的75%，而Re佔該硬金屬組合物總重HfC is more than about 48% by weight based on the total weight of the hard metal composition, and Re is less than about 52% by weight based on the total weight of the hard metal composition. 5. The hard metal composition comprises: hard particles comprising at least one carbide, wherein the carbide is selected from the carbides formed by the IVb of the IVb, Vb and VIb groups of the periodic table, excluding WC, TiC and HfC. And a binder matrix of bonded hard particles comprising Re, wherein the hard particles are less than 75% of the total weight of the hard metal composition, and Re accounts for the total weight of the hard metal composition

1057D-6939-PF 39 1339219 量的4%至72%。 6.如第5項所述之硬金屬紱合物，其中該碳化物為 ZrC且高於約該硬金屬組合物總重量的32%，而低於約該硬金屬組合物總重量的6 8 %。 7·如第5項所述之硬金屬組合物，其中該碳化物為 VC且高於約該硬金屬組合物總重量的28%，而低於約该硬金屬組合物總重量的7 2 %。 8·如第5項所述之硬金屬級合物，其中該碳化物為 NbC且高於約該硬金屬組合物總重量的刊％，而低於約該硬金屬組合物總重量的64%。 9.如第5項所述之硬金屬組合物，其中該碳化物為 TaC且高於約該硬金屬組合物總重量的5ι%，而Re低於約該硬金屬組合物總重量的49%。 H).如第5項所述之硬金屬組合物，其中該碳化物為 Chq且高於約該硬金屬組合物總重量的32%，而以低於約該硬金屬組合物總重量的6 8 %。 η·如第5項所述之硬金屬組合物其中該碳化物為 M〇2C且高於約該硬金屬組合物總重昝、里量的39%，而Re低於約該硬金屬組合物總重量的6 1 %。 12· 一種硬金屬組合物包括：包括至少-種氣化物的硬粒子，其中該氮化物擇自由元素遇期表中—及…族元素所形成的氣化物；以及以及一黏結硬粒子的黏結劑基質包括Re ’其中Re約佔該硬金屬組合物總重量的々％至 72%。1057D-6939-PF 39 1339219 The amount is 4% to 72%. 6. The hard metal composition of claim 5, wherein the carbide is ZrC and is greater than about 32% by weight of the total of the hard metal composition, and less than about 6 8 of the total weight of the hard metal composition. %. The hard metal composition of item 5, wherein the carbide is VC and is greater than about 28% by weight of the total of the hard metal composition, and less than about 72% by weight of the total weight of the hard metal composition. . 8. The hard metal grade according to item 5, wherein the carbide is NbC and is higher than about the total weight of the hard metal composition, and less than about 64% of the total weight of the hard metal composition. . 9. The hard metal composition of clause 5, wherein the carbide is TaC and is greater than about 5% by weight of the total weight of the hard metal composition, and Re is less than about 49% of the total weight of the hard metal composition. . H). The hard metal composition of item 5, wherein the carbide is Chq and is greater than about 32% by weight of the total of the hard metal composition, and less than about 6 of the total weight of the hard metal composition. 8 %. The hard metal composition according to item 5, wherein the carbide is M〇2C and higher than about 39% of the total weight of the hard metal composition, and Re is less than about the hard metal composition. The total weight is 61%. 12. A hard metal composition comprising: hard particles comprising at least a vaporized material, wherein the nitride is selected from a vapor formed by an elemental period-and a group of elements; and a binder that bonds the hard particles The matrix comprises Re' wherein Re represents from about 々% to 72% of the total weight of the hard metal composition.

1057D-6939-PF 40 1339219 ^ » 13. 如第12項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的28%至89%。 14. 如第12項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的34%至92%，而Re 約佔該硬金屬組合物總重量的8%至66%。 15. 如第12項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的50%至96%，而Re 約佔該硬金屬組合物總重量的4%至50%。 H 16.如第12項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的30%至91%，而Re 約佔該硬金屬組合物總重量的9%至70%。 17. 如第12項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34%至92%，而Re 約佔該硬金屬組合物總重量的8%至66%。 18. 如第12項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的5丨％至96%，而Re 鲁約佔該硬金屬組合物總重量的4%至49%。 19. 一種硬金屬組合物包括：包括至少一種氮化物的硬粒子，其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一黏結硬粒子的黏結劑基質包括錄基超合金，其中該錄基超合金約佔該硬金屬組合物總重量的1.7%至50%。 20. 如第19項所述之硬金屬組合物，其中該氮化物為 ΤιΝ且約佔該硬金屬組合物總重量的5〇%至96%，而該鎳 41The hard metal composition according to item 12, wherein the nitride is ZrN and accounts for about 28% to 89% of the total weight of the hard metal composition. 14. The hard metal composition of item 12, wherein the nitride is ZrN and comprises from about 34% to 92% by weight of the total of the hard metal composition, and Re is about 8 parts by weight of the total weight of the hard metal composition. % to 66%. 15. The hard metal composition according to item 12, wherein the nitride is HfN and accounts for about 50% to 96% by weight of the total of the hard metal composition, and Re accounts for about 4% by weight of the total weight of the hard metal composition. % to 50%. The hard metal composition according to item 12, wherein the nitride is VN and accounts for about 30% to 91% by weight of the total of the hard metal composition, and Re accounts for about the total weight of the hard metal composition. 9% to 70%. 17. The hard metal composition of item 12, wherein the nitride is NbN and comprises from about 34% to 92% by weight based on the total weight of the hard metal composition, and Re is about 8 parts by weight of the total weight of the hard metal composition. % to 66%. 18. The hard metal composition of item 12, wherein the nitride is TaN and comprises from about 5% to about 96% by weight based on the total weight of the hard metal composition, and Re ru is about the total weight of the hard metal composition. 4% to 49%. 19. A hard metal composition comprising: hard particles comprising at least one nitride, wherein the nitride is selected from nitrides formed by elements of groups IVb and Vb of the periodic table; and a binder matrix of bonded hard particles includes A base superalloy, wherein the base superalloy comprises from about 1.7% to about 50% by weight based on the total weight of the hard metal composition. 20. The hard metal composition according to item 19, wherein the nitride is ΤιΝ and accounts for about 5% to 96% of the total weight of the hard metal composition, and the nickel 41

1057D-6939-PF 1339219 基超合金約佔該硬金屬組合物總重量的4 %直5 G % 21. 如第19項所述之硬金屬組合物’其中該氣化物為 ZrN且約佔該硬金屬組合物總重量的58%至97% ’而該鎳基超合金約佔該硬金屬組合物總重量的3%至42% ° 22, 如第19項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的72%至98.2% ’而該錄基超合金約佔該硬金屬組合物總重量的1 · 8 %至2 8 %。 23·如第19項所述之硬金屬組合物，其中該氮化物為 # VN且約佔該硬金屬組合物總重量的53%至96%，而該鎳基超合金約佔該硬金屬組合物總重量的4%至47%。 24. 如第19項所述之硬金屬組合物，其中該氤化物為 NbN且約佔該硬金屬組合物總重量的52%至97%，而該錄基超合金約佔該硬金屬組合物總重量的3 %至42%。 25. 如第19項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的73%至98.3%，而該錄基超合金約佔該硬金屬組合物總重量的1.7 %至2 7 %。鲁 26. 一種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中IVb、Vb及VIb 族元素所形成的碳化物；以及一黏結硬粒子的黏結劑基質包括Re及鎳基超合金，其中該硬粒子約佔該硬金屬組合物總重量的26.1%至98.4%。 .27.如第26項所述之硬金屬組合物，其中該破化物為 TiC且約佔該硬金屬組合物總重量的26丨％至％ 1 %，以不超過約該硬金屬組合物總重量的73.而該鎳基超合金 1057D-6939-PF 42 1339219 不超過約該硬金屬組合物總重量的5 1.1 %。 28. 如第26項所述之硬金屬組合物，其中該破化物為 ZrC且約佔該硬金屬組合物總重量的32%至96%，Re不超過約該硬金屬組合物總重量的67.7%而該鎳基超合金不超過約該硬金屬組合物總重量的44.1 %。 29. 如第26項所述之硬金屬組合物，其中該碳化物為且約佔該硬金屬組合物總重量的47.7%至98.1 %，Re 不超過約該硬金屬組合物總重量的52.1%而該鎳基超合金 # 不超過約該硬金屬組合物總重量的29.2%。 3 0.如第26項所述之硬金屬組合物，其中該碳化物為 VC且約佔該硬金屬組合物總重量的28.3%至95.6%，Re 不超過約該硬金屬組合物總重量的71.5%而該鎳基超合金不超過約該硬金屬組合物總重量的48.4%。 31.如第26項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的36%至96.9%，Re 等於或低於約該硬金屬組合物總重量的63.8%而該鎳基超鲁合金等於或低於約該硬金屬組合物總重量的3 9.9 %。 32·如第26項所述之硬金屬組合物，其中該碳化物為 TaC且約佔該硬金屬組合物總重量的51%至98.3%，Re 等於或低於約該硬金屬組合物總重量的48.8%而該鎳基超合金等於或低於約該硬金屬組合物總重量的26.5%。 33.如第26項所述之硬金屬組合物，其中該碳化物為 Cr2C3且約佔該硬金屬組合物總重量的32.4%至96.4%， Re等於或低於約該硬金屬組合物總重量的6人3%而該鎳基 1057D-6939-PF 43 1339219 η 超合金等於或低於約該硬金屬組合物總重量的43 6%。 34. 如第26項所述之硬金屬組合物，其中該碳化物為 Μοβ且約佔該硬金屬組合物總重量的39 至97 ，1057D-6939-PF 1339219 The base superalloy is about 4% by weight of the total weight of the hard metal composition. The hard metal composition as described in item 19 wherein the gasification is ZrN and accounts for the hard The total weight of the metal composition is from 58% to 97% by weight, and the nickel-based superalloy is from about 3% to 42% of the total weight of the hard metal composition, such as the hard metal composition of item 19, wherein The nitride is HfN and accounts for about 72% to 98.2% of the total weight of the hard metal composition and the base superalloy accounts for about 1.8% to 28% of the total weight of the hard metal composition. The hard metal composition according to item 19, wherein the nitride is #VN and accounts for about 53% to 96% of the total weight of the hard metal composition, and the nickel-based superalloy occupies the hard metal combination. 4% to 47% of the total weight of the object. 24. The hard metal composition of claim 19, wherein the telluride is NbN and comprises from about 52% to about 97% by weight of the total of the hard metal composition, and the base superalloy comprises about the hard metal composition. 3% to 42% of the total weight. The hard metal composition according to item 19, wherein the nitride is TaN and accounts for 73% to 98.3% of the total weight of the hard metal composition, and the recording superalloy accounts for about the hard metal composition. The total weight is between 1.7% and 27%. Lu 26. A hard metal composition comprising: hard particles comprising at least one carbide, wherein the carbide is selected from carbides formed by elements of groups IVb, Vb and VIb of the periodic table; and a binder of bonded hard particles The matrix comprises Re and a nickel-based superalloy, wherein the hard particles comprise from about 26.1% to about 98.4% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the breaking compound is TiC and accounts for about 26% to % 1% of the total weight of the hard metal composition, and not more than about the total of the hard metal composition. The weight of 73. and the nickel based superalloy 1057D-6939-PF 42 1339219 does not exceed about 5.1% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the breaking compound is ZrC and accounts for about 32% to 96% by weight of the total of the hard metal composition, and Re does not exceed about 67.7 of the total weight of the hard metal composition. % and the nickel-based superalloy does not exceed about 44.1% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the carbide is and accounts for 47.7% to 98.1% of the total weight of the hard metal composition, and Re does not exceed 52.1% of the total weight of the hard metal composition. The nickel-based superalloy # does not exceed about 29.2% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the carbide is VC and accounts for about 28.3% to 95.6% of the total weight of the hard metal composition, and Re does not exceed about the total weight of the hard metal composition. 71.5% and the nickel-based superalloy does not exceed about 48.4% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the carbide is NbC and accounts for 36% to 96.9% by weight of the total of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 63.8% of the nickel-based superalloy is equal to or lower than about 3.99% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the carbide is TaC and accounts for about 51% to 98.3% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 48.8% and the nickel based superalloy is equal to or less than about 26.5% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the carbide is Cr2C3 and accounts for about 32.4% to 96.4% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. The 6-person 3% and the nickel-based 1057D-6939-PF 43 1339219 η superalloy is equal to or lower than about 43% of the total weight of the hard metal composition. The hard metal composition according to item 26, wherein the carbide is Μοβ and accounts for 39 to 97 of the total weight of the hard metal composition.

Re等於或低於約該硬金屬組合物總重量的6〇 2%而該鎳基超合金等於或低於約該硬金屬組合物總重量的36 3%。 35. 如第26項所述之硬金屬組合物’其中該碳化物為 WC且約佔該硬金屬組合物總重量的52 至98 ，以等於或低於約該硬金屬組合物總重量的46 9%而該錄基超 • 合金等於或低於約該硬金屬組合物總重量的25%。 36. —種硬金屬組合物包括：包括至少一種氮化物的硬粒子’其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一黏結硬粒子的黏結劑基質包括Re及鎳基超合金，其中該硬粒子約佔該硬金屬組合物總重量的28%至98.3%。 37. 如第36項所述之硬金屬組合物，其中該氮化物為 TiN且約佔該硬金屬組合物總重量的28%至95.6%，Re等籲於或低於約該硬金屬組合物總重量的71·7%而該鎳基超合金等於或低於約該硬金屬組合物總重量的48.7%。 38. 如第36項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的34.5%至96.7%，Re 等於或低於約該硬金屬組合物總重量的65.3%而該鎳基超合金等於或低於約該硬金屬組合物總重量的4 1.4%。 39·如第36項所述之硬金屬組合物，其中該氤化物為 HfN且約佔該硬金屬組合物總重量的49.8%至98.2%，Re 1057D-6939-PF 44 1339219 ... « m 等於或低於約該硬金屬組合物總重量的50%而該錄基超合金等於或低於約該硬金屬組合物總重量的2 7.5 %。 40.如第36項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的30%至96%，Re等於或低於約該硬金屬組合物總重量的69.6 %而該鎳基超合金等於或低於約該硬金屬組合物總重量的46.2%。 4 1.如第3 6項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34.4%至96.7%，Re Φ 等於或低於約該硬金屬組合物總重量的65.3%而該鎳基超合金等於或低於約該硬金屬組合物總重量的41 · 5 %。 42.如第36項所述之硬金屬組合物，其中該氮化物為 TaN且約伯該硬金屬組合物總重量的$ 〇. 7 %至9 8.3 %，Re 等於或低於約該硬金屬組合物總重量的49· 1 %而該鎳基超合金等於或低於約該硬金屬組合物總重量的2 6.8 %。 43 . —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中IVb、Vb及VIb ®族元素所形成的碳化物；以及一黏結硬粒子的黏結劑基質包括Re及Co ’其中該硬粒子約佔該硬金屬組合物總重量的 26.1% 至 98,2%。 44. 如第43項所述之硬金屬組合物，其中該碳化物為 TiC且約佔該硬金屬組合物總重量的26.1 %至94.6%，Re 等於或低於約該硬金屬組合物總重量的73.6%而Co等於或低於約該硬金屬組合物總重量的54.1 %。 45. 如第43項所述之硬金屬組合物，其中該碳化物為 1057D-6939-PF 45 1339219Re is equal to or lower than about 6 〇 2% of the total weight of the hard metal composition and the nickel-based superalloy is equal to or lower than about 36 3% of the total weight of the hard metal composition. 35. The hard metal composition of item 26 wherein the carbide is WC and comprises from about 52 to 98 of the total weight of the hard metal composition, equal to or less than about 46 of the total weight of the hard metal composition. 9% and the recording super-alloy is equal to or less than about 25% of the total weight of the hard metal composition. 36. A hard metal composition comprising: hard particles comprising at least one nitride 'where the nitride is selected from nitrides formed by elements IVb and Vb of the periodic table; and a binder matrix comprising bonded hard particles comprises Re and a nickel-based superalloy, wherein the hard particles comprise from about 28% to 98.3% by weight of the total of the hard metal composition. The hard metal composition according to item 36, wherein the nitride is TiN and accounts for 28% to 95.6% of the total weight of the hard metal composition, and Re or the like is at or below about the hard metal composition. The total weight is 71.7% and the nickel based superalloy is equal to or lower than about 48.7% of the total weight of the hard metal composition. 38. The hard metal composition of item 36, wherein the nitride is ZrN and comprises from about 34.5% to 96.7% by weight of the total of the hard metal composition, and Re is equal to or less than about the total weight of the hard metal composition. 65.3% of the nickel-based superalloy is equal to or lower than about 1.4% of the total weight of the hard metal composition. The hard metal composition according to item 36, wherein the telluride is HfN and accounts for about 49.8% to 98.2% of the total weight of the hard metal composition, Re 1057D-6939-PF 44 1339219 ... « m It is equal to or lower than about 50% of the total weight of the hard metal composition and the base superalloy is equal to or lower than about 2.5% by weight of the total weight of the hard metal composition. The hard metal composition according to item 36, wherein the nitride is VN and accounts for about 30% to 96% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 69.6% and the nickel-based superalloy is equal to or lower than about 46.2% of the total weight of the hard metal composition. 4. The hard metal composition according to item 3, wherein the nitride is NbN and accounts for 34.4% to 96.7% of the total weight of the hard metal composition, and Re Φ is equal to or lower than about the hard metal combination. The total weight of the material is 65.3% and the nickel-based superalloy is equal to or lower than about 41.5% of the total weight of the hard metal composition. The hard metal composition according to item 36, wherein the nitride is TaN and is about 7. 7 % to 9 8.3 % of the total weight of the hard metal composition, and Re is equal to or lower than about the hard metal. The total weight of the composition is 49. 1% and the nickel-based superalloy is equal to or lower than about 26.8% of the total weight of the hard metal composition. 43. A hard metal composition comprising: hard particles comprising at least one carbide, wherein the carbide is selected from carbides formed by elements IVb, Vb and VIb® of the periodic table; and bonding of a bonded hard particle The agent matrix comprises Re and Co' wherein the hard particles comprise from about 26.1% to 98,2% of the total weight of the hard metal composition. The hard metal composition according to item 43, wherein the carbide is TiC and accounts for about 26.1% to 94.6% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 73.6% and Co is equal to or lower than about 54.1% of the total weight of the hard metal composition. 45. The hard metal composition of item 43, wherein the carbide is 1057D-6939-PF 45 1339219

ZrC且約佔該硬金屬組合物總重量的32%至96% ’ Re等於或低於約該硬金屬組合物總重量的67.7%而Co等於或低於約該硬金屬組合物總重量的47.1 %。 46. 如第43項所述之硬金屬組合物，其中該碳化物為 HfC且約佔該硬金屬組合物總重量的47.6%至97.8% ’ Re 等於或低於約該硬金屬組合物總重量的52.1%而Co等於或低於約該硬金屬組合物總重量的3 1.8%。 47. 如第43項所述之硬金屬組合物，其中該碳化物為 # VC且約佔該硬金屬組合物總重量的28_3%至95.1%，Re 等於或低於約該硬金屬組合物總重量的71.4%而Co等於或低於約該硬金屬組合物總重量的5 1.5 %。 48. 如第43項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的36%至96.5%，Re 等於或低於約該硬金屬組合物總重量的63.8%而Co等於或低於約該硬金屬組合物總重量的42·8%。 49. 如第43項所述之硬金屬組合物，其中該碳化物為 _ TaC且約佔該硬金屬組合物總重量的5 1 %至98% ’ Re等於或低於約該硬金屬組合物總重量的4 8,8 %而C 〇等於或低於約該硬金屬組合物總重量的28.9%。 50. 如第43項所述之硬金屬組合物，其中該碳化物為 Cr2C3且約佔該硬金屬組合物總重量的32.4%至96%，Re 等於或低於約該硬金屬組合物總重量的6 7 · 3 %而C 〇等於或低於約該硬金屬組合物總重量的46.6%。 51. 如第43項所述之硬金屬組合物，其中該碳化物為 1057D'6939-PF 46 ::339219 截 t M〇2C且約佔該硬金屬組合物總重量的39 6%至97%，等於或低於約該硬金屬組合物總重量的6〇 2%而c〇等於或低於約該硬金屬組合物總重量的39 2%。 52. 如帛43額述之硬金屬組合物，纟中該碳化物為 wc且約佔該硬金屬組合物總重量的52 9%至98 2%，心等於或低於約該硬金屬組合物總重量的46 9%而c〇等於或低於約該硬金屬組合物總重量的27.4% ^ 53. -種硬金屬組合物包括：包括至少一種氮化物的 •硬粒子，其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一包括Re及C〇且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的28%至98%。 54. 如第53項所述之硬金屬組合物，其中該氮化物為 TiN且約佔該硬金屬組合物總重量的28%至95%，Re最高至約該硬金屬組合物總重量的7 1.6%而Co最高至約該硬金屬組合物總重量的5 1.7%。 ® 55.如第53項所述之硬金屬組合物，其中該氮化物為ZrC and about 32% to 96% of the total weight of the hard metal composition 'Re is equal to or lower than about 67.7% of the total weight of the hard metal composition and Co is equal to or lower than about 47.1 of the total weight of the hard metal composition. %. The hard metal composition according to item 43, wherein the carbide is HfC and accounts for 47.6% to 97.8% of the total weight of the hard metal composition. Re is equal to or lower than about the total weight of the hard metal composition. 52.1% and Co is equal to or lower than about 3.8% of the total weight of the hard metal composition. 47. The hard metal composition of item 43, wherein the carbide is #VC and comprises from about 28% to about 95.1% by weight of the total of the hard metal composition, and Re is equal to or less than about the total of the hard metal composition. 71.4% by weight and Co is equal to or lower than about 51.5% of the total weight of the hard metal composition. The hard metal composition according to item 43, wherein the carbide is NbC and accounts for 36% to 96.5% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 63.8% and Co is equal to or lower than about 42.8% of the total weight of the hard metal composition. The hard metal composition according to item 43, wherein the carbide is _TaC and accounts for about 51% to 98% of the total weight of the hard metal composition. Re is equal to or lower than about the hard metal composition. The total weight is 48.8% and C? is equal to or lower than about 28.9% of the total weight of the hard metal composition. The hard metal composition according to item 43, wherein the carbide is Cr2C3 and accounts for about 32.4% to 96% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 6 7 · 3 % and C 〇 is equal to or lower than about 46.6% of the total weight of the hard metal composition. 51. The hard metal composition of item 43, wherein the carbide is 1057D'6939-PF 46::339219 t m〇2C and accounts for about 396% to 97% of the total weight of the hard metal composition. , equal to or lower than about 6 2 % of the total weight of the hard metal composition and c 〇 equal to or lower than about 39 2% of the total weight of the hard metal composition. 52. The hard metal composition as described in 帛43, wherein the carbide is wc and accounts for 529% to 98 2% of the total weight of the hard metal composition, and the core is equal to or lower than about the hard metal composition. 46 9% of the total weight and c 〇 is equal to or lower than about 27.4% of the total weight of the hard metal composition ^ 53. The hard metal composition includes: hard particles including at least one nitride, wherein the nitride is selected a nitride formed by elements of Groups IVb and Vb in the Periodic Table of the Elements; and a binder matrix comprising Re and C〇 for bonding hard particles, wherein the hard particles comprise about 28% of the total weight of the hard metal composition To 98%. 54. The hard metal composition of clause 53, wherein the nitride is TiN and comprises from about 28% to 95% by weight of the total of the hard metal composition, and Re is up to about 7 of the total weight of the hard metal composition. 1.6% and Co up to about 5.7% of the total weight of the hard metal composition. The hard metal composition of item 53, wherein the nitride is

ZrN且約佔該硬金屬組合物總重量的34.5%至96.3%，Re 最高至約該硬金屬組合物總重量的65.3%而Co最高至約該硬金屬組合物總重量的44.4%。 56.如第53項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的49.8%至98%，最高至約該硬金屬組合物總重量的50%而Co最高至約該硬金屬組合物總重量的30%。 1057D-6939^PF 47 1339219 L、 » * • 57.如第53項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的3〇%至％ 5%，汉^最高至約該硬金屬組合物總重量的69.6%而c〇最高至約該硬金屬組合物總重量的49.3%。 Λ 58·如第53項所述之硬金屬魬合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34 4%至·96 3%，^ 最高至約該硬金属組合物總重量的65 3%而c〇最高至約6 該硬金屬組合物總重量的44.5 %。 • 59.如第S3項所述之硬金屬組合物，其中該氮化物為ZrN and about 34.5% to 96.3% by weight of the total hard metal composition, Re up to about 65.3% by weight of the total hard metal composition and Co up to about 44.4% by weight of the total of the hard metal composition. 56. The hard metal composition of clause 53, wherein the nitride is HfN and comprises from about 49.8% to 98% by weight of the total of the hard metal composition, up to about 50% by weight of the total weight of the hard metal composition. And Co is up to about 30% of the total weight of the hard metal composition. The hard metal composition of item 53, wherein the nitride is VN and accounts for about 3% to 5% of the total weight of the hard metal composition. , up to about 69.6% of the total weight of the hard metal composition and c〇 up to about 49.3% of the total weight of the hard metal composition. The hard metal composition according to Item 53, wherein the nitride is NbN and accounts for about 34 4% to ·96 3% of the total weight of the hard metal composition, and up to about the hard metal combination 65 3% of the total weight of the material and c〇 up to about 44.5% of the total weight of the hard metal composition. 59. The hard metal composition of item S3, wherein the nitride is

TaN且約佔該硬金屬組合物總重量的5〇 7%至98%，心最高至約該硬金屬組合物總重量的491%而C〇最高至約該硬金屬組合物總重量的29.2%。 60. —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該;ε反化物擇自由元素週期表中IVb、vb及族元素所形成的碳化物；以及一包括鎳基超合金及c〇且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬籲組合物總重量的4 5 %至9 8 %。 61. 如第60項所述之硬金屬組合物，其中該碳化物為 TiC且約佔該硬金屬組合物總重量的45 %至95%，該鎳基超合金最高至約該硬金屬組合物總重量的51·5%而Co最高至約該硬金屬組合物總重量的54.5%。 62_如第60項所述之硬金屬組合物，其中該碳化物為 TiC且約佔該硬金屬組合物總重量的52%至96% ’該鎳基超合金最高至約該硬金屬組合物總重量的44.4%而Co最 1057D-6939-PF 48 1339219 ^丨· * •鼻 •u Λ 高至約該硬金屬組合物總重量的47.4%。 63. 如第60項所述之硬金屬組合物’其中該碳化物為 HfC且約佔該硬金屬組合物總重量的68%至98%，該鎳基超合金最高至約該硬金屬組合物總重量的2 9 %而C 〇最高至約該硬金屬組合物總重量的3 2 %。 64. 如第60項所述之硬金屬組合物，其中該碳化物為 VC且約佔該硬金屬組合物總重量的48%至96%，該鎳基超合金最高至約該硬金屬組合物總重量的49%而Co最高 • 至約該硬金屬組合物總重量的52%。 65. 如第60項所述之硬金屬組合物’其中該碳化物為 NbC且約佔該硬金屬組合物總重量的5 7%至97%，該鎳基超合金最高至約該硬金屬組合物總重量的4 〇 %而C 〇最高至約該硬金屬組合物總重量的43%。 66. 如第60項所述之硬金屬組合物，其中該碳·化物為 TaC且約佔該硬金屬組合物總重量的71%至98%，該鎳基超合金最高至約該硬金屬組合物總重量的27%而c〇最高籲至約該硬金屬組合物總重量的29%。 67·如第60項所述之硬金屬組合物，其中該碳化物為 Cr2C3且約佔該硬金屬組合物總重量的53%至96% ’該錄基超合金最高至約該硬金屬組合物總重量的67.3 %而C〇最南至約該硬金屬組合物總重量的4 4 %。 68.如第60項所述之硬金屬組合物，其中該碳化物為 Mo2C且約佔該硬金屬組合物總重量的60%至97% ’該錄基超合金最高至約該硬金屬組合物總重量的36·5%而C〇 1057D-6939-PF 49 ⑧ 1339219 V： ' ·，最高至約該硬金屬組合物總重量的3 9 %。 69_如第60項所述之硬金屬紐合物，其中該碳化物為 wc且約伯該硬金屬組合物總重量的72%至98%，該鎳基超合金最高至約該硬金屬組合物總重量的46 9%而C〇最高至約該硬金屬組合物總重量的2 7.5 %。 70. —種硬金屬組合物包括：包括至少一種氮化物的硬粒子’其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一包括鎳基超合金及Co且用來 •黏結硬粒子的黏結劑基質’其中該硬粒子約佔該硬金屬組合物總重量的47%至98% 71. 如第70項所述之硬金屬組合物，其中該氮化物為 TiN且約佔該硬金屬組合物總重量的47%至96%，該鎳基超合金最高至約該硬金屬組合物總重量的49%而Co最高至約該硬金屬組合物總重量的52%。 72. 如第70項所述之硬金屬纽合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的55%至97%，該鎳基籲超合金最高至約該硬金屬組合物總重量的42%而Co最高至約該硬金屬組合物總重量的45%。 73. 如第70項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的70%至98%，該鎳基超合金最高至約該硬金屬組合物總重量的3 1 %而Co最高至約該硬金屬組合物總重量的27%。 74. 如第70項所述之硬金屬组合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的50%至96%，該鎳基 1057D-6939-PF 50 1339219 m 超合金最高至約該硬金屬組合物總重量的5 3 %而Co最高至約該硬金屬組合物總重量的44%。 75.如第70項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的55%至97% ’該鎳基超合金最高至約該硬金屬組合物總重量的47%而Co最高至約該硬金屬組合物總重量的40%。如第70項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的70%至98%，該錦基 • 超合金最高至約該硬金屬組合物總重量的30%而Co最高至約該硬金屬組合物總重量的2 6 %。 77. —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中IVb、Vb及Vlb 族元素所形成的碳化物；以及一包括Re、鎳基超合金及 Co且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的26%至98.3%。 78. 如第77項所述之硬金屬組合物，其中該碳化物為 _ TiC且約佔該硬金屬組合物總重量的26%至95%，Re最高至約該硬金屬組合物總重量的73.6%，該鎳基超合金最高至約該硬金屬組合物總重量的5 1 ·3%而Co最高至約該硬金屬組合物總重量的5 4.3 %。 79. 如第77項所述之硬金屬組合物，其中該碳化物為 ZrC且約佔該硬金屬組合物總重量的32%至96%，Re最高至約該硬金屬組合物總重量的67.7%，該鎳基超合金最高至約該硬金屬組合物總重量的44.2%而Co最高至約該硬 1057D-6939-PF 51 ⑤ 1339219 • » % ’ 金屬組合物總重量的47.2%。 80. 如第77項所述之硬金屬組合物，其中該碳化物為 HfC且約佔該硬金屬組合物總重量的48%至98%，Re最高至約該硬金屬組合物總重量的52.1 % ’該鎳基超合金最高至約該硬金屬組合物總重量的29.3 %而Co最高至約該硬金屬組合物總重量的3 1.8%。 81. 如第77項所述之硬金屬組合物’其中該碳化物為 VC且約佔該硬金屬組合物總重量的28%至96%，Re最高籲至約該硬金屬組合物總重量的7 1.5 %，該錄基超合金最高至約該硬金屬組合物總重量的48.6%而Co最高至約該硬金屬組合物總重量的5 1.7 %。 82·如第77項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的36%至97%，Re最高至約該硬金屬組合物總重量的63.8%，該鎳基超合金最高至約該硬金屬組合物總重量的40%而Co最高至約該硬金屬組合物總重量的4 3 %。 # 83.如第77項所述之硬金屬組合物，其中該碳化物為TaN and about 〇7% to 98% of the total weight of the hard metal composition, the core is up to about 491% of the total weight of the hard metal composition and C〇 is up to about 29.2% of the total weight of the hard metal composition. . 60. A hard metal composition comprising: hard particles comprising at least one carbide, wherein the ε derivative is selected from the carbides formed by IVb, vb and group elements of the periodic table; and a nickel-based superalloy And a binder matrix for bonding hard particles, wherein the hard particles comprise from about 45 to 98% of the total weight of the hard metal composition. 61. The hard metal composition of clause 60, wherein the carbide is TiC and comprises from about 45% to about 95% by weight of the total of the hard metal composition, the nickel-based superalloy up to about the hard metal composition The total weight is 51.5% and the Co is up to about 54.5% of the total weight of the hard metal composition. The hard metal composition according to item 60, wherein the carbide is TiC and accounts for about 52% to 96% of the total weight of the hard metal composition. The nickel-based superalloy is up to about the hard metal composition. The total weight is 44.4% and the Co is the most 1057D-6939-PF 48 1339219 ^ 丨 · * • nose • u Λ up to about 47.4% of the total weight of the hard metal composition. 63. The hard metal composition of claim 60 wherein the carbide is HfC and comprises from about 68% to 98% by weight of the total of the hard metal composition, the nickel based superalloy up to about the hard metal composition The total weight is 29% and the C 〇 is up to about 32% of the total weight of the hard metal composition. 64. The hard metal composition of clause 60, wherein the carbide is VC and comprises from about 48% to about 96% by weight of the total of the hard metal composition, the nickel-based superalloy up to about the hard metal composition 49% of the total weight and Co is the highest • to about 52% of the total weight of the hard metal composition. 65. The hard metal composition of item 60 wherein the carbide is NbC and comprises from about 7% to 97% by weight of the total of the hard metal composition, the nickel-based superalloy up to about the hard metal combination The total weight of the material is 4% by weight and C? is up to about 43% of the total weight of the hard metal composition. The hard metal composition according to item 60, wherein the carbon compound is TaC and accounts for 71% to 98% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal combination. 27% of the total weight of the material and c〇 is up to about 29% of the total weight of the hard metal composition. The hard metal composition according to item 60, wherein the carbide is Cr2C3 and accounts for about 53% to 96% of the total weight of the hard metal composition. The recording base superalloy is up to about the hard metal composition. The total weight is 67.3% and C〇 is the most south to about 4 4 % of the total weight of the hard metal composition. The hard metal composition according to item 60, wherein the carbide is Mo2C and accounts for about 60% to 97% of the total weight of the hard metal composition. The recording base superalloy is up to about the hard metal composition. The total weight is 36.5% and C〇1057D-6939-PF 49 8 1339219 V: '·, up to about 39% of the total weight of the hard metal composition. 69. The hard metal conjugate according to item 60, wherein the carbide is wc and is about 72% to 98% by weight of the total of the hard metal composition, and the nickel-based superalloy is up to about the hard metal combination. The total weight of the material is 46 9% and the C 〇 is up to about 27.5% of the total weight of the hard metal composition. 70. A hard metal composition comprising: hard particles comprising at least one nitride 'where the nitride is selected from nitrides formed by elements IVb and Vb of the periodic table; and 1 comprising a nickel-based superalloy and Co A binder substrate for bonding hard particles, wherein the hard particles comprise from about 47% to 98% by weight of the total weight of the hard metal composition. 71. The hard metal composition according to item 70, wherein the nitride is TiN And accounting for about 47% to 96% of the total weight of the hard metal composition, the nickel-based superalloy up to about 49% of the total weight of the hard metal composition and Co up to about 52% of the total weight of the hard metal composition. . The hard metal conjugate according to item 70, wherein the nitride is ZrN and accounts for 55% to 97% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal. 42% of the total weight of the composition and Co up to about 45% of the total weight of the hard metal composition. The hard metal composition according to item 70, wherein the nitride is HfN and accounts for 70% to 98% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal composition. The total weight is 31% and the Co is up to about 27% of the total weight of the hard metal composition. 74. The hard metal composition of clause 70, wherein the nitride is VN and comprises from about 50% to about 96% by weight of the total of the hard metal composition, the nickel based 1057D-6939-PF 50 1339219 m superalloy Up to about 53% of the total weight of the hard metal composition and Co up to about 44% of the total weight of the hard metal composition. The hard metal composition according to item 70, wherein the nitride is NbN and accounts for about 55% to 97% of the total weight of the hard metal composition. The nickel-based superalloy is up to about the hard metal composition. 47% of the total weight and Co up to about 40% of the total weight of the hard metal composition. The hard metal composition according to item 70, wherein the nitride is TaN and accounts for 70% to 98% of the total weight of the hard metal composition, and the base metal superalloy is up to about the total of the hard metal composition. 30% by weight and Co up to about 26% of the total weight of the hard metal composition. 77. A hard metal composition comprising: hard particles comprising at least one carbide, wherein the carbide is selected from carbides formed by elements IVb, Vb and Vlb of the periodic table; and one comprising Re, nickel based super Alloy and Co and a binder matrix for bonding hard particles, wherein the hard particles comprise from about 26% to 98.3% by weight of the total of the hard metal composition. 78. The hard metal composition of item 77, wherein the carbide is _TiC and comprises from about 26% to 95% by weight of the total of the hard metal composition, and Re is up to about the total weight of the hard metal composition. 73.6%, the nickel-based superalloy is up to about 5 1 · 3% of the total weight of the hard metal composition and Co is up to about 4.3 % of the total weight of the hard metal composition. The hard metal composition according to item 77, wherein the carbide is ZrC and accounts for about 32% to 96% by weight of the total of the hard metal composition, and Re is up to about 67.7 of the total weight of the hard metal composition. %, the nickel-based superalloy is up to about 44.2% of the total weight of the hard metal composition and Co is up to about 47.2% of the total weight of the hard 1057D-6939-PF 51 5 1339219 • » % 'metal composition. The hard metal composition according to item 77, wherein the carbide is HfC and accounts for about 48% to 98% by weight of the total of the hard metal composition, and Re is up to about 52.1 of the total weight of the hard metal composition. % 'the nickel-based superalloy up to about 29.3% of the total weight of the hard metal composition and Co up to about 3.8% of the total weight of the hard metal composition. 81. The hard metal composition of item 77 wherein the carbide is VC and comprises from about 28% to 96% by weight of the total weight of the hard metal composition, Re is up to about the total weight of the hard metal composition. 7 1.5%, the recording base superalloy is up to about 48.6% of the total weight of the hard metal composition and Co is up to about 5-1.7% of the total weight of the hard metal composition. 82. The hard metal composition of item 77, wherein the carbide is NbC and comprises from about 36% to about 97% by weight of the total of the hard metal composition, and Re is up to about 63.8 by weight of the total weight of the hard metal composition. %, the nickel-based superalloy up to about 40% of the total weight of the hard metal composition and Co up to about 43% of the total weight of the hard metal composition. #83. The hard metal composition of item 77, wherein the carbide is

TaC且約佔該硬金屬組合物總重量的5 1 %至98.3%，Re 最咼至約該硬金屬組合物總重量的4 8.8 % ’該鎮基超合金最高至約該硬金屬組合物總重量的26.6%而Co最高至約該硬金屬組合物總重量的29%。 84.如第77項所述之硬金屬組合物’其中該碳化物為 CoC3且約佔該硬金屬組合物總重量的32%至96%，Re最高至約該硬金屬組合物總重量的67.3%，該鎳基超合金最 1057D-6939-PF 52 冋至約該硬金屬組合物總重量的43 8%而C〇最高至約該硬金屬組合物總重量的& 8%。 85.如第77項所述之硬金屬組合物，其中該碳化物為 M〇2C且約佔該硬金屬紐合物總重量的μ%至π%，最 :至約該硬金屬組合物總重量的6〇 2% ’該鎳基超合金最同至約該硬金屬組合物總重量的36 4%而c〇最高至約該硬金屬組合物總重量的3 9 3 %。TaC and from about 51% to 98.3% by weight of the total of the hard metal composition, and Re up to about 4.88% of the total weight of the hard metal composition. The town-based superalloy is up to about the total of the hard metal composition. 26.6% by weight and Co up to about 29% of the total weight of the hard metal composition. 84. The hard metal composition of item 77 wherein the carbide is CoC3 and comprises from about 32% to 96% by weight of the total of the hard metal composition, and Re is up to about 67.3 by weight of the total hard metal composition. %, the nickel-based superalloy is at most 1057D-6939-PF 52 冋 to about 43 8% of the total weight of the hard metal composition and C 〇 up to about 8% of the total weight of the hard metal composition. The hard metal composition according to item 77, wherein the carbide is M〇2C and accounts for about μ% to π% of the total weight of the hard metal complex, most: to about the total of the hard metal composition. 6〇2% by weight 'The nickel-based superalloy is up to about 36% by weight of the total weight of the hard metal composition and c〇 up to about 393% of the total weight of the hard metal composition.

86.如第77項所述之硬金屬組合物，其中該碳化物為 C且約佔該硬金屬組合物總重量的至％%，以最高至約該硬金屬組合物總重量# 46.9%，該錄基超合金最高至約該硬金屬組合物總重量的25,丨％而c〇最高至約該硬金屬組合物總重量的27.5%。 87. 一種硬金屬級合物包括：包括至少-種氮化物的硬粒子’ *中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的1化物；以及一包# Re、鎳基超合金及c〇The hard metal composition according to item 77, wherein the carbide is C and accounts for about %% by weight of the total of the hard metal composition, up to about 46.9% of the total weight of the hard metal composition. The recording superalloy is up to about 25, % by weight based on the total weight of the hard metal composition and c is up to about 27.5% by weight of the total weight of the hard metal composition. 87. A hard metal grade comprising: a hard particle comprising at least a nitride, wherein the nitride is selected from a compound formed by elements IVb and Vb of the periodic table; and a package #Re, a nickel base Superalloy and c〇

且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的2 8 %至9 8.3 %。 88.如第87項所述之硬金屬組合物，其中該氮化物為 ΤΠΝ且約佔該硬金屬組合物總重量的28%至％%，最高至約該硬金>1組合物總重量& 71 6%，該錦基超合金最高至約該硬金屬組合物總重量的48 8%而c〇最高至約該硬金屬組合物總重量的5丨9 %。 89.如第87項所述之硬金屬組合物’其中該氮化物為 ZrN且約彳占違硬金屬組合物總重量的34%至97%，Re最And a binder matrix for bonding hard particles, wherein the hard particles comprise from about 28% to about 9.83 % by weight based on the total weight of the hard metal composition. 88. The hard metal composition of clause 87, wherein the nitride is cerium and comprises from about 28% to about 9% by weight of the total of the hard metal composition, up to about the total weight of the hard gold >& 71 6%, the base-based superalloy is up to about 48% of the total weight of the hard metal composition and c〇 is up to about 5.9 % of the total weight of the hard metal composition. 89. The hard metal composition according to item 87, wherein the nitride is ZrN and about 34% to 97% by weight of the total weight of the hard metal composition, Re most

1057D-6939-PF 53 1339219 •ϊ ' 高至約該硬金屬組合物總重量的65.3% ’該鎳基超合金最向至約該硬金屬組合物總重量的4 1.6 %而C 〇最高至約該硬金屬組合物總重量的44.6%。 90. 如第87項所述之硬金屬組合物’其中該氮化物為 H fN且約佔該硬金屬組合物總重量的5 0 %至9 8 %，Re最高至約該硬金屬組合物總重量的50%，該鎳基超合金最高至約該硬金屬組合物總重量的27.5 %而Co最高至約該硬金屬組合物總重量的30%。 91. 如第87項所述之硬金屬組合物’其中該氮化物為 VN且約佔該硬金屬組合物總重量的30%至96%，Re最高至約該硬金屬組合物總重量的6 0 %，該鎳基超合金最高至約該硬金屬組合物總重量的46.4%而Co最高至約該硬金屬組合物總重量的49%。 92，如第87項所述之硬金屬組合物’其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34%至97%，Re最局至約該硬金屬組合物總重量的6 5 %，該鎳基超合金最高至約該硬金屬組合物總重量的42%而Co最高至約該硬金屬組合物總重量的4 5 %。 93. 如第87項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金属組合物總重量的51%至98.3%，Re 最高至約該硬金屬組合物總重量的49%，該鎳基超合金最局至約該硬金屬組合物總重量的2 7 %而c 〇最高至約該硬金屬組合物總重量的29%。 94. —種硬金屬組合物包括：包括wc及TiC的硬粒 1057D-6939-PF 54 1339219 •a « ’ 子’其中包括wc的硬粒子約佔該硬金屬組合物總重量的 40%至96% ’而包括TiC的硬粒子約佔該硬金屬組合物總重量的0.3%至21% ;以及一含Re且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4%至54%。 95·，一種硬金屬組合物包括：包括WC及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 44%至96%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的2 1 % ;以及一含Re且用來黏結硬粒子的黏結 φ 劑基質約佔該硬金屬組合物總重量的4 %至4 8 %。 96. —種硬金屬組合物包括：包括WC、TiC及TaC的硬粒子，其中包括W C的硬粒子約佔該硬金屬組合物總重量的36%至95% ’包括TiC的硬粒子最高至約該硬金屬組合物總重量的22%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的25 % ;以及一含Re用來黏結硬粒子的 . 黏結劑基質約佔該硬金屬組合物總重量的4 %至5 4 %。 97. —種硬金屬組合物包括：包括WC及TiC的硬粒 Φ子，其中包括w c的硬粒子約佔該硬金屬組合物總重量的 60%至98% ’而包括TiC的硬粒子最高至約該硬金屬組合物總重量的25% ;以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約伯該硬金屬組合物總重量的1.5 %至3 1 %。 98. —種硬金屬組合物包括：包括WC及TaC的硬粒子，其中包括W C的硬粒子約佔該硬金屬組合物總重量的 63%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的2 6 % ;以及一含錄基超合金且用來黏結硬粒子 1057D-6939-PF 55 1339219 t* . · 的黏結劑基質約佔該硬金屬組合物總重量的丄5%至26%。 99. 一種硬金屬組合物包括：包括wc、Tic及TaC的硬粒子，其中包括W C的硬粒子約佔該硬金屬組合物總重量的51%至98%，包括Tic的硬粒子最高至約該硬金屬組合物總重量的23%，而包括TaC的硬粒子最高至約該硬金属組合物總重量的26% ;以及一含鎳基超合金且用來點結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的1 5% 至 26%。 Φ 1 00. 一種硬金屬組合物包括：包括WC及Tic的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 40%至98%，而包括TiC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的52%及29%。 1 〇 1. —種硬金屬組合物包括：包括wc及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的籲44%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的47%及25%。 102. —種硬金屬組合物包括：包括wc、Tic及Tac 的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的40%至98%，包括TiC的硬粒子最高至約該硬金屬組合物總重量的23%，而包括TaC的硬粒子最高至約該硬 1057D-6939-PF 56 1339219 ’ 金屬組合物總重量的26% ;以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的5 3 %及3 0 %。 103. —種硬金屬組合物包括：包括wc及丁⑴的硬粒子’其中包括WC的硬粒子約佔該硬金屬組合物總重量的 40%至98%，而包括TiC的硬粒子最高至約該硬金属組合物總重量的23%;以及一含Re及—含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的53 鲁％及31%。 104. —種硬金屬組合物包括·•包括wc及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 44%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Re及一含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的47 % 及 28%。 105. —種硬金屬組合物包括：包括WC、TiC及TaC 籲的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的40%至98% ’包括TiC的硬粒子最高至約該硬金屬組合物總重量的23 % ’而包括TaC的硬粒子最高至約該硬金屬組合物總重里的26% ;以及一含Re及一含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的53%及33% ° 106. —種硬金屬組合物包括：包括WC及TiC的硬粒子’其中包括wc的硬粒子約佔該硬金屬組合物總重量的 1057D-6939-PF 57 ⑤ 1339219 ▲ 58%至98%，而包括TiC：的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Co及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的33%及29%。 107. —種硬金屬组合物包括：包括we及TaC的硬粒子’其中包括WC的硬粒子約佔該硬金屬組合物總重量的 61%至98% ’而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Co及一含鎳基超合金且用來參黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的28%及25%。1057D-6939-PF 53 1339219 • ϊ 'up to about 65.3% of the total weight of the hard metal composition'. The nickel-based superalloy is up to about 4.6% of the total weight of the hard metal composition and C 〇 up to about The total weight of the hard metal composition was 44.6%. 90. The hard metal composition according to item 87, wherein the nitride is HfN and accounts for about 50% to 98% of the total weight of the hard metal composition, and Re is up to about the total of the hard metal composition. 50% by weight, the nickel-based superalloy is up to about 27.5% of the total weight of the hard metal composition and Co is up to about 30% of the total weight of the hard metal composition. 91. The hard metal composition of item 87 wherein the nitride is VN and comprises from about 30% to about 96% by weight of the total of the hard metal composition, and Re is up to about 6 of the total weight of the hard metal composition. 0%, the nickel-based superalloy is up to about 46.4% by weight of the total hard metal composition and Co is up to about 49% of the total weight of the hard metal composition. 92. The hard metal composition of item 87, wherein the nitride is NbN and comprises from about 34% to about 97% by weight of the total of the hard metal composition, and Re is up to about the total weight of the hard metal composition. 65%, the nickel-based superalloy up to about 42% of the total weight of the hard metal composition and Co up to about 45 % of the total weight of the hard metal composition. 93. The hard metal composition of clause 87, wherein the nitride is TaN and comprises from about 51% to 98.3% by weight of the total of the hard metal composition, and Re is up to about 49 of the total weight of the hard metal composition. %, the nickel-based superalloy is up to about 27% of the total weight of the hard metal composition and c 〇 up to about 29% of the total weight of the hard metal composition. 94. A hard metal composition comprising: hard particles including wc and TiC 1057D-6939-PF 54 1339219 • a « 'sub' wherein the hard particles including wc account for about 40% to 96% of the total weight of the hard metal composition %' and hard particles including TiC account for about 0.3% to 21% of the total weight of the hard metal composition; and a binder matrix containing Re and used to bond hard particles accounts for about 4% of the total weight of the hard metal composition. To 54%. 95. A hard metal composition comprising: hard particles comprising WC and TaC, wherein the hard particles comprising WC comprise from about 44% to 96% by weight of the total of the hard metal composition, and the hard particles comprising TaC are up to about The solid metal composition has a total weight of 21%; and a bonded φ agent matrix containing Re and used to bond the hard particles accounts for about 4% to 48% of the total weight of the hard metal composition. 96. A hard metal composition comprising: hard particles comprising WC, TiC and TaC, wherein the hard particles comprising WC comprise from about 36% to 95% by weight of the total weight of the hard metal composition. 22% of the total weight of the hard metal composition, and the hard particles including TaC up to about 25% of the total weight of the hard metal composition; and a Re containing a binder for the hard particles. From 4% to 54% of the total weight of the composition. 97. A hard metal composition comprising: hard grain Φ comprising WC and TiC, wherein hard particles comprising wc comprise from about 60% to 98% of the total weight of the hard metal composition, and hard particles including TiC up to About 25% of the total weight of the hard metal composition; and a nickel-based superalloy and the binder matrix for bonding the hard particles is about 1.5% to 31% of the total weight of the hard metal composition. 98. A hard metal composition comprising: hard particles comprising WC and TaC, wherein the hard particles comprising WC comprise from about 63% to 98% by weight of the total of the hard metal composition, and the hard particles comprising TaC are up to about 2 6 % of the total weight of the hard metal composition; and a binder matrix containing the recording base superalloy and used to bond the hard particles 1057D-6939-PF 55 1339219 t* · · about 总 of the total weight of the hard metal composition 5% to 26%. 99. A hard metal composition comprising: hard particles comprising wc, Tic and TaC, wherein the hard particles comprising WC comprise from about 51% to 98% by weight of the total of the hard metal composition, and the hard particles comprising Tic up to about 23% of the total weight of the hard metal composition, and hard particles including TaC up to about 26% of the total weight of the hard metal composition; and a binder matrix containing a nickel-based superalloy and used to bond hard particles The hard metal composition has a total weight of from 15% to 26%. Φ 1 00. A hard metal composition comprising: hard particles comprising WC and Tic, wherein hard particles comprising WC comprise from about 40% to 98% by weight of the total weight of the hard metal composition, and hard particles comprising TiC up to about 24% of the total weight of the hard metal composition; and a binder matrix containing Re and a nickel-containing superalloy and used to bond the hard particles up to about 52% and 29%, respectively, of the total weight of the hard metal composition. 1 〇 1. The hard metal composition includes: hard particles including wc and TaC, wherein the hard particles including WC account for about 44% to 98% of the total weight of the hard metal composition, and the hard particles including TaC are the highest. Up to about 24% of the total weight of the hard metal composition; and a binder matrix comprising Re and a nickel-containing superalloy and used to bond the hard particles up to about 47% and 25, respectively, of the total weight of the hard metal composition %. 102. A hard metal composition comprising: hard particles comprising wc, Tic and Tac, wherein the hard particles comprising WC comprise from about 40% to 98% by weight of the total of the hard metal composition, and the hard particles comprising TiC are up to about 23% of the total weight of the hard metal composition, and hard particles including TaC up to about 26% of the total weight of the hard 1057D-6939-PF 56 1339219 'metal composition; and a Re-containing and nickel-containing superalloy And the binder matrix for bonding the hard particles is up to about 3% and 30%, respectively, of the total weight of the hard metal composition. 103. A hard metal composition comprising: hard particles comprising wc and butyl (1) wherein hard particles comprising WC comprise from about 40% to 98% by weight of the total of the hard metal composition, and hard particles comprising TiC up to about 23% of the total weight of the hard metal composition; and a binder matrix containing Re and - containing c〇 and used to bond the hard particles up to about 53% and 31%, respectively, of the total weight of the hard metal composition. 104. A hard metal composition comprising: hard particles comprising wc and TaC, wherein the hard particles comprising WC comprise from about 44% to 98% by weight of the total weight of the hard metal composition, and the hard particles comprising TaC are up to about 24% of the total weight of the hard metal composition; and a binder matrix containing Re and a c-containing binder for bonding hard particles up to about 47% and 28%, respectively, of the total weight of the hard metal composition. 105. A hard metal composition comprising: hard particles comprising WC, TiC and TaC, wherein the hard particles comprising WC comprise from about 40% to 98% by weight of the total weight of the hard metal composition. About 23% of the total weight of the hard metal composition' and the hard particles including TaC up to about 26% of the total weight of the hard metal composition; and a binder containing Re and a c-containing crucible for bonding hard particles The matrix is up to about 53% and 33% by weight of the total weight of the hard metal composition, respectively. 106. The hard metal composition comprises: hard particles including WC and TiC, wherein hard particles including wc account for the hard metal composition. The total weight of 1057D-6939-PF 57 5 1339219 ▲ 58% to 98%, and the hard particles including TiC: up to about 24% of the total weight of the hard metal composition; and a Co-containing and nickel-containing superalloy The binder matrix used to bond the hard particles is up to about 33% and 29%, respectively, of the total weight of the hard metal composition. 107. A hard metal composition comprising: hard particles comprising we and TaC 'hard particles comprising WC comprising from about 61% to 98% by weight of the total weight of the hard metal composition' and hard particles comprising TaC up to about 24% of the total weight of the hard metal composition; and a binder matrix comprising Co and a nickel-containing superalloy and used to bind the hard particles, respectively, up to about 28% and 25% of the total weight of the hard metal composition.

108. —種硬金屬組合物包括：包括we、TiC及TaC 的硬粒子’其中包括WC的硬粒子約佔該硬金屬組合物總重量的57%至98%，包括TiC的硬粒子最高至約該硬金屬組合物總重量的23 % ’而包括TaC的硬粒子最高至約該硬金屬組合物總重量的26% ;以及一含Co及一含錄基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬 _ 組合物總重量的3 3 %及3 0 %。 109. —種硬金屬組合物包括：包括WC及TiC的硬粒子’其中包括WC的硬粒子約佔該硬金屬組合物總重量的 40%至98% ’而包括TiC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含c〇、一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的32%、54%及29%。 110. —種硬金屬組合物包括：包括WC及TaC的硬粒 1057D-6939-PF 58 1339219 * , Λ · ν 子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 45%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24%，·以及一含c〇、一含^及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的28%、47%及26%。 111. 一種硬金屬組合物包括：包括wc、Tic及TaC 的硬粒子，其中包括Wc的硬粒子約佔該硬金屬組合物總重量的35%至93%，包括TiC的硬粒子最高至約該硬金屬 • 組合物總重量的25%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的26% ;以及一含c〇 ' —含Re及一含鎮基超合金且用來黏結硬粒子的點結劑基質分別最高至約該硬金屬組合物總重量的44%、65%及4 1 %。 1 1 2. —種硬金屬組合物包括：包括丁i(：的硬粒子約佔該硬金屬組合物總重量的19%至88%，而包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的3 8 % ;以及一含Re 且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重鲁量的9.5%至65%。 113. —種硬金屬組合物包括：包括TiN的硬粒子約佔該硬金屬組合物總重量的21%至89%，而包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的36% ;以及一含Re 且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的9%至63%。 114. 一種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的85%，而包括m〇2C的硬粒 1057D-6939-PF 59 ⑤ 1339219 上 . 拿子最阿至約該硬金屬組合物總重量的36% ;以及一含Re 且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的9%至64%。 115‘一種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的83 %，包括TiN的硬粒子最同至約該硬金屬組合物總重量的85%，包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的25%，包括wc的硬粒子最高至約該硬金屬組合物總重量的39%、包括TaC的籲硬粒子最高至約該硬金屬組合物總重量的30%，包括Vc 的硬粒子最高至約該硬金屬組合物總重量的11%，包括 cr2C3的硬粒子最高至約該硬金屬組合物總重量的16%; 以及一含Re且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的6%至65%。 1 1 6. —種硬金屬組合物包括：包括TiC的硬粒子約佔該硬金屬組合物總重量的30%至90% ’而包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的4〇% ;以及一含鎳籲基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4 %至4 1 %。 117. —種硬金屬組合物包括：包括TiN的硬粒子最高至約該硬金屬組合物總重量的91 %，而包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的3 8 % ;以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4 %至3 8 %。 118. —種硬金屬組合物包括：包括Tic的硬粒子最高 1057D-6939-PF 60 ⑤ 1339219 «u . « i 至約該硬金屬組合物總重量的90% ’包括丁iN的硬粒子最高至約該硬金屬組合物總重量的9 1 %，包括m〇2C的硬粗子最高至約該硬金屬組合物總重量的38% ;以及一含錄基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4%至40%。 Η 9. —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括m〇2C的硬粒鲁子最高至約該硬金屬組合物總重量的25%，包括WC的硬粒子最高至約該硬金屬組合物總重量的42%、包括Tac的硬粒子最高至約該硬金屬組合物總重量的36%，包括vc 的硬粒子最高至約該硬金屬組合物總重量的14%，包括 CoC：3的硬粒子最高至約該硬金屬組合物總重量的1 ; 、及έ錄基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的2%至40%。 120· —種硬金屬組合物包括：包括丁丨^的硬粒子最高至約該硬金屬組合物總重量的9〇%，包括TiN的硬粒子最冋至約該硬金屬組合物總重量的91%，包括Μ·的硬粒子最向至約該硬金屬組合物總重量的38% ;以及一含Re 一 ’土超&金且用來黏結硬粒子的黏結劑基質分別最间至，.勺該硬金屬組合物總重量W 64%及40%。 121 • 種硬金屬組合物包括：包括TiC的硬粒子最高士、’勺該硬金屬組合物總重量的的％，包括⑽的硬粒子最门至..勺該硬金屬組合物總重量的，包括Μ。：。的硬粒108. A hard metal composition comprising: hard particles comprising we, TiC and TaC 'hard particles comprising WC comprising from about 57% to 98% by weight of the total weight of the hard metal composition, up to about from hard particles of TiC 23% of the total weight of the hard metal composition' and the hard particles including TaC up to about 26% of the total weight of the hard metal composition; and a bond containing Co and a containing superalloy and used to bond hard particles The agent bases are each up to about 33% and 30% of the total weight of the hard metal composition. 109. A hard metal composition comprising: hard particles comprising WC and TiC 'hard particles comprising WC comprising from about 40% to 98% by weight of the total weight of the hard metal composition' and hard particles comprising TiC up to about 24% of the total weight of the hard metal composition; and a binder matrix containing c〇, a Re-containing and a nickel-containing superalloy and used to bond the hard particles up to about 32% of the total weight of the hard metal composition, respectively. , 54% and 29%. 110. A hard metal composition comprising: hard particles 1057D-6939-PF 58 1339219* comprising WC and TaC, wherein the hard particles comprising WC comprise about 45% of the total weight of the hard metal composition to 98%, and the hard particles including TaC are up to about 24% of the total weight of the hard metal composition, and a binder matrix containing c〇, a containing and a nickel-containing superalloy for bonding hard particles. Up to about 28%, 47%, and 26%, respectively, of the total weight of the hard metal composition. 111. A hard metal composition comprising: hard particles comprising wc, Tic, and TaC, wherein the hard particles comprising Wc comprise from about 35% to about 93% by weight of the total of the hard metal composition, and the hard particles comprising TiC are up to about Hard metal • 25% of the total weight of the composition, and hard particles including TaC up to about 26% of the total weight of the hard metal composition; and one containing c〇'-containing Re and a town-containing superalloy and used The binder base of the bonded hard particles is up to about 44%, 65%, and 41%, respectively, of the total weight of the hard metal composition. 1 1 2. The hard metal composition comprises: hard particles comprising butyl i: about 19% to 88% by weight of the total hard metal composition, and hard particles including Mo2C up to about the hard metal composition 38% of the total weight; and a binder matrix containing Re and used to bond the hard particles constitutes about 9.5% to 65% of the total weight of the hard metal composition. 113. A hard metal composition includes: The hard particles of TiN account for about 21% to 89% of the total weight of the hard metal composition, and the hard particles including Mo2C are up to about 36% of the total weight of the hard metal composition; and one contains Re and is used to bond hard particles. The binder matrix comprises from about 9% to 63% by weight of the total weight of the hard metal composition. 114. A hard metal composition comprising: hard particles comprising TiC up to about 85% by weight of the total of the hard metal composition, including m〇2C hard particle 1057D-6939-PF 59 5 1339219 upper. The handle is up to about 36% of the total weight of the hard metal composition; and a binder matrix containing Re and used to bond hard particles accounts for 9% to 64% of the total weight of the hard metal composition. 115' A hard metal composition includes: Hard particles including TiC Up to about 83% by weight of the total weight of the hard metal composition, including hard particles of TiN up to about 85% by weight of the total hard metal composition, including hard particles of Mo2C up to about the total weight of the hard metal composition. 25%, including hard particles of wc up to about 39% of the total weight of the hard metal composition, hard particles including TaC up to about 30% of the total weight of the hard metal composition, hard particles including Vc up to About 11% of the total weight of the hard metal composition, including hard particles of cr2C3 up to about 16% of the total weight of the hard metal composition; and a binder matrix containing Re and used to bond hard particles to the hard metal 6% to 65% by weight of the total composition. 1 1 6. The hard metal composition includes: hard particles including TiC in an amount of about 30% to 90% by weight based on the total weight of the hard metal composition, and hard particles including Mo2C Up to about 4% by weight based on the total weight of the hard metal composition; and a binder base comprising a nickel-based superalloy and used to bond the hard particles to about 4% to 41% of the total weight of the hard metal composition. 117. A hard metal composition comprising: hard particles comprising TiN up to about 91% of the total weight of the hard metal composition, and the hard particles including Mo2C up to about 38% of the total weight of the hard metal composition; and a binder matrix containing a nickel-based superalloy and used to bond hard particles The hard metal composition has a total weight of 4% to 38%. 118. A hard metal composition includes: hard particles including Tic up to 1057D-6939-PF 60 5 1339219 «u. « i to about the hard metal combination 90% of the total weight of the article comprises: hard particles of the butyl iN up to about 91% of the total weight of the hard metal composition, and hard roughs of m〇2C up to about 38% of the total weight of the hard metal composition; And a binder matrix comprising a recording base superalloy and used to bond the hard particles comprises from about 4% to about 40% by weight of the total weight of the hard metal composition. Η 9. A hard metal composition comprising: hard particles comprising Tic up to about 90% by weight of the total hard metal composition, hard particles comprising TiN up to about 90% by weight of the total hard metal composition, including The hard grain of m〇2C is up to about 25% of the total weight of the hard metal composition, including the hard particles of WC up to about 42% of the total weight of the hard metal composition, and the hard particles including Tac up to about 36% of the total weight of the hard metal composition, including hard particles of vc up to about 14% by weight of the total hard metal composition, including hard particles of CoC: 3 up to about 1 of the total weight of the hard metal composition; The matrix of the binder and the binder matrix used to bond the hard particles comprise from about 2% to about 40% by weight of the total weight of the hard metal composition. 120. The hard metal composition comprises: hard particles comprising butyl lanthanum up to about 9% by weight of the total weight of the hard metal composition, hard particles comprising TiN up to about 91% by weight of the total hard metal composition. %, including hard particles of Μ· up to about 38% of the total weight of the hard metal composition; and a binder matrix containing Re-'s super-amp; gold and used to bond hard particles, respectively. The total weight of the hard metal composition of the scoop is 64% and 40%. 121 • The hard metal composition includes: a hard particle including TiC, a % of the total weight of the hard metal composition, including the hard particle of (10), the total weight of the hard metal composition, Including Μ. :. Hard grain

1057D-6939-PF 1^39219 ί 子最向至約該硬金屬組合物總重量的26%，包括WC的硬珠立子|。取回至，力該硬金屬組合物總重量的42%、包括TaC的更粒子最而至約該硬金屬組合物總重量的3 3 %，包括VC 的硬粒子最高至約該硬金屬組合物總重量的丨6%，包括 Cr2(：3的硬粒子最高至約該硬金屬組合物總重量的1 8% ; 以方 _ s Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及4〇 %。鲁 122· —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最呵至約該硬金屬組合物總重量的9 1 %，包括Mo2C的硬粒子最兩至約該硬金屬組合物總重量的3 8 % ;以及一含Re 及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最南至約該硬金屬組合物總重量的64%及42%。 123. —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括M〇2C的硬粒子最向至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最向至約該硬金屬組合物總重量的33%，包括vc 的硬粒子最尚至約該硬金屬組合物總重量的丨6 %，包括 CoC3的硬粒子最尚至約該硬金屬組合物總重量的1 ; 以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及421057D-6939-PF 1^39219 ί is most likely to be about 26% of the total weight of the hard metal composition, including WC's hard bead |. Retrieving to force 42% of the total weight of the hard metal composition, more particles including TaC up to about 33% of the total weight of the hard metal composition, including hard particles of VC up to about the hard metal composition丨6% of the total weight, including Cr2 (: 3 hard particles up to about 18.8% of the total weight of the hard metal composition; _ s Re and a nickel-containing superalloy and used to bond the hard particles The agent matrix is up to about 64% and 4% by weight of the total weight of the hard metal composition, respectively. Lu 122. The hard metal composition comprises: hard particles including Tic up to about 90% of the total weight of the hard metal composition. The hard particles comprising TiN are up to about 91% by weight of the total hard metal composition, and the hard particles comprising Mo2C are up to about 38% of the total weight of the hard metal composition; and one containing Re and one containing The nickel-based superalloy and the binder matrix for bonding the hard particles are respectively up to about 64% and 42% of the total weight of the hard metal composition. 123. The hard metal composition includes: hard particles including Tic up to About 89% of the total weight of the hard metal composition, including hard particles of TiN up to about the hard metal 90% of the total weight of the compound, including hard particles of M〇2C up to about 26% of the total weight of the hard metal composition, including hard particles of wc up to about 42% of the total weight of the hard metal composition, including The hard particles of TaC are up to about 33% of the total weight of the hard metal composition, and the hard particles including vc are up to about 6% of the total weight of the hard metal composition, and the hard particles including CoC3 are up to about The total weight of the hard metal composition is 1; and a binder matrix containing Re and a nickel-containing superalloy and used to bond the hard particles is up to about 64% and 42% of the total weight of the hard metal composition, respectively.

1057D-6939-PF 62 1339219 大. 3 124. —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的90%，包括ΤίΝ的硬粒子最高至約該硬金屬組合物總重量的91%，包括M〇2C的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含Re 及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及43 %。 125. —種硬金屬組合物包括：包括Tic的硬粒子最高鲁至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最向至約該硬金屬組合物總重量的9〇%，包括M〇2c的硬粒子最高至約該硬金屬組合物總重量的26%，包括WC的硬粒子最南至約該硬金屬組合物總重量的42%、包括Tac的硬粒子最高至約該硬金屬組合物總重量的33 %，包括VC 的硬粒子最高至約該硬金屬組合物總重量的丨6 %，包括 C r 2 C 3的硬粒子最高至約該硬金屬組合物總重量的以及一含Re及一含Co且用來黏結硬粒子的黏結劑基質分籲別最高至約該硬金屬組合物總重量的64%及43% 126. —種硬金屬組合物包括：包括丁丨匸的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最而至約該硬金屬組合物總重量的91 %，包括m〇2C的硬粒子最尚至約該硬金屬組合物總重量的3 8 % ;以及一含錦基超合金及一含Co且用來黏結硬粒子的黏結劑基質分別最咼至約該硬金屬組合物總重量的40%及43 %。 127. —種硬金屬組合物包括··包括TiC的硬粒子最高 1057D-6939-PF 63 1339219 '1' · · η 至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最尚至約該硬金屬組合物總重量的9〇%，包括M〇2C的硬粒子最南至約該硬金屬組合物總重量的26%，包括WC的硬板子最南至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最南至約該硬金屬組合物總重量的3 3 %，包括VC 的硬粒子最南至約該硬金屬組合物總重量的丨6 %，包括 CqC3的硬粒子最高至約該硬金屬組合物總重量的18% : 以及一含鎳基超合金及一含C〇且用來黏結硬粒子的黏結 _劑基質分別最高至約該硬金屬組合物總重量的40%及43 %。 128· —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最而至約該硬金屬組合物總重量的9 1 %，包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含鎳基超合金及一含Ni且用來黏結硬粒子的黏結劑基質分別最尚至約該硬金屬組合物總重量的40%及43 %。春 129· —種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括Mo；jC的硬粒子最高至約該硬金屬組合物總重量的26% ’包括WC的硬敕子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最高至約該硬金屬組合物總重量的33%，包括VC 的硬粒子最高至約該硬金屬組合物總重量的16 %，包括 Cr2C3的硬粒子最高至約該硬金屬組合物總重量的18% ; 1057D-6939-PF 64 屮9219 以及♦鎳基超合金及一含Ni 1用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的娜及43 %。 130. —種硬金屬組合物包括：包括丁丨匸的硬粒子最高至約該硬金屬組合物總重量的9〇%，包括丁⑴的硬粒子最高至約該硬金屬組合物總重量的91%，包括M〇2c的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含汉卜一含鎳基超合金及一含Co且用來黏結硬粒子的黏結劑基 •質分別最高至約該硬金屬組合物總重量的64%、40%及42 %。 131. 種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的89% ,包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括M〇2C的硬粒子最高至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42% '包括TaC的硬粒子最高至約該硬金屬組合物總重量的33 %，包括vc _的硬粒子最高至約該硬金屬組合物總重量的1 6 %，包括 Cr2C3的硬粒子最高至約該硬金屬組合物總重量的18^ . 以及一含Re' —含鎳基超合金及一含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的63 %、39% 及 42% 〇 132· —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的90% ’包括TiN的硬粒子最高至約該硬金屬組合物總重量的9 1 %，包括M〇2C的硬粒 1057D-6939-PF 65 ?9219 子最南至約該硬金屬組合物總重量的3 8% ;以及一含Re、含錄基超合金及一含Ni且用來黏結硬粒子的黏結劑基貝分別最南至約該硬金屬組合物總重量的63%、4〇%及42 %。 133. —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最阿至約該硬金屬組合物總重量的90%，包括M〇2C的硬粒鲁子最兩至約該硬金屬組合物總重量的26%，包括WC的硬板子取愚至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最南至約該硬金屬組合物總重量的33%，包括vc 的硬粒子最高至約該硬金屬組合物總重量的丨6 %，包括 Cl>2C3的硬粒子最高至約該硬金屬組合物總重量的1 ; 、及含Re、一含錄基超合金及一含Ni且用來黏結硬粒子的點結劑基質分別最高至約該硬金屬組合物總重量的63 %、39% 及 42%。魯 134. —種硬金屬組合物包括：包括pc的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最问至約該硬金屬組合物總重量的9丨％，包括M〇2c的硬粒子最向至約該硬金屬組合物總重量的38% ;以及一含、一含Ni及一含Co且用來黏結硬粒子的黏結劑基質分別最两至約該硬金屬組合物總重量的63 %、40%及42%。 135. —種硬金屬組合物包括：包括丁丨匚的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最南至約該硬金屬組合物總重量的9〇%，包括m〇2C的硬粒1057D-6939-PF 62 1339219 Large. 3 124. The hard metal composition comprises: hard particles comprising Tic up to about 90% of the total weight of the hard metal composition, including hard particles of up to about the hard metal 91% by weight of the total composition, including hard particles of M〇2C up to about 38% by weight of the total hard metal composition; and a binder matrix containing Re and a Co-containing binder for hard particles respectively up to About 64% and 43% of the total weight of the hard metal composition. 125. A hard metal composition comprising: hard particles comprising Tic up to about 89% by weight of the total hard metal composition, hard particles comprising TiN up to about 9% by weight of the total weight of the hard metal composition The hard particles comprising M〇2c are up to about 26% of the total weight of the hard metal composition, including the hard particles of WC up to about 42% of the total weight of the hard metal composition, and the hard particles including Tac up to about 33% of the total weight of the hard metal composition, including hard particles of VC up to about 6% of the total weight of the hard metal composition, hard particles including Cr 2 C 3 up to about the total weight of the hard metal composition. And a binder matrix comprising Re and a Co-containing binder for bonding hard particles, up to about 64% and 43% by weight of the total weight of the hard metal composition. 126. The hard metal composition comprises: The hard particles of the crucible are up to about 90% of the total weight of the hard metal composition, and the hard particles including TiN are up to about 91% of the total weight of the hard metal composition, and the hard particles including m〇2C are up to about 38% of the total weight of the hard metal composition; and a gold-containing superalloy and a Co-containing Bonding the hard particles to the binder matrix are most 咼 to about 40% and 43% of the total weight of the hard metal composition. 127. A hard metal composition comprising: hard particles comprising TiC up to 1057D-6939-PF 63 1339219 '1' · · η to about 89% by weight of the total hard metal composition, hard particles including TiN Up to about 9% by weight of the total weight of the hard metal composition, including hard particles of M〇2C up to about 26% of the total weight of the hard metal composition, and the hard board comprising WC is up to about the hard metal composition. 42% of the total weight, the hard particles including TaC are up to about 33% of the total weight of the hard metal composition, including the hard particles of VC up to about 6% of the total weight of the hard metal composition, including CqC3 The hard particles are up to about 18% of the total weight of the hard metal composition: and a nickel-based superalloy and a binder-containing matrix containing C 〇 and used to bond the hard particles are up to about the total of the hard metal composition, respectively. 40% and 43% by weight. 128. The hard metal composition comprises: hard particles comprising Tic up to about 90% of the total weight of the hard metal composition, hard particles comprising TiN up to about 91% of the total weight of the hard metal composition, The hard particles including Mo2C are up to about 38% of the total weight of the hard metal composition; and a nickel-based superalloy and a binder matrix containing Ni and used to bond the hard particles are each up to about the hard metal composition. 40% and 43% of the total weight. Spring 129. The hard metal composition comprises: hard particles comprising TiC up to about 89% of the total weight of the hard metal composition, hard particles comprising TiN up to about 90% of the total weight of the hard metal composition, including The hard particles of Mo; jC are up to about 26% of the total weight of the hard metal composition. The hard ketone including WC is up to about 42% of the total weight of the hard metal composition, and the hard particles including TaC are up to about the hard. 33% by weight of the total metal composition, including hard particles of VC up to about 16% by weight of the total hard metal composition, including hard particles of Cr2C3 up to about 18% by weight of the total hard metal composition; 1057D-6939 - PF 64 屮 9219 and ♦ nickel-based superalloy and a binder matrix containing Ni 1 for bonding hard particles up to about 43% of the total weight of the hard metal composition, respectively. 130. A hard metal composition comprising: hard particles comprising butadiene up to about 9% by weight of the total weight of the hard metal composition, including hard particles of the butyl (1) up to about 91 of the total weight of the hard metal composition. %, including hard particles of M〇2c up to about 38% of the total weight of the hard metal composition; and a binder containing a Hanb-nickel-containing superalloy and a Co-containing binder for bonding hard particles Up to about 64%, 40%, and 42%, respectively, of the total weight of the hard metal composition. 131. The hard metal composition comprises: hard particles comprising TiC up to about 89% by weight of the total hard metal composition, and hard particles comprising TiN up to about 90% by weight of the total hard metal composition, including M〇 The hard particles of 2C are up to about 26% of the total weight of the hard metal composition, and the hard particles including wc are up to about 42% of the total weight of the hard metal composition. The hard particles including TaC are up to about the hard metal composition. 33% of the total weight, including hard particles of vc_ up to about 16% of the total weight of the hard metal composition, including hard particles of Cr2C3 up to about 18^ of the total weight of the hard metal composition, and one containing Re '—The nickel-containing superalloy and a binder matrix containing c〇 and used to bond the hard particles are up to about 63%, 39% and 42%, respectively, of the total weight of the hard metal composition. The inclusions include: hard particles comprising Tic up to about 90% of the total weight of the hard metal composition 'hard particles comprising TiN up to about 91% of the total weight of the hard metal composition, including hard particles 1057D of M〇2C -6939-PF 65 ?9219 sub-most south to about 3 of the total weight of the hard metal composition 8%; and a binder containing Re, a recording superalloy and a Ni-containing binder for bonding hard particles, respectively, up to about 63%, 4%, and 42% of the total weight of the hard metal composition . 133. A hard metal composition comprising: hard particles comprising Tic up to about 89% by weight of the total hard metal composition, hard particles comprising TiN up to about 90% by weight of the total hard metal composition, including The hard grain of M〇2C is up to about 26% of the total weight of the hard metal composition, and the hard board including WC is taken up to about 42% of the total weight of the hard metal composition, and the hard particles including TaC are the southernmost Up to about 33% by weight of the total hard metal composition, including hard particles of vc up to about 6% of the total weight of the hard metal composition, including hard particles of Cl > 2C3 up to about the total weight of the hard metal composition And a binder base containing Re, a nickel-containing superalloy and a Ni-containing binder for hard particles, respectively, up to about 63%, 39%, and 42% of the total weight of the hard metal composition. Lu 134. A hard metal composition comprising: hard particles comprising pc up to about 90% of the total weight of the hard metal composition, hard particles comprising TiN most desirably up to about 9% by weight of the total weight of the hard metal composition The hard particles comprising M〇2c are up to about 38% of the total weight of the hard metal composition; and the binder matrix containing one, one containing Ni and one containing Co and used to bond the hard particles are respectively up to about The total weight of the hard metal composition was 63%, 40% and 42%. 135. A hard metal composition comprising: hard particles comprising butadiene up to about 89% by weight of the total hard metal composition, hard particles comprising TiN up to about 9% of the total weight of the hard metal composition. %, including m〇2C hard particles

1057D-6939-PF 1339219 .½ 丨·.、子最南至約該硬金屬組合物總重量的26%，包括WC的硬粒子最商至約該硬金屬組合物總重量的42%、包括TaC的1057D-6939-PF 1339219 .1⁄2 、·., sub-most south to about 26% of the total weight of the hard metal composition, including WC hard particles most preferably to about 42% of the total weight of the hard metal composition, including TaC of

硬粒子最高至約該硬金屬組合物總重量的33%，包括VC 的硬粒子最高至約該硬金屬組合物總重量的1 6 %，包括Hard particles up to about 33% by weight of the total hard metal composition, including hard particles of VC up to about 16% of the total weight of the hard metal composition, including

Cr2<：3的硬粒子最高至約該硬金屬組合物總重量的1 8% ; 以及一含Re、一含Ni及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的63 %、42% 及 42% 〇 136. 一種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最阿至約該硬金屬組合物總重量的91 %，包括Mo2C的硬粒子最南至約該硬金屬組合物總重量的38% ;以及一含鎳基超合金、一含Ni及一含Co且用來黏結硬粒子的黏結劑基貝分別最高至約該硬金屬組合物總重量的40%、42%及43 1:57·—種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最间至約該硬金屬組合物總重量的90%，包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的26%，包括WC的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最高至約該硬金屬組合物總重量的33 %，包括VC 的硬粒子最高至約該硬金屬組合物總重量的16%，包括 C r2 C3的硬粒子最高至約該硬金屬組合物總重量的1 8 % ; 以及一含錄基超合金、一含Ni及一含Co且用來黏結硬粒 67The hard particles of Cr2<:3 are up to about 18.8% of the total weight of the hard metal composition; and a binder matrix containing Re, a Ni-containing and a Co-containing binder for bonding hard particles up to about the hard 63%, 42%, and 42% of the total weight of the metal composition 〇 136. A hard metal composition includes: hard particles including TiC up to about 90% of the total weight of the hard metal composition, hard particles including TiN Up to about 91% by weight of the total hard metal composition, including hard particles of Mo2C up to about 38% by weight of the total hard metal composition; and a nickel-containing superalloy, one containing Ni and one containing Co The binder base to bond the hard particles is up to about 40%, 42% and 43 of the total weight of the hard metal composition, respectively. The composition of the hard metal includes: hard particles including TiC up to about the hard 89% of the total weight of the metal composition, including hard particles of TiN up to about 90% of the total weight of the hard metal composition, including hard particles of Mo2C up to about 26% of the total weight of the hard metal composition, including WC Hard particles up to about 42% by weight of the total hard metal composition, hard particles including TaC Up to about 33% by weight of the total hard metal composition, including hard particles of VC up to about 16% by weight of the total hard metal composition, hard particles including Cr2C3 up to about the total weight of the hard metal composition 18%; and a recording base superalloy, one containing Ni and one containing Co and used to bond hard particles 67

1057D-6939-PF 1339219 5： . · 子的黏結劑基質分別最高至約該硬金屬組合物總重量的40 %、42% 及 42%。 13 8. —種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的9 1 %，包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的3 8 % ;以及一含鎳基超合金、一含N i及一含C 〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的40%、42%及43 • %。 139. —種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的89%，包括ΉΝ的硬粒子最高至約該硬金屬組合物總重量的90%，包括m〇2C的硬粒子最高至約該硬金屬組合物總重量的26%，包括WC的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最高至約該硬金屬組合物總重量的33%，包括VC 的硬粒子最高至約該硬金屬組合物總重量的丨6 %，包括 ® Ci^C3的硬粒子最高至約該硬金屬組合物總重量的丨;; 以及一含Re、一含鎳基超合金、一含Ni及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的 63%、39%、42% 及 42%。 140. —種硬金屬組合物包括：包括至少一種硼化物的硬粒子，其中該硼化物擇自由元素週期表中ivb、vb及VIb 族凡素所形成的硼化物；以及一包括Re且用來黏結硬粒子的黏結劑基質，其中Re約佔該硬金屬組合物總重量的4%1057D-6939-PF 1339219 5: . The binder matrix is up to about 40%, 42% and 42%, respectively, of the total weight of the hard metal composition. 13 8. The hard metal composition comprises: hard particles comprising TiC up to about 90% of the total weight of the hard metal composition, hard particles comprising TiN up to about 91% of the total weight of the hard metal composition, The hard particles including Mo2C are up to about 38% of the total weight of the hard metal composition; and a nickel-based superalloy, a N-containing and a C-containing cerium and a binder matrix for bonding hard particles are respectively up to About 40%, 42%, and 43% of the total weight of the hard metal composition. 139. A hard metal composition comprising: hard particles comprising TiC up to about 89% by weight of the total hard metal composition, and hard particles comprising cerium up to about 90% by weight of the total hard metal composition, including m The hard particles of 〇2C are up to about 26% of the total weight of the hard metal composition, including hard particles of WC up to about 42% of the total weight of the hard metal composition, and hard particles including TaC up to about the hard metal combination. 33% of the total weight of the material, including hard particles of VC up to about 6% of the total weight of the hard metal composition, including hard particles of ® Ci^C3 up to about 总 of the total weight of the hard metal composition; A binder matrix comprising Re, a nickel-containing superalloy, a Ni-containing and a Co-containing binder for bonding hard particles, respectively, up to about 63%, 39%, 42% and 42% of the total weight of the hard metal composition %. 140. A hard metal composition comprising: hard particles comprising at least one boride, wherein the boride is selected from boride formed by ivb, vb, and VIb of the periodic table; and a binder matrix of bonded hard particles, wherein Re accounts for about 4% of the total weight of the hard metal composition

1057D-6939-PF 68 ⑧ 至 76%。1057D-6939-PF 68 8 to 76%.

Ml.如第140項所述之硬金屬組合物，其中該硼化物為TiB2且約佔該硬金屬組合物總重量的24%至87·5 % ’其中Re約佔該硬金屬組合物總重量的12.5%至76%。 142. 如第140項所述之硬金屬組合物，其中該硼化物為ZrB2且約佔該硬金屬組合物總重量的30%至90.5%，其中Re約佔該硬金屬組合物總重量的9.5%至70%。 143. 如第140項所述之硬金屬組合物，其中該硼化物為HfB2且約佔該硬金屬組合物總重量的44·5%至94.5% ’ 其中Re約佔該硬金屬組合物總重量的5 · 5 %至55.5 %。 144. 如第140項所述之硬金屬組合物，其中該硼化物為VB2且約佔該硬金屬組合物總重量的27%至89%，其中 Re約佔該硬金屬組合物總重量的11%至73%。 145. 如第140項所述之硬金屬組合物’其中該硼化物為NbB2且約佔該硬金屬組合物總重量的34%至92% ’其中Re約佔該硬金屬組合物總重量的8%至66%。 146. 如第140項所述之硬金屬組合物’其中該硼化物為TaB2且約佔該硬金屬組合物總重量的47%至95% ’其中Re約佔該硬金屬組合物總重量的5%炱53%。 147·如第140項所述之硬金屬組合物，其中該硼化物為Cr3B2且約佔該硬金屬組合物總重量的至90,5% ’ 其中Re約佔該硬金屬組合物總重量的9.5%至69.5%。 148.如第140項所述之硬金屬組合物’其中該硼化物為MoB2且約佔該硬金屬組合物總重量的36%至92.5% ’The hard metal composition according to item 140, wherein the boride is TiB2 and accounts for about 24% to 87.5% of the total weight of the hard metal composition, wherein Re accounts for about the total weight of the hard metal composition. 12.5% to 76%. 142. The hard metal composition of item 140, wherein the boride is ZrB2 and comprises from about 30% to about 90.5% by weight of the total of the hard metal composition, wherein Re is about 9.5 of the total weight of the hard metal composition. % to 70%. 143. The hard metal composition of item 140, wherein the boride is HfB2 and comprises from about 44.5% to 94.5% of the total weight of the hard metal composition. wherein Re is about the total weight of the hard metal composition. 5 · 5 % to 55.5 %. 144. The hard metal composition of clause 140, wherein the boride is VB2 and comprises from about 27% to about 89% by weight based on the total weight of the hard metal composition, wherein Re is about 11% by weight of the total weight of the hard metal composition. % to 73%. 145. The hard metal composition of item 140 wherein the boride is NbB2 and comprises from about 34% to 92% by weight of the total weight of the hard metal composition, wherein Re is about 8 parts by weight of the total weight of the hard metal composition. % to 66%. 146. The hard metal composition of item 140 wherein the boride is TaB2 and comprises from about 47% to 95% by weight of the total weight of the hard metal composition, wherein Re is about 5 parts by weight of the total weight of the hard metal composition. %炱53%. The hard metal composition of item 140, wherein the boride is Cr3B2 and comprises about 90,5% of the total weight of the hard metal composition, wherein Re is about 9.5 of the total weight of the hard metal composition. % to 69.5%. 148. The hard metal composition of item 140 wherein the boride is MoB2 and comprises from about 36% to 92.5% of the total weight of the hard metal composition.

1057D-6939-PF 13392191057D-6939-PF 1339219

其中Re約佔該硬金屬組合物總重量的7.5%至64%。 1 49·如第1 40項所述之硬金屬組合物，其中該硼化物為WB且約佔該硬金屬組合物總重量的5 3 %至96%，其中 R e約佔該硬金屬組合物總重量的4 %至4 7 %。 15 0.如第140項所述之硬金屬組合物，其中該硼化物為W2 B且約佔該硬金屬組合物總重量的5 3 %至9 6 %，其令Re約佔該硬金屬組合物總重量的4%至47%。 151· —種硬金屬組合物包括：包括至少一種矽化物的鲁硬粒子’其中該石夕化物擇自由元素週期表中IVb、Vb及VIb 族元素所形成的石夕化物；以及一包括Re且用來黏結硬粒子的黏結劑基質，其中Re約佔該硬金屬組合物總重量的6% 至 77%。 152·如第151項所述之硬金屬組合物，其中該石夕化物為TisSh且約佔該硬金屬組合物總重量的23%至87%，其中Re約佔該硬金屬組合物總重量的13%至77%。 153.如第151項所述之硬金屬組合物，其中該矽化物鲁為Zr0Si5且約佔該硬金屬組合物總重量的28%至90%，其中Re約佔該硬金屬組合物總重量的1 〇%至72 %。 154·如第151項所述之硬金屬組合物，其中該石夕化物為NbSh且約佔該硬金屬組合物總重量的31%至91%，其中Re約佔該硬金屬組合物總重量的9%至69%。 15 5.如第151項所述之硬金屬組合物，其中該矽化物為TaSiz且約佔該硬金屬組合物總重量的38%至93%，其中Re約佔該硬金屬組合物總重量的7%至62%。 1057D-6939-PF 70 1339219v . 156.如第151項所述之硬金屬組合物，其中該矽化物為MoSiz且約佔該硬金屬組合物總重量的3 1 %至9 1 %，其中Re約佔該硬金屬組合物總重量的9%至69%。 1 5 7.如第1 5 1項所述之硬金屬組合物，其中該矽化物為WSh且約佔該硬金屬組合物總重量的40%至94%，其中Re約佔該硬金屬組合物總重量的6%至60%。 158. —種硬金屬組合物包括：硬粒子；以及一包括w 且用來黏結硬粒子的黏結劑基質。 159·如第158項所述之硬金屬組合物，其中該硬粒子包括至少一種碳化物，其中該碳化物擇自由元素週期表中 IVb、Vb及VIb族元素所形成的碳化物，且其中W約佔該硬金屬組合物總重量的6%至77%。 160. 如第159項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的28%至89%，其中 W約佔該硬金屬組合物總重量的丨丨％至72%。 161. 如第159項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的34%至92%，其中 W約佔該硬金屬組合物總重量的8%至66%。 162•如第159項所述之硬金屬組合物，其中該碳化物為HfC且約佔該硬金屬組合物總重量的50%至96% ’其中 W約佔該硬金屬組合物總重量的4%至50%。 163.如第159項所述之硬金屬組合物，其中該碳化物為VC且約佔該硬金屬組合物總重量的30%至90% ’其中 W約佔該硬金屬組合物總重量的丨〇%至70%。 1057D-6939-PF 71 164·如第159項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的3 8%至93 %，其中W約佔該硬金屬組合物總重量的7%至62%。 165. 如第159項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的53%至96%，其中力約佔該硬金屬組合物總重量的4%至47%。 166. 如第159項所述之硬金屬組合物，其中該碳化物為Cr2C3且約佔該硬金屬組合物總重量的34%至92%，其中W約佔該硬金屬組合物總重量的8%至66%。 167. 如第159項所述之硬金屬组合物，其中該碳化物為Mo2C且約佔該硬金屬組合物總重量的41%至94%，其中W約佔該硬金屬組合物總重量的6%至59%。 168. 如第159項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的55%至96%，其中力約佔該硬金屬組合物總重量的4%至45%。 169. 如第158項所述之硬金屬組合物，其中該硬粒子包括至少一種氮化物，其中該氮化物擇自由元素週期表中 IVb及Vb族元素所形成的氮化物，且其中W約佔該硬金屬組合物總重量的4%至72%。 170·如第169項所述之硬金屬組合物，其中該氮化物為TiN且約佔該硬金屬組合物總重量的28%至89%，其中 W約佔該硬金屬組合物總重量的1 1 %至*72%。 171.如第169項所述之硬金屬組合物，其中該氮化物為ZrN且約佔該硬金屬組合物總重量的36%至92% ’其中 1057D-6939-PF 72 W約佔該硬金屬組合物總重量的8%至64%。 172.如第169項所述之硬金屬組合物，其中該氮化物為HfN且約佔該硬金屬組合物總重量的52%至96%，其中W約佔該硬金屬組合物總重量的4%至48%。 173·如第169項所述之硬金屬組合物，其中該氮化物為VN且約佔該硬金屬組合物總重量的32%至91%，其中 W約佔該硬金屬組合物總重量的9%至68%。 174. 如第169項所述之硬金屬組合物，其中該氮化物為NbN且約佔該硬金屬組合物總重量的36%至92%，其申W約佔該硬金屬組合物總重量的8%至64%。 175. 如第169項所述之硬金屬組合物，其中該氮化物為TaN且約佔該硬金屬組合物總重量的53 %至96 %，其中W約佔該硬金屬組合物總重量的4%至47%。 1 76.如第1 58項所述之硬金屬組合物，其中該硬粒子包括至少一種硼化物，其中該硼化物擇自由元素週期表中 iVb及Vb族元素所形成的硼化物，且其中W約佔該硬金屬組合物總重量的3 %至74%。 177·如第176項所述之硬金屬組合物，其中該氮化物為TiB2且約佔該硬金屬組合物總重量的26%至88%，其中W約佔該硬金屬組合物總重量的1 2%至74%。 178. 如第176項所述之硬金屬組合物，其中該氮化物為ZrB2且約佔該硬金屬組合物總重量的32%至91%，其中W約佔該硬金屬組合物總重量的9%至68%。 179. 如第176項所述之硬金屬組合物，其中該氮化物Wherein Re represents from 7.5% to 64% of the total weight of the hard metal composition. The hard metal composition according to item 40, wherein the boride is WB and accounts for about 53% to 96% of the total weight of the hard metal composition, wherein R e accounts for about the hard metal composition. 4% to 47% of the total weight. The hard metal composition according to item 140, wherein the boride is W2 B and accounts for about 53% to 96% of the total weight of the hard metal composition, which causes Re to account for the hard metal combination. 4% to 47% of the total weight of the object. 151· a hard metal composition comprising: a hard particle comprising at least one telluride, wherein the austenite is selected from the group of elements IVb, Vb and VIb of the periodic table; and a A binder matrix for bonding hard particles, wherein Re is from about 6% to 77% by weight based on the total weight of the hard metal composition. 152. The hard metal composition of item 151, wherein the lithium compound is TisSh and comprises from about 23% to 87% by weight based on the total weight of the hard metal composition, wherein Re accounts for about the total weight of the hard metal composition. 13% to 77%. 153. The hard metal composition of clause 151, wherein the telluride is Zr0Si5 and comprises from about 28% to about 90% by weight of the total of the hard metal composition, wherein Re is about the total weight of the hard metal composition. 1 〇% to 72%. 154. The hard metal composition of item 151, wherein the alexandry is NbSh and comprises from about 31% to about 91% by weight based on the total weight of the hard metal composition, wherein Re is about the total weight of the hard metal composition. 9% to 69%. 15. The hard metal composition of item 151, wherein the telluride is TaSiz and comprises from about 38% to 93% by weight of the total of the hard metal composition, wherein Re is about the total weight of the hard metal composition. 7% to 62%. 156. The hard metal composition of item 151, wherein the telluride is MoSiz and comprises from about 31% to 91% of the total weight of the hard metal composition, wherein Re is about It accounts for 9% to 69% of the total weight of the hard metal composition. The hard metal composition according to item 151, wherein the telluride is WSH and accounts for about 40% to 94% of the total weight of the hard metal composition, wherein Re accounts for about the hard metal composition. 6% to 60% of the total weight. 158. A hard metal composition comprising: hard particles; and a binder matrix comprising w and used to bond the hard particles. 159. The hard metal composition of item 158, wherein the hard particles comprise at least one carbide, wherein the carbide is selected from the carbides formed by elements IVb, Vb, and VIb of the periodic table, and wherein It accounts for about 6% to 77% of the total weight of the hard metal composition. 160. The hard metal composition of clause 159, wherein the carbide is TiC and comprises from about 28% to 89% by weight based on the total weight of the hard metal composition, wherein W is about 总 of the total weight of the hard metal composition.丨% to 72%. 161. The hard metal composition of item 159, wherein the carbide is ZrC and comprises from about 34% to 92% by weight of the total of the hard metal composition, wherein W is about 8 parts by weight of the total weight of the hard metal composition. % to 66%. 162. The hard metal composition of clause 159, wherein the carbide is HfC and comprises from about 50% to 96% by weight of the total weight of the hard metal composition, wherein W is about 4% by weight of the total weight of the hard metal composition. % to 50%. 163. The hard metal composition of clause 159, wherein the carbide is VC and comprises from about 30% to about 90% by weight of the total weight of the hard metal composition, wherein W is about 总 of the total weight of the hard metal composition. 〇% to 70%. The hard metal composition of item 159, wherein the carbide is NbC and accounts for about 38% to 93% of the total weight of the hard metal composition, wherein W accounts for about the hard The metal composition has a total weight of 7% to 62%. 165. The hard metal composition of item 159, wherein the carbide is TaC and comprises from about 53% to 96% by weight of the total of the hard metal composition, wherein the force is about 4% by weight of the total weight of the hard metal composition. % to 47%. 166. The hard metal composition of item 159, wherein the carbide is Cr2C3 and comprises from about 34% to 92% by weight of the total of the hard metal composition, wherein W is about 8 parts by weight of the total weight of the hard metal composition. % to 66%. 167. The hard metal composition of item 159, wherein the carbide is Mo2C and comprises from about 41% to 94% by weight based on the total weight of the hard metal composition, wherein W is about 6 parts by weight of the total weight of the hard metal composition. % to 59%. 168. The hard metal composition of item 159, wherein the carbide is WC and comprises from about 55% to 96% by weight of the total of the hard metal composition, wherein the force is about 4% by weight of the total weight of the hard metal composition. % to 45%. 169. The hard metal composition of item 158, wherein the hard particles comprise at least one nitride, wherein the nitride is selected from nitrides formed by elements IVb and Vb of the periodic table, and wherein W is about The hard metal composition has a total weight of 4% to 72%. The hard metal composition of item 169, wherein the nitride is TiN and comprises from about 28% to 89% by weight based on the total weight of the hard metal composition, wherein W is about 1% by total weight of the hard metal composition. 1% to *72%. 171. The hard metal composition of item 169, wherein the nitride is ZrN and comprises from about 36% to 92% by weight of the total weight of the hard metal composition, wherein 1057D-6939-PF 72 W accounts for the hard metal. 8% to 64% by weight of the total composition. 172. The hard metal composition of item 169, wherein the nitride is HfN and comprises from about 52% to about 96% by weight of the total of the hard metal composition, wherein W is about 4% by weight of the total weight of the hard metal composition. % to 48%. 173. The hard metal composition of item 169, wherein the nitride is VN and comprises from about 32% to about 91% by weight based on the total weight of the hard metal composition, wherein W is about 9% by weight of the total weight of the hard metal composition. % to 68%. 174. The hard metal composition of item 169, wherein the nitride is NbN and comprises from about 36% to 92% by weight based on the total weight of the hard metal composition, and the W is about the total weight of the hard metal composition. 8% to 64%. 175. The hard metal composition of item 169, wherein the nitride is TaN and comprises from about 53% to 96% by weight of the total of the hard metal composition, wherein W is about 4% by weight of the total weight of the hard metal composition. % to 47%. The hard metal composition of claim 1, wherein the hard particle comprises at least one boride, wherein the boride is selected from the boride formed by the iVb and Vb elements of the periodic table, and wherein It accounts for about 3% to 74% of the total weight of the hard metal composition. 177. The hard metal composition of item 176, wherein the nitride is TiB2 and comprises from about 26% to about 88% by weight based on the total weight of the hard metal composition, wherein W is about 1% by weight based on the total weight of the hard metal composition. 2% to 74%. 178. The hard metal composition of item 176, wherein the nitride is ZrB2 and comprises from about 32% to about 91% by weight based on the total weight of the hard metal composition, wherein W is about 9% by weight of the total weight of the hard metal composition. % to 68%. 179. The hard metal composition of item 176, wherein the nitride

1057D-6939-PF ‘ .· 為HfB2且約佔該硬金屬組合物總重量的46%至95% ’其中W約佔該硬金屬組合物總重量的5%至54% ° 180, 如第176項所述之硬金屬組合物’其中該氮化物為VB2且約佔該硬金屬組合物總重量的28%至90% ’其中 W約佔該硬金屬組合物總重量的1 〇%至72%。 181. 如第176項所述之硬金屬組合物，其中該氮化物為NbB2且約佔該硬金屬組合物總重量的36%至92% ’其中W約佔該硬金屬組合物總重量的8%至64%。 . 182.如第176項所述之硬金屬組合物’其中該氮化物為TaB2且約佔該硬金屬組合物總重量的49%至95% ’其中W約佔該硬金屬組合物總重量的5%至5 1 %。 183. 如第176項所述之硬金屬組合物’其中該氮化物為Cr3B2且約佔該硬金屬組合物總重量的32%至91% ’其中W約佔該硬金屬組合物總重量的9%至68%。 184. 如第176項所述之硬金屬組合物’其中該氮化物為MoB2且約佔該硬金屬組合物總重量的38%至93%，其胃中W約佔該硬金屬組合物總重量的7%至62%。 185·如第176項所述之硬金屬組合物，其中該氮化物為WB且約佔該硬金屬組合物總重量的55%至96%，其中 W約佔該硬金屬組合物總重量的4%至45%。 1 86.如第1 76項所述之硬金屬組合物，其中該氮化物為W2B且約佔該硬金屬組合物總重量的56%至97%，其中W約佔該硬金屬組合物總重量的3%至44%。 187.如第158項所述之硬金屬組合物’其中該硬粒子 1057D-6939-PF 74 包括至少一種矽化物，其中該矽化物擇自由元素週期表中 iVb及Vb族元素所形成的矽化物且其中w約佔該硬金屬組合物總重量的6%至75%。 188.如第187項所述之硬金屬組合物，其中該矽化物為Ti5Si3且約佔該硬金屬組合物總重量的25%至88%，其中W約佔該硬金屬組合物總重量的12%至75%。 1 89.如第187項所述之硬金屬組合物，其中該矽化物為 2r6Si5且约佔該硬金屬組合物總重量的30%至90%，其中 W約佔該硬金屬組合物總重量的1 〇%至70%。 190. 如第187項所述之硬金屬組合物，其中該矽化物為NbSi2且約佔該硬金屬組合物總重量的33 %至9 1 %，其中W約佔該硬金屬組合物總重量的9 %至6 7 %。 191. 如第187項所述之硬金屬組合物，其中該矽化物為TaSi2且約佔該硬金屬組合物總重量的40%至93 %，其中W約佔該硬金屬組合物總重量的7 %至6 0 %。 192. 如第187項所述之硬金屬組合物，其中該矽化物為MoSi2且約佔該硬金屬組合物總重量的3 1 %至9 1 %，其中W約佔該硬金屬組合物總重量的9%至67%。 193. 如第187項所述之硬金屬組合物，其中該矽化物為WSi2且約佔該硬金屬組合物總重量的42%至94%，其中W約佔該硬金屬組合物總重量的6%至58%。 194. 如第158項所述之硬金屬組合物，其中黏結劑基質除W之外更進一步包括Re 195. 如第194項所述之硬金屬組合物，其中該硬粒子 1057D-6939-PF 75 ，2i9 今》包括至少一種碳化物，其中該碳化物擇自由元素週期表中 IVb、Vb及vib族元素所形成的碳化物，且其中Re低於約讀硬金屬組合物總重量的73%而W低於約該硬金屬組合物總重量的72%。 196.如第195項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的42%至94%。 197•如第195項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至92%。 198. 如第195項所述之硬金屬組合物，其中該碳化物為H fC且約佔該硬金屬組合物總重量的4 8 %至9 5 %。 199. 如第195項所述之硬金屬組合物，其中該碳化物為V C且約佔該硬金屬組合物總重量的2 8 %至9 〇 %。 2〇〇·如第I95項所述之硬金屬組合物，其中該碳化物為N b C且約佔該硬金屬組合物總重量的3 6 %至9 3 %。 20 1 ·如第1 95項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的5 1 %至96 %。 202. 如第195項所述之硬金屬組合物，其中該碳化物為CoC3且約佔該硬金屬組合物總重量的Μ%至92%。 203. 如第1 95項所述之硬金屬組合物，其中該碳化物為M〇2C且約佔該硬金屬組合物總重量的39%至94%。 204. 如第195項所述之硬金屬級合物，其中該碳化物為W C且約佔該硬金屬組合物總重量的$ 3 %至9 6 %。 205. 如第194項所述之硬金屬乡旦合物，其中該硬粒子包括至少一種氮化物’其中該氮化物擇自由元素週期表中 1057D-6939-PF 76 λ^2ΐ9 - , » iVb 及 ^ 知TL素所形成的氮化物，且其中Re低於約該硬金屬°且σ物總重量的7 1 %而w低於約該硬金屬組合物總重量的70%。 206’如第2〇5項所述之硬金屬組合物其中該氮化物為TiN且約佔該硬金屬組合物總重量的μ%至9〇%。 207’如第205項所述之硬金屬組合物，其中該氮化物為ZrN且約佔該硬金屬組合物總重量的34%至92%。 2〇8.如第2〇5項所述之硬金屬組合物，其中該氮化物為HfN且約佔該硬金屬組合物總重量的50%至96%。 209. 如第205項所述之硬金屬組合物，其中該氮化物為VN且約伯該硬金屬組合物總重量的3 〇 %至9 1 %。 210. 如第205項所述之硬金屬組合物，其中該氮化物為NbN且約佔該硬金屬組合物總重量的Μ%至92%。 2Π.如第205項所述之硬金屬組合物，其中該氮化物為TaN且約佔該硬金屬組合物總重量的5丨％至％%。 212. 如第194項所述之硬金屬組合物，其中該硬粒子包括至少一種硼化物，其中該硼化物擇自由元素週期表第 4第、5及第6行元素所形成的硼化物，且其中Re低於約該硬金屬組合物總重量的7 5 %而W低於約該硬金屬組合物總重量的73%。 213. 如第212項所述之硬金屬組合物，其中該硼化物為T i B 2且約佔該硬金屬組合物總重量的2 4 %至8 8 %。 214. 如第212項所述之硬金屬組合物，其中該硼化物為ZrB2且約佔該硬金屬組合物總重量的3〇%至9 1 %。 1057D-6939-PF 77 ^39219 ,»W ' > · a 215.如第212項所述之硬金屬組合物，其中該硼化物為HfB；j且約佔該硬金屬組合物總重量的24%至88%。 215 A.如第212項所述之硬金屬組合物，其中該硼化物為VB2且約佔該硬金屬組合物總重量的27%至90% a 216·如第212項所述之硬金屬組合物，其中該硼化物為NbB2且約佔該硬金屬組合物總重量的34%至92%。 217.如第212項所述之硬金屬組合物，其中該硼化物為TaB2且約佔該硬金屬組合物總重量的47%至96%。馨 218.如第212項所述之硬金屬組合物，其中該硼化物為Cr3B2且約佔該硬金屬組合物總重量的32%至91%。 219. 如第212項所述之硬金屬组合物，其中該硼化物為MoB2且約佔該硬金屬組合物總重量的36%至93%。 220. 如第212項所述之硬金屬組合物，其中該硼化物為WB且約佔該硬金屬組合物總重量的53%至96%。 22 1 ·如第2 1 2項所述之硬金屬組合物，其中該硼化物為W2B且約佔該硬金屬組合物總重量的54%至97%。泰 222.如第194項所述之硬金屬組合物，其中該硬粒子包括至少一種矽化物，其中該矽化物擇自由元素週期表中 IVb、Vb及VIb族元素所形成的矽化物，且其中Re低於約該硬金屬組合物總重量的76%而W低於約該硬金屬組合物總重量的74%。 223·如第222項所述之硬金屬組合物，其中該石夕化物為Ti5Si3且約佔該硬金屬組合物總重量的24%至88%。 224.如第222項所述之硬金屬組合物，其中該石夕化物 1057D-6939-PF 78 1339219 ;» * . ί> 為丁i5Si3且約佔該硬金屬組合物總重量的24%至88%。 225‘如第222項所述之硬金屬組合物，其中該石夕化物為NbSiz且約佔該硬金屬組合物總重量的3丨％至9丨％。 226. 如第222項所述之硬金屬組合物，其中該矽化物為TaSh且約佔該硬金屬組合物總重量的3丨％至93 %。 227. 如第222項所述之硬金屬組合物，其中該矽化物為MoSh且約佔該硬金屬組合物總重量的3丨％至9丨％。 228. 如第2 22項所述之硬金屬組合物，其中該石夕化物鲁為NbSi2且約佔該硬金屬組合物總重量的4〇%至94%。 229. —種硬金屬組合物包括：包括至少一種氮化物的硬粒子，其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一包括Re及C〇且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的71%而Co低於約該硬金屬組合物總重量的52%。 23 0.如第229項所述之硬金屬組合物，其中該氮化物為TiN且約佔該硬金屬組合物總重量的28%至95%。 ® 23 1.如第229項所述之硬金屬組合物，其中該氮化物為ZrN且約佔該硬金屬組合物總重量的34%至96% « 232. 如第229項所述之硬金屬組合物，其中該氮化物為HfN且約佔該硬金屬組合物總重量的5〇%至98%。 233. 如第229項所述之硬金屬組合物，其中該氮化物為VN且約佔該硬金屬組合物總重量的3〇%至96%。 234. 如第229項所述之硬金屬組合物，其中該氮化物為NbN且約佔該硬金屬組合物總重量的34%至96%。1057D-6939-PF ' . . is HfB2 and accounts for about 46% to 95% of the total weight of the hard metal composition 'where W is about 5% to 54% ° 180 of the total weight of the hard metal composition, as in the 176th The hard metal composition described in the section wherein the nitride is VB2 and accounts for about 28% to 90% of the total weight of the hard metal composition, wherein W is from about 1% to about 72% by weight based on the total weight of the hard metal composition. . 181. The hard metal composition of item 176, wherein the nitride is NbB2 and comprises from about 36% to 92% by weight of the total weight of the hard metal composition, wherein W is about 8 parts by weight of the total weight of the hard metal composition. % to 64%. 182. The hard metal composition of item 176, wherein the nitride is TaB2 and comprises from about 49% to 95% by weight of the total weight of the hard metal composition, wherein W is about the total weight of the hard metal composition. 5% to 51%. 183. The hard metal composition of item 176, wherein the nitride is Cr3B2 and comprises from about 32% to 91% by weight of the total weight of the hard metal composition, wherein W is about 9% by weight of the total weight of the hard metal composition. % to 68%. 184. The hard metal composition of item 176, wherein the nitride is MoB2 and comprises from about 38% to 93% by weight of the total of the hard metal composition, and the W in the stomach accounts for about the total weight of the hard metal composition. 7% to 62%. 185. The hard metal composition of item 176, wherein the nitride is WB and comprises from about 55% to about 96% by weight based on the total weight of the hard metal composition, wherein W is about 4% by weight based on the total weight of the hard metal composition. % to 45%. The hard metal composition of item 1, wherein the nitride is W2B and comprises from about 56% to about 97% by weight based on the total weight of the hard metal composition, wherein W is about the total weight of the hard metal composition. 3% to 44%. 187. The hard metal composition of item 158, wherein the hard particle 1057D-6939-PF 74 comprises at least one telluride, wherein the telluride is selected from the group consisting of iVb and Vb elements of the periodic table. And wherein w is about 6% to 75% of the total weight of the hard metal composition. 188. The hard metal composition of item 187, wherein the telluride is Ti5Si3 and comprises from about 25% to 88% by weight based on the total weight of the hard metal composition, wherein W is about 12% by weight based on the total weight of the hard metal composition. % to 75%. The hard metal composition of item 187, wherein the telluride is 2r6Si5 and comprises from about 30% to 90% by weight based on the total weight of the hard metal composition, wherein W is about the total weight of the hard metal composition. 1 〇% to 70%. 190. The hard metal composition of item 187, wherein the telluride is NbSi2 and comprises from about 33% to about 91% by weight of the total of the hard metal composition, wherein W is about the total weight of the hard metal composition. 9 % to 6 7 %. 191. The hard metal composition of item 187, wherein the telluride is TaSi2 and comprises from about 40% to about 93% by weight of the total of the hard metal composition, wherein W is about 7 of the total weight of the hard metal composition. % to 60%. 192. The hard metal composition of item 187, wherein the telluride is MoSi2 and comprises from about 31% to 91% of the total weight of the hard metal composition, wherein W is about the total weight of the hard metal composition. 9% to 67%. 193. The hard metal composition of item 187, wherein the telluride is WSi2 and comprises from about 42% to 94% by weight based on the total weight of the hard metal composition, wherein W is about 6 parts by weight of the total weight of the hard metal composition. % to 58%. 194. The hard metal composition of item 158, wherein the binder matrix further comprises Re 195. In addition to W, the hard metal composition according to item 194, wherein the hard particle 1057D-6939-PF 75 , 2i9 herein includes at least one carbide, wherein the carbide is selected from the carbides formed by elements IVb, Vb and vib of the periodic table, and wherein Re is less than 73% of the total weight of the hard metal composition. W is less than about 72% of the total weight of the hard metal composition. 196. The hard metal composition of clause 195, wherein the carbide is TiC and comprises from about 42% to 94% by weight of the total of the hard metal composition. 197. The hard metal composition of clause 195, wherein the carbide is ZrC and comprises from about 32% to about 92% by weight of the total of the hard metal composition. 198. The hard metal composition of item 195, wherein the carbide is HfC and comprises from about 48% to about 95% of the total weight of the hard metal composition. 199. The hard metal composition of item 195, wherein the carbide is V C and comprises from about 28% to about 9 % by weight based on the total weight of the hard metal composition. The hard metal composition of item I95, wherein the carbide is N b C and accounts for about 36% to 93% of the total weight of the hard metal composition. The hard metal composition according to item 1 95, wherein the carbide is TaC and accounts for about 51% to 96% of the total weight of the hard metal composition. The hard metal composition according to item 195, wherein the carbide is CoC3 and accounts for about Μ% to 92% of the total weight of the hard metal composition. 203. The hard metal composition of clause 1 95, wherein the carbide is M〇2C and comprises from about 39% to 94% by weight of the total of the hard metal composition. 204. The hard metal grade of item 195, wherein the carbide is W C and comprises from about 3% to about 96% of the total weight of the hard metal composition. 205. The hard metal sylide of claim 194, wherein the hard particles comprise at least one nitride, wherein the nitride is selected from the group of 1057D-6939-PF 76 λ^2ΐ9 - , » iVb and ^ The nitride formed by the TL is known, and wherein Re is less than about the hard metal and 7.1% of the total weight of the σ material and w is less than about 70% of the total weight of the hard metal composition. 206. The hard metal composition of item 2, wherein the nitride is TiN and comprises from about μ% to about 9% by weight based on the total weight of the hard metal composition. 207. The hard metal composition of clause 205, wherein the nitride is ZrN and comprises from about 34% to about 92% by weight based on the total weight of the hard metal composition. The hard metal composition of item 2, wherein the nitride is HfN and comprises from about 50% to about 96% by weight based on the total weight of the hard metal composition. 209. The hard metal composition of clause 205, wherein the nitride is VN and is from about 3% to about 91% of the total weight of the hard metal composition. 210. The hard metal composition of clause 205, wherein the nitride is NbN and comprises about Μ% to 92% of the total weight of the hard metal composition. The hard metal composition according to item 205, wherein the nitride is TaN and accounts for about 5% to % by weight based on the total weight of the hard metal composition. The hard metal composition according to item 194, wherein the hard particles comprise at least one boride, wherein the boride is selected from boride formed by elements of the fourth, fifth and sixth elements of the periodic table, and Wherein Re is less than about 75 % of the total weight of the hard metal composition and W is less than about 73% of the total weight of the hard metal composition. 213. The hard metal composition of clause 212, wherein the boride is T i B 2 and comprises from about 24% to about 88% by weight of the total of the hard metal composition. 214. The hard metal composition of clause 212, wherein the boride is ZrB2 and comprises from about 3% to about 91% by weight of the total weight of the hard metal composition. The hard metal composition of item 212, wherein the boride is HfB; j and comprises about 24% by weight of the total weight of the hard metal composition. % to 88%. 215 A. The hard metal composition of item 212, wherein the boride is VB2 and comprises from about 27% to 90% by weight of the total weight of the hard metal composition a 216. The hard metal combination as described in item 212 And wherein the boride is NbB2 and comprises from about 34% to about 92% by weight based on the total weight of the hard metal composition. 217. The hard metal composition of clause 212, wherein the boride is TaB2 and comprises from about 47% to about 96% by weight of the total of the hard metal composition. The hard metal composition of item 212, wherein the boride is Cr3B2 and comprises from about 32% to about 91% by weight based on the total weight of the hard metal composition. 219. The hard metal composition of clause 212, wherein the boride is MoB2 and comprises from about 36% to about 93% by weight of the total of the hard metal composition. 220. The hard metal composition of clause 212, wherein the boride is WB and comprises from about 53% to about 96% by weight of the total of the hard metal composition. The hard metal composition of item 2, wherein the boride is W2B and comprises from about 54% to about 97% by weight based on the total weight of the hard metal composition. The hard metal composition according to Item 194, wherein the hard particle comprises at least one telluride, wherein the telluride is selected from the telluride formed by elements of groups IVb, Vb and VIb of the periodic table, and wherein Re is less than about 76% of the total weight of the hard metal composition and W is less than about 74% of the total weight of the hard metal composition. 223. The hard metal composition of clause 222, wherein the lithium compound is Ti5Si3 and comprises from about 24% to about 88% by weight based on the total weight of the hard metal composition. 224. The hard metal composition according to item 222, wherein the lithographic compound 1057D-6939-PF 78 1339219; » * . ί> is butyl i5Si3 and accounts for about 24% to 88% of the total weight of the hard metal composition. %. 225. The hard metal composition of item 222, wherein the alumite is NbSiz and comprises from about 3% to about 9% by weight based on the total weight of the hard metal composition. 226. The hard metal composition of clause 222, wherein the telluride is TaSh and comprises from about 3% to about 93% by weight of the total weight of the hard metal composition. 227. The hard metal composition of item 222, wherein the telluride is MoSh and comprises from about 3% to about 9% by weight based on the total weight of the hard metal composition. 228. The hard metal composition of item 2, wherein the compound is NbSi2 and comprises from about 4% to about 94% by weight based on the total weight of the hard metal composition. 229. A hard metal composition comprising: hard particles comprising at least one nitride, wherein the nitride is selected from nitrides formed by elements of group IVb and Vb of the periodic table; and one comprises Re and C〇 and is used A binder matrix of bonded hard particles, wherein Re is less than about 71% by weight based on the total weight of the hard metal composition and Co is less than about 52% by weight based on the total weight of the hard metal composition. The hard metal composition of item 229, wherein the nitride is TiN and comprises from about 28% to about 95% by weight based on the total weight of the hard metal composition. The hard metal composition according to item 229, wherein the nitride is ZrN and accounts for about 34% to 96% of the total weight of the hard metal composition « 232. The hard metal as described in item 229 A composition wherein the nitride is HfN and comprises from about 5% to 98% by weight based on the total weight of the hard metal composition. 233. The hard metal composition of clause 229, wherein the nitride is VN and comprises from about 3% to about 96% by weight of the total weight of the hard metal composition. 234. The hard metal composition of clause 229, wherein the nitride is NbN and comprises from about 34% to about 96% by weight of the total of the hard metal composition.

1057D-6939-PF 79 丄幻9219 > 235. 如第229項所述之硬金屬組合物，其中該氮化物為Τ3Ν且約佔該硬金屬組合物總重量的51%至98%。 236. -種硬金屬组合物包括：包括至少—㈣化物的硬粒子’其中該爛化物擇自由元素週期表中及vib 族元素所形成的蝴化物；以及一包括RUC〇且用來黏結 T粒子的黏結劑基質’其中Re低於約該硬金屬組合物總重量的75%而Co低於約該硬金屬組合物總重量的兄％。 237·如第236項所述之硬金屬組合物，其中該硼化物鲁為TiB2且約佔該硬金屬組合物總重量的24%至34%。 23 8.如第236項所述之硬金屑紐合物，其中該硼化物為Z r B2且約佔該硬金屬組合物總重量的3 〇 %至9 6 %。 23 9.如第236項所述之硬金屬絚合物，其中該硼化物為H fB 2且約佔該硬金屬組合物總重量的4 5 %至9 8 %。 240. 如第236項所述之硬金屬組合物，其中該蝴化物為V B2且約佔該硬金属組合物總重量的2 7 %至9 5 %。 241. 如第236項所述之硬金屬級合物，其中該硼化物鲁為NbB2且約佔該硬金屬組合物總重量的34%至96%。 242. 如第230項所述之硬金屬挺合物，其中該硼化物為TaB2且約佔該硬金屬組合物總重量的48%至98%。 243. 如第236項所述之硬金屬紐合物，其中該硼化物為Cr3B2且約佔該硬金屬組合物總重量的30%至96%。 244. 如第236項所述之硬金屬乡且合物，其中該硼化物為MoB2且約佔該硬金屬組合物總重量的36%至97% ° 245. 如第236項所述之硬金屬組合物，其中該硼化物 1057D-6939-PF 80 丄拃219 為WB且約佔該硬金屬組合物總重量的5 3 %至9 8 %。 246. 如第236項所述之硬金屬組合物，其中該硼化物為WZB且約佔該硬金屬組合物總重量的55%至98%。 247. —種硬金屬組合物包括：包括至少一種石夕化物的硬粒子’其中該矽化物擇自由元素週期表中IVb及Vb族元素所形成的矽化物；以及一包括Re及c〇且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的76%而Co低於約該硬金屬組合物總重量的57%。 248. 如第247項所述之硬金屬組合物，其中該石夕化物為Tiji3且約佔該硬金屬組合物總重量的24%至94%。 249. 如第247項所述之硬金屬組合物，其中該石夕化物為Zr0Si3且約佔該硬金屬組合物總重量的28%至95%。 250. 如第247項所述之硬金屬組合物，其中該碎化物為N b S i2且約佔該硬金屬組合物總重量的3 1 %至9 6 %。 251. 如第247項所述之硬金屬組合物，其中該碎化物為TaSi2且約佔該硬金屬組合物總重量的至。 2 5 2 ·如第2 4 7項所述之硬金屬組合物，其中該石夕化物為Mo Sis且約佔該硬金屬組合物總重量的3丨％至96%。 253. 如第247項所述之硬金屬組合物，其中該石夕化物為W S i 2且約佔該硬金屬組合物總重量的4 〇 %至9 7 %。 254. —種硬金屬組合物包括：包括至少一種碳化物的硬粒子’其中該碳化物擇自由元素週期表中I Vb、Vb及VIb 族元素所形成的碳化物；以及一包括Re及Mo且用來黏結 1057D-6939-PF 81 13 妒 219. 硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重里的74%而Mo低於約該硬金屬組合物總重量的57%。 255. 如第254項所述之硬金屬組合物’其中該碳化物為TiC且約佔該硬金屬組合物總重量的26%至94%。 256. 如第254項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至95%。 257·如第254項所述之硬金屬組合物，其中該碳化物為HfC且約佔該硬金屬組合物總重量的48%至98%。 258·如第254項所述之硬金屬組合物，其中該碳化物為V C且約佔該硬金屬組合物總重量的2 8 %至9 5 %。 259. 如第254項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的36%至98%。 260. 如第254項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的$ 1 %至98%。 261‘如第254項所述之硬金屬組合物，其中該碳化物為CoC3且約佔該硬金屬組合物總重量的32%至95%。 262. 如第254項所述之硬金屬組合物，其中該碳化物為Μοζ(：且約佔該硬金屬組合物總重量的40%至97%。 263. 如第254項所述之硬金屬組合物，其中該碳化物為W C且約佔該硬金屬組合物總重量的5 3 %至9 8 %。 264. —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中ivb、Vb及vib 族元素所形成的碳化物；以及一包括Re及Ni且用來黏結·' 硬粒子的黏結劑基質’其中Re低於約該硬金屬組合物總重235. The hard metal composition of item 229, wherein the nitride is Τ3Ν and accounts for about 51% to 98% of the total weight of the hard metal composition. 236. A hard metal composition comprising: a hard particle comprising at least a (four) compound, wherein the ruthenium is selected from a halide formed by a periodic table and a vib group element; and one comprising a RUC 〇 and used to bond the T particle The binder matrix 'where Re is less than about 75% of the total weight of the hard metal composition and Co is less than about % of the total weight of the hard metal composition. 237. The hard metal composition of clause 236, wherein the boride is TiB2 and comprises from about 24% to about 34% by weight of the total of the hard metal composition. The hard gold filings according to item 236, wherein the boride is Z r B2 and accounts for from about 3 % to about 96 % of the total weight of the hard metal composition. The hard metal composition according to item 236, wherein the boride is H fB 2 and accounts for about 45 to 98% of the total weight of the hard metal composition. 240. The hard metal composition of clause 236, wherein the wafer is V B2 and comprises from about 27% to about 95% of the total weight of the hard metal composition. 241. The hard metal composition of clause 236, wherein the boride is NbB2 and comprises from about 34% to about 96% by weight of the total of the hard metal composition. 242. The hard metal conjugate of item 230, wherein the boride is TaB2 and comprises from about 48% to about 98% by weight based on the total weight of the hard metal composition. 243. The hard metal conjugate according to item 236, wherein the boride is Cr3B2 and comprises from about 30% to about 96% by weight based on the total weight of the hard metal composition. 244. The hard metal compound of claim 236, wherein the boride is MoB2 and comprises from about 36% to 97% of the total weight of the hard metal composition. 245. The hard metal of item 236. The composition wherein the boride 1057D-6939-PF 80 丄拃219 is WB and comprises from about 53% to 98% of the total weight of the hard metal composition. 246. The hard metal composition of clause 236, wherein the boride is WZB and comprises from about 55% to 98% by weight of the total weight of the hard metal composition. 247. A hard metal composition comprising: hard particles comprising at least one cerium compound, wherein the cerium compound is selected from the group consisting of groups IVb and Vb of the periodic table; and one comprising Re and c 〇 A binder matrix for bonding hard particles, wherein Re is less than about 76% of the total weight of the hard metal composition and Co is less than about 57% of the total weight of the hard metal composition. 248. The hard metal composition of item 247, wherein the alumite is Tiji3 and comprises from about 24% to about 94% by weight of the total of the hard metal composition. 249. The hard metal composition of clause 247, wherein the alumite is ZrOSi3 and comprises from about 28% to about 95% by weight of the total of the hard metal composition. 250. The hard metal composition of clause 247, wherein the shreds are NbSi2 and comprise from about 31% to about 96% of the total weight of the hard metal composition. 251. The hard metal composition of clause 247, wherein the shreds are TaSi2 and comprise up to about the total weight of the hard metal composition. The hard metal composition according to item 2, 47, wherein the cerium compound is Mo Sis and accounts for about 3% to 96% by weight based on the total weight of the hard metal composition. 253. The hard metal composition of item 247, wherein the lithium compound is W S i 2 and comprises from about 4% to about 97% by weight based on the total weight of the hard metal composition. 254. A hard metal composition comprising: hard particles comprising at least one carbide wherein the carbide is selected from the group consisting of elements of the group I Vb, Vb and VIb of the periodic table; and one comprising Re and Mo A binder matrix for bonding 1057D-6939-PF 81 13 妒 219. hard particles, wherein Re is less than about 74% of the total weight of the hard metal composition and Mo is less than about 57% of the total weight of the hard metal composition. . 255. The hard metal composition as described in item 254 wherein the carbide is TiC and comprises from about 26% to about 94% by weight based on the total weight of the hard metal composition. 256. The hard metal composition of clause 254, wherein the carbide is ZrC and comprises from about 32% to about 95% by weight of the total of the hard metal composition. 257. The hard metal composition of clause 254, wherein the carbide is HfC and comprises from about 48% to about 98% by weight of the total of the hard metal composition. 258. The hard metal composition of clause 254, wherein the carbide is V C and comprises from about 28% to about 95% by weight of the total weight of the hard metal composition. 259. The hard metal composition of clause 254, wherein the carbide is NbC and comprises from about 36% to 98% by weight of the total weight of the hard metal composition. 260. The hard metal composition of item 254, wherein the carbide is TaC and comprises from about 1% to about 98% by weight of the total weight of the hard metal composition. 261. The hard metal composition of item 254, wherein the carbide is CoC3 and comprises from about 32% to about 95% by weight of the total of the hard metal composition. 262. The hard metal composition of item 254, wherein the carbide is Μοζ (: and comprises from about 40% to 97% by weight of the total of the hard metal composition. 263. The hard metal of item 254. a composition wherein the carbide is WC and comprises from about 53% to about 98% by weight of the total of the hard metal composition. 264. A hard metal composition comprising: hard particles comprising at least one carbide, wherein the carbonization a carbide formed by elements of the ivb, Vb, and vib elements of the periodic table of the free element; and a binder matrix comprising Re and Ni for bonding the 'hard particles' wherein Re is less than about the total of the hard metal composition weight

1057D-6939-PF 821057D-6939-PF 82

丄339219 *> · 量的74%而Ni低於約該硬金屬組合物總重量的。 265. 如第264項所述之硬金屬組合物’其中該碳化物為TiC且約佔該硬金屬組合物總重量的26%至95%。 266. 如第264項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至96%。 267. 如第264項所述之硬金屬組合物，其中該碳化物為HfC且約佔該硬金屬組合物總重量的48%至98%。 268. 如第264項所述之硬金屬組合物，其中該碳化物 _ 為VC且約佔該硬金屬組合物總重量的28%至95%。 269. 如第264項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的36%至97%。 270·如第264項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的5丨％至％ %。 271·如第264項所述之硬金屬組合物，其中該碳化物為Cr2C3且約佔該硬金屬組合物總重量的32%至96%。 272. 如第264項所述之硬金屬組合物，其中該碳化物鲁為MoC且約佔該硬金屬組合物總重量的4〇%至97%。 273. 如第264項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的η %至98%。 274. —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中IVb、vb及VIb 族元素所形成的碳化物；以及一包括Re及Ni且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的74%而Cr低於約該硬金屬組合物總重量的48%。丄339219 *> · 74% of the amount and Ni is less than about the total weight of the hard metal composition. 265. The hard metal composition of item 264, wherein the carbide is TiC and comprises from about 26% to about 95% by weight of the total of the hard metal composition. 266. The hard metal composition of clause 264, wherein the carbide is ZrC and comprises from about 32% to about 96% by weight of the total of the hard metal composition. 267. The hard metal composition of clause 264, wherein the carbide is HfC and comprises from about 48% to about 98% by weight of the total weight of the hard metal composition. 268. The hard metal composition of clause 264, wherein the carbide _ is VC and comprises from about 28% to 95% by weight of the total weight of the hard metal composition. 269. The hard metal composition of clause 264, wherein the carbide is NbC and comprises from about 36% to about 97% by weight of the total of the hard metal composition. The hard metal composition of item 264, wherein the carbide is TaC and comprises from about 5% to about 9% by weight based on the total weight of the hard metal composition. The hard metal composition of item 264, wherein the carbide is Cr2C3 and comprises from about 32% to about 96% by weight based on the total weight of the hard metal composition. 272. The hard metal composition of clause 264, wherein the carbide is MoC and comprises from about 4% to about 97% by weight of the total weight of the hard metal composition. 273. The hard metal composition of clause 264, wherein the carbide is WC and comprises from about 7% to 98% by weight of the total weight of the hard metal composition. 274. A hard metal composition comprising: hard particles comprising at least one carbide, wherein the carbide is selected from carbides formed by elements of groups IVb, vb and VIb of the periodic table; and one comprising Re and Ni A binder matrix for bonding hard particles, wherein Re is less than about 74% by weight based on the total weight of the hard metal composition and Cr is less than about 48% by weight based on the total weight of the hard metal composition.

1057D-6939-PF 83 275. 如第274項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的26%至96%。 276. 如第264項所述之硬金屬組合物’其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至97%。 277·如第264項所述之硬金屬組合物，其中該碳化物為HfC且约佔該硬金屬組合物總重量的48%至98%。 2 78.如第264項所述之硬金屬組合物，其中該碳化物為V C且約佔該硬金属組合物總重量的2 8 %至9 5 %。 2 79.如第264項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的36%至97%。 280. 如第264項所述之硬金屬組合物，其中該碳化物為T a C且約佔該硬金屬組合物總重量的5 1 %至9 8 %。 281. 如第264項所述之硬金屬組合物，其中該碳化物為CoC3且約佔該硬金屬組合物總重量的32%至97%。 282·如第264項所述之硬金屬組合物，其中該碳化物為M〇2C且約佔該硬金屬組合物總重量的至。 283. 如第264項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的$3 %至98,6 %。 284. —種硬金屬組合物的製造方法，包括：預備一金屬表面，接著進行一熱噴塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：至少包括碳化物、氮化物、硼化物或矽化物的硬粒子；以及一至少包括Re且用來黏結硬粒子的黏結劑基質。 285•—種硬金屬組合物的製造方法，包括：預備一金275. The hard metal composition of item 274, wherein the carbide is TiC and comprises from about 26% to about 96% by weight of the total of the hard metal composition. 276. The hard metal composition as described in item 264 wherein the carbide is ZrC and comprises from about 32% to about 97% by weight of the total of the hard metal composition. 277. The hard metal composition of clause 264, wherein the carbide is HfC and comprises from about 48% to about 98% by weight of the total of the hard metal composition. The hard metal composition according to item 264, wherein the carbide is V C and accounts for about 28% to 95% of the total weight of the hard metal composition. The hard metal composition of item 264, wherein the carbide is NbC and comprises from about 36% to about 97% by weight based on the total weight of the hard metal composition. 280. The hard metal composition of item 264, wherein the carbide is T a C and comprises from about 51% to about 98% of the total weight of the hard metal composition. 281. The hard metal composition of clause 264, wherein the carbide is CoC3 and comprises from about 32% to about 97% by weight of the total of the hard metal composition. 282. The hard metal composition of clause 264, wherein the carbide is M〇2C and is about to about the total weight of the hard metal composition. 283. The hard metal composition of clause 264, wherein the carbide is WC and comprises from about 3% to 98,6% of the total weight of the hard metal composition. 284. A method of making a hard metal composition, comprising: preparing a metal surface, followed by performing a thermal spray process to coat a layer of a hard metal on the metal surface, wherein the hard metal layer comprises: at least a carbide, nitrogen a hard particle of a compound, a boride or a telluride; and a binder matrix comprising at least Re and used to bond the hard particles. 285•—Methods for producing a hard metal composition, including: preparing a gold

1057D-6939-PF 1339219 屬表面，#著進行-熱噴塗製程將一層硬金屬層塗佈在金屬表面上’其中該硬金屬層包括：至少包括碳化物氣化物、硼化物或石夕化物的硬粒子；卩及—至少包括—錄基超合金且用來黏結硬粒子的黏結劑基質。 286. —種硬金屬組合物的製造方法，包括：預備一金屬表面，接著進行-熱噴塗製程將一層硬金屬層塗佈在金屬表面上’其中該硬金屬層包括：至少包括碳化物、氮化1057D-6939-PF 1339219 is a surface, #着进行-thermal spraying process coating a layer of hard metal on a metal surface' wherein the hard metal layer comprises: at least a carbide vapor, boride or a lithiated hard Particles; 卩 and - at least include a binder matrix for the recording of superalloys and used to bond hard particles. 286. A method of making a hard metal composition comprising: preparing a metal surface, followed by a thermal spray process to coat a layer of hard metal on a metal surface, wherein the hard metal layer comprises: at least a carbide, nitrogen Chemical

物、硼化物或矽化物的硬粒子；以及一至少包括w且用來黏結硬粒子的黏結劑基質。【實施方式】硬金屬材料的組成（comp0siti〇ns)會直接影響硬金屬的特性與應用成效，當然在製造中的製程條件與設備也會對其特性成效有影響◊還有，硬金屬材料的組成也會影響硬金屬原材的成本，並與製造成本相關。因此，找出經濟的硬金屬材料的組成，且又能具有良好的特性，乃是業界亟而努力的課題。本案即提供一種新的硬金屬組合物，其具有特別選擇之黏結劑基質（binder matrix)材料，並且具有提供優良特性的優點。本案的硬金屬組合物包含各種的硬粒子與各種的黏結劑基質材料。一般來說’硬粒子可以是週期表中IVB ' VB 與VIB族之金屬元素的碳化物，例如ivb之金屬碳化物有 TiC，ZrC，HfC、VB 之金屬碳化物有 vc，NbC，TaC、VIB 之金屬:碳化物有ChC2, MhC，WC。硬粒子也可以是週期表中IVB與VB族之金屬元素的氮化物，例如之金屬氮a hard particle of a boride or telluride; and a binder matrix comprising at least w and used to bond the hard particles. [Embodiment] The composition of hard metal materials (comp0siti〇ns) will directly affect the characteristics and application results of hard metals. Of course, the process conditions and equipment in manufacturing will also have an impact on the performance of their properties. Also, hard metal materials The composition also affects the cost of hard metal stock and is related to manufacturing costs. Therefore, finding the composition of the economical hard metal material and having good characteristics is an issue that the industry is striving for. The present invention provides a new hard metal composition having a specially selected binder matrix material and having the advantage of providing superior properties. The hard metal composition of the present invention comprises various hard particles and various binder matrix materials. In general, 'hard particles can be carbides of IVB 'VB and VIB metal elements in the periodic table. For example, metal carbides of ivb have TiC, ZrC, HfC, VB metal carbides are vc, NbC, TaC, VIB Metal: Carbide has ChC2, MhC, WC. The hard particles may also be nitrides of metal elements of the IVB and VB groups of the periodic table, such as metal nitrogen.

1057D-6939-PF 85 119 化物有TiN，ZrN，HfN、VB之金屬氮化物有VN，NbN, TaN。其中，最被廣泛使用之硬粒子材料係碳化鎢，例如是單原子（mono)的WC。許多氮化物可以與碳化物混合而形成硬粒子。亦即，上述的兩種或兩種以上或其他的碳化物與氮化物可以結合而形成wc基硬金屬或非wc基硬金屬。這裡要提醒的是，本案所述之不同碳化物的混合物係不僅限於WC和TiC的混合物、WC、TiC和TaC的混合物。除了不同的碳化物之外，氮化物碳氮化合物、硼化物及矽化物也可當作硬金屬組合物中的硬粒子，在本應用中會敘述各種不同適合的硬粒子。關於黏結劑基質的材料組成，除了提供一基質用以與粒子黏結在一起，也能夠有效地影響硬金屬的硬度與耐火性。一般來說，黏結劑基質可以包含一種或多種的週期表中第八列之過渡金屬’例如c〇, Ni, Fe ;黏結劑基質也可以包含一種或多種的週期表中帛6B列之過渡金屬，例如M〇, &。上述的兩種或兩種以上或其他的黏結劑金屬可以混在一起使用而形成所需要的黏結劑來黏結適當的硬粒子。關於一些黏結劑基質’例如使用具有不同相對重量之Co, Ni 與Mo的組合物。本案所提的硬金屬組合物係基於發明者等的驗證，而提出一特別的黏結劑基質材料，❿能使本發明的硬金屬具有良好的特性而符合不同應用之特別需求。特別是，本案所提的黏結劑基暂4 4；、丨 ’ 劁丞質材枓對於硬金屬的特性有很明顯的改善’例如彈性c e 1 a e+;. 坪庄Ulastleity)、剛性（rigidhy)與強度參數1057D-6939-PF 85 119 The metal nitrides of TiN, ZrN, HfN and VB are VN, NbN, TaN. Among them, the most widely used hard particle material is tungsten carbide, for example, a mono atomic WC. Many nitrides can be mixed with carbides to form hard particles. That is, two or more of the above or other carbides and nitrides may be combined to form a wc-based hard metal or a non-wc-based hard metal. It is to be noted here that the mixture of different carbides described in this case is not limited to a mixture of WC and TiC, a mixture of WC, TiC and TaC. In addition to the different carbides, nitride carbonitrides, borides and tellurides can also be used as hard particles in hard metal compositions, and various suitable hard particles will be described in this application. The material composition of the binder matrix, in addition to providing a matrix for bonding to the particles, can also effectively affect the hardness and fire resistance of the hard metal. In general, the binder matrix may comprise one or more transition metals in the eighth column of the periodic table, such as c〇, Ni, Fe; the binder matrix may also comprise one or more transition metals in column 6B of the periodic table. , for example, M〇, &. Two or more of the above or other binder metals may be used in combination to form the desired binder to bond the appropriate hard particles. With respect to some binder substrates, for example, compositions of Co, Ni and Mo having different relative weights are used. The hard metal composition proposed in the present invention is based on the verification by the inventors and the like, and a special binder matrix material is proposed, which enables the hard metal of the present invention to have good characteristics to meet the special needs of different applications. In particular, the binder base proposed in this case is temporarily 4 4; 丨' 劁丞 material 枓 has a significant improvement in the properties of hard metals [eg elastic ce 1 a e+;. Ulastleity), rigid (rigidhy) Strength parameter

1057D-6939-PF (咖ngth Parameters 含橫切破裂強度、拉伸強度與衝擊強度）。因此，發明者認定本發明所提出之硬金屬組合物中的特別的黏結劑基質材料，能夠改善材料特性而提升硬金屬的特性與效能。 …更特別的是’上述硬金屬組合物中的特別的黏結劑基貞係包含Re、Ni基超合金或—種至少包含犯基超合金和其他黏結劑材料之-的組合物。其他合適的黏結劑材料可以包含，尤其是以或c〇。Ni基超合金在相當高溫下係具籲有高材料強度。由包含有Re與^基超合金的黏結劑材料所組成之硬金屬在高溫下可以具有高的材料強度，且在高溫下可以展現優良的功效。除此之外，州基超合金也展現對腐蝕與氧化的優良抵抗性，如此，當採用川基超合金當作是黏結劑材料時，能夠改善硬金屬的相關抵抗性。β 本案的硬金屬組合物可以包含黏結劑基質材料係佔該硬金屬組合物總體積的3〜4〇體積％，而其相對應的硬粒子所佔的體積比率係97〜60體積％。在上述的體積比率範圍攀中，黏結劑基質材料一般係佔該硬金屬組合物總體積的 4〜35體積％。最好是，黏結劑基質材料係佔該硬金屬組合物、.心體積# 5〜3 0體積。/。。而該黏結劑基質材料佔該硬金屬組合物總重量的重量百分比係可從該硬金屬組合物的特別組合物導出。在許多實施例中，該黏結劑基質主要由Ni基超合金所構成以及包含具有其他元素（例如Re, Co, Ni，Fe，Mo與 Cr)的Ni基超合金的各種組合物。所希望的川基超合金除1057D-6939-PF (Cangng Parameters contains cross-cutting strength, tensile strength and impact strength). Accordingly, the inventors have determined that the particular binder matrix material in the hard metal compositions proposed by the present invention can improve material properties and enhance the properties and performance of hard metals. More particularly, the special binder base in the above hard metal composition comprises a composition comprising a Re, a Ni-based superalloy or a material comprising at least a base superalloy and other binder materials. Other suitable binder materials may be included, especially with or c. Ni-based superalloys have high material strength at relatively high temperatures. A hard metal composed of a binder material containing a Re and a base superalloy can have high material strength at a high temperature and exhibit excellent effects at a high temperature. In addition, state-based superalloys exhibit excellent resistance to corrosion and oxidation, so when using Kawasaki superalloys as binder materials, they can improve the resistance of hard metals. The hard metal composition of the present invention may comprise a binder matrix material in an amount of from 3 to 4% by volume based on the total volume of the hard metal composition, and a corresponding volume ratio of the hard particles in the range of from 97 to 60% by volume. In the above volume ratio range, the binder matrix material generally accounts for 4 to 35 vol% of the total volume of the hard metal composition. Preferably, the binder matrix material accounts for the hard metal composition, and the volume of the core volume is 5 to 30 volumes. /. . The weight percentage of the binder matrix material to the total weight of the hard metal composition can be derived from the particular composition of the hard metal composition. In many embodiments, the binder matrix consists essentially of a Ni-based superalloy and various compositions comprising a Ni-based superalloy having other elements such as Re, Co, Ni, Fe, Mo and Cr. Desirable Chuanji superalloy

1057D-6939-PF 87 1339219 了包含Ni與Co, Cr，Al，Ti，Mo, W之外，也可更包含有Ta， Nb,B，Zr與C的其他元素。例如，Ni基超合金可以包含佔有該超合金該硬金屬組合物總重量之重量百分比的構成金屬：Ni 係 30〜70%，Cr 係 1〇〜3〇%，Co 係 0〜25%，A1 與 Ti 總量係 4-12%、Mo 係〇〜1〇%、w 係 0〜10°/。、Ta 係〇〜1〇% ' Nb係〇〜5°/。以及Hf係〇〜5%。Ni基超合金可更含有個別或雙方的Re和Hf ’例如Re係〇〜10%、Hf係0〜5%。具有 Re的Ni基超合金可以在高溫下被應用。Ni基超合金可更 φ 含有其他元素，例如少量的B，Zr與C。在某些應用中，TaC與NbC在一既定量下具有相似之性質’所以在硬金屬組合物中，TaC與NbC可以互相部分或全部取代對方。在某些硬金屬的設計中，HfC與NbC也可以互相部分或全部取代TaC。WC, TiC，TaC可以被單獨或混合地被製造於固溶的型式中。當一混合物被使用時，該混合物係從下列族群中至少選擇一種，即（丨）Wc，TiC與 TaC的混合物’（2)WC，TiC與NbC的混合物，（3)WC，TiC 籲與至少TaC與NbC中之一的混合物，（4)wc，TiC與至少 HfC與NbC中之-的混合物。多種碳化物的固溶體可以比些奴化物的混合物展現更好的特性和效能。因此，硬粒 —種，即（1)WC，TiC 與 TaC 的1057D-6939-PF 87 1339219 Other elements including Ni, Co, Cr, Al, Ti, Mo, W, and further including Ta, Nb, B, Zr and C. For example, the Ni-based superalloy may comprise a constituent metal in a weight percentage of the total weight of the hard metal composition of the superalloy: Ni system 30 to 70%, Cr system 1 to 3 %, Co system 0 to 25%, A1. The total amount of Ti is 4-12%, Mo is 〇1%, and w is 0~10°/. , Ta system 〇~1〇% ' Nb system 〇~5°/. And Hf system 〇 ~ 5%. The Ni-based superalloy may further contain individual or both Re and Hf' such as Re 〇 10% and Hf 0 to 5%. Ni-based superalloys with Re can be applied at high temperatures. Ni-based superalloys can contain other elements such as a small amount of B, Zr and C. In some applications, TaC and NbC have similar properties at a given level. Therefore, in a hard metal composition, TaC and NbC may partially or completely replace each other. In some hard metal designs, HfC and NbC can also partially or completely replace TaC with each other. WC, TiC, TaC may be produced in a solid solution form either singly or in combination. When a mixture is used, the mixture is selected from at least one of the following groups: (丨) Wc, a mixture of TiC and TaC '(2) WC, a mixture of TiC and NbC, (3) WC, TiC appeals to at least a mixture of one of TaC and NbC, (4) wc, a mixture of TiC and at least HfC and NbC. Solid solutions of multiple carbides can exhibit better properties and performance than mixtures of ensomers. Therefore, hard grain species, ie (1) WC, TiC and TaC

NbC中之一的固溶體。子係從下列族群中至少選擇一種固溶體’（2)WC，TiC與NbC的g 作為黏結劑材料的Ni基超合金可以是在γ_γ，相中，其A solid solution of one of NbC. The sub-system selects at least one solid solution from the following groups: (2) WC, and the Ni-based superalloy of TiC and NbC as the binder material may be in γ_γ, phase,

1057D-6939-PF 88 1^39219 中具有FCC結構的γ，相係與γ相混合，且Ni基超合金在既定含量内，強度會隨著溫度而提升。還有，％基超合金在腐蝕與氧化的抵抗性也有很好的效果。m基超合金可以部分或全部取代在一些C〇基黏結劑組合物中# c〇。本案揭示一製程範例，由於本案的硬金屬中的黏結劑基質中的 Re與Ni基超合金可以有效地提升硬金屬在高溫下的效能，例如由於有低Re的存在而使Ni基超合金能在較低溫 ^ °因而使製程能維持在合理的低溫下燒結而對製程有利。除此之外，黏結劑組合物中的相當低含量的以，可条低黏，纟。劑材料成本’而使這材料具有可行的經濟性。 .相對於黏結劑基質中的特別組成份的所有材料構成，上述Ni基超合金可以佔有數重量百分比到100重量％。典尘的⑷基超合金可以在γ_γ,相增強狀態下主要包含鎳與其 •屬元素以致於隨著溫度提升而展現增強的強度。、跟一般黏結劑材料Co相比，許多Ni基超合金可具有 =車又低的熔點，該Ni基超合金例如是美國Special Metals 么司 1 造的 Rene_95, Udimet 7〇〇, Udimet 72〇，其主要包含1057D-6939-PF 88 1^39219 has γ with FCC structure, phase system is mixed with γ phase, and the strength of Ni-based superalloy increases with temperature within a given content. Also, the %-based superalloy has a good effect on corrosion and oxidation resistance. The m-based superalloy may be partially or fully substituted in some C-based binder compositions #c〇. This case discloses an example of a process. Since the Re and Ni-based superalloys in the binder matrix of the hard metal in this case can effectively improve the performance of the hard metal at high temperatures, for example, the Ni-based superalloy can be obtained due to the presence of low Re. At lower temperatures, the process can be maintained at a reasonable low temperature and is advantageous for the process. In addition, the relatively low content of the binder composition can be low in viscosity and enthalpy. The material cost' makes this material viable economics. The above Ni-based superalloy may occupy several weight percentages to 100% by weight with respect to all materials constituting a specific component in the binder matrix. The (4)-based superalloy of the dust can contain mainly nickel and its genus in the γ_γ phase enhancement state so as to exhibit enhanced strength as the temperature increases. Compared with the general cement material Co, many Ni-based superalloys can have a low melting point of the car, such as Rene_95, Udimet 7〇〇, Udimet 72〇, manufactured by Special Metals, USA. Mainly contains

Nl 並 ^ 合 C〇, Cr，AI，Ti，M〇, Nb，W，B 與 Zr。跟採用 Co 黏結劑的硬金屬比較的話，僅採用上述Ni基超合金的點結劑材料不會增加所得的硬金屬之熔點。 ' ' 在貫施例中，該N i基超合金可以使用於黏 =劑:而改善硬金屬在高溫下（約50(TC或以上）的材料硬又一不具有Ni基超合金於黏結劑令的硬金屬相比較，在 J試許夕忒品（samples)之後證實具有Μ基超合金於黏結 1057D-6939*pp 89 ⑧ 1339219 > 1 , ♦ 劑中的硬金屬的材料硬度和強度確實有明顯的改善，例如在低操作溫度下至少有1 〇%的改善。下表係顯示比較具有 Ni基超合金於黏結劑中的試品”P65”與”P46A”以及具有純 Co的黏結劑試品”P49”與’’P47A”的硬度參數，其比較結果係顯示於表4。黏結劑中的Ni基超合金(簡稱：NS)的效果試品代號 Co 或 NS 黏結劑在室溫下的硬度 Hv(kg/mm2) 在室溫下的表面破裂韌性Ksc (*106Pa.m2) 比較結果 P49 Co : 10vol.% 2186 6.5 P65 NS ： 10vol.% 2532 6.7 Hv値大於P49約 16% P47A Co : 15vol.% 2160 6.4 P46A NS ： 15vol.% 2364 6.4 Hv値大於Ρ47Α約 10% 要注意的是，在500°C以上的操作高溫下，具有Ni基超合金於黏結劑中的硬金屬試品可以展現比不具有Ni基超合金於黏結劑中的硬金屬試品更高的材料硬度。除此之 φ 外，跟使用 Co作為黏結劑的傳統硬金屬或陶瓷金屬相比較，Ni基超合金的黏結劑材料也可以改善所得之硬金屬或陶曼金屬的财腐姓性。Nl and ^ C〇, Cr, AI, Ti, M〇, Nb, W, B and Zr. In comparison with a hard metal using a Co bond, the use of the above-mentioned Ni-based superalloy material does not increase the melting point of the obtained hard metal. In the example, the Ni-based superalloy can be used in the adhesive: to improve the hard metal at high temperatures (about 50 (TC or above) material hard and no Ni-based superalloy in the binder Compared with the hard metal, it is confirmed that the hardness and strength of the hard metal in the agent are confirmed by the sulphide-based superalloy in the test after the test of the test sample. 1057D-6939*pp 89 8 1339219 > Significant improvements, such as at least 1% improvement at low operating temperatures. The following table shows the comparison of samples with the Ni-based superalloy in the binder "P65" and "P46A" and a binder with pure Co. The hardness parameters of the samples "P49" and "'P47A" are shown in Table 4. Effect of Ni-based superalloy (abbreviation: NS) in the binder Sample code Co or NS binder at room temperature Hardness Hv (kg/mm2) Surface fracture toughness at room temperature Ksc (*106Pa.m2) Comparison result P49 Co : 10vol.% 2186 6.5 P65 NS : 10vol.% 2532 6.7 Hv値 is greater than P49 by about 16% P47A Co : 15vol.% 2160 6.4 P46A NS : 15vol.% 2364 6.4 Hv値 is greater than Ρ47Α about 10% It should be noted that At operating temperatures above 500 ° C, hard metal samples with Ni-based superalloys in the binder can exhibit higher material hardness than hard metal samples without Ni-based superalloys in the binder. In addition to the conventional hard metal or ceramic metal using Co as a binder, the Ni-based superalloy binder material can also improve the hardness of the obtained hard metal or Tauman metal.

Ni基超合金可以獨自使用或與其他元素結合而製作想要的黏結劑基質。上述其他元素例如是Re，Co, Ni，Fe， Mo和Cr。Ni基超合金跟上述其他元素結合而形成之黏結劑基質可以是Ni基超合金、其他之Ni基超合金或非Ni 基超合金。使用Re當作是黏結劑材料，能夠提供硬粒子的強結 1057D-6939-PF 90 1339219 s* ' ο強度特別疋可以提供所得之硬金屬材料的高熔點。Re 的熔係3 1 80 C ’遠尚於一般使用的c〇黏結劑材料。亦 ? 15刀地貝獻使用Re當作是黏結劑的硬金屬的優良性質，例如提升所得之硬金屬石更度與在高溫下的強度。Re 也有黏結劑材料所想㈣其他特性。例如，與^具Re黏結 Μ材料的相似硬金屬相比較，具有Re於黏結劑基質中的硬金屬的硬度、杈切破裂強度、破裂韌性以及熔點能夠有明顯的提升。在具有Re於黏結劑基質中的基硬金屬其硬度Hv可達2600kg/mm2以上。而一些示範的wc基硬金屬，其熔點（例如燒結溫度）係大於22〇〇<t。與本案比較，在習知Brookes書中表2」所示之具有c〇黏結劑的wc基硬金属，其燒結溫度係於15〇〇t以下。具有高燒結溫度的硬金屬使得該材料能夠在低於燒結溫度下的高溫下操作。例如，由具有含R e的硬金屬材料所構成之工具能夠在高速下操作而減少製程時間而提升效率。使用Re當作是黏結劑材料於硬金屬中，然而在實際製程中可旎會有一些限制。例如，Re所預期的高溫特性導致製程上需要尚燒結溫度。然而這需要可以操作更高燒結皿度的爐子來進行此製程’但是這種要能夠在2200 以上操作之爐子很責而並不被廣泛使用。在美國專利第547653 j 號中，有揭示一種快速全方向壓製（rapid 〇mnidirecti〇nal compaction，ROC)方法，應用於具有使用6〜8wt%的純Re 來當作是黏結劑材料的WC基硬金屬製程，而用來降低製程溫度。然而這ROC製程仍然很貴而不適用於商業製程。Ni-based superalloys can be used on their own or in combination with other elements to make the desired binder matrix. The other elements mentioned above are, for example, Re, Co, Ni, Fe, Mo and Cr. The binder matrix formed by combining the Ni-based superalloy with the other elements described above may be a Ni-based superalloy, another Ni-based superalloy or a non-Ni-based superalloy. The use of Re as a binder material provides a strong bond of hard particles. 1057D-6939-PF 90 1339219 s* ' ο The strength of the concrete can provide the high melting point of the resulting hard metal material. Re's melting system 3 1 80 C ' is far from the commonly used c〇 binder material. Also, 15 knives use Re as an excellent property of a hard metal which is a binder, such as enhancing the hardness of the hard metal obtained and the strength at a high temperature. Re also has other properties of the binder material (4). For example, the hardness, chopped fracture strength, fracture toughness, and melting point of a hard metal having Re in a binder matrix can be significantly improved as compared with a similar hard metal having a Re-bonded ruthenium material. The hardness Hv of the base hard metal having Re in the matrix of the binder can be up to 2600 kg/mm2 or more. While some exemplary wc-based hard metals have melting points (e.g., sintering temperatures) greater than 22 Å < t. In comparison with the present case, the wc-based hard metal having a c〇 binder as shown in Table 2 of the conventional Brookes book has a sintering temperature of 15 〇〇t or less. A hard metal having a high sintering temperature allows the material to operate at a high temperature below the sintering temperature. For example, a tool composed of a hard metal material containing Re can operate at a high speed to reduce process time and improve efficiency. Re is used as a binder material in hard metals, however there are some limitations in the actual process. For example, the high temperature characteristics expected by Re result in a need for a sintering temperature in the process. However, this requires a furnace that can operate a higher degree of sintering to carry out the process'. However, such a furnace that can operate above 2200 is responsible and not widely used. In U.S. Patent No. 547,653, a rapid omni-directional compaction (ROC) method is disclosed, which is applied to a WC-based hard material having 6 to 8 wt% of pure Re as a binder material. Metal process, used to reduce process temperature. However, this ROC process is still expensive and not suitable for commercial processes.

1057D-6939-PF 91 ⑤ 1339219 > * . * a 上述硬金屬組合物以及此處所敘述之組成方法的一優點，係可以提供或考慮到一額外的實際製程來製造具有使用Re或Re與其他黏結材料的混合物於黏結劑的硬金屬。特別是，這兩階段步驟可以製造硬金屬，該硬金屬中的Re係佔所得的硬金屬的該硬金屬組合物總重量之 25^%以上。如此的具有25wt%以上Re之硬金屬係可達到在高溫下具有高硬度與材料強度。使用純Re當作是硬金屬的黏結劑材料的另—限制係籲 '在35(TC以上的空氣中會嚴重被氧化。這種不良的氧化抵杬性會嚴重影響使用純Re當作黏結劑材料使用於別〇乞以上的應用。因為Ni基超合金在1〇〇(rc以下具有特殊的強度和抗氧化性，因此使用Ni基超合金和Re的混合物當作是黏結劑的話，其中Re係該黏結劑中的支^材才= (dominant materiai)而被用來改善所得的硬金屬的強度和抗氧化性。另一方面，添加額外的Re於只要包含有川基超合金的黏結劑係能夠增加所得硬金屬的熔點範圍，而能鲁改善Ni基超合金黏結劑的高溫強度和抗潛變性 resistance) ° -般而言’ Re所沾之重量比率係為硬金屬中黏結劑總重的數wt%〜l〇〇wt%。最好是，Re所佔之重量比率係為黏結劑總重的5wt%以上。在一些實施例中，黏結劑基質中的Re係佔所得之硬金屬總重的25wt%以上。具有如此高濃1057D-6939-PF 91 5 1339219 > * . * a An advantage of the above hard metal composition and the composition method described herein may be provided or taken into account in an additional practical process for manufacturing with Re or Re and other A mixture of bonding materials is a hard metal to the bonding agent. In particular, the two-stage step can produce a hard metal in which the Re is more than 25% by weight based on the total weight of the hard metal composition of the resulting hard metal. Such a hard metal having a Re of 25% by weight or more can achieve high hardness and material strength at a high temperature. The use of pure Re as a binder material for hard metals is another limitation. It is severely oxidized at 35 (the air above TC. This poor oxidation resistance will seriously affect the use of pure Re as a binder. The material is used in other applications. Because Ni-based superalloys have special strength and oxidation resistance below 1 rc, a mixture of Ni-based superalloy and Re is used as a binder, among which Re The binder in the binder is used to improve the strength and oxidation resistance of the obtained hard metal. On the other hand, an additional Re is added as long as the binder system containing the Kawasaki superalloy is included. It can increase the melting point range of the obtained hard metal, and can improve the high temperature strength and the resistance to the latent change of the Ni-based superalloy adhesive. ° Generally speaking, the weight ratio of Re is the total weight of the binder in the hard metal. Preferably, the weight ratio of Re is more than 5% by weight of the total weight of the binder. In some embodiments, the Re in the binder matrix accounts for the total amount of hard metal obtained. More than 25wt% by weight. With such a high concentration

度的Re係能夠在本案的兩階段製程中以相當低的溫度來製造。又 1057D-6939-PF ⑤ 92 1339219 為Re比其他被使用於硬金屬中的材料責，所以在成什含Re的黏結劑基質時要考慮成本。部分下列例子中係 =映了廷成本考量。一般而言’根據一製程形成一種硬金屬組合拍y，甘4 # 及具有與第It 分散的具有第一材料的硬粒子；以〃材料不同之第二材料之一黏結劑基質；其 J :黏結劑基質包含銖(Re)元素且上述硬粒子係以實 b =勻的方式散佈於該黏結劑基質中。該黏結劑基質可以 ❿ 其他材料的混合物，用以降低Re的總含量而降低原材料的妙杰士 2 t — 成本，並且探測其他黏結劑材料提升該點結劑效果例如該黏結劑基質具有Re和其他人物，該其他材料包含Re與至少^基超合金的混合物: =與至少_ Ni基超合金的混合物、Re，c〇與其他材料的混合物。表1係列出一些硬金屬組成的例子。在這表中， := 係：稱為”硬金屬(ha——)，，，而TiC基組成係被稱為陶t金屬（cermets)”。傳統上，加粒子被^盘m。的混合物冑Ni肖M〇2C的混合物黏結係被稱為，，陶究金屬”。這裡的陶兗金屬可更包括纟Tic與彻的混合物或 t】c、TiN、wc、TaC與Nbc的混合物所構成之粒子，以及由Mm。的混合物或州心。{的混合物所構成之黏 ^每—rn组成’係於表中列出三種不同，量百分率的黏結劑材料。當作是一例子，該黏結劑可以疋ΝΓ基超合金與c〇的混合物，而該等硬粒子可以是 m:，WC的混合^在粒成令，該黏結劑可以佔 1057D-6939-PF 9 3 ⑤ 1339219 4 .. *» 該硬金屬總重的2〜40wt%。該範圍在許多應用中係被設定於3〜3 5 wt%，而且在其他應用中係被設定於4〜3 Owt%。表1 (NS : Ni基超合金，Re :銶，Co :鈷）黏結劑組成硬粒子組成 Γ黏結劑wt.% 範圍 2°d黏結劑wt.% 範圍 3ri黏結劑wt.% 範圍 Re WC 4 to 40 5 to 35 6 to 30 WC-TiC-TaC-NbC 4 to 40 5 to 35 6 to 30 NS WC 2 to 30 3 to 25 4 to 20 WC-TiC-TaC-NbC 2 to 30 3 to 25 4 to 20 硬金屬 NS-Re WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS-Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS Mo2C-TiC 5 to 40 6 to 35 8 to 40 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 40 6 to 35 8 to 40 陶瓷金屬 Re Mo2C-TiC 10 to 55 12 to 50 15 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 10 to 55 12 to 50 15 to 45 NS-Re Mo2C-TiC 5 to 55 6 to 50 8 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 55 6 to 50 8 to 45 製造具有使用Re或Ni基超合金於黏結劑基質的硬金屬可以由下述方法來完成。首先，準備具有所想要的硬粒子的粉末，例如一種或多種的碳化物或碳氮化物。這粉末可以包含不同碳化物的混合物或碳化物與碳氮化物的混合物。然後將這粉末與含有Re或Ni基超合金的適當之黏結劑基質材料混合。除此之外，可添加壓製潤滑劑（例如臘）於上述混合物中。亦即，將上述硬粒子、黏結劑基質材料與潤滑劑藉由輾磨（milling)或研磨（attriting) —段時間（如數小時）而完全地混合，以便使每一硬粒子皆被黏結劑基質材料所被覆，因而促進在後續製程中的硬粒子之結合。上述硬粒子也被潤滑劑所被覆，因而有利於混合製程以及降低或避免硬粒The degree of Re can be manufactured at a relatively low temperature in the two-stage process of the present case. 1057D-6939-PF 5 92 1339219 Re is responsible for other materials used in hard metals, so cost should be considered when forming a binder matrix containing Re. Some of the following examples are based on the cost of the court. Generally, 'a hard metal combination is formed according to a process, gamma 4# and a hard particle having a first material dispersed with the first It; and a binder substrate having a second material different from the bismuth material; The binder matrix contains bismuth (Re) elements and the above hard particles are dispersed in the binder matrix in a solid b = uniform manner. The binder matrix can be used as a mixture of other materials to reduce the total content of Re and reduce the cost of the raw material, and to detect other binder materials to enhance the pointing effect, for example, the binder matrix has Re and Other characters, the other material comprises a mixture of Re and at least a base superalloy: = a mixture with at least a _Ni based superalloy, a mixture of Re, c 〇 and other materials. Table 1 shows an example of some hard metal compositions. In this table, := system: called "hard metal (ha -),,, and TiC-based composition is called cermets". Traditionally, the addition of particles has been made m. The mixture of 胄Ni Xiao M〇2C is known as the "metal". The pottery metal here can further include a mixture of 纟Tic and T or a mixture of t, c, TiN, wc, TaC and Nbc. The particles formed, as well as the mixture of Mm. or the state of the heart. The composition of the mixture of {-- rn consists of three different, percentage percentages of the binder material. As an example, The binder may be a mixture of a cerium-based superalloy and c ,, and the hard particles may be a mixture of m:, WC, and the binder may account for 1057D-6939-PF 9 3 5 1339219 4 . *» The total weight of the hard metal is 2 to 40 wt%. This range is set at 3 to 3 5 wt% in many applications, and is set at 4 to 3 Owt% in other applications. Table 1 (NS : Ni-based superalloy, Re: 銶, Co: Cobalt) Adhesive composition Hard particle composition Γ Adhesive wt.% Range 2°d binder wt.% Range 3ri binder wt.% Range Re WC 4 to 40 5 to 35 6 to 30 WC-TiC-TaC-NbC 4 to 40 5 to 35 6 to 30 NS WC 2 to 30 3 to 25 4 to 20 WC-TiC-TaC-NbC 2 to 30 3 to 25 4 to 20 Hard metal NS-Re WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC- NbC 2 to 40 3 to 35 4 to 30 NS-Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS Mo2C-TiC 5 to 40 6 to 35 8 to 40 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 40 6 to 35 8 to 40 Ceramic metal Re Mo2C-TiC 10 to 55 12 to 50 15 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 10 to 55 12 to 50 15 to 45 NS-Re Mo2C-TiC 5 to 55 6 to 50 8 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 55 6 to 50 8 to 45 Manufactured with Re or Ni The hard metal of the base superalloy in the binder matrix can be accomplished by the following method. First, a powder having the desired hard particles, such as one or more carbides or carbonitrides, is prepared. This powder may comprise a mixture of different carbides or a mixture of carbides and carbonitrides. This powder is then mixed with a suitable binder matrix material containing a Re or Ni based superalloy. In addition to this, a pressing lubricant such as wax may be added to the above mixture. That is, the hard particles, the binder matrix material and the lubricant are completely mixed by milling or atatting for a period of time (eg, several hours) so that each hard particle is adhered to the binder matrix. The material is coated to promote the bonding of hard particles in subsequent processes. The above hard particles are also covered by the lubricant, thus facilitating the mixing process and reducing or avoiding the hard particles.

1057D-6939-PF 94 ⑤ 1339219 > * . · 接者，對上述已研磨的混合物前燒結、成型α Β η 奶連續地進仃壓製、 1以及最終燒結製程，而形成 ==製程係一種藉由在硬粒子炼點以下之溫度加轨，轉變成連續塊狀物，且燒結製程可以在初壓進行。在此製程中，黏結劑材料會被緻密化而形 \續的黏結劑基質來黏結硬粒子於其中。之後，可在所得之硬金屬表面上更被覆額外的一或多層塗佈，而提升硬金属的效能。第丨圖係顯示上述製程的流程圖。在—實施例中，黏結的碳化物之製程包括溶劑中濕、真，乾燥、壓製以及在真空中的液相燒結。液相燒結的溫度係於黏結劑材料的熔點（例如（：〇在1495。〇與硬金屬此合物的共熔溫度（eutectic temp，例如在丨32〇 c)之間。—般而言，黏結的碳化物的燒結溫度係1360〜1480 °c之間。對於在黏結劑合金的具有低濃度的Re或％基超合金之新材料而言，其製程與傳統的黏結的碳化物製程類似。在真空中的液相燒結原理係被應用於此。所以上述燒結溫度係略高於黏結劑合金與碳化物的共熔溫度。例如， P17(黏結劑合金中的Re係25wt%)的燒結條件係在真空甲以1 700 C加熱1小時。第2圖係顯示根據固相燒結的兩階段步驟來製造本發明中各硬金屬的製造流程圖。可以採用兩階段燒結步驟之硬金屬係具有高濃度Re於黏結劑基質中，而不同於需要在高溫下進行之液相燒結。這兩階段燒結步驟可以在較低溫 (22 00°C以下）進行’因而能夠使用傳統的爐子而不用購置 1057D-6939-PF· 95 1339219 ,ν ' ,. • νΓ 昂貴之高溫設備’所以具有經濟性。由於黏結劑合金和碳化物的高共熔溫度而使液相燒結可能無法實施，所以在上述兩階段步驟係捨棄液相燒結。如上所述，在如此高溫燒結係需要能夠在高溫操作的爐子，因此不合乎經濟效益。上述兩階段步驟的第一步驟係一真空燒結，亦即黏結劑基質和硬粒子之混合物材料係於真空中被燒結。該混合物起初被處理過（例如濕磨、乾燥和壓製），其相似於製作黏結的碳化物之傳統製程。燒結的第一步驟係於低於黏結參劑合金與碳化物的共熔溫度的溫度下進行，所以可忽略之間的多孔性問題（porosity)。第二步驟係在低於共熔溫度進行之固相燒結，而且在一加壓條件下而可忽略在第一步驟後殘留於燒結過的混合物中的殘留孔洞問題。熱均壓（h〇t isostatic pressing，HIP)製程可當作是第二步驟燒結。在燒結過程中’經由熱和壓力施加於該材料而降低製程溫度，這不同於沒有壓力的高溫製程。還有，惰性氣體可加於其中而傳遞該壓力到該燒結混合物，其壓力可以超過籲l〇〇〇bar。HIP製程中的壓力可以降低製程溫度以及使其可使用於傳統設備的爐子。用以達成全敏密化的固相燒結和 HIP的溫度通常能顯著地低於液相燒結的溫度。例如，試品P62係使用純Re當作是黏結劑而可以被全緻密化，其條件係在2200°C下進行卜2小時燒結，之後在2〇〇〇<t、 3 0000PSI以及Ar氣氛下進行約1小時的hip製程。要.、主意的是’要使用粒徑小於0.5μιη的極微細硬粒子，因而能降低全緻密化該硬金屬的燒結溫度。例如，在製造試品 1057D-6939-PF 96 1339219 ·» … v b P63時，若使用極微細的WC粒子的話，則燒結溫度可降至約2000。(：。這兩步驟方法比習知美國專利第547653丨號所教導之快速全方向壓製（ROC)方法來得便宜，而符合經濟效益。下段係敘述一些硬金屬的組成和特性的例子，其各種黏結劑基質材料係包含至少有Re或Ni基超合金。表2係舉出一些試品名稱（或批號），其一些組合物係用於形成代表的硬金屬。其中，H1代表Re，而L1，L2, L3 ♦係代表三種市面上的Ni基超合金。表3係更列出上述三種代表的Ni基超合金，其各別為Ud}met 72〇 (U72())，Rene % (R-95)以及Udimet 700 (U7〇〇)。表4係列出代表的硬合金之組成，亦即針對在黏結劑基質中含有或不含有Re或犯基超合金。例如，批號P17的材料組成主要包含有88克的 T32(WC)、3 克的 I32(TiC)、3 克的 A31(TaC)、】5 克的 m(Re) 以及4.5克的L2(R_95)當作是黏結劑，還有2克的臘“η) 當作是潤滑劑。批號P58係只有把Ni基 •黏結劑的硬金屬’而不含Re。這些硬金屬係被製造= 試而敘述有Re與Ni基超合金之一或兩者當作是黏結劑時，其所得之硬金屬的各種特性。表5_8更提供了上述各種不同組成之硬金屬的特性的歸納。第3圖〜第8圖係顯示本案中部分被選擇的試品的量測圖第3、4圖係顯示測量用於切削鋼等級（steei⑶ grade)的些代表性的硬金屬的韌性和硬度參數。第5、6 圖係』示琪]量用於不含鐵切削等級⑶⑴叫1057D-6939-PF 94 5 1339219 > * . · Receiver, before the above-mentioned ground mixture is sintered, the formed α Β η milk is continuously pressed and pressed, 1 and the final sintering process, and the formation of == process is a kind of borrowing It is converted into a continuous mass by the addition of the temperature below the hard particle refining point, and the sintering process can be carried out at the initial pressure. In this process, the binder material is densified and shaped into a continuous matrix of binder to bond the hard particles therein. Thereafter, an additional one or more layers of coating can be applied to the resulting hard metal surface to enhance the performance of the hard metal. The figure is a flow chart showing the above process. In the embodiment, the process of cemented carbide includes wet, true, dry, pressed, and liquid phase sintering in a vacuum. The temperature of the liquid phase sintering is at the melting point of the binder material (for example, (〇 is at 1495. 〇 and the eutectic temp of the hard metal compound (for example, 丨32〇c). The sintering temperature of the bonded carbide is between 1360 and 1480 ° C. For new materials with low concentration of Re or % based superalloy in the binder alloy, the process is similar to the conventional bonded carbide process. The principle of liquid phase sintering in vacuum is applied here. Therefore, the above sintering temperature is slightly higher than the eutectic temperature of the binder alloy and the carbide. For example, the sintering condition of P17 (25 wt% of Re in the cement alloy) It is heated at 1 700 C for 1 hour in vacuum A. Fig. 2 is a flow chart showing the manufacture of each hard metal in the present invention according to a two-stage step of solid phase sintering. The hard metal system can be used in a two-stage sintering step. The concentration Re is in the binder matrix, unlike the liquid phase sintering which needs to be carried out at high temperature. The two-stage sintering step can be carried out at a lower temperature (below 22 00 ° C)' thus enabling the use of a conventional furnace without purchasing 1057 D-6939-PF· 95 1339219 , ν ' ,. • νΓ expensive high-temperature equipment 'is economical. Liquid phase sintering may not be possible due to the high eutectic temperature of the binder alloy and carbide, so the above two The stage step is to abandon the liquid phase sintering. As described above, in such a high temperature sintering system, a furnace capable of operating at a high temperature is required, which is not economical. The first step of the above two-stage step is a vacuum sintering, that is, a binder matrix and The mixture of hard particles is sintered in a vacuum. The mixture is initially treated (eg wet milling, drying and pressing), which is similar to the conventional process for making bonded carbides. The first step of sintering is below the bonding. The temperature of the eutectic alloy and the eutectic temperature of the carbide is carried out, so the porosity problem can be neglected. The second step is solid phase sintering below the eutectic temperature, and under a pressurized condition. The problem of residual pores remaining in the sintered mixture after the first step can be neglected. The hot isostatic pressing (HIP) process can be regarded as Two-step sintering. During the sintering process, the process temperature is lowered by heat and pressure applied to the material, which is different from the high temperature process without pressure. Also, an inert gas may be added thereto to transfer the pressure to the sintered mixture, The pressure can exceed the pressure. The pressure in the HIP process can lower the process temperature and make it available for furnaces used in conventional equipment. The temperature of the solid phase sintering and HIP used to achieve full-sensitivity densification is usually significantly lower. For the temperature of liquid phase sintering, for example, the sample P62 can be fully densified using pure Re as a binder, and the conditions are sintered at 2200 ° C for 2 hours, followed by 2 〇〇〇 < The hip process was carried out for about 1 hour at t, 3 0000 PSI and Ar atmosphere. It is desirable to use very fine hard particles having a particle diameter of less than 0.5 μm, thereby reducing the sintering temperature of the fully densified hard metal. For example, when the test sample 1057D-6939-PF 96 1339219 ·» v b P63 is produced, if extremely fine WC particles are used, the sintering temperature can be lowered to about 2,000. (The two-step method is cheaper than the fast omnidirectional pressing (ROC) method taught by the conventional US Pat. No. 547,653, and is economical. The following section describes examples of the composition and characteristics of some hard metals, various The binder matrix material comprises at least a Re or Ni-based superalloy. Table 2 lists some sample names (or batch numbers), some of which are used to form a representative hard metal, wherein H1 represents Re, and L1 , L2, L3 ♦ represents three kinds of Ni-based superalloys on the market. Table 3 further lists the above three representative Ni-based superalloys, each of which is Ud}met 72〇(U72()), Rene % (R -95) and Udimet 700 (U7〇〇). The composition of the hard alloy represented by the series in Table 4, that is, for the presence or absence of Re or base superalloy in the matrix of the binder. For example, the material composition of batch number P17 is mainly Contains 88 grams of T32 (WC), 3 grams of I32 (TiC), 3 grams of A31 (TaC), 5 grams of m (Re), and 4.5 grams of L2 (R_95) as binders, and 2 grams of wax "η" is used as a lubricant. Lot P58 is only a hard metal of Ni-based binder and does not contain Re These hard metals are manufactured to test the various characteristics of the hard metal obtained when one of the Re and Ni-based superalloys or both are used as a binder. Table 5-8 also provides the hard metals of the above various compositions. The summary of the characteristics. Fig. 3 to Fig. 8 show the measurement charts of some selected samples in this case. Figures 3 and 4 show some representative hard metals measured for cutting steel grade (steei(3) grade). The toughness and hardness parameters. The 5th and 6th drawings are shown in the figure] for the iron-free cutting grade (3) (1)

1057D-6939-PF 97 1339219 9 grade)的一些代表性的硬金屬的韌性和硬度參數。該等測試係於固相燒結HIP製程前與後所進行，且該等測試資料可建議用於HIP製程而有效改善這些材料的韌性和硬度。第 7圖係顯示一些試品的硬度與溫度之關係圖。當做比較，第7、8圖也顯示在同一測試條件下測量市面的C2與C6 碳化物，其中第7圖係顯示熱硬度Hk和溫度之關係，而第 8圖係顯示從室溫到1 000°C的硬度改變狀況。從上述測試圖可清楚發現，根據本發明組合物的硬金屬在高溫硬度方 φ 面勝於市販等級材料。這些結果顯示，與Co基黏結劑基質材料比較，有最好效能之黏結劑基質係具有Re與Ni基超合金之一或兩者而當作是黏結劑材料。表21057D-6939-PF 97 1339219 9 grade) The toughness and hardness parameters of some representative hard metals. These tests are performed before and after the solid phase sintering HIP process, and such test data can be recommended for the HIP process to effectively improve the toughness and hardness of these materials. Figure 7 shows the hardness versus temperature of some samples. For comparison, Figures 7 and 8 also show the measurement of C2 and C6 carbides in the market under the same test conditions, with Figure 7 showing the relationship between hot hardness Hk and temperature, while Figure 8 shows the temperature from room temperature to 1000. The hardness of °C changes. It is clear from the above test chart that the hard metal of the composition according to the present invention is superior to the commercially available grade material in the high temperature hardness. These results show that the best performance binder matrix has one or both of Re and Ni-based superalloys as a binder material compared to Co-based binder matrix materials. Table 2

代疏 (Code) 粉未組成注釋(Note) T32 WC 粒徑1.5μιη ' Alldyne公司製丁3 5 WC 粒徑1.5 μηι、Alldyne公司製 Y20 Mo 粒徑 1.7~2.2μιη、Alldyne 公司製 L3 U-700 -325 網目、Special Metal 公司的 Udimet 700 L1 U-720 -325 網目 ' Special Metal 公司的 Udimet 720 L2 Re-95 -325 網目、Special Metal 公司的 Rene 95 H1 Re -325 網目、Rhenium Alloy 公司製 132 TiC AEE公司製的Ti-302 12] TiB2 AEE公司製的Ti-2(H、卜5μιη A31 TaC AEE公司製的TA-301 Y31 Mo2C AEE公司製的MO-301 D31 VC AEE公司製的VA-301 B1 Co AEE公司製的CO-101 K1 Ni AEE公司製的Ni-101Code Powder No note (Note) T32 WC particle size 1.5μιη ' Alldyne butyl 3 5 WC particle size 1.5 μηι, Alldyne Y20 Mo particle size 1.7~2.2μιη, Alldyne L3 U-700 -325 mesh, Special Metal's Udimet 700 L1 U-720 -325 mesh 'Special Metal's Udimet 720 L2 Re-95 -325 mesh, Special Metal's Rene 95 H1 Re -325 mesh, Rhenium Alloy's 132 TiC Ti-302 manufactured by AEE Corporation 12] Ti-2 manufactured by TiB2 AEE Co., Ltd. (TA, 301, manufactured by TA-301 Y31 Mo2C AEE Co., Ltd., manufactured by TA-301 Y31 Mo2C AEE Co., Ltd., VA-301 B1, manufactured by VC AEE Co., Ltd. Ni-101 by CO-101 K1 Ni AEE Co., Ltd.

1057D-6939-PF 98 ⑤ 1339219 1 * .1057D-6939-PF 98 5 1339219 1 * .

K2 Ni AEE公司製的Ni-102 113 TiN Cerac公司製的T-1153 C21 ZrB2 Cerac公司製的Z-1031 Y6 Mo AEE公司製的Mo+100、1〜2μπι L6 A1 AEE 公司製的 Al-100、1~5μπι R31 b4c ΑΕΕ 公司製的 Bo-301、3μηι T3.8 wc 粒徑0.8μπι、Α1丨dyne公司製 T3.4 wc 粒徑〇.4μπι、OMG公司製 T3.2 wc 粒徑〇.2μπι、OMG公司製表3 Ni Co Cr A1 Ti Mo Nb W Zr B C V R95 61.982 8.04 13.16 3.54 2.53 3.55 3.55 3.54 0.049 0.059 U700 54.331 17.34 15.35 4.04 3.65 5.17 .028 .008 .04 .019 .019 .005 U720 56.334 15.32 16.38 3.06 5.04 3.06 0.01 1.30 .035 .015 .012 .004 表4 批號組成(單位：克） P17 Hl=1.5, L2=4.5, 132=3, A31=3, T32=88, Wax=2 P18 H 卜3, L2=3,132=3, A31=3, T32=88, Wax=2 P19 Hl=1.5, L3=4.5, 132=3, A31=3, T32=88, Wax=2 P20 Hl=3,13=3,132=3, A31=3, T32=88, Wax=2 P25 Hl=3.75, L2=2.25· 132=3, A31=3, T32=88’ Wax=2 P25A Η1 =3.75, L2=2.25, 132=3, A31=3, T32=88, Wax=2 P3I H 1=3.44, B 1=4.4, T32=92.16, Wax=2 P32 Hl=6.75, Bl=2.88, T32=90.37, Wax=2 P33 Hl=9.93, Bl=1.41, T32=88.66, Wax=2 P34 L2=14.47,132=69.44, Y31=16.09 P35 Hl=8.77, L2=10.27,132=65.73, Y31=15.23 P36 Hl=16.66, L2=6.50,132=62.4, Y31 = 14.56 P37 H卜23.80, L2=3.09,132=59.38, Y31=13.76 P38 Kl=15.51，132=68.60, Y31=15.89 P39 K2=15.51, 132=68.60, Y3I=15.89 P40 Hl=7.57, L2=2.96,132=5.32, A31=5.23, T32=78.92, Wax=2 P40A Hl=7.57, L2=2.96,132-5.32, A31=5.23, T32=78.92, Wax=2 P41 L2=1.45,132=5.20, A31=5.11，T32=77.14, Wax=2 P41A H1=11.1,L2=1.45> 132=5.20, A3I=5.11, T32=77.14, Wax=2 P42 Hl=9.32, L2=3.64,132=6.55, A31=6.44,121=0.40, R31=4.25, T32=69.40, Wax=2Ni-102 manufactured by K2 Ni AEE Co., Ltd., T-1153 C21 ZrB2 manufactured by Cerac, Inc., Z-1031 Y6 Mo AEE Co., Ltd., Mo+100, 1~2μπι L6 A1 AEE, Al-100, 1~5μπι R31 b4c ΑΕΕ Bo-301, 3μηι T3.8 wc particle size 0.8μπι, 3.41丨dyne T3.4 wc particle size 4.4μπι, OMG company T3.2 wc particle size 〇.2μπι OMG Company Table 3 Ni Co Cr A1 Ti Mo Nb W Zr BCV R95 61.982 8.04 13.16 3.54 2.53 3.55 3.55 3.54 0.049 0.059 U700 54.331 17.34 15.35 4.04 3.65 5.17 .028 .008 .04 .019 .019 .005 U720 56.334 15.32 16.38 3.06 5.04 3.06 0.01 1.30 .035 .015 .012 .004 Table 4 Batch number composition (unit: gram) P17 Hl=1.5, L2=4.5, 132=3, A31=3, T32=88, Wax=2 P18 H Bu 3 , L2=3,132=3, A31=3, T32=88, Wax=2 P19 Hl=1.5, L3=4.5, 132=3, A31=3, T32=88, Wax=2 P20 Hl=3,13=3,132 =3, A31=3, T32=88, Wax=2 P25 Hl=3.75, L2=2.25·132=3, A31=3, T32=88' Wax=2 P25A Η1 =3.75, L2=2.25, 132=3 , A31=3, T32=88, Wax=2 P3I H 1=3.44, B 1=4.4, T32=92.16, Wax=2 P32 Hl=6.75, Bl=2.88, T32=9 0.37, Wax=2 P33 Hl=9.93, Bl=1.41, T32=88.66, Wax=2 P34 L2=14.47,132=69.44, Y31=16.09 P35 Hl=8.77, L2=10.27,132=65.73, Y31=15.23 P36 Hl=16.66, L2=6.50,132=62.4, Y31= 14.56 P37 HBu 23.80, L2=3.09,132=59.38, Y31=13.76 P38 Kl=15.51,132=68.60, Y31=15.89 P39 K2=15.51, 132= 68.60, Y3I=15.89 P40 Hl=7.57, L2=2.96,132=5.32, A31=5.23, T32=78.92, Wax=2 P40A Hl=7.57, L2=2.96,132-5.32, A31=5.23, T32=78.92, Wax=2 P41 L2=1.45,132=5.20, A31=5.11, T32=77.14, Wax=2 P41A H1=11.1, L2=1.45> 132=5.20, A3I=5.11, T32=77.14, Wax=2 P42 Hl =9.32, L2=3.64,132=6.55, A31=6.44,121=0.40, R31=4.25, T32=69.40, Wax=2

1057D-6939-PF 99 ⑤ 1339219 .V …1057D-6939-PF 99 5 1339219 .V ...

P43 Hl=9.04? L2=3.53,132=6.35, A31=6.24, 121=7.39, R31=0.22, T32=67.24, Wax=2 P44 m=8.96, L2=3.50,132=14.69, A31=6.19. T32=66.67, Wax=2 P45 Hl=9.37. L2=3.66, 132=15.37, A31=6.47: Y31 =6.51, T32=58.61, Wax=2 P46 H卜 11.40, L2=4.45,132=5.34f A31=5,25, T32=73.55, Wax=2 P46A Hl = 11.40, L2=4.45,132=5.34, A31-5.25, T32=73.55? Wax=2 P47 Hl=11.35, Bl=4.88, 132=5.32. A31=5.23, T32=73.22, Wax=2 P47A HI = I1.35, Bl=4.88,132=5.32, A31=5.23, T32=73.22. Wax=2 P48 Hl=3.75, L2=2.25,132=5, A31=5, T32=84? Wax=2 P49 Hl=7.55f Bl=3.25; 132=5.31, A31=5.2L T32=78.68, Wax=2 P50 HI =4.83, L2=1.89, 132=5.31, A31-5.22, T32=82.75. Wax=2 P51 H 1=7.15, L2=0.93, 132=5.23, A31=5.14, T32=81.55, Wax=2 P52 Bl=8? D31=0.6, T3.8=91.4, Wax=2 P53 Bl=8, D31=0.6, T3.4=91.4, Wax-2 P54 Bl=8, D31=0.6, T3.2=91.4, Wax=2 P55 Hl=1.8, Bl=7.2, D31=0.6; T3.4=90.4, Wax=2 P56 Hl=1.8, Bl=7,2, D31=0.6, T3.2=90.4, Wax=2 P56A Hl=1.8, Bl=7.2, D3卜0.6, T3.2=90.4, Wax=2 P57 Hl=1.8, Bl=7.2, T3.2=91，Wax=2 P58 L2=7.5, D31=0.6. T3.2=91.9, Wax=2 P59 HI =0.4, Bl=3, L2=4.5, D31=0.6, T3.2=91.5, Wax=2 P62 Hl = 14.48,132=5.09, A31=5.00’ T3.2=75.43, Wax=2 P62A H 1=14.48, 132=5.09, A31=5.00, T3.2=75.43, Wax=2 P63 Hl=12.47, L2=0.86, 132=5.16, A31=5.07, T3.2=76.45, Wax=2 P65 Hl=7.57, L2=2.96,132=5.32, A31=5.23, T3.2=78.92T Wax=2 P65A Hl=7.57, L2=2.96,132=5.32, A31=5.23, T3.2=78.92. Wax=2 P66 Hl=27.92,132=4.91, A31=4.82, T3.2=62.35, Wax=2 P67 Hl=24.37, L3=1.62,132-5.04, A31=4.95, T32=32.01, T33=32.0L Wax=2 P69 L2=7.5, D31=0.4, T3.2=92.1, Wax=2 P70 Ll=7.4, D31=0.3, T3.2=92.3, Wax=2 P71 L3=7.2, D31=0.3, T3.2=92.5, Wax=2 P72 Hl=1.8, Bl=7.2, D31=0.3, T3.2=90.7, Wax=2 P73 HI = I.8, 81=4.8, L2=2.7, D3I=0.3, T3.2=90.4f Wax=2 P74 Hl=1.8, Bl=3, L2=4.5, D31=0.3, T3.2=90.4, Wax=2 P75 Hl=0.8, Bl=3, L2=4.5, D31=0.3, T3.2=91.4, Wax=2 P76 Hl=0.8; Bl=3, Ll=4.5, D31=0.3, T3.2=91.4, Wax=2 P77 Hl=0.8, Bl=3, L3=4.5, D31=0.3, T3.2=91.4, Wax=2 P78 Hl=0.8, Bl=4,5, Ll=3, D31=0.3. T3.2=91.4, Wax=2 P79 Hl=0.8, Bl=4.5, L3=3.1, D31=0.3, T3.2=91.3, Wax=2 許多代表性種類的硬金屬組成係如下述，用以說明這些硬金屬的設計係包含有Re與Ni基超合金之一或兩者。這些代表性種類的硬金屬組成係基於用於所得硬金屬或陶P43 Hl=9.04? L2=3.53,132=6.35, A31=6.24, 121=7.39, R31=0.22, T32=67.24, Wax=2 P44 m=8.96, L2=3.50,132=14.69, A31=6.19. T32 =66.67, Wax=2 P45 Hl=9.37. L2=3.66, 132=15.37, A31=6.47: Y31=6.51, T32=58.61, Wax=2 P46 Hb 11.40, L2=4.45,132=5.34f A31=5 , 25, T32=73.55, Wax=2 P46A Hl = 11.40, L2=4.45,132=5.34, A31-5.25, T32=73.55? Wax=2 P47 Hl=11.35, Bl=4.88, 132=5.32. A31=5.23 , T32=73.22, Wax=2 P47A HI = I1.35, Bl=4.88,132=5.32, A31=5.23, T32=73.22. Wax=2 P48 Hl=3.75, L2=2.25,132=5, A31=5 , T32=84? Wax=2 P49 Hl=7.55f Bl=3.25; 132=5.31, A31=5.2L T32=78.68, Wax=2 P50 HI=4.83, L2=1.89, 132=5.31, A31-5.22, T32 =82.75. Wax=2 P51 H 1=7.15, L2=0.93, 132=5.23, A31=5.14, T32=81.55, Wax=2 P52 Bl=8? D31=0.6, T3.8=91.4, Wax=2 P53 Bl=8, D31=0.6, T3.4=91.4, Wax-2 P54 Bl=8, D31=0.6, T3.2=91.4, Wax=2 P55 Hl=1.8, Bl=7.2, D31=0.6; T3. 4=90.4, Wax=2 P56 Hl=1.8, Bl=7,2, D31=0.6, T3.2=90.4, Wax=2 P56A Hl=1.8, Bl=7.2, D3 Bu 0.6, T3.2=90.4, Wax=2 P57 Hl=1.8, Bl=7.2, T3.2=91, Wax=2 P58 L2=7.5, D31=0.6 T3.2=91.9, Wax=2 P59 HI =0.4, Bl=3, L2=4.5, D31=0.6, T3.2=91.5, Wax=2 P62 Hl = 14.48,132=5.09, A31=5.00' T3 .2=75.43, Wax=2 P62A H 1=14.48, 132=5.09, A31=5.00, T3.2=75.43, Wax=2 P63 Hl=12.47, L2=0.86, 132=5.16, A31=5.07, T3. 2=76.45, Wax=2 P65 Hl=7.57, L2=2.96,132=5.32, A31=5.23, T3.2=78.92T Wax=2 P65A Hl=7.57, L2=2.96,132=5.32, A31=5.23, T3.2=78.92. Wax=2 P66 Hl=27.92,132=4.91, A31=4.82, T3.2=62.35, Wax=2 P67 Hl=24.37, L3=1.62,132-5.04, A31=4.95, T32= 32.01, T33=32.0L Wax=2 P69 L2=7.5, D31=0.4, T3.2=92.1, Wax=2 P70 Ll=7.4, D31=0.3, T3.2=92.3, Wax=2 P71 L3=7.2, D31=0.3, T3.2=92.5, Wax=2 P72 Hl=1.8, Bl=7.2, D31=0.3, T3.2=90.7, Wax=2 P73 HI = I.8, 81=4.8, L2=2.7, D3I=0.3, T3.2=90.4f Wax=2 P74 Hl=1.8, Bl=3, L2=4.5, D31=0.3, T3.2=90.4, Wax=2 P75 Hl=0.8, Bl=3, L2= 4.5, D31=0.3, T3.2=91.4, Wax=2 P76 Hl=0.8; Bl=3, Ll=4.5, D31=0.3, T3.2=91.4, Wax=2 P77 Hl=0.8, Bl=3, L3=4.5, D31=0.3, T3.2=91.4, Wax=2 P78 Hl=0.8, Bl=4,5, Ll=3, D31=0.3. T3.2=91.4, Wax=2 P79 Hl=0.8, Bl=4.5, L3=3 .1, D31=0.3, T3.2=91.3, Wax=2 Many representative types of hard metal compositions are as follows to illustrate that these hard metal designs contain one or both of Re and Ni-based superalloys. . These representative types of hard metal compositions are based on the hard metal or ceramic used to obtain

1057D-6939-PF 100 ⑤ 13392191057D-6939-PF 100 5 1339219

^金屬之黏結劑基質的組成而定義。帛__使用具有纯之黏結劑基質，第二類係使用具有Re心的黏結劑基、第二類係使用具有Ni基超合金的黏結劑基質，而第四 :係使用具有結合Re而沒有co的Ni基超合金的黏結劑基質。一般來說，用於硬金屬的硬且耐火的粒子係可以包括^ Defined by the composition of the metal binder matrix.帛__ uses a matrix of pure binder, the second type uses a binder base with Re core, the second type uses a binder matrix with a Ni-based superalloy, and the fourth: uses a combination of Re without Co-based Ni-based superalloy binder matrix. In general, hard and refractory particle systems for hard metals can include

碳化物、氮化物、碳氮化物、硼化物以及矽化物。其中碳化物例如是 WC，TiC，TaC，HfC，NbC，M〇2C，Cr2C3, vc, ZrC 籲B4C與Sic。其中氮化物例如是TiN，ZrN, HfN，VN,細， TaN與BN。其中碳氮化物例如是Ti(c,N), Ta(c，N)，Carbides, nitrides, carbonitrides, borides, and tellurides. Among them, the carbides are, for example, WC, TiC, TaC, HfC, NbC, M〇2C, Cr2C3, vc, ZrC, B4C and Sic. Among them, nitrides are, for example, TiN, ZrN, HfN, VN, fine, TaN and BN. Wherein carbonitrides are, for example, Ti(c,N), Ta(c,N),

Nb(C，N)，V(C，N)，Zr(C，N)。其中硼化物例如是 TiB2, ZrB2 HfB2, TaB2, VB2, MoB2, WB與W2B。其中矽化物例如是 TaSi2，WSi2，NbSi2與MoSi2。上述四種類的硬金屬或陶瓷金屬也能夠使用這些和其他硬且耐火的粒子。在第一類的使用具有純Re之黏結劑基質的硬金屬或陶瓷金屬中’ Re係佔整體硬金屬或陶瓷金屬體積的約籲5~40ν〇1.〇/〇。例如表4中的批號P62具有Re 10v〇1 %、wc 70vol.%、TiC 1 5vol·%以及 TaC 5vol.%，該組成可換算成Nb (C, N), V (C, N), Zr (C, N). Among them, the borides are, for example, TiB2, ZrB2 HfB2, TaB2, VB2, MoB2, WB and W2B. Among them, the tellurides are, for example, TaSi2, WSi2, NbSi2 and MoSi2. These and other hard and refractory particles can also be used for the above four types of hard or ceramic metals. In the first type of hard metal or ceramic metal using a binder substrate having a pure Re, the Re system accounts for about 5 to 40 ν 〇〇〇〇 of the volume of the entire hard metal or ceramic metal. For example, the lot number P62 in Table 4 has Re 10v〇1%, wc 70vol.%, TiC 1 5vol·%, and TaC 5vol.%, and the composition can be converted into

Re 14.48wt·%、WC 75.43wt.%、TiC 5.09wt.% 以及丁aC 5.0wt.%。在製程中，試片P62-4係以2100°C真空燒結約i 小時以及2158°C真空燒結約1小時。該材料的密度約係 14.51g/cc，其計算密度（理想密度）係14.50g/cc。在室溫下的lCKg荷重下測量10次的平均硬度係2627±35Kg/mm2。所測的表面破壞韌性Ksc係約7.4E6Pa.ru1/2,其係以在1 〇KgRe 14.48 wt.%, WC 75.43 wt.%, TiC 5.09 wt.%, and D-A 5.0 5.0 wt.%. In the process, the test piece P62-4 was vacuum sintered at 2100 ° C for about 1 hour and vacuum sintered at 2158 ° C for about 1 hour. The material has a density of about 14.51 g/cc and a calculated density (ideal density) of 14.50 g/cc. The average hardness measured 10 times at a lCKg load at room temperature was 2627 ± 35 kg/mm 2 . The surface fracture toughness measured by Ksc is about 7.4E6Pa.ru1/2, which is at 1 〇Kg.

1057D-6939-PF 101 ⑧ 1339219 '· · 荷重下的.Palmvist破裂強度而估計而得。在此種類下的另一個例子是表4中的p 6 6。批號P 6 6 的組成具有 Re 20vol·%、WC 60vol.%、Tic 15vol.%以及 TaC 5vol.%，該組成可換算成 Re 27.92wt.%、WC 62‘35wt·%、TiC 4.91wt.0/〇以及 TaC 4‘82wt.〇/〇。試片 P66-4 係先以2200°C真空燒結約1小時，然後在固相中以HIP製程除去多孔與孔隙。所得之硬金屬的密度約係14 4〇g/cc，其計算密度係1 5.04g/cc。在室溫下的1 〇Kg荷重下測量7 φ 次的平均硬度係2402±44Kg/mm2。所測的表面破壞物性kSc 係約8.1 E6Pa’m |/2。試品P66以及在此所述的其他具有高濃度Re(重量百分比大於25%)的組合物，係當作獨一的黏結劑材料或黏結劑中的兩種或多種不同黏結劑材料之一，其能夠用於高操作溫度下的各種應用，以及可基於固相燒結的兩階段製程。硬财火粒子的與Re多重化合種類的微結構和特性，例如碳化物、氮化物、碳氮化物、碎化物以及主體係能 •夠提供比與Re化合的WC材料更多的優點。例如，與 WC-TiC-TaC化合的Re係能夠提供比與wc材料化合的以更好的切削鋼的抗坑孔（crater resistance)特性。另一例子係由MhC耐火粒子以及與TiC化合於其中的Re黏結劑所構成之材料。關於第二類的具有Re_c〇合金之黏結劑基質，該 Re-Co合金約佔總體材料組成之5〜4〇v〇h%。在一些實施例中，黏結劑中的Re/Co之比例係約〇〇卜〇 99。跟具有化合1057D-6939-PF 101 8 1339219 '· · Estimated by the strength of the Palmvist under the load. Another example under this category is p 6 6 in Table 4. The composition of the batch number P 6 6 has Re 20 vol·%, WC 60 vol.%, Tic 15 vol.%, and TaC 5 vol.%, and the composition can be converted into Re 27.92 wt.%, WC 62'35 wt.%, TiC 4.91 wt. /〇 and TaC 4'82wt.〇/〇. The test piece P66-4 was first vacuum sintered at 2200 ° C for about 1 hour, and then the pores and pores were removed by a HIP process in a solid phase. The resulting hard metal had a density of about 14 4 g/cc and a calculated density of 1 5.04 g/cc. The average hardness of 7 φ times measured at 1 〇Kg load at room temperature was 2402 ± 44 Kg/mm 2 . The surface damage property kSc measured was about 8.1 E6 Pa'm |/2. Test sample P66 and other compositions having a high concentration of Re (greater than 25% by weight) as described herein are regarded as one of two or more different binder materials in a unique binder material or binder. It can be used in a variety of applications at high operating temperatures, as well as a two-stage process based on solid phase sintering. The microstructures and properties of the hard-fired particles and Re multiple types, such as carbides, nitrides, carbonitrides, shreds, and host systems, provide more advantages than Re-combined WC materials. For example, the Re series combined with WC-TiC-TaC can provide better crater resistance characteristics than steel materials combined with wc materials. Another example is a material composed of MhC refractory particles and a Re binder in which TiC is compounded. Regarding the second type of binder matrix having a Re_c〇 alloy, the Re-Co alloy accounts for about 5 to 4 〇v〇h% of the total material composition. In some embodiments, the ratio of Re/Co in the binder is about 〇〇〇。 99. With a combination

1057D-6939-PF ⑧⑩ 102 1339219 u < » I · (* > C〇的硬金屬相比較’含有Re的組合物可以改善所得硬金屬的機械性質，例如在高溫下的硬度、強度和韌性。黏結劑基質中的Re含量越多的話，則在高溫下的特性越好。此種類的另一個例子是表4中的P3 1。P3 1的組成具有 Re 2.5v〇l.%、c〇 7.5vol·%以及 WC 90vol.%，該組成可換算成 Re 3.44wt.%、Co 4.40wt.%以及 WC 92.12wt.%。在製程中’試片P31-1係以17251真空燒結約1小時，在此燒結下有少量的孔洞存在。所得硬金屬的密度約係 • 15.16g/cc，其計算密度係15.27g/cc。在室溫下的l〇Kg荷重下測的平均硬度係1 8 8 9 ± 1 8 K g / m m2。所測的表面破壞動性Ksc係約7.7E6Pa.m1/2。除此之外，在燒結之後，試片 P3 1-I再經過約i600t：/15Ksi之約一小時的HIP處理。該 HIP處理可以實質地消除混合物中的空孔間隙，而增加材料密度。經過HIP處理之後，所測得的密度約是15.25g/cc，其計算密度係1 5.27g/cc。在室溫下的1 〇Kg荷重下測的平均硬度係1 889± 1 8Kg/mm2。所測的表面破壞韌性Ksc係約 Φ 7.6E6Pa.m丨/2。此種類的另一個例子是表4中的P32。P32的組成具有 Re 5.0vol.%、Co 5·0vol.%以及 WC 90vol.%，該組成可換算成 Re 6.75wt.°/〇、Co 2.88wt.%以及 WC 90.38wt.%。在製程中，試片P32_4係以1 800。(：真空燒結約1小時。所得硬金屬的密度約係15_58g/cc，其計算密度係1 5.57g/cc。在室溫下的1 〇Kg荷重下測的平均硬度係2065Kg/mm2。所測的表面破壞韌性Ksc係約5.9E6Pa.m1/2。在燒結之後，試片 1057D-6939-PF 103 1339219 Λ ' ♦ <» ϊ Ρ3 2-4亦再經過約ι 600°C /l5Ksi之約一小時的hip處理。經過HIP處理之後，所測得的密度約是1 5.57g/cc，其計算密度係1 5 · 5 7g/cc。在室溫下的1 〇Kg荷重下測的平均硬度係 2012±12Kg/mm2。所測的表面破壞物性Ksc係約 5.8E6Pa.mW2。第三個例子是表4中的P33°P33的組成具有Re 7.5 v ο 1 · %、C 〇 2.5 v ο 1 · % 以及 W C 9 0 v ο 1. % ’ 該組成可換算成 Re 9.93wt·%、Co 1.4 1 wt·%以及 WC 8 8_66wt.%。在製程中， # 試片Ρ33·7係以195〇°C真空燒結約1小時，且仍有孔隙存在。所得硬金屬的密度約係15.38g/cc，其計算密度係 15.87g/cc。在室溫下的10Kg荷重下測的平均硬度係 20 8 1 Kg/mm2。所測的表面破壞勃性Ksc係約5.6E6Pa，m1/2。在燒結之後，試片P33-7亦再經過約1600°C /15Ksi之約一小時的HIP處理。經過HIP處理之後，所測得的密度約是 15.82g/cc，其計算密度係15.87g/cc。在室溫下的10Kg荷重下測的平均硬度係2039士 1 8Kg/mm2。所測的表面破壞動鲁性 Ksc 係約 6.5E6Pa.m1/2。表5化合有Re-Co合金的硬金屬溫度。C 密度g/cc 硬度韌性晶粒尺寸燒結 HIP 計算的測量的 Kg/mm2 xlO6 Pa-m1/2 P55-1 1350 1300 14.77 14.79 2047 8.6 極細 P56-5 1360 1300 14.77 14,72 2133 8.6 極細 P56A-4 1350 1300 14.77 14.71 2108 8.5 極細 P57-1 1350 1300 14.91 14.93 1747 12.3 細表4中的試品P55、P56A以及P57係具有將Re-Co合金 1057D-6939-PF 104 ⑧ 1339219 te · 當作黏結劑基質的種類之例子。除了 P57不含VC之外，這些試品係含有Re 1.8%、Co 7.2%以及VC 0.6%，其餘是WC。這些不同的組成係用來研究硬金屬的晶粒尺寸對硬度Hv與韌性 Ksc的影響。表6 Ni基超合金，Ni, Re與Co的特性測試溫度 C R-95 U-700 U720 Ni Re Co 密 iS(g/CX·) 21 8.2 7.9 8.1 8.9 21 8.9 熔點(°c) 1255 1205 1210 1450 3180 1495 彈性係數(Gpa) 21 30.3 32.4 32.2 207 460 211 最大拉伸強度 (Mpa) 21 1620 1410 1570 317 1069 234 760 1170 1035 1455 800 620 870 690 1150 1200 414 0.2% 降伏強度 (Mpa) 21 1310 965 1195 60 760 1100 825 1050 800 870 635 1200 拉伸延長率 (%) 21 15 17 13 30 >15 760 15 20 9 800 5 870 27 1200 2 抗氧化性優優優好差好1057D-6939-PF 810 102 1339219 u < » I · (* > C〇 hard metal phase comparison 'Re-containing composition can improve the mechanical properties of the resulting hard metal, such as hardness, strength and toughness at high temperatures The more the Re content in the binder matrix, the better the characteristics at high temperatures. Another example of this species is P3 1 in Table 4. The composition of P3 1 has Re 2.5v〇l.%, c〇 7.5 vol·% and WC 90 vol.%, the composition can be converted into Re 3.44 wt.%, Co 4.40 wt.%, and WC 92.12 wt.%. In the process, the test piece P31-1 is vacuum sintered at 17251 for about 1 hour. There is a small amount of pores in the sintering. The density of the obtained hard metal is about 15.16g/cc, and the calculated density is 15.27g/cc. The average hardness measured under the l〇Kg load at room temperature is 18 8 9 ± 1 8 K g / m m2. The measured surface damage dynamic Ksc is about 7.7E6Pa.m1/2. In addition, after sintering, the test piece P3 1-I passes through about i600t: /15Ksi. About one hour of HIP treatment. The HIP treatment can substantially eliminate the void gap in the mixture and increase the material density. After HIP treatment, The obtained density was about 15.25 g/cc, and the calculated density was 15.27 g/cc. The average hardness measured under a 1 〇 Kg load at room temperature was 1 889 ± 1 8 Kg/mm 2 . The measured surface failure toughness Ksc It is about Φ 7.6E6Pa.m丨/2. Another example of this kind is P32 in Table 4. The composition of P32 has Re 5.0vol.%, Co 5·0vol.%, and WC 90vol.%, which can be converted. Re 6.75 wt. ° / 〇, Co 2.88 wt.% and WC 90.38 wt.%. In the process, the test piece P32_4 is 1 800. (: vacuum sintering for about 1 hour. The density of the obtained hard metal is about 15_58g / Cc, which has a calculated density of 1.57 g/cc. The average hardness measured under a 1 〇 Kg load at room temperature is 2065 Kg/mm 2 . The measured surface fracture toughness Ksc is about 5.9E6 Pa.m 1/2. , test piece 1057D-6939-PF 103 1339219 Λ ' ♦ <» ϊ Ρ 3 2-4 is also subjected to about one hour of hip treatment at about 600 ° C / l5 Ksi. After HIP treatment, the measured density is about It is 1 5.57 g/cc, and its calculated density is 1 5 · 5 7 g/cc. The average hardness measured under a 1 〇 Kg load at room temperature is 2012 ± 12 kg/mm 2 . The surface destructive property Ksc measured was about 5.8E6Pa.mW2. The third example is that the composition of P33°P33 in Table 4 has Re 7.5 v ο 1 · %, C 〇 2.5 v ο 1 · %, and WC 9 0 v ο 1. % ' This composition can be converted into Re 9.93wt· %, Co 1.4 1 wt·%, and WC 8 8_66 wt.%. In the process, #片片Ρ33·7 was vacuum sintered at 195 °C for about 1 hour, and there were still pores. The resulting hard metal had a density of about 15.38 g/cc and a calculated density of 15.87 g/cc. The average hardness measured at a load of 10 Kg at room temperature was 20 8 1 Kg/mm 2 . The surface damage measured was about 5.6E6 Pa, m1/2. After sintering, the test piece P33-7 was further subjected to HIP treatment at about 1600 ° C / 15 Ksi for about one hour. After HIP treatment, the measured density was about 15.82 g/cc and its calculated density was 15.87 g/cc. The average hardness measured under a load of 10 kg at room temperature was 2039 ± 18 kg/mm 2 . The measured surface damage dynamic Ksc is about 6.5E6Pa.m1/2. Table 5 combines the hard metal temperature of the Re-Co alloy. C Density g/cc Hardness toughness Grain size Sintered HIP Calculated Kg/mm2 xlO6 Pa-m1/2 P55-1 1350 1300 14.77 14.79 2047 8.6 Very fine P56-5 1360 1300 14.77 14,72 2133 8.6 Very fine P56A-4 1350 1300 14.77 14.71 2108 8.5 Very fine P57-1 1350 1300 14.91 14.93 1747 12.3 The test specimens P55, P56A and P57 in Table 4 have Re-Co alloy 1057D-6939-PF 104 8 1339219 te · as the binder matrix An example of the kind. Except that P57 does not contain VC, these samples contain Re 1.8%, Co 7.2%, and VC 0.6%, and the rest are WC. These different compositions are used to study the effect of grain size of hard metals on hardness Hv and toughness Ksc. Table 6 Characteristics of Ni-based superalloys, Ni, Re and Co Test temperature C R-95 U-700 U720 Ni Re Co MiS(g/CX·) 21 8.2 7.9 8.1 8.9 21 8.9 Melting point (°c) 1255 1205 1210 1450 3180 1495 Elasticity (Gpa) 21 30.3 32.4 32.2 207 460 211 Maximum tensile strength (Mpa) 21 1620 1410 1570 317 1069 234 760 1170 1035 1455 800 620 870 690 1150 1200 414 0.2% Falling strength (Mpa) 21 1310 965 1195 60 760 1100 825 1050 800 870 635 1200 Tensile elongation (%) 21 15 17 13 30 >15 760 15 20 9 800 5 870 27 1200 2 Excellent oxidation resistance

第三種類係根據具有Ni基超合金的黏結劑基質，其 Ni基超合金係佔所得硬金屬中所有材料的5〜40vol.%。Ni 基超合金係具有γ’強化機制的高溫合金。三種不同的強化合金Rene’95, Udimet 720與Udimet 700係被當作是例子而展現黏結劑強度效應於硬金屬的機械性質。該等Ni基超合金特別在高溫下具有高強度，而且具有良好的環境抵抗The third type is based on a binder matrix having a Ni-based superalloy, and the Ni-based superalloy is 5 to 40 vol.% of all materials in the obtained hard metal. The Ni-based superalloy is a superalloy having a γ' strengthening mechanism. Three different reinforced alloys, Rene’95, Udimet 720 and Udimet 700, were used as examples to demonstrate the effect of binder strength on the mechanical properties of hard metals. These Ni-based superalloys have high strength especially at high temperatures and have good environmental resistance.

1057D-6939-PF 105 ⑧ 性，例如抗蝕、抗氧化。因此，與化合有c〇的硬金屬相比毂，該等Ni基超合金可以增加化合有川基超合金的硬金屬之硬度。要注意的是，如表6所示，該等Ni基超合金的拉伸強度遠大於一般黏結劑材料Co。這顯示Ni基超合金士於硬金屬來說’是一個报好的黏結劑材料。此種類的一例是表4中的P580P58的組成具有1057D-6939-PF 105 8 properties, such as corrosion resistance, oxidation resistance. Therefore, compared with the hard metal in which c〇 is combined, the Ni-based superalloys can increase the hardness of the hard metal compounded with the Kawasaki superalloy. It should be noted that, as shown in Table 6, the tensile strength of the Ni-based superalloys is much larger than that of the general binder material Co. This shows that Ni-based superalloys are a good binder material for hard metals. An example of this kind is the composition of P580P58 in Table 4

Rene’95 7.5wt.%、VC 0,6wt.%以及 WC 9l.9wt·%，並與表 4 中的 Co 化合物 P54(8%C〇, 0.6%VC 與 91.4%WC)比較。如表7所示，P58的硬度明顯大於P54。表7 P54和P58的比較燒結 HIP 硬度 (Kg/mm2) 章刀性 (\in6 P。一 1/2、 P54-1 1350°C /lhr 在 Ar lhr 下，1305°C， 15KSI 2094 8.8 P54-2 138〇t /lhr 2071 7.8 _ P54-3 142〇t / lhr 2107 8.5 P58-1 在 1350, 1380, 1400, 1420, 1450, 1475 的各溫度°C下lhr 2322 7.0 P58-3 1450〇C / lhr 2272 7.4 P58-5 1500°C / lhr 2259 7.2 P58-7 1550〇C / lhr 2246 7.3 第四種類係Ni基超合金加上Re而當作是黏結劑基質’其係佔所得硬金屬或陶瓷金屬中所有材料的 5〜40vol.%。因為添加Re可增加上述添加有Re的m基超Rene'95 7.5 wt.%, VC 0, 6 wt.% and WC 9l.9 wt.%, and compared with the Co compound P54 (8% C 〇, 0.6% VC and 91.4% WC) in Table 4. As shown in Table 7, the hardness of P58 is significantly greater than P54. Table 7 Comparison of P54 and P58 Sintered HIP Hardness (Kg/mm2) Clarity (\in6 P. One 1/2, P54-1 1350 °C /lhr Under Ar lhr, 1305 ° C, 15KSI 2094 8.8 P54- 2 138〇t /lhr 2071 7.8 _ P54-3 142〇t / lhr 2107 8.5 P58-1 at 1350, 1380, 1400, 1420, 1450, 1475 at each temperature °C lhr 2322 7.0 P58-3 1450〇C / Lhr 2272 7.4 P58-5 1500 ° C / lhr 2259 7.2 P58-7 1550 〇 C / lhr 2246 7.3 The fourth type is a Ni-based superalloy with Re as a binder matrix' which is the resulting hard metal or ceramic 5~40vol.% of all materials in the metal. Because the addition of Re can increase the above-mentioned m-based super added with Re

合金的黏結劑的熔點’所以當Re含量增加時，具有上述添加有Re的Ni基超合金的硬金屬的製程溫度就會跟著增加。具有不同Re濃度之各種硬金屬係列於表8中。表9 則顯示列於表8中之硬金屬的所測性質。 1057D-6939-PF 106 ⑧ 1339219 表8具有Ni基超合金與Re的黏結劑之硬金屬The melting point of the alloy binder is such that when the Re content is increased, the process temperature of the hard metal having the above Ni-based superalloy added with Re increases. A list of various hard metals having different Re concentrations is shown in Table 8. Table 9 shows the measured properties of the hard metals listed in Table 8. 1057D-6939-PF 106 8 1339219 Table 8 Hard metal with Ni-based superalloy and Re binder

組成，wt.% Re於黏結劑中之比例燒結溫度。c Re Rene95 U-700 U-720 WC TiC TaC ΡΪ7 1.5 4.5 88 3 3 25% 1600-1750 P18 3 3.0 88 3 3 50% 1600-1775 P25 3.75 2.25 88 3 3 62.5% 1650〜1825 P48 3.75 2.25 84 5 5 62.5% 1650〜1825 P50 4.83 1.89 82.75 5.31 5.22 71.9% 1675〜1850 P40 7.57 2.96 78.92 5.32 5.23 71.9% 1675-1850 P46 11.40 4.45 73.55 5.34 5.24 71.9% 1675〜1850 P51 7.15 0.93 81.55 5.23 5.14 88.5% 1700〜1900 P41 11.10 1.45 77.14 5.20 5.11 88,5% 170(M900 P63 12.47 0.86 76.45 5.16 5.07 93.6% 1850-2100 P19 1.5 4.5 88 3 3 25% 1600〜1750 P20 3 3 88 3 3 50% 1600〜1775 P67 24.37 1.62 64.02 5.04 4.95 93.6% 1950〜2300 表9具有Ni基超合金與Re的黏結劑之硬金屬的性質溫度。C 密度g/cc 硬度Hv 韌性Ksc 燒結 HIP 計算的測量的 Kg/mm2 xl06Pa-ml/2 P17 1700 14.15 14.18 2120 6.8 P17 1700 1600 14.15 14.21 2092 7.2 P18 1700 14.38 14.47 2168 5.9 P18 1700 1600 14.38 14.42 2142 6.1 P25 1750 14.49 14.41 2271 6.1 P25 1750 1600 14.49 14.48 2193 6.5 P48 1800 1600 13.91 13.99 2208 6.3 P50 1800 1600 13.9 13.78 2321 6.5 P40 1800 13.86 13.82 2343 P40 1800 1600 13.86 13.86 2321 63 P46 1800 13.81 13.88 2282 7.1 P46 1800 1725 13.81 13.82 2326 6.7 P51 1800 1600 14.11 13.97 2309 6.6Composition, wt.% Re ratio in the binder sintering temperature. c Re Rene95 U-700 U-720 WC TiC TaC ΡΪ7 1.5 4.5 88 3 3 25% 1600-1750 P18 3 3.0 88 3 3 50% 1600-1775 P25 3.75 2.25 88 3 3 62.5% 1650~1825 P48 3.75 2.25 84 5 5 62.5% 1650~1825 P50 4.83 1.89 82.75 5.31 5.22 71.9% 1675~1850 P40 7.57 2.96 78.92 5.32 5.23 71.9% 1675-1850 P46 11.40 4.45 73.55 5.34 5.24 71.9% 1675~1850 P51 7.15 0.93 81.55 5.23 5.14 88.5% 1700~1900 P41 11.10 1.45 77.14 5.20 5.11 88,5% 170 (M900 P63 12.47 0.86 76.45 5.16 5.07 93.6% 1850-2100 P19 1.5 4.5 88 3 3 25% 1600~1750 P20 3 3 88 3 3 50% 1600~1775 P67 24.37 1.62 64.02 5.04 4.95 93.6% 1950~2300 Table 9 Properties of hard metals with Ni-based superalloy and Re binder. C Density g/cc Hardness Hv Toughness Ksc Sintered HIP Calculated Kg/mm2 xl06Pa-ml/2 P17 1700 14.15 14.18 2120 6.8 P17 1700 1600 14.15 14.21 2092 7.2 P18 1700 14.38 14.47 2168 5.9 P18 1700 1600 14.38 14.42 2142 6.1 P25 1750 14.49 14.41 2271 6.1 P25 1750 1600 14.49 14.48 2193 6.5 P48 1800 1600 13.91 13.99 2208 6.3 P50 1800 1600 13.9 13.78 2321 6.5 P40 1800 13.86 13.82 2343 P40 1800 1600 13.86 13.86 2321 63 P46 1800 13.81 13.88 2282 7.1 P46 1800 1725 13.81 13.82 2326 6.7 P51 1800 1600 14.11 13.97 2309 6.6

1057D-6939-PF 107 ⑧ 13392191057D-6939-PF 107 8 1339219

货 - ---—' 第四種類的另一例子係使用5〜40vol.%的黏結劑，該點結劑係包含Ni基超合金、Re與Co。包含有化合Ni基超口金、Re與c〇的硬金屬之代表組成係列於表1 〇中有優良功效之硬金屬的黏結劑材料測„式一些所選擇的試品而來研究具有州超合金的黏結劑基質的特性。一般來說，犯超合金不僅提升高溫下的強度，而且在高溫下有優良的抗氧化性與抗腐純。州超合金有複雜的微結構和強度機制。-般來說，Ni超合金主要是γ_γ，的析出強化和固溶強化。所以這些測量結果顯# Ni超合金可以作為具表U係列出一些所選的試品中各組成佔硬金屬總重的重量百分率。其試品中的wc粒子的尺寸係〇如。表Goods - --- - 'Another example of the fourth type uses 5 to 40 vol.% of a binder comprising a Ni-based superalloy, Re and Co. A representative series of hard metals containing a combination of Ni-based super-gold, Re and c〇 is a series of hard-metal binder materials with excellent efficacy in Table 1. The characteristics of the binder matrix. In general, the superalloy not only enhances the strength at high temperatures, but also has excellent oxidation resistance and corrosion resistance at high temperatures. State superalloys have complex microstructures and strength mechanisms. In other words, Ni superalloys are mainly γ_γ, precipitation strengthening and solid solution strengthening. Therefore, these measurements show that #Ni superalloys can be used as the weight of the total weight of hard metals in some selected samples of the U series. Percentage. The size of the wc particles in the sample is as follows.

1057D-6939-PF ⑧ 108 1339219 ，* * ., 1 2係列出兩階段製程的條件以及試品的所測密度、硬度參數以及韌性參數。表中的Palmqvist破壞韌性Ksc係從 Vicker Indentor公司製造之Palmqvist破裂強度測試機的總破裂強度計算而得，其Ksc = 0.087*(Hv*W)1/2。其推算方式可參閱 Warren and H.Matzke, Proceedings of the International Conference On the Science of Hard Materials, Jackson, Wyoming, Aug 23-28，1981。硬度 Hv 和破裂長度係在1 OKg荷重下測試1 5秒。在每一測試中，每一試片都 φ 有八個壓痕以及用於所列資料之計算結果的平均值。表11 重量°/。體積％ Re Co R-95 WC VC 黏結劑中的Re 黏結劑 P54 0 8 0 91.4 0.6 0 13.13 P58 0 0 7.5 91.9 0.6 0 13.25 P56 1.8 7,2 0 90.4 0.6 20 13.20 P72 1.8 7.2 0 90.7 0.3 20 13.18 P73 1.8 4,8 2.7 90,4 0,3 20 14.00 P74 1.8 3 4.5 90.4 0.3 20 14.24 鲁表12 試品編號燒結條件 HIP條件計算密度 g/c.c. 測量密度g/c.c. 硬度 HvKg/mm2 Palmqvist 訪性 Ksc E6 Pa *ml/2 P54-5 1360°C/lhr 14.63 14.58 2062i35 8.9±0.2 1360〇C/lhr 1305〇C/15KSI/lhr 14.55 2090±22 8.5±0.2 P58-7 1550〇C/lhr 14.50 14.40 2064±12 7.9±0.2 1550°C/lhr 1305°C/15KSI/lhr 14.49 2246±23 7·3 土 0.1 P56-5 1360°C/lhr 14.77 14.71 2064土23 8.2±0.1 1360°C/lhr 13〇5°C/15KSI/lhr 14.72 2133土34 8.6±0.2 P72-6 1475°C/lhr 14.83 14.77 2036±34 8.5±〇-6 1475〇C/lhr 13〇5°C/15KSI/lhr 14.91 2041土30 9.1 ±0.4 P73-6 1475〇C/lhr 14.73 14.70 2195±23 7.7±0.11057D-6939-PF 8 108 1339219 , * * ., 1 2 series The conditions of the two-stage process and the measured density, hardness parameters and toughness parameters of the sample. The Palmqvist failure toughness Ksc in the table is calculated from the total rupture strength of a Palmqvist burst strength tester manufactured by Vicker Indentor, which has a Ksc = 0.087*(Hv*W) 1/2. For a calculation, see Warren and H. Matzke, Proceedings of the International Conference On the Science of Hard Materials, Jackson, Wyoming, Aug 23-28, 1981. Hardness Hv and burst length were tested for 1 5 seconds at 1 OKg load. In each test, each test piece had φ with eight indentations and an average of the calculated results for the listed data. Table 11 Weight ° /. Re% binder in the volume % Re Co R-95 WC VC binder P54 0 8 0 91.4 0.6 0 13.13 P58 0 0 7.5 91.9 0.6 0 13.25 P56 1.8 7,2 0 90.4 0.6 20 13.20 P72 1.8 7.2 0 90.7 0.3 20 13.18 P73 1.8 4,8 2.7 90,4 0,3 20 14.00 P74 1.8 3 4.5 90.4 0.3 20 14.24 Lu Table 12 Sample No. Sintering Conditions HIP Condition Calculation Density g/cc Measurement Density g/cc Hardness HvKg/mm2 Palmqvist Interview Ksc E6 Pa *ml/2 P54-5 1360°C/lhr 14.63 14.58 2062i35 8.9±0.2 1360〇C/lhr 1305〇C/15KSI/lhr 14.55 2090±22 8.5±0.2 P58-7 1550〇C/lhr 14.50 14.40 2064 ±12 7.9±0.2 1550°C/lhr 1305°C/15KSI/lhr 14.49 2246±23 7·3 Soil 0.1 P56-5 1360°C/lhr 14.77 14.71 2064 Earth 23 8.2±0.1 1360°C/lhr 13〇5 °C/15KSI/lhr 14.72 2133 soil 34 8.6±0.2 P72-6 1475°C/lhr 14.83 14.77 2036±34 8.5±〇-6 1475〇C/lhr 13〇5°C/15KSI/lhr 14.91 2041 soil 30 9.1 ±0.4 P73-6 1475〇C/lhr 14.73 14.70 2195±23 7.7±0.1

1057D-6939-PF 109 ⑧ 1339219 <» ,, 1475〇C/lhr 1305°C/15KSI/lhr 14.72 2217±25 8.1 土 0.2 P74-5 1500°C/lhr and 1520t/lhr 14.69 14.69 2173士30 7.4士0.3 1500°°C/lhr and 1520°C/lhr 1305°C/15KSI/lhr 14.74 2223土34 7.7 土 0.1 在這些試品中，試品P54係使用傳統的含Co黏結劑。試品P58係使用Ni超合金來取代P54中的Co而當作是黏結劑。因此，Hv硬度從P54的2090提升到P58的2246。在試品Ρ56中，係使用Re與Co的混合物來取代Co來當作是黏結劑，且其對應的Hv係從P54的2090提升到P56 的2133。試品Ρ72、Ρ73與Ρ74係具有相同含量的Re，但有不同含量之Co與R95。使用於試品P73與P74中的Re， Co與R95混合物，係用來取代試品P72中的當作是黏結劑之Re與Co的混合物。其硬度從2041(P72)到2217(P73)與 2223(P74)。表13 重量％體積％ Re R-95 Co TiC TaC WC (2μπι) WC (0.2μΓη) 黏結劑中的Re 黏結劑 P17 1.5 4.5 0 3 3 δδ 0 25 8.78 P18 3 3 0 3 3 88 0 50 7.31 P25 3.75 2.25 0 3 3 88 0 62*5 6.57 P48 3.75 2.25 0 5 5 84 0 62.5 6.3 P50 4.83 1.89 0 5.31 5.22 82.75 0 71.9 6.4 P5I 7.15 0.93 0 5.23 5.14 81.55 0 88.5 6.4 P49 7,55 0 3.25 5.31 5.21 78.68 0 69.9 10 P40A 7.57 2.96 0 5.32 5.23 78.92 0 71.9 10 P63 12.47 0.86 0 5.16 5.07 0 76.45 93.6 10 1101057D-6939-PF 109 8 1339219 <» ,, 1475〇C/lhr 1305°C/15KSI/lhr 14.72 2217±25 8.1 Soil 0.2 P74-5 1500°C/lhr and 1520t/lhr 14.69 14.69 2173士30 7.4 ± 0.3 1500 ° ° C / lhr and 1520 ° C / lhr 1305 ° C / 15 KSI / lhr 14.74 2223 soil 34 7.7 soil 0.1 In these samples, the test sample P54 uses a conventional Co-containing binder. The sample P58 was replaced with a Ni superalloy in place of Co in P54 as a binder. Therefore, the Hv hardness is increased from 2090 of P54 to 2246 of P58. In the sample Ρ56, a mixture of Re and Co was used in place of Co as a binder, and its corresponding Hv system was raised from 2090 of P54 to 2133 of P56. Samples Ρ72, Ρ73 and Ρ74 have the same content of Re, but have different contents of Co and R95. The mixture of Re, Co and R95 used in the samples P73 and P74 was used to replace the mixture of Re and Co as the binder in the test sample P72. Its hardness ranges from 2041 (P72) to 2217 (P73) and 2223 (P74). Table 13 wt% vol% Re R-95 Co TiC TaC WC (2μπι) WC (0.2μΓη) Re binder in the binder P17 1.5 4.5 0 3 3 δδ 0 25 8.78 P18 3 3 0 3 3 88 0 50 7.31 P25 3.75 2.25 0 3 3 88 0 62*5 6.57 P48 3.75 2.25 0 5 5 84 0 62.5 6.3 P50 4.83 1.89 0 5.31 5.22 82.75 0 71.9 6.4 P5I 7.15 0.93 0 5.23 5.14 81.55 0 88.5 6.4 P49 7,55 0 3.25 5.31 5.21 78.68 0 69.9 10 P40A 7.57 2.96 0 5.32 5.23 78.92 0 71.9 10 P63 12.47 0.86 0 5.16 5.07 0 76.45 93.6 10 110

1057D-6939-PF 1339219 •· * ., Ρ62Α 14.48 0 0 5.09 5.00 0 75.43 100 10 Ρ66 27.92 0 0 4.91 4.82 0 6235 100 20 測試一些所選擇的試品而來研究具有Re的黏結劑基質的特性。表13係所測試的試品。具有2μιη與0.2μπι兩種不同尺寸之WC粒子係被使用。表1 4係列出兩階段製程的條件以及所選之試品的所測密度、硬度參數以及韌性參數0 表141057D-6939-PF 1339219 •· * ., Ρ62Α 14.48 0 0 5.09 5.00 0 75.43 100 10 Ρ66 27.92 0 0 4.91 4.82 0 6235 100 20 Test the properties of the binder matrix with Re by testing some of the selected samples. Table 13 is the test sample tested. WC particle systems having two different sizes of 2 μm and 0.2 μm were used. Table 1 The conditions of the two-stage two-stage process and the measured density, hardness parameters and toughness parameters of the selected samples are shown in Table 14

1¾¾¾ 麵畊 Him牛言十算密度g/c.C. 酒遣密度g/c.c. 硬度 Hv Kg/nW Palmqvist 1¾¾ KscE6Pa-m,/2 PI7-5 18Q0°C/1 hr l600°C/l5KS//Ihr Μ.Ϊ5 14.21 2092±3 7.2±O.I PI8-3 1800°C/lhr 1600°C/15KSI/lhr 14.38 14.59 2028±88 6.8 士 0.3 P25-3 1750〇C/lhr 160〇r/15KSI/lhr 14.49 14.48 2193±8 6.5±0.1 P48-1 1800°C/lhr 1600°C/15KSI/lhr 13.91 13.99 2208±12 6.3±0.4 P50-4 1800°C/lhr 1600°C/15KSI/lhr 13.9 13.8 2294土20 6·3 土 0.1 P51-I 1800°C/lhr 1600PC/15KSI/Ihr 14.11 13.97 2309±6 6.6±0.1 Ρ40Α-Ϊ )800°C/lhr )600DC/15KSI/]hr 】3.86 13.86 2321±]〇 6.3 土 0.] P49-1 1800°C/lhr 1600〇C/15KSI/lhr 13.91 13.92 2186土29 6.5±0.2 P62A-6 2200〇C/lhr 1725r/30KSI/lhr 14.5 14.41 2688士22 6.7±0.1 P63-5 2200〇C/lhr 1725°C/30KSI/lhr 14.31 14.37 2562±31 6.7±0.2 P66-4 2200°C/lhr 15.04 14.40 2402士44 8.2±0.4 P66-4 2200t/lhr 1725DC/30KSI/Ihr 15.04 14.52 P66-4 2200〇C/lhr ]725°C/30KSI/lhr + 1950°C/30KSI/lhr 15.04 14.53 2438士47 6.9±0.2 P66-5 2200〇C/lhr 15.04 14,33 2092土23 7.3 士 0.3 P66-5 2200〇C/lhr 1725〇C/30KSI/lhr 15.04 14.63 P66-5 2200〇C/lhr I725t/30KSI/lhr + 1850°C/30KSI/lhr 15.04 14.66 2207士17 7.1±0.2 表〗5更顯示出所選試品在各不同溫度下的所測硬度13⁄43⁄43⁄4 face tilling Him beast ten density d/gC wine density g/cc hardness Hv Kg/nW Palmqvist 13⁄43⁄4 KscE6Pa-m,/2 PI7-5 18Q0°C/1 hr l600°C/l5KS//Ihr Μ. Ϊ5 14.21 2092±3 7.2±OI PI8-3 1800°C/lhr 1600°C/15KSI/lhr 14.38 14.59 2028±88 6.8 ± 0.3 P25-3 1750〇C/lhr 160〇r/15KSI/lhr 14.49 14.48 2193± 8 6.5±0.1 P48-1 1800°C/lhr 1600°C/15KSI/lhr 13.91 13.99 2208±12 6.3±0.4 P50-4 1800°C/lhr 1600°C/15KSI/lhr 13.9 13.8 2294 soil 20 6·3 Soil 0.1 P51-I 1800°C/lhr 1600PC/15KSI/Ihr 14.11 13.97 2309±6 6.6±0.1 Ρ40Α-Ϊ)800°C/lhr )600DC/15KSI/]hr 】3.86 13.86 2321±]〇6.3 Earth 0. ] P49-1 1800°C/lhr 1600〇C/15KSI/lhr 13.91 13.92 2186 soil 29 6.5±0.2 P62A-6 2200〇C/lhr 1725r/30KSI/lhr 14.5 14.41 2688士22 6.7±0.1 P63-5 2200〇 C/lhr 1725°C/30KSI/lhr 14.31 14.37 2562±31 6.7±0.2 P66-4 2200°C/lhr 15.04 14.40 2402士44 8.2±0.4 P66-4 2200t/lhr 1725DC/30KSI/Ihr 15.04 14.52 P66-4 2200〇C/lhr ]725°C/30KSI/lhr + 1950°C/30KSI/lhr 15.04 14.53 2438士47 6.9±0.2 P66-5 2200〇C/ Lhr 15.04 14,33 2092 soil 23 7.3 ± 0.3 P66-5 2200 〇 C / lhr 1725 〇 C / 30KSI / lhr 15.04 14.63 P66-5 2200 〇 C / lhr I725t / 30KSI / lhr + 1850 ° C / 30KSI / lhr 15.04 14.66 2207 ± 17 7.1 ± 0.2 Table 〖5 shows the measured hardness of the selected sample at different temperatures

1057D-6939-PF 111 ⑧ 1339219 .¼ , _ ♦ * n 參數，其中Knoop硬度Hk係藉由Nikon QM hot hardness tester在1公斤荷重下1 5秒而測量，而R係在高溫下所測之Hk相對於在25°C下所測之Hk的比值。C2與C6碳化物的熱硬度試片係購買自 MSC公司（Melville, NY)製造的 inserts SUN434。表151057D-6939-PF 111 8 1339219 .1⁄4 , _ ♦ * n parameters, where Knoop hardness Hk is measured by Nikon QM hot hardness tester at 1 kg load for 1 5 seconds, while R system is measured at high temperature for Hk Relative to the ratio of Hk measured at 25 °C. The hot hardness test pieces of C2 and C6 carbides were purchased from inserts SUN434 manufactured by MSC Corporation (Melville, NY). Table 15

批號 !1試溫度°C Hv@250 25 400 500 600 700 800 900 1880 1720 1653 1553 1527 2092 P17-5 Hk, Kg/mm2 ±10 ±17 ±25 土 29 土 6 土 3 R,% 100 91 88 83 81 1773 1513 1467 1440 1340 2028 P18-3 Hk, Kg/mm2 土 32 土 12 ±21 土 10 士 16 ±88 R,% 100 85 83 81 76 1968 1813 1710 1593 2193 P25-3 Hk, Kg/mm2 ±45 士 12 土 0 ±5 ±8 R,% 100 92 87 81 2000 1700 1663 1583 1540 2321 P40A-1 Hk, Kg/mm2 ±35 士 17 士 12 ±21 ±35 土 10 R,% 100 85 83 79 77 1925 1613 1533 1477 1377 2208 P48-1 Hk, Kg/mm2 ±25 ±15 ±29 土 6 土 15 士 12 R，％ 100 84 80 77 72 2023 1750 1633 1600 2186 Hk, Kg/mm2 P49-1 土 32 ±0 ±6 士 17 土 29 R, % 100 87 81 79 2057 1857 1780 1713 1627 2294 Hk, Kg/mm2 P50-4 ±25 土 15 ±20 土 6 ±40 土 20 R,% 100 90 87 83 79 2050 1797 1743 1693 1607 2309 Hk, Kg/mm2 P5M 土 26 ±6 ±35 土 15 ±15 士 6Batch number! 1 test temperature °C Hv@250 25 400 500 600 700 800 900 1880 1720 1653 1553 1527 2092 P17-5 Hk, Kg/mm2 ±10 ±17 ±25 Earth 29 Soil 6 Soil 3 R,% 100 91 88 83 81 1773 1513 1467 1440 1340 2028 P18-3 Hk, Kg/mm2 Soil 32 Soil 12 ± 21 Soil 10 ± 16 ± 88 R, % 100 85 83 81 76 1968 1813 1710 1593 2193 P25-3 Hk, Kg/mm2 ±45士12土0 ±5 ±8 R,% 100 92 87 81 2000 1700 1663 1583 1540 2321 P40A-1 Hk, Kg/mm2 ±35 ± 17 ± 12 ± 21 ± 35 ± 10 R, % 100 85 83 79 77 1925 1613 1533 1477 1377 2208 P48-1 Hk, Kg/mm2 ±25 ±15 ±29 Soil 6 Earth 15 ± 12 R,% 100 84 80 77 72 2023 1750 1633 1600 2186 Hk, Kg/mm2 P49-1 Earth 32 ±0 ±6 士17土29 R, % 100 87 81 79 2057 1857 1780 1713 1627 2294 Hk, Kg/mm2 P50-4 ±25 Soil 15 ±20 Soil 6 ±40 Earth 20 R,% 100 90 87 83 79 2050 1797 1743 1693 1607 2309 Hk, Kg/mm2 P5M Soil 26 ± 6 ± 35 ± 15 ± 15 ± 6

1057D-6939-PF 112 ⑧ 1339219 心. 、 · s R, % 100 88 85 83 78 P62A-6 Hk, Kg/mm2 2228 ±29 2063 ±25 1960 土 76 1750 ±0 2688 ±22 R，％ 100 93 88 79 P63-5 Hk, Kg/mm2 1887 ±6 1707 土3 5 1667 土 15 1633 土 6 1603 土 25 2562 士31 R, % 100 dmm Hk, Kg/mm2 1503 士 38 988 ±9 711 ±0 584 土 27 1685 土 16 R,% 100 66 47 39 C6剧匕物 Hk, Kg/mm2 1423 ±23 1127 土 25 1090 ±10 1033 士 23 928 ±18 1576 ±11 R,% 100 79 77 73 65 硬金屬中的含有Re的黏結劑基質係提升了含有 Co-Re, Ni超合金-Re, Ni超合金-Re-Co的黏結劑合金之熔點。例如，P63的熔點遠大於被使用於固相燒結製程的2200 °C。具有Re於黏結劑（例如P 1 7至P63)中的該硬金屬的熱硬度值遠大於傳統的含Co硬金屬（C2與C6碳化物）。特別是，上述測量結果顯示增加黏結劑中的Re濃度係能夠增加 φ 在高溫下的硬度。在該等試品中，具有純Re當作是黏結劑的P62A係具有最高的硬度。具有94%Re與6%Ni基超合金R95當作是黏結劑組成的P63係具有第二高的硬度。接著是 P40A(71.9%Re-29.1%R95)、P49(69.9%Re-30.1%R95)、 P51(88.5%Re-11.5%R95)與 P50(71.9%Re-28.1%R95)。具有 62.5%Re-37.5%R95的黏結劑的試品P48，在這些試品中的硬度是最低的，其原因是因為Re的含量最少。在另一種類中，硬金屬或陶瓷金屬可以包含與TiC和 TiN化合於具有Ni, Mo或Mo2C之黏結劑基質中。陶瓷金 1057D-6939-PF 113 屬中的黏結劑Ni可以被Re, Re-Co, Ni基超合金，Re-Ni基超合金或Re-Co-Ni基超合金部分或全部取代。例如，P3 8 和P39係典型的化合有Ni的陶瓷金屬。而P34係化合有 Rene95的陶瓷金屬。P35, P36, P37與 P45係化合有 Re-Rene95 的陶瓷金屬。P34, P35, P36, P37, P38, P39 與 P45 的組成係列於表1 6中。表16 P34至P39的組成重量％ Re Rene95 Nil Ni2 TiC Mo2C WC TaC P34 14.47 69.44 16.09 P35 8.77 10.27 65.37 15,23 P36 16.6 6.50 62.40 14.46 P37 23.8 3.09 59.38 13.76 P38 15.51 68.60 15.89 P39 15.51 68.60 15.89 P45 9.37 3.66 15.37 6.51 58.6 6.47 表1 7-29列出額外三種組成範圍。表Π利用純Re當作黏結劑來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物組成範圍1 組成範圍2 組成範圍3 估算熔點t：體積％重量％體積％重量％體積％重量％ Re黏結 Re 7.25 to 40 25 to 74 7.25 to 35 25 to 70 7.25 to 30 25 to 65 3000 to 3200 TiC TiC 60 to 92.75 26 to 75 65 to 92.75 30 to 75 70 to 92.75 35 to 75 Re黏結 Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 3000 to 3200 ZrC ZrC 60 to 97 32 to 93 65 to 96 37 to 88 70 to 95 42 to 86 Re黏結 Re 16.75 to 40 25 to 52 16.75 to 35 25 to 47 16.75 to 30 25 to 42 3000 to 3200 HfC Hf€ 60 to 83.25 48 to 75 65 to 83.25 53 to 75 70 to 83.25 58 to 75 Re黏結 Rc 3 to 40 11 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2700.·.〇 3100 VC VC 60 to 97 28 to 89 65 to 96 33 to 86 70 to 95 38 to 83 Re黏結 Re 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 54 3000 to 3200 1141057D-6939-PF 112 8 1339219 Heart, · s R, % 100 88 85 83 78 P62A-6 Hk, Kg/mm2 2228 ±29 2063 ±25 1960 Earth 76 1750 ±0 2688 ±22 R,% 100 93 88 79 P63-5 Hk, Kg/mm2 1887 ±6 1707 Soil 3 5 1667 Soil 15 1633 Soil 6 1603 Soil 25 2562 士 31 R, % 100 dmm Hk, Kg/mm2 1503 ± 38 988 ± 9 711 ± 0 584 1685 Soil 16 R,% 100 66 47 39 C6 Drama Hk, Kg/mm2 1423 ±23 1127 Earth 25 1090 ±10 1033 ±23 928 ±18 1576 ±11 R,% 100 79 77 73 65 Contains in hard metals Re's binder matrix enhances the melting point of the binder alloy containing Co-Re, Ni superalloy-Re, Ni superalloy-Re-Co. For example, the melting point of P63 is much larger than 2200 °C used in the solid phase sintering process. The hardness of the hard metal having Re in the binder (e.g., P 17 to P63) is much greater than that of the conventional Co-containing hard metal (C2 and C6 carbide). In particular, the above measurement results show that increasing the Re concentration in the binder can increase the hardness of φ at high temperatures. Among these samples, P62A having pure Re as a binder has the highest hardness. The P63 system having 94% Re and 6% Ni-based superalloy R95 as a binder has the second highest hardness. This was followed by P40A (71.9% Re-29.1% R95), P49 (69.9% Re-30.1% R95), P51 (88.5% Re-11.5% R95) and P50 (71.9% Re-28.1% R95). Sample P48 of a binder having 62.5% Re-37.5% R95 had the lowest hardness in these samples because the content of Re was the least. In another class, the hard metal or ceramic metal may comprise a combination of TiC and TiN in a binder matrix having Ni, Mo or Mo2C. The cement Ni in the genus 1057D-6939-PF 113 can be partially or completely replaced by Re, Re-Co, Ni-based superalloy, Re-Ni based superalloy or Re-Co-Ni based superalloy. For example, P3 8 and P39 are typical ceramic metals in which Ni is combined. The P34 system combines the ceramic metal of Rene95. P35, P36, P37 and P45 are combined with ceramic metal of Re-Rene95. The composition of P34, P35, P36, P37, P38, P39 and P45 is shown in Table 16. Table 16 Composition weight % of P34 to P39 Re Rene95 Nil Ni2 TiC Mo2C WC TaC P34 14.47 69.44 16.09 P35 8.77 10.27 65.37 15,23 P36 16.6 6.50 62.40 14.46 P37 23.8 3.09 59.38 13.76 P38 15.51 68.60 15.89 P39 15.51 68.60 15.89 P45 9.37 3.66 15.37 6.51 58.6 6.47 Table 1 7-29 lists the additional three component ranges. The surface Π uses pure Re as a binder to bond carbides formed by elements of groups IVb, Vb and VIb of the periodic table or nitrides formed by elements of group IVb and Vb of the periodic table. Composition range 3 Estimated melting point t: % by volume % by weight % by weight % by weight % by weight Re% Re 7.25 to 40 25 to 74 7.25 to 35 25 to 70 7.25 to 30 25 to 65 3000 to 3200 TiC TiC 60 to 92.75 26 to 75 65 to 92.75 30 to 75 70 to 92.75 35 to 75 Re Bonding Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 3000 to 3200 ZrC ZrC 60 to 97 32 to 93 65 to 96 37 to 88 70 to 95 42 to 86 Re-bonding Re 16.75 to 40 25 to 52 16.75 to 35 25 to 47 16.75 to 30 25 to 42 3000 to 3200 HfC Hf € 60 to 83.25 48 to 75 65 to 83.25 53 to 75 70 to 83.25 58 To 75 Re Bonding Rc 3 to 40 11 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2700.·.3100 VC VC 60 to 97 28 to 89 65 to 96 33 to 86 70 to 95 38 to 83 Re Bonding Re 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 54 3000 to 3200 114

1057D-6939-PF 13,392191057D-6939-PF 13,39219

NbC NbC 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 46 to 88 Re黏結 Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 38 3000 to 3200 TaC TaC 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 62 to 93 Re黏結 Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 57 1700 to 1900 Cr2C3 Cr2C3 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 43 to 86 Re黏結 Re 3 to 40 7 to 61 4 to 35 9 to 55 5 to 30 11 to 50 2300 to 2600 Mo2C Mo2C 60 to 97 39 to 93 65 to 96 45 to 91 70 to 95 50 to 89 Re黏結 Re 20 to 40 25 to 47 20 to 35 25 to 42 20 to 30 25 to 37 2700 to 2900 wc WC 60 to 80 53 to 75 65 to 80 58 to 75 70 to 80 63 to 75 Re黏結 Re 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 17 to 62 2900 to 3100 TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 38 to 83 Re黏結 Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2900 to 3100 ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Re黏結 Re 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 39 3000 to 3200 HfN HfN 60 to 97 50 to 96 65 to 96 55 to 94 70 to 95 61 to 93 Re黏結 Re 3 to 40 9 to 70 4 to 35 13 to 65 5 to 30 16 to 62 2100 to 2300 VN VN 60 to 97 30 to 91 65 to 96 35 to 87 70 to 95 38 to 84 Re黏結 Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2300 to 2500 NbN NbN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Re黏結 Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 39 3000 to 3200 TaN TaN 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 61 to 93NbC NbC 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 46 to 88 Re Bonding Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 38 3000 to 3200 TaC TaC 60 to 97 51 To 96 65 to 96 56 to 94 70 to 95 62 to 93 Re Bonding Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 57 1700 to 1900 Cr2C3 Cr2C3 60 to 97 32 to 91 65 to 96 37 To 88 70 to 95 43 to 86 Re Bonding Re 3 to 40 7 to 61 4 to 35 9 to 55 5 to 30 11 to 50 2300 to 2600 Mo2C Mo2C 60 to 97 39 to 93 65 to 96 45 to 91 70 to 95 50 To 89 Rebond Re 20 to 40 25 to 47 20 to 35 25 to 42 20 to 30 25 to 37 2700 to 2900 wc WC 60 to 80 53 to 75 65 to 80 58 to 75 70 to 80 63 to 75 Re Bond Re 3 To 40 11 to 72 4 to 35 14 to 68 5 to 30 17 to 62 2900 to 3100 TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 38 to 83 Re Bonding Re 3 to 40 8 to 66 4 To 35 11 to 61 5 to 30 13 to 55 2900 to 3100 ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Re Bonding Re 3 to 40 4 to 50 4 to 35 6 to 45 5 To 30 7 to 39 3000 to 3200 HfN HfN 60 to 97 50 to 96 65 to 96 55 to 94 70 to 95 61 to 93 Re Bonding Re 3 to 40 9 to 70 4 to 35 13 to 65 5 to 30 16 to 62 2100 to 2300 VN VN 60 to 97 30 to 91 65 to 96 35 to 87 70 to 95 38 to 84 Re Bonding Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2300 to 2500 NbN NbN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Re Bonding Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 39 3000 to 3200 TaN TaN 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 61 to 93

表18在黏結劑中利用鎳基超合金來黏結由元素週期表中IVb及Vb族元素所形成的氮化物組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ NBSA- NBSA 3 to 40 4 to 50 4 to 35 6 to 44 5 to 30 7 to 39 TiN TiN 60 to 97 50 to 96 65 to 96 56 to 94 70 to 95 61 to 93 NBSA- NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 ZrN ZrN 60 to 97 58 to 97 65 to 96 63 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.8 to 28 4 to 35 2.4 to 24 5 to 30 3 to 19 HfN HfN 60 to 97 72 to 98.2 65 to 96 76 to 97.6 70 to 95 81 to 97 NBSA- NBSA 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 VN VN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 1057D-6939-PF 115 琴19 NBSA- NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 NbN NbN 60 to 97 52 to 97 65 to 96 33 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.7 to 27 4 to 35 2.3 to 23 5 to 30 3 to 19 TaN TaN 60 to 97 73 to 98.3 65 to 96 77 to 97.7 70 to 95 81 to 97 表19在黏結記中利用Re及鎮基超合金來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由1% Re+99%鎳基超合金至99%Re+l%鎳基超合金Table 18 uses a nickel-based superalloy in the binder to bond the nitride composition range of the IVb and Vb elements of the periodic table. Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% NBSA - NBSA 3 to 40 4 to 50 4 to 35 6 to 44 5 to 30 7 to 39 TiN TiN 60 to 97 50 to 96 65 to 96 56 to 94 70 to 95 61 to 93 NBSA- NBSA 3 to 40 3 to 42 4 To 35 4 to 37 5 to 30 5 to 32 ZrN ZrN 60 to 97 58 to 97 65 to 96 63 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.8 to 28 4 to 35 2.4 to 24 5 to 30 3 To 19 HfN HfN 60 to 97 72 to 98.2 65 to 96 76 to 97.6 70 to 95 81 to 97 NBSA- NBSA 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 VN VN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 1057D-6939-PF 115 Piano 19 NBSA- NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 NbN NbN 60 to 97 52 to 97 65 to 96 33 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.7 to 27 4 to 35 2.3 to 23 5 to 30 3 to 19 TaN TaN 60 to 97 73 to 98.3 65 to 96 77 to 97.7 70 to 95 81 to 97 Table 19 at In the case, Re and the town-based superalloy are used to bond the carbide formed by the elements of Group IVb, Vb and VIb of the periodic table or the nitride formed by the elements of Group IVb and Vb of the periodic table, wherein the binder is composed of The ratio ranges from 1% Re+99% nickel-based superalloy to 99% Re+l% nickel-based superalloy

材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Re+NBSA) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.21 to 64.3 - NBSA 0.03 to 39.6 0.04 to 51.1 0.04 to 34.7 0.06 to 45.9 0.05 to 29.7 0.07 to 40.4 TiC TiC 60 to 97 26.1 to 95.1 65 to 96 30.5 to 93.6 70 to 95 35.5 to 92 (Re+NBSA) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5 - NBSA 0.03 to 39.6 0.03 to 44.1 0.04 to 34.7 0.05 to 39.0 0.05 to 29.7 0.06 to 33.8 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 94 (Re+NBSA) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 - NBSA 0.03 to 39.6 0.02 to 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 HfC HfC 60 to 97 47.7 to 98.1 65 to 96 53 to 97.4 70 to 95 58.6 to 96.7 (R 叶 NBSA) Re 0.03 to 39.6 0.11 to 71.5 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8 - NBSA 0.03 to 39.6 0.04 to 48.4 0.04 to 34.7 0.05 to 43.3 0.05 to 29.7 0.06 to 37.9 VC VC 60 to 97 28.3 to 95.6 65 to 96 32.8 to 94.2 70 to 95 38 to 92.8 (Re+NBSA) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1 - NBSA 0.03 to 39.6 0.03 to 39.9 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbC NbC 60 to 97 36 to 96.9 65 to 96 41 to 95.8 70 to 95 46.6 to 94.8 (Re+NBSA) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38 - NBSA 0.03 to 39.6 0.016 to 26.5 0.04 to 34.7 0.02 to 22.6 0.05 to 29.7 0.03 to 18.9 TaC TaC 60 to 97 51 to 98.3 65 to 96 56.3 to 97.7 70 to 95 61.8 to 97.] (Re+NBSA) Re 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.16 to 57.0 - NBSA 0.03 to 39.6 0.03 to 43.6 0.04 to 34.7 0.04 to 38.6 0.05 to 29.7 0.05 to 33.4 O2C3 60 to 97 32.4 to 96.4 65 to 96 37.3 to 95.2 70 to 95 42.8 to 94.0 (Re+NBSA) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3 - NBSA 0.03 to 39.6 0.025 to 36.3 0.04 to 34.7 0.03 to 31.6 0.05 to 29.7 0.04 10 26.9 Mo2C Mo2C 60 to 97 39.6 to 97.3 65 to 96 44.8 to 96.4 70 to 95 50.5 to 95.5 (Re+NBSA) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.02 to 21.3 0.05 to 29.7 0.025 to 17.8 WC WC 60 to 97 52.9 to 98.4 65 to 96 58.2 to 97.9 70 to 95 63.6 to 97.3 (Re+NBSA) Re 0.03 to 39.6 0.1 to 71.7 0.04 to 34.7 0.15 to 67.2 0.05 to 29.7 0.19 to 62 - NBSA 0.03 to 39.6 0.04 to 48.7 0.04 to 34.7 0.05 to 43.5 0.05 to 29.7 0.06 to 38Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% (Re+NBSA) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.21 to 64.3 - NBSA 0.03 to 39.6 0.04 to 51.1 0.04 to 34.7 0.06 to 45.9 0.05 to 29.7 0.07 to 40.4 TiC TiC 60 to 97 26.1 to 95.1 65 to 96 30.5 to 93.6 70 to 95 35.5 to 92 (Re+NBSA) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5 - NBSA 0.03 to 39.6 0.03 to 44.1 0.04 to 34.7 0.05 to 39.0 0.05 to 29.7 0.06 to 33.8 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 94 (Re+NBSA) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 - NBSA 0.03 to 39.6 0.02 to 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 HfC HfC 60 to 97 47.7 To 98.1 65 to 96 53 to 97.4 70 to 95 58.6 to 96.7 (R leaf NBSA) Re 0.03 to 39.6 0.11 to 71.5 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8 - NBSA 0.03 to 39.6 0.04 to 48.4 0.04 to 34.7 0.05To 43.3 0.05 to 29.7 0.06 to 37.9 VC VC 60 to 97 28.3 to 95.6 65 to 96 32.8 to 94.2 70 to 95 38 to 92.8 (Re+NBSA) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 To 53.1 - NBSA 0.03 to 39.6 0.03 to 39.9 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbC NbC 60 to 97 36 to 96.9 65 to 96 41 to 95.8 70 to 95 46.6 to 94.8 (Re+NBSA) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38 - NBSA 0.03 to 39.6 0.016 to 26.5 0.04 to 34.7 0.02 to 22.6 0.05 to 29.7 0.03 to 18.9 TaC TaC 60 to 97 51 to 98.3 65 to 96 56.3 to 97.7 70 to 95 61.8 to 97.] (Re+NBSA) Re 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.16 to 57.0 - NBSA 0.03 to 39.6 0.03 to 43.6 0.04 to 34.7 0.04 to 38.6 0.05 to 29.7 0.05 To 33.4 O2C3 60 to 97 32.4 to 96.4 65 to 96 37.3 to 95.2 70 to 95 42.8 to 94.0 (Re+NBSA) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3 - NBSA 0.03 to 39.6 0.025 to 36.3 0.04 to 34.7 0.03 to 31.6 0.05 to 29.7 0.04 10 26.9 Mo2C Mo2C 60 to 97 39.6 to 97.3 65 to 96 44.8 to 96.4 70 to 95 50.5 to 95.5 (Re+NBSA) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.02 to 21.3 0.05 to 29.7 0.025 to 17.8 WC WC 60 to 97 52.9 to 98.4 65 to 96 58.2 to 97.9 70 to 95 63.6 to 97.3 (Re+NBSA) Re 0.03 to 39.6 0.1 To 71.7 0.04 to 34.7 0.15 to 67.2 0.05 to 29.7 0.19 to 62 - NBSA 0.03 to 39.6 0.04 to 48.7 0.04 to 34.7 0.05 to 43.5 0.05 to 29.7 0.06 to 38

1057D-6939-PF 116 ⑧ :19 :19 TiN TiN 60 to 97 28 to 95.6 65 to 96 32.6 to 94.1 70 to 95 37.8 to 92.7 (Re+NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.3 0.05 to 29.7 0.14 to 54.8 - NBSA 0.03 lo 39.6 0.03 to4I；4 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.4 ZrN ZrN 60 to 97 34.5 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re+NBSA) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2 - NBSA 0.03 to 39.6 0.017 to 27.5 0.04 to 347 0.02 to 23.5 0.05 to 29.7 0.03 to 19.6 HfN HfN 60 to 97 49.8 to 98.2 65 to 96 55.1 to 97.6 70 to 95 60.7 to 97 (Re+NBSA) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6 - NBSA 0.03 to 39.6 0.04 to 46.2 0.04 to 34.7 0.05 to 41.1 0.05 to 29.7 0.06 to 35.8 VN VN 60 to 97 30 to 96 65 to 96 35 to 94.7 70 to 95 40 to 93.3 (Re+NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.4 0.05 to 29.7 0.14 to 54.9 - NBSA 0.03 to 39.6 0.03 to 41.5 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.5 NbN NbN 60 to 97 34.4 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re+NBSA) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.08 to 38.3 - NBSA 0.03 to 39.6 0.017 to 26.8 0.04 to 34.7 0.02 to 22.8 0.05 to 29.7 0.027 to 19 TaN TaN 60 to 97 50.7 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97 表20在黏結劑中利用Re及Co(Re+Co)來黏結由元素週期表中丨Vb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由1 %Re+99%Co 至 99%Re+l %Co 材料組成範圍1 組成範圍2 組成範圍3 體積％重fi % 體愤％重量％體積％重a % (Re+Co) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.20 to 64.3 • Co 0.03 to 39.6 0.05 to 54.1 0.04 to 34.7 0.07 to 48.9 0.05 to 29.7 0.08 to 43.3 TiC TiC 60 to 97 26.1 to94.6 65 to 96 30.4 to 92,8 70 to 95 35.5 to 91 (Re+Co) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5 • Co 0.03 to 39.6 0.04 to 47.1 0.04 to 34.7 0.05 to 42.0 0.05 to 29.7 0.06 to 36.6 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 (Re+Co) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 Co 0.03 to 39.6 0.02 to 31.8 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.035 to 23 HfC HiC 60 to 97 47.6 to 97.8 65 to 96 53 to 97.1 70 to 95 58.6 to 96.3 (Re+Co) Re 0.03 to 39.6 0.11 to 71.4 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8 - Co 0.03 to 39.6 0.05 to 51,5 0.04 to 34.7 0.06 to 46.3 0.05 to 29.7 0.07 to 40.8 VC VC 60 to 97 28.3 to 95.1 65 to 96 32.8 to 93.5 70 to 95 38 to 92 (Re+Co) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1 • Co 0.03 to 39.6 0.03 to 42.8 0.04 to 34.7 0.04 to 37.8 0.05 to 29.7 0.05 to 32.6 NbC NbC 60 to 97 36 to 96.5 65 to 96 41 to 95.4 70 to 95 46.6 to 94*2 (Re+Co) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38 Co 0.03 to 39.6 0.018 to 28.9 0.04 to 34.7 0.024 to 24.8 0.05 to 29.7 0.03 to 20.8 TaC TaC 60 to 97 51 to 98 65 to 96 56.3 to 97.4 70 to 95 61.8 to 96.8 (Re+Co) Rc 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 1171057D-6939-PF 116 8 :19 :19 TiN TiN 60 to 97 28 to 95.6 65 to 96 32.6 to 94.1 70 to 95 37.8 to 92.7 (Re+NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.3 0.05 To 29.7 0.14 to 54.8 - NBSA 0.03 lo 39.6 0.03 to 4I; 4 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.4 ZrN ZrN 60 to 97 34.5 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re+NBSA Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2 - NBSA 0.03 to 39.6 0.017 to 27.5 0.04 to 347 0.02 to 23.5 0.05 to 29.7 0.03 to 19.6 HfN HfN 60 to 97 49.8 to 98.2 65 to 96 55.1 to 97.6 70 to 95 60.7 to 97 (Re+NBSA) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6 - NBSA 0.03 to 39.6 0.04 to 46.2 0.04 to 34.7 0.05 to 41.1 0.05 to 29.7 0.06 to 35.8 VN VN 60 to 97 30 to 96 65 to 96 35 to 94.7 70 to 95 40 to 93.3 (Re+NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.4 0.05 to 29.7 0.14 to 54.9 - NBSA 0.03 to 39.6 0.03 to 41.5 0.04 to 34.7 0.04 to 36.5 0.05 To 29.7 0.05 to 31.5 NbN NbN 60 to 97 34.4 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re+NBSA) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.08 to 38.3 - NBSA 0.03 to 39.6 0.017 to 26.8 0.04 to 34.7 0.02 to 22.8 0.05 to 29.7 0.027 to 19 TaN TaN 60 to 97 50.7 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97 Table 20 utilizes Re and Co in the binder ( Re+Co) to bond carbides formed by 丨Vb, Vb and VIb elements of the periodic table or nitrides formed by elements IVb and Vb of the periodic table, wherein the composition ratio of the binder is 1% Re+99%Co to 99%Re+l %Co Material composition range 1 Composition range 2 Composition range 3 vol% Weight fi% % Body anger % Weight % Volume % Weight a % (Re+Co) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.20 to 64.3 • Co 0.03 to 39.6 0.05 to 54.1 0.04 to 34.7 0.07 to 48.9 0.05 to 29.7 0.08 to 43.3 TiC TiC 60 to 97 26.1 to94.6 65 to 96 30.4 to 92,8 70 To 95 35.5 to 91 (Re+Co) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 To 62.9 0.05 to 29.7 0.16 to 57.5 • Co 0.03 to 39.6 0.04 to 47.1 0.04 to 34.7 0.05 to 42.0 0.05 to 29.7 0.06 to 36.6 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 (Re +Co) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 Co 0.03 to 39.6 0.02 to 31.8 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.035 to 23 HfC HiC 60 to 97 47.6 to 97.8 65 To 96 53 to 97.1 70 to 95 58.6 to 96.3 (Re+Co) Re 0.03 to 39.6 0.11 to 71.4 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8 - Co 0.03 to 39.6 0.05 to 51,5 0.04 to 34.7 0.06 to 46.3 0.05 to 29.7 0.07 to 40.8 VC VC 60 to 97 28.3 to 95.1 65 to 96 32.8 to 93.5 70 to 95 38 to 92 (Re+Co) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1 • Co 0.03 to 39.6 0.03 to 42.8 0.04 to 34.7 0.04 to 37.8 0.05 to 29.7 0.05 to 32.6 NbC NbC 60 to 97 36 to 96.5 65 to 96 41 to 95.4 70 to 95 46.6 to 94*2 (Re+Co) Re 0.03 To 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 t o 38 Co 0.03 to 39.6 0.018 to 28.9 0.04 to 34.7 0.024 to 24.8 0.05 to 29.7 0.03 to 20.8 TaC TaC 60 to 97 51 to 98 65 to 96 56.3 to 97.4 70 to 95 61.8 to 96.8 (Re+Co) Rc 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 117

1057D-6939-PF I3、392.19 • Co 0.03 to 39.6 0.04 to 46.6 0 D4to 34.7 0.05 io41.5 0.05 to 29.7 0.06 to 36.1 Cr,C3 O2C3 60 to 97 32.4 to 96 65 to 96 37.3 lo94.6 70 to 95 42.7 to 93.3 (Rc+Co) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3 - Co 0.03 to 39.6 0.03 to 39.2 0.04 to 34.7 0.04 to 34.3 0.05 to 29.7 0.05 to 29.4 Mo2C Mo2C 60 to 97 39.6 to 97 65 to 96 44.8 to 96 70 to 95 50.5 to 95 (Re+Co) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - Co 0.03 to 39.6 0.017 to 27.4 0.04 to 34.7 0.023 to 23.4 0.05 to 29.7 0.028 10 19.6 WC WC 60 to 97 52.9 to98.2 65 to 96 58.2 to 97 70 to 95 63.6 to 97 (Re+Co) Re 0.03 to 39.6 0.1 to7L6 0.04 to 34.7 0.15 to 67.1 0.05 to 29.7 0.19 to 62 - Co 0.03 to 39.6 0.05 to 51.7 0.04 to 34.7 0.06 to 46.5 0.05 to 29.7 0.07 to 41 TiN TiN 60 lo 97 28 to 95 65 to 96 32.6 to 93.4 70 to 95 37.8 to 92 (Re+Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.3 0.05 to 29.7 O.)4io 54.8 - Co 0.03 to 39.6 0.035 to 44.4 0.04 to 34.7 0.046 to 39.3 0.05 to 29.7 0.056 to 34 ZrN 2rN 60 to 97 34.5 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re+Co) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2 - Co 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 25.7 0.05 to 29 7 0.03 to 21.6 HfN HfN 60 to 97 49.8 to 98 65 to 96 55.1 to 97.3 70 to 95 60.7 to 96.6 (Ren-Co) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6 - Co 0.03 to 39.6 0.04 to 49.3 0.04 to 34.7 0.055 to 44 0.05 to 29.7 0.06710 38.6 VN VN 60 to 97 30 to 95.5 65 to 96 35 to 94 70 to 95 40 to 92.6 (Re+Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.4 0.05 to 29.7 0.)4 to 54.8 - Co 0,03 to 39.6 0.035 to 44.5 0.04 to 34.7 0.046 to 39.4 0.05 to 29.7 0.057 to 34.1 NbN NbN 60 to 97 34.4 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re+Co) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.075 to 383 - Co 0.03 to 39.6 0.019 to 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0,03 to 21 TaN TaN 60 to 97 50.7 to 9S 65 to 96 56 to 97.4 70 lo 95 61.5to 96.71057D-6939-PF I3, 392.19 • Co 0.03 to 39.6 0.04 to 46.6 0 D4to 34.7 0.05 io41.5 0.05 to 29.7 0.06 to 36.1 Cr, C3 O2C3 60 to 97 32.4 to 96 65 to 96 37.3 lo94.6 70 to 95 42.7 To 93.3 (Rc+Co) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3 - Co 0.03 to 39.6 0.03 to 39.2 0.04 to 34.7 0.04 to 34.3 0.05 to 29.7 0.05 to 29.4 Mo2C Mo2C 60 to 97 39.6 to 97 65 to 96 44.8 to 96 70 to 95 50.5 to 95 (Re+Co) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - Co 0.03 to 39.6 0.017 to 27.4 0.04 to 34.7 0.023 to 23.4 0.05 to 29.7 0.028 10 19.6 WC WC 60 to 97 52.9 to98.2 65 to 96 58.2 to 97 70 to 95 63.6 to 97 (Re+Co) Re 0.03 to 39.6 0.1 to7L6 0.04 to 34.7 0.15 to 67.1 0.05 to 29.7 0.19 to 62 - Co 0.03 to 39.6 0.05 to 51.7 0.04 to 34.7 0.06 to 46.5 0.05 to 29.7 0.07 to 41 TiN TiN 60 lo 97 28 to 95 65 to 96 32.6 to 93.4 70 to 95 37.8 to 92 (Re+Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.3 0.05 to 29.7 O.)4io 54.8 - C o 0.03 to 39.6 0.035 to 44.4 0.04 to 34.7 0.046 to 39.3 0.05 to 29.7 0.056 to 34 ZrN 2rN 60 to 97 34.5 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re+Co) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2 - Co 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 25.7 0.05 to 29 7 0.03 to 21.6 HfN HfN 60 to 97 49.8 to 98 65 to 96 55.1 to 97.3 70 to 95 60.7 to 96.6 (Ren-Co) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6 - Co 0.03 to 39.6 0.04 to 49.3 0.04 to 34.7 0.055 to 44 0.05 to 29.7 0.06710 38.6 VN VN 60 To 97 30 to 95.5 65 to 96 35 to 94 70 to 95 40 to 92.6 (Re+Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.4 0.05 to 29.7 0.)4 to 54.8 - Co 0,03 to 39.6 0.035 to 44.5 0.04 to 34.7 0.046 to 39.4 0.05 to 29.7 0.057 to 34.1 NbN NbN 60 to 97 34.4 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re+Co) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.075 to 383 - Co 0.03 to 39.6 0.019 to 29 .2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0,03 to 21 TaN TaN 60 to 97 50.7 to 9S 65 to 96 56 to 97.4 70 lo 95 61.5to 96.7

表21在黏結劑中利用鎳基超合金及Co來黏結由元素週期表中IVb、Vb及VIb族元素所形成 • 的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由1 %鎳基超合金+99%Co至99%鎳基超合金+l%Co 材料組成範圍1 組成範圔2 組成範圍3 體梢％重量％體稍％重量％體積％重量％ (NBSA+Co) NBSA 0.03 to 39.6 0.05 to 51.5 0.04 lo 34.7 0.06 to 46.2 0.05 ΐο 29.7 0.0S to 40.6 Co 0.03 to 39.6 0.05 to 54.5 0.04 to 34.7 0.07 to 49.2 0.05 to 29.7 0.09 to 43.6 TiC TiC 60 lo 97 45 to 95 65 to 96 50 to 93.6 70 to 95 56 to 92 (NBSA+Co) NBSA 0.03 to 39.6 0.04to 44.4 0.04 to 34.7 0.05 to 39.2 0.05 to 29.7 0.06 to 57.5 - Co 0.03 to 39.6 0.04 to 47.4 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 34 ZrC ZrC 60 to 97 52 to 96 65 to 96 57 to 95 70 to 95 63 to 94 (NBSA+Co) NBSA 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.026 to 25 0.05 to 29.7 0.03 to 21 - Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27.5 0.05 to 29.7 0.036 to 23 HfC HfC 60 to 97 68 to 98 65 to 96 72 to 97.4 70 to 95 77 to 96.8 (>JBSA+Co) NBSA 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 297 0.07 to 38Table 21 uses a nickel-based superalloy and Co in the binder to bond carbides formed by elements of groups IVb, Vb and VIb of the periodic table or nitrides formed by elements of group IVb and Vb of the periodic table. The composition ratio of the binder is from 1% nickel-based superalloy +99%Co to 99% nickel-based superalloy +l%Co material composition range 1 composition range 2 composition range 3 body tip % weight % body slightly % weight % volume %% by weight (NBSA+Co) NBSA 0.03 to 39.6 0.05 to 51.5 0.04 lo 34.7 0.06 to 46.2 0.05 ΐο 29.7 0.0S to 40.6 Co 0.03 to 39.6 0.05 to 54.5 0.04 to 34.7 0.07 to 49.2 0.05 to 29.7 0.09 to 43.6 TiC TiC 60 Lo 97 45 to 95 65 to 96 50 to 93.6 70 to 95 56 to 92 (NBSA+Co) NBSA 0.03 to 39.6 0.04to 44.4 0.04 to 34.7 0.05 to 39.2 0.05 to 29.7 0.06 to 57.5 - Co 0.03 to 39.6 0.04 to 47.4 0.04 To 34.7 0.05 to 42 0.05 to 29.7 0.07 to 34 ZrC ZrC 60 to 97 52 to 96 65 to 96 57 to 95 70 to 95 63 to 94 (NBSA+Co) NBSA 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.026 to 25 0.05 To 29.7 0.03 to 21 - Co 0.03 to 39.6 0.02 to 32 0.04 to 34. 7 0.03 to 27.5 0.05 to 29.7 0.036 to 23 HfC HfC 60 to 97 68 to 98 65 to 96 72 to 97.4 70 to 95 77 to 96.8 (>JBSA+Co) NBSA 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 297 0.07 to 38

1057D-6939-PF 118 ⑧ I3、392191057D-6939-PF 118 8 I3, 39219

- Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.08 to 41 VC VC 60 to 97 48 to 96 65 to 96 53 to 93.5 70 to 95 59 to 93 (NBSA+Co) NBSA 0.03 to 39.6 0.03 to 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 - Co 0.03 to 39.6 0.035 to 43 0.04 to 34.7 0.046 to 38 0.05 to 29.7 0.06 to 33 NbC NbC 60 to 97 57 to 97 65 to 96 62 to 96 70 to 95 67 to 95 (NBSA+Co) NBSA 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.03 to 19 - Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 TaC TaC 60 to 97 71 to 98 65 to 96 75 to 97.8 70 to 95 79 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 - Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 Cr2C3 Cr2C3 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 (MBSA+Co) NBSA 0.03 to 39.6 0.026 to 36.5 0.04 to 34.7 0.035 to 32 0.05 to 29.7 0.044 to 27 - Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 30 Mo2C Mo2C 60 to 97 60 to 97 65 to 96 65 to 96 70 to 95 70 to 95.6 (NBSA+Co) NBSA 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - Co 0.03 to 39.6 0.018 to 27.5 0.04 to 34.7 0.024 to 23.5 0.05 to 29.7 0.03 to 19.7 wc WC 60 to 97 72 to98 65 lo 96 76 to 98 70 to 95 80 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.4 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 - Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.065 to 47 0.05 to 29.7 0.08 to 41 TiN TiN 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 (NBSA+Co) NBSA .0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 - Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 ZrN ZrN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (NBSA+Co) NBSA 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.03 to 22 - Co 0.03 to 39.6 0.02 to 27 0.04 to 34.7 0.024 to 23 0.05 to 29.7 0.03 to 20 HfN HfN 60 to 97 · 70 to 98 65 to 96 74 to 97.6 70 to 95 78 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.045 to 53 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.07 to 41 - Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.055 to 40 0.05 to 29.7 0.066 to 34 VN VN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 (NBSA+Co) NBSA 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 - Co 0.03 to 39.6 0.03 to 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbN NbN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (Re+Co) NBSA 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 - Co 0.03 to 39.6 0.017 to 26 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.03 to 19 TaN TaN 60 to 97 70 to 98 65 to 96 75 to 97.7 70 to 95 79 to 97 表22 在黏結劑中利用Re、鎳基超合金及Co來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由0.5%+0.5%Co+99%鎮基超合金至0.5%Re+99%Co+0.5%鎳基超合金材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％- Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.08 to 41 VC VC 60 to 97 48 to 96 65 to 96 53 to 93.5 70 to 95 59 to 93 (NBSA+Co) NBSA 0.03 to 39.6 0.03 To 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 - Co 0.03 to 39.6 0.035 to 43 0.04 to 34.7 0.046 to 38 0.05 to 29.7 0.06 to 33 NbC NbC 60 to 97 57 to 97 65 to 96 62 to 96 70 to 95 67 to 95 (NBSA+Co) NBSA 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.03 to 19 - Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 TaC TaC 60 to 97 71 to 98 65 to 96 75 to 97.8 70 to 95 79 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 - Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 Cr2C3 Cr2C3 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 (MBSA+Co) NBSA 0.03 to 39.6 0.026 to 36.5 0.04 to 34.7 0.035 to 32 0.05 to 29.7 0.044 to 27 - Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 2 9.7 0.05 to 30 Mo2C Mo2C 60 to 97 60 to 97 65 to 96 65 to 96 70 to 95 70 to 95.6 (NBSA+Co) NBSA 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - Co 0.03 to 39.6 0.018 to 27.5 0.04 to 34.7 0.024 to 23.5 0.05 to 29.7 0.03 to 19.7 wc WC 60 to 97 72 to98 65 lo 96 76 to 98 70 to 95 80 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.4 to 49 0.04 To 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 - Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.065 to 47 0.05 to 29.7 0.08 to 41 TiN TiN 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 (NBSA+Co) NBSA .0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 - Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 ZrN ZrN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (NBSA+Co) NBSA 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.03 to 22 - Co 0.03 to 39.6 0.02 to 27 0.04 to 34.7 0.024 to 23 0.05 to 29.7 0.03 to 20 HfN HfN 60 to 97 · 70 to 98 65 to 96 74 to 97.6 7 0 to 95 78 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.045 to 53 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.07 to 41 - Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.055 to 40 0.05 to 29.7 0.066 to 34 VN VN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 (NBSA+Co) NBSA 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 - Co 0.03 to 39.6 0.03 To 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbN NbN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (Re+Co) NBSA 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 To 26 0.05 to 29.7 0.032 to 22 - Co 0.03 to 39.6 0.017 to 26 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.03 to 19 TaN TaN 60 to 97 70 to 98 65 to 96 75 to 97.7 70 to 95 79 to 97 Table 22 In the binder, Re, a nickel-based superalloy and Co are used to bond carbides formed by elements of groups IVb, Vb and VIb of the periodic table or nitrides formed by elements of group IVb and Vb of the periodic table, wherein The composition ratio of the binder ranges from 0.5%+0.5%Co+99% of the base-based superalloy to 0.5%Re+99%Co+0.5% nickel-based super Gold Material Composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt%

1057D-6939-PF 1191057D-6939-PF 119

13392191339219

(Re+Co Re 0.015 to 39.6 0.06 to 73.6 0.02 to 34.65 0.08 to 69.3 0.025 to 29.7 0.1 to 64.3 +NBSA) NBSA 0.015 to 39.6 0.02 to 51.3 0.02 to 34.65 0.03 to 46.0 0.025 to 29.7 0.035 to 40.5 - Co 0.015 to 39.6 0.03 to 54.3 0.02 to 34.65 0.036 to 49.0 0.025 to 29.7 0.045 to 43.5 TiC TiC 60 to 97 26 to 95 65 to 96 30 to 94 70 to 95 35 to 92 (Re+Co Re 0.015 to 39.6 0.05 to 67.7 0.02 to 34.65 0.06 to 62.9 0.025 to 29.7 0.08 to 57.5 +NBSA) NBSA 0.015 to 39.6 0.017 to 44.2 0.02 to 34.65 0.022 to 39.1 0.025 to 29.7 0.028 to 33.9 - Co 0.015 to 39.6 0.02 to 47.2 0.02 to 34.65 0.027 to 42.0 0.025 to 29.7 0.034 to 36.7 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 94 (Re+Co Re 0.015 to 39.6 0.025 to 52.1 0.02 to 34.65 0.034 to 46.8 0.025 to 29.7 0.042 to 41.2 +NBSA) NBSA 0.015 to 39.6 0.009 to 29.3 0.02 to 34.65 0.012 to 25.1 0.025 to 29.7 0.015 to 21 - Co 0.015 to 39.6 0.01 to 31.8 0.02 to 34.65 0.014 to 27.4 0.025 to 29.7 0.018 to 23.1 HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97.4 70 to 95 59 to 96.8 (Re+Co Re 0.015 to 39.6 0.06 to 71.5 0.02 to 34.65 0.08 to 67 0.025 to 29.7 0.09 to 61.8 +NBSA) NBSA 0.015 to 39.6 0.02 to 48.6 0.02 to 34.65 0.026 to 43.4 0.025 to 29.7 0.032 to 38 - Co 0.015 to 39.6 0.024 to 51.7 0.02 to 34.65 0.032 to 46.4 0.025 to 29.7 0.04 to 40.9 VC VC 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re+Co Re 0.015 to 39.6 0.04 to 63.8 0.02 to 34.65 0.05 to 58.7 0.025 to 29.7 0.07 to 53.1 +NBSA) NBSA 0.015 to 39.6 0.015 to 40 0.02 to 34.65 0.02 to 35 0.025 to 29.7 0.024 to 30 - Co 0.015 to 39.6 0.017 to 43 0.02 to 34.65 0.023 to 37.9 0.025 to 29.7 0.03 to 32.7 NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 (Re+Co Re 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.03 to 43.5 0.025 to 29.7 0.04 to 38 +NBSA) NBSA 0.015 to 39.6 0.008 to 26.6 0.02 to 34.65 0.011 to 22.6 0.025 to 29.7 0.013 to 18.9 - Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 24.8 0.025 to 29.7 0.016 to 20.8 TaC TaC 60 to 97 51 to 98.3 65 to 96 56 to 97.7 70 to 95 61.8 to 97.2 (Re+Co Re 0.015 to 39.6 0.05 to 67.3 0.02 to 34.65 0.06 to 62.5 0.025 to 29.7 0.08 to 57 +NBSA) NBSA 0.015 to 39.6 0.017 to 43.8 0.02 to 34.65 0.022 to 38.7 0.025 to 29.7 0.027 to 33.5 - Co 0.015 to 39.6 0.02 to 46.8 0.02 to 34.65 0.027 to 41.6 0.025 to 29.7 0.033 to 36.2 Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to94 (Re+Co Re 0.015 to 39.6 0.03 to 60.2 0.02 to 34.65 0.05 to 55 0.025 to 29.7 0.06 to 49 +NBSA) NBSA 0.015 to 39.6 0.013 to 36.4 0.02 to 34.65 0.017to31.7 0.025 to 29.7 0.02 to 27 - Co 0.015 to 39.6 0.015 to 39.3 0.02 to 34.65 0.02 to 34 0.025 to 29.7 0.025 to 29 Mo2C Mo2C 60 to 97 39 to 97 65 to 96 45 to 96 70 to 95 50 to 95.6 (Re+Co Re 0.015 to 39.6 0.02 to 46.9 0.02 to 34.65 0.027 to 41.7 0.025 to 29.7 0.034 to 36.3 +NBSA) NBSA 0.015 to 39.6 0.008 to 25.1 0,02 to 34.65 0.01 to 21.3 0.025 to 29.7 0.013 to 17.8 - Co 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.012 to 23.5 0.025 to 29.7 0.015 to 19.6 WC WC 60 to 97 53 to 98 65 to 96 58 to 97.8 70 to 95 64 to 97.4 材针組成範圍1 組成範圍2 組成範圍3 體積％重量％體積0/。重量％體積％重量％ (Re+Co Re 0.015 to 39.6 0.06 to 71.6 0.02 to 34.65 0.08 to 67.2 0.025 to 29.7 0.1 to 62 +NBSA) NBSA 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.027 to 43.6 0.025 to 29.7 0.032 to 38.2 - Co 0.015 to 39.6 0.025 to 51.9 0.02 to 34.65 0.03 to 46.6 0.025 to 29.7 0.04 to 41(Re+Co Re 0.015 to 39.6 0.06 to 73.6 0.02 to 34.65 0.08 to 69.3 0.025 to 29.7 0.1 to 64.3 +NBSA) NBSA 0.015 to 39.6 0.02 to 51.3 0.02 to 34.65 0.03 to 46.0 0.025 to 29.7 0.035 to 40.5 - Co 0.015 to 39.6 0.03 to 54.3 0.02 to 34.65 0.036 to 49.0 0.025 to 29.7 0.045 to 43.5 TiC TiC 60 to 97 26 to 95 65 to 96 30 to 94 70 to 95 35 to 92 (Re+Co Re 0.015 to 39.6 0.05 to 67.7 0.02 to 34.65 0.06 To 62.9 0.025 to 29.7 0.08 to 57.5 +NBSA) NBSA 0.015 to 39.6 0.017 to 44.2 0.02 to 34.65 0.022 to 39.1 0.025 to 29.7 0.028 to 33.9 - Co 0.015 to 39.6 0.02 to 47.2 0.02 to 34.65 0.027 to 42.0 0.025 to 29.7 0.034 to 36.7 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 94 (Re+Co Re 0.015 to 39.6 0.025 to 52.1 0.02 to 34.65 0.034 to 46.8 0.025 to 29.7 0.042 to 41.2 +NBSA) NBSA 0.015 to 39.6 0.009 to 29.3 0.02 to 34.65 0.012 to 25.1 0.025 to 29.7 0.015 to 21 - Co 0.015 to 39.6 0.01 to 31.8 0.02 to 34.65 0.014 to 27.4 0.025 to 29.7 0.018 to 23.1 HfC HfC 60 to 97 48 to 98 65 to 96 53 to 9 7.4 70 to 95 59 to 96.8 (Re+Co Re 0.015 to 39.6 0.06 to 71.5 0.02 to 34.65 0.08 to 67 0.025 to 29.7 0.09 to 61.8 +NBSA) NBSA 0.015 to 39.6 0.02 to 48.6 0.02 to 34.65 0.026 to 43.4 0.025 to 29.7 0.032 To 38 - Co 0.015 to 39.6 0.024 to 51.7 0.02 to 34.65 0.032 to 46.4 0.025 to 29.7 0.04 to 40.9 VC VC 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re+Co Re 0.015 to 39.6 0.04 to 63.8 0.02 to 34.65 0.05 to 58.7 0.025 to 29.7 0.07 to 53.1 +NBSA) NBSA 0.015 to 39.6 0.015 to 40 0.02 to 34.65 0.02 to 35 0.025 to 29.7 0.024 to 30 - Co 0.015 to 39.6 0.017 to 43 0.02 to 34.65 0.023 to 37.9 0.025 to 29.7 0.03 to 32.7 NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 (Re+Co Re 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.03 to 43.5 0.025 to 29.7 0.04 to 38 +NBSA) NBSA 0.015 to 39.6 0.008 to 26.6 0.02 to 34.65 0.011 to 22.6 0.025 to 29.7 0.013 to 18.9 - Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 24.8 0.025 to 29.7 0.016 to 20.8 TaC TaC 60 to 97 51 to 98.3 65 to 9 6 56 to 97.7 70 to 95 61.8 to 97.2 (Re+Co Re 0.015 to 39.6 0.05 to 67.3 0.02 to 34.65 0.06 to 62.5 0.025 to 29.7 0.08 to 57 +NBSA) NBSA 0.015 to 39.6 0.017 to 43.8 0.02 to 34.65 0.022 to 38.7 0.025 To 29.7 0.027 to 33.5 - Co 0.015 to 39.6 0.02 to 46.8 0.02 to 34.65 0.027 to 41.6 0.025 to 29.7 0.033 to 36.2 Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to94 (Re+Co Re 0.015 To 39.6 0.03 to 60.2 0.02 to 34.65 0.05 to 55 0.025 to 29.7 0.06 to 49 +NBSA) NBSA 0.015 to 39.6 0.013 to 36.4 0.02 to 34.65 0.017to31.7 0.025 to 29.7 0.02 to 27 - Co 0.015 to 39.6 0.015 to 39.3 0.02 to 34.65 0.02 to 34 0.025 to 29.7 0.025 to 29 Mo2C Mo2C 60 to 97 39 to 97 65 to 96 45 to 96 70 to 95 50 to 95.6 (Re+Co Re 0.015 to 39.6 0.02 to 46.9 0.02 to 34.65 0.027 to 41.7 0.025 to 29.7 0.034 to 36.3 +NBSA) NBSA 0.015 to 39.6 0.008 to 25.1 0,02 to 34.65 0.01 to 21.3 0.025 to 29.7 0.013 to 17.8 - Co 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.012 to 23.5 0.025 to 29.7 0.015 to 19.6 WC WC 60 t o 97 53 to 98 65 to 96 58 to 97.8 70 to 95 64 to 97.4 Material needle Composition range 1 Composition range 2 Composition range 3 vol% % by weight Volume 0/. % by weight % by weight (Re+Co Re 0.015 to 39.6 0.06 to 71.6 0.02 to 34.65 0.08 to 67.2 0.025 to 29.7 0.1 to 62 +NBSA) NBSA 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.027 to 43.6 0.025 to 29.7 0.032 to 38.2 - Co 0.015 to 39.6 0.025 to 51.9 0.02 to 34.65 0.03 to 46.6 0.025 to 29.7 0.04 to 41

1057D-6939-PF 1201057D-6939-PF 120

TiN TiN 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re-^-Co Re 0.015 to 39.6 0.04 to 65.3 0.02 to 34.65 0.06 to 60.3 0.025 to 29.7 0.07 to 54.8 +NBSA) NBSA 0.015 to 39.6 0.016 to 41.6 0.02 to 34.65 0.02 to 36.6 0.025 to 29.7 0.025 to 31.5 - Co 0.015 to 39.6 0.02 to 44.6 0.02 to 34.65 0.025 to 40 0.025 to 29.7 0.03 to 34 2rN ZrN 60 to 97 34 to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re+Co Re 0.015 to 39.6 0.02 to 50 0.02 to 34.65 0.03to45 0.025 to 29.7 0.04 to 39 +NBSA NBSA 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.011 to 23.5 0.025 to 29.7 0.014 to 20 - Co 0.015 to 39.6 0.01 to 30 0.02 to 34.65 0.013 to 25.8 0.025 to 29.7 0.017 to 22 HfN _ 60 to 97 50 to 98 65 to 96 55 to 97.6 70 to 95 61 to 97 Re+Co Re 0.015 to 39.6 0.05 to 60 0.02 to 34.65 0.07 to 65 0.025 to 29.7 0.09 to 60 +NBSA NBSA 0.015 to 39.6 0.02 to 46.4 0.02 to 34.65 0.024to41.2 0.025 to 29.7 0.03 to 36 - Co 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 39 VN VN 60 to 97 30 to 96 65 to 96 35 to 95 70 to 95 40 to 93 Re+Co Re 0.015 to 39.6 0.04 to 65 0.02 to 34.65 0.06 to 60 0.025 to 29.7 0.07 to 55 +NBSA NBSA 0.015 to 39.6 0.016to 42 0.02 to 34.65 0.02 to 37 0.025 to 29.7 0.025 to 32 - Co 0.015 to 39.6 0.02 to 45 0.02 to 34.65 0.025 to 39.5 0.025 to 29.7 0.03 to 34 NbN NbN 60 to 97 34to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re+Co Re 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 38 +NBSA NBSA 0.015 to 39.6 0.008 to 27 0.02 to 34.65 0.011 to 23 0.025 to 29.7 0.014 to 19 - Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 25 0.025 to 29.7 0.016 to 21 TaN TaN 60 to 97 51 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97.1 表23利用Re來黏結WOTiC或WOTaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重童％ Re Re 3 to 40 4 to 54 4 to 35 5 to 49 5 to 30 7 to 43 - WC 40 to 96 40 to 96 43 to 94.5 44 to 94 45 to 93 48 to 93 WC+TiC TiC I to 48 0.3 to 21 1.5 to 43 0.5 to 19 2 to 45 0.6 to 18 Re Re 3 to 40 4 to 48 4 to 35 5 to 42 5 to 30 7 to 37 - WC 50 to 96.5 44 to 96 55 to 95 49 to 94 60 to 93.5 55 to 92 WC+TaC TaC 0.5 to 24 0.5 to 21 1 to 22 1 to 19 1.5 to 18 1.5 to!8 Re Re 3 to 40 4 to 48 4 to 35 5 to 43 5 to 30 7 to 38 - WC 40 to 95.5 36 to 95 45 to 93 41 to 93 50 to 90 48 to 90 WC+TiC TiC 1 to 48 0.3 to 22 2 to 45 0.6 to 20 3 to 42 0.9 to 18 +TaC TaC 0.5 to 20 0.5 to 25 1 to 18 0.8 to 22 2 to 15 2 to 17 表24利用鎳基超合金來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍〗組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ NBSA NBSA 3 to 40 1.5 to31 4 to 35 2 to 26 5 to 30 3 to 23TiN TiN 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re-^-Co Re 0.015 to 39.6 0.04 to 65.3 0.02 to 34.65 0.06 to 60.3 0.025 to 29.7 0.07 to 54.8 +NBSA) NBSA 0.015 To 39.6 0.016 to 41.6 0.02 to 34.65 0.02 to 36.6 0.025 to 29.7 0.025 to 31.5 - Co 0.015 to 39.6 0.02 to 44.6 0.02 to 34.65 0.025 to 40 0.025 to 29.7 0.03 to 34 2rN ZrN 60 to 97 34 to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re+Co Re 0.015 to 39.6 0.02 to 50 0.02 to 34.65 0.03to45 0.025 to 29.7 0.04 to 39 +NBSA NBSA 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.011 to 23.5 0.025 to 29.7 0.014 to 20 - Co 0.015 to 39.6 0.01 to 30 0.02 to 34.65 0.013 to 25.8 0.025 to 29.7 0.017 to 22 HfN _ 60 to 97 50 to 98 65 to 96 55 to 97.6 70 to 95 61 to 97 Re+Co Re 0.015 to 39.6 0.05 to 60 0.02 To 34.65 0.07 to 65 0.025 to 29.7 0.09 to 60 +NBSA NBSA 0.015 to 39.6 0.02 to 46.4 0.02 to 34.65 0.024to41.2 0.025 to 29.7 0.03 to 36 - Co 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 39 VN VN 60 to 97 30 t o 96 65 to 96 35 to 95 70 to 95 40 to 93 Re+Co Re 0.015 to 39.6 0.04 to 65 0.02 to 34.65 0.06 to 60 0.025 to 29.7 0.07 to 55 +NBSA NBSA 0.015 to 39.6 0.016to 42 0.02 to 34.65 0.02 to 37 0.025 to 29.7 0.025 to 32 - Co 0.015 to 39.6 0.02 to 45 0.02 to 34.65 0.025 to 39.5 0.025 to 29.7 0.03 to 34 NbN NbN 60 to 97 34to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re+Co Re 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 38 +NBSA NBSA 0.015 to 39.6 0.008 to 27 0.02 to 34.65 0.011 to 23 0.025 to 29.7 0.014 to 19 - Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 25 0.025 to 29.7 0.016 to 21 TaN TaN 60 to 97 51 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97.1 Table 23 Rebonding WOTiC or WOTaC or WC+TiC+TaC compositional composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol%% Re Re 3 to 40 4 to 54 4 to 35 5 to 49 5 to 30 7 to 43 - WC 40 to 96 40 to 96 43 to 94.5 44 to 94 45 to 93 48 to 93 WC+TiC TiC I to 48 0 .3 to 21 1.5 to 43 0.5 to 19 2 to 45 0.6 to 18 Re Re 3 to 40 4 to 48 4 to 35 5 to 42 5 to 30 7 to 37 - WC 50 to 96.5 44 to 96 55 to 95 49 to 94 60 to 93.5 55 to 92 WC+TaC TaC 0.5 to 24 0.5 to 21 1 to 22 1 to 19 1.5 to 18 1.5 to! 8 Re Re 3 to 40 4 to 48 4 to 35 5 to 43 5 to 30 7 to 38 - WC 40 to 95.5 36 to 95 45 to 93 41 to 93 50 to 90 48 to 90 WC+TiC TiC 1 to 48 0.3 to 22 2 to 45 0.6 to 20 3 to 42 0.9 to 18 +TaC TaC 0.5 to 20 0.5 to 25 1 to 18 0.8 to 22 2 to 15 2 to 17 Table 24 Composition of WC+TiC or WC+TaC or WC+TiC+TaC using nickel-based superalloys Composition range 2 Composition range 3 vol% % by weight 5% by volume 5% by volume 5% by weight NBSA NBSA 3 to 40 1.5 to 31 4 to 35 2 to 26 5 to 30 3 to 23

1057D-6939-PF 121 13^9219 - WC 40 to 96 60 to 98 43 to 94.5 63 to 97 45 to 93 66 to 96.5 WC 十 Tie TiC 1 to 48 0.3 to 25 1.5 to 43 0.5 to 22 2 to 45 0.6 to 20 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 18 - WC 50 to 96. 5 63 to 98 55 to 95 67 to 97 60 to 93.5 71 to 96 WC+TaC TaC 0.5 to 24 0.5 to 26 1 to 22 1 to 23 1.5 to 18 1.5 to 21 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 19 - WC 40 to 95.5 51 to 98 45 to 93 56 to 96 50 to 90 61 to 94 WC+TiC TiC 1 to 48 0.4 to 23 2 to 45 0.8 to 21 3 to 42 1 to 19 +TaC TaC 0.5 to 20 0.6 to 26 1 to 18 1 to 23 2 to 15 2 to 18 表25利用Re及鎳基超合金來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成1057D-6939-PF 121 13^9219 - WC 40 to 96 60 to 98 43 to 94.5 63 to 97 45 to 93 66 to 96.5 WC Ten Tie TiC 1 to 48 0.3 to 25 1.5 to 43 0.5 to 22 2 to 45 0.6 to 20 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 18 - WC 50 to 96. 5 63 to 98 55 to 95 67 to 97 60 to 93.5 71 to 96 WC+TaC TaC 0.5 to 24 0.5 to 26 1 to 22 1 to 23 1.5 to 18 1.5 to 21 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 19 - WC 40 to 95.5 51 to 98 45 to 93 56 to 96 50 To 90 61 to 94 WC+TiC TiC 1 to 48 0.4 to 23 2 to 45 0.8 to 21 3 to 42 1 to 19 +TaC TaC 0.5 to 20 0.6 to 26 1 to 18 1 to 23 2 to 15 2 to 18 Table 25 Recombination of WC+TiC or WC+TaC or WC+TiC+TaC using Re and Ni-based superalloys

材料組成範圍1 組成範圍2 組成範圍3 體積0/〇重a% 體積％重量％體積％重量％ (Re+ Re 0.03 to 39.6 0.04 to 52 0.04 to 34.65 0.06 to 48 0.05 to 29.7 0.07 to 45 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.026 to 23 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96.6 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+ Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18 - WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95.5 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to21.5 2 to 18 2 to 19 (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21 - WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC+TiC TiC 1 to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19 十TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18 表26利用Re及Co來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成Material composition range 1 Composition range 2 Composition range 3 Volume 0/〇 weight a% Volume% Weight% Volume% Weight% (Re+ Re 0.03 to 39.6 0.04 to 52 0.04 to 34.65 0.06 to 48 0.05 to 29.7 0.07 to 45 NBSA) NBSA 0.03 To 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.026 to 23 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96.6 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+ Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18 - WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95.5 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21 - WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC+TiC TiC 1 to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0. 9 to 19 Ten TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18 Table 26 Rebonding WC+TiC or WC+TaC or WC+TiC+TaC using Re and Co

材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.055 to 48 0.05 to 29.7 0.07 to 43 Co) Co 0.03 to 39.6 0.0I7to31 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 26 - WC 40 lo 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC+TiC TiC 1 to 48 0.3 to 23 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+ Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 Co) CO 0.03 to 39.6 0.017 to 28 0.04 to 34.65 0.023 to 24 0.05 to 29.7 0.03 to 20 - WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21 2 to 18 2 to 19 (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 Co) Co 0.03 to 39.6 0.017 to 33 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 23 - WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC+TiC TiC I to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.055 to 48 0.05 to 29.7 0.07 to 43 Co) Co 0.03 to 39.6 0.0 I7to31 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 26 - WC 40 lo 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC+TiC TiC 1 to 48 0.3 to 23 1.5 to 45 0.5 to 22 2 To 42 0.6 to 21 (Re+ Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 Co) CO 0.03 to 39.6 0.017 to 28 0.04 to 34.65 0.023 to 24 0.05 to 29.7 0.03 to 20 - WC 50 To 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21 2 to 18 2 to 19 (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 Co) Co 0.03 to 39.6 0.017 to 33 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 23 - WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC+TiC TiC I to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19

l〇57D-6939-PF 122 1339219 » » · +TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18 表27利用Co及鎳基超合金來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範園3 體積％重量％體積°/。重量％體積％重量％ (Co+ Co 0.03 to 39.6 0.018 to 33 0.04 to 34.65 0.024 to 29 0.05 to 29.7 0.03 to 25 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.03 to 23 - wc 40 to 96 58 to 98 43 to 94.5 61 to 97 45 to 93 64 to 96.7 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.7 to 21 (Co+ Co 0.03 to 39.6 0.018 to 28 0.04 to 34.65 0.024 to 24 0.05 to 29.7 0.03 to 20 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18 - WC 50 to 96.5 61 to 98 55 to 95 65 to 97 60 to 93 69 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Co+ Co 0.03 to 39.6 0.0)8 to 33 0.04 to 34.65 0.024 to 28 0.05 to 29.7 0.03 to 23 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21 - WC 40 to 95.5 57 to 98 45 to 93 62 to 96 50 to 90 67 to 94 WC+TiC TiC 1 to 48 0.4 to 23 2 to 45 0.7 to 21 3 to 42 1 to 19 +TaC TaC 0.5 to 20 0.6 to 26 "o 18 ]to 23 2 to 15 2 to 18l〇57D-6939-PF 122 1339219 » » · +TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18 Table 27 Bonding WC+TiC or WC+ with Co and Ni-based superalloys Composition of TaC or WC+TiC+TaC Composition range 1 Composition range 2 Composition range 3 vol% wt% volume °/. Weight % vol% % by weight (Co+ Co 0.03 to 39.6 0.018 to 33 0.04 to 34.65 0.024 to 29 0.05 to 29.7 0.03 to 25 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.03 to 23 - wc 40 to 96 58 to 98 43 to 94.5 61 to 97 45 to 93 64 to 96.7 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.7 to 21 (Co+ Co 0.03 to 39.6 0.018 to 28 0.04 To 34.65 0.024 to 24 0.05 to 29.7 0.03 to 20 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18 - WC 50 to 96.5 61 to 98 55 to 95 65 to 97 60 to 93 69 To 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Co+ Co 0.03 to 39.6 0.0)8 to 33 0.04 to 34.65 0.024 to 28 0.05 to 29.7 0.03 to 23 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21 - WC 40 to 95.5 57 to 98 45 to 93 62 to 96 50 to 90 67 to 94 WC+TiC TiC 1 to 48 0.4 to 23 2 to 45 0.7 to 21 3 to 42 1 to 19 +TaC TaC 0.5 to 20 0.6 to 26 "o 18 ]to 23 2 to 15 2 to 18

表28 利用Re、鎳基超合金及Co來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成，其中黏結劑組成比例範圍由〇.5%Re+99.5%鎳基超合金至99.5%Re+0.5%鎳基超合金至0.5 %Re+0.5%鎳基超合金+99%Co 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積。/。重量％體積％重量％ (Re+Co Re 0.015 to 39.8 0.02 to 54 0.02 to 34.8 0.027 to 48 0.025 to 29.9 0.035 to 43 NBSA) NBSA 0.015 to 39.8 0.008 to 29 0.02 to 34.8 0.01 to 26 0.025 to 29.9 0.13 to 24 Co 0 to 39.6 0 to 32 Oto 34.7 Oto 29 0 to 29.8 Oto 26 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+Co Re 0.015 to 39.8 0.02 to 47 0.02 to 34.8 0.027 to 42 0.025 to 29.9 0.034 to 37 +NBSA) NBSA 0.015 to 39.8 0.008 to 26 0.02 to 34.8 0.01 to 22 0.025 to 29.9 0.13 to 18 - Co 0 to 39.6 Oto 28 Oto 34.7 Oto 24 0 to 29.8 Oto 20 WC 50 to 96.5 45 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 0.9 to 21 2 to 18 1.8tol9 (Re+ Re 0.015 to 39.8 0.02 to 65 0.02 to 34.8 0.027 to 58 0.025 to 29.9 0.034 to 51 NBSA NBSA 0.015 to 39.8 0.008 to41 0.02 to 34.8 0.01 to 34 0.025 to 29.9 0.13 to 28 +Co) Co 0 to 39.6 0 to 44 Oto 34.7 Oto 37 0 to 29.8 Oto 31 - WC 35 to 85 35 to 93 40 to 80 41 to 88 40 to 75 47 to83 WC+TiC TiC I to 50 0.3 to 25 2 to 45 0.6 to 22 3 to 40 0.9 to 18Table 28 uses Re, nickel-based superalloy and Co to bond the composition of WC+TiC or WC+TaC or WC+TiC+TaC, wherein the composition ratio of the binder ranges from 〇.5%Re+99.5% nickel-base superalloy to 99.5 %Re+0.5% nickel-based superalloy to 0.5% Re+0.5% nickel-based superalloy +99%Co material composition range 1 composition range 2 composition range 3 vol% wt% volume. /. % by weight 5% by weight (Re+Co Re 0.015 to 39.8 0.02 to 54 0.02 to 34.8 0.027 to 48 0.025 to 29.9 0.035 to 43 NBSA) NBSA 0.015 to 39.8 0.008 to 29 0.02 to 34.8 0.01 to 26 0.025 to 29.9 0.13 to 24 Co 0 to 39.6 0 to 32 Oto 34.7 Oto 29 0 to 29.8 Oto 26 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 To 22 2 to 42 0.6 to 21 (Re+Co Re 0.015 to 39.8 0.02 to 47 0.02 to 34.8 0.027 to 42 0.025 to 29.9 0.034 to 37 +NBSA) NBSA 0.015 to 39.8 0.008 to 26 0.02 to 34.8 0.01 to 22 0.025 to 29.9 0.13 to 18 - Co 0 to 39.6 Oto 28 Oto 34.7 Oto 24 0 to 29.8 Oto 20 WC 50 to 96.5 45 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 0.9 to 21 2 to 18 1.8tol9 (Re+ Re 0.015 to 39.8 0.02 to 65 0.02 to 34.8 0.027 to 58 0.025 to 29.9 0.034 to 51 NBSA NBSA 0.015 to 39.8 0.008 to41 0.02 to 34.8 0.01 to 34 0.025 to 29.9 0.13 to 28 + Co) Co 0 to 39.6 0 to 44 Oto 34.7 Oto 37 0 to 29.8 Oto 31 - WC 35 to 85 35 to 9 3 40 to 80 41 to 88 40 to 75 47 to83 WC+TiC TiC I to 50 0.3 to 25 2 to 45 0.6 to 22 3 to 40 0.9 to 18

1057D-6939-PF 123 ⑧ 13^9219 • » , +TaC 丁aC 0.5 to 25 0.4 to 26 1 to 22 0.8 to 24 2 to 20 1.6 to 211057D-6939-PF 123 8 13^9219 • » , +TaC 丁 aC 0.5 to 25 0.4 to 26 1 to 22 0.8 to 24 2 to 20 1.6 to 21

表29額外材料及其組成批號組成重量％ Re R95 Co U700 U720 Ni wc TiC TaC VC Mo2C TiN P80 0 0 14.28 74.15 5.835 5.733 P81 0.736 0 13.904 73.84 5.811 5.709 P82 0.707 6.026 7.3694 74.31 5.847 5.744 P83 0.679 12.82 0 74.83 5.889 5.785 P84 1.45 5.903 7.1237 73.98 5.622 5.719 P85 3.06 5.532 6.7027 73.27 5.766 5.665 P86 1.45 5.903 7.1237 36.99 5.822 5.719 P87 1.063 4.126 5.4174 78.14 5.676 5.576 P88 1.861 7.57 9.1372 69.59 5.974 5.869 P89 1.368 5.572 6.7242 80.31 3.004 3.023 P99 0 0 5.5 15 29 10 9.5 20 P100 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P101 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P102 4.8 10 14.5 28.1 9.7 9.5 19.4 P103 9.6 20 11.25 21.65 7.5 7.1 14.9 P104 7.2 15 12.8 25 8.6 8.1 17.3 P105 15 7.5 13.6 26.35 9.05 8.9 18.1 P106 14.49 0 0 74.415 5.092 6.003 P107 15.101 0 0 66.875 7.076 10.95 P108 11.796 0.7485 0.437 75727 5.182 6.109 P109 12.303 0.7807 0.456 68.105 7.206 11.15 P110 9.5724 1.4017 0.761 76.812 5.256 6.196 Pill 9.9896 1.4628 0.794 69.124 7.314 11.32 P112 6.9929 2.1369 1.16 78.07 5.342 6.298 P113 14.131 4.3182 2.343 67.447 5.398 6.363 P114 21.418 6.545 3.552 56.602 5.454 6.43 P115 3.8745 3.0258 1.642 79.591 5.446 6.421 P116 7.988 6.2383 3.385 70.155 5.614 6.619 P117 12.363 9.6552 5.24 60.119 5.793 6.829 P118 1.8824 3.5833 1.961 80.561 5.513 6.499 P119 2.8849 5.4917 3.006 76.345 5.632 6.64 P120 5.0264 9.5681 5.237 ' 67.339 5.888 6.941 P121 13.157 0.5708 0 75.078 5.138 6.057 P122 5.294 2.0672 0 81.057 5.316 6.266Table 29 Additional Materials and Their Composition Lots Composition Weight % Re R95 Co U700 U720 Ni wc TiC TaC VC Mo2C TiN P80 0 0 14.28 74.15 5.835 5.733 P81 0.736 0 13.904 73.84 5.811 5.709 P82 0.707 6.026 7.3694 74.31 5.847 5.744 P83 0.679 12.82 0 74.83 5.889 5.785 P84 1.45 5.903 7.1237 73.98 5.622 5.719 P85 3.06 5.532 6.7027 73.27 5.766 5.665 P86 1.45 5.903 7.1237 36.99 5.822 5.719 P87 1.063 4.126 5.4174 78.14 5.676 5.576 P88 1.861 7.57 9.1372 69.59 5.974 5.869 P89 1.368 5.572 6.7242 80.31 3.004 3.023 P99 0 0 5.5 15 29 10 9.5 20 P100 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P101 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P102 4.8 10 14.5 28.1 9.7 9.5 19.4 P103 9.6 20 11.25 21.65 7.5 7.1 14.9 P104 7.2 15 12.8 25 8.6 8.1 17.3 P105 15 7.5 13.6 26.35 9.05 8.9 18.1 P106 14.49 0 0 74.415 5.092 6.003 P107 15.101 0 0 66.875 7.076 10.95 P108 11.796 0.7485 0.437 75727 5.182 6.109 P109 12.303 0.7807 0.4 56 68.105 7.206 11.15 P110 9.5724 1.4017 0.761 76.812 5.256 6.196 Pill 9.9896 1.4628 0.794 69.124 7.314 11.32 P112 6.9929 2.1369 1.16 78.07 5.342 6.298 P113 14.131 4.3182 2.343 67.447 5.398 6.363 P114 21.418 6.545 3.552 56.602 5.454 6.43 P115 3.8745 3.0258 1.642 79.591 5.446 6.421 P116 7.988 6.2383 3.385 70.155 5.614 6.619 P117 12.363 9.6552 5.24 60.119 5.793 6.829 P118 1.8824 3.5833 1.961 80.561 5.513 6.499 P119 2.8849 5.4917 3.006 76.345 5.632 6.64 P120 5.0264 9.5681 5.237 ' 67.339 5.888 6.941 P121 13.157 0.5708 0 75.078 5.138 6.057 P122 5.294 2.0672 0 81.057 5.316 6.266

1057D-6939-PF 124 ⑧ 13392191057D-6939-PF 124 8 1339219

重量％ Re R95 Co U700 U720 Ni WC TiC TaC VC Mo2C TiN P123 19.908 5.9798 1.976 60.41 5.382 6.344 P124 20.68 9.9386 2.736 54.464 5.59 6.59 P125 1.5492 3.0246 0.833 82.731 5.444 6.418 P126 84621 13.217 3.639 61723 5.948 7.011 P127 12.191 13.964 3.844 61702 3.808 4.49 P128 11.906 0.5166 0 86.99 0.604 P129 1.6752 2.0169 1.9524 93.77 0.599 P130 11.97 8.0334 8.085 71.33 0.6 P131 1.4372 3.8162 3.7765 90.39 0.596 P132 6.6223 1.3705 1.3191 90.1 0.605 P133 5.505 1.7196 1.6331 90.55 0.609 P134 11.43 5.0212 4.8443 78.11 0.613 P135 1.644 2.3344 2.571 79.98 3.151 10.32 P136 3.6545 5.1371 5.657 73.439 0 12.11 P137 4.4642 6.3916 7.039 69.776 0 12.33 P138 4.899 6.5757 7.241 69.279 1.435 10.57 P139 6.5381 7.902 8.702 64.651 1-459 10.75 P140 3.0601 5.5324 6.703 73.274 5.766 5.665 P141 2.9261 5.2902 6.409 71.233 3.308 10.83 P142 5.0649 6.1371 7.419 67.113 3.337 10.93 A 13.853 0.2847 0.314 74.887 5.125 5.538 B 2.7327 5.0305 0 81.358 5.488 5.391 C 3.0601 5.5324 6.703 73.274 5.766 5.665 D 1.8803 3.5793 1.988 81.637 5.507 5.41 E 7.7737 9.4819 0 71.578 5.633 5.534 P144 0.6786 12.821 0 74.827 5.889 5.785 P145 0.6437 5.663 0 80.041 3.194 10.46 P146 1.8837 5.3941 0 81.786 5.517 5.42 P147 2.3479 5.1953 0 81.552 5.501 5.404 P148 1.5479 8.462 0 76.038 3.264 10.69 P149 1.6376 15.347 0 68.255 3.453 11.31 J 25.75 2.5 14.5 24.1 8.5 8 16.65 K 11.671 0.4143 0.3935 0 0 86.92 0.605 L 2.6826 5.5683 0 0 0 91.32 0.43 M 3.5669 0 14.235 0 0 81.75 0452 N 0 7.5039 0 0 0 92.06 0.44 0 12.515 0 0 0 0.2541 86.63 0.601 P 1.7969 0 0 6.9309 90.68 0.597 Q 0 0 0 7.4214 91.98 0.602% by weight Re R95 Co U700 U720 Ni WC TiC TaC VC Mo2C TiN P123 19.908 5.9798 1.976 60.41 5.382 6.344 P124 20.68 9.9386 2.736 54.464 5.59 6.59 P125 1.5492 3.0246 0.833 82.731 5.444 6.418 P126 84621 13.217 3.639 61723 5.948 7.011 P127 12.191 13.964 3.844 61702 3.808 4.49 P128 11.906 0.5166 0 86.99 0.604 P129 1.6752 2.0169 1.9524 93.77 0.599 P130 11.97 8.0334 8.085 71.33 0.6 P131 1.4372 3.8162 3.7765 90.39 0.596 P132 6.6223 1.3705 1.3191 90.1 0.605 P133 5.505 1.7196 1.6331 90.55 0.609 P134 11.43 5.0212 4.8443 78.11 0.613 P135 1.644 2.3344 2.571 79.98 3.151 10.32 P136 3.6545 5.1371 5.657 73.439 0 12.11 P137 4.4642 6.3916 7.039 69.776 0 12.33 P138 4.899 6.5757 7.241 69.279 1.435 10.57 P139 6.5381 7.902 8.702 64.651 1-459 10.75 P140 3.0601 5.5324 6.703 73.274 5.766 5.665 P141 2.9261 5.2902 6.409 71.233 3.308 10.83 P142 5.0649 6.1371 7.419 67.113 3.33 7 10.93 A 13.853 0.2847 0.314 74.887 5.125 5.538 B 2.7327 5.0305 0 81.358 5.488 5.391 C 3.0601 5.5324 6.703 73.274 5.766 5.665 D 1.8803 3.5793 1.988 81.637 5.507 5.41 E 7.7737 9.4819 0 71.578 5.633 5.534 P144 0.6786 12.821 0 74.827 5.889 5.785 P145 0.6437 5.663 0 80.041 3.194 10.46 P146 1.8837 5.3941 0 81.786 5.517 5.42 P147 2.3479 5.1953 0 81.552 5.501 5.404 P148 1.5479 8.462 0 76.038 3.264 10.69 P149 1.6376 15.347 0 68.255 3.453 11.31 J 25.75 2.5 14.5 24.1 8.5 8 16.65 K 11.671 0.4143 0.3935 0 0 86.92 0.605 L 2.6826 5.5683 0 0 0 91.32 0.43 M 3.5669 0 14.235 0 0 81.75 0452 N 0 7.5039 0 0 0 92.06 0.44 0 12.515 0 0 0 0.2541 86.63 0.601 P 1.7969 0 0 6.9309 90.68 0.597 Q 0 0 0 7.4214 91.98 0.602

1057D-6939-PF 125 133.9219 •· *> f s 8.371 0 0 5.3814 85.67 0.579 τ 1.6967 0 4.681 0 92.98 0.645 u 3.9002 0 0 3.8684 91.6 0.636 P150 0 0 14.847 84.68 0.469 P151 0 3.2554 11.851 84.38 0.51 重量％ Re R95 Co U700 U720 Ni WC TiC TaC VC M02C TiN P152 1.5219 3.225 11.153 83.59 0.505 P153 12.451 1.2899 4.6957 81.09 0.478 P154 2.6486 2.9933 7.6052 54.464 0.509 P155 0 0 11.55 82.731 0.414 P156 1.1019 3.5804 6.2338 61.723 0.671 P157 0 3.761 6.5607 86.24 0.675 P158 0 0 9.9898 88.04 0.512 P159 0.9437 3.0766 5.5161 88.41 0.502 P160 0 3.0946 5.9144 89 0.505 P161 0 0 8.7552 89.5 0.506 P162 2.967 5.6892 0.6379 0.654 89.817 0.2346 P163 0.581 8.1942 0.9297 0.8972 89.156 0.2413 P164 2.16 7.569 0.8669 0.8333 88.331 0.2391 P165 2.801 6.7279 1.976 2.026 86.226 0.2422 P166 2.797 8.3834 1.2603 1.2361 86.082 0.2418 P167 2.789 11.13 0 0 85.84 0.24111057D-6939-PF 125 133.9219 •· *> fs 8.371 0 0 5.3814 85.67 0.579 τ 1.6967 0 4.681 0 92.98 0.645 u 3.9002 0 0 3.8684 91.6 0.636 P150 0 0 14.847 84.68 0.469 P151 0 3.2554 11.851 84.38 0.51 wt% Re R95 Co U700 U720 Ni WC TiC TaC VC M02C TiN P152 1.5219 3.225 11.153 83.59 0.505 P153 12.451 1.2899 4.6957 81.09 0.478 P154 2.6486 2.9933 7.6052 54.464 0.509 P155 0 0 11.55 82.731 0.414 P156 1.1019 3.5804 6.2338 61.723 0.671 P157 0 3.761 6.5607 86.24 0.675 P158 0 0 9.9898 88.04 0.512 P159 0.9437 3.0766 5.5161 88.41 0.502 P160 0 3.0946 5.9144 89 0.505 P161 0 0 8.7552 89.5 0.506 P162 2.967 5.6892 0.6379 0.654 89.817 0.2346 P163 0.581 8.1942 0.9297 0.8972 89.156 0.2413 P164 2.16 7.569 0.8669 0.8333 88.331 0.2391 P165 2.801 6.7279 1.976 2.026 86.226 0.2422 P166 2.797 8.3834 1.2603 1.2361 86.082 0.2418 P167 2.789 11.13 0 0 85.84 0.241 1

3 Ο - 4 1列出金屬陶究組成物的組成範圍。3 Ο - 4 1 List the composition range of the metal ceramic composition.

表 30 利用 Re 爲黏結劑來黏結 TiC+Mo2C 或 TiN+Mo2C 或 TiC+TiN+Mo2C 或 TiC+TiN+Mo2C +WC+TaC+VC+Cr2C3 林料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ Re Re 3 to 30 9.5 to 65 4 to 27 13 to 60 5 to 25 15 to 58 - TiC 43 to 97 19 to 88 48 to 92 23 to 79 51 to 90 25 to 75 TiC+Mo2C Mo2C Oto 27 Oto 38 Oto 26 0 to 36 Oto 24 Oto 33 Re Re 3 to 30 9 to 63 4 to 27 12 to 58 5 to 25 15 to 56 - TiN 43 to 97 21 to 89 48 to 92 25 to 81 51 to 90 27 to 76 TiN+Mo2C Mo2C Oto 27 Oto 36 Oto 26 Oto 34 Oto 24 Oto 31 Re Re 3 to 30 9 to 64 4 to 27 12 to 60 5 to 25 15 to 58 - TiC 0.3 to 93.7 0.2 to 84 0.4 to 91.6 0.3 to 79 0.5 to 89.5 0.35 to 74 TiC+TiN TiN 0.3 to 93.7 0.3 to 85 0.4 to 91.6 0.4 to 80 0.5 to 89.5 0.5 to 76 +Mo2C Mo2C Oto 27 Oto 36 Oto 26 Oto 34 Oto 24 0 to 31Table 30 Re-bonding agent is used to bond TiC+Mo2C or TiN+Mo2C or TiC+TiN+Mo2C or TiC+TiN+Mo2C +WC+TaC+VC+Cr2C3 forest composition range 1 composition range 2 composition range 3 vol% weight % vol% 重量% vol% Re Re 3 to 30 9.5 to 65 4 to 27 13 to 60 5 to 25 15 to 58 - TiC 43 to 97 19 to 88 48 to 92 23 to 79 51 to 90 25 to 75 TiC +Mo2C Mo2C Oto 27 Oto 38 Oto 26 0 to 36 Oto 24 Oto 33 Re Re 3 to 30 9 to 63 4 to 27 12 to 58 5 to 25 15 to 56 - TiN 43 to 97 21 to 89 48 to 92 25 to 81 51 to 90 27 to 76 TiN+Mo2C Mo2C Oto 27 Oto 36 Oto 26 Oto 34 Oto 24 Oto 31 Re Re 3 to 30 9 to 64 4 to 27 12 to 60 5 to 25 15 to 58 - TiC 0.3 to 93.7 0.2 to 84 0.4 to 91.6 0.3 to 79 0.5 to 89.5 0.35 to 74 TiC+TiN TiN 0.3 to 93.7 0.3 to 85 0.4 to 91.6 0.4 to 80 0.5 to 89.5 0.5 to 76 +Mo2C Mo2C Oto 27 Oto 36 Oto 26 Oto 34 Oto 24 0 to 31

1057D-6939-PF 126 (Τ' 1339219 -i* ·1057D-6939-PF 126 (Τ' 1339219 -i* ·

Re Re 3 to 30 6 to 65 4 to 27 9 to 61 5 to 25 11 to 65 TiC 0.3 to 93.5 0.1 to 83 0.4 to 91.3 0.2 to 78 0.5 to 89.1 0.3 to 74 - TiN 0.3 to 93.5 0.15 to 85 0.4 to 91.3 0.2 to 80 0.5 to 89.1 0.3 to 76 Mo2C Oto 28 Oto 25 Oto 26 Oto 25 Oto 24 Oto 24 TiC+TiN wc 0.1 to 20 0.15 to 39 0.15 to 15 0.25 to 32 0.2 to 12 0.35 to 28 +Mo2C TaC 0.1 to 15 0.15 to 30 0.15 to 12 0.25 to 25 0.2 to 10 0.3 to 22 +WC+TaC VC Oto 15 Oto 11 Oto 12 Oto 10 Oto 10 0 to 9 +VC+Cr2C3 Cr2C3 Oto 15 Oto 16 Oto 12 Oto 14 Oto 10 0tol2 表31利用鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或DC+TiN+Mo2C或TiC+TiN +Mo2C+WC+TaC+VC+Cr2C3Re Re 3 to 30 6 to 65 4 to 27 9 to 61 5 to 25 11 to 65 TiC 0.3 to 93.5 0.1 to 83 0.4 to 91.3 0.2 to 78 0.5 to 89.1 0.3 to 74 - TiN 0.3 to 93.5 0.15 to 85 0.4 to 91.3 0.2 to 80 0.5 to 89.1 0.3 to 76 Mo2C Oto 28 Oto 25 Oto 26 Oto 25 Oto 24 Oto 24 TiC+TiN wc 0.1 to 20 0.15 to 39 0.15 to 15 0.25 to 32 0.2 to 12 0.35 to 28 +Mo2C TaC 0.1 to 15 0.15 to 30 0.15 to 12 0.25 to 25 0.2 to 10 0.3 to 22 +WC+TaC VC Oto 15 Oto 11 Oto 12 Oto 10 Oto 10 0 to 9 +VC+Cr2C3 Cr2C3 Oto 15 Oto 16 Oto 12 Oto 14 Oto 10 0tol2 31Using a nickel-based superalloy as a binder to bond TiC+Mo2C or TiN+Mo2C or DC+TiN+Mo2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量°/〇體積％重量％ NBSA NBSA 3 to 30 4 to 41 4 to 27 5 to 37 5 to 25 6 to 34 - TiC 43 to 94 30 to 90 48 to 92 35 to 87 51 to 90 37 to 84 TiC+Mo2C Mo2C 3 to 27 4 to 40 4 to 26 6 to 39 5 to 24 8 to 36 NBSA NBSA 3 to 30 4 to 38 4 to 27 5 to 34 5 to 25 6 to 32 - TiN 43 to 94 32 to 91 48 to 92 37 to 88 51 to 90 40 to 85 TiN+Mo2C Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 NBSA NBSA 3 to 30 4 to 40 4 to 27 5 to 36 5 to 25 6 to 34 - TiC 0.3 to 93.7 0.2 to 90 0.4 to 91.6 0.3 to 86 0.5 to 89.5 0.4 to 83 TiC+TiN TiN 0.3 to 93.7 0.3 to 91 0.4 to 91.6 0.4 to 88 0.5 to 89.5 0.5 to 85 +Mo2C Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 8 to 34 NBSA NBSA 3 to 30 2 to 40 4 to 27 4 to 36 5 to 25 5 to 34 TiC 0.3 to 93.3 0.15 to 90 0.4 to 91.3 0.2 to 86 0.5 to 89.3 0.3 to 83 - TiN 0.3 to 93.3 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.3 0.45 to 84 Mo2C 3 to 27 4 to 25 4 to 26 6 to 26 5 to 24 8 to 25.5 TiC+TiN WC 0.1 to 20 0.25 to 42 0.15 to 15 0.4 to 34 0.2 to 12 0.5 to 29 +Mo2C TaC 0.1 to 15 0.25 to 36 0.15 to 12 0.4 to 30 0.2 to 10 0.5 to 26 +WC+TaC VC Oto 15 0 to 14 Oto 12 Oto 12 Oto 10 Oto 10 +VC+Cr2C3 ^Γ2〇3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表32利用Re及鎳基超合金爲黏結劑來黏結TiC+M〇2C或TiN+M〇2C或TiC+TiN+M〇2C或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體《% 重量％體積％重量％ (Re+NBSA) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 - NBSA 0.03 to 29.7 0.03 to 40 0.04 to 26.73 0.05 to 36 0.05 to 24.75 0.06 to 34 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 84Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt 〇/〇 vol% wt% NBSA NBSA 3 to 30 4 to 41 4 to 27 5 to 37 5 to 25 6 to 34 - TiC 43 to 94 30 To 90 48 to 92 35 to 87 51 to 90 37 to 84 TiC+Mo2C Mo2C 3 to 27 4 to 40 4 to 26 6 to 39 5 to 24 8 to 36 NBSA NBSA 3 to 30 4 to 38 4 to 27 5 to 34 5 to 25 6 to 32 - TiN 43 to 94 32 to 91 48 to 92 37 to 88 51 to 90 40 to 85 TiN+Mo2C Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 NBSA NBSA 3 to 30 4 to 40 4 to 27 5 to 36 5 to 25 6 to 34 - TiC 0.3 to 93.7 0.2 to 90 0.4 to 91.6 0.3 to 86 0.5 to 89.5 0.4 to 83 TiC + TiN TiN 0.3 to 93.7 0.3 to 91 0.4 to 91.6 0.4 to 88 0.5 to 89.5 0.5 to 85 +Mo2C Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 8 to 34 NBSA NBSA 3 to 30 2 to 40 4 to 27 4 to 36 5 to 25 5 to 34 TiC 0.3 to 93.3 0.15 to 90 0.4 to 91.3 0.2 to 86 0.5 to 89.3 0.3 to 83 - TiN 0.3 to 93.3 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.3 0.45 to 84 Mo2C 3 to 27 4 to 25 4 to 26 6 to 26 5 to 24 8 to 25.5 TiC+TiN WC 0.1 to 20 0.25 to 42 0.15 to 15 0.4 to 34 0.2 to 12 0.5 to 29 +Mo2C TaC 0.1 to 15 0.25 to 36 0.15 to 12 0.4 to 30 0.2 to 10 0.5 to 26 + WC+TaC VC Oto 15 0 to 14 Oto 12 Oto 12 Oto 10 Oto 10 +VC+Cr2C3 ^Γ2〇3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 Table 32 Bonding with Re and Nickel-Based Superalloy as Adhesive TiC+M〇2C or TiN+M〇2C or TiC+TiN+M〇2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 Material composition range 1 Composition range 2 Composition range 3 vol% wt% Body “% Weight % Volume % Weight % (Re+NBSA) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 - NBSA 0.03 to 29.7 0.03 to 40 0.04 to 26.73 0.05 to 36 0.05 to 24.75 0.06 to 34 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 84

1057D-6939-PF 127 ⑧ +Mo〇C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA) Rc 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 - NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.04 to 34 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 wc 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0,1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to K) 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表33利用Re及Ni爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 _材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Re+Ni) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 - Ni 0.03 to 29.7 0.04 to 42 0.04 to 26.73 0.05 to 38 0.05 to 24.75 0.0610 36 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 Oto 90 Oto 83 +M02C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+*Ni) Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 - Ni 0.03 to 29,7 0.03 to 42 0.04 to 26.73 0.04 to 39 0,05 to 24.75 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 +M02C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 vc Oto 15 Oto )6 Oto 12 Oto 13 Oto 10 Oto 11 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表34利用Re及Co爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或TiC+TiN +Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量。/〇 Re+Co Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.05 to 39 0.05 to 24.75 0.06 to 36 - TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 83 TiC+TiN TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 +M02C Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 1281057D-6939-PF 127 8 +Mo〇C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA) Rc 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 - NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.04 to 34 TiC + TiN TiC 0.3 to 93.5 0.15 to 89 . 40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 wc 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0,1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to K) 0.3 To 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 Table 33 Re-bonding TiC+Mo2C or TiN+Mo2C or TiC+TiN using Re and Ni as binders +Mo2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 _Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% (Re+Ni) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 - Ni 0.03 to 29.7 0.04 to 42 0.04 to 26.73 0.05 to 38 0.05 to 24.75 0.0610 36 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 Oto 90 Oto 83 +M02C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+*Ni) Re 0.03 to 29.7 0.06 To 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 - Ni 0.03 to 29,7 0.03 to 42 0.04 to 26.73 0.04 to 39 0,05 to 24.75 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 To 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 +M02C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 vc Oto 15 Oto ) 6 Oto 12 Oto 13 Oto 10 Oto 11 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 Table 34 uses Re and Co as binders to bond TiC+Mo2C or TiN+Mo 2C or TiC+TiN+Mo2C or TiC+TiN +Mo2C+WC+TaC+VC+Cr2C3 Material Composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt. /〇Re+Co Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.05 to 39 0.05 to 24.75 0.06 to 36 - TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 83 TiC+TiN TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 +M02C Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 128

1057D-6939-PF 1339219 • «1057D-6939-PF 1339219 • «

Re+Co Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 - TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 TiC+TiN Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +Mo2C WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 34 0.2 to 12 0.35 to 29 十 WC+TaC TaC 0.1 to 15 0.15 to 32 0.15 to 12 0.25 to 27 0.2 to 10 0.3 to 24 +VC+Cr2C3 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 〇2〇} Oto 15 Oto 18 Oto 12 0 to 15 Oto 10 0tol3 表35利用鎳基超合金及Co爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+M〇2C或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3Re+Co Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 - TiC 0.3 to 93.5 0.15 to 89 . 40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 TiC+TiN Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +Mo2C WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 34 0.2 to 12 0.35 to 29 Ten WC+TaC TaC 0.1 to 15 0.15 to 32 0.15 to 12 0.25 to 27 0.2 to 10 0.3 to 24 +VC +Cr2C3 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 〇2〇} Oto 15 Oto 18 Oto 12 0 to 15 Oto 10 0tol3 Table 35 uses Ni-based superalloy and Co as a binder to bond TiC+Mo2C or TiN +Mo2C or TiC+TiN+M〇2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體稍％重量％體積％重s% 體積％重量％ (NBSA+Co) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34 - Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.06 to 39 0.05 to 24.75 0.07 to 37 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA+Co) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.05 to 34 - Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 lo 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo:C TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +WC+TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表36 36利用鎳基超合金及Ni爲黏結劑來黏結TIC+MozC或TiN+Mo2C或TiC+TiN+ Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重s% 體椬％重 a°/。 (NBSA+Ni) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34 - Ni 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.055 to 39 0.05 to 24.75 0.07 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 0 to 88 0 to 90 Oto 85 +Mo2C TiN 0 to 94 Oto 91 Oto 92 Oto 89 0 to 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA+Ni) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.035 to 36 0.05 to 24.75 0.05 to 34 - Ni 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36Material composition range 1 Composition range 2 Composition range 3 Body slightly % Weight % Volume % Weight s% Volume % Weight % (NBSA+Co) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34 - Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.06 to 39 0.05 to 24.75 0.07 to 37 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA+Co) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.05 to 34 - Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 lo 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo:C TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +WC+TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 1 5 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 Table 36 36 Bonding TIC+MozC or TiN+Mo2C or TiC+TiN+ Mo2C using a nickel-based superalloy and Ni as a binder Or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% s% 椬% weight a°/. (NBSA+Ni) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34 - Ni 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.055 to 39 0.05 to 24.75 0.07 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 0 to 88 0 to 90 Oto 85 +Mo2C TiN 0 to 94 Oto 91 Oto 92 Oto 89 0 to 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA+Ni) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.035 to 36 0.05 to 24.75 0.05 to 34 - Ni 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36

1057D-6939-PF 129 ⑧ 1339219 t1057D-6939-PF 129 8 1339219 t

TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +WC+TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 0 to 15 Oto 18 Oto 12 Oto 15 Oto 10 0to!3 表37利用Re、Co及鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +WC+TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 0 to 15 Oto 18 Oto 12 Oto 15 Oto 10 0to!3 Table 37 uses Re, Co and nickel-based superalloys as Adhesive to bond TiC+Mo2C or TiN+Mo2C or TiC+TiN+Mo2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體稹％ mm% 體積％重量°/o 體積％重量％ (Re^NBSA Re 0.03 to 29.4 0.1 to 64 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Co) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 34 - Co 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 0 to 88 0 to 90 0 to 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 +Co) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0,2 to 86 0.5 to 89.1 0.3 to 83 TiC+TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +Mo2C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +WC+TaC WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表38利用Re、Ni及鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重s% 體積％重s% 體積％重量％ (Re+NBSA Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Νί) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 33 - Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 Oto 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57Material composition range 1 Composition range 2 Composition range 3 Volume % mm% Volume % Weight ° / o Volume % Weight % (Re^NBSA Re 0.03 to 29.4 0.1 to 64 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Co NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 34 - Co 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 0 to 88 0 to 90 0 to 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re +NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 +Co) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0,2 to 86 0.5 to 89.1 0.3 to 83 TiC+TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +Mo2C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +WC+Ta C WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 Table 38 uses Re, Ni and nickel-based superalloys as binders to bond TiC+Mo2C or TiN+Mo2C or TiC+TiN+Mo2C or TiC +TiN+Mo2C+WC+TaC+VC+Cr2C3 Material composition range 1 Composition range 2 Composition range 3 Volume % Weight s% Volume % Weight s% Volume % Weight % (Re+NBSA Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Νί) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 33 - Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 Oto 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 Oto 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57

1057D-6939-PF 130 ⑧ 1339219 4 * « +Ni) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33 - Ni 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +M〇iC TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89,1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 we 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 O2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表39利用Re、Ni及Co爲黏結劑來黏結TiC+M〇2C或TiN+M〇2C或TiC+TiN+Mo2C或TiC+ TiN+Mo2C+WC+TaC+VC+Cr2C31057D-6939-PF 130 8 1339219 4 * « +Ni) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33 - Ni 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +M〇iC TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89,1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 we 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 O2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 Table 39 uses Re, Ni and Co as Adhesive to bond TiC+M〇2C or TiN+M〇2C or TiC+TiN+Mo2C or TiC+ TiN+Mo2C+WC+TaC+VC+Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體積％重量〇/〇體積％重量0/〇體積％重量％ (Re+Ni Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Co) Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 - Co 0.03 to 29,4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC+TiN TiC Oto 94 0 to 90 Oto 92 Oto 87 Oto 90 Oto 83 +Mo2C TiN 0 to 94 Oto 91 Oto 92 Oto 88 Oto 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+Ni Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 +Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiC+TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 +M02C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +WC+TaC WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 0 to 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Olo 12 Oto 15 Oto 10 Oto 13 表40利用Co、Ni及鎳基超合金爲黏結劑來黏結ΤΧ+Μο2(：或TiN+Mo2C或TiC+TiN+Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量0/〇體積％重量0/〇體積％重量％ (NBSA+Ni NBSA 0.03 to 29.4 0.04 to 40 0.04 to 26.46 0.5 to 36 0.05 to 24.5 0.06 to 34 +Co) Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 37 - Co 0.03 to 29.4 0.04 to 43 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 Oto 90 Oto 84 +M02C TiN Oto 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85Material composition range 1 Composition range 2 Composition range 3 vol% weight 〇/〇 volume% weight 0/〇 volume% weight% (Re+Ni Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 + Co) Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 - Co 0.03 to 29,4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC+TiN TiC Oto 94 0 To 90 Oto 92 Oto 87 Oto 90 Oto 83 +Mo2C TiN 0 to 94 Oto 91 Oto 92 Oto 88 Oto 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+Ni Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 +Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 - Co 0.03 to 29.4 0.03 to 42 0.04 To 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiC + TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 To 83 +M02C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +WC+TaC WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 0 to 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Olo 12 Oto 15 Oto 10 Oto 13 Table 40 uses Co, Ni and nickel-based superalloys as binders to bond ΤΧ+Μο2 (: or TiN+Mo2C or TiC+TiN+Mo2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 Material composition range 1 Composition range 2 Composition range 3 vol% weight 0/〇 volume% weight 0/〇 volume% weight% (NBSA+Ni NBSA 0.03 to 29.4 0.04 to 40 0.04 to 26.46 0.5 to 36 0.05 to 24.5 0.06 to 34 +Co) Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 37 - Co 0.03 to 29.4 0.04 to 43 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 Oto 90 Oto 84 +M02C TiN Oto 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85

1057D-6939-PF 131 ⑧ 1339219 • ·1057D-6939-PF 131 8 1339219 • ·

Mo2C 3 to 27 4 to 38 4 to 26 5 to 37 5 to 24 7 to 34 (NBSA+Ni NBSA 0.03 to 29.4 0.025 to 40 0.04 to 26.46 0.035 to 36 0.05 to 24.5 0.05 to 33 +Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 TiC+TiN TiN 0.3 to 93.5 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +Mo2C Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +WC+TaC wc 0.1 to 20 0.25 to 42 0.15 to 15 0.35 to 35 0.2 to 12 0. 5 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.25 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.45 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 0 to 15 Oto 10 Oto 13 表41利用Re、Ni、Co及鎳基超合金爲黏結劑來黏結TiC+M〇2C或TiN+M〇2C或TiC+TiN+ Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3Mo2C 3 to 27 4 to 38 4 to 26 5 to 37 5 to 24 7 to 34 (NBSA+Ni NBSA 0.03 to 29.4 0.025 to 40 0.04 to 26.46 0.035 to 36 0.05 to 24.5 0.05 to 33 +Co) Ni 0.03 to 29.4 0.025 To 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 TiC+TiN TiN 0.3 to 93.5 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +Mo2C Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +WC+TaC Wc 0.1 to 20 0.25 to 42 0.15 to 15 0.35 to 35 0.2 to 12 0. 5 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.25 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.45 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 0 to 15 Oto 10 Oto 13 Table 41 uses Re, Ni, Co and nickel-based superalloys as binders to bond TiC+M〇2C or TiN+M〇2C Or TiC+TiN+ Mo2C or TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體積％重a% 體稂％重量°/。體積％重fi% (Re+NBSA+Ni Re 0.03 to 29.1 0.1 to 63 0.04 to 26.19 0.13 to 59 0.05 to 24.25 0.16 to 57 +Co) NBSA 0.03 to 29.1 0.035 to 39 0.04 to 26.19 0.45 to 36 0.05 to 24.25 0.055 to 33 - Ni 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.05 to 38 0.05 to 24.25 0.06 to 36 TiC+TiN Co 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.5 to 38 0.05 to 24.25 0.06 to 36 +M02C TiC Oto 94 Oto 90 Oto 92 Oto 87 Oto 90 Oto 84 TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA+Ni Re 0.03 to 29.1 0.06 to 63 0.04 to 26.19 0.1 to 59 0.05 to 24.25 0.12 to 56 +Co) NBSA 0.03 to 29.1 0.02 to 39 0.04 to 26.19 0.03 to 35 0.05 to 24.25 0.04 to 33 - Ni 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.035 to 38 0.05 to 24.25 0.05 to 35 Co 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.03 to 38 0.05 to 24.25 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5io 25*5 +VC+Cr2〇3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.3 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.2 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 0to.l5 Oto 10 Oto 13 表42-5 1列出額外不同組成物的组成範圍，與上述部分組成物類似’在表42-51中的一些組成可應用在高溫下，其應用溫度顯示在表格最後一列估算熔點中。如以上所述’帶有Re、鎳基超合金或兩者的結合可加強 1057D-6939-PF 132 广、 ⑧ 1339219 在高溫下材料的性質。通常利用w在不同的硬粒子中例如：碳化物、氮化物、碳氣化合物、删化物或石夕化物當作組成元素。當用來作黏結劑基質時無論是單獨使用或連同其他金屬皆可大幅提高硬金屬材料的熔點至2500°C至3 500°C，因此以W基黏結劑基質可在高溫下應用。，在表43-48中明顯地顯示以W 為基底的黏結劑基質熔點約3500°C。表47中以Re及Co來黏結氮化物的組成物，其中硬金屬組合物中氮化物可由氮化物及碳化物的結合物來取 • 代。此硬金屬組合物包括至少一種由元素週期表中IVb及 Vb族元素所形成的氮化物及一種由元素週期表中IVb、Vb 及VIb族元素所形成的碳化物，以及一包含Re及Co用來黏結硬粒子的黏結劑基質。表42 Re黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中IVb、 Vb及V[b族元素所形成的砂化物Material Composition range 1 Composition range 2 Composition range 3 vol% weight a% body 稂% weight °/. Volume % Weight fi% (Re+NBSA+Ni Re 0.03 to 29.1 0.1 to 63 0.04 to 26.19 0.13 to 59 0.05 to 24.25 0.16 to 57 +Co) NBSA 0.03 to 29.1 0.035 to 39 0.04 to 26.19 0.45 to 36 0.05 to 24.25 0.055 To 33 - Ni 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.05 to 38 0.05 to 24.25 0.06 to 36 TiC+TiN Co 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.5 to 38 0.05 to 24.25 0.06 to 36 +M02C TiC Oto 94 Oto 90 Oto 92 Oto 87 Oto 90 Oto 84 TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA+Ni Re 0.03 to 29.1 0.06 to 63 0.04 to 26.19 0.1 to 59 0.05 to 24.25 0.12 to 56 +Co) NBSA 0.03 to 29.1 0.02 to 39 0.04 to 26.19 0.03 to 35 0.05 to 24.25 0.04 to 33 - Ni 0.03 to 29.1 0.025 to 42 0.04 To 26.19 0.035 to 38 0.05 to 24.25 0.05 to 35 Co 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.03 to 38 0.05 to 24.25 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 To 83 +Mo2C TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5io 25*5 +VC+Cr2〇3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.3 To 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.2 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 0to.l5 Oto 10 Oto 13 Table 42 -5 1 lists the compositional range of the additional different compositions, similar to the above-mentioned partial compositions. Some of the compositions in Tables 42-51 can be applied at elevated temperatures, and the application temperatures are shown in the estimated melting point in the last column of the table. The combination of Re, nickel-based superalloy or a combination of the two as described above enhances the properties of the material at 1057D-6939-PF 132 wide and 8 1339219 at elevated temperatures. Usually, w is used as a constituent element in different hard particles such as carbide, nitride, carbon gas compound, smear or sinus. When used as a binder matrix, either alone or in combination with other metals, the melting point of the hard metal material can be greatly increased to 2500 ° C to 3 500 ° C, so the W-based binder matrix can be applied at high temperatures. The melting point of the W-based binder matrix is clearly shown in Tables 43-48 to be about 3500 °C. In Table 47, a composition of a nitride is bonded with Re and Co, wherein the nitride in the hard metal composition can be replaced by a combination of nitride and carbide. The hard metal composition includes at least one nitride formed from elements IVb and Vb of the periodic table and a carbide formed from elements IVb, Vb and VIb of the periodic table, and one containing Re and Co. To bond the matrix of hard particles to the binder. Table 42 Rebonded boride formed by elements of group IVb, Vb and VIb of the periodic table or silicide formed by groups IVb, Vb and V of the periodic table

組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量％ °C Re黏結 Re 3 to 40 12.5 to 76 4 to 35 16 to 71 5 to 30 20 to 67 2700 to TiB2 TiB2 60 ιο 97 24 to 87.5 65 to 96 29 to 84 70 to 95 33 to 80 3000 Re黏結 Re 3 to 40 9.5 to 70 4 to 35 12.5 to 65 5 to 30 15 to 60 2800 to ZrB2 ZrB2 60 to 97 30 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 3000 Re黏結 Rc 3 to 40 5.5 to 55.5 4 to 35 7 to 50 5 to 30 9 to 44.5 3000 to HfB2 HfB2 60 to 97 44.5 to 94.5 65 to 96 50 to 93 70 to 95 55.5 to 91 3200 Re黏結 Re 3 to 40 11 to 73 4 to 35 14.5 to 69 5 to 30 18 to 64 2000 to vb2 vb2 60 to 97 27 to 89 65 to 96 31 to 85.5 70 to 95 36 to 82 2500 Rc黏結 Re 3 ίο 40 8 to 66 4 to 35 M to 61 5 to 30 13 lo 55.5 2800 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44.5 to 87 3100 Re黏結 Re 3 to 40 5 to 53 4 to 35 6.5 to 47 5 to 30 8 to 42 3000 to TaB2 TaB2 60 to 97 47 to 95 65 to 96 53 to 93.5 70 to 95 58 to 92 3200 Re黏結 Re 3 to 40 9.5 to 69.5 4 to 35 12.5 to 65 5 to 30 ί5 ίο 60 1800 to Cr3B2 Cr3B2 60 lo 97 30.5 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 2200 Re黏結 Re 3 to 40 7.5 to 64 4 to 35 10 to 59 5 to 30 12.5 to 54 2000 toComposition range 1 Composition range 2 Composition range 3 Estimated melting point volume % % by weight Volume % Weight % Volume % Weight % °C Rebond Re 3 to 40 12.5 to 76 4 to 35 16 to 71 5 to 30 20 to 67 2700 to TiB2 TiB2 60 ιο 。。。。。。。。。 65 to 96 35 to 87.5 70 to 95 40 to 85 3000 Re Bonding Rc 3 to 40 5.5 to 55.5 4 to 35 7 to 50 5 to 30 9 to 44.5 3000 to HfB2 HfB2 60 to 97 44.5 to 94.5 65 to 96 50 to 93 70 to 95 55.5 to 91 3200 Re Bonding Re 3 to 40 11 to 73 4 to 35 14.5 to 69 5 to 30 18 to 64 2000 to vb2 vb2 60 to 97 27 to 89 65 to 96 31 to 85.5 70 to 95 36 to 82 2500 Rc Bonding Re 3 ίο 40 8 to 66 4 to 35 M to 61 5 to 30 13 lo 55.5 2800 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44.5 to 87 3100 Re Bonding Re 3 to 40 5 to 53 4 to 35 6.5 to 47 5 to 30 8 to 42 3000 to TaB2 TaB2 60 to 97 47 to 95 65 to 96 53 to 93.5 70 to 95 58 to 92 32 00 Re Bonding Re 3 to 40 9.5 to 69.5 4 to 35 12.5 to 65 5 to 30 ί5 ίο 60 1800 to Cr3B2 Cr3B2 60 lo 97 30.5 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 2200 Re Bonding Re 3 to 40 7.5 to 64 4 to 35 10 to 59 5 to 30 12.5 to 54 2000 to

1057D-6939-PF 133 ⑤ 13392191057D-6939-PF 133 5 1339219

MoB2 60 to 97 36 to 92.5 65 to 96 41 to 90 70 to 95 46 to 87.5 Re黏結 Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2700 to WB WB 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 3000 Rc黏結 Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2600 to w2b W2B 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 2900 Re黏結 Re 3 to 40 13 to 77 4 to 35 17 to 72 5 to 30 20 to 68 2000 to Ti5Si3 Ti5Si3 60 to 97 23 to 87 65 to 96 28 to 83 70 to 95 32 to 80 2400 Re黏結 Re 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2100 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 Re黏結 Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to NbSi2 NbSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Re黏結 Re 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 51 2200 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 88 2600 Re黏結 Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Re黏結 Re 3 to 40 6 to 60 4 to 35 9 to 55 5 to 30 11 to 49 1800 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 9] 70 to 95 51 to 89 2200MoB2 60 to 97 36 to 92.5 65 to 96 41 to 90 70 to 95 46 to 87.5 Re Bonding Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2700 to WB WB 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 3000 Rc Bonding Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2600 to w2b W2B 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 2900 Re bonded Re 3 to 40 13 to 77 4 to 35 17 to 72 5 to 30 20 to 68 2000 to Ti5Si3 Ti5Si3 60 to 97 23 to 87 65 to 96 28 to 83 70 to 95 32 to 80 2400 Re Bonding Re 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2100 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 Re Bonding Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to NbSi2 NbSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Re Bonding Re 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 51 2200 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 88 2600 Re Bonding Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to MoSi2 M oSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Re Bonding Re 3 to 40 6 to 60 4 to 35 9 to 55 5 to 30 11 to 49 1800 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 9] 70 to 95 51 to 89 2200

表43 W黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中 rvb及Vb族元素所形成的氮化物組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量°/。體積％重量％體積％重量％ t W黏結 w 3 to 40 11 to 72 4 to 35 25.02 to 70 5 to 30 25.02 to 65 3000 to 3300 Tie TiC 60 to 97 28 to 89 65 to 96 30 to 74.98 70 to 95 35 to 74.98 W黏結 W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 56 3200 to 3500 ZrC ZrC 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44 to 87 W黏結 W 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 40 3300 to 3500 HfC HfC 60 to 97 50 to 96 65 to 96 55 to 64 70 to 95 60 to 93 W黏結 W 3 to 40 10 to 70 4 to 35 ]3 to 65 5 to 30 16 to 60 2700 to 3300 VC VC 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 W黏結 w 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 11 to51 3000 to 3500 NbC NbC 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 W黏結 W 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 3300 to 3500 TaC TaC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 W黏結 W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 ]700 to 2100 Cr2C3 Cr2C3 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 W黏結 W 3 to 40 6 to 59 4 to 35 8 to 53 5 to 30 10 to 48 2400 to 2600 Mo2C Mo2C 60 to 97 41 to 94 65 to 96 47 to 93 70 to 95 52 to 90 W黏結 w 3 to 40 4 to 45 4 to 35 5 to 40 5 to 30 6 to 35 2800 to 3000 wc wc 60 to 97 55 to 96 65 to 96 60 to 95 70 to 95 65 to 94 w黏結 w 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 16 to 60 2800 to 3300Table 43 W Bonding carbides formed by elements of Groups IVb, Vb and VIb of the Periodic Table of the Elements or nitrides formed by elements of the rvb and Vb elements of the periodic table of the composition range 1 Composition range 2 Composition range 3 Estimated melting point volume % Weight ° /. Volume % Weight % Volume % Weight % t W Bonding w 3 to 40 11 to 72 4 to 35 25.02 to 70 5 to 30 25.02 to 65 3000 to 3300 Tie TiC 60 to 97 28 to 89 65 to 96 30 to 74.98 70 to 95 35 to 74.98 W Bonding W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 56 3200 to 3500 ZrC ZrC 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44 to 87 W Bonding W 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 40 3300 to 3500 HfC HfC 60 to 97 50 to 96 65 to 96 55 to 64 70 to 95 60 to 93 W Bonding W 3 to 40 10 to 70 4 to 35 ]3 to 65 5 to 30 16 to 60 2700 to 3300 VC VC 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 W bonding w 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 11 to51 3000 to 3500 NbC NbC 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 W Bonding W 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 3300 to 3500 TaC TaC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 W Bonding W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 ]700 to 2100 Cr2C3 Cr2C3 60 to 97 34 to 92 65 to 96 39 to 89 7 0 to 95 45 to 87 W Bonding W 3 to 40 6 to 59 4 to 35 8 to 53 5 to 30 10 to 48 2400 to 2600 Mo2C Mo2C 60 to 97 41 to 94 65 to 96 47 to 93 70 to 95 52 to 90 W Bonding w 3 to 40 4 to 45 4 to 35 5 to 40 5 to 30 6 to 35 2800 to 3000 wc wc 60 to 97 55 to 96 65 to 96 60 to 95 70 to 95 65 to 94 w Bonding w 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 16 to 60 2800 to 3300

1057D-6939-PF 134 ⑧ 1339219 « *1057D-6939-PF 134 8 1339219 « *

TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 40 lo 84 W黏結 W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to 3300 ZrN ZrN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W黏結 W 3 to 40 4 to 48 4 to 35 6 to 43 5 to 30 7 to 37 3200 to 3500 HfN HfN 60 to 97 52 to 96 65 to 96 57 to 94 70 to 95 63 to 93 W黏結 W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 15 to 58 2000 to 2400 VN VN 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 85 W黏結 W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2200 to 2600 NbN NbN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W黏結 W 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 37 3000 to 3500 TaN TaN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 93 表44 W黏結由元素週期表中rvb、Vb及VIb族元素所形成的硼化物或由元素週期表中 IVb、Vb及VIb族元素所形成的矽化物TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 40 lo 84 W Bonding W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to 3300 ZrN ZrN 60 to 97 36 To 92 65 to 96 41 to 90 70 to 95 47 to 88 W Bonding W 3 to 40 4 to 48 4 to 35 6 to 43 5 to 30 7 to 37 3200 to 3500 HfN HfN 60 to 97 52 to 96 65 to 96 57 To 94 70 to 95 63 to 93 W Bonding W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 15 to 58 2000 to 2400 VN VN 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 To 85 W Bonding W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2200 to 2600 NbN NbN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W Bonding W 3 To 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 37 3000 to 3500 TaN TaN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 93 Table 44 W-bonded by rvb in the periodic table a boride formed by the Vb and VIb elements or a telluride formed from elements of the IVb, Vb and VIb elements of the periodic table.

組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重S% 體積％重量％ °C W黏結 w 3 to 40 12 to 74 4 to 35 15 to 70 5 to 30 18 to 65 2700 to TiB2 TiB2 60 to 97 26 to 88 65 to 96 30 to 85 70 to 95 35 to 82 3000 W黏結 W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 2800 to ZrB2 ZrB2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 3000 W黏結 W 3 to 40 5 to 54 4 to 35 7 to 48 5 to 30 8 to 42 3000 to HfB2 HfB2 60 to 97 46 to 95 65 to 96 52 to 93 70 to 95 58 to 92 3400 W黏結 W 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2000 to vb2 vb2 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 W黏結 w 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to NbB2 NbB2 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 3400 W黏結 W 3 to 40 5 to 51 4 to 35 6 to 45 5 to 30 7 to 40 3100 to TaB2 TaB2 60 to 97 49 to 95 65 to 96 55 to 94 70 to 95 60 to 93 3400 W黏結 W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 1800 to Cr3B2 Cr3B2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 2200 W黏結 W 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 52 2000 to MoB2 MoB2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 48 to 88 2400 W鈷結 W 3 to 40 4 to 45 4 to 35 5 to 39 5 to 30 6 to 34 2700 to WB WB 60 to 97 55 to 96 65 to 96 61 to 95 70 to 95 66 to 94 3000 W黏結 W 3 to 40 3 to 44 4 to 35 5 to 38 5 to 30 6 to 33 2600 to w2b w2b 60 to 97 56 to 97 65 to 96 62 to 95 70 to 95 67 to 94 2900 w黏結 w 3 to 40 12 to 75 4 to 35 16 to 71 5 to 30 19 to 66 2000 to Ti5Si, Ti5Si3 60 to 97 25 to 88 65 to 96 29 to 84 70 to 95 34 to 81 2400 W黏結 w 3 to 40 10 to 70 4 to 35 13 to 65 5 to 30 16 to 60 2100 to Zr6Si5 Zr6Si5 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 2500 W黏結 W 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 toComposition range 1 Composition range 2 Composition range 3 Estimated melting point volume % Weight % Volume % Weight S% Volume % Weight % °CW Bonding w 3 to 40 12 to 74 4 to 35 15 to 70 5 to 30 18 to 65 2700 to TiB2 TiB2 60 to 97 26 to 88 65 to 96 30 to 85 70 to 95 35 to 82 3000 W Bonding W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 2800 to ZrB2 ZrB2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 3000 W Bonding W 3 to 40 5 to 54 4 to 35 7 to 48 5 to 30 8 to 42 3000 to HfB2 HfB2 60 to 97 46 to 95 65 to 96 52 to 93 70 to 95 58 to 92 3400 W Bonding W 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2000 to vb2 vb2 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 W bonding w 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to NbB2 NbB2 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 3400 W bonding W 3 to 40 5 to 51 4 to 35 6 to 45 5 to 30 7 to 40 3100 to TaB2 TaB2 60 to 97 49 to 95 65 to 96 55 to 94 70 to 95 60 to 93 3400 W Bonding W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 1800 to Cr3B2 Cr3B2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 2200 W Bonding W 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 52 2000 to MoB2 MoB2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 48 to 88 2400 W cobalt knot W 3 to 40 4 to 45 4 to 35 5 to 39 5 to 30 6 to 34 2700 to WB WB 60 to 97 55 To 96 65 to 96 61 to 95 70 to 95 66 to 94 3000 W Bonding W 3 to 40 3 to 44 4 to 35 5 to 38 5 to 30 6 to 33 2600 to w2b w2b 60 to 97 56 to 97 65 to 96 62 To 95 70 to 95 67 to 94 2900 w Bonding w 3 to 40 12 to 75 4 to 35 16 to 71 5 to 30 19 to 66 2000 to Ti5Si, Ti5Si3 60 to 97 25 to 88 65 to 96 29 to 84 70 to 95 34 to 81 2400 W Bonding w 3 to 40 10 to 70 4 to 35 13 to 65 5 to 30 16 to 60 2100 to Zr6Si5 Zr6Si5 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 2500 W Bonding W 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 to

1057D-6939-PF 135 ③ 1339219 m1057D-6939-PF 135 3 1339219 m

NbSi2 NbSi2 60 to 97 33 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 W黏結 W 3 to 40 7 to 60 4 to 35 9 to 55 5 to 30 11 to 49 2200 to TaSi2 TaSi2 60 to 97 40 to 93 65 to 96 45 to 91 70 to 95 51 to 89 2600 W黏結 W 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 to MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 W黏結 W 3 to 40 6 to 58 4 to 35 8 to 53 5 to 30 10 to 47 1800 to WSi2 WSi2 60 to 97 42 to 94 65 to 96 47 to 92 70 to 95 43 to 90 2200NbSi2 NbSi2 60 to 97 33 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 W Bonding W 3 to 40 7 to 60 4 to 35 9 to 55 5 to 30 11 to 49 2200 to TaSi2 TaSi2 60 to 97 40 To 93 65 to 96 45 to 91 70 to 95 51 to 89 2600 W Bonding W 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 to MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 38 To 89 70 to 95 43 to 86 2200 W bonding W 3 to 40 6 to 58 4 to 35 8 to 53 5 to 30 10 to 47 1800 to WSi2 WSi2 60 to 97 42 to 94 65 to 96 47 to 92 70 to 95 43 To 90 2200

表45 Re及W(Re+W)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成範圍由l%Re+99%W至 99%Re+l%W 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體植％重fi% °C Re+W Re 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.19 to 64 2900 黏結 W 0.03 to 39.6 0.1 to 72 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 to TiC TiC 60 to 97 26 to 89 65 to 96 30 to 86 70 to 95 35 to 83 3300 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.15 to 57 3000 黏結 W 0.03 to 39.6 0.08 to 66 0.04 to 34.7 0.11 to 61 0.05 to 29.7 0.13 to 55 to ZrC ZrC 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 42 to 87 3400 Re+W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 黏結 W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to HfC HfC 60 to 97 48 to 95 65 to 96 53 to 94 70 to 95 58 to 93 3500 Re+W Re 0.03 to 39.6 0.11 to71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 61.8 2700 黏結 W 0.03 to 39.6 0.1 to 69 0.13 to 65 0.06 to 46.3 0.15 to 60 0.07 to 40.8 to VC VC 60 to 97 28 to 90 33 to 87 32.8 to 93.5 70 to 95 38 to 84 3000 Re+W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 3200 i黏結 W 0.03 to 39.6 0.07 to 56 0.04 to 34.7 0.09 to 56 0.05 to 29.7 0.11 to51 to NbC NbC 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 47 to 88 3500 Re+W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 3)00 黏結 W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 to TaC TaC 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 62 to 93 3500 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14 to 57 1700 黏結 W 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 to Cr2C3 Cr2〇j 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 43 to 87 1900 Re+W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2400 黏結 W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 53 0.05 to 29.7 0.1 to 47 to Mo2C Mo2C 60 to 97 39 to 94 65 to 96 45 to 92 70 to 95 50 to 90 2600 Re + W Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2700 黏結 W 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to WC WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900Table 45 Re and W (Re+W) bond carbide formed by elements of group IVb, Vb and VIb of the periodic table or nitride formed by elements of group IVb and Vb of the periodic table, wherein the composition range of the binder From l%Re+99%W to 99%Re+l%W Composition range 1 Composition range 2 Composition range 3 Estimated melting point volume % Weight % Volume % Weight % Body weight % fi% °C Re+W Re 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.19 to 64 2900 Bonding W 0.03 to 39.6 0.1 to 72 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 to TiC TiC 60 to 97 26 to 89 65 to 96 30 to 86 70 to 95 35 to 83 3300 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.15 to 57 3000 Bonding W 0.03 to 39.6 0.08 to 66 0.04 to 34.7 0.11 to 61 0.05 to 29.7 0.13 to 55 to ZrC ZrC 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 42 to 87 3400 Re+W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 Bonding W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to HfC HfC 60 to 97 48 to 95 65 to 96 53 to 94 70 to 95 58 to 93 3500 Re+W Re 0.03 to 39.6 0.11 to71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 61.8 2700 Bonding W 0.03 to 39.6 0.1 to 69 0.13 to 65 0.06 to 46.3 0.15 to 60 0.07 to 40.8 to VC VC 60 to 97 28 to 90 33 to 87 32.8 to 93.5 70 to 95 38 to 84 3000 Re+W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 3200 i Bonding W 0.03 to 39.6 0.07 to 56 0.04 to 34.7 0.09 to 56 0.05 to 29.7 0.11 to51 to NbC NbC 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 47 to 88 3500 Re+W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 3)00 Bonding W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 to TaC TaC 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 62 to 93 3500 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14 to 57 1700 Bonding W 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 to Cr2C3 Cr2〇j 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 43 to 87 1900 Re+W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2400 Bonding W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 53 0.05 to 29.7 0.1 to 47 to Mo2C Mo2C 60 to 97 39 to 94 65 to 96 45 to 92 70 to 95 50 to 90 2600 Re + W Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2700 Bonding W 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to WC WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900

1057D-6939-PF 136 ⑧ 1339219 气 -1057D-6939-PF 136 8 1339219 Gas -

Re +W Re 0.03 to 39.6 0.1 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 2900 黏結 W 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 60 to TiN TiN 60 to 97 28 to 90 65 to 96 32 to 87 70 to 95 38 to 84 3200 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2900 黏結 W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 45 to 88 3200 Re +W Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 3100 黏結 W 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 37 to HfN HfN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 3400 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 59 2100 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to VN VN 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2300 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2300 黏結 W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbN NbN 60 to 97 35 to 92 65 to 96 39 to 90 70 to 95 45 to 88 2500 Re +W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 2900 黏結 W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 to TaN TaN 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 61 to 93 3400Re +W Re 0.03 to 39.6 0.1 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 2900 Bonding W 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 60 to TiN TiN 60 to 97 28 To 90 65 to 96 32 to 87 70 to 95 38 to 84 3200 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2900 Bonding W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 To 58 0.05 to 29.7 0.12 to 53 to ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 45 to 88 3200 Re +W Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 To 39 3100 Bonding W 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 37 to HfN HfN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 3400 Re +W Re 0.03 To 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 59 2100 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to VN VN 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2300 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2300 Bonding W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbN NbN 60 to 97 35 to 92 65 to 96 39 to 90 70 to 95 45 to 88 2500 Re +W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 2900 Bonding W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 to TaN TaN 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 61 to 93 3400

表46 Re及W(Re+W)黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中IVb及Vb族元素所形成的矽化物，其中黏結劑組成範圍由1 %Re+99%W至 99%Re+l%W 組成範圍1 組成範圍2 組成範圔3 估算熔點體積％重量°/« 體重量％體積％重量％ °c Re +W Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.16 to 71 0.05 to 29.7 0.2 to 66 2900 黏結 W 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.18 to 64 to TiB2 TiB2 60 to 97 24 to 88 65 to 96 29 to 85 70 to 95 33 to 82 3100 ^Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 2900 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to ZrB2 ZrB2 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 3100 Re +W Re 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 50 0.05 to 29.7 0.09 to 44 3100 黏結 W 0.03 to 39.6 0.05 to 53 0.04 to 34.7 0.07to48 0.05 to 29.7 0.08to42 to HiB2 HiB2 60 to 97 44 to 95 65 to 96 50〇93 70 to 95 55 to 92 3300 Re +W Re 0.03 to 39.6 0.11 to 73 0.14 to 67 0.15 to 68 0.17 to 62 0.18 to 63 2000 黏結 W 0.03 to 39.6 0.1 to 71 0.13 to 65 0.13 to 66 0.15 to 60 0.16 to 61 to vb2 vb2 60 to 97 27 to 90 33 to 87 31 to 86 70 to 95 36 to 84 2200 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.1 to 61 0.05 to 29.7 0.13 to 55 2900 黏結 W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 44 to 88 3100 Re +W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 黏結 W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 39 0.05 to 29,7 0.07 to 39 toTable 46 Re and W (Re+W) bonding borides formed by elements of group IVb, Vb and VIb of the periodic table or bismuth formed by elements of group IVb and Vb of the periodic table, wherein the composition range of the binder From 1%Re+99%W to 99%Re+l%W Composition range 1 Composition range 2 Composition range 3 Estimated melting point volume % Weight °/« Body weight % Volume % Weight % °c Re +W Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.16 to 71 0.05 to 29.7 0.2 to 66 2900 Bonding W 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.18 to 64 to TiB2 TiB2 60 to 97 24 to 88 65 to 96 29 to 85 70 to 95 33 to 82 3100 ^Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 2900 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 To 57 to ZrB2 ZrB2 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 3100 Re +W Re 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 50 0.05 to 29.7 0.09 to 44 3100 Bond W 0.03 To 39.6 0.05 to 53 0.04 to 34.7 0.07to48 0.05 to 29.7 0.08to42 to HiB2 HiB2 60 to 97 44 To 95 65 to 96 50〇93 70 to 95 55 to 92 3300 Re +W Re 0.03 to 39.6 0.11 to 73 0.14 to 67 0.15 to 68 0.17 to 62 0.18 to 63 2000 Bonding W 0.03 to 39.6 0.1 to 71 0.13 to 65 0.13 To 66 0.15 to 60 0.16 to 61 to vb2 vb2 60 to 97 27 to 90 33 to 87 31 to 86 70 to 95 36 to 84 2200 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.1 to 61 0.05 to 29.7 0.13 To 55 2900 Bonding W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 44 to 88 3100 Re +W Re 0.03 To 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 Bonding W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 39 0.05 to 29,7 0.07 to 39 to

1057D-6939-PF 137 ⑧ 1339219 »*1057D-6939-PF 137 8 1339219 »*

TaB2 TaB2 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 3300 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1900 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14to 57 to CrjB2 Cr3B2 60 to 97 32 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2100 Re +W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2000 黏結 W 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.11 to51 to MoB2 MoB2 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 46 to 88 2200 Re +W Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 2800 黏結 W 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to WB WB 60 to 97 53 to 96 65 to 96 57 to 95 70 to 95 64 to 94 2900 Re +W Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 2700 黏結 W 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.05 to 38 0.05 to 29.7 0.06 to 33 to W2B W2B 60 to 97 54 to 97 65 to 96 60 to 95 70 to 95 65 to 94 2900 Re +W Re 0.03 to 39.6 0.13 to 76 0.04 to 34.7 0.17 to 72 0.05 to 29.7 0.21 to 67 2000 i黏結 W 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 70 0.05 to 29.7 0.19 to 65 to Ti5Si3 Ti5Si3 60 to 97 24 to 88 65 to 96 28 to 84 70 to 95 32 to 81 2200 Re +W Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 61 2100 黏結 W 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.15 to 59 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 87 70 to 95 38 to 84 2400 Re + W Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 黏結 W 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to NbSi2 NbSi2 60 to 97 31 to91 65 to 96 36 to 89 70 to 95 41 to 86 2100 Re +W Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.12 to 51 2300 黏結 W 0.03 to 39.6 0.07 to 60 0,04 to 34.7 0.09 to 54 0,05 to 29.7 0.11 to 49 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 2500 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to MoSi2 MoSi2 60 to 97 31 to91 65 to 96 36 to 89 70 to 95 41 to 86 2100 ,Re +W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 54 0.05 to 29.7 0.11 to 49 1900 黏結 W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 52 0.05 to 29.7 0.1 to 47 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 92 70 to 95 51 to 90 2100 表47 Re及Co(Re+Co)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成範圍由l%Re+99%Co 至 99%Re+l%Co 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量〇/〇體積％重量％體積％重量％ °C Re +Co Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 黏結 Co 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 49 0.05 to 29.7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re +Co Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 1057D-6939-PF 138 ⑧ 1339219 m 黏結 Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 37 to ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 Re +Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 4】 1400 黏結 Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.04 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re +Co Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 黏結 Co 0.03 to 39.6 0.05 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 41 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Co Rc 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 黏結 Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Co Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 黏結 Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 ‘ Re +Co Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 F黏結 Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 黏結 Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0,04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Co Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1400 黏結 Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.028 to 20 to WC WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900 Re + Co Re 0.03 to 39.6 0.1! to 71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 黏結 Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to TiN TiN 60 to 97 28 to 95 65 to 96 33 to 93 70 to 95 38 to 92 3200 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 i黏結 Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to W ZrN ZrN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3200 Re + Co Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 1400 黏結 Co 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to HfN HfN 60 to 97 50 to 98 65 to 96 55 to 97 70 to 95 61 to 97 3200 Re + Co Re 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 60 1400 黏結 Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 39 to VN VN 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 2300 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 黏結 Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to NbN NbN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 2500 Re + Co Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 1400 黏結 Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 lo 21 to TaN TaN 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 98 3200TaB2 TaB2 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 3300 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1900 Bonding W 0.03 to 39.6 0.09 To 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14to 57 to CrjB2 Cr3B2 60 to 97 32 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2100 Re +W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 To 59 0.05 to 29.7 0.13 to 53 2000 Bonding W 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.11 to51 to MoB2 MoB2 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 46 to 88 2200 Re +W Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 2800 Bonding W 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to WB WB 60 to 97 53 To 96 65 to 96 57 to 95 70 to 95 64 to 94 2900 Re +W Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 2700 Bonding W 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.05 To 38 0.05 to 29.7 0.06 to 33 to W2B W2B 60 to 97 54 to 97 65 to 96 60 To 95 70 to 95 65 to 94 2900 Re +W Re 0.03 to 39.6 0.13 to 76 0.04 to 34.7 0.17 to 72 0.05 to 29.7 0.21 to 67 2000 i Bond W 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 70 0.05 to 29.7 0.19 to 65 to Ti5Si3 Ti5Si3 60 to 97 24 to 88 65 to 96 28 to 84 70 to 95 32 to 81 2200 Re +W Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 61 2100 Bonding W 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.15 to 59 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 87 70 to 95 38 to 84 2400 Re + W Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 Bonding W 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to NbSi2 NbSi2 60 to 97 31 to91 65 to 96 36 to 89 70 to 95 41 to 86 2100 Re +W Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.12 to 51 2300 Bonding W 0.03 to 39.6 0.07 to 60 0,04 to 34.7 0.09 to 54 0,05 to 29.7 0.11 to 49 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 2500 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to MoSi2 MoSi2 60 to 97 31 to91 65 to 96 36 to 89 70 to 95 41 to 86 2100 , Re + W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 54 0.05 to 29.7 0.11 to 49 1900 Bonding W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 52 0.05 to 29.7 0.1 to 47 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 92 70 to 95 51 to 90 2100 Table 47 Re and Co (Re+Co) bonding is IVb in the periodic table. a carbide formed by elements of group Vb and VIb or a nitride formed of elements of group IVb and Vb of the periodic table, wherein the composition of the binder ranges from 1% Re+99%Co to 99%Re+l%Co 1 Composition range 2 Composition range 3 Estimated melting point volume % Weight 〇 / 〇 volume % Weight % vol% % Weight % °C Re + Co Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 Bonding Co 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 49 0.05 to 29.7 0.08 to 4 3 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re + Co Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 1057D-6939- PF 138 8 1339219 m Bonding Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 37 to ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 Re +Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 4] 1400 Bonding Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.04 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re +Co Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 Bonding Co 0.03 to 39.6 0.05 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 41 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Co Rc 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 Bonding Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to N bC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Co Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 Bonding Co 0.03 to 39.6 0.02 To 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 ' Re +Co Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 F Bonding Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 To 93 1900 Re + Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 Bonding Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0,04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Co Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1400 Bonding Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.028 to 20 to WC WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900 Re + Co Re 0.03 to 39.6 0.1! to 71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 Bonding Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to TiN TiN 60 to 97 28 to 95 65 to 96 33 to 93 70 to 95 38 to 92 3200 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 i Bonding Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to W ZrN ZrN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3200 Re + Co Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 1400 Bonding Co 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to HfN HfN 60 to 97 50 to 98 65 to 96 55 to 97 70 to 95 61 to 97 3200 Re + Co Re 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 60 1400 Bonding Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 39 to VN VN 60 to 97 30 to 96 65 to 96 35 to 9 4 70 to 95 40 to 93 2300 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 Bonding Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to NbN NbN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 2500 Re + Co Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 1400 Bonding Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 lo 21 to TaN TaN 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 98 3200

1057D-6939-PF 139 ⑧ 1339219 表48 Re及Co(Re+Co)黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中IVb及Vb族元素所形成的矽化物，其中黏結劑組成範圍由l%Re+99%Co 至 99%Re+l%Co 組成範圍1 組成範圍2 組成範圍3 估算熔點 Volume % Weight % Volume % Weight % Volume % Weight % °C Re +Co Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.18to71 0.05 to 29.7 0.22 to 66 1400 黏結 Co 0.03 to 39.6 0.05 to 56 0.04 to 347 0.07 to 51 0.05 to 29.7 0.08 to 45 to TiB2 TiB2 60 to 97 24 to 34 65 to 96 29 to 92 70 to 95 34 to 90 3100 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.17 to 59 1400 黏結 Co 0.03 to 39.6 0.04 to 49 0.05 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to ZrB2 ZrB2 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 3100 Re +Co Re 0.03 to 39.6 0.06 to 55 0.04 to 34.7 0.08 to 50 0.05 to 29.7 0.09 to 44 1400 黏結 Co 0.03 to 39.6 0.2 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29.7 0.04 to 25 to 1 HfB2 HfB2 60 to 97 45 to 98 65 to 96 50〇97 70 to 95 56 to 96 3200 Ψ Re +Co Re 0.03 to 39.6 0.12 to 73 0.14 to 67 0.16 to 69 0.17 to 62 0.2 to 63 1400 黏結 Co 0.03 to 39.6 0.05 to 53 0.13 to 65 0.06 to 48 0.15 to 60 0.08 to 42 to vb2 vb2 60 to 97 27 to 95 33 to 87 31 to 93 70 to 95 36 to 91 2200 Re + Co Re 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.12 to 61 0.05 to 29.7 0.14 to 55 1400 黏結 Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to NbB2 NbB2 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3100 Re + Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 黏結 Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.035 to 23 to TaB2 TaB2 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 58 to 96 3300 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.17 to 59 1400 黏結 Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to Cr3B2 Cr3B2 60 to 97 30 to 96 65 to 96 35 to 93 70 to 95 41 to 93 2100 Re +Co Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 _黏結 Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to MoB2 MoB2 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 46 to 94 2200 Re + Co Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 1400 黏結 Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WB WB 60 to 97 53 to 98 65 to 96 59 to 98 70 to 95 64 to 97 2900 Re + Co Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 1400 黏結 Co 0.03 to 39.6 0.016 to 26 0.04 to 34.7 0.021 to 22 0.05 to 29.7 0.027 to 19 to W2B w2b 60 to 97 55 to 98 65 to 96 60 to 98 70 to 95 65 to 97 2900 Re+Co Re 0.03 to 39.6 0.14 to 76 0.04 to 34.7 0.18 to 72 0.05 to 29.7 0.23 to 67 1400 黏結 Co 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 47 to Ti5Si3 Ti5Si3 60 to 97 '24 to 94 65 to 96 28 to 92 70 to 95 32 to 90 2200 Re + Co Re 0.03 to 39.6 0.11 to71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 黏結 Co 0.03 to 39.6 0.05 to 51 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to Zr6Si5 ZrN 60 to 97 28 to 95 65 to 96 33 to 94 70 to 95 38 to 92 24001057D-6939-PF 139 8 1339219 Table 48 Re and Co(Re+Co) bonding is formed by the boride formed by elements of group IVb, Vb and VIb of the periodic table or by elements of group IVb and Vb of the periodic table. Telluride, in which the composition of the binder ranges from 1% Re+99%Co to 99%Re+l%Co. Composition range 1 Composition range 2 Composition range 3 Estimated melting point Volume % Weight % Volume % Weight % Volume % Weight % °C Re +Co Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.18to71 0.05 to 29.7 0.22 to 66 1400 Bonding Co 0.03 to 39.6 0.05 to 56 0.04 to 347 0.07 to 51 0.05 to 29.7 0.08 to 45 to TiB2 TiB2 60 to 97 24 to 34 65 to 96 29 to 92 70 to 95 34 to 90 3100 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.17 to 59 1400 Bonding Co 0.03 to 39.6 0.04 to 49 0.05 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to ZrB2 ZrB2 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 3100 Re +Co Re 0.03 to 39.6 0.06 to 55 0.04 to 34.7 0.08 to 50 0.05 to 29.7 0.09 to 44 1400 Bonding Co 0.03 to 39.6 0.2 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29 .7 0.04 to 25 to 1 HfB2 HfB2 60 to 97 45 to 98 65 to 96 50〇97 70 to 95 56 to 96 3200 Ψ Re +Co Re 0.03 to 39.6 0.12 to 73 0.14 to 67 0.16 to 69 0.17 to 62 0.2 to 63 1400 Bonding Co 0.03 to 39.6 0.05 to 53 0.13 to 65 0.06 to 48 0.15 to 60 0.08 to 42 to vb2 vb2 60 to 97 27 to 95 33 to 87 31 to 93 70 to 95 36 to 91 2200 Re + Co Re 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.12 to 61 0.05 to 29.7 0.14 to 55 1400 Bonding Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to NbB2 NbB2 60 to 97 34 to 96 65 to 96 39 To 95 70 to 95 45 to 94 3100 Re + Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 Bonding Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.035 To 23 to TaB2 TaB2 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 58 to 96 3300 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.17 to 59 1400 Bonding Co 0.03 To 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to Cr3B2 Cr3B 2 60 to 97 30 to 96 65 to 96 35 to 93 70 to 95 41 to 93 2100 Re +Co Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 _ Bonding Co 0.03 to 39.6 0.03 To 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to MoB2 MoB2 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 46 to 94 2200 Re + Co Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 To 41 0.05 to 29.7 0.07 to 36 1400 Bonding Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WB WB 60 to 97 53 to 98 65 to 96 59 to 98 70 to 95 64 to 97 2900 Re + Co Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 1400 Bonding Co 0.03 to 39.6 0.016 to 26 0.04 to 34.7 0.021 to 22 0.05 to 29.7 0.027 to 19 to W2B w2b 60 to 97 55 to 98 65 to 96 60 to 98 70 to 95 65 to 97 2900 Re+Co Re 0.03 to 39.6 0.14 to 76 0.04 to 34.7 0.18 to 72 0.05 to 29.7 0.23 to 67 1400 Bonding Co 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 47 to Ti5Si3 Ti5Si3 60 to 97 '24 to 9 4 65 to 96 28 to 92 70 to 95 32 to 90 2200 Re + Co Re 0.03 to 39.6 0.11 to71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 Bonding Co 0.03 to 39.6 0.05 to 51 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to Zr6Si5 ZrN 60 to 97 28 to 95 65 to 96 33 to 94 70 to 95 38 to 92 2400

1057D-6939-PF 140 ⑧ 13.392191057D-6939-PF 140 8 13.39219

Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 58 1400 黏結 Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 37 to NbSi2 NbSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re + Co Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.1 to 57 0.05 to 29.7 0.12 to 51 1400 黏結 Co 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to TaSi2 TaSi2 60 to 97 38 to 97 65 to 96 43 to 96 70 to 95 49 to 95 2500 Re + Co Re 0.03 to 39.6 0.] to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1400 黏結 Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.07 to 38 to MoSi2 MoSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re +Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 黏結 Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0,05to29.7 0.046 to 29 to WSi2 WSi2 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 51 to 95 2100Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 58 1400 Bonding Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 37 to NbSi2 NbSi2 60 to 97 31 To 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re + Co Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.1 to 57 0.05 to 29.7 0.12 to 51 1400 Bonding Co 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 To 36 0.05 to 29.7 0.05 to 31 to TaSi2 TaSi2 60 to 97 38 to 97 65 to 96 43 to 96 70 to 95 49 to 95 2500 Re + Co Re 0.03 to 39.6 0.] to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1400 Bonding Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.07 to 38 to MoSi2 MoSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re +Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 Bonding Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0,05to29.7 0.046 to 29 to WSi2 WSi2 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 51 to 95 2100

表49 Re及M〇(Re+M〇)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物，其中黏結劑組成範圍由l%Re+99%Mo至99%Re+1%Mo 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量°/〇 °C Re +Mo Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 69 0.05 to 29.7 0.2 to 64 2600 黏結 Mo 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 46 to TiC TiC 60 to 97 26 to 94 65 to 96 30 to 92 70 to 95 35 to 90 3200 Re +Mo Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 2600 黏結 Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to ZrC ZrC 60 to 97 32 to 95 65 to 96 37 to 94 70 to 95 42 to 92 3200 Re +Mo Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 2600 黏結 Mo 0.03 to 39.6 0.02 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29.7 0.04 to 25 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 +Mo _黏結 Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.18 to 62 2600 Mo 0.03 to 39.6 0.05 to 55 0.13 to 65 0.07 to 49 0.15 to 60 0.08 to 44 to VC VC 60 to 97 28 to 95 33 to 87 33 to 93 70 to 95 38 to 91 2900 Re + Mo Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2600 黏結 Mo 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 35 to NbC NbC 60 to 97 36 to 96 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re+ Mo Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 2600 黏結 Mo 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.03 to 22 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 96 3200 Re +Mo Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1700 黏結 Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to Cr2C3 Cr2〇3 60 to 97 32 to 95 65 to 96 37 to 94 70 to 95 43 to 92 1900 Re + Mo Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2500 黏結 Mo 0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 141Table 49 Re and M〇(Re+M〇) bond carbides formed by elements of group IVb, Vb and VIb of the periodic table, wherein the composition of the binder ranges from 1%Re+99%Mo to 99%Re+1 %Mo Composition range 1 Composition range 2 Composition range 3 Estimated melting point volume % Weight % Volume % Weight % Volume % Weight ° / 〇 °C Re +Mo Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 69 0.05 to 29.7 0.2 to 64 2600 Bonding Mo 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 46 to TiC TiC 60 to 97 26 to 94 65 to 96 30 to 92 70 to 95 35 to 90 3200 Re +Mo Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 2600 Bonding Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to ZrC ZrC 60 to 97 32 to 95 65 to 96 37 To 94 70 to 95 42 to 92 3200 Re +Mo Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 2600 Bonding Mo 0.03 to 39.6 0.02 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29.7 0.04 To 25 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 32 00 +Mo _bond Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.18 to 62 2600 Mo 0.03 to 39.6 0.05 to 55 0.13 to 65 0.07 to 49 0.15 to 60 0.08 to 44 to VC VC 60 to 97 28 to 95 33 to 87 33 to 93 70 to 95 38 to 91 2900 Re + Mo Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2600 Bonding Mo 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 35 to NbC NbC 60 to 97 36 to 96 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re+ Mo Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 To 38 2600 Bonding Mo 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.03 to 22 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 96 3200 Re +Mo Re 0.03 To 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1700 Bonding Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to Cr2C3 Cr2〇3 60 to 97 32 to 95 65 To 96 37 to 94 70 to 95 43 to 92 1900 Re + Mo Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2500 Bonding Mo 0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 To 95 50 to 95 2600 141

1057D-6939-PF B392191057D-6939-PF B39219

Re + Mo Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2600 黏結 Mo 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to WC WC 60 to 97 53 to 98 65 to 96 58 to 97 70 to 95 64 to 97 2900 表50 Re及Ni(Re+Ni)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物，其中黏結劑組成範圍由l%Re+99%Ni至99%Re+l%Ni 組成範圍1 組成範圍2 組成範圍3 估#溶點體積％重量％體積％重量°/。體積％重量％ °C Re+Ni Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 黏結 Ni 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.06 to 49 0.05 to 29.7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re+Ni Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 黏結 Ni 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 36 to ^ ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 W Re+Ni Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 黏結 Co 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.034 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re+Ni Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 黏結 Ni 0.03 to 39.6 0.04 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 40 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Ni Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 黏結 Ni 0.03 to 39.6 0,03 to 43 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Ni Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 黏結 Ni 0.03 to 39.6 0.018 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 Re+Ni Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 費黏結 Ni 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 O2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Ni Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 黏結 Ni 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Ni Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.06 to 42 0.05 to 29.7 0.07 to 36 1400 黏結 Ni 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WC WC 60 to 97 53 to 98 65 to 96 58 to 98 70 to 95 64 to 97 2900 表51 Re及Cr(Re+Cr)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物，其中黏結劑組成範圍由1 %Re+99%Cr至99%Re+] %CrRe + Mo Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2600 Bonding Mo 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to WC WC 60 to 97 53 To 98 65 to 96 58 to 97 70 to 95 64 to 97 2900 Table 50 Re and Ni (Re+Ni) bonded carbides formed by elements of group IVb, Vb and VIb of the periodic table, wherein the composition of the binder consists of l%Re+99%Ni to 99%Re+l%Ni Composition range 1 Composition range 2 Composition range 3 Estimation #Solution point volume % Weight % Volume % Weight °/. Volume % Weight % °C Re+Ni Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 Bonding Ni 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.06 to 49 0.05 to 29.7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re+Ni Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 Bonding Ni 0.03 to 39.6 0.04 To 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 36 to ^ ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 W Re+Ni Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 Bonding Co 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.034 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 To 96 3200 Re+Ni Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 Bonding Ni 0.03 to 39.6 0.04 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 40 to VC VC 60 To 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Ni Re 0.0 3 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 Bonding Ni 0.03 to 39.6 0,03 to 43 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Ni Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 Bonding Ni 0.03 to 39.6 0.018 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 Re+Ni Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 fee bonding Ni 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 O2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Ni Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 Bonding Ni 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 To 96 70 to 95 50 to 95 2600 Re + Ni Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.06 to 42 0.05 to 29.7 0.07 to 36 1400 Bonding Ni 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WC WC 60 to 97 53 to 98 65 to 96 58 to 98 70 to 95 64 to 97 2900 Table 51 Re and Cr (Re+Cr) bonded carbides formed from elements IVb, Vb and VIb of the periodic table, wherein the composition of the binder ranges from 1% Re+99%Cr to 99% Re+] %Cr

組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量％ °CComposition range 1 Composition range 2 Composition range 3 Estimated melting point Volume % Weight % Volume % Weight % Volume % Weight % °C

1057D-6939-PF 142 ⑧ 13392191057D-6939-PF 142 8 1339219

' I' I

Re +Cr Re 0.03 to 39.6 0.13 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1800 黏糸έ Cr 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 39 to TiC TiC 60 to 97 26 to 96 65 to 96 30 to 94 70 to 95 36 to 93 3200 Rc +Cr Re 0.03 to 39.6 0.1 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1800 黏結 Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 32 to ZrC ZrC 60 to 97 32 to 97 65 to 96 37 to 95 70 to 95 42 to 94 3200 Re +Cr 黏結 __Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.09 to 41 1800 Cr 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.027 to 19 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 98 70 to 95 59 to 97 3200 Re +Cr 黏結 Re —〜·— 0.03 to 39.6 0.11 to71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1800 Cr 0.03 to 39.6 0.04 to 46 0.13 to 65 0.05 to 41 0.15 to 60 0.06 to 35 to VC vc 60 to 97 28 to 96 33 to 87 33 to 95 70 to 95 38 to 93 2900 Re + Cr 黏結 Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1800 Cr 0.03 to 39.6 0.026 to 37 0.04 to 34.7 0.034 to 33 0.05 to 29.7 0.04 to 28 to ^ NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 3200 Re + Cr Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 18⑻ 黏結 TaC Cr 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.019 to 2] 0.05 to 29.7 0.024 to 17 to TaC 60 to 97 51 to 98 65 to 96 56 to 98 70 to 95 62 to 97 3200 Re +Cr 黏結 Cr2C3 Re ------ 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.16 to 57 1800 Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to Cr2C3 60 to 97 32 to 97 65 to 96 37 to 96 70 to 95 43 to 95 1900 Re + Cr 黏結 Mo2C Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1800 Cr 0.03 to 39.6 0.023 to 34 0.04 to 34.7 0.03 to 29 0.05 to 29.7 0.037 to 25 to M〇jC 60 to 97 40 to 98 65 to 96 45 to 97 70 to 95 50 to 96 2600 Re + Cr 黏結 WC Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1800 Cr 0.03 to 39.6 0.014 to 23 0.04 to 34.7 0.018 to 20 0.05 to 29.7 0.023 to 16 to WC 60 to 97 53 to 98.6 65 to 96 58 to 98 70 to 95 64 to 97.6 2900 具有上述組成之硬金屬或陶瓷金屬可以應用在很多方面，例如，可應用於用來除去目標物材質的耐磨元件例如用於切削工具、磨輪、鑽具中的耐磨元件。該工具可以含有由其他不同材料製成的支撐元件’例如鋼。這些耐磨元件可以鑲於支撐元件中。該工具可以設計成包含多種嵌入物被鑲於支撐元件中。例如許多礦業用的鑽具包含許多硬金屬材料所構成之小釦子。當然可應用的工具包括鑽具、切削工具、磨具、刀具、鋸子等等各式各樣的需要耐 143Re +Cr Re 0.03 to 39.6 0.13 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1800 Adhesive Cr 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 39 to TiC TiC 60 to 97 26 to 96 65 to 96 30 to 94 70 to 95 36 to 93 3200 Rc +Cr Re 0.03 to 39.6 0.1 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1800 Bonding Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 32 to ZrC ZrC 60 to 97 32 to 97 65 to 96 37 to 95 70 to 95 42 to 94 3200 Re +Cr Bonding __Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.09 to 41 1800 Cr 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.027 to 19 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 98 70 to 95 59 to 97 3200 Re + Cr Bonding Re —~·— 0.03 to 39.6 0.11 to71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1800 Cr 0.03 to 39.6 0.04 to 46 0.13 to 65 0.05 to 41 0.15 to 60 0.06 to 35 to VC vc 60 to 97 28 to 96 33 to 87 33 to 95 70 to 95 38 to 93 2900 Re + Cr Bonding Re 0.03 t o 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1800 Cr 0.03 to 39.6 0.026 to 37 0.04 to 34.7 0.034 to 33 0.05 to 29.7 0.04 to 28 to ^ NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 3200 Re + Cr Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 18(8) Bonded TaC Cr 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.019 to 2] 0.05 To 29.7 0.024 to 17 to TaC 60 to 97 51 to 98 65 to 96 56 to 98 70 to 95 62 to 97 3200 Re +Cr Bonded Cr2C3 Re ------ 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.16 to 57 1800 Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to Cr2C3 60 to 97 32 to 97 65 to 96 37 to 96 70 to 95 43 to 95 1900 Re + Cr Bonding Mo2C Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1800 Cr 0.03 to 39.6 0.023 to 34 0.04 to 34.7 0.03 to 29 0.05 to 29.7 0.037 to 25 to M〇jC 60 to 97 40 to 98 65 to 96 45 to 97 70 to 95 50 to 96 2600 Re + Cr Bonding WC Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1800 Cr 0.03 to 39.6 0.014 to 23 0.04 to 34.7 0.018 to 20 0.05 to 29.7 0.023 to 16 to WC 60 to 97 53 to 98.6 65 to 96 58 to 98 70 to 95 64 to 97.6 2900 Hard metal or ceramic metal with the above composition can be applied in many aspects, for example, it can be applied to wear-resistant components for removing target materials, such as for use in cutting tools, grinding wheels, and drills. Grinding components. The tool may contain support elements such as steel made of other different materials. These wear elements can be embedded in the support element. The tool can be designed to include a plurality of inserts that are embedded in the support member. For example, many mining drills contain small buttons made up of many hard metal materials. Of course, the tools that can be used include drills, cutting tools, grinding tools, knives, saws, etc.

1057D-6939-E>F ⑧ 1339219 ► * 磨耗之工具。除此之外’可根據元件的特別需[ 構造用的外罩、外表面或—些層來配合元件在某些環的操作應用。兄特別的是，上述的硬金屬可以用來製作切削工具，而能對金屬、合金、複合物、輯、木頭以及其他材料進= 機械加工。這些切削工具可以包含用來旋轉、冑、鑽的錄嵌物，還有鑽孔器、鉸刀、鉸床、栓頭、套子與研磨具等等。由於上述的工具在切削時會達到5〇(rc的高溫，所以本案之適用於高溫之硬金屬材料非常適用於上述工具因而有特別之功效。例如，可增加工具壽命以及可藉由增加切削速度而改善切削品質。本發明的硬金屬材料除了可應用於抽線…丨^ drawing)、擠製（extrusi〇n)、鍛造以及冷加工之外，也能用於粉末製程中的模具和衝頭。還#，也可用於礦業的耐磨元件。本發明的硬金屬材料除了可製造成塊材的形式也可塗佈在金屬表面上。本發明硬金屬材料的塗佈有助於在金屬表面心成一硬金屬$纟達到下部金屬#料所難以達到的高硬度值。以本發明組成所製成的金屬塊材成本相當昂貴，因此制㈣的方切本發明之硬金属㈣在價格低廉且硬度較低的金屬材料±，可有效降低成本且提升所需的硬度。户種用來製造商用硬金屬的粉末製程也可用來製造本發明的硬金屬。例如’一 Re含量超過總重量⑽的黏1057D-6939-E>F 8 1339219 ► * Tools for wear. In addition to this, the special needs of the components [the outer cover, the outer surface or the layers of the construction may be used to match the components in the operation of certain rings. In particular, the hard metal described above can be used to make cutting tools, and can be machined for metals, alloys, composites, series, wood, and other materials. These cutting tools can include inserts for rotation, boring, and drilling, as well as drills, reamers, reamers, bolts, covers, and abrasives. Since the above tool can reach 5 〇 (rc high temperature), the hard metal material suitable for high temperature in this case is very suitable for the above tools and thus has special effects. For example, it can increase the tool life and increase the cutting speed. In addition to being applicable to drawing, extrusion, forging and cold working, the hard metal material of the present invention can also be used for molds and punches in a powder process. Also #, can also be used in mining wear-resistant components. The hard metal material of the present invention can be applied to a metal surface in addition to being made into a block. The coating of the hard metal material of the present invention contributes to the formation of a hard metal in the surface of the metal to a high hardness value which is difficult to achieve with the lower metal material. The metal block produced by the composition of the present invention is relatively expensive, so that the hard metal (4) of the present invention can be effectively reduced in cost and improved in hardness by the low-cost and low-hardness metal material. The powder process used to make commercial hard metals can also be used to make the hard metals of the present invention. For example, the viscosity of a Re content exceeding the total weight (10)

1057D-6939-PF ⑧ 144 1339219 ，丨 * 結劑基質可用固態燒結製程來製造以消除多孔性，接著以熱均壓（hot isostatic pressing，HIP)製程取代液相燒結1057D-6939-PF 8 144 1339219 , 丨 * The binder matrix can be fabricated by a solid state sintering process to eliminate porosity, followed by a hot isostatic pressing (HIP) process instead of liquid phase sintering.

第9圖顯示多種上述硬金屬組合物材料及結構製造方法的流程圖，如圖所示，可以一濕式的混合製程利用液體輾磨，將黏結劑的合金粉末與硬粒子粉末混合，其中輾磨製程中可添加潤滑劑（例如：蠟）來減低摩擦。第9圖中左手邊的製造流程為利用含潤滑劑的濕式輾磨來製造硬金屬。利用真空乾燥法（vacuum drying)或喷霧乾燥法（spray drying)將混合物作第一次乾燥來製造經過潤滑的粉末接著將該經過潤滑的粉末藉由衝壓、擠製或冷均壓來形成塊材及成形。冷均壓製裎是利用均勻的壓力使粉末結合。將成形的塊材透過多種加熱過程以除去潤滑劑，例如可將加壓成形的塊材在真空或氫氣氣氛下利用液相燒結，接著更進一步利用熱均壓製程來形成最後的硬金屬塊材。若黏結劑合金粉末與硬粒子粉末混合時未使用潤滑劑，則該未經潤滑的粉末在乾燥製程後可經由兩種不同的方法來製造最後的硬金屬組合物。第一種方法是利用熱询壓，第二種方法是利用熱喷塗法在真空中將粉末形成=金屬基材上，接著將金屬基材移除使完成最後單獨存在的項金屬。除此之外，若需要可再利用一熱均壓製程來降低多孔性。在金屬表面形成硬金屬塗層的過程中，可利用—熱喷塗製程在真空條件下將硬金屬塗佈在金屬表面上。例如可在鋼鐵表面或工具表面塗佈一硬金屬層來提高其硬度以增 1057D-6939-PF 145 » ' •k 加性能。第]〇圖顯示熱喷塗製程實施例的流程圖。有多種已知的熱喷塗製程可用來在金屬表面進行塗佈製程，例如ASM手冊第7冊（P4〇8, MM)中描述熱喷塗製程如：―種能夠將金屬、陶瓷、介金屬化合物複合材料以及巧分子形成塗佈層或獨立的結構的微粒結合製程。在 ^塗衣轾中可將粉末、金屬線材或條狀金屬材料置入燃燒或以電弧加熱（arc_heated)的喷射器中，經過加熱、熔化或軟化、加速再經由控制喷塗至表面或基板上。在喷塗衝擊 _的過矛王中，微粒快速固化 '冷卻、收縮以及逐漸累積成一沈積物於表面。在沈積過程中薄塗佈層經過一超過106k/s 的南冷卻速率。 —熱喷塗製程可利用化學能或電能來加熱填入喷射器中材料，形成一熔化的流體經過加速在基材表面完成塗佈。不同的熱喷塗製程顯示在ASM手冊第7冊p4〇94i〇中第3及第4圖。不同熱喷塗製程細節詳述在分別刊載於 ASM 手冊第 7 冊 p〇wer Meul Techn〇i〇gies _ • APPlication(l998)中 P396_407 及 Ρ4〇8·419 中 Lawley 以 al 的 “spray forming” 以及 Knighi et al 的“^謂！如叮Figure 9 is a flow chart showing a plurality of the above hard metal composition materials and structure manufacturing methods. As shown in the figure, a wet mixing process can be used to mix the alloy powder of the binder with the hard particle powder by liquid honing. Lubricants (eg wax) can be added to the grinding process to reduce friction. The manufacturing process on the left hand side of Figure 9 is the use of wet honing with lubricant to make hard metal. The mixture is first dried by vacuum drying or spray drying to produce a lubricated powder, and then the lubricated powder is formed into a block by stamping, extrusion or cold equalization. Materials and forming. Cold-pressing enthalpy is the use of uniform pressure to bond the powder. The shaped block is passed through various heating processes to remove the lubricant. For example, the press-formed block can be sintered in a liquid phase under a vacuum or a hydrogen atmosphere, and then further subjected to a hot press process to form a final hard metal block. . If the binder alloy powder is mixed with the hard particle powder without using a lubricant, the unlubricated powder can be used to make the final hard metal composition by two different methods after the drying process. The first method utilizes thermal interrogation, and the second method utilizes thermal spraying to form the powder into a metal substrate in a vacuum, followed by removal of the metal substrate to complete the final separately present term metal. In addition, if necessary, a heat-reduction process can be reused to reduce the porosity. In the process of forming a hard metal coating on the metal surface, the hard metal may be coated on the metal surface under vacuum using a thermal spray process. For example, a hard metal layer can be applied to the steel surface or tool surface to increase its hardness to increase the performance of 1057D-6939-PF 145 » ' • k. The figure shows a flow chart of an embodiment of a thermal spray process. There are a number of known thermal spray processes that can be used to coat processes on metal surfaces. For example, ASM Handbook Volume 7 (P4〇8, MM) describes thermal spray processes such as: “Can be used to metal, ceramic, and intermetallic Compound composites and microparticle bonding processes that form a coating layer or a separate structure. The powder, metal wire or strip metal material can be placed in a burning or arc-heated ejector in a coating coat, heated, melted or softened, accelerated and then sprayed onto the surface or substrate by control. . In the Spear King, which sprays the impact _, the particles quickly solidify 'cooling, shrinking and gradually accumulating a deposit on the surface. The thin coating layer passes through a south cooling rate of over 106 k/s during the deposition process. - The thermal spray process uses chemical or electrical energy to heat the material filled into the ejector to form a molten fluid that accelerates the coating on the surface of the substrate. The different thermal spray processes are shown in Figures 3 and 4 of the ASM Handbook Volume 7 p4〇94i〇. Details of the different thermal spray processes are detailed in the ASM Handbook, Volume 7, p〇wer Meul Techn〇i〇gies _ • APPlication (l998), P396_407 and Ρ4〇8·419, Lawley's “spray forming” with al and Knighi et al's "^说!如叮

Forming Of Material” ° 雖然本發明已以較佳實施例揭露如上，然其並非用以限定本發明，任何熟習此技藝者，在不脫離本發明之精神和範圍内，當可作些許之更動與潤飾’因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 1057D-6939-PF 146 ⑧ 1339219 j Λ ( 【圖式簡單說明】第1圖是顯示根據一方法來製造本發明硬金屬的一典型製造流程圖。第2圖是顯示在固態下根據兩階段燒結步驟來製造本發明硬金屬的一典型製造流程圖。第 3、4、5、6、金屬之一些測定性質 7與8圖係顯示所選擇的代表性的硬Although the present invention has been described above by way of a preferred embodiment, it is not intended to limit the invention, and those skilled in the art can make some modifications without departing from the spirit and scope of the invention. The scope of protection of the present invention is therefore defined by the scope of the appended claims. 1057D-6939-PF 146 8 1339219 j Λ ( [Simple Description] Figure 1 shows the manufacture of this method according to a method. A typical manufacturing flow chart for inventing a hard metal. Fig. 2 is a flow chart showing a typical manufacturing process for producing a hard metal of the present invention according to a two-stage sintering step in a solid state. Some properties of the third, fourth, fifth, and sixth metals. 7 and 8 graphs show the selected representative hard

第9及第10圖係說明熱噴塗的方法。【主要元件符號說明】無Figures 9 and 10 illustrate the method of thermal spraying. [Main component symbol description] None

1057D-6939-PF 1471057D-6939-PF 147

Claims

133*9219 第094108009號中文申請專利範圍修正本十、申請專利範圍： 1. 一種材料，包括： B.14133*9219 No. 094108009 Chinese Patent Application Amendment 10 Scope of Application: 1. A material, including: B.14

1 硬粒子，該硬粒子包括WC及TaC ;以及一黏結劑基質，黏結該硬粒子，該黏結劑基質包括Re 及鎳基超合金，其中該WC及TaC分別佔該材料總重量的44%至98%、及最高至24%，該黏結劑基質中的該Re及鎳基超合金分別佔該材料總 φ 重量的最高至47%、及最高至25%，且該Re佔該黏結劑基質總重量的25%或以上。 2.如申請專利範圍第1項所述之材料，其中該材料由兩階段步驟製造，包括在真空中以低於該硬粒子及該黏結劑基質混合物的共熔溫度之1 700°C或以上燒結該硬粒子及該黏結劑基質混合物，之後在壓力及鈍性氣體存在下，以低於該硬粒子及該黏結劑基質混合物的共熔溫度之1 600°C或以上燒結該硬粒子及該黏結劑基質混合物。 fp 3. —種材料，包括：硬粒子，該硬粒子包括WC、Tie及TaC ;以及一黏結劑基質，黏結該硬粒子，該黏結劑基質包括Re 及鎳基超合金，其中該WC、TiC及TaC分別佔該材料總重量的40%至 98%、最高至23%、及最高至26%，該Re及鎳基超合金分別佔該材料總重量的最高至 53%、及最高至30%， [ 1057D-6939-PF2 148 1339219 且該Re佔該黏結劑基質總重量的25%或以上。 4 ·如申清專利範圍第3項所述之材料，其中該材料由兩 1 階段步驟製造，包括在真空中以低於該硬粒子及該黏結劑基質混合物的共熔溫度之丨70(rc或以上燒結該硬粒子及該黏結劑基質混合物，之後在壓力及鈍性氣體存在下，以低於該硬粒子及該黏結劑基質混合物的共熔溫度之丨6〇(rc或以上燒結該硬粒子及該黏結劑基質混合物。 5 · —種材料，包括： Φ 硬粒子，該硬粒子包括WC及Tic ;以及一黏結劑基質，黏結該硬粒子，該黏結劑基質包括Co、 Re及鎳基超合金，其中該WC及TiC分別佔該材料總重量的40%至98%、及最1¾至24%，該Co佔該材料總重量的最高至32%，該^及鎳基超合金分別佔該材料總重量的最高至54%、及最高至29〇/〇，且該Re佔該黏結劑基質總重量的25%或以上。馨 6. —種材料，包括：硬粒子，該硬粒子包括WC及TaC ;以及一黏結劑基質’黏結該硬粒子，該黏結劑基質包括C〇、 Re及錄基超合金，其中該WC及TaC分別佔該材料總重量的45%至98%、及最高至24%，該Co佔該材料總重量的最高至28%，該Re及鎳基超合金分別佔該材料總重量的最高至47%、及最高至26%， r 1057D-6939-PF2 149 1339219 ' 且該Re佔該黏結劑基質總重量的25%或以上。 7. —種材料，包括：硬粒子，該硬粒子包括WC、TiC及TaC ;以及一黏結劑基質，黏結該硬粒子，該黏結劑基質包括Co、 Re及鎳基超合金，其中該WC、TiC及TaC分別佔該材料總重量的35%至 93%、最高至25%、及最高至26%，該Co佔該材料總重量的最高至44%，該Re及鎳基超合 φ 金分別佔該材料總重量的最高至65%、及最高至4 1 %，且該Re佔該黏結劑基質總重量的25%或以上。1 hard particles comprising WC and TaC; and a binder matrix comprising a Re and a nickel-based superalloy, wherein the WC and TaC account for 44% of the total weight of the material, respectively 98%, and up to 24%, the Re and nickel-based superalloys in the binder matrix account for up to 47% and up to 25% of the total φ weight of the material, respectively, and the Re accounts for the total matrix of the binder. 25% or more by weight. 2. The material of claim 1, wherein the material is manufactured by a two-stage process comprising a vacuum of less than 1700 ° C or more of the eutectic temperature of the hard particle and the binder matrix mixture. Sintering the hard particles and the binder matrix mixture, and then sintering the hard particles and the bonding at a temperature lower than 1 600 ° C or more of the eutectic temperature of the hard particles and the binder matrix mixture in the presence of pressure and a passive gas Mixture of the matrix. Fp 3. A material comprising: hard particles comprising WC, Tie and TaC; and a binder matrix comprising the hard particles, the binder matrix comprising Re and a nickel-based superalloy, wherein the WC, TiC And TaC accounted for 40% to 98%, up to 23%, and up to 26%, respectively, of the total weight of the material, and the Re and nickel-based superalloys accounted for up to 53% and up to 30% of the total weight of the material, respectively. [1057D-6939-PF2 148 1339219 and the Re accounts for 25% or more of the total weight of the binder matrix. 4. The material of claim 3, wherein the material is manufactured by two one-stage steps, including 丨70 (rc) in a vacuum below the eutectic temperature of the hard particle and the binder matrix mixture. Sintering the hard particles and the binder matrix mixture, and then sintering the hard particles at a temperature lower than the eutectic temperature of the hard particles and the binder matrix mixture in the presence of a pressure and a passive gas. And the binder matrix mixture. 5 - a material comprising: Φ hard particles, the hard particles include WC and Tic; and a binder matrix to bond the hard particles, the binder matrix including Co, Re and nickel based super The alloy, wherein the WC and TiC respectively account for 40% to 98%, and most 13⁄4 to 24% of the total weight of the material, and the Co accounts for up to 32% of the total weight of the material, and the nickel-based superalloy accounts for The total weight of the material is up to 54%, and up to 29 〇 / 〇, and the Re accounts for 25% or more of the total weight of the binder matrix. Xin 6. A variety of materials, including: Hard particles, the hard particles include WC And TaC; and a binder matrix 'sticky The hard particles, the binder matrix comprises C〇, Re and a recording superalloy, wherein the WC and TaC respectively account for 45% to 98% and up to 24% of the total weight of the material, and the Co accounts for the total weight of the material. Up to 28%, the Re and nickel-based superalloys account for up to 47% and up to 26% of the total weight of the material, respectively, r 1057D-6939-PF2 149 1339219 ' and the Re accounts for the total weight of the binder matrix 25% or more. 7. A material comprising: hard particles comprising WC, TiC and TaC; and a binder matrix bonded to the hard particles, the binder matrix comprising Co, Re and nickel based super An alloy wherein the WC, TiC and TaC comprise from 35% to 93%, up to 25%, and up to 26%, respectively, of the total weight of the material, the Co accounting for up to 44% of the total weight of the material, the Re and nickel The base super φ gold accounts for up to 65% and up to 41% of the total weight of the material, respectively, and the Re accounts for 25% or more of the total weight of the binder matrix.

1057D-6939-PF2 1501057D-6939-PF2 150