TWI299738B

TWI299738B - Process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer

Info

Publication number: TWI299738B
Application number: TW91134680A
Authority: TW
Inventors: Louwet Frank; Groenendaal Bert
Original assignee: Agfa Gevaert
Priority date: 2002-05-16
Filing date: 2002-11-29
Publication date: 2008-08-11
Also published as: TW200306988A; TW200307707A; TWI276650B

Description

1299738 A7 製造聚（3,4- 5 10 五、發明說明（/ 發明領域本發明係有關於一種於聚陰離子存在下二烷氧基噻吩）聚合物之方法。發明背景由於其引人注目之電學與/或光學性能，聚噻吩已被廣泛地抓时，藉化學或電化學之氧化或還原，可使聚噻吩變成具有導電性。 EP-A 257573揭示一種本性的導電聚合物，其中經由 2-位置與/或5-位置之連接，使其相互偶合，統計地平均有 60至1〇〇重量％之結構單元，其衍生自至少一種具式之單體： (請先Mtt背面之注意事項再填S本頁)1299738 A7 Manufacture of poly(3,4- 5 10 V. INSTRUCTION DESCRIPTION (/ FIELD OF THE INVENTION The present invention relates to a dialkoxythiophene in the presence of a polyanion) polymer. BACKGROUND OF THE INVENTION Due to its remarkable electrical And/or optical properties, when polythiophene has been extensively captured, chemically or electrochemically oxidized or reduced, the polythiophene becomes electrically conductive. EP-A 257 573 discloses a conductive polymer of the nature, wherein via 2- The positions and/or 5-positions are coupled to each other, statistically having an average of 60 to 1% by weight of the structural unit derived from at least one of the monomers: (Please first note the back of Mtt) Fill in this page)

R 15R 15

H S Η (1) 經濟部智.β財產局貝工消ff合作社印» ο 2H S Η (1) Ministry of Economic Affairs Zhi. β Property Bureau Beigong ff cooperative cooperative printing » ο 2

其中 R1 為 C!·1·烷氧基基團或·〇((：：Η2(：：Η2〇)η(：：Η3，其 n=1 至4 ’與R1為氫原子、Ci i2_烷基基團、Ci i2-烷氧基基團或-0(CH2CH20)nCH3,其 η=ι 至 4,或 R1 與 R1 同為-〇(CH2)m-CH2-或-〇(CH2)m_0-，其至12，有〇至40重量。/。之結構單元，其衍生自至少一種具式（2)之單體·· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 91. 3. 2,000 1 1299738Wherein R1 is C!·1·alkoxy group or 〇((::Η2(::Η2〇)η(::Η3, where n=1 to 4′ and R1 is a hydrogen atom, Ci i2_alkane a group, a Ci i2-alkoxy group or -0(CH2CH20)nCH3, η=ι to 4, or R1 and R1 are the same as -〇(CH2)m-CH2- or -〇(CH2)m_0- , up to 12, has a structure of 40% by weight. It is derived from at least one monomer of formula (2) · This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 91. 3. 2,000 1 1299738

發明說明（Z) 5 -中R與R各自獨立地為氫原子、幽素原子、 =團6或芳基或連同與其連接之碳原子生成-個芳族環2 ” R各自獨立地代表氫原子，或者r3連同r4以及盘接之碳原子，或者R5連同R6以及與其連接之碳原子:、各生成一個芳㈣，x代表氧原手、硫原子、泰團'吼烧基基團或％芳基基團，有G至4G重量％之結構單元，其衍生自至少一種具式（3)之單體： 10DESCRIPTION OF THE INVENTION (Z) 5 - wherein R and R are each independently a hydrogen atom, a crypto atom, a group 6 or an aryl group or a carbon atom to which it is bonded to form an aromatic ring 2" R each independently represents a hydrogen atom , or r3 together with r4 and the carbon atom to be bonded, or R5 together with R6 and the carbon atom to which it is attached: each to form an aromatic (four), x represents an oxygen precursor, a sulfur atom, a Thai group, a thiol group or a % aromatic a radical having from G to 4 G weight percent of a structural unit derived from at least one monomer of formula (3): 10

15 其中R ’ R，R9與Ri〇各自獨立地代表氮原子、烧基基團、烷氧基基團或芳基基團，γ與z各自獨立地代表氧原子、硫原子、^NH棊團、烷基基團或=N_芳基基團，Ri代表芳烯基團、雜芳烯棊團·，或具式（CH=CH)。之共軛系統’其中〇為卜2或3,有〇至4〇重量％之結構單元，其衍生自至少一種具式（4)之單體：經濟部智M財產局貝工消費合作社印製 ο 215 wherein R ' R, R 9 and Ri 〇 each independently represent a nitrogen atom, a pyridyl group, an alkoxy group or an aryl group, and γ and z each independently represent an oxygen atom, a sulfur atom, a ^NH group , an alkyl group or an =N-aryl group, Ri represents an aralylene group, a heteroarylene group, or a formula (CH=CH). The conjugate system 'where 〇 is 2 or 3, has 〇 to 4 〇% by weight of the structural unit, which is derived from at least one monomer of formula (4): Printed by Ministry of Economic Affairs, M Property Bureau, Bayer Consumer Cooperative ο 2

其中R12與R13各自獨立地代表氫原子、齒素雇.子、Cm2_ 烧基基團、C^2-烷氧基基團、Ci 4_烷基胺基基團或Cm-酿基胺基基團’ R14代表鹵素原子、Cl_12_烷基基團、Cm2- 本紙張尺度通用中國國家標準（CNS)A4规格（21〇 x 297公麓 91. 3. 2,000 [299738Wherein R12 and R13 each independently represent a hydrogen atom, a dentate, a Cm2_alkyl group, a C^2-alkoxy group, a Ci 4_alkylamino group or a Cm-bristyl amino group Group 'R14 stands for halogen atom, Cl_12_alkyl group, Cm2- This paper scales Common Chinese National Standard (CNS) A4 specification (21〇x 297 mm麓91. 3. 2,000 [299738

五、發明說明（S ) 烷氧基基團、Cy烷基胺基基團或Cl-4_醯基胺基基團，及 X具有同前之意義，其中於25 °c下，氧化形態聚合物可完王/谷解於二極質子惰性溶劑，並且於25。(3下，可獲得於1 〇〇宅升溶劑中至少含有〇·1公克聚合物之溶液。 ΕΡ_Α 339340揭示一種包含具下式結構單元之聚噻吩： 5 10V. Description of the invention (S) an alkoxy group, a Cyalkylamino group or a Cl-4-decylamino group, and X have the same meaning as above, wherein the oxidative polymerization at 25 ° C The substance can be dissolved in a bipolar aprotic solvent and at 25. (3) A solution containing at least 1 gram of polymer in 1 liter of house liter solvent can be obtained. ΕΡ_Α 339340 discloses a polythiophene comprising a structural unit having the following formula: 5 10

(請先閱讀背面之注意事項再填寫本頁) 15 其中Α代表選擇地取代之伸烷基，並由相關噻吩經氧化性聚合反應製備。 EP-A 44〇957揭示聚噻吩之分散液，其係由具式⑴之刼構單元所構成： ,0——R丁 . I I 1 I I I I 訂--------- 經濟部智慧財產局貝工消费合作社印製 20 (I) 其中R與R2各自獨立地代表氫或陰離子之存在下，連同生成—種選擇地取狀^•伸幻殘餘物，於實例3中，將空氣於聚合溶液中冒泡。此外，WalSh等人，1999年於大分子，第32冊， •院基基團，或於驾(Please read the notes on the back and fill out this page.) 15 Wherein Α represents a substituted alkyl group and is prepared by oxidative polymerization of the relevant thiophene. EP-A 44 957 957 discloses a dispersion of polythiophene which is composed of a unit of formula (1): , 0 - R. II 1 IIII ------------- Ministry of Economics Intellectual Property Bureau of Peking Consumers Co., Ltd. 20 (I) where R and R2 each independently represent the presence of hydrogen or an anion, together with the formation-selectively taking the shape of the phantom residue, in Example 3, the air is polymerized. Bubbling in the solution. In addition, WalSh et al., 1999, in Macromolecules, Volume 32, • Institute-based groups, or driving

本紙張尺度邮中Η 8 S：鮮（chs〉A4規格⑽X 91· 3· 2,000 1299738 A7 B7 五、發明說明（詧） (請先閲讀背面之注意事項再填寫本頁) 2397至2399頁，報導由化學聚合反應製備3-取代之雜芳基聚噻吩，其使用4莫耳當量氯化鐵，於50°C之氣仿中，在以乾燥空氣缓慢清除之情況下進行。Pomerantz等人， 1991年於合成金屬，第41 | 43冊，第825至830頁，報 5 導聚（3-烷基噻吩）之製備，使用無水氯化鐵，於氯仿中，而且在乾燥空氣於反應混合物中冒泡之情況下進行。然而，聚合物，例如：包含一個氧或氮族元素之原子之五環雜環化合物，之電聚合反應，傳統地於惰性氣體掩蓋下進行，參見如：JP 59-210947，與Zhang等人，2001年於 1〇固態電化學期初，第5冊，第74至79頁。對於迄今已被製備與研究之導電性聚合物，其一般性之缺點為·.對於某些應用，導電性仍然過低，其可見光透射度不足，對曝露於可見光與紫外光之安定性太低，與/或其無法加工。 15 發明目的因此本發明之」層面為提供聚噗吩或噻吩共聚物，其具有高導電性、高可見光透射度、對曝露於可見光與紫外光之高度安定性，與良好的如工性。經濟部智慧財產局貝工消ff合作社印製 2〇本發明之其他層面與優點經下文之敘述後將趨明顯。發明概述 * 聚噻吩之聚合，傳統地係於空氣之存在下，甚至在空氣於反應混合物中冒泡之情況下進行，令人驚訝地發現， 91. 3. 2,000 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公*〉 1299738 A7 五、發明說明（女 ^化地或還原地聚合之聚噻吩或噻吩共聚物，其於存在有聚陰離子，如：聚（苯乙烯績酸），及於惰性氣體環境下之水陡質中進行，使得每公升反應介質存在少於3毫克之氧〃在二氣存在下聚合得到之聚噻吩相較，前者於特殊之透，度具有大幅增加的導電性，並具有改良的安定性。實現本發明層面可使用一種製備聚嚐吩或喧吩共聚物之水性或非水性溶液或分散液之方法，其包含依式⑴之結構單元：口 5 10 Ό——R丁經濟部智慧財產局貝工消费合作社印製其中R1與R2各自獨立地代表氫、或Cn烧基基團、或連 15 g生成-種選擇地取代之C15_伸烧基殘餘物，包括下述步驟備㈣吩或嗔吩共聚物時，於存在有聚陰離子之反應介ΐ中使用一種引發劑，在氧化或還原之條件下，及於情性壞境中進行，使得當添加該引發劑後，反應介質中每公升反應介質存在少於3毫克之氧。 2〇 #現本發明層面亦可藉使用—種由前文肺方法製得之聚=吩或嘧吩共聚物之水性或非水性溶液或分散液。戶、見本^明層面亦可藉提供一種水性或非水性溶液或刀政液之用途，其包含前文揭示之聚喧吩或喧吩共聚物之水性溶液或分散液。 ---------^9—' 本紙張尺細中a^iV(CNS)A4規格⑽ 297公釐） 91- 3. 2,000The paper size is 邮 8 S: Fresh (chs>A4 size (10)X 91· 3· 2,000 1299738 A7 B7 V. Invention description (詧) (Please read the note on the back and fill out this page) 2397 to 2399, report The 3-substituted heteroaryl polythiophene was prepared by chemical polymerization using 4 moles of ferric chloride in a gas imitation at 50 ° C, with slow removal by dry air. Pomerantz et al., 1991 Years in Synthetic Metals, 41st | 43nd, pp. 825-830, reported the preparation of 5-conducting (3-alkylthiophene), using anhydrous ferric chloride in chloroform, and in the dry air in the reaction mixture In the case of a bubble, however, a polymer, for example, a pentacyclic heterocyclic compound containing an atom of an oxygen or a nitrogen group element, is electropolymerized conventionally under the cover of an inert gas, see, for example, JP 59-210947 , and Zhang et al., 2001, 1 〇 Solid State Electrochemistry, Vol. 5, pp. 74-79. For conductive polymers that have been prepared and studied to date, the general disadvantage is that Application, conductivity is still too low, it is visible The transmittance is insufficient, the stability to exposure to visible light and ultraviolet light is too low, and/or it cannot be processed. 15 OBJECTS OF THE INVENTION Therefore, the aspect of the present invention provides a polyporphyrin or thiophene copolymer which has high conductivity and high Visible light transmittance, high stability to exposure to visible light and ultraviolet light, and good workability. Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Beigong ff Co., Ltd. 2 其他 Other aspects and advantages of the present invention will be described below. The invention is summarized. * Polymerization of polythiophene, traditionally in the presence of air, even in the case of air bubbling in the reaction mixture, surprisingly found that 91. 3. 2,000 paper scales for China National Standard (CNS) A4 Specification (210 X 297 gong*> 1299738 A7 V. INSTRUCTION DESCRIPTION (Polythiophene or thiophene copolymer polymerized in a chemically or reductive manner, in the presence of polyanions such as poly(styrene) It is carried out in water steepness in an inert gas atmosphere, so that less than 3 mg of oxonium per liter of reaction medium is polymerized in the presence of digas. The former has a greatly increased conductivity and improved stability. The method of the present invention can be used to prepare an aqueous or non-aqueous solution or dispersion of a polyphenol or a porphin copolymer. It contains the structural unit according to formula (1): Port 5 10 Ό - R Ding Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed in which R1 and R2 each independently represent hydrogen, or Cn alkyl group, or even 15 g Selectively replacing the C15_extension base residue, including the following step (4) phenanthrene or porphin copolymer, using an initiator in the presence of a polyanion in the reaction medium, under oxidation or reduction conditions And in an emotional environment such that when the initiator is added, less than 3 milligrams of oxygen per liter of reaction medium is present in the reaction medium. 2 〇 # The present invention may also utilize an aqueous or non-aqueous solution or dispersion of a poly-pheno- or sulfimene copolymer prepared by the previous lung method. The use of an aqueous or non-aqueous solution or a knife solution may also be provided by the user, including an aqueous solution or dispersion of the polyporphin or porphin copolymer disclosed above. ---------^9—' This paper size is a^iV(CNS)A4 specification (10) 297 mm) 91- 3. 2,000

經濟部智慧財產局貝工消f合作钍印製Ministry of Economic Affairs, Intellectual Property Bureau, Beigong, F, Cooperation, Printing

本紙張尺度適用中a國家棵率（CNS〉A4規格（21G x 297公爱） 1299738 一實現本發明層面亦可藉使用一種導電層，其製備使用 -種水性或非水性溶液或分散液，其包含前文揭示之聚嗔吩或噻吩共聚物之水性或非水性分散液。實現本發明層面亦可藉使用一種抗攀電層，其製備使用-種水性或非水性溶液或分散後，其包含一種聚嗔吩或噻吩共聚物之水性或非水性溶液或分散液。本發明之其他層面揭示於申請專利範圍之附屬項目中。、發明詳述定義This paper scale is applicable to the country a country rate (CNS>A4 specification (21G x 297 public) 1299738. The implementation of the invention may also use a conductive layer prepared by using an aqueous or non-aqueous solution or dispersion. An aqueous or non-aqueous dispersion comprising the polyporphin or thiophene copolymer disclosed above. The layer of the invention may also be implemented by using an anti-climbing layer, which is prepared by using an aqueous or non-aqueous solution or dispersion, which comprises a An aqueous or non-aqueous solution or dispersion of a polyporphin or thiophene copolymer. Other aspects of the invention are disclosed in the accompanying items of the scope of the patent application.

Ci·5·伸烷基團一詞代表甲烯、it乙烯、i，3_丙烯、丨，‘ 丁浠與1，5-戊烯基團。引發劑一詞意指能引發聚合反應之物類。烷基一詞意指於烷基基團中每個碳原子之所有可能的變化，亦即對於三個碳原子為：正丙基與異丙基，對於四個碳原子為：正丁基、異丁基與第三丁基，對於五個碳原子為：正戊基、U-二甲基_丙基、2,2_二甲基_丙基與2_甲基_丁美等。 . 土對於本發明，水性一詞意指包含至少60體積。/❶之水，以至少體積％之水為較佳，與選擇地包含可水溶混之有 91· 3· 2,000The term Ci.5.alkylene group represents methylene, it ethylene, i,3-propene, anthracene, 'butanthene and 1,5-pentenyl group. The term initiator refers to a species that initiates a polymerization reaction. The term alkyl refers to all possible variations of each carbon atom in the alkyl group, ie for three carbon atoms: n-propyl and isopropyl, for four carbon atoms: n-butyl, Isobutyl and tert-butyl, for five carbon atoms: n-pentyl, U-dimethyl-propyl, 2,2-dimethyl-propyl and 2-methyl-butyl. Soil For the purposes of the present invention, the term aqueous is meant to include at least 60 volumes. / ❶ water, preferably at least 5% by volume of water, and optionally containing water-soluble mixture 91·3· 2,000

I —II · 11 (琦先Μ讀背面之注意事項再填寫本頁0 tr--------- 1299738 A7I —II · 11 (Notes on the back of Qi first read this page again tr tr--------- 1299738 A7

發明說明（7) 機溶劑，如：醇類，例如：甲醇、乙醇、2_丙醇醇、辛醇、十六醇等，二醇類，例如：乙二醇、二j 甲基σ比洛烧_、甲氧其石π 油 Ν’ 丁酮等。丙每，以及嗣類’例如：2-丙鋼與2- 5 10 其囿“聚f基非水性溶劑”―詞意指—種具有至少兩個經基基團之非水性溶劑。 ==本發明之共沸物一詞’或者習知為共沸混合 “包含兩種或多種液體之溶液’魅成於蒸會改變。用於揭不本發明之導電層一詞，同時包括導電塗覆物與抗靜電層？導電性一詞意指具有低於1〇ί歐姆/正方之表面電阻。抗靜電一詞意指具有於範圍1〇6至1〇"歐姆/正方之表面電阻，亦即其無法用作電極。 15 ‘‘增進導電性”一詞意指一種可增進導電性之方法，例經濟部智慧財產局貝 X 消费合作社印製如·藉與兩沸點液體接觸，如：二_或多元羥基_與/或羧基基團，或包含有機化合物之醯胺或内醯胺基團，隨後選擇地於高溫加熱，以於100與25〇。〇之間為較佳，以進行丨至 90秒為較佳，而使導電性增強。另外對於介電常數^ 15 20 之質子惰性化合物之案例，如：N-甲基吡咯烷酮，可使用低於loot：之溫度。由聚噻吩可觀察到此種導電性之增強’而且可於製備最外層時或其後發生。此種處理所使用之液體，以如EP-A 686662與EP-A 1003179所揭示之N-甲基吡咯烷酮與二乙二醇為最佳。 9 本紙張尺度適用中國國家標羊（CNS)A4規格（21〇 X 297公发） 91. 3. 2,000 1299738 吩） A7 五、發明說明（汉）用於本發明之PEDOT代表聚（3,‘乙烯基二氧基噻 5 稀酉旨）用於本發明之EDOT代表3,4_乙烯基二氧基噻吩。用於本發明之ADOT代表3,4-伸烷基二氧基噻吩。用於本發明之PSS代表聚（苯乙烯磺酸）或聚（磺酸苯乙 10 用於本發明之PET代表聚（對苯二甲酸乙二醇酯）。備聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之方法貫現本發門層面可使用一種製備聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之方法，其包含依式⑴之結構單元：製 (請先閱讀背面之注意事項再填寫本頁) 裝 15 R1-_^0—R1" n I n n 一睿 d n ι ί ί n n I - 絰濟部智慧財產局貝工消f合作社印製 ο 2 其中R1與R2各自獨立地代表氫、或（^ ^烷基棊團、或連同生成一種選擇地取代之伸烷基殘餘物，包括下述步驟：製備聚噻吩或噻吩共聚物時，在25°C與大氣壓力下，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件及於惰性環境中進行，使得當添加該引發劑後，反應介質中每公升反應介質存在少於3毫克之氧。 91· 3. 2.000 1299738 A7 5 10 15 經濟部智慧財產局貝工消费合作社印製 20 發明說明（7) 依本發明方法之第一個實例，包括下列步驟：製備聚噻吩或喧吩共聚物時，在坑與大氣壓力下，於存在有聚陰離子之反應介質中使用—種引發劑，在氧化或還原之條件及於惰性ί讀巾進行，使得#添加該引質中每公升反應介質存在少於15毫克之氧。反應” 依照本發明方法之第二個實例，包括下列步驟噻吩或嗔吩共聚物時，在坑與大氣壓力下，於聚陰離子之反應介料❹—種弓丨㈣，在氧化或還原之條件及於惰性環境巾進行，使得#添加該引質中每公升反應介質存在少於0.5毫克之氧。反應"貝中氧之浪度可使用任何方法予以調節，例如術、延長惰性氣體，如:氬氣、氮氣或氦氣，於反應介質中之冒泡時間、在惰性氣體之掩蓋下，於一具有 ΐΐϊ的反應中消耗氧氣，較佳者為將惰性氣體於反應介 ’直至完成聚合反應，因此可將反應介質中之氧展度、准持於母公升反應介質存在少於3毫克之氧。 …:照，發明方法之第三個實例’惰性環境為於氣氣、氦氣或氩氣之環境。之二月方法之第四個實例，(3,4-二烧氧基嗜吩) 聚口物或/、聚物對於溶液或分散液中聚陰離子之率為於1:0.95至1:6.5之範圍。之月方法之第五個實例，(3,4-二院氡基喧吩) 2來合物或共聚物對於溶液或分散液中聚陰離子之重量比率為於1:1·8至ι··6·4之範圍。 -----------^ ill----訂.-------- (請先閲讀背面之注意事項再填寫本頁) 本紙度適用中F國家標箏 91. 3 11 1299738 五、發明說明（丨D ) 依照本發明方法之第六個實例，（3,4-二烷氧基噻吩）之聚合物或共聚物對於溶液或分散液中聚陰離子之重量比率為於1:3·0至1:6·4之範圍。 5 10 依照本發明方法之第七個實例，依式⑴之結構單元為選自群組包括：選擇地烷氧基基團取代之3,‘伸甲基二氧基喧吩單元、選擇地烷基或芳基基團取代之3,4-伸乙基二氧棊嗔吩單元，選擇地烷基或芳基基團取代之3,‘伸乙基二氧基噻吩單元，一種依照式（I)之單元，其中R2同為1，2-環己烯基團、選擇地娱;基或芳基基團取代之3,4_伸丙基二氧基噻吩單元、選擇地烧基或芳基基團取代之3,4_ 伸丁基二氧基嗔吩單元，與選擇地烧基或芳基基團取代之 3，4-伸戊基二氧基嗤吩單元。依照本發明方法之第八個實例，噻吩共聚物為至少一種於25°C時水中溶解度低於2.2公克/公升之3,4-伸烷基二 15 氧噻吩化合物，與至少一種於25°C時水中溶解度至少為 2·2公克/公升之3,4-伸烷基二氧噻吩化合物，以及一種聚陰離子，之共聚物。請先闓讀背面之注意事項再填寫本頁(7) Machine solvents, such as: alcohols, such as: methanol, ethanol, 2-propanol, octanol, cetyl alcohol, etc., glycols, such as: ethylene glycol, di-j-methyl σ bilol Burning _, methicillin π oil Ν 'butanone and the like. C, and hydrazines such as 2-propene steel and 2- 5 10 囿 "polyf-based non-aqueous solvent" - the word means a non-aqueous solvent having at least two radicals. == The term azeotrope of the present invention 'or conventionally azeotropically mixed "a solution containing two or more liquids" is changed in steaming. It is used to uncover the term "conductive layer of the present invention" and includes conductive Coating and antistatic layer? The term "electrical conductivity" means having a surface resistance of less than 1 欧姆 ohm / square. The term antistatic means having a surface resistance of 1 〇 6 to 1 〇 ohms / square , that is, it cannot be used as an electrode. 15 ''Enhanced conductivity' means a method that enhances conductivity. For example, the Ministry of Economic Affairs, the Intellectual Property Bureau, X Consumers Co., Ltd. prints such as by contact with two boiling liquids, such as : Di- or polyhydric hydroxy- and/or carboxyl groups, or decyl or decylamine groups comprising an organic compound, which are subsequently selectively heated at elevated temperatures to 100 and 25 Torr. Preferably, it is preferred to carry out the crucible to 90 seconds, and the conductivity is enhanced. In addition, for the case of an aprotic compound having a dielectric constant of 15 20 , such as N-methylpyrrolidone, a temperature lower than the loot: can be used. This increase in conductivity can be observed from the polythiophene and can occur at or after the preparation of the outermost layer. The liquids used in such a treatment are preferably N-methylpyrrolidone and diethylene glycol as disclosed in EP-A 686 662 and EP-A 1003179. 9 This paper scale applies to China National Standard Sheep (CNS) A4 specification (21〇X 297 public hair) 91. 3. 2,000 1299738 指) A7 V. Invention Description (Han) PEDOT representative for the present invention (3, ' Vinyldioxythiazide 5) The EDOT used in the present invention represents 3,4-vinyldioxythiophene. The ADOT used in the present invention represents 3,4-alkylenedioxythiophene. The PSS used in the present invention represents poly(styrenesulfonic acid) or poly(sulfonic acid phenylethyl 10. The PET used in the present invention represents poly(ethylene terephthalate). The water of the prepared polythiophene or thiophene copolymer Or a method of non-aqueous solution or dispersion. A method of preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer comprising a structural unit according to formula (1): Read the notes on the back and fill out this page) Install 15 R1-_^0—R1" n I nn I Rui dn ι ί ί nn I - Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Beigong F. Co., Ltd. ο 2 where R1 and R2 each independently represents hydrogen, or (^^alkyl group, or together with the formation of a selectively substituted alkyl residue, comprising the steps of: preparing a polythiophene or thiophene copolymer at 25 ° C and atmospheric pressure Under the force, an initiator is used in the reaction medium in which the polyanion is present, and is carried out under the conditions of oxidation or reduction and in an inert environment, so that when the initiator is added, less than 3 mg per liter of the reaction medium exists in the reaction medium. Oxygen. 91· 3. 2.000 1299738 A7 5 10 15 Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed 20 Inventive Note (7) According to the first example of the method of the present invention, the following steps are included: when preparing a polythiophene or a porphin copolymer, in a pit At atmospheric pressure, an initiator is used in the reaction medium in which the polyanion is present, and is carried out under conditions of oxidation or reduction and in an inert paper towel, so that the addition of the element has less than 15 mg per liter of the reaction medium. Oxygen. Reaction" According to a second example of the process of the present invention, including the following steps of thiophene or porphin copolymer, in the pit and atmospheric pressure, in the reaction of the polyanion 介-species 丨 (4), in oxidation or reduction The conditions are carried out in an inert environment towel such that #Addition of the primer contains less than 0.5 milligrams of oxygen per liter of reaction medium. Reactions"The oxygen in the shell can be adjusted by any method, such as surgery, prolonging the inert gas Such as: argon, nitrogen or helium, the bubbling time in the reaction medium, under the cover of inert gas, consumes oxygen in a helium reaction Preferably, the inert gas is passed through the reaction until the polymerization reaction is completed, so that the oxygen spread in the reaction medium can be less than 3 mg of oxygen present in the mother liter reaction medium. Three examples of 'inert atmospheres are in the atmosphere of gas, helium or argon. The fourth example of the February method, (3,4-di-oxygenated phenanthrene) agglomerates or /, polymers for The rate of polyanion in the solution or dispersion is in the range of 1:0.95 to 1:6.5. The fifth example of the monthly method, (3,4-dienyl fluorenyl porphin) 2 conjugate or copolymer The weight ratio of the polyanion in the solution or dispersion is in the range of 1:1·8 to ι··6·4. -----------^ ill----book.-------- (please read the notes on the back and then fill out this page) This paper applies to the F-country standard 91. 3 11 1299738 V. INSTRUCTION DESCRIPTION (丨D) According to a sixth example of the process of the invention, the weight ratio of the polymer or copolymer of (3,4-dialkoxythiophene) to the polyanion in the solution or dispersion is In the range of 1:3·0 to 1:6·4. 5 10 According to a seventh example of the method of the present invention, the structural unit according to formula (1) is selected from the group consisting of: a substituted alkoxy group substituted by 3, a methylenedioxythiophene unit, a selected alkane a 3,4-extended ethyldioxythiophene unit substituted with a aryl group or an aryl group, optionally substituted with an alkyl or aryl group, 3'-ethyldioxythiophene unit, one according to formula (I a unit wherein R 2 is a 1,2-cyclohexenyl group, optionally a 3,4 propyl propyl thiophene unit, a decyl or aryl group substituted with a aryl group or an aryl group; The group is substituted with a 3,4-butyl butyloxyphene unit, and a 3,4-exopentyloxy oxene unit substituted with a selective alkyl or aryl group. According to an eighth aspect of the process of the present invention, the thiophene copolymer is at least one 3,4-alkylalkyldioxythiophene compound having a solubility in water of less than 2.2 g/liter at 25 ° C, and at least one at 25 ° C A 3,4-alkylenedioxythiophene compound having a solubility in water of at least 2·2 g/liter, and a copolymer of a polyanion. Please read the back of the note first and then fill out this page.

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經濟部智慧財產局貝消 f 合作社印製 20 依照本發明方法之第九個實例，於25°C時水中溶解度至少為2.2公克/公升之3,4-伸烷基二氧噻吩化合物，其係選自群組包括：3,4-二氫-2H-噻嗯基[3,4-b]{l，4]二π号英 (di〇xin)-2-基·甲醇、3,4-二氫-2H-噻嗯基[3,4-b][l，4]二今呼 (dioxepip)-3-醇、（2,3-二氩-σ塞嗯基[3,4-b][l，4]二喝英-2-基-甲氧基）-乙酸乙酯、（2,3-二氫-噻嗯基[3,4·b][l,4]二呤英-2-基-曱氧基）·乙酸、2-{2-[2_(2-甲氧基-乙醯氧基）_乙醯氧基] 12 本紙張尺度適用中國國家標半（CNS)A4规格（21〇 x 297公发） 3. 2,000 1299738 A7 B7Ministry of Economic Affairs, Intellectual Property Bureau, Beifa, Co., Ltd. Printing 20 According to the ninth example of the method of the present invention, a 3,4-alkylenedioxythiophene compound having a solubility in water of at least 2.2 g/liter at 25 ° C Selected from the group consisting of: 3,4-dihydro-2H-thienyl [3,4-b]{l,4]diπxin-2-yl·methanol, 3,4- Dihydro-2H-thingyl[3,4-b][l,4]dijinepip-3-ol, (2,3-di-argon-σ syl-[3,4-b] [l,4]diethyl-2-yl-methoxy)-acetic acid, (2,3-dihydro-thienyl [3,4·b][l,4]dioxin-2 -yl-decyloxy)-acetic acid, 2-{2-[2_(2-methoxy-acetoxy)-ethoxycarbonyl] 12 This paper scale applies to China National Standard Half (CNS) A4 specification ( 21〇x 297 mil) 3. 2,000 1299738 A7 B7

五、發明說明（// ) -乙氧甲基卜2 5 10 15 絰濟部智慧財產局8工消f合作社印製 20 一匕一氫-噻嗯基[3,4-b][l，4]二啐英與4-(2,3_ 喧嗯基[3,4频1，4]:$英_2_基_甲氧基)_丁烧鈉鹽。氧化劑用於吼略之氧化性聚合反應者，例如：欽述於美國化子子會期刊’第85冊，第454至458頁⑽3年):與 4合物科學期刊，部份A，聚合物化學，第26冊，第⑶7 至1294頁（1988年），可使用於噻吩之氧化性聚合反應。依知、本發明方法之第十個實例，聚合反應為氡化性，其用以引發聚合反應之價廉並且容易獲得之氧化劑，係遷自群組包括：鐵（ΙΠ)鹽類，例如··氧化鐵、有機酸之鐵（ΙΠ) 孤颏例如·Fe(0Ts)3、過氧化氫、重鉻酸鉀、鹼金屬與邁硫酸銨、鹼金屬之過硼酸鹽與高錳酸鉀。 ^理論上噻吩之氧化性聚合反應，每莫耳具式（I)之噻吩需要2.25當量之氧化劑[參見如：聚合物科學期刊，部份 A，聚合物化學，第26冊，第1287至1294頁年）]，貫際上每個可聚合之單元，使用過量〇1至2當量之氧化劑。使用過硫酸鹽與鐵（ΙΠ)鹽類具有甚大技術上之優點，其不會造成腐钕。此外，在特殊添加物之存在下，依式⑴ 嗔％化合物之氧化性聚合反應進行甚為緩慢，以致喧吩與氧化劑可相互生成一種溶液或糊狀物，並可加至待處理之基質上。將此溶液或糊狀物加妥後，可將塗覆基質加熱以加速氧化性聚合反應，如US 6,001，281與WO 00/14139所揭示，將其併入本文供參考。還原性聚合反應可使用Stille(有機錫）途徑或 13 請先閲讀背面之注意事項再填寫本頁裝 I I 訂本紙張尺度適用中國國家標半（CNS)A4規格（210 X 297公龙） 91. 3. 2,000 1299738 Α7V. Description of the invention (// ) - Ethoxymethyl b 2 5 10 15 Ministry of Finance, Intellectual Property Bureau, 8 Workers, F, Co., Ltd. Printed 20 匕氢-hydrogen-thiol [3,4-b][l, 4] Dioxin and 4-(2,3_ 喧基 [3,4 rib 1,4]: $英_2_基_methoxy)-butylate sodium salt. The oxidizing agent is used for the oxidative polymerization of the sulphur, for example, as described in the Journal of the American Society of Affinity, Vol. 85, pp. 454-458 (10), 3 years): Journal of Science and Technology, Part A, Polymer Chemistry, Vol. 26, pp. (3) 7 to 1294 (1988), can be used for the oxidative polymerization of thiophenes. According to the tenth example of the method of the present invention, the polymerization reaction is deuteration, and the oxidant which is used for initiating the polymerization reaction and which is easy to obtain is excreted from the group including iron (ΙΠ) salts, for example. Iron oxide, iron of organic acid (ΙΠ), such as · Fe(0Ts)3, hydrogen peroxide, potassium dichromate, alkali metal and ammonium sulfate, alkali metal perborate and potassium permanganate. ^ Theoretically, the oxidative polymerization of thiophene requires 2.25 equivalents of oxidant per mole of thiophene of formula (I) [see eg, Journal of Polymer Science, Part A, Polymer Chemistry, Book 26, pages 1287 to 1294). Page year)], Continually use 1 to 2 equivalents of oxidant per polymerizable unit. The use of persulfate and iron (strontium) salts has the technical advantage that it does not cause corrosion. In addition, in the presence of a special additive, the oxidative polymerization of the compound of formula (1) 嗔% is carried out very slowly, so that the porphin and the oxidant can form a solution or paste with each other and can be added to the substrate to be treated. . After the solution or paste is added, the coated substrate can be heated to accelerate the oxidative polymerization, as disclosed in U.S. Patent No. 6,001,281, the disclosure of which is incorporated herein by reference. Reductive polymerization can be carried out using the Stille (Organic Tin) route or 13. Please read the notes on the back and fill out this page. II. The paper size is applicable to the China National Standard Half (CNS) A4 specification (210 X 297 male dragon). 3. 2,000 1299738 Α7

五、發明說明（〖I ) Suzuki(有機硼）途徑進行，其分別揭示於2〇〇1年之四面體報導，第42冊，第155至1S7頁，與1998年之大分子，第31冊，第2047至2〇56頁，或使用鎳錯合物，揭示於如：1999年之曰本化學學會期刊，第72冊，第62ι頁，以$ 及1998年之南級材料，第冊，第93至116頁依照本發明方法之第十一個實例，此方法另外包括下i 列步驟：⑴將至少一種非水性溶劑與包含依式⑴結構單元之之來噻吩或耆吩共聚物之水性分散液相混合;與⑴）將步驟製得混合物中之水蒸發，^其水含量至少減少65重里/。，較佳者為至少有一種添加之非水性溶劑無法與水生成/、’弗物，較佳者為另外至少有一種添加之非水性溶劑可與水生成共沸物，此可使水蒸發更加迅速，而且當含水量大幅減少後，其添加有利於立即加速降低殘餘之含水量。 4醇、異丙醇、正丙醇、正丁醇、第二丁醇、甲基異丁基酮、乙酸乙酯等，皆為能與水生成二元共沸物之有機液體之實例，例如：正丁醇可容易地使含水量降至低於5重量 % 〇 5 10 15 先閲讀背面之注意事項再填寫本頁裝 I I 訂經濟部智慧財產局興工消費合作社印焚 ο 2 通吊依本發明方法中，水可被移除之程度決定於水能穿越分散液擴散至表面之能力，其取決於在蒸發條件下，聚噻吩或噻吩共聚物/聚陰離子之黏度，然而聚噻吩或噻吩共聚物/聚陰離子分散液之黏度，主要決定於聚嗔吩或嗔吩共聚物/聚陰離子於最終分散液中之含量。對於·0·8重量0/0 PED0T/PSS，及PEDOT對PSS重量比率為1:2.4之分散液，其含水量可容易地達到1至5重量❶/〇,但是僅增加本紙張尺度邮中函國家棵準（CNS)A4規格⑽< 297公爱） 91. 3. 2,000 1299738 A7 五、發明說明（丨彡）PEDOT對PSS重量比率為丨：2 4之pED〇T/pss丨〇重量 °/〇，對分散液黏度即具有強烈的影響，而使其容易地可達成之含水量，增加為丨〇至丨5重量％。進行蒸餾之溫度以於80〇C或低於8〇〇c之溫度為較，，以於70它或低於70它為最佳。已發現於88至89t之1度進行蒸餾獲得之聚噻吩或噻吩共聚物/聚陰離子分散液，在處理成-種網印糊狀物後，可得到具有明顯較高表面電阻之印刷物。應私月依本發明方法獲得之聚噻吩或噻吩共聚物/聚陰離子分散液’在大氣環境下儲存時，其㈣性十分安定。依照本發明方法之第十二個貪例，此方法另外包括下列步驟.（1)將至少-種非水性溶劑與包含依式⑴結構單元之聚嗔吩或喧吩共聚物之水性分散液相混合；與⑼將步驟⑴製得混合物中之水蒸發，直至其水含量至少減少70重量〇/〇。 . ㈣本發明方法之第十三個實例，此方法另外包括下列步驟：⑴將至少-種非水性溶劑與3,4_二烧氧基嗜吩之聚合物或共聚物之水性分散液與聚陰離子相混合；與⑻將步，⑴製得混合物中之水蒸發，直至其水含量至少減少 20 重量％。依照本發明方法之第十四個實例，此方法另外包括下列步驟.（1)將至少-種非水性溶劑與包含依式⑴結構單先之聚嗟吩或嗔吩共聚物之水性分散液相混合;與⑼將步驟 ⑴裝得混合物中之水蒸發’直至其水含量至少減少90重 5 10 15 15 本紙JlT尺度制t B料财（CNS)A4祕（ϋ97公 91. 3. 2t000 (锖先閲讀背面之注意事項再填寫本頁) ^--------t--- %, 1299738 經濟部智慧財產局員工消费合作社印製 ο 2 A7 五、發明說明— 量〇/〇〇依照本發明方法之第十五個實例，此方法另外包括下 J二驟.（1)將至少一種非水性溶劑與包含依式⑴結構單元 5 基吩或喧吩共聚物之水性分散液相混合；與（ii)將步驟 ^製得混合物中之水蒸發，直至其水含量至少減少95重 Ϊ % 〇依照本發明方法之第十六個實例，此方法另外包括下 J ^驟.（1)將至少一種非水性溶劑與包含依式⑴結構單元 10 塞吩或4吩共聚物之水性分散液相混合;與（ii)將步驟 (Ο製得混合物中之水蒸發，直至其水含量至少減少9 量％。依妝本發明方法冬第十七個實例，此方法另外包括下 ^驟.（1)將至少一種非水性溶劑與包含依式⑴結構單元之♦塞力或噻吩共聚物之水性分散液相混合；與⑴）將步驟 15 (丄)。製得混合物中之水蒸發，直至其水含量至少減少65重里％，而且其中非水性溶劑與水生成一種共沸混合物，此使水更迅速地蒸發。正丁醇為此種非水性溶劑之實例，可容易地使含水量降至低於5重量0/〇。氧濃度可使用Knick程序單元73氧予以測定，令 InPro _〇系列氧偵測器，由㈣此τ〇ι—公司提供些谓測器係基於-種極譜之氧測定，Clark極譜債測录本上包括一只工作電極（陰極），一只反/參考電極（陽極 ------------·丨 i------tr--------- (請先閲讀背面之注意事項再填寫本頁) 16 1299738 A7 B7 15 五、發明說明（A) 與一可滲透氧之薄膜，以其將電極與介質分離。供應陰極固定極化電壓之發送器需要還原氧，移動穿越薄膜之氧分子即於陰極被還原，肉時，於暢極進行氧化，氧化後之陽極金屬（銀）被釋放至電解質中，電解質閉合陽極與陰極間 5 之電路（離子傳導）。以此方法產生之電流藉發送器測定，其與在樣品介質中之氧氣（氧分子）分壓成正比。水性之6重量％聚（苯乙烯磺酸）水溶液中之氧含量，以此技術測定為6.5毫克/公升。一種聚（苯乙烯磺酸）溶液（於25T：與1013 hPa(毫巴) 1〇下，藉將氧氣於其中冒泡，以氧予以飽和，其具有38.45 毫克/公升之氧含量，此數值可視為於25°C與1013 hPa(亳巴）下，氧氣於聚（苯乙烯磺酸）溶液之最大溶解度。依式（I)之結構單元相對於依式（I)結構單元之噻吩單體 (請先闓讀背面之注意事項再填寫本頁) 裝---— 訂--------- R-0、V. INSTRUCTIONS INSTRUCTIONS (I) Suzuki (Organic Boron) Pathway, which is disclosed in the Tetrahedron Report of 2, 1 year, Volume 42, pages 155 to 1S7, and the 1998 Macromolecule, Book 31 , pages 2047 to 2, p. 56, or the use of nickel complexes, as disclosed in, for example, the Journal of the Institute of Chemistry, 1999, 72nd, 62d, with $ and 1998 Southern Materials, Volume 1, Paragraphs 93 to 116 According to an eleventh example of the process of the present invention, the process additionally comprises the following steps: (1) water-based at least one non-aqueous solvent and a thiophene or porphin copolymer comprising a structural unit of formula (1) Dispersing the liquid phase to mix; and (1)) evaporating the water in the mixture obtained in the step, and reducing the water content by at least 65 cc. Preferably, at least one of the added non-aqueous solvents is incapable of forming an azeotrope with water with water, or a non-aqueous solvent, preferably at least one additional non-aqueous solvent, which allows the water to evaporate more It is rapid, and when the water content is drastically reduced, its addition facilitates an immediate acceleration to reduce the residual moisture content. 4 alcohol, isopropanol, n-propanol, n-butanol, second butanol, methyl isobutyl ketone, ethyl acetate, etc., are all examples of organic liquids capable of forming a binary azeotrope with water, for example : n-butanol can easily reduce the water content to less than 5% by weight 〇5 10 15 First read the back of the precautions and then fill out this page to install II. Ministry of Economic Affairs Intellectual Property Bureau Xinggong Consumer Cooperatives Printing and Burning ο 2 In the method of the invention, the extent to which water can be removed is determined by the ability of water to diffuse through the dispersion to the surface, depending on the viscosity of the polythiophene or thiophene copolymer/polyanion under evaporation conditions, whereas polythiophene or thiophene copolymerization The viscosity of the material/polyanion dispersion is mainly determined by the content of the polybenzazole or porphin copolymer/polyanion in the final dispersion. For the dispersion of ·0·8 weight 0/0 PED0T/PSS, and PEDOT to PSS weight ratio of 1:2.4, the water content can easily reach 1 to 5 weight ❶ / 〇, but only increase the paper size in the mail Letter Country Green (CNS) A4 Specification (10) < 297 Public Love) 91. 3. 2,000 1299738 A7 V. Invention Description (丨彡) PEDOT vs. PSS Weight Ratio: 4 2 4 pED 〇 T / pss 丨〇 Weight ° /〇, has a strong influence on the viscosity of the dispersion, and makes it easy to achieve the water content, increasing to 丨 to 5% by weight. The temperature at which the distillation is carried out is at a temperature of 80 ° C or lower, preferably 70 or less. It has been found that a polythiophene or thiophene copolymer/polyanion dispersion obtained by distillation at a temperature of from 88 to 89 t, after being processed into a screen printing paste, can obtain a printed matter having a significantly higher surface resistance. When the polythiophene or thiophene copolymer/polyanion dispersion obtained by the method of the present invention is stored in an atmospheric environment, its (iv) property is very stable. According to the twelfth method of the method of the present invention, the method further comprises the following steps: (1) an aqueous dispersion liquid of at least one non-aqueous solvent and a polyporphin or porphin copolymer comprising a structural unit of the formula (1) Mixing; and (9) evaporating the water in the mixture obtained in the step (1) until the water content thereof is reduced by at least 70% 〇/〇. (d) A thirteenth example of the method of the present invention, the method further comprising the steps of: (1) dispersing at least a non-aqueous solvent with an aqueous dispersion of a polymer or copolymer of 3,4-dioxaoxyphene The anion phase is mixed; and (8) the step, (1) the water in the mixture is evaporated until its water content is reduced by at least 20% by weight. According to a fourteenth example of the method of the present invention, the method further comprises the following steps: (1) dispersing at least one non-aqueous solvent with an aqueous dispersion liquid comprising a poly(porphin) or porphin copolymer of the formula (1) Mixing; and (9) evaporating the water in the mixture prepared in step (1) until its water content is reduced by at least 90 weights 5 10 15 15 The paper JlT scale system t B material (CNS) A4 secret (ϋ97 public 91. 3. 2t000 (锖Read the notes on the back and fill out this page.) ^--------t--- %, 1299738 Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives ο 2 A7 V. Description of the Invention - Quantities / 〇〇 According to a fifteenth example of the method of the present invention, the method additionally comprises the following step: (1) mixing at least one non-aqueous solvent with an aqueous dispersion liquid comprising a phenanthrene or porphin copolymer of the structural unit (1) And (ii) evaporating the water in the mixture prepared in step 2 until the water content thereof is reduced by at least 95% by weight. 〇 In accordance with the sixteenth example of the method of the present invention, the method additionally includes the following step (1). Having at least one non-aqueous solvent with a thiophene or a phenanthene containing a structural unit of formula (1) The aqueous dispersion of the mixture is mixed; and (ii) the step (the water in the mixture is evaporated until the water content thereof is reduced by at least 9% by weight. According to the seventeenth example of the method of the present invention, the method additionally includes (1) mixing at least one non-aqueous solvent with an aqueous dispersion liquid comprising a keel or thiophene copolymer according to the structural unit of formula (1); and (1)) preparing step 15 (丄). The water evaporates until its water content is reduced by at least 65% by weight, and wherein the non-aqueous solvent forms an azeotropic mixture with water, which causes the water to evaporate more rapidly. n-butanol is an example of such a non-aqueous solvent, which can be easily The water content is reduced to less than 5 wt%/〇. The oxygen concentration can be determined using the Knick program unit 73 oxygen, so that the InPro _〇 series oxygen detectors are provided by (d) this τ〇ι—the company is based on - Polarographic oxygen measurement, Clark polarographic record book includes a working electrode (cathode), a counter / reference electrode (anode ------------ 丨 i--- ---tr--------- (Please read the notes on the back and fill out this page) 16 1299738 A7 B7 15 V. Description of the invention (A) with a membrane permeable to oxygen, which separates the electrode from the medium. The transmitter that supplies the fixed polarization of the cathode needs to reduce oxygen, and the oxygen molecules moving through the membrane are reduced at the cathode. At the time, the oxidation is performed, the oxidized anode metal (silver) is released into the electrolyte, and the electrolyte closes the circuit between the anode and the cathode (ion conduction). The current generated by the method is measured by the transmitter, and The oxygen (oxygen molecule) in the sample medium was proportional to the partial pressure. The oxygen content in the aqueous 6 wt% poly(styrenesulfonic acid) aqueous solution was determined by this technique to be 6.5 mg/liter. A poly(styrenesulfonic acid) solution (at 25T: and 1013 hPa (millibar) 1 Torr, by which oxygen is bubbled and saturated with oxygen, which has an oxygen content of 38.45 mg / liter, this value can be seen The maximum solubility of oxygen in a poly(styrenesulfonic acid) solution at 25 ° C and 1013 hPa (。巴). The structural unit of formula (I) relative to the thiophene monomer of the structural unit of formula (I) Please read the notes on the back and fill out this page. Pack---- Order--------- R-0,

Ο—R 經濟部智«財產局貝工消費合作社印31 20 (工）其中R1與R2各自獨立地代表氫、或Cw-烷基基團、或連同生成一種選擇地取代之伸烷基殘餘物，依本發明之式（I)噻吩化合物，其可藉習知方法製備，如：醚轉化反應，揭示於 DE 3804522，及於 HOUBENWEYL，第 VI/3 17 本紙張尺度適用中國國家楳半（CNS)A4規格（210 X 297公* ) 91. 3. 2,000 1299738 A7 五、發明說明（丨心）冊，部份3，第m至173頁（1971年），使用一種噻吩衍生物，例如：3,4-二曱氧基噻吩，或藉雙WilUams〇n反應，其於 1994 年揭示於 Electrochimica Acta，第 39 冊，第 1345 至1347頁，使用一種σ愈吩衍生物，例如：3,4-二羥基噻吩 -2,5 «竣酸之二甲g旨。 5 10 15 經濟部智慧財產局貝工消费合作社印製 20 聚陰離子可用於依照本發明分散液中之聚陰離子化合物，揭示於EP-A 440957，其包括：聚合乏羧酸，如：聚丙烯酸、聚甲基丙烯酸、或聚馬來酸與聚磺酸，例如：聚（苯亡烯碎酸）。這些聚羧酸與聚磺酸亦可為乙烯基羧酸與乙烯基磺酸與其他可聚合單體，如：丙烯酸酯、甲基丙烯酸酯與苯乙烯，所生成之共聚物。依照本發明方法之第十八個實例，聚陰離子為聚（苯乙稀石黃酸）。非水性溶劑依照本發明方法之第十九個實例，此方法另外包括下列步驟：（i)將至少一種非水性溶劑與包含依式⑴結構單元之聚噻吩或噻吩丼聚物之水性分散液相混合；與（丨丨)將步驟 (^。製得混合物中之水蒸4，直至其水含量至少減少、65重 :/〇而其中之非水性溶劑係選自群組包括：醇類、酮類、芳烯類、酯類、醚類，與其混合物。依照本發明方法之第二十個實例，此方法另外包括下 (锖先閲讀背面之注意事項再填寫本頁) ^ i -------^--------- 91. 3. 2,000 [299738 經濟部贊慧財產局員工消f合作社印» 五、發明說明（/y) 歹J二驟.（1)將至少一種非水性溶劑與包含依式⑴結構單元之：“或噻吩共聚物之水性分散液相混合;與⑼將步驟 (丄)f得混合物中之水蒸發，直至其水含量至少減少65重而/、中之非水性溶劑為一種二醇醚或一種環狀醚，如：四氫呋喃。依^本發明方法之第二十一個實例，此方法另外包括 -二驟.（1)將|少_種非水性溶劑與包含依式⑴結構單驟r、: ^或鳴吩共聚物之水性分散液相混合;與(ii)將步混合物中之水蒸發，直至其水含量至少減少65 里。’而其中之非水性溶劑為非水溶混。 =照本發明方法之第二十二個實例，此方法另外包括 _ v驟.⑴將至少—種非水性溶劑與包含依式⑴結構單吩或㈣絲物之水性分散液相混合;與（Π)將步 =丄：仔混合物中之水蒸發’直至其水含量至少減少65 溶^ Γ而其中至少—種非水性溶劑為一種聚經基非水性下列本I明方法之第二十三個實例，此方法另外包括 ^驟：⑴將至少—種非水聽触包含依式⑴結構單嗔吩共聚物之水性分散液相混合;與⑼將步驟（1)1侍混合物中之水蒗發重量。/。，而”於另外；、:丰至其水含量至少減少65 水性溶劑。外細作步驟中至少添加一種其他的非 :照本發明方法之第二十四個實例，此方法另外包括 v驟：ω將至少-種非水性溶劑與包含依式⑴結構單 ίο 15 20 本紙張尺度適用中準（CNS)A4規格（210 X 297公：*「 (請先閲讀背面之注意事項再填寫本頁) u· n n n n ΛΜΙ tn n JM，0 i n ί ί i —9 e_i« < 9L 3· 2,000 1299738 A7Ο—R Ministry of Economic Affairs «Property Bureau, Bayer Consumer Cooperatives, 31 20 (Working) where R1 and R2 each independently represent hydrogen, or a Cw-alkyl group, or together with a selectively substituted alkyl residue A thiophene compound of the formula (I) according to the present invention, which can be prepared by a conventional method, such as an ether conversion reaction, disclosed in DE 3804522, and in HOUBENWEYL, VI/3 17 paper scale applicable to the Chinese national half (CNS) ) A4 size (210 X 297 gong*) 91. 3. 2,000 1299738 A7 V. Description of invention (丨心), Part 3, pages m to 173 (1971), using a thiophene derivative, for example: 3 , 4-dimethoxy thiophene, or by the double WilUams 〇n reaction, which was disclosed in 1994 in Electrochimica Acta, Vol. 39, pp. 1345 to 1347, using a sigma-derived derivative, for example: 3,4- Dihydroxythiophene-2,5 «Dimethyl citrate. 5 10 15 Ministry of Economic Affairs, Intellectual Property Bureau, Bayer Consumers Co., Ltd. 20 Polyanions can be used in the polyanionic compounds in the dispersions according to the invention, as disclosed in EP-A 440 957, which comprises: polymeric carboxylic acids, such as polyacrylic acid, Polymethacrylic acid, or polymaleic acid and polysulfonic acid, for example: poly(benzalene). These polycarboxylic acids and polysulfonic acids may also be copolymers of vinyl carboxylic acid and vinyl sulfonic acid with other polymerizable monomers such as acrylate, methacrylate and styrene. According to an eighteenth example of the process of the invention, the polyanion is poly(phenylephedrine). Non-Aqueous Solvent According to a nineteenth example of the process of the present invention, the process additionally comprises the steps of: (i) at least one non-aqueous solvent and an aqueous dispersion liquid comprising a polythiophene or thiophene fluorene polymer having a structural unit of formula (1) Mixing; and (丨丨) the step (^. The water in the mixture is steamed 4 until its water content is at least reduced, 65 weight: /〇 and wherein the non-aqueous solvent is selected from the group consisting of: alcohols, ketones Classes, arylenes, esters, ethers, and mixtures thereof. According to the twentieth example of the method of the present invention, the method additionally includes the following (please read the back of the back sheet and fill in this page) ^ i ---- ---^--------- 91. 3. 2,000 [299738 Ministry of Economic Affairs, Zhanhui Property Bureau, staff elimination, cooperative printing] 5. Invention description (/y) 歹J two steps. (1) At least A non-aqueous solvent is mixed with an aqueous dispersion comprising a structural unit of formula (1): "or a thiophene copolymer; and (9) the water in the mixture obtained in step (丄) f is evaporated until the water content thereof is at least 65 weights/ The non-aqueous solvent is a glycol ether or a cyclic ether such as tetrahydrofuran. A twenty-first example of the inventive method, the method further comprising - two steps. (1) a non-aqueous solvent and an aqueous dispersion comprising a copolymer of the formula (1) Mixing; and (ii) evaporating the water in the step mixture until its water content is reduced by at least 65. 'While the non-aqueous solvent is non-aqueous miscible. = According to the twenty-second example of the method of the invention, The method further comprises the following steps: (1) mixing at least one non-aqueous solvent with an aqueous dispersion liquid comprising a monophene or (iv) structure of the formula (1); and evaporating the water in the mixture of the mixture with the (Π) Until the water content is reduced by at least 65, and at least one of the non-aqueous solvents is a poly-based non-aqueous. The following twenty-third examples of the method of the present invention, the method further comprises: (1) at least The non-aqueous hearing comprises an aqueous dispersion-mixing of the monothiophene copolymer according to the formula (1); and (9) the weight of the water in the mixture of the step (1) is 。, and "in addition; The water content is reduced by at least 65 aqueous solvents. At least one of the external fine steps is added. Non-invention: According to the twenty-fourth example of the method of the present invention, the method additionally includes v: ω will be at least a non-aqueous solvent and contains a structure of the formula (1). The paper size is applicable to the standard (CNS) A4. Specifications (210 X 297 s: * " (Please read the note on the back and fill out this page) u· nnnn ΛΜΙ tn n JM,0 in ί ί i —9 e_i« < 9L 3· 2,000 1299738 A7

四乳酸乙酯會引起凝膠的生成，故不適用，苄醇、糠醇與環己烷會產生相分離，故不適用。經濟部智慧財產局員工消费合作社印« 依照本發明方法之第二十五個實例，此方法另外包括 20下列步驟：⑴將至少一種非水性溶劑與包含依式（1)結構單疋之聚噻吩或噻吩共聚物之水性分散液相混合；與驟(二)〇製得混合物中之水蒸發，直至其水含量至·少減少幻重量％ ’而其t非水性溶劑係選自群組包括·仏丙二醇、丙一醇、二乙二醇、N-甲基吡咯烷酮、N，N_二甲基曱醯| 本紙張尺度瑱用中請)A4規格⑽x 297公度)_ 3. 2,000 經濟部智.«財產局員工消貸合作社印製 1299738 Α7 _ Β7 玉、發明說明（11) N-甲基乙醯胺、N，N-二申基乙醯胺、甘油、己二醇，與乙酸卡必醇自旨。結合劑 5 實現本發明層面亦可藉一種依本發明方法獲得之聚喧吩或嗔吩共聚物之水性或非水性溶液或分散液。依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之第一個實例，聚咳吩或嗔吩共聚物之水性或非水性溶液或分散液另外包含一種結合劑，此結合劑可將使 10 用依本發明組成物製得之抗靜電或導電層之成份結合在一起，而令載體之非平面結構能夠獲得較佳的塗覆，此結合劑亦可增加依本發明方法製得之組成物之黏度。依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之第二個實例，聚嗔吩或Π塞吩共聚物之水性或非 15 水性溶液或分散液另外包含一種聚酯胺基甲酸酯共聚物結合劑，如：BAYER 公司出品之 DISPERCOLL VPKA 8481。依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之第三個實例，聚喧吩或嗔吩共聚物之水性或非水性溶液或分散液另外包含一種結合劑，此結合劑係選自 20 群組包括：聚丙烯酸酯、羧基甲基纖維素、聚乙烯基吡咯烧酮、羥基丙基纖維素、具磺酸基團包含羧酸酯之共聚物、經羥基修飾之丙烯酸共聚物與聚（乙烯醇）。評估結合劑之適用性可將〇·1重量％之特殊結合劑加至依本發明包含PEDOT/PSS組成物之典型分散液介質本紙張尺度適用中國國家標準（CNS〉A4規格（21〇 χ 297公藿〉 91. 3. 2,000 (請先Μ讀背面之注意事項再填寫本頁) 裝 --訂-------- A7 1299738 B7___ 五、發明說明) 中，例如：87重量％ 1，2-丙二醇、9重量％二乙二醇、3重量％去離子水、0.5重量％ ZONYL® FSO，與0.5重量％矽酮消泡劑X50860A。一種結合劑，其溶解於此種分散液介質之程度達到0.1重量°/❶者，可視為適合用於依本發明之 5 組成物。特別適合之結合劑包括：結合劑01 = CARBOPOL⑧ETD-2623，一種與聚烯基聚醚相交聯之丙烯酸之均質-與共聚物，B· F. Goodrich公司出品； 1〇結合劑02 = CARBOPOL® Aqua 30，一種丙烯酸與丙烯酸乙酯共聚物之膠乳，B· F· Goodrich公司出品; 結合劑03 = AMBERGUM® 3021，一種羧基甲基纖維素， Hercules公司出品；結合劑04 = LUVISKOL⑧K30，一種聚乙烯基吡咯烷酮， 15 BASF公司出品；結合劑05 = —種羥基烷基纖維素甲基丙基醚，Shin-Etsu 化學公司出品；結合劑06 = KLUCEL® L，羥基丙基纖維素，Hercules公司出品； 2〇結合齊j 07 = NEOCRYL® BT24，一種以丙烯酸酯為基質之水性膠乳，Zenica公司出品；結合劑08 = AQUACER⑧503，一種以丙烯酸酯為·基質之水性膠乳，BYC Cera公司出品；結合劑09 = P0LYPH0BE⑧TR117, 一種以丙烯酸酯為基質 ^ 22 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閲讀背面之注意事項再填寫本頁) · n l n n n n ft 一 · ί 1 n n n n n t 0 經濟部智慧財產局貝工消费合作社印¾ 91. 3. 2,000 1299738 A7 _B7_ 五、發明說明（叫）之水性膠乳，Union Carbide公司出品；結合劑10 = AMOREX® CR2900，一種以丙烯酸酯為基質之水性膠乳，Westvaco公司出品； (請先《讀背面之注意事項再填寫本頁) 結合劑11 = CRX-8057-45，一種以丙烯酸酯為基質之水性 5 膠乳，Westvaco公司出品；結合劑12 = PRIMALtm EP-5380，一種54重量％以丙烯酸酯為基質之水性膠乳，H〇hm and Haas公司出口· 口口, 結合劑13 = JAGOTEX® KEM1020，一種58重量％以丙烯 10 …酸酯為基質之水性膠乳，Ernst Jager Chem·Ethyl tetraacetate causes the formation of a gel, so it is not suitable. Benzyl alcohol, decyl alcohol and cyclohexane are phase-separated, so it is not suitable. Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Printing « According to the twenty-fifth example of the method of the present invention, the method additionally comprises the following steps: (1) at least one non-aqueous solvent and a polythiophene comprising a monoterpene of the formula (1) Or the aqueous dispersion of the thiophene copolymer is mixed; the water in the mixture prepared with the bis(2) oxime is evaporated until the water content thereof is reduced by a minimum of %, and the non-aqueous solvent is selected from the group consisting of Propylene glycol, propanol, diethylene glycol, N-methylpyrrolidone, N,N-dimethylhydrazine | This paper size is used in the application) A4 size (10) x 297 cm)_ 3. 2,000 Ministry of Economic Affairs . «Property Bureau employee loan cooperative cooperative printed 1299738 Α7 _ Β7 jade, invention description (11) N-methyl acetamide, N, N-di- stilbene, glycerol, hexanediol, and acetic acid Alcohol is the purpose. Bonding Agent 5 An aqueous or non-aqueous solution or dispersion of the polymorphic or porphin copolymer which can be obtained by the process of the present invention can also be achieved by the present invention. In accordance with a first example of an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer of the present invention, the aqueous or non-aqueous solution or dispersion of the polycopenment or porphin copolymer additionally comprises a binder, the binder The composition of the antistatic or conductive layer prepared by using the composition of the present invention can be combined to obtain a better coating of the non-planar structure of the carrier, and the bonding agent can also be added according to the method of the present invention. The viscosity of the composition. According to a second example of an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer according to the invention, the aqueous or non-15 aqueous solution or dispersion of the polyporphin or ruthenium copolymer additionally comprises a polyester amine group Formate copolymer binder, such as DISPERCOLL VPKA 8481 from BAYER. According to a third example of an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer according to the invention, the aqueous or non-aqueous solution or dispersion of the polyporphin or porphin copolymer additionally comprises a binder, the binder It is selected from the group consisting of polyacrylate, carboxymethyl cellulose, polyvinylpyrrolidone, hydroxypropyl cellulose, copolymer with sulfonic acid group containing carboxylate, acrylic acid copolymer modified with hydroxyl group. And poly(vinyl alcohol). Evaluating the applicability of the binder can add 〇·1% by weight of a special binder to the typical dispersion medium containing the PEDOT/PSS composition according to the present invention. The paper scale applies to the Chinese national standard (CNS>A4 specification (21〇χ297藿〉 91. 3. 2,000 (please read the note on the back and fill out this page) 装---------- A7 1299738 B7___ V. Invention description), for example: 87% by weight 1 , 2-propanediol, 9 wt% diethylene glycol, 3% by weight deionized water, 0.5 wt% ZONYL® FSO, and 0.5 wt% anthrone defoamer X50860A. A binder dissolved in the dispersion medium To the extent of 0.1% by weight, it can be considered to be suitable for use in the composition according to the invention. Particularly suitable binders include: binder 01 = CARBOPOL8 ETD-2623, an acrylic acid crosslinked with a polyalkenyl polyether. Homogeneous-copolymer, B.F. Goodrich; 1〇Binder 02 = CARBOPOL® Aqua 30, a latex of acrylic acid and ethyl acrylate copolymer, produced by B·F·Goodrich; Bond 03 = AMBERGUM® 3021, a carboxymethyl cellulose, Her Produced by cules; bond 04 = LUVISKOL8K30, a polyvinylpyrrolidone, produced by 15 BASF; binder 05 = hydroxyalkyl cellulose methyl propyl ether, produced by Shin-Etsu Chemical Co.; binder 06 = KLUCEL ® L, hydroxypropyl cellulose, produced by Hercules; 2〇 combined with j 07 = NEOCRYL® BT24, an acrylate-based waterborne latex, produced by Zenica; binder 08 = AQUACER8503, an acrylate Matrix water-based latex, produced by BYC Cera; Bond 09 = P0LYPH0BE8TR117, one based on acrylate ^ 22 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the back of the note first) Matters fill out this page) · nlnnnn ft a · ί 1 nnnnnt 0 Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperatives Print 3⁄4 91. 3. 2,000 1299738 A7 _B7_ V. Inventive Description (called) Water-based latex, produced by Union Carbide; Bond 10 = AMOREX® CR2900, an acrylate-based waterborne latex, produced by Westvaco; (please first Note on the back side. Fill in this page. Bonding agent 11 = CRX-8057-45, an acrylate-based waterborne 5 latex, available from Westvaco; binder 12 = PRIMALtm EP-5380, a 54% by weight acrylic acid Ester-based aqueous latex, H〇hm and Haas export · mouth, binder 13 = JAGOTEX® KEM1020, a 58% by weight aqueous latex based on propylene 10 acid ester, Ernst Jager Chem·

Rohstoffe GmbH 公司出品；結合劑 14 = PERMUTEX® PS-34f320，一種 54 重暈％以丙烯酸酯為基質之水性膠乳，Stahl Holland BV 公司出品； 15 結合劑15 = JAGOTEX® KEM4009，一種55重量％丙烯酸酯共聚物之水性膠乳，Ernst Jager Chem. Rohstoffe GmbH 公司出品；經濟部智慧財產局貝工消费合作社印製結合劑16 = GOOD RITE® K797，一種50重量％丙烯酸 -AMPS共聚物冬水性膠乳，B. F. Goodrich公 2〇司出品；結合劑17 = GOOD RITE® K-7058，一種50重量％水溶性丙稀酸聚合物，B· F· Goodrich公司出品；結合劑18 = NARLEX® DX2020，一種丙烯酸/苯乙烯共聚物之膠乳，Alco化學公旬出品；、 23 91. 3. 2,000 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） 1299738 A7 B7 五、發明說明（u) 結合劑19 = ALCOPERSE⑧725，一種丙烯酸/苯6烯共聚物之膠乳，Alco化學公司出品；結合劑20 = CARB0POL® EP2，一種18.1重量％非交聯之甲基丙烯酸/丙烯酸乙酯共聚物之膠乳，B· F. 5 Goodrich公司出品；結合劑21 = 97·5-99·5%經水解之聚（乙烯醇），WACKER CHEMIE公司出品；結合劑 22 = DISPERCOLLTM U VP ΚΑ 848 Ϊ，一種聚酯胺基甲酸酯共聚物之分散液，BAYER公司出品； 10 結合劑丨，2與20對於分散液之黏度具有邦常強烈的影響，而不受PpDOT/PSS含量之控制。顏料與染料依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液 15 或分散液之第四個實例，聚噻吩或噻吩共聚物之水性或非水性溶液或分散液另外包含一種顏料或染料以提供具顏色或不透明的組成物。欲達成透明且具顏色的組成物可藉加入具顏色的染料或顏料，如：偶氮與酞花青顏料。欲達成不透明組成物亦可藉加入一種黑色顏料，如： 20 BAYER 公司之 LEVANYL® A-SF、BAYER 公司之 LEVANYL® NLF、Degussa公司的一種碳黑分散劑 KL1925，以及Mikuni公司的一種碳黑分散劑MHI黑色 8102M，或者是足夠重量的二氧化鈦顏料，能使所塗覆之層厚成為不透明。 ' 24 (請先閲讀背面之注意事項再填寫本頁) 裝 n I n ft 一 · n ί ί ί ί i » 經濟部笮寒財產局貝工消费合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） 91. 3. 2,000 1299738 A7 B7五、發明說明（兮）適合之顏料包括：經濟部智慧財產局貝工消t合作社印¾Produced by Rohstoffe GmbH; Bond 14 = PERMUTEX® PS-34f320, a 54% dilute acrylate based aqueous latex, available from Stahl Holland BV; 15 Bond 15 = JAGOTEX® KEM4009, a 55 wt% acrylate Waterborne Latex of Copolymer, produced by Ernst Jager Chem. Rohstoffe GmbH; Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed Bonding Agent 16 = GOOD RITE® K797, a 50% by weight acrylic-AMPS copolymer winter water latex, BF Goodrich Produced by the company; binder 17 = GOOD RITE® K-7058, a 50% by weight water-soluble acrylic polymer, produced by B·F·Goodrich; binder 18 = NARLEX® DX2020, an acrylic/styrene Latex of copolymer, produced by Alco Chemical Co., Ltd.; 23 91. 3. 2,000 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public) 1299738 A7 B7 V. Invention description (u) Bonding agent 19 = ALCOPERSE8725, an acrylic/benzene 6ene copolymer latex, available from Alco Chemical Company; binder 20 = CARB0POL® EP2, a 18.1% by weight non-crossing Lacquer of methacrylic acid/ethyl acrylate copolymer, produced by B.F. 5 Goodrich; binder 21 = 97·5-99.5% hydrolyzed poly(vinyl alcohol), produced by WACKER CHEMIE; Agent 22 = DISPERCOLLTM U VP ΚΑ 848 Ϊ, a dispersion of polyester urethane copolymer, produced by BAYER; 10 binder 丨, 2 and 20 have a strong influence on the viscosity of the dispersion, and not Controlled by PpDOT/PSS content. Pigment and Dye According to a fourth example of an aqueous or non-aqueous solution 15 or dispersion of a polythiophene or thiophene copolymer according to the invention, the aqueous or non-aqueous solution or dispersion of the polythiophene or thiophene copolymer additionally comprises a pigment or dye Provides a color or opaque composition. To achieve a transparent and coloured composition, a colored dye or pigment such as an azo and phthalocyanine pigment can be added. To achieve opaque composition, a black pigment can also be added, such as: LEVANYL® A-SF from 20 BAYER, LEVANYL® NLF from BAYER, a carbon black dispersant KL1925 from Degussa, and a carbon black dispersion from Mikuni The agent MHI black 8102M, or a titanium dioxide pigment of sufficient weight, makes the applied layer thickness opaque. ' 24 (Please read the note on the back and then fill out this page) Install n I n ft a · n ί ί ί i » Ministry of Economic Affairs, Cold Property Bureau, Bayer Consumer Cooperative Printed on this paper scale, applicable to China National Standard (CNS) ) A4 size (210 X 297 public) 91. 3. 2,000 1299738 A7 B7 V. Invention description (兮) Suitable pigments include: Ministry of Economic Affairs, Intellectual Property Bureau, Beigong Consumer Co., Ltd. Print 3⁄4

(請先閲讀背面之注意事項再填寫本頁)(Please read the notes on the back and fill out this page)

本紙張尺度適用中國國家楳準（CNS>A4規格（210 X 297公* ) 91. 3. 2,000 1299738 A7 B7 五、發明說明Uf ) PIG04This paper scale is applicable to China National Standard (CNS>A4 specification (210 X 297 public*) 91. 3. 2,000 1299738 A7 B7 V. Invention description Uf ) PIG04

LEVANYL® BAYER Blue G-LFLEVANYL® BAYER Blue G-LF

NN

N PIGQ5N PIGQ5

HOSTAPERM ® Blue B2GHOSTAPERM ® Blue B2G

CLARIANTCLARIANT

-----------裝 * -------訂--I------ (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局貝工消t合作社印製-----------Installation *-------Set--I------ (Please read the notes on the back and fill in this page) Ministry of Economic Affairs Intellectual Property Bureau Printing by the cooperative

本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公* ) 91. 3. 2,000 1299738 A7 B7 五、發明說明（攻）經濟部智慧財產局貝工消费合作社印製 PIG07 LEVANYL ⑧ N-LF BAYER ^~ 一種分散於水中之碳黑顏料 PIG08 LEVANYL" A-SF BAYER ^^^ 一種分散於水中之碳黑顏料 ^ PIG09 MHI 8102M DEGUSSA 一種分散於水中之碳黑顏料___^ 一種分之碳f 顏料 ^ PIG 10 ΊΓ\Τ Λ Λ GA黑色1 Mikuni Color Ltd PIG 11 Bonjet黑色 CW-2 Orient 司、A 一種分散於水中之碳黑顏料 ^ PIG 12 Bonjet黑色 CW-1 Orient 化學司一種分散於水中之碳黑顏料 ^ PIG13 FX-GBI-015 Nagase Nippon Shokubai 一種分散於2- 丁_ (50-80%)+曱基異丁基酮 (8-20°/。)中之碳黑顏料 PIG14 LEVANYL^ B-LF BAYER 一種分散於水中之破黑顏料 PIG15 TPX10Q CABOT公司一種經修飾碳黑於水中之？0%分散液 PIG16 TPX100 CA^OT公司一種經修飾碳黑於水中之15%分散液 27 (請先閲讀背面之注意事項再填寫本頁) « ft n n n i n n ^ 4 n It n ft d ΛΜΙ 1 本紙張尺度通用中Η國家標準（CNS)A4規格（210 X 297公爱〉 91. 3. 2,000 5 10 15 經濟部智慧財產局貝工消费合作社印製This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 public*) 91. 3. 2,000 1299738 A7 B7 V. Invention description (attack) Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed PIG07 LEVANYL 8 N- LF BAYER ^~ A carbon black pigment dispersed in water PIG08 LEVANYL" A-SF BAYER ^^^ A carbon black pigment dispersed in water ^ PIG09 MHI 8102M DEGUSSA A carbon black pigment dispersed in water ___^ A carbon f Pigment ^ PIG 10 ΊΓ \ Τ Λ Λ GA Black 1 Mikuni Color Ltd PIG 11 Bonjet Black CW-2 Orient Division, A A carbon black pigment dispersed in water ^ PIG 12 Bonjet Black CW-1 Orient Chemical Division A dispersion in water Carbon black pigment ^ PIG13 FX-GBI-015 Nagase Nippon Shokubai A carbon black pigment PIG14 LEVANYL^ dispersed in 2-butyl _ (50-80%) + decyl isobutyl ketone (8-20 ° /.) B-LF BAYER A black pigment PIG15 dispersed in water, TPX10Q CABOT, a modified carbon black in water? 0% dispersion PIG16 TPX100 CA^OT A modified carbon black 15% dispersion in water 27 (please read the back note before filling this page) « ft nnninn ^ 4 n It n ft d ΛΜΙ 1 paper Standard General China National Standard (CNS) A4 Specification (210 X 297 Public Loyalty) 91. 3. 2,000 5 10 15 Ministry of Economic Affairs Intellectual Property Bureau Beigong Consumer Cooperative Printed

1299738 五、發明說明（zl ) 交聯劑或分散或非一包含-===: 氧基丙㈣劑騎氧錢（例如:3·縮水甘油 —甲乳基矽烷）、矽烷之水解產物（例如：四乙醒氧基石夕院或四甲氧基石夕烧之水解產物），如即564911戶^ L併入本文供參考，以及二·或募聚·異氰酸醋，選擇地為成塊形態。防沫劑依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之第六個實例，聚噻吩或噻吩共聚物之水性或非水性溶液或分散液另外包含一種防沫劑。適合的防沫劑為矽防沫劑Χ50860Α。界面活性劑依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之第七個實例，聚噻吩或噻吩共聚物之水性或非水性溶液或分散液另外包含一種界面活性劑。依照本發明聚噻吩或噻吩共聚物之水性或非水性溶、液或分散液之第八個實例，聚噻吩或噻吩共聚物之水性或非水性溶液或分散液另外包含一種添加之陰離子性界面活性劑0 28 裝本紙張尺度適用中國國家楳準（CNS)A4規格（210 X 297公爱） 91· 3. 2,000 1299738 A7 -—------ -B7 五、發明說明（τη ) (請先閲讀背面之注意事項再填寫本頁) 依照本發明聚噻吩或噻吩共聚物之水性或非水性溶液或分散液之第九個實例，聚噻吩或噻吩共聚物之水性或非水性溶液或分散液另外包含一種非離子性界面活性劑，例如：羥乙基化/氟烷基界面活性劑、聚羥乙基化矽樹脂界面 5 活性劑、聚矽氧烷/聚醚界面活性劑、全氟烷基羧酸之銨鹽、聚經乙基化界面洁性劑與含氟界面活性劑。適合的非離子性界面活性劑包括：界面活性劑第〇1號=ZONYL® FSN，一種40重量％ F(CF2CF2)1-9CH2CH20(CH2CH20)xH，於 50 重量％異丙 10 醇於水溶液，之溶液，其中x=0至約25，杜邦公司產品5 界面活性劑第〇2 號=z〇nyl® FSN-100·· f(cf2cf2)1-9ch2ch2o(ch2ch2o)xh，其中 χ=0 至約 25，杜邦公司產品； 15 界面活性劑第03號=ZONYL⑧FS300，一種40重量％氟化界面活性劑之水溶液，杜邦公司產品；經濟部智慧財產局貝工消費合作社印製界面活性劑第〇4號=z〇NYL® FSO，一種50重量％羥乙基化非離子性含氟界面活性劑混合物，具式： F(CF2CF2)“7CH2CH20(CH2CH20)yH，其中 y=〇至約 2〇 1 $ ’於重量％乙二醇於水溶液，之溶液，杜邦公司產品；界面活性劑第Q5號=ZONYL® FSO-100，一種杜邦公司之罗里乙基化非離子含氟界面活性劑，具式： F(CF2CF2)K7CH2CH20(CH2CH20)yH，其中产〇至約 29 3. 2,000 本紙張尺度通用中國國家標準（CNS)A4規格（21〇 χ 297公釐） 1299738 A7 B7 五、發明說明（β) 15，杜邦公司產品； (请先Mtt背面之注意事項再填S本頁) 界面活性劑第06號sTegoglide® 410，一種聚石夕氧院·聚合物共聚物之界面活性劑，Goldschmidt公司產品；界面活性劑第07號=Tego wet®，一種聚石夕氧烧-聚酯共聚物 5 之界面活性劑，Goldschmidt公司產品；界面活性劑第 08 號 =FLUORAD® FC431: CF3(CF2)7S02(C2H5)N-CH2C(H〇CH2CH2)nOH，3M 公司產品；界面活性劑第09號=FLUORAD⑧FC126，一種全氟羧酸銨 1〇鹽之混合物，3M公司產品；界面活性劑第10號=聚氡基乙烯-10-十二醚界面活性劑第11號=FLUORAD® FC430，一種98.5活性氟脂肪族酯，3M公司產品；適合的陰離子性界面活性劑包括： 15 养面活性劑第12號=ZONYL® 7950，’一種氟化之界面活性劑，杜邦公司產品；界面活性劑第13號=ZONYL⑧FSA，一種25重量％ FCCFsCFOMCt^CHACH/HWOOLi，於 50 重量％異丙醇於水滲液，之溶液，杜邦公司產品；經濟部智慧財產局貝工消f合作社印¾ 2〇界面活性劑第14號=ZONYL® FSE，一種14重量％ [F(CF2CF2V7CH2CH20]xP(0)(0NH4)y，其中 x=l 或 2; y=2或1;與x+y=3，於70重量％乙二醇於水溶液，之溶液，杜邦公司產品；界面活性劑第15號^ZONYL® FSJ，一種40重量％之、 30 91. 3. 2,000 本紙張尺度適用中國國冢標率（CNS)A4規格（210 X 297公« ) 1299738 A7 B7 五、發明說明（圬） [FCCFAFOuC^C^OKPCOXONHA，其中 χ==1 或 2· y=2或1;與x+y=3,與一種碳氫化奋物界面活性劑於 25重量％異丙醇於水溶液，之摻合物溶液，杜邦公司產品；界面活性劑第16號=ZONYL® FSP，一種35重量0/〇，其中 χ=1 咬 2· y=2或1;與x+y=3 ’於69.2重量％異丙醇於水溶液，之溶液，杜邦公司產品;· 界面活性劑第 17 號 =Z〇NYL® UR: [FCCFAFjMCEbCH^AOXOHV 其中 x==1 或 2; 或1;與x+y=3，杜邦公司產品；界面活性劑第18號=ZONYl^ TBS: —種33重量％ F(CF2CF2)3_8CH2CH2S03H，於 4.5 重量％乙酸於水溶液，之溶液，杜邦公司產品；界面活性劑第19號=全氟辛酸之銨鹽； 5 10 15 (锖先Mtt背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 ο 2 工業上之應用聚噻吩與噻吩聚合物之水性溶液或分散液，具有高導電性連同低可見光吸收度，與對紅外線輻射之高吸收度，包含聚噻吩與噻吩共聚物之水性溶液或分散液可應用至廣大範圍之硬質與柔韌基質，例如：陶瓷、玻璃與塑膠，並且特別適合用於柔韌基質，例如：塑膝板片，其基質可被大幅彎曲並且變形，但不會令聚噻吩或噻吩共聚物層損失導電性。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公龙ΐ 91. 3. 2,000 A7 1299738 五、發明說明（弘）此種聚噻吩與噻吩共聚物可使用於如：光電設備、電池、電容器與有機與無機之電致發光裝董、電磁屏蔽層、熱屏蔽層、廣泛種類製品之抗靜電塗覆物，包括：照相軟片、熱錄像之A錄材料與光熱錄像之記錄材料、自動窗、 5 電鉻裝置、用於有機與生物有機材料之偵測器、場效應電晶體、印刷板、導電性樹脂黏著劑，與free-standing導電性軟片[參見募_與聚噻吩手冊之第1〇章，D. Fichou編輯， Wiley，VCH 出版社，Weinheim(1999 年）]。本發明將藉比較與發明實例説明於後，這些實例中之 10 百分率與比率，除另指明外，皆依重量計。下列載體被用於比較與發明實例： • AUTOSTAT® = —種175微米厚度經熱安定之聚（對苯二曱酸乙二醇酯）[PET]，雙面皆被替代，AUTOTYPE國際公司出品； 15 · Π5微米厚度經熱安定之PET，以替代層編號01予以塗覆0 替代層編號01具有下列之組成: 88%亞乙烯基氣化物、1〇%丙烯酸甲酯與2%衣康酸之共聚物 79.1% Kiesels〇r 100F，BAYER公司之〆種膠狀石夕石 18.6% Mersolat® Η，BAYER公司之一種界面活性劑 0.4% Ultravon® W，CIBA-GEIGY公司之一種界南活性劑 1.9% 下列諸層被用於比較與發明實例： •一層LUXPRINT™ 7153E(—種高K介電絕緣體），使用本紙張尺度埤用中國國家標準（CNS)A4規格（210x297公釐） (請先閲讀背面之注意事項再填寫本頁) ·丨丨丨丨丨丨丨·丨i丨丨I丨I · ' 經濟部智.«財產局員工消费合作钍印製 91. 3. 2,000 A7 1299738 B7__ 五、發明說明（糾） P55網目加以絲網印刷； •一層LUXPRINTTM 7138J(—種白色磷），使用P55網目加以絲網印刷。 (請先閲讀背面之注意事項再填寫本頁) 於前未述及之下列成份被用於比較與發明實例之組成 5 物： •非水性溶劑： CA=乙酸卡必醇酯[二（乙二醇）乙基醚乙酸酯] D CJ =二乙二醇 PD = 1，2-丙二醇（丙二醇） j〇 BuOH =正丁醇 • GTMS = 3-縮水甘油氧基丙基三甲氧基矽烷製備3,4_伸烷基二氧噻吩-均聚物比較實例i 15 於25X：將562.5公克5.6重量％之聚（苯乙烯磺酸) 經濟部知*慧財產局貝工消费合作社印製 [PSS](分子量=290,000)水溶液，2437.5公克去離子水與 12.78公克（90毫莫耳）EDOT，於一具有攪拌器之4公升反應容器中進行混合，此溶液中之氧濃度為6.5毫克/公升，其係使用Knick程序單元73氧，及使用InPro 6000系列 2〇氧偵測器，予以測定。隨後加入0.225公克Fe2(S04)3· 9H20 與25.7公克硫代硫酸鈉以引發聚合反應。反應混合物於 25°C攪拌7小時後，另外添加4.3公克硫代硫酸鈉。再經 16小時之反應時間後，將反應混合物以離子交換樹脂 (BAYER 公司出品之 300 毫升 Lewatit™ S100MB + 500 毫〜 33 本紙張尺度適用中國國家楳準（CNS)A4規格（210 297公釐） 91. 3. 2,000 :299738 A7 B7 五、發明說明（多2 ) 升Lewatit™ M600MB)處理二次。得到之混合物另外於95 °C熱處理2小時，並將獲得之黏稠混合物以高切變（微流化器於600巴）處理，經此過程後得到1800公克1.09重量％之藍色分散液。 5 10 15 經濟部智.«財產局貝工消#合作社印¾ 20 比較實例2 於25艺將562.5公克5.6重量％之聚（苯乙烯磺酸） [PSS](分子量=290,000)水溶液，2437.5公克去象子水與 12.78公克（90毫莫耳）EDOT，於一具有攪拌器與氧氣入口之4公升反應容器中進行混合，以氧氧於此混合物中冒泡 30分鐘後，將12.78公克（90毫莫耳）EDOT加至此溶液。此溶液中之氧濃度為38.45毫克/公升，其係使用Knick程序單元73氧，及使用InPro 6000系列氧偵測器，予以測定。隨後加入0.225公克Fe2(S〇4)3· 9H20與25.7公克硫代硫酸鈉以引發聚合反應。反應混合物於25°C攪拌7小時後，另外添加4.3公克硫代硫酸鈉。再經16小時之反應時間後，將反應混合物以離子交換樹脂（BAYER公司出品之 300 毫升 Lewatit™ S100MB + 500 毫升 Lewatit™ M600MB) 處理二次。得到之混合物另外於95°C熱處理2小時，並將獲得之黏稠混合物以高切變（微流化器於600巴）處理，經此過程後得到1760公克1.12重量％之藍色分散液。發明實例1 於室溫下將438.23公克5.99重量°/◦之聚（苯6烯磺酸） 34 本紙張尺度適用中國國家楳準（CNS)A4規格（210 X 297公* ) 91. 3. 2,000 (請先闓讀背面之注意事項再填寫本頁) 經濟部智.€財產局貝工消ff合作社印¾ 1299738 A7 _B7__ 五、發明說明（妗） [PSS](分子量=290,000)水溶液與2061.77公克去離子水，於一具有攪拌器與氮氣入口之4公升尽應容器中進行混合。以氮氣於此混合物中冒泡30分鐘後，將12.78公克（90 毫莫耳）EDOT加至此溶液。此溶液中之氧濃度為0.52毫克 5 /公升，其係使用Kpick程序單元73氧，及使用InPro 6000 系列氧偵測器，予以測定。隨後加入0.225公克Fe2(S04)3· 9H20與25.7公克硫代硫酸鈉以引發聚合反應。反應混合物於25°C攪拌7小時後，另外添加4.3公克硫代硫酸鈉。再經16小時之反應時間後，將反應混合物以離子交換樹脂 1〇 (300 毫升 LewatitTM S100MB + 500 毫升 Lewatit™ M600MB) 處理二次。得到之混合物另外於95°C熱處理2小時，並將獲得之黏稠混合物以高切變（微流化器於600巴）處理，經此過程後得到1950公克1.02重量％之PEDOT 1藍色分散液。 15 發明實例2 · 於25它將438·23公克5.99重量％之聚（苯乙烯磺酸） [PSS](分子量=290,000)水溶液與2061.77公克去離子水，於一具有攪拌II與氮氣入口之4公升反應容器中進行混合。以氮氣於此混合物中冒泡30分鐘後，將12.78公克（90 2〇毫莫耳）EDOT加至此溶液。此溶液中之氧濃度為2.66毫克 /公升，其係使用Knick程序單元73氧，及使用InPro 6000 系列氧偵測器，予以測定。隨後加入0.225公克Fe2(S04)3· 9H20與25.7公克硫代硫酸鈉以引發聚合反應。反應混合物於25°C攪拌7小時後，另外添加4.3公克硫代硫酸鈉。 ' 35 本紙張尺度適用中國國家楳準（CNS)A4規格（210 X 297公釐） 91. 3. 2,000 丨丨丨--------♦裝——丨丨訂·丨丨——Φ (請先Mtt背面之注意事項再填寫本頁) 1299738 A7 五、發明說明（3今）再經16小時之反應時間後，將反應混合物以離子交換樹脂 (BAYER 公司出品之 300 毫升 LewatitTM S100MB + 500 毫升LewatitTM M600MB)處理二次。得到之混合物另外於95 。(：熱處理2小時，並將獲得之黏稠混合物以高切變（微流化 5 器於600巴）處理，經此過程後得到1840公克1.03重量％之PEDOT 2藍色分散液。 PEDOT 1與PEDOT 2之特徵 PEDOT 1與PEDOT 2之分子量係藉水性凝膠滲透色 1〇譜法測定，相對於聚（苯乙烯磺酸）鈉，其係以紫外線-可見光於785奈米之吸收度予以偵測。pfeDOT 1與PED〇T 2 之分子量，連同其於水性分散液中之濃度顯示於表1。 15 盘L· 共聚物編號 PEDOT /PSS之濃度 [重量％] 分子量 [785奈米] PEDOT 1 1.02 490,000 PEDOT 2 1.03 390,000 經濟部智慧財產局貝工消t合作社印製以比較實例1與2，及發明實例1與2，之分散液為基質之分散液製備導電層塗覆分散液之製造係將3-縮水甘油氧基丙基三甲氧基矽烷、ZONYL® FS0100，一種偏二氣乙烯、甲基丙烯酸酯與衣康酸之共聚物膠乳（88/10/2)，與N-甲基吡咯烷酮添加 36 91. 3. 2,000 (請先Ht*背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公« ) 1299738 A7 B7__ 五、發明說明（ (請先Htt背面之注意事項再填寫本頁) 至比較實例1與2，及發明實例1與2，之分散液，用以製造塗覆層，使用醫用刀將替代層1塗覆於一 Π5微米之聚 (對苯二甲酸乙二醇酯）載體上，並於45°C乾燥3.5分鐘，其具有下列之組成： 5 PEDOT 28.9毫克/公尺2 [PEDOT]/PSS 100 毫克/公尺 2 ZONYL® FS0100 8 毫克/公尺 2 ’ 3-縮水甘油氧基丙基三甲氧基砍烷 100毫克/公尺2 偏二氯乙烯、甲基丙烯酸酯與衣 100毫克/公尺2 10 康酸之共聚物膠乳（88/10/2) N-曱基吡咯烷蜩 2毫升/公尺2 以比較實例1與2,及發明實例1與2,之分散液為基質之分散液製備導電層之特徵 15 塗覆層乏光學密度係使用具可見光濾光器之1299738 V. INSTRUCTIONS (zl) Crosslinking agent or dispersed or non-containing -===: oxypropyl (tetra) agent riding oxygen (eg: 3 · glycidol - methyl lactyl decane), hydrolyzate of decane (eg : tetraethyl oxime oxe Xiyuan or tetramethoxy zebao burning hydrolysis product), such as 564,911 households ^ L incorporated herein for reference, and two or condensed polyisocyanate, selected as a block form . Antifoaming agent According to a sixth example of an aqueous or nonaqueous solution or dispersion of a polythiophene or thiophene copolymer according to the invention, the aqueous or nonaqueous solution or dispersion of the polythiophene or thiophene copolymer additionally comprises an antifoaming agent. A suitable antifoaming agent is antifoaming agent Χ50860Α. Surfactant A seventh example of an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer according to the present invention, the aqueous or non-aqueous solution or dispersion of the polythiophene or thiophene copolymer additionally comprises a surfactant. An eighth example of an aqueous or non-aqueous solution, liquid or dispersion of a polythiophene or thiophene copolymer according to the invention, the aqueous or non-aqueous solution or dispersion of the polythiophene or thiophene copolymer additionally comprises an added anionic interface activity Agent 0 28 The paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 public) 91· 3. 2,000 1299738 A7 -—------ -B7 V. Invention description (τη ) (Please Read the back of the precautions and then fill out this page. A ninth example of an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer according to the invention, an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer Also included is a nonionic surfactant such as hydroxyethylated/fluoroalkyl surfactant, polyhydroxyethylated oxime resin interface 5 active agent, polyoxyalkylene/polyether surfactant, perfluoroalkane An ammonium salt of a carboxylic acid, a polyethylated interfacial detergent and a fluorosurfactant. Suitable nonionic surfactants include: Surfactant No. 1 = ZONYL® FSN, a 40% by weight F(CF2CF2)1-9CH2CH20(CH2CH20)xH, in 50% by weight of isopropyl 10 alcohol in aqueous solution, Solution, where x=0 to about 25, DuPont product 5 Surfactant No. 2 = z〇nyl® FSN-100·· f(cf2cf2) 1-9ch2ch2o(ch2ch2o)xh, where χ=0 to about 25 , DuPont products; 15 surfactants No. 03 = ZONYL8FS300, a 40% by weight aqueous solution of fluorinated surfactant, DuPont products; Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperatives printed surfactants No. 4 = z〇NYL® FSO, a 50% by weight hydroxyethylated nonionic fluorosurfactant mixture of the formula: F(CF2CF2) "7CH2CH20(CH2CH20)yH, where y = 〇 to about 2〇1 $ ' Weight % ethylene glycol in aqueous solution, solution, DuPont products; surfactant Q5 = ZONYL® FSO-100, a DuPont ethylolized nonionic fluorine surfactant, with: F( CF2CF2) K7CH2CH20(CH2CH20)yH, which yields to about 29 3. 2,000 paper scales Use Chinese National Standard (CNS) A4 specification (21〇χ 297 mm) 1299738 A7 B7 V. Invention description (β) 15, DuPont products; (Please refill the S page on the back of Mtt) Surfactant No. 06 sTegoglide® 410, a surfactant of polyoxo-polymer copolymer, Goldschmidt product; surfactant #07 = Tego wet®, a poly-stone oxy-polyester copolymer 5 Surfactant, Goldschmidt product; Surfactant No. 08 = FLUORAD® FC431: CF3(CF2)7S02(C2H5)N-CH2C(H〇CH2CH2)nOH, 3M Company product; Surfactant No. 09=FLUORAD8FC126 , a mixture of ammonium perfluorocarboxylic acid 1 〇 salt, 3M company product; surfactant 10th = polydecyl vinyl-10-dodecyl ether surfactant 11th = FLUORAD® FC430, a 98.5 active fluoro fat Group esters, 3M products; Suitable anionic surfactants include: 15 Noodle active agent No. 12 = ZONYL® 7950, 'a fluorinated surfactant, DuPont products; surfactants No. 13 = ZONYL8FSA , a 25 wt% FCCFsC FOMCt^CHACH/HWOOLi, a solution of 50% by weight of isopropanol in water, and DuPont's products; Ministry of Economic Affairs, Intellectual Property Bureau, Beigongxiaof Cooperative, Printing 3⁄4 2〇 surfactant, No. 14 = ZONYL® FSE, a solution of 14% by weight of [F(CF2CF2V7CH2CH20]xP(0)(0NH4)y, wherein x=l or 2; y=2 or 1; and x+y=3, in 70% by weight of ethylene glycol in aqueous solution , DuPont product; Surfactant No. 15 ^ZONYL® FSJ, a 40% by weight, 30 91. 3. 2,000 This paper scale applies to China National Standard Rate (CNS) A4 specification (210 X 297 public « ) 1299738 A7 B7 V. INSTRUCTIONS (圬) [FCCFAFOuC^C^OKPCOXONHA, where χ==1 or 2· y=2 or 1; and x+y=3, with a hydrogenated surfactant surfactant at 25 wt% Isopropanol in aqueous solution, blend solution, DuPont product; Surfactant No. 16 = ZONYL® FSP, a 35 weight 0 / 〇, where χ = 1 bite 2 · y = 2 or 1; and x + y=3 'in 69.2% by weight of isopropanol in aqueous solution, a solution of DuPont; · Surfactant No. 17 = Z〇NYL® UR: [FCCFAFjMCEbCH^AOXOHV where x==1 or 2; or 1; With x+y= 3, DuPont products; surfactants No. 18 = ZONYl ^ TBS: - 33% by weight F (CF2CF2) 3_8CH2CH2S03H, 4.5% by weight acetic acid in aqueous solution, the solution, DuPont products; surfactant 19th = Ammonium Perfluorooctanoate; 5 10 15 (Notes on the back of Mtt's back page) Fill in the page of the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives ο 2 Industrial applications of aqueous solutions or dispersions of polythiophenes and thiophene polymers, With high conductivity, low visible light absorption, and high absorbance to infrared radiation, aqueous solutions or dispersions containing polythiophene and thiophene copolymers can be applied to a wide range of hard and flexible substrates such as ceramics, glass and plastics. It is particularly suitable for use in flexible substrates, such as plastic knee sheets, the matrix of which can be greatly bent and deformed without loss of conductivity of the polythiophene or thiophene copolymer layer. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 Gonglong ΐ 91. 3. 2,000 A7 1299738 V. Invention Description (Hong) This polythiophene and thiophene copolymer can be used for, for example, optoelectronic equipment, batteries Capacitors and organic and inorganic electroluminescent devices, electromagnetic shielding layers, heat shielding layers, antistatic coatings for a wide range of products, including: photographic film, A-record material for thermal recording and recording materials for photo-thermal recording, automatic Windows, 5 electric chrome devices, detectors for organic and bio-organic materials, field-effect transistors, printed boards, conductive resin adhesives, and free-standing conductive films [see the Philippine and Polythiophene Manuals 1 ,, edited by D. Fichou, Wiley, VCH Press, Weinheim (1999). The invention will be described by comparison and examples of inventions, the 10 percentages and ratios in these examples, unless otherwise indicated, The following carriers were used for comparison and invention examples: • AUTOSTAT® = a 175 micron thick thermally stabilized poly(ethylene terephthalate) [PET], both sides replaced, AUTOTYPE Co., Ltd.; 15 · Π 5 μm thick heat-stabilized PET, coated with substitute layer number 01 0 Replacement layer number 01 has the following composition: 88% vinylidene vapor, 1% methyl acrylate and 2% Copolymer of itaconic acid 79.1% Kiesels〇r 100F, BAYER's gelatin-like Shishishi 18.6% Mersolat® Η, a surfactant of BAYER 0.4% Ultravon® W, a kind of borderline of CIBA-GEIGY Active Agent 1.9% The following layers were used for comparison and invention examples: • One layer of LUXPRINTTM 7153E (a high-k dielectric insulator) using the Chinese National Standard (CNS) A4 specification (210x297 mm) Please read the notes on the back and fill out this page. · ·丨丨丨丨丨丨丨·丨i丨丨I丨I · 'Ministry of Economics and Intelligence. «Procurement Bureau employees' consumption cooperation 钍Print 91. 3. 2,000 A7 1299738 B7__ V. Invention description (correction) P55 mesh screen printing; • One layer of LUXPRINTTM 7138J (-white phosphorus), screen printing using P55 mesh. (Please read the note on the back and fill in this page) The following ingredients are used Compositions of the invention examples: • Non-aqueous solvent: CA = carbitol acetate [di(ethylene glycol) ethyl ether acetate] D CJ = diethylene glycol PD = 1,2-propanediol ( Propylene glycol) j〇BuOH = n-butanol • GTMS = 3-glycidoxypropyltrimethoxydecane Preparation 3,4_alkylenedioxythiophene-homopolymer Comparative Example i 15 at 25X: 562.5 g 5.6 % by weight of polystyrene (styrene sulfonic acid) Ministry of Economic Affairs knows that * Hui Property Bureau Bayer Consumer Cooperatives printed [PSS] (molecular weight = 290,000) aqueous solution, 2437.5 grams of deionized water and 12.78 grams (90 millimoles) EDOT, A 4 liter reaction vessel with a stirrer was mixed and the oxygen concentration in the solution was 6.5 mg/liter, which was determined using the Knick program unit 73 oxygen and using an InPro 6000 Series 2 helium oxygen detector. Subsequently, 0.225 g of Fe2(S04)3·9H20 and 25.7 g of sodium thiosulfate were added to initiate polymerization. After the reaction mixture was stirred at 25 ° C for 7 hours, an additional 4.3 g of sodium thiosulfate was added. After a reaction time of 16 hours, the reaction mixture was applied to an ion exchange resin (300 ml of LewatitTM S100MB + 500 MPa to 33 sheets of paper produced by BAYER) for the Chinese National Standard (CNS) A4 specification (210 297 mm). 91. 3. 2,000 : 299738 A7 B7 V. Description of the invention (more 2) LewatitTM M600MB) treated twice. The resulting mixture was additionally heat treated at 95 °C for 2 hours, and the obtained viscous mixture was treated with high shear (microfluidizer at 600 bar), after which 1800 g of a 1.09 wt% blue dispersion was obtained. 5 10 15 Ministry of Economic Affairs Zhi. «Property Bureau Beigongxiao #Cooperative Printing 3⁄4 20 Comparative Example 2 In 25 Arts, 562.5 grams of 5.6% by weight of poly(styrenesulfonic acid) [PSS] (molecular weight = 290,000) aqueous solution, 2437.5 grams Deionized water and 12.78 grams (90 millimoles) of EDOT were mixed in a 4 liter reaction vessel with a stirrer and oxygen inlet. After bubbling oxygenate in the mixture for 30 minutes, 12.78 grams (90) mM EDOT is added to this solution. The oxygen concentration in this solution was 38.45 mg/liter, which was determined using the Knick program unit 73 oxygen and using an InPro 6000 series oxygen detector. Subsequently, 0.225 g of Fe2(S〇4)3.9H20 and 25.7 g of sodium thiosulfate were added to initiate polymerization. After the reaction mixture was stirred at 25 ° C for 7 hours, an additional 4.3 g of sodium thiosulfate was added. After a reaction time of 16 hours, the reaction mixture was treated twice with an ion exchange resin (300 ml LewatitTM S100MB + 500 ml LewatitTM M600MB by BAYER). The resulting mixture was additionally heat treated at 95 ° C for 2 hours, and the obtained viscous mixture was treated with high shear (microfluidizer at 600 bar), after which 1,760 g of a 1.12% by weight blue dispersion was obtained. Inventive Example 1 438.23 g of 5.99 wt/min poly(benzene 6-ene sulfonic acid) at room temperature 34 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 male*) 91. 3. 2,000 (Please read the note on the back and fill out this page.) Ministry of Economic Affairs. € Property Bureau Begongxiao ff Cooperative Printing 3⁄4 1299738 A7 _B7__ V. Invention Description (妗) [PSS] (molecular weight = 290,000) aqueous solution and 2061.77 g Deionized water was mixed in a 4 liter container with a stirrer and nitrogen inlet. After bubbling 30 minutes of this mixture with nitrogen, 12.78 grams (90 millimoles) of EDOT was added to the solution. The oxygen concentration in this solution was 0.52 mg 5 /liter, which was determined using Kpick program unit 73 oxygen and using an InPro 6000 series oxygen detector. Subsequently, 0.225 g of Fe2(S04)3.9H20 and 25.7 g of sodium thiosulfate were added to initiate polymerization. After the reaction mixture was stirred at 25 ° C for 7 hours, an additional 4.3 g of sodium thiosulfate was added. After a further 16 hours of reaction time, the reaction mixture was treated twice with ion exchange resin 1 Torr (300 mL LewatitTM S100MB + 500 mL LewatitTM M600MB). The resulting mixture was additionally heat treated at 95 ° C for 2 hours, and the obtained viscous mixture was treated with high shear (microfluidizer at 600 bar), after which 1,950 g of 1.02% by weight of PEDOT 1 blue dispersion was obtained. . 15 Inventive Example 2 · At 25 it will be 438.23 g of 5.99 wt% poly(styrenesulfonic acid) [PSS] (molecular weight = 290,000) aqueous solution with 2061.77 g of deionized water, with a stirring II and nitrogen inlet 4 Mix in a liter reaction vessel. After bubbling 30 minutes of this mixture with nitrogen, 12.78 grams (90 2 Torr) of EDOT was added to the solution. The oxygen concentration in this solution was 2.66 mg / liter, which was determined using the Knick program unit 73 oxygen and using an InPro 6000 series oxygen detector. Subsequently, 0.225 g of Fe2(S04)3.9H20 and 25.7 g of sodium thiosulfate were added to initiate polymerization. After the reaction mixture was stirred at 25 ° C for 7 hours, an additional 4.3 g of sodium thiosulfate was added. ' 35 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 91. 3. 2,000 丨丨丨-------- ♦ 装 - 丨丨丨丨丨丨丨丨Φ (Please fill out this page on the back of Mtt) 1299738 A7 V. Invention description (3) After 16 hours of reaction time, the reaction mixture is ion exchange resin (300 ml LewatitTM S100MB + produced by BAYER) 500 ml of LewatitTM M600MB) was treated twice. The resulting mixture was additionally at 95. (: Heat treatment for 2 hours, and the obtained viscous mixture was treated with high shear (microfluidization at 600 bar), and after this process, 1840 g of 1.03 wt% PEDOT 2 blue dispersion was obtained. PEDOT 1 and PEDOT Characteristics of 2 The molecular weights of PEDOT 1 and PEDOT 2 are determined by the water gel permeation color 1 〇 spectrum method, and the absorption is detected by ultraviolet-visible light at 785 nm relative to sodium poly(styrenesulfonate). The molecular weights of pfeDOT 1 and PED 〇 T 2 , together with their concentrations in the aqueous dispersion, are shown in Table 1. 15 Disk L· Copolymer No. PEDOT / PSS Concentration [% by weight] Molecular weight [785 nm] PEDOT 1 1.02 490,000 PEDOT 2 1.03 390,000 Ministry of Economic Affairs Intellectual Property Bureau Beigong Consumer Co., Ltd. Printed the manufacturing system for preparing conductive layer coating dispersions by comparing the dispersions of Examples 1 and 2, and the dispersions of Invention Examples 1 and 2 3-glycidoxypropyltrimethoxydecane, ZONYL® FS0100, a copolymer of vinylidene, methacrylate and itaconic acid (88/10/2), added with N-methylpyrrolidone 36 91. 3. 2,000 (please first Ht* on the back) Please fill out this page again.) This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public « ) 1299738 A7 B7__ V. Invention description ( (Please fill in this page on the back of Htt) 1 and 2, and dispersions of inventive examples 1 and 2, for producing a coating layer, using a medical knife to apply the replacement layer 1 to a 5 μm poly(ethylene terephthalate) carrier And dried at 45 ° C for 3.5 minutes, which has the following composition: 5 PEDOT 28.9 mg / m 2 [PEDOT] / PSS 100 mg / m 2 ZONYL® FS0100 8 mg / m 2 ' 3-glycidyl oxygen Propyl trimethoxy decane 100 mg / m 2 vinylidene chloride, methacrylate and clothing 100 mg / m 2 10 Coconic acid copolymer latex (88/10/2) N-mercaptopyrrole Alkane 蜩 2 ml / ft 2 to compare the properties of Examples 1 and 2, and the dispersions of the inventive examples 1 and 2, the dispersion of the conductive layer is formed. 15 The coating layer is deficient in optical density using a visible light filter.

MacBethTM TD904密度計測定，藉測量10只細條之堆疊體，再由其獲得單一細條之光學密度，表2中之數值包括 PET載體之光學密度。經濟部智S財產局S工消费合作社印製塗覆層表面電阻之測定係於溫度25 °C與相對濕度 2〇 30%之室内條件下，將印刷層與平行之諸銅電極接觸，平行之銅電極各為35毫米長並間隔35毫米，且能形成線接觸，電極則以Teflon®絕緣體予以分開，藉此可直接測量表面電阻，其結果亦顯示於表2。隨後依照DIN 54004，使用圖解物料測試技術BV公、 37 91. 3. 2,000 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公* )The MacBethTM TD904 densitometer measures the optical density of a single strip by measuring a stack of 10 strips, and the values in Table 2 include the optical density of the PET carrier. The surface resistance of the printed coating layer printed by the S Department of the Ministry of Economic Affairs, S Property Bureau, is measured at a temperature of 25 ° C and a relative humidity of 2 〇 30%. The printed layer is in contact with the parallel copper electrodes, in parallel. The copper electrodes are each 35 mm long and 35 mm apart, and can form a line contact, and the electrodes are separated by a Teflon® insulator, whereby the surface resistance can be directly measured, and the results are also shown in Table 2. Subsequently, according to DIN 54004, using the graphic material testing technology BV, 37 91. 3. 2,000 paper scales apply to the Chinese National Standard (CNS) A4 specification (210 297 297 **)

5 11A5 11A

經濟部智S財產局貝工消賁合作社印S ο 2 1299738 A7 _B7__ 五、發明說明（釙）司之SUNTESTtm Cps設備，經由其玻璃濾光器，將塗覆層曝露於人工日光下（由氙燈提供）。表2所示之係鈇為曝露於SuntestTM x小時後之表面電阻對曝露於Suntgst前表面電阻之比率。表2: 實例反應介質中氧之數量毫克/公升 PEDOT/PSS 濃度 [重量％] 起始表面電阻 [歐姆/正方] 外徑曝露於SuntestTM 後之表面電阻對起始表面電阻之比率曝露48 小時後曝露96 小時後比較1 6.5 1.09 2900 0.067 83 11000 比較2 38.45 1.11 21000 0.066 50 1646 發明1 0.52 1.02 1200 0.066 13 157 發明2 2.66 1.03 1200 0.065 12 151 表2之結果顯示：起始表面電阻與PEDOT/PSS-層之安定性，主要決定於3,4-伸乙基二氧基噻吩在聚（苯乙烯磺酸) 存在下進行聚合反應時，反應介質中氧之數量，反應介質中氧冬濃度較低時，表面電阻則較低，而且曝露於 Sur^testTM之安定性較南’誠如曝路於SuntestTM後表面電阻對起始表面電阻之較低比率之所示。發明實例3 於室溫下將10.649公斤4.93重量％之聚（笨乙烯磺酸） [PSS](分子量=290,000)水溶液與39351公克去離子水，於 38 本紙張尺度適用中國國家標羋〈CNS)A4洗格（21〇 κ 297公发） 91. 3. 2,000 (請先Mtt背面之注意事項Wt填窝本頁) 裝 § 1299738 經濟部智慧財產局員工消#合作社印焚 A7 B7 五、發明說明（θ) 一具有擐拌器（180轉/分鐘）與氮氣入口之60公升Biichi 反應容器中進行混合。以氮氣於此混合物中冒泡30分鐘後，將213公克（1.5莫耳）EDOT加至此溶液，並將反應混合物加熱至30°C。此溶液中之氧濃度為〇.〇8毫克/公升， 5 其係使用Knick程序單元73氧，及使用InPro 6000系列氧偵測器，予以測定。隨後加入3.75公克Fe2(S04)3· 9H2〇與428.2公克硫代硫酸鈉以引發聚合反應。反應混合物於 3Q°C攪拌7小時後，另外添加71.6公克硫代硫酸鈉。再經 16小時之反應時間後，冷卻至25°C，並停止氮氣冒泡。將 1〇分散液以離子交換樹脂（5000毫升!^〜3出頂810〇]^^ + 8320毫升LewatitTM M600MB)處理二次。得到之混合物另外於95°C熱處理2小時，並將獲得之黏稠混合物（50730公克，1，03重量％)先以15485公克去離子水稀釋，再以高切變[微流化器於40 MPa (400巴）]處理，經此過程後得到Ministry of Economic Affairs, S Property Bureau, Begong Chong Cooperative, Printing S ο 2 1299738 A7 _B7__ V. Invention Description (钋) The SUNTESTtm Cps device of the company, through its glass filter, exposes the coating to artificial sunlight (by the xenon lamp) provide). The enthalpy shown in Table 2 is the ratio of the surface resistance after exposure to SuntestTM x hours to the surface resistance exposed to Sungtst. Table 2: Example Number of Oxygen in Reaction Medium Mg/L PEDOT/PSS Concentration [% by weight] Starting surface resistance [ohm/square] The ratio of surface resistance to initial surface resistance after exposure to SuntestTM is exposed for 48 hours. Comparison after exposure for 96 hours 1 6.5 1.09 2900 0.067 83 11000 Comparison 2 38.45 1.11 21000 0.066 50 1646 Invention 1 0.52 1.02 1200 0.066 13 157 Invention 2 2.66 1.03 1200 0.065 12 151 The results of Table 2 show: initial surface resistance and PEDOT/PSS - The stability of the layer is mainly determined by the amount of oxygen in the reaction medium when the polymerization of 3,4-extended ethyldioxythiophene is carried out in the presence of poly(styrenesulfonic acid), and the oxygen winter concentration in the reaction medium is low. The surface resistance is lower, and the stability of exposure to Sur^testTM is shown by the lower ratio of surface resistance to initial surface resistance after exposure to SuntestTM. Inventive Example 3 10.649 kg of 4.93 wt% poly(stupyl sulfonic acid) [PSS] (molecular weight = 290,000) aqueous solution and 39,951 g of deionized water were applied at room temperature, and the Chinese national standard (CNS) was applied to 38 paper scales. A4 Washing (21〇κ 297 mil) 91. 3. 2,000 (Please note on the back of Mtt Wt fills the page) § 1299738 Ministry of Economic Affairs Intellectual Property Bureau employee elimination #Cooperative Printing A7 B7 V. Invention Description (θ) A 60 liter Biichi reaction vessel with a stirrer (180 rpm) and a nitrogen inlet was mixed. After bubbling with nitrogen for 30 minutes in this mixture, 213 g (1.5 mol) of EDOT was added to the solution, and the reaction mixture was heated to 30 °C. The oxygen concentration in this solution was 〇.〇8 mg/liter, 5 which was determined using the Knick program unit 73 oxygen and using an InPro 6000 series oxygen detector. Subsequently, 3.75 g of Fe2(S04)3·9H2〇 and 428.2 g of sodium thiosulfate were added to initiate polymerization. After the reaction mixture was stirred at 3Q ° C for 7 hours, an additional 71.6 g of sodium thiosulfate was added. After a reaction time of 16 hours, it was cooled to 25 ° C and nitrogen bubbling was stopped. The 1 分散 dispersion was treated twice with ion exchange resin (5000 ml!^~3 top 810 〇]^^ + 8320 ml LewatitTM M600MB). The resulting mixture was additionally heat treated at 95 ° C for 2 hours, and the obtained viscous mixture (50730 g, 1.03 wt%) was first diluted with 15485 g of deionized water and then subjected to high shear [microfluidizer at 40 MPa). (400 bar)] processing, after this process is obtained

15 65.315 公斤 PEDOT 3，為一種 0.82 重量％，PEDOT 對 PSS 重量比率為1:2.46之藍色分散液。於網印印墨之應用發明實例4至7 2〇發明實例4至7之起始組成物之製備係將顯示於表3 之溶劑與數量，與表3顯示數量之PEDOT 3相混合，並於攪拌下將得到的混合物藉蒸餾予以蒸發，使用表3所示之水浴溫度與50 hPa(毫巴）之真空，獲得之組成物亦顯示於表3 〇、 39 本紙張尺度適用中國國家楳準（CNS)A4規格（210 X 297公龙） 91. 3. 2,000 !!ι*έ--------tr---------φ (請先Mtt背面之注意事項再填寫本頁) 1299738 五、發明說明（荈）表3: A7 B715 65.315 kg PEDOT 3, a 0.82 wt% blue dispersion of PEDOT to PSS weight ratio of 1:2.46. Application to Screen Printing Ink Invention Examples 4 to 7 2 The preparation of the starting compositions of Inventive Examples 4 to 7 will be shown in Table 3, the solvent and amount, mixed with the amount of PEDOT 3 shown in Table 3, and The obtained mixture was evaporated by distillation under stirring, and the composition obtained by using the water bath temperature shown in Table 3 and a vacuum of 50 hPa (millimeter) was also shown in Table 3. 〇, 39 The paper scale was applicable to the Chinese national standard ( CNS)A4 specification (210 X 297 male dragon) 91. 3. 2,000 !!ι*έ--------tr---------φ (please fill in the notes on the back of Mtt) This page) 1299738 V. Description of invention (荈) Table 3: A7 B7

發明實例編號除水前之混合物水浴溫度 [°C] (最終）組成物非水性溶劑 PEDOT 3 之數量 (公克） PEDOT/ PSS 非水性溶劑水 (重量％) 種類數量 (公克） [重量％] 種類數t (重量％) 4 BuOH 2335 2333 60 2.74 PD+ 93.06 4.2 PD 900 DEG DEG 98 5 BuOH 233 5、 2333 70 3.10 PD+ 94.70 2.2 PD 900 DEG DEG 98 6 PD 900 2333 60 2.88 PD+ 91.02 6.1 t)EG 98 DEG 7 PD 900 2333 70 3.00 PD+ 94.50 2.5 DEG 98 DEG (請先閱讀背面之注意事項再填寫本頁) 裝這些組成物中之PEDOT含量，得自將PEDOT/PSS之含量除以3.4，於0.806與0.912重量％之間變化。EMBODIMENT EXAMPLE No. Water bath temperature before water removal [°C] (final) Quantity of non-aqueous solvent PEDOT 3 (g) PEDOT/ PSS Non-aqueous solvent water (% by weight) Species (g) [% by weight] Number t (% by weight) 4 BuOH 2335 2333 60 2.74 PD+ 93.06 4.2 PD 900 DEG DEG 98 5 BuOH 233 5, 2333 70 3.10 PD+ 94.70 2.2 PD 900 DEG DEG 98 6 PD 900 2333 60 2.88 PD+ 91.02 6.1 t) EG 98 DEG 7 PD 900 2333 70 3.00 PD+ 94.50 2.5 DEG 98 DEG (Please read the note on the back and fill out this page) The PEDOT content of these compositions is obtained by dividing the PEDOT/PSS content by 3.4 at 0.806 and 0.912. Change between weight%.

5 IX 經濟部智慧財產局貝工消费合作社印¾ ο 2 將發明實例4至7起始組成物以表4所示之網目進行網印，使用一種人工操作之印刷機，印刷至AUTOSTAT饱 CT07載體上，並將得到之印刷物於130°C乾燥2分鐘。印刷物之光學密度係使用經藍色、綠色、紅色與可見光濾光器傳輸之MacBeth™ TR924密度計測定，其結果顯示於表4。印刷物表面電阻之測定，如同比較實例1與2，及發明實例1與2所述，其結果亦顯示於表4。印刷品質係依斑點評估，於0至5之尺度以目視測定， 0相當於一良好的無斑點層，依照卞列準則： 40 本紙張尺度適用中國國家楳準（CNS)A4規格（210 297公* ) 91. 3. 2,000 1299738 A7 B7 五、發明說明（31) 斑點評估為0: 目視檢查未兔斑點；斑點評估為1: 印刷物之1至10%含斑點；斑點評估為2 印刷物之11至20%含斑點；斑點評估為3: 印刷物之21至40%含斑點；斑點評估為4: 印刷物之41至60%含斑點；斑點評估為5: 印刷物高於60%含斑點。與依痕跡評估（印刷缺陷，其中之點缺陷留下一個像彗星之痕跡），於0至5之尺度以目視測定，0相當於一良好的無痕跡層，依照下列準則：痕跡評估為0: 目視檢查未見痕跡；痕跡評估為1: 印刷物之0至1%含痕跡；痕跡評估為2 印刷物之1.1至5°/。含痕跡；痕跡評估為3: 印刷物之5.1至10%含痕跡；痕跡評估為4: 印刷物之1〇·1至15%含痕跡；痕跡ff估為5: 印刷物高於15%含痕跡。印刺物之品質結果，與光學密度測定，與表面電阻之結果，顯示於表4。烴濟部智慧財產局貝工消t合作社印製使用製自經水浴溫度60°C將水共沸蒸發之起始物料製得之印刷物，其印刷性能與製自經水浴溫度70°C將水共沸蒸發者無明顯差異，添加醇類，如：異丙醇或正丁醇，可改良印刷品質，減少斑點與痕跡之存在。 —'—„----裝--------tr-·-------- (請先闓讀背面之注意事項再填鸾本頁) 本紙張尺度適用中國國家楳準（CNS)A4規格（210^ 297公;Ϊ ) 91. 3. 2,000 1299738 A7 B7 經濟部智惡財產局貝工消货合作社印製五、發明說明) 表4: 起始組成物之發明實例編號 4 5 6 7 使用之網目 P34 P34 P34 P34 D藍色 0.29 0.32 0.29 0.29 D綠色 0.36 0.39 0.36 0.37 D紅色 0.47 0.52 0.48 0.49 D可見光‘ 0.30 0.34 0.31 0.31 斑點試驗 3 3 3 3 痕跡試驗 1 1 1 1 表面電阻 [歐姆/正方] 101 90 96 95 這些起始組成物隨後用於製備發明實例4至7之不透明組成物，籍添加適當數量之顯示於表5之成份，包括黑色顏料PIG07，以製備100公克表中所示之組成物。表5: 成份發明實例編號之組成物編號4 編聲5 編號6 編號7 PEDOT 0.733 0.830 0.771 0.803 PEDOT/PSS 2.494 2.822 2.622 2.731 PD+DEG+BuOH 88.546 88.218 88.418 88.309 3_縮水甘油氧基丙基三甲氧基矽烷 0.5 0.5 0.5 0.5 ZONYL® FSO100 0.25 0.25 0.25 0.25 X5060A 0.05 0.05 0.05 0.05 結合劑02 6.66 6.66 6.66 6.66 PIG07 1.50 1.50 1.50 1.50 42 (請先閲讀背面之注意事項再填K本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210< 297公*) 91. 3. 2,000 裝i!訂---------· A7 1299738 __B7__ 五、發明說明（㈦）將發明實例4至7之不透明組成物以表6所示之網目進行網印，使用一種人工操作之網目印刷機，印刷至 AUTOSTAT® CT7 載體上，以及 LUXPRINT® 7138J 與 LUXPRINTTM 7153E 層，並將得到之 AUTOSTATTM CT7 於 5 12(TC 乾燥 2 分鐘，及 LUXPRINT® 7138J 與 LUXPRINT™ 7153E層於130°C乾燥5分鐘，對於表面電阻與光學密度與印刷品質之評估則如前述。於AUTOSTAT™ CT7印刷物之印刷品質結果與光學密度測定，顯示於表6，於AUTOSTATTM CT7、LUXPRINT 1〇 7138J與LUXPRINT™ 7153E印刷物之表面電阻結果亦顯示於表6。表6: 不透明組成物之發明實例編號 4 5 . 6 7 使用之網目 P34 P34 Ρ34 Ρ34 於 Autostat® CT7 D藍色 / 1.57 1.52 1.28 1.42 D綠色 1.54 1·47 1.26 1.35 D紅色 1.52 1.45 1.25 1.37 D·可見光 1.54 1.46 1.26 1.39 斑點試驗 1 1 2 2 痕跡試驗 1 1 2 2 表面電阻[歐姆/正方1 Autostat® CT7 205 211 209 274 Luxprint® 7138J 176 177 161 226 Luxprint® 7153E 269 262 211 300 43 中國國家標準（CNS)A4 蜣格^21〇 < 297 公3^ ' 91. 3. 2,000 (請先：5讀背面之注意事項再填寫本頁) 裝丨丨丨丨.1^·丨--1丨丨丨·. 絰濟部智慧財產局員工消t合作钍印製 1299738 A7 B7 五、發明說明（吵）對於所評估之三種表面，其印刷性能皆令人滿意。發明實例8至19 發明實例8至19之起始組成物之製備係將顯示於表7 5 之溶劑與數量，與表7顯示數量之PEDOT 3相混合，並於攪拌下將得到的混合物藉蒸餾予以蒸發，使用水浴溫度60 艽與50 hPa(毫巴）之真空，獲得之組成物亦顯示於表7。表7: 除水前之混合物起始組成物非水性溶劑 PEDOT 3 之數量 [公斤] PEE)OT/PSS 非水性溶劑水 [重量％] 種類數量 [公斤] [重量％] 種類數量[重量％] PD DEG 9.765 1.085 44.310 3.0 PD+ DEG 91.5 5.5 (請先Mtt背面之注意事項再填寫本頁) 經濟部智S財產局貝工消#合作社印製此起始組成物用於製備發明實例8至19之不透明組成物，藉添加適當數量之顯示於表8之成份，包括各種黑色顏料，以製備100公克表中所示之組成物。3-縮水甘油氧基丙基三曱氧朞矽烷、ZONYL® FS0100與X5060A於攪拌下先加至起始組成物中，隨後於攪拌下加入顏料與結合劑02，除了發明實例13與14之案例外。於發明實例1 7 之糊狀物案例，結合劑22為於攪拌下最後加入之成份。本紙張尺度適用中國國家標箏（CNS)A4規格（210 X 297公* ) 91. 3. 2,000 1299738 A7 B7 五、發明說明（衫）成份5 IX Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperatives Print 3⁄4 ο 2 Inventive Examples 4 to 7 The starting composition was screen printed on the mesh shown in Table 4, and printed to the AUTOSTAT full CT07 carrier using a manually operated printing press. The printed matter obtained was dried at 130 ° C for 2 minutes. The optical density of the printed matter was measured using a MacBethTM TR924 densitometer transmitted through blue, green, red, and visible light filters, and the results are shown in Table 4. The surface resistance of the printed matter was measured as in Comparative Examples 1 and 2, and Inventive Examples 1 and 2, and the results are also shown in Table 4. Printing quality is determined by spotting, visually measured on a scale of 0 to 5, with 0 being a good non-spotted layer, according to the guidelines: 40 This paper scale applies to China National Standard (CNS) A4 specification (210 297 mm) * ) 91. 3. 2,000 1299738 A7 B7 V. Description of invention (31) Spot assessment is 0: Visual inspection of rabbit spots; Spot assessment 1: Corresponding to 1 to 10% of prints containing spots; Spot assessment of 2 prints 11 to 20% contained spots; spots were evaluated as 3: 21 to 40% of the prints contained spots; spots were evaluated as 4: 41 to 60% of the prints contained spots; spots were evaluated as 5: prints above 60% contained spots. With the trace evaluation (printing defects, where the point defects leave a trace like a comet), visually measured on a scale of 0 to 5, 0 corresponds to a good trace-free layer, according to the following criteria: Trace evaluation is 0: No trace was observed by visual inspection; the trace was evaluated as 1: 0 to 1% of the printed matter contained traces; the trace was evaluated as 1 to 5 °/ of the printed matter. Traces are included; traces are evaluated as 3: 5.1 to 10% of the printed matter contains traces; traces are evaluated as 4: 1 to 1% of the printed matter contains traces; trace ff is estimated to be 5: printed matter is higher than 15% with traces. The quality results of the spurs, the optical density measurements, and the surface resistance are shown in Table 4. The Hydrocarbon Ministry of Intellectual Property's Intellectual Property Bureau Beigongxiao Co. Co., Ltd. prints the printed matter prepared from the starting material of azeotropic evaporation of water at a temperature of 60 ° C, and its printing performance is 70 ° C from the water bath temperature. There is no significant difference in azeotropic evaporation. Adding alcohols such as isopropanol or n-butanol can improve the printing quality and reduce the presence of spots and marks. —'—„----装--------tr-·-------- (Please read the notes on the back and fill in this page) This paper scale applies to China. (CNS) A4 specification (210^297 public; Ϊ) 91. 3. 2,000 1299738 A7 B7 Ministry of Economic Affairs, Intellectual Property Bureau, Bureau of Goods and Crafts Cooperatives, Printing 5, Invention Description) Table 4: Examples of the initial composition No. 4 5 6 7 Mesh used P34 P34 P34 P34 D blue 0.29 0.32 0.29 0.29 D green 0.36 0.39 0.36 0.37 D red 0.47 0.52 0.48 0.49 D visible light '0.30 0.34 0.31 0.31 spot test 3 3 3 3 Trace test 1 1 1 1 Surface Resistance [Ohm/Positive] 101 90 96 95 These starting compositions were subsequently used to prepare the opaque compositions of Inventive Examples 4 to 7, by adding an appropriate amount of the ingredients shown in Table 5, including the black pigment PIG07, to prepare 100. Compositions shown in the gram table. Table 5: Composition number of the invention example number 4 Layout 5 No. 6 No. 7 PEDOT 0.733 0.830 0.771 0.803 PEDOT/PSS 2.494 2.822 2.622 2.731 PD+DEG+BuOH 88.546 88.218 88.418 88.309 3 _ glycidoxypropyl trimethoxy decane 0.5 0.5 0.5 0.5 ZONYL® FSO100 0.25 0.25 0.25 0.25 X5060A 0.05 0.05 0.05 0.05 Bonding agent 06 6.66 6.66 6.66 6.66 PIG07 1.50 1.50 1.50 1.50 42 (Please read the notes on the back and refill this page) This paper scale applies to Chinese national standards. (CNS) A4 specification (210 < 297 public*) 91. 3. 2,000 installed i! order---------· A7 1299738 __B7__ V. Description of invention ((7)) The opaque composition of inventive examples 4 to 7 Screen printing on the mesh shown in Table 6, using a manually operated screen printer, printing onto the AUTOSTAT® CT7 carrier, and LUXPRINT® 7138J and LUXPRINTTM 7153E layers, and obtaining the AUTOSTATTM CT7 at 5 12 (TC drying) After 2 minutes, and LUXPRINT® 7138J and LUXPRINTTM 7153E layers were dried at 130 ° C for 5 minutes, the evaluation of surface resistance and optical density and print quality was as described above. The print quality results and optical density measurements of the AUTOSTATTM CT7 prints are shown in Table 6. The surface resistance results for the AUTOSTATTM CT7, LUXPRINT 1〇 7138J and LUXPRINTTM 7153E prints are also shown in Table 6. Table 6: Invention Example of opaque composition No. 4 5 . 6 7 Mesh used P34 P34 Ρ34 Ρ34 on Autostat® CT7 D blue / 1.57 1.52 1.28 1.42 D green 1.54 1·47 1.26 1.35 D red 1.52 1.45 1.25 1.37 D· Visible light 1.54 1.46 1.26 1.39 Spot test 1 1 2 2 Trace test 1 1 2 2 Surface resistance [ohm/square 1 Autostat® CT7 205 211 209 274 Luxprint® 7138J 176 177 161 226 Luxprint® 7153E 269 262 211 300 43 China National Standard ( CNS)A4 ^格^21〇< 297 public 3^ ' 91. 3. 2,000 (please first: 5 read the back note and then fill out this page) 丨丨丨丨.1^·丨--1丨丨丨·. 智慧智慧智慧智慧智慧智慧智慧 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Inventive Examples 8 to 19 Preparation of the starting compositions of Inventive Examples 8 to 19 The solvent and the amount shown in Table 75 were mixed with the amount of PEDOT 3 shown in Table 7, and the obtained mixture was distilled by stirring. Evaporation was carried out using a water bath temperature of 60 Torr and a vacuum of 50 hPa (millimeter), and the composition obtained is also shown in Table 7. Table 7: Pre-water mixture mixture composition Non-aqueous solvent PEDOT 3 Quantity [kg] PEE) OT/PSS Non-aqueous solvent water [% by weight] Species quantity [kg] [% by weight] Species quantity [% by weight] PD DEG 9.765 1.085 44.310 3.0 PD+ DEG 91.5 5.5 (Please fill out this page on the back of Mtt) The Ministry of Economic Affairs S Property Bureau Beigongxiao #Cooperative printed this starting composition for the preparation of inventive examples 8 to 19 The opaque composition was prepared by adding the appropriate amount of the ingredients shown in Table 8, including various black pigments, to prepare a composition shown in the 100 gram table. 3-glycidoxypropyltrioxane decane, ZONYL® FS0100 and X5060A were first added to the starting composition with stirring, followed by the addition of pigment and binder 02 with stirring, except for the case of inventive examples 13 and 14. outer. In the case of the paste of Inventive Example 1, the binder 22 is the last component to be added under stirring. This paper scale applies to China National Standards (CNS) A4 specification (210 X 297 public*) 91. 3. 2,000 1299738 A7 B7 V. Invention description (shirt) Ingredients

PEDOTPEDOT

PEDOT/PSSPEDOT/PSS

PD+DEGPD+DEG

GTMS ZONYL® FS0100GTMS ZONYL® FS0100

X50860A 結合劑X50860A bonding agent

結合劑22 PIG07 ~I PIG10 PIGU PIG12 PIGO PIG14 PIG15~ PIG16 去離子水 9 組成物之發明實例編號[重量％ ] 11 12 13 14 15 16 17 18 19 0.76 2.66 81.01 0.5 0.25 0.05 6.66 4.0 4.87 0.74 2.60 79.46 0.5 0.25 0.05 6.66 5.7 4.78 0.74 2.60 79.46 0.5 0.25 0.05 6.66 5.7 4.78 0.76 0.77 0.78 0.77 0.77 0.77 0.75 0.74 0.73 2.66 2.69 2.73 2.69 2.69 2.69 2.63 2.60 2.55 81.20 81.92 83.30 81.92 81.92 81.92 81.10 79.46 77.72 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 1.5 3.0 3.0 3.0 2.0 X〇" (請先Mt#背面之注意事項再填寫本頁) 3.8 3.0 5.7 4.88 4.93 5.01 4.93 4.93 4.93 4.81 4.78 7.6 4.67 15 經濟部智.«財產局貝工消貧合作社印31 20 發明實例8至19之不透明組成物，除發明實例12略為較黏稠外，皆為些微黏稠。這些不透明組成物均至少置放過夜，而後以表9所示之網目進行網印，使用一種人工操作之網目印刷機，印刷至AUTOSTAT® CT7載體上，以及 LUXPRINT® 7138J 與 LUXPRINT™ 7153E 層，並將得到之 AUTOSTAT™ CT7於 130 °C乾燥 2分鐘，及 LUXPRINT® 7138J 與 LUXPRINTTM 7153E 層於 130°C 乾燥 5分鐸，對於表面電阻與光學密度與印刷品質之評估，則依照發明實例3至7之敘述。 45 91. 3. 2,000 本紙張尺度適用中國國家標準·（CNS)A4規袼（21〇 < 297公3E ) 1299738 A7 B7 五、發明說明（忤）於AUTOSTAT™ CT7印刷物之印刷品質結果與光學密度測定，顯示於表9，於AUTOSTAT™ CT7、LUXPRINT 7138J與LUXPRINTtm 7153E印刷物之表面電阻結果亦顯示於表9。 (請先閱讀背面之注意事項再填窵本頁) 表9: 不透明組成物之發ajE 實例編號 8 9 10 11 12 13 14 15 16 17 18 19 使用之網目 P34 P34 P34 P34 P34 P34 P34 P34 P34 Ρ34 Ρ34 Ρ34 於 Autostat® C17 : D蘇色 0.70 1.71 2.03 0.36 2.84 Q.98 1.65 1.87 2.22 2.20 2.85 0.94 D綠色 0.75 1.66 1.97 0.43 2JI 0.99 1.62 L85 2·16 2.04 2.64 0.94 D紅色 0.83 1.64 1.8δ 0.52 2.62 1.05 1.62 L87 2.16 2.01 2.57 0.98 D可見先 0.71 1.67 1.97 0.38 2.77 0.97 1.62 1.85 2.18 2.07 2.77 0.93 斑點試驗 3 3-4 3 3 0 2 1 1 3 0 4 痕跡試驗 2 1-2 2-3 0-1 1 1 2-3 1 1 4 0-1 1-2 表面電陴[@ :姆/J 匕方] Autostat^ CT7 rt>) 98 106 115 100 91 94 94 .94 84 113 114 121 Luxprint 7138J _ f〇\ 104 99 — 89 88 83 86 77 94 104 - Luxprint 7153E 114 124 92 95 104 98 89 108 113 - 對於所評估之三種表面，其印刷性能皆令人滿意。 ο 2 經濟部智毪財產局貝工消貧合作社印» 46 91. 3. 2,000 1299738 A7 B7 五、發明說明（矽）製備具有不同PSS:PEDOT比率之PEDOT/PSS 實例20 於25 °C將顯示於表10數量之聚（苯乙烯磺酸） [PSS](分子量=290,000)溶液與顯示於表10對於特殊 5 PEDOT種類數量之去離子水，於一具有授拌器與氮氣入口之適合反應容器中進行混合。以氮氣於此混合物中冒泡30 分鐘後’將顯示於表1 〇對於特殊PEDOT種類數量之EDOT 加至此溶液。此溶液中之氧濃度為低於1.0毫克/公升，其係使用Knick程序單元73氧，及使用InPro 6000系列氧 10 偾測器，予以測定。隨後加入相對於濃度各為0.13毫莫耳與41.6毫莫耳之Fe2(S04)3· 9H20與硫代硫酸鈉以引發聚合反應。反應混合物中EDOT之濃度為30毫莫耳，PSS 之濃度為57毫莫耳。隨之將反應混合物於25。(：攪拌7小時，而後另外添加對於特殊PEDOT種類數量之硫代硫酸 15 鈉，相對於濃度6.95毫莫耳。再經16小時之反應時間後，將反應混合物以離子交換樹脂（3〇〇毫升Lewatit™ S100MB + 500毫升Lewatit™ M600MB)處理二次。得到之混合物另外於95°C熱處理2小時，並將獲得之黏稠混合物以高切變 [微流化器於60 MPa(600巴）]處理。 (請先Htt背面之注意事項豕填寫本頁) 裝 ----tr«--------- 經濟部智慧財產局A工消费合作社印製本紙張尺度適用中國國家標準·（CNS)A4規格（210 * 297公发） 91. 3. 2,000Binding agent 22 PIG07 ~I PIG10 PIGU PIG12 PIGO PIG14 PIG15~ PIG16 Deionized water 9 Composition example number [% by weight] 11 12 13 14 15 16 17 18 19 0.76 2.66 81.01 0.5 0.25 0.05 6.66 4.0 4.87 0.74 2.60 79.46 0.5 0.25 0.05 6.66 5.7 4.78 0.74 2.60 79.46 0.5 0.25 0.05 6.66 5.7 4.78 0.76 0.77 0.78 0.77 0.77 0.77 0.75 0.74 0.73 2.66 2.69 2.73 2.69 2.69 2.69 2.63 2.60 2.55 81.20 81.92 83.30 81.92 81.92 81.92 81.10 79.46 77.72 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 1.5 3.0 3.0 3.0 2.0 X〇" (Please note the following on the back of Mt#) 3.8 3.0 5.7 4.88 4.93 5.01 4.93 4.93 4.93 4.81 4.78 7.6 4.67 15 Ministry of Economic Affairs Zhi. «Property Bureau Becoming Poverty Alleviation Cooperatives 31 20 Inventive Examples 8 to 19 opaque compositions, except for the invention example 12 is slightly more viscous, both Slightly sticky. These opaque compositions were placed at least overnight and then screen printed on the mesh shown in Table 9, using a manually operated screen printer, printed onto the AUTOSTAT® CT7 carrier, and LUXPRINT® 7138J and LUXPRINTTM 7153E layers, and The obtained AUTOSTATTM CT7 was dried at 130 °C for 2 minutes, and the LUXPRINT® 7138J and LUXPRINTTM 7153E layers were dried at 130 °C for 5 minutes. For surface resistance and optical density and print quality evaluation, according to Inventive Examples 3 to 7. Narrative. 45 91. 3. 2,000 This paper scale applies to Chinese National Standards (CNS) A4 Regulations (21〇< 297 3E) 1299738 A7 B7 V. INSTRUCTIONS (忤) Print Quality Results and Optics on AUTOSTATTM CT7 Prints The density measurements are shown in Table 9. The surface resistance results for the AUTOSTATTM CT7, LUXPRINT 7138J and LUXPRINTtm 7153E prints are also shown in Table 9. (Please read the notes on the back and fill in this page.) Table 9: Amorphous composition of ajE Example No. 8 9 10 11 12 13 14 15 16 17 18 19 Mesh used P34 P34 P34 P34 P34 P34 P34 P34 P34 Ρ34 Ρ34 Ρ34 on Autostat® C17 : D Susie 0.70 1.71 2.03 0.36 2.84 Q.98 1.65 1.87 2.22 2.20 2.85 0.94 D Green 0.75 1.66 1.97 0.43 2JI 0.99 1.62 L85 2·16 2.04 2.64 0.94 D Red 0.83 1.64 1.8δ 0.52 2.62 1.05 1.62 L87 2.16 2.01 2.57 0.98 D visible first 0.71 1.67 1.97 0.38 2.77 0.97 1.62 1.85 2.18 2.07 2.77 0.93 spot test 3 3-4 3 3 0 2 1 1 3 0 4 Trace test 2 1-2 2-3 0-1 1 1 2 -3 1 1 4 0-1 1-2 Surface 陴 [@ :姆/J 匕方] Autostat^ CT7 rt>) 98 106 115 100 91 94 94 .94 84 113 114 121 Luxprint 7138J _ f〇\ 104 99 — 89 88 83 86 77 94 104 - Luxprint 7153E 114 124 92 95 104 98 89 108 113 - The printing performance is satisfactory for all three surfaces evaluated. ο 2 Ministry of Economic Affairs Zhizhi Property Bureau Becoming Poverty Alleviation Cooperatives » 46 91. 3. 2,000 1299738 A7 B7 V. INSTRUCTIONS (矽) Preparation of PEDOT/PSS with different PSS:PEDOT ratios Example 20 will be displayed at 25 °C The amount of poly(styrenesulfonic acid) [PSS] (molecular weight = 290,000) solution shown in Table 10 is shown in Table 10 for a special 5 PEDOT type of deionized water in a suitable reaction vessel with a stirrer and nitrogen inlet. Mix in. After bubbling with nitrogen for 30 minutes in this mixture, the amount of EDOT added to the amount of the special PEDOT species will be added to this solution. The oxygen concentration in this solution was less than 1.0 mg/liter, which was determined using the Knick program unit 73 oxygen and using an InPro 6000 series oxygen 10 detector. Subsequently, Fe2(S04)3.9H2 and sodium thiosulfate, each having a concentration of 0.13 mmol and 41.6 mmol, were added to initiate polymerization. The concentration of EDOT in the reaction mixture was 30 mmol and the concentration of PSS was 57 mmol. The reaction mixture was then brought to 25. (: Stir for 7 hours, then add additional 15 parts of sodium thiosulfate for a special PEDOT type, relative to a concentration of 6.95 mmol. After a reaction time of 16 hours, the reaction mixture was ion exchange resin (3 ml) LewatitTM S100MB + 500 ml LewatitTM M600MB) was treated twice. The resulting mixture was additionally heat treated at 95 ° C for 2 hours and the resulting viscous mixture was treated with high shear [microfluidizer at 60 MPa (600 bar)] (Please note the following on the back of Htt 豕 fill out this page) Pack----tr«--------- Ministry of Economic Affairs Intellectual Property Bureau A Workers' Consumption Cooperative Printed this paper scale applies to Chinese national standards·( CNS) A4 specification (210 * 297 mil) 91. 3. 2,000

I 299738 A7 B7 五、發明說明（认）表10: 10 15 PEDOT 種類 EDOT 重量 [公克]I 299738 A7 B7 V. Description of invention (recognition) Table 10: 10 15 PEDOT Type EDOT Weight [g]

PSS 溶液重量 [公克] 溶液濃度[重量 %] 非水合之硫酸鐵 [III]重量 [公克] 起始添加之硫代硫酸鈉 [公克] 隨後添加之硫代硫[ 酸鈉 [公克] 水之重量公克] 4 12.78 12.78 438.23 438.23 5.99 5.99 0.225 0.225 25.7 25.7 4.3 4.3 2061.77 2061.77 使用以實例2分散液為基質之分散液以製備並鑑定種類1 導電層塗覆分散液之製造係將3-環氧丙烷丙基三甲基矽烷、 ZONYL® FS0100, 一種偏二氣乙烯、甲基丙烯酸酯與衣康酸之共聚物膠乳（88/10/2)，與N-曱基吡咯烷酮添加至實例 20之分散液，用以製造種類1塗覆層，使用醫用刀塗覆於含替代層1之175微米聚（對苯二甲酸乙二醇酯）載體上，並於45°C乾燥3.5分鐘，其具有下列之組成：經濟部智慧財產局貝工消f合作社印¾ 20 PEDOT [PEDOT]/PSS ZONYL® FS0100 3-環氧丙烷丙基三甲基矽烷偏二氯乙烯、甲基丙烯酸酯與衣康酸之共聚物膠乳（8 8/10/2) N-甲基咕17各烧酮 28.9毫克/公尺2 100毫克/公尺2 8毫克/公尺2 100毫克/公尺2 100毫克/公尺2 2毫升/公尺2 I I 1-1 I f ] i 1 I · III I i I I 111 一 0 111 n n I 1 nf : - t i (請先Mtt背面之注意事項再填窵本頁) 48 本紙張尺度適用中國國家楳準（CNS)A4規格（210 X 297公* ) 91. 3. 2,000 1299738 A7 B7 五、發明說明（¢7) 使用以實例20分散液為基質之分散液製得之導電層之特徵塗覆層之光學密度係使用具可見光濾光器之 MacBethTM TD904密度計測定，藉測量1〇只細條之堆疊 5 體，再由其獲得單一細條之光學密度，表11中之數值包括 PET載體之光學密度。塗覆層表面電阻之測定係於溫度25。(：與相對濕度 30%之室内條件下測定，如同比較實例1與2，及發明實例1與2之所述，其結果亦顯示於表11。 10 隨後依照DIN 54004 ’使用圖解物料測試技術BV公司之SUNTEST™ CPS設備’經由其玻璃濾光器，將種類i 之層曝露於人工曰光下（由氙燈提供）。表丨丨所示之係數為曝露於SuntestTM x小時後之表面電阻對曝露於Suntest前表面電阻之比率。 15 (請先閱讀背面之注意事項再填寫本頁) 裝 ϋ» n n In 一 ·〆_ # i flu n n n n I ft 經濟部智慧財產局貝工消費合作社印製表11: PEDOT 種類 PEDOT/PSS 分散液之數量 [亳升] PEDOT/PSS 之濃度 [重量％] 起始表面電阻 [歐姆/正方] 外徑曝露於 Suntest™ 48 小時後之表面電阻對起始表面 4 1950 1.02 _1200 10^066^ 13 5 1950 — 1.03 ' 1200~' -——-- ΤμΓ ----—j 1 mJ 12 表11之結果顯示：依本發明在實質上無氧存在下製; 包含PEDOT/PSS之層，相較於比較實例i與2之有氧， 49 91. 3. 2,000 %· 1299738 A7 B7 經濟部智慧財產局貝工消货合作社印製五、發明說明（饨）在下製得包含PEDOT/PSS之層（參見表2)，前者較後者具有較低之起始電阻與改良之安定性。實例21 5 於25 C將顯示於表12數量之聚（笨乙稀績酸） [PSS](分子量=290,000)溶液與顯示於表ι2對於特殊 PEDOT種類數量之去離子水，於一具有攪拌器與氮氣入口之適合反應谷器中進行混善。以氮氣於此混合物中冒泡3 Q 分鐘後，將顯示於表12對於特殊PEDOT種類數量之EDOT 10 加至此溶液，得到EDOT之濃度為30毫莫耳。此溶液中之氧?辰度為低於1.0宅克/公升，其係使用Knick程序單元 73氧，及使用Inpro 6000系列氧偵測器，予以測定。隨後加入相對於濃度各為〇·13毫莫卑與41.6毫莫耳之 Fe2(S〇4)3· 9氏0與硫代硫酸鈉以引發聚合反應。反應混合 15 物中’ EDOT之濃度為30毫莫耳，&於pEDOT種類6與 7 ’其PSS之濃度為23毫莫耳，對於ped〇T種類8與9 為36毫莫耳，對於PED0T種類1〇與^為57毫莫耳，對於PEDOT種類12與13為74毫莫耳，對於PEDOT種類14至17為149毫莫耳。隨之將反應混合物於^它攪拌 20 7小時，而後另外添加對於特殊PEDOT種類數量之硫代硫酸納’相對於濃度6·95毫莫耳。再經16小時之反應時間後’將反應混合物以離孚交換樹脂（3〇〇毫升Lewatit™ S100MB + 500 毫升 LewatitTM M600MB)處理二次。得到之混合物另外於951熱處理2小時，並將獲得之黏稠混合物 ' 50 (請先閲讀背面之注意事項#填寫本頁) 裝訂---- ·%· 本紙張尺度適用中國國家標半（CNS)A4規格（210 X 297公爱） 91. 3. 2,000 1299738 A7 B7 五、發明說明（^ ) 以高切變[微流化器於60 MPa(600巴）]處理。表10: PEDOT 種類 ED0T 重量 [公克] PSS 非水合之硫酸鐵 [III]重量[公克] 起始添加之硫代硫酸鈉 [公克] 7小時後添加之硫代硫酸鈉 [公克] 水之重量 [公克i 溶液濃度 [毫莫耳] 溶液濃度『重量 %] 6 10.65 23 4.81 0.187 21.4 3.58 22B0.87 7 10.65 23 4.81 0.187 21.4 3.58 2280.87 8 10.65 36 4.81 0.187 21.4 3.58 2152.25 9 10.65 36 4.81 0.187 21.4 3.58 2152.25 10 10.65 57 5.99 0.187 21.4 3.58 2061.77 11 10.65 57 5.99 0.187 21.4 3.58 2061.77 12 10.65 74 4.81 0.187 21.4 3.58 1788.2 13 10.65 74 4.81 0.187 21.4 3.58 1788.2 14 8.52 149 4.81 0.149 17.1 2.86 862.11 15 8.52 149 4.81 0.149 17.1 2.86 862.11 16 213 149 4.90 3.75 428.2 71.6 22092.7 17 213 149 4.90 3.75 428.2 71.6 22092.7 18 213 149 4.90 3.75 428.2 71.6 22092.7 PEDOT種類17使用相同條件，惟未進行於95°C下進行熱處理2小時獲得之PSS:PEDOT重量與莫耳比率、PSS/PEDOT濃度、像用Ubbelohde黏度計，水浴控溫於25°C測得之黏度、於雙模式顆粒尺寸分佈中之頂點顆粒尺寸、與每毫升中顆粒尺寸大於1微米之顆粒數，皆顯示於表13。 (請先閲讀背面之注意事項再填寫本頁) 裝 (I n ft « n n n n i I n A - 絰濟部智毪財產局貝工消货合作社印製 91. 3. 2,000 本紙張尺度適用中國國家標準（CNS)A4規格（210^ 297公* ) 1299738 A7 B7 五 5 11 發明說明（h ) A 13; PEDOT 種類 PSS/ PEDOT 重量比率 pssT PEDOT 莫耳比率 PEDOT/ PSS-濃度 [重量％] 黏度“ cP 均質化之前/之後之頂點顆粒尺寸[奈米] 顆粒數/ 亳升 >1微米 6 0.98 0.76 0.73 226 1086/47 0.98 0.76 0.65 120 1076/45 ΤΤόΐΓο7^ ^8 1.55 ~Π20^ 0.86 225 1042/44 9 1.55 1.20 0.82 150 973/42 [jTo^ 1.96 ^1.51 0.96 • 910/43 TT4xid^j 11 2.46 1.90 0.03 240 647/68 4.8x10^ l^J2^ 3.18 ~2JTj 1 64 759/33 3.6x10^ Γ3 3、18 二—： 2.45 「0,93 60 734/32 3,2x107^ 14 6.36 4.91 1.83 94 493/27 2.9xl〇r Γ15 6.36 4^9Fj 1.89 118 560/26 3.3xl07 16 6.42(50L) 4.96 1.55 59 /26 1.1x10^ 17 6.42(50L-UT) 4.96 1.66 53 /23 1.2x10^ 18 未經熱處理1 4.96J 1.32 59 /18 1.5x10^ 使用以實例21分散液為基質之分散液以製備並鑑定種類j 導電層使用以實例21分散液為棊質之分散液製備種巔1導電層’並如貫例15所述之分散液般予以鑑定，種類1導電層之結果顯示於表14。 (請先閲tt背面之注意事項再填寫本頁) · n n ϋ n 1 n n^δ4· n i n .1 n n fli 暴經濟部智慧財產局員工消t合作社印製 91. 3. 2,000 本紙張尺度中H g祕i|MCNS)A4規格（21G X 297^¾) 1299738 A7 B7 五、發明說明（il) 表14: PEDOT種類 PSS/PEDOT 重量比率 PSS/PEDOT 莫耳比率表面電阻 [歐姆/正方] 外徑包括載體 6 0.98 0.76 3000 0.061 7 0.98 0.76 3300 0.062 8 1.55 λ r\ r\ i .zu 1700 0.065 9 1.55 1.20 1600 0.065 10 1.96 1.51 1000 0.066 11 2.46 1.90 1100 0.065 12 3.18 2.45 870 0.063 13 3.18 2.45 770 0.065 14 6.36 4.91 730 0.064 15 6.36 4.91 720 0.065 16 6.42(50L) 4.96 640 0.066 17 6.42(50L-UT) 4.96 640 0.065 18 未經熱處理 4.96 690 0.067 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局貝工消费合作社印製表14之結果令人驚訝地顯示依本發明在實質上無氧存在下製得包含PEDOT/PSS之層，其表面電阻隨著 PSS:PEDOT比率之增加而降低，此與文獻中對於 PEDOT/PSS得到之數據有所不同，後者顯示表面電阻隨著 BSSrPEDOT比率之增加而升高，參見如：M. Lefebvre等人 1999年於化學材料，第11冊，第262至268頁發表之論文，其報導製自EDOT與NaPPS之水溶液與乙腈（AN)溶液之PEDOT/PSS，具有PSS對於PEDOT之比率於0.24至 3 · 3 3之範圍。 ^ · I------^--1------ — 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公发） 91. 3. 2,000 A7 B7 五、發明說明_ 1299738 使用之溶劑獲得之PSS:PEDOT比率起始導電率丨S公分_11 乙腈/水 ϋ·48 1.3 乙腈/水 0.67 1.0 乙月青 0.71 L5 乙腈/水 0.91 0.3 乙腈/水 1.0 2.5 乙腈/水 3.33 6 χ ΙΟ-3 水 0.24 9.9 水 2.0 0.3 水 2.5 0.4 實例22 10 於25 °c將顯示於表15數量之聚（苯乙烯磺酸） [PSS](ALCO出品之VERS A TL77，具有數目平均分子量 =25,000與重量平均分子量=72,000)溶液與顯示於表15對於特殊PEDOT種類數量之去離子水，於一具有攪拌器與氮氣入口之適合反應容器中進行混合。以氮氣於此混合物 15 中冒泡30分鐘後，將顯示於表15對於特殊PEDOT種類數量之EDOT加至此溶液，得到EDOT之濃度為30毫莫耳。此溶液中之氧濃度為低於1.0毫克/公升，其係使用 Knick程序單元73氧，及使用InPro 6000系列氧偵測器，予以測定。隨後加入相對於濃度各為0.13毫莫耳與41.6 20 毫莫耳之Fe2(S〇4)3· 9H20與硫代硫酸鈉以引發聚合反應。反應混合物中，EDOT之濃度為30毫莫耳，對於PEDOT 種類19，其PSS之濃度為46毫莫耳，對於PEDOT種類 20為57毫莫耳，對於PEDOT種類21為57毫莫耳，對於 PEDOt種類22為69毫莫耳，對於PEDOT種類23為93 、 54 本紙張尺度適用中國國家標準（CNS)A4規格（210^ 297公* ) (請先《讀背面之注意事項再填寫本頁) ^---------^--I------ 經濟部智慧財產局貝工消t合作社印焚 91. 3. 2,000 1299738 A7 B7 五、發明說明（θ ) 毫莫耳。隨之將反應混合物於25°C攪拌7小時，而後另外添加對於特殊PEDOT種類數量之硫代硫酸鈉，相對於濃度6.94毫莫耳。再經16小時之反應時間後，將反應混合物以離子交換樹脂（300毫升LewatitTM S100MB + 500毫升 5 LewatitfM M600MB)處理二次。得到之混合物另外於050C 熱處理2小時，並將獲得之黏稠混合物以高切變[微流化器於60 MPa(600巴）]處理。表15: Ί PEDOT 種類 EDOT 重量 [公克] PSS 非水合之硫酸鐵 [III]重量[公克] 起始添加之硫代硫酸鈉 [公克] 7小時後添加今疏代硫酸鈉重量[公克] 水之重量 [公克] 重量 [公克] 溶液濃度 [重量％] 19 8.52 17.04 4.01 0.149 17.13 2.86 1575.07 20 8,52 21.00 4.01 「0,149 17.13 2.86 1476.311 21 8.52 21.00 4.01 0.149 17.13 2.86 1476.31 22 8.52 25.56 4.01 r 0.149 17.13 2.86 1362.6 23 8.52 34.08 4.01 0.149 17.13 2.86 1150.07 -------*----—裝---- (請先閲讀背面之注意事項再填寫本頁) 訂--------- 經濟部智慈財產局貝工消贊合作社印梨獲得之PSS:PEDOT重量與莫耳比率、PEDOT/ PSS濃度、使用Ubbelohde黏度計，水浴控溫於25t：測得之黏度、於雙模式顆粒尺寸分佈中之頂點顆粒尺寸、與每毫升中願粒尺寸大於1微米之顆粒數，皆顯示於表16。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 91. 3. 2,000 1299738 A7 _B7五、發明說明（^) 表16: PEDOT 種類 PSS/ PEDOT 重量比率 PSS/ PEDOT 莫耳比率 PEDOT/ PSS-濃度 [重量％] 黏度 cP 均質化之前/之後之頂點顆粒尺寸[奈米] 顆粒數/ 毫升 >1微米 19 2.00 1.54 0.93 240 983/67 8.2x10' 20 2.46 1.90 1.21 10 1249/101 7.9x10' 21 2.46 1.90 1.22 50 1224/98 7.2xl05 22 3.00 2.32 1.35 31 1062/87 8.0x10' 23 4.00 3.09 1.75 57 126/83 8.4x10' 使用以實例22分散液為基質之分散液以製備並鑑定種類1 導電層使用以實例22分散液為基質之分散液製備種類1導電層，並如同實例20所述之分散液般予以鑑定，種類1導電層之結果顯示於表17。表17: PEDOT種類 PSS/PEDOT 重量比率 PSS/PEDOT 莫耳比率表面電阻 [歐姆/正方] 外徑包括載體 19 2.00 1.54 3300 0.059 20 2.46 1.90 1900 0.063 21 2.46 1.90 1700 0.063 22 3.00 2.32 1500 0.062 23 4.00 3.09 1300 0.062 !!!!?--------tr! (請先Μ讀背面之注意事項再填寫本頁) 經濟部智慧財屋局貝工消货合作社印製 20 表17之結果確認了表14之結果，令人驚訝地顯示依本發明在實質上無氧存在下製得包含PEDOT/PSS之層，其表面電阻隨著PSS:PEDOT比率之增加而降低、 56 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 91. 3. 2,000 1299738 Α7 Β7 經濟部智慧財產局貝工消費合作社印製五、發明說明（it) 單體之合成合成2-乙醯氧基甲基-2,3·二氫-噻嗯基[3,4-bni，4]二崎英 -5,7-二羧酸二甲酯。〇PSS solution weight [g] Solution concentration [% by weight] Non-hydrated ferric sulfate [III] Weight [g] Initial addition of sodium thiosulfate [g] Subsequent addition of thiosulfur [sodium [g] water weight克] 4 12.78 12.78 438.23 438.23 5.99 5.99 0.225 0.225 25.7 25.7 4.3 4.3 2061.77 2061.77 Using the dispersion of the example 2 dispersion as a substrate to prepare and identify the type 1 conductive layer coating dispersion of the 3-methylpropane propane Trimethyl decane, ZONYL® FS0100, a copolymer of vinylidene, methacrylate and itaconic acid (88/10/2), and N-mercaptopyrrolidone added to the dispersion of Example 20, To make a type 1 coating layer, apply it to a 175 micron poly(ethylene terephthalate) carrier containing the replacement layer 1 using a medical knife, and dry at 45 ° C for 3.5 minutes, which has the following Composition: Ministry of Economic Affairs, Intellectual Property Bureau, Beigong Consumer Co., Ltd. 3⁄4 20 PEDOT [PEDOT]/PSS ZONYL® FS0100 3-Ethylene oxide propyl trimethyl decane copolymerization of dichloroethylene, methacrylate and itaconic acid Latex (8 8/10/2) N-methyl hydrazine 17 Ketone 28.9 mg / m 2 100 mg / m 2 8 mg / m 2 100 mg / m 2 100 mg / m 2 2 ml / m 2 II 1-1 I f ] i 1 I · III I i II 111 a 0 111 nn I 1 nf : - ti (Please note the following on the back of Mtt) Page 48 This paper size applies to China National Standard (CNS) A4 (210 X 297 male*) 91. 3. 2,000 1299738 A7 B7 V. INSTRUCTIONS (¢7) Characteristics of Conductive Layers Prepared Using Dispersions Based on the Dispersion of Example 20 The optical density of the coating layer was measured using a MacBethTM TD904 densitometer with visible light filters. For the measurement, the optical density of a single strip is obtained by measuring a stack of 5 strips of 1 strip, and the values in Table 11 include the optical density of the PET carrier. The surface resistance of the coating was determined at a temperature of 25. (: Measured under room conditions with a relative humidity of 30%, as in Comparative Examples 1 and 2, and Invention Examples 1 and 2, the results are also shown in Table 11. 10 Subsequently using the graphic material testing technique BV according to DIN 54004 ' The company's SUNTESTTM CPS device exposes the layer of type i to artificial light (provided by a xenon lamp) via its glass filter. The coefficient shown is the surface resistance to exposure after exposure to SuntestTM x hours. The ratio of surface resistance to Suntest. 15 (Please read the note on the back and fill out this page) Decoration » nn In 〆〆 _ # i flu nnnn I ft Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed Table 11 : PEDOT Type PEDOT/PSS Dispersion Quantity [亳升] PEDOT/PSS Concentration [% by weight] Starting surface resistance [ohm/square] OD exposed to SuntestTM surface resistance after 48 hours vs. starting surface 4 1950 1.02 _1200 10^066^ 13 5 1950 — 1.03 ' 1200~' -——-- ΤμΓ ----—j 1 mJ 12 The results of Table 11 show: in the presence of substantially oxygen-free according to the invention; including PEDOT /PSS layer, compared to comparison Example i and 2 aerobic, 49 91. 3. 2,000 %· 1299738 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Beigong Consumer Cooperative Printing 5, invention description (饨) The layer containing PEDOT/PSS is produced underneath (see table 2), the former has lower initial resistance and improved stability than the latter. Example 21 5 at 25 C will show the amount of poly(stupid acid) [PSS] (molecular weight = 290,000) solution shown in Table 12 The deionized water shown in Table 1 for a specific PEDOT type is mixed in a suitable reaction vessel with a stirrer and a nitrogen inlet. After bubbling with nitrogen for 3 Q minutes in this mixture, it will be shown in Table 12. For the special PEDOT type of EDOT 10 added to this solution, the concentration of EDOT is 30 millimolar. The oxygen in this solution is less than 1.0 gram / liter, which uses the Knick program unit 73 oxygen, and use Inpro 6000 series oxygen detectors were measured, followed by the addition of Fe2(S〇4)3·9·0 and sodium thiosulfate with a concentration of 〇13 mmol and 41.6 mmoles to initiate polymerization. The concentration of 'EDOT' in the reaction mixture 15 is 30 millimolar, & pED OT types 6 and 7' have a PSS concentration of 23 millimolar, 36 mA for ped〇T types 8 and 9, and 57 millimoles for PED0T types 1 and ^, for PEDOT types 12 and 13 74 millimoles, 149 millimoles for PEDOT types 14 to 17. The reaction mixture was then stirred for a period of 20 7 hours, and then an additional amount of sodium thiosulfate for a particular PEDOT species relative to a concentration of 6.95 mmol was added. After a reaction time of 16 hours, the reaction mixture was treated twice with a reciprocating resin (3 liters of LewatitTM S100MB + 500 ml of LewatitTM M600MB). The resulting mixture was additionally heat treated at 951 for 2 hours, and the viscous mixture obtained was '50 (please read the notes on the back #fill this page) Binding---- ·%· This paper scale applies to China National Standard Half (CNS) A4 size (210 X 297 public) 91. 3. 2,000 1299738 A7 B7 V. Description of invention (^) Treated with high shear [microfluidizer at 60 MPa (600 bar)]. Table 10: PEDOT type ED0T Weight [g] PSS Non-hydrated ferric sulfate [III] Weight [g] Initial addition of sodium thiosulfate [g] Sodium thiosulfate [g] added after 7 hours [weight of water [克i solution concentration [mole] solution concentration "% by weight" 6 10.65 23 4.81 0.187 21.4 3.58 22B0.87 7 10.65 23 4.81 0.187 21.4 3.58 2280.87 8 10.65 36 4.81 0.187 21.4 3.58 2152.25 9 10.65 36 4.81 0.187 21.4 3.58 2152.25 10 10.65 57 5.99 0.187 21.4 3.58 2061.77 11 10.65 57 5.99 0.187 21.4 3.58 2061.77 12 10.65 74 4.81 0.187 21.4 3.58 1788.2 13 10.65 74 4.81 0.187 21.4 3.58 1788.2 14 8.52 149 4.81 0.149 17.1 2.86 862.11 15 8.52 149 4.81 0.149 17.1 2.86 862.11 16 213 149 4.90 3.75 428.2 71.6 22092.7 17 213 149 4.90 3.75 428.2 71.6 22092.7 18 213 149 4.90 3.75 428.2 71.6 22092.7 PEDOT category 17 uses the same conditions, but does not perform heat treatment at 95 ° C for 2 hours to obtain PSS: PEDOT weight to molar ratio , PSS / PEDOT concentration, such as Ubbelohde viscometer, water bath temperature control at 25 ° C measured viscosity, in the double The vertex particle size in the mode particle size distribution and the number of particles larger than 1 micron in size per ml are shown in Table 13. (Please read the precautions on the back and fill out this page) Pack (I n ft « nnnni I n A - Printed by the Ministry of Economic Affairs, Zhiji Property Bureau, 91. 3. 2,000 This paper scale applies to Chinese national standards (CNS) A4 specification (210^297 public*) 1299738 A7 B7 five 5 11 invention description (h) A 13; PEDOT type PSS/ PEDOT weight ratio pssT PEDOT molar ratio PEDOT / PSS-concentration [% by weight] viscosity "cP Vertex particle size before/after homogenization [nano] Particle number / soaring > 1 micron 6 0.98 0.76 0.73 226 1086/47 0.98 0.76 0.65 120 1076/45 ΤΤόΐΓο7^ ^8 1.55 ~Π20^ 0.86 225 1042/44 9 1.55 1.20 0.82 150 973/42 [jTo^ 1.96 ^1.51 0.96 • 910/43 TT4xid^j 11 2.46 1.90 0.03 240 647/68 4.8x10^ l^J2^ 3.18 ~2JTj 1 64 759/33 3.6x10^ Γ3 3 , 18 2 -: 2.45 "0,93 60 734/32 3,2x107^ 14 6.36 4.91 1.83 94 493/27 2.9xl〇r Γ15 6.36 4^9Fj 1.89 118 560/26 3.3xl07 16 6.42(50L) 4.96 1.55 59 /26 1.1x10^ 17 6.42(50L-UT) 4.96 1.66 53 /23 1.2x10^ 18 without heat treatment 1. 4.96J 1.32 59 /18 1.5x10^ Use to disperse with example 21 The liquid is a dispersion of the substrate to prepare and identify the type j conductive layer. The conductive layer of the seed layer 1 is prepared by using the dispersion of the example 21 dispersion as an enamel, and is identified as the dispersion described in Example 15, and the type 1 is electrically conductive. The results of the layers are shown in Table 14. (Please read the note on the back of the tt and then fill out this page) · nn ϋ n 1 nn^δ4· nin .1 nn fli Ministry of Economic Affairs, Ministry of Intelligence, Intellectual Property Bureau, employee t-cooperative printing 91. 3. 2,000 paper size H g secret i|MCNS) A4 size (21G X 297^3⁄4) 1299738 A7 B7 V. Invention description (il) Table 14: PEDOT type PSS/PEDOT Weight ratio PSS/PEDOT Molar ratio surface Resistance [ohm/square] OD includes carrier 6 0.98 0.76 3000 0.061 7 0.98 0.76 3300 0.062 8 1.55 λ r\ r\ i .zu 1700 0.065 9 1.55 1.20 1600 0.065 10 1.96 1.51 1000 0.066 11 2.46 1.90 1100 0.065 12 3.18 2.45 870 0.063 13 3.18 2.45 770 0.065 14 6.36 4.91 730 0.064 15 6.36 4.91 720 0.065 16 6.42 (50L) 4.96 640 0.066 17 6.42 (50L-UT) 4.96 640 0.065 18 without heat treatment 4.96 690 0.067 (Please read the notes on the back first) Fill in this page again) The results of the Table 14 of the Ministry of Intellectual Property's Bayer Consumers Co., Ltd. surprisingly show that the layer containing PEDOT/PSS is produced in the presence of substantially oxygen-free according to the present invention, and its surface resistance increases with the PSS:PEDOT ratio. This is different from the data obtained for PEDOT/PSS in the literature, which shows that the surface resistance increases with the increase of the BSSrPEDOT ratio, see for example: M. Lefebvre et al., 1999, Chemical Materials, Vol. 11, No. Papers published on pages 262 to 268, reported as PEDOT/PSS from aqueous solutions of EDOT and NaPPS and acetonitrile (AN) solutions, with a ratio of PSS to PEDOT ranging from 0.24 to 3 · 3 3 . ^ · I------^--1------ — This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mil) 91. 3. 2,000 A7 B7 V. Invention Description _ 1299738 PSS obtained using solvent: PEDOT ratio Initial conductivity 丨S cm _11 Acetonitrile / hydrazine · 48 1.3 Acetonitrile / water 0.67 1.0 Ethyl acetate 0.71 L5 Acetonitrile / water 0.91 0.3 Acetonitrile / water 1.0 2.5 Acetonitrile / water 3.33 6 χ ΙΟ-3 Water 0.24 9.9 Water 2.0 0.3 Water 2.5 0.4 Example 22 10 The amount of poly(styrenesulfonic acid) [PSS] shown in Table 15 at 25 °c (ALCO produced VERS A TL77, with number average The solution of molecular weight = 25,000 and weight average molecular weight = 72,000) and deionized water shown in Table 15 for a particular PEDOT type were mixed in a suitable reaction vessel with a stirrer and nitrogen inlet. After bubbling in this mixture 15 with nitrogen for 30 minutes, the amount of EDOT shown in Table 15 for a particular PEDOT species was added to the solution to give an EDOT concentration of 30 mmol. The oxygen concentration in this solution was less than 1.0 mg/liter, which was determined using the Knick program unit 73 oxygen and using an InPro 6000 series oxygen detector. Subsequently, Fe2(S〇4)3.9H2 and sodium thiosulfate were added in an amount of 0.13 mmol and 41.6 20 mmol, respectively, to initiate a polymerization reaction. The concentration of EDOT was 30 millimolar in the reaction mixture, 46 millimoles for PEDOT species 19, 57 millimolar for PEDOT species 20, and 57 millimoles for PEDOT species 21, for PEDOt Type 22 is 69 millimolar, for PEDOT category 23 is 93, 54 paper size applies to China National Standard (CNS) A4 specification (210^297 public*) (please read the back note and fill out this page) ^ ---------^--I------ Ministry of Economic Affairs Intellectual Property Bureau Beigong Consumer Co., Ltd. Printing and Burning 91. 3. 2,000 1299738 A7 B7 V. Invention Description (θ) Milligram. The reaction mixture was then stirred at 25 ° C for 7 hours, and then an additional amount of sodium thiosulfate was added for a particular PEDOT species relative to a concentration of 6.94 mmol. After a further 16 hours of reaction time, the reaction mixture was treated twice with ion-exchange resin (300 mL of LewatitTM S100MB + 500 ml of 5 Lewatitf M M600MB). The resulting mixture was further heat treated at 050 C for 2 hours, and the obtained viscous mixture was treated with high shear [microfluidizer at 60 MPa (600 bar)]. Table 15: Ί PEDOT Type EDOT Weight [g] PSS Non-hydrated Ferric Sulfate [III] Weight [g] Initial addition of sodium thiosulfate [g] 7 hours after adding sodium sulphate weight [g] Water Weight [g] Weight [g] Solution concentration [% by weight] 19 8.52 17.04 4.01 0.149 17.13 2.86 1575.07 20 8,52 21.00 4.01 "0,149 17.13 2.86 1476.311 21 8.52 21.00 4.01 0.149 17.13 2.86 1476.31 22 8.52 25.56 4.01 r 0.149 17.13 2.86 1362.6 23 8.52 34.08 4.01 0.149 17.13 2.86 1150.07 -------*-----Install---- (Please read the notes on the back and fill out this page) Order --------- Economy PSI: PEDOT weight and molar ratio, PEDOT/PSS concentration, Ubbelohde viscometer, water bath temperature control at 25t: measured viscosity, dual mode particle size distribution The apex particle size in the middle, and the number of particles larger than 1 micron in each milliliter, are shown in Table 16. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 91. 3. 2,000 1299738 A7 _B7 V. Invention Description (^) Table 16: PEDOT Type PSS/ PEDOT Weight Ratio PSS/ PEDOT Molar Ratio PEDOT/ PSS-Concentration [% by weight] Viscosity cP Peak particle size before/after homogenization [Nano] Particles / ml> 1 micron 19 2.00 1.54 0.93 240 983/67 8.2x10' 20 2.46 1.90 1.21 10 1249/101 7.9x10' 21 2.46 1.90 1.22 50 1224/98 7.2xl05 22 3.00 2.32 1.35 31 1062/87 8.0x10' 23 4.00 3.09 1.75 57 126/83 8.4x10' Using a dispersion of the dispersion of Example 22 to prepare and identify the type 1 conductive layer. A type 1 conductive layer was prepared using the dispersion of Example 22 dispersion as a matrix, and dispersed as described in Example 20. The results were identified as liquid, and the results of the type 1 conductive layer are shown in Table 17. Table 17: PEDOT type PSS/PEDOT Weight ratio PSS/PEDOT Molar ratio surface resistance [ohm/square] Outer diameter including carrier 19 2.00 1.54 3300 0.059 20 2.46 1.90 1900 0.063 21 2.46 1.90 1700 0.063 22 3.00 2.32 1500 0.062 23 4.00 3.09 1300 0.062 !!!!?--------tr! (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Wisdom House, Beikes Co., Ltd. Printed 20 Confirmation of the results of Table 17 The results of Table 14 surprisingly show that a layer comprising PEDOT/PSS is produced in the presence of substantially no oxygen in accordance with the present invention, the surface resistance of which decreases with increasing PSS:PEDOT ratio, 56 paper scales for China National Standard (CNS) A4 Specification (210 X 297 mm) 91. 3. 2,000 1299738 Α7 Β7 Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed 5, Invention Description (it) Synthesis of Monomer 2-Ethylene Oxide Methyl-2,3·dihydro-thienyl [3,4-bni,4] bis-sodium-5,7-dicarboxylic acid dimethyl ester. 〇

10 如US 5，111，327所述，將3,4-二羥基噻吩-2,5-二羧酸二甲酯與環氧溴丙烷進行反應，可獲得2-乙醯氧基曱基-2,3-二氫-噻嗯基[3,4-b][l,4]二哼英-5,7-二羧酸二曱酯與3-乙醯氧基_3,4·二氫_2Η_噻嗯基二啐呼_6,8_二羧酸二 15 甲酯之70/30莫耳混合物。此混合物隨後藉一種乙醯化/選擇性結晶程序加以分離：將2-乙醯氧基甲基-2,3-二氫-噻嗯基[3,4-b][l,4]二畤英-5,7-二羧酸二甲酯與3-乙醯氧基甲基 _3,4-二氫-211-喧嗯基[3,4-1)；1[1，4]二崎呼-6,8-二缓酸二甲酯之7〇/30莫耳混舍物（143公克，0.496莫耳）溶解於二氣甲 20 烧中（丨·5公升），而後添加三乙胺（80毫升），繼之以滴加方式加入乙醯氯（43毫升），經由些微之冷卻，將反應持續維持於約25°C，加料後將混合物於251：繼續授拌·ΐ小時。隨後將反應禺合物分別以1Μ鹽酸，1Μ碳酸氫納水溶液，與氯化鈉飽和水溶液清洗數次。將溶劑移除，並將得 ' 57 本紙張尺度適用中Η國家標準（CNS)A4規格（210 X 297公* 91· 3. 2t〇〇〇 (請先wtt背面之注意事項再填寫本頁)10 2-Methoxyoxyindenyl-2 can be obtained by reacting dimethyl 3,4-dihydroxythiophene-2,5-dicarboxylate with epibromohydrin as described in US 5,111,327 ,3-dihydro-thienyl[3,4-b][l,4]dioxin-5,7-dicarboxylic acid dinonyl ester and 3-ethyloxy-3-3,4·dihydro_ 2 Η _ 嗯基啐啐 _ _ 6,8-dicarboxylic acid di 15 methyl ester 70/30 molar mixture. This mixture is then separated by an acetylation/selective crystallization procedure: 2-Ethyloxymethyl-2,3-dihydro-thienyl [3,4-b][l,4]dioxene Dimethyl ketone-5,7-dicarboxylate with 3-ethoxycarbonylmethyl-3,4-dihydro-211-喧-[3,4-1);1[1,4]二崎7〇/30mol mixed material of -6,8-di-low-acid dimethyl ester (143g, 0.496mol) dissolved in two gas (20 liters), then added triethylamine (80 ml), followed by dropwise addition of acetamidine chloride (43 ml), and the reaction was continuously maintained at about 25 ° C by little cooling. After the addition, the mixture was allowed to continue at 251 hr. Subsequently, the reaction mixture was washed with a solution of 1 Μ hydrochloric acid, 1 Μ aqueous sodium hydrogencarbonate, and a saturated aqueous solution of sodium chloride for several times. Remove the solvent and get the '57 paper size for the China National Standard (CNS) A4 specification (210 X 297 public* 91· 3. 2t〇〇〇 (please fill in the back of this note on the back of the wtt)

1299738 五、發明說明（饨）=之固體使用乙醇予以再結晶，於過濾與清洗濾渣後，獲知純乙醯氧基甲基_2,3-二氫-噻嗯基[3,4-1)][1，4]二呤英 -5,7-一羧酸二甲酯，以核磁共振儀與質譜儀加以鑑定。 5 合成3-乙釅氧基_3,4-二氫-2Η•噻嗯基-6,8-二羧酸二曱酯 101299738 V. Description of the invention (饨)=The solid is recrystallized using ethanol. After filtering and washing the filter residue, the pure ethoxymethyl 2,3-dihydro-thiol group [3,4-1) is obtained. [1,4] Dioxin-5,7-monocarboxylic acid dimethyl ester was identified by NMR and mass spectrometry. 5 Synthesis of 3-ethoxycarbonyl_3,4-dihydro-2Η•Thionyl-6,8-dicarboxylic acid dinonyl ester 10

(請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局貝工消費合作社印製(Please read the notes on the back and fill out this page.) Printed by the Ministry of Economic Affairs and Intellectual Property Bureau.

—Ο 0— 其7-員環異構物’ 3-乙醯氧基-3，4-二氫-2Η-嗔嗯基 [3，4-b][ 1，4]二畤呼-6,8-二羧酸二甲酯，可藉將前述再結晶程序之濾液濃縮予以分離，剩餘之殘留物，為2-乙醯氧基甲基-2,3-二氫-噻嗯基[3,4-b：l[l，4]二啐英-5,7-二羧酸二甲酯與3-乙醯氧基_3,4_二氫-2H-喧嗯基[3,4-b][l，4]二哼呼二羧酸二甲酯之混合物（莫耳比率約1:2)，隨後使用二乳化碎耩管柱色谱法分離成個別化合物（洗提液··二氣甲烷/乙酸乙酯=90/10)，最後得到純3-乙醯氧基_3,4-二氳-211-σ塞嗯基[3,4-b][l，4]二今呼-6,8-二緣酸二曱g旨，以及一些額外的純乙醯氧基甲基-2,3-二氫-σ塞喝基[3,4_b][l，4]二崎英τ5,7-二羧酸二甲酯。本紙張尺度適用中國國家標準（CNS)A4規格（210 * 297公« > 3· 2,000 1299738 A7 B7 五、發明說明（上;？）合成2-羥基曱基_2,3_二氫_噻嗯基[3,4_b]以,4]二畤英_5,7_ 二羧酸—Ο 0—the 7-membered cyclic isomer ' 3-ethyl methoxy-3,4-dihydro-2 fluorene-fluorenyl [3,4-b][ 1,4] dioxin-6, The dimethyl 8-dicarboxylate can be isolated by concentrating the filtrate of the aforementioned recrystallization procedure, and the remaining residue is 2-ethyloxymethyl-2,3-dihydro-thienyl [3, 4-b: l[l,4] dimethyl dioxin-5,7-dicarboxylate and 3-ethoxycarbonyl _3,4-dihydro-2H- fluorenyl [3,4-b ] [l,4] a mixture of dimethyl dioxo-dicarboxylate (molar ratio of about 1:2), which is then separated into individual compounds using two-emulsified mash column chromatography (eluent · di-methane /ethyl acetate = 90/10), finally obtained pure 3-ethoxycarbonyl _3,4-diindole-211- σ 嗯 [ [3,4-b][l,4] 二今呼-6 , 8-dicarboxylic acid diterpene g, and some additional pure ethyl methoxymethyl-2,3-dihydro-σ sylvestyl [3,4_b][l,4] saki τ5,7 - Dimethyl dicarboxylate. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 * 297 public « > 3 · 2,000 1299738 A7 B7 V. Description of the invention (up; ?) Synthesis of 2-hydroxyindolyl 2,3_dihydro-thiazide嗯基[3,4_b]以,4]二畤英_5,7_ Dicarboxylic acid

/0H/0H

將2乙醯氧基甲基_2,3-二氫-噻嗯基[3,4-b][l，4]二哼英 10 -5,7_一緩酸二曱醋（6〇公克，〇·ΐ8莫耳）溶解於乙醇中（_ 公升），隨後添加氫氧化鉀(36公克）至此溶液，繼之於持續、"卩下力人水（5〇〇毫升），加水後將反應混合物繼續攪拌 3、〇分鐘，再將溶劑藉蒸餾移除。於殘餘之反應混合物部份，以滴加方式加入冰（5〇公克）與濃鹽酸（25毫升）之混合 15 物，並予攪拌。隨後將混合物過濾，並以水清洗濾渣，於乾燥後得到定量生成之純2_羥基甲基-2,3_二氫_噻嗯基 [3,4_b][l，4]二畤英_5,7_二羧酸，以核磁共振儀與質譜儀加以鑑定。、 ------*-----^ Μ--------^--------- (锖先閲tt背面之注意事項再填寫本頁) 經濟部智慧財產局貝工消費合作钍印¾ ο 2 合成3-羥基-3,4_二氫-2H_噻嗯基[3,4_b][1，4]二啐呼_6,8_ 羧酸 59 本紙張尺度通用t ®國家標準（CNS)A4規格⑽κ 297公度 91. 3. 2,000 1299738 A7 B7 玉、發明説明（只）2 ethoxycarbonylmethyl 2,3-dihydro-thienyl [3,4-b][l,4]dioxin 10 -5,7_a sulphuric acid di vinegar (6 gram gram , 〇·ΐ8 Moer) dissolved in ethanol (_ liter), then added potassium hydroxide (36 grams) to this solution, followed by continuous, & 卩卩力 force water (5 〇〇 ml), after adding water The reaction mixture was stirred for a further 3 minutes and the solvent was removed by distillation. To the remaining portion of the reaction mixture, a mixture of ice (5 liters) and concentrated hydrochloric acid (25 ml) was added dropwise and stirred. Subsequently, the mixture was filtered, and the filter residue was washed with water to obtain a quantitatively produced pure 2-hydroxymethyl-2,3-dihydro-thiol[3,4_b][l,4]dioxin_5 after drying. , 7_ dicarboxylic acid, identified by nuclear magnetic resonance and mass spectrometry. , ------*-----^ Μ--------^--------- (Please read the READ on the back of the tt and fill in this page) Property Bureau Bayer Consumer Cooperation 钍 Printing 3⁄4 ο 2 Synthesis of 3-hydroxy-3,4_dihydro-2H_Thienyl [3,4_b][1,4] Dioxo_6,8_ Carboxylic Acid 59 Paper Scale universal t ® national standard (CNS) A4 specification (10) κ 297 mm 91. 3. 2,000 1299738 A7 B7 jade, invention description (only)

0H0H

10 純 3-羥基_3,4_二氫_2H•噻嗯基[3,4_b][1，4]二啐呼_6,8_二羧酸之製備與如述之2-經基甲基-2,3-二氫-σ塞嗯基[3,4-b][l，4] 二崎英-5,7_一羧酸合成方法類似，並使用相同莫耳數量之缚劑。合成（2,3—二氫-噻嗯基[3,4_b；|[l，4]二哼英_2_基）-曱醇（Ml) 請先 Μ 讀背之注意事項5 5裝頁訂 /-Γ0Η Η % 經濟部智慧財產局貝工消f合作社印製 ο 2 將2-經基曱基_2,3_一氫-σ基嗯基[3,4-b][l,4]二π等英·5,7-二羧酸（48公克，〇·184莫耳）溶解於队沁二甲基乙醯胺中 (500公升），並添加重鉻酸銅（8.6公克）與喳咁（15滴），随本紙張尺度適用中國國家標羊(CNS)A4規格（210 X 297公釐） 91. 3. 2,000 1299738Preparation of pure 3-hydroxy-3,4_dihydro-2H•thienyl[3,4_b][1,4]dioxin-6,8-dicarboxylic acid and 2-armament as described The base-2,3-dihydro-σ syl-[3,4-b][l,4] bis-sodium-5,7-monocarboxylic acid is synthesized in a similar manner and uses the same molar amount of the binding agent. Synthesis (2,3-dihydro-thienyl [3,4_b;|[l,4]dioxin-2-yl)-sterol (Ml) Please read the following notes 5 5 /-Γ0Η Η % Ministry of Economic Affairs Intellectual Property Bureau Beigongxiao f Cooperative Printed ο 2 2-Based base 2,3_-hydrogen-σ-based [3,4-b][l,4] Di-π-iso- 5,7-dicarboxylic acid (48 g, 〇·184 mol) was dissolved in 沁 dimethyl acetamide (500 liters) and added copper dichromate (8.6 g) and hydrazine咁 (15 drops), with the Chinese National Standard Sheep (CNS) A4 specification (210 X 297 mm) 91. 3. 2,000 1299738

發明說明（约）後將此混合物於150。(：攪拌2小時，繼之冷卻至25°C，再將其倒入乙酸乙酯中。藉過渡將催化劑移除，並以酸水與氣化鈉之飽和水溶液清洗渡潰，經移除溶劑後，藉真空蒸餾（115至120t：; 0·05毫米汞柱）分離出純（2,3-二氫_噻嗯基 [3,4-b][l，4]二呤英-2_基>曱醇。合成 3,4-二氫-2H-噻嗯基[3,4-bni，4]二畤呼_3-醇（M2) 10DESCRIPTION OF THE INVENTION (Approximately) This mixture is then at 150. (: stirring for 2 hours, followed by cooling to 25 ° C, and then pouring it into ethyl acetate. The catalyst was removed by the transition, and the solution was washed with a saturated aqueous solution of acid water and sodium carbonate, and the solvent was removed. After that, pure (2,3-dihydro-thienyl [3,4-b][l,4]dioxin-2_ was isolated by vacuum distillation (115 to 120t:; 0.05 mmHg). Base > sterol. Synthesis of 3,4-dihydro-2H-thienyl [3,4-bni,4]dioxan-3-alcohol (M2) 10

(請先閲tt背面之注意事項再填寫本頁) 裝 15 純3,4-二氫-2H-噻嗯基[3,4-b][l，4]二畤呼-3,醇之製備與前述之（2,3-;氫-噻嗯基[3,4-b][l，4]二畤英-2-基甲醇合成方法類似，並使用相同莫耳數量之試劑，同時使用二氧化矽以管柱色譜法加以純化（洗提液：二氣甲烷）。 T n n cn ff ^ ^ 0 n It n n n i λϋ - 經濟部智慧財產局貝工消t合作社印製 ο 2 合成（2,3-二氫-噻嗯基[3,4-b][l，4]二呤英-2-基甲氧基）_乙酸乙酯（M3) 本紙張尺度適用中國國家標準（CNS)A4規格（210 « 297公釐） 3. 2,〇〇〇 1299738 A7 B7(Please read the note on the back of tt and then fill out this page) Install 15 pure 3,4-dihydro-2H-thienyl [3,4-b][l,4]dioxagen-3, preparation of alcohol Similar to the above (2,3-; hydrogen-thienyl [3,4-b][l,4]dioxin-2-ylmethanol synthesis method, and using the same molar amount of reagent, while using two The cerium oxide is purified by column chromatography (eluent: di-methane). T nn cn ff ^ ^ 0 n It nnni λϋ - Ministry of Economic Affairs Intellectual Property Bureau Beigong Consumer Co., Ltd. ο 2 Synthesis (2,3 -Dihydro-Thienyl [3,4-b][l,4]dioxin-2-ylmethoxy)-ethyl acetate (M3) This paper size applies to the Chinese National Standard (CNS) A4 specification ( 210 « 297 mm) 3. 2, 〇〇〇1299738 A7 B7

五、發明說明（&◊)V. Invention Description (&◊)

〇〇 0-V/Λ ί 〇 10 15 ，（2,3·二古氫“塞嗯基[3,4_b][M]二吟英士附” π 克，4〇毫莫耳)於氮氣覆蓋下，溶解於四氫吱喃中（1〇〇毫升）。以分批添加方式加入氫化鈉（1·9公克）後，將反應混 ^物持續攪拌30分鐘，再以滴加方式加入溴乙酸乙酯（5.3 笑升），並於25°C繼續挽拌1小時，繼之將反應混合物倒入乙ί文乙酯中，並以1M鹽酸清洗，再以1M碳酸氫鈉水溶液清洗後，予以濃縮，得到定量生成之純（2，弘二氫-噻嗯基[3,4-13^1,4]二呤英基甲氧基）_乙酸乙酯，以核磁共^ 儀與質譜儀加以鑑定。 •基）-甲醇（6.9公合成（2,3-二氫-噻嗯基[3,44][1，4]二口号英_2-基甲氧基）_乙酸（M4) (請先Htt背面之注意事項再填窝本頁)〇〇0-V/Λ ί 〇10 15 ,(2,3·二古氢 “塞姆基[3,4_b][M]二吟英士附” π克, 4〇毫耳) under nitrogen blanket , dissolved in tetrahydrofuran (1 〇〇 ml). After adding sodium hydride (1·9 g) in portions, the reaction mixture was stirred for 30 minutes, and then ethyl bromoacetate (5.3 liters) was added dropwise, and the mixture was further stirred at 25 ° C. After 1 hour, the reaction mixture was poured into ethyl acetate, washed with 1M hydrochloric acid, and then washed with 1M aqueous sodium hydrogen carbonate solution, and then concentrated to give quantitatively pure (2, bishydro-thiol) [3,4-13^1,4] Diterpene methoxy)-ethyl acetate was identified by a nuclear magnetic resonance spectrometer and a mass spectrometer. • base)-methanol (6.9 s synthes (2,3-dihydro-thienyl [3,44][1,4] di-n-butyl-2-ylmethoxy)-acetic acid (M4) (please first Htt) Note on the back and fill in this page)

絰濟部智慧財產局貝工消费合作社印製 ο 2Printed by the Ministry of Commerce, Intellectual Property Bureau, Bayer Consumer Cooperative ο 2

本紙張尺度適用中國國家楳準（CNS)A4規格（210 x 297公* > 91· 3. 2,〇〇〇 1299738 A7 B7 五、發明說明（t、）將（2,3-二氫-噻嗯基[3,4_b][1，4]二啐英_2_基曱氧基）_乙酸乙酯（10.2公克，40毫莫耳）於氮氣覆蓋下，溶解於乙醇 (100毫升）與水（50耷升）中，並加入氫氧化鉀（2·9公克），將混合物加熱至35它計30分鐘，隨後藉蒸餾移除溶劑， 5 再加入乙酸乙酯（50毫升），冰水（50毫升）與濃鹽酸（5毫升），並予以劇烈攪拌。繼之將有機相分離，使用氯化鈉飽和溶液清洗，再以無水硫酸鎂加以乾燥，並予以濃縮。最後將粗產物使用乙酸乙酯/己烷（1/1)進行再結晶，獲得純 (2,3-二氫-噻嗯基[3,4-b][l，4]二哼英-2-基甲氧基）-乙酸，以 10 核磁共振儀與質譜儀加以鑑定。合成2_{2-[2-(2-曱氧基-乙醯氧基）_乙醯氧基]-乙氧甲基}-2,3-二氫-喧嗯基[3,4-13][1，4]二今英（]\45)This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 public* > 91· 3. 2, 〇〇〇1299738 A7 B7 5. Invention description (t,) will (2,3-dihydro- Diethyl [3,4_b][1,4]dioxin-2-yloxy)ethyl acetate (10.2 g, 40 mmol) dissolved in ethanol (100 mL) under nitrogen blanket Water (50 liters), and add potassium hydroxide (2.9 g), heat the mixture to 35 for 30 minutes, then remove the solvent by distillation, 5 then add ethyl acetate (50 ml), ice water (50 ml) and concentrated hydrochloric acid (5 ml), and stirred vigorously. The organic phase was separated, washed with a saturated sodium chloride solution, dried over anhydrous magnesium sulfate and concentrated. Ethyl ester/hexane (1/1) was recrystallized to obtain pure (2,3-dihydro-thienyl [3,4-b][l,4]dioxin-2-ylmethoxy) -Acetic acid, identified by a 10 NMR spectrometer and a mass spectrometer. Synthesis of 2_{2-[2-(2-decyloxy-ethoxy)-ethoxycarbonyl]-ethoxymethyl}-2,3 - Dihydro-喧-[3,4-13][1,4]二今英(]\45)

s 20 進行3,4-二甲氧基喧吩（12·9公克，89毫莫耳）與{2-[2-(2- 甲氧基-乙醯氧基）-乙醮氧基]醯氧基甲基卜1，2_乙二醇 (24.5公克）於甲苯中（150亳升）之醚轉化反應，係將這些化合物之混合物於連續的氮氣流動下，加熱（於l〇〇°c )24小時，隨後將反應混合物倒入二氣曱烧中（200毫升），並將有、 63 本紙張尺度遘用中國國家標準（CNS)A4規格（210 X 297公* ) (請先閱讀背面之注意事項再填寫本頁) ^ · I-------^---------. 經濟部智《財產局員工消費合作钍印褽 91. 3. 2,000 1299738 五 5 10 經濟部智.«財產局α工消費合作钍印槊s 20 is carried out with 3,4-dimethoxy porphin (12·9 g, 89 mmol) and {2-[2-(2-methoxy-acetoxy)-ethenyloxy] hydrazine Ether conversion of 1,2-ethanediol (24.5 g) in toluene (150 liters) by mixing a mixture of these compounds under continuous nitrogen flow (at l〇〇°c) ) 24 hours, then the reaction mixture was poured into two gas smoldering (200 ml), and 63 paper grades were used in the Chinese National Standard (CNS) A4 specification (210 X 297 metric*) (please read the back first) Note: Please fill out this page) ^ · I-------^---------. Ministry of Economic Affairs, "Property Bureau staff consumption cooperation 钍印褽 91. 3. 2,000 1299738 five 5 10 Ministry of Economic Affairs, Zhizhi.

B7 發明說明（機相以1Μ碳酸氫納水溶液洛与/先，再以丨辰氯化鈉水溶液清洗，經無水硫酸鎂乾燥後，再 ,^ 丹卞/辰縮，由此可得到黏辋夕油液，最後藉真空蒸餾獲得％ ^ 甘、〇电2气2_[2-(2-甲氧基-乙醯氧基）-乙&&氧基]-乙氧甲基}_2 3 _ ^ * 口等英。 1 一虱-噻嗯基二合成聚環氧乙烧取狀(2,3H嗯基[3，例英-2-基_甲醇（M6)B7 Description of the invention (The machine phase is treated with 1 Μ aqueous solution of sodium bicarbonate and / / first, and then washed with a solution of sodium chloride sodium chloride, dried with anhydrous magnesium sulfate, and then, ^ 卞卞 / 缩 ,, thus can be obtained Oil, finally obtained by vacuum distillation to obtain % ^ 甘, 〇 electricity 2 gas 2_[2-(2-methoxy-ethoxy)-B&&oxy]-ethoxymethyl}_2 3 _ ^ * 口等英. 1 一虱-Thienyl II Synthetic Poly Ethylene Ethylene Bake Shape (2,3H 基 [3, 英英-2-基_Methanol (M6)

V 將對-甲苯磺醯氣（8·4公克，44毫莫耳）於氮氣覆蓋下，溶。解於吼咬中（2〇毫升）。將反應溫度持續維持於約25至30 以滴加方式加入-種單經基官能化之聚環氧乙燒（分子里一750公克/莫耳，15公克，2〇毫莫耳）於吼咬（3〇毫升）之溶f加料㈣反應混合物再攪拌2小時，而後倒入冰 $ i、g义中’使用—氯甲燒萃取其水相，隨後合併諸有機部伤並以1M石反g曼氫鈉水溶液清洗，最後以管柱色譜法加 =純化（使用二氧化砍，洗提液：分別為二氣甲烧與乙醇），得到純甲苯磺酸鹽官能化之聚環氧乙烷。將（2,3-二氫·噻嗯基[3,4_b][1，4]二嘮英_2_基兴甲醇〇 ·〇 91. 3. 2,000 [299738 A7 B7 五、發明說明（U ) 公克，5·8毫莫耳）於氮氣覆蓋下，溶解於四氫呋喃中（25 毫升）。添加氫化鈉（〇·25公克）並持續攪拌30分鐘，再以淹加方式加入一種曱苯磺酸化聚環氧乙烷（5.3公克）於四氧咬°南（25毫升）之溶液’加料後將反應混合物迴流2小時，繼之冷卻至25°C。而後將反應混合物倒入倒入冰水中 (包含數滴濃鹽酸），並使用二氣甲烷進行萃取，隨後將合併之有機部份以1M碳酸氫鈉水溶液清洗，再以飽和氣化鈉水容液清洗，使用無水硫酸鎂加以乾燥，並予_穠縮，最後以管柱色譜法加以純化（使用二氧化矽，洗提液：二氯甲燒/甲醇（95/5))，得到純PEO取代之EDOT，以檢磁共振儀與凝膠滲透色譜儀加以鑑定。合成4_(2,3-二氫-噻嗯基[3,4-b][l，4]二u号英_2_基_甲氧基）_ 丁烷-1-磺酸鈉鹽（M7) 5 10 15 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局貝工消費合作钍印製 20V was dissolved in p-toluenesulfonate (8.4 g, 44 mmol) under nitrogen blanket. Solution in the bite (2 ml). The reaction temperature was continuously maintained at about 25 to 30 by adding a single-based functionalized polyepoxybutene (a 750 g/mole in the molecule, 15 g, 2 Torr) to the bite. (3 〇 ml) of the solution f (4) the reaction mixture was stirred for another 2 hours, then poured into the ice $ i, g 义 'use - chloroformal to extract its aqueous phase, then combined with organic damage and 1M stone anti-g The mixture was washed with a solution of Mann aqueous sodium, and finally purified by column chromatography (using a oxidative chopping, eluent: dioxo and ethanol respectively) to obtain a pure tosylate functionalized polyethylene oxide. (2,3-Dihydro·Thienyl [3,4_b][1,4] Dioxin_2_Keixing Methanol 〇·91. 3. 2,000 [299738 A7 B7 V. Description of invention (U) Glucose, 5.8 mmol, dissolved in tetrahydrofuran (25 mL) under nitrogen blanket. Sodium hydride (〇·25 g) was added and stirring was continued for 30 minutes, and then a solution of terpene sulfonated polyethylene oxide (5.3 g) in tetrahydrogenbate (25 ml) was added by flooding. The reaction mixture was refluxed for 2 hours and then cooled to 25 °C. Then, the reaction mixture was poured into ice water (containing a few drops of concentrated hydrochloric acid), and extracted with di-methane, and then the combined organic portions were washed with a 1 M aqueous solution of sodium hydrogencarbonate, and then saturated with sodium chloride aqueous solution. Washed, dried with anhydrous magnesium sulfate, and _ condensed, and finally purified by column chromatography (using cerium oxide, eluent: methylene chloride / methanol (95/5)), to obtain pure PEO The EDOT was identified by a magnetic resonance spectrometer and a gel permeation chromatograph. Synthesis of 4_(2,3-dihydro-thienyl[3,4-b][l,4]di-u-indole-2-yl-methoxy-butane-1-sulfonate sodium salt (M7) ) 5 10 15 (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Bureau, Bayer Consumer Cooperation, Print 20

S〇3Na 將（2,3-二氫-噻嗯基[3,4_b][1，4]二噚英_2-基甲醇π” 克，40毫莫耳）於氮氣覆蓋下，溶解於四氣咬喃中（⑽ 升）。添加氫化鈉（1.76公克）並持續攪拌3〇分鐘，再以 65 良紙張尺度4用中Β 0家樣準（CNS)二規格⑽χ挪公^ 91* 3. 2,000 A7 1299738 B7___ 五、發明說明（以）加方式加入丁酮萘迫績内S旨（6·0公克）。加料後將反應混合物迴流3小時，繼之冷卻至25°c，將溶劑移除，並加入甲醇，混合物經攪拌，過濾後，將濾液濃縮。剩餘之油液藉加入己烷與乙醇予以固化，再加以攪拌，最後經過濾與乾 5 燥得到純4-(2,3-二氩-噻嗯基[3,4-b][l，4]二哼英-2-基-甲氧基）-丁烷-1-磺酸鈉鹽，以核磁共振儀與質譜儀加以鑑定。製備3，？:#烷基二氧噻吩共來物發明實例23至34 10 於聚（苯乙烯磺酸）存在下，EDOT與Ml至M7之水溶液共聚合反應（CP1至CP12) 發明實例23至34之3,4-伸烷基二氧噻吩共聚物之分散液，其製備係於25°C將87公克5.99重量％之聚（苯乙烯磺酸）[PSS](分子量=290,000)水溶液與413公克去離子 15 水，於一具有攪拌器與氮氣入口之1公升反應容器中進行混合。以氮氣於此混合物中冒泡30分鐘後，將EDOT(用量參見表18A或18B)與共單體（編號與用量參見表18A或 18B)加至此溶液，再以氮氣於此反應混合物中冒泡3(J)分鐘。隨後加入0.0375公克硫酸鐵與4.28公克硫代硫酸鈉 2〇以引發共聚合反應。反應混合物於25°C攪拌7小時後，另外添加0.7公克硫代硫酸鈉。再經16小時之反應時間後，將反應混合物以離子交換樹脂（50毫升Lewatit1^ S100MB + 80毫升LewatitTM M600MB)處理二次。得到之混合物另外於95°C熱處理2小時，並將獲得之黏稠混合物以高切變、 66 本紙張尺度適用中國國家標箏（CNS〉A4規格（210 X 297公* ) (請先閲讀背面之注意事項再填寫本頁) ft in I n I n 11 訂--------- 經濟部智«財產局貝工消货合作社印^ 91. 3. 2,000 1299738 A7 B7 五、發明說明 (微流化器於600巴）處理，經此過程後得到一種共聚物之分散液（其種類、製得數量與分散液中之共聚物濃度參見表 18A 與 18B) 〇經濟部智慧財產局貝工消f合作社印製表 18A: 發明實例編號 23 24 25 26 27 28 EDOT重量 [公克] 1.92 1.7 1.92 1.7 1.92 1.7 EDOT _莫耳] 13.5 11.96 13.5 11.96 13.5 11.96 共聚物 Ml Ml M2 M2 M4 M4 共聚物重量 [公克] 0.258 0.516 0.258 0.516 0.345 0.69 共聚物 [毫莫耳] 1.49 3.00 1.49 3.00 1.49 3.00 共聚物分散液 CP1 CP2 CP3 CP4 CP5 CP6 製得（共）聚物分散液之重量『公克1 570 470 560 495 450 455 分散液中之 (共）聚物濃度 [重量％] Q.78 0.82 0.82 0.83 0.76 1.14 (請先閲讀背面之注意事項再填寫本頁) 裝訂--------- 本紙張尺度瑱用中國國家標準（CNS>A4規格（210 297公釐） 91. 3. 2,000 1299738 A7 B7 五、發明說明（U〇表 18B: 發明實例編號 29 30 31 32 33 34 EDOT重量 [公克] 1.92 1.7 1.92 1.7 1.92 ί.7 ED0T [毫莫耳] 13.5 11.96 13.5 11.96 13.5 11.96 共聚物 M5 M5 M6 M6 M7 Μ7 共聚物重量 [公克] 0.477 0.954 1.104 2.208 0.496 0.992 共聚物 [毫莫耳] 1.49 3.00 1.49 3.00 1.49 3.00 共聚物分散液 CP7 CP8 CP9 CP10 CP11 CP12 製得（共）聚物分散液之重量 [公克] 690 680 380 510 51Q 60 分散液中之 (共）聚物濃度 [重量％] 0.65 0.70 0.80 0.80 0.80 0.82 發明實例23至34之共聚物之特徵共聚物之分子量係藉水性凝膠滲透色譜法測定，相對於聚（苯乙烯磺酸）鈉，其係以紫外線-可見光於785奈米之吸收偵測。於添加引發劑前，反應介質具有少於3毫克/ 公升氧之情況下，所製得共聚物之分子量，連同其於製得分散液中之濃度，以及共單體之莫耳％理論濃度，皆顯示於表19。 (請先閲讀背面之注意事項再填寫本頁)S〇3Na will be (2,3-dihydro-thienyl[3,4_b][1,4]dioxin-2-ylmethanol π" g, 40 mmol) dissolved in four under nitrogen blanket Gas smothered ((10) liters. Add sodium hydride (1.76 grams) and continue to stir for 3 minutes, then use 65 good paper size 4 with Β 0 sample (CNS) 2 specifications (10) χ 公 ^ ^ * * * * 2,000 A7 1299738 B7___ V. Description of invention (in) Adding butanone naphthalene to the effect of S (6·0 g). After the addition, the reaction mixture was refluxed for 3 hours, followed by cooling to 25 ° C to remove the solvent. And adding methanol, the mixture is stirred, filtered, and the filtrate is concentrated. The remaining oil is solidified by adding hexane and ethanol, and then stirred, finally filtered and dried to obtain pure 4-(2,3-di The sodium salt of argon-thienyl [3,4-b][l,4]dioxin-2-yl-methoxy)-butane-1-sulfonate was identified by a nuclear magnetic resonance spectrometer and a mass spectrometer. Preparation 3, ?: #alkyldioxythiophene co-ingredients Inventive Examples 23 to 34 10 In the presence of poly(styrenesulfonic acid), EDOT and Ml to M7 aqueous solution copolymerization (CP1 to CP12) Inventive Example 23 34 of 3, 4-alkylene a dispersion of a dioxythiophene copolymer prepared by treating 87 g of a 5.99 wt% aqueous solution of poly(styrenesulfonic acid) [PSS] (molecular weight = 290,000) with 413 g of deionized 15 water at 25 ° C. The stirrer was mixed with a 1 liter reaction vessel in a nitrogen inlet. After bubbling with nitrogen for 30 minutes in this mixture, EDOT (see Table 18A or 18B for amounts) and comonomer (see Table 18A or 18B for numbering and dosing) This solution was added and bubbled with nitrogen for 3 (J) minutes in this reaction mixture. Then, 0.0375 g of iron sulfate and 4.28 g of sodium thiosulfate were added to initiate copolymerization. The reaction mixture was stirred at 25 ° C for 7 hours. After that, an additional 0.7 g of sodium thiosulfate was added. After a reaction time of 16 hours, the reaction mixture was treated twice with an ion exchange resin (50 ml of Lewatit 1^S100MB + 80 ml of LewatitTM M600MB). The resulting mixture was additionally at 95°. C heat treatment for 2 hours, and the viscous mixture obtained is suitable for Chinese national standard kite (CNS>A4 specification (210 X 297 public*) with high shear and 66 paper scales (please read the notes on the back and fill in the form) Page) ft in I n I n 11 Order--------- Ministry of Economic Affairs «Property Bureau of the Bureau of Goods and Crafts Cooperatives Printing ^ 91. 3. 2,000 1299738 A7 B7 V. Invention Description (microfluidizer 600 bar) treatment, after this process to obtain a dispersion of a copolymer (the type, the amount of the copolymer and the concentration of the copolymer in the dispersion see Tables 18A and 18B) 〇 Ministry of Economic Affairs Intellectual Property Bureau Beigong Xiao F Co., Ltd. Table 18A: Inventive Example No. 23 24 25 26 27 28 EDOT Weight [g] 1.92 1.7 1.92 1.7 1.92 1.7 EDOT _ Moll] 13.5 11.96 13.5 11.96 13.5 11.96 Copolymer Ml Ml M2 M2 M4 M4 Copolymer Weight [g] 0.258 0.516 0.258 0.516 0.345 0.69 Copolymer [mole] 1.49 3.00 1.49 3.00 1.49 3.00 Copolymer dispersion CP1 CP2 CP3 CP4 CP5 CP6 The weight of the (co)polymer dispersion is obtained in gram 1 570 470 560 495 450 455 dispersion (co-polymer concentration) [% by weight] Q.78 0.82 0.82 0.83 0.76 1.14 (Please read the note on the back and fill out this page) Binding --------- This paper scale uses Chinese national standards (CNS>A4 specification (210 297 mm) 91. 3. 2,000 12997 38 A7 B7 V. INSTRUCTIONS (U) Table 18B: Invention Example No. 29 30 31 32 33 34 EDOT Weight [g] 1.92 1.7 1.92 1.7 1.92 ί.7 ED0T [mole] 13.5 11.96 13.5 11.96 13.5 11.96 Copolymer M5 M5 M6 M6 M7 Μ7 Copolymer weight [g] 0.477 0.954 1.104 2.208 0.496 0.992 Copolymer [mole] 1.49 3.00 1.49 3.00 1.49 3.00 Copolymer dispersion CP7 CP8 CP9 CP10 CP11 CP12 prepared (co)polymer dispersion Weight [g] 690 680 380 510 51Q 60 Concentration of (co)polymer in the dispersion [% by weight] 0.65 0.70 0.80 0.80 0.80 0.82 Characteristics of the copolymer of Inventive Examples 23 to 34 The molecular weight of the copolymer is infiltrated by aqueous gel Chromatographic determination, relative to sodium poly(styrenesulfonate), was detected by UV-visible absorption at 785 nm. The molecular weight of the copolymer produced, together with the concentration in the resulting dispersion, and the theoretical molar concentration of comonomer, prior to the addition of the initiator, with less than 3 mg/liter oxygen. Both are shown in Table 19. (Please read the notes on the back and fill out this page)

經濟部智慧財產局貝工消#合作社印製本紙張尺度適用中國國家楳準（CNS〉A4規格（210 297公* ) 91. 3. 2,000 1299738 Α7 Β7 五、發明說明（t/ 表19: 共聚物編號共單體編號莫耳％共聚物/PSS之濃度 [重量％] 分子量 [785奈米] CP1Ministry of Economic Affairs Intellectual Property Bureau Beigongxiao #Cooperative Printed Paper Size Applicable to China National Standard (CNS>A4 Specification (210 297 public*) 91. 3. 2,000 1299738 Α7 Β7 V. Invention Description (t/ Table 19: Copolymerization Material number, common monomer number, mole %, concentration of copolymer/PSS [% by weight] molecular weight [785 nm] CP1

Ml 10 0.78 620,000 CP2Ml 10 0.78 620,000 CP2

Ml 20 0.82 580,000 CP3 M2 10 0.82 670,000 CP4 M2 20 0.83 725,000 CP5 M4 10 0.76 560,000 CP6 M4 20 1.14 540,000 CP7 M5 10 0.65 650,000 CP8 M5 20 0.70 725,000 CP9 M6 10 0.8 430,000 CP10 M6 20 0.8 415,000 CP11 M7 10 0.80 750,000 CP12 M7 20 0.82 780,000 (請先閱讀背面之注意事項再填寫本頁) 裝 15 使用包含發明實例23至34共聚物之分散液製備塗覆層使用發明實例23至34之分散液製備塗覆分散液，其製法與前述比較實例1與2，及發明實例1與2之分散液相同，用以製造塗覆層。藉使用醫用'刀塗覆於附屬之175 微米聚（對苯二曱酸乙烯酯）載體上，並於45°C乾燥3.5分鐘，其具有下列之組成： I I I I 一 « d n n n i n t— I 丨經濟部智慧財產局具工消t合作钍印製 20 ADOT與共單體（或PEDOT)之共聚物 ADOT與共單體（或PEDOT)/PSS 之共聚物 ZONYL® FS0100 3-環氧丙烷丙基三甲基矽烷偏二氣乙烯、甲基丙烯酸酯與衣 69 28.9毫克/公尺2 100毫克/公尺2 8毫克/公尺2 100毫克/公尺2 100毫克/公尺2 91· 3· 2,000 本紙張尺度通用中國國家楳準（〇^)八4規格（210»<297公釐) 1299738 A7 五、發明說明（fe) 康酸之共聚物膠乳（88/10/2) N-曱基吡咯烧酮 2毫升/公尺2 5 10 包含發明實例23至34共聚物之塗覆層之特徵一般而言，所期望之EDOT共聚物性能介於相對均聚物者之間。均聚物EDOT, Ml與M3於相同條件下進行電聚合，具有可相匹比之電阻率，然而均聚物M2，M4與 M6具有較電聚合之PEDOT明顯較高之電阻率，參見表2= 表20:Ml 20 0.82 580,000 CP3 M2 10 0.82 670,000 CP4 M2 20 0.83 725,000 CP5 M4 10 0.76 560,000 CP6 M4 20 1.14 540,000 CP7 M5 10 0.65 650,000 CP8 M5 20 0.70 725,000 CP9 M6 10 0.8 430,000 CP10 M6 20 0.8 415,000 CP11 M7 10 0.80 750,000 CP12 M7 20 0.82 780,000 (Please read the note on the back side and fill out this page) Pack 15 Prepare the coating layer using the dispersion containing the copolymers of Inventive Examples 23 to 34. Using the dispersions of Inventive Examples 23 to 34, prepare a coating dispersion, The preparation method was the same as that of the above Comparative Examples 1 and 2, and the dispersions of Inventive Examples 1 and 2, for producing a coating layer. It was applied to the attached 175 micron poly(vinyl terephthalate) carrier by a medical 'knife and dried at 45 ° C for 3.5 minutes, and it had the following composition: IIII A « dnnnint — I 丨 Ministry of Economy Intellectual Property Bureau has a cooperation with the company. 20 Copolymer of ADOT and Co-monomer (or PEDOT) Copolymer of ADOT and Co-monomer (or PEDOT)/PSS ZONYL® FS0100 3-Epoxypropane propyl trimethacrylate Base hexanes, ethylene oxide, methacrylate and clothing 69 28.9 mg / meter 2 100 mg / meter 2 8 mg / meter 2 100 mg / meter 2 100 mg / meter 2 91 · 3 · 2,000 Paper Scale General China National Standard (〇^) 八4 Specification (210»<297 mm) 1299738 A7 V. Invention Description (fe) Copolymer Copolymer Latex (88/10/2) N-Mercaptopyrrole Ketone 2 ml / meter 2 5 10 Characteristics of the coating layer comprising the copolymers of Inventive Examples 23 to 34 In general, the desired EDOT copolymer properties are between the relative homopolymers. The homopolymer EDOT, Ml and M3 are electropolymerized under the same conditions, and have comparable electrical resistivity. However, the homopolymers M2, M4 and M6 have significantly higher electrical resistivity than the electrically polymerized PEDOT, see Table 2. = Table 20:

20 包含發明實例23至34共聚物之塗覆層，直表面電阻與光學密度之測定與前述包含比較實例1與2，及發明實例1與2均聚物之塗覆層相同，其結果顯示於表2/。、經濟部智慧財產局貝X消貧合作社印製本紙張尺度適用中國國家標準（CNS〉A4規格（210 X 297公* ) 91. 3. 2,000 f锖先閲讀背面之注意事項再填寫本頁)20 The coating layer comprising the copolymers of Inventive Examples 23 to 34, the direct surface resistance and the optical density were measured in the same manner as the coating layers comprising Comparative Examples 1 and 2, and Inventive Examples 1 and 2 homopolymers, the results of which are shown in Table 2/. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, the X X Poverty Cooperative. This paper scale applies to the Chinese national standard (CNS>A4 specification (210 X 297 public*) 91. 3. 2,000 f锖Read the back of the note and fill out this page)

1299738 A7 B7 五、發明說明（θ ) 表21: 發明實例編號 (共)聚物編號共單體包含(共)聚物之塗覆層編號莫耳％表面電阻 [歐姆/正方] 曝露於SuntestTM 48小時後之表面電阻對起始表面電阻之比率外徑 1 PEDOT 1 — 0 1200 13 0.066 2 PEDOT 2 -- 0 1200 12 0.065 3 CPI Mi 10 1300 21 0.068 4 CP2 Ml 20 1400 27 0.068 5 CP3 M2 10 1300 24 0.067 6 CP4 M2 20 ，1200 20 0.067 7 CP5 M3 10 2200 74 0.060 8 CP6 M3 20 2500 72 0.063 9 CP7 M4 10 1700 38 0.067 10 CP8 M4 20 1300 24 0.067 11 CP9 M5 Ϊ0 5800 91 0.067 12 CP10 M5 20 23000 1766 Q.062 13 CP11 M6 10 1900 28 0.069 14 CP12 M6 20 1800 0.066 (請先閲讀背面之注意事項再填寫本頁) 裝經濟部智«財產局貝工>#費合作社印製包含CPI，CP2，CP3，CP4與CP8.等共聚物，及EDOT 與Ml，M2與M5之共聚物，之塗覆層，令人驚訝地發現 \ 具有與PEDOT 1與PEDOT 2可相匹比之性能。本發明可包括任何於此含蓄地或明白地或總括地揭示之特徵或特徵之組合，不論其是否與本申請專利之發明相關聯。鑑於前文之敘述，對精於此方面技藝者應明顯得知，於本發明範圍内可作各種的修飾。訂--------- 本紙張尺度迷用中國國家楳準（CNS)A4規格（210 X 297公* ) 91. 3. 2,0001299738 A7 B7 V. INSTRUCTIONS (θ) Table 21: Invention Example Number (co)polymer number co-monomer containing (co)polymer coating layer number mol% Surface resistance [ohm/square] Exposure to SuntestTM 48 Ratio of surface resistance to initial surface resistance after hours OD 1 PEDOT 1 — 0 1200 13 0.066 2 PEDOT 2 -- 0 1200 12 0.065 3 CPI Mi 10 1300 21 0.068 4 CP2 Ml 20 1400 27 0.068 5 CP3 M2 10 1300 24 0.067 6 CP4 M2 20 , 1200 20 0.067 7 CP5 M3 10 2200 74 0.060 8 CP6 M3 20 2500 72 0.063 9 CP7 M4 10 1700 38 0.067 10 CP8 M4 20 1300 24 0.067 11 CP9 M5 Ϊ0 5800 91 0.067 12 CP10 M5 20 23000 1766 Q.062 13 CP11 M6 10 1900 28 0.069 14 CP12 M6 20 1800 0.066 (Please read the note on the back and fill out this page) Install the Ministry of Economics «Property Bureau Beacon> #费合作社Printing includes CPI, CP2 Copolymers such as CP3, CP4 and CP8., and copolymers of EDOT and Ml, M2 and M5, have surprisingly found that they have comparable properties to PEDOT 1 and PEDOT 2 . The present invention may include any combination of features or features disclosed herein either implicitly or explicitly or collectively, whether or not it is associated with the invention of the present application. In view of the foregoing, it will be apparent to those skilled in the art that various modifications are possible within the scope of the invention. Order --------- This paper scale is confusing with China National Standard (CNS) A4 specification (210 X 297 public*) 91. 3. 2,000

Claims

1299738 修正i補充•丨六、申請專科範圍 ίο 15 2. 3· ^利申請案第91134680號修正 --Amended Claims in .中文本-附件(二), Chinese - EncLfID ^氏國97年1月丨I日送呈） (Submitted on January π, 2008) -種製備-種聚塞吩或4吩共聚物之水性或非水性溶液或分散液之方法，其包含依式⑴之結構單元：1299738 Amendment i Supplement • Sixth, apply for specialist scope ίο 15 2. 3· ^ Application No. 91134680 Amendment--Amended Claims in . Chinese-Annex (II), Chinese - EncLfID ^The State of January 97丨(Imitted on January π, 2008) - A method for preparing an aqueous or non-aqueous solution or dispersion of a polycemente or a 4-phene copolymer comprising a structural unit according to formula (1):

(I) 20 4. 其中R與R各自獨立地代表氫、或CM—烷基基團、或連同生成一種選擇地取代之Cly伸烷基殘餘物，包括下述步驟：製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後’該反應介質中每公升該反應介質存在少於3毫克之氧。 i 根據申請專利範圍第1項之方法，其中當添加該引發劑後’该反應介質中每公升該反應介質存在少於1.5毫克之氧。 & 根據申請專利範圍第丨項之方法，其中當添加該y發劑後，該反應介質中每公升該反應介質存在少於〇·5毫克之氧。根據申請專利範圍第1項之方法，其中依式⑴之該結構單元係選自群組包括:選擇地烷基基團取代之3，^伸甲基二氧基噻吩單元、選擇地烷基或芳基基團取代之 3’4_伸乙基二氧基嗔吩單元，選擇地烧基或芳基基團取(I) 20 4. wherein R and R each independently represent hydrogen, or a CM-alkyl group, or together with the formation of a selectively substituted Cly alkyl residue, comprising the steps of: preparing a polythiophene or thiophene copolymer In the case of a reaction medium in which a polyanion is present, an initiator is used, under oxidizing or reducing conditions, and in an inert environment, such that after the addition of the initiator, the reaction medium is present per liter of the reaction medium. Less than 3 mg of oxygen. i. The method of claim 1, wherein less than 1.5 milligrams of oxygen per liter of the reaction medium is present in the reaction medium after the addition of the initiator. & </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; The method of claim 1, wherein the structural unit according to formula (1) is selected from the group consisting of: a selected alkyl group substituted 3, a methyldioxythiophene unit, a selected alkyl group or An aryl group substituted 3'4_extended ethyldioxy porphin unit, selected as a decyl or aryl group

規格（210x297公釐） 91535·範圍-接 4 訂嬢〇ς 8 8 〇c A B C η 經濟部智慧財產局員工消費合作社印製 1299738 六、申請專利範圍代之3,4-伸乙基二氧基噻吩單元，一種依照式(I)之單元，其中R1與R2同為1，2-環己烯基團、選擇地烷基或芳基基團取代之3,4-伸丙基二氧基噻吩單元、選擇地烷基或芳基基團取代之3,4-伸丁基二氧基噻吩單元，與選 5 擇地烷基或芳基基團取代之3,4-伸戊基二氧基噻吩單元。 5. 根據申請專利範圍第1項之方法，其中該噻吩共聚物為一種於25°C時水中溶解度低於2.2公克/公升之3,4-伸烷基二氧噻吩化合物、與一種於25°C時水中溶解度 10 至少為2.2公克/公升之3,4-伸烧基二氧噻吩化合物以及一種聚陰離子之共聚物。 6. 根據申請專利範圍第5項之方法，其中該於25°C時水中溶解度至少為2.2公克/公升之3,4-伸烷基二氧噻吩化合物，係選自群組包括：3,4-二氫-2H-噻嗯基[3,4- 15 b][l，4]二咩英-2-基-甲醇、3,4_二氫-2H-噻嗯基[3,4- b][l，4]二畤呼_3_醇、（2,3-二氫-噻嗯基[3,4-b][l，4]二畤英-2-基-甲氧基）-乙酸乙醋、（2,3 -二鼠-ϋ塞嗯基[3,4_ b][l，4]二呤英-2-基-曱氧基)_乙酸、2-{2-[2-(2-曱氧基·乙醯氧基)-乙醯氧基]-乙氧曱基} -2,3-二氫-噻嗯基[3，4- 20 b][l，4]二畤英與 4-(2,3_二氫-噻嗯基[3,4-b][l，4]二哼英- 2_基-甲氧基)_ 丁烷小磺酸鈉鹽。 7. 根據申請專利範圍第1項之方法，其中該聚陰離子為聚（苯乙烯績酸）。 8. 根據申請專利範圍第1項之方法，其中該惰性環境為本紙張尺度適用中國國家標準(CNS)A4規格（210 χ 297公釐）Specifications (210x297 mm) 91535·Scope-connected 4 Ordering 8 8 〇c ABC η Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1299738 VI. Patent application scope 3,4-extended ethyldioxy a thiophene unit, a unit according to formula (I) wherein R1 and R2 are 1,2-cyclohexenyl groups, optionally substituted with alkyl or aryl groups, 3,4-propyldioxythiophene a 3,4-tert-butyldioxythiophene unit substituted with a unit selected from an alkyl or aryl group, and a 3,4-exopentyldioxy group substituted with a decyl or aryl group Thiophene unit. 5. The method of claim 1, wherein the thiophene copolymer is a 3,4-alkylenedioxythiophene compound having a solubility in water of less than 2.2 g/liter at 25 ° C, and one at 25 ° A copolymer of 3,4-extended dioxythiophene compound having a solubility of 10 in water of at least 2.2 g/liter and a polyanion. 6. The method of claim 5, wherein the 3,4-alkylenedioxythiophene compound having a solubility in water of at least 2.2 g/liter at 25 ° C is selected from the group consisting of: 3, 4 - dihydro-2H-thienyl [3,4- 15 b][l,4]dioxin-2-yl-methanol, 3,4-dihydro-2H-thienyl [3,4- b ][l,4]二畤呼_3_ol, (2,3-dihydro-thienyl [3,4-b][l,4]dioxin-2-yl-methoxy)- Acetate acetate, (2,3-di- oxan-[3,4_b][l,4]dioxin-2-yl-decyloxy)-acetic acid, 2-{2-[2- (2-decyloxyethyloxy)-ethenyloxy]-ethoxycarbonyl} -2,3-dihydro-thenyl [3,4- 20 b][l,4]dioxin And sodium 4-(2,3-dihydro-thienyl [3,4-b][l,4]dioxin-2-yl-methoxy-butane small sulfonic acid sodium salt. 7. The method of claim 1, wherein the polyanion is poly(styrene). 8. According to the method of claim 1, wherein the inert environment is the Chinese National Standard (CNS) A4 specification (210 297 297 mm).

1299738 經濟部智慧財產局員工消費合作社印製六、申請專利範圍 10 15 20 A8 B8 C8 一種氮氣、氦氣或氬氣之環境。 9· 一種聚嗔吩或嗜吩共聚物之水性分散液，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性分散液之方法，其包含依式⑴之結構單元·· R- ···. 0- •rH ...........m 其中R1與R2各自獨立地代表氫、或Cl_5-烷基基團、戈連同生成一種選擇地取代之Ci-5-伸烧基殘餘物，包括下述步驟:製備聚喧吩或喧吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後’該反應介質中每公升該反應介質存在少於3毫克之氧。 10·—種聚噻吩或噻吩共聚物之非水性分散液，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性分散液之方法，其包含依式⑴之結構單元： R- (I) 本紙張尺度適用中關家標準(cns)A4規格（別χ 297公爱）1299738 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing VI. Patent application scope 10 15 20 A8 B8 C8 A nitrogen, helium or argon environment. 9. An aqueous dispersion of a polyporphin or a phenanthrene copolymer, which obtains a method for preparing an aqueous dispersion of a polythiophene or a thiophene copolymer, comprising a structural unit according to formula (1). ···. 0- •rH ...........m where R1 and R2 each independently represent hydrogen, or a Cl_5-alkyl group, together with a selectively substituted Ci-5- Stretching residue, comprising the steps of: preparing a polyporphin or a porphin copolymer, using an initiator in a reaction medium in which a polyanion is present, under oxidizing or reducing conditions, and in an inert environment Thus, when the initiator is added, there is less than 3 milligrams of oxygen per liter of the reaction medium in the reaction medium. 10. A non-aqueous dispersion of a polythiophene or thiophene copolymer obtained by a process for preparing a non-aqueous dispersion of a polythiophene or thiophene copolymer comprising a structural unit according to formula (1): R- (I) This paper scale applies to the Chinese National Standards (cns) A4 specification (Do not 297 297 public)

〇ς 8 8 〇c A B cn 1299738 夂'申請專利範圍 5 其中R1與R2各自獨立地代表氫、或Q-5-烷基基團、或連同生成一種選擇地取代之Ci_5-伸烧基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 10 R1—0 0—R丁 • ! i li 15 一 (I) 11·一種聚噻吩或噻吩共聚物之水性溶液，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包含依式(I)之結構單元： η 經濟部智慧財產局員工消費合作社印製 20 其中R1與R2各自獨立地代表氫、或烷基基團、或連同生成一種選擇地取代之Cw伸烧基殘餘物，包括下述步驟:製備聚喧吩或σ塞吩共聚物時’於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3薹克之氧。 12·—種聚噻吩或噻吩共聚物之非水性溶液，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性溶液本紙張尺度適用中國國家標準(CNS)A4規格（210x297公釐） ----- 1299738 A8 B8 C8 六、申請專利範圍之方法，其包含依式(I)之結構單元: (I) 其中R1與R2各自獨立地代表氫、或C^-烷基基團、或連同生成一種選擇地取代之伸烷基殘餘物，包 10 括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 15 13.—種包含聚噻吩或噻吩共聚物之水性分散液之水性或非水性分散液用於塗覆物件之用途，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性分散液之方法，其包含依式(I)之結構單元：經濟部智慧財產局員工消費合作社印制衣〇ς 8 8 〇c AB cn 1299738 夂 'Application No. 5 wherein R 1 and R 2 each independently represent hydrogen, or a Q-5-alkyl group, or together with the formation of a selectively substituted Ci_5-alkylate residue , comprising the steps of: preparing a polythiophene or a thiophene copolymer, using an initiator in a reaction medium in which a polyanion is present, under oxidizing or reducing conditions, and in an inert environment, such that when the initiator is added Thereafter, less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium. 10 R1—0 0—R • • ! i li 15 I(I) 11·An aqueous solution of a polythiophene or thiophene copolymer, which is obtained by a method for preparing an aqueous solution of a polythiophene or thiophene copolymer , which comprises a structural unit according to formula (I): η Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperative Print 20 wherein R1 and R2 each independently represent hydrogen, or an alkyl group, or together with a selectively substituted Cw extension a base residue comprising the steps of: preparing a polyporphin or a σ-septene copolymer using an initiator in a reaction medium in which a polyanion is present, under oxidizing or reducing conditions, and in an inert environment Thus, when the initiator is added, less than 3 grams of oxygen per liter of the reaction medium is present in the reaction medium. 12. A non-aqueous solution of a polythiophene or thiophene copolymer obtained by a non-aqueous solution for preparing a polythiophene or thiophene copolymer. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm). ----- 1299738 A8 B8 C8 6. A method for applying for a patent, comprising a structural unit according to formula (I): (I) wherein R1 and R2 each independently represent hydrogen or a C^-alkyl group Or in combination with the formation of a selectively substituted alkyl residue, the process comprising the steps of: preparing a polythiophene or a thiophene copolymer, using an initiator in the reaction medium in which the polyanion is present, in oxidation or reduction The conditions are carried out, and in an inert environment, such that when the initiator is added, less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium. 15 13. Use of an aqueous or non-aqueous dispersion comprising an aqueous dispersion of a polythiophene or a thiophene copolymer for coating articles obtained by an aqueous dispersion for preparing a polythiophene or thiophene copolymer The method comprises the structural unit according to formula (I): Ministry of Economic Affairs, Intellectual Property Office, employee consumption cooperative, printed clothing

• ί . I * I 孓1 〇 0—R I 20 R °χ / I Λ- (I) 其中R1與R2各自獨立地代表氫、或Cw烷基基團、本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） 1299738 〇ς 8 8 〇c A B C η 六、申請專利範圍 10 或連同生成一種選擇地取代之C^-伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 14. 一種包含聚嗔吩或嗔吩共聚物之非水性分散液之水性或非水性分散液用於塗覆物件之用途，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性分散液之方法，其包含依式⑴之結構單元： •rH 15 經濟部智慧財產局員工消費合作社印製 20 (I); 其中R1與R2各自獨立地代表氫、或Cw-烷基基團、或連同生成一種選擇地取代之C^-伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 15.—種包含聚噻吩或噻吩共聚物之水性溶液之水性或非水性分散液用於塗覆物件之用途，其獲得可藉一種用於• ί . I * I 孓1 〇0—RI 20 R °χ / I Λ- (I) where R1 and R2 each independently represent hydrogen or a Cw alkyl group, and the paper scale applies to the Chinese National Standard (CNS) A4 size (210 X 297 mm) 1299738 〇ς 8 8 〇c ABC η VI. Application No. 10 or together with the formation of a selectively substituted C^-alkyl residue, including the steps of: preparing polythiophene or In the case of a thiophene copolymer, an initiator is used in the reaction medium in which the polyanion is present, under oxidizing or reducing conditions, and in an inert environment such that the reaction is per liter of the reaction medium after the addition of the initiator The medium has less than 3 milligrams of oxygen. 14. Use of an aqueous or non-aqueous dispersion comprising a non-aqueous dispersion of a polyporphin or a porphin copolymer for coating articles, obtainable by a non-aqueous preparation for preparing a polythiophene or thiophene copolymer A method of dispersing a liquid comprising a structural unit according to formula (1): • rH 15 Ministry of Economy, Intellectual Property Office, Staff Consumer Cooperative, Printing 20 (I); wherein R1 and R2 each independently represent hydrogen, or a Cw-alkyl group, Or together with the formation of a selectively substituted C^-alkylene residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer, using an initiator in the reaction medium in which the polyanion is present, in oxidation or reduction The conditions are carried out, and in an inert environment, such that when the initiator is added, less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium. An aqueous or non-aqueous dispersion comprising an aqueous solution of a polythiophene or a thiophene copolymer for use in coating articles, which can be obtained by using one

本紙張尺度適用中國國家標準(CNS)A4規格（210 χ 297公釐） A8 B8 C8 _D8_ 經濟部智慧財產局員工消費合作社印製 1299738 六、申請專利範圍製備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包含依式(I)之結構單元：This paper scale applies to China National Standard (CNS) A4 specification (210 297 297 mm) A8 B8 C8 _D8_ Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1299738 VI. Patent application scope Preparation of an aqueous solution of polythiophene or thiophene copolymer The method comprising the structural unit according to formula (I):

其中R1與R2各自獨立地代表氫、或Ci_5-烷基基團、或連同生成一種選擇地取代之Ci_5-伸烷基殘餘物，包 10 括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 15 16·—種包含聚嗜吩或喧吩共聚物之非水性溶液之水性或非水性分散液用於塗覆物件之用途，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性溶液之方法，其包含依式(I)之結構單元：Wherein R1 and R2 each independently represent hydrogen, or a Ci_5-alkyl group, or together with the formation of a selectively substituted Ci_5-alkylene residue, comprising the steps of: preparing a polythiophene or thiophene copolymer, Using an initiator in the reaction medium in which the polyanion is present, under oxidizing or reducing conditions, and in an inert environment, such that when the initiator is added, there is less than 3 per liter of the reaction medium in the reaction medium. Mg of oxygen. 15 16 - an aqueous or non-aqueous dispersion of a non-aqueous solution comprising a poly (phenophene or porphin copolymer) for use in coating articles, which is obtainable by a non-polyester or thiophene copolymer A method of aqueous solution comprising a structural unit according to formula (I):

其中R1與R2各自獨立地代表氫、或C^-烷基基團、本紙張尺度適用中國國家標準(CNS)A4規格（210x297公釐）Wherein R1 and R2 each independently represent hydrogen or a C^-alkyl group, and the paper size applies to the Chinese National Standard (CNS) A4 specification (210x297 mm).

1299738 A8 B8 C81299738 A8 B8 C8

六、申請專利範圍或連同生成一種選擇地取代之Cw-伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發 5 劑後，該反應介質中每公升該反應介質存在少於3 I 克之氧。、笔 17.—種包含聚噻吩或噻吩共聚物之水性溶液之水性或非水性溶液用於塗覆物件之用途，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包 10 含依式(I)之結構單元： '6. The scope of the patent application or together with the formation of a selectively substituted Cw-alkylene residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer, using an initiator in the reaction medium in which the polyanion is present, Oxidation or reduction, and in an inert environment, such that after the addition of the initiator 5, less than 3 I of oxygen per liter of the reaction medium is present in the reaction medium. 17. The use of an aqueous or non-aqueous solution comprising an aqueous solution of a polythiophene or thiophene copolymer for coating articles, which is obtained by a method for preparing an aqueous solution of a polythiophene or thiophene copolymer , its package 10 contains structural units of formula (I): '

15 (i) 經濟部智慧財產局員工消費合作社印製 20 其中R1與R2各自獨立地代表氫、或Cm-烷基基團、或連同生成一種選擇地取代之Cm-伸烧基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 18·—種包含聚噻吩或噻吩共聚物之非水性溶液之水性或非水性溶液用於塗覆物件之用途，其獲得可藉一種用於本紙張尺度適用中關家標準(CNS)A4規格(210 X 297公釐）15 (i) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Print 20 where R1 and R2 each independently represent hydrogen, or a Cm-alkyl group, or together with a selectively substituted Cm-extension base residue, including The following steps: when preparing a polythiophene or a thiophene copolymer, using an initiator in a reaction medium in which a polyanion is present, under oxidizing or reducing conditions, and in an inert environment, such that when the initiator is added, There is less than 3 milligrams of oxygen per liter of the reaction medium in the reaction medium. 18. An aqueous or non-aqueous solution comprising a non-aqueous solution of a polythiophene or a thiophene copolymer for use in coating articles, which is obtainable by a Medium Standard (CNS) A4 specification for use on this paper scale ( 210 X 297 mm)

1299738 B8 C8 _m_ 六、申請專利範圍製備一種聚喧吩或σ塞吩共聚物之非水性溶液之方法，其包含依式(I)之結構單元： R1—0、〇——R丁1299738 B8 C8 _m_ VI. Scope of Application Patent A method for preparing a non-aqueous solution of a polyporphin or σ-cephene copolymer comprising a structural unit according to formula (I): R1—0, 〇-R

經濟部智慧財產局員工消費合作社印製 (I) 其中R1與R2各自獨立地代表氫、或烷基基團、或連同生成一種選擇地取代之Ci_5-伸烧基殘餘物，包 10 括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 15 19. 一種包含聚噻吩或噻吩共聚物之水性分散液之可印刷糊狀物，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性分散液之方法，其包含依式(I)之結構單元：Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative (I) wherein R1 and R2 each independently represent hydrogen, or an alkyl group, or together with a selectively substituted Ci_5-extension base residue, including the following Step: preparing a polythiophene or thiophene copolymer, using an initiator in a reaction medium in which a polyanion is present, under oxidizing or reducing conditions, and in an inert environment, such that when the initiator is added, the reaction There is less than 3 milligrams of oxygen per liter of the reaction medium in the medium. 15 19. A printable paste comprising an aqueous dispersion of a polythiophene or a thiophene copolymer, which obtains a method for preparing an aqueous dispersion of a polythiophene or a thiophene copolymer, which comprises a formula (I) ) The structural unit:

(I) 其中R1與R2各自獨立地代表氫、或烷基基團、本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） 1299738 A8 B8 C8 m 六、申請專利範圍或連同生成一種選擇地取代之Cw-伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發 5 劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 20.—種包含聚噻吩或噻吩共聚物之非水性分散液之可印刷糊狀物，其獲得可藉一種用於製備一種聚Π塞吩或嗔吩共聚物之非水性分散液之方法，其包含依式⑴之結構 10 單元··(I) wherein R1 and R2 each independently represent hydrogen or an alkyl group, the paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299738 A8 B8 C8 m VI. Application for patent scope or Forming a selectively substituted Cw-alkylene residue comprising the steps of: preparing a polythiophene or a thiophene copolymer, using an initiator in a reaction medium in which a polyanion is present, under oxidation or reduction conditions, And in an inert environment such that less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium upon addition of the initiator. 20. A printable paste comprising a non-aqueous dispersion of a polythiophene or a thiophene copolymer, which is obtained by a process for preparing a non-aqueous dispersion of a polydecene or a porphin copolymer, Contains the structure 10 unit according to formula (1)··

經濟部智慧財產局員工消費合作社其中R1與R2各自獨立地代表氫、或Cw烷基基團、或連同生成一種選擇地取代之C^-伸烷基殘餘物，包括下述步驟:製備聚嗔吩或嗜吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原 20 之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 21.—種包含聚噻吩或噻吩共聚物之水性溶液之可印刷糊狀物，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚製 1299738Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative where R1 and R2 each independently represent hydrogen, or a Cw alkyl group, or together with the formation of a selectively substituted C^-alkyl residue, including the following steps: preparing polyfluorene When the pheno- or phenanthrene copolymer is used, an initiator is used in the reaction medium in which the polyanion is present, under oxidation or reduction 20, and in an inert environment, so that when the initiator is added, the reaction medium is There is less than 3 milligrams of oxygen per liter of the reaction medium. 21. A printable paste comprising an aqueous solution of a polythiophene or a thiophene copolymer, obtainable by the use of a polythiophene or thiophene copolymer 1299738

六、申請專利範圍物之水性溶液之方法，其包含依式(I)之結構單元:6. A method of applying for a patented aqueous solution comprising a structural unit according to formula (I):

10 其中R1與R2久白或連同生$ ^ ^地代表氫、或Cl.5成基基團、 S制t擇地取代之Ci·5舰基殘餘物，包陰離子之反吩或嗔吩共聚物時，於存在有聚 : Μ;丨貝中使用一種引發劑，在氧化或還原之耗件下，及於惰性環中趸原劑後，w /¾ Μ 士/ 付當添加該引發古^反應W中每公升該反應介質存在少於3毫克之氧。 & 15 22.-種包含料吩料吩找物之非水性驗狀物二其獲得可藉—種用於製備―種聚_^ = 元： … 味叫人丞-刀口基口聚物之非水性溶液之方法，其包含依式⑴之結構單 R- Ό一R3" 經濟部智慧財產局員工消費合作社印製 20 (I) 其中R1與R2各自獨立地代表氫、或Cw烷基基團、或連同生成一種選擇地取代之Cl-s_伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚10 wherein R1 and R2 are white or together with the birth of $ ^ ^ to represent hydrogen, or Cl. 5 alkyl group, S to replace the Ci·5 ship base residue, the anion of reverse porphin or porphin copolymerization When present, in the presence of poly: Μ; use an initiator in mussels, under the consumption of oxidizing or reducing, and after the inerting agent in the inert ring, w / 3⁄4 / / pay when adding the trigger ^ There is less than 3 mg of oxygen per liter of the reaction medium in the reaction. & 15 22.- Non-aqueous test substance containing the material quotation of the material, and the obtained material can be used for the preparation of the seed-growth _^ = yuan: ... A method of non-aqueous solution comprising a structure of formula (1), single R-Ό-R3" Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, Printing 20 (I) wherein R1 and R2 each independently represent hydrogen or a Cw alkyl group Or, together with the formation of a selectively substituted Cl-s_alkylene residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer, in the presence of a poly

本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） 10 R-ο (I) 15 經濟部智慧財產局員工消費合作社印製 20This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 10 R-ο (I) 15 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print 20

1299738 B8 ___ C8 " " ------------- 六、申請專利範圍陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3 克之氧。 5 23 •種使用包含聚噻吩或噻吩共聚物之水性分散液之水性或非水性分散液製得之導電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性分散液之方法’其包含依式⑴之結構單元： Ο—R2" 其中R1與R2各自獨立地代表氫、或（^ ^烷基基團或連同生成一種選擇地取代之（：^5_伸烷基殘餘物，括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有陰離子之反應介質中使用一種引發劑，在氧化或還之條件下，及於惰性環境中進行，使得#添加該引劑後，該反應介質中每公升該反應介質存在少於3 克之氧。 •一種使用包含聚噻吩或噻吩共聚物之非水性分散液之性或非水性分散液製得之導電層，其獲得可藉一種於製備一種聚噻吩或噻吩共聚物之非水性分散液之法，其包含依式(I)之結構單元：中國國家標準(CNS)A4規格（210 χ 297公釐）1299738 B8 ___ C8 "" ------------- VI. Patent application range Anionic reaction medium is used in an oxidizing or reducing condition and in an inert environment. Thus, when the initiator is added, less than 3 grams of oxygen per liter of the reaction medium is present in the reaction medium. 5 23 • A conductive layer prepared using an aqueous or non-aqueous dispersion comprising an aqueous dispersion of a polythiophene or a thiophene copolymer, which is obtained by a method for preparing an aqueous dispersion of a polythiophene or thiophene copolymer 'It contains a structural unit according to formula (1): Ο-R2" wherein R1 and R2 each independently represent hydrogen, or (^^alkyl group or together with the formation of a selectively substituted (:^5_alkyl residue) Including the following steps: when preparing a polythiophene or thiophene copolymer, an initiator is used in a reaction medium in which an anion is present, and is oxidized or further, and in an inert environment, so that # after adding the primer The reaction medium contains less than 3 grams of oxygen per liter of the reaction medium. • A conductive layer made using a non-aqueous dispersion of a non-aqueous dispersion comprising a polythiophene or a thiophene copolymer, which can be obtained by a A method for preparing a non-aqueous dispersion of a polythiophene or a thiophene copolymer, comprising a structural unit according to formula (I): Chinese National Standard (CNS) A4 specification (210 χ 297 mm)

1299738 〇ς 8 8 0C A B c D 六、申請專利範圍1299738 〇ς 8 8 0C A B c D VI. Patent application scope

5 ⑴ 其中R1與R2各自獨立地代表氫、或烷基基图、或連同生成一種選擇地取代之伸烷基殘餘物，包括下述步驟··製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原 0 之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 25·—種使用包含聚噻吩或噻吩共聚物之水性溶液之水性或非水性分散液製得之導電層，其獲得可藉一種用於製 5 備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包含依式⑴之結構單元：經濟部智慧財產局員工消費合作社印制衣 205 (1) wherein R 1 and R 2 each independently represent hydrogen, or an alkyl group diagram, or together with the formation of a selectively substituted alkyl residue, including the following steps: when preparing a polythiophene or thiophene copolymer, The polymerization medium of the polyanion is used in an oxidation or reduction of 0, and in an inert environment, such that when the initiator is added, less than 3 mg per liter of the reaction medium is present in the reaction medium. oxygen. 25. A conductive layer made using an aqueous or non-aqueous dispersion comprising an aqueous solution of a polythiophene or a thiophene copolymer, which is obtained by a method for preparing an aqueous solution of a polythiophene or thiophene copolymer , which contains the structural unit of formula (1): Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printed clothing 20

, (I) j 二中R與R各自獨立地代表氫、或Ci_5·燒基基團、或連同生成一種選擇地取代之（^厂伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚, (I) j wherein R and R each independently represent hydrogen, or a Ci_5.alkyl group, or together with the formation of a selectively substituted alkyl residue, comprising the steps of: preparing a polythiophene or When a thiophene copolymer is present, there is a poly

1299738 六、申請專利範圍 A8 B8 C8 StL· 陰離子之反應介質中使用之條件下，及於惰性環境中進行，使得當添加該引發劑後’該反應介質中每公升該反應介質存在少於3毫克之氧。 26· —種使用包含聚噻吩或噻吩共聚物之非水性溶液之水十全或非水性分散液製得之導電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性溶液之方法，其包含依式⑴之結構單元： 10 R-〇〇- (工)丨 15 經濟部智慧財產局員工消費合作社印製 20 其中R1與R2各自獨立地代表氫、或C1-5-烧基基團、或連同生成一種選擇地取代之Cy伸烧基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後’該反應介質中每公升該反應介質存在少於3毫克之氧。 27· 一種使用包含聚噻吩或噻吩共聚物之水性溶液之水性或非水性溶液製得之導電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包含依式(I)之結構單元：本紙張尺度適用中國國家標準(CNS)A4規格⑽χ 297公爱） 1299738 A8 B8 C8 六、申請專利範圍 10 15 -rH I(I), 其中R1與R2各自獨立地代表氫、或C^-烷基基團、或連同生成一種選擇地取代之Ci_5-伸烧基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 28.—種使用包含聚噻吩或噻吩共聚物之非水性溶液之水性或非水性溶液製得之導電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性溶液之方法，其包含依式(I)之結構單元： R-0、經濟部智慧財產局員工消費合作社印製 20 (I) 其中R1與R2各自獨立地代表氫、或C^-烷基基團、或連同生成一種選擇地取代之Ci_5-伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚1299738 VI. Patent application scope A8 B8 C8 StL· Anion is used in the reaction medium and in an inert environment, so that when the initiator is added, there is less than 3 mg per liter of the reaction medium in the reaction medium. Oxygen. 26. A conductive layer prepared using a water-free or non-aqueous dispersion of a non-aqueous solution comprising a polythiophene or a thiophene copolymer, which is obtained by a non-aqueous solution for preparing a polythiophene or thiophene copolymer The method comprises the structural unit according to formula (1): 10 R-〇〇- (工)丨15 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 20 wherein R1 and R2 each independently represent hydrogen, or C1-5-burn a radical, or together with the formation of a selectively substituted Cy stretch residue, comprising the steps of: preparing a polythiophene or thiophene copolymer, using an initiator in the reaction medium in which the polyanion is present, in oxidation or Under reducing conditions, and in an inert environment, there is less than 3 milligrams of oxygen per liter of the reaction medium in the reaction medium after the addition of the initiator. 27. A conductive layer made using an aqueous or non-aqueous solution comprising an aqueous solution of a polythiophene or a thiophene copolymer, which obtains a method for preparing an aqueous solution of a polythiophene or thiophene copolymer, comprising Structural unit of formula (I): This paper scale applies to China National Standard (CNS) A4 specification (10) 297 297 public) 1299738 A8 B8 C8 VI. Patent application scope 10 15 -rH I(I), where R1 and R2 are independently Representing hydrogen, or a C^-alkyl group, or together with the formation of a selectively substituted Ci_5-extension base residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer in the presence of a polyanion An initiator is used, under oxidizing or reducing conditions, and in an inert environment such that when the initiator is added, less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium. 28. A conductive layer made using an aqueous or non-aqueous solution comprising a non-aqueous solution of a polythiophene or a thiophene copolymer, which is obtained by a method for preparing a non-aqueous solution of a polythiophene or a thiophene copolymer, It comprises a structural unit according to formula (I): R-0, Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, 20 (I) wherein R1 and R2 each independently represent hydrogen, or a C^-alkyl group, or together Forming a selectively substituted Ci_5-alkylene residue comprising the steps of: preparing a polythiophene or a thiophene copolymer in the presence of a poly

本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） 1299738 A8 B8 C8 m /、、申清專利範圍陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 5 29.種使用包含聚ϋ塞吩或嗔吩共聚物之水性分散液之水性或非水性分散液製得之抗靜電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性分散液之方法，其包含依式⑴之結構單元：經濟部智慧財產局員工消費合作社製本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） A8 B8 C8 經濟部智慧財產局員工消費合作社印製 1299738 六、申請專利範圍This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1299738 A8 B8 C8 m /, Shenqing patent range Anion reaction medium uses an initiator under oxidation or reduction conditions, and This is carried out in an inert environment such that, after the addition of the initiator, less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium. 5 29. An antistatic layer prepared using an aqueous or non-aqueous dispersion comprising an aqueous dispersion of a polydecyl phenanthrene or a porphin copolymer, which is obtainable by an aqueous solution for preparing a polythiophene or thiophene copolymer The method of dispersing liquid, comprising the structural unit according to formula (1): Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, paper size, applicable to China National Standard (CNS) A4 specification (210 X 297 mm) A8 B8 C8 Ministry of Economic Affairs Intellectual Property Office staff Consumer Cooperatives Printed 1299738 VI. Application for Patent Scope

其中R1與R2各自獨立地代表氫、或C^-烷基基團、或連同生成一種選擇地取代之Cw-伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原 10 之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 31. —種使用包含聚嗔吩或嗔吩共聚物之水性溶液之水性或非水性分散液製得之抗靜電層，其獲得可藉一種用於 15 製備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包含依式(I)之結構單元：Wherein R1 and R2 each independently represent hydrogen, or a C^-alkyl group, or together with the formation of a selectively substituted Cw-alkylene residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer, The use of an initiator in the presence of a polyanion is carried out under conditions of oxidation or reduction 10 and in an inert environment such that when the initiator is added, there is less than 3 per liter of the reaction medium in the reaction medium. Mg of oxygen. 31. An antistatic layer prepared using an aqueous or non-aqueous dispersion comprising an aqueous solution of a polyporphin or a porphin copolymer, which is obtained by using an aqueous solution for preparing a polythiophene or thiophene copolymer for 15 The method comprising the structural unit according to formula (I):

其中R1與R2各自獨立地代表氫、或Cy烷基基團、或連同生成一種選擇地取代之Ci_5-伸烧基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐）Wherein R 1 and R 2 each independently represent hydrogen, or a Cy alkyl group, or together with the formation of a selectively substituted Ci_5-extension base residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer, in the presence of The size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm)

Α8 Β8 C8 1299738 ‘ ---------- - 六、申請專利β 陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後’該反應介質甲每公升該反應介質存在少於3毫克之氧。 5 32·—種使用包含聚噻吩或噻吩共聚物之非水性溶液之水性或非水性分散液製得之抗靜電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性溶液之方法，其包含依式⑴之結構單元：Α8 Β8 C8 1299738 ' ---------- - 6. Applying an initiator to the reaction medium of the patented beta anion, under oxidizing or reducing conditions, and in an inert environment, so that when added After the initiator, the reaction medium contains less than 3 milligrams of oxygen per liter of the reaction medium. 5 32 - an antistatic layer prepared using an aqueous or non-aqueous dispersion of a non-aqueous solution comprising a polythiophene or a thiophene copolymer, which is obtained by a non-aqueous solution for preparing a polythiophene or thiophene copolymer The method comprising the structural unit according to formula (1):

⑴ 經濟部智慧財產局員工消費合作社印製其中R1與R各自獨立地代表氫、或C1-5-烧基基團、 15 或連同生成一種選擇地取代之C^-伸烷基殘餘物，包括下述步驟:製備聚σ塞吩或嗜吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫 20 克之氧。 33·—種使用包含聚噻吩或噻吩共聚物之水性溶液之水性或非水性溶液製得之抗靜電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之水性溶液之方法，其包含依式⑴之結構單元：本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） 1299738 · A8 B8 C8 D只六、申請專利範圍 R- Ό- •R2! CD 10 15 其中R1與R2各自獨立地代表氫、或C^-烷基基團、或連同生成一種選擇地取代之Ci_5-伸烧基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 34· —種使用包含聚嘻吩或喧吩共聚物之非水性溶液之水性或非水性溶液製得之抗靜電層，其獲得可藉一種用於製備一種聚噻吩或噻吩共聚物之非水性溶液之方法，其包含依式(I)之結構單元： R-Ov Ό- -R2] 經濟部智慧財產局員工消費合作社印製 20 (I) 其中R1與R2各自獨立地代表氫、或C^-烷基基團、或連同生成一種選擇地取代之伸烷基殘餘物，包括下述步驟:製備聚噻吩或噻吩共聚物時，於存在有聚(1) The Department of Intellectual Property's Intellectual Property Office, the Staff Consumer Cooperative, which prints R1 and R each independently representing hydrogen, or a C1-5-alkyl group, 15 or together with a selectively substituted C^-alkyl residue, including The following steps: when preparing a poly-sigma phenanthrene or a phenanthrene copolymer, using an initiator in a reaction medium in which a polyanion is present, under oxidizing or reducing conditions, and in an inert environment, such that when the addition is initiated After the agent, less than 3 mils of oxygen per liter of the reaction medium is present in the reaction medium. An antistatic layer prepared using an aqueous or nonaqueous solution comprising an aqueous solution of a polythiophene or a thiophene copolymer, which is obtained by a method for preparing an aqueous solution of a polythiophene or a thiophene copolymer, Contains structural unit according to formula (1): This paper scale applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299738 · A8 B8 C8 D only six, patent application scope R- Ό- • R2! CD 10 15 R1 and R2 each independently represent hydrogen, or a C^-alkyl group, or together with the formation of a selectively substituted Ci_5-extension base residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer, in the presence of The reaction medium having a polyanion is used in an oxidizing or reducing condition, and in an inert environment, such that when the initiator is added, less than 3 mg per liter of the reaction medium is present in the reaction medium. oxygen. 34. An antistatic layer prepared using an aqueous or non-aqueous solution comprising a non-aqueous solution of a polyporphin or a porphin copolymer, which is obtained by a non-aqueous solution for preparing a polythiophene or thiophene copolymer The method comprises the structural unit according to formula (I): R-Ov Ό--R2] Ministry of Economic Affairs Intellectual Property Office employee consumption cooperative printing 20 (I) wherein R1 and R2 each independently represent hydrogen, or C^- An alkyl group, or together with the formation of a selectively substituted alkyl residue, comprising the steps of: preparing a polythiophene or a thiophene copolymer in the presence of a poly

本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐） 1299738 A8 B8 C8 D只躪I 六、申請專利範圍陰離子之反應介質中使用一種引發劑，在氧化或還原之條件下，及於惰性環境中進行，使得當添加該引發劑後，該反應介質中每公升該反應介質存在少於3毫克之氧。 i 訂 4:0 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐）This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1299738 A8 B8 C8 D only 躏I VI. Patent application range Anionic reaction medium uses an initiator under oxidation or reduction conditions. And in an inert environment such that when the initiator is added, less than 3 milligrams of oxygen per liter of the reaction medium is present in the reaction medium. i Order 4:0 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Print This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm)