TWI291502B - Finishing of absorbent materials - Google Patents

Abstract

A process for finishing absorbent materials by treatment with at least one aqueous liquor comprising at least one organic polymer, at least one organic or inorganic solid in particulate form, and at least one emulsifier selected from emulsifiers of the general formula I and II, where R1 is selected from C6-C40-alkyl, R2 is at each instance the same or different and selected from hydrogen and methyl, m and n are the same or different and each selected from integers in the range from 0 to 10, R3 is at each instance the same or different and selected from C6-C20-alkyl, M is an alkali metal or ammonium.

Description

1291502 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種加工吸收性材料的方法，其係藉由使 用至少一種含水溶液處理該吸收性材料而完成，該含水溶 液包括 至少一種有機聚合物，1291502 IX. Description of the Invention: The present invention relates to a method of processing an absorbent material by treating the absorbent material with at least one aqueous solution comprising at least one organic polymerization. Object,

至少一種粒子形式的有機或無機固體，以及 至少一種乳化劑，其係選自通式IAt least one organic or inorganic solid in the form of particles, and at least one emulsifier selected from Formula I

和通式II的乳化劑 r3oocAnd emulsifier of formula II r3ooc

)~Λ M03S COOR3 此處：)~Λ M03S COOR3 Here:

Rl係選自C6-C4〇-烷基以及含有一至五個碳碳雙鍵的c3_C4〇_ 烯基， R2在每個例子中為相同或不同，並係選自氫和曱基， m和η為相同或不同，各係選自〇到10範圍中的整數， R3在每個例子中為相同或不同，並係選自氫和C6_C2()_烷基， Μ為驗金屬或銨。 101246.doc 1291502 【先前技術】 纺織品的加工是商章φ料π a茶中浚侍越來越重要的一個領域。加 工紡織品使其具有防皮知奸一 啕防水和防π的性質是特別引人關注的。 現代化的方法在某些情況下使用戶斤謂的―Effect⑧，並 且透過使用-種粗辣面賦予紡織品防水的性能。 WO 96/04123描述具有包括凸起和凹陷之人造表面結構 的自清潔表面，這種結構的特徵特別是其結構參數。例如， 這種結構的製備方法是將結構壓花於一種熱塑性易成型的 疏水性材料上，或者將鐵氟龍（Tefl〇n)粉末塗覆於已被 UHU®處理過的表面上。美國專利第3,354,〇22號揭示一種 以類似方法製成的防水表面。 歐洲專利EP-A 0 933 388揭示製造結構化表面的方法，包 括先利用照相印刷石版術製造一個陰模，用這個模去壓印 塑膠膜，然後再利用氟化烷基矽烷將經壓印的塑膠膜疏水 化。 然而，上面所提到的方法都不適合用於紡織品的防污和 防水加工上。 WO 02/84013提出將例如由聚酯組成的纖維疏水化，其係 經由將纖維牵引通過80°C的熱十氫萘浴中，該浴中已懸浮 有1% Aerosil 8200的疏水化石夕膠。 WO 02/84016提出將編織聚酯織物疏水化，其係經由將編 織聚酯織物牽引通過50°C的熱二甲亞砜（DMSO)浴中，該浴 中已懸浮有1% Aeroperl 8200的疏水化矽膠。 這兩種疏水化方法有一個共同的特點，就是選用的溶劑 101246.doc 1291502 使得纖維都是部分溶解。這需要用到大量的有機溶劑，並 a在大多數情況下這是不希望發生的。此外，用有機溶劑 處理過後會對纖維的機械性能產生影響。 WO 〇1/75216提出使紡織纖維和織物具有防水和防污性 的方法，這種方法例如是讓紡織纖維和織物裝備成一個含 兩組分的層，其中一個組分是分散介質，而另一個組分是 膠體。W〇〇1/75216中描述的加工方法提供—加工塗層，其 中膠體為各向異性地分散於分散介質中，其中可以看到在 加工塗層和周圍表面之間的邊界層處膠體明顯變濃。這種 方法使用了含有每公升高達5W_il812s的加工溶液。 然而，用卿〇1/75216中描述的方法對纺織品進行加工 時，在很多情況下纺織品會缺乏讓人滿意的機械強度。 【發明内容】 本發明為了這個目的因而提供了—種加工吸收性材料的 方法’這種方法沒有上面提到的那些缺點，同時它還提供 了非常好的防水和防污性銥。盔 丄 不丨万生肊。為了延個目的本發明還提供 了具有防污和防水性的紡織品。另外，為了這個目的，本 發明提供有供吸收性材料之防水和防污加工料溶液。 吾這個目的可以由開始時定義的方。 L貧施方式】 二 =發明的吸收性材料包括像是紙，木板，木材，建 病材枓(像如究磚’混凝土’天 -類的物品，還包括皮革… 石以及灰砂磚等） 料。紡織原料一方皮革而較佳為紡織原 s如為纖維’粗紗，紗，線，另一方 101246.doc 1291502 面為.像疋編織而成的織品，斜㈣六』丨 ，"衣服等的紡織織物特料’非編織而成的織品 品的妨織織物。例如，風帆者：用於例如製造戶外纺織 桌布，遮陽蓬以及—些像是椅 布 蓋物。 鞦韆或長凳用的傢俱遮 用於本發明的吸收性姑祖 可以由不同的物質組成。例如 ::然纖維和合成纖維以及混合纖維。天然纖維的實丄象 :蠶絲’手毛以及棉花。合成纖維的實例為聚酿 =稀，聚丙稀猜，聚對苯二甲酸乙二醋和黏液纖維。同 羡地’改質過的天_維可以按照本發明的方 如纖維素乙酸酯。 復例 本發明方法要用到至少—種含水溶液。用於本發明的含 液包含有多種溶液’以室溫下為液體的分率為基準， 其含至少5重量％的水。含水溶液中水的含量較佳是至少。 重量％，更佳是至少50重量％，而最佳是至知重量％。以 室溫下為液體的分率為基準’水的最大含量是1〇〇重量。 較佳是97重量％，而尤佳是95重量0/〇。 用於本發明的含水溶液可以包括有機_，例如甲醇， 乙醇，異丙醇，丙酮’甲基乙基酮，甲基異丁基酮，乙二 醇單-正丁輕，乙二醇單異丁喊，乙酸，正丁醇，異丁醇， 正己醇及其異構物，正辛醇及其異構物，正十二醇及其異 構物’和水。有機溶劑的含量可佔本發明所用含水溶液的 0.2’重量❶/。，而較佳為0.5-35重量％。以室溫下為液體的 分率為基準，水含量為100重量％的含水溶液因而不含任何 I01246.doc 1291502 的有機溶劑。 本發明方法中所用的至少_種溶 合物。右拖取人仏、 匕括至少一種有機聚 有機聚&物可以作為黏合劑用。 合劑的你田θ y t 有機聚合物發揮黏 J的作用疋例如透過形成一層薄獏 將粒子相互枯合，也可以把粒子和⑽^這層薄膜可 為將粒子與待塗覆的紡織原料黏合。 料黏合，較佳 本發明的一個具體實施例中， 烯糸尤種有機聚合物包括 钸糸不飽和疏水性單體（25 〇c時， i古/八1、 在水中的溶解度低於 克升）的聚合物或共聚物。在共聚 A. s , 你/、爪物中，疏水性單體佔 共聚物至少50重量％，較佳為至少75重量％。 較佳的單體係選自由下列組成的群組 CVC24·烯烴，特別是含有2_24個碳原子的α·烤烴，例如， 乙稀，丙稀…丁稀’異丁烯…己烯，】_辛稀，i癸烯， 二碳烯，卜十六碳烯或1-十八碳烯； 乙烯基芳族化合物，例如’苯乙烯，α_甲基苯乙烯，順 1，2-,苯乙烯’反· 1>2-二苯乙烯’二烯烴，像是13-丁二 烯，環戊二烯，氣丁二燁或異戊二稀，c5_c】8_環稀烴，像 是環戊婦’環己稀’降冰片稀，二聚合的環戍二稀， 直鍵或支鍵G-Cw烧缓酸的乙烯酯，例如乙酸乙烯酯， 丙酸乙烯醋’正丁酸乙烯醋，正己酸乙烯顆，正辛酸乙稀 酯，月桂酸乙烯酯，硬脂酸乙烯酯， C】-C2〇-醇的（甲基）丙烯酸_，例如（甲基）丙烯遊甲醋，（甲 基）丙烯酸乙醋，（甲基）丙烯酸正丙_，（甲基）丙稀酸異丙 酯，（甲基）丙烯酸正丁酯，（甲基）丙烯酸異丁酯，（甲基）丙 I01246.doc 1291502 1夂-乙基己酉旨’（甲基）丙稀酸正 (甲基）丙稀酸正-十二燒酯，（甲 烯酸第三丁酯，（甲基）丙烯酸2 辛醋，（甲基）丙烯酸正癸酯，（甲 基）丙烯酸正-二十烷酯， 的單體。Rl is selected from the group consisting of C6-C4 〇-alkyl and c3_C4〇-alkenyl having one to five carbon-carbon double bonds, and R2 is the same or different in each case, and is selected from hydrogen and sulfhydryl groups, m and η The same or different, each line is selected from an integer in the range of 〇 to 10, R3 is the same or different in each case, and is selected from hydrogen and C6_C2()-alkyl, and is a metal or ammonium. 101246.doc 1291502 [Prior Art] The processing of textiles is an increasingly important field in the business of quotation. It is particularly interesting to process textiles to make them resistant to skin and water. The modern method in some cases makes the user's “Effect8”, and through the use of a rough surface to impart waterproof performance to the textile. WO 96/04123 describes a self-cleaning surface having an artificial surface structure comprising projections and depressions, the characteristics of which are in particular structural parameters. For example, such a structure can be prepared by embossing the structure onto a thermoplastically formable hydrophobic material or by applying a Teflon powder to a surface that has been treated with UHU®. U.S. Patent No. 3,354, filed on Jun. 22 discloses a water-repellent surface made in a similar manner. A method for producing a structured surface is disclosed in the European patent EP-A 0 933 388, which comprises first using a photographic lithography process to make a negative mold, which is used to emboss a plastic film and then embossed with a fluorinated alkyl decane. The plastic film is hydrophobized. However, the above mentioned methods are not suitable for use in antifouling and water repellent processing of textiles. WO 02/84013 proposes hydrophobizing fibers, for example composed of polyester, by drawing the fibers through a hot decalin bath at 80 ° C in which 1% Aerosil 8200 hydrophobized fossil has been suspended. WO 02/84016 proposes hydrophobizing a woven polyester fabric by drawing a woven polyester fabric through a hot dimethyl sulfoxide (DMSO) bath at 50 ° C in which 1% Aeroperl 8200 is suspended. Silicone gum. A common feature of the two hydrophobization methods is the use of the solvent 101246.doc 1291502 to partially dissolve the fibers. This requires a large amount of organic solvent, and a is undesirable in most cases. In addition, treatment with an organic solvent has an effect on the mechanical properties of the fiber. WO 〇 1/75216 proposes a method for imparting water and soil resistance to textile fibers and fabrics, for example by arranging textile fibers and fabrics into a two-component layer, one of which is a dispersion medium and the other One component is a colloid. The processing method described in W〇〇1/75216 provides a processed coating in which the colloid is anisotropically dispersed in a dispersion medium, wherein it can be seen that the colloid is significantly changed at the boundary layer between the processed coating and the surrounding surface. concentrated. This method uses a processing solution containing up to 5W_il 812s per liter. However, when the textile is processed by the method described in pp. 1/75216, in many cases the textile lacks satisfactory mechanical strength. SUMMARY OF THE INVENTION The present invention thus provides a method of processing an absorbent material for this purpose. This method does not have the disadvantages mentioned above, and it also provides very good water repellency and antifouling properties. Helmets are not worth living. The present invention also provides a textile having antifouling and water repellency for the purpose of extending the object. Further, for this purpose, the present invention provides a water repellent and antifouling processing solution for an absorbent material. My purpose can be defined by the party at the beginning. L lean method] Second = the invention of absorbent materials including paper, wood, wood, diseased materials (like the brick 'concrete' day-class items, including leather... stone and lime sand bricks, etc.) material. Textile raw material one leather and preferably textile original s such as fiber 'roving, yarn, thread, the other side 101246.doc 1291502 surface is like woven fabric, oblique (four) six 丨, " clothes and other textiles Fabric woven fabric of non-woven fabrics. For example, sailors: for example, for making outdoor textile tablecloths, awnings, and some like chair covers. Furniture for Swing or Bench Covering The absorbent ancestors used in the present invention may be composed of different substances. For example: :: fiber and synthetic fiber as well as mixed fiber. The real image of natural fiber: silk 'hand hair and cotton. Examples of synthetic fibers are polystyrene = dilute, polypropylene guess, polyethylene terephthalate and mucilage fibers. The same modified "days" may be in accordance with the invention such as cellulose acetate. EXAMPLES At least one aqueous solution is used in the process of the invention. The liquid used in the present invention contains a plurality of solutions which contain at least 5% by weight of water based on the fraction of liquid at room temperature. The content of water in the aqueous solution is preferably at least. The % by weight, more preferably at least 50% by weight, and most preferably at % by weight. The maximum content of water is 1 gram by weight based on the fraction of liquid at room temperature. It is preferably 97% by weight, and particularly preferably 95% by weight. The aqueous solution used in the present invention may include organic _, such as methanol, ethanol, isopropanol, acetone 'methyl ethyl ketone, methyl isobutyl ketone, ethylene glycol mono-n-butyl light, ethylene glycol single different Ding, acetic acid, n-butanol, isobutanol, n-hexanol and its isomers, n-octanol and its isomers, n-dodecyl alcohol and its isomers' and water. The content of the organic solvent may be 0.2' by weight of the aqueous solution used in the present invention. It is preferably from 0.5 to 35% by weight. The aqueous solution having a water content of 100% by weight based on the fraction of the liquid at room temperature thus does not contain any organic solvent of I01246.doc 1291502. At least one of the solvents used in the process of the invention. Right-handed mantle, including at least one organic polyorganic poly-amplifier, can be used as a binder. The mixture of your θ y t organic polymer acts as a binder. For example, by forming a thin layer of ruthenium, the particles and the film can be bonded to the textile material to be coated. Preferably, in one embodiment of the present invention, the olefinic organic polymer comprises a hydrophobic unsaturated monomer (25 〇c, i ancient / 8.1, solubility in water is less than 克升a polymer or copolymer. In the copolymerization of A.s, the hydrophobic monomer accounts for at least 50% by weight of the copolymer, preferably at least 75% by weight. A preferred single system is selected from the group consisting of CVC24. olefins, especially alpha-bake hydrocarbons having 2 to 24 carbon atoms, for example, ethylene, propylene, butadiene, isobutylene, hexene, , i-decene, dicarbene, hexadecene or 1-octadecene; vinyl aromatic compounds such as 'styrene, α-methylstyrene, cis 1,2- styrene' · 1 > 2- stilbene 'diene, such as 13-butadiene, cyclopentadiene, gas dioxin or isoprene, c5_c] 8-ring rare hydrocarbons, such as cyclopentanol ring Diluted 'norborn borneol, dimerized ring bismuth dilute, straight bond or branch G-Cw sulphuric acid vinyl ester, such as vinyl acetate, propionic acid vinyl vinegar 'n-butyric acid vinyl vinegar, tetrahexanoic acid vinyl , ethylene octoate, vinyl laurate, vinyl stearate, C]-C2 〇-alcohol (meth)acrylic acid _, such as (meth) propylene vinegar, (meth) acrylate , (meth)acrylic acid n-propyl, isopropyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, (methyl) propyl I01246.doc 1291 502 1夂-ethylhexyl ketone '(methyl)acrylic acid n-dodecyl ester of (meth) acrylate, (tert-butyl methacrylate, 2 octyl vinegar, (meth) acrylate, A monomer of n-decyl (meth)acrylate or n-eicosyl (meth)acrylate.

2,732,370號中所述），氟化或全氟化醇的（甲基）丙烯酸醋， 例如像是氟化或全氟化C3_Ci4-烷基醇，例如 最佳的單體係選自齒化單體和含有矽氧烷基 幽化單體包括氯化烯烴，像是例如氯乙烯和_ 最佳的鹵化單體是含氟烯烴，像是例如二(2,732,370), a fluorinated or perfluorinated alcoholic (meth)acrylic acid vinegar, such as, for example, a fluorinated or perfluorinated C3_Ci4-alkyl alcohol, for example, the most preferred single system is selected from the group consisting of a monomeric monomer And containing a oxoalkyl group, including chlorinated olefins such as, for example, vinyl chloride and _ the preferred halogenated monomer is a fluorine-containing olefin, such as for example

HO-CH2-CH2-正-C6F13，HO-CH2-CH2-正-C8F17，HO-CH2-ch2-正-c10f21 ’ ho-ch2-ch2-正-C12F2M (甲基）丙烯酸酯， 其例如描述於美國專利第2,642,416號，美國專利第 φ 3,239,557號，英國專利第1，118,007號，美國專利第 3,462,296號中。 同樣地，例如，（曱基）丙稀酸縮水甘油酯和式ΠΙ酯的共 聚物HO-CH2-CH2-正-C6F13, HO-CH2-CH2-正-C8F17, HO-CH2-ch2-n-c10f21 'ho-ch2-ch2-n-C12F2M (meth) acrylate, as described, for example, in U.S. Patent No. 2,642, 416, U.S. Patent No. 3,239, 557, U.S. Patent No. 1,118,007, U.S. Patent No. 3,462,296. Similarly, for example, a copolymer of (fluorenyl)glycidyl acrylate and an oxime ester

、r4 ,so厂 R4為氫，甲基，乙基， 101246.doc -11 - ⑧ 1291502 R 為甲基，乙基， X 為4到12的整數，而最佳為6到8， y 為1到11的整數，而較佳為1到6， 或者是帶有氣化羧酸乙烯酯的（曱基）丙烯酸縮水甘油酯 也是適合的。 適用的共聚物另外包括氟化或全氟化C3_C12_烷基醇（例 W’HO-CH2-CH2-CF3，HO-CH2-CH2-C2F5，HO-CH2-CH2-正-c3f7，HO-CH2-CH2K3F7，ho-ch2-ch2-正-c4f9， HO-CH2-CH2-正-C5FU ，HO-CH2-CH2_ 正-C6Fn ， HO-CHrCHr正-CvF〗5)的（甲基）丙烯酸酯和非鹵化Ci-c2〇-醇之（曱基）丙烯酸酯（例如（曱基）丙烯酸曱酯，（甲基）丙烯酸 乙酯，（甲基）丙烯酸正丁酯，（甲基）丙烯酸正丙酯，（甲基） 丙烯酸2-乙基己酯，（曱基）丙烯酸正辛酯，（甲基）丙烯酸正 癸酯，（曱基）丙烯酸正-十二烷酯，（甲基）丙烯酸正_二十烷 酯）的共聚物。 適當之氟化5^合物和共聚物的綜述例如見於M. Lewin 等人的《纖維和織物的化學加工方法（Chemical Pr〇cessing of Fibers and Fabrics)》，B部分，第 2卷，Marcel Dekker， 紐約（1984)，第172頁以下及第178-182頁。 其他適當的氣化聚合物例如揭示於德國專利第 199 120 810號中。 在帶有矽氧烷基的烯烴群組中，可能提及的例子為通式 IV a到IV c的烯烴 101246.doc -12· 1291502, r4 , so plant R4 is hydrogen, methyl, ethyl, 101246.doc -11 - 8 1291502 R is methyl, ethyl, X is an integer from 4 to 12, and most preferably 6 to 8, y is 1 An integer of from 11, to preferably from 1 to 6, or a glycidyl (meth) acrylate having a vaporized vinyl carboxylate is also suitable. Suitable copolymers additionally include fluorinated or perfluorinated C3_C12_alkyl alcohols (eg W'HO-CH2-CH2-CF3, HO-CH2-CH2-C2F5, HO-CH2-CH2-正-c3f7, HO-CH2 -CH2K3F7, ho-ch2-ch2-正-c4f9, HO-CH2-CH2-正-C5FU, HO-CH2-CH2_正-C6Fn, HO-CHrCHr-CvF (5) (meth) acrylate and non Halogenated (indenyl) acrylate of Ci-c2 oxime-ol (for example, decyl methacrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, n-propyl (meth) acrylate, (Methyl) 2-ethylhexyl acrylate, n-octyl (meth) acrylate, n-decyl (meth) acrylate, n-dodecyl (meth) acrylate, (meth) acrylate Copolymer of a decaalkyl ester). A review of suitable fluorinated 5^ compounds and copolymers is found, for example, in M. Lewin et al., "Chemical Pr〇cessing of Fibers and Fabrics", Part B, Volume 2, Marcel Dekker New York (1984), p. 172 and pp. 178-182. Other suitable gasification polymers are disclosed, for example, in German Patent No. 199 120 810. Among the groups of olefins having a decyloxy group, examples which may be mentioned are the olefins of the formulae IV a to IV c 101246.doc -12· 1291502

IV aIV a

IV bIV b

R6係選自 IV cR6 is selected from IV c

Cl-Cl8-烷基，例如甲基，乙基’正丙基，異丙基，正丁基， 異丁基’第二丁基’第三丁基，正戊基，#戊基，第二戊 基’新戊基’ 1，2·二甲基丙基，異戊基，正己基，異己基， 第二己基，正庚基’異庚基，正辛基，正壬基，正癸基， 正-十二烷基’正-十四烷基’正_十六烷基，正十八烷基； 較佳是G-C6-烷基’例如甲基，乙基，正丙基，異丙基正 丁基’異丁基，第二丁第三丁基，正戊基，異戊基， 第二戊基，新戊基，1，2-二曱基丙基，異戊基，正己基，異 己基，第二己基，更佳為Ci_C4_烷基，例如曱基，乙基，正 丙基，異丙基，正丁基，異丁基，第二丁基和第三丁基， 特別是曱基。 CVCm-芳基，例如苯基，萘基，2_萘基，κ蒽基，2_蒽基， 9-蒽基，1-菲基，2-菲基，3-菲基，4-菲基以及9-菲基，較 101246.doc -13 · 1291502 佳是笨基’ i-萘基和2_萘基’更佳的是苯基。 cvc12-環烷基，例如環丙基，環丁基，環戍基，環己基， 環庚基，環辛基，環壬基，環癸基，環十1基和環十二 烧基；較佳的選擇是環戍基，環己基和環庚基 或者是Si(CH3)3。 a為2到1〇_範圍中的整數，而特別是高達1〇〇。 b為0到6範圍中的整數，而特別是丨到之。 -可以使用的聚合物進一步包含：聚醚，像是例如聚乙二 酵’聚丙二_，聚丁-酿，取 一％ I四虱呋喃；聚已内酯，聚碳 敲5曰$乙烯基縮丁醛，由脂族二羧酸或芳族二羧酸和/或 月曰知醇或芳知_酵生成之部分芳香系的聚醋，例如由帶 有2到18個碳原子的脂族二醇(像是例如乙二醇，丙二醇， 1，4_ 丁二醇，己二醇’ i冬辛二醇或雙龄a)和帶有頂18 個碳原子的脂族二㈣(像是例如丁二酸，戊二酸，己二酸 ，*烷一羧馱）生成的聚酯；由對苯二甲酸和帶有2到】8 個碳原子的脂族二醇（像是例如乙二醇，丙二醇，^-丁二 醇，1，6-己二醇或丨，^辛二醇）生成的聚酯。 上面提到的聚醋可例如以一元醇封端，一元醇譬如為含 有4到12個碳原子者，例如正丁醇，正己醇，正辛醇，正癸 醇或正-十二烷醇。 上面提到的聚酯可例如以一元羧醆封端元羧酸譬如 為硬脂酸。 適备的聚合物進-步包括三聚氛胺_甲酸樹醋，服-甲酸樹 醋’ Ν，Ν·^甲基·4,5•二經基伸乙基脲，它們可以用Cl 101246.doc -14- 1291502 酉芋鱗化。 有機聚合物的分子量可以有很大範圍的選擇。重量平均 分子量的範圍可為每莫耳1000到10 000 000克，較佳的 耗圍為每莫耳2500到5 000 000克，其可以用下面方法中的 至）一種方法來測定：光散射，凝膠滲透層析術（GPC)以及 黏度測量法。當使用來自聚烯烴（例如聚乙烯，聚丙烯或聚 異丁烯，而且也包括乙烯和丙烯，丁烯或卜己烯的共聚物） 群組中的聚合物時，分子量的範圍宜為每莫耳3〇 〇〇〇到 5 000 〇〇〇克。 對刀子里分佈寬度的要求並非這麼苛刻，其範圍是從U 到20。通常範圍是從2到1 〇。 本發明之一具體實施例中’上述有機聚合物的分率至少 是每公升含水溶液包含0.1克，較佳是至少!克，而更佳是 至少1〇克。最大的分率是例如每公升包含5〇〇克，較佳是25〇 克，而更佳是100克。Cl-Cl8-alkyl, such as methyl, ethyl 'n-propyl, isopropyl, n-butyl, isobutyl 't-butyl' tert-butyl, n-pentyl, #pentyl, second Pentyl 'neopentyl' 1,2 dimethylpropyl, isopentyl, n-hexyl, isohexyl, second hexyl, n-heptyl 'isoheptyl, n-octyl, n-decyl, n-decyl , n-dodecyl 'n-tetradecyl'-n-hexadecyl, n-octadecyl; preferably G-C6-alkyl' such as methyl, ethyl, n-propyl, iso Propyl n-butyl 'isobutyl, second butylene, n-pentyl, isopentyl, second amyl, neopentyl, 1,2-dimercaptopropyl, isopentyl, hexyl Base, isohexyl, second hexyl, more preferably Ci_C4_alkyl, such as decyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl and t-butyl, Especially the base. CVCm-aryl, such as phenyl, naphthyl, 2-naphthyl, κ-mercapto, 2-hydrazino, 9-fluorenyl, 1-phenanthryl, 2-phenanthryl, 3-phenanthryl, 4-phenanthryl And 9-phenanthryl, more than 101246.doc -13 · 1291502 is better than stylyl 'i-naphthyl and 2-naphthyl' is more preferred is phenyl. Cvc12-cycloalkyl, such as cyclopropyl, cyclobutyl, cyclodecyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclodecyl, cyclodecyl, cyclodecyl and cyclodode; Preferred choices are cyclodecyl, cyclohexyl and cycloheptyl or Si(CH3)3. a is an integer in the range of 2 to 1 〇 _, and in particular up to 1 〇〇. b is an integer in the range of 0 to 6, and especially to it. - The polymer which can be used further comprises: a polyether such as, for example, poly(ethylene glycol) polyacrylic acid, polybutylene, and one% I tetrafurfuran; polycaprolactone, polycarbon knocking 5 曰 $ vinyl Butyral, a partially aromatic condensate formed from an aliphatic dicarboxylic acid or an aromatic dicarboxylic acid and/or a hydrazine or a saccharide, for example, an aliphatic having 2 to 18 carbon atoms a diol (such as, for example, ethylene glycol, propylene glycol, 1,4-butanediol, hexanediol 'i winter octanediol or double age a) and an aliphatic bis(tetra) with a top 18 carbon atoms (like for example a polyester formed from succinic acid, glutaric acid, adipic acid, alkane-carboxylate; from terephthalic acid and an aliphatic diol having 2 to 8 carbon atoms (such as, for example, ethylene glycol) , propylene glycol, ^-butanediol, 1,6-hexanediol or hydrazine, octanediol) polyester. The above-mentioned polyester may be, for example, blocked with a monohydric alcohol such as those having 4 to 12 carbon atoms, such as n-butanol, n-hexanol, n-octanol, n-nonanol or n-dodecanol. The polyesters mentioned above may, for example, be blocked with a monocarboxylic carboxylic acid such as stearic acid. Suitable polymer steps include triammine-formic acid vinegar, serving-formic acid vinegar' Ν, Ν·^ methyl·4,5• di-based ethyl-ethyl urea, which can be used with Cl 101246.doc -14- 1291502 酉芋 Scaled. The molecular weight of the organic polymer can be varied over a wide range. The weight average molecular weight can range from 1000 to 10 000 000 grams per mole, with a preferred cost of 2500 to 5 000 000 grams per mole, which can be determined by one of the following methods: light scattering, Gel permeation chromatography (GPC) and viscosity measurement. When using polymers from a polyolefin (for example polyethylene, polypropylene or polyisobutylene, but also copolymers of ethylene and propylene, butene or hexene), the molecular weight should be in the range of 3 per mole. 〇〇〇〇 5,000 gram. The requirements for the width of the distribution in the knife are not so harsh, and the range is from U to 20. Usually the range is from 2 to 1 〇. In one embodiment of the invention, the fraction of the above organic polymer is at least 0.1 gram, preferably at least gram, and more preferably at least 1 gram per liter of the aqueous solution. The maximum fraction is, for example, 5 gram per liter, preferably 25 gram, and more preferably 100 gram.

本發明之-具體實施例中，有機聚合物是不溶於含水溶 液的本毛明所用有機聚合物不溶的意思是指在室溫條 下，溶液中的溶解度少於1克/公升，更佳為少於(U克/公升 本發明之-具體實施例包含使用 升° 合物。 乂田禋不问的有機聚 本發明之一具體實施例中，至少— 子形式存在，它的中央傾向 有機聚合物是以粒 較佳為。.5到3。微米’而更佳 )广未’ 值）。 铽水（中值’數目平均 101246.doc ⑧ -15- 12915〇2 *本發明方法中所用至少一種含水溶液包括一種有機或無 機的固體物，這種固體物質以粒子形式存在，與上面提到 的聚合物不同，例如它的分率至少為5 5克/公升，較佳為至 克/ a升，而更佳為至少1〇克/公升。最大分率總計可為 約150克/公升。另外的固體物本質上可以是無機或有機 的，但較佳為無機的。 合適之無機或有機固體物質的實例是聚乙烯，聚丙烯， 鲁聚異丁稀以及聚苯乙浠，而且還可以是其與彼此的共聚物 $者和一或多種其他烯烴的共聚物，其他的烯烴像是例如 • 笨乙烯，丙烯酸曱酯，丙烯酸乙酯，甲基丙稀酸曱酯，丙 稀酸丁醋，甲基丙烯酸丁酿，丙稀酸2-乙基己基醋，甲基 丙婦0文2-乙基己基醋，順丁稀二酸軒或甲基順丁稀二酿 亞胺。較佳的聚乙烯或聚丙烯在例如歐洲專利第Ep_A 〇 761 696號中有所描述。 、特別適當的無機或有機固體物f包括無機材料，尤其是 φ週期表3到14族中的固態無機氧化物，碳酸鹽，磷酸鹽，矽 酸鹽或硫酸鹽，例如，氧化約，二氧化石夕或氧化銘，碳酸 飼’硫酸約或石夕酸約，其中氧化銘和二氧化石夕是較佳的。 更佳為以石夕膠形式存在的二氧化矽。而最佳是火成 (pyrogeme)㈣。固態無機氧化物可藉加熱到彻刪。c熱 超 b或車乂佺為通過物理或化學吸附的有機或有機金 屬化合物的方法使疏水性化。為了達到這個目的，顆粒要 在塗覆步驟之前先與例如下列物質進行反應：包括至少一 個吕成基的有機金屬，例如院基鐘化合物，像是甲基鐘， 101246.doc -16- 1291502 正丁基鋰或正己基鋰；或矽烷，像是，六曱基二矽氮烷， 辛基一甲氧基石夕烧’特別是_化石夕烧’像是三曱基氣石夕烧 或二氯二曱基矽烷。 本發明之一具體實施例係使用疏水固體無機氧化物和其 相應的非疏水無機氧化物的混合物，兩者的重量比範圍例 如為100 : 0到〇 : 100，較佳為99 ··丨到6〇 : 40，而更佳為99 : 1 到 80 ·· 20 〇 φ 較佳為至少一種有機或無機固體物是疏水性的。在這裏 疏水性的意思可以理解為溶解度小於丨克/公升，較佳為低 於〇·3克/公升（室溫下測量者）。 無機固體物本質上較佳為多孔型。多孔結構最佳是以根 據德國標準DIN 66131測量的ΒΕΤ表面積為其特徵。所用無 機固體物較佳可具有5到1〇00平方米/克的ΒΕΤ表面積，尤佳 的乾圍為10到800平方米/克，而更佳的範圍是2〇到5〇〇平方 米/克。 # 本發明之一具體實施例中，至少有一種以粒子形式存在 的無機或有機固體物。其中央傾向顆粒直徑（中間值，數目 平均值）經測量為至少丨奈米，較佳是至少3奈米，而更佳是 至少6奈米。最大顆粒直徑（中間值，數目平均值^是⑺㈧太 米，較佳為350奈米，而更佳為1〇〇奈米。顆粒直徑可以= -般使用的方法來測定，像是例如穿透式電子顯微鏡法。 有機聚合物相對於以粒子形式存在之有機或無機固體物 的重量比通常的範圍是9:1到1:9,較佳的範圍是4:_·· 4，而更佳的範圍是7 ·· 3到4 ·· 6。 101246.doc -17- Ϊ291502 本發明之-具體實施例中，至少有一種以球形顆粒形式 存在的無機或有機固體物’其預期包括有粒狀的固體物， 其中至少75重量％，較佳為至少9〇重量％是以球形的形式存 在’而其他的粒子則是以粒狀形態存在。 本發明之-具體實施例中，至少有一種無機或有機固體 物可以形成聚集體和/或黏聚物。當一或多種的無機或有機 固體物以聚集體和/或黏聚物的形成存在時，它們可以由2 至數千個基本粒子組成，而且結果為球形，關於顆粒外形 和大小的具體細節與此基本粒子息息相關。 本發明方法中使用的至少一種溶液包括至少一種表面活 性劑’其係選自通式I的乳化劑 R2In the specific embodiment of the present invention, the organic polymer is insoluble in the aqueous solution, and the organic polymer used in the present invention is insoluble, meaning that the solubility in the solution is less than 1 g/liter, more preferably at room temperature. Less than (U g / liter of the invention - the specific embodiment comprises the use of a lysate. In one embodiment of the present invention, at least the sub-form exists, its central tendency to organic polymerization Preferably, the particles are preferably .5 to 3. Micron 'and more preferably wide'. Hydrophobic (median number average 101246.doc 8 -15- 12915 〇 2 * at least one aqueous solution used in the process of the invention comprises an organic or inorganic solid, which is present in the form of particles, as mentioned above The polymer is different, for example, having a fraction of at least 55 g/liter, preferably to gram/a liter, and more preferably at least 1 gram/liter. The maximum fraction may be about 150 g/liter. The additional solids may be inorganic or organic in nature, but are preferably inorganic. Examples of suitable inorganic or organic solid materials are polyethylene, polypropylene, ruthenium butadiene and polystyrene, and It is a copolymer of one copolymer with each other and one or more other olefins. Other olefins are, for example, stupid ethylene, decyl acrylate, ethyl acrylate, methacrylate, butyl acrylate , methacrylic acid butyl, 2-ethylhexyl acrylate, methyl propyl ketone 2-ethylhexyl vinegar, cis-butyl succinate or methyl cis-butyl diimide. Polyethylene or polypropylene in, for example, European Patent No. Ep_A 〇761 696 Described, particularly suitable inorganic or organic solids f include inorganic materials, especially solid inorganic oxides, carbonates, phosphates, citrates or sulfates of the φ periodic table 3 to 14, for example, oxidation About, the dioxide is oxidized or oxidized, the carbonic acid is fed with 'sulfuric acid or about oxalate, and the oxidized sulphur and the sulphur dioxide are preferred. More preferably, the cerium oxide is present in the form of shi eve. It is pyrogeme (4). The solid inorganic oxide can be heated to the end. c Thermal super b or rutting is hydrophobic by physical or chemical adsorption of organic or organometallic compounds. Purpose, the particles are first reacted with, for example, the following materials prior to the coating step: including at least one organometallic, such as a compound clock compound, such as a methyl clock, 101246.doc -16-1291502 n-butyl lithium or hexa Lithium hydride; or decane, such as hexamethylene diazoxide, octyl methoxy sulphide 'especially _ fossil sizzling' like triterpene gas smoldering or dichloro decyl decane. One of the inventions By way of example, a mixture of a hydrophobic solid inorganic oxide and its corresponding non-hydrophobic inorganic oxide is used, the weight ratio of the two being, for example, 100:0 to 〇:100, preferably 99··丨 to 6〇:40, and More preferably, 99: 1 to 80 · · 20 〇 φ is preferably at least one organic or inorganic solid which is hydrophobic. Here, the meaning of hydrophobicity is understood to mean a solubility of less than gram per liter, preferably less than 〇. · 3 g / liter (measured at room temperature). The inorganic solids are preferably porous in nature. The porous structure is preferably characterized by a ruthenium surface area measured according to the German standard DIN 66131. The inorganic solids used are preferably It has a crucible surface area of 5 to 1 00 m 2 /g, particularly preferably a dry circumference of 10 to 800 m 2 /g, and a more preferred range of 2 to 5 m 2 /g. In one embodiment of the invention, there is at least one inorganic or organic solid in the form of particles. The central propensity particle diameter (intermediate value, number average) is measured to be at least 丨 nanometer, preferably at least 3 nm, and more preferably at least 6 nm. The maximum particle diameter (intermediate value, the average value of the number ^ is (7) (eight) too rice, preferably 350 nm, and more preferably 1 〇〇 nanometer. The particle diameter can be determined by a general method, such as, for example, penetration. Electron microscopy. The weight ratio of organic polymer to organic or inorganic solids in the form of particles is usually in the range of 9:1 to 1:9, preferably in the range of 4:_··4, and more preferably The range is 7 ·· 3 to 4 ··· 6. 101246.doc -17- Ϊ291502 In the embodiment of the present invention, at least one inorganic or organic solid in the form of spherical particles is expected to include granular The solid matter, wherein at least 75% by weight, preferably at least 9% by weight is present in the form of a sphere, and the other particles are present in a granular form. In the embodiment of the invention, at least one inorganic Or organic solids may form aggregates and/or binders. When one or more inorganic or organic solids are present in the form of aggregates and/or binders, they may consist of 2 to thousands of elementary particles. And the result is spherical, about the particle And it is closely related to the specific details of this elementary particle size of at least one solution used in the method of the present invention comprises at least one surfactant 'which is selected from emulsifiers of general formula I R2

和通式II的乳化劑And emulsifiers of formula II

R3OOC M〇3S COOR3 此處· R 選自（VCw烷基，例如正己基，異己基，正庚美， 異庚基，正辛基，異辛基，正壬基，正癸基，異癸 基，正-十一烷基，正-十二烷基，異-十二烷基，、正六 101246.doc -18- 1291502 十三烷基，正-十四烷基，異-十四烷基，正·十五恢 基’正-十六烧基’正-十八烧基’正_二十燒美，正 -C30H61，正-C40H81， T有一到五個C _ C雙鍵的C^Cw稀基，這此碳碳雙 鍵可以例如是分離的也可以是共輛的。可提及的實 例有烯丙基，-(CH2)2-CH=CH2 ，全-順 -(CH2)8-(CH=CH-CH2)3CH3 ， 全 _ 順R3OOC M〇3S COOR3 where R is selected from (VCw alkyl, eg n-hexyl, isohexyl, n-gumime, isoheptyl, n-octyl, isooctyl, n-decyl, n-decyl, isodecyl , n-undecyl, n-dodecyl, iso-dodecyl, n. six 101,246.doc -18- 1291502 tridecyl, n-tetradecyl, iso-tetradecyl,正·五十五恢基'正-六烧烧基'正-十八烧基' 正正20 burned beauty, 正-C30H61, 正-C40H81, T has one to five C _ C double bond C^Cw A dilute group, such a carbon-carbon double bond may be, for example, isolated or co-vehicle. Examples which may be mentioned are allyl, -(CH2)2-CH=CH2, per-cis-(CH2)8- (CH=CH-CH2)3CH3, full _ 顺

-(ch2)8-(ch=ch-ch2)2(ch2)4ch3 ， 全-順 -(CH2)8-CH=CH- (ch2)7ch3， r2 在每種情況下為相同或不同，且係選自氫和甲基， 較佳為甲基， m和η為相同或不同，都選自〇到1〇範圍中的整數，較佳為 1或2，而更佳為2， 3 R 在每種情況下為相同或不同，且選自氫和c:6-c2(r烷-(ch2)8-(ch=ch-ch2)2(ch2)4ch3 , all-cis-(CH2)8-CH=CH-(ch2)7ch3, r2 is the same or different in each case, and It is selected from the group consisting of hydrogen and methyl, preferably methyl, and m and η are the same or different and are selected from an integer in the range of 〇 to 1 ,, preferably 1 or 2, and more preferably 2, 3 R per In the case of the same or different, and selected from hydrogen and c:6-c2 (r-alkane)

基，例如正己基，異己基，正庚基，異庚基，正辛 基，異辛基，正壬基，正癸基，異癸基，正_十一烷 基，正-十二烷基，異-十二烷基，正_十三烷基，正_ 十四烷基，異-十四烷基，正_十五烷基，正_十六烷 基，正-十八院基，正-二十烧基； M 為一種鹼金屬或銨。 p礼2劑佔含水溶液的比例可以有很大範圍的選擇，它的 ^擇乾圍為0·1到200克/公升，較佳的範圍為0·2到100克/公 升而更佳為高達50克/公升。 本發明方法利含水溶液可於其中加人—或多種增稍劑 101246.doc •19- 1291502 以"周整其黏度’該增稠劑例如可以是天然或合成的。適用 的合成增稠劑是聚（甲基）丙烯酸系化合物，聚羧酸，聚醚， ^亞胺’聚醯胺以及聚胺基甲酸酯，特別是包括85重量％ 到95重罝％丙烯酸，4重量％到14重量％丙烯醯胺以及約〇.〇1 重1 %到1重量％式¥的（曱基）丙烯醯胺衍生物Base, for example, n-hexyl, isohexyl, n-heptyl, isoheptyl, n-octyl, isooctyl, n-decyl, n-decyl, isodecyl, n-undecyl, n-dodecyl ,iso-dodecyl, n-tridecyl, n-tetradecyl, iso-tetradecyl, n-pentadecyl, n-hexadecyl, n-eighteenth, n-Ethyl burnt; M is an alkali metal or ammonium. The ratio of the agent 2 to the aqueous solution may have a wide range of choices, and the dry range is from 0.1 to 200 g/liter, preferably from 0. 2 to 100 g/liter, and more preferably Up to 50 g / liter. The method of the present invention may contain a human or a plurality of extenders in an aqueous solution. 101246.doc • 19-1291502 The thickener may be natural or synthetic, for example, by "rounding its viscosity". Suitable synthetic thickeners are poly(meth)acrylic compounds, polycarboxylic acids, polyethers, imine polyamines and polyurethanes, especially comprising from 85% to 95% by weight of acrylic acid. 4% by weight to 14% by weight of acrylamide and about 〇.〇1 by weight of 1% to 1% by weight of (mercapto) acrylamide derivatives

V (其分子量]\^的範圍是1〇〇 〇〇〇到2〇〇 〇〇〇克/公升，式中的每 個R疋甲基或較佳為氫）的共聚物。天然來源之增稠劑的實 例包括瓊脂，鹿角菜苷，改質澱粉以及改質纖維素。 增稠劑的用量範圍例如為佔本發明方法所用溶液的〇重 賣％到10重量％，較佳的範圍是〇〇5重量％到5重量％，而更 佳的範圍是〇·1重量。/。到3重量％。V (its molecular weight) is a copolymer of 1 〇〇 to 2 〇〇 g / liter, each R 疋 methyl or preferably hydrogen in the formula. Examples of thickeners of natural origin include agar, carrageenin, modified starch, and modified cellulose. The thickener is used, for example, in an amount of from 10% by weight to 5% by weight of the solution used in the process of the present invention, preferably in the range of from 5% by weight to 5% by weight, and more preferably in the range of 〇·1 by weight. /. Up to 3 wt%.

本發明方法巾所用溶液在室溫τ之動態黏度的㈣較佳 ^ 1到5000 mPa.s，尤佳的範圍為2到4〇〇〇，*更佳的 範圍為5到2000 mPa.s，例如使用B_kfieid黏度計，按昭 ASTM D2196-81的方法測定。 本發明方法是以至少—種含水溶液處理吸收性材料的方 式進行。可以用相同或不同的含水溶液進行多次的 驟。 / 本發明之—具體實施財，本發明方法包括先用一種含 水洛液處理吸收性材料’特別是紡織品，這種含水溶液包 括至少-種有機聚合物，此外還包含—種以粒子形式存在 101246.doc -20. 1291502 〇有機固體物’或較佳為無機固體物，以及至少〆種通式】 =的乳化劑’然後用-種新的含水溶液再處理’這種新的 j水’谷液包括有機聚合物㈣再包括以粒子形式存在的有 機或無機固體物。 、t I體實施例中，本發明方法包括先用-種含 、夜處里吸收性材料，特別是纺織品，這種含水溶液包 少—種有機聚合物，此外還包括-種以粒子形式存在The solution for the method of the present invention has a dynamic viscosity at room temperature τ of (4) preferably from 1 to 5000 mPa.s, particularly preferably from 2 to 4 Å, and more preferably from 5 to 2000 mPa.s, For example, it is measured by the method of Show ASTM D2196-81 using a B_kfieid viscometer. The process of the present invention is carried out by treating the absorbent material with at least one aqueous solution. Multiple steps can be carried out with the same or different aqueous solutions. / The present invention - the specific method, the method of the present invention comprises first treating the absorbent material 'in particular textiles with an aqueous suspension liquid, the aqueous solution comprising at least one type of organic polymer, and further comprising a species in the form of particles 101246 .doc -20. 1291502 〇Organic solids' or preferably inorganic solids, and at least emulsifiers of the general formula = then re-treat with a new aqueous solution of 'this new j water' valley The liquid comprises an organic polymer (iv) and further comprises an organic or inorganic solid in the form of particles. In the embodiment of the present invention, the method of the invention comprises first using an in-situ, absorbent material at night, especially a textile, the aqueous solution containing less than one kind of organic polymer, and further comprising - in the form of particles presence

6、有機固體物’或較佳為無機固體物，以及至少一種通式I 或π的乳化劑，鈇徭用―接虹ΛΑ A , …、谩用種新的含水溶液再處理，這種新的 含水溶液包括另一錄古她®人仏 4 有栈聚5物以及至少一種通式I或II的 礼化劑’但不再包括以粒子形式存在的有機或無機固體物。 本發明之-較佳具體實施例中，本發明方法包括先用一 種含水溶液處理紡織品，這種含水溶液包括至少一種有機 1合物’此外還有一種以粒子形式存在的有機或者最好是 無機的固體物，以及至少一插 一 夕種通式1或11的乳化劑，然後用 :種新的，水溶液再處理’這種新的含水溶液不再 口物’但是包括已在第—步驟中使用過之以粒子形式存= 的無機固體物’以及至少一種通式I或II的乳化劑。 本發明方法進行操作時，溫度並不是那麼具關鍵性… 液的溫度範圍可以在_，c範圍之間，： 15到50。(：之間。 视固疋在 進行本發明方法所用的機器可以是吸收性材 紡織品）加工操作常用的機器，例如一或多個、、疋 (pad_mangles)。較佳是能把紡織品垂直進料的初^染: 101246.doc 1291502 的必要構件是兩個可以相互接觸擠壓的輥，通過兩個輥的 相互擠壓將紡織品拉出。液體要充滿輥中使液面在輥之 上，並潤濕紡織品。壓力使紡織品受擠壓，並確保持續的 加入0 本發明之—特定具體實施例中使用—個初染機，操 纺織品進料的速度範圍是每分鐘⑽米，較佳是 30米。 咬 …收的選擇為使得本發明方法提供的溶液吸收範圍 為25重量％到85重量％’較佳的範圍是重量％到70重量％。 、Ϊ發明之―特^具體實施例係、將含水溶液的泡珠塗布和 初染機作結合。本發明之另— /、體實施例係將含水溶液的 到刀塗布和初染機作結合。 H和、r A A k 月之又一具體實施例為將 ;合液的噴塗和初染機作結合。本發明的另-且體實施 例為將含水溶液的輥塗和初染機作結合。 =本發明處理過後，經處理㈣收性材料，特別是坊 ’’以用紡織品工業中常用的方法乾燥。 據本务日月方法進行的處理後可接著作埶卢理 可以連續或批次的方式摔作孰♦作熱處理，熱處理 個报大r“處理的持續時間可以有-固很大耗圍的選擇。典型的有 3。分鐘，特別是30秒到5分鐘1行=間為約10秒到約 加熱到高達^ …、處理的#作為將溫度 阿達18〇C，較佳為高達15(ΓΓ . ^ 必須合適於織物的敏感度。 。熱處理的溫度當然 …處理適用方法的一個例子是埶 熱處理法是I m _ …、乾法。另一種適當的 使用4多種的紅外線輻射器。 I0i246.doc a -22- !2915〇2 e本發明之—具體實施例中，待處理的吸收性材料，特別 是紡織品材料在按照本發明處理之前先提供一黏合層。這 個主黏合層的提供可以使用-種底漆。當要加工合成纖維 時’使用底漆是較佳的選擇。 本發明之-具體實施例中，應用於待處理吸收性材料， 特別是紡織品材料的黏合層可以例如是一種或多種的聚人 物，在這種情況下，聚合物的合成也可以在待處理的吸: 性材料，特別是紡織品材料上進行。特別適用的聚合物且 有交聯基或可交聯基，例如帶有自由經基，幾基，一級或 -級胺基或硫醇基之天然或合成的聚合物。非常適用之聚 !物的實例是木質素’多醋，聚乙烯醇以及聚乙稀亞胺： 乂聯可例如透過與異氰s旨，二經甲基脲或Hi_ I 二經基伸乙基脲（Dmdheu)的後續反應而完成。宜: 特佳的交聯劑是三聚氰胺-甲咖，它可以用甲醇驗化。 另一具體實施例中’當要對聚S旨或聚醯胺進行處理時， o.omm重量較佳為G1重量％狀5重量％的纺織 叩要用強鹼（例如氳氧化納水溶液或氫氧化卸水溶液）進行 部分皂化反應以皂化之。 t發明另提供依本發^法加4吸收性 纺織品。按照本發明的加工方法提供了本發明具有一:戈； 層塗層的吸收性好粗 ’夕 ' 特別是紡織品。本發明的吸收性材 料，特別是紡織品，且古復w 性材 的吸收性材料，特別污和防水性能。本發明 吸收性材料，特別曰有非常好的機械強度。在 、J疋、、、方織品中，按照本發明作塗覆時，所 101246.doc -23- 1291502 用的固體較佳是各向同性的或者基本上是各向同性的消散 方、i個加工塗層中’也就是說，在加工塗層和周圍大氣之 間的邊界層中看不到任何的濃度差。 -具體實施例中，本發明的吸收性材料，特 包括0.5到50克/平方米的塗層，較佳為1$iJ2〇克/平方求的塗 層，而更佳為1.5到17克/平方米的塗層。 本毛月進步&供含水的溶液，其包括至少一種有機聚 合物，至少一種粒子形態的有機或無機固體，以及至少一 種礼化劑，該乳化劑係選自通式I的乳化劑 R2 〇6. An organic solid material or preferably an inorganic solid, and at least one emulsifier of the formula I or π, which is treated with a new aqueous solution, using a new type of aqueous solution, this new The aqueous solution comprises another granules of the genus 4 having a stack of 5 and at least one ritual of the formula I or II 'but no longer including organic or inorganic solids in the form of particles. In a preferred embodiment of the invention, the process of the invention comprises first treating the textile with an aqueous solution comprising at least one organic compound and additionally having an organic or preferably inorganic form in the form of particles Solid matter, and at least one emulsifier of formula 1 or 11, and then treated with a new, aqueous solution, 'this new aqueous solution is no longer a mouthful' but includes already in the first step An inorganic solid as used in the form of particles and at least one emulsifier of the formula I or II are used. When the process of the invention is operated, the temperature is not so critical... The temperature range of the liquid can be between _, c, and: 15 to 50. (: Between. The machine used in the method of the present invention may be an absorbent material textile) a machine commonly used for processing operations, such as one or more, _ (pad_mangles). Preferably, the primary material capable of feeding the textile vertically: 101246.doc 1291502 The necessary components are two rolls which can be pressed against each other, and the textile is pulled out by mutual squeezing of the two rolls. The liquid is filled in the roll so that the liquid level is on the roll and wets the textile. The pressure causes the textile to be squeezed and ensures continued addition to the present invention, which is used in a particular embodiment - a primary dyeing machine that feeds the textile at a speed in the range of (10) meters per minute, preferably 30 meters. The bite is selected such that the solution provided by the process of the invention has an absorption range of from 25% to 85% by weight. A preferred range is from 3% to 70% by weight. The invention is a combination of an aqueous solution-containing bead coating and a first dyeing machine. Another embodiment of the invention combines an aqueous solution to a knife coating and a primary dyeing machine. Another embodiment of H and r A A k months is to combine a liquid-sprayed spray with a primary dyeing machine. Another embodiment of the invention combines an aqueous solution roll coating with a primary dyeing machine. After the treatment of the present invention, the treated (four) retractable material, in particular, is dried by methods commonly used in the textile industry. According to the daily and monthly methods of the current affairs, the works can be connected to the work. Lu Li can be used as a heat treatment in a continuous or batch manner. The heat treatment can be used to report the duration of the treatment. Typically there are 3. minutes, especially 30 seconds to 5 minutes, 1 row = between about 10 seconds to about heating up to ..., treated # as the temperature Ada 18 〇 C, preferably up to 15 (ΓΓ. ^ Must be suitable for the sensitivity of the fabric. The temperature of the heat treatment is of course... An example of a suitable method of treatment is that the heat treatment method is I m _ ..., dry method. Another suitable use of more than 4 kinds of infrared radiators I0i246.doc a -22-!2915〇2 e In the embodiment of the invention, the absorbent material to be treated, in particular the textile material, is provided with an adhesive layer prior to treatment according to the invention. The provision of this primary adhesive layer can be used. Primer. The use of a primer is a preferred option when processing synthetic fibers. In a particular embodiment of the invention, the adhesive layer applied to the absorbent material to be treated, in particular the textile material, may for example be one or more In this case, the synthesis of the polymer can also be carried out on the absorbent material to be treated, in particular on textile materials. Particularly suitable polymers and having crosslinkable or crosslinkable groups, for example with freedom A natural or synthetic polymer of a base, a few groups, a primary or a grade of an amine or a thiol group. An example of a very suitable poly! material is lignin' polyacetate, polyvinyl alcohol and polyethyleneimine: The combination can be carried out, for example, by a subsequent reaction with isocyanate, dimethyl urea or Hi-I diethylidene (Dmdheu). Preferably: a particularly good crosslinking agent is melamine-methyl coffee, which can be used. In another embodiment, 'when the poly-S or polydecylamine is to be treated, the o.omm weight is preferably G1% by weight, and 5% by weight of the textile is to be oxidized with a strong base (for example, hydrazine). The sodium saponification solution or the aqueous saponification solution is subjected to a partial saponification reaction to saponify. The invention further provides a absorbing textile according to the present invention. The processing method according to the present invention provides the invention with a gradation; The absorption is very good, the 'eve' is especially textile. Absorbent materials, especially textiles, and absorbent materials of ancient complex w, particularly dirt and water-repellent properties. The absorbent material of the present invention, in particular, has very good mechanical strength. In, J疋, ,, In fabrics, when applied in accordance with the present invention, the solids used in 101246.doc -23- 1291502 are preferably isotropic or substantially isotropic dissipative, i processed coatings. No difference in concentration is observed in the boundary layer between the processed coating and the surrounding atmosphere. In a specific embodiment, the absorbent material of the present invention specifically comprises a coating of 0.5 to 50 g/m 2 , preferably A coating of 1$iJ2 gram per square, and more preferably a coating of 1.5 to 17 grams per square meter. The present invention relates to an aqueous solution comprising at least one organic polymer, at least one particulate organic or inorganic solid, and at least one emulsifier selected from the group consisting of an emulsifier of the formula I R2 〇

R—N ΟR-N Ο

R ‘ 和通式II的乳化劑 r3ooc )~Λ " m〇3s coor3 此處每個變數係定義如上。本發明溶液例如對於加工吸 收性材料’特別是纺織品都是非常有用的。 溶劑 亡’X明洛液可以包含更多的組分，例如一或多種的有機 特 本t月進步提供本發明溶液用來加工吸收性材料， 別是紡織品的用途。 101246.doc -24- 1291502 本發明進-步提供了-種生產含水溶液的方&，下文亦 稱之為本發明之製法。本發明之製法包含混合下列組分： 至少一種有機聚合物， 至少一種粒子形態的有機或無機固體物， 水，和 視情況存在的一或多種有機溶劑， 以及視情況存在的一或多種通式的乳化劑。 • 本發明之製法通常是在室溫到高達約⑽。c的溫度範圍 内進行，室溫是較佳的選擇。 • 本發明之製法—般都包括-均句化的步驟，例如利用機 •械或氣體風力的授拌，搖動，超音波作用或這幾種方式的 結合。然而’在有些情況下，均勻化步驟也可以省卻。 組成成份的添加順序原則上是可以自由選擇的。例如， 第-步可以是製備一種聚合物以及一種有機或無機固體物 之不含水和溶劑的混合物，然後把乾燥的混合物分散於有 _㈣劑或水和有機溶劑和通式l5iui之乳化劑的混合物中或 疋水和通式I或π之乳化劑的混合物中。 本發明之製法的一個具體實施例中，一開始的步驟為製 備包合有機聚合物，粒子形態的有機或無機固體物， 多種通式咖的乳化劑的配方，以及要是合適的話另包含 水和2多種的有機溶劑。在進行本發明之吸收性材料的 =里之别，按照本發明的液體是經由用水和另外的有機溶 M (如果合適的話）對根據本發明之配方進行稀釋製得的。本 ^月配方較佳包含不超過15重量％的水，尤佳為約〇丄10重 101246.doc -25- 1291502 量％的水，更佳為高達5重量％的水。根據本發明之配方也 可以不含水。 本發明此外還提供了包括有機聚合物，粒子形態之有機 或無機固體物，-或多種通幻或叫乳化劑以及要是合適 的話另包含水和一或多種有機溶劑的配方，其中水的分率 可為約0.1-10重量％，而較佳為高達5重量。/(^根據本發明的 配方對製造根據本發明的含水溶液特別有用。 Φ 本發明茲以實例進行說明。 實例1 :本發明含水溶液的製備 實例1.1 :本發明含水溶液1 · i的製備 利用機械攪拌將下列物質在一燒瓶中混合·· 8 7 2 · 8克的蒸顧水， 68.1克無規共聚物的含水分散液（固體物的含量為2〇重量 °/〇)，共聚物是由10重量的曱基丙烯酸和9〇重量％的 CH2=C(CH3)COCKCH2-CH2K6F13 形成的，其分子量 Mn φ 為3000克/莫耳（凝膠滲透層析法）， 86.5克無規共聚物的含水分散液（固體物的含量為2〇重量 /〇) ’共聚物疋由20重量％的丙稀酸和8〇重量的乙稀形成 的，其1^為20000克/莫耳，用n，N-二甲基乙醇胺中和， pH值在8.5和9.5之間。 然後添加12· 8克一甲基石夕氧烧基改質的火成石夕石，其bet 表面積為225平方米/克，按照德國標準規範〇1>1 66131測 定，主要的粒子尺寸：1〇奈米（中間值，數目平均值） 以及添加 101246.doc -26- 1291502 8.8克通式1.1的胺R ‘ and emulsifier of formula II r3ooc )~Λ " m〇3s coor3 Here each variable is defined as above. The solution of the invention is very useful, for example, for processing absorbent materials, particularly textiles. Solvents The 'X Mingluo liquid may contain more components, such as one or more organic specials, to provide the use of the solution of the invention for processing absorbent materials, other textiles. 101246.doc -24- 1291502 The present invention further provides a process for producing an aqueous solution, hereinafter also referred to as the process of the present invention. The process of the invention comprises mixing the following components: at least one organic polymer, at least one organic or inorganic solid in the form of particles, water, and optionally one or more organic solvents, and optionally one or more formulas Emulsifier. • The process of the invention is typically at room temperature up to about (10). Room temperature is a preferred choice for the temperature range of c. • The method of the present invention generally includes steps of homogenization, such as the use of mechanical or gas wind mixing, shaking, ultrasonic or a combination of these. However, in some cases, the homogenization step can also be eliminated. The order in which the components are added is in principle freely selectable. For example, the first step may be to prepare a polymer and a mixture of an organic or inorganic solid without water and a solvent, and then disperse the dried mixture in an emulsifier having a _(iv) agent or water and an organic solvent and a formula 1-5iui. The mixture is either in the mixture of hydrazine and an emulsifier of the formula I or π. In a specific embodiment of the process of the present invention, the first step is to prepare an organic or inorganic solid in the form of an organic polymer, a particle form, an emulsifier of a plurality of formulas, and, if appropriate, water and 2 kinds of organic solvents. In the case of carrying out the absorbent material of the invention, the liquid according to the invention is obtained by diluting the formulation according to the invention with water and an additional organic solvent M, if appropriate. The present month formulation preferably comprises no more than 15% by weight of water, more preferably about 10% by weight of 101246.doc -25 - 1291502% by volume, more preferably up to 5% by weight of water. The formulation according to the invention may also be free of water. The invention furthermore provides a formulation comprising an organic polymer, an organic or inorganic solid in the form of particles, or a plurality of phantom or emulsifiers and, if appropriate, water and one or more organic solvents, wherein the fraction of water It may be from about 0.1 to 10% by weight, and preferably up to 5 parts by weight. /(^ The formulation according to the invention is particularly useful for the manufacture of an aqueous solution according to the invention. Φ The invention is illustrated by way of example. Example 1: Preparation of an aqueous solution of the invention Example 1.1: Preparation of an aqueous solution of the invention 1 · i Mechanical stirring The following materials were mixed in a flask. 8 7 2 · 8 g of distilled water, 68.1 g of a random dispersion of a random copolymer (solid content of 2 〇 weight / 〇), the copolymer was Formed from 10 parts by weight of methacrylic acid and 9% by weight of CH2=C(CH3)COCKCH2-CH2K6F13, the molecular weight Mn φ is 3000 g/mole (gel permeation chromatography), 86.5 g of random copolymer Aqueous dispersion (solid content of 2 〇 weight / 〇) 'Copolymer 疋 formed by 20% by weight of acrylic acid and 8 〇 by weight of ethylene, 1 ^ is 20,000 g / mol, with n Neutralized with N-dimethylethanolamine, pH between 8.5 and 9.5. Then add 12. 8 grams of monomethyl oxalate-modified igneous stone, with a bet surface area of 225 square meters / Gram, measured according to the German standard specification 〇1 > 1 66131, the main particle size: 1 〇 nano (middle Value, number average) and addition of 101246.doc -26- 1291502 8.8 g of amine of formula 1.1

OH OH 1.1 其係以32重量％的鹽酸水溶液中和，讓其分散1〇分鐘（用 Uhraturrax攪拌器），獲得本發明的含水溶液1 · 1，其pH值為 7.5 〇 實例1.2 :本發明含水溶液1.2的製備 利用機械攪拌將下列物質在一燒瓶中混合： 872.8克的蒸餾水， 6 8.1克無規共聚物的含水分散液（固體物的含量為2 〇重量 %)’共聚物是由10重量。/〇的甲基丙烯酸和9〇重量％的 CH2=C(CH3)COO-CH2-CH2-正 _(：6Ϊ?13形成的，其分子量Mn 為3000克/莫耳（凝膠滲透層析法）， 86.5克無規共聚物的含水分散液（固體物的含量為2〇重量 °/〇) ’共聚物是由20重量％的丙烯酸和8〇重量％的乙烯形成 的，其]^^為20 〇〇〇克/莫耳，用N，N-二甲基乙酵胺中和， pH值在8.5和9.5之間。 然後添加12.8克二甲基矽氧烷基改質的火成矽石，其bet 表面積為225平方米/克，按照德國標準規範din 66131測 定’主要的粒子尺寸·· 1G奈米（中間值，數目平均值） 以及添加 8.8克通式ι·2的胺 101246.doc -27- 1291502 〇OH OH 1.1 was neutralized with a 32% by weight aqueous hydrochloric acid solution and allowed to disperse for 1 Torr (using a Uhraturrax stirrer) to obtain an aqueous solution of the present invention 1 .1 having a pH of 7.5 〇 Example 1.2: The present invention contains Preparation of aqueous solution 1.2 The following materials were mixed in a flask by mechanical stirring: 872.8 g of distilled water, 68.1 g of an aqueous dispersion of random copolymer (solid content of 2% by weight) 'Copolymer was made up of 10 weights . /〇 methacrylic acid and 9〇% by weight of CH2=C(CH3)COO-CH2-CH2-正_(:6Ϊ?13, its molecular weight Mn is 3000 g/mole (gel permeation chromatography ), an aqueous dispersion of 86.5 g of a random copolymer (solid content of 2 〇 weight / 〇) 'The copolymer is formed from 20% by weight of acrylic acid and 8% by weight of ethylene, which is ^^ 20 g / mol, neutralized with N,N-dimethylethylamine, pH between 8.5 and 9.5. Then add 12.8 g of dimethyl sulfoxyalkyl modified igneous vermiculite , with a bet surface area of 225 m 2 /g, measured according to the German standard specification din 66131 'main particle size · 1G nanometer (intermediate value, number average) and 8.8 g of amine of formula ι·2 added 101246.doc -27- 1291502 〇

其係以32重量％的鹽酸水溶液中和，讓其分散1〇分鐘（用It was neutralized with a 32% by weight aqueous solution of hydrochloric acid and allowed to disperse for 1 minute (using

Ultraturrax攪拌器），獲得本發明的含水溶液丨2，其pH值為 7.5 〇 實例1.3 :本發明含水溶液1 ·3的製備 _ 利用機械攪拌將下列物質在一燒瓶中混合： 872.8克的蒸餾水， 68·1克無規共聚物的含水分散液（固體物的含量為2〇重量 — %)，共聚物是由1〇重量％的曱基丙烯酸和90重量％的 CH2=C(CH3)COO-CH2-CH2-正-QF〗3形成的，其分子量Μη 為3000克/莫耳（凝膠滲透層析法）， 86·5克無規共聚物的含水分散液（固體物的含量為2〇重量 φ °〆。）’共聚物是由20重量％的丙稀酸和80重量％的乙烯形成 的’其]\4〜為20 000克/莫耳，用ν，Ν-二甲基乙醇胺中和， pH值在8.5和9.5之間。 然後添加12.8克二甲基矽氧烷基改質的火成矽石，其bet 表面積為225平方米/克，按照德國標準規範DIN 66131測定， 主要的粒子尺寸·· 1〇奈米（中間值，數目平均值）以及添加 8.8克通式1.3的胺 101246.doc -28- 1291502Ultraturrax stirrer) to obtain the aqueous solution of the present invention 丨2 having a pH of 7.5 〇 Example 1.3: Preparation of the aqueous solution of the present invention 1-3. The following materials were mixed in a flask by mechanical stirring: 872.8 g of distilled water, An aqueous dispersion of 68. 1 gram of random copolymer (solid content of 2 〇 wt-%), the copolymer is composed of 1% by weight of methacrylic acid and 90% by weight of CH2=C(CH3)COO- CH2-CH2-正-QF3 formed with an molecular weight Μη of 3000 g/mole (gel permeation chromatography), an aqueous dispersion of 86.5 g of random copolymer (solid content of 2〇) Weight φ ° 〆.) 'The copolymer is formed from 20% by weight of acrylic acid and 80% by weight of ethylene's] \4~ is 20 000 g / mol, using ν, Ν-dimethylethanolamine And, the pH is between 8.5 and 9.5. Then add 12.8 g of dimethylphosphonium alkyl modified fumed vermiculite with a bet surface area of 225 m 2 /g, determined according to the German standard DIN 66131, the main particle size · 1 〇 nano (intermediate value) , the number average) and the addition of 8.8 g of the amine of formula 1.3 101246.doc -28- 1291502

1.3 其係以32重;f %的鹽酸水溶 _物ax授拌器），獲孝讓其刀放1 〇分鐘（用 75。 ^于本务曰月的含水溶液1.3,其PH值為 實例2織物的加工 貫例2 · 1用本發明的含水溶液丨·丨作處理 貫例2 · 1 · 1聚g旨的處理 在Mathis生產的初染機（型號為HVFi2〇85)上用溶液u 處理一個基重量為220克/平方米的編織聚醋織物。輥的擠 f壓力為2.6巴。$導致獲得6G%的液體吸收。塗布速度為 每分鐘2米。隨後將處理過的聚酯織物放在12〇<>c的張布機 上乾燥。最後的熱處理操作在^❻乞下使用循環的空氣持續 3分鐘。獲得本發明經處理的聚酯織物2.〗· 1。 實例2.1.2聚醯胺的處理 在Mathis生產的初染機（型號為HVF12085)上用溶液1.1 處理一個基重量為160克/平方米的編織聚醯胺織物。輥的 擠出壓力為2.6巴。這導致獲得65%的液體吸收。塗布速度 為每分鐘2米。隨後將處理過的聚醯胺織物放在120°C的張 布機上乾燥。最後的熱處理操作在1 50°C下使用循環的空氣 持續3分鐘。獲得本發明經處理的聚醯胺織物2· 1 ·2。 實例2.1.3聚丙烯酸系物的處理 在Mathis生產的初染機（型號為HVF12085)上用溶液1·1 101246.doc •29- 1291502 處理一個基重量為295克/平方米之編織聚丙烯酸系物的織 物。輥的擠出壓力為2 6巴。這導致獲得5〇%的液體吸收。 塗布速度為每分鐘2米。隨後將處理過的聚丙烯酸系物織物 放在120°C的張布機上乾燥。最後的熱處理操作在i5〇ct下 使用循％的空氣持續3分鐘。獲得本發明經處理的聚丙烯酸 系物織物2.1.3。 實例 2·2·1 到 2·2·3 以及 2.3.1 到 2·3·31.3 The system is 32 weight; f% hydrochloric acid water soluble _ material ax feeder, filial piety let the knife put for 1 〇 minutes (with 75. ^ in the service of the month of the aqueous solution 1.3, the PH value of the example 2 Processing Example 2 of the fabric The treatment with the aqueous solution of the present invention is carried out. The treatment of the example 2 · 1 · 1 polyg is treated with the solution u on the first dyeing machine (model HVFi2〇85) manufactured by Mathis. A woven polyester fabric having a basis weight of 220 g/m2. The squeezing pressure of the rolls was 2.6 bar. $ resulted in a liquid absorption of 6 G%. The coating speed was 2 m per minute. The treated polyester fabric was then placed. Dry on a 12 〇<>c cloth spreader. The final heat treatment operation uses circulating air for 3 minutes. The treated polyester fabric of the present invention is obtained 2. 〗 〖1. Example 2.1. Treatment of 2 Polyamides A woven polyamide fabric having a basis weight of 160 g/m 2 was treated with solution 1.1 on a primary dyeing machine (model HVF12085) manufactured by Mathis. The extrusion pressure of the rolls was 2.6 bar. A 65% liquid absorption is obtained. The coating speed is 2 meters per minute. The treated polyamide fabric is then placed at 120 ° C. The machine was dried on a sheeting machine. The final heat treatment was carried out using circulating air for 3 minutes at 150 ° C. The treated polyamide fabric of the present invention was obtained in the range of 2.1·2. Example 2.1.3 Treatment of polyacrylic acid series A woven polyacrylic fabric having a basis weight of 295 g/m 2 was treated with a solution of 1·1 101246.doc •29-1291502 on a first dyeing machine (model HVF12085) manufactured by Mathis. The extrusion pressure of the rolls was 2 6 bar. This resulted in a liquid absorption of 5 %. The coating speed was 2 meters per minute. The treated polyacryl fabric was then dried on a 120 ° C machine. The final heat treatment was performed at i5. 5% of air was used for 3 ct for 3 minutes to obtain the treated polyacrylic fabric of the present invention 2.1.3. Examples 2·2·1 to 2·2·3 and 2.3.1 to 2·3·3

除了在實例厶2·1到2·2·3中，用本發明的含水溶液1>2代替 本發明的含水溶液u以及在實例2 31到2 3 3中，用本發明 的合水〉谷液1·3代替本發明的含水溶液丨·」之外，茲重複實例 2.1.1 到 2.1.3 〇 •根據本發明處理之紡織品樣品的防水試驗 已根據本發明處理和待處理的纺織品樣品用手拉緊，终 後^釘子將其固定在_平的木板上，木板的傾角在}。到列 的:圍内：連續的調整。然後用一個套管將各別的水滴农 笔米的π度滴到紡織品樣品上。水滴的質量為* =:傾斜的角度減小，-直到水滴正要開始以串珠狀 :切下滴並且沒有任何的黏著現象為止。結果示於表〗 根勘―_5侧進行測試 表1 ·傾斜的角度In addition to the examples 厶2·1 to 2·2·3, the aqueous solution 1>2 of the present invention is used in place of the aqueous solution u of the present invention, and in the examples 2 31 to 2 3 3, the combined water of the present invention is used. In addition to the aqueous solution of the present invention, in addition to the aqueous solution of the present invention, examples 2.1.1 to 2.1.3 are repeated. • Waterproofing test of textile samples treated according to the present invention. Textile samples processed and to be treated according to the present invention. Hold it tightly, and then nail it to the _ flat plank, the inclination of the board is at }. To the column: within the circumference: continuous adjustment. Then use a cannula to drop the π degrees of each drop of rice into the textile sample. The mass of the water droplet is * =: the angle of the tilt is reduced, - until the water droplet is about to start to be beaded: the drop is cut and there is no sticking. The results are shown in the table. Test on the _5 side. Table 1 · Angle of inclination

101246.doc -30- 1291502 223 ~~~- 7 〜 —2·3·1 '~~- 5 ^ 23.2 — 7 ~ 233 _--- ------— <20重量％ <20重量％ <20重量％ ^"""—I 至里 /〇 本1明的纺織品樣品（聚g旨’聚酿 乂釅恥，聚丙烯酸系物）每種 都擁有非常好的機械穩定性。為了 J進仃檢測，在傾斜角度 重新確定之前，對每個樣品都尊 又 石丨要進仃2000次的拉緊然後 開的過程。傾斜的角度和表丨 双1相比沒有任何的改變。101246.doc -30- 1291502 223 ~~~- 7 ~ —2·3·1 '~~- 5 ^ 23.2 — 7 ~ 233 _--- ------— <20% by weight <20重量% <20% by weight ^"""-I 至里/〇本1明的纺织样 (聚聚的'聚聚乂酽, shame, polyacrylic) each has very good Mechanical stability. In order to detect the J, the process of tightening and then opening the sarcophagus for each sample is performed before the tilt angle is re-determined. The angle of the tilt is not changed from the double 1 1 .

3K 101246.doc3K 101246.doc

Claims (1)

，129 6217號專利申請案 中文申請專利範圍替換本(96年5月） 十、申請專利範圍： 1· 一種加工吸收性材料之方法’其係使用至少一種含水溶 液處理該吸收性材料，該含水溶液包括： 至少一種選自烯系不飽和疏水性單體之聚合物及共聚 物的有機聚合物，其在25t時具有低於i克/公升之水中 溶解度， 至少一種呈粒子形式的有機或無機固體，其係選自聚 乙烯、聚丙烯、聚異丁烯及聚苯乙烯，及其與彼此或與 一或多種其他稀烴之共聚物，及週期表3到14族中的固態 氧化物、碳酸鹽、磷酸鹽、矽酸鹽或硫酸鹽，以及 至少一種乳化劑，其係選自通式j, Patent Application No. 129 6217, Chinese Patent Application Substitution (May 96) X. Patent Application Range: 1. A method of processing an absorbent material, which is to treat the absorbent material using at least one aqueous solution, the inclusion The aqueous solution comprises: at least one organic polymer selected from the group consisting of polymers and copolymers of ethylenically unsaturated hydrophobic monomers having a solubility in water of less than 1 g/liter at 25 t, at least one organic or inorganic in the form of particles a solid selected from the group consisting of polyethylene, polypropylene, polyisobutylene, and polystyrene, and copolymers thereof with each other or with one or more other dilute hydrocarbons, and solid oxides, carbonates of Groups 3 to 14 of the periodic table. a phosphate, a citrate or a sulphate, and at least one emulsifier selected from the group consisting of 和通式II的乳化劑 r3ooc )~λ 3 mo3s coor 其中： r1係選自C6-C4Q-烷基以及具有一至五個碳碳雙鍵的 C3-C4G-稀基’ R在每個例子中為相同或不同，並係選自氫和甲基， 101246-960523.doc 1291502 Π1和η為相同或不同，各選自〇到10範圍中的整數， R3在每個例子中為相同或不同，並且係選自氫和 〇6<2〇_ 烧基， Μ 為驗金屬或錢。 2·如請求項丨之方法，其中該有機或無機固體或該有機或無 機固體之至少一者為疏水性。 3·如請求項1或2之方法，其中該吸收性材料的表面在進行 該處理之前先塗上一層黏合層。 4·如請求項1或2之方法，其中該或該等固體係為一或多種 無機固體。 5·如請求項1或2之方法，其中該或該等有機或無機固體係 以至少5.5克/公升的分率存在於溶液中。 6·如請求項1或2之方法，其中該或該等有機或無機固體具 有10到1000奈米之顆粒直徑（中間值，數目平均值）。 7·如請求項1或2之方法，其中該吸收性材料係紡織品材料。 8· 一種含水溶液，其包括 0.1至500克/公升之至少一種選自烯系不飽和疏水性單 體之聚合物及共聚物的有機聚合物，其在25<5(：時具有低 於1克/公升之水中溶解度， 5.5至150克/公升之至少一種呈粒子形 < 的有機或無機 固體，其係選自聚乙烯、聚丙烯、聚異丁烯及聚苯乙烯， 及其與彼此或與一或多種其他烯烴之共聚物，及週期表3 到14族中的固態氧化物、碳酸鹽、磷酸鹽、矽酸鹽或硫 酸鹽， 101246-960523.doc •1291502 0.1至200克/公升之至少一種乳化劑，其係選自通式工And an emulsifier of the formula II r3ooc )~λ 3 mo3s coor wherein: r1 is selected from C6-C4Q-alkyl and C3-C4G-dilth' R having one to five carbon-carbon double bonds is in each case The same or different, and selected from hydrogen and methyl, 101246-960523.doc 1291502 Π1 and η are the same or different, each selected from the integers ranging from 〇 to 10, and R3 is the same or different in each case, and It is selected from hydrogen and 〇6<2〇_ 烧基, Μ for metal or money. 2. The method of claim 1, wherein at least one of the organic or inorganic solid or the organic or inorganic solid is hydrophobic. 3. The method of claim 1 or 2, wherein the surface of the absorbent material is coated with an adhesive layer prior to the treatment. 4. The method of claim 1 or 2, wherein the or the solids are one or more inorganic solids. 5. The method of claim 1 or 2, wherein the or the organic or inorganic solid is present in the solution at a fraction of at least 5.5 grams per liter. 6. The method of claim 1 or 2, wherein the or the organic or inorganic solids have a particle diameter (intermediate value, number average) of from 10 to 1000 nm. 7. The method of claim 1 or 2, wherein the absorbent material is a textile material. 8. An aqueous solution comprising 0.1 to 500 g/liter of at least one organic polymer selected from the group consisting of polymers and copolymers of ethylenically unsaturated hydrophobic monomers, having a ratio of less than 1 at 25 <克 / liter of water solubility, 5.5 to 150 g / liter of at least one of the organic or inorganic solids in the form of particles, selected from polyethylene, polypropylene, polyisobutylene and polystyrene, and with each other or a copolymer of one or more other olefins, and a solid oxide, carbonate, phosphate, citrate or sulphate of Groups 3 to 14 of the Periodic Table, 101246-960523.doc • 1291502 0.1 to 200 g/L at least An emulsifier selected from the group consisting of 和通式II的乳化劑 r3oocAnd emulsifier of formula II r3ooc mo3s coor3 其中： R選自烷基以及具有一至五個碳碳雙鍵的 C3-C4Q_烯基， r2每個例子中為相同或不同，並係選自氫和曱基， m和η為相同或不同，各選自〇到1〇範圍中的整數， R每個例子中為相同或不同，並且係選自氫和c6 c 烷基， 20" M 鹼金屬或銨，以及 以至/jnL下為液體的分率為基準，至少5重量％的水。 9. 一種利用如請求項8之含水溶液於加工吸收性材料的用 途。 10· —種用來製造如請求項8之含水溶液之配方的用途，其中 該配方包括有機聚合物，呈粒子形態的有機或無機固體 材料’ 一或多種通式I或π的乳化劑，及若適當，一 101246-960523.doc •1291502 種有機溶劑，以及若適當，水，且水的分率不超過丨5重 量％，其係以配方中室溫下為液體的所有分率為基準。 11· 一種配方，其包括有機聚合物，呈粒子形態的有機或無 機固體材料，一或多種通式I或II的乳化劑，及若適當， 一或多種有機溶劑，以及若適當，水，其中水的分率不 超過15重量％。 101246-960523.doc 4Mo3s coor3 wherein: R is selected from the group consisting of an alkyl group and a C3-C4Q-alkenyl group having one to five carbon-carbon double bonds, and r2 is the same or different in each of the examples, and is selected from hydrogen and a fluorenyl group, and m and η are the same Or different, each selected from the group consisting of 〇 to 1 整数, R is the same or different in each case, and is selected from hydrogen and c6 c alkyl, 20" M alkali metal or ammonium, and even under /jnL The liquid fraction is based on at least 5% by weight of water. 9. Use of an aqueous solution according to claim 8 for processing an absorbent material. 10. The use of a formulation for the manufacture of an aqueous solution according to claim 8, wherein the formulation comprises an organic polymer, an organic or inorganic solid material in the form of particles, one or more emulsifiers of the formula I or π, and If appropriate, a 101246-960523.doc • 1291502 organic solvent, and if appropriate, water, and the water fraction does not exceed 丨 5% by weight, based on all fractions of the formulation at room temperature. 11. A formulation comprising an organic polymer, an organic or inorganic solid material in the form of particles, one or more emulsifiers of the formula I or II, and, if appropriate, one or more organic solvents, and if appropriate, water, wherein The fraction of water does not exceed 15% by weight. 101246-960523.doc 4