1273114 九、發明說明 【發明所屬之技術領域】 本發明係有關於一種多機能母粒及其纖維之製造方 法，特別疋一種竹炭母粒以及其纖維之製造方法。 【先前技術】 枝肖b丨生織物係添加功能性粒子或成分於織物纖維之 内’或直接由具有機能性之纖維編織而成。例如以活性碳粒 子用來除臭或吸附移除雜質、吸附毒性物質與臭味。 目前機能性纖維之運用相當廣泛，美國專利編號 ，_，742、編號 Ml9,44G、編號 5,238,899、編號 4,772,455 便提供了數種活性碳纖維，可以製成各種織物用來移除 附雜質、毒性物質與臭味。 、次 然而’活性碳纖維之機能性僅侷限於吸附雜質與除臭， …、法進一步提供其他機能。 、BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a multi-functional masterbatch and a fiber thereof, and more particularly to a method for producing a bamboo charcoal masterbatch and a fiber thereof. [Prior Art] The fabric is added with functional particles or components within the fabric fibers or directly woven from functional fibers. For example, activated carbon particles are used to deodorize or adsorb impurities, adsorb toxic substances and odors. At present, the use of functional fibers is quite extensive. U.S. Patent No. _, 742, No. Ml9, 44G, No. 5, 238, 899, No. 4, 772, 455 provide several kinds of activated carbon fibers, which can be made into various fabrics for removing impurities, toxic substances and Stinky. However, the function of the activated carbon fiber is limited to the adsorption of impurities and deodorization, and the method further provides other functions. ,
〜竹炭（bamb。。eh㈣。al)乃是採用天㈣材‘竹子經由 间，皿燒製而得之，相較於傳統活 名 ^ x 町厌具有可吸收渴 乳、遠紅外線並且釋放負離子之 τ及收二 無毒盔宝，已声爷、雷m 且竹厌源自於天然 奋u ‘、、、。 運用於汽車内裝、農作紡織品、建築填 充口口、環境濾材紡織品用以除臭 ’、、 用於醫瘃你储純口” 尹化玉虱或水質；更被利 、醫療保健、我口口以及運動用織 潘M^ ^ 用以，為除異味、促進血 液循壞以及利用負離子阻止細菌病毒促進 紡織品之中，不僅可使織物；直。將竹炭加入 添加多彳f枪+ g卩π、夕種複合功能，且不需 J加夕種拉子即可達到多種效 大&降低了產品之成 5 !273114 本。日本專利編號JP2,003,253,557更提供—種多功能可吸 寸有故鹽類、返紅外線己極臭味之活性碳纖維。 風然而，習知之機能性纖維的製造過程都必須經過多次化 予處理，或使用各種程序，例如浸$責、喷霧、炫喷或直接碳 化的方式，將功能性成分黏著以於基材之上。而這些處理 所使用之化學試劑，極有可能殘留於纖維之中， Γ常會有掉粒、脫落的現象，在使料反Μ為另-種污 木物的來源。再加上，功能性成分常會造成纖維的物理性質 不佳’影響功能性纖維的應用範圍。 為了解決此-問題，日本專利編號JP2,003,041，438提 供了一種利用熔融紡絲之鞘/芯（sheath /core，s/c)形能， _碳添加於紡絲的外鞘部分，改善纖維物性不佳： 題。 然而’此-方法需要經過複雜的加工程序，例如使用 =紡嘴進行芯鞘型複合紡絲，或使開纖製程製造鞘/芯 ’Core ’ S/C)形態的紡絲。不僅需要額外之設備投 入’解造成原料成本的增加，並不符合經濟效益。 因此有需要提供一種制敍霞& v曰士办 处讲Μ Μ 禋I私早純又具有多種機性之多機 月b性的纖維以及纖維母粒。 【發明内容】 /此本發明的目的在於提供-種製程單純又具有竹 ^種機性之纖維母粒以及纖維1以解決習知技術製程 '、以及由功能性成分所造成之物性不佳或化學殘留的 1273114 題’並同時具有竹炭成分所提供的多種機性。 本發明主要是結合微粉化技術、多機能特性、混練 =利用竹炭所具有的多項優異性質，直接與聚酿等 ::&仃捏合混煉加工’再經高溫熔融混練程序押出 後進仃冷卻固化切粒即可得到多機能聚s旨母粒。~ Bamboo charcoal (bamb.. eh (4). al) is made from the bamboo of the sky (four) material, which is obtained by firing between the bamboo and the dish. Compared with the traditional name, the x-cho is capable of absorbing thirsty milk, far infrared rays and releasing negative ions. τ and the second non-toxic helmet treasure, has been singer, thunder m and bamboo dislike stems from the natural struggle u ',,,. It is used in automobile interiors, agricultural textiles, building filling mouths, environmental filter materials and textiles for deodorization, and for medical treatment of your pure mouth. Yin Huayu or water quality; more benefit, health care, my mouth and sports Using woven pan M ^ ^, in order to remove odor, promote blood circulation and use negative ions to prevent bacterial viruses from promoting textiles, not only fabrics; straight. Adding bamboo charcoal to adding 彳f gun + g卩π, 夕The compound function, and does not need J plus eve seed puller to achieve a variety of effects & reduce the product into 5! 273114. Japanese patent number JP2, 003, 253, 557 also provides a variety of versatile can absorb the salt, Reactive infrared carbon fiber with extreme odor. Wind However, the manufacturing process of conventional functional fibers must be processed several times, or using various procedures such as dip, spray, dazzle or direct carbonization. The functional ingredients are adhered to the substrate. The chemical reagents used in these treatments are likely to remain in the fibers, and the cockroaches often have the phenomenon of falling off and falling off. The source of the stained wood. In addition, the functional ingredients often cause poor physical properties of the fiber's influence on the application range of the functional fiber. In order to solve this problem, the Japanese Patent No. JP2,003,041,438 provides a use of melt spinning. Sheath / core, s / c shape energy, _ carbon is added to the outer sheath portion of the spinning, improving the physical properties of the fiber: Problem. However - this method requires complicated processing procedures, such as = Spinning of the core-sheath type composite spinning, or the spinning process to make the sheath/core 'Core 'S/C) form of spinning. Not only does the additional equipment investment require 'solutions to increase the cost of raw materials, it is not economical. Benefits. Therefore, it is necessary to provide a kind of fiber and fiber masterbatch which is a kind of multi-function moon-like fiber and fiber masterbatch. The object of the invention is to provide a fiber masterbatch and a fiber 1 which are purely bamboo-like and have a process to solve the conventional technical process, and the problem of poor physical properties or chemical residues caused by functional components. Simultaneously The invention has the advantages of various functions provided by the bamboo charcoal component. The invention mainly combines the micronization technology, the multi-functional property, the kneading = the use of many excellent properties of the bamboo charcoal, directly with the brewing, etc.:: & kneading and kneading processing After being extruded by a high-temperature melt-kneading process, the granules can be obtained by cooling and solidifying the pellets.
本發明的另一目在於提升多機能纖維或織物的耐水 :抗菌性以及遠紅外線之吸收機能。將含有竹炭成 :广母粒透過一般溶融紡絲的方法製成纖維表面上 :、有竹炭微粒附著之竹炭纖維。再將竹炭纖維進行假撚 二工成紗或形成竹炭纖維織品’並對竹炭纖維紡織品進 灯、水丨生忒驗、抗菌試驗以及遠紅外線試驗。 :據以上所述之試驗結果證實，本發明所提供之製 :：並且無需繁複之化學處理或加工製程即可獲得 竹厌的纖維素材。並且藉由添加竹炭此材料得到多 機能’以免去額外機能材料添加，達到 之需求。 【實施方式】 、為了讓本發明所提供之多機能母粒及其纖維之製造 方法更加清楚起見，本說明蚩將 斟张姐· +兄月"將以本發明之較佳實施例 子所揭路之技術特徵加以詳細說明。 ::炭係-種採自天然之竹子，經由高溫燒製而得之 夕孔性活性碳，具有可吸收濕氣、遠紅外線並且釋放負離 7 1273114 子之功能。在本發明的較佳實施例之中，竹炭係以竹子 ^於溫度大、約则以⑼代碳化生成^發明所提供之 =能母粒及其纖耗-種添加竹炭成分之 其纖維。 劑、=:明的一些實施例之中，首先，將分散劑以及濕潤 =於…例如水、苯類、醇類、藤類、或盼類之中進行 再將竹炭粉末加混合液之中進行高速攪拌，之後 研磨製程形成竹炭研磨液。在本發明的—些實施例之中，竹 厌之添加量大約為研磨液重量的0·5%物。在本 較佳實施例之中，竹炭研磨液在進行研磨之前介質（水）、竹 散劑、濕潤劑之重量比例為62:2〇:6: =研磨液中竹炭粉末的平均粒徑小於〇·5心，19〇%之 私末粒径小於1 # m。 :本：明之中分散劑可以為高分子量分散劑、低分子量 刀政別、陰離子型分散劑、陽離子型分散劑、或非離子型分 ;劑二發明的一些實施例之中，研磨液之分散劑係採 列如由Glaory⑧公司所提供，型號分別為PT201、 mT5G、tdi64l、mt83gml、⑽之分齡或由 752W R ^ 供’型號分別為此咖7卿、D咖s =⑧0rrs76〇w、D寧幻彻之分散劑"交佳為 ⑴:二⑧么司所提供型號為PT201之分散劑。在本發明的 :=之中’研磨液之濕润劑係採用，例如由⑴a”⑧ 供，型號分別為 TR16、BP、〇D4〇、Suif〇xy8。Another object of the present invention is to improve the water resistance of multi-functional fibers or fabrics: antibacterial properties and absorption properties of far infrared rays. The bamboo charcoal-containing: broad masterbatch is formed on the surface of the fiber by a general melt spinning method: bamboo charcoal fiber to which bamboo charcoal particles are attached. The bamboo charcoal fiber is then subjected to false twisting, forming a bamboo fiber fabric or forming a bamboo charcoal fiber fabric, and introducing bamboo charcoal fiber textiles into a lamp, a water test, an antibacterial test, and a far infrared ray test. According to the test results described above, it is confirmed that the fiber provided by the present invention can be obtained without complicated chemical processing or processing. And by adding bamboo charcoal, this material is multi-functional' to avoid the need to add additional functional materials to meet the demand. [Embodiment] In order to make the method for manufacturing the multi-functional masterbatch and the fiber thereof provided by the present invention more clear, the present description will be based on the preferred embodiment of the present invention. The technical features of the road are described in detail. ::Carbon-based from the natural bamboo, the high-temperature firing of the fucible activated carbon, has the function of absorbing moisture, far infrared rays and releasing the negative ion 7 1273114. In a preferred embodiment of the present invention, the bamboo charcoal is made of bamboo at a high temperature, and then carbonized by (9) to form a fiber of the bamboo charcoal component. In some embodiments of the agent, =: Ming, first, the dispersant and the wetting = in the water, benzene, alcohol, vine, or the like, and then the bamboo charcoal powder is mixed with the mixture. Stirring at high speed, followed by a grinding process to form a bamboo charcoal slurry. In some of the embodiments of the present invention, the amount of addition is about 0.5% of the weight of the slurry. In the preferred embodiment, the weight ratio of the medium (water), the bamboo powder, and the wetting agent before the grinding of the bamboo charcoal slurry is 62:2 〇:6: = the average particle diameter of the bamboo charcoal powder in the polishing liquid is less than 〇· 5 hearts, 19% of the private particle size is less than 1 # m. The present dispersant may be a high molecular weight dispersant, a low molecular weight knife, an anionic dispersant, a cationic dispersant, or a nonionic component; in some embodiments of the invention, the dispersion of the slurry The dosage system is as provided by Glaory8, and the models are PT201, mT5G, tdi64l, mt83gml, (10), or 752W R ^ for the model, respectively, for this coffee, 7 coffee, s = 80rrs76〇w, D Ning Fantasy Dispersant " Jiaojia is (1): 2 8 company provides the model of PT201 dispersant. In the present invention, the humectant of the polishing liquid is used, for example, by (1) a"8, and the models are TR16, BP, 〇D4〇, and Suif〇xy8, respectively.
WET 之“相，或由TEG⑽公司所提供，型號分別為 8 1273114 500、WET 270、WET 245之濕潤劑；較佳為teg〇⑧公司 所提供型號為WET 500之濕潤劑。 接著將含有蒙脫蠟（Montan Wax)之微粉臘分散劑或是 具有有機無機結構之偶合劑（coupling agent)加入研磨液之 中加以混合攪拌，在本發明之中，微粉臘分散劑或偶合劑的 添加量大約在重量百分比〇.5wt%到5〇wt。/。之間，較佳係 與研磨液中所含之固體成分的重量相等。在本發明的一些實 施例之中，微粉臘分散劑或偶合劑係採用，例如由台灣增 格股份有限公司所提供，型號分別為CA-202、CA-109、The "phase" of WET, or the humectant of the model number 8 1273114 500, WET 270, WET 245, provided by TEG (10), preferably the humectant of the model WET 500 supplied by the company teg〇8. A micronized wax dispersant of a wax (Montan Wax) or a coupling agent having an organic inorganic structure is added to the polishing liquid to be mixed and stirred. In the present invention, the addition amount of the fine powder wax dispersant or coupling agent is about The weight percentage 〇.5wt% to 5〇wt% is preferably equal to the weight of the solid component contained in the polishing liquid. In some embodiments of the present invention, the fine powder wax dispersant or coupling agent is Adopted, for example, by Taiwan Zengge Co., Ltd., models are CA-202, CA-109,
Lica 1、Lica 12、Lica 09、Lica38、NZ 37、NZ44、NZ12 之偶合劑；台灣克萊恩股份有限公司所提供，型號分別為 Licowax PP230 ^ Licowax E ^ Licowax 〇P . Ceridust555 1 ^ Ceridust VP6071 ^ Ceridust3620 ? ^ M Ceridust5551 之分散劑。 然後將合成樹脂粉體加入混合液中充分攪拌，再進行一 乾燥製程以形成竹炭聚合物粉體。在本發明的一些實施例之 合成樹脂粉體至少包括聚酯系聚合物、聚醯胺系聚合物、聚 亞醯胺系聚合物、或聚烯烴系聚合物。其中聚酯系聚合物至 少包括’聚對苯二甲酸丁二醋（polybutylene Terephthalate，PBT)、聚對苯二甲酸乙二酿（p〇lyethylene Terephthalate ，PET)、或聚對苯二曱酸丙二酯 (polyUimethylene terephthalate，ρττ);聚醯胺系聚合物、 或聚亞醯胺系聚合物至少包括’尼龍；聚烯烴系聚合物至少 包括，聚乙烯或聚丙烯。在本發明的較佳實施例之中，合成 9 1273114 樹脂粉體係聚對苯二甲酸乙—酽 在本發明之中， /· f .. 括合成樹脂之不同牿从 rins1C V1Scosity)配比調整步…生黏度 特性黏度所需要之人出似 4 ^達成多機能母粒 又斤而要之合成樹月旨粉末之甘拉 末一次加入混合液之中， 將5成樹脂粉 或分批加入混人该夕Λ 以在攪拌過程之中持續 口 — 中，也可 加入混合液之中。在太& 又將口成树脂粉末 性黏度大約在15:=的較佳軸之中，母粒特 度聚對苯二甲酸乙二醋：;:： =之不同特性黏 之中。 欖拌過私之中徐徐加入混合液 出之=將;^ ^粉體^人雙螺桿押出機進行昆煉，押 :之：進订冷部固化，再進行切粒可得到多機能合成樹乂甲 成之多機能母粒進行—炫融壓力試驗，以驗μ :: 好之分散性。請參照第1圖，係根據本發明對； 機能母粒所進行的溶㈣力試驗之所繪示之壓力__= t由測試結果分析，壓力沒有上升現象可知，多機能母粒 具有良好之分散性。 ,、本實施例將詳述藉由實施例丨所提供之多機能母粒所 製成之多機能纖維、多機能織品以及其製造方法。 將含有竹炭之多機能母粒與一般合成樹脂粒以特定 t例混合，其中竹炭含量的多募，以及母粒的混合比例 端視多機能纖維的設計以及運用範圍而定。在本發明之 中，多機能母粒之竹炭重量百分比含量大約在0.25xwt%到 10 1273114 5 0%{%之間。在本私日日#暫1+, 你令^明的第2貫施例之中，選用含有重量 百分比大約為 1 0 W t ^ ^ /°之竹厌多機能母粒與一般合成樹脂 母粒以15/85〜50/50的比例加以混合。 接著將混合均勻之混合母粒置於9(TC〜13(TC之乾 燥環境下乾燥，直到含水率3〇ppm“下為止，再以一般 的熔融紡絲機在溫度27〇它〜29〇 t ，紡絲速度 2500〜4500m/min以上紡絲，紡製成纖度7〇〜3〇〇d的竹炭 聚酯長纖維。再將竹炭聚酯長纖維以高速短加熱假撚 機，在200〜35(TC下以車速300〜6〇〇m/min延伸h5〜2 2 倍，加工製成纖度70〜300d、強度2g/d以上、細度〇ld 至20d之加工紗。再利用傳統針織與梭織技術例如，袋編、 移環、吊目等設計變化將加工紗織成一多機能織品。 實施例3 為證實本發明所提供之多機能母粒、多機能纖維、以及 多機能織品具有雨耐水洗性、抗菌性佳、高除臭率以及高 遠紅外線之機能的特性，因此針對多機能纖維、多機能纖 ^ 維之加工紗、以及多機能織品進行耐水性試驗、抗菌試 驗、遠紅外線試驗、以及除臭試驗，並與市售品作效能 比較。 耐水洗試驗的試驗項目，可分為褪變色試驗及色譜值 色差度試驗兩項。其中褪變色試驗係依照美國紡織化學 師與印染師協會（American Association of Textile Chemists and Colorists ，AATCC)標準，AATCC 135-2001(2)(n)A(i i)4LB LOAD 10 CYCLES 水洗 10 次 11 1273114 之後色變標準值為4級。而色譜值色差度試驗，則是以 色譜值色差度試驗儀 Color Analyzer TC- 1 800 ΜΚΠ進 行测試，以D65光源、視野1 0度作為操作參數，將檢測 樣本疊四層水洗10次，測試四點平均值。 將多機能纖維、多機能纖維之加工紗、以及多機能織品 水洗 10次之後，測試織物之變色程度以及色譜值色差 度。實驗結果如表一與表二所示：Lica 1, Lica 12, Lica 09, Lica38, NZ 37, NZ44, NZ12 coupling agent; provided by Taiwan Klein Co., Ltd., model is Licowax PP230 ^ Licowax E ^ Licowax 〇P . Ceridust555 1 ^ Ceridust VP6071 ^ Ceridust3620 ? ^ Dispersal of M Ceridust5551. Then, the synthetic resin powder is added to the mixed solution and thoroughly stirred, and then subjected to a drying process to form a bamboo charcoal polymer powder. The synthetic resin powder of some embodiments of the present invention includes at least a polyester-based polymer, a polyamine-based polymer, a polyimide polymer, or a polyolefin-based polymer. The polyester polymer includes at least polybutylene terephthalate (PBT), p〇lyethylene Terephthalate (PET), or poly(p-phenylene terephthalate) PolyUimethylene terephthalate (ρττ); a polyamidamide-based polymer, or a polyamidite-based polymer comprising at least 'nylon; the polyolefin-based polymer comprising at least polyethylene or polypropylene. In a preferred embodiment of the present invention, the synthesis of 9 1273114 resin powder system polyethylene terephthalate is in the present invention, /· f .. including the difference in synthetic resin from rins1C V1Scosity) adjustment step ...the viscosity of the characteristic viscosity of the person required to appear 4 ^ to reach the multi-functional masterbatch and the jin and the synthesis of the tree of the powder of the ganala once added to the mixture, add 50% of the resin powder or batch into the mixed This sputum can be added to the mixture during the stirring process. In the preferred axis of the too & resin powder viscosity of about 15:=, the masterbatch characteristic polyethylene terephthalate:;:: = different characteristics of the viscosity.榄 拌 过 加入 加入 加入 加入 加入 加入 加入 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ A multi-functional masterbatch performs a dazzling pressure test to test μ :: good dispersibility. Referring to Fig. 1, according to the present invention, the pressure of the solution (four) force test performed by the functional masterbatch is analyzed by the test result, and the pressure does not rise. It is known that the multi-functional masterbatch has good properties. Dispersibility. In this embodiment, a multi-functional fiber, a multi-functional fabric made by the multi-functional masterbatch provided by the embodiment, and a method for producing the same will be described in detail. The multi-functional masterbatch containing bamboo charcoal is mixed with the general synthetic resin pellet in a specific t-form, wherein the multi-raise of the bamboo charcoal content and the mixing ratio of the masterbatch are determined by the design and application range of the multi-functional fiber. In the present invention, the weight percent of bamboo charcoal of the multi-functional masterbatch is between about 0.25 x wt% and 10 1273114 50% {%. In this private day #暂1+, in the second example of the method, you choose bamboo masterbatch and general synthetic resin masterbatch containing about 10 W t ^ ^ /° by weight. Mix in a ratio of 15/85 to 50/50. Then, the mixed and mixed masterbatch is placed in 9 (TC~13 (drying in a dry environment of TC until the water content is 3〇ppm), and then it is tempered at a temperature of 27 一般 to a general melt spinning machine. Spinning speed of 2500~4500m/min or more, spinning into bamboo charcoal polyester long fiber with a fineness of 7〇~3〇〇d. Then heat the bamboo charcoal polyester long fiber with high speed short heating false twisting machine at 200~35 (Under TC, the speed is 300~6〇〇m/min, h5~2 2 times, and processed into a processed yarn with a fineness of 70~300d, a strength of 2g/d or more, and a fineness of 〇ld to 20d. Reuse traditional knitting and shuttle. Weaving techniques such as bagging, shifting, lifting, etc., woven the processed yarn into a multi-functional fabric. Example 3 To demonstrate that the multi-functional masterbatch, multi-functional fiber, and multi-functional fabric provided by the present invention have rain resistance Water washability, antibacterial property, high deodorization rate, and high far infrared function. Therefore, water resistance test, antibacterial test, far infrared ray test, multi-functional fiber, multi-functional fiber processing yarn, and multi-functional fabric are tested. Deodorization test and performance ratio with commercial products The test items of the water wash test can be divided into two parts: the fade color test and the chromatographic color difference test. The fade color test is in accordance with the American Association of Textile Chemists and Colorists (AATCC) standards. , AATCC 135-2001 (2) (n) A (ii) 4LB LOAD 10 CYCLES After washing 10 times 11 1273114, the color change standard value is 4. For the chromatographic value color difference test, it is the chromatographic color difference tester Color Analyzer TC- 1 800 ΜΚΠ test, using D65 light source, field of view 10 degrees as operating parameters, the test sample is washed four times in four layers, testing the four-point average. Multi-functional fiber, multi-functional fiber processing yarn, After washing the multi-functional fabric for 10 times, the degree of discoloration of the fabric and the color difference of the chromatographic value were tested. The experimental results are shown in Table 1 and Table 2:
表一、織物之褪變色試驗結果 試驗項目 試驗結果 水洗1 0次 牢度 褪變 色 4 表二、織物之色譜值色差試驗結果 試驗項目 試驗結果 水洗前 水洗10次後 色譜值 L氺 26.9 28.33 a氺 0.72 0.70 b氺 1.62 1.45 △ E值（色差 度） -- 1.4 根據表一视變色試驗的分析結果顯不，在水洗1 〇次 之後織品的色變質極符合AATCC標準值4級；根據表 二色譜值色差試驗的分析結果顯示，在水洗1 〇次之後織 12 1273114 品的淨色差度（△ E)僅1.4，遠低於一般標準3。因此可證 實本發明所提供之多機能纖維、多機能纖維之加工紗、以 及多機能織品具有極高的耐水洗程度。Table 1. Fabric discoloration test results Test items Test results Washed 10 times fastness Fading discoloration 4 Table 2, Chromatographic values of fabrics Test results Test items Test results Washed 10 times before washing, chromatographic value L氺26.9 28.33 a氺0.72 0.70 b氺1.62 1.45 △ E value (color difference) -- 1.4 According to the analysis results of the color change test in Table 1, the color change of the fabric after the washing is 1 times meets the AATCC standard value of 4; according to Table 2 The analysis of the value color difference test showed that the net color difference (ΔE) of the weave 12 1273114 product after washing only 1 time was only 1.4, which was much lower than the general standard 3. Therefore, it can be confirmed that the multi-functional fiber, the multi-functional fiber processed yarn, and the multi-functional fabric provided by the present invention have an extremely high degree of washing resistance.
本發明之抗菌試驗係以Judicial Information System 國際標準『JIS LI 902-1998纖維產品抗菌性試驗方法及 抗菌效果』的方法進行試驗。試驗之菌種為金黃色葡萄 球菌re似）ATCC 編號 ATCC 6538P 與 肺炎桿菌（尺㈣he) ATCC 編號 ATCC4352 兩種’分別培養1 8小時後計算生菌數以檢測樣品的抑菌 效果以及殺菌效果。驗證公式如第一式與第二式所示· 殺菌值=l〇g(Ma/Mc)·.·····第一式 抑菌值=log(Mb/Mc) .......第二式 其中，Ma為第0小時接種菌種立即沖刷樣品之後所 計數之生菌數；Mb係被沖刷過之樣品經過ι8小時培養 後之生囷數’ M c係未經沖刷之樣品經過1 $小時典養後 之生菌數。 ° 依據曰本纖維製品新機能評價協議會之狖 菌標準，抑菌值>2·2表示測試樣本有抑菌效果，殺# >0表示測試樣本有殺菌效果。 π 81 本發明之抗囷试驗測試結果如表三所·—The antibacterial test of the present invention was tested by the Judicial Information System international standard "JIS LI 902-1998 Antibacterial Test Method for Fiber Products and Antibacterial Effect". The strains tested were Staphylococcus aureus remarks ATCC No. ATCC 6538P and K. pneumoniae (foot (four) he) ATCC No. ATCC4352 Two kinds were cultured for 18 hours, and the number of bacteria was counted to test the antibacterial effect and bactericidal effect of the sample. The verification formula is as shown in the first formula and the second formula. • Sterilization value = l〇g (Ma/Mc) ······ The first type of inhibition value = log (Mb/Mc) ...... In the second formula, Ma is the number of bacteria counted after the inoculation of the inoculated strain at the 0th hour; the number of bacteria in the Mb-treated sample after 8 hours of incubation is 'M c unwashed sample After 1 $ hour of colonization, the number of bacteria. ° According to the cockroach standard of the new functional evaluation protocol of 曰本纤维制品, the antibacterial value>2·2 indicates that the test sample has antibacterial effect, kill # >0 indicates that the test sample has bactericidal effect. π 81 The test results of the anti-caries test of the present invention are shown in Table 3 -
試驗項目 一般聚酯 多 布 流$ —一—~< 加 13 1273114 235 iijt ϋ值 肺炎桿菌 (AATCCj£jj^Test item General polyester Multi-distribution Flow $-一-~< Add 13 1273114 235 iijt Devaluation K. pneumoniae (AATCCj£jj^
黃色 (AATCC6538P) "S 火 ^&~ή±~~~~— 表一柷菌忒驗測試結果， 义-—-1-— 纖維、多機能纖維之加工紗、·明所提供之多機能 球菌具有明顯的抑菌鱼及夕機能織品對金黃葡萄 抑菌功效。 、’又囷效果’對肺炎桿菌也有明顯的 本發明之遠紅外線測試項 射率測試儀器及熱電偶，、旦α線放射率試驗係採用放 工紗在49°c之下的紅外里測本發明所提供之多機能加 採用遠紅外線升溫值測 〜卜線升溫測試則 齒素燈照射欲測試之針^ ^如则〜_以5_之 照射時間為l〇min ;再 “、、射距離10〇cm， 紅外線放射率試驗之測試結果綠 升…。 圖係根據本發明對多機能加工㈣ 弟圖。弟2 夢驗結果所繪示之波長_放射率 、·工夕卜線放射率試 之多機能加卫紗在溫度机之下圖^示本發明所提供 範圍之平均遠紅外線放射率大於。·8，;皮二3〜^的 放射率。遠紅外線升溫測試的結果如表、四戶^之运紅外線 般聚酯針織 測二果 一··丨___β· 27766 根據表 — 結果顯示，本發明所提供之多機能針 ：之分析 ’ σ口）的遠紅 14 1273114 外線吸收率高於一般聚酯針織布。 本發明之除臭試驗係以10x 1〇cm之梭織物置入一體 積為5L含有濃度^ 3L_1〇〇ppm之氨（顧3)器❸袋 中，持續1小時之後量測袋中氨氣的殘留濃度，再計算 梭織物的除臭率。量測結果如表五所示： 表五、多機能姓她士入& 試 驗項目 試驗 …4 不 結果 一般聚酯 針織布 多機能梭 織布 nh3 消臭 性能 Ohr νη3 初始 濃度 100 100 lhr νη3 殘留 濃度 100 -------- 3 1 νη3 除臭 率 0% --------- 69% 由表五夕機旎梭織布除臭試驗之分析結果顯示，本 發明所提供之多機能梭織布（織品）的除臭率高達_遠 高於一般聚酯梭織布。 由以上所述的分析可以證實，本發明所提供之多機能纖 維、多機能纖維之加工紗、以及多機能織品(針織布或梭織 布）以及多機能母粒都具有高耐水洗性、抗菌性佳、高除 臭率以及高遠紅外線之吸收機能的等技術優勢。而且不需 要使用複雜的製程以及添加多種功能性成分即可得具有多 重機能性之多機能母粒、多機能纖維之加工紗、以及多機能 織品。 15 1273114 雖然本發明已以較佳 V吩Μ丄，热兵亚非 定本發明，任何熟習此技藝者，在不脫離本發明之精神和:艮 圍内，當可作各種之更動與潤飾，因此本發明之保 ： 視後附之申請專利範圍所界定者為準。 田 【圖式簡單說明] 以上所述之說明書已詳細 合相關圖示說明，讀者將對本發 的了解。 描述本發明的實施例，再配 明的與技術優勢有更進一步 圖係根據本發明對多機能母粒所進行的 試驗之所繪示之壓力_時間曲線圖。 第2圖係根據本發 十丄、 d對夕钱月匕加工紗所進行之紅外線 放射率試驗結果所纷示 之波長-放射率曲線圖。 【主要元件符號說明】 16Yellow (AATCC6538P) "S Fire^&~ή±~~~~— The results of the test results of the bacteria, Yi--1-- fiber, multi-functional fiber processing yarn, · Ming provides more Functional cocci have obvious antibacterial activity against bacteriostatic fish and eve functional fabrics against golden grapes. , '囷 囷 ' 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对 对The multi-function provided by the use of far-infrared heating temperature measurement ~ Bu-line heating test is the needle of the tooth lamp to be tested ^ ^ If then ~ _ 5_ of the irradiation time is l〇min; then ",, shooting distance 10 〇cm, the test result of the infrared emissivity test is green.... The figure is based on the multi-functional processing (4) of the invention. The wavelength of the infrared test, the radiation rate of the electric radiation test The multi-function plus yarn under the temperature machine shows that the average far-infrared emissivity of the range provided by the present invention is greater than .8, and the emissivity of the skin 2 3~^. The results of the far-infrared heating test are shown in the table, four households. ^Infrared-like polyester-knitted measurement 2#·丨___β· 27766 According to the table - the results show that the multi-function needle provided by the present invention: the analysis of the 'σ mouth' of the far red 14 1273114 is higher than the external absorption rate General polyester knitted fabric. The invention The odor test was carried out by placing a volume of 10×1〇cm of woven fabric into a volume of 5L ammonia (Gu 3) ❸ bag containing a concentration of 3L_1〇〇ppm, and measuring the residual concentration of ammonia in the bag after 1 hour, and then measuring the residual concentration of ammonia in the bag. Calculate the deodorization rate of the woven fabric. The measurement results are shown in Table 5: Table 5, multi-function surname her herd into & test project test...4 no result general polyester knitted fabric multi-functional woven fabric nh3 deodorizing performance Ohr Νη3 Initial concentration 100 100 lhr νη3 Residual concentration 100 -------- 3 1 νη3 Deodorization rate 0% --------- 69% Deodorization test by the table The analysis results show that the deodorizing rate of the multi-functional woven fabric (fabric) provided by the present invention is as high as _ much higher than that of the general polyester woven fabric. The multi-functional fiber provided by the present invention can be confirmed by the above analysis. , multi-functional fiber processing yarn, multi-functional fabric (knitted fabric or woven fabric) and multi-functional masterbatch have the technical advantages of high washability, good antibacterial property, high deodorization rate and high far infrared absorption function. And don't need to use complicated processes and add multiple functions. The energy component can obtain multi-function masterbatch with multi-functionality, processed yarn of multi-functional fiber, and multi-functional fabric. 15 1273114 Although the present invention has been commanded by the preferred V, the heat is not the invention, any Those skilled in the art can make various changes and refinements without departing from the spirit and scope of the present invention. Therefore, the protection of the present invention is as defined in the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS The above description of the present invention has been described in detail with reference to the accompanying drawings, and the description of the present invention will be further understood. The pressure-time plot of the test performed. Fig. 2 is a graph showing the wavelength-emission rate of the results of the infrared ray spectroscopy test performed on the yarns processed by Shiyan and d. [Main component symbol description] 16