TWI232246B - Antistatic flexible intermediate bulk container - Google Patents

Antistatic flexible intermediate bulk container Download PDF

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TWI232246B
TWI232246B TW90129258A TW90129258A TWI232246B TW I232246 B TWI232246 B TW I232246B TW 90129258 A TW90129258 A TW 90129258A TW 90129258 A TW90129258 A TW 90129258A TW I232246 B TWI232246 B TW I232246B
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Taiwan
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antistatic
bis
butyl
polyester
flexible intermediate
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TW90129258A
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Chinese (zh)
Inventor
Rene Jud
Ernst Minder
Ederhard Krause
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Ciba Sc Holding Ag
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Publication of TWI232246B publication Critical patent/TWI232246B/en

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Abstract

The invention pertains to a woven antistatic flexible intermediate bulk container (FIBC) comprising a polyolefin fiber or strip containing as an antistatic additive a polyetheresteramide, a polyester-ether block copolymer or an antistatic composition containing said polyetheresteramide or said polyester-ether block copolymer at least partially, as warp and/or weft thread.

Description

1232246 A7 __B7_____ 五、發明說明（/ ) ----I----—----· 11 (請先閱讀背面之注意事項再填寫本頁) 本發明是關於織造抗靜電可撓性中間體容器（FIB〇) ，其可以安全地與因爲靜電荷緣故而具有相當程度***危 險的物品使用，像是化學粉末或顆粒，或者是小麥之類。 本發明的進一步主題是一種製造織造抗靜電可撓性中間體 容器的方法，以及用於織造可撓性中間體容器的抗靜電處 理用之經選抗靜電組成物之用途。 已知將聚合物施加強的靜電荷，並且一旦應用之後， 因爲聚合物的低導電性，所以只能將該電荷緩慢地放電。 此不僅是爲了美觀的理由而需要快速放電’並且在許多例 子中，也爲了安全的緣故。如果該靜電荷不是連續地耗散 ，則可能因爲電荷太高而發生火花，再接著發生點火，此 已經常造成嚴重的***。 聚烯烴FIBC的絕緣表面可以產生且持有電荷爲經常 歷時一延長時間。該電荷通常是從充電或放電過程期間材 料的流動而產生在該FIBC上。一旦在該FIBC上產生充足 的電荷，在該FIBC的電荷表面和任何導電的設備和/或人 員之間，可能發生電暈放電（brush discharge)。該放電可 以具有充足的能量來點火多數的溶劑氛圍及一些非常敏感 的粉塵氛圍。 已知經由能增進表面導電性之添加劑的加入來限制靜 電荷，但是該物質的缺點爲：當大氣溼度低時，實際上是 無效的。因此較佳是使用在低大氣溼度下有效的添加劑， 其通常是經由增加該單位體積導電率（volume conductivity )來達到。然而，用來增加單位體積導電率的已知物質， 3 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公g ) A7 1232246 _____B7 ___ 五、發明說明（Ύ) ------------1·裝—— (請先閱讀背面之注意事項再填寫本頁) 例如碳黑或金屬粉末，可改變該聚合物的機械性質但無法 用於透明聚合物。除此之外，對添加劑之額外要求爲生態 上無瑕疵的。 關於抗靜電添加劑和靜電荷的反應機構之進一步詳述 可於，例如，在作者是R· Gachter和Η. Muller之“Plastics Additives Handbook” ，第三版，1990，第 749-775 頁中發 現。 · % 現今發現可以利用聚烯烴纖維作爲經紗線（warp threads)和/或緯紗線（weft threads)來製備織造可撓性中 間體容器（FIBC)，其包括聚醚酯醯胺或聚酯-醚嵌段共聚 物作爲抗靜電添加劑。該電荷耗散地夠快，使得在大多數 例子中不需要特別的接地，因此減少人爲失誤。該抗靜電 性質是永久的，並且本質上與溼度無關。再者，該抗靜電 組成物並不賦予纖維或紗條任何顏色，並且該纖維或紗條 的機械性質本質上維持不變。可以使用該FIBC許多次而不 需要損失其有利的性質。 因此本發明的一個主題是織造抗靜電可撓性中間體容 器（FIBC)，其包括至少部分作爲經紗線及/或緯紗線之聚 烯烴纖維或紗條，其包括聚醚酯醯胺、聚酯-醚嵌段共聚物 ，或是含有該聚醚酯醯胺或該聚酯-醚嵌段共聚物之抗靜電 組成物來作爲抗靜電添加劑。 可以形成該纖維或紗條之典型的聚烯烴敘述如下。 1·單烯烴和雙烯烴的聚合物，例如聚丙烯、聚異丁烯 、聚丁-1-烯、聚-4-甲基戊-1-烯、聚異戊二烯或聚丁二烯； 4 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） A7 1232246 __B7__ 五、發明說明（3 ) / . .---------------- (請先閱讀背面之注意事項再填寫本頁) 以及環烯烴的聚合物，例如環戊烯或降㈣烯；聚乙烯（其 可以選擇***聯），例如高密度聚乙烯（HDPE)、高密度 且高分子量聚乙烯（HDPE-HMW)、高密度且超高分子量 聚乙烯（HDPE-UHMW)、中密度聚乙烯（MDPE)、低密 度聚乙烯（LDPE)、線性低密度聚乙烯（LLDPE)、（ VLDPE)及（ULDPE)。 可以用不同的方法，並且尤其是由下列的方法，來製 備聚烯烴，即在前述段落中所例證單烯烴的聚合物，較佳 爲聚乙烯和聚丙烯。 自由基聚合反應（通常是在高壓及加熱的溫度下）。 b)使用催化劑之催化聚合反應，其通常包括一個或者 多於一個週期表中第IVb、Vb、VIb或VIII族的金屬。這些 金屬經常具有一或多於一個配位基，特別是可以π-或σ-配位之氧化物、鹵化物、醇化物、酯類、醚類、胺類、烷 基類、烯基類或芳基類。這些金屬錯合物可以爲自由形式 或固定在基質上，特別是在活化的氯化鎂、氯化鈦（ΠΙ ) 、三氧化二鋁或氧化矽。這些催化劑可以是可溶於或是不 可溶於該聚合反應介質中。該催化劑可以單獨使用於聚合 反應中，或者可以進一步使用活化劑；特別是烷基金屬、 氫化金屬、烷基金屬鹵化物、烷基金屬氧化物或烷基金屬 四氫吡喃，該金屬爲週期表中第I a、na和/或HI a族之元 素。可以合宜地進一步以酯類、醚類 '胺類或甲矽烷基醚 族群來改性該活化劑。這些催化劑系統通常稱爲Phillips、 Standard Oil Indiana、Ziegler (-Natta) 、TNZ (DuPont)、 5 __ __ ___________ -___________________________ — - 本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） 1232246 A7 _—------------—-— _________B7__-___ 五、發明說明（[|/ ) 金屬茂（metallocene)或單一位置之催化劑（ssc)。 ------------裝--- (請先閱讀背面之注意事項再填寫本頁)1232246 A7 __B7_____ V. Description of the invention (/) ---- I ---------- · 11 (Please read the precautions on the back before filling out this page) This invention is about the antistatic flexibility of weaving Bulk Container (FIB0), which can be safely used with items that have a considerable degree of explosion risk due to electrostatic charge, such as chemical powders or granules, or wheat or the like. A further subject of the present invention is a method of manufacturing a woven antistatic flexible intermediate container and the use of a selected antistatic composition for antistatic processing of a woven flexible intermediate container. It is known to apply a strong electrostatic charge to a polymer, and once applied, the charge can only be discharged slowly due to the low conductivity of the polymer. This is required not only for quick aesthetic reasons' but also for safety reasons in many cases. If the electrostatic charge is not continuously dissipated, a spark may occur because the charge is too high, followed by ignition, which has often caused severe explosions. Polyolefin FIBC's insulating surface can generate and hold charge for a prolonged period of time. The charge is typically generated on the FIBC from the flow of material during the charging or discharging process. Once sufficient charge is generated on the FIBC, a corona discharge may occur between the charged surface of the FIBC and any conductive equipment and / or persons. This discharge can have enough energy to ignite most solvent atmospheres and some very sensitive dust atmospheres. It is known to limit the electrostatic charge through the addition of additives that enhance surface conductivity, but the disadvantage of this substance is that it is virtually ineffective when the atmospheric humidity is low. Therefore, it is preferable to use an additive effective at low atmospheric humidity, which is usually achieved by increasing the volume conductivity. However, for the known substances used to increase the conductivity per unit volume, 3 paper sizes are applicable to the Chinese National Standard (CNS) A4 specification (210 χ 297 g) A7 1232246 _____B7 ___ V. Description of the invention (Ύ) ----- ------- 1 · Packing—— (Please read the notes on the back before filling this page) For example, carbon black or metal powder can change the mechanical properties of the polymer but cannot be used for transparent polymers. In addition, the additional requirements for additives are ecologically flawless. Further details on the antistatic additive and electrostatic charge reaction mechanisms can be found, for example, in "Plastics Additives Handbook" by R. Gachter and R. Muller, Third Edition, 1990, pages 749-775. ·% It is now found that polyolefin fibers can be used as warp threads and / or weft threads to make woven flexible intermediate containers (FIBC), which include polyetheresteramide or polyester- The ether block copolymer acts as an antistatic additive. This charge dissipates fast enough so that in most cases no special grounding is required, thus reducing human error. This antistatic property is permanent and is essentially independent of humidity. Furthermore, the antistatic composition does not impart any color to the fiber or sliver, and the mechanical properties of the fiber or sliver remain essentially unchanged. This FIBC can be used many times without losing its advantageous properties. Therefore, a subject of the present invention is a woven antistatic flexible intermediate container (FIBC), which includes polyolefin fibers or slivers that are at least partially used as warp and / or weft yarns, which include polyetheresteramide, polyamine An ester-ether block copolymer or an antistatic composition containing the polyetheresteramide or the polyester-ether block copolymer is used as an antistatic additive. Typical polyolefins from which the fibers or slivers can be formed are described below. 1. Polymers of mono- and di-olefins, such as polypropylene, polyisobutylene, polybut-1-ene, poly-4-methylpent-1-ene, polyisoprene or polybutadiene; 4 Paper size applies to China National Standard (CNS) A4 (210x 297 mm) A7 1232246 __B7__ V. Description of the invention (3) /.. ---------------- (Please read first Note on the back page, please fill in this page) and polymers of cycloolefins, such as cyclopentene or norbornene; polyethylene (which can be selectively crosslinked), such as high density polyethylene (HDPE), high density and high molecular weight polymer Ethylene (HDPE-HMW), high density and ultra high molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), (VLDPE), and (ULDPE). Polyolefins, i.e., polymers of monoolefins as exemplified in the foregoing paragraphs, can be produced by different methods, and especially by the following methods, preferably polyethylene and polypropylene. Free radical polymerization (usually under high pressure and heated temperature). b) Catalytic polymerization using a catalyst, which typically includes one or more metals from Groups IVb, Vb, VIb or VIII of the Periodic Table. These metals often have one or more than one coordination group, especially oxides, halides, alcoholates, esters, ethers, amines, alkyls, alkenyls or Aryl class. These metal complexes can be free-form or immobilized on a substrate, in particular activated magnesium chloride, titanium (III) chloride, alumina, or silicon oxide. These catalysts may be soluble or insoluble in the polymerization reaction medium. The catalyst can be used alone in the polymerization reaction, or an activator can be further used; especially an alkyl metal, a hydrogenated metal, an alkyl metal halide, an alkyl metal oxide, or an alkyl metal tetrahydropyran, the metal is a period Elements of Groups Ia, na and / or HIa in the table. The activator may suitably be further modified with esters, ethers' amines or silyl ether families. These catalyst systems are commonly referred to as Phillips, Standard Oil Indiana, Ziegler (-Natta), TNZ (DuPont), 5 __ __ ___________ -___________________________ —-This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) ) 1232246 A7 _--------------------- _________ B7 __-___ 5. Description of the invention ([| /) Metallocene or single-site catalyst (ssc). ------------ Install --- (Please read the precautions on the back before filling this page)

2·在1)所敘述聚合物的混合物，例如聚丙烯與聚異丁 烯、聚丙烯與聚乙烯的混合物（例如PP/I1DPE、pp/LDPE )’以及不同型式聚乙稀的混合物（例如LDPE/HDPE)。 .¼ 3·單烯烴和雙烯烴與彼此或與其他乙烯基單體的共聚 物’例如乙烯/丙烯共聚物、線性低密度聚乙烯（lldpe) 和其與低密度聚乙烯（LDPE)之混合物、丙烯/丁小烯共 聚物、丙烯/異丁烯共聚物、乙烯/丁-丨—烯共聚物、乙烯/己 烯共聚物、乙烯/甲基戊烯共聚物、乙烯/庚烯共聚物、乙 烯/辛烯共聚物、丙烯/丁二烯共聚物、異丁烯/異戊二烯異 丁烯共聚物、乙烯/丙烯酸烷酯共聚物、乙烯/甲基丙烯酸 院酯共聚物、乙烯/乙酸乙烯酯共聚物及其與一氧化碳的共 聚物、或乙烯/丙烯酸共聚物及其鹽類（離子交聯聚合物） ’以及乙烯與丙稀和像是己二烯、二環戊二烯或亞乙基_降 (四)烯的二烯之三元共聚物；以及該共聚物與彼此和與在上 面1)中所敘述聚合物的混合物，例如聚丙烯/乙烯-丙烯共 聚物、LDPE/乙烯-乙酸乙烯酯共聚物（EVA)、LDPE/乙烯 -丙烯酸共聚物（EAA)、LLDPE/EVA、LLDPE/EAA和交替 或無規聚烷撐/一氧化碳共聚物。 現今的FIBC主要是從聚丙烯纖維或紗條所製的，其 也是本發明之最佳具體例。 以已知的方法來完成該聚醚酯醯胺、該聚酯-醚或含有 該聚醚酯醯胺或該聚酯_醚之抗靜電組成物，以及選擇性添 加劑摻和於該聚烯烴纖維或紗條。 6 本纸張尺度適用中國國豕&準（CNS)A4規格（21〇 X 297公爱） A7 1232246 __B7___ 五、發明說明) 可以利用本身已知像是軋光機、攪拌機、捏合機、擠 壓機之類的裝置，經由本身已知之方式藉由將該成份等和 添加劑（如果需要的話）與聚烯烴混合之方法來進行該摻 和。該添加劑單獨地或在彼此的混合物中。其亦可能使用 所謂母料。 可以用已知的方法將本發明之抗靜電聚烯烴製成所欲 的形式。該方法包括，例如擠壓、抽絲、射出模製、擠壓 吹塑、燒結或加壓/燒結。 較佳的纖維或紗條是以抽絲或擠壓吹塑所形成的。 聚烯烴纖維和紗條的製造是例如在Saechtling， Kunststoff Taschenbuch 21. Ausgabe，1979，Seite 226 戶斤敘述 的。 特別較佳的是經由將經擠壓吹塑的薄膜切割成所欲白勺 大小之紗條。 該纖維厚度可以在廣寬的範圍內調整，並且特別是從 10μ至2000μ。如果是形成紗條，則其通常具有1〇μ至 ΙΟΟΟμ的厚度，較佳是1〇〇μ至800μ，更佳是100μ至600μ ’ 以及0.5 mm至50 mm的寬度，較佳是1 mm至20 mm且更 佳是1 mm至5 mm 0 該織造纖維可以是任何形式的織物組織。 該織造纖維的重量較佳是100 g/m2至500 g/m2’更佳 是 100 g/m2 至 400 g/m2 基於該聚烯烴的重量，該抗靜電添加劑較佳是存在5 % -100%的量，更佳是7% -30%。 7 本纸張尺度適用中國國家標準(CNS)A4^各（210 x 297公爱） (請先閱讀背面之注意事項再填寫本頁) * ϋ ϋ ϋ IV ϋ n i^OJ· I I n I n n 1232246 A7 ^___B7__ 五、發明說明（U ) 本發明的特別優點爲：並非每一條經紗線或緯紗線均 需要是抗靜電的。對許多應用而言，具有例如每兩條、每 三條或每四條經紗線和/或緯紗線抗靜電就可能足夠的。其 他組合也是可能的。多少經紗線和/或緯紗線應包括該抗靜 電添加劑是取決於該FIBC的最終用途，並且可以經由適當 的試驗來找到。通常其不應低於每50條經紗線和/或緯紗 線。 較佳是織造抗靜電可撓性中間體容器，其中至少每20 條經紗線和/或緯紗線包括該抗靜電添加劑。 在本發明的更佳具體例中，每5條或更多經紗線和/或 緯紗線是由該抗靜電聚烯烴所製的。 如果將該抗靜電聚烯烴使用於每一條經紗線和/或緯紗 線中，則得到特別導電的FIBC。 抗靜電經紗線和緯紗線交叉的數量是定義該FIBC的 最終導電性的一個要素，因此使得明白地調整所欲的導電 性。 該FIBC可以額外地包括一層塗層，其亦選擇性地包 括該抗靜電添加劑。該塗層可以在該FIBC的內部或外部。 也可能該FIBC僅被部份地塗佈在一面或兩面表面上，較佳 是一半被塗佈。 較佳是織造抗靜電可撓性中間體容器，其中該抗靜電 添加劑是聚醚酯醯胺或是含有該聚醚酯醯胺之抗靜電組成 物。 同樣地，較佳是織造抗靜電可撓性中間體容器，其在 8 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------i I (請先閱讀背面之注意事項再填寫本頁) -δ - %· A7 1232246 ____B7______ 五、發明說明（7) 該內部和/或外部表面上，在具有基於該塗層的固體重量， 含有該抗靜電添加劑7% -30%的量之塗料。 --------I-----· I I (請先閱讀背面之注意事項再填寫本頁) 更佳是該塗層僅在該FIBC的內部上。 在一些例子中，即使該FIBC的纖維並不包括抗靜電 添加劑，以具有抗靜電塗層仍可能達到抗靜電性質。 因此本發明的另一個觀點是一種織造抗靜電可撓性中 間體容器（FIBC)，其包含··由聚烯烴纖維或紗條所製的 織造物，其織造物在該內部和/或外部表面上具有塗層，在 基於該塗層的固體重量下，含有份量爲7% -30%之聚醚酯 醯胺、聚酯-醚嵌段共聚物或含有聚醚酯醯胺或聚酯-醚嵌 段共聚物之抗靜電組成物作爲抗靜電添加劑。 特別是該塗層具有10 g/m2至100 g/m2的重量，較佳是 10 g/m2 至 50 g/m2。 % 該塗層可以是由像是聚烯烴之熱塑性聚合物所製的， 其是從熔融物來被塗覆成積層板，或者其可以由熱固性或 其他可交聯聚合物所製成，此可能經由例如浸漬、塗刷或 噴塗來塗覆。 當使用熱塑性聚合物時，聚丙稀和聚乙烯爲較佳。 亦可能將以抗靜電試劑處理過之纖維與紙或鋁層合。 其較佳是在該FIBC的內部上完成。如果使用紙，其亦可能 包括該抗靜電添加劑。 合適塗料和塗漆的例子如下： 1·以冷或熱可交聯的醇酸（alkyd)、丙儲酸酯、聚酯 、環氧或蜜胺（melamine)樹脂，或該樹脂的混合物爲主 9 P氏張尺度適用中國國家3準（CNS)A4規格（210 X 297公餐) ' — Ϊ232246 A7 '—-----------B7___ 五、發明說明（分） 之塗漆，如果需要的話加入硬化催化劑； 2·以含羥基丙烯酸酯、聚酯或聚醚樹脂，以及脂族或 芳2族異氰酸酯、異氰脲酸酯或聚異氰酸酯爲主之雙組份聚 胺基甲酸酯塗漆； 3·以嵌段異氰酸酯、異氰脲酸酯或聚異氰酸酯爲主之 單組份聚胺基甲酸酯塗漆，其是在烘烤期間去封端的，且 如果需要的話加入蜜胺樹脂； 4·以三烷氧基羰基三氮畊交聯劑，和像是丙烯酸酯、 聚酯或聚醚樹脂之含羥基樹脂爲主之單組份聚胺基甲酸酯 塗漆； 5·以脂族或芳族胺基甲酸酯丙烯酸酯、或在該胺基甲 酸酯結構之中具有自由胺基之聚胺基甲酸酯丙烯酸酯，以 及蜜胺樹脂或聚醚樹脂爲主之單組份聚胺基甲酸酯塗漆， 如果需要的話加入硬化催化劑； 6.以（聚）酮亞胺，以及脂族或芳族異氰酸酯、異氰 脲酸酯或聚異氰酸酯爲主之雙組份塗漆； 7·以（聚）酮亞胺，以及不飽和丙烯酸酯樹脂或聚乙 醯乙酸酯樹脂或甲基丙烯醯胺基羥基乙酸甲酯爲主之雙組 份塗漆； 8·以含羧基或胺基之聚丙烯酸酯，以及聚環氧化物爲 主之雙組份塗漆； 9.以含酐基之丙烯酸酯樹脂爲主，和以聚羥基或聚胺 基成份爲主之雙組份塗漆； 10·以含酐基之丙烯酸酯，和聚環氧化物爲主之雙組份 10 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ---------------- (請先閱讀背面之注意事項再填寫本頁) 訂： 1232246 A7 p-—--^____^L_ 五、發明說明（C| ) 塗漆； U·以（聚）聘唑啉（oxazoline)，和含酐基之丙烯酸 ’或不飽和丙烯酸酯樹脂，或脂族或芳族異氰酸酯 '異氰^腺酸酯或聚異氰酸酯爲主之雙組份塗漆； 不飽和聚丙烯酸酯和聚丙二酸酯爲主之雙組份塗 漆； 13·Μ熱塑性丙烯酸酯樹脂，或與醚化蜜胺樹脂組合之 聯两烯酸酯樹脂爲主之熱塑性聚丙烯酸酯塗漆； 14·&矽氧烷改性或氟改性之丙烯酸酯樹脂爲主之塗漆 系統； 15·以具有蜜胺樹脂（例如六甲氧基甲基蜜胺）作爲交 _齊!1 (_催化的）丙二酸酯-嵌段異氰酸酯爲主之塗漆系統 ，尤其是透明塗料。 也可能將該FIBC具備有內袋作爲上述塗層之替代品 ’其並不需要完全地固定在該FIBC的纖維上。該內袋也包 括聚醚酯醯胺或含有該聚醚酯醯胺之抗靜電組成物，並且 例如與該FIBC形成焊接。該內袋可能由合成聚合物所製， 較佳是由聚烯烴，或像是紙或棉花之纖維素材料所製的。 聚烯烴的例子已敘述過。 較佳是織造抗靜電可撓性中間體容器，其中由聚烯烴 薄膜所製的內袋是鬆開的或部份固定在該織造物上，並且 包括該抗靜電添加劑。 可以用標準的方法，將該抗靜電添加劑摻入該內袋中 ，例子已列於上。在纖維素材料的例子中，該抗靜電添加 11 (請先閱讀背面之注意事項再填寫本頁) 1 n ΜΜ§ ί ϋ ϋ n 一5OJ· n I n MmMe ϋ I e 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1232246 Δ7 __Β7_____ 五、發明說明（1ϋ) 劑可以與適當的溶劑混合，並且經由噴塗或浸漬來應用， 並且接著蒸發該溶劑。也可能經由滾筒式塗佈來應用。如 果使用溶劑，則該抗靜電添加劑爲懸浮液形式，且不溶解 0 該FIBC也可能額外具備有導電或“半導體”纖維， 其可能是在經紗線或緯紗線中。導電纖維的例子爲碳纖維 或金屬纖維。該金屬可能爲例如··鐵、鎳、鋼或銀。“半 導體”纖維的例子在US 5,478，154中。 該抗靜電添加劑包括聚醚酯醯胺或聚酯-醚嵌段共聚物 。US 4,332,920描述合適的聚醚酯醯胺及其製造。在ΕΡ-Α-0 613 919中將一些含有雙酚Α單元之聚醚酯醯胺提出來作 爲熱塑性聚合物用之抗靜電添加劑。DE 28 37 687描述一 種製備該聚醚酯醯胺的方法，並且GB 1 518 060揭示其作 爲抗靜電纖維和絲線的用途。 US 6，140,405描述適用於本發明，以聚酯-醚嵌段共聚 物及聚醚酯醯胺爲主之耗散靜電聚合物。 較佳的聚酯-醚嵌段共聚物包含乙二醇、對苯二甲酸或 對苯二甲酸二甲酯，與聚乙二醇之反應產物。這些以及其 他可利用之聚酯-醚共聚物的其他例子敘述於聚合物科學及 工程百科全書（Encyclopedia of Polymer Science and Engineering)，第 12 冊，John Wiley & Sons，Inc· NY，1988 ，第 49-52 頁。 特別合適的聚醚酯醯胺和聚酯-醚類是商業上可得到的 ，例如從 Elf Atochem Corp.，商品名稱 Pebax® ;從 Sanyo 12 (請先閱讀背面之注意事項再填寫本頁) 裝 訂·- 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公髮） A7 1232246 ^_B7___ 五、發明說明（1 I )2. Mixtures of polymers described in 1), such as polypropylene and polyisobutylene, polypropylene and polyethylene (such as PP / I1DPE, pp / LDPE) 'and mixtures of different types of polyethylene (such as LDPE / HDPE) ). .¼3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers' such as ethylene / propylene copolymers, linear low density polyethylene (lldpe) and mixtures thereof with low density polyethylene (LDPE), Propylene / butene copolymer, propylene / isobutylene copolymer, ethylene / butene-ene copolymer, ethylene / hexene copolymer, ethylene / methylpentene copolymer, ethylene / heptene copolymer, ethylene / octene Olefin copolymer, propylene / butadiene copolymer, isobutylene / isoprene isobutylene copolymer, ethylene / alkyl acrylate copolymer, ethylene / methacrylic acid ester copolymer, ethylene / vinyl acetate copolymer, and their Copolymers of carbon monoxide, or ethylene / acrylic acid copolymers and their salts (ionic cross-linked polymers) 'and ethylene and propylene and like hexadiene, dicyclopentadiene or ethylene-nor (tetra) ene Terpolymer of diene; and mixtures of the copolymer with each other and with the polymer described in 1) above, such as polypropylene / ethylene-propylene copolymer, LDPE / ethylene-vinyl acetate copolymer (EVA ), LDPE / ethylene-acrylic acid copolymer (EAA), LLDPE / EVA, LLDPE / EAA and alternating or random polyalkylene / carbon monoxide copolymers. Today's FIBC is mainly made from polypropylene fibers or slivers, which is also the best embodiment of the present invention. The polyetheresteramide, the polyester-ether or an antistatic composition containing the polyetheresteramine or the polyester-ether, and a selective additive are blended into the polyolefin fiber by a known method. Or sliver. 6 This paper size applies to China National Standards & Standards (CNS) A4 (21〇X 297 public love) A7 1232246 __B7___ V. Description of the invention) It can be used by itself such as calender, mixer, kneader, extrusion The blending is performed by a device such as a press by mixing the ingredients and the like and additives (if necessary) with the polyolefin in a manner known per se. The additives are alone or in a mixture with each other. It is also possible to use so-called masterbatches. The antistatic polyolefin of the present invention can be formed into a desired form by a known method. The method includes, for example, extrusion, wire drawing, injection molding, extrusion blow molding, sintering, or compression / sintering. The preferred fibers or slivers are formed by drawing or extrusion blow molding. The manufacture of polyolefin fibers and slivers is described, for example, in Saechtling, Kunststoff Taschenbuch 21. Ausgabe, 1979, Site 226. It is particularly preferred to cut the extruded blown film into slivers of a desired size. The fiber thickness can be adjusted within a wide range, and especially from 10 μ to 2000 μ. If the sliver is formed, it usually has a thickness of 10 μ to 100 μ, preferably 100 μ to 800 μ, more preferably 100 μ to 600 μ ′, and a width of 0.5 mm to 50 mm, preferably 1 mm to 20 mm and more preferably 1 mm to 5 mm 0 The woven fiber may be any form of fabric weave. The weight of the woven fiber is preferably 100 g / m2 to 500 g / m2 ', more preferably 100 g / m2 to 400 g / m2. Based on the weight of the polyolefin, the antistatic additive is preferably present in an amount of 5% to 100%. The amount is more preferably 7% -30%. 7 This paper size applies to Chinese National Standard (CNS) A4 ^ each (210 x 297 public love) (Please read the precautions on the back before filling this page) * ϋ ϋ ϋ IV ϋ ni ^ OJ · II n I nn 1232246 A7 ^ ___ B7__ 5. Description of the invention (U) The special advantage of the present invention is that not every warp or weft yarn needs to be antistatic. For many applications it may be sufficient to have, for example, every two, three or four warp and / or weft yarns antistatic. Other combinations are also possible. How much warp and / or weft yarns should include the antistatic additive is dependent on the end use of the FIBC and can be found through appropriate testing. Generally it should not be lower than every 50 warp and / or weft threads. A woven antistatic flexible intermediate container is preferred, wherein the antistatic additive is included at least every 20 warp and / or weft yarns. In a more preferred embodiment of the present invention, every 5 or more warp and / or weft yarns are made of the antistatic polyolefin. If this antistatic polyolefin is used in every warp and / or weft yarn, a particularly conductive FIBC is obtained. The number of crossings of the antistatic warp and weft yarns is an element defining the final conductivity of the FIBC, thus making it possible to explicitly adjust the desired conductivity. The FIBC may additionally include a coating which also optionally includes the antistatic additive. The coating can be inside or outside the FIBC. It is also possible that the FIBC is only partially coated on one or both surfaces, preferably half. A woven antistatic flexible intermediate container is preferred, wherein the antistatic additive is polyetheresteramide or an antistatic composition containing the polyetheresteramide. Similarly, a woven antistatic flexible intermediate container is preferred, which applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) at 8 paper sizes ------------ --i I (Please read the notes on the back before filling this page) -δ-% · A7 1232246 ____B7______ V. Description of the invention (7) On the inner and / or outer surface, the weight of the solid based on the coating Paints containing 7% -30% of the antistatic additive. -------- I ----- · I I (Please read the notes on the back before filling this page) It is better that the coating is only on the inside of the FIBC. In some examples, even though the fibers of the FIBC do not include antistatic additives to have an antistatic coating, it is possible to achieve antistatic properties. Therefore, another aspect of the present invention is a woven antistatic flexible intermediate container (FIBC) comprising a woven fabric made of polyolefin fibers or sliver, the woven fabric being on the inner and / or outer surface There is a coating layer on the basis of the solid weight of the coating layer, containing polyetheresteramide, polyester-ether block copolymer or polyetheresteramine or polyester-ether in an amount of 7% to 30% The antistatic composition of the block copolymer acts as an antistatic additive. In particular, the coating has a weight of 10 g / m2 to 100 g / m2, preferably 10 g / m2 to 50 g / m2. % The coating can be made of a thermoplastic polymer like a polyolefin, which is coated from a melt to form a laminate, or it can be made of a thermoset or other cross-linkable polymer. It is applied, for example, by dipping, painting or spraying. When thermoplastic polymers are used, polypropylene and polyethylene are preferred. It is also possible to laminate fibers treated with antistatic agents with paper or aluminum. It is preferably done on the inside of the FIBC. If paper is used, it may also include the antistatic additive. Examples of suitable coatings and lacquers are as follows: 1. Mainly cold or hot crosslinkable alkyd, propionate, polyester, epoxy or melamine resins, or mixtures thereof 9 P-scale is applicable to China National Standard 3 (CNS) A4 (210 X 297 meals) '— Ϊ232246 A7' —----------- B7___ V. Painting of the invention description (minutes) Add hardening catalyst if necessary; 2. Two-component polyurethane based on hydroxyl-containing acrylate, polyester or polyether resin, and aliphatic or aromatic 2 isocyanate, isocyanurate or polyisocyanate. Ester paints; 3. One-component polyurethane paints, mainly block isocyanates, isocyanurates or polyisocyanates, which are unblocked during baking and added if necessary Melamine resins; 4. Trialkoxycarbonyl triazene crosslinkers, and one-component polyurethane coatings based on hydroxyl-containing resins such as acrylic, polyester or polyether resins; 5. Aliphatic or aromatic urethane acrylate, or a polyamine having a free amine group in the urethane structure Urethane acrylate, and one-component polyurethane coatings based on melamine resin or polyether resin, if necessary, add a hardening catalyst; 6. (poly) ketimine, and aliphatic Or two-component paint based on aromatic isocyanate, isocyanurate or polyisocyanate; 7. (poly) ketimine, and unsaturated acrylate resin or polyethylene acetate resin or methacrylic acid双 two-component paint based on methyl amino glycolate; 8. two-component paint based on carboxyl or amine-based polyacrylates and polyepoxide; 9. based on anhydride-containing Acrylic resin-based, and two-component paints based on polyhydroxy or polyamine-based components; 10 · Two-component based on anhydride-containing acrylates and polyepoxides China National Standard (CNS) A4 Specification (210 X 297 mm) ---------------- (Please read the precautions on the back before filling this page) Order: 1232246 A7 p- —-- ^ ____ ^ L_ 5. Description of the invention (C |) Painting; U · (Poly) oxazoline, and acrylic acid containing anhydride group 'or unsaturated Acrylic resin, or aliphatic or aromatic isocyanate 'isocyanate or polyisocyanate-based two-component paint; unsaturated polyacrylate and polymalonate-based two-component paint; 13 · M thermoplastic acrylate resin, or diacrylate resin combined with etherified melamine resin-based thermoplastic polyacrylate paint; 14 & Silane-modified or fluorine-modified acrylate resin is Main paint system; 15 · Paint system with melamine resin (such as hexamethoxymethylmelamine) as the cross-linked! 1 (_catalyzed) malonate-block isocyanate, especially It is clear paint. It is also possible to equip the FIBC with an inner bag as an alternative to the above coating 'which does not need to be completely fixed to the FIBC fibers. The inner bag also includes a polyetheresteramide or an antistatic composition containing the polyetheresteramide, and forms a weld with the FIBC, for example. The inner bag may be made of a synthetic polymer, preferably a polyolefin, or a cellulosic material such as paper or cotton. Examples of polyolefins have been described. Preferred is a woven antistatic flexible intermediate container in which an inner bag made of a polyolefin film is loosened or partially fixed to the woven fabric and includes the antistatic additive. Standard methods can be used to incorporate the antistatic additive into the inner bag. Examples are listed above. In the case of cellulosic materials, this antistatic additive 11 (please read the precautions on the back before filling this page) 1 n ΜΜ§ ί ϋ ϋ n 5OJ · n I n MmMe ϋ I e This paper size applies to China Standard (CNS) A4 specification (210 X 297 mm) 1232246 Δ7 __Β7 _____ 5. Description of the invention (1ϋ) The agent can be mixed with a suitable solvent and applied by spraying or dipping, and then the solvent is evaporated. It is also possible to apply via roller coating. If a solvent is used, the antistatic additive is in the form of a suspension and does not dissolve. The FIBC may also be additionally provided with conductive or "semiconductor" fibers, which may be in warp or weft yarns. Examples of the conductive fiber are carbon fiber or metal fiber. The metal may be, for example, iron, nickel, steel or silver. An example of a "semiconductor" fiber is in US 5,478,154. The antistatic additive includes polyetheresteramide or polyester-ether block copolymer. US 4,332,920 describes suitable polyetheresteramides and their manufacture. In EP-A-0 613 919, some polyetheresteramides containing bisphenol A units were proposed as antistatic additives for thermoplastic polymers. DE 28 37 687 describes a method for preparing the polyetheresteramide, and GB 1 518 060 discloses its use as an antistatic fiber and thread. US 6,140,405 describes a static dissipative polymer based on polyester-ether block copolymers and polyetheresteramides suitable for use in the present invention. Preferred polyester-ether block copolymers include the reaction product of ethylene glycol, terephthalic acid or dimethyl terephthalate with polyethylene glycol. Other examples of these and other available polyester-ether copolymers are described in the Encyclopedia of Polymer Science and Engineering, Volume 12, John Wiley & Sons, Inc. NY, 1988, Chapter 49-52 pages. Particularly suitable polyetheresteramides and polyester-ethers are commercially available, for example from Elf Atochem Corp., trade name Pebax®; from Sanyo 12 (please read the notes on the back before filling this page) ·-This paper size applies to China National Standard (CNS) A4 specification (210 X 297 issued) A7 1232246 ^ _B7 ___ 5. Description of the invention (1 I)

Chem. Corp.，商品名稱 Pelestat® ;從 Β· F· Goodrich Company，商品名稱 Stat-Rite® ;以及從 Dupont Company， 商品名稱Hytrel®。 較佳是含有聚醚酯醯胺之抗靜電組成物。該組成物是 描述於US 5,965,206中。 較佳的組成物包括形成纖維或纖維狀的有機聚合性材 料與能夠離子導電且能夠摻入該聚烯烴中之聚醚酯醯胺或 聚酯-醚嵌段共聚物，該聚醚酯醯胺或該聚酯-醚嵌段共聚 物係本質上吸附地接合至該纖維上，或者溶解於其中，並 且在該聚烯烴基質中與其形成網路，其中該纖維不可溶。 能夠離子導電之該聚醚酯醯胺或聚酯-醚嵌段共聚物的一部 份具有極性基團，其能夠錯合或溶合無機或有機質子酸的 鹽類。 必須選擇該纖維狀或形成纖維的有機聚合性材料，使 其不溶解於該聚烯烴基質中，但能夠形成網狀結構的蓮續 纖維。 爲了良好的導電性，一但當其被摻入該聚合物中，該 有機材料的纖維有利的是彼此連續或儘可能在許多點上彼 此交叉。以該方法來形成導電路徑，該電荷可以經由其而 流出。 因爲能夠離子導電之該纖維和聚合物或共聚物是高分 子量的化合物，所以實質上其並沒有被滲出的危險，結果 該抗靜電性質特別地持久。 該聚合物的穩定性質，像是熱穩定性和抗光性及抗水 13 _____________— 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------4·裝—— (請先閱讀背面之注意事項再填寫本頁) •laj·- A7 1232246 _______Β7 _Chem. Corp., trade name Pelestat®; from Beta Goodrich Company, trade name Stat-Rite®; and from Dupont Company, trade name Hytrel®. An antistatic composition containing polyetheresteramide is preferred. This composition is described in US 5,965,206. The preferred composition includes a fiber or fibrous organic polymerizable material and a polyetheresteramide or polyester-ether block copolymer capable of ion conduction and being incorporated in the polyolefin, and the polyetheresteramine Either the polyester-ether block copolymer is adhesively bonded to the fiber in nature, or is dissolved therein and forms a network with it in the polyolefin matrix, where the fiber is insoluble. Part of the polyetheresteramide or polyester-ether block copolymer capable of ion conduction has a polar group, which is capable of dissolving or dissolving salts of inorganic or organic proton acids. The fibrous or fiber-forming organic polymerizable material must be selected so that it does not dissolve in the polyolefin matrix, but can form a continuous fiber with a network structure. For good electrical conductivity, once it is incorporated into the polymer, the fibers of the organic material are advantageously continuous with each other or cross each other as many points as possible. In this way, a conductive path is formed through which the charge can flow out. Since the fibers and polymers or copolymers capable of ion conduction are high molecular weight compounds, there is essentially no danger of being exuded, and as a result, the antistatic properties are particularly durable. The stability properties of the polymer, such as thermal stability and light resistance and water resistance 13 _____________ — This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --------- --- 4 · install—— (Please read the precautions on the back before filling this page) • laj ·-A7 1232246 _______ Β7 _

五、發明說明（|7J 解性，在多數例子中實質上是不受影響的。 ---------------- (請先閱讀背面之注意事項再填寫本頁) 該抗靜電添加劑較佳是連續纖維形式的混合物，該混 合物包含： (bl)爲纖維狀或形成纖維混合，並且不溶解於該聚 烯烴基質的有機聚合性材料，其是選自聚丙烯酸酯、聚甲 基丙烯酸酯、聚丙烯腈、聚乙烯醇、聚乙酸乙烯酯、聚醯 胺、聚胺基甲酸酯或聚酯所組成之族群； (b2)聚醚酯醯胺或聚酯-醚嵌段共聚物；以及 (b3)選自 LiCl〇4、LiCF3S〇3、NaCl〇4、LiBF4、NaBF4 、KBF4、NaCFsSCh、Kcl〇4、KPF6、KCF3S〇3、KC4F9S〇3、 Ca(Cl〇4)2、Ca(PF6)2、Mg(Cl〇4)2、Mg(CF3S〇3)2、Zn(Cl〇4)2 、Zn(PF〇2或Ca(CF3SCb)2所組成之族群的鹽，其已錯合或 溶合於該聚醚酯醯胺或聚酯_醚嵌段共聚物（b2)中。 更佳是連續纖維形式的混合物，該混合物包含： (bl )以重量計30-70%之聚醯胺； (b2)以重量計70-30%之聚醚酯醯胺或聚酯_醚嵌段 共聚物；以及 (b3)以重量計0.1-10%之選自LiCl〇4、LiCF3S〇3、 NaCICU、LiBF4、NaBF4、KBF4、NaCFsSCh、Kcl〇4、KPF6、 KCF3S〇3、KC4F9S〇3、Ca(Cl〇4)2、Ca(PF6)2、Mg(Cl〇4)2、 Mg(CF3S〇3)2 、Zn(Cl〇4)2 、Zn(PF6)2 或 Ca(CF3S〇3)2 所組成 之族群的鹽，其已錯合或溶合於該聚醚酯醯胺或聚酯-醚嵌 段共聚物（b2)中，成份的總和爲100%。 該抗靜電組成物是從 Ciba Specialty Chemicals Company 14 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 x 297公釐） I232246 A7 〜^ ____B7_ 五、發明說明（iy 商業上可得到的，商品名稱Irgastat®P18和Irgastat®P22。 ------------Λ裝—— (請先閱讀背面之注意事項再填寫本頁) 該抗靜電混合物可能進一步額外包括添加劑，像是加 工、光和熱穩定劑。例子如下。 &氧化劑 1丄烷基化單苯酚，例如2,6-二-第三丁基-4-甲基苯酚 、2-第三丁基-4,6-二甲基苯酚、2,6-二-第三丁基斗乙基苯 酚、2,6-二-第三丁基-4-正丁基苯酚、2,6-二-第三丁基斗異 丁基苯酚、2,6-二環戊基斗甲基苯酚、2- ( α-甲基環己基 )-4,6-二甲基苯酚、2,6-二-十八基-4-甲基苯酚、2,4,6-三環 己基苯酚、2,6-二-第三丁基-4-甲氧基甲基苯酚，直鏈或在 支鏈分支的壬基苯酚，例如2,6-二-壬基-4-甲基苯酚、2,4-二甲基-6- ( 1’-甲基十一-Γ-基）苯酚、2,4-二甲基-6- ( 1’-甲基十七-1’-基）苯酚、2,4-二甲基-6- ( 1，-甲基十三-1’-基 )苯酚及其混合物。 1.2. 烷某硫甲基苯酚，例如2,4-二辛基硫甲基-6-第三丁 基苯酚、2,4-二辛基硫甲基-6-甲基苯酚、2,4-二辛基硫甲基 -6-乙基苯酚、2,6-二-十二基硫甲基-4-壬基苯酚。 1.3. 氤酲和烷基化氣醢，例如2,6-二-第三丁基-4-甲氧 基苯酚、2,5-二-第三丁基氫醌、2,5-二-第三戊基氫醌、2,6-二苯基斗十八氧基苯酚、2,6-二-第三丁基氫醌、2,5-二-第 三丁基斗羥基苯甲醚、3,5-二-第三丁基-4-羥基苯甲醚、 3,5-二-第三丁基4-羥苯基硬脂酸酯、雙（3,5-二-第三丁基-4-羥苯基）己二酸酯。 1.4·牛育酉分（tocopherols)，例如育酌、/9-生育 15 本紙張尺度適用中國國家標準（CNS)A4規格(210 X 297公f ) A7 1232246 五、發明說明（丨f) 酚、r-生育酚、生育酚及其混合物（維他命E)。 1.5. 羥基化硫二苯某醚，例如2,2，-硫基雙（6-第三丁 基-4-甲基苯酚）、2,2’-硫基雙（4-辛基苯酚）、4,4’-硫基 雙（6-第三丁基各甲基苯酚）、4,4，-硫基雙（6·第三丁基-2-甲基苯酚）、4,4’-硫基雙（3,6-二-第二戊基苯酚）、4,4’-雙（2,6-二甲基-4-羥苯基）二硫。 1.6. 亞烷基雙酚，例如2,2，-亞甲基雙（6-第三丁基-4-甲基苯酚）、2,2’-亞甲基雙（6-第三丁基斗乙基苯酚）、 2,2’·亞甲基雙〔4-甲基-6- ( α-甲基環己基）-苯酚〕、2,2’-亞甲基雙（4-甲基-6-環己基苯酚）、2,2’-亞甲基雙（6-壬 基-4-甲基苯酚）、2,2’-亞甲基雙（4,6-二-第三丁基苯酚） 、2,2’-亞乙基雙（4,6-二-第三丁基苯酚）、2,2’-亞乙基雙 (6-第三丁基-4-異丁基苯酚）、2,2，-亞甲基雙〔6-(〇:-甲 苄基）斗壬基苯酚〕、2,2’-亞甲基雙〔6- ( α，α-二甲苄基 )-4-壬基苯酚〕、4,4’-亞甲基雙（2,6-二-第三丁基苯酚） 、4,4’-亞甲基雙（6-第三丁基-2-甲基苯酚）、1，1-雙（5-第 三丁基-4-羥基-2-甲基苯基）丁烷、2,6-雙（3-第三丁基-5-甲基-2-羥苄基）-4-甲基苯酚、1，1，3·三（5-第三丁基-4-羥 基_2_甲基苯基）丁烷、1,1-雙（5-第三丁基-4-羥基-2-甲基 苯基）各正十二基锍基丁烷、雙〔3,3-雙（3’-第三丁基-4’-羥苯基）丁酸乙二醇酯〕、雙（3-第三丁基-4-羥基-5-甲基-苯基）二環戊二烯、雙〔2- (3，-第三丁基-2，-羥基-5，-甲苄 基）-6-第三丁基-4-甲基苯基〕對苯二甲酸酯、ι，ΐ-雙-( 3,5-二甲基-2-羥苯基）丁烷、2,2-雙（3,5-二-第三丁基-4-羥 16 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ^ (請先閱讀背面之注意事項再填寫本頁) --------訂--------- %· 1232246 A7 __B7 _ 五、發明說明（K) 苯基）丙烷、2,2-雙（5-第三丁基-4-羥基-2-甲基苯基）_4_ 正十二基毓基丁烷、1，1，5,5-四（5-第三丁基-4-羥基-2-甲基 苯基）戊烷。 1·7_·—〇:_、Ν-和S-苄基化合物，例如3,5,3’，5、四-第三丁 基-4,4’-二羥基二苄基醚、4-羥基-3,5-二甲苄基酼基乙酸十 八酯、4-羥基-3,5-二-第三丁基苄基锍基乙酸十三酯、三（ 3.5- 二-第三丁基斗羥苄基）胺、雙（4-第三丁基-3-羥基- 2.6- 二甲苄基）二硫基對苯二甲酸酯、雙（3,5_二-第三丁基 -4-羥苄基）硫、3,5-二-第三丁基-4-羥苄基毓基乙酸異辛酯 〇 1.8. 羥苄基化丙二酸酯，例如2,2·雙（3,5-二-第三丁 基-2_羥苄基）丙二酸二-十八酯、2- (3-第三丁基-4-羥基-5-甲苄基）丙二酸二-十八酯、2,2·雙（3,5-二-第三丁基-4-羥 苄基）丙二酸二-十二基毓基乙酯、2,2-雙（3,5-二-第三丁 基-4-羥苄基）丙二酸雙〔4- (1，1，3,3-四甲基丁基）苯〕酯 〇 1.9. 芳族羥苄某化合物，例如1，3,5-三（3,5-二-第三丁 基-4-羥苄基）-2,4,6·三甲基苯、1，4-雙（3,5-二-第三丁基-4· 羥苄基）-2,3,5,6-四甲基苯、2,4,6-三（3,5-二-第三丁基-4-羥苄基）苯酚。 1.10. 三氮拼（triazine)化合物，例如2,4-雙（辛基疏 基）-6- (3,5-二-第三丁基-4-羥基苯胺基）-1，3,5·三氮畊、 2-辛基锍基-4,6-雙（3,5-二-第三丁基-4-羥基苯胺基）-1，3,5-三氮明：、2-辛基锍基-4,6-雙（3,5-二-第三丁基I羥基苯氧 17 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱1 ~ ----------------- (請先閱讀背面之注意事項再填寫本頁) - A7 1232246 五、發明說明（) ---------------- (請先閱讀背面之注意事項再填寫本頁) 基）-1，3,5-三氮明:、2,4,6-三（3,5-二-第三丁基斗羥基苯氧 基）-1，2,3-三氮啡、1，3,5-三（3,5-二-第三丁基-4-羥苄基） 異氰脲酸酯、1，3,5-三（4-第三丁基-3-羥基-2,6-二甲苄基） 異氰脲酸酯、2,4,6-三（3,5-二-第三丁基-4-羥苯基乙基）-1，3,5-三氮畊、1，3,5-三（3,5-二-第三丁基-4-羥苯基丙醯基 )-六氫-1，3,5-三氮畊、1，3,5-三（3,5-二環己基-4-羥苄基） 異氰脲酸酯。 1 苄某膦酸酯，例如2,5-二-第三丁基-4-羥苄基膦酸 二甲酯、3,5·二-第三丁基斗羥苄基膦酸二乙酯、3,5-二-第 三丁基-4-羥苄基膦酸二-十八酯、5-第三丁基-4-羥基-3_甲 苄基膦酸二-十八酯，3,5-二-第三丁基-4-羥苄基膦酸之單乙 基酯的鈣鹽。 % ΓΠ.醯某胺某苯酚，例如4-羥基月桂醯苯胺、4-羥基 硬脂醯苯胺、N- (3,5_二·第三丁基-4-羥苯基）胺基甲酸辛 酯。 ΓΠ. β- (3.5·二-第三丁基-4-羥苯某）丙酸與單-或冬 元醇的酯類，像是與甲醇、乙醇、正辛醇、異辛醇、十八 烷醇、1，6-己二醇、1，9-壬二醇、乙二醇、1,2-丙二醇、2,2-二甲基丙二醇、硫基二甘醇、二甘醇、三甘醇、異戊四醇 、三(羥乙基）異氰脲酸酯、Ν，Ν’-雙（羥乙基）乙二醯胺、 3-噻十一烷醇、3-瞳十五烷醇、三甲基己二醇、三甲基醇 丙烷、4-羥甲基小磷-2,6,7-三聘雙環[2·2·2]辛烷。 1.14. β- (5-第三丁某-4-羥基-3-甲基苯基）丙酸與單-霞多元醇的酯類，像是與甲醇、乙醇、正辛醇、異辛醇、 18 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 1232246 ____B7___ 五、發明說明（^ ------I--I------ (請先閱讀背面之注意事項再填寫本頁) 十八烷醇、1,6-己二醇、1，9-壬二醇、乙二醇、U-丙二醇 、2,2-二甲基丙二醇、硫基二甘醇、二甘醇、三甘醇、異戊 四醇、三(羥乙基）異氰脲酸酯、N，N，-雙（羥乙基）乙二醯 胺、3-噻十一烷醇、3-噻十五烷醇、三甲基己二醇、三甲 基醇丙烷、4-羥甲基小磷-2,6,7-三聘雙環[2.2.2]辛烷；3,9-雙〔2- { 3- (3-第三丁基-4-羥基-5-甲基苯基）丙醯氧基）-U-二甲基乙基〕-2,4,8，10-四腭螺[5.5]十一烷。 1.15. β- (3,5-二環己基-4-羥茏某）丙酸與單-或多元—麗 Μ旨類，像是與甲醇、乙醇、辛醇、十八烷醇、1，6-己二醇 、1，9-壬二醇、乙二醇、1，2-丙二醇、2,2-二甲基丙二醇、 硫基二甘醇、二甘醇、三甘醇、異戊四醇、三（羥乙基）異 氰脲酸酯、Ν，Ν’-雙（羥乙基）乙二醯胺、3-_十一烷醇、 3-_十五烷醇、三甲基己二醇、三甲基醇丙烷、4-羥甲基-1-磷-2,6,7-三腭雙環[2.2.2]辛烷。 1.16. 3,5-二-第三丁某斗羥苯某乙酸與單-或多元醇_殷 酯類，像是與甲醇.、乙醇、辛醇、十八烷醇、1，6-己二醇、 1，9-壬二醇、乙二醇、1，2-丙二醇、2,2-二甲基丙二醇、硫 基二甘醇、二甘醇、三甘醇、異戊四醇、三（羥乙基）異氰 脲酸酯、Ν，Ν’-雙（羥乙基）乙二醯胺、3-噻十一烷醇、3-噻十五烷醇、三甲基己二醇、三甲基醇丙烷、4-羥甲基-1-磷-2,6,7-三腭雙環[2.2.2]辛烷。 1.17. β· (3,5-二-第三丁基-4-羥苯某）丙酸之醯胺，像 是Ν，Ν’-雙（3,5-二-第三丁基-4·羥苯基丙醯基）六亞甲基 二醯胺、Ν，Ν’-雙（3,5-二-第三丁基-4-羥苯基丙醯基）三亞 19 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 1232246 _______B7__ 五、發明說明（β) ------------β裝—— (請先閱讀背面之注意事項再填寫本頁) 甲基二醯胺、Ν，Ν’-雙（3,5-二-第三丁基-4-羥苯基丙醯基） 醯肼、Ν，Ν，-雙〔2- ( 3-〔 3,5-二-第三丁基-4-羥苯基〕丙醯 氧基）乙基〕乙二醯胺（由Uniroyal所提供之 Naugard®XL-l )。 1.18.抗壞血酸(維他命C) 1」Q.胺杭氬化劑，例如N，N5-二-異丙基-對-伸苯基二 胺、N，N’-二-第二丁基-對-伸苯基二胺、N，N’-雙（1，4-二甲 基戊基）-對·伸苯基二胺、N，N’-雙（L·乙基-3-甲基戊基）-對-伸苯基二胺、N，N’-雙（1-甲基庚基）-對-伸苯基二胺、 N，N’-二環己基-對-伸苯基二胺、N，N’-二苯基-對-伸苯基二 胺、N，N’-雙（2-萘基）-對-伸苯基二胺、N-異丙基-Ν’-苯基 -對-伸苯基二胺、Ν- ( 1，3-二甲基丁基）-Ν’-苯基-對-伸苯 基二胺、Ν- ( 1-甲基庚基）-Ν’-苯基-對-伸苯基二胺、Ν-環 己基-Ν’-苯基-對-伸苯基二胺、4-(對-甲苯胺磺醯基）二苯 基胺、Ν，Ν’-二甲基-Ν，Ν’-二·第二丁基-對-伸苯基二胺、二 苯基胺、Ν-烯丙基二苯基胺、4-異丙氧基二苯基胺、Ν-苯 基-1-基胺、Ν- (4-第三辛基苯基）小萘基胺、Ν-苯基-2-萘基胺、辛烷基化二苯基胺；例如ρ，ρ’-二-第三辛基二苯基 胺、4-正丁基胺基苯酚、4-丁醯基胺基苯酚、4-壬醯基胺基 苯酚、4-十二醯基胺基苯酚、4-十八醯基胺基苯酚、雙（4-甲氧基苯基）胺、2,6-二-第三丁基-4-二甲基胺基甲基苯酚 、2,4’-二胺基二苯基甲烷、4,4’-二胺基二苯基甲烷、 Ν，Ν，Ν’，Ν’-四甲基-4,4’·二胺基二苯基甲烷、1,2-雙〔（2-甲 基苯基）胺基〕乙烷、1，2-雙（苯基胺基）丙烷、（鄰-甲 20 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 1232246 B7_ 五、發明說明（（I) 苯基）雙縮胍（biguanide)、雙〔4_ ( Γ，3’-二甲基丁基） 苯基〕胺、第三辛基化Ν-苯基-1-基胺，單-和二烷基化 第三丁基/第三辛基二苯基胺的混合物，單-和二烷基化壬 基二苯基胺的混合物，單-和二烷基化十二基二苯基胺的混 合物，單-和二烷基化異丙基/異己基二苯基胺的混合物， 單-和二烷基化第三丁基二苯基胺、2,3-二氫-3,3-二甲基-4H-M-苯并硫氮啡（benzothiazine )、啡 _ 啡（ phenothiazine)，單-和二院基化第三丁基/第三辛基啡噻啡 的混合物，單-和二烷基化第三辛基啡_啡的混合物、N-烯 丙基啡瞳明1、队队^"’-四苯基-1，4-二胺基丁-2-烯、义队雙 (2,2,6,6-四甲基哌啶-4-基）-六亞甲基二胺、雙（2,2,6,6-四甲基哌啶-4·基）癸二酸酯、2,2,6,6-四甲基派啶-4·酮、 2,2,6,6-四甲基派啶-4-醇。 2.柴外光吸收劑和光穩定劑 2丄2- (2’-羥苯某）苯并***，例如2- (2、羥基-5’-甲基苯基）苯并***、2- (3’，5’-二-第三丁基-2’-羥苯基） 苯并***、2- (5’-第三丁基-2’-羥苯基）苯并***、2- (2’_ 羥基-5’- ( 1，1,3,3-四甲基丁基）苯基）苯并***、2-( 3，，5，-二·第三丁基-2’-羥苯基）-5-氯苯并***、2- (3’-第三 丁基_2’_羥基-5’-甲基苯基）-5-氯苯并***、2- (3’-第二丁 基-5’-第三丁基-2’-羥苯基）苯并***、2- (2，-經基-4’-辛氧 基苯基）苯并***、2- (3’，5’_二-第三戊基-2’-羥苯基）苯 并***、2- (3’,5’-雙（α，α-二甲苄基）-2，·羥苯基）苯并 ***、2- (3’-第三丁基-2’-羥基-5，- (2-辛氧基羰基乙基） 21 ---------------- (請先閱讀背面之注意事項再填寫本頁) · · 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 !232246 —___21- 五、發明說明（W ) -------------· 11 (請先閱讀背面之注意事項再填寫本頁) 苯基）-5-氯苯并***、2- (3，-第三丁基-5’-〔2- (2-乙基己 基氧基）羰基乙基〕-2’-羥苯基）-5-氯苯并***、2- (3’-第三丁基-2’-羥基-5’- (2-甲氧基羰基乙基）苯基）-5-氯苯 并***、2- (3，-第三丁基-2’·羥基-5’- (2-甲氧基羰基乙基 )苯基）苯并***、2- (3，-第三丁基-2’-羥基-5’- (2-辛氧 基羰基乙基）苯基）苯并***、2- (3’-第三丁基-5’-〔2-( L乙基己基氧基）羰基乙基〕-2’-羥苯基）苯并***、2-( 3’-十二基-2’-羥基-5’-甲基苯基）苯并***、2· (3，-第三丁 基-2’-羥基-5’- (2-異辛氧基羰基乙基）苯基）苯并***、 2,2’-亞甲基雙〔4- (1，1，3,3-四甲基丁基）-6-苯并***-2-基 苯酚〕；2-〔3’-第三丁基·5’- (2-甲氧基羰基乙基）-2’-羥 苯基〕-2Η-苯并***與聚乙二醇300之酯交換產物；〔R-CH2CH2—C〇〇一CH2CH2—〕2，其中 R= 3’-第三丁基-4、經 基-5’-2H-苯并***-2-基苯基、2-〔 2’-羥基-3’- ( α，-二甲 苄基）-5’- ( 1，1，3,3-四甲基丁基）苯基〕-苯并***；2-〔 2’-羥基-3’- ( 1，1，3,3-四甲基丁基）-5’- ( α，-二甲苄基） 苯基〕-苯并二哩。 2.2. 2-羥某二苯甲酮，例如4-羥基、4-甲氧基、4-辛氧 基、4-癸氧基、4-十二氧基、4-苄氧基、4,2’，4’-三羥基和 2’-羥基-4,4’-二甲氧基的衍生物。 _2J•取代及未取代苯甲酸之酯類，例如水楊酸4-第三 丁基苯酯、水楊酸苯酯、水楊酸辛基苯酯、二苄醯基間苯 二酚、雙（4-第三丁基芣醯基）間苯二酚、3,5-二·第三丁 基-4-羥基苯甲酸2,4-二_第三丁基苯酯、3,5-二-第三丁基-4- 22 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1232246 B7 五、發明說明（yp --------------裝--- (請先閱讀背面之注意事項再填寫本頁) 羥基苯甲酸十六酯、3,5-二-第三丁基-4-羥基苯甲酸十八酯 、3,5-二-第三丁基斗羥基苯甲酸2-甲基-4,6-二·第三丁基苯 酯。 M.丙烯酸酯，例如α-氰基-β，β-二苯基丙烯酸乙酯、 α-氰基-β，β-二苯基丙烯酸異辛酯、α-羧基甲氧基苯丙燦 酸甲酯、α-氰基-β-甲基-對-甲氧基苯丙烯酸甲酯、α-氰 基--甲基-對-甲氧基苯丙烯酸丁酯、α-羧基甲氧基-對-甲 氧基苯丙烯酸甲酯、和Ν- (β_羧基甲氧基-β-氰基乙烯基） -2-甲基D引II朵。 2.5. 鎮化合物，例如2,2’-硫基雙〔4- (1，1，3,3-四甲基 丁基）苯酚〕與其他像是正丁基胺、三乙醇胺或Ν-環己基 二乙醇胺的配位基或無其他配位基，像是1 : 1或1 : 2錯 合之鎳錯合物，二丁基二硫基胺基甲酸鎳鹽，像是4-羥基-3,5-二-第三丁基苄基膦酸的甲酯或乙酯之單烷基酯的鎳鹽 ，像是2-羥基-4-甲基苯基十一基酮肟之酮肟的鎳錯合物， 像是1-苯基-4-月桂醯基-5-羥基吡唑與其他配位基或無其他 配位基之鎳錯合物。 2.6. 位阻胺，例如雙（2,2,6,6-四甲基-4-呢啶基）癸二 酸酯、雙（2,2,6,6-四甲基斗呢啶基）丁二酸酯、雙（ 1，2,2,6,6-五甲基-4-顿啶基）癸二酸酯、雙（μ辛氧基_ 2,2,6,6-四甲基-4-Ρ飛啶基）癸二酸酯、雙（1，2,2,6,6-五甲基-4-呢啶基）正丁基-3,5-二-第三丁基-4-羥苄基丙二酸酯、；ΙΟ-羥乙基 ） -2,2,6,6-四甲基-4-羥基呢啶與丁二酸的縮合物 、Ν，Ν’-雙（2,2,6,6-四甲基斗顿啶基）六亞甲基二胺與4-第 23 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1232246 A7 ____B7___ 五、發明說明（yV) ---------------- (請先閱讀背面之注意事項再填寫本頁) 三辛基胺基-2,6-二氯-1，3,5_三氮啡的直鏈或環狀縮合物、 三（2,2,6,6-四甲基-4-哌啶基）氮基三乙酸酯、四（2,2,6,6-四甲基-4-呢啶基）-1，2,3,4-丁烷四羧酸酯、1，1’- ( 1，2-乙烷 二基）-雙（3,3,5,5·四甲基呢啡酮）、4-苄醯基-2,2,6,6-四 甲基呢啶、4-硬脂醯基氧基-2,2,6,6-四甲基顿啶、雙（ 1，2,2,6,6-五甲基呢啶基）-2-正丁基-2-(2-羥基-3,5-二-第三 丁基苄基）-丙二酸酯、3-正辛基-7,7,9,9-四甲基-1，3,8-三吖 螺[4.5]癸烷-2,4-二酮、雙（1-辛氧基-2,2,6,6-四甲基呢啶基 )癸二酸酯、雙（1-辛氧基-2,2,6,6-四甲基哌啶基）丁二酸 酯、N，N’-雙（2,2,6,6-四甲基-4-呢啶基）六亞甲基二胺與4-嗎福啉基-2,6-二氯-1,3,5-三氮畊的直鏈或環狀縮合物、2-氯 _4,6·雙（4-正丁基胺基-2,2,6,6-四甲基呢啶基）-1，3,5-三氮 啡與U-雙（3-胺基丙基胺基）乙烷的縮合物、2-氯-4,6-二 (4-正丁基胺基-1，2,2,6,6-五甲基顿啶基）-1，3,5-三氮啡與 1,2-雙（3-胺基丙基胺基）乙烷的縮合物、8-乙醯基-3-十二 基-7,7,9,9-四甲基-1，3,8·三吖螺[4.5]癸烷-2,4-二酮、3-十二 基-1- (2,2,6,6-四甲基斗派啶基）毗咯啶-2,5-二酮、3-十二 基小（1，2,2,6,6-五甲基-4-派啶基）吡咯啶-2,5-二酮、4-十 六基氧基與4-硬脂醯基氧基-2,2,6,6-四甲基呢啶的混合物、 N，N’-雙（2,2,6,6_四甲基-4-呢啶基）六亞甲基二胺與4-環己 基胺基-2.6-二氯-1，3,5-三氮畊的縮合物、1，2-雙（3-胺基丙 基胺基）乙烷與2,4,6-三氯-1，3,5-三氮啡，以及4-丁基胺基 -2,2,6,6-四甲基哌啶的縮合物（CAS Reg· Νο·[136504-96-6] );1，6-己烷二胺與2,4,6·三氯-1，3,5-三氮啡，以及Ν，Ν-二 24 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1232246 A7 —^一 ___B7 五、發明說明（yj) 丁基胺與4-丁基胺基-2,2,6,6-四甲基呃啶的縮合物（CAS Reg. No.[192268-64-7]) ; N- ( 2,2,6,6-四甲基_4_呃啶基）-正十二基丁二醯亞胺、N- ( 1，2,2,6,6-五甲基-4_呢啶基）-正 十一基丁二醯亞胺、2-~f—^基_7,7,9,9_四甲基小聘-3,8-二口丫 -4-酮基-螺[4.5]癸烷、7,7,9,9-四甲基-2-環十一基-1-聘-3,8-二吖-4-酮基螺-[4.5]癸烷與表氯醇（epichlorohydrin)的反 應產物、U-雙（1，2,2,6,6-五甲基-4-呃啶基氧基羰基）-2-(4·甲氧基苯基）乙烯、N，N’-雙-甲醯基·Ν，Ν’_雙（2,2,6,6-四甲基-4-呢啶基）六亞甲基二胺、4-甲氧基亞甲基丙二酸 與1，2,2,6,6-五甲基斗羥基顿啶的二酯、聚〔甲基丙基-3-氧 基-4_(2,2,6,6-四甲基斗呃啶基）〕矽氧烷、順丁烯二酸酐 -1烯烴共聚物與2,2,6,6-四甲基-4-胺基哌啶或1，2,2,6,6-五 甲基-4-胺基呢啶的反應產物。 2J.乙二醯胺，例如4,4’_二辛氧基草醯替苯胺、2,2’-二乙氧基草醯替苯胺、2,2’-二辛氧基-5,5’-二-第三丁草醯替 苯胺、2,2’-二·十二基氧基-5,5’-二-第三丁草醯替苯胺、2-乙氧基-2’·乙基草醯替苯胺、Ν，Ν’-雙（3-二甲基胺基丙基 )乙二醯胺、2-乙氧基-5-第三丁基-2’-乙草醯替苯胺和其與 2-乙氧基-2’-乙基-5,4’-二-第三丁草醯替苯胺的混合物、鄰-和對-甲氧基-二取代草醯替苯胺的混合物、以及鄰-和對-乙 氧基-二取代草醯替苯胺的混合物。 2·8· 2- (2-羥苯某）-1·3,5-三氮咁，例如2,4,6-三（2-羥 基-4-辛氧基苯基）-1，3,5-三氮啡、2- (2-羥基-4-辛氧基苯 基）-4,6-雙（2,4-二甲基苯基）-1，3,5-三氮啡、2- (2,4-二羥 25 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公愛） (請先閱讀背面之注意事項再填寫本頁) n -ϋ i_i n 一-OJe I n n ϋ n ϋ A7 1232246 ___ B7____ 五、發明說明) 苯基）-4,6-雙（2,4-二甲基苯基）-1，3,5-三氮啡、2,4-雙（2-羥基-4-丙基氧基苯基）-6- (2,4-二甲基苯基）-1，3,5-三氮啡 、2- (2-羥基冰辛氧基苯基）-4,6-雙（4-甲基苯基）-1，3,5-三氮畊、2- (2-羥基-4·十二基氧基苯基）-4,6-雙（2,4-二甲 基苯基）-1，3,5-三氮畊、2- (2-羥基-4-十三基氧基苯基）-4,6-雙（2,4-二甲基苯基）-1，3,5_三氮啡、2-〔 2-羥基-4- (2-羥基-3-丁基氧基丙氧基）苯基〕-4,6-雙（2,4-二甲基）-1，3,5-三氮啡、2-〔 2-羥基-4- ( 2-羥基-3·辛氧基丙基氧基） 苯基〕-4,6-雙（2,4-二甲基）-1，3,5-三氮畊、2-〔4-(十二 基氧基/十三基氧基-2-羥基丙氧基）-2-羥苯基〕-4,6-雙（ 2,4-二甲基苯基）-1，3,5_三氮啡、2-〔 2-羥基-4- (2-羥基-3-十二基氧基丙氧基）苯基〕-4,6-雙（2,4-二甲基苯基）-1，3,5-三氮啡、2- (2-羥基-4-己基氧基）苯基-4,6-二苯基-1,3,5-三氮啡、2-(2-羥基冰甲氧基苯基）-4,6-二苯基-1，3,5-三氮啡、2,4,6-三〔2-羥基斗（3-丁氧基-2-羥基丙氧 基）苯基〕-1，3,5-三氮啡、2- (2-羥苯基）-4- (4-甲氧基苯 基）-6-苯基-1，3,5-三氮啡、2- { 2-羥基斗〔3· (2-乙基己基 -1-氧基）-2-羥基丙基氧基〕苯基} -4,6-雙（2,心二甲基苯 基）_1，3,5-三氮畊。 3·金屬鈍化劑（metal deactivator)，例如N，N’-二苯基乙二 醯胺、N-水楊醛-Ν’-水楊醯基肼、N，N’_雙（水楊醯基）肼 、N，N’-雙（3,5-二-第三丁基斗羥苯基丙醯基）肼、3-水楊 醯基胺基-1，2,4-***、雙（苯亞甲基）乙二醯基二醯肼、 草醯替苯胺、異肽醯基二醯肼、癸二醯基雙苯基醯肼、 26 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ---------------- (請先閱讀背面之注意事項再填寫本頁) -C-0 . A7 1232246 五、發明說明（/) N，N，-二乙醯基己二醯基二醯肼、n，n’-雙（水楊醯基）乙二 醯基二醯肼、N，N’-雙（水楊醯基）硫基丙醯基二醯胼。 ------------減裝—— (請先閱讀背面之注意事項再填寫本頁) 4_酯和亞膦酸酯，例如亞磷酸三苯酯、亞磷酸二苯 基烷酯、亞磷酸苯基二烷酯、亞磷酸三（壬基苯基）酯、 亞磷酸三月桂酯、亞磷酸三-十八酯、二亞磷酸二硬脂醯基 異戊四醇酯、亞磷酸三（2,4-二-第三丁基苯基）酯、二亞 磷酸二異癸基異戊四醇酯、二亞磷酸雙（2,4-二-第三丁基 苯基）異戊四醇酯、二亞磷酸雙（2,4-二-茴香基苯基）異 戊四醇酯、二亞磷酸雙（2,6-二-第三丁基-4-甲基苯基）異 戊四醇酯、二亞磷酸二異癸基氧基異戊四醇酯、二亞磷酸 雙（2,4-二-第三丁基-6-甲基苯基）異戊四醇酯、二亞磷酸 雙（2,4,6_三（第三丁基苯基）異戊四醇酯、三亞磷酸三硬 脂醯基山梨糖醇酯、二亞膦酸四（2,4-二-第三丁基苯基）-4,4’-亞聯苯基酯、6-異辛氧基-2,4,8，10·四-第三丁基-12H-二 苯[d.g]-l，3,2-二氧雜磷辛英(phosphocin)、亞磷酸雙（2,4-二 -第三丁基-6-甲基苯基）甲酯、亞磷酸雙（2,4-二-第三丁基 -6-甲基苯基）乙酯、6-氟-2,4,8，10-四-第三丁基-12-甲基-二 苯[d.g]-l，3,2-二氧雜磷辛英(phosphocin)、2,2’，2’’-氮基〔亞 磷酸三乙基-三（3,3’，5,5’-四-第三丁基-1，1’聯苯-2,2’-二基 )酯〕、亞磷酸2-乙基己基（3,3’，5,5’_四-第三丁基-1，1’聯 苯-2,2’-二基）酯、5-丁基-5-乙基-2- (2,4,6-三-第三丁基苯 氧基）-1，3,2-二氧雜憐丙環(phosphirane)。 下列的亞磷酸酯是較佳的： 亞磷酸三（2,4-二-第三丁基苯基）酯（Irgafos®168, 27 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1232246 A7 B7 五、發明說明（*/ί)V. Explanation of the invention (| 7J is interpretable, and in most cases it is essentially unaffected. ---------------- (Please read the precautions on the back before filling this page ) The antistatic additive is preferably a mixture in the form of continuous fibers, the mixture comprising: (bl) a fibrous or fiber-forming mixture, and an organic polymerizable material insoluble in the polyolefin matrix, which is selected from polyacrylates , Polymethacrylate, polyacrylonitrile, polyvinyl alcohol, polyvinyl acetate, polyamidoamine, polyurethane or polyester; (b2) polyetheresteramidoamine or polyester- Ether block copolymer; and (b3) selected from the group consisting of LiCl04, LiCF3S03, NaCl04, LiBF4, NaBF4, KBF4, NaCFsSCh, Kcl04, KPF6, KCF3S03, KC4F9S03, Ca (Cl. 4) 2, Ca (PF6) 2, Mg (Cl〇4) 2, Mg (CF3S〇3) 2, Zn (Cl〇4) 2, Zn (PF〇2 or Ca (CF3SCb) 2 Salt, which has been complexed or dissolved in the polyetheresteramide or polyester-ether block copolymer (b2). More preferably a mixture in the form of continuous fibers, the mixture comprising: (bl) 30 by weight -70% polyamide; (b2 ) 70-30% by weight of polyetheresteramide or polyester-ether block copolymer; and (b3) 0.1-10% by weight selected from LiClO4, LiCF3S03, NaCICU, LiBF4, NaBF4, KBF4, NaCFsSCh, KclO4, KPF6, KCF3S〇3, KC4F9S〇3, Ca (Cl〇4) 2, Ca (PF6) 2, Mg (Cl〇4) 2, Mg (CF3S〇3) 2, Salts of the group consisting of Zn (Cl〇4) 2, Zn (PF6) 2 or Ca (CF3S〇3) 2, which have been mismatched or dissolved in the polyetheresteramide or polyester-ether block copolymer (B2), the total of the ingredients is 100%. The antistatic composition is from Ciba Specialty Chemicals Company 14 This paper size applies Chinese National Standard (CNS) A4 specification (21 × x297 mm) I232246 A7 ~ ^ ____B7_ V. Description of the invention (iy commercially available, trade names Irgastat® P18 and Irgastat® P22. ------------ ΛPackage-(Please read the precautions on the back before filling this page) ) The antistatic mixture may further include additives such as processing, light, and thermal stabilizers. Examples are as follows. &Amp; Oxidant 1 丄 alkylated monophenol, such as 2,6-di-tert-butyl-4-methyl Phenol, 2-tert-butyl -4,6-dimethylphenol, 2,6-di-tertiary-butyl ethyl phenol, 2,6-di-tertiary-butyl-4-n-butyl phenol, 2,6-di-tertiary Tributyl pipeisobutylphenol, 2,6-dicyclopentyl pipemethylphenol, 2- (α-methylcyclohexyl) -4,6-dimethylphenol, 2,6-bis-octadecyl 4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-third-butyl-4-methoxymethylphenol, nonylphenol branched straight or branched , Such as 2,6-bis-nonyl-4-methylphenol, 2,4-dimethyl-6- (1'-methylundecyl-Γ-yl) phenol, 2,4-dimethyl- 6- (1'-methylheptadecan-1'-yl) phenol, 2,4-dimethyl-6- (1, -methyltridec-1'-yl) phenol, and mixtures thereof. 1.2. Alkyl thiomethylphenol, such as 2,4-dioctylthiomethyl-6-third butylphenol, 2,4-dioctylthiomethyl-6-methylphenol, 2,4- Dioctylthiomethyl-6-ethylphenol, 2,6-di-dodecylthiomethyl-4-nonylphenol. 1.3. Thorium and alkylated tritium, such as 2,6-di-tertiary-butyl-4-methoxyphenol, 2,5-di-tertiary-butylhydroquinone, 2,5-di-tertiary Tripentylhydroquinone, 2,6-diphenylpiperidinyl phenol, 2,6-di-tertiary-butylhydroquinone, 2,5-di-tertiary-butylhydroxyanisole, 3 , 5-Di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl 4-hydroxyphenylstearate, bis (3,5-di-tert-butyl- 4-hydroxyphenyl) adipate. 1.4 · Tocopherols, such as breeding, / 9-bearing 15 This paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 male f) A7 1232246 V. Description of the invention (丨 f) Phenol, r- Tocopherols, tocopherols and mixtures (vitamin E). 1.5. A hydroxylated thiodiphenyl ether, such as 2,2, -thiobis (6-third-butyl-4-methylphenol), 2,2'-thiobis (4-octylphenol), 4,4'-thiobis (6-third butyl methylphenol), 4,4, -thiobis (6 · third butyl-2-methylphenol), 4,4'-thio Bis (3,6-di-second pentylphenol), 4,4'-bis (2,6-dimethyl-4-hydroxyphenyl) disulfide. 1.6. Alkylene bisphenols, such as 2,2, -methylenebis (6-thirdbutyl-4-methylphenol), 2,2'-methylenebis (6-thirdbutyl Ethylphenol), 2,2 '· methylenebis [4-methyl-6- (α-methylcyclohexyl) -phenol], 2,2'-methylenebis (4-methyl-6 -Cyclohexylphenol), 2,2'-methylenebis (6-nonyl-4-methylphenol), 2,2'-methylenebis (4,6-di-third-butylphenol) , 2,2'-ethylenebis (4,6-di-third-butylphenol), 2,2'-ethylenebis (6-third-butyl-4-isobutylphenol), 2 , 2, -methylenebis [6- (〇: -methylbenzyl) noronylphenol], 2,2'-methylenebis [6- (α, α-dimethylbenzyl) -4- Nonylphenol], 4,4'-methylenebis (2,6-di-third-butylphenol), 4,4'-methylenebis (6-third-butyl-2-methylphenol) ), 1,1-bis (5-third butyl-4-hydroxy-2-methylphenyl) butane, 2,6-bis (3-third butyl-5-methyl-2-hydroxy Benzyl) -4-methylphenol, 1,1,3 · tris (5-thirdbutyl-4-hydroxy_2_methylphenyl) butane, 1,1-bis (5-thirdbutyl 4-hydroxy-2-methylphenyl) n-dodecyl Butane, bis [3,3-bis (3'-thirdbutyl-4'-hydroxyphenyl) butyrate], bis (3-thirdbutyl-4-hydroxy-5- Methyl-phenyl) dicyclopentadiene, bis [2- (3, -third-butyl-2, -hydroxy-5, -methylbenzyl) -6-third-butyl-4-methylbenzene Group] terephthalate, ι, ΐ-bis- (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis (3,5-di-third-butyl- 4-Hydroxy 16 This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) ^ (Please read the precautions on the back before filling this page) -------- Order ---- -----% · 1232246 A7 __B7 _ 5. Description of the invention (K) Phenyl) propane, 2,2-bis (5-third butyl-4-hydroxy-2-methylphenyl) _4_ Diyl decyl butane, 1,1,5,5-tetrakis (5-third butyl-4-hydroxy-2-methylphenyl) pentane. 1 · 7_ · —〇: _, N- and S-benzyl compounds, such as 3,5,3 ', 5, tetra-third butyl-4,4'-dihydroxydibenzyl ether, 4-hydroxyl -3,5-Dimethylbenzylfluorenyl octadecyl ester, 4-hydroxy-3,5-di-tertiary butylbenzylfluorenyl tridecyl ester, tris (3.5-di-tertiary butyl) Hydroxybenzyl) amine, bis (4-third-butyl-3-hydroxy-2.6-dimethylbenzyl) dithioterephthalate, bis (3,5-di-third-butyl-4 -Hydroxybenzyl) sulfur, 3,5-di-tert-butyl-4-hydroxybenzylidene isooctyl acetate. 1.8. Hydroxybenzyl malonate, such as 2,2.bis (3, 5-Di-tertiarybutyl-2-hydroxybenzyl) dioctadecyl malonate, 2- (3-tertiarybutyl-4-hydroxy-5-methylbenzyl) malonate di-10 Octaester, 2,2 · bis (3,5-di-tertiarybutyl-4-hydroxybenzyl) malonate di-dodecyl chloroethyl, 2,2-bis (3,5-di -Third-butyl-4-hydroxybenzyl) malonate bis [4- (1,1,3,3-tetramethylbutyl) benzene] ester 1.9. Aromatic hydroxybenzyl compound, such as 1, 3,5-tris (3,5-di-tert-butyl-4-hydroxybenzyl) -2,4,6 · trimethylbenzene, 1,4-bis (3,5-di-tert-butyl -4 · hydroxybenzyl) -2,3,5,6- Methylbenzene, 2,4,6-tris (3,5-di - tert-butyl-4-hydroxybenzyl) phenol. 1.10. Triazine compounds, such as 2,4-bis (octylsulfanyl) -6- (3,5-di-third-butyl-4-hydroxyaniline) -1,3,5 · Triazine, 2-octylfluorenyl-4,6-bis (3,5-di-third-butyl-4-hydroxyaniline) -1,3,5-triazine :, 2-octyl Fluorenyl-4,6-bis (3,5-di-third-butyl-I-hydroxyphenoxy 17) This paper size applies to China National Standard (CNS) A4 (210 X 297 public love 1 ~ ------ ----------- (Please read the precautions on the back before filling this page)-A7 1232246 V. Description of the invention () ---------------- ( Please read the notes on the back before filling out this page) Base) -1,3,5-triazine :, 2,4,6-tri (3,5-di-tertiary-butylhydroxyphenoxy) 1,2,3-triazine, 1,3,5-tris (3,5-di-third-butyl-4-hydroxybenzyl) isocyanurate, 1,3,5-tris ( 4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate, 2,4,6-tris (3,5-di-tert-butyl-4-hydroxyphenyl) Ethyl) -1,3,5-triazine, 1,3,5-tris (3,5-di-third-butyl-4-hydroxyphenylpropanyl) -hexahydro-1,3, 5-triazine, 1,3,5-tris (3,5-dicyclohexyl-4-hydroxybenzyl) isocyanide 1 benzyl phosphonate, such as dimethyl 2,5-di-tert-butyl-4-hydroxybenzylphosphonic acid, 3,5 · di-tert-butyl benzylphosphonic acid bis Ethyl ester, 3,5-bis-tertiary-butyl-4-hydroxybenzylphosphonic acid di-octadecyl ester, 5-third butyl-4-hydroxy-3-methylbenzylphosphonic acid di-octadecyl ester Calcium salt of the monoethyl ester of 3,5-di-tertiary-butyl-4-hydroxybenzylphosphonic acid.% ΓΠ. 醯 A certain phenol, such as 4-hydroxylauryl aniline, 4-hydroxystearate醯 aniline, N- (3,5-di-tertiarybutyl-4-hydroxyphenyl) octyl carbamate. ΓΠ. Β- (3.5 · di-tertiarybutyl-4-hydroxybenzene) propyl Esters of acids with mono- or winter alcohols, such as with methanol, ethanol, n-octanol, isooctanol, stearyl alcohol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol Alcohol, 1,2-propylene glycol, 2,2-dimethylpropylene glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, isopentaerythritol, tris (hydroxyethyl) isocyanurate, N, Ν'-bis (hydroxyethyl) ethylenediamine, 3-thiaundecanol, 3-dipentadecanyl alcohol, trimethylhexylene glycol, trimethyl alcohol propane, 4-hydroxymethyl small phosphorus -2,6,7-Triple bicyclo [2 · 2 · 2] octane. 1.14. Β- (5- Tributyl-4-hydroxy-3-methylphenyl) propionic acid and mono-xia polyol esters, such as with methanol, ethanol, n-octanol, isooctanol, 18 This paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) A7 1232246 ____B7___ V. Description of the invention (^ ------ I--I ------ (Please read the precautions on the back before filling this page) Stearyl alcohol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, U-propylene glycol, 2,2-dimethylpropylene glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol Alcohol, isopentaerythritol, tris (hydroxyethyl) isocyanurate, N, N, -bis (hydroxyethyl) ethylenediamine, 3-thiaundecanol, 3-thiapentadecanyl alcohol , Trimethylhexylene glycol, trimethyl alcohol propane, 4-hydroxymethyl small phosphorus-2,6,7-tricyclic bicyclo [2.2.2] octane; 3,9-bis [2- {3- (3-Third-butyl-4-hydroxy-5-methylphenyl) propanyloxy) -U-dimethylethyl] -2,4,8,10-tetrapyrespiro [5.5] 11 alkyl. 1.15. Β- (3,5-dicyclohexyl-4-hydroxyammonium) propionic acid and mono- or poly-methyl ethers, such as with methanol, ethanol, octanol, stearyl alcohol, 1,6 -Hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, 2,2-dimethylpropanediol, thiodiethylene glycol, diethylene glycol, triethylene glycol, isopentaerythritol , Tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) ethylenediamine, 3-undecyl alcohol, 3-pentadecanyl alcohol, trimethylhexamethylene Alcohol, trimethyl alcohol propane, 4-hydroxymethyl-1-phospho-2,6,7-triamidinebicyclo [2.2.2] octane. 1.16. 3,5-Di-tert-butyl hydroxybenzene, acetic acid, and mono- or polyhydric alcohols / indoles, such as with methanol., Ethanol, octanol, stearyl alcohol, 1,6-hexanedione Alcohol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, 2,2-dimethylpropanediol, thiodiethylene glycol, diethylene glycol, triethylene glycol, isoprene tetraol, tri ( Hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) ethanediamine, 3-thiaundecanol, 3-thiapentadecanyl alcohol, trimethylhexanediol, trimethyl Methyl alcohol propane, 4-hydroxymethyl-1-phospho-2,6,7-triamidinebicyclo [2.2.2] octane. 1.17. Β · (3,5-di-tert-butyl-4-hydroxybenzene) propionate, such as N, N'-bis (3,5-di-tert-butyl-4 · Hydroxyphenylpropanyl) hexamethylenediamine, Ν, Ν'-bis (3,5-di-third-butyl-4-hydroxyphenylpropanyl) triine 19 This paper is for China National Standard (CNS) A4 specification (210 X 297 mm) A7 1232246 _______B7__ V. Description of the invention (β) ------------ β equipment—— (Please read the precautions on the back before filling This page) Methyldiamine, N, N'-bis (3,5-di-third-butyl-4-hydroxyphenylpropanyl), hydrazine, N, N, -bis [2- (3 -[3,5-Di-tert-butyl-4-hydroxyphenyl] propanyloxy) ethyl] ethanediamine (Naugard® XL-1 provided by Uniroyal). 1.18. Ascorbic acid (vitamin C) 1 "Q. Ammonium argonizing agents, such as N, N5-di-isopropyl-p-phenylene diamine, N, N'-di-second butyl-p- Phenylenediamine, N, N'-bis (1,4-dimethylpentyl) -p-phenylene diamine, N, N'-bis (L · ethyl-3-methylpentyl) ) -P-phenylene diamine, N, N'-bis (1-methylheptyl) -p-phenylene diamine, N, N'-dicyclohexyl-p-phenylene diamine, N, N'-diphenyl-p-phenylene diamine, N, N'-bis (2-naphthyl) -p-phenylene diamine, N-isopropyl-N'-phenyl- P-phenylene diamine, N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylene diamine, N- (1-methylheptyl) -N'- Phenyl-p-phenylene diamine, N-cyclohexyl-N'-phenyl-p-phenylene diamine, 4- (p-toluidinesulfonyl) diphenylamine, N, N ' -Dimethyl-N, N'-di · second-butyl-p-phenylene diamine, diphenylamine, N-allyl diphenylamine, 4-isopropoxydiphenylamine , N-phenyl-1-ylamine, N- (4-third octylphenyl) small naphthylamine, N-phenyl-2-naphthylamine, octyl alkylated diphenylamine; Such as ρ, ρ'-di-third-octyldiphenylamine, 4-n-butylaminophenol, 4-butylfluorenylaminophenol, 4-nonamylaminophenol, 4-dodecylamino Phenol, 4-octadecylaminophenol, bis (4-methoxyphenyl) amine, 2,6-di-third-butyl-4-dimethylaminomethylphenol, 2,4 ' -Diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, Ν, Ν, Ν ', N'-tetramethyl-4,4' · diaminodiphenylmethane, 1 , 2-bis [(2-methylphenyl) amino] ethane, 1,2-bis (phenylamino) propane, (o-A-20) This paper size applies to Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) A7 1232246 B7_ V. Description of the invention ((I) Phenyl) biguanide, bis [4_ (Γ, 3'-dimethylbutyl) phenyl] amine, third octyl N-phenyl-1-ylamine, mono- and dialkylated tertiary butyl / third octyldiphenylamine mixtures, mono- and dialkylated nonyldiphenylamine mixtures , A mixture of mono- and dialkylated dodecyldiphenylamine, a mixture of mono- and dialkylated isopropyl / isohexyldiphenylamine, -And dialkylated third butyldiphenylamine, 2,3-dihydro-3,3-dimethyl-4H-M-benzothiazine, phenothiazine, Mono- and Di-Alkylated Tertiary Butyl / Third Octyl Phorphine Mixtures, Mono- and Di-Alkylated Tertiary Octyl Phorphine-Mixtures, N-Allyl Phoromide 1, Team ^ &Quot; '-tetraphenyl-1,4-diaminobut-2-ene, bis (2,2,6,6-tetramethylpiperidin-4-yl) -hexamethylene Diamine, bis (2,2,6,6-tetramethylpiperidine-4 · yl) sebacate, 2,2,6,6-tetramethylpiperidine-4 · one, 2,2, 6,6-tetramethylpyridin-4-ol. 2. Chai external light absorber and light stabilizer 2 丄 2- (2'-hydroxybenzene) benzotriazole, such as 2- (2, hydroxy-5'-methylphenyl) benzotriazole, 2- (3 ', 5'-Di-third-butyl-2'-hydroxyphenyl) benzotriazole, 2- (5'-third-butyl-2'-hydroxyphenyl) benzotriazole, 2- ( 2'_hydroxy-5'- (1,1,3,3-tetramethylbutyl) phenyl) benzotriazole, 2- (3,5, -di-tertiarybutyl-2'- Hydroxyphenyl) -5-chlorobenzotriazole, 2- (3'-third butyl_2'_hydroxy-5'-methylphenyl) -5-chlorobenzotriazole, 2- (3 '-Second-butyl-5'-Third-butyl-2'-hydroxyphenyl) benzotriazole, 2- (2, -Ethyl-4'-octyloxyphenyl) benzotriazole, 2- (3 ', 5'_di-tertiarypentyl-2'-hydroxyphenyl) benzotriazole, 2- (3', 5'-bis (α, α-dimethylbenzyl) -2 , · Hydroxyphenyl) benzotriazole, 2- (3'-third butyl-2'-hydroxy-5,-(2-octyloxycarbonylethyl) 21 --------- ------- (Please read the precautions on the back before filling this page) · · This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) A7! 232246 —___ 21- V. hair Instructions (W) ------------- · 11 (Please read the notes on the back before filling this page) Phenyl) -5-chlorobenzotriazole, 2- (3, -Third butyl-5 '-[2- (2-ethylhexyloxy) carbonylethyl] -2'-hydroxyphenyl) -5-chlorobenzotriazole, 2- (3'-third Butyl-2'-hydroxy-5'- (2-methoxycarbonylethyl) phenyl) -5-chlorobenzotriazole, 2- (3, -tertiarybutyl-2 '· hydroxy-5 '-(2-methoxycarbonylethyl) phenyl) benzotriazole, 2- (3, -third-butyl-2'-hydroxy-5'-(2-octyloxycarbonylethyl) benzene Group) benzotriazole, 2- (3'-third butyl-5 '-[2- (L ethylhexyloxy) carbonylethyl] -2'-hydroxyphenyl) benzotriazole, 2 -(3'-dodecyl-2'-hydroxy-5'-methylphenyl) benzotriazole, 2 · (3, -third butyl-2'-hydroxy-5'- (2-iso Octyloxycarbonylethyl) phenyl) benzotriazole, 2,2'-methylenebis [4- (1,1,3,3-tetramethylbutyl) -6-benzotriazole- 2-ylphenol]; 2- [3'-third butyl · 5'- (2-methoxycarbonylethyl) -2'-hydroxyphenyl] -2fluorene-benzotriazole and polyethylene glycol 300 transesterification products; R-CH2CH2-—C〇〇-CH2CH2—] 2, where R = 3'-third butyl-4, acyl-5'-2H-benzotriazol-2-ylphenyl, 2- [2 ' -Hydroxy-3'- (α, -dimethylbenzyl) -5'- (1,1,3,3-tetramethylbutyl) phenyl] -benzotriazole; 2- [2'-hydroxy -3'- (1,1,3,3-tetramethylbutyl) -5 '-(α, -dimethylbenzyl) phenyl] -benzodi mile. 2.2. 2-Hydroxybenzophenone, such as 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2 Derivatives of ', 4'-trihydroxy and 2'-hydroxy-4,4'-dimethoxy. _2J • Esters of substituted and unsubstituted benzoic acids, such as 4-tert-butylphenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzylfluorenyl resorcinol, bis (4 -Third-butylfluorenyl) resorcinol, 3,5-di-tertiary-butyl-4-hydroxybenzoic acid 2,4-di-third-butylphenyl ester, 3,5-di-th Tributyl-4- 22 This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) 1232246 B7 V. Description of the invention (yp -------------- --- (Please read the precautions on the back before filling this page) Hexadecyl hydroxybenzoate, Stearyl 3,5-di-third-butyl-4-hydroxybenzoate, 3,5-Di-section Tributyl hydroxybenzoic acid 2-methyl-4,6-di · tertiary butyl phenyl ester M. Acrylates such as α-cyano-β, β-diphenylethyl acrylate, α-cyano Isooctyl-β, β-diphenylacrylate, α-carboxymethoxyphenylpropanoic acid methyl ester, α-cyano-β-methyl-p-methoxyphenylacrylate, α-cyano -Methyl-p-methoxyphenyl acrylate, α-carboxymethoxy-p-methoxyphenyl acrylate, and N- (β-carboxymethoxy-β-cyanovinyl ) 2-Methyl D group II. 2.5. Town compounds such as 2,2'-thiobis [4- (1,1,3,3-tetramethylbutyl) phenol] and others like n-butyl Ligand, triethanolamine, or N-cyclohexyldiethanolamine or no other ligands, such as 1: 1 or 1: 2 nickel complex, nickel dibutyldithiocarbamate Salts, such as nickel salts of monoalkyl esters of methyl or ethyl esters of 4-hydroxy-3,5-di-tert-butylbenzylphosphonic acid, such as 2-hydroxy-4-methylphenyldeca Nickel complexes of monoketoxime and ketoxime, such as nickel complexes of 1-phenyl-4-lauryl-5-hydroxypyrazole with other ligands or without other ligands. 2.6. Hindered amines, such as bis (2,2,6,6-tetramethyl-4-nonidinyl) sebacate, bis (2,2,6,6-tetramethylpiperidinyl) butane Acid ester, bis (1,2,2,6,6-pentamethyl-4-tonidyl) sebacate, bis (μoctyloxy-2,2,6,6-tetramethyl-4 -P-pyridinyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-nonidinyl) n-butyl-3,5-di-tert-butyl-4- Condensation of hydroxybenzyl malonate, 10-hydroxyethyl) -2,2,6,6-tetramethyl-4-hydroxymorphine and succinic acid Compound, Ν, Ν'-bis (2,2,6,6-tetramethyldotonidyl) hexamethylenediamine and 4-th 23rd paper This paper is applicable to China National Standard (CNS) A4 specifications ( 210 X 297 mm) 1232246 A7 ____B7___ 5. Description of the Invention (yV) ---------------- (Please read the precautions on the back before filling this page) Trioctylamino Straight-chain or cyclic condensates of -2,6-dichloro-1,3,5-triazine, tris (2,2,6,6-tetramethyl-4-piperidinyl) azinetriethyl Acid ester, tetra (2,2,6,6-tetramethyl-4-meridinyl) -1,2,3,4-butane tetracarboxylic acid ester, 1,1'- (1,2-ethyl Alkyl diyl) -bis (3,3,5,5 · tetramethylmorphinone), 4-benzylfluorenyl-2,2,6,6-tetramethylmorphine, 4-stearylmethyloxanyl -2,2,6,6-tetramethylammonium, bis (1,2,2,6,6-pentamethylmeridinyl) -2-n-butyl-2- (2-hydroxy-3 , 5-di-tertiary-butylbenzyl) -malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triaziro [4.5] decane -2,4-diketone, bis (1-octyloxy-2,2,6,6-tetramethylmorphinyl) sebacate, bis (1-octyloxy-2,2,6, 6-tetramethylpiperidinyl) succinate, N, N'-bis (2,2,6,6-tetramethyl-4-nonidinyl) Linear or cyclic condensate of methylenediamine and 4-morpholinyl-2,6-dichloro-1,3,5-triazine, 2-chloro-4,6 · bis (4- Condensate of n-butylamino-2,2,6,6-tetramethylmeridinyl) -1,3,5-triazine and U-bis (3-aminopropylamino) ethane , 2-chloro-4,6-bis (4-n-butylamino-1,2,2,6,6-pentamethylpyridinyl) -1,3,5-triazine and 1,2 -Condensate of bis (3-aminopropylamino) ethane, 8-acetamido-3-dodecyl-7,7,9,9-tetramethyl-1,3,8 · triazine Spiro [4.5] decane-2,4-dione, 3-dodecyl-1- (2,2,6,6-tetramethylpiperidinyl) pyrrolidine-2,5-dione, 3-Dodecyl (1,2,2,6,6-pentamethyl-4-pyridinyl) pyrrolidine-2,5-dione, 4-hexadecyloxy, and 4-stearyl hydrazone A mixture of oxy-2,2,6,6-tetramethylmidine, N, N'-bis (2,2,6,6-tetramethyl-4-meridinyl) hexamethylene di Condensate of amine and 4-cyclohexylamino-2.6-dichloro-1,3,5-triazine, 1,2-bis (3-aminopropylamino) ethane and 2,4,6 -Condensate of trichloro-1,3,5-triazine, and 4-butylamino-2,2,6,6-tetramethylpiperidine (CAS Reg · Νο · [136504-96-6 ]); 1,6-hexane Amine and 2,4,6 · trichloro-1,3,5-triazine, and Ν, Ν- 二 -24 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1232246 A7 — ^ ____ B7 V. Description of the invention (yj) Condensate of butylamine and 4-butylamino-2,2,6,6-tetramethyluridine (CAS Reg. No. [192268-64-7 ]); N- (2,2,6,6-tetramethyl-4_eridinyl) -n-dodecylsuccinimide, N- (1,2,2,6,6-pentamethyl -4_methylenepyridyl) -n-undecylbutanediimine, 2- ~ f- ^ yl_7,7,9,9_tetramethyl small pin-3,8-dikouya-4 -Keto-spiro [4.5] decane, 7,7,9,9-tetramethyl-2-cycloundecyl-1-an-3,8-diaz-4-ketospiro- [4.5] Reaction product of decane and epichlorohydrin, U-bis (1,2,2,6,6-pentamethyl-4-eridyloxycarbonyl) -2- (4 · methoxybenzene Group) ethylene, N, N'-bis-formamyl group · N, N'_bis (2,2,6,6-tetramethyl-4-nonidyl) hexamethylenediamine, 4-formyl The diester of oxymethylenemalonic acid and 1,2,2,6,6-pentamethyl piperidine, poly [methylpropyl-3-oxy-4_ (2,2,6, 6-tetramethylpyridinyl)] Siloxane, maleic anhydride-1 olefin Was the reaction product of an amine with 2,2,6,6-tetramethyl-4-piperidinyl or 1,2,2,6,6-pentamethyl-4-piperidine amine in it. 2J. Ethylenediamine, such as 4,4'-dioctyloxypyrrolidine, 2,2'-diethoxypyrrolidine, 2,2'-dioctyloxy-5,5 ' -Di-tertiary butylicidamine, 2,2'-di · dodecyloxy-5,5'-di-tertiary butylicidamine, 2-ethoxy-2 '· ethyl Chlorfendibenzidine, Ν, Ν'-bis (3-dimethylaminopropyl) ethylenediamine, 2-ethoxy-5-tertiarybutyl-2'-acetochlor, and its Mixtures with 2-ethoxy-2'-ethyl-5,4'-di-tert-butyrolidin, mixtures of o- and p-methoxy-disubstituted sulfenil, and o- -And a mixture of p-ethoxy-disubstituted oxadiazine. 2 · 8 · 2- (2-hydroxybenzene) -1 · 3,5-triazine, such as 2,4,6-tris (2-hydroxy-4-octyloxyphenyl) -1,3, 5-triazine, 2- (2-hydroxy-4-octyloxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2 -(2,4-Dihydroxy 25 This paper size is applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 public love) (Please read the precautions on the back before filling out this page) n -ϋ i_i n 一 -OJe I nn ϋ n ϋ A7 1232246 ___ B7____ 5. Description of the invention) Phenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2,4-bis ( 2-hydroxy-4-propyloxyphenyl) -6- (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxybenzyloxyphenyl) ) -4,6-bis (4-methylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4 · dodecyloxyphenyl) -4,6-bis ( 2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4-tridecyloxyphenyl) -4,6-bis (2,4-bis Methylphenyl) -1,3,5-triazine, 2- [2-hydroxy-4- (2-hydroxy-3-butyloxypropoxy) phenyl] -4,6-bis ( 2,4-dimethyl) -1,3,5-triazine, 2- [2-hydroxy-4- (2-hydroxy-3 · octyloxy Alkoxy) phenyl] -4,6-bis (2,4-dimethyl) -1,3,5-triazine, 2- [4- (dodecyloxy / tridecyloxy -2-hydroxypropoxy) -2-hydroxyphenyl] -4,6-bis (2,4-dimethylphenyl) -1,3,5_triazine, 2- [2-hydroxy- 4- (2-hydroxy-3-dodecyloxypropoxy) phenyl] -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2 -(2-hydroxy-4-hexyloxy) phenyl-4,6-diphenyl-1,3,5-triazine, 2- (2-hydroxyglacialmethoxyphenyl) -4,6 -Diphenyl-1,3,5-triazine, 2,4,6-tri [2-hydroxy- (3-butoxy-2-hydroxypropoxy) phenyl] -1,3,5 -Triazine, 2- (2-hydroxyphenyl) -4- (4-methoxyphenyl) -6-phenyl-1,3,5-triazine, 2- {2-hydroxy bucket [ 3 · (2-ethylhexyl-1-oxy) -2-hydroxypropyloxy] phenyl} -4,6-bis (2, cardiodimethylphenyl) _1,3,5-triazine Plow. 3. Metal deactivator, such as N, N'-diphenylethylenediamine, N-salicylaldehyde-N'-salicylhydrazine, N, N'_bis (salicyl) hydrazine, N , N'-bis (3,5-di-tert-butylpiperidinopropylpropylhydrazine) hydrazine, 3-salicylaminoamino-1,2,4-triazole, bis (benzylidene) ethyl Difluorenyldihydrazine, chlorhexidine, isopeptylfluorenyldihydrazine, decanedipylbisphenylhydrazine, 26 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---------------- (Please read the notes on the back before filling this page) -C-0. A7 1232246 V. Description of the invention (/) N, N,-Diethyl Fluorenylhexamethylene dihydrazide, n, n'-bis (salicyl) hydrazine dihydrazine, N, N'-bis (salicyl) thiopropylhydrazine difluorene. ------------ Reduction—— (Please read the precautions on the back before filling this page) 4_ Ester and phosphinate, such as triphenyl phosphite, diphenyl phosphite Alkyl ester, phenyldialkyl phosphite, tris (nonylphenyl) phosphite, trilauryl phosphite, tri-octadecyl phosphite, distearyl isopropyltetraol diphosphite, Tris (2,4-di-third-butylphenyl) phosphite, diisodecyl isopentaerythritol diphosphite, bis (2,4-di-third-butylphenyl) diphosphite Isopentaerythritol ester, bis (2,4-di-anisylphenyl) diphosphite, bis (2,6-di-third-butyl-4-methylphenyl) diphosphite ) Isopentaerythritol ester, diisodecyloxy isopentaerythritol diphosphite, bis (2,4-di-third-butyl-6-methylphenyl) isopentaerythritol diphosphite Bis (2,4,6_tri (third butylphenyl) isopentaerythritol diphosphite, tristearyl sorbitan triphosphite, tetra (2,4-di -Third-butylphenyl) -4,4'-biphenylene ester, 6-isooctyloxy-2,4,8,10 · tetra-third-butyl-12H-diphenyl [dg]- l, 3,2-dioxa Phosphocin, bis (2,4-di-third-butyl-6-methylphenyl) methyl phosphite, bis (2,4-di-third-butyl-6-methyl) phosphite Phenyl) ethyl ester, 6-fluoro-2,4,8,10-tetra-tert-butyl-12-methyl-diphenyl [dg] -1,3,2-dioxaphosin ( phosphocin), 2,2 ', 2' '-nitrogen [triethyl phosphite-tris (3,3', 5,5'-tetra-third-butyl-1,1'biphenyl-2,2 '-Diyl) ester], 2-ethylhexyl phosphite (3,3', 5,5'_tetra-third-butyl-1,1'biphenyl-2,2'-diyl) ester, 5-butyl-5-ethyl-2- (2,4,6-tri-tert-butylphenoxy) -1,3,2-dioxirane. The following phosphorous acid Esters are preferred: Tris (2,4-di-tert-butylphenyl) phosphite (Irgafos® 168, 27) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1232246 A7 B7 V. Description of Invention (* / ί)

Ciba-Geigy)、亞磷酸三（壬基苯基）酯 ㈧Ciba-Geigy), tris (nonylphenyl) phosphite ㈧

(B)(B)

(C) ----------------- (請先閱讀背面之注意事項再填寫本頁) 訂· (ch3)3c-^^—。一 C(CH3)3 (ch3)3c(C) ----------------- (Please read the notes on the back before filling this page) Order (ch3) 3c-^^ —. 1 C (CH3) 3 (ch3) 3c

ch3ch3

H，CH, C

C(CH3)3 (CH3)3C、 (E) ’。彳XV。 ο—7 ^-0C (CH3) 3 (CH3) 3C, (E) '.彳 XV. ο—7 ^ -0

C(CH3)3 (CH3)3C 0—\' /—0 (F) H37CiT~0—P、 X 0 —C18H37C (CH3) 3 (CH3) 3C 0— \ '/ —0 (F) H37CiT ~ 0—P, X 0 —C18H37

-p—och2ch3 (G) 28 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐〉 A7 1232246 __ B7___ 五、發明說明（V^) --------------裝--- (請先閱讀背面之注意事項再填寫本頁) 5. 經胺，例如N，N-二苄基羥胺、N，N-二乙基羥胺、Ν，Ν·二 辛基羥胺、Ν，Ν-二月桂基羥胺、Ν，Ν-二-十四基羥胺、Ν，Ν-二-十六基羥胺、Ν,Ν-二-十八基羥胺、Ν-十六基-Ν-十八基 羥胺、Ν-十七基十八基羥胺，從氫化牛脂胺（tallow amine)所衍生之N，N-二烷基羥胺。 6. 硝酮，例如N-苄基_α-苯基硝酮、N-乙基-α-甲基硝酮、 Ν_辛基-α-庚基硝酮、Ν-月桂基-α-十一基硝酮、Ν-十四基-α-十三基硝酮、Ν-十六基-α-十五基硝酮、Ν-十八基-α-十七 基硝酮、Ν-十六基-α-十七基硝酮、Ν-十八基-α·十五基硝 酮、Ν-十七基-α-十七基硝酮、Ν-十八基-α-十六基硝酮， 從氫化牛脂胺所衍生之Ν，Ν-二烷基羥胺所衍生的硝酮。 7·硫基增效劑（Thiosvnergists)，例如硫基二丙酸二月桂酯 或硫基二丙酸二硬脂酯。 8. 過氧化物淨化劑(Peroxide scavengers)，伊!ί如冷-硫疏基 二丙酸的酯類，例如月桂酯、硬脂酯、十四烷酯或十三烷 酯，锍基苯并咪唑或2-锍基苯并咪唑的鋅鹽、二丁基二锍 基胺基甲酸鋅鹽、二硫二-十八烷、丙酸異戊四醇-四（β-十 二基酼基)酯。 9. 聚醯胺穩定劑，例如與碘和/或磷化合物組合之銅鹽，以 及二價錳的鹽。 10. 鹼性共穩定劑，例如蜜胺、聚乙烯吡咯烷酮、雙氰胺、 三烯丙基氰脲酸酯、尿素衍生物、胼衍生物、胺、聚醯胺 、聚胺基甲酸酯、較高脂肪酸的鹼金屬鹽及鹼土金屬鹽， 例如硬脂酸銘、硬脂酸鋅、山俞酸鎂（magnesium behenate 29 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1232246 A7 ____B7__ 五、發明說明（7f) )、硬脂酸鎂、蓖麻醇酸鈉（sodi腿ricinoleate)和軟脂酸 鉀（potassium palmitate)、鄰苯二酌銻或鄰苯二酸鋅。 11·核化劑（nucleating agent)，例如無機物質，像是滑石 ，像是二氧化鈦或氧化鎂之金屬氧化物，較佳是鹼土金屬 之磷酸鹽、碳酸鹽或硫酸鹽；有機化合物，像是單-或多羧 酸及其鹽類，例如4-第三丁基苯甲酸、己二酸、二苯基乙 酸、丁二酸鈉或苯甲酸鈉；聚合化合物，像是離子性共聚 物（離聚物）。尤其佳爲1，3 : 2,4-雙（3’，4’_二甲基苯亞甲 基）山梨糖醇、1，3 : 2,4-二（對-甲基二苯亞甲基）山梨糖 醇和1，3 : 2,4-二（苯亞甲基）山梨糖醇。 12. 塡充劑和增強劑，例如碳酸鈣、矽酸鹽、玻璃纖維、玻 璃燈泡、石棉（asbestos)、滑石（talc)、高嶺土（kaolin )、雲母（mica)、硫酸鋇、金屬氧化物和氫氧化物，碳 黑、石墨、木粉（wood flour)和其他天然產物之粉末或纖 維，合成纖維。 13. 其他添加劑_，例如塑化劑、潤滑劑、乳化劑、顏料、流 變添加劑、催化劑、流量控制劑、螢光增白劑（optical brighteners)、耐火劑、助抗靜電劑和發泡劑。 14·苯并映喃酮（Benzofuranones)和明丨除酮（indolinone 1，例如在 U.S. 4,325,863 ; U.S. 4,338,244 ; U.S. 5，175,312 ；U.S. 5,216,052 ； U.S. 5,252,643 ； DE-A-4316611 ； DE-A-4316622 ; DE-A-4316876 ; EP-A-0589839 或 EP-A-0591102 所 揭示的，或是3-〔4- (2-乙醯氧基乙氧基）-苯基〕_5,7_二-第三丁基-苯并呋喃-2-酮，5,7-二-第三丁基-3-〔4- (2-硬脂 30 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------------裝--- (請先閱讀背面之注意事項再填寫本頁) 15J· A7 1232246 五、發明說明（> ) 醯基氧基乙氧基）-苯基〕-苯并呋喃-2-酮，3,3’-雙〔5,7-二 -第三丁基-3- (4-〔2-羥基乙氧基〕-苯基）苯并呋喃-2-酮 〕，5,7-二-第三丁基-3- (4-乙氧基苯基）苯并呋喃-2-酮， 3- (4-乙醯氧基-3,5-二甲基苯基）-5,7-二-第三丁基苯并呋 喃-2-酮，3- (3,5-二甲基-4-三甲基乙醯基氧基苯基）-5,7-二-第三丁基苯并呋喃-2-酮，3- (3,4-二甲基苯基）-5,二-第三丁基苯并呋喃-2-酮，3- (2,3-二甲基苯基）-5,7-二-第 三丁基-苯并呋喃-2-酮。 本發明的進一步主題是一種製造織造抗靜電可撓性中 間體容器之方法，包含有：將聚醚酯醯胺、聚酯-醚嵌段共 聚物或含有聚醚酯醯胺或聚酯-醚嵌段共聚物之抗靜電組成 物摻和於聚烯烴纖維或紗條中作爲抗靜電添加劑，以及在 編織該織造物中使用該聚烴纖維或紗條來至少部分作爲經 紗線和/或緯紗線。 本發明的再進一步主題是使用聚醚酯醯胺、聚酯-醚嵌 段共聚物或含有聚醚酯醯胺或聚酯-醚嵌段共聚物之抗靜電 組成物作爲抗靜電添加劑，來製造織造抗靜電可撓性中間 體容器，其包括將其摻和於聚烯烴纖維或紗條中，並且至 少部份將該聚烯烴纖維或紗條編織於織造物中作爲經紗線 和/或緯紗線。 上面所賦予之定義及參考資料亦應用於方法及利用。 下列的實施例說明本發明。 織造物：200 g/m2，由Debant，Turkey所製造的-p—och2ch3 (G) 28 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) A7 1232246 __ B7___ V. Description of the invention (V ^) ----------- --- Pack --- (Please read the notes on the back before filling this page) 5. Amine, such as N, N-dibenzylhydroxylamine, N, N-diethylhydroxylamine, N, N · dioctyl Hydroxylamine, N, N-dilaurylhydroxylamine, N, N-di-tetradecylhydroxylamine, N, N-di-hexadecylhydroxylamine, N, N-di-octadecylhydroxylamine, N-hexadecyl -N-octadecylhydroxylamine, N-heptadecyloctadecylhydroxylamine, N, N-dialkylhydroxylamine derived from hydrogenated tallow amine. 6. Nitrones, such as N-benzyl_α -Phenyl nitrone, N-ethyl-α-methyl nitrone, N-octyl-α-heptyl nitrone, N-lauryl-α-undecyl nitrone, N-tetradecyl-α -Tridecyl nitrone, N-hexadecyl-α-pentadecyl nitrone, N-octadecyl-α-heptadecyl nitrone, N-hexadecyl-α-heptadecyl nitrone, N -Octadecyl-α · pentadecyl nitrone, N-heptadecyl-α-heptadecyl nitrone, N-octadecyl-α-hexadecyl nitrone, N derived from hydrogenated tallow amine, Derived from N-dialkylhydroxylamine Nitrones. 7. Thiosvnergists, such as dilauryl thiodipropionate or distearyl thiodipropionate. 8. Peroxide scavengers, Yi! Cold-thiothiodipropionic acid esters, such as lauryl, stearyl, tetradecyl or tridecyl esters, zinc salts of fluorenylbenzimidazole or 2-fluorenylbenzimidazole, dibutyl Zinc diamidocarbamate, dithiodi-octadecane, isopentaerythritol-tetrakis (β-dodecylfluorenyl) propionate 9. Polyamine stabilizers, such as with iodine and / or Copper salts of combinations of phosphorus compounds and salts of divalent manganese. 10. Basic co-stabilizers such as melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, osmium derivatives , Amines, polyamides, polyurethanes, alkali metal salts and alkaline earth metal salts of higher fatty acids, such as magnesium stearate, zinc stearate, magnesium behenate (magnesium behenate 29 This paper applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1232246 A7 ____B7__ V. Description of the invention (7f)), magnesium stearate, sodium ricinoleate (so diricinoleate) and potassium palmitate, antimony phthalate, or zinc phthalate. 11. Nucleating agents, such as inorganic substances, such as talc, such as titanium dioxide or magnesium oxide Metal oxides, preferably phosphates, carbonates or sulfates of alkaline earth metals; organic compounds, such as mono- or polycarboxylic acids and their salts, such as 4-tert-butylbenzoic acid, adipic acid, Diphenylacetic acid, sodium succinate or sodium benzoate; polymeric compounds such as ionic copolymers (ionomers). Particularly preferred are 1,3: 2,4-bis (3 ', 4'-dimethylbenzylidene) sorbitol, and 1,3: 2,4-bis (p-methyldiphenylmethylene) ) Sorbitol and 1,3: 2,4-bis (benzylidene) sorbitol. 12. Radon fillers and enhancers, such as calcium carbonate, silicates, fiberglass, glass bulbs, asbestos, talc, kaolin, mica, barium sulfate, metal oxides, and Hydroxides, powders or fibers of carbon black, graphite, wood flour and other natural products, synthetic fibers. 13. Other additives_, such as plasticizers, lubricants, emulsifiers, pigments, rheological additives, catalysts, flow control agents, optical brighteners, refractory agents, auxiliary antistatic agents and foaming agents . 14. Benzofuranones and indolinone 1, such as in US 4,325,863; US 4,338,244; US 5,175,312; US 5,216,052; US 5,252,643; DE-A-4316611; DE-A-4316622; DE-A-4316876; as disclosed in EP-A-0589839 or EP-A-0591102, or 3- [4- (2-ethoxyethoxy) -phenyl] -5,7_di-section Tributyl-benzofuran-2-one, 5,7-di-tert-butyl-3- [4- (2-stearin 30) This paper size applies to China National Standard (CNS) A4 (210 X 297 (Mm) ------------- Packing --- (Please read the notes on the back before filling this page) 15J · A7 1232246 V. Description of the invention (>) (Oxy) -phenyl] -benzofuran-2-one, 3,3'-bis [5,7-di-third-butyl-3- (4- [2-hydroxyethoxy] -phenyl ) Benzofuran-2-one], 5,7-di-tert-butyl-3- (4-ethoxyphenyl) benzofuran-2-one, 3- (4-acetamido- 3,5-dimethylphenyl) -5,7-di-third-butylbenzofuran-2-one, 3- (3,5-dimethyl-4-trimethylethylfluorenyloxy Phenyl) -5,7-di-tert-butylbenzofuran-2-one, 3- (3, 4-dimethylphenyl) -5, di-third-butylbenzofuran-2-one, 3- (2,3-dimethylphenyl) -5,7-di-third-butyl- Benzofuran-2-one. A further subject of the present invention is a method for manufacturing a woven antistatic flexible intermediate container, comprising: polyetheresteramide, a polyester-ether block copolymer or a polyether The antistatic composition of esteramine or polyester-ether block copolymer is blended into polyolefin fibers or sliver as an antistatic additive, and the polyalkylene fiber or sliver is used to weave the woven fabric to at least partially As warp and / or weft yarns. A further subject of the present invention is the use of polyetheresteramides, polyester-ether block copolymers or resistances containing polyetheresteramides or polyester-ether block copolymers. An electrostatic composition is used as an antistatic additive to manufacture a woven antistatic flexible intermediate container, which comprises blending it into a polyolefin fiber or sliver, and at least partially weaving the polyolefin fiber or sliver into a woven fabric. It is used as warp and / or weft yarns. The definitions and references given above also apply to methods and uses. Example embodiments of the present invention described column wovens:. 200 g / m2, manufactured by the Debant, Turkey's

聚丙烯：型式：F401-Z 31 --------------裝—— (請先閱讀背面之注意事項再填寫本頁) · 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） A7 !232246 ^_B7_ 五、發明說明（ ---------I------ (請先閱讀背面之注意事項再填寫本頁) 製造商：PolskiKancernNaftowyORLENSA，Poland 在經紗線中每四條纖維包括以15重量％之IrgastatP18 在緯紗線中每四條纖維包括15重量％之Irgastat P18 Irgastat® P18 和 Irgastat® P22 是從 Ciba Specialty Chemicals Inc.商業上可得到之抗靜電添加劑。 緯紗線 型式 丹尼爾denier 寬度mm 厚度# m 標準型 1279 3 51 15% P18 1292 2.95 59 經紗; 線 型式 丹尼爾denier 寬度mm 厚度// m 標準型 1778 3.05 71 15% P18 1924 2.95 77 織造物組織：Stahlinger型織物 一面（內部）以25°/。P22塗佈，20g/m2 樹脂型式 PP 製造商 Elenac Polyethylene, Deutschland 名稱 Lupolen 2424 HK 型式號碼 2426 H MFI (gr/102) 1.88 試驗：根據1996年之VDI報告編號1272來進行放電 試驗，結果示於表1中。 32 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公 1232246 A7 ___B7 五、發明說明（γΐ) 表1 試驗編號 抗靜電設備 結果 1控制 無Irgastat之上面織造物 > 100 nC 2 具有 15% Irgastat P18 之 上面織造物 <30 nC，無法將易燃的 丙烷/空氣混合物點火 3 具有 15% Irgastat P18 且 內部以 25 % Irgastat P22 塗佈之上面織造物 <30 nC，無法將易燃的 丙烷/空氣混合物點火 該灼燒試驗進一步描述於例如：在Journal of Electrostatics, 30 (1993)，115-122，以及在 Inst· Phys. Conf. Ser· No. 143,第121-124頁；在1995年四月2-5日之第九 屆Electrostatics國際會議上所提出。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------------i I (請先閱讀背面之注意事項再填寫本頁) 訂-·Polypropylene: Type: F401-Z 31 -------------- Loading—— (Please read the precautions on the back before filling this page) · This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) A7! 232246 ^ _B7_ V. Description of the invention (--------- I ------ (Please read the precautions on the back before filling this page) Manufacturer : PolskiKancernNaftowyORLENSA, Poland Every four fibers in the warp yarn include 15% by weight of IrgastatP18 Every four fibers in the weft yarn include 15% by weight of Irgastat P18 Irgastat® P18 and Irgastat® P22 are commercially available from Ciba Specialty Chemicals Inc. Antistatic additive obtained. Weft yarn type Daniel denier width mm thickness # m standard type 1279 3 51 15% P18 1292 2.95 59 warp yarn; linear type Daniel denier width mm thickness // m standard type 1778 3.05 71 15% P18 1924 2.95 77 Weaving structure: one side (inside) of Stahlinger type fabric is coated at 25 ° /. P22, 20g / m2 resin type PP manufacturer Elenac Polyethylene, Deutschland name Lupolen 2424 HK type number 2426 H MFI (gr / 102) 1.88 test: The discharge test was performed according to the VDI Report No. 1272 of 1996, and the results are shown in Table 1. 32 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 public 1232246 A7 ___B7 V. Description of the invention (γΐ) Table 1 Test No. Antistatic Equipment Result 1 Control top fabric without Irgastat > 100 nC 2 top fabric with 15% Irgastat P18 < 30 nC, unable to ignite flammable propane / air mixture 3 with 15% Irgastat P18 and The upper woven fabric coated with 25% Irgastat P22 < 30 nC, unable to ignite a flammable propane / air mixture. The ignition test is further described in, for example, Journal of Electrostatics, 30 (1993), 115-122, And presented at Inst. Phys. Conf. Ser. No. 143, pp. 121-124; presented at the Ninth Electrostatics International Conference, April 2-5, 1995. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------- i I (Please read the precautions on the back before filling this page) Order-·

Claims (1)

46 2 2 3 2 3988)8 ABCD 六、申請專利範圍 ^一種織造抗靜電可撓性中間體容器（FIBC)，其包 括含有7% -30% (基於聚丙烯重量）之抗靜電組成物之聚 丙嫌纖維或紗條，該抗靜電組成物包括 (bl)爲纖維狀或形成纖維混合並且不溶解於該聚烯 烴基質的有機聚合性材料，其是選自聚丙烯酸酯、聚甲基 丙烯酸酯、聚丙烯腈、聚乙烯醇、聚乙酸乙烯酯、聚醯胺 、聚胺基甲酸酯或聚酯所組成之族群中； (b2)聚醚酯醯胺或聚酯_醚嵌段共聚物；以及 (b3)選自 LiCICU、LiCF3S〇3、NaCl〇4、LiBF4、NaBF4 、KBF4、NaCFsSCb、KC1〇4、KPF6、KCFsSCb、KC4F9S〇3、 Ca(Cl〇4)2、Ca(PF6)2、Mg(Cl〇〇2、Mg(CF3S〇3；h 、Zn(Cl〇〇2 、Zn(PF〇2或Ca(CF3S〇3)2所組成之族群的鹽，其已錯合或 溶合於該聚醚酯醯胺或聚酯·醚嵌段共聚物（b2)中； 其中至少每20條經紗線和/或緯紗線包含該抗靜電組 成物。 2. 如申請專利範圍第1項之織造抗靜電可撓性中間體 容器，其在該內部和/或外部表面上，具有塗層，在基於該 塗層的固體重量下含有7% -30%份量之該抗靜電添加劑。 3. 如申請專利範圍第1項之織造抗靜電可撓性中間體 容器，其中由聚烯烴薄膜所製成的內袋被鬆開的或是部份 固定在該繊造物上’並且包含該抗靜電添加劑° 4. 如申請專利範圍第1項之織造抗靜電可撓性中間體 容器，其中該抗靜電添加劑是連續纖維形式的混合物，該 混合物包含： 1 格(2. 297 公愛) (請先閲讀背面之注意事項再塡寫本頁)46 2 2 3 2 3988) 8 ABCD VI. Application for Patent ^ A woven antistatic flexible intermediate container (FIBC), which includes polypropylene containing 7% to 30% (based on polypropylene weight) of an antistatic composition Suspicious fibers or slivers, the antistatic composition includes (bl) a fibrous or fiber-forming organic polymerizable material that is insoluble in the polyolefin matrix and is selected from polyacrylates, polymethacrylates, Polyacrylonitrile, polyvinyl alcohol, polyvinyl acetate, polyamine, polyurethane or polyester; (b2) polyetheresteramine or polyester-ether block copolymer; And (b3) selected from LiCICU, LiCF3S〇3, NaCl〇4, LiBF4, NaBF4, KBF4, NaCFsSCb, KC104, KPF6, KCFsSCb, KC4F9S03, Ca (Cl〇4) 2, Ca (PF6) 2, Salts of the group consisting of Mg (Cl002, Mg (CF3S〇3; h, Zn (Cl002, Zn (PF〇2 or Ca (CF3S〇3) 2, which have been mismatched or dissolved in The polyetheresteramide or polyester · ether block copolymer (b2); wherein at least every 20 warp and / or weft yarns contain the antistatic composition. The woven antistatic flexible intermediate container according to item 1, which has a coating on the inner and / or outer surface, and contains 7% to 30% by weight of the antistatic based on the solid weight of the coating Additives. 3. The woven antistatic flexible intermediate container according to item 1 of the patent application scope, wherein the inner bag made of a polyolefin film is loosened or partially fixed on the fabricated product and contains The antistatic additive ° 4. The woven antistatic flexible intermediate container according to item 1 of the patent application scope, wherein the antistatic additive is a mixture in the form of continuous fibers, and the mixture contains: 1 compartment (2.297 public love) (Please read the notes on the back before writing this page) 訂： 線 1232246 留 C8 D8 六、申請專利範圍 (bU 30,70重量％之聚_胺； (b2) 70-30重量％之聚醚酯醯胺或聚酯·醚嵌段共聚 物；以及 (b3) 0.1-10 重量％ 之選自 LiCl〇4、LiCFsSO” NaCia 、UBF4、NaBh、KBF4、NaCFsSCb、Kcl〇4、KPFe、KCF3SO3 、KC4F9SO3、Ca(Cl〇4)2、Ca(PF〇2、Mg(Cl〇〇2、Mg(CF3S〇3)2 、Zn(Cl〇4)2、Zn(PF小或Ca(CF3S〇3)2所組成之族群的鹽， 其已錯合或溶合於該聚醚酯醯胺或聚酯-醚嵌段共聚物（b2 ).中，成份的總和爲100¾。 5.—種製造織造抗靜電可撓性中間體容器之方法，其 包括： 倂入作爲抗靜電添加劑之根據申請專利範圍第1項之 抗靜電組成物到聚丙烯纖維或紗條中，及 至少每20條經紗線和/或緯紗線使用該聚烯烴纖維或 紗條0 ..........................裝·............訂----------------線 (請先閱讀背面之注意事項再塡寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐）Order: line 1232246 leaving C8 D8 VI. Patent application scope (bU 30,70% by weight of polyamine; (b2) 70-30% by weight of polyetheresteramide or polyester-ether block copolymer; and ( b3) 0.1-10% by weight selected from LiClO4, LiCFsSO "NaCia, UBF4, NaBh, KBF4, NaCFsSCb, KclO4, KPFe, KCF3SO3, KC4F9SO3, Ca (Cl〇4) 2, Ca (PF〇2, Salts of the group consisting of Mg (Cl〇〇2, Mg (CF3S〇3) 2, Zn (Cl〇4) 2, Zn (PF small or Ca (CF3S〇3) 2, which have been mismatched or dissolved in In the polyetheresteramide or the polyester-ether block copolymer (b2), the total of the components is 100¾. 5. A method for manufacturing a woven antistatic flexible intermediate container, including: The antistatic composition of the antistatic additive according to item 1 of the scope of patent application is applied to polypropylene fibers or slivers, and the polyolefin fibers or slivers are used at least every 20 warp and / or weft yarns ... ............. Installed ............ Order ------------ ---- Line (Please read the precautions on the back before transcribing this page) This paper size applies to China National Standard (CNS) A4 (210 X 29 7 mm)
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI509118B (en) * 2013-04-26 2015-11-21 Asiatic Fiber Corp Preparation of conductive yarns

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI509118B (en) * 2013-04-26 2015-11-21 Asiatic Fiber Corp Preparation of conductive yarns

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