TW593749B - Aqueous lubricant and surface treatment of metal materials - Google Patents

Aqueous lubricant and surface treatment of metal materials Download PDF

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Publication number
TW593749B
TW593749B TW090109853A TW90109853A TW593749B TW 593749 B TW593749 B TW 593749B TW 090109853 A TW090109853 A TW 090109853A TW 90109853 A TW90109853 A TW 90109853A TW 593749 B TW593749 B TW 593749B
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Taiwan
Prior art keywords
resin
water
surface treatment
lubricant
film layer
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TW090109853A
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Chinese (zh)
Inventor
Ryousuke Kawagoshi
Masaaki Fujii
Masayuki Yoshida
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Nihon Parkerizing
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Publication of TW593749B publication Critical patent/TW593749B/en

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82—After-treatment
    • C23C22/83—Chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/22—Compounds containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/22—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/14—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved
    • C10M149/18—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C10M2201/0663—Molybdenum sulfide used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C10M2217/0453—Polyureas; Polyurethanes used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2080/00—Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Lubricants (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

The present invention provides an aqueous lubricant for forming a coating with excellent slipping lubricity on metal materials and a surface treating method by using the same. The said aqueous lubricant is characterized by comprising molybdenum disulfide particles having average size of 0.5-10 nm and a water soluble resin with break strength above 300 kg/cm<2>, breaking elongation rate below 10%, and average molecular weight of 5000-50000, wherein said water soluble resin is polyester resin or aqueous polyurethane resin.

Description

593749 A7 B7 五、發明說明（ 經濟部智慧財產局員工消費合作社印製 【實施例】 以下列舉幾個實施例與比較例以便說明本發明之有 用性。 〔材料〕 對下述鋼鐵材料進行了處理。 平板·· S45C，尺寸：30mmx 80mm，厚度 1mm 滑動潤滑試驗片（SRV) : SUJ2 24x 8ram 〔前處理〕 洗滌處理：用市售洗滌劑（註冊商標Finecleaner— 4360 ’日本pARKERiziNG股份有限公司製）的2°/◦水溶液60 °C下浸潰3分鐘後，自來水洗滌30秒鐘。 磷酸錳處理··洗滌處理後，浸潰在市售的表面調整 劑（註冊商標一Prepalan 55 (實施例3)或Prepalan VM (實施例4和對照例2)，均日本PARKERIZING股份有 限公司製）的3%水溶液中，接著用市售的磷酸錳化成劑 (註冊商標Parhos MIA，PARKERIZING股份有限公司製） 的15%水溶液在95它下作5分鐘浸潰處理。其後水洗和乾 燥。 實施你II 在上述洗滌處理過的鋼鐵材料表面上塗布下述表面 處理液1後，在160°C下進行10分鐘燒接。 表面處理液1 二硫化鉬：平均粒徑2. 〇毫微米 水系樹脂：聚酯系樹脂593749 A7 B7 V. Description of the invention (Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Examples] The following examples and comparative examples are provided to illustrate the usefulness of the present invention. [Materials] The following steel materials were processed Flat plate S45C, size: 30mmx 80mm, thickness 1mm Sliding lubrication test piece (SRV): SUJ2 24x 8ram [Pretreatment] Washing treatment: Use a commercially available detergent (registered trademark Finecleaner — 4360 'made by pARKERiziNG Co., Ltd.) After being immersed in a 2 ° / ◦ aqueous solution at 60 ° C for 3 minutes, it was washed with tap water for 30 seconds. After the manganese phosphate treatment, it was immersed in a commercially available surface conditioner (registered trademark Prepalan 55 (Example 3) ) Or Prepalan VM (Example 4 and Comparative Example 2), both in a 3% aqueous solution manufactured by PARKERIZING Co., Ltd., followed by the use of a commercially available manganese phosphate forming agent (registered trademark Parhos MIA, manufactured by PARKERIZING Co., Ltd.) A 15% aqueous solution is immersed for 5 minutes at 95 ° C. After that, it is washed with water and dried. Perform your II coating on the surface of the steel material after the above washing treatment. Surface treatment liquid 1 was fired at 160 ° C. for 10 minutes. Surface treatment liquid 1 Molybdenum disulfide: average particle diameter 2.0 mm Water-based resin: Polyester-based resin

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« — — — — — — II I ϋ I I I — — — — — — — — ! I I I I ϋ I I I _ I 593749 發明說明（） 樹脂斷裂強度：350千克/平方釐米 樹脂延伸率：2% '、 樹脂的平均分子量·· 1〇〇〇〇 處理液1疋將二硫化鉬粉末分散在聚酯樹脂水分散 液中製成的。 實施例2 在上述洗滌處理過的鋼鐵材料表面上布下述 處理液2後’在厦C下進行1G分鐘燒接。 面 表面處理液2 二硫化鉬（平均粒徑）·· 4· 〇毫微米 水系樹脂：聚酯系樹脂 樹脂斷裂強度：320千克/平方釐米 樹脂延伸率：1% 樹脂的平均分子量·· 12 〇 〇 〇 處理液2是將二硫化鉬粉末分散在聚酯樹脂水 液中製成的。 政 f施例3 經濟部智慧財產局員工消費合作社印製 對上述洗滌處理過的鋼鐵材料實施磷酸錳處理，然 後在表面上塗布下述表面處理液3，最後在2201：下、# '、 5分鐘燒接。 進行 表面處理液3 二硫化鉬（平均粒徑）：2 〇毫微米 水系樹脂：水性聚氨酯樹脂 樹脂斷裂強度：310千克/平方釐米 μ紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 593749 A7 ------~___B7 _ 五、發明說明（） 樹脂延伸率：5% 樹脂的平均分子量：8000 處理液3是二硫化鉬粉末分散在聚酯樹脂水性分散 液中製成的。 實施例4 將上述洗務處理過的鋼鐵材料，在加熱到仍。^的下 述表面處理液4中浸潰處理1〇分鐘。接著水洗和乾燥。 然後塗布實施例3使用的表面處理液3，18〇t下進行1〇 分鐘燒接。 表面處理液4 二硫化鉬（平均粒徑）·· 15毫微米 水系樹脂：水性聚氨酯樹脂 樹脂斷裂強度：350千克/平方釐米 樹脂延伸率：3% 樹脂的平均分子量·· 15000 處理液4是二硫化鉬粉末分散在聚酯樹脂水性分散 液中製成。 比較例1 僅進行上述洗滌處理，不實施其後的表面處理。 比較例2 僅進行上述洗滌處理及磷酸錳處理，未實施其後的 表面處理。 表1示出有關實施例1〜4以及對照例1和2中鱗酸 猛層溥膜厚度、粒桉和粗糙度、表面處理後形成的潤滑薄 -------------m (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 一 δ，— — — — — — — I· I — — — — — — — — — — — — — — — — — — — — — — 11«— — — — — — — II I ϋ III — — — — — — —! IIII ϋ III _ I 593749 Description of the invention () Resin breaking strength: 350 kg / cm² Resin elongation: 2% ', average resin Molecular weight: 10,000 treatment solution 1 疋 Dispersed molybdenum disulfide powder in a polyester resin aqueous dispersion. Example 2 The following treatment liquid 2 was applied on the surface of the steel material after the washing treatment described above, and was fired at 1 ° C for 1 minute. Surface surface treatment liquid 2 Molybdenum disulfide (average particle size) ... 4 nm water-based resin: polyester-based resin resin breaking strength: 320 kg / cm2 resin elongation: 1% average molecular weight of the resin 12 The treatment solution 2 is prepared by dispersing molybdenum disulfide powder in a polyester resin aqueous solution. Example 3 Printing by the Consumers 'Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs applies the manganese phosphate treatment to the above-mentioned washed steel materials, and then applies the following surface treatment liquid 3 on the surface, and finally 2201: 下, #', 5 Burn in minutes. Surface treatment liquid 3 Molybdenum disulfide (average particle size): 20 nm Water-based resin: Water-based polyurethane resin Resin breaking strength: 310 kg / cm² Paper size Applicable to China National Standard (CNS) A4 (210 X 297 cm) (Centi) 593749 A7 ------ ~ ___ B7 _ 5. Description of the invention () Resin elongation: 5% Resin average molecular weight: 8000 Treatment liquid 3 is made of molybdenum disulfide powder dispersed in polyester resin aqueous dispersion of. Example 4 The iron and steel materials treated as described above were heated to still. The surface treatment liquid 4 described below was immersed for 10 minutes. It is then washed and dried. Then, the surface treatment liquid 3 used in Example 3 was applied and fired for 10 minutes at 180 ° t. Surface treatment liquid 4 Molybdenum disulfide (average particle size) ... 15 nm water-based resin: water-based polyurethane resin resin Breaking strength: 350 kg / cm2 Resin elongation: 3% Average molecular weight of the resin 15000 Treatment liquid 4 is two Molybdenum sulfide powder is made by dispersing in polyester resin aqueous dispersion. Comparative Example 1 The above-mentioned washing treatment was performed only, and the subsequent surface treatment was not performed. Comparative Example 2 Only the above washing treatment and manganese phosphate treatment were performed, and the subsequent surface treatment was not performed. Table 1 shows the film thickness, granules and roughness of the scale acid fibrous layer in Examples 1 to 4 and Comparative Examples 1 and 2, and the lubricating thinness formed after surface treatment. -m (Please read the notes on the back before filling out this page) The Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed a δ, — — — — — — — I · I — — — — — — — — — — — — — — — — — — — — — — — 11

593749 A7 經濟部智慧財產局員工消費合作社印製593749 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

發明說明（ 性 B7 膜層中崎和碳量、以及滑 驗用以下方法進行。 ‘結果。滑動潤滑試 〔滑動潤滑試驗〕 用市售SRV試驗機進行了評價。 、 和未處理的鋼球（SUJ2，直徑1〇真^处之的試驗片 頓載荷、50赫兹振動頻率、2毫米振幅下在=〇牛 =數及摩擦係數達到0·6前所需二 == 長，潤滑性越好。 』此打間越 表1所示的資料說明，本發明可以得到優良的濁滑 表 磷酸錳薄膜^ 滑動潤滑 評價 厚度 (#m) 粒徑 (#m) 粗糙f (//m) Mo (g/m2) C (g/m2) SRV滑動時 間（秒） 實施例1 — — 1.5 1. 5 200 實施例2 — — 2·0~ 2· 0 200 實施例3 3 2 卜1· 5 3. 0 ~~~O~ 300 實施例4 10 20 8~ 4. 0 4. 0 300 比較例1 0 0 — 0 0 5 比較例2 10 8 8 0 0 25 本發明採用特定的水系樹脂製成水系潤滑劑，然後 用此水系潤滑劑進行金屬材料表面處理，這樣能在低成本 和環境污染小條件下使金屬材料表面形成具有極優良滑動 潤滑特性的薄膜，產生優良效果。 12 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）[Explanation of the Invention] (Sulfur content, carbon content in the B7 film layer, and slip test were performed by the following methods. 'Results. Sliding Lubrication Test [Slip Lubrication Test] It was evaluated with a commercially available SRV test machine.), And untreated steel balls (SUJ2 The test piece's load at a diameter of 10 mm, a vibration frequency of 50 Hz, and an amplitude of 2 mm at a value of 0 N = and a coefficient of friction required to reach 0.6 before the two = = long, the better the lubricity. " The data shown in Table 1 below shows that the present invention can obtain an excellent manganese phosphate film with a slick surface ^ Sliding lubrication evaluation thickness (#m) Particle size (#m) Rough f (// m) Mo (g / m2) C (g / m2) SRV sliding time (seconds) Example 1 — 1.5 1. 5 200 Example 2 — 2 · 0 ~ 2 · 0 200 Example 3 3 2 Bu 1 · 5 3. 0 ~ ~~ O ~ 300 Example 4 10 20 8 ~ 4. 0 4. 0 300 Comparative Example 1 0 0 — 0 0 5 Comparative Example 2 10 8 8 0 0 25 The present invention uses a specific water-based resin to make a water-based lubricant. This water-based lubricant is then used for surface treatment of metal materials, so that the surface of metal materials can be formed with extremely low cost and low environmental pollution. Film with excellent sliding and lubricating properties, producing excellent results. 12 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

請 先 閱 讀 背 之 注 意 事 項 1 再 本臂^ 頁 I 訂 線 593749 五、發明說明（ 本·Έ適用中國國 &amp; 【發明所屬之技術領域】 4 ’本發明涉及由二硫化鉬和具有特uf : 3潤滑劑，以及使用這種潤滑劑的金屬材料^的 【先前技術】 二硫化鉬自古以來就作為固體潤滑劑使用，gp佔相 ，還在以各種汽車部件為首的各種用途中m =現 劑 ΐ 二; 另一方面’在1940年代石粦酸結處理作為细Please read the note 1 on the back first, then this arm ^ Page I Thread 593749 5. Description of the invention (this is applicable to the country of China &amp; [Technical Field to which the Invention belongs] 4 'The present invention relates to the use of molybdenum disulfide and has special uf : 3 lubricants, and metal materials using this lubricant [prior art] Molybdenum disulfide has been used as a solid lubricant since ancient times, gp is dominant, and it is also used in various applications including various automotive parts. M = present Agent ΐ ;; on the other hand 'in the 1940's hydrazone was treated as fine

ί ί面ΐϊίΛ化。因此’防止金篇間ί ϊ iSS if了於許多滑動部件的使用條件 敌出了心更祕要求，而財望部件的朗 了戰） X 297公釐）ί ί 面 ΐϊίΛ 化. Therefore, ‘preventing the gold article ’s iSS if the conditions of use of many sliding parts are met. The enemy ’s desire is more secretive, and the wealth expecting part is clear.) X 297 mm)

,裝--------訂· -線· -I I I n n I (請先閱讀背面之注意事項再填寫本頁) n I n - 593749 五 、發明說明（ B7 ί； 92. 8. 20 .¾... 心场合下’傳統的伽轉膜不能單獨獲得所需的充 硫化:!===二提出在娜上形成二 構，其特徵械麵Λ賴雜傳動機 邻八刀疋由合金工具鋼製成，在此嚙合 二、:層和固定潤滑膜固體的潤滑齒輪，而固 诉劑:之社入;形成。但是’關於形成固體潤滑膜的潤 tr 何記載。而特開平9-184079號公報(耐 ί=: 耐磨損構件’其中在壓力環的上下表面 毫^二if ^及在其晶粒_間分散有平均粒徑1〜2 ?合=聚_酿亞胺、環氧樹脂、聚亞胺與聚二作; 的機械性質。其實施例中使用聚_先亞胺 作拈a诏，採用的是有機溶劑的塗裝方法。 女 【發明要解決的課題】 【:=Γ水系潤滑劑及其表面的處理方法， 本發明人等就上奴有技鱗在之_的解決手段進 本紙張尺度適用中國, Installed -------- order · -line · -III nn I (Please read the precautions on the back before filling out this page) n I n-593749 V. Description of the invention (B7 ί; 92. 8. 20 .¾ ... Under the circumstance, the traditional gamma film can't obtain the required filling and vulcanization alone:! === Two proposed to form a second structure on the na, its characteristic mechanical surface It is made of alloy tool steel, and here it meshes with the second and the third layer and the fixed lubricating gear of the solid lubricating film, and the solid complaint agent: the company enters; formation. But what is the record about the formation of a solid lubricating film? No. -184079 (resistant = = wear-resistant member 'wherein the upper and lower surfaces of the pressure ring ^ ^ if ^ and the average particle size 1 ~ 2 dispersed between the grains _ = = poly_imine, The mechanical properties of epoxy resin, polyimide, and polyimide. In the examples, poly_imide is used as 拈 a 诏, and an organic solvent coating method is used. Female [Problems to be Solved by the Invention] [ : = Γ water-based lubricant and surface treatment method, the present inventors and others have adopted a solution to solve this problem. This paper is applicable to China.

丨裴--------訂： -1· H ^1 線ί (請先閱讀背面之注音？事項再填寫本頁) 593749 A7 五、發明說明（ B7 取 Tf. 年月日 補尤 行深入研究，結果新發現由特練㈣二硫化姉具有特定機 械特性的樹脂組成的水系潤滑劑以及使用這種潤滑劑的表面處 理方法’此外還新發現使之形成特定構g樓薄膜層和潤滑劑層 組成的複合膜的方法。 曰 •也就是說，本發明涉及一種水系潤滑劑，其特徵在於其 中含有平均粒徑0.5〜10毫微米的二硫化鉬，以及斷裂強度3〇〇 千克/平方釐米以上、斷裂延伸律10%以下、平均分子量5〇〇〇 〜50000的水系樹脂。其中所說的水系樹脂聚酯樹脂或水性聚 胺酯樹脂。此外，本發明還提供了一種金屬材料的表面材料的 表面處理方法，其特徵在於使所說的水系潤滑劑與清潔的金屬 材料表面接觸，形成含有以鉬計(U〜5·〇克/平方米二硫化鉬， 以碳計0·1〜5.0克/平方米樹脂的水系潤滑劑薄膜層，然後再 100〜250°C下進行燒接。本發明也提供了 一種金屬材料的表面 ，理方法，其特徵在於使所說的潤滑劑與薄膜厚度1〜15毫微 米、結晶粒徑0.5〜30毫微米、表面粗糙度（R2) 〇·5〜2〇毫微米 的被晶狀磷酸錳薄膜覆蓋的金屬表面接觸，使之形成含有以在目 計〇·1〜5.0克/平方米二硫化鉬，以碳計0j〜5 〇克/平方米樹 脂的水系潤滑劑薄膜層後，在1〇〇〜250°C下進行燒接，使之形 成由磷酸錳薄膜層和潤滑膜層組成的複合膜。少 【發明的實施方式】 以下詳細說明本發明。 對用作本發明處理物件的材料並無特別限制，主要 i 訂 線 本纸張尺㈣財@ 標準（CNS)A4規格（21(^ 297公髮 ^5749 五 、發明說明（ f用於鋼鐵材料，例如碳素鋼、鉻合金鋼、鉻鉬合金鋼、言# 鉻合金鋼、鋁、鋁合金等。 π厌 本發明的水系潤滑劑可以牛採用使二硫化鉬和水系樹 =^在水中的方法製造。本發_水_滑劑中使用二硫化 、’的平均粒徑必須處於0.5〜10毫微米範圍内。用平均粒徑處於 =乾圍内的二硫化鉬可以獲得優良滑動特性。低於05 半 無問題，但是成本增高並不好。另—方面若超過ίο ^只在潤滑劑中的分散就會惡化，也不好。本發明水系潤 γ中用的水系樹脂，是能在水中溶解D散使用的一些樹 ^例醋樹脂、聚氨醋樹脂、多紛樹脂等。特別聚@旨樹脂 ^7/生聚氨s旨系樹脂（分散液）。聚脂系樹脂可以舉出用對苯二 ，，間笨二甲酸的聚化物作為共聚成份的聚_脂；而聚氨 可以f出以聚鱗多_、聚s旨多元醇等多元醇，以及 二^胺^氰_旨 '其撐稱二異氰酸麟聚異氰酸_為基料 太L、生聚氨自旨樹脂。這些樹脂必須使用斷裂強度3GG千克/平 里ί米以上、斷裂延伸率1G%、平均分子量5_〜5_〇的標 盆。，因為斷裂強度高而延伸帛低的樹脂有優良的耐磨損性。 二平均分子s對處理劑的分散性有影響，所以必須處於此範 圍内。 ★以下說_上述H潤關纽金屬材料表面的方 ^讀金屬材料的表面處理方法是··首先使職的水系潤滑 t清潔的金屬材料表面接觸，形成含有以輯01〜50克/平 米的一硫化錮，以碳計0.1〜〇·5克/平方 (請先閱讀背面之注意事項再填寫本頁) . -線· S氏張尺度適用規格(i~ x 297公釐） 593749 五、發明說明（ 米樹脂的水_滑㈣膜層’織在觸〜25rcT進行 通過這種燒接’使金屬材料表面形成含有以崎αι 70 :克坪方軸和(U〜5.()克/平方米碳的潤滑劑賴。經 種k接乾祕’ la和碳料自附著量低於G1克/平方米碍，^ =到足夠的滑動性：關和碳的各自附著量超過5 G克/平方= B寸，雖然沒有出現特別的問題，但經濟性卻變差。 '、 對水系潤滑劑與金屬材料的接觸方法沒有特別限制 ^用浸潰法和法等。其中包括使水_滑劑以原 或者以稀釋處理液形式接觸。而且也可以並用表面活性劑，^ ，使二硫化_-塗布。對這種處職巾二硫化姉 度沒有特別限制，其各自濃度通常〇1 的/辰 :左右較優。濃度低於〇.1%時，塗布次數衫不能獲 塗布量，因此使工序延長在經濟上不合算。反之一旦超過&amp; 就會使處理液的穩定性劣化，也不好。 〇 …孟無之後在100〜25(rc溫度下進行燒接和乾燥，使之形点 潤滑薄膜層。這種燒接乾_目的在於揮發水份，τ 餘溫度必彡聽赴職圍，絲叙15G〜細。^範_^乾 —w對鋼鐵材料實施上述金屬材料表面處理方法時，從滑動 潤》月性、附*性和耐腐紐角度盘看 細，_磷__在卜15 成 内、，:粒直徑為0.5〜30毫微米，表面粗縫度(R2)= 〇㈣二 微米細内較優。薄膜厚度低於1毫 ^ Μ--------^------ (請先閱讀背面之注意事項再填寫本頁} •線！ 本紙張尺度適用中國國家標準（Cisii)A4 ^^TiioT 297公釐） 593749 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 η 五、發明說明（ ]Β7ρ| 1 Μ δ. 20 fifliq ^上度降低，則不良好。薄膜厚度超過15毫微米時， 啦。嫩徑低於Ο.5 不妊。本尾充刀而超過30毫微米摩擦係數增高也 2〇毫微:二:二丄112)低於〇.5毫微米附著性降低，而超過 &quot;微未表面粗糙度增大，潤滑薄膜的覆蓋性差，所以都不好。ΐΐίΐϊϊϊΞΙ度，是將化成處理後的構件剖開後，用金 ° ™崎綱的掃描 市售的表1_軸2_編㈣。姆链度是用 ，，著里用市售縈光χ射線分析裝 以;;不:，量已知的數個樣品，瞻 =著=作曲線將 件是赋下測定 1吏3认祕乳化的條件，一般優選的條 線 本紙張尺度顧+關家標準(CNS)A4 ^^(210^: S i公釐）丨 Pei -------- Order: -1 · H ^ 1 Line ί (Please read the phonetic on the back? Matters before filling out this page) 593749 A7 V. Description of the invention (B7 is based on Tf. After in-depth research, it was found that a water-based lubricant composed of a resin with specific mechanical properties and a surface treatment method using this lubricant was newly discovered. In addition, it was also newly discovered to form a specific structure film layer and A method for a composite film composed of a lubricant layer. That is, the present invention relates to an aqueous lubricant, which is characterized in that it contains molybdenum disulfide with an average particle diameter of 0.5 to 10 nm and a breaking strength of 300 kg / Water-based resin with a square centimeter or more, a fracture extension law of 10% or less, and an average molecular weight of 5000 to 50,000. Among them, the water-based resin polyester resin or water-based polyurethane resin. In addition, the present invention also provides a surface material of a metal material The surface treatment method is characterized in that the water-based lubricant is brought into contact with the surface of a clean metal material to form a layer containing molybdenum (U ~ 5.0 g / m2 molybdenum disulfide in terms of carbon, 0.1 ~ 1 in terms of carbon). 5.0g / m2 resin water-based lubricant film layer, and then fired at 100 ~ 250 ° C. The present invention also provides a surface of a metal material, a physical method, characterized in that the lubricant and the film A metal surface covered with a crystalline manganese phosphate film having a thickness of 1 to 15 nm, a crystal grain size of 0.5 to 30 nm, and a surface roughness (R2) of 0.5 to 20 nm is formed so that it contains Calculate 0.1 to 5.0 g / m2 of molybdenum disulfide and 0j to 50 g / m2 of resin as a water-based lubricant film layer of resin, and then sinter at 100 to 250 ° C to form A composite film composed of a manganese phosphate film layer and a lubricating film layer. [Embodiments of the invention] The present invention will be described in detail below. There are no particular restrictions on the material used as the processing object of the present invention, mainly i.财 @Standard （CNS) A4 Specification （21 (^ 297 公 发 ^ 5749) V. Description of the invention (f for steel materials, such as carbon steel, chrome alloy steel, chrome molybdenum alloy steel, chrome #chrome alloy steel, aluminum, Aluminum alloy, etc. π hate the water-based lubricant of the present invention can be mined Molybdenum disulfide and water-based tree = ^ made in water. The use of disulfide in this hair _ water _ slip agent, the average particle size must be in the range of 0.5 to 10 nanometers. Molybdenum disulfide inside can obtain excellent sliding characteristics. Less than 05 is no problem, but the cost increase is not good. In addition, if it exceeds ίο ^ only the dispersion in the lubricant will worsen, and it is not good. The water system of the present invention The water-based resins used in the run γ are some of the vinegar resins, polyurethane resins, and multi-resin resins that can be used to dissolve D powder in water. In particular, poly resins aim at resins 7 / raw polyurethanes. Dispersion liquid). Polyester resins can include polyesters using terephthalic acid, m-phenylene dicarboxylic acid as the copolymerization component; and ammonia can be used to produce polyscale, polystyrene, etc. Polyols, as well as diamines and cyanogens, are called diisocyanates and polyisocyanates, which are base materials that are too L and raw polyamines. These resins must use standard pots with a breaking strength of 3GG kg / m or more, an elongation at break of 1G%, and an average molecular weight of 5 to 5 mm. Resin with low elongation due to high breaking strength has excellent abrasion resistance. The two average molecules s have an effect on the dispersibility of the treating agent, so it must be within this range. ★ Here is the description of the above_____________________________________________________________________________________________________________ The surface treatment method of the metal material is to first contact the surface of a clean metal material with a water-based lubricant to form a surface containing Rhenium monosulfide, 0.1 to 0.5 g / sq. In terms of carbon (please read the precautions on the back before filling this page).-Applicable specifications for line and S-sheet scale (i ~ x 297 mm) 593749 V. Invention Description (The water-sliding film layer of rice resin 'weaves in contact ~ 25rcT by this firing' to form the surface of the metal material containing 崎 α 70: gram square shaft and (U ~ 5. () G / square The lubricant of rice carbon is Lai. After the kind of k is dry, the self-adhesion amount of carbon and carbon material is lower than G1 g / m2, ^ = to sufficient sliding property: the respective adhesion amount of Guan and carbon exceeds 5 G g / Square = B inch, although there are no special problems, the economy is poor. '、 There are no particular restrictions on the method of contacting water-based lubricants with metallic materials. It can be contacted in the form of original or diluted treatment solution. It can also be combined with surfactant, ^, to make disulfide _-Coating. There is no particular limitation on the disulfide degree of this kind of office towel, and their respective concentrations are usually 0/1 / day: better. If the concentration is less than 0.1%, the number of coats cannot be applied, so It is not economical to extend the process. On the other hand, if it exceeds & it will degrade the stability of the treatment liquid, which is also not good. 〇 ... Meng Wu will be fired and dried at 100 ~ 25 (rc temperature to make it shape Point lubricating film layer. The purpose of this firing dry is to evaporate moisture, and the remaining temperature will be 15G ~ fine. ^ 范 _ ^ 乾 —w Apply the above-mentioned metal material surface treatment method to steel materials At the time, from the perspective of sliding lubricity, lunar, attachment, and corrosion resistance, _ phosphorus __ is within 15%, the diameter of the grain is 0.5 ~ 30 nm, and the surface roughness (R2) = 〇㈣2 micron fine is better. Film thickness is less than 1mm ^ Μ -------- ^ ------ (Please read the precautions on the back before filling in this page} • Line! This paper Standards apply to Chinese National Standard (Cisii) A4 ^^ TiioT 297 mm) 593749 Employees' Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs, India 5. Description of the invention (] B7ρ | 1 Μ δ. 20 fifliq ^ The lower the degree, it is not good. When the thickness of the film exceeds 15 nm, the tender diameter is less than 0.5. Infertility. The tail is filled with a knife and the friction exceeds 30 nm Increasing the coefficient is also 20 nanometers: two: two 丄 112) the adhesion is lower than 0.5 nanometers, and the surface roughness increases beyond "micro" and the coverage of the lubricating film is poor, so it is not good. After cutting the chemically treated member, the commercially available table 1_axis 2_edited with a scan of gold ° ™ Sakizuna. Farm ,, is the chain of a commercially available rayon in light χ-ray analysis apparatus not to ;;:, a known amount of several samples, looking for = = the curves measured at 1 forming member is a three officials recognize secret emulsion Conditions, generally preferred strips, paper size Gu + Guan Jia Standard (CNS) A4 ^^ (210 ^: S i mm)

Claims (1)

593749 A8 B8 UK —---音 欠 丁·— 六、申請專利範園 蠢1礙 1· 一種水系潤滑劑，其特徵在於其令含有平 10¾微求的二硫化鉬，以及斷裂強度; 2 5ΐΙΪ5；4ΪΪ^ .的表面處理方法，其特徵在於如申請專禾 〜15 毫微米: 的被晶狀磷度㈣0.5〜20毫《 鉬計0 1〜5 n a，寻版设盍的金屬表面接觸，形成含有以 平^半灼胙平方米的二硫化錮，以碳計αι〜5·0克/ 行燒S Ϊ2ί潤 滑劑薄膜層後，在100〜250°C下進 複ί膜層。之形成由鱗酸猛薄膜層和潤滑薄膜層組成的 £l«**ptrVLjsr4.t?:2:r.:/irf^rtrl^w 13 从毛格（：IGx297公楚）593749 A8 B8 UK —--- Yin O Ding — 6. Application for patent Fan Yuan 1 1 1. A water-based lubricant, which is characterized in that it contains molybdenum disulfide, which is about 10 ¾ micron, and breaking strength; 2 5ΐΙΪ5 The surface treatment method of 4ΪΪ ^ is characterized in that if the application is special ~ 15 nm: the crystallinity is 0.5 ~ 20 millimeters, the molybdenum meter is 0 1 ~ 5 na, and the metal surface of the plate-setting device is in contact. After forming a thin film containing sulfide disulfide with a square meter of half a square meter of square meters, α ˜5 · 0 g per row of carbon, and a thin film of lubricant ， 2 ί, a film layer was added at 100 ~ 250 ° C. The formation of £ l «** ptrVLjsr4.t?: 2: r.: / Irf ^ rtrl ^ w consisting of a scale acid film layer and a lubricating film layer from Maoge (: IGx297)
TW090109853A 2000-06-28 2001-04-25 Aqueous lubricant and surface treatment of metal materials TW593749B (en)

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JP2008069413A (en) * 2006-09-14 2008-03-27 Nippon Steel & Sumikin Stainless Steel Corp Lubricant steel sheet
CN101205499B (en) * 2007-11-28 2010-06-09 周贤言 Aluminum-magnesium alloy wiredrawing lubricant
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