經濟部智慧財產局員工消費合作社印製 589420 A7 B7 五、發明説明（1 ) 本發明旨在敘述一種預定向聚酯絲的紡絲與絡筒的方 法，本發明所製的預定向聚酯絲中除由本發明所述方法而 製得的預定向聚酯絲外，還有至少90%重量比的聚對苯二 甲酸丁二醇酯（PBT)或聚對苯二甲酸丙二醇酯（PTMT) 的成份（最好是PTMT) ’此外，本發明並敘述一種就紡絲 與絡同後的聚醋絲’再經伸長加工織法’製造膨鬆聚醋絲 (BULKY POLYESTER FILAMENTS)的方法。 用兩階段法連續生產聚酯絲，特別是聚對苯二甲酸乙 二醇酯（PET )細絲，是已知的技術，在第一階段，先將 平滑預定向絲紡絲及絡筒，然後細絲在第二階段伸長加工 成爲成品，再經熱固定，或是用伸長織法製成膨鬆絲。 F· FOURNE 在 1995 年由慕尼黑 HANSER VERIAG 出 版的「合成纖維」一書中，對此曾提供一些他的看法，不 過其中談到PET纖維的生產時，祇槪括提到其變動特性， 而沒有觸及紐絲技術。 製造各種可紡絲型聚合物，譬如聚丙烯、聚醯胺、聚 酯等，固係德國專利申請DE-0S 38 19 913之目的，但由 其加工的聚合物溫度資料中可以推知，它不過在所作的實 例中提到PET纖維而已。 當連續生產PTMT或PBT細絲時，存在的問題是預定 向細絲在常溫儲存時，會有顯著的收縮傾向，這現象存在 於紡絲之後，或絡筒之時，以及絡筒後幾個小時，結果是 纖維的長度縮短了，線軸的主體被壓縮，在極端的狀況下， 會發生筒管本身緊緊的收縮在線軸上，無法拿開或取下， 本紙張尺度適用中關家榡準（CNS ) Μ規格（2】〇>< 297公麓）4 (請先閱讀背面之注意事項再填寫本頁) 訂- 經濟部智慧財產局員工消費合作社印製 589420 Α7 Β7 五、發明説明（2 ) 甚至筒管還會變成馬鞍狀，周邊堅硬而中央凹陷的現象， 這就是說，細絲的紡織特性，譬如烏絲特（USTER)此時 會變得不均勻的強，這會在筒管加工時發生不能絡筒或退 繞問題（UNSPOOLING PROBLEM)，不過這個問題惟於限 制筒管重量於4公斤以下可獲解決，還有在PET加工時， 不會發生這個問題。 並且據觀察，不同於PET絲，預定向PBT或PTMT 絲在儲存時還有加速老化的問題，一旦出現結構性硬化現 象，結果會大大減損其加工收縮性而產生結晶化，此種PBT 或PTMT絲祇能有條件地供進一步加工，這會在伸長織法 加工時產生失誤與明顯地降低其加工後的線之抗撕裂性， 結果，還會導致伸長加工速度降低與其伸長比率減少。 PET不同於PBT或PTMT的原因據說是其結構性與特 性不同所造成的，據2000年出版的國際化學纖維第50卷 53頁以及9·月13日至15日在DORNBIM舉行的國際人造 纖維會議，都有此一說，因此這裡不妨假定不同的鏈因子 是造成其不同特性的主因。 最先爲這些問題尋找解決方案的是世界專利申請WO 99/27168以及歐洲專利申請EP 0 731 196 B1，據WO 99/27168揭示的聚酯纖維的成份，至少要有90%重量比的 聚對苯二甲酸丙二醇酯，此外，其加工收縮率要在5%至 16%之間，其伸長撕裂在20%至60%之間，又WO 99/27168 所述的聚酯纖維製造方法係以紡絲與絡筒爲主，文中所指 的紡絲移除速度，最大不超過2100m/min，不過此法不具 度適用中國ΐ家標準（CNS ) Λ4規格（210X 297公釐)~I" —^ IF (請先閱讀背面之注意事項再填寫本頁) 589420 Α7 Β7 經濟部智慧財產局員工消費合作社印製 五、發明説明（3 ) 有經濟效益，此因速度過低，其所製成之聚酯纖維還有強 的結晶性，不適於伸長加工織法。 EP 0 731 196 B1主張的關於合成線之紡絲，伸長加工 以及絡筒方法，其特點在絡筒前，須經過熱處理以降低其 收縮傾向，得適用此法的合成纖維也包括PTMT，但其所 採熱處理方式，係將合成線緊密的導入一縱長加熱表面而 不相接觸’因而提高了此製法的成本，且還有高結晶化的 缺點’故僅有限度的適於進一步的伸長加工。 預定向PTMT細絲的伸長加工依1997年2月出版國 際化學纖維第47卷第72至74頁的白朗博士與CHUAH二 人合寫的「以PTMT爲底的紡織纖維伸長加工織法」一文 所見，其紡織速度低於450m/min較適合，因爲在此條件 下所生產的纖維會具有更好的材料特性，據說其抗撕裂性 會在 26.5CN/tex(紡織速度 450m/min)至 29.15 CNAex(紡 織速度850m/min)之間，撕裂伸長率個別爲38% (紡織速 度 450m/min)或 33.5% (紡織速度 850m/min)。 又據世界專利申請W0 01/04393揭示，PTMT的加工 收縮範圍在3至40%之間，此値係在生產此絲後立即測定 的，此値如第1圖所示，在正常狀態下儲存四週後會降到 20%。 第1圖旨在說明三個PTMT-POY筒管在正常氣候修 件下儲存相當時間後，其加工收縮率發生變化情形，其# 第16號及第17號筒管都有一高於40%之起始値，儲存123 週後，其加工收縮會降至30%以上，當然最好能超過4〇°/°° (請先閱讀背面之注意事項再填寫本頁) i0. 訂* f 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐） 6 589420 A7 B7 五、發明説明（4 ) 如其起始値縱高於40%如第18號筒管所示，經過四週儲 存期間後，此値會降至低於臨界値30%。 第2圖爲PTMT-POY的力與膨脹的曲線圖，如撕裂伸 長率相等，其自然伸展比（NVV)，會超過或等於15%如2 圖（a)所示，而2圖（b)則爲NVV等於〇的情形。 加工收縮是量度纖維的加工性能及其結晶度，据WO 01/04393所見，纖維如含有高結晶性之塑膠，其加工性能 很差，而且只能在低伸長比及低伸長速度下加工。 有鑒於今日科技現狀，本發明旨在提供一種適合由至 少90%重量比的PBT或PTMT合成的PBT-POY或 PTMT-POY細絲的製造及絡筒方法，這會使生產預定向聚 酯絲與絡筒的方法與方式簡單化，尤其在其撕裂伸長値方 面，能定在90%至165%之間，這代表一種高均勻度及低 結晶度的特性値。 本發明還有一項附帶任務，在提供一能使預定向聚酯 絲的製造與絡筒方法在大的技術規模與合於經濟原則下進 行，依據本發明的方法，其移除速度要儘可能提高，最好 是高於2200m/min，在絡筒時能承受的筒管重量，要大於 4公斤。 本發明另有一項增進預定向聚酯的儲存性，期望於使 用本發明之方法後，能儲存更長的時間，譬如四週，並能 防止其在儲存期間發生壓縮線軸本體，特別是避免筒管收 縮至軸心，以致形成馬鞍（周邊堅硬與中間凹陷），如能做 到這一步，則於筒管加工時不會發生解不開或退繞問題。 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） I 1---. ... 1---- I— I - II ϋ ϋ (请先閱讀背面之注意事項存填寫本貢) 訂· 經濟部智慧財產局員工消費合作社印製 589420 經濟部智慧財產局員工消費合作社印製 A7 B7 - ---_ 五、發明説明（5 ) 根據本發明，預定向聚酯絲還能簡單地在伸長加 法中作高速加工，最好是超過45〇m/min，由伸長加工織、法 得到的絲，應該有優越的材料特性，譬如其抗撕裂性gg 於26CN/tex，其撕裂伸長度在HE絲（註Η·Ε·是德文h〇ch ELASmZITATS之縮寫，代表一種高延展性的細絲或紗） 爲30%以上’在SET絲（註SET絲表不由一特定加工織法 而製成的絲，在德國被稱爲假扭轉紗）爲36%以上。 此項任務以及其他尙未在上文中---表明之任務，均 可依本發明所述之紡絲加工以及絡筒方法獲得解決，其戶斤 有特點均已開列於申請專利事項第1項內，有關本發θ月方 法之適度變更事項亦都列在請求專利事項第1項的子項 內，以求保護，依本發明的紡絲加工方法而得之預定向聚 酯則列在各單項內請求保護，如預定向聚酯絲的伸長加工 列在請求專利事項第6項，由伸長加工織法而得之膨鬆絲 則列在請求專利事項第7及第8項，請求保護。 爲製造其中至少含有90%重量比的PBT或PTMT (最 好是PTMT)的預定向聚酯絲，吾人已能透過以下各項事 實，成功地製成有極佳物性的聚酯絲，即使在正常狀況下 儲存四週後，沒有發現老化或顯著損壞其均勻性或是在絡 筒時會發生其筒管有解不開或退繞問題： a. 紡絲延遲在70.至500範圍內。 b. 細絲自紡絲噴嘴出來後，經過30mm至200mm長的 冷卻延遲區。 c. 細絲冷卻到固化溫度以下。 J ------—tr------·— (請先閱讀背面之注意事項再填寫本頁) 本紙浪尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 經濟部智慧財產局員工消費合作社印製 589420 A7 B7 五、發明説明（6 ) d. 細絲在噴嘴下方500mm至2500mm的距離處捆束 (BUNDLED)。 e. 在移出導絲輥之前後，線的張力定在0.05CN/d tex 至 0.20CN/d tex 之間，最好是 〇.15CN/d tex。 f. 線在張力〇.〇25CN/d tex至〇.i5CN/d tex間進行絡 筒。 g·絡筒速度調節在2200m/min至6000m/min之間。 同時，根據本發明的方法，還有一系列的附加優點如 下： 一根據本發明，可用簡單的方法與方式，大規模及經 濟地進行工作，尤其是允許以至少2200m/min之高移出速 度進行紡絲及絡筒工作，同時還能使生產軸上的線重，超 過4公斤。 一使用本發明的方法，還可不用紡絲添加劑，有降低 聚酯絲生產成本的效益。 一經由本發明方法所得之預定向聚酯絲能以簡單方法 及方式，大技術規模及經濟方式，進行伸長加工，並能在 .進一步伸長織法加工時以高於450m/min速度進行之。 一由於經依本發明方法而得之預定向聚酯絲的高均句 性，乃能提供一種良好的捲軸設計，此項設計還可取得預 定向聚酯絲的均勻一致以及其無失誤表面著色性與進一步 的加工性。 一經由本發明伸長加工織法而得之絲具有高於 26CN/tex的抗撕裂性，還有對HE絲的超過30%的撕裂伸 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐)~一 〜 - (請先閱讀背面之注意事項再填寫本頁) L# . 訂： 經濟部智慧財產局員工消費合作社印製 589420 A7 B7 五、發明説明（7 ) 長率以及對SET絲的超過36%的撕裂伸長率等優點。 本發明所敘述的方法係關於生產預定向聚酯絲及 其絡筒方法’其所得之預定向聚酯絲含有至少90%重量比 之PBT或PTMT，對技術人員而言，PBT與PTMT皆爲已 知的東西，其中PBT可由對酸與同莫耳量的1，4二丁醇聚 合凝結而成，PTMT是由對酸與同莫耳的1，3丙二醇聚合 凝結而成，這兩種聚酯的混合物，對本發明而言，以PTMT 較好。 聚酯可以是單質的或共聚物，特別可以考慮爲共聚物 的，除再生之PTMT或PBT單元外，還有至多15莫耳％ 重量比的重複聚酯，重複聚單體，例如乙二醇、二甘醇、 三甘醇、1，4環巳烷二甲醇、聚乙二醇及己二酸，對本發 明而言，最好是聚酯單質聚合物。 本發明的聚酯可以有一般量的添加劑物質作爲混合 物，例如催化劑、安定劑、防靜電劑、防氧化劑、抑火劑、 著色劑、著色劑吸收改變劑、光安定劑、有機磷、亮光劑、 及舖墊劑、聚酯最好有細絲總重量的0至5重量％的添加 劑。 此外’聚酯可以有少量的分枝成分，其數量最好是細 絲總重量的0.5重量％以下，本發明偏好的分枝成分有多 功能酸，譬如三苯六羧酸、焦苯六羧酸、或三至六價酒精， 譬如三甲醇丙烷、季戊四醇、甘油或對應的氫氧酸。 本發明可用的聚酯最好是可塑的熱塑膠，並且還能被 紡絲與絡筒成爲細絲，聚酯的黏度在0.70至〇.95dl/g之間 本紙張尺度適用中國國家標準（CNS )八4規格（2丨0X297公釐）1〇 —---------------— 丁·______ i ^ i (請先閲讀背面之注意事項再填寫本頁) 589420 A7 B7 濟 部 智 慧 財 產 局 消 費 合 社 印 製 五、發明説明（8 是特別有利的。 根據本發明的方法，聚酯熔漿的熔融及多種熔體的混 合，是經由固定轉速的紡絲幫浦進行的，其轉速可依已知 的計算方式加以調節，以求達到需要的細絲纖度 (TITER)，然後將其壓入噴嘴組合，再經過噴嘴板的噴嘴 孔而成爲熔化的絲。 ~ 熔漿還能由聚合物切片（CHIPS)自擠壓機壓出開 最好先將切片乾燥至含水量低於30ppm，特別要低"人 15ppm爲佳。 熔漿溫度通常稱之爲紡絲溫度，係在紡絲幫浦前谢^ 之，視所使用的聚合物或多種聚合物之混合物的培點定 定，最好定於下面公式1的範圍內： _ 公式1Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 589420 A7 B7 V. Description of the invention (1) The present invention aims to describe a method for spinning and winding a predetermined direction polyester yarn. The predetermined direction polyester yarn produced by the present invention In addition to the predetermined-oriented polyester filaments prepared by the method of the present invention, there is also at least 90% by weight of polybutylene terephthalate (PBT) or polytrimethylene terephthalate (PTMT). Ingredients (preferably PTMT) 'In addition, the present invention also describes a method for producing bulky polyester yarns by spinning and weaving the same polyester yarns and then' stretching and weaving '. The continuous production of polyester yarns, especially polyethylene terephthalate (PET) filaments, using a two-stage process is a known technique. In the first stage, the smooth spinning and winding of the silk are first planned. Then the filaments are stretched into a finished product in the second stage, and then heat-fixed, or made into bulk yarns by an elongation weaving method. F · FOURNE provided some of his opinions in the book "Synthetic Fibers" published by HANSER VERIAG in Munich in 1995. However, when talking about the production of PET fibers, he only mentioned the characteristics of the changes, without Touching the technology of the button. The manufacture of various spinnable polymers, such as polypropylene, polyamide, polyester, etc., is the purpose of German patent application DE-0S 38 19 913, but it can be inferred from the temperature data of the polymer processed by it, but it is not PET fibers are mentioned in the examples made. When continuous production of PTMT or PBT filaments, there is a problem that when the filaments are intended to be stored at room temperature, there will be a significant tendency to shrink. This phenomenon exists after spinning, or when winding, and after the winding The result is that the length of the fiber is shortened and the main body of the spool is compressed. Under extreme conditions, the bobbin itself will shrink tightly on the spool and cannot be removed or removed. This paper applies to Zhongguan Jiayu. Standard (CNS) Μ Specification (2) 〇 > 297 feet 4 (Please read the notes on the back before filling out this page) Order-Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 589420 Α7 Β7 V. Invention Explanation (2) Even the bobbin will become saddle-shaped, with the periphery being hard and centrally recessed. This means that the textile characteristics of the filament, such as USTER, will become unevenly strong at this time. UNSPOOLING PROBLEM occurs during bobbin processing, but this problem can only be solved by limiting the bobbin weight to less than 4 kg, and this problem does not occur during PET processing. And it is observed that, unlike PET filaments, PBT or PTMT filaments are scheduled to undergo accelerated aging during storage. Once structural hardening occurs, the processing shrinkage will be greatly impaired and crystallization will occur. Such PBT or PTMT The silk can only be further processed conditionally. This will cause errors during the elongation weaving process and significantly reduce the tear resistance of the processed thread. As a result, the elongation processing speed and its elongation ratio will decrease. The reason why PET is different from PBT or PTMT is said to be due to its different structure and characteristics. According to International Chemical Fibers Volume 50, page 53, published in 2000, and the International Man-made Fibers Conference held in DORNBIM from September 13th to 15th. , Both have said this, so here we might as well assume that different chain factors are the main causes of their different characteristics. The first to find solutions to these problems is the world patent application WO 99/27168 and the European patent application EP 0 731 196 B1. According to the composition of the polyester fiber disclosed in WO 99/27168, at least 90% by weight of the polymer In addition, the propylene terephthalate has a processing shrinkage ratio of 5% to 16%, an elongation tear of 20% to 60%, and the polyester fiber manufacturing method described in WO 99/27168 is based on Spinning and winding are mainly used. The spinning removal speed referred to in this article can not exceed 2100m / min, but this method is not applicable to the China Standard (CNS) Λ4 specification (210X 297 mm) ~ I " — ^ IF (Please read the precautions on the back before filling this page) 589420 Α7 Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (3) It is economical because of the low speed. Polyester fibers also have strong crystallinity and are not suitable for elongation weaving. EP 0 731 196 B1's method for spinning, elongating and winding of synthetic threads is characterized by the need to undergo heat treatment before winding to reduce its tendency to shrink. Synthetic fibers that are suitable for this method also include PTMT. The heat treatment method adopted is to introduce the synthetic wire tightly into a longitudinal heating surface without contacting each other, thereby increasing the cost of this manufacturing method, and also having the disadvantage of high crystallization, so it is only suitable for further elongation processing. . Elongation processing to PTMT filaments is based on the article entitled "PTMT-based textile fiber elongation processing weaving method" co-authored by Dr. Bai Lang and CHUAH, published in International Chemical Fibers Volume 47, pages 72 to 74 in February 1997. It can be seen that its textile speed is less than 450m / min, because the fibers produced under this condition will have better material properties. It is said that its tear resistance will be between 26.5CN / tex (textile speed 450m / min) to Between 29.15 CNAex (textile speed 850m / min), the tear elongation is 38% (textile speed 450m / min) or 33.5% (textile speed 850m / min). According to the world patent application WO 01/04393, the processing shrinkage range of PTMT is between 3 and 40%, which is measured immediately after the production of this yarn. As shown in Figure 1, it is stored under normal conditions. After four weeks it will drop to 20%. Figure 1 is intended to illustrate the change in processing shrinkage of three PTMT-POY bobbins after they have been stored under normal climatic repair parts for a considerable period of time. The ## 16 and 17 # bobbins all have a higher than 40%. Initially, after storage for 123 weeks, the processing shrinkage will be reduced to more than 30%. Of course, it is better to exceed 40 ° / °° (please read the precautions on the back before filling this page) i0. Order * f This paper size Applicable to Chinese National Standard (CNS) Λ4 specification (210X297 mm) 6 589420 A7 B7 V. Description of the invention (4) If its initial height is higher than 40% as shown in No. 18 bobbin, after four weeks of storage period, Will fall below the critical threshold of 30%. Figure 2 is a plot of the force and expansion of PTMT-POY. If the tear elongation is equal, its natural stretch ratio (NVV) will exceed or equal to 15% as shown in Figure 2 (a), and Figure 2 (b ) Is the case where NVV is equal to 0. Processing shrinkage is a measure of the processability and crystallinity of fibers. According to WO 01/04393, fibers with high crystallinity have poor processability and can only be processed at low elongation ratios and low elongation speeds. In view of the current state of science and technology, the present invention aims to provide a method for manufacturing and winding a PBT-POY or PTMT-POY filament suitable for synthesis of at least 90% by weight of PBT or PTMT. The winding method and method are simplified, especially in terms of tear elongation, which can be set between 90% and 165%, which represents a characteristic of high uniformity and low crystallinity. The present invention also has an incidental task, in providing a method for manufacturing and winding a predetermined direction of polyester yarns on a large technical scale and economic principles. According to the method of the present invention, the removal speed should be as high as possible. It is better to increase it, it is better than 2200m / min, and the weight of the bobbin that can be supported during winding is more than 4kg. Another aspect of the present invention is to improve the storage property of the polyester. It is expected that after using the method of the present invention, it can be stored for a longer time, such as four weeks, and can prevent the spool body from being compressed during storage, especially to avoid the bobbin. Shrink to the center of the axis, so that a saddle is formed (the periphery is hard and the depression is in the middle). If this step can be done, the problem of unfastening or unwinding will not occur during the processing of the bobbin. This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 mm) I 1 ---. ... 1 ---- I— I-II ϋ ϋ (Please read the precautions on the back and fill in this Gong) Order · Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 589420 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7----_ V. Description of the invention (5) According to the present invention, it is expected that Simply perform high-speed processing in the elongation addition, preferably more than 450m / min. The silk obtained by the elongation process should have superior material properties, such as its tear resistance gg at 26CN / tex, which The tear elongation is 30% or more in HE wire (Note: ··· is the abbreviation of German Hoch ELASmZITATS), which represents a type of high ductility filament or yarn. The yarn produced by processing weaving is called more than 36% in Germany). This task, as well as other tasks not mentioned above, can be solved according to the spinning processing and winding method described in the present invention. The characteristics of the households are listed in item 1 of the patent application. In addition, the relevant changes to the method of this issue are also listed in the sub-item of item 1 of the patent application for protection. The planned polyester obtained according to the spinning processing method of the present invention is listed in each Within a single item of protection, if the elongation processing of polyester yarn is scheduled to be listed in item 6 of the patent application, the bulky yarn obtained from the elongation weaving method is listed in item 7 and 8 of the patent application and protection is requested. In order to manufacture a predetermined-oriented polyester yarn containing at least 90% by weight of PBT or PTMT (preferably PTMT), we have been able to successfully produce polyester yarns with excellent physical properties through the following facts, even in After storage for four weeks under normal conditions, no aging or significant damage to its uniformity or unwinding or unwinding of the bobbin occurred during winding: a. Spinning delay was in the range of 70. to 500. b. After the filament comes out of the spinning nozzle, it passes through a cooling delay zone of 30mm to 200mm in length. c. The filaments are cooled below the solidification temperature. J ------— tr ------ · — (Please read the notes on the back before filling in this page) The paper scale is applicable to China National Standard (CNS) A4 (210X 297 mm) Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative 589420 A7 B7 V. Description of the invention (6) d. The filaments are bundled at a distance of 500mm to 2500mm below the nozzle (BUNDLED). e. Before removing the godet roller, the tension of the thread is set between 0.05CN / d tex and 0.20CN / d tex, preferably 0.15CN / d tex. f. Winding of the thread between tension 0.25CN / dtex to 0.15CN / dtex. g. Winding speed is adjusted between 2200m / min and 6000m / min. At the same time, according to the method of the present invention, there are a series of additional advantages as follows:-According to the present invention, simple methods and methods can be used to work on a large scale and economically, especially to allow spinning at a high removal speed of at least 2200 m / min. The wire and the winder work, and at the same time, the weight of the production shaft can exceed 4 kg. As long as the method of the present invention is used, it is possible to eliminate the need for spinning additives, which has the benefit of reducing the production cost of polyester yarns. Once the predetermined-direction polyester yarn obtained by the method of the present invention can be stretched in a simple method and manner, in a large technical scale and economically, and can be further processed at a speed higher than 450 m / min during further stretch weaving processing. As a result of the high uniformity of the predetermined orientation polyester yarn obtained by the method according to the present invention, a good reel design can be provided. This design can also achieve the uniformity of the predetermined orientation polyester yarn and its fault-free surface coloring. And further processability. Once the silk obtained through the elongation weaving method of the present invention has a tear resistance higher than 26CN / tex, and a tear elongation of more than 30% of the HE silk, the paper size is applicable to the Chinese National Standard (CNS) A4 specification ( 210X 297 mm) ~ 1 ~-(Please read the notes on the back before filling this page) L #. Order: Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 589420 A7 B7 V. Description of the invention (7) Length rate and The tear elongation of SET wire exceeds 36% and other advantages. The method described in the present invention relates to a method for producing a predetermined direction polyester yarn and a winding method thereof. The obtained predetermined direction polyester yarn contains at least 90% by weight of PBT or PTMT. For a technician, both PBT and PTMT are Known things, in which PBT can be formed by polymerizing and condensing 1,4 dibutanol with the same molar amount, and PTMT is formed by polymerizing and condensing 1,3 propylene glycol with the same molar amount. For the present invention, a mixture of esters is preferably PTMT. Polyesters can be elemental or copolymers, especially copolymers. In addition to recycled PTMT or PBT units, there are up to 15 mol% by weight repeating polyesters, repeating monomers, such as ethylene glycol , Diethylene glycol, triethylene glycol, 1,4-cyclomethylene dimethanol, polyethylene glycol, and adipic acid. For the purposes of the present invention, polyester monomers are preferred. The polyester of the present invention may have a general amount of additive substances as a mixture, such as a catalyst, a stabilizer, an antistatic agent, an antioxidant, a fire suppressant, a colorant, a colorant absorption modifier, a light stabilizer, an organic phosphorus, and a brightener. The bedding agent and polyester preferably have an additive of 0 to 5% by weight based on the total weight of the filaments. In addition, 'polyester may have a small amount of branching components, and its amount is preferably 0.5% by weight or less based on the total weight of the filaments. The preferred branching components of the present invention are multifunctional acids such as triphenylhexacarboxylic acid and pyrophenylhexacarboxylic acid. Acids, or tri- to hexavalent alcohols, such as trimethylolpropane, pentaerythritol, glycerol or the corresponding hydroxide acid. The polyester usable in the present invention is preferably a plastic thermoplastic, and can also be spun into a filament through spinning and winding. The viscosity of the polyester is between 0.70 and 0.95 dl / g. ) 8 4 specifications (2 丨 0X297mm) 1〇 —---------------— Ding ______ i ^ i (Please read the precautions on the back before filling this page) 589420 A7 B7 Printed by the Consumers' Association of the Ministry of Intellectual Property of the Ministry of Education 5. The invention description (8 is particularly advantageous. According to the method of the present invention, the melting of the polyester melt and the mixing of various melts are carried out through a spinning shaft with a fixed speed. The speed of the pump can be adjusted according to a known calculation method to achieve the required filament fineness (TITER), then press it into the nozzle assembly, and then pass through the nozzle holes of the nozzle plate to become molten silk. The melt can also be extruded from the extruder by polymer chips (CHIPS). It is best to dry the chips to a moisture content of less than 30 ppm, especially lower than 15 ppm. The melt temperature is usually called spinning. Temperature is stated before spinning pump ^ depending on the polymer or polymers used Given training set point of the mixture, preferably set in the range of the following Equation 1: Equation 1 _
Tm+ 15°C < Tsp < Tm + 45〇C 其中Tm爲聚酯熔點（t )Tm + 15 ° C < Tsp < Tm + 45〇C where Tm is the melting point of polyester (t)
Tsp爲紡絲溫度（°c ) 指定的參數是用來限制其含水量或加熱量以降低其黏度 應該是愈低愈好，在本發明而言，最好降低黏^ 0.12dl/g，如能降至〇.08dl/g最爲理想。 '麥 熔漿的均勻度會直接影響細絲的物性，因此，最 紡絲幫浦後面使用一裝有至少一個元件的靜態混合器，土 熔漿均勻。 噴嘴板的溫度，視紡絲溫度而定，由所謂附屬加熱。 控制，可考慮用聯苯（DIPHYL)加熱的紡絲棒或外加 I.--------MW-----^訂------Φ (請先閱讀背面之注意事項再填寫本頁〕 本紙張尺度適用中國國家標準（CNS ) Λ4規格（2Ι〇Χ 297公釐）Η 經濟部智慧財產局員工消費合作社印製 589420 A7 五、發明説明（9 ) 流或輻射加熱器爲附屬加熱器，通常噴嘴板的溫度要與纺 絲溫度一致。 提商噴嘴板的溫度，可由減低噴嘴組合的壓力達成 之，根據1971年出版的“化學_維”第21卷第379頁κ. RIGGERT所著“聚酯簾布線之製法”記載減少每1〇〇bAR 壓力會增高溫度4°C左右。 又用疏鬆的過濾介質，也可控制噴嘴壓力，特別是用 顆粒平均在〇·1至1.2mm之間的鋼砂，特別是在〇·12至 0.75mm之間的爲最佳，或是用小於40細度的圓形過濾片 (此可由金屬纖維或膜製成）均無不可。 此外，降低噴嘴孔的壓力，也有助於總壓力之下降， 噴嘴壓力最好在80至450 bAR之間，特別是在100至250 bAR之間最爲有利。 紡絲延遲lsp，即是移除速度與噴灑速度之商，是根 據美國專利申請US 5 250 245所載的公式2，由聚合物或 多種聚合物之混合物的密度，噴嘴孔的直徑以及個別細絲 的纖度（TITER)計算而得如下： 公式2 lsp=2.25、1〇5、（ 5、7Γ )、D2 ( cm) /dpf ( den) 其中 ά 爲熔漿密度（g/cm3)、PTMT=1.12g/cm3 D爲噴嘴孔直徑（cm)Tsp is the spinning temperature (° c). The specified parameter is used to limit its water content or heating to reduce its viscosity. The lower the viscosity, the better. In the present invention, it is best to reduce the viscosity ^ 0.12dl / g, such as It can be reduced to 0.08dl / g. 'The uniformity of the wheat slurry directly affects the physical properties of the filaments. Therefore, a static mixer equipped with at least one element is used behind the most spinning pump, and the soil slurry is uniform. The temperature of the nozzle plate is determined by the so-called auxiliary heating depending on the spinning temperature. For control, consider using a diphenyl (DIPHYL) heated spinning rod or additional I .-------- MW ----- ^ order ------ Φ (Please read the precautions on the back first Please fill in this page again] This paper size applies Chinese National Standards (CNS) Λ4 specification (2Ι〇 × 297 mm) 印 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 589420 A7 V. Description of invention (9) Flow or radiant heater As an auxiliary heater, the temperature of the nozzle plate is usually the same as the spinning temperature. The temperature of the nozzle plate can be achieved by reducing the pressure of the nozzle combination. According to "Chemical_Dimension", vol. 21, p. 379, published in 1971 κ RIGGERT's "Manufacturing Method of Polyester Curtain Wiring" records that reducing the pressure per 100bAR will increase the temperature by about 4 ° C. Also using a loose filter medium, the nozzle pressure can also be controlled, especially with an average particle size of 0.1 Steel grit between 1.2mm, especially between 0.12 and 0.75mm, or a circular filter with a fineness of less than 40 (this can be made of metal fibers or membranes) is indispensable In addition, reducing the pressure in the nozzle hole also helps to reduce the total pressure. The nozzle pressure is best It is most advantageous between 80 and 450 bAR, especially between 100 and 250 bAR. Spinning delay lsp, which is the quotient of removal speed and spray speed, is based on the formula contained in US patent application US 5 250 245 2. Calculated from the density of the polymer or a mixture of polymers, the diameter of the nozzle hole, and the fineness (TITER) of the individual filaments as follows: Formula 2 lsp = 2.25, 105, (5, 7Γ), D2 ( cm) / dpf (den) where ά is the melt density (g / cm3), PTMT = 1.12g / cm3 D is the nozzle hole diameter (cm)
Dpf —爲個別細絲的纖度（den ) 在本發明的架構下，紡絲延遲在70至500之間，特別是在 1〇〇至250之間爲佳。 J 0-------- 訂·------· (請先閱讀背面之注意事項再填寫本頁) 本纸张尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）12 589420 . A7 B7 五、發明説明（l〇 ) 噴嘴孔的長度/直徑比最好在1.5與6之比，特別是以1.5 與4之比爲理想。 (請先閱讀背面之注意事項再填寫本頁) 壓出的細絲經過冷卻延遲區，在噴嘴組合的正下方， 構成一反彈區，在此區內，自噴嘴孔出來的細絲，被保護 不受冷卻氣體的直接影響，而減速或延遲冷卻，在反彈區 的主動部份，先被導引至紡絲棒，並由參差的噴嘴組合將 其叉開，俾使細絲爲加熱的隔板所圍繞，一被動部份係由 絕緣層及未受熱的架構所形成，主動反彈區的長度在〇至 100mm之間，被動反彈區的長度在20至120mm之間，總 長度要維持在30至200mm，最好是30至120mm之間。 主動反彈區的替代方案爲在紡絲棒之下附加一後續加 熱器，與主動反彈區不同的是此區呈圓柱形或長方形，並 有一與紡絲棒獨立加熱的加熱器。 在放射狀的冷卻系統內，像同心圓似的包圍著細線， 其冷卻延遲功能即由圓柱覆蓋而達成。 然後細絲終於冷卻到固化溫度以下，依本發明而言， 固化溫度係指熔漿轉換成固體的溫度。 經濟部智慧財產局員工消費合作社印製 在本發明的架構下，證明最好是將絲冷卻至不再有黏 性的溫度，如能將其冷卻至結晶溫度，尤其是低於玻璃轉 換溫度之下最爲有利。 技術人員都知道冷卻細絲的方法，依本發明而言，使 用冷卻氣體，尤其是利用冷空氣，是特別有價値的，冷卻 空氣的溫度最好在12 °至35°C之間，尤其在16 °至26°C 之間，冷卻空氣的冷卻速度則以在0.20至〇.55m/SEC之間 尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐）13 經濟部智慧財產局員工消費合作社印製 589420 A7 B7 五、發明説明（11 ) 爲最有利。 個別的成線系統，是由個別的冷卻管與穿過孔的板壁 所組成，可用來冷卻細絲，係主動供應冷卻的空氣，或利 用細絲的自吸現象，達成冷卻每一根細絲目的，個別管的 替代方案是使用橫向吹風。 冷卻及延遲區的一個特別架構爲在一長10到17.5cm 的區域內，提洪冷卻的空氣給延遲區出來的絲使用，其長 度最好是10到80cm，對絡筒後纖度不到1.5d tex的細絲 而言，此區域長度以10至40cm爲佳，而對纖度在1.5至 9.0d tex的細絲而言，此區域長度則以20至80cm爲佳， 其後細絲與空氣同時經過一截面積漸小的通道，空氣與細 絲速度比爲0.2至20比1，最好是0·4至5比1，移除的 設定則由朝細絲機方向的截面積縮小及尺寸變化控制之。 當細絲溫度冷卻到固化溫度以下之後，細絲就被捆束 成線，束絲距離自噴嘴底側開始算起，此對本發明而言， 是比較合適的，然後依一般技術人員已知的方法計算之， 即由線上測量速度或線上測量溫度法決之，譬如用德國 TSI公司出品的雷射/都普勒風速計或GORATEC公司出品 的型號IRRIS 160紅外線攝影機均無不可，其距離在500 至2500mm之間，最好是在500至1800mm之間，纖度小於 3.5 d tex的細絲最好束絲距離在小於1500mm，較厚的細 絲，則須在更長的距離捆束。Dpf is the fineness (den) of individual filaments. Under the framework of the present invention, the spinning delay is between 70 and 500, especially between 100 and 250. J 0 -------- Order · ------ · (Please read the notes on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 12 589420. A7 B7 V. Description of the invention (10) The length / diameter ratio of the nozzle hole is preferably 1.5 to 6, especially the ratio of 1.5 to 4 is ideal. (Please read the precautions on the back before filling in this page) The extruded filament passes through the cooling delay zone and forms a rebound zone directly below the nozzle assembly. In this zone, the filament coming out of the nozzle hole is protected It is not directly affected by the cooling gas, but decelerates or delays cooling. In the active part of the rebound zone, it is first guided to the spinning rod, and it is split by a combination of nozzles, so that the filaments are heated. Surrounded by the board, a passive part is formed by an insulating layer and an unheated structure. The length of the active rebound area is between 0 and 100 mm, and the length of the passive rebound area is between 20 and 120 mm. The total length must be maintained at 30. To 200mm, preferably 30 to 120mm. An alternative to the active rebound zone is to add a subsequent heater under the spinning rod. The difference from the active rebound zone is that the zone is cylindrical or rectangular and has a heater that is heated independently from the spinning rod. In the radial cooling system, a thin line is enclosed like a concentric circle, and its cooling delay function is achieved by covering the cylinder. The filaments are finally cooled below the solidification temperature. According to the present invention, the solidification temperature refers to the temperature at which the melt is converted to a solid. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs under the framework of the present invention, it is proved that it is best to cool the wire to a temperature no longer sticky, if it can be cooled to the crystallization temperature, especially below the glass transition temperature The next most favorable. The skilled person knows the method of cooling filaments. According to the present invention, the use of cooling gas, especially cold air, is particularly valuable. The temperature of the cooling air is preferably between 12 ° and 35 ° C, especially at Between 16 ° and 26 ° C, the cooling rate of the cooling air is in the range of 0.20 to 0.55m / SEC, which applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm). 13 The Consumer Property Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Printing 589420 A7 B7 5. The invention description (11) is the most advantageous. The individual wire-forming system is composed of individual cooling pipes and the wall of the plate that passes through the hole. It can be used to cool the filaments, which is the active supply of cooling air or the self-priming phenomenon of the filaments to achieve the cooling of each filament. Purpose, an alternative to individual tubes is to use a lateral blower. A special structure of the cooling and delay zone is that in a region of 10 to 17.5 cm in length, the air from the flood zone is used for the filaments from the delay zone. The length is preferably 10 to 80 cm, and the fineness after the winding is less than 1.5. For filaments of d tex, the length of this area is preferably 10 to 40 cm, and for filaments of fineness of 1.5 to 9.0 d, the length of this area is preferably 20 to 80 cm. At the same time, after passing through a passage with a smaller cross-sectional area, the air-to-filament speed ratio is 0.2 to 20 to 1, preferably 0.4 to 5 to 1. The setting removed is reduced by the cross-sectional area toward the filament machine and Controlling dimensional changes. When the temperature of the filaments is cooled below the curing temperature, the filaments are bundled into strands, and the distance between the filaments starts from the bottom side of the nozzle. This is more suitable for the present invention, and then known to those skilled in the art Calculated by the method, that is, determined by the online measurement speed or online temperature method, such as the use of a laser / Doppler anemometer produced by the German TSI company or a model IRRIS 160 infrared camera produced by the GORATEC company. Between 2500mm, preferably between 500 and 1800mm, filaments with a fineness of less than 3.5 d tex are preferably bundled at a distance of less than 1500mm, and thicker filaments must be bundled at a longer distance.
在本發明架構下，所有與細絲接觸的表面，必須由低 摩擦力物質製成，如此，可以完全避免線端（THREAD 本紙悵尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） ----------0-----.1T------· (請先閱讀背面之注意事項再填寫本頁) 14 經濟部智慧財產局員工消費合作社印製 589420 A7 ______B7 五、發明説明（12 ) ENDS)的形成，並可生產高價位的細絲，德國CERMATEC 公司出品的低摩擦表面「TRIBO fil」證明是特別適用的。 細絲的捆束，係在一加油裝置中進行，由此裝置提供所 需要的紡絲劑給細絲，一特別適用的加油機，其特徵爲： 有一進料部份，一個附有進油孔的絲通道，還有一出料部 份’其進料部份裡面大得似漏斗狀，如此設計，庶可避免 其時還有乾的細絲與之接觸，絲通道及進油孔二者的寬度 可依細絲的纖度及其數量調節之，適當的油孔及寬度應在 1.0至4.0mm之間，其出料部份被設計爲攪拌區，最好內 有油箱，此種加油裝置可自德國CERMATEC公司或美國 GOULSTON公司購得。 依本發明而言’均句的使用油是有極大幫助的，根據 1992年11月出版的化學纖維—紡織工業雜誌第42/94期第 896頁所載，此可由ROSSA量器測之，使用此種方法量測 油覆標準偏差値應在90 diGIT以下，最好不要超過，但 本發明偏好的油覆標準差値是在45以下，特別以低於3〇 爲最理想。油覆標準差値90或45相當於&2%或3.1%的變 異係數。 在本發明的架構下，管線與幫浦設計，則以能自行排 氣’以防止氣泡的形成最爲有利，此與氣泡會導致油於使 用時發生振盪有關。 依本發明所見’在絡筒之前最好先交織 (mTER-WEAWNG)，是故，噴嘴附有封閉的通道，是特 別合適的’因爲如此設計’於交織時縱使線的張力低而空 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公^ -- ----------0^-----*-—11------· (請先閱讀背面之注意事項再填寫本頁) 589420 A7 B7 五、發明説明（l3 ) 氣壓力高，仍可避免線在***孔中發生勾線的問題，交織 噴嘴最好裝在導絲輥之間，如此線的出口張力被風的進入 與排出不同速度所節制，就不會超過0.5 CN/dtex，但基本 上其値仍應在0.05與0.15 CN/d tex之間，而其時捲入的 空氣壓力應在0.5至5.5bAR之間，而絡筒速度達3500m/min 時，其空氣壓力至多是3.0 bAR。 結點數（NODE NUMBER)最好設定在l〇n/m，所以 最大的縫隙長度如低於l〇〇cm與結點的變異係數低於100% 係特別有利的，當使用的空氣壓力超過1.0 bAR，結點數 就會高於15n/m，其特徵是高均勻度。由此，其變異係數 爲低或等於70%，最大縫隙長度爲50cm，在實務上，德國 FAMCO公司出品的LD型的系統裝置，美國SLACK & PARR 公司的雙系統裝置或是HEBERLEIN公司的POLYJET型噴 嘴都是特別合用的選擇。 導絲輥（GALETTE)周圍速度被稱爲移除速度，在線 圏內的線，捲在筒管成形體（捲軸）及筒管之前，可使用 額外的導絲輥。 穩定、無失誤的筒管成形體，乃是絲線無失誤移除以 及未來作進一步無失誤加工的先決條件，因此，在本發明 的架構下，捲線張力應在0.025至〇·15 CN/d tex的範圍內， 最好是在0.03至0.08 CN/d tex之間。 對本發明的方法而言，有一項重要的參數，與細線在 移出之前或在導絲輥之間的張力調節有關，此處所說的張 力主要包括以HAMANA量器所測定的實際定向張力，導絲 ‘本纸浪尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐）16 —. -- (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 589420 A7 B7 五、發明説明（14 ) 器與加油裝置上的摩擦應力’以及線與空氣摩擦應力比， 在本發明的架構下，線在移出前與在導絲輥之間的張力應 在0.05 至 0.20CN/d tex 之間，最好是在 0.08 至 0·15 CN/d tex 之間。 過低的張力，如低於〇·〇5 CN/d tex，一定不會產生預 期的預定向水準，如張力超過〇·2〇 CN/d tex，則此張力就 會對絡筒中的筒管以及儲存期間的筒管發生一種記憶效 應，因而導致線的特性値爲之劣化。 依據本發明，張力可由加油器與噴嘴間的距離，其摩 擦表面以及加油器與移出輥間的間隙長度調節之，該間隙 長度以不超過6_0m爲佳，最好要低於2.0m，是故，紡絲 機與移出機二者安裝的位置，如果是平行的，就能確保細 線加工，成直線地進行。 絲線在捆束點與絡筒加工間的時間調節 (CONDITIONING TIME)，可以幾何參數說明之，在此段 須快速進行加工的時間內，若稍有鬆弛，足以影響捲軸的 品質。 所謂調節的時間，最好選在50至200毫秒（MS)之 間。 又依據本發明的POY絡筒速度，是在2200m/min與 3500m/min 範圍內。 在依據本發明方法執行工作時的一個有利狀況，就是 筒管鄰近的溫度爲小於45°C，最好在12至35°C之間，相 對溼度在40至85%之間，在進一步加工前的POY，其顧存 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公慶）^ —. 衣-- (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 589420 A 7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（l5 ) 期間的溫度要小於或等於45°c，此外，POY捲軸（SPOOLS) 在進一步加工前，在溫度12至35°C以及相對溼度40至85% 條件下至少儲存四個小時最爲合適。 依本發明的方法所得的細絲，在正常狀況的條件儲存 4週之後，有以下優點： a·其撕裂伸長率在90至165%之間，最好在90至135% 之間。 b.加工收縮率最少30%，但以大於或等於40%爲佳。 c·正常烏絲特低於1.1%，最好是〇·9%以下。 d·雙折射率在0.030與0.058之間。 e.密度低於1.35g/cm3，最好小於1·33 g/cm3。 f·最大張力強度變異係數小於或等於4.5%，最好是小 於或等於2.5% 〇 g·撕裂伸長變異係數小於或等於4.5%，最好是小於或 等於2.5%。 所謂“正常狀況”，其意義對技術人員而言是已知 的，在德國工業標準DIN 53802是有明文規定的。依DIN 53802規定，正常狀況是指溫度在20 °加減2°C之間，相 對溼度在65加減2%之間。 依本發明的架構，還有額外的好處，是加工收縮率， 如在絡筒後立即測之，應在50至65%之間，如有正常狀況 下儲存四週之後會降低至30%，最好是大於或等於40%， 又有驚訝的發現，以此種方式生產的P0Y捲軸可供進一步 加工’其成效又必顯著。 (請先閱讀背面之注意事項再填寫本頁) # 訂 本纸張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） 18 589420 A7 B7 五、發明説明（l6 ) 在此關係上，我們不禁要考慮到一個現實問題，就是 實務上，無論在POY生產、儲存或運輸時，是無法永遠維 持所謂正常氣候狀況的，一旦線的結晶現象出現’縱然其 程度十分輕微，此後就會經常發生POY捲軸變形，伸長比 率與紡織速度降低以及於進一步加工時有斷裂等問題，不 過，細線如能維持上述加工收縮規格，其降低程度要比傳 統細線要輕得多。 此外，本發明偏好的細絲，縱儲存2個月也不會改變 DTY顏色的深度，在儲存20個月後；其顏色的改變，如 環境溫度不高於451的話，應在95加減3%之間。 再者，本發明偏好的細絲，其自然伸長比在大於或等 於15%之間，特別好的時候，此値應在18至65%範圍內， 自然伸長比愈高，其伸長性會愈好，在同等膨脹條件下， 高自然伸長比的絲，就能達到更高的伸長比率。 自然伸長比爲力與膨脹曲線對比圖的源頭，以百分比 表示的，此値向來是測量強度與膨脹率的方法中所使用的 撕裂裝置所決定的。 第2圖a與第2圖b係以圖解方式說明，自然伸長比 (NVV)的特性値，在第2圖b中的NVV是零，當力施於 圖中膨脹線上後，就可由圖表上呈現的情形，來說明此値 的變化。 吾人茲假定自然伸長比是量測絲線定向的一種標準， NVV値小於15%，代表聚酯的初期結晶化，低的NVV値 是可由絲線的熱處理提高至絡筒溫度達成的，絡筒溫度至 本纸张尺度適用巾國國家標準（CNS ) Λ4規格（2l〇x 297公幻19 —--------MW— (請先閲讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作社印製 589420 A7 B7 五、發明説明（17 ) 少要比PES玻璃轉換溫度高。 決定上述材料特性値的方法，對技術人員而言，是已 知的，此可由技術文獻中得之，雖然，決定大多數參數的 方式，都不相同，但下列方法，在本發明已獲證明都特別 適合用來決定細絲的特性數據。 固有黏度可於25°C溫度下，用UBBELOHDE公司的毛 細管粘度計測量，然後再依現在已知的計算式計算之，酣 與1，2二氯苯混合物可用來作溶劑，其重量比爲3:2，溶液 濃度是〇.5g聚酯對l〇〇ml溶液。 METTLER公司的一種DSC量熱計可用來量測熔點， 結晶溫度以及玻璃轉換溫度，在此，先將樣品加熱至280 °C，熔化後再驟然冷卻之，DSC量測係在20至280°C溫度 範圍內以每分鐘加熱10度的方法進行，其溫度値則由處理 器定之。 (請先閱讀背面之注意事項再填寫本頁) I - % 参· T · 、τ 經濟部智慧財產局員工消費合作社印製 細絲密度是由密度/梯度管在溫度23加減O.rC下測 定的，所用的試劑有正庚烷及四氯甲烷，如以無定形聚酯 的密度Da與結晶聚酯的密度Dk爲基準可由密度量測的結 果來計算細絲的結晶度，茲以PTMT爲例，依文獻所載之 方法計算之，則： Da=l .295g/cm3 ； Dk=l .429g/cm3 細絲的纖度（TITER)是用一現成的精密捲線機與一 重量計測知的，POY細絲的預應力（PRESTRESSING)爲 0.05 CN/d tex，紡織加工線（DTY)的預應力爲0.2 CN/d tex。 抗撕裂性及撕裂伸長率是由STATIMAT量器依下開條 本纸張尺度適用中國國家標準（CNS ) Λ4規格（210父29*7公釐〉2〇 經濟部智慧財產局員工消費合作社印製 589420 A7 __B7__ 五、發明説明（is ) 件決定的，夾子長度在POY爲200mm，在DTY爲500 mm ; 量測速度在POY爲2000 mm/in，在DTY爲1500 mm/in ;預 應力在 POY 爲 0.05 CN/d tex，在 DTY 爲 0.2CN/dtex，抗撕 裂性還可由纖度除以最大張力値得之，同時，撕裂伸長率 可於最大承載時算得之。 量測絲條（STRANDS OF FILAMENTS)的加工收縮値 係在水中無張力狀態下進行，水溫爲95加減4°C，歷時10 加減Imin，絲條是由捲絲機製成，其預應力爲〇.(β CN/d tex (POY)或0_2 CN/d tex (DTY)，量測絲條長度在溫度處理 前或後進行均可，其預應力在0.2 CN/d tex，其加工收縮率 則依一般已知方式，就絲條不同長度計算之。 雙折射率可依德國專利申請DE 19 519 898方法決定 之，詳如DE 19 519 898所載。 紡織加工的起皴値，可依德國工業標準DIN 53840， 第1部份所載在溫度120 °C下用德國STEIN公司的 TEXTUMET量器測知的。 正常烏絲特値是用4 CX烏絲特計測定的，以烏絲特％ 表示之，其測試速度爲1〇〇 m/min，測試時間爲2·5 min。 本發明的POY能以簡易方式作進一步的加工，特別是 在伸長加工織法上，在本發明的架構下，伸長加工織法最 好是每分鐘高於500m速度進行，如能在每分鐘高於700rn 速度加工爲最好，伸長比最好爲超過1:1.35，特別有利的 是1:1·40或以上，伸長加工如能使用高溫加熱型，譬如 BARMAG公司出品的AFK機，則是特別合適的。 本纸張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐）21 "~ ----------费----------訂------- (請先閱讀背面之注意事項再填寫本頁) 589420 A7 B7 五、發明説明（l9 ) (請先閱讀背面之注意事項再填寫本頁) 以此種方式產製的膨鬆絲，線頭（THREAD ENDS)不 多’而且，在95°C溫度加工條件下，用沒有載體的分散著 色劑著色後（TERASIL海藍色），會呈現十分優越的著色 深度及均勻性。 依照本發明方法產製的膨鬆絲最好能有超過26 CN/d tex的抗撕裂性，以及36%以上的撕裂伸長率，就HE膨鬆 絲而言（註：HE是德國名詞，爲HOCH ELASITIZITATE 的縮寫，代表一種高延展性的細絲）。它可在第二加熱器製 之，無需加熱，即可製得，其抗撕裂性最好在26 CN/d tex 以上，撕裂伸長値要高於30%。 依本發明方法製得的細絲，其墊襯（PAD)彈性均極 佳。 茲以下列實驗例說明本發明使用的方法，但本發明的 範圍並不受這些實驗例的限制。 實驗例1至2 結絲與絡筒 經濟部智慧財產局員工消費合作社印製 PTMT片（CHIPS)的固有黏度爲0.93dl/g，其熔化黏 度爲325 Pas (在2.4 Hz及255°C溫度條件下測得），其熔 點是227°C，結晶溫度72°C，玻璃轉換溫度45°C，用混合 攪拌乾燥機在130t溫度下乾燥之，至其含水量到達llppm 止，然後將其放在BARMAG公司的3E4型壓出成型機熔 化之.，至熔體溫度達255°C，然後經過產品線被送至紡絲 幫浦，其中有一 SULZER公司SMX型的靜電攪拌機，內 有15個元件，內徑爲15mm，被輸送的熔體量爲63 g/min， 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐） 22 589420 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（2〇 ) 滯留時間爲6min，自紡絲幫浦送入噴嘴組合的數量大槪是 30·7 g/min，靜電器攪拌機內有一個元件，爲FLUITEC出 品，HD-CSE型，內徑爲10mm，被安裝在紡絲幫浦之後， 而在噴嘴組合入口之前，產品線與紡絲段的附屬加熱裝 置，包括幫浦及噴嘴組合，其溫度被設定在255°C，噴嘴 組合包含有350至500微米大小，高30mm的鋼砂作成的 過濾介質，20微米的濾膜（過濾器），以及40微米纖維織 成的濾片，此後，熔漿經過80mm直徑的噴嘴板被壓出， 噴嘴板上有34個直徑0.25的孔，長1.〇111111，其噴嘴壓力 約 120 bAR。 冷卻延遲區的長度爲100mm，其中30mm爲加熱分隔 牆，70mm爲絕緣的未加熱的架構，其後，熔化的線在一 吹軸中被冷卻，此吹軸爲橫向吹，距離長達1500mm，冷 風速爲0.35 m/sec，溫度是18°C，其相對溼度爲80%，細 絲的固化點距紡絲噴嘴下方約800mm之處。 細線在距離噴嘴1050mm之處因得一細線加油器所給 紡絲劑之助而束絲，此加油裝置有一 TRIBOFIL表面，其 進入孔直徑爲1mm，所給的藥劑量爲相對於全部線的重量 之 0.40 % 〇 細線在捆束後被送至絡筒機，加油裝置與第一移除輥 間的距離爲3.2m，調節時間（CONDITIONING TIME)視速 度而定，在144至168ms之間，一對移除輥被細線環繞成 S狀，一在1·5 bAR空氣壓力下操作的TEMCO公司製造的 交織噴嘴就被安裝在移除輥之間，爲符合速度調節的需 本紙張尺度適用中國國家標準（CNS ) 規格（210X 297公釐） 23 (請先閲讀背面之注意事項再填寫本頁) 訂 589420 A7 B7 五、發明説明（21 要，BARMAG公司的SW6型捲繞紗線的機具（WINDING DEVICE)就被設定在相當於絡筒張力5 CN的情況下，其 室溫爲24°C，相對溼度60%，從而，筒管周邊的溫度也被 定在34°C左右。 在本實驗架構下，移除速度在實驗例1爲2940 • m/min，在實驗例2爲2506 m/min，下面表1代表額外的 實驗參數，表2則是POY的特性値，這兩套設定都可製得 10 kg的捲軸（SPOOL)，而且皆能自筒管裝置上移下，不 生任何問題。 表1 :實驗參數 實驗例1 實驗例2 移除速度 〔m/min〕 2940 2506 絡筒速度 〔m/min〕 2926 2500 紡絲延遲 178 152 細線張力 在導絲輥前⑴ .〔cN〕 14 10 在導絲輥之間⑴最大 〔cN〕 11 7.5 碰、縛蹴(2) 〔cN/dtex〕 0.13 0.08 在導絲輥之間(2)最大 〔cN/dtex〕 0.10 0.06 細線絡筒張方（1) '1 〔cN〕 5.0 5.0 細線絡筒張力(2) L-- 〔cN/dtex〕 0.048 0.048 (1) 絕對 (2) 與纖ϋ相對値 成張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) ---訂 經濟部智慧財產局員工消費合作社印製 24 589420 B7 五、發明説明（22 ) 表2 :預定向PTMT細絲 随特性値 -—— 實驗例1 實驗例2 纖度 〔dtex〕 105 123 抗撕裂性 〔cN/dtex〕 23.4 20.7 撕裂伸長率 ' 1^---- (%] 98 127 正常烏絲特 (%) 0.9 0.76 加工收縮 〔％〕 46 33 雙折射率xlO3 Δη 52 43 密度 〔g/cm3〕 1.320 1.318 虽 〔 ％〕 2.2 1.9 CV-撕裂伸長率 〔％〕 2.2 1.9 CV :變異係數 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印t (1):在正常狀況下儲存四週後所測 伸長加工織法： 將PTMT絲軸在德國工業標準DIN 53802所載之正常 氣候下，儲存四星期，然後被送至BARMAG公司製造的 FK6-S-900型的伸長紡織機加工，下面表3代表所產生的 SET細絲（註：SET係由一特定的紡織加工程序所產的絲， 在德國有“假扭轉紗”之稱）之實驗參數，表4爲膨鬆SET 絲的實驗參數。Under the framework of the present invention, all surfaces in contact with the filaments must be made of a low-friction substance. In this way, the wire ends can be completely avoided (THREAD paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) ---------- 0 -----. 1T ------ · (Please read the precautions on the back before filling out this page) 14 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 589420 A7 ______B7 5. Description of the invention (12) ENDS), and can produce high-priced filaments, the low-friction surface "TRIBO fil" produced by the German company CERMATEC proves to be particularly applicable. The bundling of filaments is performed in an oiling device, which provides the required spinning agent to the filaments. A particularly suitable oiling machine is characterized by: a feeding part, and an oiling attachment The silk channel of the hole also has a discharge part. Its feed part is as large as a funnel. In this design, it can prevent dry filaments from contacting it at the same time, both the silk channel and the oil inlet. The width can be adjusted according to the fineness and quantity of the filaments. The appropriate oil hole and width should be between 1.0 and 4.0mm. The discharge part is designed as a mixing zone. It is best to have a fuel tank inside. It can be purchased from German company CERMATEC or American GOULSTON. According to the present invention, the use of oil is extremely helpful. According to the chemical fiber-textile industry journal, published in November 1992, 42/94, page 896, this can be measured by a ROSSA meter and used. The standard deviation 油 of the oil coating measured by this method should be below 90 diGIT, and it is better not to exceed it, but the standard deviation 油 of the oil coating preferred by the present invention is 45 or less, and the most preferable is less than 30. The standard deviation of oil cover 値 90 or 45 is equivalent to a coefficient of variation of & 2% or 3.1%. Under the framework of the present invention, the design of pipelines and pumps is most advantageous in that the gas can be vented on its own to prevent the formation of air bubbles. This is related to the air bubbles that cause the oil to oscillate during use. According to the present invention, 'mTER-WEAWNG' is best to be interlaced before the winding. Therefore, the nozzle has a closed channel, which is particularly suitable 'because of this design' when interlacing, even if the thread tension is low, the paper is empty. Standards are applicable to China National Standard (CNS) A4 specifications (210X297 male ^----------- 0 ^ ----- * -— 11 ------ · (Please read the Please fill in this page again) 589420 A7 B7 V. Description of the invention (l3) High air pressure can still avoid the problem of thread hooking in the insertion hole. The interlacing nozzle is best installed between the godet rollers. The outlet tension is controlled by the different speeds of the wind entering and exiting, and it will not exceed 0.5 CN / dtex, but basically its pressure should still be between 0.05 and 0.15 CN / d tex, and the air pressure involved at that time should be between Between 0.5 and 5.5 bAR, and when the winding speed reaches 3500 m / min, the air pressure is at most 3.0 bAR. The NODE NUMBER is best set to 10n / m, so the maximum gap length is less than l00cm and the coefficient of variation of the node below 100% are particularly advantageous. When the air pressure used exceeds 1.0 bAR, the number of nodes will be higher than 15 n / m, which is characterized by high uniformity. Therefore, its coefficient of variation is low or equal to 70%, and the maximum gap length is 50cm. In practice, the German LD-type system device produced by FAMCO company in Germany, SLACK & PARR The company's dual system device or HEBERLEIN's POLYJET nozzle are particularly suitable choices. The speed around the guide roller (GALETTE) is called the removal speed, and the line in the coil is wound on the bobbin forming body (reel). Before the bobbin, an additional godet roller can be used. A stable and error-free bobbin forming body is a prerequisite for the error-free removal of the yarn and further error-free processing in the future. Therefore, under the framework of the present invention, The tension of the winding wire should be in the range of 0.025 to 0.15 CN / d tex, preferably 0.03 to 0.08 CN / d tex. For the method of the present invention, there is an important parameter, which is related to the fine line before it is removed or The tension adjustment between the godet rollers is related to the actual orientation tension measured by the HAMANA gauge. The guide wire 'paper scale is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 (%) 16 —.-(Please read the precautions on the back before filling out this page) Order printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 589420 A7 B7 V. Description of the invention (14) Friction stress on the device and fueling device ' As well as the frictional stress ratio of the wire to the air, under the framework of the present invention, the tension between the wire and the godet before being removed should be between 0.05 and 0.20 CN / d tex, preferably between 0.08 and 0 · 15 CN / d tex. Too low tension, such as below 0.005 CN / d tex, will not produce the expected level of intended direction. If the tension exceeds 0.20 CN / d tex, this tension will affect the bobbin in the winder. And a memory effect occurs on the bobbin during storage, which causes the characteristics of the thread to deteriorate. According to the invention, the tension can be adjusted by the distance between the oiler and the nozzle, the friction surface and the length of the gap between the oiler and the removal roller. The gap length is preferably not more than 6_0m, and preferably less than 2.0m. If the installation positions of the spinning machine and the removal machine are parallel, the thin wire processing can be ensured to be performed in a straight line. CONDITIONING TIME between the binding point of the yarn and the processing of the winding can be explained by geometric parameters. If there is a slight slack in this period of time that must be processed quickly, it will be enough to affect the quality of the reel. The adjustment time is preferably selected between 50 and 200 milliseconds (MS). According to the invention, the POY winder speed is in the range of 2200m / min and 3500m / min. An advantageous condition when performing work according to the method of the present invention is that the temperature near the tube is less than 45 ° C, preferably between 12 and 35 ° C, and the relative humidity is between 40 and 85%, before further processing POY, its paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297 public holidays) ^ —. Clothing-(Please read the precautions on the back before filling this page) Order the staff of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative 589420 A 7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. The temperature during the description of the invention (l5) must be less than or equal to 45 ° c. In addition, the POY scroll (SPOOLS) must be at It is most suitable to store at least 4 hours at 12 to 35 ° C and 40 to 85% relative humidity. The filaments obtained according to the method of the present invention have the following advantages after 4 weeks of storage under normal conditions: a. Their tear elongation is between 90 and 165%, preferably between 90 and 135%. b. The processing shrinkage is at least 30%, but preferably greater than or equal to 40%. c. Normal Uster is below 1.1%, preferably below 0.9%. d. The birefringence is between 0.030 and 0.058. e. The density is less than 1.35 g / cm3, preferably less than 1.33 g / cm3. f · The coefficient of variation of the maximum tensile strength is 4.5% or less, preferably 2.5% or less. g · The coefficient of variation of the tear elongation is 4.5% or less, preferably 2.5% or less. The meaning of the so-called "normal condition" is known to the skilled person, and is specified in the German Industrial Standard DIN 53802. According to DIN 53802, the normal condition means that the temperature is between 20 ° plus or minus 2 ° C, and the relative humidity is between 65 plus or minus 2%. According to the framework of the present invention, there is an additional benefit, that is, the shrinkage rate of processing. If measured immediately after winding, it should be between 50 and 65%. If it is stored for four weeks under normal conditions, it will be reduced to 30%. Fortunately, it is greater than or equal to 40%, and I was surprised to find that the POY reel produced in this way can be used for further processing, and its effect must be significant. (Please read the notes on the back before filling in this page) # The size of the paper is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 18 589420 A7 B7 V. Description of the invention (l6) In this connection, We can't help but consider a practical issue, that is, in practice, no matter what the so-called normal climatic conditions cannot be maintained forever during POY production, storage or transportation, once the crystallization of the line appears' even if its degree is very slight, it will often be frequent thereafter. Problems such as POY reel deformation, reduced elongation and spinning speed, and breakage during further processing have occurred. However, if the thin thread can maintain the above-mentioned processing shrinkage specifications, the reduction will be much lighter than the traditional thin thread. In addition, the preferred filament of the present invention does not change the depth of DTY color after 2 months of storage. After 20 months of storage, the color change, such as the ambient temperature is not higher than 451, should be increased or decreased by 3% at 95%. between. Furthermore, the preferred filament of the present invention has a natural elongation ratio of 15% or more. When it is particularly good, it should be in the range of 18 to 65%. The higher the natural elongation ratio, the more extensible it will be. Well, under the same expansion conditions, a yarn with a high natural elongation ratio can achieve a higher elongation ratio. The natural elongation ratio is the source of the comparison graph of the force and expansion curve, expressed as a percentage. This direction has always been determined by the tearing device used in the method of measuring the strength and expansion rate. Figure 2a and Figure 2b illustrate the characteristics of the natural elongation ratio (NVV) 图解. The NVV in Figure 2b is zero. When a force is applied to the expansion line in the figure, it can be shown on the chart. The situation presented to illustrate this change. We hereby assume that the natural elongation ratio is a standard for measuring the orientation of silk threads. NVV 値 is less than 15%, which represents the initial crystallization of polyester. Low NVV 値 can be achieved by increasing the temperature of the silk heat treatment to the winding temperature. The size of this paper is applicable to the national standard (CNS) Λ4 specification (2l0x 297 public magic 19 —-------- MW— (Please read the precautions on the back before filling this page) Order · Ministry of Economic Affairs wisdom Printed by the Consumer Cooperative of the Property Bureau 589420 A7 B7 V. Description of the invention (17) It is less than the PES glass transition temperature. The method for determining the above-mentioned material properties is known to the skilled person, which can be found in the technical literature In conclusion, although the methods for determining most parameters are different, the following methods have been proved to be particularly suitable for determining the characteristic data of filaments in the present invention. Intrinsic viscosity can be used at 25 ° C using UBBELOHDE Measured by the company's capillary viscometer, and then calculated according to the calculation formula now known. A mixture of rhenium and 1,2 dichlorobenzene can be used as a solvent. Its weight ratio is 3: 2 and the solution concentration is 0.5 g of polyester. l〇〇ml A DSC calorimeter from METTLER can be used to measure the melting point, crystallization temperature and glass transition temperature. Here, the sample is heated to 280 ° C, melted and then cooled suddenly. The DSC measurement is between 20 and 280. The temperature range is ° C, which is heated by 10 degrees per minute, and the temperature is determined by the processor. (Please read the precautions on the back before filling this page) I-% ·· T · τ Intellectual property of the Ministry of Economic Affairs The density of filaments printed by the Bureau's consumer cooperative is measured by the density / gradient tube at a temperature of 23 plus or minus O.rC. The reagents used are n-heptane and tetrachloromethane. The density of the ester Dk can be used as a reference to calculate the crystallinity of the filaments from the results of density measurement. Here, PTMT is taken as an example and calculated according to the method contained in the literature, then: Da = l.295g / cm3; Dk = l.429g / cm3 The fineness of the filament (TITER) is measured using a ready-made precision winding machine and a weight meter. The prestress of the POY filament is 0.05 CN / d tex, and the prestress of the textile processing line (DTY) is 0.2 CN / d tex. Tear resistance and tear elongation are determined by STATI The MAT gauge is based on the following paper. The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210 father 29 * 7 mm> 20) printed by the employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 589420 A7 __B7__ V. Description of the invention (is ), The length of the clamp is 200mm at POY and 500 mm at DTY; the measuring speed is 2000 mm / in at POY and 1500 mm / in at DTY; the pre-stress is 0.05 CN / d tex at DTY and at DTY For 0.2CN / dtex, the tear resistance can also be obtained by dividing the fineness by the maximum tension. At the same time, the tear elongation can be calculated at the maximum load. The measuring shrinkage of STRANDS OF FILAMENTS is performed under tension in water. The water temperature is 95 ° C plus or minus 4 ° C, which lasts 10 minus Imin. The yarn is made by a winding machine, and its prestress is 〇. (Β CN / d tex (POY) or 0_2 CN / d tex (DTY), the length of the wire can be measured before or after the temperature treatment, its prestress is 0.2 CN / d tex, and its processing shrinkage is According to generally known methods, different lengths of yarn are calculated. The birefringence can be determined according to the method of German patent application DE 19 519 898, as detailed in DE 19 519 898. The starting point of textile processing can be determined according to Germany The industry standard DIN 53840, part 1 is measured at a temperature of 120 ° C with a TEXTUMET measuring instrument from the German company STEIN. Normal Uster is measured with a 4 CX Uster meter, with Uster% In other words, the test speed is 100 m / min and the test time is 2.5 minutes. The POY of the present invention can be further processed in a simple manner, especially on the elongation weaving method, under the framework of the present invention. The elongation weaving is best performed at a speed higher than 500m per minute, if it can be higher than 700rn per minute The speed processing is the best, and the elongation ratio is more than 1: 1.35, which is particularly advantageous is 1: 1 · 40 or more. The elongation processing is particularly suitable if it can use a high-temperature heating type, such as the AFK machine from BARMAG. The paper size applies to the Chinese National Standard (CNS) Α4 specification (210 × 297 mm) 21 " ~ ---------- fee ---------- order ---- --- (Please read the notes on the back before filling this page) 589420 A7 B7 V. Description of the invention (l9) (Please read the notes on the back before filling this page) The bulky yarn produced in this way, There are not many THREAD ENDS '. Moreover, under 95 ° C processing conditions, after coloring with a dispersing colorant without a carrier (TERASIL sea blue), it will show very good color depth and uniformity. According to the method of the present invention The produced bulky yarn should have a tear resistance of more than 26 CN / d tex and a tear elongation of more than 36%. For HE bulky yarn (Note: HE is a German term for HOCH ELASITIZITATE (Abbreviation for "high ductility filament"). It can be made in a second heater without heating. The tear resistance is preferably above 26 CN / d tex, and the tear elongation is higher than 30%. The filaments prepared according to the method of the present invention have excellent padding (PAD) elasticity. The following experiments are performed. The examples illustrate the methods used in the present invention, but the scope of the present invention is not limited by these experimental examples. Experimental Examples 1 to 2 Intrinsic viscosity of printed PTMT tablets (CHIPS) produced by the Consumer Cooperatives of the Intellectual Property Bureau of the Intellectual Property Bureau of the Ministry of Economics and Winding It is 0.93dl / g, its melting viscosity is 325 Pas (measured at 2.4 Hz and 255 ° C), its melting point is 227 ° C, crystallization temperature is 72 ° C, glass transition temperature is 45 ° C, and it is stirred with mixing The dryer dries at 130t until its moisture content reaches llppm, and then puts it on the 3E4 extruder of BARMAG Company to melt it, until the melt temperature reaches 255 ° C, and then sends it through the product line. To the spinning pump, there is an SMX-type electrostatic mixer of SULZER company, which has 15 elements, an inner diameter of 15mm, and a melt volume of 63 g / min. The paper size applies to the Chinese National Standard (CNS) Λ4 Specifications (210X 297 mm) 22 589420 Member of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Consumer Cooperative A7 B7 V. Description of the invention (20) The residence time is 6 minutes. The number of self-spinning pumps fed into the nozzle assembly is 30 · 7 g / min. There is a component in the electrostatic mixer, which is FLUITEC. Produced, HD-CSE type, 10mm inner diameter, installed after the spinning pump, but before the nozzle assembly inlet, the auxiliary heating device of the product line and spinning section, including the pump and nozzle assembly, its temperature is set At 255 ° C, the nozzle assembly contains a filter medium made of steel sand with a size of 350 to 500 microns and a height of 30mm, a filter membrane (filter) of 20 microns, and a filter sheet woven of 40 microns. Thereafter, the melt passes through An 80mm diameter nozzle plate was pressed out. The nozzle plate had 34 holes with a diameter of 0.25 and a length of 1.011111. The nozzle pressure was about 120 bAR. The length of the cooling delay zone is 100mm, of which 30mm is a heated partition wall, and 70mm is an unheated structure that is insulated. Thereafter, the melted wire is cooled in a blow shaft, which is a lateral blow with a distance of up to 1500mm. The cold wind speed is 0.35 m / sec, the temperature is 18 ° C, and the relative humidity is 80%. The solidification point of the filament is about 800 mm below the spinning nozzle. The thin thread is bundled at a distance of 1050 mm from the nozzle due to the spinning agent provided by a thin thread oiler. This refueling device has a TRIBOFIL surface, the diameter of the entrance hole is 1 mm, and the dose is given relative to the weight of the entire thread 0.40% 〇 After being bundled, the thin wire is sent to the winder. The distance between the refueling device and the first removal roller is 3.2m. The adjustment time depends on the speed and is between 144 and 168ms. The removal roller is surrounded by a thin line into an S shape. As soon as the interlaced nozzle manufactured by TEMCO company is operated under the air pressure of 1.5 bAR, it is installed between the removal rollers. In order to meet the requirements of speed adjustment, the paper size is applicable to China Standard (CNS) Specifications (210X 297mm) 23 (Please read the precautions on the back before filling out this page) Order 589420 A7 B7 V. Description of the invention (21 points, Barmag AG's SW6 type winding machine (WINDING DEVICE) is set to the equivalent of a winding tension of 5 CN. The room temperature is 24 ° C and the relative humidity is 60%. Therefore, the temperature around the tube is also set at about 34 ° C. In the experimental framework , The removal speed is in Experimental Example 1 2940 • m / min, 2506 m / min in Experimental Example 2, Table 1 below represents additional experimental parameters, and Table 2 shows the characteristics of POY. Both sets of settings can produce a 10 kg reel (SPOOL). And it can be removed from the bobbin device without any problems. Table 1: Experimental parameters Experimental example 1 Experimental example 2 Removal speed [m / min] 2940 2506 Winding speed [m / min] 2926 2500 Spinning delay 178 152 Fine thread tension is in front of the godet roller. (CN) 14 10 Maximum between the godet rollers (cN) 11 7.5 Touching and binding (2) [cN / dtex] 0.13 0.08 Between the godet rollers ( 2) Maximum [cN / dtex] 0.10 0.06 Thin wire winder tension square (1) '1 [cN] 5.0 5.0 Thin wire winder tension (2) L-- [cN / dtex] 0.048 0.048 (1) Absolute (2) and The relative scale of the fiber is applicable to the Chinese National Standard (CNS) Α4 specification (210 X 297 mm) (Please read the precautions on the back before filling out this page) --- Order printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 24 589420 B7 V. Description of the invention (22) Table 2: Random characteristics of the intended PTMT filaments 实验 --- Experimental Example 1 Experimental Example 2 Fineness 〔Dtex〕 105 123 Tear resistance [cN / dtex] 23.4 20.7 Tear elongation '1 ^ ---- (%) 98 127 Normal Ustel (%) 0.9 0.76 Processing shrinkage (%) 46 33 Birefringence Rate xlO3 Δη 52 43 Density [g / cm3] 1.320 1.318 Although [%] 2.2 1.9 CV-Tear Elongation (%) 2.2 1.9 CV: Coefficient of Variation (Please read the precautions on the back before filling this page) Wisdom of the Ministry of Economic Affairs (1): The elongation weaving measured after four weeks of storage under normal conditions: The PTMT silk shaft is stored for four weeks in the normal climate described in the German Industrial Standard DIN 53802, and then sent to The FK6-S-900 type elongation textile machine manufactured by BARMAG Company, the following Table 3 represents the SET filaments produced (Note: SET is a filament produced by a specific textile processing program. "Name"). Table 4 shows the experimental parameters of bulk SET yarn.
紡織加工誤差可用BARMAG公司的UNITENS測知， 並可用下列公式調節測得之數據1 UP/LP= 3.0CN UM/LN= 6.0CN 本紙張尺度適用中國國家標率（CNS ) A4規格（210 X 297公釐） 25 589420 A7 B7 五、發明説明（23 ) 表3 :伸長加工織法的實驗參數 實驗例1 實驗例2 速度 〔m/min〕 700 700 伸長比 1:1.48 1:1.65 D/Y比 2.1 2.1 溫度-加熱器1 「C〕 155 155 溫度-加熱器2 「C〕 160 160 紡織誤差 〔n/10 km〕 0 0 絲線張力 F1，在裝置前 〔cN〕 20 20 F2,在裝置後 〔cN〕 19 18 f2-cv 〔％〕 1.2 1.3 F2-CV F2的變異係數 (請先閱讀背面之注意事項再填寫本頁) 表4 :伸長加工上的材料ί 時性値 實驗例1 實驗例2 纖度 〔dtex〕 78 82 抗撕裂性 〔cN/dtex〕 27.7 29.0 撕裂伸長率 〔％〕 39.4 39.9 表面目視-著色評估 均勻 均勻 〔％〕 85 87 捲曲 〔％〕 24.5 25 經濟部智慧財產局員工消費合作社印製 ***（PLUG)性能可由第2加熱器的冷卻程序變更之，這 就是說，經由所謂HE細絲之生產，其捲曲度會提升至 47%，撕裂伸長率降至33%。 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210Χ 297公釐）The textile processing error can be measured by UNITENS of BARMAG Company, and the measured data can be adjusted by the following formula: 1 UP / LP = 3.0CN UM / LN = 6.0CN This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 (Mm) 25 589420 A7 B7 V. Description of the invention (23) Table 3: Experimental parameters of elongation weaving Experimental example 1 Experimental example 2 Speed [m / min] 700 700 Elongation ratio 1: 1.48 1: 1.65 D / Y ratio 2.1 2.1 Temperature-heater 1 "C] 155 155 Temperature-heater 2" C] 160 160 Textile error [n / 10 km] 0 0 Thread tension F1, before the device [cN] 20 20 F2, after the device [ cN] 19 18 f2-cv (%) 1.2 1.3 Coefficient of variation of F2-CV F2 (please read the precautions on the back before filling this page) Table 4: Materials on elongation processing 値 Timeliness 値 Experimental example 1 Experimental example 2 Fineness [dtex] 78 82 Tear resistance [cN / dtex] 27.7 29.0 Tear elongation (%) 39.4 39.9 Surface visual-coloring evaluation uniformity and uniformity (%) 85 87 Curl (%) 24.5 25 Employees, Intellectual Property Office, Ministry of Economic Affairs Consumer Cooperative Print Insertion (PLUG) Performance The cooling procedure of the second heater was changed. This means that, through the production of so-called HE filaments, the degree of crimp will be increased to 47%, and the tear elongation will be reduced to 33%. This paper applies the Chinese National Standard (CNS) ) Λ4 specification (210 × 297 mm)