TW587110B - Multi-component fibers having enhanced reversible thermal properties and methods of manufacturing thereof - Google Patents

Abstract

The invention relates to a multi-component fiber having enhanced reversible thermal properties and methods of manufacturing thereof. The multi-component fiber comprises a fiber body formed from a plurality of elongated members, at least one of the elongated members comprising a temperature regulating material dispersed therein. The temperature regulating material comprises a phase change material. The multi-component fiber may be formed via a melt spinning process or a solution spinning process and may be used or incorporated in various products where a thermal regulating property is desired. For example, the multi-component fiber may be used in textiles, apparel, footwear, medical products, containers and packagings, buildings, appliances, and other products.

Description

587110 A7 B7 五、發明説明（1 ) 相關申請參照 本申請案是Haggard於2000年1 〇月1 9日提出申 請的、美國專利申請序號〇 9 / 6 9 1 ，1 6 4，名稱爲 、、Temperature Adaptable Textile Fiber and Method of587110 A7 B7 V. Description of the invention (1) Related applications With reference to this application, the application was filed by Haggard on October 19, 2000, US Patent Application Nos. 09/6 9 1, 1 64, and the names are ,, Temperature Adaptable Textile Fiber and Method of

Preparing Same以及 Magill 等於 200 1 年 9 月 2 1 日提 出申請的、美國專利申請序號爲09/960 ，591 ， 名甲冉爲 Multi-component Fibers Having Enhanced Reversible Thermal Properties"的部分接續申請案。本申請案聲明於 2 0 0 1年9月2 1日提出申請的、美國臨時申請案序號 6〇/ 2 3 4 ，4 1 0的專利之權益，彼等的內容以引用 的方式倂入本文中。 本申請案相關於Hartmann於2001年9月21日提 出申請的、美國專利申請序號0 9 / 9 6 0 ，9 0 1的審 查中專利申請案，名稱爲''Stable Change Materials for Use in Temperature Regulating Synthetic Fibers, Fabrics and Textiles"以及Hartmann等人於200 1年2月6日提出申 請的美國專利申請序號0 9 / 7 7 7，5 1 2的審查中專 利申請案，名稱爲、Melt Spinnable Concentrate Pellets H a v i n g E n h a n c e d R e v e l· s i b 1 e T h e l· m a 1 P l· o p e r t i e s "等之中所揭 示的發明，彼等的整個揭示內容都以引用的方式倂入本文 中 〇 發明領域 本發明是關於具有強化的可逆熱學性質的合成纖維° 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製Preparing Same and Magill are part of the continuation applications filed on September 21, 2001, US patent application serial number 09/960, 591, and the first name is Multi-component Fibers Having Enhanced Reversible Thermal Properties ". This application declares the rights and interests of the U.S. Provisional Application Serial No. 60/2/4, 4 10 filed on September 21, 2001, and their contents are incorporated herein by reference. in. This application is related to a pending patent application filed by Hartmann on September 21, 2001, U.S. Patent Application Serial Nos. 0 9/9 60, 9 0 1 and named `` Stable Change Materials for Use in Temperature Regulating Synthetic Fibers, Fabrics and Textiles " and Hartmann et al., U.S. Patent Application Serial No. 0 9/7 7 7, 5 1 2 filed on February 6, 2001, under the name of the patent, Melt Spinnable Concentrate Pellets The inventions disclosed in Haven R evel · sib 1 e T hel · ma 1 P l · operties " etc., their entire disclosures are incorporated herein by reference. FIELD OF THE INVENTION The present invention is About synthetic fibers with enhanced reversible thermal properties ° This paper is sized to the Chinese National Standard (CNS) A4 (21〇X 297 mm) (Please read the precautions on the back before filling out this page) Staff of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives

-4- 587110 A7 _______B7 五、發明説明（2) 特定言之’本發明是關於包括相變材料的多成份纖維以及 經由熔融紡絲或溶液紡絲法合成該纖維的方法。 發明背景 許多纖維織品是由合成纖維製成的。傳統上，生產合 成纖維的方法有_ ··溶液紡絲法和溶融紡絲法。溶液紡 絲法通吊用來生產丙烯酸樹脂纖維，而熔融紡絲方法通常 用來生產尼虛纖維、聚酯纖維、聚丙烯纖維以及其他類似 種類的纖維。正如所熟知者，一尼龍纖維包括一長鏈的、 合成的聚醯胺聚合物，其特徵是具有一 C 〇 N H 一醯胺基 ， 尔目0纖維包括一長鏈的合成聚合物，其具有至少g 5 重重％的經取代芳族羧酸酯單元，且一聚丙烯纖維包括一 長鏈的合成結晶聚合物，其具有至少8 5重量％的烯烴單 元且典型地，其具有數平均分子量約4 〇，〇 〇 〇或更大 熔融紡絲法是特別値得注意的，因爲在紡織品工業上 使用的眾多的合成纖維都是用該技術製造的。熔融紡絲法 通常是將一種熔融的聚合物材料經由一種熟知的噴絲頭的 衣置而形成眾多單股的合成纖維。一旦形成，合成纖維可 以聚集成一股或切成短纖維。合成纖維可以製成針織物， 機織或非織製品，或者可將合成纖維紡成紗線，該紗線能 進一步紡織或針織製成人造織品。 相變材料業經摻加到單一成份的丙烯酸纖維中，以增 加纖維本身以及由纖維製成的紡織品的可逆熱學性質。這 本紙張尺度適用中國國家標準（CNS)八4規格（210>< 297公着） -----P---^---- (請先閱讀背面之注意事項再填寫本頁) 卜訂 經濟部智慧財產局員工消費合作社印製 -5 - 587110 Α7 Β7 五、發明説明（3) (請先閲讀背面之注意事項再填寫本頁) 是很容易做到的’部分原因在於形成丙烯酸纖維的溶液紡 絲過程中典型地伴隨著高水平的揮發性物質（如，溶劑） 。然而，要將相變材料摻到熔融紡絲的纖維中係有問題者 ’因爲在纟谷融肪絲過程中通常不用或不希望使用高水平揮 發性物質之故。以前試圖將相變材料添加入熔融紡絲合成 纖維中的嘗試典型地包括將含有一種相變材料的微囊和標 準纖維級熱塑性聚合物形成摻合物，然後，經由熔融紡絲 形成單一成份的合成纖維。除非使用低濃度的微囊，否則 ’這樣的嘗試通常會導致微囊在纖維內分散不足、纖維性 質差以及不良的可加工性。但是，在低微囊濃度之下，那 麽，所希望的經由添加相變材料達到強化的可逆的熱學性 質之目的會變得難以實現。 正因在此種背景之下，有需要發展包括相變材料的多 成份纖維。 發明槪述 經濟部智慧財產局員工消費合作社印製 於一創新方面中，本發明係有關一種具有強化的可逆 熱學性質之多成份纖維。在一具體實例中，該多成份纖維 包括眾多由延伸成份組成的纖維體，其中至少一個延伸成 份中包括溫度調節性材料。 在另一具體實例中，該多成份纖維包括一第一延伸成 ί刀’其包括一第一聚合物型材料’與一分散在該第一聚合 物型材料中的一種溫度調節性材料。該多成份纖維也可以 包括一第二延伸成份，其包括一第二聚合物型材料，其中 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公慶） ~ 6 - 587110 Α7 Β7 五、發明説明（4) 該第二延伸成份係與該第一延伸成份相互接合。 -----ιιβΐ (請先閱讀背面之注意事項再填寫本頁) 在另一具體實例中，該多成份纖維包括~種芯成份， 該芯成份中包括一種溫度調節性材料。該多成份纖維甚至 還可以包括一種包圍芯成份的鞘成份。 於第二創新方面中，本發明係有關一種具有強化的可 逆熱學性質的纖維。在一具體實例中，該纖維包括至少一 個實質地延伸貫穿纖維長度且包括由一第一聚合物型材料 和溫度調節性材料的摻合物之內部成份。在該內部內部成 份可包圍著一外部成份，其中該外部成份包括由一第二聚 合物型材料。 於第三創新方面中，本發明係有關一種芯/鞘型纖維 。在一具體實例中，該芯/鞘型纖維包括一種存在於纖維 中並實質地貫穿整根纖維長度的芯成份，其中該芯成份包 括一第一聚合物型材料和溫度調節性材料的摻合物。該芯 /鞘型纖維更可包括一種鞘成份，該鞘成份形民纖維的外 部且包圍著芯成份，其中該鞘成份包括一第二聚合物型材 料。 經濟部智慧財產局員工消費合作社印製 於第四創新方面中，本發明係有關一種海包島型纖維 (island-in-sea fiber )。在一具體實例中，海包島型纖維可 包括經配置在該纖維內並實質地貫穿整根纖維長度之眾多 島成份，其中每個島成份彼此隔離並包括由島狀聚合物型 材料和溫度調節性材料的摻合物。該海包島型纖維更可包 括形成纖維外層並包圍每個島成份的一種海成份，其中該 海型成份包括一種海型聚合物型材料。 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇χ297公釐） 587110 A7 B7 五、發明説明（5) 於第五創新方面中，本發明係有關一種製造和加工有 強化的具可逆熱學性質的纖維之方法。在一具體實例中， 該方法包括將一種溫度調節性材料和一第一聚合物型材料 混合形成摻合物，並在纖維擠出裝置的紡絲箱中將該摻合 物和一第二聚合物型材料組合，使該第二聚合物型材料包 圍該摻合物。該方法可更包括從紡絲箱的紡嘴擠出摻合物 和該第二聚合物型材料以形成一纖維，其具有由摻合物形 成的內層，與包圍該內層由該第二聚合物型材料形成的外 部成份。 方^桌/、創新方面中’本發明係有關一種製造有強化的 具可逆熱學性質的纖維之方法。在一具體實例中，該方法 可包括先形成眾多單獨的摻合物，其中每一摻合物包括一 種溫度調節性材料和一第一聚合物型材料，並在纖維擠出 衣置的紡絲相中將該眾多丨參合物和該第二聚合物型材料組 合’使得該第二聚合物型材料包圍該眾多單獨摻合物。該 方法更可包括將該眾多單獨的摻合物和該第二聚合物型材 料從纖維擠出裝置的紡絲箱的紡嘴擠出而形成一纖維，§亥 纖維的外部成份係由該第二聚合物型材料形成並包圍著眾 多由眾多單獨的摻合物形成之內部成份。 於第七創新方面中，本發明係有關一種織物。在—具 體實例中，該織物由眾多纖維混合而成，其中至少〜,纖糸隹 展現出強化的可逆熱學性質。該纖維包括由一第一聚$ _ 型材料和一種溫度調節性材料的摻合物構成的至少_丨^ @ 成份，其中該內部成份實質地擴展到整根纖維長度。該，纖 本紙張尺度適用中.國國家標準（CNS ) A4規格（210X297公釐） . ^---^ 丨 衣-- (請先閲讀背面之注意事項再填寫本頁)-4- 587110 A7 _______B7 V. Description of the Invention (2) Specifically, the present invention relates to a multi-component fiber including a phase change material and a method for synthesizing the fiber by melt spinning or solution spinning. BACKGROUND OF THE INVENTION Many fiber fabrics are made of synthetic fibers. Traditionally, the methods for producing synthetic fibers include: · solution spinning and melt spinning. The solution spinning method is used to produce acrylic resin fibers, while the melt spinning method is usually used to produce nylon fibers, polyester fibers, polypropylene fibers, and other similar types of fibers. As is well known, a nylon fiber includes a long-chain, synthetic polyamide polymer, which is characterized by having a CONH-amidamine group, and the mesh 0 fiber includes a long-chain synthetic polymer, which has At least 5 weight percent of substituted aromatic carboxylic acid ester units, and a polypropylene fiber including a long chain synthetic crystalline polymer having at least 85 weight percent olefin units and typically having a number average molecular weight of about Melt-spinning processes of 40,000 or greater are of particular interest because the numerous synthetic fibers used in the textile industry are manufactured using this technology. Melt spinning usually involves passing a molten polymer material through a well-known spinneret to form a large number of individual synthetic fibers. Once formed, synthetic fibers can be aggregated into strands or cut into short fibers. Synthetic fibers can be made into knitted fabrics, woven or non-woven products, or synthetic fibers can be spun into yarns which can be further woven or knitted into artificial fabrics. Phase change materials are incorporated into single-component acrylic fibers to increase the reversible thermal properties of the fibers themselves and the textiles made from the fibers. This paper size is in accordance with China National Standard (CNS) 8-4 specifications (210 > < 297) ----- P --- ^ ---- (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -5-587110 Α7 Β7 V. Description of the invention (3) (Please read the precautions on the back before filling this page) It is easy to do 'Part of the reason is the formation of acrylic acid Solution spinning of fibers is typically accompanied by high levels of volatile substances (eg, solvents). However, the incorporation of phase change materials into melt-spun fibers is problematic because high levels of volatile materials are generally not used or desired during the gluten-fat process. Previous attempts to add phase change materials to melt-spun synthetic fibers typically include forming a blend of microcapsules containing a phase change material and a standard fiber-grade thermoplastic polymer, and then forming a single component via melt spinning synthetic fiber. Unless low concentrations of microcapsules are used, such attempts generally result in insufficient dispersion of microcapsules in the fibers, poor fiber properties, and poor processability. However, at low concentrations of microcapsules, it may become difficult to achieve the desired purpose of enhancing the reversible thermal properties by adding phase change materials. Because of this background, there is a need to develop multicomponent fibers including phase change materials. Description of the invention Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In an innovative aspect, the present invention relates to a multi-component fiber with enhanced reversible thermal properties. In a specific example, the multi-component fiber includes a plurality of fibrous bodies composed of extended components, and at least one of the extended components includes a temperature-regulating material. In another specific example, the multi-component fiber includes a first stretched blade, which includes a first polymer-type material, and a temperature-adjustable material dispersed in the first polymer-type material. The multi-component fiber may also include a second extension component, which includes a second polymer-type material, in which the paper size is applicable to China National Standard (CNS) A4 specifications (210 × 297 public holidays) ~ 6-587110 Α7 Β7 5. Description of the Invention (4) The second extension component is bonded to the first extension component. ----- ιιβΐ (Please read the notes on the back before filling this page) In another specific example, the multi-component fiber includes a ~ core component, and the core component includes a temperature-regulating material. The multicomponent fiber may even include a sheath component surrounding the core component. In a second innovative aspect, the invention relates to a fiber having enhanced reversible thermal properties. In a specific example, the fiber includes at least one internal component that extends substantially through the fiber length and includes a blend of a first polymer-type material and a temperature-regulating material. The internal component may surround an external component, wherein the external component includes a second polymer-type material. In a third innovative aspect, the invention relates to a core / sheath fiber. In a specific example, the core / sheath fiber includes a core component that is present in the fiber and substantially runs through the entire fiber length, wherein the core component includes a blend of a first polymer-type material and a temperature-regulating material. Thing. The core / sheath fiber may further include a sheath component, which forms an outer portion of the common fiber and surrounds the core component, wherein the sheath component includes a second polymer-type material. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In the fourth innovation aspect, the present invention relates to an island-in-sea fiber. In a specific example, the sea-island type fiber may include a plurality of island components configured within the fiber and substantially throughout the entire fiber length, where each island component is isolated from each other and includes an island-like polymer material and temperature Blends of regulatory materials. The sea-island type fiber may further include a sea-type component forming a fiber outer layer and surrounding each island component, wherein the sea-type component includes a sea-type polymer-type material. This paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 587110 A7 B7 V. Description of the invention (5) In the fifth innovation aspect, the present invention relates to a manufacturing and processing with enhanced reversible heat The nature of the fiber method. In a specific example, the method includes mixing a temperature-regulating material and a first polymer-type material to form a blend, and polymerizing the blend and a second polymer in a spinning box of a fiber extrusion device. The material-type material combination allows the second polymer-type material to surround the blend. The method may further include extruding the blend and the second polymer-type material from a spinning nozzle of the spin box to form a fiber having an inner layer formed of the blend, and surrounding the inner layer by the second Polymer-based materials form an external component. The present invention relates to a method for manufacturing a reinforced fiber having reversible thermal properties. In a specific example, the method may include first forming a plurality of individual blends, where each blend includes a temperature-regulating material and a first polymer-type material, and spinning the fiber in a fiber extrusion garment The combination of the plurality of reference compounds and the second polymer-type material in the phase allows the second polymer-type material to surround the plurality of individual blends. The method may further include extruding the plurality of individual blends and the second polymer-type material from a spinning nozzle of a spinning box of a fiber extrusion device to form a fiber. The outer component of the fiber is composed of the first The dipolymer type material forms and surrounds a number of internal components formed from a plurality of individual blends. In a seventh innovative aspect, the invention relates to a fabric. In a specific example, the fabric is made of a mixture of many fibers, of which at least ~, the rayon exhibits enhanced reversible thermal properties. The fiber includes at least a component consisting of a blend of a first polymer-type material and a temperature-regulating material, wherein the internal component extends substantially to the entire fiber length. The size of fiber paper is applicable in China. National Standard (CNS) A4 (210X297mm)

、1T 經濟部智慧財產局員工消費合作社印製 -8 - 587110 A7 _一_____B7五、發明説明（6) 維還可以包括一形成該纖維的外部且包括該內部成份之外 部成份，其中該外部成份包括一第二聚合物型材料。 在力一具體貫例中’該織物由眾多纖維混合而成，其 中至少一纖維展現出強化的可逆熱學性質。該纖維包括一 由眾多延伸成份構成的纖維體，其中至少一延伸成份包括 一經分散在其中的溫度調節性材料。 圖式之簡略說明 爲更佳地理解本發明，要配合後附圖式參閱下面的詳 細說明。 圖1顯示在本發明一些具體實例中的各種範例多成份 纖維的放大截面圖。 圖2顯示在本發明一具體實例中的一範例芯/鞘型纖 維的三維圖。 經濟部智慧財產局員工消費合作社印製 一不 圖 一7Γ〇 顯維顯圖 3 三 4 維 圖 的圖三 維 的 纖 維 型 鞘\ 芯 例 ΛΤ-Ε 》車 - 另 的 中 例 實 澧 具1 明 發 本 在 SWP 具1 明 發 本 在 纖 型 島 包 海 例 A-E1 的 中 例 的 用 所 ru 二 維 纖 份 成 多 成 形 中 例 實 具1 明。 發置 本裝 示出 顯擠 5 維 圖纖 例 範 按質 示性 顯多 6 許 圖的 維 纖 型 鞘/ 芯 一一彐一一 種 6 的 成 製 者 論 討 中 IX 例 施 實 如 數 參 造 製 和 (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-8T 587110 A7 _ 一 _____B7 V. Description of Invention (6) The dimension may also include an external component forming the exterior of the fiber and including the internal component, wherein the external component The composition includes a second polymer-type material. In the specific embodiment of the force-the fabric is a mixture of a plurality of fibers, at least one of which exhibits enhanced reversible thermal properties. The fiber includes a fibrous body composed of a plurality of extension components, and at least one of the extension components includes a temperature-adjustable material dispersed therein. Brief description of the drawings For a better understanding of the present invention, please refer to the following detailed description in conjunction with the accompanying drawings. Fig. 1 shows enlarged cross-sectional views of various exemplary multicomponent fibers in some embodiments of the present invention. Fig. 2 shows a three-dimensional view of an exemplary core / sheath type fiber in a specific example of the present invention. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 7 shows the three dimensions. Figure 3 shows the three-dimensional figure. The three-dimensional fiber-type sheath \ core case ΛΤ-Ε "car-another example of the real case. The hair case in the SWP has 1 case. The hair case is in the middle example of the fiber island package sea case A-E1. The example of the two-dimensional fiber component multi-forming is shown in the example. The installation of this equipment shows an example of a squeezed 5-dimensional figure fiber, which is significantly more qualitative than the 6-dimensional figure. The dimensional fiber type sheath / core one by one, one type 6 is discussed in the discussion by the producers. Manufacturing and (Please read the notes on the back before filling out this page)

本紙張尺度適用中.國國家標準（CNS ) A4規格（210X 297公釐） -9- 587110 A7 B7 五、發明説明（7) 主要元件對照表 10 12 13 14 15 ， 15, ， 15" ， 15，"15 16，16,，16，，，16，"，16" 37，37、37，，，37，"，37，， 38，38,，38"，38…， 20 21 ， 22 ， 23 ， 24 26 ， 27 ， 28 ， 29 30 39 ， 4卜 43 ， 45 ， 47 ， 49 ， 51 ， 53 ， 55 4〇 ， 42 ， 44 ， 46 ， 48 ， 50 ， 52 ， 54 56，56， 經濟部智慧財產局員工消費合作社印製 57，63 58，64 59，60 6卜62 70 71 左欄 多成份纖維 多成份纖維 多成份纖維 ，35，35,，35，，，35，" 第一眾多延伸成份 36 ， 36, ， 36" ， 36"， 第二眾多延伸成份 第一眾多延伸成份 第二眾多延伸成份 中欄 芯/鞘型纖維 並列型纖維 右欄 第一延伸成份 第二延伸成份 第二眾多延伸成份 芯成份 鞘成份 芯/鞘型纖維 溫度調節性材料 海包島型纖維 海成份 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -10- 587110 A7 B7 五、發明説明（8) 經濟部智慧財產局員工消費合作社印製 72， 73 ， 74 ， 75 島成份 76， 77 ， 78 ， 79 島聚合材料 80， 81 溫度調節性材料 82 海聚合材料 110 纖維擠出設備 112 貯料斗 113 位置 114 貯料斗 116 螺旋擠壓器 118 螺旋擠壓器 119 位置 120 加熱管 121 位置 122 加熱管 124 計量泵 126 計量泵 127 位置 128 紡絲箱 130 紡嘴 132 洞孔 134 多成份纖維 136 吸出器 138 管 140 多成份纖維細纖 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X 297公釐） -11 - 經濟部智慧財產局員工消費合作社印製 587110 A7 -^___B7 五、發明説明（9) 142 布匹形成篩網帶 144 車昆 146 輥 148 抽器箱 150 輥 發明詳細說明 本發明是關於包括一種或多種相變材料的多成份纖維 及其製造方法。根據本方明的多個具體實例，此等多成份 纖維具有吸收或釋放熱量，從而達到減小或消除熱流動的 能力。此外’該多成份纖維可以具有更好的加工性能（例 如在纖維或由其所製產品的製造中），改良的強度，纖維 內較大的相變材料含量，或更高的相變材料塡充量。此等 多成份纖維可以用於或加到多種產品中使其具有溫度調節 性質’同時使產品具有改良的強度。例如，根據本發明多 個具體實例製備的多成份纖維可以用於紡織品（例如，織 物），衣物（例如，戶外服裝，潛水服和防護服裝），足 部用品（例如’襪子，鞋和鞋內底），醫用產品（例如熱 毯’治療墊’束縛帶，冷袋，熱袋），箱罐和包裝（例如 ’飮料袋，食品袋，炊具，座墊，電路板），建材（例如 ’牆壁或天花板的絕熱層，牆紙，窗簾襯裏，包裹管道， 毛毯和瓦片）’設備（例如室內絕熱設備），以及其他產 品（例如’汽車隔板材料，睡袋和寢具）。 除提供溫度調節性質外，根據本發明諸多具體實例的 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公慶） (請先閱讀背面之注意事項再填寫本頁)This paper size is applicable. National National Standard (CNS) A4 specification (210X 297 mm) -9- 587110 A7 B7 V. Description of the invention (7) Cross-reference table of main components 10 12 13 14 15 ， 15 ， 15 " ， 15 , &Quot; 15 16, 16 ,, 16 ,,, 16, ", 16 " 37, 37, 37,, 37, ", 37, 38, 38, 38 ", 38 ..., 20 21, 22, 23, 24 26, 27, 28, 29 30 39, 4b 43, 45, 47, 49, 51, 53, 55 4〇, 42, 44, 46, 48, 50, 52, 54 56, 56, Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 57, 63 58, 64, 59, 60 6 62 62 71 71 Multi-component fiber in the left column Multi-component fiber Multi-component fiber, 35, 35, 35, 35, " A plurality of extension components 36, 36 ,, 36 ", 36 ", a second plurality of extension components, a first plurality of extension components, a second plurality of extension components, a core / sheath fiber side-by-side fiber, a right column, a first extension component, and a second extension component. Second multitude extension component core component sheath component core / sheath fiber temperature-regulating material sea-island fiber Sea ingredients (please read the notes on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) -10- 587110 A7 B7 V. Description of invention (8) Intellectual property of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Bureau 72, 73, 74, 75 Island composition 76, 77, 78, 79 Island polymer material 80, 81 Temperature regulating material 82 Sea polymer material 110 Fiber extrusion equipment 112 Storage hopper 113 Location 114 Storage hopper 116 Screw extruder 118 Screw extruder 119 position 120 heating tube 121 position 122 heating tube 124 metering pump 126 metering pump 127 position 128 spinning box 130 spinning nozzle 132 hole 134 multi-component fiber 136 extractor 138 tube 140 multi-component fiber Fine fiber (please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (21 × 297 mm) -11-Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 587110 A7 -^ ___ B7 V. Description of the invention (9) 142 Cloth forming screen belt 144 Chekun 146 Roller 148 Extractor box 150 Roller hair Detailed Description The present invention relates comprise one or more multicomponent fibers, and method of manufacturing the phase change material. According to several specific examples of the present invention, these multicomponent fibers have the ability to absorb or release heat, thereby achieving the ability to reduce or eliminate heat flow. In addition, 'the multi-component fiber can have better processing properties (such as in the manufacture of fibers or products made therefrom), improved strength, a larger content of phase change materials in the fibers, or higher phase change materials 塡Recharge. These multi-component fibers can be used in or added to a variety of products to give them temperature regulating properties' while giving the products improved strength. For example, multi-component fibers prepared according to various embodiments of the present invention can be used in textiles (eg, fabrics), clothing (eg, outdoor clothing, wetsuits, and protective clothing), foot products (eg, 'socks, shoes, and footwear) Bottom), medical products (such as thermal blanket 'therapeutic pads' straps, cold bags, hot bags), boxes and packaging (such as 'bags, food bags, cookers, seat cushions, circuit boards), building materials (such as' Insulation for walls or ceilings, wallpaper, curtain lining, wrapping pipes, blankets and tiles) 'equipment (such as indoor thermal insulation equipment), and other products (such as' car partition materials, sleeping bags and bedding). In addition to providing temperature adjustment properties, the paper size according to many specific examples of the present invention is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 public holidays) (Please read the precautions on the back before filling this page)

-12- 587110 ΑΊ ___ Β7 五、發明説明（β (請先閱讀背面之注意事項再填寫本頁} 多成份纖維在產品中加入後，該產品還具備其他性能。例 如’衣物或足部用品中加入該纖維材料後可以降低皮膚表 面的潮氣，如排汗帶來的潮氣。舉例來說，該多成份纖維 可以降低皮膚表面的溫度和濕度，從而達到降低皮膚表面 潮濕度和提高舒適度的目的。衣物或足部用品具體材料的 選用和設計可以更好的提高其除濕功能。 根據本發明中的某些具體實例，該多成份纖維可以包 括衆多延伸成份。根據本發明某些具體實例，該多成份纖 維可包括一由衆多延伸成份構成的纖維體。該纖維體一般 可以延伸且具有至其直徑的數倍（如，1 0 〇倍或更多） 的長度。該纖維體可以具有多種規則或不規則橫截面，舉 例而言但不限於，圓形，多葉形，八邊形，橢圓，五邊形 ，長方形，正方形，梯形，三角形，楔形等。根據本發明 某些具體實例，兩或多個延伸成份（如兩個相鄰延伸成份 )可以相互接合，組合，聯合，或粘合形成單一纖維體。 經濟部智慧財產局員工消費合作社印製 根據本發明某些具體實例，至少一個延伸成份包括溫 度調節性材料。典型地，溫度調節性材料包括一或多種使 多成份纖維具有強化之可逆熱學性質的相變材料。在本發 明一些具體實例中，延伸成份可包括相同或相異的聚合物 型材料，並且至少一延伸成份有溫度調節性材料分散其中 。溫度調節性材料通常是均勻的分散於至少一延伸成份中 。但是，根據多成份纖維所需的特別的性質而定，可以改 變溫度調節性材料在一或多種延伸成份中的分散。根據本 發明某些具體實例，兩個或多個成份中可包括相同或不同 本紙張尺度適用中.國國家樣準（CNS ) Α4規格（210Χ 297公釐） -13- 587110 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（1) 的溫度調節性材料。 根據多成份纖維所需的特別應用而定，延伸成份可以 有不同的分散結構。例如，延伸成份可以排列成海包島型 結構或鞘-芯結構。延伸成份也可以有其他分散形狀，舉 例而言但不限於，矩陣狀或棋盤狀，花瓣狀，並列狀，或 帶狀分散等。根據本發明具體實例，延伸成份可以排列成 束狀，於其中延伸成份槪括地呈相互平行。根據本發明其 他具體實例一或多種延伸成份可以延伸到至少部分纖維體 長度，而且，如果需要可以令其貫穿整體。例如根據本發 明某些具體實例，至少有一個內成份可以大體延伸至多成 份纖維的長度，並且包括一種溫度調節性材料。該內部成 份延伸穿過該多成份纖維的長度之程度可以決定於，例如 該多成份纖維所合意的熱調節性質。此外，其他因素（例 如’合意的機械性質或形成該多成份纖維得方法）。如此 ’在一具體實例中，內成份可以延伸過該多成份纖維總長 度的約一半到其總長度以提供要求的熱學可逆性質。該多 成份纖維的外部成份包圍其內部成份且形成該多成份纖維 的外部。 根據本發明某些具體實例，該多成份纖維約在約 〇 · 1到約1〇〇◦丹尼（denier)或約0 · 1到約1〇〇 丹尼之間。根據本發明一具體實例，該多成份纖維一般約 爲約0 · 5 -約1 〇丹尼。諳於此技者都知道，一丹尼一 般理解爲每單位長度纖維的重量數（如，克每9 0 0 〇米 (請先閱讀背面之注意事項再填寫本頁) .IT —II —4. · 衣. l·訂！ 本纸張尺度適用中國國家標準（CNS )A4規格（210X297公釐） -14- 587110 A7 B7 五、發明説明（^ 根據本發明某些具體實例，該多成份纖維可以根據需 要製成一段或多段丹尼數更小之纖維。例如，包括多成份 材料的延伸成份可以分開，製成兩段或多段丹尼數更小之 纖維。也可以採用或同時採用將包括一或多種延伸成份（ 或其一部分或多部分）的多成份纖維溶解或熔化掉的方法 ，製成一段或多段丹尼數更小之纖維。典型地，得到的丹 尼數更小之纖維材料至少有一者包括溫度調節性材料，使 其具有需要的熱控性能。 根據多成份纖維的製造技術，深加工的需要，或多成 份纖維材料的特殊應用，該多成份纖維中可以再加入一種 或多種添加劑，舉例而言但不限於水，界面活性劑，分散 劑，消泡劑（如，含矽酮化合物或含氟化合物），抗氧化 劑（如，阻酚和亞磷酸鹽），熱安定劑（如，亞磷酸鹽， 有機磷化合物，有機羧酸金屬鹽和酚類化合物），光或 u V安定劑（如，羥基苯甲酸鹽，阻羥基苯甲酸鹽和阻胺 )，微波吸收劑（如，多官能性伯醇，甘油和碳），強化 纖維（如，碳纖維，芳族聚醯胺纖維和玻璃纖維），傳導 性纖維或粒子（如，石墨或活性炭纖維或粒子），潤滑劑 ，加工助劑（如，脂肪酸金屬鹽，脂肪酸酯，脂肪酸醚， 脂肪醯胺，磺胺類，聚矽氧烷，有機磷化合物，含矽化合 物，含氟化合物，和酚多醚），滯燃劑（如，鹵化化合物 ’磷化合物，有機磷酸酯，有機溴化物，氫氧化鋁，三聚 氰胺衍生物，氫氧化鎂，銻化合物，氧化銻，和硼化物） ’抗阻斷劑（如，矽石，滑石，沸石，金屬碳酸鹽和有機 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 衣. 、11 經濟部智慧財產局員工消費合作社印製 -15- 587110 A7 B7 五、發明説明（d (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 聚合物）’防霧劑（如，非離子界面活性劑，甘油酯，聚 丙三醇酯，山梨聚糖醇酯和其乙氧基化物，壬基苯基乙氧 基化合物’和醇的乙氧基化合物），抗靜電劑（如非離子 化合物諸如脂肪酸酯，乙氧基化烷基胺，二乙醇胺，和乙 氧基化醇；陰離子化合物諸如烷基磺酸鹽和烷基磷酸鹽； 陽離子化合物如金屬氯化物，甲基硫酸鹽或硝酸鹽，和季 錢鹽化合物；與兩性化合物如烷基乙內銨鹽），抗微生物 劑（如，砷化合物，硫磺，銅化合物，異噻唑啉鄰苯二甲 醯胺，胺基甲酸鹽，無機銀鹽試劑，銀鋅沸石，銅銀沸石 ’銀沸石’金屬氧化物和矽酸鹽），交聯劑或控制降解劑 (如，過氧化物，偶氮化合物和矽烷），著色劑，色素， 染料，螢光增白劑或光學增白劑（如，二苯并腭唑，苯基 香豆素和二（苯乙烯基）聯苯），塡充劑（如天然礦物和 金屬如氧化物，氫氧化物，碳酸鹽，硫酸鹽，和矽酸鹽； 滑石；粘土；鈣矽石；石墨；碳黑；碳纖維；玻璃纖維和 珠粒；陶瓷纖維和珠粒；金屬纖維和珠粒；麵粉；天然的 或人造的纖維如木纖維，澱粉纖維，或纖維素粉），偶合 劑（如，矽烷，鈦酸鹽，鉻酸鹽，脂肪酸鹽，酐，環氧化 物，與不飽和聚合酸），強化劑，結晶或成核劑（如，所 有可以提高或改良聚合物內結晶性的物質，如提高晶體的 生長速率/動力學，晶體成長數，或晶體生長類型），等 。一或多種包括多成份纖維的延伸成份可以有一種或多種 添加劑分散其中。 根據本發明某些具體實例，某些處理手段或塗層可以 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -16- 587110 A7 _B7_ 五、發明説明（j (請先閲讀背面之注意事項再填寫本頁) 施加到多成份纖維以使其具有其他性質，舉例而言但不限 於耐污染性，防水性，柔軟性，與除濕性。範例處理或塗 層包括 Nextec Application Inc.的 Epic,Intera Technologies Inc.的 Intera，杜邦公司的 Zonyl Fabric Protectoi.s，3M 公司的 Scotchgard 5 等 。 參看圖1 ，其中示出多種根據本發明某些具體實例得 到的多成份纖維的放大橫截面圖，依次是纖維1 2，1 3 ，14，21，22，23，24，26，27，28, 29 ，和34。特定言之，圖1中是根據本發明某些具體 實例得到的多種包括多成份纖維的延伸成份之範例排列構 型。 經濟部智慧財產局員工消費合作社印製 如圖1所示，每一多成份纖維（如纖維2 1 )具有衆 多相對於構成多成份纖維的眾多延伸成份（如3 9和4 0 )之不同的橫截面。根據本處所示的具體實例，該等延伸 成份包括第一延伸成份（或第一眾多延伸成份）（如圖1 中陰影處）和第二延伸成份（或第二眾多延伸成份）（如 圖1中未加陰影處）。這裏的第一延伸成份（或眾多延伸 成份）最好由包括分散在其中的溫度調節性材料之聚合物 型材料所形成。該第二延伸成份（或第二眾多延伸成份） 可以由同樣的聚合物型材料或具有其他略爲不同性質的聚 合物型材料所形成。這裏必須注意到圖1中所示的延伸成 份的數目，形狀，和大小是舉例說明而非限於此，且其他 多種具體實例同樣屬於本發明範疇。 雖然圖1中只示出具有圓形或三葉形橫截面的多成份 本紙張尺ϋ用中國國家標準（CNS ) A4規格（210'乂297公釐） " 一 -17 - 587110 A7 __ B7_ 五、發明説明（j C請先閱讀背面之注意事項再填寫本頁) 纖維，具有其他規則或不規則形狀的橫截面者也涵蓋於本 發明中，舉例而言但不限於多成份纖維的橫截面可以有多 葉形，八邊形，橢圓，五邊形，長方形，正方形，梯形， 三角形，楔形等。這裏必須注意到，一般而言，該第一眾 多延伸成份可以由相同的或不同的聚合物型材料構成，且 該第二眾多延伸成份可以由相同的或不同的聚合物型材料 構成。而且，根據本發明某些具體實例，溫度調節性材料 一般分散於第二延伸成份（或眾多第二延伸成份）中。這 裏還必須注意到兩種或多種的溫度調節性材料可以分散於 相同的或不同的延伸成份中。舉例來說，一第一溫度調節 性材料可以分散在第一延伸成份中，而一第二可能具有不 同性質的溫度調節性材料則分散於第二延伸成份中（如， 兩種不同的相轉變材料）。 經濟部智慧財產局員工消費合作社印製 根據本發明某些具體實例，一或多種延伸成份可以直 接由溫度調節性材料構成，而無須將溫度調節性材料分散 於聚合物型材料中。舉例來說，溫度調節性材料可包括可 使其具有強化的可逆熱學性質且可以用來形成第一延伸成 份（或眾多第一延伸成份）之一種聚合物（或聚合物混合 物）。對於該等具體實例，第二延伸成份（或第二眾多延 伸成份）最好，但不要求，能充分的包裹該第一延伸成份 (或第一眾多延伸成份），以防止或減輕溫度調節性材料 的損失或洩漏。另外，必須知道者，一般說來，兩個或多 個延伸成份可以由相同的或不同的溫度調節性材料構成。 參看圖1 ，左欄1 〇中列出3個範例多成份纖維1 2 本紙張尺@用中國國家標準（CNS) M規格（21GX297公麓） ~ -18- 587110 A7 B7 五、發明説明（d (請先閱讀背面之注意事項再填寫本頁) ’ 1 3 ’和1 4 °該多成份纖維1 2包括眾多排列成花瓣 狀的延伸成份。在這一具體實例中，眾多第一第一延伸成 份5 ，1 5 ，1 5 r/ ，1 5 M,，和1 5 M，，和第二眾多第 一延伸成份6，1 6 / ，1 6 " ，1 6 ",，和1 6 以交 替方式排列’且其橫截面爲楔形。通常，諸延伸成份可以 有相同的或不同的橫截面形狀或大小。而且，雖然圖式中 的多成份纖維1 2包括十個延伸成份，但是必須認知者， 一般有兩個或更多的延伸成份可以花瓣狀排列，並且至少 有一個延伸成份典型地包括溫度調節性材料。 多成份纖維1 3包括眾多以海包島型排列的延伸成份 。在該具體實例中，第一眾多延伸成份3 5，3 5 -， 3 5〃 ，3 5 等延伸至大體與多成份纖維1 3相當的長 度，而且彼此分開。該眾多第一延伸成份3 5 , 3 5，， 3 5〃 ，3 5⑴係經配置於第二延伸成份3 6內，由是形 經濟部智慧財產局員工消費合作社印製 成在該第二延伸成份3 6 海〃內的、、島〃。此等、、海" 內 > 島〃的排列可使溫度調節性材料在多成份纖維1 3內 的分佈更加均勻。在該具體實例中，每一該第一眾多延伸 成份3 5 ，3 5 / ，3 5 〃 ，3 5 等的橫截面形狀爲梯 形。但是，必須注意到，其他的多種規則或不規則的橫截 面形狀也屬於本發明範疇，如經由實例中方法但不限於此 等方法，可以有圓形，多葉形，八邊形，橢圓，五邊形， 長方形，梯形，正方形，三角形，楔形，等。典型地，眾 多第一延伸成份3 5 ，3 5 >，3 5 〃 ，：3 5…等可以有 相同的或不同的橫截面形狀與大小。而且，雖然多成份纖 本紙浪尺度適用中國國家標準（CNS ) A4規格（210X297公慶） -19- 587110 A7 B7 五、發明説明（j 維1 3包括1 6個眾多第一延伸成份3 5，3 5 /， 3 5〃 ，3 5 等，並且爲第二延伸成份3 6所包圍，但 是必須注蒽到，一般情況是有一或多種延伸成份位於延伸 成份3 6內，並被該第二延伸成份3 6其包圍。 多成份纖維1 4包括呈條紋狀排列的眾多延伸成份。 在該具體實例中，第一眾多延伸成份，3 7，3 7 / ， 3 7〃 ，3 7…和第二眾多延伸成份3 8，3 8 / ， 3 8 ，3 8 以交替方式分散，並且在多成份纖維內呈 縱向條紋。典型地，延伸成份可以有相同的或不同的橫截 面形狀或大小（如，與縱切片相關的寬度）。如果需要， 多成份纖維1 4可爲自捲曲或自變形纖維，該纖維的該自 捲曲或自變形性能能夠使纖維具有鬆密度，絕緣，延展等 性能。雖然多成份纖維1 4如圖式包括9個延伸成份，但 是必須注意到，通常，可將兩個或多個延伸成份以條紋狀 排列，同時至少有一個延伸成份典型地包括溫度調節性材 料。 在多成份纖維1 2和1 4的情況中，第一延伸成份（ 如’ 1 5 )係顯示成被鄰近的第二延伸成份或多成份（如 ’ 1 6和1 6 "')部分包圍，而於多成份纖維1 3的情況 中’第一延伸成份（如，3 5 )係顯示成被單一完整的第 二延伸成份3 6所包圍。當第一延伸成份（如1 5 )不是 被完整包圍時，宜於但不要求使用盛裝結構（如，微囊體 )來盛裝分散在第一延伸成份內的溫度調節性材料。如果 需要，該等多成份纖維1 2，1 3，和1 4可以進一步加 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂！ 經濟部智慧財產局員工消費合作社印製 -20- 587110 A7 B7 五、發明説明（y (請先閲讀背面之注意事項再填寫本頁) 工製成一或更多較小丹尼數的纖維。舉例來說，包括多成 份纖維1 2的延伸成份可以分開，或者將一或多種延伸成 份（或其一部分或多部分）溶掉或溶化掉。得到的小丹尼 數的纖維可，例如，包括相互接合的延伸成份1 5和1 6 〇 圖1中欄2 0示出四種範例芯/鞘型纖維2 1 ，2 2 ，2 3和2 4。特定言之，每股鞘/芯型纖維2 1 ，2 2 ’ 2 3和2 4包括眾多以芯/鞘型排列的延伸成份。 鞘/芯型纖維2 1包括第一延伸成份3 9 ，其經配置 在第二延伸成份4 0中且爲該第二延伸成份4 0所包圍。 特定言之，第一延伸成份3 9係經形成爲包括溫度調節性 材料的芯成份。 而這一延伸成份位於第二延伸成份4 0的中心，並被 其包圍，第二延伸成份就構成鞘成份。本例中，鞘/芯型 纖維2 1包括占重量比的2 5 %的芯成份和占重量比的 7 5 %的鞘成份。 經濟部智慧財產局員工消費合作社印製 鞘/芯型纖維2 2包括第一延伸成份4 1和第二延伸 成份4 2 ，其中第二延伸成份4 2包圍第一延伸成份4 1 。如上一具體實例所述，包括溫度調節性材料的第一延伸 成份4 1形成芯成份。而這一延伸成份4 1位於第二延伸 成份4 2的中心，並被其完全包圍，第二延伸成份4 2就 構成鞘成份。在本例中，鞘/芯型纖維2 2包括5 0重量 %的芯成份和5 0重量％的鞘成份。 鞘/芯型纖維2 3包括第一延伸成份4 3和第二延伸 本紙張尺度適用中國國家標準（CNS ) A4規格（210 x 297公釐） -21 - 經濟部智慧財產局員工消費合作社印製 587110 A7 __ B7 五、發明説明（j 成份4 4，其中第二延伸成份4 4包圍第一延伸成份4 3 。但是，在本例中包括溫度調節性材料的第一延伸成份 4 3形成的芯成份，位於偏離構成鞘成份的第二延伸成份 4 4中心的位置。本例中，鞘/芯型纖維2 3可包括任意 重量比的芯成份和鞘成份，從而得到所需的溫度調節性質 和機械性能。 二某形鞘/芯型纖維2 4包括第一延伸成份4 5和第 二延伸成份4 6 ，其中第二延伸成份4 6包圍第一延伸成 份4 5。在這一具體實例中，第一延伸成份4 5形成具有 三葉形截面形狀的第一延伸成份。該芯成份位於形成鞘成 份的第二延伸成份4 6中心的位置。鞘/芯型纖維2 4實 際上可包括任意重量比的芯成份和鞘成份，從而得到所需 的溫度調節性質和機械性能。 這裏必須注意到，芯成份通常可以具有多種規則的或 不規則的橫截面形狀，舉例而言但不限於圓形，多葉形， 多邊形，橢圓，五邊形，長方形，正方形，梯形，三角形 和楔形等。雖然圖式的鞘/芯型纖維2 1 ，2 2，2 3 ， 和2 4只有一個芯成份位於鞘成份中並被其包圍，但裹必 須注意到鞘成份中可包括兩個或多個芯成份（如，類似多 成份纖維1 3的方式）。此等芯成份可以具有相同的或^ 同的橫截面形狀與大小。根據本發明具體實例，鞘/芯_ 纖維包括三個或多個以鞘-芯結構排列的延伸成份，其中 延伸成份在鞘/芯型纖維中呈縱向的同心或離心的帶狀。 圖1中右欄3 0闡示本發明某些具體實例中的〜些/範 本紙張尺度適用中國國家標準（CNS ) A4規格（2】0X297公釐） (請先閲讀背面之注意事項再填寫本頁)-12- 587110 ΑΊ ___ Β7 V. Description of the invention (β (Please read the precautions on the back before filling out this page) Multi-component fiber has other properties when it is added to the product. For example, 'clothing or foot products After adding the fiber material, the moisture on the skin surface can be reduced, such as the moisture caused by perspiration. For example, the multi-component fiber can reduce the temperature and humidity of the skin surface, so as to reduce the skin surface humidity and improve the comfort. The selection and design of specific materials for clothing or foot products can better improve its dehumidifying function. According to some specific examples in the present invention, the multi-component fiber may include a plurality of extended components. According to some specific examples of the present invention, the A multi-component fiber may include a fibrous body composed of a plurality of stretching components. The fibrous body may generally be stretched and have a length several times (eg, 100 times or more) to its diameter. The fibrous body may have various rules Or irregular cross-sections, such as, but not limited to, circular, multilobal, octagonal, elliptical, pentagonal, rectangular, Square, trapezoidal, triangular, wedge-shaped, etc. According to some specific examples of the present invention, two or more extended components (such as two adjacent extended components) can be joined, combined, combined, or bonded to form a single fibrous body. Ministry of Economic Affairs Printed by the Intellectual Property Bureau Staff Consumer Cooperative in accordance with certain specific examples of the present invention, at least one of the extended components includes a temperature-adjustable material. Typically, the temperature-adjustable material includes one or more phase transitions that provide multi-component fibers with enhanced reversible thermal properties Materials. In some specific examples of the present invention, the extension components may include the same or different polymer-type materials, and at least one extension component is dispersed in a temperature-adjustable material. The temperature-adjustable material is generally uniformly dispersed in at least one extension Composition. However, depending on the particular properties required of the multi-component fiber, the dispersion of the temperature-regulating material in one or more of the elongation components can be changed. According to certain embodiments of the present invention, two or more components may be used. Including the same or different standards of this paper. China National Standard (CNS) Α4 specifications ( 210 × 297 mm) -13- 587110 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. The temperature-regulating material of the invention description (1). Depending on the special application required for the multi-component fiber, the extended component can have Different dispersion structures. For example, the extension component can be arranged in a sea-island structure or a sheath-core structure. The extension component can also have other dispersed shapes, such as, but not limited to, a matrix or checkerboard shape, a petal shape, and a side-by-side shape. Or band-shaped dispersion, etc. According to the specific examples of the present invention, the extension components can be arranged in a bundle, in which the extension components are parallel to each other. According to other specific examples of the present invention, one or more of the extension components can be extended to at least part of the fiber body length. Moreover, if necessary, it can be made to penetrate the whole. For example, according to some specific examples of the present invention, at least one internal component can extend substantially to the length of the multi-component fiber, and includes a temperature regulating material. The extent to which the internal component extends through the length of the multicomponent fiber can be determined, for example, by the desirable thermal regulation properties of the multicomponent fiber. In addition, other factors (e.g., 'desired mechanical properties or the method by which the multicomponent fiber is formed). As such, in a specific example, the internal component can extend over about half of the total length of the multicomponent fiber to its total length to provide the required thermally reversible properties. The external components of the multicomponent fiber surround its internal components and form the exterior of the multicomponent fiber. According to some specific examples of the present invention, the multicomponent fiber is between about 0.1 to about 100 denier or about 0.1 to about 100 denier. According to a specific embodiment of the present invention, the multi-component fiber is generally about 0.5 to about 10 deniers. As those skilled in the art know, a Denny is generally understood as the weight per unit length of fiber (for example, grams per 9,000 meters (please read the precautions on the back before filling out this page). IT —II —4 · Clothing. L · Order! This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -14-587110 A7 B7 V. Description of the invention (^ According to some specific examples of the present invention, the multi-component fiber Fibers with smaller denier numbers can be made as required. For example, extended components that include multi-component materials can be separated to make fibers with smaller denier numbers in two or more sections. It can also be used or used simultaneously. A method of dissolving or melting off one or more multi-component fibers with an extended component (or one or more portions thereof) to make a fiber having one or more segments having a smaller denier number. Typically, a fiber material having a smaller denier number is obtained. At least one of them includes a temperature-regulating material to provide the required thermal control properties. According to the manufacturing technology of multi-component fibers, the need for deep processing, or the special application of multi-component fiber materials, Add one or more additives, such as, but not limited to, water, surfactants, dispersants, defoamers (eg, silicone-containing or fluorine-containing compounds), antioxidants (eg, hindered phenol and phosphite) ), Thermal stabilizers (eg, phosphites, organophosphorus compounds, metal salts of organic carboxylic acids, and phenolic compounds), light or UV stabilizers (eg, hydroxybenzoate, hydroxybenzoate, and hydroxybenzoate) Amines), microwave absorbents (eg, polyfunctional primary alcohols, glycerol, and carbon), reinforcing fibers (eg, carbon fibers, aromatic polyamide fibers, and glass fibers), conductive fibers or particles (eg, graphite or activated carbon fibers) Or particles), lubricants, processing aids (eg, fatty acid metal salts, fatty acid esters, fatty acid ethers, fatty amines, sulfonamides, polysiloxanes, organophosphorus compounds, silicon-containing compounds, fluorine-containing compounds, and phenols Polyethers), flame retardants (eg, halogenated compounds' phosphorus compounds, organic phosphates, organic bromides, aluminum hydroxide, melamine derivatives, magnesium hydroxide, antimony compounds, antimony oxide, and boride) 'Anti-blocking agents (such as silica, talc, zeolite, metal carbonate and organic paper) This paper applies Chinese National Standard (CNS) A4 specifications (210X 297 mm) (Please read the precautions on the back before filling this page ) Clothing. 11 Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -15- 587110 A7 B7 V. Invention Description (d (Please read the notes on the back before filling this page) Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Polymers) 'anti-fog agents (eg, nonionic surfactants, glycerides, polyglycerol esters, sorbitan esters and their ethoxylates, nonylphenylethoxy compounds' and ethoxylates of alcohol Compounds), antistatic agents (such as non-ionic compounds such as fatty acid esters, ethoxylated alkylamines, diethanolamine, and ethoxylated alcohols; anionic compounds such as alkyl sulfonates and alkyl phosphates; cations Compounds such as metal chlorides, methyl sulfates or nitrates, and quaternary salt compounds; with amphoteric compounds such as alkyl betaine salts, antimicrobials (such as arsenic compounds, sulfur, copper compounds, isothiophenes Oxazoline phthaloxamine, carbamate, inorganic silver salt reagent, silver zinc zeolite, copper silver zeolite 'silver zeolite' metal oxide and silicate), cross-linking agent or controlled degradation agent (eg, Peroxides, azo compounds and silanes), colorants, pigments, dyes, fluorescent brighteners or optical brighteners (eg, dibenzoxazole, phenylcoumarin, and bis (styryl) Benzene), rhenium fillers (such as natural minerals and metals such as oxides, hydroxides, carbonates, sulfates, and silicates; talc; clay; calcareous silica; graphite; carbon black; carbon fibers; glass fibers and beads Grains; ceramic fibers and beads; metal fibers and beads; flour; natural or artificial fibers such as wood fibers, starch fibers, or cellulose powder; coupling agents (such as silanes, titanates, chromates, Fatty acid salts, anhydrides, epoxides, and unsaturated polymeric acids), strengthening agents, crystallization or nucleating agents (eg, all substances that can improve or improve the crystallinity in polymers, such as increasing the crystal growth rate / kinetics, Crystal growth number, or crystal growth type), . One or more of the elongation components including the multicomponent fiber may be dispersed therein with one or more additives. According to some specific examples of the present invention, certain treatment methods or coatings can be applied to the Chinese paper standard (CNS) A4 (210X297 mm) at this paper size. -16- 587110 A7 _B7_ V. Description of the invention (j (please read the back first (Please fill in this page again) Apply to multi-component fiber to make it have other properties, such as but not limited to pollution resistance, water resistance, softness, and dehumidification. Example treatments or coatings include Nextec Application Inc. Epic, Intera of Intera Technologies Inc., Zonyl Fabric Protectoi.s of DuPont, Scotchgard 5 of 3M, etc. See FIG. 1 for enlarged cross-sections of various multi-component fibers obtained according to some specific examples of the present invention The graphs are the fibers 1, 2, 3, 14, 21, 22, 23, 24, 26, 27, 28, 29, and 34 in order. In particular, FIG. 1 shows a variety of types obtained according to some specific examples of the present invention. Exemplary arrangement of extended components including multi-component fibers. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs as shown in Figure 1, each multi-component fiber (such as fiber 2 1) has a large number of For the different cross-sections of the many extension components (such as 39 and 40) constituting the multi-component fiber, according to the specific example shown here, the extension components include the first extension component (or the first plurality of extension components) ( As shown in the shaded area in Figure 1) and the second extended component (or the second plurality of extended components) (not shown in the shaded area in Figure 1). The first extended component (or multiple extended components) here is preferably composed of dispersed in The temperature-adjustable material is formed of a polymer-type material. The second extension component (or the second plurality of extension components) may be formed of the same polymer-type material or other polymer-type materials having slightly different properties. Here It must be noted that the number, shape, and size of the extended components shown in FIG. 1 are illustrative and not limited thereto, and various other specific examples also belong to the scope of the present invention. Although FIG. -Shaped cross-section multi-component paper size used in China National Standard (CNS) A4 size (210 '乂 297 mm) " I-17-587110 A7 __ B7_ V. Description of the invention (j C Please read first Read the notes on the back and fill in this page again) Fibers, those with other regular or irregular cross-sections are also covered in the present invention. For example, but not limited to, the cross-section of multi-component fibers can have multi-lobed, octagonal Shapes, ellipses, pentagons, rectangles, squares, trapezoids, triangles, wedges, etc. It must be noted here that in general, the first plurality of extension components can be composed of the same or different polymer-type materials, and the first The plurality of extension components may be composed of the same or different polymer-type materials. Moreover, according to some specific examples of the present invention, the temperature regulating material is generally dispersed in the second extended component (or a plurality of second extended components). It must also be noted here that two or more temperature-regulating materials may be dispersed in the same or different extension components. For example, a first temperature-adjustable material may be dispersed in the first extension component, and a second temperature-adjustable material that may have different properties is dispersed in the second extension component (eg, two different phase transitions) material). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to some specific examples of the present invention, one or more extended components may be directly composed of temperature-adjustable materials without dispersing the temperature-adjustable materials in the polymer-type material. For example, the temperature-regulating material can include a polymer (or polymer mixture) that can have enhanced reversible thermal properties and can be used to form a first extension component (or multiple first extension components). For these specific examples, the second extension component (or the second plurality of extension components) is the best, but it is not required to be able to sufficiently wrap the first extension component (or the first plurality of extension components) to prevent or reduce temperature regulation Loss or leakage of materials. In addition, it must be known that, in general, two or more extension components may be composed of the same or different temperature-regulating materials. Referring to Figure 1, three example multi-component fibers are listed in the left column 10. This paper ruler @ China National Standard (CNS) M specification (21GX297 male foot) ~ -18-587110 A7 B7 V. Description of the invention (d (Please read the notes on the back before filling out this page) '1 3' and 1 4 ° The multi-component fiber 1 2 includes a large number of extension components arranged in a petal shape. In this specific example, many first first extensions Ingredients 5, 15, 1 5 r /, 1 5 M ,, and 1 5 M ,, and a second plurality of first extended ingredients 6, 1 6 /, 1 6 ", 1 6 " ,, and 1 6 'Alternatively arranged' and its cross-section is wedge-shaped. Generally, the extension components can have the same or different cross-sectional shapes or sizes. Moreover, although the multi-component fiber 12 in the diagram includes ten extension components, it must be Acknowledgers, generally, two or more extension components can be arranged in a petal shape, and at least one extension component typically includes a temperature-adjustable material. Multi-component fibers 13 include a plurality of extension components arranged in a sea-island type. In this specific example, the first plurality of extended components 3 5, 3 5- 3 5〃, 3 5 and so on extend to a length substantially equal to the multicomponent fiber 1 3 and are separated from each other. The plurality of first extension components 3 5, 3 5, 3 5〃, 3 5⑴ are arranged in the second extension The component 36 is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the island is included in the second extended component, 36 islands. The arrangement of the islands " inside > The temperature-regulating material can be more uniformly distributed in the multi-component fiber 1 3. In this specific example, the cross-sectional shapes of each of the first plurality of extended components 3 5, 3 5 /, 3 5 〃, 3 5, etc. It is trapezoidal. However, it must be noted that other various regular or irregular cross-sectional shapes also belong to the scope of the present invention. For example, through the methods in the examples but not limited to these methods, there can be round, multi-lobed, octagonal , Ellipse, pentagon, rectangle, trapezoid, square, triangle, wedge, etc. Typically, many first extension components 3 5, 3 5 >, 3 5 ，,: 3 5 ... etc. may have the same or different Shape and size of the cross section. Also, although many The size of the fiber paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 public holiday) -19- 587110 A7 B7 V. Description of the invention (j dimension 1 3 includes 16 numerous first extension components 3 5, 3 5 /, 3 5〃, 3 5, etc., and are surrounded by the second extended component 36, but anthracene must be injected. Generally, one or more extended components are located in the extended component 3 6 and are surrounded by the second extended component 36. Surrounded. The multicomponent fiber 14 includes a plurality of extended components arranged in a stripe pattern. In this specific example, the first plurality of extended components, 3 7, 3 7 /, 3 7〃, 3 7 ... and the second plurality of extended components 3 8, 3 8 /, 3 8, 3 8 are dispersed in an alternating manner, and It has longitudinal stripes in the multicomponent fiber. Typically, the extension components may have the same or different cross-sectional shapes or sizes (e.g., widths associated with longitudinal sections). If desired, the multi-component fiber 14 may be a self-crimped or self-deformed fiber, and the self-crimped or self-deformed property of the fiber can make the fiber have bulky, insulating, and ductile properties. Although the multicomponent fiber 14 includes nine extension components as shown in the drawing, it must be noted that, in general, two or more extension components may be arranged in a stripe shape, and at least one of the extension components typically includes a temperature-regulating material. In the case of multi-component fibers 1 2 and 1 4, the first extended component (such as' 1 5) is shown to be surrounded by the adjacent second extended component or multi-component (such as' 1 6 and 16 " '). In the case of the multi-component fiber 1 3, the 'first extended component (eg, 3 5) is shown to be surrounded by a single complete second extended component 36. When the first extension component (such as 15) is not completely surrounded, it is suitable, but not required, to use a containment structure (such as a microcapsule) to contain the temperature-adjustable material dispersed in the first extension component. If necessary, these multi-component fibers 1 2, 1 3, and 1 4 can be further added to this paper size applicable to China National Standard (CNS) A4 specifications (210X297 mm) (Please read the precautions on the back before filling this page) Order! Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -20- 587110 A7 B7 V. Description of the invention (y (Please read the precautions on the back before filling this page) Fabricate one or more fibers with a smaller Denny number. For example, the elongation component including the multicomponent fiber 12 can be separated, or one or more of the elongation component (or one or more parts thereof) can be dissolved or dissolved. The resulting fiber with a small Denny number can, for example, include The intertwined extension components 15 and 16 are shown in column 20 of FIG. 1 as four exemplary core / sheath fibers 2 1, 2 2, 2 3 and 24. In particular, each sheath / core fiber 2 1, 2 2 '2 3, and 2 4 include a plurality of extension components arranged in a core / sheath type. Sheath / core fibers 2 1 include a first extension component 3 9 which is arranged in the second extension component 40 and It is surrounded by the second extension component 40. In particular, the first extension component 39 is formed as a core component including a temperature regulating material. This extension component is located at the center of the second extension component 40, and Surrounded by it, the second extension component constitutes the sheath component. In this example, the sheath / core fiber 2 1 includes a core component of 25% by weight and a sheath component of 75% by weight. Printed sheath / core fiber by the Consumer Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs 2 2 includes the first extension component 4 1 and The second extended component 4 2, wherein the second extended component 4 2 surrounds the first extended component 4 1. As described in the previous specific example, the first extended component 41 including the temperature-adjustable material forms a core component. This extended component 41 is located at the center of the second extension component 42 and is completely surrounded by it, and the second extension component 42 constitutes a sheath component. In this example, the sheath / core fiber 2 2 includes 50% by weight of the core component and 50% by weight of sheath component. Sheath / core fiber 2 3 includes the first extension component 4 3 and the second extension This paper size applies Chinese National Standard (CNS) A4 specification (210 x 297 mm) -21-Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative 587110 A7 __ B7 V. Description of the invention (j component 4 4 in which the second extended component 4 4 surrounds the first extended component 4 3. However, the first A core component formed by an extended component 4 3, located Offset from the center of the second extension component 4 4 constituting the sheath component. In this example, the sheath / core fiber 2 3 may include a core component and a sheath component in any weight ratio, so as to obtain the required temperature adjustment properties and mechanical properties. Two certain sheath / core fibers 2 4 include a first extension component 4 5 and a second extension component 4 6, wherein the second extension component 4 6 surrounds the first extension component 45. In this specific example, the first extension The component 45 forms a first extended component having a trilobal cross-sectional shape. The core component is located at the center of the second extended component 46 which forms a sheath component. The sheath / core fiber 24 can actually include a core component and a sheath component in any weight ratio, so as to obtain the required temperature-adjusting properties and mechanical properties. It must be noted here that the core component can generally have a variety of regular or irregular cross-sectional shapes, such as but not limited to circular, multi-lobal, polygonal, elliptical, pentagonal, rectangular, square, trapezoidal, triangular, and Wedge etc. Although the illustrated sheath / core fibers 2 1, 2 2, 2 3, and 2 4 have only one core component located in and surrounded by the sheath component, it must be noted that the sheath component may include two or more core components Ingredients (eg, similar to multi-component fiber 1 3). These core components may have the same or the same cross-sectional shape and size. According to a specific example of the present invention, the sheath / core fiber comprises three or more extension components arranged in a sheath-core structure, wherein the extension components are longitudinally concentric or centrifugal bands in the sheath / core fiber. The right column 30 in Figure 1 illustrates some of the specific examples of the present invention. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (2) 0X297 mm. (Please read the precautions on the back before filling in this. page)

-22- 587110 A7 _B7_ _ 五、發明説明（2(] 例並列型纖維。特定言之，每一並列型纖維2 6 ，2 7， 2 8，2 9，和3 4包括眾多以並列狀排列的延伸成份。 (請先閱讀背面之注意事項再填寫本買) 並列型纖維2 6包括第一延伸成份4 7和第二延伸成 份4 8 ，其中4 7鄰近4 8並被其部分包圍。在該具體實 例中延伸成份4 7和4 8的橫截面形狀爲半圓形。此處， 該並列型纖維2 6包括5 0重量％的第一延伸成份4 7和 5 0重量％的第二延伸成份4 8。此處必須注意到，延伸 成份4 7和4 8可以另外或同時以花瓣狀或條狀排列。 並列型纖維2 7包括第一延伸成份4 9和第二延伸成 份5 0，其中4 9鄰近5 0並被其部分包圍。在該具體實 例中，並列型纖維2 7包括2 0重量％的第一延伸成份 4 9和8 0重量％的第二延伸成份5 0。此處必須注意到 ，延伸成份4 9和5 0可以分別或一起以芯/鞘型排列， 其中第一延伸成份4 9位於第二延伸成份5 0中偏離圓心 的位置並被其部分包圍。 經濟部智慧財產局員工消費合作社印製 並列型纖維2 8和2 9是兩個範例混合粘度型纖維。 每股纖維的第一延伸成份5 1或5 3中分散著溫度調節性 材料，並且鄰近第二延伸成份5 2或5 4並被其部分包圍 。一般認爲混合粘度纖維是一種自捲曲或自變形纖維，其 中纖維的自捲曲或自變形性質使其具有蓬鬆，絕緣，伸展 或其他類似的性質。典型地，混合粘度纖維包括眾多由不 同聚合物型材料構成的延伸成份。例如，並列型纖維2 8 ’其桌一延伸成份5 1可以由一第一聚合物型材料構成， 而第二延伸成份5 2可以由第二聚合物型材料構成，其中 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） " -—- -23- 587110 A7 - —____B7 五、發明説明（21) (請先閲讀背面之注意事項再填寫本頁) 第二聚合物型材料可以以某種方式不同於第一聚合物型材 料。在該具體貫例中，第一聚合物型材料和第.二聚合物型 材料包括各具不同粘度或分子量的聚合物（如，分別爲兩 種不同分子量的聚丙烯或一聚丙烯和一聚乙烯）。拉製出 並列型纖維2 8後，延伸成份5 1和5 2之間可能造成不 均句應力’且並列型纖維2 8可能發生捲曲或彎曲。根據 本發明其他具體實例，第一聚合物型材料和第二聚合物型 材料可包括具有不同結晶度的聚合物。例如，第一聚合物 型材料相對於第二聚合物型材料可以具有較低的結晶度。 虽拉製出並列型纖維2 8時，第一聚合物型材料和第二聚 合物型材料可能進行不同程度的結晶和取向，從而、、鎖定 纖維2 8的取向和應力。當結晶度足夠大時可能需要防 止或減低纖維2 8在熱處理過程中的再取向。並列型纖維 2 8和2 9實際上可包括任意重量比的第一延伸成份和第 二延伸成份’從而得到所需的溫度調節性質，機械性質， 自捲曲性質和自變形性質。 經濟部智慧財產局員工消費合作社印製 並列型纖維3 4是一範例A B A纖維，該纖維包括一 位於第二眾多延伸成份5 6和5 6 >之間並被其部分包圍 的第一延伸成份5 5。在該具體實例中，第一延伸成份由 包括溫度調節性材料的第一聚合物形材料構成。而第二延 伸成份5 6和5 6 /可以由第一聚合物形材料構成，也可 以由不同於第一聚合物形材料的聚合物2構成。典型地， 延伸成份5 6和5 6 /具有不同的橫截面形狀與大小（如 ，不同位置具有不同寬度）。此處必須注意到延伸成份 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公趁） •24- 587110 A7 B7 五、發明説明（ ，5 6和5 6 /可以同時或分別以條狀排列。 接著參看圖2，顯示出的是一範例鞘一芯型纖維 的三維圖。鞘/芯型纖維5 9包括一 5 7和圍繞芯成份的環狀鞘成份5 8 芯成份5 7實質地延伸至鞘/芯型纖 溫度調節性材料6 1的芯成份5 7處 被其完全包圍或包住，鞘成份5 8則 在該具體實例中，溫度調節性材料6 材料的微囊，而微囊均勻的散佈在整 於此技者都明白，微囊較佳者係均勻 也不是對所有應用都是必須的。芯成 份5 8问心的或偏芯的位置，並且銷 上可包括任意重量比的芯成份5 7和 到所需的溫度調節性質和機械性質。 圖3示出另一鞘/芯型纖維6 〇 型纖維5 9 —樣，該鞘/芯型纖維6 般呈圓柱狀的芯成份 。在該具體實例中， 維5 9的長度。包括 在鞘成份5 8中，並 形成纖維的外皮層。 1包括眾多裝有相變 個芯成份5 7中。諳 散佈在芯成份中，但 份5 7可以位於鞘成 /芯型纖維5 9實際 鞘成份5 8，從而得 的三維圖。和鞘/芯 0包括一般呈圓柱狀 (請A·閱讀背面之注意事項再填寫本頁) — a = I...... I I -- · 衣· 訂l· 經濟部智慧財產局員工消費合作社印製 的芯成份6 3 ，其延伸至與鞘/芯型纖維6 〇大體相當的 長度。心成份6 3處在ί哀狀的銷成份6 4中，並被其完全 包住或圍住’而鞘成份形成纖維的外皮層。本例中的溫度 調節性材料6 2包括自然狀態分散的相變材料（如，相變 材料未進入囊體中，也就是非膠囊狀或非微囊狀分散）， 並且相變材料可以均勻的散佈在芯成份6 3中。諳於此技 者都明白’如果相變材料能夠均句的散佈到芯成份6 3中 ，可以扮到較佳的效果，但也不是對所有應用都是必須的 -Jt n lit · -25 587110 A7 經濟部智慧財產局員工消費合作社印製 五、發明説明（ 。圖3中示出的具體實例中，相變材料在芯成份6 3中彼 此分開，形成相互獨立的區域。鞘成份6 4圍繞芯成份 6 3 ，從而包住芯成份6 3中的相變材料。相應地，鞘成 份6 4可以防止或減小纖維處理或使用過程中相變材料的 滲漏或損失。芯成份6 3可以位於鞘成份6 4的同芯的或 偏芯的位置’鞘/芯型纖維6 0可包括任意重量比的芯成 份與鞘成份，以達到需要的溫度調節性質和機械性能。 圖4示出一個實例中的海包島型纖維7 〇的三維圖。 海包島型纖維7 0包括圓柱形的島成份7 2，7 3 ，7 4 ’ 7 5和海成份7 1 ，島成份散佈於海成份中，並被其圍 繞或包住。在該具體實例中，島成份7 2，7 3 ，7 4和 7 5實質地延伸至海包島型纖維7 0的長度。雖然本實施 例中只列出四個島成份，但是必須注意到海包島型纖維 7 0可以有其他數目的島成份，決定於海包島型纖維7〇 的合意應用。海成份7 1由海聚合物型材料8 2構成，島 成份7 2 ，7 3 ，7 4和7 5分別由島聚合物型材料7 6 ’ 77，78和79構成。海聚合物型材料82和島聚合 物型材料7 6 ，7 7，7 8，7 9可以相同也可以在某種 方式上不同。島成份72 ，73 ，74和75內可以分散 有一種或多種溫度調節性材料。如圖4所示，海包島型纖 維7 0包括兩種不同的溫度調節性材料8 0和8 1 。島成 份7 2和7 5包括溫度調節性材料8 0，而島成份7 3和 7 4包括溫度調節性材料8 1。此處，溫度調節性材料 8 1和8 2可以各自包括以自然狀態分散的相變材料，而 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X聊公釐） 衣-- (請先閱讀背面之注意事¾再填寫本頁j «41. —訂 HI. -26- 587110 A7 _____ B7 五、發明说明（2』 (請先閱讀背面之注意事項再填寫本頁) 在個別島成份中形成彼此分離的相。海成份7 1圍繞島成 份7 2，7 3 ’ 7 4和7 5，從而包住島海包島型纖維 •7 0中的相變材料。海包島型纖維7 0可包括任意重量比 的島成份7 2 ’ 7 3，7 4和7 5與海成份7 1 ，以達到 需要的溫度調節性質和機械性質。 經濟部智慧財產局員工消費合作社印製 如前所述’根據本發明某些具體實例，該多成份纖維 可包括一種或多種溫度調節性材料。一種溫度調節性材料 中可以有一種或多種相變材料，相變材料可包括任意的具 有在一定控溫範圍內經由吸收或釋放熱量以減小或消除熱 流這一性質的物質（或該種物質的摻合物）。控溫範圍可 包括一特別轉變溫度或一段轉變溫度範圍。本發明具體實 例中採用的相變材料最好在相變材料吸收或釋放能量時能 夠抑制熱能流動’一般是相變材料發生兩種狀態之間的相 變時（如’液態和固態，液態和氣態，固態和氣態，或兩 種固態）。該作用典型地爲短暫的，如在加熱或冷卻過程 中’發生至相變材料的相變潛熱被吸收或釋放爲止。相變 材料可以儲存或釋放熱量，並且經由加熱或冷源可以使相 變材料有效再生。經由選擇合適的相變材料，該多成份纖 維可以適用於各種不同的產品。 根據本發明具體實例，相變材料可爲固/固相轉變材 料。固/固相轉變材料一般是一種發生兩固相之間轉變的 相變材料（如’晶相或介晶相的轉變），且典型地在使用 過程中不會變成液相。 根據本發明多種具體實例，該多成份纖維中可以加入 本紙張尺度適用中國國家標準（CNS ) M規格（2i〇X297公釐） -27- 587110 A7 ______ _B7 五、發明説明（ (請先聞讀背面之注意事項再填寫本頁) 各種相轉變材料，包括多種有機或無機物質。根據實例 範例相轉變材料包括（但不限於）烴類（如，直鏈烷烴或 石蠟族烴’支鏈烷烴，不飽和烴，鹵化烴和環狀烴），水 合鹽（如’六水合氯化鈣，六水合溴化鈣，六水合硝酸鎂 ’二水□硝酸鋰’四水合氟化鉀，硫酸鋁銨，六水合氯化 錢，十水合碳酸鈉，十二水合磷酸二鈉，十水合硫酸鈉， 和二水合醋酸鈉），蠟，油，水，脂肪酸，脂肪酸酯，二 元酸，二元酯，1 一鹵化物，第一醇，芳族化合物，包合 物’半包合物，氣體包合物，酸酐（如，硬脂酸酐），乙 二醇碳酸酯，多羥基醇（如，2，2 一二甲基一 1 , 3 — 丙一醇，2〜羥甲基一 2 —甲基一 1 ，3 —丙二醇，乙二 醇’聚乙一醇’季戊四醇，雙季戊四醇，五聚丙三醇，四 甲醇基乙院’新戊二醇，四甲醇基丙醇，2 —胺基一 2 一 甲基一 1 ，3 —丙二醇，一胺基季戊四醇，二胺基季戊四 經濟部智慧財產局員工消費合作杜印製 醇和二（經甲基）乙酸），聚合物（如，聚乙烯，聚乙二 醇’聚環氧乙烷，聚丙烯，聚丙二醇，聚四亞甲基二醇， 聚丙烯丙二酸酯，聚新戊二醇癸二酸酯，聚戊烷戊二酸酯 ，聚肉豆蔑酸乙烯基酯，聚硬脂酸乙烯基酯，聚月桂酸乙 _基酯’聚甲基丙烯酸十六烷基酯，聚甲基丙烯酸十八烷 基醋’由乙二醇或其衍生物與二酸或其衍生物經由聚縮反 應製得的聚酯’及共聚物，例如烷烴側鏈或聚乙二醇側鏈 的聚丙烯酸酯或聚甲基丙烯酸酯，與包括聚乙烯，聚乙二 醇’聚環氧乙院’聚丙烯，聚丙二醇，或聚四亞甲基二醇 的共聚物’金屬’或上述的混合物。 本紙張尺度適用中國國家標準（CNS ) A4規格（2ΐ〇χ 297公慶） -28- A7-22- 587110 A7 _B7_ _ V. Description of the invention (2 () Examples of side-by-side fibers. In particular, each side-by-side fiber 2 6, 2 7, 2 8, 2 9, and 3 4 includes a plurality of side-by-side fibers. (Please read the precautions on the back before filling in this purchase) The side-by-side fiber 2 6 includes a first extension component 4 7 and a second extension component 4 8, of which 4 7 is adjacent to and surrounded by 4 8. In this specific example, the cross-sectional shapes of the extension components 47 and 48 are semicircular. Here, the side-by-side fiber 26 includes 50% by weight of the first extension component 47 and 50% by weight of the second extension. Component 4 8. It must be noted here that the extended components 4 7 and 4 8 may additionally or simultaneously be arranged in the shape of petals or stripes. The side-by-side fibers 2 7 include a first extended component 4 9 and a second extended component 50, of which 4 9 is adjacent to and surrounded by 50. In this specific example, the side-by-side fiber 27 includes 20% by weight of a first extension component 49 and 80% by weight of a second extension component 50. It is necessary here It is noted that the extension components 49 and 50 may be arranged in a core / sheath type separately or together, wherein the first extension component 4 9 is located off the center of the second extension component 50 and is surrounded by it. The side-by-side fibers 2 8 and 2 9 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs are two examples of mixed-viscosity fibers. The temperature-adjustable material is dispersed in the first elongation component 5 1 or 5 3 and is adjacent to and surrounded by the second elongation component 5 2 or 54. The mixed-viscosity fiber is generally considered to be a self-curling or self-deforming fiber in which The self-curling or self-deforming nature of the fiber makes it fluffy, insulating, stretchy, or other similar properties. Typically, mixed-viscosity fibers include a number of extension components composed of different polymer-type materials. For example, side-by-side fibers 2 8 ' Table 1 extended component 51 can be composed of a first polymer-type material, and the second extended component 51 can be composed of a second polymer-type material, in which the paper size applies to the Chinese National Standard (CNS) A4 specification (210X297) (%) &Quot; -—- -23- 587110 A7-—____ B7 V. Description of the invention (21) (Please read the notes on the back before filling this page) The second polymer type material Differ in some way from the first polymer-type material. In this specific example, the first polymer-type material and the second polymer-type material include polymers each having a different viscosity or molecular weight (eg, respectively Two kinds of polypropylene with different molecular weight or one polypropylene and one polyethylene). After drawing the parallel fibers 2 8, the stretched components 5 1 and 5 2 may cause uneven sentence stress' and the parallel fibers 2 8 may Curling or bending occurs. According to other specific examples of the present invention, the first polymer-type material and the second polymer-type material may include polymers having different crystallinity. For example, the first polymer-based material may have a lower crystallinity than the second polymer-based material. Although the side-by-side fibers 28 are drawn, the first polymer-type material and the second polymer-type material may undergo different degrees of crystallization and orientation, thereby locking the orientation and stress of the fibers 28. When the crystallinity is sufficiently large, it may be necessary to prevent or reduce the reorientation of the fiber 28 during the heat treatment. The side-by-side fibers 2 8 and 2 9 may actually include a first stretched component and a second stretched component 'at any weight ratio to obtain desired temperature-adjusting properties, mechanical properties, self-crimping properties, and self-deforming properties. The side-by-side fiber 3 4 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is an exemplary ABA fiber including a first extension component located between and surrounded by a second plurality of extension components 5 6 and 5 6 > 5 5. In this specific example, the first extension component is composed of a first polymer-shaped material including a temperature-adjustable material. The second extension components 56 and 56 / may be composed of the first polymer-shaped material, or may be composed of the polymer 2 different from the first polymer-shaped material. Typically, the extended components 5 6 and 5 6 / have different cross-sectional shapes and sizes (eg, different locations have different widths). It must be noted here that the extended components of this paper are in accordance with the Chinese National Standard (CNS) A4 specifications (210X297). 24--587110 A7 B7 V. Description of the invention (, 5 6 and 5 6 / can be arranged in strips simultaneously or separately Next, referring to FIG. 2, a three-dimensional view of an exemplary sheath-core fiber is shown. The sheath / core fiber 5 9 includes a 5 7 and a ring-shaped sheath component 5 8 surrounding the core component. The core component 5 7 extends substantially. The core component 5 of the sheath / core fiber temperature regulating material 6 1 is completely surrounded or enveloped by 7 thereof, and the sheath component 5 8 is a microcapsule of the temperature regulating material 6 in this specific example, and the microcapsule The uniform distribution is understood by those skilled in the art, even if the microcapsule is better, it is not necessary for all applications. The core component is centered or off-center, and the pin can include any weight ratio. The core component 57 and the required temperature-adjusting properties and mechanical properties are shown in Fig. 3. Fig. 3 shows another sheath / core fiber 60. The type 0 fiber 5 9 is the same. The sheath / core fiber 6 is generally a cylindrical core component. In this specific example, the length of dimension 5 9 is included in the sheath component 5 8 And forms the outer skin layer of the fiber. 1 includes a number of core components 5 7 filled with phase change. 谙 is scattered in the core component, but the portion 5 7 can be located in the sheath-forming / core fiber 5 9 the actual sheath component 5 8, The resulting three-dimensional figure. And the sheath / core 0 includes a generally cylindrical shape (please read the notes on the back and fill in this page) — a = I ...... II-· clothing · order l · economic The core component 6 3 printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives extends to a length substantially equivalent to the sheath / core fiber 60. The heart component 6 3 is in the sorrow-shaped pin component 6 4 and is Completely enveloping or enclosing 'while the sheath component forms the outer sheath of the fiber. The temperature-regulating material 62 in this example includes a phase change material dispersed in its natural state (eg, the phase change material does not enter the capsule, that is, non-capsule Or non-microcapsule-like dispersion), and the phase change material can be uniformly dispersed in the core component 63. Those skilled in the art understand that 'if the phase change material can be uniformly dispersed in the core component 63, it can be disguised. For better results, but not necessary for all applications -Jt n lit · -25 587110 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (. In the specific example shown in FIG. 3, the phase change materials are separated from each other in the core component 63 to form an independent area. The sheath component 64 surrounds the core Ingredient 6 3, thereby covering the phase change material in core ingredient 63. Correspondingly, sheath component 64 can prevent or reduce leakage or loss of phase change material during fiber processing or use. Core ingredient 63 can be located Concentric or eccentric position of the sheath component 6 4 The sheath / core fiber 60 may include a core component and a sheath component in any weight ratio to achieve the required temperature adjustment properties and mechanical properties. FIG. 4 shows a three-dimensional view of an island-in-sea fiber 70 in one example. The sea-island-type fiber 70 includes a cylindrical island component 7 2, 7 3, 7 4 ′ 7 5 and a sea component 7 1. The island component is dispersed in the sea component and is surrounded or surrounded by it. In this specific example, the island components 7 2, 7, 3, 74, and 7 5 extend substantially to the length of the sea-island-type fiber 70. Although only four island components are listed in this embodiment, it must be noted that the sea-island type fiber 70 may have other number of island components, which depends on the desired application of the sea-island type fiber 70. The sea component 7 1 is composed of a sea polymer type material 8 2, and the island components 7 2, 7 3, 7 4 and 7 5 are respectively made of an island polymer type material 7 6 ′ 77, 78 and 79. The sea polymer type material 82 and the island polymer type material 7 6, 7 7, 7 8, 7 9 may be the same or different in some way. The island components 72, 73, 74, and 75 may have one or more temperature-regulating materials dispersed therein. As shown in Fig. 4, the sea-island type fiber 70 includes two different temperature-regulating materials 80 and 8 1. The island components 72 and 75 include a temperature-adjustable material 80, and the island components 73 and 74 include a temperature-adjustable material 81. Here, the temperature-regulating materials 8 1 and 8 2 may each include a phase change material dispersed in a natural state, and this paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X chat mm). Read the notes on the back ¾ and then fill out this page j «41. — Order HI. -26- 587110 A7 _____ B7 V. Description of the invention (2" (Please read the notes on the back before filling this page) In the individual island ingredients Phases separated from each other. The sea component 7 1 surrounds the island components 7 2, 7 3 ′ 7 4 and 7 5, thereby encapsulating the phase change material in the island-in-sea island-type fiber • 70. The island-in-sea fiber 7 0 It can include island components 7 2 '7 3, 7 4 and 7 5 and sea components 7 1 in any weight ratio to achieve the required temperature-regulating properties and mechanical properties. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to some specific examples of the present invention, the multi-component fiber may include one or more temperature-adjustable materials. One temperature-adjustable material may have one or more phase change materials, and the phase change material may include any material having a certain temperature control. Absorb or release heat within range A substance (or a blend of such substances) that reduces or eliminates heat flow. The temperature control range may include a particular transition temperature or a range of transition temperatures. The phase change material used in the specific examples of the present invention is preferably in the phase Change materials can inhibit the flow of thermal energy when absorbing or releasing energy. Generally, a phase change material undergoes a phase change between two states (such as' liquid and solid, liquid and gaseous, solid and gaseous, or two solids). This effect Typically transient, such as during the heating or cooling process, until the latent heat of the phase change material is absorbed or released. The phase change material can store or release heat, and can make the phase change material effective by heating or cooling Regeneration. By selecting a suitable phase change material, the multi-component fiber can be suitable for various products. According to the specific example of the present invention, the phase change material can be a solid / solid phase transition material. The solid / solid phase transition material is generally a kind of occurrence A phase change material that transitions between two solid phases (such as a 'crystalline or mesogenic phase transition) and typically does not become a liquid phase during use. According to various specific examples of the present invention, the multi-component fiber can be added to the paper size applicable to the Chinese National Standard (CNS) M specification (2i0X297 mm) -27- 587110 A7 ______ _B7 5. Description of the invention ((Please read first Note on the back, please fill out this page again) Various phase transition materials, including a variety of organic or inorganic substances. According to the examples, phase transition materials include (but are not limited to) hydrocarbons (eg, straight-chain paraffins or paraffin hydrocarbons, branched-chain alkanes, Unsaturated hydrocarbons, halogenated hydrocarbons and cyclic hydrocarbons), hydrated salts (such as 'calcium chloride hexahydrate, calcium bromide hexahydrate, magnesium nitrate hexahydrate', lithium nitrate dihydrate, potassium nitrate tetrahydrate, ammonium aluminum sulfate, Chlorinium hexahydrate, sodium carbonate decahydrate, disodium phosphate dodecahydrate, sodium decahydrate dehydrate, and sodium acetate dihydrate), waxes, oils, water, fatty acids, fatty acid esters, dibasic acids, dibasic esters, 1 Monohalide, first alcohol, aromatic compound, inclusion compound'semi-inclusion compound, gas inclusion compound, acid anhydride (eg, stearic anhydride), ethylene glycol carbonate, polyhydric alcohol (eg, 2, 2 dimethyl-1, 3 — propane Alcohols, 2 ~ hydroxymethyl-1, 2-methyl-1, 3-propanediol, ethylene glycol 'polyethylene glycol' pentaerythritol, dipentaerythritol, pentaglycerol, tetramethanol methyl ethyl ether 'neopentyl glycol, tetramethanol Propyl alcohol, 2-amino-1, 2-methyl-1, 3-propanediol, monoamine pentaerythritol, diamine pentaerythritol, Intellectual Property Bureau of the Ministry of Economic Affairs, employee consumption cooperation Du printed alcohol and di (methyl) acetic acid ), Polymers (eg, polyethylene, polyethylene glycol, polyethylene oxide, polypropylene, polypropylene glycol, polytetramethylene glycol, polypropylene malonate, polypentyl glycol sebacate Esters, polypentane glutarate, polymyristate vinyl ester, polyvinyl stearate, polyethyl laurate 'polyhexadecyl methacrylate, polydecyl methacrylate Octyl vinegar 'Polyester produced by the polycondensation reaction of ethylene glycol or its derivative with a diacid or its derivative' and copolymers, such as polyalkylene esters of alkane side chains or polyethylene glycol side chains or Polymethacrylate, with polyethylene, polyethylene glycol 'polyethylene oxide' polypropylene, polypropylene glycol Or mixtures of the above or 'metal' copolymer of polytetramethylene glycol. This paper size applies to China National Standard (CNS) A4 specification (2ΐ〇χ 297 public celebration) -28- A7

587110 五、發明説明（ 相轉變材料的選擇典型地取決於所需要的轉變溫度或 所多成份纖維的合意應用。例如，具有接近室溫的轉變 溫度之相變材料宜於供將所得多成份纖維摻加到經設計成 讓使用者保持舒適溫度的衣物中之應用所用。 根據本發明某些具體貫例，相轉變材料的轉變溫度範 圍可爲約- 5 °C到約1 2 5 °C。於現時供衣著應用所用的 較佳具體實例中，相轉變材料的轉變溫度爲在約2 2 °C到 約4 0 °C或約2 2 °C到約2 8 °C範圍內。 根據本發明具體實例，特別有用的相變材料包括碳數 在1 0 - 4 4的鏈烷烴（亦即C i Q - C 4 4鏈烷烴）。表1 列出可以在本文所述多成份纖維中用作相變材料的範例 (請先閱讀背面之注意事項再填寫本頁) !鏈院烴。鏈院烴的熔點一般與其碳數有關。例 如正二十八烷，其每分子中含有2 8個直鏈的碳原子，熔 點爲6 1 . 4 C。比較正十二院’其每分子中含有1 3個 直鏈的碳原子，熔點爲- 5 · 5 °C。根據本發明一具p實 例，每分子含有十八個直鏈碳原子且其熔點爲2 8 . 2。〇 的正十八烷特別適合用於衣物應用中。587110 V. Description of the invention (The choice of phase transition material typically depends on the required transition temperature or the desired application of the multicomponent fiber. For example, a phase change material with a transition temperature close to room temperature is suitable for the multicomponent fiber For use in applications incorporated in clothing designed to maintain a comfortable temperature for the user. According to certain embodiments of the present invention, the transition temperature of a phase change material can range from about -5 ° C to about 125 ° C. In the presently preferred embodiment for clothing applications, the phase transition material has a transition temperature in the range of about 22 ° C to about 40 ° C or about 22 ° C to about 28 ° C. According to the present invention Specific examples of particularly useful phase change materials include alkanes with a carbon number of 10 to 4 (ie C i Q-C 4 4 alkanes). Table 1 lists those that can be used in the multicomponent fibers described herein. Examples of phase change materials (please read the notes on the back before filling this page)! Chain chain hydrocarbons. The melting point of chain chain hydrocarbons is generally related to its carbon number. For example, n-octacosane contains 2 8 The carbon atom of the chain, the melting point is 6 1. 4 C. Compare positive ten Yuan 'each molecule contains 13 straight-chain carbon atoms with a melting point of -5 · 5 ° C. According to an example of the present invention, each molecule contains eighteen straight-chain carbon atoms and its melting point is 2 8. 2.0 n-octadecane is particularly suitable for use in clothing applications.

CC

-C 訂 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -29- 587110 A7 B7 五、發明説明（27) 表 1 經濟部智慧財產局員工消費合作社印製 碳原子數 熔點（°C ) 正二十八烷 2 8 6 1.4 正二十七烷 2 7 5 9.0 正二十六烷 2 6 5 6.4 正二十五烷 2 5 5 3.7 正二十四烷 2 4 5 0.9 正二十三烷 2 3 4 7.6 正二十二烷 2 2 4 4.4 正二十一烷 2 1 4 0.5 正二十烷 2 0 3 6.8 正十九烷 19 3 2.1 正十八院 18 2 8.2 正十七烷 17 2 2.0 正十六烷 16 18.2 正十五烷 15 10.0 正十四烷 14 5 . 9 正十三烷 13 -5.5 其他有用的相變材料包括聚合物型相變材料，其轉變 溫度必須適用於多成份纖維的合意應用範圍（如，用於衣 物時的轉變溫度約2 2 °C到約4 0 °C )。聚合物型相變材 料可以具有包括一或多種單體單元的多種鏈結構。特定言 之，聚合物型相變材料可包括直鏈聚合物，支鏈聚合物（ 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 衣· I訂 b. -30- 587110 經濟部智慧財產局員工消費合作社印製 A7 五、發明説明（ 如’星形支鍵聚合物’梳形支鍵聚合物，樹枝狀支鍵聚合 物），或彼等的混合物。聚合物型相變材料可包括均聚物 ，共聚物（如，三元共聚物，統計共聚物，無規共聚物， 交替共聚物，週期型共聚物，嵌段共聚物，星形共聚物， 或接枝共聚物），或彼等的混合物。諳於此技者都知道， 聚合物的反應性和官能性可以經由添加官能基來改變，例 如胺基，醯胺基，羧基，羥基，酯基，醚，環氧基，酸酐 ，異氰酸酯，矽烷，酮和醛。此外，包括相變材料的一種 聚合物也可以交聯，交纏或氫鍵結合，從而提高其初性或 對熱，溼氣，或化學品抗性。 根據本發明某些具體貫例，由於聚合物型相變材料較 之於非聚合物型相變材料（如鏈烷烴）具有較大的分子量 ’分子尺寸和粘度，使其可以得到較佳的效果。由於其較 大的分子尺寸和粘度’聚合物型相變材料在多成份纖維處 理和使用過程中渗漏的可能性減小。例如當在鞘/芯型纖 維和海包島型纖維中加入該聚合物型材料，由於其較大的 为卞尺寸或較局的粘度’其很難穿過構成纖維外表的鞘成 份或海成份。當根據本發明具體實例在多成份纖維中加入 聚合物型相變材料’ g亥聚合物型相變材料除能提供溫度調 節性質外，還可以改善纖維的機械性能（如，展延性，抗 張強度和硬度）。如果需要，具有合適轉變溫度的聚合物 型相變材料可以和另一相變材料結合形成纖維的延伸成份 。根據本發明某些具體實例，聚合物型相變材料可提供足 夠的機械性質’使其可以不需該聚合物型材料而單獨構成 本紙張尺度適用中國國家襟準（CNS ) A4規格（210X297公釐) ------ (請先閲讀背面之注意事項再填寫本頁)-C Order Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -29- 587110 A7 B7 V. Description of the invention (27) Table 1 Wisdom of the Ministry of Economic Affairs Printed carbon atom number melting point (° C) by the Consumer Cooperative of the Property Bureau n-octacosane 2 8 6 1.4 n-heptacosane 2 7 5 9.0 n-heptacosane 2 6 5 6.4 n-heptacosane 2 5 5 3.7 N-tetracosane 2 4 5 0.9 N-coscosane 2 3 4 7.6 N-coscosane 2 2 4 4.4 N-icosane 2 1 4 0.5 N-icosane 2 0 3 6.8 N-nonadecane 19 3 2.1 Nine Eighteen Houses 18 2 8.2 N-Heptadecane 17 2 2.0 N-Hexadecane 16 18.2 N-Pentadecane 15 10.0 N-Tetradecane 14 5. 9 N-Tridecane 13 -5.5 Other useful phase change materials include For polymer-based phase change materials, the transition temperature must be suitable for the desired application range of the multicomponent fiber (for example, the transition temperature for clothing is about 2 ° C to about 40 ° C). The polymer-type phase change material may have a variety of chain structures including one or more monomer units. In particular, polymer phase change materials can include linear polymers, branched polymers (this paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) (Please read the precautions on the back before (Fill in this page) Clothing · Order b. -30- 587110 Printed by A7, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs 5. Description of the invention Polymers), or mixtures thereof. Polymeric phase change materials may include homopolymers, copolymers (eg, terpolymers, statistical copolymers, random copolymers, alternating copolymers, periodic copolymers, Block copolymers, star copolymers, or graft copolymers), or mixtures thereof. As those skilled in the art know, the reactivity and functionality of polymers can be changed by adding functional groups, such as amine groups. , Amine, carboxyl, hydroxy, ester, ether, epoxy, anhydride, isocyanate, silane, ketone and aldehyde. In addition, a polymer including phase change materials can also be crosslinked, entangled or hydrogen bonded, Thereby improving its originality Resistant to heat, moisture, or chemicals. According to certain embodiments of the present invention, polymer phase change materials have a larger molecular weight than non-polymer phase change materials (such as paraffins). Size and viscosity, so that it can get better results. Due to its larger molecular size and viscosity, polymer-type phase change materials are less likely to leak during multicomponent fiber processing and use. For example, when in the sheath / The core-type fiber and the sea-island-type fiber are added with the polymer-type material, and because of its larger size or local viscosity, it is difficult to pass through the sheath or sea component that constitutes the appearance of the fiber. Specific Examples of the Invention Addition of a polymer-type phase change material to a multi-component fiber In addition to providing temperature-regulating properties, the polymer phase change material can also improve the mechanical properties of the fiber (eg, ductility, tensile strength, and hardness ). If necessary, a polymer-type phase change material with a suitable transition temperature can be combined with another phase change material to form an extended component of the fiber. According to some specific examples of the present invention, the polymer type The variable material can provide sufficient mechanical properties, so that it can be constituted without the polymer type material. This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) ------ (Please read first (Notes on the back then fill out this page)

-31 - 587110 A7 _______B7___ 五、發明説明（ 延伸成份’這樣可以加入高濃度的聚合物型相變材料，從 而改善纖維的溫度調節性質。 (請先閲讀背面之注意事項再填寫本頁) 舉例來說，本發明某些具體實例中可以採用聚乙二醇 作爲相變材料。聚乙二醇的熔點一般隨著數平均分子量的 改變而變。例如，數平均分子量5 7 〇 — 6 3 〇的聚乙二 醇（如，Carbowax 6 0 〇）其熔點爲 2 0 °C — 2 5 °C ， 使其適用於衣物應用。其他適用於不同控溫範圍的聚乙二 醇包括 Carbowax 4 0 0 (熔點 4 °C — 8 °C ) ，Carbowax 1 5 0 0 (熔點 4 4 °C — 4 8 °C )，和 Carbowax 6〇0 0 (熔點5 6 r — 6 3 °C )。本發明中的某些具體 實例中也可以採用熔點在6 0 °C - 6 5 t之間的聚環氧乙 烷作爲溫度調節性材料。其他合意的相變材料包括熔點在 〇 °C - 4 0 °C之間的聚酯，該聚酯可爲二元醇（或其衍生 物）與二元酸（或其衍生物）縮聚形成者。表2中列出多 種可由二元醇與二元酸組合製得的範例聚酯材料之熔點。 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -32- 587110-31-587110 A7 _______B7___ 5. Description of the invention (Extension component 'This can add a high concentration of polymer-type phase change material, so as to improve the temperature adjustment properties of the fiber. (Please read the precautions on the back before filling this page) Examples That is, polyethylene glycol can be used as a phase change material in some specific examples of the present invention. The melting point of polyethylene glycol generally changes with the change of the number average molecular weight. For example, the number average molecular weight of 5 7-0-6 3 0 Glycol (eg Carbowax 6 0 〇) has a melting point of 20 ° C-2 5 ° C, making it suitable for clothing applications. Other polyethylene glycols suitable for different temperature control ranges include Carbowax 4 0 0 (melting point 4 ° C — 8 ° C), Carbowax 1 5 0 0 (melting point 4 4 ° C — 4 8 ° C), and Carbowax 6 0 0 (melting point 5 6 r — 6 3 ° C). In some specific examples, polyethylene oxide with a melting point between 60 ° C-65 t can also be used as a temperature regulating material. Other desirable phase change materials include melting points between 0 ° C-40 ° C. Polyester, which can be a diol (or a derivative thereof) and a diol (Or its derivative) the formation of polycondensation. Table 2 lists the melting points of a variety of exemplary polyester materials that can be prepared by the combination of glycols and dibasic acids. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. National Standard (CNS) A4 Specification (210X297 mm) -32- 587110

AA

7 B 五、發明説明（3() 表 2 經濟部智慧財產局員工消費合作社印製 二 元 醇 二元酸 聚酯熔點（t' ) 乙 二 醇 碳 酸 39 乙 二 醇 庚 二 酸 2 5 乙 二 醇 二 甘 醇 酸 17-20 乙 二 醇 硫 二 戊 酸 2 5-28 1 > 2 — 丙 二 醇 二 甘 醇 酸 17 丙二醇 丙 二 酸 3 3 丙二醇 戊 二 酸 3 5-39 丙 二 醇 二 甘 醇 酸 2 9-32 丙 二 醇 庚 二 酸 37 1 3 3 — 丁 二 醇 硫 苯 基 二 戊 酸 32 1 3 - 丁 二 醇 聯 苯 甲 酸 3 6 1 J 3 - 丁 二 醇 二 苯 甲 院 間 二 酸 38 1 3 — 丁 二 醇 反 式 對 苯 二 甲 酸 18 丁二醇 戊 二 酸 36-38 丁 二 醇 庚二酸 38-4 1 丁二醇 壬 一 酸 37-39 丁二醇 硫 二 戊 酸 37 丁 二 醇 鄰 苯 二 甲 酸 17 丁 二 醇 二 戊 酸 3 4 新 戊 二 醇 乙 一 酸 3 7 新 戊 二 醇 辛 二 酸 17 新 戊 二 醇 癸二酸 26 戊二醇 琥 珀 酸 3 2 戊 二 醇 戊 二 酸 22 戊 二 醇 乙 — 酸 3 6 戊 一 醇 庚 二 酸 39 戊 二 醇 對 苯 二 乙 酸 3 3 戊二醇 二 甘 醇 酸 3 3 己 — 醇 戊 二 酸 28-34 己 一 醇 4 — 辛 二 酸 酯 20 庚 二 醇 草 酸 3 1 戌 一 醇 4 - 辛 二 酸 酯 39 壬 — 醇 間 苯 二 甘 醇 酸 3 5 癸 二 醇 丙二酸 2 9-34 癸 二 醇 間 苯 二 酸 3 4-36 癸 二 醇 內 消 旋 酒 石 酸 33 二 乙 二 醇 草 酸 1 0 二 乙 二 醇 辛二酸 2 8-35 二 乙 二 醇 癸 二 酸 3 6-44 二 乙 二 醇 鄰 苯 二 甲 酸 11 二 乙 二 醇 反 式 對 苯 二 甲 酸 2 5 三 乙 二 醇 辛 二 酸 28 三 乙 二 醇 硫 苯 基 二 戊 酸 24 三 乙 二 醇 鄰 苯 二 甲 酸 10 三 乙 二 醇 二 戊 酸 38 對 二 羥 基 甲 苯 丙二酸 36 間 二 羥 基 甲 苯 辛 二 酸 27 間 二 羥 基 甲 苯 二 乙 二 醇 酸 3 5 C— (請先閱讀背面之注意事項再填寫本頁)7 B V. Description of the invention (3 () Table 2 Melting point (t ') of glycol dibasic polyester polyester printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy 2 Glycol carbonate 39 Glycol pimelic acid 2 5 Ethylene Glycolic acid 17-20 Ethylene glycol thiovaleric acid 2 5-28 1 > 2 — Propylene glycol diethylene glycol acid 17 Propylene glycol malonic acid 3 3 Propylene glycol glutaric acid 3 5-39 Propylene glycol diethylene glycol 2 9-32 Propanediol pimelic acid 37 1 3 3-Butanediol thiophenyl divaleric acid 32 1 3-Butanediol dibenzoic acid 3 6 1 J 3-Butanediol dibenzoic intermedium diacid 38 1 3 — Butanediol trans terephthalic acid 18 Butanediol glutaric acid 36-38 Butanediol pimelic acid 38-4 1 Butanediol azelaic acid 37-39 Butanediol thiodivalerate 37 Butanediol Phthalic acid 17 Butanediol dipentanoic acid 3 4 Neopentyl glycol monocarboxylic acid 3 7 Neopentyl glycol suberic acid 17 Neopentyl glycol sebacic acid 26 Pentylene glycol succinic acid 3 2 Pentylene glycol glutaric acid 22 Pentylene glycol ethane-acid 3 6 Pentyl alcohol pimelic acid 39 Pentylene glycol terephthalic acid 3 3 Pentylene glycol diethylene glycol 3 3 Hexa — Alcohol glutaric acid 28-34 Hexyl alcohol 4-suberic acid ester 20 Heptanediol oxalic acid 3 1 Phenyl alcohol 4-Suberic acid ester 39 Nonyl alcohol isophthalic acid 3 5 Decanediol malonic acid 2 9-34 Decanediol isophthalic acid 3 4-36 Decane meso-tartaric acid 33 Diethylene glycol oxalic acid 1 0 Diethylene glycol suberic acid 2 8-35 Diethylene glycol sebacic acid 3 6 -44 Diethylene glycol phthalic acid 11 Diethylene glycol trans terephthalic acid 2 5 Triethylene glycol suberic acid 28 Triethylene glycol thiophenyl divaleric acid 24 Triethylene glycol phthalic acid 10 Triethylene glycol divaleric acid 38 p-dihydroxytoluene malonic acid 36 m-dihydroxytoluene Acid 27 A dihydroxy terephthalic acid ethylene glycol 3 5 C- (Read Notes on the back and then fill the page)

、1T 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -33- 587110 Α7 Β7 五、發明説明（31) . -- (請先閲讀背面之注意事項再填寫本頁) 根據本發明一些具體實例，具有合適轉變溫度的聚合 物型相變材料可以經由將一種相變材料（如上述範例相變 材料）與聚合物（或混合聚合物）反應得到。舉例來說， 正十八酸（硬脂酸）可以與聚乙燦醇反應或醋化得到聚乙 細硬脂酸酉Η，或將十二酸（月桂酸）用聚乙傭醇反應或醋 化洛到聚月桂酸乙烯酯。也可以將多種相變材料合倂（如 具有一種或多種官能基的相變材料如，胺基，羧酸，羥基 ，壞氧基，矽烷，硫酸基等）且與聚合物反應得到具有較 佳轉變溫度的聚合物型相轉變材料。 一種相轉變材料可包括兩種或多種物質的混合物（如 ，兩種或多種上述範例相轉變材料）。經由選用兩種或多 種不同的物質（如兩種不同的鏈烷烴）且形成彼等的混合 物，可以將控溫範圍調整加寬，從而供多成份纖維的任何 特別應用所用。根據本發明某些具體實例，當在多成份纖 維中摻加兩種或多種物質的混合物時，該多成份纖維可展 現出兩段或多段不同的轉變溫度，或一段經改變的轉變溫 度。 經濟部智慧財產局員工消費合作社印製 根據本發明一些具體實例，溫度調節性材料中的相變 材料可以呈自然狀態分散（如，相變材料爲非囊裝者，亦 即非微囊狀或巨囊態）。在製造多成份纖維過程中，自然 狀態的相變材料可以以多種形式的固態存在（如塊狀，粉 末狀，小球狀，顆粒狀，薄片狀等）或以多種形式的液態 存在（如熔融態，溶解於溶劑中等）。 根據本發明其他具體實例，溫度調節性材料可包括盛 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） -34- 587110 A7 B7 五、發明説明（32) (請先閲讀背面之注意事項再填寫本頁} 裝結構以囊包，盛裝，圍繞，吸收相變材料或與相變材料 反應。在製is多成fb纖維或生產其產品的過程中，此盛裝 結構可以予以相變材料有效的保護（如在高溫或高剪應力 條件下保護相變材料）。而且，盛裝結構可以減輕或防止 多成份纖維使用過程中相變材料的損失。根據本發明某些 具體實例，採用盛裝結構係合宜者，但不要求，於其中有 相變材料分散其內的第一延伸成份被第二延伸成份所不完 全包圍。 經濟部智慧財產局員工消費合作社印製 舉例來說，溫度調節性材料可包括眾多裝有相變材料 的微囊，且該微囊可以均勻的或不均勻的分散在至少一個 延伸成份中。微囊可以形成相變材料的皮層，而且可包括 具有規則或不規則形狀的個別的微囊（如，球形，橢球形 等）。其中單個的微囊可以具有相同的或不同的形狀或大 小。根據本發明某些具體實例，微囊的最大線型尺寸（如 直徑）可以爲約0 . 0 1到約1 〇 〇微米。於本發明一較 佳具體實例中，該微囊通常爲球體狀且其最大線型尺寸（ 如直徑）在約0 · 5到約3微米之間。其他盛裝結構的例 子包括，例如但不限於，二氧化矽顆粒（如沈澱二氧化矽 顆粒，發煙二氧化矽顆粒，和其混合物），沸石顆粒，碳 粒子（如，石墨顆粒，活性炭粒子，和其混合物），和吸 收劑物質（如，聚合物吸收劑，超吸收劑物質，纖維質物 質，聚（甲基）丙烯酸酯材料，聚（甲基）丙烯酸物質的 金屬鹽，或上述的混合物）。例如，溫度調節性材料中可 包括塡充有相變材料的二氧化矽顆粒，碳顆粒，或一種吸 本紙張尺度適用中國國家標準（ CNS ) A4規格（210X297公釐） 一 ' -35- 587110 經濟部智慧財產局員工消費合作社印製 中關家標準（CNS ) A4規格7^ 297公| } A7 B7 五、發明説明（θ 收劑物質。 根據本發明某些具體實例，一或多種延伸成份可包括 高達約1 0 0重量％的溫度調節性材料。典型地，一個延 伸成份中可包括高達約9 0重量％的溫度調節性材料（如 ，咼達約5 0重量％或高達約2 5重量％ )。根據目前較 佳的一些具體實例，延伸成份中的溫度調節性材料約5重 纛％到約7 0重量％。如此，在一具體實例中，延伸成份 可包括6 0重量％溫度調節性材料，且在其他具體實例中 ，延伸成份可包括約1 〇重量％到約3 〇重量％或約丄5 重量％到約2 5重量％溫度調節性材料。 如上所述，根據本發明一些具體實例，該多成份纖維 可包括眾多延伸成份。此等延伸成份可以由相同的或不同 的聚合物型材料製得。根據本發明某些具體實例，延伸成 份可包括由具有分散在其內的溫度調節性材料之第〜聚合 物型材料製得的第一延伸成份（或第一眾多延伸成份f = 另外，延伸成份可包括由第二聚合物型材料製得的第一延 伸成份（或第二眾多延伸成份），其中第二聚合物型材料 可以在某種方式不同於第一聚合物型材料。此處必須注意 到延伸成份可以由相同的聚合物型材料製得，即第—2 一聚合物型材料是相同的。根據本發明某些具體實例，溫 度調節性材料可包括聚合物型相變材料，該相變材料可f 提供足夠強的機械性胃’使#可以不需該第—聚纟物材:: 即構成第一延伸成份（或眾多第一延伸成份）。 、 通常’聚合物型材料（如，第—聚合物型材料或第二 (請先閱讀背面之注意事項再填寫本頁)、 1T This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) -33- 587110 Α7 Β7 V. Description of invention (31).-(Please read the precautions on the back before filling this page) In some specific examples of the present invention, a polymer-type phase change material having a suitable transition temperature can be obtained by reacting a phase change material (such as the above-mentioned exemplary phase change material) with a polymer (or a mixed polymer). For example, n-octadecanoic acid (stearic acid) can be reacted or vinegarized with polyethylene glycol to obtain poly (ethylene stearate), or dodecanoic acid (lauric acid) can be reacted with polyethylene glycol or vinegar. Mellow to Polyvinyl Laurate. It is also possible to combine multiple phase change materials (such as phase change materials with one or more functional groups such as amine, carboxylic acid, hydroxyl, badoxy, silane, sulfate, etc.) and react with the polymer to obtain a better Polymer-type phase transition material with transition temperature. A phase change material may include a mixture of two or more substances (eg, two or more of the above-mentioned exemplary phase change materials). By selecting two or more different substances (such as two different paraffins) and forming their mixtures, the temperature control range can be adjusted and widened for any special application of multicomponent fibers. According to some embodiments of the present invention, when a multi-component fiber is blended with a mixture of two or more substances, the multi-component fiber may exhibit two or more different transition temperatures, or a changed transition temperature. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to some specific examples of the present invention, phase change materials in temperature-regulating materials can be dispersed in a natural state (for example, phase change materials are non-encapsulated, that is, non-encapsulated or Macrocystic state). In the manufacture of multi-component fibers, phase change materials in their natural state can exist in various forms of solids (such as lumps, powders, pellets, granules, flakes, etc.) or in various forms of liquids (such as molten State, dissolved in solvents, etc.). According to other specific examples of the present invention, the temperature-regulating material may include the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) -34- 587110 A7 B7 V. Description of the invention (32) (Please read the back Please fill in this page again for attention} The packaging structure is to encapsulate, contain, surround, absorb phase change materials or react with phase change materials. In the process of making BF fiber or producing its products, this packaging structure can be phase changed. Effective protection of materials (such as protecting phase change materials under high temperature or high shear stress conditions). Furthermore, the containment structure can reduce or prevent the loss of phase change materials during the use of multi-component fibers. According to some specific examples of the present invention, the use of containment The structure is suitable, but it is not required. The first extension component in which the phase change material is dispersed is not completely surrounded by the second extension component. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, for example, temperature regulation The material may include a plurality of microcapsules filled with a phase change material, and the microcapsules may be uniformly or unevenly dispersed in at least one extension component The microcapsules can form a cortex of a phase change material, and can include individual microcapsules (eg, spherical, ellipsoidal, etc.) having a regular or irregular shape. The individual microcapsules can have the same or different shapes or sizes. According to some specific examples of the present invention, the maximum linear size (eg, diameter) of the microcapsules may be about 0.01 to about 100 microns. In a preferred embodiment of the present invention, the microcapsules are generally spherical and Its maximum linear size (such as diameter) is between about 0.5 and about 3 microns. Examples of other containment structures include, for example, but not limited to, silica particles (such as precipitated silica particles, fumed silica particles) , And mixtures thereof), zeolite particles, carbon particles (eg, graphite particles, activated carbon particles, and mixtures thereof), and absorbent materials (eg, polymer absorbents, superabsorbent materials, cellulosic materials, poly (methyl) ) Acrylate materials, metal salts of poly (meth) acrylic materials, or mixtures of the foregoing). For example, temperature-adjustable materials may include dioxide filled with phase change materials Silicon granules, carbon granules, or a paper size suitable for the Chinese National Standard (CNS) A4 (210X297 mm)-'35 -587110 Printed by Zhongguanjia Standard (CNS) A4 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Specifications 7 ^ 297 male |} A7 B7 V. Description of the invention (θ-receiving substance. According to some specific examples of the present invention, the one or more elongating ingredients may include up to about 100% by weight of temperature-regulating materials. Typically, An extended component may include up to about 90% by weight of a temperature-adjustable material (eg, up to about 50% by weight or up to about 25% by weight). According to some currently preferred embodiments, the temperature in the extended component The conditioning material is from about 5 weight percent to about 70 weight percent. As such, in a specific example, the extension component may include 60% by weight of a temperature-adjustable material, and in other specific examples, the extension component may include about 10% by weight to about 30% by weight or about 5% by weight to About 25% by weight of a temperature-adjustable material. As mentioned above, according to some embodiments of the present invention, the multi-component fiber may include a plurality of elongation components. These extensions can be made from the same or different polymer-type materials. According to some specific examples of the present invention, the extension component may include a first extension component (or a plurality of extension components f = In addition, an extension component) made of a polymer material having a temperature-adjustable material dispersed therein. It may include a first extension component (or a second plurality of extension components) made from a second polymer type material, where the second polymer type material may be different from the first polymer type material in some way. It must be noted here The extension component can be made of the same polymer-type material, that is, the first two polymer-type materials are the same. According to some specific examples of the present invention, the temperature-regulating material may include a polymer-type phase change material. The variable material can provide a sufficiently strong mechanical stomach so that the first polymer material is not required: that is, the first extension component (or many first extension components) is formed. Generally, a polymer-type material (such as First, polymer type material or second (Please read the precautions on the back before filling this page)

-36 - M7110 A7 --------__B7 五、發明説明（34) -- 聚合物型材料）可包括任意的能夠形成延伸成份的聚合物 (或聚合物的混合物）。根據本發明一些具體實例，延伸 成ί刀可以由任思的纖維形成性聚合物（或纖維形成性聚合 物的混□物）所形成。根據本發明具體實例，當採用熔融 紡絲法形成多成份纖維時，聚合物型材料中可包括一種熱 塑聚合物（或熱塑聚合物混合物）（亦即可經加熱製得熔 融體，且隨後成型或模製形成一延伸成份）。根據本發明 其他具體實例，聚合物型材料中可包括一種彈性體聚合物 (或其混合物）。 聚合物型材料包括的聚合物（或聚合物的混合物）可 具有一種或多種單體單位構成的多種鏈結構。特定言之， 聚合物型材料可包括線型聚合物，支鏈聚合物（星形支鏈 聚合物’梳形支鏈聚合物，樹枝狀支鏈聚合物），或其混 合物。聚合物型材料可包括均聚物，共聚物（如，三元共 聚物’統計共聚物，無規共聚物，交替共聚物，週期型共 聚物’嵌段共聚物，星形共聚物，或接枝共聚物），或其 混合物。諳於此技者都知道，聚合物的反應性和功能性可 以經由添加官能基來改變，例如胺基，醯胺基，羧基，羥 基’酯基，醚，環氧基，酸酐，異氰酸酯，矽烷，酮和醛 。包括相變材料的一種聚合物也可以相互交聯，交纒或以 氫鍵結合，從而提高其韌性或對熱，溼氣，或化學品抗性 〇 根據本發明多種具體實例，製備延伸成份的範例聚合 物包括，例如但不限於，聚醯胺（如，尼龍6 ，尼龍6 / 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X297公釐） (請先閲讀背面之注意事項再填寫本頁) C· 訂 經濟部智慧財產局8工消費合作社印製 -37- 587110 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（ 6 ，尼龍1 2，聚天冬胺酸，聚榖胺酸等），聚胺，聚亞 醯胺，聚丙烯酸（如聚丙烯醯胺，聚丙烯腈，甲基丙烯酸 酯，丙烯酸酯等），聚碳酸酯（如聚雙酚A碳酸酯，聚碳 酸丙一酯等），聚二烯（如聚丁二烯，聚異戊二烯，聚原 冰片烯等），聚環氧化物，聚酯（如聚對苯二甲酸乙二醇 醋’聚對苯二甲酸丁二醇酯，聚對苯二甲酸丙二醇酯，聚 已內酯，聚乙交酯，聚***酯，聚羥基丁酸酯，聚羥基戊 酸酯’聚己二酸乙二醇酯，聚己二酸丁二醇酯，聚琥珀酸 丙二醇酯等），聚醚（如聚乙二醇（聚環氧乙烷），聚丁 一醇’聚環氧丙院，聚氧亞甲基（多聚甲醒），聚四亞甲 基醚（聚四氫呋喃），聚表氯醇等），聚氟碳化合物，甲 醛聚合物（如脲-甲醒，三聚氰胺一甲醒，苯酣一甲醛等 )’天然聚合物（如纖維素，殻聚糖，木質素，鱲等）， 聚烯烴（如聚乙烯，聚丙烯，聚丁烯，聚（異）丁烯，聚 辛烯等），聚伸苯基（如聚苯氧醚，聚苯硫醚，聚苯颯_ 等），含矽聚合物（如聚二甲基矽氧烷，聚羧甲基矽烷等 )’聚胺基甲酸酯，乙烯聚合物（如聚乙烯縮丁醛，聚乙 烯醇，聚乙烯醇的酯和醚，聚乙酸乙烯酯，聚苯乙烯，聚 甲基苯乙烯，聚氯乙烯，聚乙烯吡咯烷酮，聚甲基乙烯|迷 ，聚乙基乙烯醚，聚乙烯基甲基酮等），聚縮醛，聚芳基 化合物，和共聚物（如聚乙烯-共-乙酸乙烯酯，聚乙少希 一共—丙烯酸，聚對苯二甲酸丁二酯一共一對苯二甲酸乙 二酯，.聚月桂內醯胺一嵌段一四氫呋喃等）。 根據本發明具體實例，第一聚合物型材料中可包括〜 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁)-36-M7110 A7 --------__ B7 V. Description of the Invention (34)-Polymer-type materials) may include any polymer (or polymer mixture) capable of forming an extended component. According to some specific examples of the present invention, the extension knife can be formed of any of the fiber-forming polymers (or a mixture of fiber-forming polymers). According to a specific example of the present invention, when a multi-component fiber is formed by a melt spinning method, the polymer-type material may include a thermoplastic polymer (or a thermoplastic polymer mixture) (that is, a melt can be obtained by heating, and It is then shaped or molded to form an extended composition). According to other embodiments of the present invention, the polymer-type material may include an elastomeric polymer (or a mixture thereof). Polymeric materials include polymers (or mixtures of polymers) that can have multiple chain structures composed of one or more monomer units. In particular, the polymer-type material may include a linear polymer, a branched polymer (star-branched polymer ' comb branched polymer, dendritic branched polymer), or a mixture thereof. Polymeric materials can include homopolymers, copolymers (eg, terpolymers 'statistical copolymers, random copolymers, alternating copolymers, periodic copolymers' block copolymers, star copolymers, or Copolymers), or mixtures thereof. As those skilled in the art know, the reactivity and functionality of polymers can be changed by adding functional groups, such as amine, amine, carboxy, hydroxy 'ester, ether, epoxy, anhydride, isocyanate, silane , Ketones and aldehydes. A polymer including a phase change material can also be cross-linked, cross-linked, or bonded by hydrogen bonding, thereby improving its toughness or resistance to heat, moisture, or chemicals. According to various specific examples of the present invention, the preparation of extended components Exemplary polymers include, for example, but not limited to, polyamide (eg, nylon 6, nylon 6 / this paper size applies Chinese National Standard (CNS) A4 specifications (210 X297 mm) (please read the notes on the back before filling This page) C. Printed by the 8th Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-37- 587110 Printed by the Consumers Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 5. Description of the invention (6, Nylon 12, Polyaspartic acid, Polyamic acid, etc.), polyamine, polyimide, polyacrylic acid (such as polyacrylamide, polyacrylonitrile, methacrylate, acrylate, etc.), polycarbonate (such as polybisphenol A carbonate, Polypropylene carbonate, etc.), polydiene (such as polybutadiene, polyisoprene, polyorbornene, etc.), polyepoxide, polyester (such as polyethylene terephthalate) Polybutylene terephthalate Propylene glycol ester, polycaprolactone, polyglycolide, polylactide, polyhydroxybutyrate, polyhydroxyvalerate 'polyethylene adipate, polybutylene adipate, polyamber Acid propylene glycol esters, etc.), polyethers (such as polyethylene glycol (polyethylene oxide), polybutylene glycol 'polypropylene oxide, polyoxymethylene (polymethylethylene), polytetramethylene Ether (polytetrahydrofuran), polyepichlorohydrin, etc.), polyfluorocarbons, formaldehyde polymers (such as urea-methylamine, melamine-methylamine, phenylhydrazine-formaldehyde, etc.) 'natural polymers (such as cellulose, shell poly Sugar, lignin, osmium, etc.), polyolefins (such as polyethylene, polypropylene, polybutene, poly (iso) butene, polyoctene, etc.), polyphenylene (such as polyphenylene oxide, polyphenylene sulfide) Ether, polyphenylene oxide, etc.), silicon-containing polymers (such as polydimethylsiloxane, polycarboxymethylsilane, etc.) 'polyurethanes, ethylene polymers (such as polyvinyl butyral, poly Vinyl alcohol, esters and ethers of polyvinyl alcohol, polyvinyl acetate, polystyrene, polymethylstyrene, polyvinyl chloride, polyvinylpyrrolidone, polymethylethylene | Fans, polyethyl vinyl ether, polyvinyl methyl ketone, etc.), polyacetals, polyaryl compounds, and copolymers (such as polyethylene-co-vinyl acetate, polyethylene glycol-acrylic, poly Butyl terephthalate, ethylene terephthalate, polylaurolactam monoblock, tetrahydrofuran, etc.) According to a specific example of the present invention, the first polymer-type material may include ~ this paper size Applicable to China National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page)

• 38 - 587110 A7 _____B7 五、發明説明（Μ (請先閱讀背面之注意事Ji再填寫本頁) 經濟部智慧財產局w工消費合作社印製 種有助於在第一延伸成份（或眾多第一延伸成份）中分散 或倂入溫度調節性材料的聚合物。根據本發明某些具體實 例’第一聚合物型材料中可包括一種與溫度調節性材料相 容’易混合或具有親和力的聚合物（或聚合物的混合物） 。在本發明具體實例中，上述的親和力主要決定於，例如 但不限於，第一聚合物型材料與溫度調節性材料溶解參數 ，極性，疏水性和親水性的相近性。該親和力有助於在製 造纖維的中間過程，溶解或熔化形成第一聚合物型材料時 ’有效的添加溫度調節性材料。如此，最終有助於在多成 份纖維中加入更均勻分散的，大量的或大裝載量的相變材 料。在同時具有盛裝結構溫度調節性材料的具體實例中， 聚合物型材料可包括一種聚合物（或聚合物的摻合物）， 該聚合物可以與盛裝結構與/或相變材料具有親和力。舉 例來說’如果溫度調節性材料包括眾多裝有相變材料的微 囊’可以選擇一種聚合物（或混合聚合物），該聚合物與 微囊親和（如形成微囊的一種或多種材料）。再舉例來說 本發明具體貫例採用包括與形成微囊相同或相似聚合物 型材料的第一聚合物型材料（舉例來說，如果微囊的外層 包括尼龍’第一聚合物型材料中也可以加入尼龍）。該親 和力有助於在製造纖維的中間過程，溶解或熔化形成第一 聚合物型材料時，有效的添加溫度調節性材料。如此，最 ’終有助於在多成份纖維中加入更均句分散的，大量的或大 裝載量的相變材料。在本發明目前效果較佳的一具體實例 中’第一聚合物型材料可以選用一種很難與溫度調節性材 本紙張尺度適财麵家辟（CNS ) 格（2iGx 297公瘦） -39- 587110 A7 _____ B7 五、發明説明（37) 料反應的物質，如此當溫度調節性材料加入第一聚合物型 材料中時，可以得到較佳的控溫效果。 (請先閱讀背面之注意事項再填寫本頁) 根據本發明某些具體實例，第一聚合物型材料中可包 括種聚合物（或聚合物混合物），該聚合物具有與溫度 調節性材料的輕微或部分相容性或易混合性或親和力（如 一種半混溶性聚合物）。該部分親和力在高溫條件或熔融 紡絲過程中足夠使溫度調節性材料有效的分散，並且有助 於纖維製備。當製備得到多成份纖維後，在低溫和低剪應 力的條件下，該部分親和力將使溫度調節性材料分離出來 。在本發明相變材料以自然狀態分散的具體實例中，該部 分親和力使相變材料難溶於聚合物型材料而析出，在多成 份纖維中形成相變材料的聚集區域。根據本發明一些具體 實例，此等區域的形成有助於相變材料在兩相間的轉變， 從而丨疋局纖維的溫度調自卩性質。另外’此等區域的形成也 能夠減小或防止處理或使用多成份纖維過程中相變材料的 損失。 經濟部智慧財產局員工消費合作社印製 舉例來說，某些相變材料如鏈烷烴在低濃度或溫度高 於溶解溫度的條件下，與包括聚乙烯或聚乙烯-共-乙酸 乙烯酯的聚合物型材料相容。在高溫下或高濃度鏈烷烴的 條件下，將一種鏈烷烴（或多種鏈烷烴摻合物）與聚乙烯 或聚乙烯-共-乙酸乙烯酯混合，可以得到均勻的摻合物 ，該均勻的摻合物使熔融紡絲過程的控形成，泵送和處理 更加容易。該多成份纖維形成後冷卻，鏈烷烴變的難溶， 析出，形成眾多相互獨立的區域。此等區域使鏈烷烴在高 本紙張尺度適用中.國國家標準（CNS ) A4規格（210X297公釐） -40- 587110 制效果。特定言之， 溫下的優良混溶，因 過程的穩定性。在低 溫度），聚乙烯-共 ，使鏈烷烴可以分離 聚合物型材料可以在 節性材料的載體。另 的處理過程中保持第 的完整性，使纖維的 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（ 純條件下ί谷化或晶化’從而提商纖維的溫度調節性質。另 外，此等區域的形成也能夠減小或防止處理或使用多成份 纖維過程中鏈烷烴的損失。根據本發明一些具體實例，第 一聚合物型材料中的乙烯-乙酸乙烯酯共聚物可約5重量 %到5 0重量％的乙酸乙烯酯。一目前較佳的具體實例中 ，乙酸乙烯酯含量宜於爲1 8重量％到約2 5重量％。此 種乙酸乙燒酯含量可以在鏈院烴與聚乙燦一共一乙酸乙烯 酯混合時，具有較好的溫度混溶性控 此種乙酸乙烯酯含量可以促成在較高 此經由提高摻合物均勻性而幫助熔紡 溫下（如室溫或普通市售纖維的使用 -乙酸乙烯酯與鏈烷煙只是部分混溶 出來在纖維中形成微小區域。 根據本發明某些具體實例，第一 多成份纖維的製作過程中充當溫度調 外’第一聚合物型材料還可以在纖維 一延伸成份（或眾多第一延伸成份） 最終產物具有良好的機械性能。 根據本發明一具體實例，第一聚合物型材料可包括一 種低分子量的聚合物（或多種低分子量聚合物的混合物） ’該低分子量聚合物在加熱形成熔體後一般具有較小的粘 度’該較小的粘度可以有效促進溫度調節性材料在熔體中 的分散。如諳於此技者所知悉者，某些聚合物可爲具有不 同不同的分子量的多種形式，因爲聚合物的分子量可由製 (請先閱讀背面之注意事項再填寫本頁)• 38-587110 A7 _____B7 V. Description of the invention (M (please read the notice on the back Ji before filling out this page) The Intellectual Property Bureau of the Ministry of Economic Affairs and the Industrial and Commercial Cooperatives will print species that will help in the first extension (or many A polymer that is dispersed or incorporated in a temperature-adjustable material. According to some embodiments of the present invention, the first polymer-type material may include a polymer that is compatible with the temperature-adjustable material, which is easy to mix or has affinity. (Or a mixture of polymers). In the specific example of the present invention, the above-mentioned affinity is mainly determined by, for example, but not limited to, the solubility parameter, polarity, hydrophobicity, and hydrophilicity of the first polymer-type material and the temperature-adjustable material. Similarity. This affinity helps to 'effectively add temperature-regulating materials when dissolving or melting to form the first polymer-type material in the middle process of manufacturing fibers. In this way, it ultimately helps to add more uniform dispersion in multi-component fibers , Large, or large load phase change materials. In a specific example of a temperature-regulating material that also contains a structure, the polymer type The material may include a polymer (or a blend of polymers) that has an affinity for the containment structure and / or phase change material. For example, 'if the temperature-regulating material includes a plurality of Capsules can choose a polymer (or mixed polymer) that is compatible with the microcapsules (such as one or more materials forming microcapsules). For another example, the specific embodiments of the present invention include the same or A first polymer-type material that is similar to a polymer-type material (for example, if the outer layer of the microcapsules includes nylon ', nylon can also be added to the first polymer-type material). This affinity helps in the intermediate process of manufacturing fibers, When dissolving or melting to form the first polymer-type material, it is effective to add a temperature-regulating material. In this way, it will ultimately help to add a more uniform phase-dispersed, large or large loading phase change material to the multi-component fiber In a specific example of the present invention with better results, the first polymer-type material can be selected from a material that is difficult to adjust with temperature-adjustable materials. CNS grid (2iGx 297 male thin) -39- 587110 A7 _____ B7 V. Description of the invention (37) Materials that react with materials, so that when the temperature-regulating material is added to the first polymer-type material, better results can be obtained. (Please read the notes on the back before filling this page) According to some specific examples of the present invention, the first polymer-type material may include a polymer (or polymer mixture), which has Slight or partial compatibility or miscibility or affinity of the temperature-adjustable material (such as a semi-miscible polymer). This partial affinity is sufficient to effectively disperse the temperature-adjustable material during high temperature conditions or during melt spinning, and It is helpful for fiber preparation. After the multi-component fiber is prepared, under the conditions of low temperature and low shear stress, the affinity of this part will separate the temperature-adjustable material. In a specific example where the phase change material of the present invention is dispersed in a natural state, this part of the affinity makes the phase change material difficult to dissolve and dissolve in the polymer-type material and precipitates, and forms an aggregation region of the phase change material in the multicomponent fiber. According to some specific examples of the present invention, the formation of these regions facilitates the transformation of the phase change material between the two phases, so that the temperature of the local fiber is self-tuning. In addition, the formation of these regions can also reduce or prevent the loss of phase change material during the processing or use of multicomponent fibers. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. For example, certain phase change materials such as paraffins are polymerized with polyethylene or polyethylene-co-vinyl acetate at low concentrations or temperatures above the dissolution temperature. Compatible materials. Under the conditions of high temperature or high concentration of paraffin, a paraffin (or a plurality of paraffin blends) is mixed with polyethylene or polyethylene-co-vinyl acetate to obtain a uniform blend. Blends allow controlled formation of the melt spinning process, pumping and handling easier. After the multi-component fiber is cooled, the paraffin becomes insoluble and precipitates, forming a plurality of independent regions. These areas make paraffins suitable for high paper sizes. National Standard (CNS) A4 (210X297 mm) -40-587110 system effect. In particular, excellent miscibility at temperature due to process stability. At low temperatures), polyethylene-copolymers allow paraffins to be separated; polymer-based materials can be used as support materials for noble materials. Another process maintains the integrity of the first, so that the employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, the consumer co-operative printed A7 B7 V. Description of the invention (in pure conditions, 谷 grained or crystallized 'to improve the temperature-adjusting properties of commercial fibers. In addition, the formation of these regions can also reduce or prevent the loss of paraffins during the processing or use of multi-component fibers. According to some specific examples of the present invention, the ethylene-vinyl acetate copolymer in the first polymer-type material may be reduced. 5 to 50% by weight of vinyl acetate. In a currently preferred embodiment, the content of vinyl acetate is preferably 18 to about 25% by weight. The content of such ethyl acetate can be in the chain When hydrocarbons are mixed with polyvinyl acetate and vinyl acetate, it has better temperature miscibility. Controlling the content of such vinyl acetate can help to improve the melt spinning temperature (such as Use of mild or ordinary commercially available fibers-vinyl acetate and paraffinic smoke are only partially miscible to form tiny regions in the fiber. According to some specific examples of the present invention, the first multi-component fiber The first polymer-type material, which acts as a temperature adjustment during the production process, can also have good mechanical properties in the fiber-extended component (or many first extended components). The final product has a good mechanical property. According to a specific example of the present invention, the first polymer-type material The material may include a low molecular weight polymer (or a mixture of low molecular weight polymers) 'The low molecular weight polymer generally has a lower viscosity after being heated to form a melt' The smaller viscosity can effectively promote temperature-regulating materials Dispersion in the melt. As known to those skilled in the art, some polymers can be in various forms with different molecular weights, because the molecular weight of the polymer can be made (please read the precautions on the back before filling out this page)

41 - 587110 A7 B7 五、發明説明（g 造聚合物的條件所決定之故。本文中的〃低分子量聚合物 〃一詞指的是一種聚合物的低分子量形式（如上述範例聚 合物的低分子量形式），且 '"分子量"指的是聚合物的婁女 平均分子量，重量平均分子量或熔融指數。舉例來說，在 本發明一具體實例中，使用數平均分子量約爲 2 0， 0 0 0 (或更小）的聚乙烯作爲低分子量聚合物。 此處必須注意到，定義低分子量聚合物的分子量或分子量 範圍決定於選用的特別聚合物（如聚乙烯）或由將溫度調 節性材料分散在低分子量聚合物熔融體中所用的方法或設 備。 根據本發明另一具體實例，第一聚合物型材料中包括 一種低分子量聚合物和一種高分子量聚合物的混合物。高 分子量聚合物一般具有強化的具物理性質（如機械性質） ，但是其在熔融狀態下的粘度較大。本文中的、、高分子量 聚合物〃指的是一種聚合物的高分子量形式（如上述範例 聚合物的高分子量形式）。所選的高分子量聚合物和低分 子量聚合物爲可以相容’或混溶，或具有親和力。該親和 力可以在製造多成份纖維時，有效的促進低分子量聚合物 ，高分子量聚合物和溫度調節性材料的混合，如此最終有 利於在多成份纖維中添加入均勻的大量的或大裝載量的相 變材料。根據本發明一些具體實例，低分子量聚合物可以 作爲高分子量聚合物和溫度調節性材料的互溶介質，從而 有助於在多成份纖維中加入溫度調節性材料。 根據本發明一些具體實例，一個延伸成份中一般包括 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） (請先閱讀背面之注意事項再填寫本頁} ••裝·41-587110 A7 B7 V. Description of the invention (determined by the conditions under which the polymer is made. The term "low molecular weight polymer" herein refers to a low molecular weight form of a polymer (such as Molecular weight form), and "" molecular weight " refers to the average molecular weight, weight average molecular weight, or melt index of the polymer. For example, in a specific example of the present invention, the number average molecular weight is about 20, 0 0 0 (or smaller) polyethylene is used as the low molecular weight polymer. It must be noted here that the molecular weight or molecular weight range of the low molecular weight polymer is determined by the particular polymer selected (such as polyethylene) or by temperature adjustment. Method or equipment for dispersing a non-polymer material in a low molecular weight polymer melt. According to another embodiment of the present invention, the first polymer-type material includes a mixture of a low molecular weight polymer and a high molecular weight polymer. High molecular weight polymerization Materials generally have enhanced physical properties (such as mechanical properties), but their viscosity in the molten state is relatively large. In this article High molecular weight polymer refers to the high molecular weight form of a polymer (such as the high molecular weight form of the above example polymer). The selected high molecular weight polymer and low molecular weight polymer are compatible or miscible. Or has an affinity. This affinity can effectively promote the mixing of low molecular weight polymers, high molecular weight polymers and temperature-adjustable materials when manufacturing multi-component fibers, so it is ultimately beneficial to add a uniform amount of Or a phase change material with a large loading. According to some specific examples of the present invention, a low molecular weight polymer can be used as a miscible medium between a high molecular weight polymer and a temperature regulating material, thereby helping to add a temperature regulating material to a multi-component fiber. According to some specific examples of the present invention, an extended component generally includes the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) (Please read the precautions on the back before filling out this page} •• Installation ·

、1T 經濟部智慧財產局員工消費合作社印製 -42- 587110 A7 B7 五、發明説明（ (請先閱讀背面之注意事項再填寫本頁) 約1 0重量％到約3 0重量％的溫度調節性材料，而剩餘 部分則包括低分子量聚合物和高分子量聚合物。舉例來說 ’在一較佳具體實例中，延伸成份中包括1 5重量％的低 分子量聚合物，7 0重量％的高分子量聚合物和1 5重量 %的溫度調節性材料。 經濟部智慧財產局員工消費合作社印製 根據本發明某些具體實例，第二聚合物型材料中的一 種聚合物（或聚合物混合物）能夠使多成份纖維具有一種 或多種較佳的物理性質。範例合意的物理性質包括，例如 但不限於，機械性質（如，延展性，抗張強度和硬度·）， 熱學性質（如熱塑性），和化學性質（如反應性）。第二 聚合物形材料中可以選用一種聚合物（或聚合物混合物） ’該聚合物可以補償第一聚合物形材料或第一延伸成份（ 或眾多第一延伸成份）一些性質的不足（如機械或熱學性 質）’例如由於加入大量的溫度調節性材料導致的此等性 質的下降。根據本發明具體實例，第二聚合物型材料可以 改善多成份纖維的所有的物理性質（如機械性質）和加工 性質（如有助於熔紡過程中纖維的形成）。第二聚合物型 材料還可以圍住包括於第一延伸成份（或眾多第一延伸成 份）的溫度調節性材料。因此，第二聚合物型材料可以使 得在多成份纖維中選用那些並不適合於處理纖維過程的高 剪應力和局溫條件的第一聚合物型材料和溫度調節性材料 。另外’第二聚合物型材料還可以防止或減小纖維處理和 使用過程中相變材料的損失。根據本發明一些具體實例第 二聚合物型材料和溫度調節性材料呈足夠的惰性，從而使 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇χ297公釐） -43- 經濟部智慧財產局員工消費合作社印製 587110 A7 ____ B7 五、發明説明（41) '溫度調節性材料維持較佳的控溫範圍。 根據本發明一具體實例，第二聚合物型材料可包括_ 種高分子量聚合物。如前所述，高分子量聚合物一般具有 強化的具物理性質（如機械性質），並且是〜種聚合物的 高分子量形式（如前述實例中的聚合物的高分子量形式·） 〇 根據本發明中的一些效果較佳的具體實例，第二聚合 物型材料可包括一種聚酯，由於其良好的加工性質，提高 最終纖維產物的加工性質，同時其對某些相變材料，如鏈 火元烴’具有不相溶性，從而減小或防止相變材料的損失。 根據本發明一具體實例，聚酯的數平均分子量約爲 20， 000 (或更大）。 現在，稍諳此藝者都可以發現本發明多種具體實例的 諸多優點。舉例來說，本發明諸多具體實例中的多成份纖 維的第一延伸成份（或眾多第一延伸成份）可包括大量的 一種或多種相變材料。根據本發明具體實例，之所以能夠 加入高塡充量的相變材料是由於在第一延伸成份（或眾多 第一延伸成份）的周圍有第二延伸成份（或第二眾多延伸 成份）。第二延伸成份中可以選用一種聚合物（或聚合物 混5物）’該聚合物可以補償第一延伸成份一些性質的不 足（如機械或熱學性質），例如由於加入大量的溫度調節 性材料導致的此等性質的下降。而且第二延伸成份中可以 含有一種聚合物，該聚合物可以改善多成份纖維的所有的 物理性質（如機械性質）和加工性質（如有助於熔紡過程 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁)， 1T Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs-42- 587110 A7 B7 V. Description of the invention ((Please read the precautions on the back before filling this page) Temperature adjustment of about 10% to about 30% by weight Materials, and the remainder includes low molecular weight polymers and high molecular weight polymers. For example, in a preferred embodiment, the extension component includes 15% by weight of low molecular weight polymers and 70% by weight of high Molecular weight polymer and 15% by weight of temperature-adjustable material. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to some specific examples of the present invention, one polymer (or polymer mixture) in the second polymer-type material can Conferring multicomponent fibers with one or more preferred physical properties. Examples of desirable physical properties include, for example, but not limited to, mechanical properties (e.g., ductility, tensile strength, and hardness ·), thermal properties (e.g., thermoplastic), and Chemical properties (such as reactivity). One polymer (or polymer mixture) can be selected for the second polymer-shaped material. 'The polymer can compensate A polymer-shaped material or a first extended component (or multiple first extended components) that lacks some properties (such as mechanical or thermal properties), such as a decrease in these properties due to the addition of a large amount of temperature-regulating materials. According to the present invention In a specific example, the second polymer-based material can improve all the physical properties (such as mechanical properties) and processing properties (such as helping the fiber formation in the melt spinning process) of the multi-component fiber. The second polymer-based material can also surround The temperature-adjustable material included in the first elongation component (or many first elongation components). Therefore, the second polymer-type material allows the selection of high shear stresses and local stresses in multicomponent fibers that are not suitable for fiber processing. The first polymer-type material and temperature-regulating material under warm conditions. In addition, the second polymer-type material can also prevent or reduce the loss of phase change materials during fiber processing and use. According to some specific examples of the present invention, the second polymer The material type and temperature-regulating material are sufficiently inert, so that this paper size applies to Chinese national standards CNS) A4 specification (21 × 297 mm) -43- Printed by the Consumers 'Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 587110 A7 ____ B7 V. Description of the invention (41)' The temperature regulating material maintains a better temperature control range. According to this A specific example of the invention, the second polymer-type material may include _ high molecular weight polymers. As mentioned earlier, high molecular weight polymers generally have enhanced physical properties (such as mechanical properties), and are Molecular weight form (such as the high molecular weight form of the polymer in the previous example) 〇 According to some specific examples of better effects in the present invention, the second polymer-type material may include a polyester, which is improved due to its good processing properties. The processing properties of the final fiber product, and at the same time it is incompatible with certain phase change materials, such as chain-fired hydrocarbons, thereby reducing or preventing the loss of phase change materials. According to a specific embodiment of the present invention, the number average molecular weight of the polyester is about 20,000 (or more). Now, those skilled in the art will find many advantages of various specific examples of the present invention. For example, the first extension component (or the plurality of first extension components) of the multicomponent fiber in many embodiments of the present invention may include a large amount of one or more phase change materials. According to a specific example of the present invention, the reason why the phase change material with a high pseudo-capacity can be added is because the second extended component (or the second extended component) is surrounded by the first extended component (or the first extended components). A polymer (or polymer mixture) can be used in the second extension component. The polymer can compensate for some properties of the first extension component (such as mechanical or thermal properties), for example, due to the addition of a large amount of temperature-regulating materials. Decline in these properties. In addition, the second extended component may contain a polymer, which can improve all physical properties (such as mechanical properties) and processing properties (such as to facilitate the melt spinning process of the multi-component fiber). This paper applies Chinese national standards (CNS) ) A4 size (210X 297mm) (Please read the notes on the back before filling this page)

-44 - 587110 A7 B7 五、發明説明（d 中纖維的形成）。另外，第二延伸成份圍繞第一延伸成份 可以防止或減小纖維處理和使用過程中相變材料的損失。 根據本發明諸多具體實例，該多成份纖維實際上可以 含有相對於第二延伸成份（或第二眾多延伸成份）的任意 重量比的包括有溫度調節性材料的第一延伸成份（或眾多 第一延伸成份）。例如但不限於，當主要考慮多成份纖維 的溫度調節性質時，該多成份纖維中可以有較大比例的包 括溫度g周節性材料的第一延伸成份。反之，如果主要考慮 多成份纖維的物理性質（如機械性質）時，不含有溫度調 節性材料的第二延伸成份所占比例可以較大。或者當權衡 考慮多成份纖維的溫度調節性質和物理性質中，第二延伸 成份中可以加入相同的或不同的溫度調節性材料。 根據本發明具體實例，該多成份纖維中包括約1重量 %到約9 9重量％的第一延伸成份（或眾多第一延伸成份 )。根據本發明一具體實例，一根多成份纖維中一般包括 約1 0重量％到約9 0重量％的第一延伸成份（或眾多第 一延伸成份）。舉例來說，在一具體實例中，鞘/芯型纖 維可包括9 0重量％的芯成份和1 〇重量％的鞘成份。在 該具體實例中，芯成份中包括6 〇重量％的溫度調節性材 料，如此鞘/芯型纖維包括約5 4重量％的溫度調節性材 料。另一具體實例中的鞘/芯型纖維包括高達約5 〇重量 %的芯成份，而該芯成份包括高達約5 0重量％的溫度調 節性材料。如此該重量比的鞘/芯型纖維就有高達約2 5 %的溫度調節性材料，使鞘/芯型纖維具有足夠的溫度調 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 •II. •45- 587110 A7 B7 五、發明説明（ (請先閱讀背面之注意事項再填寫本頁) 節性質和機械性質。此處必須注意到，一個延伸成份占多 成份纖維的總重的百分比是可以改變的，例如，經由改變 延伸成份的橫截面積或改變延伸成份在多成份纖維中的延 伸長度可以改變這一比例。 本發明諸多具體實例中的多成份纖維可以採用眾多方 法製備，例如熔融紡絲或溶液紡絲法（乾法或濕法）。無 論是熔融紡絲還是溶液紡絲，該多成份纖維都是經由由紡 嘴中的眾多洞孔中擠出的材料製得的。本處的、、紡嘴〃指 的7E纖維濟出设備的一部分’ 一'種或多種聚合物型材料和 一種或多種溫度調節性材料經紡嘴的洞孔擠出進入外界環 境。一般的紡嘴每米有1 - 5 0 〇 〇個洞孔。紡嘴可爲經 鑽孔或蝕刻的金屬板或能夠製得所需纖維的其他結構。 經濟部智慧財產局員工消費合作社印製 熔融紡絲過程中，形成多成份纖維的一種或多種聚合 物和一種或多種溫度調節性材料以熔態進入紡嘴的洞孔中 。在經由此等洞孔前，溫度調節性材料和第一聚合物型材 料預先形成一種摻合物。混合的結果是溫度調節性材料分 散入第一聚合物型材料中或被聚合物型材料至少部分包住 。在被擠出紡嘴前，沒有進入第一聚合物型材料的那部分 溫度調節性材料可以被第二聚合物型材料包住，如此可以 減小或防止最終多成份纖維產物中溫度調節性材料的損失 。上述摻合物和第二聚合物型材料可以一起流出洞孔，分 別形成不同形式的第一延伸成份（或眾多第一延伸成份） 和第二延伸成份（或第二眾多延伸成份），從而得到多成 份纖維。舉例來說，上述摻合物由洞孔中流出後可以形成 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -46 - 587110 Α7 Β7 五、發明説明（d 稍/芯型纖維的芯成份或形成海島纖維的島成份，第二聚 口物型材料由洞孔中流出後相應的形成鞘/芯型纖維的鞘 成份或海島纖維的海成份。 根據本發明一些具體實例，該多成份纖維可以用含有 第〜聚合物型材料和溫度調節性材料的顆粒製備。舉例來 δ兌’此等顆粒可包括一種由溫度調節性材料，低分子量聚 合物和高分子量聚合物在熔態下混合後固化得到的物質。 根據本發明其他的具體實例，此等顆粒可以由第一聚合物 型材料製得，並且顆粒中可以注入或吸入一種相變材料。 顆粒可以熔化形成一種摻合物和第一聚合物型材料一起採 用以上方法製備多成份纖維。 在溶液紡絲過程中，形成多成份纖維的一種或多種聚 合物型材料和一種或多種溫度調節性材料可以在進入紡嘴 前預先溶解製得溶液。採用濕法紡絲時，紡嘴浸在一種化 學浴中’材料流出紡嘴後，從溶液中析出沈澱形成一種固 體纖維。採用乾法紡絲時，材料流出紡嘴後由於溶劑在空 氣中揮發後固化形成纖維。 此處必須注意的是，無論採用哪種方法，對於某些特 殊的應用可以不使用第一聚合物型材料。舉例來說，一種 溫度調節性材料中包括一種聚合物型相變材料，該相變材 料具有良好的轉變溫度，而且同時能夠使多成份纖維具有 良好的機械性質。如此，該種溫度調節性材料可以和第二 聚合物型材料一起由洞孔中流出，分別形成不同形式的第 一延伸成份（或眾多第一延伸成份）和第二延伸成份（或 本紙張尺度適用中國國家榡準（CNS ) Α4規格（210X 297公釐） (請先閱讀背面之注意事頃再真寫衣罠) 、\st> 經濟部智慧財產局員工消費合作社印製 -47 - 587110 A7 _____B7 五、發明説明（d (請先閲讀背面之注意事項再填寫本頁) 第二眾多延伸成份）。例如溫度調節性材料由洞孔中流出 後可以形成鞘/芯型纖維的芯成份或形成海島纖維的島成 份，第二聚合物型材料由洞孔中流出後相應的形成鞘/芯 型纖維的鞘成份或海島纖維的海成份。 流過紡嘴後，該多成份纖維可以用一種導絲輪或吸出 器牽引或拉伸。舉例來說，在熔法紡絲過程中，由紡嘴中 流出的多成份纖維形成多股呈簾狀垂直向下運動的纖維， 此等纖維在進入狹長的吸出器前至少部分卒火。吸出器在 一或多種壓縮空氣噴氣機的帶動下形成快速的垂直向下的 氣流。該氣流對纖維施加拉力，使得其在紡嘴與噴氣機之 間拉長變細。在這部分加工處理的過程中，形成多成份纖 維的聚合物型材料一般是固態的。 經濟部智慧財產局員工消費合作社印製 多成份纖維形成後可以進一步加工製得眾多不同應用 的纖維。特定言之，例如但不限於，該多成份纖維可以進 一步採用織造，非織造，編織，紡織的方法製得多種褶疊 的，辮狀的，螺旋的，粘結的或非粘結的纖維製品。例如 ，該多成份纖維可以在筒管或紡成紗線，然後採用通常的 編織或紡織方法進一步加工。另有一例，該多成份纖維隨 機的置於一成形面上（如一種運動的傳送機篩帶，例如 Fourdrinier絲網）形成一種連續的非織造的網狀纖維。根 據本發明一具體實例多成份纖維在成網之前可以預先切成 短纖維。因爲短纖維較之長的或未切割（如連續纖維）的 纖維在網中的取向更加隨機，因此其優點就在於能夠得到 各向同性的非織造布。該絲網可以採用通常的粘結方法（ 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X 297公釐） ' — —- -48- 587110 A7 _ __B7 五、發明説明（ (請先閱讀背面之注意事項再填寫本頁) 如紡粘法）形成適合加工各種紡織品的穩定的非織造纖維 。範例粘結方法包括將絲網從凝網簾上提起，送入兩個熱 輥中。如果需要，其中一個熱輥上可以有若干突起，使絲 網以諸多節點的方式相互粘結。根據本發明具體實例 經濟部智慧財產局員工消費合作社印製 此處必須注意的是，織物可以由含有一種或多種不同 溫度調節性材料的多成份纖維製得。根據本發明一些具體 實例，多種溫度調節性材料可以使纖維具有兩種或多種轉 變温度。舉例來說，一種用於生產手套的織物可以由包括 相變材料A和B的多成份纖維製得。相變材料A的熔點約 爲5 °C ’而相變材料b的熔點約爲7 5艺。該多成份纖維 中的兩種相變材料的結合可以使該手套在寒冷環境（如冬 季戶外使用）和熱環境（觸摸被加熱物體如爐上的盤子時）下 同時具有良好的控溫效果。另外，織物還可以由兩種或多 種不同的多成份纖維構成（如包括不同的結構或不同的溫度 調節性材料）。舉例來說，一種織物中包括兩種鞘-芯結構的 多成份纖維，兩種多成份纖維的溫度調節性材料是不同的 。這兩種鞘-芯結構的多成份纖維使得織物在不同的環境中（ 如冷熱環境）具有良好的溫度調節性質。 接著參看圖5，本發明一具體實例中用於製備多成份 纖維1 3 4的範例纖維擠出設備1 1 〇。該設備1 1 〇可 以採用熔融紡絲法製備多成份纖維1 3 4。另外，設備 1 1 0還可以用製得的多成份纖維1 3 4進行紡粘處理得 到具有良好溫度調節性質的非織造產品。 設備1 1 0包括用於拉製多成份纖維1 3 4的紡絲箱 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公羡） -49- 587110 A7 B7 五、發明説明（ 1 2 8。如本文所用者’本處的、、紡絲箱〃指的是加工一 種或多種聚合物型材料和一種或多種溫度調節性材料以生 產濟出纖維的設備組合。根據本發明某些具體實例，紡絲 箱可包括過濾系統’分配系統和紡嘴。範例紡絲箱載於 Hills 的美國專利 5，162，074，名稱爲、、Methods of M a k i n g P1 u r a 1 C o m ρ ο n e n t F i b e r s 〃中有描述，其揭示內容以 引用的方式倂入本文。在這一具體實例中，紡絲箱1 2 8 爲兩種或多種熔態的聚合物型材料提供流動通道，從紡嘴 1 3 0流出的多成份纖維可以具有一或多種不同的結構（ 如鞘-芯結構或海島結構）。 如圖5所示，設備1 1 〇包括兩個貯料斗1 1 2和 1 1 4，分別盛裝聚合物型材料a和聚合物型材料b。聚 合物型材料A和B可爲液態的或固態的（如顆粒狀），分 別從貯料斗1 1 2和1 1 4添加到螺旋擠壓器1 1 6和 1 1 8中。如果聚合物型材料a和聚合物型材料b開始是 固態的’彼等一般被送入加熱管1 2 0和1 2 2熔化。溫 度調節性材料C可以在設備1 1 〇的眾多位置加入並與聚 合物型材料B混合，形成摻合物後再進入紡嘴1 3 〇與聚 合物型材料A混合。圖5中示出在設備11〇中添加溫度 調節性材料C的眾多範例位置。舉例來說，溫度調節性材 料可以在位置1 1 3加入貯料斗1 1 4中，在位置1 1 9 加入螺旋濟壓器1 1 8中，或在位置1 2 7添加入紡絲箱 1 2 8中。此處必須注意的是溫度調節性材料^可以直接 加入聚合物型材料B中形成摻合物，該摻合物可爲固態的 (請先閲讀背面之注意事項再填寫本頁) 、-!! 經濟部智慧財產局員Η消費合作社印製 .4---Ί ·-44-587110 A7 B7 V. Description of the invention (fiber formation in d). In addition, the second extension component surrounds the first extension component to prevent or reduce the loss of phase change material during fiber processing and use. According to many specific examples of the present invention, the multi-component fiber may actually contain a first stretched component (or a plurality of first stretched components) including a temperature-adjustable material in any weight ratio relative to the second stretched component (or the second plurality of stretched components). Extended ingredients). For example, but not limited to, when the temperature-regulating properties of the multi-component fiber are mainly considered, the multi-component fiber may include a larger proportion of the first elongation component of the temperature-g cycle material. Conversely, if the physical properties (such as mechanical properties) of the multi-component fiber are mainly considered, the proportion of the second extension component that does not contain the temperature-adjustable material may be larger. Or when weighing the temperature-regulating properties and physical properties of the multi-component fiber, the same or different temperature-regulating materials may be added to the second extension component. According to a specific example of the present invention, the multi-component fiber includes a first stretched component (or a plurality of first stretched components) of about 1% to about 99% by weight. According to a specific example of the present invention, a multi-component fiber generally includes about 10% to about 90% by weight of a first elongation component (or a plurality of first elongation components). For example, in a specific example, the sheath / core fiber may include a core component of 90% by weight and a sheath component of 10% by weight. In this specific example, the core component includes 60% by weight of the temperature-adjustable material, so that the sheath / core fiber includes about 54% by weight of the temperature-adjustable material. The sheath / core fiber in another specific example includes up to about 50% by weight of a core component, and the core component includes up to about 50% by weight of a temperature-adjustable material. In this way, the sheath / core fiber of this weight ratio has a temperature-adjustable material of up to about 25%, so that the sheath / core fiber has sufficient temperature adjustment. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm). %) (Please read the notes on the back before filling this page) Order printed by the Intellectual Property Bureau's Consumer Cooperatives of the Ministry of Economic Affairs • II. • 45-587110 A7 B7 V. Invention Description ((Please read the notes on the back before filling This page) section properties and mechanical properties. It must be noted here that the percentage of an extension component in the total weight of the multi-component fiber can be changed, for example, by changing the cross-sectional area of the extension component or by changing the extension component in the multi-component fiber. This ratio can be changed in the extension length. The multi-component fiber in many specific examples of the present invention can be prepared by many methods, such as melt spinning or solution spinning (dry or wet). Whether it is melt spinning or solution Spinning, the multi-component fiber is made from the material extruded from the numerous holes in the spinning nozzle. The 7E fiber at this location A part of one or more polymer-type materials and one or more temperature-regulating materials are extruded into the external environment through the holes of the spinning nozzle. The general spinning nozzle has 1-5000 holes per meter. Spinning The mouth can be a drilled or etched metal plate or other structure that can produce the required fibers. One or more polymers and a polymer that form a multi-component fiber during the melt spinning process of the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The temperature-adjustable material or materials enter the holes of the spinning nozzle in a molten state. Before passing through these holes, the temperature-adjustable material and the first polymer-type material form a blend in advance. The result of mixing is temperature-adjustability The material is dispersed in the first polymer-type material or is at least partially surrounded by the polymer-type material. The part of the temperature-adjustable material that does not enter the first polymer-type material can be covered by the second polymer before being extruded into the spinning nozzle. Encapsulation of this type of material can reduce or prevent the loss of temperature-regulating material in the final multi-component fiber product. The above blend and the second polymer-type material can flow out of the hole together , Forming different forms of the first extension component (or the first plurality of extension components) and the second extension component (or the second plurality of extension components) respectively, so as to obtain a multi-component fiber. For example, the above-mentioned blend is formed from a hole After the outflow, the paper size can be formed according to the Chinese National Standard (CNS) A4 specification (210X 297 mm) -46-587110 Α7 Β7 V. Description of the invention (d slightly / the core component of the core fiber or the island component forming the island fiber, After the second polyhedral material flows out of the hole, the corresponding sheath component of the sheath / core fiber or the sea component of the sea-island fiber is formed. According to some specific examples of the present invention, the multi-component fiber may contain Preparation of particles of materials and temperature-adjustable materials. For example, δ / 'These particles may include a substance obtained by mixing a temperature-adjustable material, a low molecular weight polymer, and a high molecular weight polymer in a molten state and curing. According to other specific examples of the present invention, these particles may be made of a first polymer-type material, and a phase change material may be injected or inhaled into the particles. The particles can be melted to form a blend and the first polymer-type material can be used in the above method to prepare a multi-component fiber. In the solution spinning process, one or more polymer-type materials and one or more temperature-regulating materials that form multi-component fibers can be dissolved in advance to obtain a solution before entering the spinning nozzle. In wet spinning, the spinning nozzle is immersed in a chemical bath and the material flows out of the spinning nozzle, and then precipitates out of solution to form a solid fiber. When dry spinning is used, after the material flows out of the spinning nozzle, the solvent will volatilize in the air and solidify to form fibers. It must be noted here that, no matter which method is used, the first polymer type material may not be used for some special applications. For example, a temperature-regulating material includes a polymer-type phase change material that has a good transition temperature and at the same time can provide multi-component fibers with good mechanical properties. In this way, the temperature-regulating material can flow out of the hole together with the second polymer-type material to form different forms of the first extension component (or a plurality of first extension components) and the second extension component (or the size of the paper). Applicable to China National Standard for Standards (CNS) Α4 (210X 297 mm) (Please read the notes on the back first and then write the real clothes), \ st > Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -47-587110 A7 _____B7 V. Description of the invention (d (please read the notes on the back before filling this page) The second most extended component). For example, the temperature-controlling material can flow out of the hole to form the core component or the core component After the island component of the sea-island fiber, the second polymer-type material flows out from the hole to form the sheath component of the sheath / core fiber or the sea component of the sea-island fiber. After flowing through the spinning nozzle, the multi-component fiber can be guided by a kind of Pulling or stretching by a spinning wheel or an extractor. For example, in the melt spinning process, the multi-component fibers flowing out of the spinning nozzle form a plurality of fibers that move vertically in a curtain shape. Wei at least partially died before entering the narrow aspirator. The aspirator formed a fast vertical downward air flow driven by one or more compressed air jets. The air flow exerted a tensile force on the fiber, causing it to spin between the spinning nozzle and the jet. Elongation and thinning. During this part of the processing process, the polymer-type materials that form multi-component fibers are generally solid. The multi-component fibers printed by the employee cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs can be further processed and formed. Fibers for many different applications. Specifically, for example, but not limited to, the multi-component fiber can further be woven, nonwoven, woven, and woven to produce a variety of pleated, braided, spiral, bonded or Non-bonded fiber products. For example, the multi-component fiber can be spun into a bobbin or spun into yarn, and then further processed by conventional weaving or weaving methods. In another example, the multi-component fiber is randomly placed on a forming surface (Such as a moving conveyor screen, such as a Fourdrinier wire mesh) to form a continuous nonwoven web of fibers. In a specific example, multi-component fibers can be cut into short fibers in advance before forming the web. Because short fibers have a more random orientation in the web than long or uncut fibers (such as continuous fibers), their advantage is that they can obtain various Isotropic non-woven fabric. The wire mesh can use the usual bonding method (this paper size applies the Chinese National Standard (CNS) A4 specification (21〇X 297 mm) '— —---48- 587110 A7 _ __B7 5 2. Description of the invention ((Please read the notes on the back before filling this page) such as spunbond) to form stable non-woven fibers suitable for processing various textiles. Example bonding methods include lifting the silk screen from the screen curtain and sending Into two heat rollers. If necessary, one of the heat rollers can have several protrusions, so that the screens are bonded to each other in many nodes. According to a specific example of the present invention, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. It must be noted here that the fabric can be made of multi-component fibers containing one or more different temperature-regulating materials. According to some specific examples of the present invention, a plurality of temperature-regulating materials can make the fibers have two or more transition temperatures. For example, a fabric for the production of gloves can be made from multi-component fibers including phase change materials A and B. The melting point of the phase change material A is about 5 ° C 'and the melting point of the phase change material b is about 75 ° C. The combination of two phase change materials in the multi-component fiber can make the glove have good temperature control effect in both cold environment (such as outdoor use in winter) and hot environment (when touching a heated object such as a plate on a stove). In addition, fabrics can be composed of two or more different multi-component fibers (for example, including different structures or different temperature-regulating materials). For example, a fabric contains two types of sheath-core multi-component fibers, and the two multi-component fibers have different temperature-regulating materials. These two kinds of sheath-core multi-component fibers make the fabric have good temperature regulation properties in different environments (such as hot and cold environments). Referring next to Fig. 5, an exemplary fiber extrusion apparatus 1 1 0 for preparing a multicomponent fiber 1 3 4 in a specific example of the present invention. This equipment 1 10 can use the melt spinning method to prepare multi-component fibers 134. In addition, the equipment 1 110 can also be spunbond with the multi-component fiber 1 3 4 obtained to obtain a nonwoven product with good temperature regulation properties. The equipment 1 1 0 includes a spinning box for drawing multi-component fibers 1 3 4 The size of the paper is applicable to the Chinese National Standard (CNS) A4 (210X 297 public envy) -49- 587110 A7 B7 V. Description of the invention (1 2 8. As used herein, the term "spinning box" refers to a combination of equipment that processes one or more polymer-based materials and one or more temperature-regulating materials to produce fibers. According to some specific aspects of the present invention, For example, a spinning box may include a filtration system, a 'dispensing system, and a spinning nozzle. An exemplary spinning box is contained in Hills U.S. Patent No. 5,162,074 and is named, Methods of M aking P1 ura 1 C om ρ nent Fibers There is a description in 〃, whose disclosure is incorporated herein by reference. In this specific example, the spin box 1 2 8 provides flow channels for two or more molten polymer-type materials, from the spinning nozzle 1 3 The outflowing multi-component fiber can have one or more different structures (such as a sheath-core structure or a sea-island structure). As shown in FIG. 5, the device 1 1 〇 includes two storage hoppers 1 12 and 1 14 respectively Polymeric materials a and polymerization Material type material b. Polymer type materials A and B can be liquid or solid (such as granules), which are added from the storage hoppers 1 1 2 and 1 1 4 to the screw extruder 1 1 6 and 1 1 8 If the polymer-type material a and the polymer-type material b start to be solid, they are generally sent to the heating tubes 1 2 0 and 1 2 2 for melting. The temperature-regulating material C can be added in many positions of the device 1 1 0 It is mixed with the polymer-type material B, and after forming the blend, it enters the spinning nozzle 1 30 and is mixed with the polymer-type material A. Figure 5 shows a number of exemplary locations where the temperature-adjustable material C is added to the device 11. For example, the temperature-regulating material can be added to the storage hopper 1 1 4 at position 1 1 3, the screw compressor 1 1 8 at position 1 1 9 or the spinning box 1 2 at position 1 2 7 8. It must be noted here that the temperature-regulating material ^ can be directly added to the polymer-type material B to form a blend, which can be solid (please read the precautions on the back before filling this page), -!! Printed by Consumer Property Cooperative, Member of Intellectual Property Bureau, Ministry of Economic Affairs. 4 --- Ί ·

- 50--50-

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B 經濟部智慧財產局員工消費合作社印製 五、發明説明（y 或液態的，然後再裝入貯料斗1 1 4中。另外或同時可以 將溫度調節性材料C (或具有某種不同性質的溫度調節性 材料）在設備1 1 0的眾多不同位置添加入聚合物型材料 A中形成摻合物。根據本發明一些具體實例，溫度調節性 材料C可包括一種聚合物型相變材料，該種相變材料加入 多成份纖維1 3 4後使其具有良好的機械性質。對於本發 明如此的具體貫例’可以不使用聚合物型材料B ，溫度調 節性材料可以在位置1 1 3直接加入貯料斗1 1 4中，在 結嘴1 3 0和聚合物型材料A混合形成多成份纖維1 3 4 〇 在圖5示出的具體實例中，溫度調節性材料c和聚合 物型材料B的混合過程可爲靜態混合，也可爲動態混合。 動態過程可以採用一些機械手段如攪拌混合聚合物型材料 B和溫度調節性材料C，例如使用螺旋擠壓器1 1 8。舉 例來說，當溫度調節性材料C加入貯料斗1 1 4或螺旋擠 壓器1 1 8中時，動態混合發生，混合液流在螺旋擠壓器 1 1 8中流入加熱管1 2 2中。 較之於動態混合，靜態混合一般不需要借助與任何機 械攪拌或混合手段。根據本發明一些具體實例，靜態混合 採用令兩種或多種不同材料的流動液體中途混流足夠多的 次數，從而達到滿意的混合效果。一種可以用於本發明具 體實例的範例靜態混合器在Haggard等人的美國專利 5 ’ 8 5 1 ’ 5 6 2 題爲、、Instant Mixer Spin Pack"中有 具體描述，其揭示內容以引用方式倂入本文。溫度調節性 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (#先閱讀背面之注意事項再填寫本頁)B Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (y or liquid, and then put it into the storage hopper 1 1 4. In addition or at the same time, the temperature regulating material C (or a material with some different properties) The temperature-regulating material) is added to the polymer-type material A at a number of different positions of the device 110 to form a blend. According to some specific examples of the present invention, the temperature-regulating material C may include a polymer-type phase change material. A phase change material is added to the multi-component fiber 1 3 4 to make it have good mechanical properties. For such a specific embodiment of the present invention, the polymer-type material B may not be used, and the temperature regulating material may be directly added at the position 1 1 3 In the storage hopper 1 1 4, the nozzle 130 and the polymer-type material A are mixed to form a multi-component fiber 1 3 4. In the specific example shown in FIG. 5, the temperature-controlling material c and the polymer-type material B The mixing process can be static or dynamic. The dynamic process can use some mechanical means such as mixing the polymer-type material B and the temperature-adjustable material C, such as using a screw extruder 1 18 For example, when the temperature-regulating material C is added to the storage hopper 1 1 4 or the screw extruder 1 1 8, dynamic mixing occurs, and the mixed liquid flow flows into the heating pipe 1 in the screw extruder 1 1 8 2 2. Compared to dynamic mixing, static mixing generally does not require the use of any mechanical stirring or mixing means. According to some specific examples of the present invention, static mixing uses a number of times that two or more different liquids of the liquid are mixed in the middle. In order to achieve a satisfactory mixing effect. An exemplary static mixer that can be used in specific examples of the present invention is specifically described in Haggard et al. U.S. Pat. The disclosure is incorporated herein by reference. Temperature regulation This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (#Read the precautions on the back before filling this page)

-51 - A7 B7 五、發明説明（d ~ ^ 材料C和聚合物型材料B的靜態混合可以在紡絲箱位置， 或進入紡嘴與聚合物型材料A結合前設備丨丨〇的多個其 他位置。舉例來說’溫度調節性材料C可以在位置1 2 1 加入，在加熱管中與聚合物型材料B混流發生靜態混合。 特疋B之，溫度調節性材料C的第一液態流和聚合物型材 料B的第二液態流交叉匯流形成混合良好的液流。如果需 要的s5 ’ g亥混合液流還可以在進入紡嘴1 3 〇與聚合物型 材料A結合前進一步施加靜態的或者動態的混合。 如圖5所示’聚合物型材料a的液流和混合液流分別 從加熱管1 2〇和1 2 2中流入計量泵1 2 4和1 2 6中 ’再流入紡絲箱1 2 8。紡絲箱1 2 8中形成所需結構（ 如海島結構或鞘-芯結構）的多成份纖維1 3 4的內部成 份。圖5中的設備1 1 〇中，液流在紡絲箱1 2 8中結合 ’聚合物型材料A包住上述摻合物。紡絲箱1 2 8包括紡 嘴1 3 0和拉製形成多成份纖維1 3 4的洞孔1 3 2。從 紡嘴1 3 0中流出的一排多成份纖維1 3 4被吸出器 1 3 6下拉’變細。吸出器中使用的是壓縮空氣或管 1 3 8中的氣流。吸出器1 3 6可爲槍狀的或狹槽狀的， 而且如果需要時，可以與濟出的一排纖維同寬，例如在由 多成份纖維1 3 4製得的絲網寬的方向。 此處必須注意到，可以製備眾多單獨的摻合物，每個 摻合物中包括一種或多種溫度調節性材料和一種或多種聚 合物型材料。此等單獨的混合以某種方式相互區別。例如 ，此等單獨的摻合物可包括不同的溫度調節性材料或不同 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) " -- -52 - (請先閱讀背面之注意事項再填寫本頁) -裝·-51-A7 B7 V. Description of the invention (d ~ ^ The static mixing of material C and polymer-type material B can be at the spinning box position, or multiple devices before the spinning nozzle is combined with polymer-type material A Other locations. For example, 'temperature-adjustable material C can be added at position 1 2 1 and mixed with polymer-type material B in the heating tube to cause static mixing. Specially, B, the first liquid flow of temperature-adjustable material C Cross-converge with the second liquid stream of polymer-type material B to form a well-mixed liquid stream. If required, the s5'ghai mixed liquid stream can also be further applied statically before entering the spinning nozzle 1 30 and combining with polymer-type material A Or dynamic mixing. As shown in Figure 5, the liquid flow and the mixed liquid flow of the polymer-type material a flow from the heating pipes 1 20 and 1 2 into the metering pump 1 2 4 and 1 2 6 and then flow into Spin box 1 2 8. The internal components of the multi-component fiber 1 3 4 forming the desired structure (such as a sea-island structure or a sheath-core structure) in the spin box 1 2 8. The device 1 1 0 in the liquid The flow is combined with the 'polymer type material A in the spinning box 1 2 8 to cover the above blend. Spinning Box 1 2 8 includes a spinning nozzle 1 3 0 and a hole 1 3 2 drawn to form a multi-component fiber 1 3 4. A row of multi-component fibers 1 3 4 flowing from the spinning nozzle 1 3 0 is sucked by an extractor 1 3 6 Pull down 'thinning. Compressed air or airflow in tube 1 3 8 is used in the extractor. The extractor 1 3 6 can be gun-shaped or slot-shaped, and can be aligned with the saved row if needed The fibers are of the same width, for example, in the direction of the width of the screen made of multicomponent fibers 1 3 4. It must be noted here that many individual blends can be prepared, each blend including one or more temperature-regulating properties Materials and one or more polymer-type materials. These individual blends are distinguished from one another in some way. For example, these individual blends can include different temperature-regulating materials or different paper sizes that apply Chinese National Standards (CNS ) A4 size (210X297mm) "--52-(Please read the precautions on the back before filling this page) -Installation ·

、1T 經濟部智慧財產局員工消費合作社印製 587110 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（g 的聚合物型材料。此等單獨的摻合物形成後在紡絲箱 1 2 8中聚合物型材料A組合使得聚合物型材料A包圍此 等單獨的摻合物。然後，聚合物型材料A與此等單獨的摻 合物從紡嘴中擠出形成具有所需結構的多成份纖維（如海 包島型結構）。根據本發明具體實例，由聚合物型材料A 形成的外部成份（如海成份）圍繞由眾多單獨摻合物形成 的內部成份（如島成份）構成多成份纖維。 如圖5所示，吸出器1 3 6將製得的多成份纖維細纖 140送上由輥144，146和150帶動的布匹形成 篩網帶1 4 2。連接於一個風扇的抽氣箱1 4 8吸入篩網 帶1 4 2周圍空氣，使多成份細纖維1 4 0在篩網帶 1 4 2上形成非織造網。所得產品可以進一步加工製得具 有溫度調節性質的紡織品，衣物或其他產品。 實施例 以下實施例說明本發明各個特定方面，爲業內人士具 體描述和介紹本發明。但是，此等實例不應該被認爲是用 以限制本發明範圍，彼等只是提供一特定方法用以理解與 實施本發明。 實施例1 在一個濕式沖洗裝置中加入大約5磅的低分子量聚乙 烯均聚物（A C — 1 6聚乙烯，滴點1 〇 2 °C ，由 Honey well Specialty Chemical 所製），並在約 1 1 〇 °C 到約 (請先閱讀背面之注意事項再填寫本頁)1T printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 587110 A7 B7 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Polymer description materials (g). These separate blends are formed in spinning boxes after formation The combination of the polymer-type material A in 1 2 8 makes the polymer-type material A surround these separate blends. Then, the polymer-type material A and these separate blends are extruded from the spinning nozzle to form the desired blend. Structured multi-component fibers (such as sea-island-type structures). According to a specific example of the present invention, an external component (such as a sea component) formed of a polymer-type material A surrounds an internal component (such as an island component) formed by a plurality of individual blends ) Constitutes a multi-component fiber. As shown in FIG. 5, the extractor 1 3 6 sends the obtained multi-component fiber fine fiber 140 onto a cloth driven by rollers 144, 146, and 150 to form a mesh belt 1 4 2. It is connected to a The fan's suction box 1 4 8 sucks in the surrounding air of the screen belt 1 4 2 so that the multi-component fine fibers 1 4 0 form a nonwoven web on the screen belt 1 4 2. The obtained product can be further processed to have temperature-adjusting properties Textiles and clothing Or other products. Examples The following examples illustrate various specific aspects of the present invention, and specifically describe and introduce the present invention to those skilled in the art. However, these examples should not be considered to limit the scope of the present invention, they only provide a specific The method is used to understand and implement the present invention. Example 1 A wet flushing apparatus was charged with about 5 pounds of low molecular weight polyethylene homopolymer (AC-16 polyethylene, dropping point of 1.02 ° C, from Honey well By Specialty Chemical), and at about 1 10 ° C to about (Please read the precautions on the back before filling this page)

、1T, 1T

Jt. -Ji. · 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -53- 587110 A7 B7 五、發明説明（51) (請先閱讀背面之注意事項再填寫本頁) 1 3 0 C之間將此等均聚物慢慢熔化並混和。當均聚物熔 化後’於3 0分鐘期間在熔融均聚物中緩慢加入約8磅的 一種濕餅，以形成一第一摻合物。該濕餅包括水濕微囊， 此等微囊裝有一種相變材料（lllicr〇 lot# M45-22，占微 羈和相變材料的6 3 · 2重量％，爲Microtek Laboratories， I n c ·所製）。 當加入裝有相變材料的微囊並且此等微囊在熔化的均 聚物中分散時，將水分急驟蒸餾掉。直到用Kad_Fischei·滴 定法測得剩下水分少於〇 · 1 5重量％時才終止混和過程 。將形成的第一摻合物冷卻並切割成塊狀材料以備進一步 加工。 將大約3 0磅塊狀材料與大約7 0磅化纖級聚丙烯熱 塑性聚合物乾混和形成一種乾摻合物（聚丙烯均聚物6 8 5 2 ，BP Amoco Polymers 生產）。 經濟部智慧財產局員工消費合作社印製 在一個大約2 · 5英寸單螺旋擠壓機中，將所有區段 溫度設在大約2 3 0 °C，螺旋速度每分鐘7 0轉，濾網爲 1 5 0孔，並在氮氣氣氛下，將上一步所得乾燥摻合物在 此擠壓機中擠出。用該方式形成九粒。將此等九粒在乾燥 床上乾燥過夜，乾燥系統設爲1 〇 5 °C，露點一 4 0 °C。 此等九粒的熱能儲存容量（潛熱）用D S C (差示掃描量 熱儀）測得爲2 3 . 1焦/克。 在一個溫度介於2 3 0 t到2 4 5 °C之間的多成份纖 維（本例中是雙成份纖維）紡絲箱中，採用熔融紡絲法生 產雙成份纖維。紡絲箱的規格在Hills的美國專利 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -54- 587110 A7 B7 五、發明説明（一 _~ ~- 5 ’162 ’〇74，名稱爲 ''Methods 〇f Making pluralJt. -Ji. · This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -53- 587110 A7 B7 V. Description of Invention (51) (Please read the precautions on the back before filling this page ) This homopolymer is slowly melted and mixed between 1 3 0 C. When the homopolymer was melted ', about 8 pounds of a wet cake was slowly added to the molten homopolymer over a period of 30 minutes to form a first blend. The wet cake includes water-wet microcapsules. These microcapsules are filled with a phase change material (lllicrololot # M45-22, accounting for 63. 2% by weight of the micro- and phase-change materials. Microtek Laboratories, Inc. Made). When microcapsules containing a phase change material are added and these microcapsules are dispersed in a molten homopolymer, the water is rapidly distilled off. The mixing process was not terminated until the remaining moisture measured by Kad_Fischei · titration was less than 0.15% by weight. The first blend formed is cooled and cut into lumps for further processing. Approximately 30 pounds of bulk material was dry blended with approximately 70 pounds of chemical fiber grade polypropylene thermoplastic polymer to form a dry blend (polypropylene homopolymer 6 8 5 2 manufactured by BP Amoco Polymers). The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed in a 2.5-inch single-screw extruder, set the temperature of all sections at about 230 ° C, the screw speed was 70 revolutions per minute, and the filter was 1 50 holes, and in a nitrogen atmosphere, the dry blend obtained in the previous step was extruded in this extruder. Nine grains were formed in this manner. These nine pellets were dried on a dry bed overnight. The drying system was set to 105 ° C and the dew point to 40 ° C. The thermal energy storage capacity (latent heat) of these nine capsules was measured by DSC (differential scanning calorimeter) to be 23.1 J / g. In a multi-component fiber (two-component fiber in this example) spinning box at a temperature between 230 to 250 ° C, bi-component fiber is produced by melt spinning. The specifications of the spinning box are in the US patent of Hills. The paper size is applicable to the Chinese National Standard (CNS) A4 size (210X297 mm) -54- 587110 A7 B7 V. Description of the invention (一 ~~-5 '162' 〇74, Named `` Methods 〇f Making plural

Component Flbers"。使用該九粒形成芯成份，並用聚丙燃 或尼龍形成鞘成份。 (請先閱讀背面之注意事項再填寫本頁) 製造不同的芯/鞘比例和聚合物型材料的多成份纖維 。參考圖6中6種已經生產出來的芯/鞘型纖維的一些性 質和製造參數列出來。所有此等纖維都結合一種相變材料 和裝有相變材料的微囊（、、Mpcm 〃 ），此等相變材料和微 囊占每種纖維芯成份約1 5重量％，且占每一纖維總重量 的約7 · 5重量％到約1 1 · 2 5重量％。試樣1 、2、 3的鞘成份包括聚丙烯（p p )，該聚丙烯均聚物係由BP Amoco Polymers所製。試樣4、5、6的鞘成份包括尼龍 6，係由 BASF Corp 的 Utramid B 所製。 實施例2 經濟部智慧財產局員工消費合作社印製 用K 1 9石蠟（熔點2 9 °C，潛熱1 5 0焦/克，由 A m e r i c a n R e f i n i n g G1· 〇 u p，B r a d f ο 1· d，P A 生產）浸吸多種不同 的聚乙酸乙烯酯（E V A )九粒，並加熱使其膨脹。特別 地，將Elvax 3 50 ( 1 9熔體指數，2 5重量％乙酸乙烯酯 ，由DuPont Inc·生產）和Elvax 450 ( 8熔體指數，1 8重 量％乙酸乙烯酯，由DuPont Inc.生產）九粒在不同的溫度 下加熱不同的時間。九粒在一個排水槽中從剩餘的石蠟中 過濾出來，九粒吸收石蠟的量係從起始和結束時九粒的重 量計算出來（亦即，相對於起始時九粒重量的重量百分比 增加）。表3列出在不同條件下獲得的結果。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -55- 587110Component Flbers ". These nine capsules are used to form a core component, and polypropylene or nylon is used to form a sheath component. (Please read the notes on the back before filling out this page.) Manufacture multi-component fibers with different core / sheath ratios and polymer materials. Some of the properties and manufacturing parameters of the six core / sheath fibers that have been produced are listed with reference to FIG. 6. All these fibers combine a phase change material and microcapsules (,, Mpcmcm) filled with phase change materials. These phase change materials and microcapsules account for about 15% by weight of each fiber core component, and each The total weight of the fiber is from about 7.5% to about 11.5% by weight. The sheath components of samples 1, 2, and 3 included polypropylene (p p), and the polypropylene homopolymer was made by BP Amoco Polymers. The sheath components of samples 4, 5, and 6 included nylon 6, made by Utramid B of BASF Corp. Example 2 K 1 9 paraffin printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (melting point 29 ° C, latent heat 150 joules / gram, by American Refining G1 · 〇up, Bradf ο 1 · d, PA production) soaked a variety of nine polyvinyl acetate (EVA) nine pellets and heated to expand them. Specifically, Elvax 3 50 (19 melt index, 25% by weight vinyl acetate, produced by DuPont Inc.) and Elvax 450 (8 melt index, 18% by weight vinyl acetate, produced by DuPont Inc. ) Nine capsules are heated at different temperatures for different times. Nine grains are filtered out of the remaining paraffin in a drainage tank, and the amount of nine paraffin absorbed is calculated from the weight of the nine grains at the beginning and end (ie, a weight percentage increase relative to the weight of the nine grains at the beginning ). Table 3 lists the results obtained under different conditions. This paper size applies to China National Standard (CNS) A4 (210X297 mm) -55- 587110

7 B 五、發明説明（d 經濟部智慧財產局員工消費合作社印製 表3 EVA類 型 浸吸時 間（小時 ) 浸吸溫 度（。C) 吸收的石 蠟百分比 (%) 註 El vax 450 1.0 50 16 在排水槽內粘滯。 第二天排出更多 El vax 450 1.0 40 16 在排水槽內粘滯。 第二天排出更多 Elvax 450 1.0 80 在排水槽內粘滯。 第二天排出更多 Elvax 450 1.0 55 16 在排水槽內粘滯。 第二天排出更多 Elvax 450 3.0 55 32 在排水槽內粘滯。 第二天排出更多 Elvax 450 2.0 55 26 在排水槽內粘滯。 第二天排出更多 Elvax 450 1.0 60 43 在排水槽內粘滯。 第二天排出更多 Elvax 450 2.0 60 43 在排水槽內粘滯。 第二天排出更多 Elvax 450 5.0 60 44 在排水槽內粘滯。 第二天排出更多 Elvax 450 3.0 60 39 在排水槽內粘滯。 第二天排出更多 Elvax 350 2.0 40 31 在排水槽內乾性。 保持乾性。輕微粘 Elvax 350 3.5 40 38 在排水槽內乾性。 保持乾性。輕微粘 性。 Elvax 350 2.5 45 48 在排水槽內乾性。 保持乾性。輕微粘 性。 Elvax 350 2.0 40 20 在排水槽內乾性。 保持乾性。輕微粘 性。 Elvax 3 50 2.0 40 20 在排水槽內乾性。 保持乾性。輕微粘 性。 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中.國國家標準（CNS ) A4規格（210X297公釐） -56- 587110 ΑΊ _____ Β7_ 五、發明説明（54! 然後用標準的Hills，Inc.的雙成份纖維紡絲箱生產出芯 /鞘型纖維，其芯成份由上一步描述的九粒形成。特別地 ，芯成份係由吸收的石蠟2 6 %的Elvax 450九粒或吸收的 石蠟3 1 %的Elvax 3 50九粒形成。鞘成份由聚對苯二甲酸 乙一酯（E a s t m a n F 6 1 H C， Eastman Chemical, Inc.， Kingsport，TN所製）或聚對苯二甲酸三亞甲基酯（Corten*a 5 0921 0, Shell Chemical Corp.，Houston，TX 所製）形成。 芯/鞘型纖維的差不掃描量熱法測量係使用一 Perkin Elmer Pyris 1 儀器完成的。冷卻使用 FTS Systems Intercooler 1，資料分析使用Perkin Elmer Pyris熱分析系統 ’且軟體用的是視窗3 · 7 2版。試樣係在Perkin Elmer密 封鋁製試樣盤內完成準備，並且在測試過程中，試樣始終 處於持續的氮氣流中。 (請先閱讀背面之注意事項再填寫本頁} 經濟部智慧財產局員工消費合作社印製 2 溫°c度動同 •，升 ο 速自不 P 鐘 5 的用種 ο 分在°c峰各 1 每 } 5 熱的 I 以 4 約放維 約;溫晶纖 大 3P 降結型 到；ο 鐘的鞘 卻鐘 5 分蠘 \ 冷分約每石芯 樣 1 到以將出 試約熱}。列 將大加 5P4 } 持°0及 ο 表 IX ow ; IX ο :溫 1 鐘-果 括恒 I 分約結 包下從 1 到出 件 P 度約卻算 條 ο 速持冷計 試 1的保 P 分 測 I°c溫 ο 積。 在 5 恒 5 器質 }約下從儀性 本紙張尺度適用中國國家標準（CMS ) A4規格（210X 297公釐） -57- 587110 A7 B7 五、發明説明（d 表4 鞘成份 芯成份 潛熱 丹尼/細絲 堅韌度 延伸度 (焦/克） (克/) (%) PTT Elvax 450 吸 12.3 4.4 2.2 35 收26%的石鱲 PET Elvax 350 吸 6.9 3.7 2.8 30 收31%的石鱲 PET Elvax 350 吸 8.4 34.5 1.43 57 收31%的石鱲 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本說明書提及或引述的每專利申請、專利、出版物和 其他公開文獻都以引用的方式整個地倂於本文，如同每一 個別的專利申請、專利、出版物和其他公開文獻以特定且 個別的方式指出而倂於本文作爲參考。 雖然已經由參照特定具體實例說明本發明，但必須理 解，熟詣此藝者可以對本發明做不同的變化或做等效的替 換而不连Ml後附申g靑專利範圍的旨意和範圍。而且，爲適 用於特殊的環境，對於材料、物質組成、方法、程序步驟 或諸步驟適應本發明目標、旨意和範圍做一些修改。所有 此等修改都意欲涵蓋在後附申請專利範圍的範圍內。特別 地，雖然本文所揭示的方法系參照特殊順序下實施的特別 步驟予以說明，但要了解者，此等步驟可以·組合、再劃分 或再排序形成一種等效方法而不違離本發明的教導。因此 ，除非在此處有另外指出，否則諸步驟的順序和分組並不 本紙張尺度適用中.國國家標準（CNS ) A4規格（210X 297公釐） "—'一' " -58- 587110 A7 B7 五、發明説明（^ 對本發明構成限制 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -59-7 B V. Description of the invention (d Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Table 3 EVA type soaking time (hours) Soaking temperature (.C) Percent of paraffin absorbed (%) Note El vax 450 1.0 50 16 in Viscous in the drain. More El vax 450 1.0 40 16 drained the next day. Viscosity in the drain. Elvax 450 1.0 80 Viscosity in the drain. More Elvax 450 the next day. 1.0 55 16 Sticky in the gutter. More Elvax 450 3.0 55 32 drained the next day. Drain more Elvax 450 2.0 55 26 Sticky in the drain. Drained the next day. More Elvax 450 1.0 60 43 is sticky in the drain. More Elvax 450 2.0 60 43 is drained in the next day. More Elvax 450 5.0 60 44 is drained in the second day. Drain more Elvax 450 3.0 60 39 on the second day and stick in the drain. Drain more Elvax 350 2.0 40 31 on the second day. Dry in the drain. Keep dry. Slightly stick to Elvax 350 3.5 40 38 Dry in the drain Keep dry. Slightly sticky Elvax 350 2.5 45 48 Dry in the gutter. Keep dry. Slightly sticky. Elvax 350 2.0 40 20 Dry in the gutter. Keep dry. Slightly sticky. Elvax 3 50 2.0 40 20 Dry in the gutter. Keep dry .Slightly sticky. (Please read the precautions on the back before filling this page.) The paper size is applicable. National Standard (CNS) A4 (210X297 mm) -56- 587110 ΑΊ _____ Β7_ 5. Description of the invention (54! The core / sheath fiber was then produced using a standard Hills, Inc. two-component fiber spinning box with a core component formed from the nine pellets described in the previous step. In particular, the core component was 66% Elvax absorbed paraffin 450 nine capsules or absorbed paraffin 3 1% Elvax 3 50 nine capsules. The sheath component is made of polyethylene terephthalate (Eastman F 6 1 HC, manufactured by Eastman Chemical, Inc., Kingsport, TN) or polymer Trimethylene terephthalate (Corten * a 5 0921 0, manufactured by Shell Chemical Corp., Houston, TX). Differential scanning calorimetry for core / sheath fibers was performed using a Perkin Elmer Pyris 1 instrument. FTS Systems Intercooler 1 was used for cooling, Perkin Elmer Pyris thermal analysis system was used for data analysis, and the software used was Windows 3.7.2 version. The specimens were prepared in a Perkin Elmer sealed aluminum specimen pan, and the specimens were kept under a continuous stream of nitrogen during the test. (Please read the notes on the back before filling out this page} Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 °° C ° Same as •, ο Suo Zi P Zhong 5 The type of use is divided into ° c peaks 1 per} 5 hot I with about 4 dimensions; Wen Jingxian large 3P down knot type; ο the sheath of the bell but 5 minutes 蠘 \ cold division about 1 to each core sample to test out the heat} Column will increase by 5P4} Hold ° 0 and ο Table IX ow; IX ο: Wen 1 Zhong-Guo Kuo Heng I contract contract from 1 to the P degree but the calculation is ο Quick holding cold test 1 Guaranteed P-point measurement of I ° c temperature ο product. Approx. 5 constant 5 quality} Applicability This paper size applies Chinese National Standard (CMS) A4 specification (210X 297 mm) -57- 587110 A7 B7 V. Invention Description (d Table 4 Sheath composition Core composition Latent heat Denny / filament toughness elongation (joules / gram) (g /) (%) PTT Elvax 450 suck 12.3 4.4 2.2 35 receive 26% of stone 鱲 PET Elvax 350 suck 6.9 3.7 2.8 30 Closed 31% of stone concrete PET Elvax 350 Suction 8.4 34.5 1.43 57 Closed 31% of stone concrete (Please read the precautions on the back before filling this page) Wisdom of the Ministry of Economy Each patent application, patent, publication, and other public document mentioned or quoted in this specification printed by the Property Bureau employee consumer cooperative is incorporated herein by reference in its entirety, as if each individual patent application, patent, publication, and Other publications are indicated in a specific and individual manner and are incorporated herein by reference. Although the invention has been described with reference to specific specific examples, it must be understood that those skilled in the art can make different changes to the invention or make equivalent substitutions. It does not include the purpose and scope of the patent application scope attached to M1. Moreover, in order to apply to a special environment, some modifications are made to the materials, composition of materials, methods, procedure steps or steps to adapt to the objectives, purpose and scope of the present invention. All such modifications are intended to be included within the scope of the appended patent application. In particular, although the methods disclosed herein are described with reference to special steps implemented in a particular order, it is to be understood that these steps can be combined, combined, Subdivision or reordering forms an equivalent method without departing from the teachings of the present invention. Therefore, unless There is another point here, otherwise the order and grouping of the steps are not applicable in this paper. National Standard (CNS) A4 (210X 297 mm) " — '一' -quot-58- 587110 A7 B7 V. Description of the invention (^ constitutes a limitation on the present invention (please read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) ) -59-

Claims (1)

587110 A、申請專利範圍587110 A 、 Scope of patent application nikj第911〇〇612號專利甲請案 中文申請專利範圍無劃線替換本 民國92年10月7曰修正 1 · 一種具有強化的可逆熱學性質的多成份纖維，其 經濟部智慧財產局員工消費合作社印製 煩 1 * 1包括： W ^ 由眾多延伸成份形成的 ，一者包括分散在其內的溫度調節性材料，其中該溫度調節 ;义 貴性材料含有一種相變材料以及眾多含有該相變材料的微囊 4.'' 上-(microcapsules)〇 / - ;, · 条 2·如申請專利範圍第1項之多成份纖維，其中該相 气·， f變材料具有轉變溫度在22T：至40它範圍。 .欠 I； ^ 3 ·如申請專利範圍第1項之多成份纖維，其中該相 g變材料係從下列族群中選出：烴、水合鹽、蠘、油、水、 ¥脂肪酸、脂肪酸酯、·二元酸、二元酸酯、1 -鹵化物.、第 一醇、芳族化合物、包合物、半-包合物、氣態包合物、 硬脂酸酐、碳酸伸乙基酯、多羥基醇、聚合物、金屬和彼 等的混合物。 4 ·如申請專利範圍第1項之多成份纖維，其中該相 變材料係爲具有13至28個碳原子的石蠟烴。 5 ·如申請專利範圍第1項之多成份纖維，其中該延 伸成份中至少一者包含10重量百分比至.30重量百分比之 溫度調節性材料。 6 .如申請專利範圍第1項之多成份纖維，其中該延 伸成份係經排列成海包島型結構、花瓣型結構、芯/$肖型 G張尺度適财關家轉（CNS )六4胁（21GX297公釐) -- 纖維體，該延伸成份中至少 —^! (請先閱讀背面之注意事項再填寫本頁) 訂 銶 經濟部智慧財產局員工消費合作社印製 587110 A8 B8 C8 ___ D8 々、申請專利範圍 結構、並列型結構或條紋型結構。 7 .如申請專利範圍第1項之多成份纖維，其中該纖 維體的橫截面形狀爲圓形、多葉形、八邊形、橢圓形、五 邊形、長方形、正方形、梯形或三角形。 8 ·如申請專利範圍第1項之多成份纖維，其中·該纖 維體的細度介於0 · 1到1 0 0 0丹尼之間。 9 ·如申請專利範圍第1項之多成份纖維，其更包括 分散於至少一該延伸成份中的添加劑，其中該添加劑係從 下列所構成的組合中選出者：水、界面活性劑、分散齊ij、 消泡劑、抗氧化劑、熱安定劑、光安定劑、紫外線安定劑 、微波吸收添加劑、強化纖維、傳導纖維、傳導粒子、.潤 滑劑、加工助劑、阻燃劑、防阻斷劑、防霧添加劑、抗靜 電劑、抗微生物劑、交聯劑、控制降解劑、著色劑、色素 、染料、螢光增白劑、光學增亮劑、塡充物、偶合劑.、強 化季、結晶劑、晶核形成劑和彼等的混合物。 1 0 . —種具有強化的可逆熱學性質之多成份纖維， 其包括： —第一延伸成份，其包括第一聚合物型材料與分散在 該第一聚合物型材料中的一溫度調節性材料，其中該溫度 調節性材料含有一種具有轉變溫度在22°c至40°c範圍之相 變材料，以及其中該相變材料係選自固體./固體相變材料和 聚合物型相變材料所組成之群；和 一第二延伸成份，其包括一第二聚合物型材料，其中 該第二延伸成份係與該第一延伸成份接合。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公嫠） (請先聞讀背面之注意事項再填寫本頁)nikj Patent No. 911〇〇612 patent application Chinese patent application scope of the application without a line to replace the Republic of China October 7, 1992 Amendment 1 · A multi-component fiber with enhanced reversible thermal properties, which is consumed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative printed troubles 1 * 1 include: W ^ is formed by a number of extended components, one of which includes a temperature-adjusting material dispersed therein, wherein the temperature adjustment; the noble material contains a phase-change material and many contain the phase Microcapsules of changing materials 4. 上-(microcapsules) 〇 /-;, · Article 2 · As the multi-component fiber of the scope of application for patent No. 1, wherein the phase gas ·, f changing materials have a transition temperature of 22T: To 40 it ranges. Owe I; ^ 3 · The multi-component fiber according to item 1 of the patent application scope, wherein the phase change material is selected from the following groups: hydrocarbons, hydrated salts, tritium, oil, water, ¥ fatty acids, fatty acid esters, Dibasic acids, dibasic acid esters, 1-halides., Primary alcohols, aromatic compounds, clathrates, semi-cladates, gaseous clathrates, stearic anhydride, ethyl carbonate, and more Hydroxyl alcohols, polymers, metals and mixtures thereof. 4. The multi-component fiber according to item 1 of the patent application range, wherein the phase change material is a paraffin hydrocarbon having 13 to 28 carbon atoms. 5. The multi-component fiber according to item 1 of the patent application scope, wherein at least one of the elongation components comprises a temperature-adjustable material of 10% to .30% by weight. 6. The multi-component fiber according to item 1 of the scope of the patent application, wherein the extended component is arranged into a sea-island structure, a petal-shaped structure, and a core / $ Xiao G-shaped scale. (21GX297mm)-Fibrous body, at least in the extended component-^! (Please read the precautions on the back before filling this page) Order printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economy 587110 A8 B8 C8 ___ D8 々 , Patent scope structure, side-by-side structure or stripe structure. 7. The multi-component fiber according to item 1 of the patent application scope, wherein the cross-sectional shape of the fiber body is circular, multi-lobal, octagonal, oval, pentagonal, rectangular, square, trapezoidal or triangular. 8 · The multi-component fiber according to item 1 of the patent application scope, wherein the fineness of the fiber body is between 0 · 1 and 100 0 denier. 9 · The multi-component fiber according to item 1 of the patent application scope, further comprising an additive dispersed in at least one of the extended components, wherein the additive is selected from the following combinations: water, surfactant, and dispersion ij, defoamer, antioxidant, heat stabilizer, light stabilizer, ultraviolet stabilizer, microwave absorption additive, reinforcing fiber, conductive fiber, conductive particle, lubricant, processing aid, flame retardant, anti-blocking agent , Anti-fog additives, antistatic agents, antimicrobial agents, cross-linking agents, control degradation agents, colorants, pigments, dyes, fluorescent brighteners, optical brighteners, fillers, coupling agents, strengthening seasons, Crystallizing agents, crystal nucleating agents and mixtures thereof. 1 0. A multi-component fiber with enhanced reversible thermal properties, including:-a first elongation component comprising a first polymer-type material and a temperature-regulating material dispersed in the first polymer-type material Wherein the temperature-regulating material contains a phase change material having a transition temperature in the range of 22 ° c to 40 ° c, and wherein the phase change material is selected from the group consisting of solid phase change materials and polymer phase change materials. A group; and a second extension component, which includes a second polymer-type material, wherein the second extension component is bonded to the first extension component. This paper size applies to China National Standard (CNS) A4 (210X297 cm) (Please read the precautions on the back before filling this page) 587110 A8 B8 C8 ______ D8 六、申請專利範圍 1 1 .如申請專利範圍第1 0項之多成份纖維，其中 5亥相變材料係爲多羥基醇。 ， 1 2 _如申請專利範圍第1 〇項之多成份纖維，其中該 (請先聞讀背面之注意事項再填寫本頁) 相變材料係選自聚乙二醇、聚環氧乙烷和聚酯所組成之群 〇 1 3 ·如申請專利範圍第1 〇項之多成份纖維，其中該 溫度調節性材料更包括眾多含有相變材料的微囊。 1 4 .如申請專利範圍第1 〇項之多成份纖維，其中該 第一聚合物型材料對於該溫度調節性材料具有親合力，因 而幫助該溫度調節性材料分散於該聚合物型材料中。 1 5 .如申請專利範圍第1 〇項之多成份纖維，其中 該溫度調節性材料爲一第一溫度調節性材料，且其中該第 二延伸成份進一步包括一第二溫度調節性材料分散在該第 二聚合物型材料中。 1 6 ·如申請專利範圍第1 5項之多成份纖維，其中 該第一溫度調節性材料和該第二溫度調節性材料不相同。 經濟部智慧財產局員工消費合作社印製 1 7 ·如申請專利範圍第1 〇項之多成份纖維，其中 該第一聚合物型材料和該第二聚合物型材料係獨立地從下 列族群中選出：聚醯胺、多胺、聚醯亞胺、聚丙烯酸、聚 碳酸酯、聚二烯烴、聚環氧化物、聚酯、聚醚、聚氟碳化 合物、甲醛聚合物、天然聚合物、聚烯烴、聚伸苯基、含 矽聚合物、聚胺基甲酸酯、乙烯聚合物、聚縮醛、聚芳基 化合物、共聚物和彼等的混合物。 1 8 ·如申請專利範圍第1 〇項之多成份纖維，其中 本紙張尺度適用中國國家摞準（CNS ) A4規格（210X297公釐） ----- 587110 經濟部智慧財產局員工消費合作社印製 A8 B8 C8 ------^_六、申請專利範圍 ---— 該第一聚合物型材料包括聚乙烯一共一乙酸乙烯酯，其具 有介於5重量％到9 〇重量％之間的乙酸乙烯酯。 1 9 ·如申請專利範圍第1 0項之多成份纖維，其中 該第一延伸成份係被該第二延伸成份所包圍。 2 0 ·如申請專利範圍第1 9項之多成份纖維。，其中 該第一延伸成份位於第二延伸成份內並被它完全包圍。 2 1 ·如申請專利範圍第1 〇項之多成份纖維，其中 該第一延伸成份佔有該多成份纖維總重量的1 〇 %到9 〇 % ° 2 2 ·如申請專利範圍第1 〇項之多成份纖維，其中 該多成份纖維係介於〇 · 1到1 〇 〇 〇丹尼之間。 2 3 ·如申請專利範圍第1 〇項之多成份纖維，其更 包括分散於至少一該第一聚合物型材料和該第二聚合物型 材料中的添加劑，其中該添加劑係從下列族群中選出：水 、界面活性劑、分散劑、消泡劑、抗氧化劑、熱安定劑、 光安定劑、紫外線安定劑、微波吸收添加劑、強化纖維、 傳導纖維、傳導粒子、潤滑劑、加工助劑、阻燃劑、防阻 斷劑、防霧添加劑、防靜電添加劑、抗微生物劑、交聯劑 、控制降解劑、著色劑、色素、染料、螢光增白劑、光學 增亮劑、塡充物、偶合劑、強化劑、結晶劑、晶核形成劑 和彼等的混合物。 . 2 4 . —種具有強化的可逆熱學性質之多成份纖維， 其包括： 一包括一溫度調節性材料的芯成份，其中該溫度調節 (請先閲讀背面之注意事項再填寫本頁) 1 —- - - - ! · -裝· 訂 絲· 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -4 - 587110 A8 B8 C8 六、申請專利範圍^^~一 " — 小4未才尖社'jhr 3 種具有轉變溫度在22°C至40°C範圍之聚合物 型相變材料；和 一包圍該芯成份的鞘成份。 (請先閲讀背面之注意事項再填寫本頁) 2 5 ·如申請專利範圍第2 4項之多成份纖維，其中 曰亥聚合物型相變材料的轉變溫度係在22°C至28°C之範圍。 2 6 ·如申請專利範圍第24項之多成份纖維，其中該 聚合物型相變材料係選自聚乙二醇、聚環氧乙烷和聚酯所 組成之群。 2 7 ·如申請專利範圍第.24項之多成份纖維，其中該 K $丨分彳占有該多成份纖維總重量的1 0 %到9 0 %。 2 8 ·如申請專利範圍第24項之多成份纖維，其中該 芯成份進〜步包括一第一聚合物型材料，其中該溫度調節 性材料係經分散在該第一聚合物型材料中，且其中該鞘成 份則包括一第二聚合物型材料。 2 9 ·如申請專利範圍第2 8項之多成份纖維，其中 該芯成份含有5重量％到70重量％的溫度調節性材料。 經濟部智慧財產局員工消費合作社印製 3 0 ·如申請專利範圍第2 8項之多成份纖維，其中 該第一聚合物型材料對該聚合物型相變材料具有部份親合 力，且其中該第二聚合物型材料在芯成份內包圍該聚合物 型相變材料並且爲多成份纖維提供所希望的物理性質。 3 1 ·如申請專利範圍第2 8項之多成份纖維，其中 該溫度調節性材料爲一第一溫度調節性材料，且其中該鞘 成份更包括分散於該第二聚合物型材料中的一第二溫度調 節性材料。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 587110 經濟部智慧財產局員工消費合作社印製 is8 C8六、申請專利範圍 '----- 3 2 ·如申目靑專利範圍第3丄項之多成份纖維，其中 該第一溫度調節性材料和該第二溫度調節性材料係不同者 〇 3 3 ·如申請專利範圍第2 8項之多成份纖維，其中 该第一溫度調節性材料和該第二溫度調節性材料係獨立地 從下列族群中選出：聚醯胺、多胺、聚醯亞胺、聚丙烯酸 、聚碳酸酯、聚一嫌烴 '聚環氧化物、聚酯、聚醚、聚氟 碳化合物、甲醛聚合物、天然聚合物、聚烯烴、聚伸苯基 、含矽聚合物、·聚胺基甲酸酯、乙烯聚合物、聚縮醛、聚 芳基化合物、共聚物和彼等的混合物。 3 4 ·如申請專利範圍第2 4項之多成份纖維，其中 該芯成份位於該鞘成份內並完全被該鞘成份包圍。 3 5 ·如申請專利範圍第2 4項之多成份纖維，其中 該芯成份係經同心地配置於該鞘成份內。 3 6 ·如申請專利範圍第2 4項之多成份纖維，其中 該芯成份係經偏心地配置於該鞘成份內。 3 7 .如申請專利範圍第2 4項之多成份纖維，其中 該芯成份的截面形狀爲圓形、多葉形、八邊形、橢圓形、 五邊形、矩形、正方形、梯形、三角形或楔形。 3 8 ·如申請專利範圍第2 4項之多成份纖維，其中 多成份纖維係介於0 · 1到1 0 0 〇丹尼之間。 3 9 .如申請專利範圍第2 4項之多成份纖維，其更 包括分散於該芯成份和該鞘成份中至少一者之中的一添加 劑，該添加劑係從下列族群中選出：水、界面活性劑、分 --—- (請先閲讀背面之注意事項再填寫本頁) 裝· -訂. 絲 本紙張尺度適用中國國家梂準（CNS ) Α4規格（210X297公釐） 587110 A8 B8 C8 D8 六、申請專利範圍 散劑、防泡沬劑、抗氧化劑、熱安定劑、光安定劑、紫外 安定劑、微波吸收添加劑、強化纖維、傳導纖維、傳導粒 子、潤滑劑、加工助劑、阻燃劑、防阻斷劑、防霧添加劑 、防靜電添加劑、抗微生物劑、交聯劑、控制降解劑、著 色劑、色素、染料、螢光增白劑、光學增亮劑、塡充物' 偶合劑、強化劑、結晶劑、晶核形成劑和彼等的混合物。 4 0 . —種具有強化的熱學性質之纖維，其包括： 至少一內部成份，其實質地延伸貫穿該纖維的長度， 且包括由一第一聚合物型材料和一相變材料所形成的摻合 物，其中該第一聚合物型材料對該相變材料具有部份親合 力，以致於該相變材料形成分散於該第一聚合物型材料中 之眾多區域（domains);和 一外部成份，其包圍該內部成份並形成該纖維的外部 ，其中該外部成份包括一第二聚合物型材料。 4 1 ·如申請專利範圍第4 〇項之纖維，其中該第一 聚合物型材料和第一聚合物型材料係獨立地從下列族群中 選出：聚烯烴、聚醯胺、聚酯、彈性體聚合物和彼等的混 合物。 4 2 ·如申請專利範圍第4 1項之纖維，其中該第一 聚合物型材料和該第二聚合物型材料係獨立地從下列族群 中選出的聚烯烴：聚乙烯、聚丙烯和彼等的混合物。 4 3 ·如申請專利範圍第4 〇項之纖維，其中該相變 材料在溫度- 5。(：到1 2 5。(：之範圍吸收或放出熱量。 4 4 .如申請專利範圍第4 〇項之纖維，其中該相變 本紙張尺度瓦^關家標準（CNS )八4祕（21〇><297公羡） (請先閲讀背面之注意事項再填寫本頁} 裝· 絲 經濟部智慧財產局員工消費合作社印製 587110 經濟部智慧財產局員工消費合作社印製 A8 B8 C8 _ D8申請專利範圍 材料在溫度2 2 C到4 0 °C之範圍吸收或放出熱量。 4 5 ·如申請專利範圍第4 0項之纖維，其中該相變 材料爲從下列族群中選出：C 1Q-44石蠘烴、聚環氧乙院 、聚乙二醇和彼等的混合物。 4 6 ·如申請專利範圍第4 0項之纖維，其中該第一 聚合物型材料包含具有介於5重量％和90重量％乙酸乙嫌 酯的聚乙烯-共聚-乙酸乙烯酯。 4 7 ·如申請專利範圍第4 0項之纖維 成份包括兩種或兩種以上不同的相變材料。 4 8 .如申請專利範圍第4 0項之纖維 成份包括至多5 0重量％的相變材料。 4 9 ·如申請專利範圍第4 0項之纖維 成份包括至多2 5重量％的相變材料。 5 0 ·如申請專利範圍第4 0項之纖維 該相變材料的區域係被該第一聚合物型材料所包圍。 5 1 ·如申請專利範圍第4 0項之纖維，其中該內部 成份爲界定纖維內的芯之單一內部成份。 5 2 .如申請專利範圍第4 0項之纖維，其中該纖維 包括眾多彼此隔離並被該外部成份包圍的內部成份。 5 3 ·如申g靑專利圍弟4 0項之纖維，其中該纖維 是一連續纖維或短纖維。 5 4 · —種芯/鞘型纖維，其包括： 一芯成份，其經配置於該纖維之內並實質地延伸貫穿 該纖維的長度，其中該芯成份包括一由一第一聚合物型材 其中該內部 其中該內部 其中該內部 其中該眾多 ^-- (請先閲讀背面之注意事項再填寫本頁) 訂. 絲 Μ氏張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） 587110 六、申請專利範圍 料和一相變材料所形成的摻合物，其中該第〜聚合物刑材 料對該相變材料具有部份親合力，以致於該相變材料形成 分散於該第一聚合物型材料中之眾多區域（d〇mains) ·和 一鞘成份，其形成該纖維的外部並包圍該芯成份，宜 中該鞘成份包括一第二聚合物型材料。 5 5 .如申請專利範圍第5 4項之芯/鞘型纖維，其 中該第一聚合物型材料和第二聚合物型材料係獨立地從下 列族群中選出：聚烯烴、聚醯胺、聚酯、彈性體聚合物和 彼等的混合物。 5 6 .如申請專利範圍第5 5項之芯/鞘型纖維，其 中該第一聚合物型材料和該第二聚合物型材料係獨立地從 下列族群中所選出的聚烯烴：聚乙烯、聚丙烯和彼等的混 合物。 5 7 ·如申g靑專利範圍第5 4項之心/鞘型纖維·，宜 中該相變材料爲從下列族群中選出：C i。— 4 4石蠘烴、聚 環氧乙烷、聚乙二醇和彼等的混合物。 經濟部智慧財產局員工消費合作社印製 5 8 ·如申請專利範圍第5 4項之芯/鞘型纖維，其 中該相變材料具有轉變溫度在22°C至40°C範圍。 5 9 ·如申請專利範圍第5 4項之芯/鞘型纖維，其 中該芯成份包括一由該第一聚合物型材料和至少兩不同的 相變材料所成的摻合物。 6 0 . —種海包島型（island-in-sea)纖維，其包括： 一眾多島成份，其經配置在該纖維之內並實質地延伸 貫穿該纖維的長度，其中每一該島成份都彼此隔離，並且 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） rgr:------ 587110 A8 B8 C8 D8 申請專利範圍 包括由一島狀聚合物型材料和相變材料所成的摻 中該島狀聚合物型材料對該相變材料具有部份親 致於該相變材料形成分散於該島狀聚合物型材料 區域(domains);和 一海成份’其形成該纖維的外部且包 ，其中該海成份包括一海型聚合物型材料。 6 1 .如申請專利範圍第6 〇項之海包島型 中該島狀聚合物型材料和該海型聚合物型材料係 下列族群中選出：聚烯烴、聚醯胺、聚酯、彈性 和彼等的混合物。 6 2 ·如申請專利範圍第6 1項之海包島型 中該島狀聚合物型材料和該海型聚合物型材料係 下列族群中所選出的聚烯烴··聚乙烯、聚丙烯和 合物。 合物，其 合力，以 中之眾多 圍每一該島成份 纖維，其 獨立地從 體聚合物 纖維，其 獨立地從 彼等的混 經濟部智慧財產局員工消費合作社印製 6 3 ·如申請專利範圍第6 〇項之海包島型纖維，其 中該溫度調節性材料爲一從下列所構成的組合中選出的相 變材料：C i 〇 - 4 4鏈烷烴、聚環氧乙烷、聚乙二醇和彼等 的混合物。 6 4 .如申請專利範圍第6 0項之海包島型纖維，其 中該相變材料具有轉變溫度在221至40°C範圍。 6 5 ·如申請專利範圍第6 0項之海包島型纖維，其 中至少一島成份包括一由島狀聚合物型材料和至少兩不同 的相變材料所成之摻合物。 6 6 .如申請專利範圍第6 0項之海包島型纖維，其 表紙張尺度適用中國國家榡準（CNS ) A#規格（21〇><297公釐） (請先聞讀背面之注意事項再填寫本頁)587110 A8 B8 C8 ______ D8 VI. Scope of patent application 1 1. For multi-component fiber with the scope of patent application No. 10, the phase change material is polyhydric alcohol. 1 2 _If the multi-component fiber in the scope of patent application No. 10, which (please read the notes on the back before filling this page) phase change material is selected from polyethylene glycol, polyethylene oxide and The group composed of polyesters 013. The multi-component fiber such as the item 10 of the patent application scope, wherein the temperature-regulating material further includes a plurality of microcapsules containing a phase change material. 14. The multi-component fiber as described in claim 10, wherein the first polymer-type material has an affinity for the temperature-adjustable material, thereby helping the temperature-adjustable material to be dispersed in the polymer-type material. 15. The multi-component fiber according to item 10 of the patent application scope, wherein the temperature-adjustable material is a first temperature-adjustable material, and wherein the second extension component further includes a second temperature-adjustable material dispersed in the In the second polymer type material. 16 · The multi-component fiber according to item 15 of the patent application scope, wherein the first temperature-adjustable material and the second temperature-adjustable material are different. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 17 · If the multi-component fiber of the scope of application for patent 10, the first polymer material and the second polymer material are independently selected from the following ethnic groups ： Polyamine, polyamine, polyimide, polyacrylic acid, polycarbonate, polydiene, polyepoxide, polyester, polyether, polyfluorocarbon, formaldehyde polymer, natural polymer, polyolefin , Polyphenylene, silicon-containing polymers, polyurethanes, ethylene polymers, polyacetals, polyarylates, copolymers, and mixtures thereof. 1 8 · If the multi-component fiber of item 10 in the scope of the patent application, the paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) ----- 587110 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs System A8 B8 C8 ------ ^ _ VI. Application for Patent Range ----- The first polymer-type material includes polyethylene-co-vinyl acetate, which has a content between 5 wt% and 90 wt%. Vinyl acetate. 19 · The multi-component fiber according to item 10 of the patent application scope, wherein the first extended component is surrounded by the second extended component. 20 · Multi-component fiber such as item 19 in the scope of patent application. Wherein the first extension component is located in and completely surrounded by the second extension component. 2 1 · As for the multi-component fiber in the scope of patent application item 10, wherein the first extended component accounts for 10% to 90% of the total weight of the multi-component fiber ° 2 2 · In the case of the scope of patent application item 10 Multi-component fiber, wherein the multi-component fiber is between 0.1 and 1,000 denier. 2 3 · The multi-component fiber according to item 10 of the patent application scope, further comprising additives dispersed in at least one of the first polymer-type material and the second polymer-type material, wherein the additives are from the following groups Selected: water, surfactants, dispersants, defoamers, antioxidants, heat stabilizers, light stabilizers, ultraviolet stabilizers, microwave absorption additives, reinforcing fibers, conductive fibers, conductive particles, lubricants, processing aids, Flame retardant, anti-blocking agent, anti-fog additive, anti-static additive, anti-microbial agent, cross-linking agent, control degradation agent, colorant, pigment, dye, fluorescent brightener, optical brightener, filler , Coupling agent, strengthening agent, crystallizing agent, crystal nucleating agent and mixtures thereof. 2 4. — A multi-component fiber with enhanced reversible thermal properties, including:-a core component including a temperature-regulating material, where the temperature is adjusted (please read the precautions on the back before filling out this page) 1 — ----! · -Packing · Stitching · This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) -4-587110 A8 B8 C8 VI. Patent Application ^^ ~ 一 " — Small 4 Weicaijianshe'jhr 3 polymer phase change materials with a transition temperature in the range of 22 ° C to 40 ° C; and a sheath component surrounding the core component. (Please read the precautions on the back before filling in this page) 2 5 · If the multi-component fiber of item 24 of the patent application scope, the transition temperature of the polymer phase change material is 22 ° C to 28 ° C Range. 26. The multi-component fiber according to item 24 of the application, wherein the polymer phase change material is selected from the group consisting of polyethylene glycol, polyethylene oxide, and polyester. 2 7 · If the multi-component fiber of item No. 24 of the patent application scope, wherein the K $ 丨 fraction accounts for 10% to 90% of the total weight of the multi-component fiber. 2 8 · If the multi-component fiber according to item 24 of the patent application scope, wherein the core component further comprises a first polymer-type material, wherein the temperature-regulating material is dispersed in the first polymer-type material, The sheath component includes a second polymer-type material. 29. The multi-component fiber according to item 28 of the patent application scope, wherein the core component contains 5 to 70% by weight of a temperature-adjustable material. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 30. If the multi-component fiber of item 28 of the patent application scope, the first polymer material has partial affinity for the polymer phase change material, and among them The second polymer-type material surrounds the polymer-type phase change material within the core component and provides the desired physical properties to the multi-component fiber. 3 1 · The multi-component fiber according to item 28 of the scope of patent application, wherein the temperature-adjustable material is a first temperature-adjustable material, and wherein the sheath component further includes one dispersed in the second polymer-type material. The second temperature regulating material. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 587110 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs is8 C8 6. Scope of patent application '----- 3 2 · If you apply for a patent scope The multi-component fiber according to item 3, wherein the first temperature-adjustable material and the second temperature-adjustable material are different. 03. The multi-component fiber according to item 28 of the patent application scope, wherein the first temperature The modulating material and the second temperature-regulating material are independently selected from the following groups: polyamine, polyamine, polyimide, polyacrylic acid, polycarbonate, poly-hydrocarbon 'polyepoxide, poly Esters, polyethers, polyfluorocarbons, formaldehyde polymers, natural polymers, polyolefins, polyphenylene, silicon-containing polymers, polyurethanes, ethylene polymers, polyacetals, polyaryl groups Compounds, copolymers and their mixtures. 34. The multi-component fiber according to item 24 of the patent application scope, wherein the core component is located in the sheath component and is completely surrounded by the sheath component. 3 5 · The multi-component fiber according to item 24 of the patent application scope, wherein the core component is arranged concentrically in the sheath component. 36. The multi-component fiber according to item 24 of the patent application scope, wherein the core component is eccentrically arranged in the sheath component. 37. The multi-component fiber according to item 24 of the patent application scope, wherein the cross-sectional shape of the core component is circular, multi-lobal, octagonal, oval, pentagonal, rectangular, square, trapezoidal, triangular, or Wedge-shaped. 3 8 · The multi-component fiber according to item 24 of the patent application scope, wherein the multi-component fiber is between 0.1 · 1 to 100 Denny. 39. The multi-component fiber according to item 24 of the patent application scope, further comprising an additive dispersed in at least one of the core component and the sheath component, the additive is selected from the following groups: water, interface Active agent, minus ----- (Please read the notes on the back before filling this page) Binding · -Ordering. Silk paper size applies to China National Standard (CNS) Α4 size (210X297 mm) 587110 A8 B8 C8 D8 Sixth, the scope of patent application: powder, antifoam tincture, antioxidant, heat stabilizer, light stabilizer, ultraviolet stabilizer, microwave absorption additive, reinforcing fiber, conductive fiber, conductive particles, lubricant, processing aid, flame retardant , Anti-blocking agents, anti-fog additives, anti-static additives, anti-microbial agents, cross-linking agents, control degradation agents, colorants, pigments, dyes, fluorescent brighteners, optical brighteners, fillers, coupling agents , Strengthening agents, crystallization agents, crystal nucleating agents and mixtures thereof. 40. A fiber with enhanced thermal properties, including: at least one internal component that extends substantially the length of the fiber, and includes a blend formed from a first polymer-type material and a phase change material Material, wherein the first polymer-type material has partial affinity for the phase-change material, so that the phase-change material forms a plurality of domains dispersed in the first polymer-type material; and an external component, It surrounds the internal component and forms the exterior of the fiber, wherein the external component includes a second polymer-type material. 4 1 · The fiber according to item 40 of the patent application range, wherein the first polymer-based material and the first polymer-based material are independently selected from the following groups: polyolefin, polyamide, polyester, elastomer Polymers and their mixtures. 4 2 · The fiber according to item 41 of the patent application range, wherein the first polymer-based material and the second polymer-based material are polyolefins independently selected from the following groups: polyethylene, polypropylene, and others mixture. 4 3 · The fiber according to item 40 of the patent application range, wherein the phase change material is at a temperature of -5. (: To 1 2 5. The range of (:) absorbs or emits heat. 4 4. As for the fiber of the scope of patent application No. 40, wherein the phase change of this paper scale standard ^ house standard (CNS) eighty four secret (21 〇 > < 297 public envy) (Please read the notes on the back before filling out this page.) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by A8 B8 C8 _ D8 The material for patent application range absorbs or emits heat in the temperature range of 2 2 C to 40 ° C. 4 5 · As for the fiber of patent application item 40, the phase change material is selected from the following groups: C 1Q -44 Lactone, polyethylene oxide, polyethylene glycol, and mixtures thereof. 4 6. The fiber according to item 40 of the patent application scope, wherein the first polymer-type material comprises a fiber having a content between 5% and 5% by weight. Polyethylene-co-vinyl acetate and 90% by weight of ethyl acetate. 4 7 · The fiber content of item 40 in the patent application scope includes two or more different phase change materials. 4 8. Fibre content in patent scope item 40 includes up to 50 weight % Of phase change material. 4 9 · The fiber content of item 40 in the scope of patent application includes up to 25% by weight of the phase change material. 50 · Area of the phase change material in case of fiber scope of patent application 40 It is surrounded by the first polymer-type material. 5 1 · The fiber of item 40 in the scope of patent application, wherein the internal component is a single internal component that defines the core within the fiber. 5 2. The fiber of item 0, wherein the fiber includes a plurality of internal components that are isolated from each other and surrounded by the external component. 5 3 · The fiber of item 40 of Rushen patent, where the fiber is a continuous fiber or short fiber. 5 4. A seed core / sheath fiber, comprising: a core component disposed within the fiber and substantially extending through the length of the fiber, wherein the core component includes a first polymer profile in which the Inside, inside, inside, inside, etc. ^-(Please read the notes on the back before filling out this page) Order. Silk M's scale is applicable to China National Standard (CNS) Α4 specification (210 X 297 mm) 587110 six The blend formed by the scope of patent application and a phase change material, wherein the first polymer material has partial affinity for the phase change material, so that the phase change material forms a dispersion in the first polymer type Domains in the material · and a sheath component that forms the exterior of the fiber and surrounds the core component, preferably the sheath component includes a second polymer-type material. 5 5. 54. The core / sheath fiber of item 4, wherein the first polymer-type material and the second polymer-type material are independently selected from the following groups: polyolefin, polyamide, polyester, elastomeric polymer, and other And so on. 56. The core / sheath fiber according to claim 55, wherein the first polymer material and the second polymer material are polyolefins independently selected from the following groups: polyethylene, Polypropylene and their blends. 5 7 · If applying for the core / sheath fiber of item 54 of the patent scope, it is preferable that the phase change material is selected from the following ethnic groups: C i. — 4 4 ballast hydrocarbon, polyethylene oxide, polyethylene glycol and mixtures thereof. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 8 · If the core / sheath fiber of item 54 of the patent application scope, the phase change material has a transition temperature in the range of 22 ° C to 40 ° C. 59. The core / sheath fiber according to item 54 of the patent application, wherein the core component comprises a blend of the first polymer-type material and at least two different phase change materials. 6 0. An island-in-sea fiber comprising: a plurality of island components, which are arranged within the fiber and substantially extend through the length of the fiber, each of which is an island component Are isolated from each other, and this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) rgr: ------ 587110 A8 B8 C8 D8 The scope of patent applications includes an island-like polymer material and phase change The island-like polymer-type material mixed with the material has a partial affinity for the phase-change material to form the phase-change material dispersed in the island-like polymer-type material domains; and a sea component 'its formation The fiber is external and enveloping, wherein the marine component includes a marine polymer type material. 6 1. The island polymer type material and the sea type polymer type material in the sea-island type according to the scope of the application for patent 60 are selected from the following groups: polyolefin, polyamide, polyester, elastic and Their mixture. 6 2 · If the island polymer type material and the sea type polymer type material in the sea-island type of item 61 of the patent application range are polyolefins selected from the following groups: polyethylene, polypropylene and compounds . Compound, its synergy, with a large number of fibers around each island, it is independently produced from polymer fibers, and it is independently printed from their consumer cooperatives of the Intellectual Property Bureau of the Ministry of Mixed Economy 6 3 · If applied The sea-island type fiber of the scope of patent No. 60, wherein the temperature-regulating material is a phase change material selected from a combination of: C i 〇-4 4 paraffin, polyethylene oxide, polymer Glycol and their mixtures. 64. The island-in-sea fiber according to item 60 of the patent application range, wherein the phase change material has a transition temperature in the range of 221 to 40 ° C. 65. The sea-island type fiber according to item 60 of the patent application, wherein at least one island component includes a blend of an island polymer type material and at least two different phase change materials. 6 6. If the sea-island type fiber in item 60 of the patent application scope, the paper size of the surface paper is applicable to China National Standard (CNS) A # specification (21〇 > < 297mm) (Please read the back (Please fill in this page again) 經濟部智慧財產局員工消費合作社印製 587110 A8 B8 C8 _______ D8 六、申請專利範圍 中至少兩島成份包栝不同的相變材料。 β 7 ·如申請專利範圍第6 0項之海包島型纖維，其 中至少兩島成份包括不同的島狀聚合物型材料。 6 8. —*種製造和加工具有強化的可逆熱學性質的纖 維之方法，其包括： 將一相變材料和一第一聚合物型材料混和以形成一摻 口物’其中該第一聚合物型材料對該相變材料具有部份親 合力； 在一纖維擠出裝置的紡絲箱中，將該摻合物與一第二 e物型材料組合使得該第二聚合物型材料包圍該摻合物 ;和 將該摻合物與該第二聚合物型材^從紡絲箱的紡嘴擠 出以形成一纖維，該纖維的外部成份由該第二聚合物型材 料所形成並包圍由該摻合物形成的內部成份，其中該相變 材料形成分散於該內部成份中之眾多區域（d〇mains)。 δ 9 ·如申請專利範圍第6 8項之方法，其更包括在 混合之前，將該相變材料加到該第一聚合物型材料中，其 中該相變材料和該第一聚合物型材料各別均呈液體或固體 的形式。 7 0 ·如申請專利範圍第6 8項之方法，其中該將相 變材料和該桌一聚合物型材料混和的方法包括： 提供一由該相變材料形成的一第一液體流； 提供一由該第一聚合物型材料形成的第二液體流；及 使該第一液體流和該第二液體流相交混流以形成該相 G氏張中國國家標準（哪〉八4祕711^297公釐了 (請先聞讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 587110 A8 B8 C8 _______ D8 VI. At least two islands in the scope of patent application contain different phase change materials. β 7 · If the sea-island type fiber of item 60 of the patent application scope, at least two island components include different island-like polymer-type materials. 6 8. — * A method of manufacturing and processing fibers with enhanced reversible thermal properties, comprising: blending a phase change material and a first polymer-type material to form an admixture, wherein the first polymer Material has partial affinity for the phase change material; in a spinning box of a fiber extrusion device, the blend is combined with a second e-type material such that the second polymer-type material surrounds the dopant And the second polymer profile is extruded from the spinning nozzle of the spin box to form a fiber, the outer component of the fiber is formed by the second polymer type material and surrounded by the The internal component formed by the blend, wherein the phase change material forms a plurality of domains dispersed in the internal component. δ 9 The method according to item 68 of the patent application scope, further comprising adding the phase change material to the first polymer-type material before mixing, wherein the phase change material and the first polymer-type material Each is in liquid or solid form. 70. The method of claim 68, wherein the method of mixing a phase change material with the polymer material of the table includes: providing a first liquid stream formed from the phase change material; providing a A second liquid stream formed from the first polymer-type material; and the first liquid stream and the second liquid stream are mixed to form a phase to form the phase. (Please read the notes on the back before filling in this page) 587110 A8 B8 C8 D8 經濟部智慧財產局員工消費合作社印製 々、申請專利範圍 變材料和該第一聚合物型材料的摻合物。 7 1 ·如申請專利範圍第6 8項之方法，其中該將摻 合物與該第二聚合物型材料擠出的程序爲熔融紡絲或溶液 紡絲程序。 7 2 ·如申請專利範圍第6 8項之方法，其更包括將 該纖維拉細。 7 3 ·如申請專利範圍第7 2項之方法，其更包括於 拉細纖維後’將該纖維繞在線軸上或與其他纖維組合以形 成一不織布。 7 4 · —種製造具有強化的可逆熱學性質的纖維之方 法，其包括： 形成眾多單獨的摻合物，其中每一摻合物包括一溫度 調節性材料和~聚合物型材料，其中該溫度調節性材料含 有一種相變材料以及眾多含有該相變材料的微囊（ microcapsules)； 在一個纖維擠出裝置的紡絲箱中，將該眾多單獨摻合 物與一第二聚合物型材料組合使得該第二聚合物型材料包 圍該眾多單獨慘合物；及 將該眾多單獨摻合物與該第二聚合物型材料從紡絲箱 的噴絲口擠出以形成一纖維，該纖維的外部成份細由該第 二聚合物型材料形成並且包圍由該眾多單獨摻合物形成的 內部成份。 7 5 ·如申請專利範圍第7 4項之方法，其中該相變 材料具有轉變溫度在22°C至40°C範圍。 (請先閲讀背面之注意事項再填寫本頁) •裝· 訂 絲· 本紙張尺度適用中國國家標準（CNS ) a4規格（210X297公嫠） 12 587110 六、申請專利範圍 76 . —種織物，其包括眾多摻合在—起的纖維，其 中至少一纖維展現出強化的可逆熱學性質且包括·· 至少內部成份，其包括由一第一聚合物型材料與〜 相變材料所形成的摻合物，其中該內部成份實質地延伸貫 穿該纖維的長度，且其中該第一聚合物型材料對該相變材 料具有部份親合力，以致於該相變材料形成分散於該第一 聚合物型材料中之眾多區域（domains);及 一外部成份，其形成該纖維的外部且包圍該內部成份 ，其中該外部成份包括一第二聚合物型材料。 7 7 ·如申§靑專利範圍第7 6項之紡織品，其中該內 部成份包括至少兩不同的相變材料。 7 8 .如申請專利範圍第7 6項之織物，其中該織物 包括眾多展現出強化的可逆熱學性質的纖維，且其中至少 兩纖維包括不同的相變材料。 7 9 ·如申請專利範圍第7 6項之織物，其中該纖維 包括眾多被該外部成份包圍的內部成份。 8 0 ·如申請專利範圍第7 9項之織物，其中至少兩 該內部成份包括不同的相變材料。 經濟部智慧財產局員工消費合作社印製 8 1 ·如申請專利範圍第7 6項之織物，其中該眾多 纖維係藉由一織造程序或非織程序而摻合在一起。 8 2 .如申請專利範圍第7 6項之織物，其中該眾多 的纖維係利用妨粘法慘合在一^起。 8 3 · —種織物，其包括眾多摻合在一起的纖維，其 中至少一纖維展現出強化的可逆熱學性質且包括： 本紙張尺度適用中國國家梂準（CNS ) A4規格（210X297公釐） - 587ll〇 A8 B8 C8 ----------D8 __ 六、申請專利範圍 (請先聞讀背面之注意事項再填寫本頁) 一纖維體，其係由眾多延伸成份形成的，其中至少一 該延伸成份包括一經分散在其內的溫度調節性材料，其中 該溫度調節性材料含有一種相變材料以及眾多含有該相變 材料的微囊。 8 4 ·如申請專利範圍第8 3項之織物，其中該相變 材料具有轉變溫度在22°C至40°C範圍。 8 5 .如申請專利範圍第8 3項之織物，其中該相變材 料係從下列族群中選出：烴、含水鹽、蠘、油、水、脂肪 酸、脂肪酸酯、二元酸、二元酸酯、1 一鹵化物、伯醇、 芳香化合物、包合物、部分包合物、氣態包合物、硬脂酸 酐、碳酸乙烯、多羥基醇、聚合物、金屬和彼等的混合物 〇 8 6 ·如申請專利範圍第83項之織物，其中該相變材 料係爲具有13至28個碳原子的石鱲烴。 8 7 ·如申請專利範圍第83項之織物，其中該延伸成 份中至少一者包含10重量百分比至30重量百分比之溫度 調節性材料。 經濟部智慧財產局員工消費合作社印製 8 8 ·如申請專利範圍第8 3項之織物，其中該等延 伸成份係經排列成海包島型結構、花瓣結構、芯/鞘結構 、並列結構或條狀結構。 8 9 ·如申請專利範圍第8 3項之織物，其中該纖維 體的橫截面形狀爲圓形、多葉形、八邊形、橢圓形、五邊 形、矩形、正方形、梯形或三角形。 9 0 ·如申請專利範圍第8 3項之織物，其中該纖維 -14 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 587110 A8 B8 C8 D8 「'申請專利範圍 體係介於〇 · 1到1 ο 〇 〇之間。 9 1 ·如申請專利範圍第8 3項之織物，其 括分散在至少一延伸成份中的添加劑，該添加劑 族群中選出：水、界面活性劑、分散劑、防泡沬 化劑、熱安定劑、光安定劑、紫外安定劑、微波 劑、強化纖維、傳導纖維、傳導粒子、潤滑劑、 、阻燃劑、防阻斷劑、防霧添加劑、防靜電添加 生物劑、交聯劑、控制降解劑、著色劑、色素、 光增白劑、光學增亮劑、塡充物、偶合劑、強化 劑、晶核形成劑和彼等的混合物。 9 2 .如申請專利範圍第8 3項之織物，其 纖維係藉由機織法、非織法或編織法慘合在一起。 進一步包 係從下列 劑、抗氧 吸收添加 加工助劑 劑、抗微 染料、登 劑、.結晶 中該眾多 (請先聞讀背面之注意事項再填寫本頁) -裝· 訂 絲 經濟部智慧財產局員工消費合作社印製587110 A8 B8 C8 D8 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, a blend of patent-changeable materials and the first polymer-type material. 71. The method of claim 68, wherein the process of extruding the blend with the second polymer-type material is a melt spinning or solution spinning process. 7 2 · The method according to item 68 of the scope of patent application, further comprising thinning the fiber. 7 3 · The method according to item 72 of the scope of patent application, which further comprises, after drawing the fiber, to wind the fiber on a bobbin or combine it with other fibers to form a non-woven fabric. 7 4 · A method of manufacturing fibers with enhanced reversible thermal properties, comprising: forming a plurality of individual blends, each blend including a temperature-regulating material and a polymer-type material, wherein the temperature The conditioning material contains a phase change material and a plurality of microcapsules containing the phase change material; the plurality of individual blends are combined with a second polymer-type material in a spinning box of a fiber extrusion device Causing the second polymer-type material to surround the plurality of individual polymer compounds; and extruding the plurality of individual blends and the second polymer-type material from the spinneret of the spin box to form a fiber, the fiber's External components are formed from the second polymer-type material and surround internal components formed from the plurality of individual blends. 7 5 · The method according to item 74 of the patent application range, wherein the phase change material has a transition temperature in a range of 22 ° C to 40 ° C. (Please read the precautions on the back before filling this page) • Binding, stapler, and paper size are applicable to the Chinese National Standard (CNS) a4 specification (210X297 cm) 12 587110 6. Application for patent scope 76.-A kind of fabric, which Includes a number of fibers blended together, at least one of which exhibits enhanced reversible thermal properties and includes at least an internal component, which includes a blend formed from a first polymer-type material and ~ a phase change material Wherein the internal component substantially extends through the length of the fiber, and wherein the first polymer-type material has a partial affinity for the phase-change material, so that the phase-change material forms a dispersion in the first polymer-type material A plurality of domains; and an external component that forms the exterior of the fiber and surrounds the internal component, wherein the external component includes a second polymer-type material. 7 7 • The textile of item 76 of the patent scope according to § 靑, wherein the internal component includes at least two different phase change materials. 78. The fabric of claim 76, wherein the fabric includes a plurality of fibers exhibiting enhanced reversible thermal properties, and at least two of the fibers include different phase change materials. 79. The fabric of claim 76, wherein the fiber includes a plurality of internal components surrounded by the external component. 80. The fabric according to item 79 of the patent application scope, wherein at least two of the internal components include different phase change materials. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 8 1 · If the fabric of the scope of patent application No. 76, the plurality of fibers are blended together through a weaving process or a non-woven process. 8 2. The fabric according to item 76 of the scope of the patent application, wherein the plurality of fibers are fused together using the viscosifying method. 8 3 · —A kind of fabric, including a large number of fibers blended together, at least one of which exhibits enhanced reversible thermal properties and includes: This paper size applies to China National Standard (CNS) A4 (210X297 mm)- 587ll〇A8 B8 C8 ---------- D8 __ VI. Scope of patent application (please read the precautions on the back before filling out this page) A fiber body, which is formed by many extension components, of which At least one of the extension components includes a temperature-adjustable material dispersed therein, wherein the temperature-adjustable material contains a phase change material and a plurality of microcapsules containing the phase change material. 8 4 · The fabric according to item 83 of the patent application range, wherein the phase change material has a transition temperature in the range of 22 ° C to 40 ° C. 85. The fabric according to item 83 of the scope of patent application, wherein the phase change material is selected from the following groups: hydrocarbons, hydrous salts, osmium, oil, water, fatty acids, fatty acid esters, dibasic acids, dibasic acids Esters, 1 monohalides, primary alcohols, aromatic compounds, clathrates, partially clathrates, gaseous clathrates, stearic anhydride, ethylene carbonate, polyhydric alcohols, polymers, metals, and mixtures thereof. 8 6 -The fabric as claimed in claim 83, wherein the phase change material is a ballast hydrocarbon having 13 to 28 carbon atoms. 87. The fabric as claimed in claim 83, wherein at least one of the extended components comprises a temperature-adjustable material of 10 to 30% by weight. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 8 8 · If the fabric of the patent application No. 83 is applied, the extended components are arranged into a sea-island structure, petal structure, core / sheath structure, side-by-side structure or strip状 结构。 Like structure. 89. The fabric of claim 83, wherein the cross-sectional shape of the fiber body is circular, multi-lobal, octagonal, oval, pentagonal, rectangular, square, trapezoidal, or triangular. 9 0 · If the fabric of the scope of patent application No. 83, where the fiber -14-This paper size is applicable to China National Standard (CNS) A4 specifications (210X297 mm) 587110 A8 B8 C8 D8 "'The scope of patent application system is between 〇 · 1 to 1 ο 〇〇. 9 1 · If the fabric of the scope of patent application No. 83, which includes additives dispersed in at least one extension component, the additive group selected: water, surfactant, dispersion Agent, antifoaming agent, heat stabilizer, light stabilizer, ultraviolet stabilizer, microwave agent, reinforcing fiber, conductive fiber, conductive particle, lubricant, flame retardant, anti-blocking agent, anti-fog additive, anti-fog Electrostatically added biological agents, cross-linking agents, control degradation agents, colorants, pigments, light whitening agents, optical brighteners, fillers, coupling agents, strengthening agents, crystal nucleating agents and their mixtures. 9 2 . For the fabric of the 83rd item of the patent application, the fibers are combined together by woven, non-woven or weaving methods. It further includes the following agents, anti-oxidant absorption processing additives, anti-micro dyes Deng There are a lot of agents and crystals (please read the precautions on the back before filling out this page)-binding and binding. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs.