TW584654B

TW584654B - Composition of release agent

Info

Publication number: TW584654B
Application number: TW91137448A
Authority: TW
Inventors: Juh-Shyong Lee; Su-Mei Wei; Ren-Kuen Chang; Yuan-Der Wu; Han-Ying Liou
Original assignee: Ind Tech Res Inst; Headway Advanced Materials Inc
Priority date: 2002-12-26
Filing date: 2002-12-26
Publication date: 2004-04-21
Also published as: TW200411017A

Abstract

A composition of release agent made from the components comprising silicone polymer which is generally used as an addition-type release agent, silicone compound having linear or cage molecular structure as a release modifier, catalyst, and solvent, and a composition of release agent made from the components comprising a commercial addition-type release agent formulation and the silicone compound having linear or cage molecular structure as a release modifier mentioned above. Because of the addition of the new release modifier, the peel strength of the composition of release agent of the present invention is adjustable in order to conform to the needed one.

Description

五、發明說明（1) 發明所屬之技術領域本發明有關一稀灕刑节“人型改質劑、觸媒、及、、六丨^5物，包括矽酮聚合物、離物，包括市售加成型：二:f:明又有關-種離型劑組合明之離型劑組合物因天:=成配*方及離型改«劑。本發剝離力來調配，可Ξ 型所需 ί " i ；tc"^ ^ ^ ^ ^ -般皮革或膠帶產V。偏仏衣程、觸控平板製程、以及先前技術造渦：ί凡件產業中的積層型陶瓷晶片電容(MLCC)生產製 A =王以具有離型功能的聚酯薄膜（例如PET離型膜） (為Γ基板’將嶋料塗佈於其上，乾燥後繼膜 = er«lc green tape)，將兗膜與聚酿薄膜一同捲起，可 =:階段製程如電極網印(pri與疊壓⑻他" & :私木作’強化自動化能力，降低人力成本及提高生產 2 ，而且更能確保生產品質。但是隨著MLCC新製程的發 =二£膜越來越薄，造成進行疊壓製程時，剝離瓷臈的^ “ ；4低其主要因素疋聚酯薄膜上的離型膜不適宜，瓷，^離型膜之間的剝離力變A，造成剝離㈣時竟膜破損或裏程不順暢而造成皺摺等現象，使得成功率降低。另、外j瓷膜塗佈厚度不同時，瓷膜與離型膜之間的最適宜的剝離力亦不同，而需要不同的離变劑。美國專利第6，0 0 8，3 1 0號揭示一種能抗老化的控制離V. Description of the invention (1) The technical field to which the invention belongs The invention relates to a dilute punishment "human modifiers, catalysts, and catalysts, including silicone polymers, and Sale and addition molding: two: f: Ming and related-a combination of release agents Ming of the release agent composition due to the day: = formula * side and release modification «agent. The hair peeling force to adjust, can be required for the type ί "i; tc " ^ ^ ^ ^ ^ -V ordinary leather or tape production V. Partial clothing process, touch panel process, and previous technology vortex generation: ί multilayer ceramic chip capacitors in the industry Production system A = Wang Yi's polyester film with release function (such as PET release film) (coating the material on the substrate Γ, drying the subsequent film = er «lc green tape), the film and the The poly-brew film is rolled up together, which can =: stage process such as electrode screen printing (pri and laminated sunda " &: private wood made 'to strengthen automation capabilities, reduce labor costs and improve production2, and can ensure production quality more . But with the development of the new MLCC process, the film becomes thinner and thinner, which causes the porcelain to peel off during the lamination process; 4 The main factor is that the release film on the polyester film is not suitable, and the peeling force between porcelain and ^ release film becomes A, which causes the film to be broken or the mileage is not smooth when it is peeled. In addition, when the coating thickness of the outer ceramic film is different, the optimum peeling force between the ceramic film and the release film is also different, and different release agents are required. US Patent No. 6, 0 0 8, 3 No. 10 reveals a control ion that can resist aging

〇424-9069TWF(N)；〇29l〇〇35；patncia.ptd 第6頁 584654 五、發明說明（2) " - 型添加劑（CR A )的組合物，包含至少2個可交聯的雙鍵的聚石夕氧南为子、至少2個S i - Η的聚石夕氧高分子、已經封端的聚石夕倍半氧：)：完（silylated p〇iySiiseSqUii〇xane)、白金觸媒、及抑制劑。但都在膠帶產業之應用，未提出MLCC 業的應用。美國專利第5, 7 0 8, 0 7 5號揭示一種離型劑組合物以解決在許多應用中需要各種不同剝離力規格之問題，包含至少2個烯烷基的聚矽氧烷、至少2個^—h的聚矽氧烷、含有 S 1 -H的矽樹脂、白金觸媒、及抑制劑。但是都集中在接劑方面’未提出MLCC產業的應用。〜美國專利第5, 6 9 6, 2 1 1號揭示一種離型劑組合物，能使得剝離時，以低速或高速之離型力差異變化不大，其^包含一種氟化烷基之聚矽氧烷，至少含有3個s丨—H以及一種至少含有烯烷基的MQ樹脂（為網狀結構）。但是氟化严美本過高，且並未提出MLCC產業的應用。疋土风美國專利第5，4 6 8，8 1 6號揭示一種離型改質劑，應於無溶劑型的離型劑配方中，提高低速剝離時的離心，其包含一種MQ樹脂（為網狀結構）、碳數在8至22之 :―。二稀烴（dl〇lenn)。但是未提出在MLCC產業上的應，發明内容本發明之目的係提供一種可鉍之離型劑組合物。了匕易依所需而§周控制離力本發明之另-目的係提供—種將離型改質劑添加於一〇424-9069TWF (N); 〇29l〇〇35; patncia.ptd page 6 584654 V. Description of the invention (2) "-type additive (CR A) composition comprising at least 2 crosslinkable bis The polysilicon oxygen bond of the bond is a child, at least 2 Si-plutonium polysilicon oxygen polymer, the polysilicon sesquioxane that has been capped :): finished (silylated p〇iySiiseSqUii〇xane), platinum catalyst , And inhibitors. However, they are all applied in the tape industry, and no application in the MLCC industry has been proposed. U.S. Patent No. 5, 7 0 8, 0 7 5 discloses a release agent composition to solve the problem of requiring various peel force specifications in many applications. Polysiloxane containing at least 2 alkenyl groups, at least 2 A ^ -h polysiloxane, a silicone resin containing S 1 -H, a platinum catalyst, and an inhibitor. However, they are all focused on the aspect of contact, and they have not proposed the application of the MLCC industry. ~ U.S. Patent No. 5, 6 9 6, 2 1 1 discloses a release agent composition, which can make little difference in release force at low or high speed during peeling, which contains a polymer of a fluorinated alkyl group. Siloxane contains at least 3 s 丨 -H and an MQ resin containing at least alkenyl groups (for a network structure). However, the cost of fluorinated Yanmei is too high, and no application of the MLCC industry has been proposed. Nozomi U.S. Patent No. 5,4 6 8,8 16 discloses a release modifier that should be used in a solvent-free release formulation to improve centrifugation at low speed peeling. It contains an MQ resin (for Network structure), carbon number of 8 to 22: ―. Two dilute hydrocarbons (dlOlenn). However, no application in the MLCC industry has been proposed. SUMMARY OF THE INVENTION The object of the present invention is to provide a bismuth-releasable release agent composition. In order to control the release force as needed, the other purpose of the present invention is to provide a kind of

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而能達到所需剝離力之離型劑般市售離型劑組成配方中組合物。之J2述目的’本發明之離型劑組合物係由包括下列之1成…而成：⑷HO㈣之石夕酮聚合物(SlllC_ = lym^加成型離型劑，其具有及Sl_乙稀基（Sl—H / 1二之莫耳比在"〜4.8之間），分子量在1〇〇,〇〇〇至 #之間，（b) 〇· 5~30 以成分（a)之重量為準）之離里改|劑’其是具有線形或籠形結構之矽酮 (silicone) 4匕合物，（c) S π r η π , 口观b(J〜5〇〇 PPm (以成分（a)之重量 "之觸媒，其是擇自一般矽氫加成（hydros i lylat ion) 反應用之觸媒，及⑷餘量為溶劑，其是擇自矽酮聚合物的適合溶劑。本發明之另一種離型劑組合物係由包括下列之成分混 σ而成·（ a) 2至1 0 w t %之市售加成型以矽酮聚合物為主之離型劑組成配方，及（b) 〇·5至3〇 wt%以矽酮聚合物之重i為準之離型改貝劑，疋具有線型或籠形結構之石夕酮化合物。本發明之離型劑組合物可應用於電子/光電產業，例如塗佈在PET薄膜上，能形成具有特定離型力的pET離型膜，尤其可應用於被動元件產業中的積層型陶瓷晶片電容 (MLCC)生產製造過程中，作為陶瓷漿料之載體（Carrier sheet)。本發明亦可應用於光電產業中的偏光膜製程中或觸控平板製程、以及傳統之皮革與膠帶產業。實施方式A release agent capable of achieving the required peeling force is generally a commercially available release agent to form a composition in a formulation. The purpose stated in J2 'of the release agent composition of the present invention is composed of 10% of the following: ⑷HO 石 lithosene polymer (SlllC_ = lym ^ addition molding release agent, which has (Sl-H / 12 Molar ratio is between " ~ 4.8), molecular weight is between 100,000, ##, (b), 0.5 ~ 30 is based on the weight of component (a) as Quasi) of Lilichang | agent 'It is a silicone 4 compound with a linear or cage structure, (c) S π r η π, oral view b (J ~ 50〇PPm (with ingredients (A) The weight of the catalyst is selected from the general hydrosilylation reaction, and the remainder is the solvent, which is a suitable solvent selected from the silicone polymer. Another release agent composition of the present invention is made up of a mixture of the following ingredients: (a) 2 to 10 wt% of a commercially available addition-molded silicone polymer-based release agent, And (b) 0.5 to 30 wt% of a release-modifying agent based on the weight i of the silicone polymer, i.e., a lithone compound having a linear or cage structure. The release agent composition of the present invention Can be applied to electronics / optical Industry, such as coating on PET film, can form a pET release film with a specific release force. It is especially applicable to the manufacturing process of multilayer ceramic chip capacitors (MLCC) in the passive component industry. Carrier sheet. The present invention can also be applied to the polarizing film process or touch panel process in the optoelectronic industry, and the traditional leather and tape industries.

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本發明提供一種離型劑組八混合而成：2~1〇 wt%，#杜二口物’係由包括下列之成分 l /〇車父佳為3至7 w % ^ (si 1 icone p〇lymer)力士之石夕_聚合物聚合物重量為準（較佳為3至15 f 〇·〜3〇 wt%以該石夕嗣 5 0〜5 0 0 ppm以該矽顯j〒人 ΰ 型改質劑、 1ΠΠ 、々來5物離型劑重量為準（齡γ土 AM 5 100 ΡΡΠ1)之觸媒，及其他為溶劑。羊（較么為50至 μ Γ::i:酮聚合物加成型離型劑是可藉由此技藝中二=或在市場上講得之加成型離型劑，具； SI J 及 S卜CH = CH2 (Sl-H / Sl_CH = CH2 之莫耳比在 124 δ 之間’較佳在2.0至3.5之間；分子量在1〇〇,〇〇〇至 1，0 0 0，0 0 0 之間，較佳在 3 〇〇，〇〇〇至 7 〇〇，〇〇〇之間。媒所使用之觸媒是擇自一般以-[1/以—(：11二(：}12加成型用觸較佳為白金系統之觸媒。擇群所使用之溶劑是擇自矽酮聚合物的適合溶劑，較隹為甲苯、正庚烷、曱基乙基酮等、及其組合所組成之組所使用之離型改質劑為具有下列線形之分子結構之穎矽酮化合物： y 民 Ri R2 1¾ 1¾The present invention provides a release agent group consisting of eight mixtures: 2 to 10 wt%, # 杜二口物 'is composed of the following ingredients 1 / 〇 Che Fujia is 3 to 7 w% ^ (si 1 icone p 〇lymer) Lishi's Shi Xi _ polymer polymer weight (preferably 3 to 15 f 〇 · ~ 30 wt% based on the Shi Xi 嗣 5 0 ~ 50 0 ppm to the silicon display j〒人 ΰ) Type modifiers, 1ΠΠ, 5th release agent based on weight (age γ soil AM 5 100 PPΠ1) catalyst, and other solvents. Sheep (more than 50 to μ Γ :: i: ketone polymerization Additive release agents are additive release agents that can be obtained from this technique in the art == or on the market; SI J and S. CH = CH2 (Sl-H / Sl_CH = Molar ratio of CH2 Between 124 δ 'is preferably between 2.0 and 3.5; molecular weight is between 100,000 and 10,000, and preferably between 30,000 and 7,000. 〇，〇〇〇。 The catalyst used in the media is selected from-[1 / 以 — (: 11 二 (:} 12) The catalyst for the addition is preferably a platinum system catalyst. Used by Select Group The solvent is a suitable solvent selected from silicone polymers. The heptane, Yue ethyl ketone and the like, and combinations thereof of the release agent is a modified silicone Ying ketone compound of the following molecular structure having the line: y China Ri R2 1¾ 1¾

II I I I I 1¾ —a —X a-o)m( a-o)n(a-o)0(sKV2i-1¾II I I I I 1¾ —a —X a-o) m (a-o) n (a-o) 0 (sKV2i-1¾

I I I I I I K=j (I)I I I I I I K = j (I)

Ri是C1-3烧基，較佳為甲烧基；R2是氫原子或(^_3 ：)：完基或cRi is a C1-3 alkyl group, preferably a methylalkyl group; R2 is a hydrogen atom or (^ _3 :): an end group or c

584654 五、發明說明（5) 稀^兀基。Rs為G 3烧基或苯基。該化合物之分子量在 3,500〜30,〇〇〇之間，較佳在5〇〇〇至2〇,〇〇〇之間部份佔 95〜60%，較佳佔95〜85%部份佔〇〜〗⑽，較佳佔〇〜5%。〇部份佔0〜10%，較佳佔〇〜5%部份佔〇〜1〇%，較佳佔 0〜5 % ’以該化合物之分子量計。此種線形離型改質劑是以矽酮單體與觸媒在高溫下反應而共聚合，除去參與反應之觸媒後，經過高真空除去未反應之單脰與低分子养聚物而製得，其中可使用之碎酮單體舉例為：環狀之（-suciuaMo-)3、（—Si(CH3) (CH3)0-)4 ^ (-Si(CH3)(CH3)0-)5 ^ (-Si(CH3)(CHCH2)0-)4 ^ (-Si(CH3)(H)〇-)4、或此等環狀單體之混合物、 H2C:CH —Si(CH3)2-〇-Si(CH3)2 —CH:CH2、h —Si口(CH3) 2#〇-Si(CH3)2-H、PhSiCH3(OCH3)2、及Ph2Si(〇CH3)2 等，外為苯基；可使用之觸媒為強酸溶液。或者，上述離型改質劑亦可為具有下列籠形之分子結構之矽酮化合物： ((R4)SiOL5)q (II) R4是氫原子或C2_1()烯：)：完基。q為8〜1β之整數。此種籠形離型改質劑是以Τ-型功a抑& ^ , ^ t 1 $夕烷單體溶於有機溶劑中’與水及觸媒在低溫下水解、端八难合反應，除去參盥反庫之觸媒及除水後，濃縮過剩的溶劍，P ^ ^ d ’即可析出此籠形之矽酮化合物，其中可使用之矽單體舉例為· CHJHSKOCH^、及Si(OC2H5)4 ;可佶田…、· ^ 」便用之觸媒為硫酸、鹽酸、醋酸等。本發明中可使用做為雜 4離型改質劑之籠形矽酮584654 V. Description of the invention (5) Rare stilts. Rs is G 3 alkyl or phenyl. The molecular weight of the compound is between 3,500 ~ 30,000, preferably between 50,000 and 20,000, accounting for 95-60%, and preferably between 95-85%. ~〗 ⑽, preferably 0 ~ 5%. 〇 part accounts for 0 ~ 10%, preferably 0 ~ 5% part accounts for 0 ~ 10%, preferably 0 ~ 5%. ′ Is calculated based on the molecular weight of the compound. This linear release modifier is made by copolymerizing a silicone monomer with a catalyst at a high temperature. After removing the catalyst participating in the reaction, the unreacted monofluorene and low-molecular-weight nutrients are removed by high vacuum. Thus, examples of the fragmented ketone monomers that can be used are: cyclic (-suciuaMo-) 3, (-Si (CH3) (CH3) 0-) 4 ^ (-Si (CH3) (CH3) 0-) 5 ^ (-Si (CH3) (CHCH2) 0-) 4 ^ (-Si (CH3) (H) 〇-) 4, or a mixture of these cyclic monomers, H2C: CH-Si (CH3) 2-〇 -Si (CH3) 2 —CH: CH2, h —Si (CH3) 2 # 〇-Si (CH3) 2-H, PhSiCH3 (OCH3) 2, and Ph2Si (〇CH3) 2, etc., the outside is phenyl; The catalyst used is a strong acid solution. Alternatively, the above-mentioned release modifier may be a silicone compound having the following cage-shaped molecular structure: ((R4) SiOL5) q (II) R4 is a hydrogen atom or C2_1 () ene :): end group. q is an integer from 8 to 1β. This clathrate release modifier is based on T-type work a & ^, ^ t 1 $ Xane monomer is dissolved in an organic solvent, and it is hydrolyzed with water and catalyst at a low temperature, and the reaction is difficult. After removing the catalyst and water from the toilet, the excess dissolved sword can be concentrated, and P ^ ^ d 'can precipitate this cage-shaped silicone compound. Examples of silicon monomers that can be used are CHJHSKOCH ^, and Si (OC2H5) 4; can be used as a catalyst ... Sulfuric acid, hydrochloric acid, acetic acid, etc. Cage silicone can be used in the present invention as a hetero 4 release modifier

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584654 五、發明說明（6) 化合物亦可使用市售來源，例如，G e 1 e s 1: I n c ·所售之 SST-V8V01 (商品名，學名是聚（乙烯基矽倍半氧烷Τ8) (P〇ly(vinylsilsesclui〇xane) -T8))4SST —Η8Η〇ι (商品品’學名是聚（氩矽倍半氧烷）—Τ 8 (poly(hydridosi lseSQUi〇xane)—Τ8))等相類似產品。所使用之離型改質劑中烯烷基之比例越高時，施用型劑組合物後所獲得之剝離力越大。雖本發明之離型劑組合物可進一步包括適量之抑以增長離型劑混合後之使用操作壽命，即適用期(㈧广 1 i fe)。例如：块醇化合物、過氧化合物等。本發明之離型劑組合物可進—σ \ ^ i 疋步包括適置之微如知子，例如：奈米級的S i 02、丁 i 〇 $ 、、、极太扒日日兄古明絲L 2或有機高分子微粒。本务明另有關一種離型劑組合 β 矽酮聚合物為主之離型劑組成配疋长平ϋ加成型以分子結構之矽酮化合物之離型改所添加具有線型或蘢形添加量可為0· 5〜30 wt%，較佳為3貝劑。，種離型改質劑之物含量計。所含之烯烷基比例越古1 5 ^t% ’以該矽酮聚合所得之剝離力越大。經過此簡單问天離型劑組合物施用後力之需求，便利的調配出所雲 4、加可因應不同剝離所使用之市售離型劑組成配^型劑^合物。型，例如··日本信越化學公司#可為溶劑型或非溶劑國Rodia公司的746 0pex系列、日=齊1型1^'370 3系列、法型KNS- 3 0 0 2系列、或其組合、或是2越化學公司的非溶劑之離型劑組成。所使用之離型他加成型矽S同聚合物工'改質劑為呈有飨形斗、〜勺八’踝形或籠形分584654 V. Description of the invention (6) The compound can also be obtained from commercially available sources, for example, G e 1 es 1: I nc · SST-V8V01 (trade name, scientific name is poly (vinylsilsesquioxane T8) (P〇ly (vinylsilsesclui〇xane) -T8)) 4SST—Η8Η〇ι (commercial product's scientific name is poly (argon silsesquioxane) -T 8 (poly (hydridosi lseSQUi〇xane) -T8)) and other phases similar product. The higher the proportion of alkenyl groups in the release modifier used, the greater the peel force obtained after application of the mold composition. Although the release agent composition of the present invention may further include an appropriate amount to increase the operating life after the release agent is mixed, that is, the pot life (㈧广 1 i fe). For example: block alcohol compounds, peroxy compounds, etc. The release agent composition of the present invention can be advanced-σ \ ^ i 疋 Steps include suitable micro-factors, such as: nano-grade S i 02, Ding i 〇 $, ,, Tai Tai Ba Ri Ri Gu Ming Ming Silk L 2 or organic polymer particles. This business note also relates to a release agent combination β silicone polymer-based release agent composition with long flats and addition of silicone compounds with molecular structure. It is 0.5 to 30 wt%, preferably 3 shells. , The content of the release modifier. The higher the proportion of alkenyl groups contained, the greater the peeling force obtained by the polymerization of the silicone. After simply asking the demand of the release agent composition after application, it is convenient to formulate the cloud 4. Add the commercially available release agent used in accordance with different peeling to form a formulation. Types, such as ... Japan Shin-Etsu Chemical Company # may be solvent type or non-solvent country Rodia 746 0pex series, Japan = Qi 1 type 1 ^ '370 3 series, French type KNS-3 0 0 2 series, or a combination thereof Or non-solvent release agent composition of 2 Koshi Chemical Co., Ltd. The release type used is the addition of silicon S and polymer. The modifiers are in the shape of a bucket, a spoon or an ankle or a cage.

0424-9069TWF(N);02910035;pat ricia.ptd0424-9069TWF (N); 02910035; pat ricia.ptd

^ 11頁 584654 五、發明說明（7) 子結構之矽酮化合物，如上述之式（I)與式（u 亦可如上述在本發明之離型劑組合物中依所需添加適 ^ 劑、有機溶劑、或微細粒子。之抑下列實施例進一步說明本發明。所之明如下·· 所不之各早體代號說 D4 ·· (-Si(CH3)(CH3)0-)4 V1 : (-Si(CH3)(CHCH2)〇-)4 V : (-Si(CH3)(H)0-)4 .Ph2Si(0R)2，Ph 為苯基，及r 為ch3^ Page 11 584654 V. Description of the invention (7) The sub-structured silicone compound, such as the above formula (I) and formula (u), can also be added as needed in the release agent composition of the present invention as needed ^ , Organic solvents, or fine particles. The following examples further illustrate the present invention. The explanation is as follows. The different early body codes are D4 (-Si (CH3) (CH3) 0-) 4 V1: (-Si (CH3) (CHCH2) 〇-) 4 V: (-Si (CH3) (H) 0-) 4. Ph2Si (0R) 2, Ph is phenyl, and r is ch3

M2Vi · H2C二CH-Si(CH3)2-〇- Si(CH3)9-CH二CH M2H : H-Si (CH3)2 —〇-Si (CH3)2 —H 2 實施例實施例1 線形離型改質劑之製備秤取0.43克D，單體、丨.86克單體47·71克匕單體、及〇· 13克之濃度為〇· 25 wt%之硫酸水溶液置於旋^式反應機之反應瓶中，蓋妥瓶蓋。啟動旋轉式反應機，升^至^ °C反應2小時後，再升溫至130Τ:反應1小時。降溫取:所得之洛液’以0 · 2 2克N a H C 〇3中和之。然後，將所得之混合物授拌均勻後’以離心分離方式將產生之鹽類去除，然後將該混合物置於蒸發器（evap〇rator )内，溫度設定18〇〇c，啟動真二馬達至氣壓小於1·◦托耳（t〇rr)後，除去低分子量寡聚物，再升溫至2 0 〇 °C維持約2小時，直到無餾出物為止。獲得本發明之線形離型改質劑（樣品編號ss„197)，具有下列結構，預設分子量為約·5〇〇〇，其中乙烯基含量為約M2Vi · H2C di-CH-Si (CH3) 2-〇- Si (CH3) 9-CH di-CH M2H: H-Si (CH3) 2 -〇-Si (CH3) 2 -H 2 Example Example 1 Linear separation Preparation of type modifiers Weigh 0.43 grams of D, monomers, 丨 .86 grams of monomers 47.71 grams of monomers, and 0.13 grams of sulfuric acid aqueous solution with a concentration of 0.25 wt% in a spin-type reaction Close the cap of the reaction bottle of the machine. Start the rotary reactor, raise it to ^ ° C for 2 hours, and then raise the temperature to 130T: react for 1 hour. Take the temperature drop: The obtained Luo liquid ′ was neutralized with 0.22 g of Na H C 03. Then, after the resulting mixture is uniformly mixed, the generated salts are removed by centrifugation, and then the mixture is placed in an evaporator (evaporator), the temperature is set to 180 ° c, and the Shinji motor is started to the air pressure After less than 1 Torr, the low-molecular-weight oligomer was removed, and the temperature was raised to 2000 ° C. for about 2 hours until no distillate was obtained. The linear release modifier (sample number ss'197) of the present invention was obtained, which has the following structure, and the preset molecular weight is about · 500, wherein the vinyl content is about

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〇424-9069TWF(N);02910035;patricia.ptd 第12頁 584654〇424-9069TWF (N); 02910035; patricia.ptd Page 12 584654

五、發明說明（8) 〇·ΐ莫耳/1000克。如表1所示。 ch3 | cn3 .» I ch=ch2 t I ch3 I (3I2=CH — Si — 0 i 1 -f-Si 〇)- v V I ri 1 -Si — CH=CH- ,I . ch3 ch3 tl I 11 ch3 L 1 ch3 貫施例2至6線形離型改質劑之製備如實施例1之相同方法依表1所示之數據進行線形離型改質劑之製備。獲得本發明之線形離型改質劑（樣品編號 SS-198至SS-2 0 2 )，樣品編號SS-198至199之結構同上述樣品編號SS-197之結構，樣品編號SS-2 0 0至SS2 0 2具有下列結構。其他數據如表1所示。 ch3 ch3 (1 .、 CH=CH9 ，I \ ch3 1 H — Si — 〇 1 I Si 〇 V | /m ch3 irSi O-H I / Π -Si-H I ch3 ch3 1 ch3V. Description of the invention (8) 〇mol / 1000 g. As shown in Table 1. ch3 | cn3. »I ch = ch2 t I ch3 I (3I2 = CH — Si — 0 i 1 -f-Si 〇)-v VI ri 1 -Si — CH = CH-, I. ch3 ch3 tl I 11 ch3 L 1 ch3 Preparation of linear release modifiers from Examples 2 to 6 In the same manner as in Example 1, the linear release modifier was prepared according to the data shown in Table 1. The linear release modifier (sample numbers SS-198 to SS-2 0 2) of the present invention was obtained, and the structure of sample numbers SS-198 to 199 was the same as that of the above-mentioned sample number SS-197, and the sample number SS-2 0 0 To SS2 0 2 has the following structure. Other data are shown in Table 1. ch3 ch3 (1., CH = CH9, I \ ch3 1 H — Si — 〇 1 I Si 〇 V | / m ch3 irSi O-H I / Π -Si-H I ch3 ch3 1 ch3

0424-9069TWF(NK〇2910〇35;pati.icia.ptd 第13頁 584654 五、發明說明（9) 表1 ‘富施例編號 1 2 3 4 5 6 所得樣品號 SS-197 SS-198 SS-199 SS-200 SS-201 SS-202 單體 ω 0.43 0.85 1.29 0.43 0.¾ 1.¾ 1.85 1.¾ 1_部 - - - lvliB - - - 13l· 1.34 134 47.71 4728 46恐 4823 47.80 4737 觸媒 HiSO^ (0.25 wt%) 〇.13g 〇.13g 0.13 g 〇.13g 0.13g 0.13 g 中和鹼 NaHCOi 〇.22g 〇.22g 0.22g 〇.22g 0.22g 0.22g 預設分子量 50CO 50⑴ 50⑴ 5000 50CO 5000 乙烯基含量 (莫耳/1QCO茚 0.1 0.2 0.3 0.1 0.2 0.3 實施例7至1 2 線形離型改質劑之製備如實施例1之相同方法依表2所示之數據進行線形離型改質劑之製備。獲得本發明之線形離型改質劑（樣品編號 SS-143至SS-148)，具有類似樣品編號SS- 2 0 0之結構。其他數據如表2所示。0424-9069TWF (NK〇2910〇35; pati.icia.ptd page 13 584654 V. Description of the invention (9) Table 1 'Rich Example No. 1 2 3 4 5 6 SS-197 SS-198 SS- 199 SS-200 SS-201 SS-202 monomer ω 0.43 0.85 1.29 0.43 0.¾ 1.¾ 1.85 1.¾ 1_part---lvliB---13l · 1.34 134 47.71 4728 46 terror 4823 47.80 4737 catalyst HiSO ^ (0.25 wt%) 〇.13g 〇.13g 0.13 g 〇.13g 0.13g 0.13 g Neutralizing base NaHCOi 〇22g 〇.22g 0.22g 〇.22g 0.22g 0.22g preset molecular weight 50CO 50⑴ 50⑴ 5000 50CO 5000 Vinyl content (Mole / 1QCO indene 0.1 0.2 0.3 0.1 0.2 0.3 Examples 7 to 12 2 Preparation of linear release modifiers The same method as in Example 1 was used to perform the linear release modifiers according to the data shown in Table 2 Preparation. The linear release modifiers of the present invention (sample numbers SS-143 to SS-148) were obtained, having a structure similar to that of sample number SS-2 0 0. Other data are shown in Table 2.

0424-9069TWF(N);0291003 5;pa t ric i a.p t d 第14頁 584654 五、發明說明（ίο) 表20424-9069TWF (N); 0291003 5; pa t ric i a.p t d p. 14 584654 V. Description of the invention (ίο) Table 2

冒施例1 爵號 7 8 9 丄0 11 12 所得樣品纊號 SS-143 SS-144 SS-145 SS-146 SS-147 SS-148 單體 (£) D4Vi 0.22 0.43 0.65 0.66 1.CB 1.29 M2H 1.34- 134 1.34 1.34 1.34 1.34 D4 48.44 4823 48D1 47.80 4758 4737 觸媒 H2S04 (0.25 t % 〇.13g 〇.13g 0.13g 0.13g 〇.13g 〇.13g 中和鹼 NaHCOS 〇.22g 0.22g 0.22g 0.22g 02¾ 預設分子量 5003 50CO 50CO 50⑴ 5003 5〇⑴ 乙晞基含量 (莫耳/10CO克） 0.05 0.10 0.15 023 025 0.JJ 實施例1 3至1 5線形離型改質劑之製備如實施例1之相同方法依表3所示之數據進行線形離型改質劑之製備。獲得本發明之線形離型改質劑（樣品編號 SS-152、SS-153、及SS-158)，具有類似樣品編號SS-200 之結構。其他數據如表3所示。Example 1 No. 7 8 9 丄 0 11 12 Sample No. SS-143 SS-144 SS-145 SS-146 SS-147 SS-148 Monomer (£) D4Vi 0.22 0.43 0.65 0.66 1.CB 1.29 M2H 1.34- 134 1.34 1.34 1.34 1.34 1.34 D4 48.44 4823 48D1 47.80 4758 4737 Catalyst H2S04 (0.25 t% 〇.13g 〇.13g 0.13g 0.13g 〇.13g 〇.13g Neutral base NaHCOS 〇.22g 0.22g 0.22g 0.22g 02¾ Preset molecular weight 5003 50CO 50CO 50⑴ 5003 50⑴ Acetyl content (mole / 10COg) 0.05 0.10 0.15 023 025 0.JJ Example 1 3 to 15 The linear release modifier is prepared as in Example 1 The same method was used to prepare the linear release modifiers according to the data shown in Table 3. The linear release modifiers of the present invention (sample numbers SS-152, SS-153, and SS-158) were obtained with similar samples Structure of No. SS-200. Other data are shown in Table 3.

0424-9069TWF(N);02910035;patncia.ptd 第15頁 584654 五、發明說明（11) ‘5施例編號 13 表3, 14 15 所得之樣品繼號 SS-152 SS-153 SS-158 D4Vi 0.% 1.C80424-9069TWF (N); 02910035; patncia.ptd Page 15 584654 V. Description of the invention (11) '5 Example No. 13 Table 3, 14 15 The sample obtained is followed by SS-152 SS-153 SS-158 D4Vi 0 .% 1.C8

M2H 1.91 3.35 1.91 D4 4723 45.79 471)1 mm 中和鹼 H2S04 (025wt%)M2H 1.91 3.35 1.91 D4 4723 45.79 471) 1 mm neutralizing base H2S04 (025wt%)

NaHC03 預設分子董〇_13g 〇.22g 35⑴ 0.13g 0_13g 0.22g 3500 20⑴ Q2D 0.25 0.33 實施例1 6至2 1 線形離型改質劑之製備如實施例1之相同方法依表4所示之數據進行線形離型改質劑之製備。獲得本發明之線形離型改質劑（樣品編號 SS-2 0 3 至 SS- 2 0 5 及 SS-212 至 SS-214)，樣品編號 SS- 2 0 3 至 SS- 2 0 5具有下列結構：NaHC03 preset molecular 〇_13g 〇.22g 35⑴ 0.13g 0_13g 0.22g 3500 20⑴ Q2D 0.25 0.33 Examples 1 to 2 1 The preparation of the linear release modifier is as shown in Table 4 in the same way as in Example 1 Data were prepared for linear release modifiers. The linear release modifiers of the present invention (sample numbers SS-2 0 3 to SS- 2 0 5 and SS-212 to SS-214) were obtained, and sample numbers SS- 2 0 3 to SS- 2 0 5 had the following structures :

3 H3 H

CH 〇 _H3 C——S1——c 〇 3 I 3 H - H cllsllcl· Ξ2. ο C I H=-H3 CHlsl— cCH 〇 _H3 C——S1——c 〇 3 I 3 H-H cllsllcl · Ξ2. Ο C I H = -H3 CHlsl— c

〇 _H3 H——S1——C ch3\ 1 + ^ — CH=CH./〇 I cr3 樣品編號SS-212至SS-214具有下列結構〇 _H3 H——S1——C ch3 \ 1 + ^ — CH = CH. / 〇 I cr3 Sample numbers SS-212 to SS-214 have the following structure

0424-9069TWF(N);02910035;pat ricia.ptd 第16頁 584654 五、發明說明（12) ch3 CH=CH2 Ph CH^ I ' / 1 \ /丨·\ 1 Si 〇t I /rj r~si 〇f- 1 -n tf V -Si - ch=ch2 □ I 1 1 IJ ch3 [1 1 11 ch3 Ph rJ 1 ch3 CH^0424-9069TWF (N); 02910035; pat ricia.ptd Page 16 584654 V. Description of the invention (12) ch3 CH = CH2 Ph CH ^ I '/ 1 \ / 丨 · \ 1 Si 〇t I / rj r ~ si 〇f- 1 -n tf V -Si-ch = ch2 □ I 1 1 IJ ch3 [1 1 11 ch3 Ph rJ 1 ch3 CH ^

I ch2=ch — 〒一〇 t 孕 ch3 其他數據如表4所示表4 菖施例編號 16 17 18 19 20 2丄所得樣品纊號 SS-203 SS-204 SS-205 SS-212 SS-213 SS-214 單體 (g) D:·， 0.43 0B5 1-¾ 0.43 0.85 129 d^b 3.6 72 10JB - - - Μιν， 1说 1_86 1.86 1.85 1.E6 1.:¾ 44.11 40.08 36.05 4271 4228 4L35 D" - - - 5 5 5 觸媒 HiSO^ f〇_25 丨11¾ 〇.13g 0.13g 〇.13g 0.13 g 0.13 g 中和鹼 NaHC Ch 〇.22g 0.22g 0為〇.22g ()22g 預設分子量 5003 5003 5000 5,0D0 5,⑽ 5,COO 乙烯基含量(莫耳:1003 ® 0.1 02 03 0.1 02 0.3 實施例2 2 離型劑組合物之製造分別依表5所示之量取實施例1至6、1 6至1 8、及1 9至 2 1中所製備之離型改質劑樣品、日本信越化學公司的溶劑型KS- 3 7 0 3離型劑、曱苯、及白金觸媒CAT-PL-50T經曱苯稀釋至1 0 °/◦，置於攪拌器中混合均勻，脫泡完全，製得本I ch2 = ch — 〒一〇t pregnancy ch3 Other data is shown in Table 4 4Example No. 16 17 18 19 20 2 丄 Sample No. SS-203 SS-204 SS-205 SS-212 SS-213 SS-214 monomer (g) D: ·, 0.43 0B5 1-¾ 0.43 0.85 129 d ^ b 3.6 72 10JB---Μν, 1 said 1_86 1.86 1.85 1.E6 1 .: ¾ 44.11 40.08 36.05 4271 4228 4L35 D "---5 5 5 Catalyst HiSO ^ f〇_25 丨 11¾ 〇.13g 0.13g 〇.13g 0.13 g 0.13 g Neutralizing base NaHC Ch 〇22g 0.22g 0 is 0.22g () 22g preset molecular weight 5003 5003 5000 5,0D0 5, ⑽ 5, COO vinyl content (mol: 1003 ® 0.1 02 03 0.1 02 0.3 Example 2 2 Production of a release agent composition was taken in Example 1 according to the amount shown in Table 5 Samples of release modifiers prepared from 6, 16 to 18, and 19 to 21, solvent-based KS-3 7 0 3 release agent from Shin-Etsu Chemical Co., Ltd., toluene, and platinum catalyst CAT-PL-50T is diluted to 10 ° / ◦ with toluene, and placed in a blender to mix evenly.

0424-9069TWF(N);02910035;pat ricia.ptd 第17頁 584654 五、發明說明（13) 發明之離型劑組合物，測定黏度、固含量。評估PET塗佈性。評估標準：佳：成膜性均勻、平整，可：有些地方會收縮，差：呈現波浪狀。評估PET密著性。評估標準：佳：用橡皮擦，擦拭3至 5回合不剝落，可：擦拭1至2回合不剝落，差··擦拭一下馬上剝落。依下列方法測試Tesa 7475標準膠帶剝離力：在離型劑組合物調製好靜置30分鐘後，使用4#線棒（9 /zm)將其塗佈於5〇 #πι之PET膜上，於130± 5°C下烘60 秒，冷卻後過夜。取玻璃片（5 cm X 10 cm X 〇· 2 cm)與 3M雙面膠帶貼合，再與上述製備好的pet離型膜試片貼合，裁切，並與Tesa 7475標準測試膠帶（2. 5 cm X 13 cm)貼合，測試膠帶另一端貼合離型紙條（2. 5 cm X 15 cm)’離型紙條掛拉力勾環，訂書針固定之。使用拉力測试機（機型.美製Adhesion/Release Tester AR-1000(米占著力試驗機））以底座機台牽引速度（1 2英寸/分鐘）進行 T e s a 7 4 7 5標準膠帶剝離力測試。所得結果如表5所示。依下列方法測試X 7 R生胚片產品（G r e e n t a p e )之剝離力：使用4#線棒（9 //m)將其塗佈於50 //in之PET膜上，於 1 3 0 ± 5 C下烘6 0秒’冷卻後過夜。使用4 #線棒在此製好之 P E T離型膜上塗佈X 7 R漿砂，於1 〇〇 ± 5 °C下烘3 0秒，冷卻後過夜。取玻璃片（5 cm X 10 cm X 0.2 cm)舆3M雙面膠帶貼合，再與上述具有X7R生胚的PET離型膜之另一面貼合，0424-9069TWF (N); 02910035; pat ricia.ptd page 17 584654 V. Description of the invention (13) The release agent composition of the invention, the viscosity and solid content were measured. Evaluation of PET coating properties. Evaluation criteria: good: uniform film formation, flat, but: shrinkage in some places, poor: wavy. Assess PET adhesion. Evaluation criteria: Good: Use an eraser to wipe for 3 to 5 rounds without peeling, OK: Wipe for 1 to 2 rounds without peeling, poor ... Wipe it off immediately. Test the peeling force of Tesa 7475 standard tape according to the following method: After the release agent composition is prepared and left for 30 minutes, it is coated on a 5〇 # πι PET film using a 4 # wire rod (9 / zm), and Bake at 130 ± 5 ° C for 60 seconds, and cool overnight. Take a glass sheet (5 cm X 10 cm X 0.2 cm) and 3M double-sided adhesive tape, and then adhere to the prepared pet release film test piece, cut, and use Tesa 7475 standard test tape (2 5 cm X 13 cm), and the other end of the test tape is attached to the release paper strip (2.5 cm X 15 cm). Use a tensile tester (model. American Adhesion / Release Tester AR-1000) to test the peeling force of Tesa 7 4 7 5 standard tape at the base machine traction speed (12 inches / minute). . The results obtained are shown in Table 5. Test the peeling force of the X 7 R green sheet product (G reentape) as follows: Use a 4 # wire rod (9 // m) to coat it on a 50 // in PET film at 1 3 0 ± 5 Bake for 60 seconds at C 'after cooling overnight. Using a 4 # wire rod, apply X 7 R mortar on this prepared P E T release film, bake at 1000 ± 5 ° C for 30 seconds, and cool overnight. Take a glass sheet (5 cm X 10 cm X 0.2 cm) and 3M double-sided tape, and then attach it to the other side of the PET release film with X7R raw embryo,

0424-9069TWF(N);02910035;pati.icia.ptd 1:1： m _ 第18頁 584654 五、發明說明（14) 裁切下玻璃大小的尺寸，X7R生試膠帶（2.5^乂13^)貼合’測%面^：6^7475標準測、门 x 15 em)，離型紙條掛拉力勾環，以訂查i 固定離型紙於拉力勾環上，# j衣以叮曰枝 ΛΗ1η . /D 衣使用拉力測試機（機型：美繫0424-9069TWF (N); 02910035; pati.icia.ptd 1: 1: m _ page 18 584654 V. Description of the invention (14) Cut the glass size, X7R raw test tape (2.5 ^ 乂 13 ^) Fit 'test% surface ^: 6 ^ 7475 standard measurement, door x 15 em), pull the paper to hang the pull hook, to check i Fix the release paper on the pull hook, # j 衣以叮叫枝 ΛΗ1η . / D clothing using tensile testing machine (model: American

Adhesion/Release Tester AR-l〇nn^+J:^,^, " 座機台牽引速度（12英寸/分鐘）$彳7R ^驗機））以底所得結果如表5所示。里)進订爪生胚剝離力測試，實施例2 3離型劑組合物之製造如實施例22之製備方法，但使用以“ 商品SSt-v8V01&sst_H8H01 (分別記為p〇ss_H斑斤。之 poss-vo*別做為本發明之離型改質劑，依表5所示之组成，衣付本發明之離型劑組合物，分別為含3重量％ P0SS-H、6 重量％ p0SS_H、3 重量％ p〇ss_Vi、及6 重量％ p〇ss-vi之離型劑組合物，與對照組（單獨ks_37〇3離型劑）分別依上述方法測得Tesa 7475標準膠帶剝離力及X7R生胚剝離力。實施例24離型劑組合物添加量之試驗將本發明之離型劑改質劑樣品編號ss_143至8§ —148、 SS-152、SS-153、及SS-158如實施例22之方法製備本發明之離型劑組合物，但離型劑改質劑添加量佔矽酮聚合物 (KNS- 3 0 0 2 )之10重量％及2〇重量％，以評估添加量對剝離力之效果。結果如表6所示。Adhesion / Release Tester AR-l0nn ^ + J: ^, ^, " Base table traction speed (12 inches / minute) $ 彳 7R ^ inspection machine)) The results are shown in Table 5. In), the claw raw embryo peeling force test was carried out. Example 2 3 The release agent composition was manufactured as in the method of Example 22, but using "Commercial SSt-v8V01 & sst_H8H01 (respectively referred to as p0ss_H spot weight. The poss-vo * should not be used as the release modifier of the present invention. According to the composition shown in Table 5, the release agent composition of the present invention is composed of 3 wt% P0SS-H and 6 wt% p0SS_H. , 3 wt% p0ss_Vi, and 6 wt% p0ss-vi release agent composition, compared with the control group (ks_37〇3 release agent alone) respectively measured the peeling force of Tesa 7475 standard tape and X7R according to the above method Embryo peeling force. Example 24 Test of Adding Amount of Release Agent Composition The release agent modifier samples of the present invention are numbered ss_143 to 8§ -148, SS-152, SS-153, and SS-158 as implemented The release agent composition of the present invention was prepared by the method of Example 22, but the addition amount of the release agent modifier was 10% by weight and 20% by weight of the silicone polymer (KNS-3002) to evaluate the addition amount. The effect on the peeling force is shown in Table 6.

0424-9069TWF(N);0291003 5;pa t π cia.p t d 第19頁 584654 五、發明說明（15)0424-9069TWF (N); 0291003 5; pa t π cia.p t d page 19 584654 V. Description of the invention (15)

表5 成獅 QM3-6 CS037 削名 CS03-9 剛-10 CS03-11 SS-197 1 9 * 12 1 9 40 1.2 1 9 40 12 1 9 40 12 1 9 40 12 1 9 40 12 SS-1® SS-1® ^-21) SS-3D1 SS-22- KS-3703 "W CAm_'5JT甲荆概駐10¾ 職⑽ 44 45 45 46 45-16 45 7.23 Ί23 7.23 7.23 723 7.23 ?ETmm 佳佳佳佳佳佳 PETS^ 口J 口·] 可口J 口J 口J T 说 7475 纖鐮剝離力 15-ίδ 13-49 124 8-10 7-9 1^28 13^D 14^28 5-7 7^ 7^ 16-36 1^20 11-24 4^-6 74 7〜9 平均偃以!吳寸） 21± 5 17± 3 19± 7 6± 1 7± 1 8± 1 X7R 剝離力 28-32 28-32 27-32 2.7-32 2.7-32 3.「>33 27^3,1 27-32 3况3 27-32 3.0-35 Zi>3D 21 〜32 27-32 2^33 27-32 2..^3,4 平均偃噪或 29± 02 3.Ci 02 2,9+ 0.3 3.0± 0.3 3.Ctt 0,3 3.2± 02 第20頁 0424-9069TWF(N);02910035;pa t r 1 c 1 a · p t d 584654 五、發明說明（16) 表5 (續）離型劑骷合物·' 樣口口纖、成_ \· 91_ _-1 Q903-2 〔£03-3 _-5 SS^D3 0.5 1 SS-2D4 0.5 1 S3-205 0.5 1 KS-JTO3 y.5 y.5 9.5 9 9 9 4.1 4U 40 40 Ci 40 GATH 牛 1.1 1.1 1.1 12 1.2 12. 鹏㈣ 5：ι 3D 3:丨 44 43 43 6.¾ 6.¾ 6..¾ 7,23 7.22： 7.23 PE理纖佳佳佳佳佳佳 PET抱澈主口J 口J 口 J 口J 口J 口J Tesa7475 &〜15 SM6 9-18 12^18 11-18 13-17 wmm 7〜16 1CM7 1CM6 匕18 12-17 13^17 刹離力 &〜16 一 17 1CM7 1W8 1W7 13-48 ^ ±g im ^ 12t 4 13± 4 15t 4 15± 3 1牡3 15± 2 >7R 3.5MD 3·5·42 4.CK5JD 3,^-3B 4.^-5£) 6.S72 生断 3540 3.7-^5 4.5-55 3.^3.7 4.jM3 7.om 剝離力 3.4-3S 3fM3 5·帽 3.^3B 4.^-5D δ.3-73 平埒偃（i裸寸） 3.7± 0,3 4,0± 0.4 5.0± 05泜斷） 3·5± 0·3 4_7± 03(拉 iff) 6少斷（拉斷）Table 5 Chengshi QM3-6 CS037 cut name CS03-9 Gang-10 CS03-11 SS-197 1 9 * 12 1 9 40 1.2 1 9 40 12 1 9 40 12 1 9 40 12 1 9 40 12 SS-1® SS-1® ^ -21) SS-3D1 SS-22- KS-3703 " W CAm_'5JT Jia Jing is stationed at 10¾ position 44 45 45 46 45-16 45 7.23 Ί23 7.23 7.23 723 7.23 ETmm Jiajiajia Jiajiajia PETS ^ mouth J mouth]] delicious J mouth J mouth JT said 7475 fiber sickle peeling force 15-δ 13-49 124 8-10 7-9 1 ^ 28 13 ^ D 14 ^ 28 5-7 7 ^ 7 ^ 16-36 1 ^ 20 11-24 4 ^ -6 74 7 ~ 9 Average 偃! Wu inch) 21 ± 5 17 ± 3 19 ± 7 6 ± 1 7 ± 1 8 ± 1 X7R Peeling force 28-32 28 -32 27-32 2.7-32 2.7-32 3. > 33 27 ^ 3,1 27-32 3case 3 27-32 3.0-35 Zi > 3D 21 〜32 27-32 2 ^ 33 27-32 2 .. ^ 3,4 Average noise or 29 ± 02 3.Ci 02 2,9+ 0.3 3.0 ± 0.3 3.Ctt 0,3 3.2 ± 02 Page 20 0424-9069TWF (N); 02910035; pa tr 1 c 1 a · ptd 584654 5. Description of the invention (16) Table 5 (continued) Skeleton compound of release agent · 'sample mouth fiber, into _ \ · 91_ _-1 Q903-2 〔£ 03-3 _-5 SS ^ D3 0.5 1 SS-2D4 0.5 1 S3-205 0.5 1 KS-JTO3 y.5 y.5 9.5 9 9 9 4.1 4U 40 40 Ci 4 0 GATH Cattle 1.1 1.1 1.1 12 1.2 12. Pengyuan 5: ι 3D 3: 丨 44 43 43 6.¾ 6.¾ 6..¾ 7,23 7.22: 7.23 PE fiberglass Allison Allison Allison PET hug Main mouth J mouth J mouth J mouth J mouth J mouth J Tesa7475 & ~ 15 SM6 9-18 12 ^ 18 11-18 13-17 wmm 7 ~ 16 1CM7 1CM6 18 12-17 13 ^ 17 Brake force & ～ 16 1 17 1CM7 1W8 1W7 13-48 ^ ± g im ^ 12t 4 13 ± 4 15t 4 15 ± 3 1 3 3 ± 2 > 7R 3.5MD 3.5 · 42 4.CK5JD 3, ^-3B 4 . ^-5 £) 6.S72 3540 3.7- ^ 5 4.5-55 3. ^ 3.7 4.jM3 7.om Peeling force 3.4-3S 3fM3 5.Cap 3. ^ 3B 4. ^-5D δ.3 -73 flat 埒偃 (i bare inch) 3.7 ± 0,3 4,0 ± 0.4 5.0 ± 05 泜 break) 3 · 5 ± 0 · 3 4_7 ± 03 (pulling) 6 less breaking (pulling)

0424-9069TWF(N);02910035;pa t r i c i a.ptd 第21頁 584654 五、發明說明（17) 表5繞 Q1C&D2 祕1 (xxm 丨孤3 _4 _-5 —1¾½) 、、'_ SS-22 1 1 SS-213 1 1 SS-214 1 1 KSJ703 9 9 9 KNS-3DD2 9 9 9 40 €ι 40 4 3 3 CATiUT 1.2 1.2 12 12 1.2 12 經— 翻0¾ 43 43 43 43 43 固織％) 7.23 7.23 7.23 6,58 7.04 7.04 ΡΕ_Γ塗爾生口J 口J 口J 割_销）问左向左 PETRIS 口] 口J 口] 差差差 T 说 7475 15-5D 15^3 1^18 3.CMD 3.Μ2 3.S45 wmm 16-20 1543D 13〜18 3.^3 3.5Λ0 3.CM2 剝離力 15^) 16〜19 13 〜18 3.CMD 3AAD 3.CMD 平均値ώ英寸） 18± 2 1S± 2. 16± 2 3,5± 0.5 3.7± 03 3.7± 0.5 X7R 25-25 25^8 13_6 3.5-4D 3.CK35 生断 2㈣ zsas： 2.4^8 3.CK3B 3.MD 32rSb 剝離力 21-30 2.¾¾ 2_从7 3_ϋ 3.0-33 3.CK36 平均偃 2社 02. 26± 02 26± 02 3,3± 0,3 3Ί± 0.3 3.3± 0.30424-9069TWF (N); 02910035; pa trici a.ptd page 21 584654 V. Description of the invention (17) Table 5 around Q1C & D2 Secret 1 (xxm 丨 solitary 3 _4 _-5 —1¾½) ,, '_ SS -22 1 1 SS-213 1 1 SS-214 1 1 KSJ703 9 9 9 KNS-3DD2 9 9 9 40 € 40 4 3 3 CATiUT 1.2 1.2 12 12 1.2 12 Warp-turn 0¾ 43 43 43 43 43 ) 7.23 7.23 7.23 6,58 7.04 7.04 ΡΕ_Γ Tu Ersheng mouth J mouth J mouth J cut_pin) ask left to left PETRIS mouth] mouth J mouth] difference difference difference T say 7475 15-5D 15 ^ 3 1 ^ 18 3 .CMD 3.Μ2 3.S45 wmm 16-20 1543D 13 ~ 18 3. ^ 3 3.5Λ0 3.CM2 peeling force 15 ^) 16 ~ 19 13 ~ 18 3.CMD 3AAD 3.CMD average inch) 18 ± 2 1S ± 2. 16 ± 2 3,5 ± 0.5 3.7 ± 03 3.7 ± 0.5 X7R 25-25 25 ^ 8 13_6 3.5-4D 3.CK35 Break 2㈣ zsas: 2.4 ^ 8 3.CK3B 3.MD 32rSb peeling force 21-30 2.¾¾ 2_from 7 3_ϋ 3.0-33 3.CK36 average 偃 2 company 02. 26 ± 02 26 ± 02 3,3 ± 0,3 3Ί ± 0.3 3.3 ± 0.3

0424-9069TWF(N);0291003 5;pa t ricia.p t d 第22頁 584654 五、發明說明（18) 表5(牵壹餓舰〜 CgCE-12 (Pm3 CK2-10 ©3241 KS3T8 (sm POSS-Vi 03 06 POSS^ 03 〇β KSOT 9.7 9.4 9.7 9.4 5 瞒 40 40 C丨 40 24 CAT-PL53T 甲 Π Π 11 丄1 05 黏廒CPS) 3〕 53 51 42 δΘ9 628 67 5ββ PE.T 塗佳佳佳 ΡΕΤ^Μ 可可可可侄 Tea7475 5-7 6^8 9-12 9-12 14〜 17 纖觀 5^7 ⑽ 9-12 9U3 1346 剝離力 5-7 9-12 1043 12〜 15 mi 5-7 9^J2 9-13 13^6 X7R 3^5ΰ 65-lfr 2S^3D 25-30 32^5 mm 杀儺力 40^5ΰ e^m 25^30 24-29 30>35 42-52 65屬 2^30 25-30 2^35 tn 451： 0.7 ^6,5 25-3D 25-30 32t 030424-9069TWF (N); 0291003 5; pa t ricia.ptd Page 22 584654 V. Description of the invention (18) Table 5 (Diamond ship ~ CgCE-12 (Pm3 CK2-10 © 3241 KS3T8 (sm POSS-Vi 03 06 POSS ^ 03 〇β KSOT 9.7 9.4 9.7 9.4 5 Concealment 40 40 C 丨 40 24 CAT-PL53T A Π Π 11 丄 1 05 Adhesive CPS) 3] 53 51 42 δΘ9 628 67 5ββ PE.T Tu Jiajia Jia ΡΕΤ ^ Μ Cocoa Cocoa Nea Tea7475 5-7 6 ^ 8 9-12 9-12 14 ~ 17 Fiberview 5 ^ 7 ⑽ 9-12 9U3 1346 Peeling force 5-7 9-12 1043 12 ~ 15 mi 5-7 9 ^ J2 9-13 13 ^ 6 X7R 3 ^ 5ΰ 65-lfr 2S ^ 3D 25-30 32 ^ 5 mm killing force 40 ^ 5ΰ e ^ m 25 ^ 30 24-29 30 > 35 42-52 65 genera 2 ^ 30 25-30 2 ^ 35 tn 451: 0.7 ^ 6,5 25-3D 25-30 32t 03

0424-9069TWF(N);02910035;pa t ric i a. p t d 第23頁 584654 五、發明說明（19) 表6 遍1¾ mm 10 wt% 旅加⑷wt% 生肚斤 X7K生肚斤剝離刀平巧偃(.e/m) 剝雛刀平巧 SS-143 分子量約500D 0.05切®乙烯基 2,1-24 1.7 〜20 M-144 分子量約50CO 乙烯基 2.1^23 1_8 〜21 SS-145 分子量約500D 0.15L乙烯墓 2.5-2.9 1,8-21 SS-146 分子量約500D 0.2. ψΐ：®乙嫌基 2.1-Z4 1.7〜20 SS-147 分子童約50CO 0.25\vt®乙烯基 2.0-24 1.8 〜21 SS-148 分子量約印CC 0.3 v⑽乙備墓 2.4-28 2,1-23 KNS-3002 (MM) ϋ _ S〜.1 · 0 目製離型調控劑 Tesa 7475胳滞剝離 )(¾生胜剝離力丨 ^ 剝離刀平均im(Mn) 剝離刀平巧iltte/m) SS-152 分子量約3500 0.：2奶％乙嫌基 2.5 〜4.6 1,7-20 SS-153 分汙量約350D 0.25奶$2烯墓 2.5-4.5 1.7-20 SS-158 分子星約2ΰ(Χ) 0.2ψι：Φ2 稀基 2.6-4,9 1.8-20 由上列實施例及對應之各表數據可知，針對溶劑型加成型矽酮聚合物之離型劑組成（如K S- 3 7 0 3系列）： CH> CH^ CH=CHi CH20424-9069TWF (N); 02910035; pa t ric i a. Ptd page 23 584654 V. Description of the invention (19) Table 6 Pass 1¾ mm 10 wt% Travel Canada ⑷wt% Raw belly weight X7K Raw belly weight stripping knife偃 (.e / m) Peeler Knife Flatly SS-143 Molecular weight approximately 500D 0.05 Cut® Vinyl 2,1-24 1.7 ～ 20 M-144 Molecular weight approximately 50CO Vinyl 2.1 ^ 23 1_8 ～ 21 SS-145 Molecular weight approximately 500D 0.15L ethylene grave 2.5-2.9 1,8-21 SS-146 molecular weight about 500D 0.2. Ψΐ: ® ethyl ether 2.1-Z4 1.7 ~ 20 SS-147 molecular child about 50CO 0.25 \ vt® vinyl 2.0-24 1.8 ～ 21 SS-148 Molecular weight approx. CC 0.3 v ⑽Ebei Tomb 2.4-28 2,1-23 KNS-3002 (MM) ϋ _ S ~ .1 · 0 Mesh release control agent Tesa 7475 (stretching and peeling) (¾ Shengsheng peeling force 丨 ^ average stripping knife im (Mn) stripping knife (brightly iltte / m) SS-152 molecular weight about 3500 0 .: 2 milk% ethyl ethyl 2.5 ~ 4.6 1, 7-20 SS-153 pollution amount About 350D 0.25 milk $ 2 ene grave 2.5-4.5 1.7-20 SS-158 molecular star about 2ΰ (χ) 0.2ψι: Φ2 dilute radical 2.64,9 1.8-20 According to the above examples and the corresponding table data, Release agent composition for solvent-based addition-type silicone polymers (such as K S-370 3 series): CH > CH ^ CH = CHi CH2

I / I w丨、丨I CH-^CH 一 Si 一〇 x Si — 〇 -j~Si — 〇 -j— Si — CH-C^ (1 )離型改質劑具有 CH, 結構者，對標準膠帶會提高其剝離力，但是對X7R生胚反而會降低I / I w 丨, 丨 I CH- ^ CH-Si-〇x Si — 〇-j ~ Si — 〇-j— Si — CH-C ^ (1) The release modifier has a CH, structure. Standard tape will increase its peeling force, but will decrease the X7R raw embryo

第24頁 0424-9069TWF(N);02910035;patricia.ptd 584654 五、發明說明（20) 其剝離力（與KS- 3 7 0 3對照例比較）。 CH〕 CH] H— Si—〇 -f-Si —ΟΙ ·' I CH, CH, (2 )離型改質劑具有 c!h3 · h " &η3 ch^ 結構者，對標準膠帶會明顯降低其剝離力，而對X7R生胚而言影響不顯著0 1:¾ CH. CH=CH-i Pl-L CH^ (3 )離型改質劑具有 =ch - f -。ί f -。tH 卜。t(卜。tf- 0¾ CH^ CH, Pl-L CHi 結構者，對標準膠帶略微提高其剝離力，但是對X7R生胚則很明顯降低其剝離力。Page 24 0424-9069TWF (N); 02910035; patricia.ptd 584654 V. Description of the invention (20) Peeling force (compared with KS-37.03 comparative example). CH] CH] H—Si—〇-f-Si —ΟΙ · 'I CH, CH, (2) The release modifier has a c! H3 · h " & η3 ch ^ structure. The peeling force is significantly reduced, but the effect on the X7R embryo is not significant. 0 1: ¾ CH. CH = CH-i Pl-L CH ^ (3) The release modifier has = ch-f-. ί f-. tH Bu. t (bu. tf- 0¾ CH ^ CH, Pl-L CHi structure, the peeling force is slightly increased for the standard tape, but it is significantly reduced for the X7R raw embryo.

,=CH CH=CHi Η (4 )離型改質劑具有 ~r0if~0t^r0Wf'0)；rCH=c^ CHj. CH^ CH> CHj 結構者，對標準膠帶而言無顯著影響，但是對X7R生胚而言，很明顯的提高其剝離力，隨其添加量之增加而明顯增加。 (5) 離型改質劑具有籠形結構的P0SS-H者，對標準膠帶顯著的降低其剝離力（與K S - 3 7 0 3對照例比較）；而對X 7 R生胚而言，顯著的提高其剝離力；隨著添加量增加時，標準膠帶之剝離力些微增加，但仍比KS-3 7 0 3對照例低許多；X7R 生胚亦顯著增加。 (6) 離型改質劑具有籠形結構的POSS-Vi者，對標準膠帶而言，略微降低其剝離力；而對X7R生胚而言，顯著的降低其剝離力；隨著添加量增加時，改變不顯著。, = CH CH = CHi Η (4) The release modifier has ~ r0if ~ 0t ^ r0Wf'0); rCH = c ^ CHj. CH ^ CH > CHj structure has no significant effect on the standard tape, but For X7R raw embryos, the peeling force is obviously improved, and it increases obviously with the increase of the added amount. (5) The POS-H with a cage structure of the release modifier has a significantly reduced peeling force (compared to the KS-3 0 7 control) for the standard tape; and for the X 7 R embryo, Significantly improved its peeling force; as the amount of addition increased, the peeling force of the standard tape slightly increased, but still much lower than that of the KS-3 703 control; the X7R embryos also increased significantly. (6) POSS-Vi with a cage structure for the release modifier has a slightly reduced peeling force for standard tapes; and significantly reduces its peeling force for X7R raw embryos; as the amount is increased Over time, the changes were not significant.

0424-9069T\VF(N) ;02910035;pat ricia.ptd 第25頁 584654 五、發明說明（21) 另者，針對非溶劑型加成型碎酮聚合物之離型劑組成（如 KNS- 3 0 0 2 系歹ij)： ce2 ch3 ch=ch, ce20424-9069T \ VF (N); 02910035; pat ricia.ptd page 25 584654 V. Description of the invention (21) In addition, it is a release agent composition for non-solvent type addition crushed ketone polymer (such as KNS-3 0 0 2 歹 ij): ce2 ch3 ch = ch, ce2

H — Si — 0 十Si - O ~j~(~Si - 0 —Si -H (1 )離型改質劑具有 & ’ Ϊη3 -CH, CH: 結構者，會顯著提高其X7R生胚的剝離力；但是添加量增加時，會降低 X7R生胚的剝離力，但比原來KNS- 3 0 0 2還是高一些；分子量在2 5 0 0至5 0 0 0附近的離型改質劑對X7R生胚的剝離力影響不太顯著。 CH2 CH 上 CH=CH·,, Ph CH 上 CH,,=CH — Si— 〇 -f-Si — 〇 -j—I- Si — 〇 j~Si ~ 0 CH=CHi (2)離型改質劑具有 1PCH, 結構者’顯者提南X 7 R生胚的剝離力。綜合上述之實驗結果，本發明透過離型改質劑的微細結構調整，達到所需要的X7R生胚或標準膠帶所需要的離型力，這與先前技術全然不同，具有創新性與實用性。雖然本發明已以較佳實施例揭露如上，然其並非用以限定本發明。任何熟習此技藝者，在不脫離本發明之精神和範圍内，當可作些許之更動與潤飾。因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。H — Si — 0 Ten Si-O ~ j ~ (~ Si-0 —Si -H (1) release modifier has & 'Ϊη3 -CH, CH: structure, will significantly increase its X7R embryo Peeling force; but when the amount is increased, the peeling force of X7R raw embryo will be reduced, but it is still higher than the original KNS- 3 0 2; the release modifier pair with molecular weight around 2 500 to 5 0 0 The effect of the peeling force of X7R raw embryos is not significant. CH = CH on CH2 CH =, CH on CH ,, = CH — Si— 〇-f-Si — 〇-j—I- Si — 〇j ~ Si ~ 0 CH = CHi (2) The release modifier has 1PCH, the peeling force of the structure of 'significant Tiuman X 7 R' embryo. Based on the above experimental results, the present invention adjusts the fine structure of the release modifier, To achieve the required release force of the X7R raw embryo or standard tape, which is completely different from the previous technology, it is innovative and practical. Although the present invention has been disclosed as above with preferred embodiments, it is not intended to limit the present invention. Invention. Any person skilled in the art can make some modifications and retouching without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention should be attached as follows The ones defined in the scope of patent application shall prevail.

0424-9069TWF(N);02910035;patricia.ptd 第26頁 584654 圖式簡單說明 0424-9069TWF(N);02910035;f)atricia.ptd 第 27 頁0424-9069TWF (N); 02910035; patricia.ptd page 26 584654 Simple explanation of the diagram 0424-9069TWF (N); 02910035; f) atricia.ptd page 27

Claims

584654 六、申請專利範圍 1 · 一種離型劑組合物，係由包括下列之成分混合而成： (a) 2〜10 wt%之石夕_聚合物（silicone polymer)加成型離型劑’其具有Si-Η及Si -乙烯基（Si-H / Si -乙稀基之莫耳比在1 · 2〜4 · 8之間），分子量在1 〇〇，〇〇〇至1，〇〇〇，〇〇〇之間， (b) 0. 5〜30 wt%以成分（a)之重量為準之離型改質劑，其是具有線形或籠形結構之；δ夕酮（s i 1 i c ο n e )化合物， (c) 50〜500 ppm (以成分（a)之重量為準）之觸媒，其是擇自石夕氫加成（hydrosilylation)反應用之觸媒，及 (d) 餘量為溶劑，其是擇自矽酮聚合物的適合溶劑。 2 ·如申請專利範圍第1項所述之離型劑組合物，其中該矽酮離型改質劑為具有下列線形之分子結構之矽酮化合物： $ Ri 1¾ 1¾ Ri I I I I Γ I I I I I I I584654 VI. Scope of patent application 1 · A release agent composition, which is composed of the following components: (a) 2 ~ 10 wt% of silicon polymer_mold (silicone polymer) addition release agent 'its It has Si-fluorene and Si-vinyl (Si-H / Si-ethylene has a molar ratio of 1.2 to 4 and 8) and a molecular weight of 10,000 to 1,000. 〇〇〇〇, (b) 0. 5 ~ 30 wt% based on the weight of the component (a) of the release modifier, which has a linear or cage structure; δ Xione (si 1 ic ο ne) compound, (c) a catalyst of 50 to 500 ppm (based on the weight of component (a)), which is a catalyst selected from the hydrosilylation reaction of Shi Xi, and (d) the rest The amount is a solvent, which is a suitable solvent selected from a silicone polymer. 2. The release agent composition according to item 1 of the scope of the patent application, wherein the silicone release modifier is a silicone compound having the following linear molecular structure: $ Ri 1¾ 1¾ Ri I I I I I Γ I I I I I I I

^ ^ Ki R；其中h是(^_3烧基，R2是氫原子、（^_3 ：)：完基、或Ch。稀烧基； R3為Ch烷基或苯基；該化合物之分子量在3, 500〜30, 000之間，（-SKIOCMO-)m 部份佔 60 〜95 %，（-SiUdUdO-), 部份佔0〜1 0 %，（ - S i ( R! ) ( r2 ) 〇 —)。部份佔〇〜1 〇 %，及 (-Si(R3)(R3)0-)p部份佔〇〜1〇 %，以該化合物之分子量計。^ Ki R; where h is (^ _3 alkyl group, R2 is hydrogen atom, (^ _3 :): end group, or Ch. Dilute group; R3 is Ch alkyl or phenyl group; molecular weight of the compound is 3 Between 500 ~ 30, 000, (-SKIOCMO-) m part accounts for 60 ~ 95%, (-SiUdUdO-), part accounts for 0 ~ 10%, (-S i (R!) (R2) 〇 —). The part accounts for 0 ~ 10%, and the (-Si (R3) (R3) 0-) p part accounts for 0 ~ 10%, based on the molecular weight of the compound.

0424-9069TWF(N);02910035;pat ricia.ptd 第28頁 584654 六、申請專利範圍 3. 如申請專利範圍第1項所述之離型劑組合物，其中該矽酮聚合物之分子量在1 0 0，0 0 0〜7 0 0，0 0 0之間。 4. 如申請專利範圍第2項所述之離型劑組合物，其中 &為甲烷基。 5. 如申請專利範圍第2項所述之離型劑組合物，其中 R2為氫原子、乙烯基、或曱烷基。 6:如申請專利範圍第2項所述之離型劑組合物，其中匕為曱烧基或苯基。 7. 如申請專利範圍第2項所述之離型劑組合物，其中 (-SiUiKRJO-),部份佔 85 〜95 %，（-SidKRdO-X 部份佔 0〜5 %，（-Si^KR^O-)。部份佔 0〜5 %，及（-Si(R3)(R3) 〇 -）p部份佔〇〜5 %，以該石夕酮化合物之分子量計。 8. 如申請專利範圍第1項所述之離型劑組合物，其中該矽酮離型改質劑為具有下列籠形之分子結構之化合物： ((R4)SiOL5)q (II) 其中，R4是氫原子或C2_1()烯烷基，及q為8〜16之整數。 9. 如申請專利範圍第8項所述之離型劑組合物，其中 R4為氫原子或乙烯基。 1 0.如申請專利範圍第1項所述之離型劑組合物，其中該溶劑是擇自甲苯、正庚烷、曱基乙基酮、及其組合所組成之組群。 11.如申請專利範圍第1項所述之離型劑組合物，進一步包括抑制劑。 1 2.如申請專利範圍第1項所述之離型劑組合物，進一0424-9069TWF (N); 02910035; pat ricia.ptd page 28 584654 VI. Patent application scope 3. The release agent composition as described in the first patent application scope item 1, wherein the molecular weight of the silicone polymer is 1 0 0, 0 0 0 to 7 0 0, 0 0 0. 4. The release agent composition as described in item 2 of the scope of patent application, wherein & is a methyl group. 5. The release agent composition according to item 2 of the scope of the patent application, wherein R2 is a hydrogen atom, a vinyl group, or a fluorenyl group. 6: The release agent composition as described in item 2 of the scope of the application for a patent, wherein the dagger is fluorenyl or phenyl. 7. The release agent composition described in item 2 of the scope of the patent application, wherein (-SiUiKRJO-), a portion of which accounts for 85 to 95%, (-SidKRdO-X, a portion of which accounts for 0 to 5%, (-Si ^ KR ^ O-). The part accounts for 0 ~ 5%, and the (-Si (R3) (R3) 0-) p part accounts for 0 ~ 5%, based on the molecular weight of the lithone compound. 8. If applied The release agent composition according to item 1 of the patent scope, wherein the silicone release modifier is a compound having the following cage-shaped molecular structure: ((R4) SiOL5) q (II) wherein R4 is a hydrogen atom Or C2_1 () alkenyl, and q is an integer from 8 to 16. 9. The release agent composition as described in item 8 of the scope of patent application, wherein R4 is a hydrogen atom or a vinyl group. 1 0. As a patent application The release agent composition according to item 1 in the scope, wherein the solvent is a group selected from the group consisting of toluene, n-heptane, fluorenyl ethyl ketone, and combinations thereof. The release agent composition further includes an inhibitor. 1 2. The release agent composition described in item 1 of the patent application scope, further

0424-9069TWF(N);02910035;pat ricia.ptd 第29頁 584654 六、申請專利範圍 --- 步包括微細粒子。 1 3 · —種離型劑組合物，係由包括下列之成分混合而成： (a )含有2至1 0 w t %之矽酮聚合物之市售加成型以矽酮聚合物為主之離型劑組成配方，及 (b) 0· 5至30 wt %訝矽酮聚合物之重量為準之離型改質劑’是具有線型或蘢形結構之矽_化合物。 1 4 ·如申晴專利範圍第1 3項所述之離型劑組合物，其中該市售加成型以矽酮聚合物為主之離型劑組成配方是擇自日本信越化學公司的溶劑型KS — 3 7 0 3系列、法國R〇dia公司的7 4 6 0 p e X糸列、日本信越化學公司的非溶劑型 KNS- 3 0 0 2系列、及其組合所組成組群。 1 5 ·如申請專利範圍第1 3項所述之離型劑組合物，其中該離型改質劑為具有下列線形之分子結構之矽酮化合物： Ri R2 Po 1¾ Ri I I I I I I R24—〇(S卜〇¥&—〇妙—〇賢〇)^民 I I I I I I (i) E-i 其中R!是(^_3烧基；R2是氫原子、Cu烧基、或C2_1Q烯:I：完基； Rs為Ch烷基或苯基；該化合物之分子量在3，5 0 0〜3 0，〇〇〇之間；（-SidKRJO-X 部份佔95〜60%，（-SidKRjO-)n 部份佔0〜10%，（-Si (!〇(&)0-)。部份佔0〜10%，及0424-9069TWF (N); 02910035; pat ricia.ptd page 29 584654 VI. Patent application scope --- The steps include fine particles. 1 3 · — A release agent composition, which is a mixture of the following components: (a) A commercially available addition of silicone polymer containing 2 to 10 wt% of a silicone polymer-based release agent The formulation composition of the molding agent, and (b) 0.5 to 30 wt% of the silicone polymer based on the weight of the release modifier is a silicon compound with a linear or 茏 -shaped structure. 1 4 · The release agent composition as described in item 13 of the patent scope of Shen Qing, wherein the commercially available addition-molded silicone polymer-based release agent is composed of a solvent type selected from Shin-Etsu Chemical Co., Ltd. KS — Group of 3 7 0 3 series, 7 4 6 0 pe X line of French Rodia Company, non-solvent KNS-3 0 2 series of Shin-Etsu Chemical Co., Ltd., and combinations thereof. 1 5 · The release agent composition as described in item 13 of the scope of patent application, wherein the release modifier is a silicone compound having the following linear molecular structure: Ri R2 Po 1¾ Ri IIIIII R24—〇 (S Bu 〇 & —〇妙 —〇贤〇) ^ IIIIII (i) Ei where R! Is (^ _3 alkyl; R2 is a hydrogen atom, Cu alkyl, or C2_1Qene: I: end group; Rs is Ch alkyl or phenyl; the molecular weight of this compound is between 3,500 and 3,000,000; (-SidKRJO-X part accounts for 95 ~ 60%, (-SidKRjO-) n part accounts for 0 ~ 10%, (-Si (! 〇 (&) 0-). The portion accounts for 0 ~ 10%, and

0424-9069TWF(N);02910035;pa t ric i a.ptd 第30頁 584654 六、申請專利範圍 (-Si(R3)(R3)0-)p部份佔0〜10%，以該化合物之分子量計。 1 6.如申請專利範圍第1 5項所述之離型劑組合物，其中&為甲烷基。 1 7.如申請專利範圍第1 5項所述之離型劑組合物，其中匕為氫原子、乙烯基、或曱烷基。 1 8.如申請專利範圍第1 5項所述之離型劑組合物，其中:R3為曱烷基或苯基。 1 9.如申請專利範圍第1 3項所述之離型劑組合物，其中該矽酮聚合物之分子量在1 0 0，0 0 0〜7 0 0，0 0 0之間。 2 0.如申請專利範圍第1 5項所述之離型劑組合物，其中（-3:1(1〇(1^1)〇-）„1部份佔85〜95%，（-3：[(1〇(心）0-),部份佔 0〜5 %，（-Si (&)(&)0-)◦部份佔 0〜5 %，及（-Si (R3) (R3) Ο - )p部份佔0〜5 %，以該石夕_化合物之分子量計。 2 1.如申請專利範圍第1 3項所述之離型劑組合物，其中該離型改質劑為具有下列籠形之分子結構之矽酮化合物： ((R4)Si01.5)q (II) 其中，R4是氫原子或C2_1Q烯烷基，q為8〜16之整數。 2 2.如申請專利範圍第2 1項所述之離型劑組合物，其中R4為氫原子或乙烯基。 2 3.如申請專利範圍第1 3項所述之離型劑組合物，進一步包括抑制劑。 2 4.如申請專利範圍第1 3項所述之離型劑組合物，進一步包括有機溶劑。0424-9069TWF (N); 02910035; pa t ric i a.ptd page 30 584654 VI. Patent application scope (-Si (R3) (R3) 0-) p part accounts for 0 ~ 10%. Molecular weight meter. 16. The release agent composition according to item 15 of the scope of the patent application, wherein & is a methyl group. 17. The release agent composition according to item 15 of the scope of the patent application, wherein the dagger is a hydrogen atom, a vinyl group, or a fluorenyl group. 1 8. The release agent composition as described in item 15 of the scope of patent application, wherein: R3 is fluorenyl or phenyl. 19. The release agent composition as described in item 13 of the scope of the patent application, wherein the molecular weight of the silicone polymer is between 1 0, 0 0 0 to 7 0 0, 0 0 0. 2 0. The release agent composition as described in item 15 of the scope of patent application, wherein (-3: 1 (1〇 (1 ^ 1) 〇-) „1 part accounts for 85 ~ 95%, (-3 : [(1〇 (心) 0-), part of 0 ~ 5%, (-Si (&) (&) 0-) ◦ part of 0 ~ 5%, and (-Si (R3) (R3) 〇-) p part occupies 0 to 5%, based on the molecular weight of the Shi Xi _ compound. 2 1. The release agent composition as described in item 13 of the scope of patent application, wherein the release modification The agent is a silicone compound having the following cage-shaped molecular structure: ((R4) Si01.5) q (II) where R4 is a hydrogen atom or a C2_1Q alkenyl group, and q is an integer from 8 to 16. 2 2. The release agent composition according to item 21 of the patent application, wherein R4 is a hydrogen atom or a vinyl group. 2 3. The release agent composition according to item 13 of the patent application, further including an inhibitor. 2 4. The release agent composition according to item 13 of the scope of patent application, further comprising an organic solvent.

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