TW573062B

TW573062B - Surface-treated metal sheets with excellent press galling resistance and handleability, and process for their manufacture

Info

Publication number: TW573062B
Application number: TW91100807A
Authority: TW
Inventors: Kengo Yoshida; Atsushi Morishita; Yujiro Miyauchi; Akira Takahashi
Original assignee: Nippon Steel Corp
Priority date: 2001-01-19
Filing date: 2002-01-18
Publication date: 2004-01-21
Also published as: MY128667A; CN1276995C; WO2002057510A1; CN1488010A; KR20030077580A; KR100543157B1; KR20050105288A

Abstract

Surface-treated metal sheets comprising 0.3-5.0 g/m<2> of a film formed from an aqueous organic/inorganic compound paint containing (1) a polyolefin wax dispersion with a molecular weight of 6000-15,000 or (2) a polyolefin wax dispersion with a molecular weight of 6000-15,000 (A) and a polyolefin wax dispersion (B) with a molecular weight of 1000-5000, with 5-35 wt% of colloidal silica in terms of solid content. Also, surface-treated metal sheets having, as a first layer, an aqueous organic/inorganic compound film containing a polyolefin wax dispersion with a molecular weight of 6000-15,000, at a dry weight of 0.05-0.3 g/m<2>, and as a second layer, an aqueous organic/inorganic compound film containing 5-35 wt% of colloidal silica in terms of solid content, at a dry weight of 0.5-5.0 g/m<2>. There are also provided an aqueous organic/inorganic compound paint and a manufacturing process, which allow manufacture of such surface-treated metal sheets.

Description

^3062 A7 " ------------B7 ____ 五、發明說明（) 本發明係有關於一種適用於汽車、家電、建材製品等，且不僅耐蝕性、黏附性及可焊性等各種性能倶佳，並具優異耐壓磨損性與耐線圈變形性之表面處理金屬板及其製造方法，以及，有關於一種可製得該表面處理金屬板之水性有機無機複合塗料。本發明並有關於一種亦適用於汽車、家電、建材製品等，且耐蝕性、黏附性及可焊性等各種性能倶佳，並具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板及其製造方法，以及，有關於一種可製造該表面處理金屬板之水性有機無機複合塗料。本發明更有關於一種表面處理金屬板及其製造方法，其亦適用於汽車、家電、建材製品等，且耐蝕性、黏附性及可焊性等各種性能倶佳，並可維持耐壓磨損性及改善捲繞鬆弛所致之線圈毀壞或條狀板材打樁時之負載崩潰等問題，進而可抑制於壓製時潤滑劑自覆膜脫落而引起之黏稠性殘渣之產生。目前已開發電解鋅系鍍鋅鋼板或熱浸鍍鋅系鋼板等表面處理鋼板，並廣泛運用於家電、建材、及汽車零件等用途上。又’该專鋼板為了提高耐钱性及塗裝黏附性之目的而大多施有鉻酸鹽處理或磷酸鹽處理等。更’近來因節省程序、節省成本之觀點而使無塗裝直接應用者逐漸增加，特別是於家電業界中，且不僅止於耐姓性或塗裝黏附性，對耐磨損性、耐指紋性、耐凝結不均性等鋼板表面外觀等級之性能要求層級也益發提高。 (請先閱讀背面之注意事項再填寫本頁) > 裝--------訂— 經濟部智慧財產局員工消費合作社印製^ 3062 A7 " ------------ B7 ____ V. Description of the invention () The invention relates to a kind of products suitable for automobiles, home appliances, building materials, etc., and not only has corrosion resistance, adhesion and A surface-treated metal plate having various properties such as good solderability, excellent pressure wear resistance and coil deformation resistance, and a method for manufacturing the same, and an aqueous organic-inorganic composite coating capable of preparing the surface-treated metal plate. The invention also relates to a surface-treated metal plate which is also suitable for automobiles, home appliances, building materials, etc., and has various properties such as corrosion resistance, adhesion and weldability, and has excellent pressure wear resistance and continuous sliding wear resistance. The invention relates to a water-based organic-inorganic composite coating capable of manufacturing the surface-treated metal plate, a manufacturing method thereof, and the like. The invention further relates to a surface-treated metal plate and a manufacturing method thereof, which is also applicable to automobiles, home appliances, building materials, and the like, and has various properties such as corrosion resistance, adhesion, and solderability, and can maintain pressure resistance and wear resistance. It can improve the problems such as coil damage caused by winding slack or load collapse during piling of strip-shaped boards, and can suppress the generation of viscous residues caused by the lubricant falling off the film during pressing. Currently, surface-treated steel sheets such as electrolytic zinc-based galvanized steel sheets or hot-dip galvanized steel sheets have been developed and widely used in home appliances, building materials, and automotive parts. In addition, the special steel sheet is often subjected to a chromate treatment or a phosphate treatment for the purpose of improving money resistance and coating adhesion. More recently, due to the point of view of saving procedures and cost, direct application of non-painting has gradually increased, especially in the home appliance industry, and not only endurance resistance or coating adhesion, wear resistance, fingerprint resistance The performance requirements of the surface appearance grades of steel plates, such as properties such as resistance to condensation and unevenness, have also increased. (Please read the precautions on the back before filling out this page) > Packing -------- Order—Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

-4- 573062 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（為因應此般需求者之性能需求，乃開發一種於業經鉻酸鹽處理之鍍鋅鋼板上形成有以特殊樹脂為基底之有機複合覆膜的塗裝金屬板。舉例言之，於日本特許公告公報特公平4 一 14191號中已揭示有一種表面處理鋼板之製造方法，其係使鉻酸鹽敷層鍍鋅鋼板上形成一於水系有機樹脂上追加調整有特定微細粒度之溶膠的有機複合覆膜，並可達到提升耐蝕性、耐指紋性等性能之效果者。曰本特許公開公報特開平3一39485號所揭示者係，於鋅系之鍍鋅鋼板上施以鉻酸鹽處理後，塗附一種於水性樹脂中分散有二氧化矽與玻璃轉移點（以點）在4〇它以上之蠟，且乾態質量為〇.3g/m2〜3.0g/m2之塗料者。又，日本特許公開公報特開平3 — 2838〇號所揭示者為一種潤滑鋼板，係於電解鋅鍍鋅鋼板上施以鉻酸鹽處理後，塗附有由業經羧化之聚乙烯樹脂與特氟隆（商標）潤滑劑構成，且乾態質量為〇.5g/m2〜4.0g/m2之塗料者。進而，如深拉加工性，為因應需要嚴格耐磨損性之需求者之要求，則開發有一種於有機覆膜中添加固態潤滑劑而使潤滑性提高之表面處理鋼板。舉例言之，日本特許公開公報特開平6_ 173〇37號所揭示者即一種具有潤滑覆膜之鋼板，該潤滑覆膜係於醚· 酉曰型胺基甲酸乙酯樹脂與環氧樹脂中添加有二氧化石夕與聚烯烴蠟者。日本特許公告公報4一 14191號所揭示之技術係一種耐蝕性、塗裝黏附性、耐指紋性及耐凝結性等性能平衡優良者’且現在亦被作為家電類之主力商品之一。然而，縱使本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 7—.!裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) -5- 573062 經濟部智慧財產局員工消費合作社印製 A7 五、發明說明（、於此種塗附有有機覆膜之表面處理鋼板上，有時仍會產生處理時之損傷，加壓加工時之磨損，或製品輸送時之磨耗 (擦傷）等。相對於此’日本特許公開公報特開平3 — 39485號及特開平3 — 28380號所揭示之技術則難以產生前述所示之加壓加工時之磨損或磨耗，再如特開平6一173〇37號所揭示之技術，縱使於如深拉加工性般嚴格之加工中仍具有優異之耐壓磨4貝性。然而，以曰本特許公開公報特開平3 一 3 9 4 8 5號、特開平3 — 28380號及特開平6— 173037號所揭示之技術等製造之鋼板表面卻形成易於滑動、繞捲鬆弛以致線圈毀壞，或條狀板材打樁時之負載崩潰等問題。因此，現在為避免該等問題，乃施行增加帶數等對策，以提高線圈捲繞時之張力，並防止包裝後之線圈產生捲繞鬆弛現象。本發明之第1主要目的即在於提供一種耐蝕性、黏附性、可焊性等各種性能倶佳，且可維持耐壓磨損性並改善捲繞鬆弛所致之線圈毀壞或條狀板材打樁時之負載崩潰等問越之表面處理金屬板與其製造方法，及一種可製造該表面處理金屬板之水性有機無機複合塗料。本發明之第2主要目的係在於提供一種耐蝕性、黏附性、可焊性等各種性能倶#，且具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板與其製造方法，及一種可製造該表面處理金屬板之水性有機無機複合塗料。本發明之第3主要目的則在於提供一種耐蝕性、黏附性、可焊性等各種性能倶#，且可維持耐壓磨損性並改善 ^紙張尺度適用中國國豕標準（CNS)A4規格（210 X 297公爱 -----------裝--------訂--------- > 、 (請先閱讀背面之注意事項再填寫本頁) -6- 573062 A7 B7 五、發明說明（捲繞鬆弛所致之線圈毀壞或條狀板材打樁時之負載崩潰等問題’進而可抑制於壓製時潤滑劑自覆膜脫落而引起黏祠性殘渣產生之表面處理金屬板與其製造方法。本t明人荨為達成前述第1目的而進行種種檢討後之結果則發現’藉由將包含有分子量在6000〜15000範圍内之 ?«烴壤分散體與適量之膠體二氧化⑦之水性有機無機複合塗料塗布於鍍金屬板上，經乾燥後形成水性有機無機複合覆膜，則可製得一種不僅耐蝕性、黏附性及可焊性等各種性能倶佳，且控制金屬板表面之動摩擦係數在0 07〜 0.15之範圍内，而靜摩擦係數在〇1〇以上，並具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，至此即完成本發明。則，於第1觀點中，本發明之要旨如下。 (1 )一種具優異财壓磨損性與耐線圈變形性之表面處理金屬板，係具有一〇.3g/m2〜5.0g/m2之水性有機無機複合覆膜者，該水性有機無機複合覆膜係包含有水性樹脂及矽酸鹽化合物之一方或兩方，進而包含有分子量在6〇〇〇〜 15000範圍内之聚烯烴蠟分散體與以固體成分換算時為$〜 35質量％之膠體二氧化矽者。 (2 )如則述（1 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該聚烯烴蠟分散體係由不含極性基且分子量在6000〜15000範圍内、粒徑為〇1μιη〜 5·0μηι之聚烯烴蠟分散體，與分子量在6000〜ι5〇〇〇範圍内、酸值在40以下、且粒徑為Ο.ίμιη〜5.0μιη之變性聚烤煙本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝 ---I---訂·！經濟部智慧財產局員工消費合作社印製 573062 A7-4- 573062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (To meet the performance needs of those who need it, a special resin was formed on a chromate-treated galvanized steel sheet. A coated metal sheet that is an organic composite coating on a substrate. For example, a method for manufacturing a surface-treated steel sheet has been disclosed in Japanese Patent Publication Gazette No. 4-14191, which is a method in which a chromate coating is galvanized. An organic composite film with a specific fine particle size sol added to the water-based organic resin is formed on the steel plate, and the effect of improving the corrosion resistance and fingerprint resistance can be achieved. Japanese Patent Laid-Open Publication No. 3-39485 The disclosed system is that after applying a chromate treatment to a zinc-based galvanized steel sheet, a wax in which a silicon dioxide and a glass transition point (in points) are dispersed in water-based resin is 40 or more is applied, and Painters with a dry mass of 0.3 g / m2 to 3.0 g / m2. Also, the one disclosed in Japanese Patent Laid-Open Publication No. Hei 3-28838 is a kind of lubricating steel sheet, which is attached to an electrolytic zinc-galvanized steel sheet. After being treated with chromate, a coating made of carboxylated polyethylene resin and Teflon (trademark) lubricant and having a dry mass of 0.5 g / m2 to 4.0 g / m2 is applied. Further, For deep drawing processability, in order to meet the requirements of those who require strict wear resistance, a surface-treated steel sheet with a solid lubricant added to the organic coating to improve its lubricity has been developed. For example, Japanese Patent Publication The gazette disclosed in Japanese Patent Application Laid-Open No. 6_173〇37 is a steel plate with a lubricating film, which is added to the ether · 酉 -type urethane resin and epoxy resin with the addition of stone dioxide and polymer. Olefin waxers. The technology disclosed in Japanese Patent Publication No. 4-14191 is a kind of excellent balance of corrosion resistance, coating adhesion, fingerprint resistance, and coagulation resistance, and it is now also used as the main product of home appliances. I. However, even if this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 7—.! Install -------- Order --------- (please first (Please read the notes on the back and fill in this page) -5- 573062 Ministry of Economic Affairs Printed by A7, Consumer Cooperatives of the Bureau of Industry. V. Invention Description (On such surface-treated steel plates coated with organic film, sometimes there will still be damage during processing, wear during pressure processing, or when the product is transported. Wear (abrasion), etc. Contrary to this, the techniques disclosed in Japanese Patent Laid-Open Publication Nos. Hei 3-39485 and Hei 3-28380 are difficult to produce the abrasion or abrasion during the pressurizing process shown above. The technique disclosed in Japanese Patent Application Laid-Open No. 6-173307 has excellent pressure-wear resistance even in processes as severe as deep drawing workability. However, Japanese Patent Laid-Open Publication No. 3-39 The surface of steel plates manufactured by the technologies disclosed in No. 4 8 No. 5, JP-A No. 3-28380, and JP-A No. 6-173037 formed problems such as easy sliding, loose coiling, which caused the coil to be damaged, or load collapse when piling the strip-shaped plate. . Therefore, in order to avoid these problems, countermeasures such as increasing the number of tapes are implemented to increase the tension when the coil is wound and to prevent the coil from being loosened after packaging. The first main object of the present invention is to provide a variety of excellent properties such as corrosion resistance, adhesion, solderability, etc., and can maintain pressure and abrasion resistance and improve the load when the coil is damaged due to winding slack or the pile is piled. The surface-treated metal plate and the manufacturing method thereof, and an aqueous organic-inorganic composite coating capable of manufacturing the surface-treated metal plate. A second main object of the present invention is to provide a surface-treated metal plate having various properties such as corrosion resistance, adhesion, solderability, and the like, and having excellent pressure wear resistance and continuous sliding wear resistance, and a method for manufacturing the same, and a method for manufacturing the same. The water-based organic-inorganic composite coating for the surface-treated metal plate can be manufactured. The third main object of the present invention is to provide a variety of properties such as corrosion resistance, adhesion, solderability, etc., and can maintain pressure and abrasion resistance and improve ^ paper size applies China National Standard (CNS) A4 specifications (210 X 297 public love ----------- install -------- order --------- >, (Please read the precautions on the back before filling this page) -6- 573062 A7 B7 V. Description of the Invention (Problems such as coil damage caused by winding looseness or load collapse when piling strips are piled up, etc. ', which can suppress the occurrence of sticky residue caused by the lubricant falling off from the film during pressing. The surface treatment metal plate and its manufacturing method. After conducting various reviews in order to achieve the first objective mentioned above, it was found that 'by including a molecular weight in the range of 6000 ~ 15000? Appropriate amount of colloidal hafnium dioxide water-based organic-inorganic composite coating is coated on metal plate and dried to form water-based organic-inorganic composite coating, which can produce a variety of properties not only excellent in corrosion resistance, adhesion and solderability, And control the dynamic friction coefficient of the metal plate surface from 0 07 to 0.15 Within this range, a surface-treated metal plate having a static friction coefficient of more than 010 and having excellent pressure wear resistance and coil deformation resistance has completed the present invention. In the first aspect, the gist of the present invention is as follows. (1) A surface-treated metal plate with excellent financial abrasion resistance and coil deformation resistance. The water-based organic-inorganic composite coating has a water-based organic-inorganic composite coating of 0.3 g / m2 to 5.0 g / m2. It contains one or both of water-based resin and silicate compound, and further contains a polyolefin wax dispersion with a molecular weight in the range of 6,000 to 15,000 and a colloidal compound with a solid content of $ to 35% by mass. (2) As described in (1), a surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance, wherein the polyolefin wax dispersion system has a polar group and a molecular weight in the range of 6000 to 15000. Polyolefin wax dispersion with a particle size of 0.01 μm to 5.0 μm and a denatured poly-cured tobacco with a molecular weight in the range of 6000 to 5,000, an acid value of 40 or less, and a particle size of 0.15 μm to 5.0 μm Paper size Use Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling out this page) Packing --- I --- Ordered! Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 573062 A7

閱讀背之注項再填 I裝頁I I I 訂 I ♦ % 573062 A7 經濟部智慧財產局員工消費合作社印製 -------— B7____五、發明說明（、分散體、肖適量之膠體二氧化石夕之水性有機無機複合塗料塗布於鍍金屬板上，經乾燥後形成水性有機無機複合覆膜，則可製得一種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板，至此即完成本發明。則，於第2觀點中，本發明之要旨如下。 (1 )一種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板，係具有一水性有機無機複合覆膜者，該水性有機無機複合覆膜係包含有水性樹脂及矽酸鹽化合物之一方或兩方，進而包含有以分子量在6〇〇〇〜15〇〇〇範圍内之聚烯烴蠟分散體構成之潤滑劑（A)，以分子量在1〇〇〇〜 5000之聚烯烴蠟分散體構成之潤滑劑（b)，與以固體成分換算時為5〜35質量％之膠體二氧化矽者；且，該水性有機無機複合覆膜係具有〇.3g/m2〜5.0g/m2。 (2 )如前述（1 )之具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板，其中該潤滑劑（A )係由不含極性基且分子量在6000〜15000範圍内、粒徑為01μηι〜 5·0μηι之聚稀煙躐分散體，與分子量在6〇〇〇〜15000範圍内、酸值在40以下、且粒徑為〇·ΐμηι〜5·0μιη之聚稀烴蠛分散體中選出之至少1種以上之潤滑劑，而潤滑劑（Β )係不含極性基且分子量在1000〜15000範圍内、粒徑為〇.1μηι〜 5·0μηι之聚烯烴蠟分散體。 (3 ) —種水性有機無機複合塗料，係包含有水性樹脂及石夕酸鹽化合物之一方或兩方，進而包含有以分子量在 6000〜15000範圍内之聚烯烴蠟分散體構成之潤滑劑 (請先閱讀背面之注意事項再填寫本頁} 零-裝 • ϋ ϋ ----訂--------- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -9- 573062Read the note at the back and fill in the page I. III. I ♦% 573062 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ----------- B7____ V. Description of the invention (, dispersion, small amount of colloid The water-based organic-inorganic composite coating of stone dioxide is coated on a metal-plated plate, and the water-based organic-inorganic composite coating is formed after drying. A surface-treated metal plate with excellent pressure resistance and continuous sliding wear resistance can be obtained. Then, the present invention has been completed. Then, in the second aspect, the gist of the present invention is as follows. (1) A surface-treated metal plate having excellent pressure wear resistance and continuous sliding wear resistance, which is a water-based organic-inorganic composite For coating, the aqueous organic-inorganic composite coating system includes one or both of an aqueous resin and a silicate compound, and further includes a polyolefin wax dispersion having a molecular weight in the range of 6,000 to 150,000. The lubricant (A) is a lubricant (b) composed of a polyolefin wax dispersion having a molecular weight of 1,000 to 5,000, and colloidal silicon dioxide having a content of 5 to 35% by mass in terms of solid content. And the water-based organic-inorganic composite coating system has 0.3 g / m2 to 5.0 g / m2. (2) The surface-treated metal plate having excellent pressure wear resistance and continuous sliding wear resistance as described in (1) above. Wherein, the lubricant (A) is a polysmoky soot dispersion containing no polar group and having a molecular weight in the range of 6000 to 15000 and a particle size of 01 μm to 5.0 μm, and a molecular weight in the range of 6000 to 15000. At least one lubricant selected from a polyhydrocarbon 蠛 dispersion having an acid value of 40 or less and a particle size of 0.ΐμηι ~ 5.0 μιη, and the lubricant (B) is free of polar groups and has a molecular weight between Polyolefin wax dispersion with a particle size of 0.1 μm to 5.0 μm in the range of 1000 to 15000. (3) A water-based organic-inorganic composite coating containing one or both of a water-based resin and a oxalate compound , And further contains a lubricant composed of a polyolefin wax dispersion with a molecular weight in the range of 6000 to 15000 (please read the precautions on the back before filling out this page) Zero-Packing • ϋ ϋ ---- Order ---- ----- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) -9- 573062

經濟部智慧財產局員工消費合作社印製 (A)，以分子量在1〇〇〇〜5〇〇〇範圍内之聚烯烴蠟分散體構成之潤滑劑（B)，與以固體成分換算時為5〜35質量％之膠體二氧化矽以及水者。 (4)如前述（3)之水性有機無機複合塗料，其中該潤滑劑（A)係由不含極性基且分子量在6〇〇〇〜15〇〇〇範圍内、粒徑為Ο.ίμιη〜5·0μιη之聚烯烴蠟分散體，與分子量在 6000〜15000範圍内、酸值在4〇以下、且粒徑為〇 ΐμιη〜 5·0μηι之變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑，而潤滑劑（Β)係不含極性基且分子量在1〇〇〇〜5〇〇〇範圍内、粒徑為〇·1μιη〜5·〇μιη之聚烯烴蠟分散體。 (5 )—種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板之製造方法，係將以乾態質量換算時為 0.3g/m2〜5.0g/m2之前述（3)之水性有機無機複合塗料塗布於鍍金屬板上後，經烘烤而形成水性有機無機複合覆膜。 (6 ) —種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板之製造方法，係將以乾態質量換算時為〇.3g/m2〜5.0g/m2之前述（4)之水性有機無機複合塗料塗布於艘金屬板上後，經烘烤而形成水性有機無機複合覆膜。本發明人等進而為達成前述第3目的而進行種種檢討後之結果則發現，藉由在鍍金屬板之上層，塗布包含有分子量在6000〜15000範圍内之聚稀烴蟻分散體之潤滑劑 (A)，及視必要更包含有分子量在1〇〇〇〜5〇〇〇範圍内之聚烯烴蠟分散體之潤滑劑（B )的水性有機無機複合塗料 (E)後’經烘烤而形成第一層，其次於塗布包含有適量本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐）Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (A), a lubricant (B) composed of a polyolefin wax dispersion with a molecular weight in the range of 1,000 to 5,000, and 5 when converted to solid content ~ 35% by mass of colloidal silica and water. (4) The aqueous organic-inorganic composite coating according to the aforementioned (3), wherein the lubricant (A) is composed of no polar group and having a molecular weight in the range of 600,000 to 150,000, and a particle size of 0. A polyolefin wax dispersion of 5.0 μm and at least one selected from a modified polyolefin wax dispersion having a molecular weight in the range of 6000 to 15000, an acid value of 40 or less, and a particle size of 0 to 50 μm The lubricant (B) is a polyolefin wax dispersion that does not contain polar groups and has a molecular weight in the range of 10,000 to 50,000 and a particle size of 0.1 μm to 5.0 μm. (5) —A method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and continuous sliding wear resistance, which will be 0.3g / m2 ~ 5.0g / m2 in the above (3) when converted to dry mass. After the water-based organic-inorganic composite coating is coated on the metal plate, the water-based organic-inorganic composite coating is formed by baking. (6) — A method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and continuous sliding wear resistance, which is 0.3 g / m2 to 5.0 g / m2 in dry mass conversion (4) After the water-based organic-inorganic composite coating is coated on the ship's metal plate, it is baked to form an water-based organic-inorganic composite coating. The present inventors have conducted various reviews to achieve the above-mentioned third objective. As a result, they have found that a lubricant containing a polyalkylene ant dispersion having a molecular weight in the range of 6000 to 15000 is applied on the upper layer of the metal plating plate (A), and if necessary, an aqueous organic-inorganic composite coating (E) containing a lubricant (B) of a polyolefin wax dispersion having a molecular weight in the range of 10,000 to 50,000, and then baked and Form the first layer, followed by coating containing an appropriate amount of the paper size applicable to Chinese National Standard (CNS) A4 specifications (210 x 297 mm)

(請先閱讀背面之注意事項再填寫本頁) 裝--------訂--------- -10- 573062 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（$ 之膠體二氧化矽之水性有機無機複合塗料（f )後，經烘烤而形成第二層，則製得一種可控制金屬板表面之動摩擦係數在0.07〜0.15之範圍内，而靜摩擦係數在〇1〇以上，且可抑制於壓製時潤滑劑自覆膜脫落而引起黏稠性殘渣產生之表面處理金屬板，至此即完成本發明。則，於第3觀點中，本發明之要旨如下。 (1 )一種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，係使第一層具有乾態質量為〇〇5§/1112〜〇.3g/m2 之水性有機無機複合覆膜（c )，該水性有機無機複合覆膜（C )係包含有水性樹脂及矽酸鹽化合物之一方或兩方，進而包含有以分子量在6000〜1 5000範圍内之聚烯烴蠟分散體構成之潤滑劑（A )者；該表面處理金屬板並使第二層具有乾態質量為0.5g/m2〜5.0g/m2之水性有機無機複合覆膜（D)，該水性有機無機複合覆膜（D)係以水性樹脂及矽酸鹽化合物之一方或兩方，進而以固體成分換算時為5 〜35質量％之膠體二氧化矽構成者。 (2 )如前述（1 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該潤滑劑（A )係由不含極性基且分子量在600 0〜15000範圍内、粒徑為〇.1 gm〜5.〇之聚烯烴蠟分散體，與分子量在6000〜15000範圍内、酸值在40以下、且粒徑為〇.]^m〜5.〇pni之變性聚稀烴堰分散體中選出之至少1種以上之潤滑劑。 (3 )如前述（1 )或（2 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該水性有機無機複合覆本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） Μ.--------tr--- (請先閱讀背面之注意事項再填寫本頁) -11- 573062 經濟部智慧財產局員工消費合作社印製 A7 五、發明說明（膜（C)係以將水性樹脂與分子量在6000〜15000範圍内之聚烯烴蠟分散體之潤滑劑（A)，及分子量在1〇〇〇〜5〇〇〇範圍内之聚烯烴蠟分散體之潤滑劑（B )混合後之複合系潤滑劑構成者。 (4 )如則述（3 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該潤滑劑（A)係由不含極性基且分子量在6000〜15000範圍内、粒徑為〇 1μηι〜5 〇μιη 之聚浠fe壌分散體，與分子量在6〇〇〇〜15〇〇〇範圍内、酸值在40以下、且粒徑為〇1(Im〜 5 〇μιη之變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑，而潤滑劑（Β )係不含極性基且分子量在1000〜5000範圍内、粒徑為01μιη〜3 〇μιη 之聚烯烴蠟分散體。 (5 )如前述（1 )至（4 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其表面之動摩擦係數係在〇·〇7〜〇·15之範圍内，而靜摩擦係數係在〇·1〇以上。 (6 )—種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法’係於鑛金屬板之上層塗布以乾態質量換算時為〇.〇5g/m2〜0.3g/m2之水性有機無機複合塗料 (E )後’經烘烤而形成第一層，而該水性有機無機複合塗料（E )係以水性樹脂及石夕酸鹽化合物之一方或兩方，進而以分子量在6000〜15000範圍内之聚烯烴躐分散體之潤滑劑（A)以及水所構成者；其次，塗布以乾態質量換算時為0.5g/m2〜5.0g/m2之水性有機無機複合塗料（ρ )後，經烘烤而形成第二層，而該水性有機無機複合塗料（F ) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ,- ^1Μ--------tr--------- ★ V (請先閱讀背面之注意事項再填寫本頁) -12- 573062 五、經濟部智慧財產局員工消費合作社印製 A7 -------B7_ 發明說明（$ 係以水性樹脂及石夕酸鹽化合物之一方或兩方、膠體二氧化矽及水所構成，且膠體二氧化矽之含量以固體成分換算時為5〜35質量％者。 (7 )如前述（6 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，其中該潤滑劑（A )係由不含極性基且分子量在6000〜i 5000範圍内、粒徑為 0·1μιη〜5·0μηι之聚烯烴蠟分散體，與分子量在6〇〇〇〜 15000範圍内、酸值在4〇以下、且粒徑為〇 1μιη〜5〇μιη之變性聚烯烴蠛分散體中選出之至少1種以上之潤滑劑。 (8 )如前述（6 )或（7 )之具優異耐壓磨損性與财線圈變形性之表面處理金屬板之製造方法，其中該水性有機無機複合塗料（Ε )係以將水性樹脂與分子量在6〇〇〇〜 15000範圍内之聚烯烴蠟分散體之潤滑劑（a),及分子量在1000〜5000之聚烯烴蠟分散體之潤滑劑（β)混合後之複合系潤滑劑，以及水構成者。 (9 )如前述（6 )至（8 )之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，其中該潤滑劑 (A )係由不含極性基且分子量在6000〜15000範圍内、粒徑為Ο.ίμηι〜5·0μηι之聚烯烴蠟分散體，與分子量在6〇〇〇〜 15000範圍内、酸值在40以下、且粒徑為〇·1μιη〜5 〇μιη之變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑，而潤滑劑（Β)係不含極性基且分子量在1〇〇〇〜5〇〇〇範圍内、粒徑為Ο.ίμηι〜3·0μηι之聚稀烴蠛分散體。以下為圖示之簡單說明。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -----------裝·---I--I I------- % ¥ ' (請先閱讀背面之注意事項再填寫本頁) -13- 573062 A7(Please read the precautions on the back before filling out this page) -------- Order --------- -10- 573062 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Description of the invention (After the colloidal silicon dioxide water-based organic-inorganic composite coating (f) is formed by baking to form a second layer, a controllable dynamic friction coefficient of the surface of the metal plate is produced in the range of 0.07 to 0.15, and The surface-treated metal plate having a static friction coefficient of at least 010 and capable of suppressing the occurrence of viscous residues caused by the lubricant from falling off from the film during pressing, has completed the present invention. In the third aspect, the gist of the present invention It is as follows: (1) A surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance. The first layer has a water-based organic-inorganic composite with a dry mass of 〇05§ / 1112 ~ 0.3g / m2. Film (c), the water-based organic-inorganic composite film (C) contains one or both of an aqueous resin and a silicate compound, and further includes a polyolefin wax dispersion having a molecular weight in the range of 6000 to 15,000 Composition of lubricant (A); the surface-treated metal Board and the second layer has a dry organic water-inorganic composite film (D) with a dry mass of 0.5 g / m2 to 5.0 g / m2, which is composed of an aqueous resin and a silicate compound Either one or both, and a colloidal silica composed of 5 to 35% by mass in terms of solid content. (2) The surface-treated metal having excellent pressure wear resistance and coil deformation resistance as described in (1) above. Plate, wherein the lubricant (A) is a polyolefin wax dispersion containing no polar group and having a molecular weight in the range of 600 0 to 15000 and a particle size of 0.1 gm to 5.0, and a molecular weight in the range of 6000 to 15000. At least one or more lubricants selected from denatured polyolefin weir dispersions having an internal acid value of 40 or less and a particle size of 0.005 to 5.0 pni. (3) As described in (1) or (2) The surface-treated metal sheet with excellent pressure wear resistance and coil deformation resistance, in which the paper size of the water-based organic-inorganic composite coating is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) M.- ------- tr --- (Please read the notes on the back before filling this page) -11- 573062 Intellectual Property of the Ministry of Economic Affairs Printed by employee consumer cooperative A7 V. Description of the invention (The film (C) is a lubricant (A) with a waterborne resin and a polyolefin wax dispersion having a molecular weight in the range of 6000 to 15000, and a molecular weight of 1,000 to 5 The lubricant of polyolefin wax dispersion (B) in the range of 0.00% is a composite lubricant composition. (4) As stated in (3), the surface has excellent pressure wear resistance and coil deformation resistance. A metal plate is treated, wherein the lubricant (A) is a poly (fe) dispersion containing no polar group and having a molecular weight in the range of 6000 to 15000 and a particle size of 0.001 μm to 50 μm, and a molecular weight of 600. At least one or more lubricants selected from a denatured polyolefin wax dispersion having an acid value of 40 or less and a particle size of 0 (Im to 50 μm), and the lubricant (B) It is a polyolefin wax dispersion that does not contain polar groups and has a molecular weight in the range of 1000 to 5000 and a particle size of 01 μm to 3 μm. (5) As described in (1) to (4) of the surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance, the surface friction coefficient is in the range of 0.07 to 0.15, and The static friction coefficient is above 0.10. (6) —Manufacturing method of a surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance is applied on the upper layer of a mineral metal plate and is 0.05 mg / m2 ~ 0.3g / m2 of the water-based organic-inorganic composite coating (E) is formed by baking to form a first layer, and the water-based organic-inorganic composite coating (E) is based on one or both of the water-based resin and the oxalate compound, and then the molecular weight Lubricant (A) of polyolefin 躐 dispersion in the range of 6000 ~ 15000 and water; secondly, apply water-based organic-inorganic composite coating (0.5g / m2 ~ 5.0g / m2 in dry mass conversion) ( ρ), and then baked to form a second layer, and the water-based organic-inorganic composite coating (F) is sized to the Chinese National Standard (CNS) A4 (210 X 297 mm),-^ 1M ---- ---- tr --------- ★ V (Please read the notes on the back before filling out this page) -12- 573062 V. Printed by A7, Consumer Cooperatives of Intellectual Property Bureau, Ministry of Economic Affairs ---- --- B7_ Description of the invention ($ is based on one or both of water-based resin and oxalate compound, colloidal silica and water And the content of colloidal silicon dioxide is 5 to 35% by mass when converted to solid content. (7) Manufacture of a surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance as described in (6) above. Method, wherein the lubricant (A) is a polyolefin wax dispersion containing no polar group and having a molecular weight in the range of 6000 to 5000 and a particle size of 0.1 μm to 5.0 μm, and a molecular weight of 600 to At least one or more lubricants selected from denatured polyolefin 蠛 dispersions having an acid value of 40 or less and a particle size of 0-1 μm to 50 μm in the range of 15000. (8) As described in (6) or (7) ) A method for manufacturing a surface-treated metal plate having excellent pressure wear resistance and deformability of a financial coil, wherein the water-based organic-inorganic composite coating (E) is obtained by polymerizing an aqueous resin with a molecular weight in a range of 6,000 to 15,000. Lubricants (a) of olefin wax dispersions, compound lubricants made of lubricants (β) of polyolefin wax dispersions having a molecular weight of 1000 to 5000, and water composition. (9) As described in (6) To (8) with excellent pressure wear resistance and coil deformation resistance A method for manufacturing a surface-treated metal plate, wherein the lubricant (A) is a polyolefin wax dispersion containing no polar group and having a molecular weight in the range of 6000 to 15000 and a particle diameter of 0. Ιμηι ~ 5.0 μηι, and a molecular weight At least one or more lubricants selected from a denatured polyolefin wax dispersion having an acid value of 40 or less and a particle size of from 0.1 μm to 50 μm in the range of 6000 to 15000, and the lubricant (B ) Is a polyhydrocarbon fluorene dispersion that does not contain polar groups and has a molecular weight in the range of 1000 to 50000 and a particle size of 0.1 μm to 3.0 μm. The following is a brief description of the illustration. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation --- I--I I -------% ¥ ' (Please read the precautions on the back before filling this page) -13- 573062 A7

經濟部智慧財產局員工消費合作社印製Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

五、發明說明（V 第1圖係說明本發明第1觀點中之表面處理金屬板。第2圖係說明本發明第2觀點中之表面處理金屬板。第3圖係說明本發明第3觀點中之表面金屬板之一例。第4圖係說明本發明第3觀點中之表面金屬板之又一例。以下即對本發明進行詳細說明。以往為提升水性有機無機複合鍍層鋼板之耐壓磨損性，一般係使用於鋼板上之水性有機無機複合覆膜中添加分子量低之聚烯烴蠟等潤滑劑之手法。藉由將如此之不含極性基且分子量低之聚烯烴蠟分散體摻合於水性有機無機覆膜中，則可使蠟以粒狀存在於覆膜表面，並使金屬板表面之親和力降低，且同時於加壓加工時將蠟壓碎而於鋼板與模具間形成一潤滑層。因此可得優異之潤滑效果，並可降低壓製時之磨損。此外，本發明之第1觀點中，係將作為潤滑劑且分子量在6000〜15000範圍内之聚烯烴蠟分散體以預定量摻合於水性有機無機複合塗料中而使用。進而，將水性有機無機複合覆膜中之膠體二氧化矽含量調節成以固體成分換算時為5〜35質量％。第1圖所示者係本發明之表面處理金屬板之例。本發明之表面處理金屬板係形成呈於鍍金屬板3上具有水性有機無機複合覆膜2之構造。該水性有機無機複合覆膜2係將換合有水性樹脂及矽酸鹽化合物之一方或兩方，進而有膠體二氧化矽、水、及作為潤滑劑之聚烯烴蠟分散體1的水性有本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) --裝！| 訂·1 ---I-- -14- 573062 Α7 Β7 經濟部智慧財產局員工消費合作社印製五、發明說明（予機無機複合塗料，以適當之方法塗布於鍍金屬板3上而形成者。如第1圖所示，聚烯烴蠟分散體1係由水性有機無機複合覆膜2呈粒狀露出。如此一來，藉由在水性有機無機複合覆膜中添加聚烯經蠛分散體，並將蠟之分子量調節成適當值，而使蠟以粒狀存在於覆膜表面並同時控制蠟之硬度及覆膜表面之親和力。進而調節二氧化矽之含有率以達成覆膜硬度與耐蝕性或黏附性等覆膜性能之互適化。由以上方式，即可製得一種不僅具有良好耐蝕性或黏附性，且可控制動摩擦係數在〇·〇7〜〇·15之範圍内、而靜摩擦係數在〇1〇以上之前所未有之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板。以下將說明本發明第1觀點之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法。本發明第1觀點之表面處理金屬板，係藉由在表面鍍敷金屬板上塗布預定之水性有機無機複合塗料，並經烘烤後形成水性有機無機複合覆膜而製造者。本發明中可應用之表面鍍敷金屬板，係包含有：鍍鋅金屬板、鍍鋅鎳金屬板、鑛鋅-鐵金屬板、鍍鋅-鉻金屬板、鍍鋅_鋁金屬板、鍍鋅_ 鈦金屬板、鍍鋅-鎂金屬板、鍍鋅-錳金屬板等鋅系之電鍍、熱浸鍍 '蒸鍍鋼板；鍍鋁或鋁合金金屬板；鍍鉛或鉛合^金金屬板；鍍錫或錫合金金屬板；更包含有於該等鍍層上含鈷、鉬、鎢、鎳、鈦、鉻、鋁、錳、鐵、鎂、鉛、銻、錫、銅、鎘、砷等以作為少量異極金屬元素或雜質者，及/或分散有二氧切、氧化銘、鈦白等無機物者。進而，亦 (請先閱讀背面之注意事項再填寫本頁) -•t--------tr---------V. Description of the Invention (V Fig. 1 illustrates the surface-treated metal plate in the first aspect of the present invention. Fig. 2 illustrates the surface-treated metal plate in the second aspect of the present invention. Fig. 3 illustrates the third aspect of the present invention. An example of a surface metal plate in FIG. 4 illustrates another example of a surface metal plate in the third aspect of the present invention. The present invention will be described in detail below. In the past, in order to improve the pressure resistance of water-based organic-inorganic composite plated steel sheets, Generally, it is a method of adding a low molecular weight polyolefin wax and other lubricants to the water-based organic-inorganic composite film used on a steel plate. By blending such a polyolefin wax dispersion having no polar group and low molecular weight into an aqueous organic In the inorganic coating, the wax can be present on the coating surface in a granular form, and the affinity of the surface of the metal plate can be reduced. At the same time, the wax is crushed during pressure processing to form a lubricating layer between the steel plate and the mold. An excellent lubricating effect can be obtained, and abrasion during pressing can be reduced. In addition, in the first aspect of the present invention, a polyolefin having a molecular weight in the range of 6000 to 15000 is used as a lubricant. The dispersion is used by mixing it with a predetermined amount in an aqueous organic-inorganic composite coating. Further, the content of colloidal silica in the aqueous organic-inorganic composite coating is adjusted to 5 to 35% by mass in terms of solid content. Figure 1 The shown is an example of the surface-treated metal plate of the present invention. The surface-treated metal plate of the present invention is formed in a structure having a water-based organic-inorganic composite coating 2 on the metal-plated plate 3. The water-based organic-inorganic composite coating 2 One or both of the water-based resin and the silicate compound are exchanged, and colloidal silica, water, and the polyolefin wax dispersion 1 as a lubricant are water-based. The paper standard is applicable to Chinese National Standards (CNS). A4 size (210 X 297 mm) (Please read the precautions on the back before filling out this page) --Installation! | Order · 1 --- I-- -14- 573062 Α7 Β7 Employee Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printed 5. Description of the invention (pre-organic inorganic composite coating, formed by coating on a metal plate 3 by an appropriate method. As shown in Figure 1, the polyolefin wax dispersion 1 is a water-based organic-inorganic composite coating 2 Granular In this way, by adding a polyene warp dispersion to the aqueous organic-inorganic composite coating, and adjusting the molecular weight of the wax to an appropriate value, the wax is present in a granular form on the surface of the coating and the wax is simultaneously controlled. The hardness and the affinity of the film surface. Then adjust the content of silicon dioxide to achieve the mutual compatibility of film hardness and film properties such as corrosion resistance or adhesion. From the above methods, a kind of not only has good corrosion resistance It is a surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance that is unprecedented, and has a controllable dynamic friction coefficient in the range of 0.07 to 0.15, and a static friction coefficient of more than 010. Hereinafter, a method for manufacturing a surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance according to the first aspect of the present invention will be described. The surface-treated metal sheet according to the first aspect of the present invention is a metal plated surface. The manufacturer applies a predetermined water-based organic-inorganic composite coating, and forms a water-based organic-inorganic composite coating after baking. The surface-plated metal plates applicable in the present invention include: galvanized metal plates, galvanized nickel metal plates, mineral zinc-iron metal plates, galvanized-chromium metal plates, galvanized_aluminum metal plates, galvanized _ Titanium metal plate, galvanized-magnesium metal plate, galvanized-manganese metal plate and other zinc-based electroplating and hot-dip galvanizing steel plates; aluminum or aluminum alloy metal plates; lead or lead alloy metal plates; Tin-plated or tin-alloy metal plates; moreover, these coatings contain cobalt, molybdenum, tungsten, nickel, titanium, chromium, aluminum, manganese, iron, magnesium, lead, antimony, tin, copper, cadmium, arsenic, etc. Those with a small amount of heteropolar metal elements or impurities, and / or those with inorganic substances such as dioxane, oxide oxide, titanium dioxide, etc. dispersed. Furthermore, also (Please read the notes on the back before filling out this page)-• t -------- tr ---------

-15- 573062 A7 —---1~ ---- 五、發明說明（孕用將以上之鍍敷與其他種類之鍍敷，例如與鍍鐵、鍍鐵_ 磷等組合之多層鍍金屬板。各鍍金屬板中之鍍敷附著量以單面在lg/m2以上為宜，若低於此則耐蝕性降低。本發明之表面處理金屬板，係可藉由於鍍金屬板上施予以提升黏附性或耐蝕性等為目的之表面處理後，形成水性有機無機複合覆膜而製得。此外，亦可不施表面處理而直接於鍍金屬板上形成水性有機無機複合覆膜而製得。該表面處理並無特別之規定，只要能達成上述目的即可，但一般而言以可提升耐蝕性或黏附性之鉻酸鹽處理較為理想。开> 成鉻酸鹽覆膜之方法，舉例言之有於以三氧化鉻、鉻酸鹽、重鉻酸鹽為主劑之水溶液中之浸潰（反應型）鉻酸鹽處理、電解型鉻酸鹽處理，進而有塗布於前述水溶液中混合有膠體二氧化矽等之處理液後，不經水洗而使之乾燥之塗布型鉻酸鹽處理方法···等。鉻酸鹽附著量宜呈以Cr換算時為5mg/m2〜 100mg/m2 之程度。附著量以Cr換算時若未達5mg/m2將無法獲得充分之耐#性，若超過l〇0mg/m2則使鉻酸鹽覆膜本身產生凝聚破壞而降低塗料黏附性。作為水性樹脂者，可運用丙烯酸酯-丙烯酸共聚物、環氧-丙烯酸共聚物、烯烴-丙烯酸共聚物、烯烴多離子聚合物、苯乙烯-丙烯酸共聚物、胺基甲酸乙酯-丙烯酸共聚物、胺基甲酸乙酯-環氧樹脂、乙烯-亞胺-丙烯酸樹脂等。為使本紙張尺度適用中_家鮮（CNS)A4規€(加χ撕公髮） (請先閱讀背面之注意事項再填寫本頁) 裝--------訂--- 經濟部智慧財產局員工消費合作社印製 -16- 573062 A7 B7 五、發明說明（用如此之水性樹脂而製搵冷 _ i仵塗枓，宜使樹脂分散於水系溶媒中而开> 成乳液。又，亦γ # J視必要而添加三聚氰胺樹脂、胺基樹脂等各種交聯劑。農笼具4之中，若特別將性能與成本兩面考慮在内時，則宜佶用、降，一 τ ^ ^ 用烯：feL -丙稀酸共聚物等丙烯酸系樹脂0此外，需嚴格之澇払I . 衣拉加工時，則宜使用硬度與伸長性兼備之胺基甲酸乙酯_環氧系樹脂。本發明所用之石夕酸鹽化合物，一般係以M2〇.nSi〇2 (Μ為納、鉀、鐘之驗金屬，福任意數）表示，且係由納矽酉夂鹽、卸石夕酸鹽、叙石夕酸鹽中選出之至少i種以上之混合物。M20與Si〇k莫耳比，即n，宜於卜1〇之範圍内。打值若未滿1 ’所得覆膜將不易吸濕且覆膜之黏附性不充分，而未達理想之效果。又，若超過J 〇則使所得覆膜變跪且加工性降低，故未臻理想。經濟部智慧財產局員工消費合作社印製本發明所用之膠體二氧化石夕，可使用球狀、線狀、或結合具有分枝之球形膠體二氧化矽之念珠狀二氧化矽中之任一種。為球狀二氧化矽時，粒子徑宜於5nm〜50nm之範圍内’為線狀二氧化矽時，宜化學結合成直徑在5nm〜 50nm 之範圍内且長度/粗細之比率為丨〜5之狀態，而為具有分枝之念珠狀二氧化矽時，宜使[結合體之長度/球形二氧化矽之平均粒徑]之比在4以上且具有1處以上之分枝。膠體二氧化矽係呈以固體成分換算時為5〜35質量％而摻合於本發明之水性有機無機複合塗料中。若未滿5質量 %將無法獲得充分之对餘性及财壓磨損性，若超過3 5質量 %則使塗料黏附性及耐壓磨損性劣化。本紙張尺度適用中國國家標準（〇\JS)A4規格（210 X 297公爱） -17- 573062 經濟部智慧財產局員工消費合作社印製 Α7 Β7 五、發明說明（y 本發明第1觀點所使用之水性有機無機複合塗料，係摻合前述水性樹脂及矽酸鹽化合物之一方或兩方，膠體二氧化石夕、水、及分子量在6000〜15000範圍内之聚烯烴壌分散體而調製成者。更理想者，則於水性有機無機複合塗料中摻合由實質上不含極性基且分子量在6000〜15000範圍内、粒徑為Ο.ίμηι〜5·0μηι之聚烯烴蠟分散體，與分子量在 6000〜15000範圍内、酸值在40以下、且粒徑為〇1μηι〜 5·0μηι之變性聚烯烴蠟分散體中選出之至少1種以上而使用。作為聚烯烴蠟分散體者，係使用令實質上不含極性基之聚乙烯蠟、聚丙烯蠟或聚丁烯蠟分散於乳化劑濃度在5 %以下，且最好不具乳化劑之水或水溶液中者。又，作為變性聚烯烴蠟分散體者，係使用令實質上不含極性基之聚乙烯蠟、聚丙烯蠟或聚丁烯蠟分散於乳化劑 /農度在5 %以下，且最好不具乳化劑之水或水溶液中者。極性基係可於催化劑存在下，藉由將聚烯烴蠟以氧、臭氧或硝酸等氧化劑進行氧化處理而導入（氧化聚烯烴蠟），或可將丙烯酸、曱基丙烯酸、巴豆酸、順丁烯二酸、反丁稀二酸、分解烏頭酸等乙烯不飽和羧酸單體與聚稀烴蝶以苯等加以溶解’並與聚合引發劑（過氧化物、氧化還原、重金屬催化劑等）一起於氮氣流中加熱並經接枝化而導入。聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均粒徑宜於Ο.ίμηι〜5·0μιη之範圍内，而使用在1〇μιη〜4 〇gm範圍内者則更為理想。質量平均粒徑未達〇1μηι時，將因易本紙張尺度適用中關家標準（CNS)A4規格（2W χ 297公爱） (請先閲讀背面之注意事項再填寫本頁) 裝-15- 573062 A7 ---- 1 ~ ---- V. Description of the invention (Pregnant use Multi-layer metal plating plate combining the above plating with other types of plating, such as iron plating, iron plating_phosphorus, etc. It is advisable that the plating adhesion amount of each metal-plated plate is lg / m2 or more on one side. If it is lower than this, the corrosion resistance is reduced. The surface-treated metal plate of the present invention can be improved by applying the metal-plated plate. After surface treatment for the purpose of adhesion or corrosion resistance, it is prepared by forming an aqueous organic-inorganic composite film. In addition, it can also be prepared by directly forming an aqueous organic-inorganic composite film on a metal plate without surface treatment. There is no special requirement for surface treatment, as long as it can achieve the above purpose, but in general, it is ideal to use chromate treatment that can improve corrosion resistance or adhesion. Open > Method for forming chromate coating, for example It is used for immersion (reactive) chromate treatment and electrolytic chromate treatment in an aqueous solution containing chromium trioxide, chromate, and dichromate as the main agent, and further, it is coated in the aforementioned aqueous solution and mixed with Colloidal silica, etc. Coating type chromate treatment methods that are dried without washing ... etc. The amount of chromate adhesion should be about 5mg / m2 ~ 100mg / m2 when converted to Cr. If the amount of adhesion is not calculated when Cr is converted, When it reaches 5 mg / m2, sufficient resistance cannot be obtained. If it exceeds 100 mg / m2, the chromate film itself will cause cohesive failure and reduce paint adhesion. As an aqueous resin, an acrylate-acrylic copolymer can be used. , Epoxy-acrylic acid copolymer, olefin-acrylic acid copolymer, olefin polyionic polymer, styrene-acrylic acid copolymer, urethane-acrylic acid copolymer, urethane-epoxy resin, ethylene Amine-acrylic resin, etc. In order to make this paper suitable for use in China _ house fresh (CNS) A4 (plus χ tear public hair) (please read the precautions on the back before filling this page) Packing ------- -Order --- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-16- 573062 A7 B7 V. Description of the invention (Cold-cooled with such water-based resin _ i 仵 coated 枓, the resin should be dispersed in the aqueous solvent On > into emulsion. Also, γ # J is added with melamine tree if necessary , Amine-based resins and other cross-linking agents. In the farm cage 4, if the performance and cost are taken into consideration in particular, it should be used, reduced, a τ ^ ^ ene: feL-acrylic acid copolymer In addition, acrylic resins are required. In addition, strict waterlogging is required. I. For urethane processing, urethane-epoxy resins with both hardness and elongation should be used. The oxalate compounds used in the present invention are generally It is expressed by M2〇.nSi〇2 (M is sodium, potassium, bell test metal, any number of blessings), and it is at least selected from sodium silicic acid salt, oxalate, and sylate A mixture of more than i kinds. The molar ratio of M20 to SiOk, that is, n, is preferably within the range of Bu 10. If the value is less than 1 ', the obtained film will not be easy to absorb moisture and the adhesion of the film will be insufficient, and the desired effect will not be achieved. In addition, if it exceeds J 0, the obtained coating film will kneel and workability will be reduced, so it is not ideal. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The colloidal silica used in the present invention may be spherical, linear, or a combination of rosary silica with branched spherical colloidal silica. When it is spherical silica, the particle diameter should be in the range of 5nm ~ 50nm. When it is linear silica, it should be chemically combined into a diameter in the range of 5nm ~ 50nm and the length / thickness ratio is 丨 ~ 5. When the state is a rosary silica with branches, the ratio of [length of combined body / average particle diameter of spherical silica] should be 4 or more and have 1 or more branches. The colloidal silicon dioxide is 5 to 35% by mass in terms of solid content, and is blended in the aqueous organic-inorganic composite coating of the present invention. If it is less than 5 mass%, sufficient margin and pressure abrasion resistance will not be obtained, and if it exceeds 35 mass%, paint adhesion and pressure abrasion resistance will be deteriorated. This paper size applies the Chinese national standard (〇 \ JS) A4 specification (210 X 297 public love) -17- 573062 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (y used in the first aspect of the invention The water-based organic-inorganic composite coating is prepared by blending one or both of the foregoing water-based resin and silicate compound, colloidal silica, water, and a polyolefin 壌 dispersion having a molecular weight in the range of 6000 to 15000. More ideally, a polyolefin wax dispersion containing substantially no polar groups and having a molecular weight in the range of 6000 to 15000 and a particle diameter of 0. Ιμηι to 5.0 μηι is blended with the molecular weight in the aqueous organic-inorganic composite coating. At least one selected from the denatured polyolefin wax dispersions having an acid value of 40 or less in the range of 6000 to 15000 and a particle size of 0.01 μm to 5.0 μm. As the polyolefin wax dispersion, it is used. Polyethylene wax, polypropylene wax, or polybutene wax that does not substantially contain a polar group is dispersed in water or an aqueous solution having an emulsifier concentration of 5% or less, and preferably without an emulsifier. For olefin wax dispersion, use polyethylene wax, polypropylene wax, or polybutene wax that does not contain polar groups, and disperse it in emulsifier / agrocity of less than 5%, preferably without emulsifier. The polar group can be introduced in the presence of a catalyst by oxidizing a polyolefin wax with an oxidizing agent such as oxygen, ozone or nitric acid (oxidizing polyolefin wax), or acrylic acid, fluorenyl acrylic acid, crotonic acid, Ethylene unsaturated carboxylic acid monomers such as maleic acid, fumaric acid, decomposed aconitic acid, etc. are dissolved with olefin etc. ' ) Heated together in a nitrogen stream and introduced by grafting. The mass average particle diameter of the polyolefin wax dispersion and the modified polyolefin wax dispersion should be in the range of 0.1 μm to 5.0 μm, and used in the range of 10 The range of μιη ~ 4 〇gm is more ideal. When the mass average particle diameter is less than 〇1μηι, the Zhongguanjia Standard (CNS) A4 specification (2W χ 297 public love) will be applied due to the paper size (please read first) Note on the back (Fill in this page)

* I ϋ ϋ I ϋ I -18* 573062 A7 五、發明說明（$ 於凝？K且女定性不佳而使效果不理想。又，若質量平均粒位超過5·0μιη，則使分散安定性低劣而致效果不理想。此外，質塁平均粒徑與數量平均粒徑之比率，宜於質量平均粒徑/數量平均粒徑< 3之範圍内。聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均分子量之範圍，宜於6000〜15000之範圍内。若質量平均分子量未達6000，耐線圈變形性將劣化而使效果不佳。又，若質置平均分子量超過丨5000，則使耐壓磨損性劣化而致效果不理想。該等聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均分子量之分析方法及條件係顯示於下，但分子量之分析並非以該方法為限。刀析方法·南溫用GPC (膠透層析術（gel permeation chromatography)) •管柱塔（column) : PS (聚苯乙烯）凝膠之混合型（2 〜4根串聯連接）* I ϋ ϋ I ϋ I -18 * 573062 A7 V. Description of the invention ($ Yu Ning? K and female characterization is not good and the effect is not ideal. Also, if the mass average particle size exceeds 5.0 μm, it will make dispersion stable. Inferior and unsatisfactory effects. In addition, the ratio of the average particle size to the number average particle size is preferably within the range of mass average particle size / number average particle size < 3. Polyolefin wax dispersion and modified polyolefin wax The mass average molecular weight of the dispersion should be in the range of 6000 to 15000. If the mass average molecular weight is less than 6000, the coil deformation resistance will be deteriorated and the effect will be poor. If the mass average molecular weight exceeds 5,000, then Degradation of pressure resistance and abrasion resistance results in unsatisfactory results. The analysis methods and conditions of the mass average molecular weight of these polyolefin wax dispersions and modified polyolefin wax dispersions are shown below, but the analysis of molecular weight is not limited to this method. Knife analysis method · GPC (gel permeation chromatography) for South Vancouver • column column: PS (polystyrene) gel mixed type (2 to 4 connected in series)

•溶媒：鄰二氣苯（ODCB)、三氣苯（TCB)等 •測定溫度：130〜140°C • "ί貞檢器：示差折射器（RI )或紅外線貞檢器 •校準曲線之作成：利用市售之單分散PS而換算成各自之分子量又’變性聚烯烴蠟分散體之依JISK 5902規定之酸值 (KOH-mg/g )之範圍，宜在40以下。若酸值超過40，潤滑劑將變硬以致無法獲得充分之潤滑性。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) ▼-裝 ----訂--------- 經濟部智慧財產局員工消費合作社印製 -19- 經濟部智慧財產局員工消費合作社印製 573〇62 A7 ——_BZ___ 五、發明說明（y 進而’該等聚烯烴蠟分散體及變性聚烯烴蠟分散體，宜使依JISK 6760規定之密度於950kg/m3〜1000kg/m3範圍内並使依JISK 2207規定之硬度（穿透度penetration )在〇.2mm以下’以X射線繞射法求取之結晶度在以上，且熔點於110°C〜150°C之範圍内。由5亥專聚稀煙堰分散體及變性聚稀烴壤分散體中選出之至少1種以上者，宜以固體成分換算時為1〜3〇質量％而摻合於水性有機無機複合塗料中。未達1質量％將無法獲得充分之耐壓磨損性，若超過30質量％則使塗料黏附性劣化，效果皆不理想。该專水性有機無機複合覆膜之附著量範圍以乾態質量計則為0.3g/m2〜5.0g/m2。更理想者為1.0g/m2〜3 〇g/m2。附著2：未達0.3g/m2則目的之耐壓磨損性將劣化，又若超過 5.0g/m2，將使焊接困難，效果皆不理想。用以形成該等水性有機無機複合覆膜之塗布方法，可使用喷霧、簾塗布法（curtain)、淋塗機（fl〇wc〇ater)、輥塗機（roll coater)、桿塗機（bar coater)、刷塗、浸潰及氣刀擠壓等任一方法。又，烘烤溫度宜於80。(：〜25(rc之範圍内。又以高於所用/閏滑劑之溶點之溫度更佳。未達8 〇 °C時，塗料中之水將難以完全揮發而使耐蝕性下降，若超過]^^則使覆膜過度硬化而降低加工性，皆非理想之效果。此外，關於乾燥設備雖無特別之限制，但可採用熱風喷霧之方法，或加熱器間接加熱方法、以紅外線進行之方本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公董)" --------- -20- I -----裝--------訂--------- * > 、 (請先閱讀背面之注意事項再填寫本頁) 573062 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（f 法、感應加熱之方法、及將其等並用之方法。本發明之表面處理金屬板表面之動摩擦係數宜於〜〇·15之範圍内，而靜摩擦係數宜在〇1〇以上。動摩擦係數高於0.15時耐壓磨損性將劣化，而動摩擦係數低於〇〇7 且靜摩擦係數低於〇· 1 〇時則使耐線圈變形性低劣，皆非理想之效果。其次，本發明之第2觀點中，係將作為潤滑劑且分子量不同之潤滑劑（A)、（Β)以預定量摻合於水性有機無機複合塗料中而使用。於此，作為潤滑劑（Α )者係使用分子量在6000〜15000範圍内之聚烯烴蠟分散體，而作為潤滑劑（B)者係使用分子量在100〇〜5〇〇〇範圍内之聚烯烴壌分散體。進而，藉由將水性有機無機複合覆膜中之二氧化石夕含有率調節成以固體成分換算時為5〜35質量％，以圖覆膜硬度與耐蝕性或黏附性等覆膜性能之互適化。第2圖所示者係本發明之表面處理金屬板之例。本發明之表面處理金屬板係形成一於鍍金屬板14上具有水性有機無機複合覆膜13之構造。該水性有機無機複合覆膜13係將水性有機無機複合塗料以適當之方法塗布於鍍金屬板14上而形成者，而該水性有機無機複合塗料係摻合有水性樹脂及石夕酸鹽化合物之一方或兩方，進而摻合有潤滑劑（A )、潤滑劑（B)與以固體成分換算時為5〜35質量％之膠體二氧化石夕以及水者。如第2圖所示，潤滑劑（a )丨丨及潤滑劑 (B) 12係由水性有機無機複合覆膜13呈粒狀露出。如此，可藉由將習知所用之分子量低之聚烯烴蠟分散本紙張尺度適用中關家標準（CNS)A4規格（21〇 x 297公爱) ----- -21- ^ I I ^--------tl--------- (請先閱讀背面之注意事項再填寫本頁) 573062 A7• Solvent: o-dichlorobenzene (ODCB), tri-gas benzene (TCB), etc. • Measurement temperature: 130 ~ 140 ° C • " ί Chastity detector: Differential refractometer (RI) or infrared chastity detector • Calibration curve Preparation: The range of the acid value (KOH-mg / g) specified by JISK 5902 for the respective molecular weights and the denatured polyolefin wax dispersions converted from the commercially available monodispersed PS is preferably 40 or less. If the acid value exceeds 40, the lubricant will harden to obtain sufficient lubricity. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ▼ -Binding ---- Order --------- Economy Printed by the Ministry of Intellectual Property Bureau ’s Consumer Cooperatives-19- Printed by the Ministry of Economic Affairs ’Intellectual Property Bureau ’s Consumer Cooperatives 573〇62 A7 ——_ BZ___ V. Description of the Invention (y and then 'These polyolefin wax dispersions and modified polyolefin wax dispersions Body, the density according to JISK 6760 should be within the range of 950kg / m3 ~ 1000kg / m3 and the hardness (penetration) according to JISK 2207 should be 0.2mm or less. The crystal obtained by the X-ray diffraction method The temperature is above, and the melting point is in the range of 110 ° C ~ 150 ° C. At least one selected from the 5Hai polymerized thin weir dispersion and denatured polyhydrocarbon soil dispersion should be converted by solid content. When it is 1 to 30% by mass, it is blended in the water-based organic-inorganic composite coating. If it is less than 1% by mass, sufficient pressure and wear resistance cannot be obtained. If it exceeds 30% by mass, the adhesion of the coating is deteriorated, and the effect is not satisfactory The adhesion range of the water-soluble organic-inorganic composite film is dry The state mass meter is 0.3g / m2 ~ 5.0g / m2. More preferably, it is 1.0g / m2 ~ 30 g / m2. Attachment 2: If it is less than 0.3g / m2, the pressure resistance and wear resistance of the purpose will be deteriorated, and If it exceeds 5.0g / m2, it will make welding difficult and the effect will be unsatisfactory. For the coating method to form these water-based organic-inorganic composite coatings, spray, curtain coating, shower coating (fl) can be used. wcoater), roll coater, bar coater, brush coating, dipping, and air knife extrusion. Also, the baking temperature should be 80. (: ~ 25 ( Within the range of rc. It is better to use a temperature higher than the melting point of the used / slip agent. When it is less than 80 ° C, it will be difficult for the water in the coating to completely volatilize and reduce the corrosion resistance. Excessive hardening of the film to reduce workability is not an ideal effect. In addition, although there are no particular restrictions on the drying equipment, hot air spraying, heater indirect heating, and infrared paper can be used. Standards apply to China National Standard (CNS) A4 specifications (210 X 297 public directors) " --------- -20- I ----- installation -------- order --- ------ * > (Please read the precautions on the back before filling out this page) 573062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (f-method, method of induction heating, and methods of using them in combination. The dynamic friction coefficient of the surface-treated metal plate surface of the present invention is preferably in the range of ~ 15, and the static friction coefficient is preferably in the range of 010 or more. When the dynamic friction coefficient is higher than 0.15, the pressure wear resistance will be deteriorated, and when the dynamic friction coefficient is lower than 0.07 and the static friction coefficient is lower than 0.1 · 0, the coil deformation resistance is inferior, which is not an ideal effect. Next, in the second aspect of the present invention, lubricants (A) and (B) having different molecular weights as lubricants are blended in a predetermined amount in an aqueous organic-inorganic composite coating and used. Here, as the lubricant (A), a polyolefin wax dispersion having a molecular weight in the range of 6000 to 15000 is used, and as the lubricant (B), a polyolefin having a molecular weight in the range of 100 to 50,000 is used.壌 dispersion. Furthermore, by adjusting the content of the dioxide in the aqueous organic-inorganic composite coating to 5 to 35% by mass in terms of solid content, the relationship between coating hardness and coating performance such as corrosion resistance or adhesion is shown. Adaptation. The figure shown in FIG. 2 is an example of the surface-treated metal plate of the present invention. The surface-treated metal plate of the present invention has a structure having a water-based organic-inorganic composite film 13 on a metal-plated plate 14. The water-based organic-inorganic composite coating 13 is formed by applying an water-based organic-inorganic composite coating to a metal plate 14 by an appropriate method, and the water-based organic-inorganic composite coating is a mixture of an aqueous resin and a oxalate compound. One or both of them are further blended with a lubricant (A), a lubricant (B), and colloidal silica and water in an amount of 5 to 35% by mass in terms of solid content. As shown in FIG. 2, the lubricant (a) and the lubricant (B) 12 are exposed in a granular form from the aqueous organic-inorganic composite film 13. In this way, by dispersing the polyolefin wax with a low molecular weight used in the past, the paper size can be applied to the CNS A4 specification (21 × x297). ----- -21- ^ II ^- ------- tl --------- (Please read the notes on the back before filling this page) 573062 A7

體與分子量高之聚稀煙蠛分散體並用而添加於水性有機無機複合覆膜中，而使蝶呈粒狀存在覆膜表面，同時抑制壤於加壓成形或連續滑動時粉碎。進而，調節二氧化石夕之含有率以圖覆膜硬度與耐㈣或黏附性等覆膜性能之互適化。藉由以上方法，不僅將具有良好之耐飯性或黏附性，並可提高财壓磨損性與連續滑動時之潤滑效果之持續力。以下，說明本發明第2觀點之具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板之製造方法。該製造方法，除使用之水性有機無機複合塗料不同此點外，基本上係與本發明第1觀點之表面處理金屬板之製造方法相同。本發明之第2觀點之表面處理金屬板亦係藉由在表面鍍敷金屬板上塗布預定之水性有機無機複合塗料，並經烘烤後形成水性有機無機複合覆膜而製造者。可應用之表面鍍敷金屬板係如先前第丨觀點之表面處理金屬板所做之說明。各鍍金屬板中之鍍敷附著量以單面在1 g/m以上為宜，若低於此則耐蝕性降低。於鍍金屬板上施予以提升黏附性或耐蝕性等為目的之表面處理後，即可形成水性有機無機複合覆膜，或亦可不施表面處理而直接形成水性有機無機複合覆膜。該表面處理並無特別之規疋八要肖b達成上述目的即可，但一般而言以可提升耐餘性或黏附性之鉻酸鹽處理較為理想。鉻酸鹽覆膜之形成方法及鉻酸鹽附著量則如先前第！觀點之表面處理金屬板所做之說明。作為水性樹脂者，亦可使用先前針對第丨觀點之表面處本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）；q ®-t--------tr--------- (請先閱讀背面之注意事項再填寫本頁) -22-It is used in combination with a high molecular weight polysmoky tartar dispersion and added to the water-based organic inorganic composite film, so that the butterflies are granular on the surface of the film, and at the same time, the soil is prevented from being crushed during pressure forming or continuous sliding. Furthermore, the content rate of the stone dioxide was adjusted so as to make the film hardness and the film performance such as resistance to rubbing or adhesiveness compatible. With the above method, it will not only have good rice resistance or adhesion, but also improve the durability of pressure wear and lubrication effect during continuous sliding. Hereinafter, a method for producing a surface-treated metal plate having excellent pressure wear resistance and continuous sliding wear resistance according to the second aspect of the present invention will be described. This manufacturing method is basically the same as the method for manufacturing a surface-treated metal plate according to the first aspect of the present invention, except that the water-based organic-inorganic composite coating material is different. The surface-treated metal plate according to the second aspect of the present invention is also manufactured by applying a predetermined water-based organic-inorganic composite coating on a surface-plated metal plate and baking it to form an aqueous organic-inorganic composite coating. Applicable surface plated metal plates are the same as those described for the surface treated metal plates in the previous point. The plating adhesion amount in each metal-plated plate is preferably 1 g / m or more on one side, and if it is less than this, the corrosion resistance is reduced. After applying a surface treatment on the metal plate to improve adhesion or corrosion resistance, an aqueous organic-inorganic composite film can be formed, or an aqueous organic-inorganic composite film can be directly formed without surface treatment. There are no special rules for this surface treatment. It is only necessary to achieve the above purpose, but in general, a chromate treatment that improves the resistance or adhesion is ideal. The method of forming the chromate film and the amount of chromate coating are as before! The viewpoint of the surface treatment of the metal sheet is explained. As a water-based resin, you can also use the Chinese paper standard (CNS) A4 (210 X 297 mm) applicable to the paper size of the surface previously mentioned in point 丨; q ®-t -------- tr- -------- (Please read the notes on the back before filling this page) -22-

(請先閱讀背面之注意事項再填寫本頁) 八丑板之說明中所舉出者。為作成塗料，同樣宜使樹脂刀散於水系溶媒中而形成乳液，亦宜視必要而添加三聚氛胺樹脂、胺基樹脂等各種交聯劑。若特別將性能與成本兩面考慮在内時，則宜制烯烴丙烯酸共聚物等丙稀酸系樹脂。此外，需嚴格之深拉加工時，且需更佳之耐連續滑動磨耗n %則且使用硬度與伸長性兼備之胺基甲酸乙醋- 環氧系樹脂。本發明第2觀點中之矽酸鹽化合物及膠體二氧化矽，亦可使用先則針對第丨觀點之表面處理金屬板之說明中所舉出者。膠體二氧化矽係呈以固體成分換算時為5〜35質量％而払σ於本發明之水性有機無機複合塗料中。若未滿$質量 %將無法獲得充分之耐蝕性及耐壓磨損性，若超過35質量 %則使塗料黏附性及耐壓磨損性劣化。經濟部智慧財產局員工消費合作社印製本發明之第2觀點中使用之水性有機無機複合塗料，係摻合預定量之前述水性樹脂及矽酸鹽化合物之一方或兩方’膠體二氧化石夕、水、及分子量不同之潤滑劑（A )、 (B)而調製者。於此，作為潤滑劑（A)者係使用分子量在6000〜15000範圍内之聚烯烴蠟分散體，而作為潤滑劑 (B )者係使用分子量在1〇〇〇〜5〇〇〇範圍内之聚烯烴蠟分散體。更理想者係，使用由不含極性基且分子量在6〇〇〇〜 15000範圍内、粒徑為〇1μιη〜5·〇μπι之聚烯烴蠟分散體，與分子量在6000〜15000範圍内、酸值在40以下、且粒徑為 0·1μηι〜5·0μιη之變性聚烯烴蠟分散體中選出之至少1種以本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公复） -23- 573062 五、發明説明（& =潤滑劑作為潤滑劑⑷，並使用不含極性基且分子二二範圍内、粒徑為G々m〜5.G_之聚烯烴蟻刀政體作為潤滑劑（B )。 μ作為聚烯烴❹散體者，係使用令實質上不含極性基之聚乙烯蠟、聚丙烯蠟、聚丁烯蠟分散於乳化劑濃度在5 %以下，且最好不具乳化劑之水或水溶液中者。又作為變性聚婦烴犧分散體者，係使用將不含極性〇土 ^乙烯if〜丙烯蠟、聚丁烯蠟分散於乳化劑濃度在5 /以下’ J«最好不具乳化劑之水或水溶液中者。極性基係 :於催化劑存在下，藉由將聚烯烴蠟以氧、臭氧或硝酸等氧化d進行氧化處理而導入（氧化聚烯烴蠟），或可將丙烯酸、曱基丙烯酸、巴豆酸m、反丁烯二酸、分解烏頭酸等乙烯不飽和羧酸單體與聚烯烴蠟以苯等加以溶解，並與聚合引發劑（過氧化物、氧化還原、重金屬催化劑等）一起於氮氣流中加熱並經接枝化而導入。聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均粒徑宜於〇·1μπι〜5·0μηι之範圍内，而使用在1〇μηι〜4〇μιη範圍内者則更為理想。質量平均粒徑未達〇 ·丨μηι時，將因易於凝聚且安定性不佳而使效果不理想。又，若質量平均粒徑超過5·0μηι，則使分散安定性低劣而致效果不理想。此外，質量平均粒徑與數量平均粒徑之比率，宜於質量平均粒徑/數量平均粒徑<3之範圍内。潤滑劑（A )中之聚烯烴蠟分散體及變性聚烯烴纖分散體之質量平均分子量之範圍，宜於6000〜15000之範圍本紙張尺度適用中國國家標準（CNS) A4規格（210X297公釐）(Please read the notes on the back before filling out this page) Those listed in the description of the eight ugly boards. In order to make a coating, it is also preferable to disperse the resin knife in an aqueous solvent to form an emulsion, and it is also advisable to add various cross-linking agents such as melamine resin and amine-based resin as necessary. When considering both performance and cost, acrylic resins such as olefin acrylic copolymers should be prepared. In addition, when strict deep drawing processing is required, and better continuous sliding abrasion resistance of n% is required, ethyl urethane-epoxy resin with both hardness and elongation is used. The silicate compound and colloidal silicon dioxide in the second aspect of the present invention may also be those mentioned in the description of the surface-treated metal plate according to the first aspect. The colloidal silica is 5 to 35% by mass in terms of solid content, and 払 σ is in the aqueous organic-inorganic composite coating of the present invention. If it is less than $% by mass, sufficient corrosion resistance and pressure and wear resistance will not be obtained. If it exceeds 35% by mass, paint adhesion and pressure and wear resistance will be deteriorated. The water-based organic-inorganic composite coating used in the second aspect of the present invention is printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, which is one or both of the aforementioned water-based resins and silicate compounds mixed with a predetermined amount of colloidal silica , Water, and lubricants (A), (B) with different molecular weights. Here, as the lubricant (A), a polyolefin wax dispersion with a molecular weight in the range of 6000 to 15000 is used, and as the lubricant (B), a molecular weight in the range of 10,000 to 5,000 is used. Polyolefin wax dispersion. More preferably, a polyolefin wax dispersion containing no polar group and having a molecular weight in the range of 6,000 to 15,000 and a particle size of 0.001 μm to 5.0 μm, and a molecular weight in the range of 6000 to 15,000, an acid At least one selected from the denatured polyolefin wax dispersions with a value of 40 or less and a particle size of 0.1 μm to 5.0 μm is applicable to the Chinese National Standard (CNS) A4 specification at this paper scale (210 X 297 public copy)- 23- 573062 V. Explanation of the invention (& = Lubricant as lubricant ⑷, and use of polyolefin ant knife polities which do not contain polar groups and in the range of molecular size 22 and particle size G々m ~ 5.G_ as lubrication Agent (B). Μ As a polyolefin dispersion, use polyethylene wax, polypropylene wax, polybutene wax that does not substantially contain polar groups to disperse the emulsifier at a concentration of 5% or less, and preferably not emulsified. In water or aqueous solution of the agent. As a denatured poly (hydrocarbon) sacrifice dispersion, it is used to disperse polar 〇土 ^ ethylene if ~ propylene wax, polybutene wax in an emulsifier concentration of 5 / below 'J « Preferably in water or aqueous solution without emulsifier. Polar group: in catalysis In the presence, the polyolefin wax is introduced by oxidizing d with oxygen, ozone, or nitric acid (oxidizing polyolefin wax), or acrylic acid, fluorenyl acrylic acid, crotonic acid m, fumaric acid, and decomposition can be introduced. Ethylene unsaturated carboxylic acid monomers such as aconitic acid and polyolefin wax are dissolved with benzene, etc., and together with a polymerization initiator (peroxide, redox, heavy metal catalyst, etc.) are heated in a nitrogen stream and introduced by grafting The mass average particle diameter of polyolefin wax dispersion and modified polyolefin wax dispersion should be in the range of 0.1 μm to 5.0 μm, and it is more ideal to use it in the range of 10 μm to 4 μm. Quality When the average particle diameter is less than 0.1 μm, the effect is unsatisfactory due to easy aggregation and poor stability. If the mass average particle diameter exceeds 5.0 μm, the dispersion stability is poor and the effect is not ideal. In addition, the ratio of the mass average particle diameter to the number average particle diameter is preferably within the range of the mass average particle diameter / number average particle diameter < 3. The polyolefin wax dispersion and the modified polyolefin fiber dispersion in the lubricant (A) The mass average molecular weight range should be in the range of 6000 ~ 15000. The paper size is applicable to China National Standard (CNS) A4 (210X297 mm)

.- ----- (請先閲讀背面之注意事項再填寫本頁) 、=& · -24- 573062 五經濟部智慧財產局員工消費合作社印製 A7 B7 發明說明（予内。若質量平均分子量未達6000將導致過軟而無法提高财連續滑動磨耗性。又’若質量平均分子量超過15〇〇〇，則使耐壓磨損性劣化而致效果不理想。潤滑劑（B)中之聚烯烴蠟分散體之質量平均分子量之範圍，宜於1000〜5000之範圍内。若質量平均分子量未達1000將導致易於熱分解’且於使表面曝露於近⑼。溫下之直接火型（direct-fired )乾燥爐中有時將無法獲得充分之潤滑特性，以致效果不理想。又，若平均分子量超過5000，則使耐連續滑動磨耗性劣化而致效果不理想。該等聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均分子量之分析方法及條件，係如本發明第1觀點之表面處理金屬板之相關說明中所述。潤滑劑（A)中之變性聚烯烴蠟分散體之依〗18 κ 59〇2 規定之酸值（KOH-mg/g)之範圍，宜在40以下。若酸值超過40，潤滑劑將過度變硬以致無法獲得充分之潤滑性。進而，潤滑劑（A )中之聚烯烴蠟分散體及變性聚烯烴蠟分散體，宜使依JIS K 6760規定之密度於950kg/m3〜 1000kg/m3範圍内，並使依JIS K 2207規定之硬度（穿透度）在0.2mm以下，而以X射線繞射法求取之結晶度在80%以上，且熔點於110°C〜15(TC之範圍内。該等潤滑劑（A )、（ B)之總含量，宜於水性有機無機複合塗料中摻合有以固體成分換算時為1〜30質量％。若未達1質量％將無法獲得充分之耐連續滑動磨耗性，若超過 3〇質量％則使塗料黏附性劣化，皆非理想之效果。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------I-----^ 11-----^--------- r - (請先閱讀背面之注意事項再填寫本頁) -25- 發明說明（？潤滑劑A相對於潤滑劑（A )、（ B)總含量之含有率，宜於10〜90%之範圍内。較10%少時將無法提高滑動磨耗性。又，較90%多時，耐壓磨損性則較僅有潤滑劑B者劣化’效果並不理想。水性有機無機複合覆膜之附著量範圍以乾態質量計係於〇.3g/m2〜5.0g/m2之範圍内。又以在i.〇g/m2〜3〇g/m2範圍内更為理想。附著量未達〇.3g/m2則目的之耐壓磨損性將劣化，又若超過5.0g/m2，將使焊接困難，效果皆不理想。用以形成本發明第2觀點中之水性有機無機複合覆膜之塗布方法、烘烤溫度、乾燥設備，係如先前有關第丨觀點中之水性有機無機複合覆膜之形成所做之敘述。其次，本發明之第3觀點，係於鍍金屬板之上層首先形成一乾態質量為0.05g/m2〜〇.3g/m2之水性有機無機複合覆膜（c)，以作為第一層，而該水性有機無機複合覆膜（c) 係由水性樹脂及矽酸鹽化合物之一方或兩方，與分子量在 6000〜15000之聚烯烴蠟分散體之潤滑劑（A)構成者，·再形成一乾態質量為0.5g/m2〜5.0g/m2之有機複合覆膜 (D)，以作為第二層，而該有機複合覆膜（13)係由水性樹脂及矽酸鹽化合物之一方或兩方與膠體二氧化矽構成，且該膠體二氧化矽之含量以固體成分換算時為5〜35質量 %者。第3圖所示者係本發明第3觀點中之第1形態之表面處理金屬板之例，第4圖所示者係第2形態之表面處理金屬板之例。 573〇62 A7.- ----- (Please read the precautions on the back before filling this page), = & · -24- 573062 Five-Economy Intellectual Property Bureau Staff Consumer Cooperatives printed A7 B7 Invention Note (inside. If quality If the average molecular weight is less than 6000, it will be too soft to improve continuous sliding abrasion resistance. If the mass average molecular weight exceeds 15,000, the pressure resistance and wear resistance will be deteriorated and the effect will be unsatisfactory. Among lubricants (B) The range of the mass average molecular weight of the polyolefin wax dispersion is preferably in the range of 1000 to 5000. If the mass average molecular weight is less than 1000, it will cause easy thermal decomposition 'and expose the surface to Kinki. Direct fire type at temperature ( direct-fired) In a drying furnace, sufficient lubricating properties may not be obtained, and the effect may be unsatisfactory. If the average molecular weight exceeds 5000, continuous sliding abrasion resistance may be deteriorated and the effect may be unsatisfactory. These polyolefin waxes are dispersed The analysis methods and conditions of the mass average molecular weight of the polymer and the modified polyolefin wax dispersion are as described in the description of the surface-treated metal plate according to the first aspect of the present invention. The range of the acid value (KOH-mg / g) specified in 18 κ 5902 according to the basic polyolefin wax dispersion should preferably be less than 40. If the acid value exceeds 40, the lubricant will become too hard to obtain sufficient Lubricity Further, the polyolefin wax dispersion and the modified polyolefin wax dispersion in the lubricant (A) should preferably have a density in the range of 950 kg / m3 to 1000 kg / m3 in accordance with JIS K 6760, and in accordance with JIS K The hardness (penetration) specified in 2207 is less than 0.2mm, and the crystallinity obtained by the X-ray diffraction method is more than 80%, and the melting point is within the range of 110 ° C ~ 15 (TC.) These lubricants ( The total content of A) and (B) should be 1 to 30% by mass in terms of solid content when blended in water-based organic-inorganic composite coatings. If it does not reach 1% by mass, sufficient continuous sliding wear resistance cannot be obtained, If it exceeds 30% by mass, the adhesion of the coating will be deteriorated, which is not an ideal effect. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------ I ----- ^ 11 ----- ^ --------- r-(Please read the notes on the back before filling this page) -25- Description of the invention (? Lubricant A phase The content ratio of the total content of lubricants (A) and (B) should be in the range of 10 to 90%. When less than 10%, sliding wear resistance cannot be improved. When more than 90%, pressure wear resistance The effect is worse than that of the lubricant B only. The adhesion range of the water-based organic-inorganic composite film is in the dry mass range of 0.3 g / m2 to 5.0 g / m2. .〇g / m2 ~ 30g / m2 is more ideal. The adhesion amount is less than 0.3g / m2, the pressure resistance of the purpose will be deteriorated, and if it exceeds 5.0g / m2, it will make welding difficult and the effect Neither is ideal. The coating method, baking temperature, and drying equipment used to form the water-based organic-inorganic composite film in the second aspect of the present invention are as described in the foregoing regarding the formation of the water-based organic-inorganic composite film in the first aspect. Next, in a third aspect of the present invention, an aqueous organic-inorganic composite film (c) having a dry mass of 0.05 g / m2 to 0.3 g / m2 is first formed on the upper layer of the metal-plated plate as the first layer, and The aqueous organic-inorganic composite coating (c) is composed of one or both of an aqueous resin and a silicate compound, and a lubricant (A) of a polyolefin wax dispersion having a molecular weight of 6000 to 15000. The organic composite coating (D) having a state mass of 0.5 g / m2 to 5.0 g / m2 is used as the second layer, and the organic composite coating (13) is composed of one or both of an aqueous resin and a silicate compound. It is composed of colloidal silicon dioxide, and the content of the colloidal silicon dioxide is 5 to 35% by mass when converted to solid content. The figure shown in Fig. 3 is an example of the surface-treated metal plate of the first form in the third aspect of the present invention, and the figure shown in Fig. 4 is an example of the surface-treated metal plate of the second form. 573〇62 A7

五、發明說明（今於第3圖中，本發明第3觀點中之第1形態之表面處理金屬板，係形成一於鍍金屬板23上具有第1層之水性有機無機複合覆膜（C) 22及第2層之水性有機無機複合覆膜（D) 24之構造。該第1層之水性有機無機複合覆膜（c ) 22係將由水性樹脂及矽酸鹽化合物之一方或兩方，進而由潤滑劑 (A )及水構成之塗料（E )以適當之方法塗布後，經烘烤而形成者，而該第2層之水性有機無機複合覆膜（D) 24係將由水性樹脂及石夕酸鹽化合物之一方或兩方，進而由膠體二氧化矽及水構成之水性有機無機複合塗料（F )以適當之方法塗布後，經烘烤而形成者。於第4圖中，本發明第3觀點中之第2形態之表面處理金屬板，係形成一於鍍金屬板23上具有第1層之水性有機無機複合覆膜（C〇 22及第2層之水性有機無機複合覆膜（D) 24之構造。該第1層之水性有機無機複合覆膜（c') 22係將由水性樹脂及石夕酸鹽化合物之一方或兩方，進而由潤滑劑 (A )及水構成之塗料（E )以適當之方法塗布後，經烘烤而形成者，而該第2層之水性有機無機複合覆膜（D) 24係將由水性樹脂及石夕酸鹽化合物之一方或兩方，進而由膠體二氧化矽及水構成之水性有機無機複合塗料（F)以適當之方法塗布後，經烘烤而形成者。如此，藉由添加分子量業已調節成適當值之聚烯烴蝶分散體而形成水性有機無機複合覆膜（C)或（C')，且於其上層形成水性有機無機複合覆膜（D )，以使蠟自水性有機無機複合覆膜（D )下方朝覆膜表面呈粒狀突出，本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) ▼-装--------訂--------- 經濟部智慧財產局員工消費合作社印製 -27-V. Description of the invention (now in Figure 3, the first form of the surface-treated metal plate in the third aspect of the present invention is to form a water-based organic-inorganic composite film with a first layer on the metal-plated plate 23 (C ) 22 and the structure of the water-based organic-inorganic composite film (D) 24 of the second layer. The water-based organic-inorganic composite film (c) 22 of the first layer is composed of one or both of the water-based resin and the silicate compound. Furthermore, the coating (E) composed of the lubricant (A) and water is applied by an appropriate method and then formed by baking, and the second layer of the water-based organic-inorganic composite film (D) 24 is composed of an aqueous resin and One or both of the oxalate compounds, and the water-based organic-inorganic composite coating (F) composed of colloidal silicon dioxide and water are formed after being coated by an appropriate method, and then formed by baking. The second aspect of the surface-treated metal plate of the third aspect of the invention is to form a water-based organic-inorganic composite film (C02 and a second-layer water-based organic-inorganic composite film) on the metal plate 23 with a first layer. (D) Structure of 24. Water-based organic-inorganic composite of the first layer The film (c ') 22 is formed by coating one or both of the water-based resin and the oxalate compound, and further the coating material (E) composed of the lubricant (A) and water by an appropriate method, followed by baking. The water-based organic-inorganic composite coating (D) 24 of the second layer is an aqueous organic-inorganic composite coating composed of one or both of water-based resin and oxalate compound, and further composed of colloidal silica and water (F ) After being coated by an appropriate method and formed by baking. In this way, an aqueous organic-inorganic composite film (C) or (C ') is formed by adding a polyolefin butterfly dispersion whose molecular weight has been adjusted to an appropriate value, and A water-based organic-inorganic composite coating (D) is formed on the upper layer so that the wax protrudes from the bottom of the water-based organic-inorganic composite coating (D) toward the surface of the coating in a granular manner. 210 X 297 mm) (Please read the precautions on the back before filling out this page) ▼ -Packing -------- Order --------- Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -27-

同時並可控㈣之硬度及覆膜表面之親和力。進而，調節水性有機無機複合覆膜（D)中二氧化碎之含有率以圖覆膜硬度與耐蝕性或黏附性等覆膜性能之互適化。如此一來’即可製知-種不僅具有良好之耐钱性或黏附性，並可控制動摩擦係數於0.07〜〇.15之範圍内，且靜摩擦係數在 0.10以上之具優異耐壓磨損性與耐線圈變形性，進而可抑制於壓製時潤滑劑自覆膜脫落而引起黏附性殘渣產生之表面處理金屬板。以下，說明本發明第3觀點之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法。該製造方法除使用之水性有機無機複合塗料不同，且形成有2層水性有機無機複合覆膜外，基本上亦與第丨觀點之表面處理金屬板之製造方法相同。可應用之表面鑛敷金屬板係如先前第丨觀點之表面處理金屬板所做之說明。各鍍金屬板中之鍍敷附著量以單面在lg/m2以上為宜，若低於此則耐蝕性降低。於鍍金屬板上施予以提升黏附性或耐蝕性等為目的之表面處理後，即可形成水性有機無機複合覆膜，或亦可不施表面處理而直接形成水性有機無機複合覆膜。該表面處理並無特別之規疋/、要爿b達成上述目的即可，但一般而言以可提升耐餘性或黏附性之鉻酸鹽處理較為理想。鉻酸鹽覆膜之形成方法及鉻酸鹽附著量則如先前第1觀點之表面處理金屬板所做之說明。作為水性樹脂者，亦可使用先前針對第丨觀點之表面處 (請先閱讀背面之注意事項再填寫本頁) ----訂--------- 經濟部智慧財產局員工消費合作社印製At the same time, the hardness of the radon and the affinity of the film surface can be controlled. Furthermore, the content ratio of the pulverized dioxide in the water-based organic-inorganic composite coating (D) was adjusted so as to adapt the coating hardness and coating performance such as corrosion resistance or adhesion. In this way, you can know-a kind that not only has good money resistance or adhesion, and can control the dynamic friction coefficient in the range of 0.07 to 0.15, and the static friction coefficient of 0.10 or more has excellent pressure wear resistance and Coil deformation resistance, which can further suppress the surface-treated metal plate that causes the adhesive residue from falling off from the film during pressing. Hereinafter, a method for producing a surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance according to the third aspect of the present invention will be described. This manufacturing method is basically the same as the method for manufacturing a surface-treated metal plate according to the first aspect, except that the water-based organic-inorganic composite coating is different and a two-layer water-based organic inorganic composite coating is formed. Applicable surface metallized metal plates are as described in the surface treatment metal plate of the previous point. The plating adhesion amount in each metal-plated plate is preferably lg / m2 or more on one side, and if it is less than this, the corrosion resistance is reduced. After applying a surface treatment on the metal plate to improve adhesion or corrosion resistance, an aqueous organic-inorganic composite film can be formed, or an aqueous organic-inorganic composite film can be directly formed without surface treatment. There are no special rules for this surface treatment 疋 /, as long as 目的 b can achieve the above purpose, but in general, it is ideal to use a chromate treatment that can improve the residual resistance or adhesion. The method for forming the chromate film and the amount of chromate deposition are as described in the surface-treated metal plate of the first aspect. As a water-based resin, you can also use the surface of the previous point of view (please read the precautions on the back before filling out this page) ---- Order --------- Consumption by the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by a cooperative

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐 -28-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm -28-

經濟部智慧財產局員工消費合作社印製 73〇62Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 73〇62

Lt屬板之說明中所舉出者。為作成塗料，同樣宜使樹脂溶媒中而形成乳液，並宜視必要而添加三聚氛子月曰基樹脂等各種交聯冑。本發明之第3觀點中，係 :選擇親水性高之樹脂作為第—層使用之水性樹脂較為理 # #為第—層使用之樹脂者，若特別將性能與成本 :面考慮在内時’則宜使用稀烴-丙稀酸共聚物等丙稀酸系樹月曰此外而嚴格之深拉加工時，且則宜使用硬度與伸長性兼備之胺基甲酸乙酯-環氧系樹脂。本發明第3觀點所用之矽酸鹽化合物與膠體二氧化矽，亦可使用先前第丨觀點之表面處理金屬板所舉出者。膠體二氧化矽係呈以固體成分換算時為5〜35質量％而摻合於本發明之水性有機無機複合塗料（F )中。若未滿5質量％將無法獲得充分之耐蝕性及耐壓磨損性，若超過 35質量％則使塗料黏附性及耐壓磨損性劣化。本發明之第3觀點中，係將前述水性樹脂及矽酸鹽化合物之一方或兩方，膠體二氧化矽、水、及潤滑劑（A )與 (B) ’以預定量摻合於水性有機無機複合塗料（e)中而加以使用。於此，作為潤滑劑（A )者係使用分子量在6000 〜15000範圍内之聚烯烴蠟分散體，而作為潤滑劑（b)者係使用分子量在1000〜5000範圍内之聚烯烴蠟分散體。更理想者係，使用由不含極性基且分子量在6000〜15000範圍内、粒徑為0.1 μιη〜5.0 μιη之聚稀煙鐵分散體’與分子量在 6000〜15000範圍内、酸值在40以下、且粒徑為〇·1μηι〜 5·0μπι之變性聚烯烴蠟分散體中選出之至少1種以上之潤本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）Lt is listed in the description of the board. In order to make a coating, it is also desirable to form an emulsion in a resin solvent, and to add various cross-linking agents such as a trimer resin, if necessary. In the third aspect of the present invention, it is more reasonable to select a resin with high hydrophilicity as the water-based resin used in the first layer. # #For resins used in the first layer, if performance and cost are specifically considered: When using acrylic resins such as dilute hydrocarbon-acrylic acid copolymers in addition to strict deep drawing processing, it is also appropriate to use urethane-epoxy resins with both hardness and elongation. The silicate compound and colloidal silica used in the third aspect of the present invention can also be those listed in the surface-treated metal plate of the previous aspect. The colloidal silicon dioxide is 5 to 35% by mass in terms of solid content, and is blended in the aqueous organic-inorganic composite coating (F) of the present invention. If it is less than 5% by mass, sufficient corrosion resistance and pressure and wear resistance will not be obtained. If it exceeds 35% by mass, paint adhesion and pressure and wear resistance will be deteriorated. In the third aspect of the present invention, one or both of the aforementioned water-based resin and silicate compound, colloidal silica, water, and lubricants (A) and (B) 'are blended in a predetermined amount in an aqueous organic compound. It is used for an inorganic composite coating material (e). Here, as the lubricant (A), a polyolefin wax dispersion having a molecular weight in the range of 6000 to 15000 is used, and as the lubricant (b), a polyolefin wax dispersion having a molecular weight in the range of 1000 to 5000 is used. More preferably, a poly-smoky iron dispersion containing no polar group and having a molecular weight in the range of 6000 to 15000 and a particle size of 0.1 μm to 5.0 μm ′ and a molecular weight in the range of 6000 to 15000 and an acid value of 40 or less And at least one selected from the modified polyolefin wax dispersions with a particle size of 0.1 μm to 5.0 μm. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm).

-29- 五、發明說明（夕滑劑作為潤滑劑（A)，並使用不含極性基且分子量在1〇〇〇 5000範圍内、粒徑為〇1μιη〜5 〇_之聚烯烴蠟分散體作為潤滑劑（Β )。作為聚烯烴蠟分散體者，係使用令實質上不含極性基 =聚乙烯蠟、聚丙烯蠟、聚丁烯蠟分散於乳化劑濃度在5 %以下，且最好不具乳化劑之水或水溶液中者。又，作為變性聚烯烴蠟分散體者，係使用將不含極性 ^之聚乙烯蠟、聚丙烯蠟、聚丁烯蠟分散於乳化劑濃度在5 %以下，且最好不具乳化劑之水或水溶液中者。極性基係 :於催化劑存在下，藉由將聚烯烴蠟以氧、臭氧或硝酸等氧化劑進行氧化處理而導入（氧化聚烯烴蠟），或可將丙婦酸、甲基丙稀酸、巴豆酸、順丁烯二酸、反丁稀二酸、刀解烏頭酸等乙烯不飽和羧酸單體與聚烯烴蠟以苯等加以溶解，並與聚合引發劑（過氧化物、氧化還原、重金屬催化劑等）一起於氮氣流中加熱並經接枝化而導入。經濟部智慧財產局員工消費合作社印製-29- V. Description of the invention (Even slip agent as lubricant (A), and use of polyolefin wax dispersion without polar group, molecular weight in the range of 100005000, particle size of 〇1μιη ~ 5 〇_ As a lubricant (B). As a polyolefin wax dispersion, it is best to disperse the polar group = polyethylene wax, polypropylene wax, polybutene wax in an emulsifier concentration of 5% or less. In water or aqueous solution without emulsifier. Also, as the denatured polyolefin wax dispersion, use polyethylene wax, polypropylene wax, polybutene wax that does not contain polar ^ in the emulsifier concentration of 5% or less. , And preferably in water or aqueous solution without emulsifier. Polar group: In the presence of a catalyst, the polyolefin wax is introduced by oxidation treatment with oxygen, ozone or nitric acid (oxidized polyolefin wax), or Ethylene unsaturated carboxylic acid monomers such as acetic acid, methyl acrylic acid, crotonic acid, maleic acid, fumaric acid, and acanthic acid and polyolefin wax can be dissolved with benzene, etc., and With polymerization initiator (peroxide, redox, heavy gold Catalysts, etc.) were heated together in a stream of nitrogen and introduced by grafting of Economic Affairs Intellectual Property Office employees consumer cooperatives printed

潤滑劑（A )中之聚烯烴蠟分散體及變性聚烯烴蠟分放體之質量平均粒徑宜於〇liim〜5〇^m之範圍内，而使用在Ι.Ομηι〜4·0μπι範圍内者則更為理想。又，潤滑劑（A) 之粒徑係使用較上層所形成之水性有機無機複合覆膜（D ) 之膜厚大者。潤滑劑（A)之質量平均粒徑未達〇1卜111時，將因易於凝聚且安定性不佳而使效果不理想。又，潤滑劑 (A)之質量平均粒徑較上層所形成之水性有機無機複合覆膜（D)小時，將因耐壓磨損性劣化而使效果不理想。此外，若質量平均粒徑超過5 〇μηι，則使分散安定性低劣The mass average particle diameter of the polyolefin wax dispersion and the modified polyolefin wax dispersion in the lubricant (A) is preferably in the range of oliim to 50m, and used in the range of 1.0 μm to 4.0 μm. The other is more ideal. The particle diameter of the lubricant (A) is the one having a larger film thickness than the aqueous organic-inorganic composite film (D) formed in the upper layer. When the mass average particle diameter of the lubricant (A) is less than 0.11 to 111, the effect is unsatisfactory due to easy aggregation and poor stability. In addition, when the mass average particle diameter of the lubricant (A) is smaller than that of the aqueous organic-inorganic composite coating (D) formed in the upper layer, the pressure-resistant abrasion resistance deteriorates and the effect is not satisfactory. In addition, if the mass average particle diameter exceeds 50 μηι, the dispersion stability is poor.

本紙張尺度_ t關家鮮（CNS)A4規格（21〇 297公釐） 573062 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（亨而致效果不理想。另，質量平均粒徑與數量平均粒徑之比率，宜於質量平均粒徑/數量平均粒徑<3之範圍内。潤滑劑（B )中之聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均粒徑宜於〇.1μηι〜3〇(lm之範圍内。又，潤滑劑（B )之粒徑係使用較上層所形成之水性有機無機複合覆膜（D )之膜厚小者。質量平均粒徑未達〇·丨μιη時，將因易於凝聚且安定性差而使效果不理想。此外，質量平均粒徑超過3·0μιη時，或使用粒徑較水性有機無機複合覆膜 (D )之膜厚大之潤滑劑（β )時，則使耐線圈變形性低劣而致效果不理想。潤滑劑（A )中之聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均分子量之範圍，宜於6〇〇〇〜15000之範圍内。若質量平均分子量未達6000將致耐線圈變形性不良而使效果不理想。又，若質量平均分子量超過丨5〇〇〇 ,則使耐壓磨損性劣化而致效果不理想。潤滑劑（B )中之聚烯烴躐分散體之質量平均分子量之範圍，宜於1000〜5000之範圍内。若質量平均分子量未達1000將導致易於熱分解，且於使表面曝露於近1〇〇〇c>c高溫下之直接火型乾燥爐中有時將無法獲得充分之潤滑特性，以致效果不理想。又，若平均分子量超過5000，則因無法獲得藉由添加潤滑劑B而再提升耐壓磨損性之效果，以致效果不理想。該等聚烯烴蠟分散體及變性聚烯烴蠟分散體之質量平均分子量之分析方法及條件，係如先前本發明第1觀點之表 ^-t--------tr--------- (請先閱讀背面之注意事項再填寫本頁) -31- 573062 經濟部智慧財產局員工消費合作社印製 A7 _____B7_____ 五、發明說明（予面處理金屬板之相關說明中所述。潤滑劑（A )中之變性聚烯烴蠟分散體之依JISK 5902規定之酸值（KOH-mg/g) 之範圍，宜在40以下。若酸值超過40，潤滑劑將過度變硬以致無法獲得充分之潤滑性。進而，潤滑劑（A)中之聚烯烴蠟分散體及變性聚烯烴蠟分散體，宜使依JISK 6760規定之密度於950kg/m3〜 1000kg/m3範圍内，並使依JISK 2207規定之硬度（穿透度）在0.2麵以下，而以X射線繞射法求取之結晶度在80%以上，且熔點於11(TC〜150。(：之範圍内。潤滑劑（A )之含量，或潤滑劑（A )及（B )之總含量，於水性有機無機複合塗料中以固體成分換算時宜為2 〜60質量％。若未達2質量％將無法獲得充分之耐壓磨損性，若超過60質量％則使塗料黏附性劣化，皆非理想之效果。水性有機無機複合覆膜（C )之附著量範圍以乾態質量計係於0.05g/m2〜0.3g/m2之範圍内。又以在0.05g/m2〜 0.2g/m2範圍内更為理想。附著量未達0.05g/m2則目的之耐壓磨損性將劣化，又若超過〇.3g/m2，則浸潤性將降低而難以形成上層覆膜，效果皆不理想。水性有機無機複合覆膜 (D )之附著量範圍以乾態質量計係於〇 5g/m2〜5 〇g/m2之範圍内。又以在1 .Og/m2〜3.0g/m2範圍内更為理想。附著量未達0.5g/m2則目的之耐壓磨損性將劣化，又若超過 5.0g/m2，將使焊接困難，效果皆不理想。用以形成本發明第3觀點中之水性有機無機複合覆膜本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公髮） (請先閱讀背面之注意事項再填寫本頁) ▼-裝--------訂--------- -32- 573062 A7 ------- B7 五、發明說明（，之塗布方法、烘烤溫度、乾燥設備，係如先前有關第1觀點中之水性有機無機複合覆膜之形成所做之敘述。本發明第3觀點之表面處理金屬板之表面動摩擦係數宜於0.07〜0.1 5之範圍内，而靜摩擦係數宜在0·10以上。動摩擦係數高於0· 1 5時將使耐壓磨損性不佳，而動摩擦係數低於0.07時及靜摩擦係數低於〇·丨〇時，則使耐線圈變形性低劣，效果皆不理想。實施例以下，係藉由實施例及比較例以具體說明本發明，但本發明並非以該等實施例為限。首先，說明本發明第1觀點之例。 (1)藥劑之種類於表1顯示所用藥劑之一覽表。除D1與D8外之聚烯烴壤为散體’其依JISK 6760規定之密度為950kg/m3〜 1000kg/m3，依JISK 2207規定之硬度（穿透度）在〇.2mm以下，而以X射線繞射法求取之結晶度在80%以上，且熔點於110°C〜150°C之範圍内。 1 I ^-t--------tr--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -33- 573062 A7 B7 五、發明說明（今表1 藥劑一覽表藥劑種類編號 - 商品名有機樹脂 A1 丙碎酸Μ月曰（東亞合成社製、AP_i5〇8(i2)) A2 1稀系水性樹脂（東邦化學工業製、aR-2300 ) A3 來胺& T酸乙酯系水性樹脂（Nippon_NSC製、RA-85 ) A4 環氧系.7M生樹脂（大曰本INK製、迪克范《音譯f、彳y夕7 7彳y》EM-60) 矽酸鹽化合物 B1 it矽酸鹽 ---- B2 鈉矽酸鹽 B3 鉀矽酸鹽膠體二氧化矽 C1 水性膠體一氧化矽（日產化學製、商品名：司諾提克斯（音譯スy一テック只》N) C2 水性膠體一氧化矽（B產化學製、商品名：司諾提克斯《音譯スy一テックUP) 聚烯烴蠟分散體 D1 聚乙烯C分子量：1000、酸值·· 〇、粒徑：3.0μιη) D2 聚乙烯（分子量：6〇〇〇、酸值：0、粒徑：3.0μιη) D3 聚乙烯（分子量：8000、酸值：〇、粒徑：3 0μπι) D4 聚乙烯（分子量：15〇〇〇、酸值：〇、粒徑：3 〇μιη) D5 聚乙烯（分子量：2〇〇〇〇、酸值：〇、粒徑：3 〇μηι) D6 聚乙烯（分+重：6000、酸值：〇、粒徑：〇 1 ) D7 聚乙烯（分子量：6000、酸值：〇、粒徑：5·0μΓη) D8 變性聚乙烯（分子量：1〇〇〇、酸值：20、粒徑：ι·〇μιη) D9 變性聚乙稀（分子量：6000、酸值：20、粒徑：Ι.Ομιη) D10 變性聚乙烯（分子量：8000、酸值：20、粒徑：Ι.Ομηι) D11 變性聚乙烯（分子量：15〇〇〇、酸值：20、粒徑：Ι.Ομηι) D12 變性聚乙烯（分子量：20000、酸值：20、粒徑：1_〇μπι) D13 變性聚乙烯（分子量：6000、酸值：20、粒徑：〇·1 μηι) D14 變性聚乙烯（分子量：6000、酸值：20、粒徑：5.〇um) D15 變性聚乙烯（分子量：6000、酸值：40、粒徑：Ι.Ομηι) D16 變性聚乙烯（分子量：6000、酸值：1〇〇、粒徑：ΐ·〇μΐη) (2 )金屬板之種類金屬板係使用表2所示者。表2 金屬板之種類與鍍敷附著量（板厚：〇.8腿） --------I--裝--------訂--------- * - (請先閱讀背面之注意事項再填寫本頁} 經濟部智慧財產局員工消費合作社印製簡碼金屬板之種類 EG _電解鋅鍍鋅鋼板（鍍敷附著量：20g/m2) ZN 一電解鋅鍍鎳鋼板（鍍敷附著量：20g/m2、鎳含有率：I2wt% ) GI 熱浸鍍鋅鋼板（鍍敷附著量：60g/m2) (3 )鉻酸鹽處理對於表2所示之EG及ZN，係於鉻酸50g/l及硫酸〇.3g/l 之浴中，以10A/dm2之電流密度通過預定之電量而施以電解型鉻酸鹽處理，並經水洗後利用熱風乾燥爐而以到達板本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -34- 573062 A7 --------B7__ 五、發明說明（$ 溫8 0 C加以乾燥。關於表2所示之GI，則係於塗布摻合有Si02/Cr03比為3 之還原率40%之還原鉻酸與二氧化矽的鉻酸鹽處理液後，不經水洗而乾燥。絡酉欠鹽覆膜之附著量係藉由螢光X射線分析，並以Cr 換算後而定量。 (4 )水性有機無機複合塗料之調製將表1所示之水性樹脂與矽酸鹽化合物之一方或兩方、膠體二氧化矽及聚烯烴蠟分散體，以表4〜6所示之比率加以摻合，而調製成水性有機無機複合塗料。 (5)水性有機無機複合塗料之塗布·乾燥方法於（3)所示之業經施以鉻酸鹽處理之鍍金屬板上，塗布以（4 )凋製且乾態質量成表4〜6所示之值之水性有機無機複合塗料，並以到達板溫14(rc進行烘烤乾燥後製成評價用樣本。此外，有機複合覆膜之附著量係藉由權重法 (weighing meth〇d)測定塗布時之液膜量而算出。 (6 )性能評價項目 a·平板耐蝕性將以（5)製成之評價用樣本，依JISZ 2371m載之鹽水喷霧試驗方法進行實驗，並於環境溫度35它下，將5%之 NaCl水溶液噴於塗裝鋼板試料上，並測定”小時後之白銹產生率。以下之評價中，◎及〇係判定為良好。 ◎:無白銹產生〇··白銹產生率未達10% 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公楚） Γ%先閱讀背面之注意事項再填寫本頁} — 丨 — _ -丨丨訂--------- 經濟部智慧財產局員工消費合作社印製 -35- 經濟部智慧財產局員工消費合作社印製 573062 A7 -----21^____ 五、發明說明（予 △:白銹產生率在10%以上，且未達50% x:白銹產生率在50%以上 b.加工部耐姓性於以（5)製成之評價用樣本試驗片上施以_之埃里克森（Edchsen)加工，並依JISZ 2371所載之鹽水喷霧試驗方法，於環境溫度35X：下，將5%2NaC1水溶液喷於塗裝鋼板試料上，並測定48小時後加工部中之白銹產生率。以下之評價中，◎及〇係判定為良好。 ◎:無白銹產生〇：白銹產生率未達5% △.白錄產生率在5%以上，且未達2〇% x :白銹產生率在20%以上 c·塗料黏附性於以（5 )製成之評價用樣本上，再以桿塗機塗布三聚亂胺醇酸樹脂塗料（關西paint製、阿米拉克《音古睪· 了 ' 7 V夕》#1000 )並使乾燥膜厚達25μιη，且於爐溫下烘烤20分鐘。其次，在放置！晚後，對浸潰於沸騰水中3〇分鐘者與不做該程序者施以7腿埃里克森加工，並將膠帶 (NICHIBAN(株）：商品名Cello-Tape)貼於試驗片之埃里克森加工部上。將膠帶迅速朝傾斜45°之方向拉伸，並以目視評價埃里克森加工部之外觀。以下之評價中，◎及〇係判定為良好。 ◎:無剝離情形〇：剝離面積率未達5% 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 χ 297公釐） 1 I-----^--------tr--------- Λ I (請先閱讀背面之注意事項再填寫本頁) -36- 573062Size of this paper _ t Guan Jiaxian (CNS) A4 specification (21,297 mm) 573062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The ratio of the diameter to the number average particle diameter is preferably in the range of mass average particle diameter / number average particle diameter < 3. The mass average particle diameter of the polyolefin wax dispersion and the modified polyolefin wax dispersion in the lubricant (B) The diameter should be in the range of 0.1 μm to 30 (lm.), And the particle size of the lubricant (B) is the one with a smaller film thickness than the water-based organic-inorganic composite coating (D) formed by the upper layer. Mass-average particles When the diameter is less than 〇 μm, the effect is not ideal due to easy aggregation and poor stability. In addition, when the mass average particle size exceeds 3.0 μm, or using a film with a larger particle diameter than the water-based organic-inorganic composite film (D) A thick lubricant (β) results in poor coil deformation resistance, resulting in unsatisfactory results. The mass average molecular weight range of the polyolefin wax dispersion and the modified polyolefin wax dispersion in the lubricant (A) is appropriate. At 600 ~ 15000 Within the range. If the mass average molecular weight is less than 6000, the coil deformation resistance will be poor and the effect will be unsatisfactory. If the mass average molecular weight exceeds 5,000, the pressure wear resistance will be deteriorated and the effect will be unsatisfactory. Lubrication The mass average molecular weight of the polyolefin fluorene dispersion in the agent (B) is preferably in the range of 1000 to 5000. If the mass average molecular weight is less than 1000, it will cause easy thermal decomposition and expose the surface to nearly 100%. 〇c> c In direct-fired drying furnaces at high temperatures, sufficient lubricating properties may not be obtained, resulting in unsatisfactory results. If the average molecular weight exceeds 5000, it is not possible to increase the resistance by adding lubricant B. The effect of compressive abrasion makes the effect unsatisfactory. The analysis methods and conditions for the mass average molecular weight of these polyolefin wax dispersions and denatured polyolefin wax dispersions are as shown in the table of the first aspect of the present invention ^ -t-- ------ tr --------- (Please read the notes on the back before filling out this page) -31- 573062 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _____B7_____ V. Description of the invention ( Give It is described in the relevant description of the surface-treated metal plate. The range of the acid value (KOH-mg / g) of the modified polyolefin wax dispersion in the lubricant (A) according to JISK 5902 should be less than 40. If the acid value If it exceeds 40, the lubricant will become too hard to obtain sufficient lubricity. Furthermore, the polyolefin wax dispersion and the modified polyolefin wax dispersion in the lubricant (A) should preferably have a density of 950 kg / in accordance with JISK 6760. m3 ~ 1000kg / m3, and make the hardness (penetration) according to JISK 2207 less than 0.2, and the crystallinity obtained by X-ray diffraction method is more than 80%, and the melting point is 11 (TC ~ 150. (: Within the range. The content of the lubricant (A), or the total content of the lubricants (A) and (B), should be 2 to 60% by mass in terms of solid content in the water-based organic-inorganic composite coating. If it does not reach 2% by mass will not be able to obtain sufficient pressure wear resistance, and if it exceeds 60% by mass, the adhesion of the coating will be deteriorated, which is not an ideal effect. The adhesion range of the water-based organic-inorganic composite film (C) is based on dry mass. It is in the range of 0.05g / m2 ~ 0.3g / m2. It is more preferable to be in the range of 0.05g / m2 ~ 0.2g / m2. If the amount of adhesion is less than 0.05g / m2, the pressure wear resistance of the purpose will be deteriorated, If it exceeds 0.3g / m2, the wettability will decrease and it will be difficult to form an upper layer film, and the effect will be unsatisfactory. The range of the adhesion amount of the water-based organic-inorganic composite film (D) is based on the dry mass at 05g / m2 Within the range of ~ 50 g / m2. It is more desirable to range from 1.0 g / m2 to 3.0 g / m2. If the amount of adhesion is less than 0.5 g / m2, the pressure wear resistance of the purpose will be deteriorated, and if it exceeds 5.0g / m2 will make welding difficult and the effects are not ideal. It is used to form the water-based organic-inorganic composite film in the third aspect of the present invention. Paper size applies to China National Standard (CNS) A4 specifications (210 X 297) (please read the precautions on the back before filling this page) ▼ -Packing -------- Order ------- --32- 573062 A7 ------- B7 V. Description of the invention (The coating method, baking temperature, and drying equipment are the same as the formation of the water-based organic-inorganic composite film in the first point of view. The surface friction coefficient of the surface-treated metal plate according to the third aspect of the present invention should be in the range of 0.07 to 0.1 5 and the static friction coefficient should be above 0 · 10. When the dynamic friction coefficient is higher than 0 · 15, the resistance The pressure wear resistance is not good, and when the dynamic friction coefficient is less than 0.07 and the static friction coefficient is less than 0 · 丨〇, the coil deformation resistance is poor, and the effects are not ideal. The following examples are based on the examples and comparative examples. The present invention will be specifically described, but the present invention is not limited to these examples. First, an example of the first aspect of the present invention will be described. (1) Types of medicines Table 1 shows a list of the medicines used. Except for D1 and D8 The olefin soil is a dispersion ', and its density according to JISK 6760 is 950kg / m3 ~ 1000kg / m3, The hardness (penetration) specified by JISK 2207 is 0.2 mm or less, and the crystallinity obtained by the X-ray diffraction method is more than 80%, and the melting point is in the range of 110 ° C to 150 ° C. 1 I ^ -t -------- tr --------- (Please read the notes on the back before filling out this page) Printed on paper standards of the Ministry of Economic Affairs and Intellectual Property Bureau's Consumer Cooperatives, this paper applies Chinese national standards (CNS) A4 specifications (210 X 297 mm) -33- 573062 A7 B7 V. Description of the invention (present table 1 Pharmacy List Pharmacy Type Number-Trade name Organic Resin A1 Propionic acid M Yue Yue (manufactured by Toa Synthetic Corporation, AP_i5 〇8 (i2)) A2 1 dilute water-based resin (manufactured by Toho Chemical Industry Co., Ltd., aR-2300) A3 lysine & T ethyl acetate water-based resin (manufactured by Nippon_NSC, RA-85) A4 epoxy resin. 7M raw resin (Made by Daikoku INK, Dick Fan "Transliteration f, 彳 yeven 7 7 彳 y" EM-60) Silicate compound B1 it silicate ---- B2 sodium silicate B3 potassium silicate colloid two Silica C1 Hydrocolloid Silicon Monoxide (manufactured by Nissan Chemical Co., Ltd., trade name: Snotex (N)) C2 hydrocolloid silicon monoxide (produced by B System, product name: SNOTIX "Transliteration Sy-Tech UP" Polyolefin Wax Dispersion D1 Polyethylene C Molecular Weight: 1000, Acid Value · 〇, Particle Size: 3.0 μm) D2 Polyethylene (Molecular Weight: 6 00, acid value: 0, particle size: 3.0 μm) D3 polyethylene (molecular weight: 8000, acid value: 0, particle size: 30 μm) D4 polyethylene (molecular weight: 150,000, acid value: 0, Particle size: 3 μm) D5 polyethylene (molecular weight: 2000, acid value: 0, particle size: 3 μm) D6 polyethylene (min. + Weight: 6000, acid value: 0, particle size: 0) 1) D7 polyethylene (molecular weight: 6000, acid value: 0, particle size: 5.0 μΓη) D8 modified polyethylene (molecular weight: 1000, acid value: 20, particle size: ι · 〇μιη) D9 modified poly Ethylene (Molecular weight: 6000, Acid value: 20, Particle size: 1.0 μm) D10 Modified polyethylene (Molecular weight: 8000, Acid value: 20, Particle size: 1.0 μm) D11 Modified polyethylene (Molecular weight: 1 500) 〇, acid value: 20, particle size: 1.0 μηι) D12 modified polyethylene (molecular weight: 20000, acid value: 20, particle size: 1_〇μπι) D13 modified polyethylene (molecular weight: 6000, acid value: 20, particle size: 0.1 μm) D14 modified polyethylene (molecular weight: 6000, acid value: 20, particle size: 5.0 μm) D15 modified polyethylene (molecular weight : 6000, acid value: 40, particle size: 1.0 μηι) D16 modified polyethylene (molecular weight: 6000, acid value: 100, particle diameter: ΐ · 〇μΐη) (2) Types of metal plates Metal plates are used Shown in Table 2. Table 2 Types of metal plates and plating adhesion (plate thickness: 0.8 legs) -------- I--installation -------- order --------- *-(Please read the precautions on the back before filling this page} Types of metal plates printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs EG _ electrolytic zinc galvanized steel (plating adhesion: 20g / m2) ZN 1 Electrolytic zinc-plated steel sheet (plating deposit: 20g / m2, nickel content: I2wt%) GI hot-dip galvanized steel sheet (plating deposit: 60g / m2) (3) Chromate treatment EG and ZN are in a bath of 50 g / l of chromic acid and 0.3 g / l of sulfuric acid, and are subjected to electrolytic chromate treatment at a current density of 10 A / dm2 through a predetermined amount of electricity, and then washed with hot air. Drying furnace to reach the paper size of the board applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -34- 573062 A7 -------- B7__ V. Description of the invention ($ temp 8 0 C Drying. The GI shown in Table 2 is a chromate treatment solution in which a reduced chromic acid and silicon dioxide with a reduction ratio of 40% in a Si02 / Cr03 ratio of 3 is applied, and then dried without washing. The amount of adhesion of the under-salt coating Fluorescent X-ray analysis and quantification after conversion to Cr. (4) Preparation of water-based organic-inorganic composite coatings One or both of the water-based resins and silicate compounds shown in Table 1, colloidal silicon dioxide and polymer The olefin wax dispersion is blended at the ratios shown in Tables 4 to 6 to prepare an aqueous organic-inorganic composite coating. (5) The coating and drying method of the aqueous organic-inorganic composite coating is applied as shown in (3). The chromate-treated metal-plated plate is coated with (4) water-based organic-inorganic composite coating with a dry mass of the values shown in Tables 4 to 6, and is baked and dried at a plate temperature of 14 (rc). Samples for evaluation were prepared. In addition, the adhesion amount of the organic composite film was calculated by measuring the amount of the liquid film at the time of coating using a weighting method. (6) Performance evaluation item a · The corrosion resistance of the plate will be ( 5) The prepared evaluation sample was tested in accordance with the JISZ 2371m salt water spray test method, and at a temperature of 35 ° C, a 5% NaCl aqueous solution was sprayed on the coated steel plate sample, and the measurement was performed after "hours." White rust generation rate. In the following evaluations, ◎ and 〇 is judged to be good. ◎: No white rust is generated. ‧ The white rust generation rate is less than 10%. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 cm). Γ% Read the precautions on the back first. Refill this page} — 丨 — _-丨丨 Order --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -35- Printed by the Employee Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 573062 A7 --- --21 ^ ____ V. Description of the invention (Presentation △: White rust generation rate is above 10% and less than 50% x: White rust generation rate is above 50% b. The survivability of the processing department is based on (5) system A sample test piece for evaluation was processed by Edchsen and sprayed with a 5% 2NaC1 aqueous solution at a temperature of 35X: in accordance with the salt water spray test method contained in JISZ 2371. On the sample, the white rust generation rate in the processed portion after 48 hours was measured. In the following evaluations, ◎ and 系 were judged to be good. ◎: No white rust is generated. 0: The white rust generation rate is less than 5%. △. The white record generation rate is more than 5% and less than 20%. X: The white rust generation rate is more than 20%. (5) The prepared evaluation sample was coated with a melamine resin coating (manufactured by Kansai paint, Amirak, "Otogura ·" V 7 "# 1000) by a bar coater, and dried. The film thickness was 25 μm, and it was baked at the oven temperature for 20 minutes. Secondly, during placement! Later, those who were immersed in boiling water for 30 minutes and those who did not perform the procedure were given 7-leg Eriksson processing, and tape (NICHIBAN (trade name: Cello-Tape)) was applied to the test piece. On the rickson processing department. The tape was rapidly stretched in a direction inclined at 45 °, and the appearance of the Eriksson processed portion was visually evaluated. In the following evaluations, ◎ and 〇 were judged to be good. ◎: No peeling condition 〇: The peeling area ratio is less than 5%. The paper size is applicable to the Chinese National Standard (CNS) A4 (21〇χ 297 mm) 1 I ----- ^ -------- tr --------- Λ I (Please read the precautions on the back before filling out this page) -36- 573062

五、發明說明（y 經濟部智慧財產局員工消費合作社印製 △:剝離面積率在5%以上，且未達50% χ :剝離面積率在50%以上 d.可連續焊接性將以（5)製成之樣本以表3所示之條件進行連續點烊試驗，並於穩定後求得可形成熔核直徑在3腿+以上之打點數表3 焊接條件項目焊接電流 8500A 通電時間 1〇週期（以50Hz) 電極前端直徑 4·5πιπιφ 電極外加壓力 200kgf 以下之評價中，◎及〇係判定為良好。 ◎:打點數在5000以上〇：打點數在2500以上且未達5〇〇〇 △:打點數在1000以上且未達2500 x :打點數未達1000 e.财壓磨損性針對以（5)製成之樣本進行矩形曲柄式壓力試驗。矩形曲柄式壓力試驗之條件，係以壓邊力6噸將樣本（ 220x 180mm)形成65x 115mm，且高度為50丽之形狀，再以目視評價成形後之滑動面。以下之評價中，◎及〇係判定為良好。 ◎:無黑化情形 1 * ^--------tr--------- c請先閱讀背面之注意事項再填寫本頁) 〇·滑動部50%以下之面積黑化，且具有滑動傷痕 △:滑動部50%以上之面積黑化，且具有滑動傷痕V. Description of the invention (y Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs △: The peeling area ratio is above 5% and less than 50% χ: The peeling area ratio is above 50% d. The continuous weldability will be (5 ) The finished sample was subjected to continuous spot test under the conditions shown in Table 3, and after being stabilized, the number of dots that can form a nugget with a diameter of 3 legs + or more was obtained. (At 50Hz) The diameter of the tip of the electrode is 4.5mm. The external pressure of the electrode is less than 200kgf. ◎ and 〇 are judged to be good. ◎: The number of dots is 5,000 or more. The number of dots is 1000 or more and less than 2500 x: The number of dots is less than 1000 e. Financial pressure abrasion resistance The rectangular crank pressure test is performed on the sample made in (5). The conditions of the rectangular crank pressure test are blank holding. The sample (220x180mm) was formed into a shape of 65x115mm and a height of 50 li with a force of 6 tons, and the sliding surface after molding was visually evaluated. In the following evaluations, ◎ and 〇 were judged to be good. ◎: No blackening 1 * ^ -------- tr-- ------- c Please read the precautions on the back before filling in this page) 〇 · The area of the sliding part is less than 50% blackened and has sliding scars △: The area of the sliding part is more than 50% blackened and has Sliding scar

-37- 573062 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（予 x:底層金屬露出，並具有擦傷 f.耐磨耗性試驗對以（5)製成之樣本，透過乙烯基樹脂膜以1〇g/cm 2 之負載施加360次/分之橢圓振動而使滑動部產生擦傷。進行10分鐘試驗後以目視評價樣本表面。以下之評價中，◎ 及〇係判定為良好。 ◎:無黑化情形〇：滑動部5 0 %以下之面積黑化 △:滑動部50%以上之面積黑化 x :底層金屬露出 g·靜摩擦係數利用新東科學製10D型HEIDON靜摩擦係數測定裝置，於0.5。/sec、平面壓穴機上黏附以（5 )製成並業經去除溢料之面積為25cm2之樣本，並於重2〇〇g之條件下測定以 (5 )製成之樣本間之靜摩擦係數。 h.動摩擦係數利用新東科學製14S型HEIDON動摩擦係數測定裝置，於直徑10mm不銹鋼球滑動，且負載1〇〇g、滑動速度^❹ 咖/min之條件下’測定以（5)製成之樣本之動摩擦係數。 i ·耐線圈變形性製造數種板厚為1 mm且摩擦係數不同之内押$⑽腿之 l〇t線圈，並將該線圈以吊車進行3次升降 Γ巧便，測定因最外卷鬆弛而產生之線圈繞捲方向（長向）最端部之變形（距離），並針對動摩擦係數、靜摩擦細述之關係進行碉杳。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 2Θ7公髮） ^--------^--------- (請先閱讀背面之注意事項再填寫本頁) -38- 573062 A7 五、發明說明（予其結果，令動摩擦係數、靜摩擦係數與因繞捲鬆弛所產生之線圈繞捲方向（長向）最端部之變形（距離）詳加對應，則動摩擦係數未達0.07、靜摩擦係數未達〇1〇時，因繞捲鬆弛所致之線圈最端部之變形係在5〇腿以上，而動摩^係數在0.07以上、靜摩擦係數在〇1〇以上時，因繞捲鬆弛所致之線圈最端部之變形則可控制在3〇咖以下。因此，實驗室之試驗中係將前述以§與11測定之靜摩擦係數與動摩擦係數作為耐線圈變形性之指標而運用。以下之評價中〇係判定為良好。 ' μ 〇··動摩擦係數在0.07以上、靜摩擦係數在〇1以上 X ·動摩擦係數未達〇·〇7、靜摩擦係數未達〇1 以上之評價結果係顯示於表7〜9。由該等結果可知，藉由本發明之技術，即可製得一種耐蝕性、黏附性、可焊性等各種性能俱佳，進而可控制動摩擦係數於〇〇7〜〇15 % 之範圍内，而靜摩擦係數在〇·!以上之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -39- 573062 A7 B7 五、發明說明（^ 經濟部智慧財產局員工消費合作社印製表4 編號 Cr 有機無機序I L合覆膜金屬板附著量水性i 皆脂/矽酸鹽化合物lj 二氧/ 匕矽2) 蠛 3) -- (g/m2) (mg/m2) 種類量種類量種類量種類量種類量 I EG 40 Al ιοο — 一 Cl 15 Dl 10 — - l.O ~ 2 EG 40 Al ιοο 一一 Cl 15 D2 10 — —. l.O 3 EG 40 Al 100 —· 一 Cl 15 D3 10 一 ------ l.O 4 EG 40 Al 100 一 - Cl 15 D4 10 - - l.O 5 EG 40 Al 100 — 一 Cl 15 D5 10 - - l.O 6 EG 40 Al 100 — 一 Cl 15 D6 10 - - l.O 7 EG 40 Al 100 — 一 Cl 15 D7 10 - — l.O 8 EG 40 Al 100 一 - Cl 15 D8 10 - — l.O 9 EG 40 Al 100 — 一 Cl 15 D9 10 - - l.O 10 EG 40 Al 100 一 - Cl 15 D10 10 - l.O II EG 40 Al 100 — — Cl 15 Dl I 10 - - l.O 12 EG 40 Al 100 一 — Cl 15 D12 10 - ---- l.O 13 EG 40 Al 100 一一 Cl 15 D13 10 - - l.O 14 EG 40 Al 100 一一 Cl 15 D14 10 - - l.O 15 EG 40 Al 100 — 一 Cl 15 D15 10 一 —--- l.O 16 EG 40 Al 100 — 一 Cl 15 D16 10 - l.O ^ 17 EG 40 Al 100 一一 Cl 15 D3 I - - Γ l.o 18 EG 40 Al 100 一一 Cl 15 D3 6 - - l.O 19 EG 40 Al 100 - - Cl 15 D3 30 - - l.o 20 EG 40 Al 100 一 — Cl 15 D4 I - - l.o 21 EG 40 Al 100 — - Cl 15 D4 6 - ~~~. l.o 22 EG 40 Al 100 一一 Cl 15 D4 30 - - l.o 23 EG 40 Al 100 — — Cl 15 D9 I - - l.o 24 EG 40 Al 100 — 一 Cl 15 D9 6 — - l.o 25 EG 40 Al 100 — 一 Cl 15 D9 30 - 一 l.o 1) 水性樹脂或/及矽酸鹽化合物全體以固體成分質量換算時為100時所摻合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之各球形蠟分散體之種類與比率本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ---1---------裝 -------訂--------- Μ * (請先閱讀背面之注意事項再填寫本頁) -40- 573062 五發明說明（予表5 ----! 編 Cr 有機無機才1 丨合覆膜號金屬板附著量水性樹脂/梦酸鹽化合物υ 二氧化矽~ 蠛附著量 (mg/m2) 種類量種類量種類量種類量種類量 (g/m2) 26 EG 40 Α1 100 一一 C1 15 D2 5 D4 5 ι7δ~ 27 EG 40 Α1 100 一一 C1 15 D2 5 D9 5 ιΤο~ 28 EG 40 Α1 100 一 _ C1 15 D3 10 一 — 0.1 29 EG 40 Α1 100 一一 C1 15 D3 10 — — οΤΓ' 30 EG 40 Α1 100 _ 一 C1 15 D3 10 一 — 27ο~· 31 EG 40 Α1 100 _ _ C1 15 D3 10 一一 ------- 32 EG 40 Α1 100 _ 一 C1 15 D3 10 一 — 10.0 33 EG 40 Α1 100 一 _ C1 15 D4 10 一 — 〇ΤΓ^ 34 EG 40 Α1 100 _ C1 15 D4 10 一一 οΤΓ~- 35 EG 40 Α1 100 _ 一 C1 15 D4 10 一一 2Τ〇~ 3 6 EG 40 Α1 100 一一 C1 15 D4 10 一 — 5.0~ 37 EG 40 Α1 100 _ 一 C1 15 D4 10 一 - ιοΓΓ" 38 EG 40 Α1 100 _ — C1 15 D9 10 一 — οΤΓ^ 39 EG 40 Α1 100 _ 一 C1 15 D9 10 一 — ο.Γ' 40 EG 40 Α1 100 _ _ C1 15 D9 10 一 — 41 EG 40 Α1 100 _ 一 C1 15 D9 10 一一 5.0 42 EG 40 Α1 100 一一 C1 15 D9 10 — - 10.0^ 43 EG 40 Α1 100 _ _ C1 0 D3 10 — 一 1.0 44 EG 40 Α1 100 _ 一 C1 5 D3 10 一一 ΓΓο~ 45 EG 40 Α1 100 _ 一 C1 10 D3 10 — — 1.0 46 EG 40 Α1 100 一 — C1 35 D3 10 一一 1.0 47 EG 40 Α1 100 一 — C1 50 D3 10 一 - 1.0 48 EG 40 Α1 100 一一 C2 0 D4 10 一 _ 1.0 49 EG 40 Α1 100 _ 一 C2 5 D4 10 一一 —— ----- 1.0 50 EG 40 Α1 100 - - C2 10 D4 10 一一 ι7ο~ 經濟部智慧財產局員工消費合作社印製一尺張紙本 1) 水性樹脂或/及矽酸鹽化合物全體以固體成分質量換算時為100時所掺合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算日夺4 1〇〇時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換瞀時^ & 100時所摻合之各球形蠟分散體之種類與比率度適用中國國家標準（CNS)A4規格（210 X 297公釐） -----裝！！丨訂·--— — — — —— (請先閱讀背面之注意事項再填寫本頁) >41- 573062 A7 B7-37- 573062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (to x: the underlying metal is exposed and has scratches. F. Abrasion resistance test For the sample made in (5), it is passed through ethylene The base resin film was subjected to an elliptical vibration of 360 times / min under a load of 10 g / cm 2 to cause abrasion on the sliding portion. After a 10-minute test, the sample surface was visually evaluated. In the following evaluations, ◎ and 〇 were judged to be good ◎: No blackening situation 〇: Area blackening of 50% or less of the sliding part △: Area blackening of 50% or more of the sliding part x: Exposed base metal g · Static friction coefficient Measured using 10D HEIDON static friction coefficient manufactured by Shinto Scientific The device was adhered to a sample made of (5) with a surface area of 25 cm2 after removing the flash material at a surface pressure of 0.5 ° / sec, and was measured at a weight of 200 g. The static friction coefficient between the samples. H. The dynamic friction coefficient was measured using a 14S type HEIDON dynamic friction coefficient measuring device manufactured by Shinto Scientific. It was slid on a stainless steel ball with a diameter of 10mm, and the load was 100g and the sliding speed was ^ ❹ coffee / min. (5) Coefficient of dynamic friction of the completed sample. I. Resistance to coil deformation. Manufacture several types of 10t coils with a thickness of 1 mm and different friction coefficients, and lift the coil 3 times with a crane. , Measure the deformation (distance) at the extreme end of the coil winding direction (long direction) caused by the looseness of the outermost coil, and carry out a detailed analysis of the relationship between the dynamic friction coefficient and the static friction. This paper size applies the Chinese National Standard (CNS ) A4 specification (210 X 2Θ7 public hair) ^ -------- ^ --------- (Please read the precautions on the back before filling this page) -38- 573062 A7 V. Invention Explanation (As a result, the dynamic friction coefficient and the static friction coefficient are made to correspond to the deformation (distance) at the extreme end of the coil winding direction (long direction) caused by the coil winding relaxation. When it reaches 〇10, the deformation at the end of the coil due to winding relaxation is more than 50 legs, and when the dynamic friction coefficient is above 0.07 and the static friction coefficient is above 010, it is caused by winding relaxation. The deformation of the end of the coil can be controlled below 30. Therefore, the actual In the laboratory test, the aforementioned static friction coefficient and dynamic friction coefficient measured with § and 11 were used as indicators of resistance to coil deformation. In the following evaluations, 0 was judged to be good. 'Μ 〇 · The dynamic friction coefficient is 0.07 or more and the static friction Coefficients above 0 × X · Dynamic friction coefficients below 0.07, and static friction coefficients below 01 are shown in Tables 7 to 9. From these results, it can be seen that the technology of the present invention can be used to produce A variety of properties, such as corrosion resistance, adhesion, solderability, etc., which can control the dynamic friction coefficient in the range of 〇07 ~ 015%, and the static friction coefficient above 〇 ·! Has excellent pressure wear resistance and resistance Coil deformable surface treated metal sheet. This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -39- 573062 A7 B7 V. Description of the Invention (^ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Table 4 No. Cr Organic Inorganic Sequence IL Combination Amount of coated metal sheet Water-based i All grease / Silicate compound lj Dioxygen / Silicon silicon 2) 蠛 3)-(g / m2) (mg / m2) Kind amount Kind amount Kind amount Kind amount Kind amount I EG 40 Al ιοο — one Cl 15 Dl 10 —-lO ~ 2 EG 40 Al ιοο one one Cl 15 D2 10 — —. LO 3 EG 40 Al 100 — · one Cl 15 D3 10 one ------ lO 4 EG 40 Al 100-Cl 15 D4 10--lO 5 EG 40 Al 100-One Cl 15 D5 10--lO 6 EG 40 Al 100-One Cl 15 D6 10--lO 7 EG 40 Al 100-One Cl 15 D7 10-— lO 8 EG 40 Al 100--Cl 15 D8 10--lO 9 EG 40 Al 100--Cl 15 D9 10--lO 10 EG 40 Al 100--Cl 15 D10 10-lO II EG 40 Al 100 — — Cl 15 Dl I 10--lO 12 EG 40 Al 100--Cl 15 D12 10----- lO 13 EG 40 Al 100-Cl 15 D13 10--lO 14 EG 40 Al 100 One Cl 15 D14 10--lO 15 EG 40 Al 100 — One Cl 15 D15 10 One ----- lO 16 EG 40 Al 100 — One Cl 15 D16 10-lO ^ 17 EG 40 Al 100 One-Cl 15 D3 I--Γ lo 18 EG 40 Al 100-one Cl 15 D3 6--lO 19 EG 40 Al 100--Cl 15 D3 30--lo 20 EG 40 Al 100 one-Cl 15 D4 I--lo 21 EG 40 Al 100 —-Cl 15 D4 6-~~~. Lo 22 EG 40 Al 100-one Cl 15 D4 30--lo 23 EG 40 Al 100 —-Cl 15 D9 I--lo 24 EG 40 Al 100 — one Cl 15 D9 6 —-lo 25 EG 40 Al 100 — one Cl 15 D9 30-one lo 1) The type of each water-based resin blended when the total amount of water-based resin or silicate compound is 100 in terms of solid content And ratio 2) the type and ratio of silicon dioxide blended when the entire organic-inorganic composite coating is 100 when the solid content mass conversion is converted 3) the entire organic-inorganic composite coating is 100 when the solid content mass conversion is 100 Types and ratios of each spherical wax dispersion This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) --- 1 --------- pack ------- Order --------- Μ * (Please read the notes on the back before filling out this page) -40- 573062 Five invention descriptions (to Table 5 ----! Edit Cr Organic and inorganic only 1 丨 Combined film No. Metal plate adhesion amount Water-based resin / dream salt compound υ Silicon dioxide ~ 蠛 adhesion amount (mg / m2) Kind amount Kind amount Kind amount Kind amount Kind amount (g / m2) 26 EG 40 Α1 100-one C1 15 D2 5 D4 5 ι7δ ~ 27 EG 40 Α1 100-one C1 15 D2 5 D9 5 ιο ~ 28 EG 40 Α1 100 one_ C1 15 D3 10 one-0.1 29 EG 40 Α1 100 one one C1 15 D3 10 — — οΤΓ '30 EG 40 Α1 100 _ One C1 15 D3 10 One — 27ο ~ · 31 EG 40 Α1 100 _ _ C1 15 D3 10 One One ------- 32 EG 40 Α1 100 _ One C1 15 D3 10 One— 10.0 33 EG 40 Α1 100 One_ C1 15 D4 10 One— 〇ΤΓ ^ 34 EG 40 Α1 100 _ C1 15 D4 10 One One οTΓ ~-35 EG 40 Α1 100 _ One C1 15 D4 10 One One 2T〇 ~ 3 6 EG 40 Α1 100 One one C1 15 D4 10 One — 5.0 ~ 37 EG 40 Α1 100 _ One C1 15 D4 10 One-ιοΓΓ " 38 EG 40 Α1 100 _ — C1 15 D9 10 One-οΤΓ ^ 39 EG 40 Α1 100 _ One C1 15 D9 10 One — ο.Γ '40 EG 40 Α1 100 _ _ C1 15 D9 10 One — 41 EG 40 Α1 100 _ One C1 15 D9 10 One One 5.0 42 EG 40 Α1 100 One One C1 15 D9 10 —-10.0 ^ 43 EG 40 Α1 100 _ _ C1 0 D3 10 — One 1.0 44 EG 40 Α1 100 _ One C1 5 D3 10 One One ΓΓο ~ 45 EG 40 Α1 100 _ One C1 10 D3 10 — — 1.0 46 EG 40 Α1 100 one — C1 35 D3 10 one one 1.0 47 EG 40 Α1 100 one — C1 50 D3 10 one-1.0 48 EG 40 Α1 100 one one C2 0 D4 10 one _ 1.0 49 EG 40 Α1 100 _ one C2 5 D4 10 one by one------ 1.0 50 EG 40 Α1 100--C2 10 D4 10 one by one ο7ο ~ Printed on one foot of paper by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1) Water-based resin or / and silicon The types and ratios of the various water-based resins blended with the acid compound as a whole when the solid content mass is 100. 2) The whole organic-inorganic composite film is converted into solid content by 4 mass. Types and ratios of silicon 3) When the whole organic-inorganic composite film is replaced by the solid content quality ^ & 100 The type and ratio of the wax dispersion are applicable to China National Standard (CNS) A4 (210 X 297 mm) ----- install! !!丨 Order --- — — — — — (Please read the notes on the back before filling this page) > 41- 573062 A7 B7

五、發明說明（，表6 編號金屬板 Cr 附著量 (mg/m2) Ϊ機無機才| ί合覆膜 '~~ 水性名 ί脂/矽暖鹽化- 二氧化矽2) 蠟31 附著量 (g/m2) 種類 Μ 種類量種類量種類量種類量 51 EG 40 A1 100 一一 C2 35 D4 10 一 10 52 EG 40 A1 100 - - C2 50 D4 10 一 1 0 53 EG 40 A2 90 Α4 10 C1 15 D3 10 — _ 1.0 54 EG 40 A2 90 Α4 10 C1 15 D4 10 一一 1.0 55 EG 40 A2 90 Α4 10 C1 15 D9 10 一一 1.0 56 EG 40 A3 90 Α4 10 C1 15 D3 10 — 一 1.0 57 EG 40 A3 90 Α4 10 C1 15 D4 10 一一 1.0 5 8 EG 40 A3 90 Α4 10 C1 15 D9 10 — 一 1.0 59 EG 40 B1 100 一一 C1 15 D3 10 一一 1.0 60 EG 40 B2 100 — — C1 15 D3 10 — 一 1.0 61 EG 40 B3 100 — — C1 15 D3 10 一一 1.0 62 EG 40 B1 90 Α1 10 C1 15 D3 10 - 一 1.0 63 EG 40 B1 90 Α4 10 C1 15 D3 10 一一卜1.0 64 EG 40 A3 90 Α4 10 C1 15 D3 10 — 一 1.0 65 EG 一 A3 90 Α4 10 C1 15 D4 10 — — 1.0 66 EG 一 A3 90 Α4 10 C1 15 D9 10 — 1.0 67 ZN 40 A3 90 Α4 10 C1 15 D3 10 一 1.0 68 G1 40 A3 90 Α4 10 C1 0 D3 10 - 一 1.0 1) 水性树月曰或/及矽酸鹽化合物全體以固體成分質量換算時為1 〇〇時所摻合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時 100時所摻合之各球形蠟分散體之種類與比率、、.'、 --------1-----裝--- f* (請先閱讀背面之注意事項再填寫本頁) 訂 % 經濟部智慧財產局員工消費合作社印製 ‘紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -42- 573062 A7 B7V. Description of the invention (, Table 6 Number of Cr attached to the metal plate (mg / m2) Ϊmachine inorganic talents | 合合膜 '~~ Water-based name 脂 lipid / silicon warm salinization-silicon dioxide 2) Wax 31 attached (g / m2) Kind M Kind amount Kind amount Kind amount Kind amount 51 EG 40 A1 100-One C2 35 D4 10-10 52 EG 40 A1 100--C2 50 D4 10-1 0 53 EG 40 A2 90 Α4 10 C1 15 D3 10 — _ 1.0 54 EG 40 A2 90 Α4 10 C1 15 D4 10 one one 1.0 55 EG 40 A2 90 Α4 10 C1 15 D9 10 one one 1.0 56 EG 40 A3 90 Α4 10 C1 15 D3 10 — one 1.0 57 EG 40 A3 90 Α4 10 C1 15 D4 10 One 1.0 5 8 EG 40 A3 90 Α4 10 C1 15 D9 10 — One 1.0 59 EG 40 B1 100 One C1 15 D3 10 One 1.0 60 EG 40 B2 100 — — C1 15 D3 10 — One 1.0 61 EG 40 B3 100 — — C1 15 D3 10 One one 1.0 62 EG 40 B1 90 Α1 10 C1 15 D3 10-One 1.0 63 EG 40 B1 90 Α4 10 C1 15 D3 10 One one 1.0 1.0 EG 40 A3 90 Α4 10 C1 15 D3 10 — 1.0 1.0 EG — A3 90 Α4 10 C1 15 D4 10 — — 1.0 66 EG — A3 90 Α4 10 C1 15 D9 10 — 1.0 67 ZN 40 A3 90 Α4 10 C1 15 D3 10-1.0 68 G1 40 A3 90 A4 10 C1 0 D3 10-1.0 1.0 Types and ratios of water-based resins 2) Types and ratios of silicon dioxide blended when the entire organic-inorganic composite coating is 100 when solid content mass conversion is used 3) 100% when the entire organic-inorganic composite coatings are converted by solid content mass Types and ratios of each spherical wax dispersion blended ,,,,,,,,,,,,,, ', -------- 1 ----- pack --- f * (Please read the precautions on the back before filling this page ) Order% Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs 'Consumer Cooperatives' Paper Size Applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -42- 573062 A7 B7

五、發明說明（T 經濟部智慧財產局員工消費合作社印製表7 編號性能備考平板耐ϋ性加工部耐蝕性塗料黏附性可焊性耐加壓加工性耐磨耗性耐線圈變形數動摩擦係數靜摩擦係數浸潰無浸潰有 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ X 0.05 0.07 比較例 2 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.07 0.15 本發明 3 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.10 0.20 本發明 4 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇 0.15 0.25 本發明 5 ◎ ◎ ◎ ◎ ◎ Δ 〇〇 0.20 0.30 比較例 6 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇 0.08 0.15 本發明 7 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.07 0.12 本發明 8 ◎ ◎ ◎ ◎ ◎ ◎ ◎ X 0.06 0.10 比較例 9 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.09 0.20 本發明 10 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.10 0.25 本發明 11 ◎ ◎ ◎ ◎ ◎ 〇〇〇 0.15 0.30 本發明 12 ◎ ◎ ◎ ◎ ◎ X Δ 〇 0.20 0.35 比較例 13 ◎ ◎ ◎ ◎ ◎ 〇〇〇 0.08 0.20 本發明 14 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.07 0.17 本發明 15 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.15 0.30 本發明 16 ◎ ◎ ◎ ◎ ◎ X X 〇 0.20 0.35 本發明 17 ◎ ◎ ◎ ◎ ◎ 〇〇〇 0.15 0.30 本發明 18 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.10 0.25 本發明 19 〇〇〇〇 ◎ ◎ ◎ 〇 0.08 0.15 本發明 20 ◎ ◎ ◎ ◎ ◎ 〇〇〇 0.15 0.30 本發明 21 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇 0.15 0.30 本發明 22 〇〇〇〇 ◎ ◎ ◎ 〇 0.08 0.15 本發明 23 ◎ ◎ ◎ ◎ ◎ 〇〇〇 0.15 0.30 本發明 24 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇 0.15 0.30 本發明 25 〇〇〇〇 ◎ ◎ ◎ 〇 0.08 0.15 本發明 --1--I------裝 -------訂--------- 、 * (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -43- 573062 A7 B7 五、發明說明（少經濟部智慧財產局員工消費合作社印製表8 編號性能備考平板耐蝕性加工部耐蝕性塗料黏附性可焊性耐加壓加工性耐磨耗性耐線圈變形數動摩擦係數靜摩擦係數浸潰無浸潰有 26 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.07 0.15 本發明 27 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.07 0.18 本發明 28 X X Δ Δ ◎ X X 〇 0.25 0.40 比較例 29 〇〇〇〇 ◎ 〇〇〇 0.15 0.30 本發明 30 ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 0.10 0.20 本發明 31 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇 0.10 0.20 本發明 32 ◎ ◎ ◎ 〇 X ◎ ◎ 〇 0.10 0.20 比較例 33 X X Δ Δ ◎ X X 〇 0.25 0.45 比較例 34 〇〇〇〇 ◎ 〇〇〇 0.15 0.35 本發明 35 ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 0.15 0.25 本發明 36 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇 0.10 0.20 本發明 37 ◎ ◎ ◎ 〇 X ◎ ◎ 〇 0.10 0.20 比較例 38 X X Δ Δ ◎ X X 〇 0.25 0.45 比較例 39 〇〇〇〇 ◎ 〇〇〇 0.15 0.35 本發明 40 ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 0.09 0.20 本發明 41 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇 0.09 0.20 本發明 42 ◎ ◎ ◎ 〇 X ◎ ◎ 〇 0.09 0.20 比較例 43 Δ Δ ◎ 〇 ◎ Δ 〇〇 0.10 0.20 比較例 44 〇〇 ◎ ◎ ◎ 〇〇〇 0.10 0.20 本發明 45 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.10 0.20 本發明 46 ◎ ◎ ◎ 〇 ◎ ◎ ◎ 〇 0.10 0.20 本發明 47 〇〇〇 Δ 〇 Δ 〇〇 0.10 0.20 比較例 48 Δ Δ ◎ 〇 ◎ Δ 〇〇 0.15 0.25 比較例 49 〇〇 ◎ ◎ ◎ 〇〇〇 0.15 0.25 本發明 50 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.15 0.25 本發明 (請先閱讀背面之注意事項再填寫本頁) 裝--------訂--------- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -44- 573062 A7V. Description of the invention (T Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 7 Number Performance Remarks Flat Plate Resistant Processing Department Corrosion Resistance Coating Adhesibility Solderability Pressure Resistance Wear Resistance Resistance Coil Deformation Dynamic Friction Coefficient There are 1 static friction coefficient impregnation and no impregnation. ◎ ◎ ◎ ◎ ◎ ◎ X 0.05 0.07 Comparative Example 2 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 0.07 0.15 The present invention 3 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.10 0.20 The present invention 4 ◎ ◎ ◎ ◎ ◎ ◎ 0.15 0.25 The present invention 5 ◎ ◎ ◎ ◎ ◎ Δ 〇〇0.20 0.30 Comparative Example 6 ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.08 0.15 Inventive 7 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.07 0.12 Inventive 8 ◎ ◎ ◎ ◎ ◎ ◎ X 0.06 0.10 Comparative Example 9 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 0.09 0.20 10 of the present invention 10 ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.10 0.25 11 of the present invention 11 ◎ ◎ ◎ ◎ ◎ 〇〇〇0.15 0.30 Invention 12 ◎ ◎ ◎ ◎ ◎ X Δ 〇0.20 0.35 Comparative Example 13 ◎ ◎ ◎ ◎ ◎ 〇〇〇0.08 0.20 This invention 14 ◎ ◎ ◎ ◎ ◎ ◎ 〇0.07 0.17 15 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ 0.15 0.15 0.30 the present invention 16 ◎ ◎ ◎ ◎ XX XX 0.20 0.35 the present invention 17 ◎ ◎ ◎ ◎ ◎ ◎ 〇〇〇0.15 0.30 the present invention 18 ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.10 0.25 The present invention 19 〇〇〇〇 ◎ ◎ ◎ 0.08 0.15 The present invention 20 ◎ ◎ ◎ ◎ ◎ 〇〇〇0.15 0.30 The present invention 21 ◎ ◎ ◎ ◎ ◎ ◎ 0.15 0.15 0.30 The present invention 22 〇〇〇〇 ◎ ◎ ◎ 0.08 0.15 The present invention 23 ◎ ◎ ◎ ◎ ◎ 〇〇〇0.15 0.30 The present invention 24 ◎ ◎ ◎ ◎ ◎ 0.15 0.15 0.30 The present invention 25 〇〇〇〇 ◎ ◎ ◎ 0.08 0.15 this Invention--1--I ------ install ------- order --------- 、 * (Please read the precautions on the back before filling this page) This paper size applies China National Standard (CNS) A4 Specification (210 X 297 mm) -43- 573062 A7 B7 V. Description of Invention (Printed by Employee Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Table 8 No. Performance Remarks Corrosion Resistance Coatings of Flat Processing Department Cohesive Pressure resistance, workability, wear resistance, coil deformation number, dynamic friction coefficient, static friction coefficient, impregnation and non-impregnation are 26 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 0.07 0.15 The present invention 27 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.07 0.18 The present invention 28 XX Δ Δ XX XX 0.25 0.40 Comparative Example 29 〇〇〇〇 ◎ 〇〇〇0.15 0.30 The present invention 30 ◎ ◎ ◎ ◎ ○ ◎ ◎ 0.10 0.20 The present invention 31 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇0.10 0.20 The present invention 32 ◎ ◎ ◎ ○ XX ◎ ◎ 0.10 0.20 Comparative example 33 XX Δ Δ ◎ XX 0.25 0.45 Comparative example 34 〇〇〇〇 ◎ 〇〇〇0.15 0.35 The present invention 35 ◎ ◎ ◎ ◎ ○ ◎ ◎ 0.15 0.25 The present invention 36 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇0.10 0.20 The present invention 37 ◎ ◎ ◎ ○ X ◎ ◎ 〇0.10 0.20 Comparative Example 38 XX Δ Δ ◎ XX 0.25 0.45 Comparative Example 39 〇〇〇〇〇 ◎ 〇〇0.15 0.15 This invention 40 ◎ ◎ ◎ ◎ ◎ ◎ 〇0.09 0.20 The present invention 41 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇0.09 0.20 The present invention 42 ◎ ◎ ◎ 〇X ◎ 〇0.09 0.20 Comparative Example 43 Δ Δ ◎ ◎ Δ 〇〇0.10 0.20 Comparative Example 44 〇〇 ◎ ◎ ◎ 〇〇〇0.10 0.20 The present invention 45 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 0.10 0.20 The present invention 46 ◎ ◎ ◎ ◎ ○ ◎ ◎ ◎ 〇0.10 0.20 Inventive 47 OO〇Δ 〇Δ 〇〇0.10 0.20 Comparative Example 48 Δ Δ ◎ ○ ◎ Δ 〇0.15 0.25 Comparative Example 49 ○ ◎ ◎ ◎ 〇〇0.15 0.25 Inventive 50 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 0.15 0.25 The present invention (please read the precautions on the back before filling in this page) Loading -------- Order --------- This paper size is applicable to Chinese national standards ( CNS) A4 size (210 X 297 mm) -44- 573062 A7

本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） -45- 573062 A7 五、發明說明（f 表10 藥劑一覽表藥劑種類編说商品名有機樹脂 A1 丙烯-樹脂' ΑρΤΓίο^τίτΰ- A2 聚烯t系水性樹脂（東邦化學工業製、AR_2300) A3 1胺基甲故日糸水性樹脂（Nipp〇n_NSC製、RA-85) A4 環氧系水性樹脂（大曰本INK製、迪克范《音譯亍、彳ック77彳y》EM-60) 碎酸鹽化合物 B1 鋰矽酸鹽 B2 鈉矽酸鹽 - B3 鉀矽酸鹽膠體二氧化矽 C1 水性膠體二氧化矽（日產化學f、商品名：司諾提克斯（音譯ス/一テックス》N) C2 水性膠體二氧化矽（日產化學盤、商品名：司諾提克斯《音譯ス/一テック只》UP) 潤滑劑A +比較 D1 聚乙烯（分子量 6000、酸值：0、粒徑：3.0μπ〇 D2 聚乙烯（分子量 8000、酸值：0、粒徑：3.0μηι) D3 聚乙烯（分子量 15000、酸值：0、粒徑：3.0)1111). D4 聚乙烯（分子量 20000、酸值：0、粒徑： D5 聚乙烯（分子量 6000、酸值：0、粒徑：Ο·1!1111) D6 聚乙烯（分子量 6000、醢值：0、粒徑：5.04111) D7 變性聚乙烯（分子量：1000、酸值：20、粒徑：Ι.ΟμηΟ D8 變性聚乙烯（分子量：6〇〇〇、酸值：2〇、粒徑：υμ111} D9 變性聚乙烯（分子量：8000、酸值：20、粒徑： D10 變性聚乙烯（分子量：15000、酸值：20、粒徑：l0!1111) D11 變性聚乙烯（分子量：20000、酸值：20、粒徑：l0!1111) D12 變性聚乙烯（分子量：6000、酸值：20、粒徑：O.^m) D13 變性聚乙烯（分子量：6000、酸值：20、粒徑： D14 變性聚乙烯（分子量：6000、醢值：40、粒徑： D15 變性聚乙烯（分子詈：6000、s以f : 1〇〇、粒徑：ιοί1111) 潤滑劑B +比較 E16 聚乙烯（分子量 500、酸值：0、粒徑： E17 聚乙烯（分子量 1000、酸值：〇、敕徑：3·υμπι; E18 聚乙烯（分子量 5000、酸值：〇、粒徑：3·0μιη) E19 聚乙烯（分子量 1000、酸值：〇、粒徑：5·0μηι) E20 聚乙烯（分子量 1000、酸值：〇、粒徑： E21 聚乙烯（分子量 5500、醅俏：〇、粒徑·· 3·0μιη) (請先閱讀背面之注意事項再填寫本頁) ▼•裝--------訂---------· 經濟部智慧財產局員工消費合作社印製 (2 )金屬板之種類金屬板係使用先前表2所示者。 (3 )鉻酸鹽處理如先前第1觀點之例所做之說明。 (4 )水性有機無機複合塗料之調製將表10所示之水性樹脂及矽酸鹽化合物之一方或兩本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -46- 573062 A7This paper size applies the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) -45- 573062 A7 V. Description of the invention (f Table 10 List of medicaments List of medicament types Compilation Trade name Organic resin A1 Propylene-resin 'ΑρΤΓίο ^ τίτΰ -A2 Polyethylene t-based water-based resin (manufactured by Toho Chemical Industries, AR_2300) A3 1 amino-methyl-based sundial water-based resin (manufactured by Nippon_NSC, RA-85) A4 epoxy-based water-based resin (manufactured by INK, DAK Fan "Transliteration, 彳ック 77 彳 y" EM-60) Broken acid salt compound B1 lithium silicate B2 sodium silicate-B3 potassium silicate colloidal silica C1 hydrocolloid silica (Nissan Chemical f Product name: Snotox (N transliteration / Nexpress) N2 C2 hydrocolloid silicon dioxide (Nissan chemical disc, trade name: Snotoxx: Transnexion / Impression) UP Lubricant A + Comparison with D1 polyethylene (molecular weight 6000, acid value: 0, particle size: 3.0 μπι) D2 polyethylene (molecular weight 8000, acid value: 0, particle diameter: 3.0 μηι) D3 polyethylene (molecular weight 15000, acid value: 0, Particle size: 3.0) 1111). D4 polyethylene (molecular weight 20 000, acid value: 0, particle size: D5 polyethylene (molecular weight 6000, acid value: 0, particle size: 0 · 1! 1111) D6 polyethylene (molecular weight 6000, threshold value: 0, particle size: 5.04111) D7 denaturation Polyethylene (molecular weight: 1000, acid value: 20, particle size: 1.0 μηΟ D8 modified polyethylene (molecular weight: 6000, acid value: 20, particle size: υμ111) D9 modified polyethylene (molecular weight: 8000, Acid value: 20, particle size: D10 modified polyethylene (molecular weight: 15000, acid value: 20, particle size: 10! 1111) D11 modified polyethylene (molecular weight: 20000, acid value: 20, particle size: 10! 1111) D12 modified polyethylene (molecular weight: 6000, acid value: 20, particle size: O. ^ m) D13 modified polyethylene (molecular weight: 6000, acid value: 20, particle size: D14 modified polyethylene (molecular weight: 6000, threshold value) : 40, particle size: D15 modified polyethylene (molecular fluorene: 6000, s to f: 100, particle size: ιοί 1111) lubricant B + comparison E16 polyethylene (molecular weight 500, acid value: 0, particle size: E17 Polyethylene (molecular weight 1000, acid value: 0, diameter: 3 · υμπι; E18 polyethylene (molecular weight 5000, acid : 0, particle size: 3.0 μm) E19 polyethylene (molecular weight 1000, acid value: 0, particle size: 5.0 μm) E20 polyethylene (molecular weight 1000, acid value: 0, particle size: E21 polyethylene (molecular weight 5500 , Qiao Qiao: 〇, particle size ·· 3 · 0μιη) (Please read the precautions on the back before filling in this page) ▼ • equipment -------- order --------- · economic (2) Types of metal plates printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives Metal plates are those shown in Table 2 above. (3) Chromate treatment As explained in the example of the first aspect. (4) Preparation of water-based organic-inorganic composite coatings One or both of the water-based resins and silicate compounds shown in Table 10 are applicable to China National Standard (CNS) A4 (210 X 297 mm) -46- 573062 A7

經濟部智慧財產局員工消費合作社印製五、發明說明（嗲方，與膠體二氧化矽及潤滑劑以表所示之比率換合，而調製成水性有機無機複合塗料。 (5 )水性有機無機複合塗料之塗布•乾燥方法於施有（3)之鉻酸鹽處理之鍍金屬板上，將以（4) 調製成之水性有機無機複合塗料以乾態質量成表丨丨〜表1 3 所示之值進行塗布，並於環境溫度為50(rc之熱風循環型乾燥爐中’以到達板溫140 °c進行烘烤乾燥而製成評價用樣本。此外’有機複合覆膜之附著量係藉由權重法測定塗布時之液膜量而算出。 (6)性能評價項目 a ·平板财餘性如先前第1觀點之例所做之說明。 b. 加工部财触性如先前第1觀點之例所做之說明。 c. 塗料黏附性如先前第1觀點之例所做之說明。 d. 可連續焊接性如先前第1觀點之例所做之說明。 e. 耐壓磨損性如先前第1觀點之例所做之說明。 f. 耐磨耗性試驗如先前第1觀點之例所做之說明。 g. 耐連續滑動磨耗性以旋轉式之滑動磨耗試驗機，於荷重5〇〇g之端子上黏本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） - - -- - - ---裝---— - — — — 訂· — — — — -* (請先閱讀背面之注意事項再填寫本頁) -47- 573062Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention The method of coating and drying the composite coating on the chromate-treated metallized plate coated with (3), the water-based organic-inorganic composite coating prepared by (4) is prepared in dry state as shown in Table 丨 ~ Table 1 3 The values shown are applied and dried in a hot-air circulation-type drying oven at an ambient temperature of 50 ° C to obtain a sample for evaluation by baking and drying at a plate temperature of 140 ° C. In addition, the adhesion amount of the organic composite film is Calculated by measuring the amount of liquid film at the time of coating with a weight method. (6) Performance evaluation item a · The profitability of the flat plate is as described in the example of the first point of view. B. The property of the processing section is the same as the first point of view. The description of the example. C. The paint adhesion is as described in the example of the first point of view. D. The continuous weldability is as described in the example of the first point of view. E. Explanation from the example of point 1. f. The abrasion resistance test is as described in the example of the previous point 1. g. Resistance to continuous sliding abrasion. A rotary sliding abrasion tester is used. The paper is adhered to a terminal with a load of 500 g. ) A4 size (210 X 297 mm)-----------------------(Please read the precautions on the back before filling out this page)- 47- 573062

經濟部智慧財產局員工消費合作社印製貼穿通10IM之塑膠（錄影帶盒），並放至加工成圓盤本表面。令其每分鐘旋轉60下且每5G次即觀察樣本表面，並以鍍層受傷之旋轉數加以評價。 h.動摩擦係數如先刖第1觀點之例所做之說明。 i·熱分解安定性將（5)製作之樣本於環境溫度為9〇〇c>c、空氣比於〜1.5範圍内之直接火型乾燥爐中以到達板溫14〇。〇進行加熱處理後，將動摩擦係數變高，且耐壓磨損性、耐連續滑動磨耗性劣化之情形敎為不良（〇，而呈同等時則判定為良好（〇）。〇：經加熱處理後，動摩擦係數、耐壓磨損性、耐連續滑動磨耗性呈同等 X :經加熱處理後，動摩擦係數變高，且耐壓磨損性、耐連續滑動磨耗性劣化以上评彳貝結果將顯示於表14〜1 6。由該等結果可知，藉由本發明之技術即可製得一耐姓性、黏附性、可焊性等各種丨生此俱佳，進而具有優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板。本紙張尺度適(CNS)A4規格⑽x 297公髮） —.—1------裝--------訂--------- , I (請先閱讀背面之注意事項再填寫本頁) -48- 573062 A7 B7 五、發明說明（f 表11 經濟部智慧財產局員工消費合作社印製Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and pasted through 10IM plastic (video cassette) and put it on the surface of the disc. The surface of the sample was observed by rotating it 60 times per minute and every 5G times, and evaluated by the number of rotations of the coating damage. h. Dynamic friction coefficient As explained in the example of the first point. i. Thermal decomposition stability The samples prepared in (5) were placed in a direct-fired drying furnace with an ambient temperature of 900 ° C and an air ratio in the range of ~ 1.5 to reach a plate temperature of 14 °. 〇 After heat treatment, the coefficient of dynamic friction is increased, and the pressure wear resistance and continuous sliding wear resistance are deteriorated. 不良 is bad (0, when it is equal, it is judged to be good (0). 〇: After heat treatment The dynamic friction coefficient, pressure wear resistance, and continuous sliding wear resistance are equal. X: After heat treatment, the dynamic friction coefficient becomes higher, and the pressure wear resistance and continuous sliding wear resistance are deteriorated. The above evaluation results will be shown in Table 14. ~ 16. From these results, it can be known that various technologies such as surname resistance, adhesion, solderability, etc. can be produced by the technology of the present invention, and thus have excellent pressure wear resistance and continuous sliding wear resistance. Surface-treated metal sheet. This paper is suitable for (CNS) A4 size (x 297). — — — 1 ---------------------- Order --------- , I (Please read the precautions on the back before filling this page) -48- 573062 A7 B7 V. Description of invention (f Table 11 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

2) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之二氧化石夕之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之各球形蠟分散體之種類與比率私紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -裝！！訂-!! · -49- 573〇62 A72) The types and ratios of the sulphur dioxide mixed when the whole organic-inorganic composite film is 100 when the solid content mass is converted. 3) The whole organic-inorganic composite film is 100 when the solid content mass is converted. Types and ratios of each spherical wax dispersion The private paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) (Please read the precautions on the back before filling this page)-Pack! !! Order-!!--49- 573〇62 A7

表12 編號 Cr 有機無機複合覆膜 ' 金屬板附著量水性名 ί脂/矽酸鹽化合物υ 二氧化矽2) 潤滑劑α3) 潤滑劑β3) 附著量 (g/m2) (mg/m2) 種類量種類量種類量種類量種類量種類量 31 EG 40 A1 100 — - C1 15 D2 1 一 — Ε17 9 1.0 32 EG 40 A1 100 一一 C1 15 D2 9 — - Ε17 1 1.0 33 EG 40 A1 100 — 一 C1 15 D3 1 一 — Ε17 9 1.0 34 EG 40 A1 100 — - C1 15 D3 9 - - Ε17 1 1.0 35 EG 40 A1 100 一 - C1 15 D2 2.5 D8 2.5 Ε17 5 1.0 3 6 EG 40 A1 100 — - C1 15 D3 2.5 D8 2.5 Ε17 5 1.0 37 EG 40 A1 100 一一 C1 15 D2 0.5 - - Ε17 0.5 1.0 38 EG 40 A1 100 — — C1 15 D2 3.0 一一 Ε17 3 1.0 39 EG 40 A1 100 一 — C1 15 D2 15.0 - - Ε17 15 1.0 40 EG 40 A1 100 — 一 C1 15 D3 0.5 - — Ε17 0.5 1.0 41 EG 40 A1 100 - — C1 15 D3 3.0 - - Ε17 3 1.0 42 EG 40 A1 100 — — C1 15 D3 15.0 - - Ε17 15 1.0 43 EG 40 A1 100 - 一 C1 15 D2 5 - - Ε17 5 0.1 ' 44 EG 40 A1 100 一一 C1 15 D2 5 - - Ε17 5 0.3 45 EG 40 A1 100 — 一 C1 15 D2 5 — - Ε17 5 2.0 46 EG 40 A1 100 — - C1 15 D2 5 — — Ε17 5 5.0 47 EG 40 A1 100 — — C1 15 D2 5 - 一 Ε17 5 10.0 48 EG 40 A1 100 — — C1 15 D3 5 - - Ε17 5 0.1 49 EG 40 A1 100 — — C1 15 D3 5 - 一 Ε17 5 0.3 50 EG 40 A1 100 — — C1 15 D3 5 — 一 Ε17 5 2.0 51 EG 40 A1 100 — - C1 15 D3 5 - - Ε17 5 5.0 52 EG 40 A1 100 — - C1 15 D3 5 一 - Ε17 5 10.0 53 EG 40 A1 100 — - C1 15 D9 5 - - Ε17 5 0.1 54 EG 40 A1 100 — - C1 15 D9 5 — - Ε17 5 0.3 55 EG 40 A1 100 — - C1 15 D9 5 一一 Ε17 5 2.0 56 EG 40 A1 100 — 一 C1 15 D9 5 — - Ε17 5 5.0 57 EG 40 A1 100 — - C1 15 D9 5 一一 Ε17 5 10.0 58 EG 40 A1 100 — — C1 0 D2 5 — - Ε17 5 1.0 59 EG 40 A1 100 一 - C1 5 D2 5 - 一 Ε17 5 1.0 60 EG 40 A1 100 — - C1 10 D2 5 — — Ε17 5 1.0 1------------------^--------- % 9 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 1)水性樹脂或/及矽酸鹽化合物全體以固體成分質量換算時為10 0時所摻合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算時為 10 0時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時4 100時所摻合之各球形蠟分散體之種類與比率Table 12 No. Cr organic-inorganic composite coating 'Metal plate adhesion amount Water-based name Lipid / silicate compound υ Silicon dioxide 2) Lubricant α3) Lubricant β3) Adhesion amount (g / m2) (mg / m2) Type Quantity type quantity type quantity type quantity type quantity type quantity 31 EG 40 A1 100 —-C1 15 D2 1 1 — Ε17 9 1.0 32 EG 40 A1 100-1 C1 15 D2 9 —-Ε17 1 1.0 33 EG 40 A1 100 — 1 C1 15 D3 1 I—E17 9 1.0 34 EG 40 A1 100 —-C1 15 D3 9--E17 1 1.0 35 EG 40 A1 100 I—C1 15 D2 2.5 D8 2.5 E17 5 1.0 3 6 EG 40 A1 100 —-C1 15 D3 2.5 D8 2.5 Ε17 5 1.0 37 EG 40 A1 100 one-to-one C1 15 D2 0.5--Ε17 0.5 1.0 38 EG 40 A1 100 — — C1 15 D2 3.0 one-one E17 3 1.0 39 EG 40 A1 100 one — C1 15 D2 15.0--Ε17 15 1.0 40 EG 40 A1 100 — One C1 15 D3 0.5-— Ε17 0.5 1.0 41 EG 40 A1 100-— C1 15 D3 3.0--Ε17 3 1.0 42 EG 40 A1 100 — — C1 15 D3 15.0- -Ε17 15 1.0 43 EG 40 A1 100-One C1 15 D2 5--Ε17 5 0.1 '44 EG 40 A1 100 One one C1 15 D2 5--Ε17 5 0.3 45 EG 40 A1 100 — One C1 15 D2 5 —-Ε17 5 2.0 46 EG 40 A1 100 —-C1 15 D2 5 — — Ε17 5 5.0 47 EG 40 A1 100 — — C1 15 D2 5-One Ε17 5 10.0 48 EG 40 A1 100 — — C1 15 D3 5--Ε17 5 0.1 49 EG 40 A1 100 — — C1 15 D3 5-Ε17 5 0.3 50 EG 40 A1 100 — — C1 15 D3 5 — Ε17 5 2.0 51 EG 40 A1 100 —- C1 15 D3 5--Ε17 5 5.0 52 EG 40 A1 100 —-C1 15 D3 5 One-Ε17 5 10.0 53 EG 40 A1 100 —-C1 15 D9 5--Ε17 5 0.1 54 EG 40 A1 100 —-C1 15 D9 5 —-Ε17 5 0.3 55 EG 40 A1 100 —-C1 15 D9 5-One Ε17 5 2.0 56 EG 40 A1 100 — One C1 15 D9 5 —-Ε17 5 5.0 57 EG 40 A1 100 —-C1 15 D9 5 One-E17 5 10.0 58 EG 40 A1 100 — — C1 0 D2 5 —-E17 5 1.0 59 EG 40 A1 100 One- C1 5 D2 5-One E17 5 1.0 60 EG 40 A1 100 —-C1 10 D2 5 — — Ε17 5 1.0 1 ------------------ ^ ---------% 9 (Please read the notes on the back before filling this page) Wisdom of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Property Bureau 1) Water-based resin or / and silicate compound The types and ratios of the various water-based resins blended at 100 when the mass conversion of solid content as a whole 2) The types and proportions of silicon dioxide blended at 100 when the mass conversion of solid content as a whole Ratio 3) The type and ratio of each spherical wax dispersion blended at 4 to 100 when the entire organic-inorganic composite film is converted to solid content mass

573〇62 A7573〇62 A7

表13 編 Cr 有機無機複合覆膜號金屬板附著量 (mg/m2) 水性# f脂/矽酸鹽化合物υ 二氧化矽2) 潤滑劑a3) 潤滑劑B3) 附著量 (g/m2) 種類量種類量種類量種類量種類量種類量 61 EG 40 Al ιοο — - Cl 35 D2 5 — E17 5 1.0 62 EG 40 Al ιοο - 一 Cl 50 D2 5 一 E17 5 1.0 63 EG 40 Al 100 — — C2 0 D2 5 一 E17 5 64 EG 40 Al 100 - — C2 5 D2 5 一 E17 5 ϊΤο^ 65 EG 40 Al 100 - — C2 10 D2 5 一 E17 5 l.O 66 EG 40 Al 100 - — C2 35 D2 5 一 E17 5 l .〇 67_ EG 40 Al 100 - 一 C2 50 D2 5 一 E17 5 iTo~ 68 EG 40 A2 90 A4 ΙΟ Cl 15 D2 5 一 E17 5 l.O 69 EG 40 A2 90 A4 ΙΟ Cl 15 D3 5 一 E17 5 iTo~ 70 EG 40 A2 90 A4 ΙΟ Cl 15 D9 5 一 E17 5 71 EG 40 A3 90 A4 ΙΟ Cl 15 D2 5 一 E17 5 \7qT~ 72 EG 40 A3 90 A4 ΙΟ Cl 15 D3 5 一 E17 5 l.O 73 —EG 40 A3 90 A4 ΙΟ Cl 15 D9 5 一 E17 5 iToT 74 EG 40 Bl 100 - - Cl 15 D2 5 一 E17 5 l.O 75 EG 40 B2 100 一 — Cl 15 D2 5 - E17 5 lTo^ 76 EG 40 B3 100 - - Cl 15 D2 5 — E17 5 iTo~~ 77 EG 40 Bl 90 Al ΙΟ Cl 15 D2 5 一 E17 5 l.O 78 EG 40 Bl 90 A4 ΙΟ Cl 15 D2 5 — E17 5 lTo^" 79 EG 一 A3 90 A4 ΙΟ Cl 15 D2 5 — E17 5 i7o^ 80 EG — A3 90 A4 ΙΟ Cl 15 D3 5 — E17 5 iTo~ 81 EG - A3 90 A4 ΙΟ Cl 15 D9 5 E17 5 i7o~ 82 ZN 40 A3 90 A4 ΙΟ Cl 15 D2 5 — E17 5 iTo'' 83 GI 40 A3 90 A4 ΙΟ Cl 15 D2 5 - - E17 5 ιΤΓ~ ---1----------裝--- • - (請先閱讀背面之注意事項再填寫本頁} Ηδτ· 1)水性樹脂或/及矽酸鹽化合物全體以固體成分質量經濟部智慧財產局員工消費合作社印製換具時為10 0時所換合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算時4 100時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時& 100時所摻合之各球形蠟分散體之種類與比率本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -51. 573062 A7 B7 五、發明說明（f 經濟部智慧財產局員工消費合作社印製表14 編號性能平板耐餘性加工部耐蝕性塗料# 浸潰無 fc附性浸潰有可焊性财加麼加工性耐磨耗性連續滑動次數動摩擦係數熱分解安定性備考 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 〇本發明 2 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 3 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 4 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 400 0.07 〇比較例 5 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 500 0.05 〇本發明 6 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 〇本發明 7 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 400 0.05 〇比較例 8 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 500 0.05 〇本發明 9 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 10 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 9000 0.06 〇本發明 11 ◎ © ◎ ◎ ◎ 〇 ◎ 450 0.07 〇比較例 12 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 500 0.05 〇本發明 13 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 600 0.05 〇本發明 14 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 600 0.06 〇本發明 15 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 400 0.08 〇本發明 16 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 X 比較例 17 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.06 〇本發明 18 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.05 〇本發明 19 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 700 0.06 〇本發明 20 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 450 0.10 〇比較例 21 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 X 比較例 22 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.07 〇本發明 23 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.06 〇本發明 24 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 700 0.07 〇本發明 25 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 450 0.15 〇比較例 26 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 X 比較例 27 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.07 〇本發明 28 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.06 〇本發明 29 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 700 0.07 〇本發明 30 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 450 0.10 〇比較例 (請先閱讀背面之注意事項再填寫本頁) 裝Table 13 Cr organic-inorganic composite coating No. metal plate adhesion amount (mg / m2) Water-based #f lipid / silicate compound υ Silicon dioxide 2) Lubricant a3) Lubricant B3) Adhesion amount (g / m2) Type Quantity Type Quantity Type Quantity Type Quantity Type Quantity 61 EG 40 Al ιοο —-Cl 35 D2 5 — E17 5 1.0 62 EG 40 Al ιοο-One Cl 50 D2 5 One E17 5 1.0 63 EG 40 Al 100 — — C2 0 D2 5-E17 5 64 EG 40 Al 100--C2 5 D2 5-E17 5 ϊΤο ^ 65 EG 40 Al 100--C2 10 D2 5-E17 5 lO 66 EG 40 Al 100--C2 35 D2 5-E17 5 l .〇67_ EG 40 Al 100-one C2 50 D2 5 one E17 5 iTo ~ 68 EG 40 A2 90 A4 ΙΟ Cl 15 D2 5 one E17 5 lO 69 EG 40 A2 90 A4 ΙΟ Cl 15 D3 5 one E17 5 iTo ~ 70 EG 40 A2 90 A4 IO Cl 15 D9 5-E17 5 71 EG 40 A3 90 A4 IO Cl 15 D2 5-E17 5 \ 7qT ~ 72 EG 40 A3 90 A4 IO Cl 15 D3 5-E17 5 lO 73 --EG 40 A3 90 A4 ΙΟ Cl 15 D9 5-E17 5 iToT 74 EG 40 Bl 100--Cl 15 D2 5-E17 5 lO 75 EG 40 B2 100--Cl 15 D2 5-E17 5 lTo ^ 76 EG 40 B 3 100--Cl 15 D2 5 — E17 5 iTo ~~ 77 EG 40 Bl 90 Al IO Cl 15 D2 5-E17 5 lO 78 EG 40 Bl 90 A4 IO Cl 15 D2 5 — E17 5 lTo ^ " 79 EG 1 A3 90 A4 ΙΟ Cl 15 D2 5 — E17 5 i7o ^ 80 EG — A3 90 A4 ΙΟ Cl 15 D3 5 — E17 5 iTo ~ 81 EG-A3 90 A4 ΙΟ Cl 15 D9 5 E17 5 i7o ~ 82 ZN 40 A3 90 A4 ΙΟ Cl 15 D2 5 — E17 5 iTo '' 83 GI 40 A3 90 A4 ΙΟ Cl 15 D2 5--E17 5 ιΤΓ ~ --- 1 ---------- install --- •-(Please Please read the precautions on the back before filling in this page} Ηδτ · 1) All the water-based resins and / or silicate compounds are printed with a solid content by the Intellectual Property Bureau of the Ministry of Economic Affairs, Ministry of Economic Affairs, and the Consumer Cooperatives. Types and ratios of each water-based resin 2) When the entire organic-inorganic composite film is converted to solid content mass 4 4 100 types and ratios of silicon dioxide blended 3) When the entire organic-inorganic composite film is converted to solid content mass & Types and ratios of each spherical wax dispersion blended at 100 hours This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) -51. 573062 A7 B7 V. Description of the invention (f Printed in Table 14 of the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives. Numbered performance flat plate resistance processing department Corrosion-resistant coating # Dipping No fc Adhesive dipping There is solderability and processing resistance Abrasion resistance Number of continuous sliding times Dynamic friction coefficient Thermal decomposition stability Remarks 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 〇 This invention 2 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇 This invention 3 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇 The present invention 4 ◎ ◎ ◎ ◎ ◎ ◎ 400 0.07 〇 Comparative Example 5 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 500 0.05 〇 The present invention 6 ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 〇 The present invention 7 ◎ ◎ ◎ ◎ ◎ ◎ 400 0.05 〇 Comparative Example 8 ◎ ◎ ◎ ◎ ◎ ◎ 500 0.05 〇 The present invention 9 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇 The present invention 10 ◎ ◎ ◎ ◎ ◎ ◎ 9000 0.06 〇 The invention 11 ◎ © ◎ ◎ ◎ ◎ ○ ◎ 450 0.07 〇 Comparative Example 12 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 500 0.05 〇 13 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ 600 0.05 〇 Ming 14 ◎ ◎ ◎ ◎ ◎ ◎ 600 0.06 〇 15 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ 400 0.08 〇 16 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 X Comparative Example 17 ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.06 〇 This invention 18 ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.05 〇 This invention 19 ◎ ◎ ◎ ◎ ◎ ◎ 700 7006 〇 This invention 20 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 450 0.10 〇 Comparative Example 21 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 X Comparative Example 22 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.07 〇 23 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.06 〇 24 of the present invention ◎ ◎ ◎ ◎ ◎ 700 0.07 〇 25 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ 450 0.15 〇 Comparative Example 26 ◎ ◎ ◎ ◎ ◎ ◎ 800 0.05 X Comparative Example 27 ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.07 〇 This invention 28 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.06 〇 This invention 29 ◎ ◎ ◎ ◎ ◎ ◎ 700 0.07 〇 30 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ 450 0.10 〇 Comparative example (please read the precautions on the back before filling in this page)

m 1_1 ϋ· 一 0、 ϋ ϋ 11 I %. 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -52- 573062 A7 B7 五、發明說明（^ 經濟部智慧財產局員工消費合作社印製表15 編號性能平板耐餘性加工部耐蝕性塗料1 浸潰無占附性浸潰有可焊性财加壓加工性耐磨耗性連續滑動次數動摩擦係數熱分解安定性備考 31 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 800 0.05 〇本發明 32 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.06 〇本發明 33 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 900 0.05 〇本發明 34 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.06 〇本發明 35 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 36 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.06 〇本發明 37 ◎ ◎ ◎ ◎ ◎ 〇〇 800 0.06 〇本發明 38 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 1100 0.05 〇本發明 39 〇〇 ◎ 〇 ◎ ◎ ◎ 1500 0.05 〇本發明 40 ◎ ◎ ◎ ◎ ◎ 〇〇 800 0.06 〇本發明 41 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 1100 0.05 〇本發明 42 〇〇 ◎ 〇 ◎ ◎ ◎ 1500 0.05 〇本發明 43 X X Δ Δ ◎ X X 100 0.08 〇比較例 44 〇〇〇〇 ◎ 〇〇 500 0.06 〇本發明 45 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 46 ◎ ◎ ◎ 〇〇 ◎ ◎ 1500 0.05 〇本發明 47 ◎ ◎ ◎ 〇 X ◎ ◎ 1800 0.06 〇比較例 48 X X Δ Δ ◎ X X 100 0.08 〇比較例 49 〇〇〇〇 ◎ 〇〇 500 0.06 〇本發明 50 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 51 ◎ ◎ ◎ 〇〇 ◎ ◎ 1500 0.05 〇本發明 52 ◎ ◎ ◎ 〇 X ◎ ◎ 1800 0.06 〇比較例 53 X X Δ Δ ◎ X X 100 0.08 〇比較例 54 〇〇〇〇 ◎ 〇〇 500 0.06 〇本發明 55 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇本發明 56 ◎ ◎ ◎ 〇〇 ◎ ◎ 1500 0.05 〇本發明 57 ◎ ◎ ◎ 〇 X ◎ ◎ 1800 0.06 〇比較例 58 Δ Δ ◎ 〇 ◎ Δ 〇 800 0.10 〇比較例 59 〇〇 ◎ ◎ ◎ 〇〇 1000 0.10 〇本發明 60 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.10 〇本發明 (請先閱讀背面之注意事項再填寫本頁) -訂-!!丨| . 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -53- 573062 A7m 1_1 一 · 一 0, ϋ ϋ 11 I%. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -52- 573062 A7 B7 V. Description of invention (^ Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Consumer Cooperatives. Table 15 Numbered properties. Flatness. Residual Machining Department. Corrosion-resistant paint. 1 Dipping. No dipping. ◎ ◎ ◎ ◎ ◎ 800 0.05 〇 32 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.06 〇 33 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 0.0 0.05 〇 34 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.06 〇 Invention 35 ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇 Inventive 36 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1200 0.06 〇 Inventive 37 ◎ ◎ ◎ ◎ ◎ 〇〇800 0.06 〇 Inventive 38 ◎ ◎ ◎ ◎ ◎ ◎ 1100 0.05 〇 This invention 39 〇〇 ◎ ◎ ◎ ◎ 1500 0.05 〇 This invention 40 ◎ ◎ ◎ ◎ ◎ 〇800 800 0.06 〇 This invention 41 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 1100 0.05 〇 This invention 42 〇〇 ◎ ◎ ◎ ◎ 1500 0.05 〇 This invention 43 XX Δ Δ ◎ XX 100 0.08 〇 Comparative Example 44 〇〇〇〇 ◎ 〇 500 500 0.06 〇 This invention 45 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇 This invention 46 ◎ ◎ ◎ 〇〇 ◎ 1500 0.05 〇 This invention 47 ◎ ◎ ◎ ○ XX ◎ 1800 1800 0.06 〇 Comparative Example 48 XX Δ Δ XX 100 0.08 〇 Comparative Example 49 〇〇〇〇〇〇〇〇500 0.06 〇Invention 50 ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇Invention 51 ◎ ◎ ◎ 〇〇 ◎ ◎ 1500 0.05 〇Invention 52 ◎ ◎ ◎ X ◎ ◎ 1800 0.06 〇 Comparative Example 53 XX Δ Δ ◎ XX 100 0.08 〇 Comparative Example 54 〇〇〇〇〇 ◎ 〇〇500 0.06 〇 This invention 55 ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.05 〇 This invention 56 ◎ ◎ ◎ 〇 ○ ◎ 1500 0.05 〇 This invention 57 ◎ ◎ ◎ 〇 X ◎ ◎ 1800 0.06 〇 Comparative Example 58 Δ Δ ◎ ○ ◎ Δ 800 800 0.10 〇 Comparative Example 59 〇 ◎ ◎ ◎ 〇〇1000 0.10 〇 This invention 60 ◎ ◎ ◎ ◎ ◎ ◎ 1000 0.10 〇 The present invention (please read the notes on the back before filling in this page) -Order- !! 丨 |. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -53- 573062 A7

繼之，說明本發明第3觀點之例 (1 )藥劑之種類 - -- - - -- - ---裝------------I--- m * (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製於表1顯示所用藥劑之一覽表。除D7外之潤滑劑A，其Next, an example (1) of the third aspect of the present invention will be described. (1) Types of medicines------------------ I --- m * (please first (Please read the notes on the back and fill in this page.) The Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs has printed a list of the medicines used in Table 1. Lubricants A other than D7, which

依 JIS K 6760規定之密度為 950kg/m3〜1000kg/m3，依 Jis K 2207規定之硬度（穿透度）在〇·2丽以下，而以X射線繞射法求取之結晶度在80%以上，且熔點於110。(：〜15(TC之範圍内。本紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公釐） -54- 573062 A7 _ _ B7 五、發明說明（，表17 藥劑一覽表藥劑種類編说商品名有機樹脂 A1 内婦酸樹脂C東亞合成社製、AP-1508(12)) A2 聚烯烴系水性樹脂（東邦化學工業製、AR—2300 ) A3 聚胺基甲酸乙8旨系水性樹腊（Nippon-NSC掣、RA-RO A4 環氧系水性樹脂（大曰本INK製、迪克范《音譯y夕7 7彳y》EM-60) 矽酸鹽化合物 B1 鋰矽酸鹽 B2 納碎酸鹽 B3 ίρ矽酸鹽 - 膠體二氧化矽 C1 水性膠體二氧化矽（日產化學踅、商品名：司諾提克斯《音譯只/一テックス）Ν) C2 水性膠體二氧化矽（日產化學製、商品名：司諾提克斯{音譯—テック7》UP) 潤滑劑A +比較 D1 聚乙稀（分子量：6000、酸值：〇、粒徑：3·0μιη) D2 聚乙稀（分子量：8000、酸值：〇、粒徑：3.0μηι) D3 聚乙烯（分子量：15000、酸值：〇、粒徑：3·0μη〇 D4 聚乙烯（分子量：20000 '酸值：〇、粒徑：3.0μιη) D5 「聚乙烯（分子量：6000、酸值：〇、粒徑：Ο.ίμηι) D6 聚乙烯（分子量：6000、酸值：〇、粒徑：5·0μιη) D7 變性聚乙烯（分子量：1000、酸值：20、粒徑：3·0μιη) D8 變性聚乙烯（分子量：6000、酸值：20、粒徑：3·0μηι) D9 變性聚乙烯（分子量：8000、酸值：20、粒徑：3·0μηι) D10 變性聚乙烯（分子量：15000、酸值：20、粒徑：3·0μπ〇 D11 變性聚乙烯（分子量：20000、酸值：20、粒徑：3·0μπ〇 D12 變性聚乙稀（分子量：6000、酸值：20、粒徑：Ο.ΐμπι) D13 變性聚乙烯（分子量：6000、酸值：20、粒徑：5·0μχη) D14 變性聚乙烯（分子量：6000、酸值：40、粒徑：3·0μιη) D15 變性聚乙烯（分子量：6000、酸值：100、粒徑：3·0μιη) 潤滑劑B +比較 E16 聚乙烯（分子量：1000、酸值：〇、粒徑：0·6μιη) E17 聚乙烯（分子量：5000、酸值：0、粒徑：〇_6μηι) E18 聚乙烯（分子量：1000、酸值：〇、粒徑：3_0μη〇 E19 聚乙烯（分子量：1000、酸值：〇、粒徑：Ο.ίμιη) -----------装--------訂--------- • « (請先閱讀背面之注意事項再填寫本頁) (2 )金屬板之種類經濟部智慧財產局員工消費合作社印製金屬板係使用先前表2所示者。 (3 )鉻酸鹽處理如先前第1觀點之例所做之說明。 (4)水性有機無機複合塗料之調製將表17所示之水性樹脂及矽酸鹽化合物之一方或兩方，與膠體二氧化矽及潤滑劑以表18〜2〇所示之比率加以本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -55- 573062 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（夕摻合，而調製成水性有機無機複合塗料。 (5 )水性有機無機複合塗料之塗布•乾燥方法於施有（3)之鉻酸鹽處理之鍍金屬板上，塗布以（4) 調製成之水性有機無機複合塗料達乾態質量為表丨8〜2〇所示之值，並以到達板溫140X：進行烘烤乾燥而製成評價用樣本。此外，有機複合覆膜之附著量係藉由權重法測定塗布時之液膜量而算出。 (6 )性能評價項目 a .平板耐餘性如先前第1觀點之例所做之說明。 b. 加工部耐餘性如先前第1觀點之例所做之說明。 c. 塗料黏附性如先前第1觀點之例所做之說明。 d·可連續焊接性如先前第1觀點之例所做之說明。 e·耐壓磨損性如先前第1觀點之例所做之說明。 f·表層潤滑劑之耐剝離性試驗針對以（5)製成之樣本連續進行ι〇〇次之前述矩形曲柄式壓力試驗。再觀察連續壓力試驗後附著於模具上之表層潤滑劑之剝離狀況而加以評價。以下之評價中〇係判定為良好。〇··無黏稠性潤滑物堆積 (請先閱讀背面之注意事項再填寫本頁)The density according to JIS K 6760 is 950kg / m3 ~ 1000kg / m3, the hardness (penetration) according to Jis K 2207 is less than 0.2 L, and the crystallinity obtained by X-ray diffraction method is 80%. Above, and the melting point is 110. (: ~ 15 (within TC.) This paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) -54- 573062 A7 _ _ B7 V. Description of the invention (, Table 17 List of medicaments List of medicaments Product name: Organic resin A1; House acid resin C; manufactured by Toa Kosei Co., Ltd .; AP-1508 (12)) A2 Polyolefin-based water-based resin (manufactured by Toho Chemical Industry Co., AR-2300) A3 Polyurethane-based resin 8 Tree wax (Nippon-NSC, RA-RO A4 epoxy water-based resin (manufactured by Daikoku INK, Dick Fan "Transliteration 7 7 彳 y" EM-60) Silicate compound B1 Lithium silicate B2 Na Broken acid salt B3 ίρ Silicate-Colloidal silica C1 Hydrocolloid silica (Nissan Chemical Co., Ltd., trade name: Snodix "Transliteration only / One テックス) N) C2 Hydrocolloid silica (Nissan Chemical Co., Ltd. System, product name: Snotiks {Transliteration-テック 7 "UP) Lubricant A + Comparison D1 Polyethylene (Molecular Weight: 6000, Acid Value: 〇, Particle Size: 3.0 μm) D2 Polyethylene (Molecular Weight : 8000, acid value: 0, particle size: 3.0 μm) D3 polyethylene (molecular weight: 15000, acid : 〇, particle size: 3.0 μη〇 D4 polyethylene (molecular weight: 20,000 'acid value: 〇, particle size: 3.0 μm) D5 "polyethylene (molecular weight: 6000, acid value: 0, particle size: 0. Ιμηι) D6 polyethylene (molecular weight: 6000, acid value: 0, particle size: 5.0 μm) D7 modified polyethylene (molecular weight: 1000, acid value: 20, particle size: 3.0 μm) D8 modified polyethylene (molecular weight: 6000, Acid value: 20, particle size: 3.0 μm) D9 modified polyethylene (molecular weight: 8000, acid value: 20, particle size: 3.0 μm) D10 modified polyethylene (molecular weight: 15000, acid value: 20, particle size: 3.0μπ〇D11 denatured polyethylene (molecular weight: 20000, acid value: 20, particle size: 3.0μπ〇D12 denatured polyethylene (molecular weight: 6000, acid value: 20, particle size: 0.) μπι) D13 denatured polyethylene Ethylene (Molecular weight: 6000, Acid value: 20, Particle size: 5.0 μxη) D14 Modified polyethylene (Molecular weight: 6000, Acid value: 40, Particle diameter: 3.0 μm) D15 Modified polyethylene (Molecular weight: 6000, Acid value : 100, particle size: 3.0 μm) Lubricant B + Comparative E16 polyethylene (molecular weight: 1000, acid : 0, particle size: 0.6 μm) E17 polyethylene (molecular weight: 5000, acid value: 0, particle size: 0-6 μm) E18 polyethylene (molecular weight: 1000, acid value: 0, particle size: 3_0 μη〇E19 poly Ethylene (Molecular weight: 1000, Acid value: 〇, Particle size: Ο.ίμιη) ----------- Packing -------- Order --------- • « (Please read the precautions on the back before filling this page) (2) Types of metal plates The metal plates printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs use the ones shown in Table 2 above. (3) Chromate treatment As explained in the example of the first aspect. (4) Preparation of water-based organic-inorganic composite coatings One or both of the water-based resins and silicate compounds shown in Table 17 and colloidal silicon dioxide and lubricants are added to this paper at the ratios shown in Tables 18 to 20. Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) -55- 573062 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (5) Coating and drying method of water-based organic-inorganic composite coating on a chromate-treated metallized plate coated with (3), coating the water-based organic-inorganic composite coating prepared in (4) to the dry state quality as the table丨 The values shown in 8 to 20 are obtained by reaching a plate temperature of 140X: baking and drying to prepare samples for evaluation. In addition, the adhesion amount of the organic composite film is determined by measuring the amount of the liquid film at the time of coating by a weight method. Calculate. (6) Performance evaluation items a. Flat plate resistance as described in the example of the first point of view. B. Processing part resistance as described in the example of the first point of view. C. Coating adhesion As in the previous point of view example Explanation. D. Continuous weldability is as described in the example of the first point of view. E. Pressure resistance is as described in the example of the first point of view. F. Peel resistance test of surface lubricant (5) The prepared sample was subjected to the aforementioned rectangular crank pressure test for 100,000 times. The peeling condition of the surface lubricant adhered to the mold after the continuous pressure test was evaluated and evaluated. In the following evaluations, 0 was judged as Good. 〇 ·· No viscous lubricant deposits (please read the precautions on the back before filling this page)

n ϋ^OJ· I ϋ ϋ ϋ I ϋ I ρn ϋ ^ OJ · I ϋ ϋ ϋ I ϋ I ρ

-56- 573062 A7 ______B7__ 五、發明說明（苓 X :有黏稠性潤滑物堆積 g·耐磨耗性試驗如先前第1觀點之例所做之說明。 h·靜摩擦係數如先前第1觀點之例所做之說明。 i·動摩擦係數如先前第1觀點之例所做之說明。以上評價結果將顯示於表21〜2 3。由該等結果可知藉由本發明之技術即可製得一耐蝕性、黏附性、可焊性等各種性能倶佳，且具優異财壓磨損性與耐線圈變形性，進而可抑制於壓製時潤滑劑自覆膜脫落而引起黏稠性殘渣產生之表面處理金屬板。 11111 裝-----1--tr--------- • 9 Γ请先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -57- 573〇62 A7 B7 五、發明說明（表18 編號金屬板 Cr 附著量 (mg/m2) 有機無機複合覆膜c 有機無機複合菝膜D 水性樹脂/ 化合身矽睃鹽分1) 潤滑劑A3) 潤滑劑 B3) 附著量 (g/m2) 水性樹脂/ 化合4 策酸鹽 0 化^ 氧夕2) 附著量 (g/m2) 種類量種類量種類量種類量種類量種類量種類量種類量 1 eg 40 A1 100 — — D1 40 — — - - 0.2 A1 100 — 一 C1 15 1.0 2 eg 40 A1 100 — — D2 40 — — — — 0.2 A1 100 一 — C1 15 1.0 3 eg 40 A1 100 — 一 D3 40 — — - - 0.2 A1 100 一一 C1 15 1.0 4 eg 40 A1 100 — — D4 40 — — - — 0.2 A1 100 一一 C1 15 1.0 5 eg 40 A1 100 — — D5 40 — — — — 0.2 A1 100 一一 C1 15 1.0' 6 eg 40 A1 100 — — D6 40 — — — — 0.2 A1 100 一一 C1 15 ι.Τ 7 eg 40 A1 100 — — D7 40 — 一 — — 0.2 A1 100 — 一 C1 15 1.0 8 eg 40 A1 100 — — D8 40 一一 - 一 0.2 A1 100 一一 C1 15 1.0 Τ7〇Γ 9 EG 40 A1 100 — — D9 40 — — — — 0.2 A1 100 — 一 C1 15' 10 eg 40 A1 100 — — D10 40 — — — — 0.2 A1 100 — 一 C1 15 1.0 11 eg 40 A1 100 - — D1 1 40 — — - — 0.2 A1 100 一一 C1 15 1.0 12 EG 40 A1 100 一 — D12 40 — — — — 0.2 A1 100 一一 C1 15 1.0 13 EG 40 A1 100 — — D13 40 — — — — 0.2 A1 100 — 一 C1 15 l.〇l 14 EG 40 A1 100 - — D14 40 — - — — 0.2 A1 100 — - C1 15 1.0 15 EG 40 A1 100 — — D15 40 — — 一一 0.2 A1 100 一 — C1 15 1.0 16 EG 40 A1 100 — — D2 30 — — E16 10 0.2 A1 100 — — C1 15 1·0_ 17 EG 40 A1 100 - — D2 30 — — E17 10 0.2 A1 100 一 - C1 15 1.0 18 EG 40 A1 100 — - D6 30 — 一 E18 10 0.2 A1 100 — — C1 15 5.0 19 EG 40 A1 100 — 一 D2 30 — — E19 10 0.2 A1 100 一 — C1 15 1.0_ 20 EG 40 A1 100 — — D2 30 — — E20 10 0.2 A1 100 — — C1 15 1.0 21 EG 40 A1 100 — 一 D9 30 — — E16 10 0.2 A1 100 — — C1 15 1.0 22 EG 40 A1 100 一 - D9 30 — — E17 10 0.2 A1 100 — — C1 15 1.0 23 EG 40 A1 100 — — D13 30 — — E18 10 0.2 A1 100 — — C1 15 5.0 24 EG 40 A1 100 — — D9 30 — — E19 10 0.2 A1 100 — - C1 15 1.0 25 EG 40 A1 100 — — D9 30 — — E20 10 0.2 A1 100 — — C1 15 1.0 26 EG 40 A1 100 — - D2 4 — — E16 36 0.2 A1 100 — — C1 15 1.0 27 EG 40 A1 100 — — D2 36 — — E16 4 0.2 A1 100 — — C1 15 1.0 28 EG 40 A1 100 — — D3 4 — — E16 36 0.2 A1 100 — — C1 15 ι .ο— 29 EG 40 A1 100 — — D3 36 — — E16 4 0.2 A1 100 — — C1 15 1.0 30 EG 40 A1 100 — — D2 10 D8 10 E16 20 0.2 A1 100 - — C1 15 1.0 (請先閱讀背面之注意事項再填寫本頁) I — I I 訂- — — I!!· 經濟部智慧財產局員工消費合作社印製 1) 水性樹脂或/及矽酸鹽化合物全體以固體成分質量換算時為100時所摻合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之各球形蠟分散體之種類與比率 -58- 573062 A7 -----B7-56- 573062 A7 ______B7__ 5. Description of the invention (Ling X: with viscous lubricant deposits g. Abrasion resistance test as explained in the previous example of the first point of view. H. Static friction coefficient as in the previous example of the first point of view The explanations are made. I. The coefficient of dynamic friction is as described in the example of the first point of view. The above evaluation results are shown in Tables 21 to 23. From these results, it is known that a corrosion resistance can be obtained by the technology of the present invention. Various properties such as, adhesion, solderability, etc., are excellent, and have excellent financial pressure abrasion resistance and coil deformation resistance, which can further suppress the surface treatment metal plate caused by the sticky residue caused by the lubricant falling off from the film during pressing. Installation ----- 1--tr --------- • 9 Γ Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employee Consumer Cooperatives This paper is applicable to Chinese countries Standard (CNS) A4 specifications (210 x 297 mm) -57- 573〇62 A7 B7 V. Description of the invention (Table 18 Number of metal plate Cr adhesion (mg / m2) Organic-inorganic composite film c Organic-inorganic composite film D Water-based resin / compounded silica gel salt 1) Lubricant A3) Lubricant B3) Adhesion (g / m2) Water-based resin / combination 4 Salt acid 0 ^ Oxygen 2) Adhesion (g / m2) Kind amount Kind amount Kind amount Kind amount Kind number Kind Quantity Type Quantity 1 eg 40 A1 100 — — D1 40 — —--0.2 A1 100 — One C1 15 1.0 2 eg 40 A1 100 — — D2 40 — — — — 0.2 A1 100 One — C1 15 1.0 3 eg 40 A1 100 — One D3 40 — —--0.2 A1 100 One one C1 15 1.0 4 eg 40 A1 100 — — D4 40 — —-— 0.2 A1 100 One one C1 15 1.0 5 eg 40 A1 100 — — D5 40 — — — — 0.2 A1 100 one one C1 15 1.0 '6 eg 40 A1 100 — — D6 40 — — — — 0.2 A1 100 one one C1 15 ι.Τ 7 eg 40 A1 100 — — D7 40 — one — — 0.2 A1 100 — one C1 15 1.0 8 eg 40 A1 100 — — D8 40 one one-one 0.2 A1 100 one one C1 15 1.0 Τ7〇Γ 9 EG 40 A1 100 — — D9 40 — — — — 0.2 A1 100 — one C1 15 '10 eg 40 A1 100 — — D10 40 — — — — 0.2 A1 100 — One C1 15 1.0 11 eg 40 A1 100-— D1 1 40 — — -— 0.2 A1 100-one C1 15 1.0 12 EG 40 A1 100 one-D12 40 — — — — 0.2 A1 100-one C1 15 1.0 13 EG 40 A1 100 — — D13 40 — — — — 0.2 A1 100 — one C1 15 l.〇l 14 EG 40 A1 100-— D14 40 —-— — 0.2 A1 100 —-C1 15 1.0 15 EG 40 A1 100 — — D15 40 — — One 0.2 A1 100 One — C1 15 1.0 16 EG 40 A1 100 — — D2 30 — — E16 10 0.2 A1 100 — — C1 15 1 · 0_ 17 EG 40 A1 100-— D2 30 — — E17 10 0.2 A1 100--C1 15 1.0 18 EG 40 A1 100 —-D6 30 — One E18 10 0.2 A1 100 — — C1 15 5.0 19 EG 40 A1 100 — One D2 30 — — E19 10 0.2 A1 100 One — C1 15 1.0_ 20 EG 40 A1 100 — — D2 30 — — E20 10 0.2 A1 100 — — C1 15 1.0 21 EG 40 A1 100 — One D9 30 — — E16 10 0.2 A1 100 — — C1 15 1.0 22 EG 40 A1 100 One-D9 30 — — E17 10 0.2 A1 100 — — C1 15 1.0 23 EG 40 A1 100 — — D13 30 — — E18 10 0.2 A1 100 — — C1 15 5.0 24 EG 40 A1 100 — — D9 30 — — E19 10 0.2 A1 100 —-C 1 15 1.0 25 EG 40 A1 100 — — D9 30 — — E20 10 0.2 A1 100 — — C1 15 1.0 26 EG 40 A1 100 —-D2 4 — — E16 36 0.2 A1 100 — — C1 15 1.0 27 EG 40 A1 100 — — D2 36 — — E16 4 0.2 A1 100 — — C1 15 1.0 28 EG 40 A1 100 — — D3 4 — — E16 36 0.2 A1 100 — — C1 15 ι .ο— 29 EG 40 A1 100 — — D3 36 — — E16 4 0.2 A1 100 — — C1 15 1.0 30 EG 40 A1 100 — — D2 10 D8 10 E16 20 0.2 A1 100-— C1 15 1.0 (Please read the notes on the back before filling out this page) I — II Order- — — I !! · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1) Types and ratios of water-based resins blended when the total amount of water-based resins and / or silicate compounds is 100 in terms of solid content mass Types and ratios of silicon dioxide blended when the entire organic-inorganic composite coating is 100 when solid content mass conversion is used3) Spherical waxes blended when the entire organic-inorganic composite coating is 100 when solid content mass conversion is used Types and ratios of dispersions -58- 573062 A7 ----- B7

五、發明說明（J 表19 編號金屬板 Cr 附著量 (mg/m2) 有機無機複合覆膜c 有機無機名 1 合水， ti樹月 !化洽 1/梦酸 ‘物D 潤滑劑A3) 潤劑] 滑 B3) 附著量 (g/m2) 水性樹脂/矽酸鹽化合物n 一氧化矽2) 附著量 (g/m2) 種類量種類量種類量種類量種類量種類量種類量種類量 3 1 EG 40 A1 100 — - D3 10 - — E16 20 0.2 A1 100 — — C1 15 1.0 32 EG 40 A1 100 — 一 D2 1.0 — - E16 1.0 0.2 A1 100 — 一 C1 15 1.0 33 EG 40 A1 100 — 一 D2 10 一 - E16 10 0.2 A1 100 — — C1 15 l.F' 34 EG 40 A1 100 — — D2 20 - 一 E16 20 0.2 A1 100 — 一 C1 15 1.0 ' 36 EG 40 A1 100 — — D2 30 - — E16 30 0.2 A1 100 — — C1 15 1.0 3 6 HG 40 A1 100 — 一 D3 1.0 - - E16 1.0 0.2 A1 100 — — C1 15 1.0 37 EG 40 A1 100 — — D3 10 - - E16 10 0.2 A1 100 — — C1 15 38 EG 40 A1 100 — - D3 20 — - E16 20 0.2 A1 100 — — C1 ιΓ 39 EG 40 A1 100 — - D3 30 — — E16 30 0.2 A1 100 — — C1 15 1.0 40 EG 40 A1 100 — — D2 40 — - - - 0.2 A1 100 — — C1 15 0.1 — 41 EG 40 A1 100 一一 D2 40 — 一一 - 0.2 A1 100 — 一 C1 15 0.5 42 EG 40 A1 100 — — D2 40 — — - - 0.2 A1 100 — 一 C1 15 2.0 43 EG 40 A1 100 — — D6 40 — — - — 0.2 A1 100 — — C1 15 5.0 44 EG 40 A1 100 — — D6 40 — — — — 0.2 A1 100 — — C1 15 10. 45 EG 40 A1 100 — — D9 40 — — — - 0.2 A1 100 — 一 C1 15 0.1 46 EG 40 A1 100 — — D9 40 — 一 - - 0.2 A1 100 — — C1 15 0.5 47 EG 40 A1 100 — — D9 40 — — — — 0.2 A1 100 — — C1 15 2.0 ~ 48 EG 40 A1 100 — — D13 40 — 一一 - 0.2 A1 100 — — C1 15 ΓΤΓο^ 49 EG 40 A1 100 — — D13 40 — 一 - — 0.2 A1 100 - - C1 15 10.0 50 EG 40 A1 100 — — D2 40 — — — - 0.01 A1 100 — — C1 15 1.0— 5 1 EG 40 A1 100 — — D2 40 — - 一 - 0.05 A1 100 - — C1 15 1.0 52 JT EG 40 A1 100 — — D2 40 — — 一 - 0.3 A1 100 - — C1 15 1.0 EG 40 A1 100 — — D9 40 — — — - 0.01 A1 100 — — C1 15 5.0 54 EG 40 A1 100 — — D9 40 — — — - 0.05 A1 100 — — C1 15 1.0 55 EG 40 A1 100 — — D9 40 — — — - 0.3 A1 100 — — C1 15 1.0 5 6 EG 40 A1 100 一一 D2 40 — — 一一 0.2 A1 100 一 — C1 0 1 .〇 57 EG 40 A1 100 — 一 D2 40 — — — — 0.2 A1 100 — 一 C1 5 1.0 58 EG 40 A1 100 — D2 40 — — — — 0.2 A1 100 — — C1 15 1.0 1)水性樹脂或/及矽酸鹽化合物全體以固體成分質量 I---· I------^--------- ^ I ' (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製換算時為100時所掺合之各水性樹脂之種類與比率 2) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算時為 100時所摻合之各球形蠟分散體之種類與比率V. Description of the invention (J Table 19 Number of Cr attached to the metal plate (mg / m2) Organic-inorganic composite coating c Organic-inorganic name 1 Hydration, ti tree month! Chemical contact 1 / dream acid 'substance D lubricant A3) Agent] slip B3) adhesion amount (g / m2) water-based resin / silicate compound n silicon oxide 2) adhesion amount (g / m2) species amount species amount species amount species amount species amount species amount species amount species amount 3 1 EG 40 A1 100 —-D3 10-— E16 20 0.2 A1 100 — — C1 15 1.0 32 EG 40 A1 100 — one D2 1.0 —-E16 1.0 0.2 A1 100 — one C1 15 1.0 33 EG 40 A1 100 — one D2 10 One-E16 10 0.2 A1 100 — — C1 15 lF '34 EG 40 A1 100 — — D2 20-One E16 20 0.2 A1 100 — One C1 15 1.0' 36 EG 40 A1 100 — — D2 30-— E16 30 0.2 A1 100 — — C1 15 1.0 3 6 HG 40 A1 100 — One D3 1.0--E16 1.0 0.2 A1 100 — — C1 15 1.0 37 EG 40 A1 100 — — D3 10--E16 10 0.2 A1 100 — — C1 15 38 EG 40 A1 100 —-D3 20 —-E16 20 0.2 A1 100 — — C1 ιΓ 39 EG 40 A1 100 —-D3 30 — — E16 30 0.2 A1 100 — — C1 15 1.0 40 EG 40 A1 100 — — D2 40 —---0.2 A1 100 — — C1 15 0.1 — 41 EG 40 A1 100-One D2 40 — One-0.2 A1 100 — One C1 15 0.5 42 EG 40 A1 100 — — D2 40 — —--0.2 A1 100 — One C1 15 2.0 43 EG 40 A1 100 — — D6 40 — — — — 0.2 A1 100 — — C1 15 5.0 44 EG 40 A1 100 — — D6 40 — — — — 0.2 A1 100 — — C1 15 10. 45 EG 40 A1 100 — — D9 40 — — —-0.2 A1 100 — one C1 15 0.1 46 EG 40 A1 100 — — D9 40 — one--0.2 A1 100 — — C1 15 0.5 47 EG 40 A1 100 — — D9 40 — — — — 0.2 A1 100 — — C1 15 2.0 ~ 48 EG 40 A1 100 — — D13 40 — One One-0.2 A1 100 — — C1 15 ΓΤΓο ^ 49 EG 40 A1 100 — — D13 40 — One — — 0.2 A1 100--C1 15 10.0 50 EG 40 A1 100 — — D2 40 — — —-0.01 A1 100 — — C1 15 1.0 — 5 1 EG 40 A1 100 — — D2 40 —-One-0.05 A1 100-— C1 15 1.0 52 JT EG 40 A1 100 — — D2 40 — — One-0.3 A1 100-— C1 15 1. 0 EG 40 A1 100 — — D9 40 — — —-0.01 A1 100 — — C1 15 5.0 54 EG 40 A1 100 — — D9 40 — — — — 0.05 A1 100 — — C1 15 1.0 55 EG 40 A1 100 — — D9 40 — — —-0.3 A1 100 — — C1 15 1.0 5 6 EG 40 A1 100 One D2 40 — — One 0.2 A1 100 One — C1 0 1. 1.057 EG 40 A1 100 — One D2 40 — — — — 0.2 A1 100 — One C1 5 1.0 58 EG 40 A1 100 — D2 40 — — — — 0.2 A1 100 — — C1 15 1.0 1) Water-based resins and / or silicate compounds as a whole solid mass I --- · I ------ ^ --------- ^ I '(Please read the notes on the back before filling out this page) Blended at 100 hours when printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Types and ratios of each water-based resin 2) Types and ratios of silicon dioxide blended when the entire organic-inorganic composite coating is 100 when solid content mass conversion is performed 3) When the entire organic-inorganic composite coatings are converted by solid content mass Types and ratios of each spherical wax dispersion blended at 100

-59- 573062 A7 ___ B7 五、發明說明（？經濟部智慧財產局員工消費合作社印製表20 編號金屬板 Cr 附著量 (mg/m2) 有本 1無機複合覆！ RC 有機無機複合覆膜D 水性樹脂化合ί 〖矽酸鹽潤滑齊1 'JA3 ) 潤界 Β: 卜劑 ο 附著量 (g/m2) 水性樹脂/矽酸鹽化合物u 二氣化矽W 附著量 (g/m2) 種類量種類量種類量種類量種類量種類量種類量種類量 59 EG 40 Α1 100 — — D2 40 — — 一 — 0.2 A1 100 — — C1 35 1.0 60 EG 40 Α1 100 — — D2 40 — — — — 0.2 A1 100 — — C1 50 1.0 61 EG 40 Α1 100 — — D2 40 — — — — 0.2 A1 100 — — C2 0 1.0 62 EG 40 Α1 100 — — D2 40 — — — 0.2 A1 100 — — C2 5 1.0 63 EG 40 Α1 100 — — D2 40 — — — 一 0.2 A1 100 — — C2 10 1.0 64 EG 40 Α1 100 — — D2 40 — 一 — 一 0.2 A1 100 — — C2 35 1 0 65 EG 40 Α1 100 — — D2 40 — 一 — — 0.2 A1 100 — — C2 50 A · V/ 1 0 66 EG 40 Α2 90 Α4 10 D2 40 — 一一一 0.2 A2 90 A4 10 C1 15 A · \J 1 0 67 EG 40 Α2 90 Α4 10 D3 40 _ 一 — 一 0.2 A2 90 A4 10 C1 15 1.0 68 EG 40 Α2 90 Α4 10 D9 40 — 一 — 0.2 A2 90 A4 10 C1 15 l o 69 EG 40 A3 90 Α4 10 D2 40 — 一一 0.2 A3 90 A4 10 C1 15 · V/ 1 〇 70 EG 40 A3 90 Α4 10 D3 40 — 一一 0.2 A3 90 A4 10 C1 15 A - v 1 〇 71 EG 40 A3 90 Α4 10 D9 40 — 一一 — 0.2 A3 90 A4 10 C1 1 5 A . \J 1 A 72 EG 40 Β1 100 — — D2 40 — — — — 0.2 B1 100 — 一 C1 15 l . y) 1 Λ 73 EG 40 Β2 100 — — D2 40 — 一 — 一 0.2 B2 100 — 一 C1 15 1 . U 1 Λ 74 EG 40 Β3 100 — — D2 40 — — — — 0.2 B3 100 一一 C1 15 1 . U 1 f\ 75 EG 40 Β1 90 Α1 10 D2 40 — — — — 0.2 B1 90 A1 10 C1 1 X： 1. u 1 r\ 76 EG 40 Β1 90 Α4 10 D2 40 — — 一一卜0.2 B1 90 A4 10 C1 1 J 1 < 1.0 77 7 8 EG EG — A3 A3 90 90 Α4 Α4 10 10 D2 D3 40 40 - - 一 - 0.2 0.2 A3 A3 90 90 A4 A4 10 10 C1 C1 1 J 15 15 1.0 1.0 1 Λ 79 80 81 EG ZN G1 40 40 A3 A3 A3 90 90 90 Α4 Α4 Α4 10 10 10 D9 D2 D2 40 40 40 - - 一一 0.2 0.2 0.2 A3 A3 A3 90 90 90 A4 A4 A4 10 10 10 C1 C1 C1 15 15 15 1 . u 1.0 r?-1.0 1)水性樹脂或/及矽酸鹽化合物全體以固體成分f量換鼻時為1 〇〇時所推合之各水性樹脂之種類與比率^ 2) 有機無機複合覆膜全體以固體成分質量換算日寺^ 100時所摻合之二氧化矽之種類與比率 3) 有機無機複合覆膜全體以固體成分質量換算日夺^ 100時所摻合之各球形蠟分散體之種類與比率-59- 573062 A7 ___ B7 V. Description of the invention (? Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employee Consumption Cooperative Table 20 Numbered metal plate Cr attached amount (mg / m2) There is an inorganic composite coating of this one! RC Organic inorganic composite coating D Water-based resin compound 〖Silicon Lubricant 1 'JA3) Moisturizing B: Bleaching agent ο Adhesive amount (g / m2) Water-based resin / silicate compound u Digasified silicon W Adhesive amount (g / m2) Kind amount Kind amount Kind amount Kind amount Kind amount Kind amount Kind amount Kind amount 59 EG 40 Α1 100 — — D2 40 — — — — 0.2 A1 100 — — C1 35 1.0 60 EG 40 Α1 100 — — D2 40 — — — — 0.2 A1 100 — — C1 50 1.0 61 EG 40 Α1 100 — — D2 40 — — — — 0.2 A1 100 — — C2 0 1.0 62 EG 40 Α1 100 — — D2 40 — — — 0.2 A1 100 — — C2 5 1.0 63 EG 40 Α1 100 — — D2 40 — — — — 0.2 A1 100 — — C2 10 1.0 64 EG 40 Α1 100 — — D2 40 — — — 0.2 A1 100 — — C2 35 1 0 65 EG 40 Α1 100 — — D2 40 — One — — 0.2 A1 100 — — C2 50 A · V / 1 0 66 EG 40 Α2 90 Α4 10 D2 40 — one by one 0.2 A2 90 A4 10 C1 15 A · \ J 1 0 67 EG 40 Α2 90 Α4 10 D3 40 _ one — one 0.2 A2 90 A4 10 C1 15 1.0 68 EG 40 Α2 90 Α4 10 D9 40 — One — 0.2 A2 90 A4 10 C1 15 lo 69 EG 40 A3 90 Α4 10 D2 40 — One 0.2 0.2 A3 90 A4 10 C1 15 · V / 1 〇70 EG 40 A3 90 Α4 10 D3 40 — One and one 0.2 A3 90 A4 10 C1 15 A-v 1 〇71 EG 40 A3 90 Α4 10 D9 40 — One and one — 0.2 A3 90 A4 10 C1 1 5 A. \ J 1 A 72 EG 40 Β1 100 — — D2 40 — — — — 0.2 B1 100 — One C1 15 l. Y) 1 Λ 73 EG 40 Β2 100 — — D2 40 — One — one 0.2 B2 100 — One C1 15 1. U 1 Λ 74 EG 40 Β3 100 — — D2 40 — — — — 0.2 B3 100-One C1 15 1. U 1 f \ 75 EG 40 Β1 90 Α1 10 D2 40 — — — — 0.2 B1 90 A1 10 C1 1 X: 1. u 1 r \ 76 EG 40 Β1 90 Α4 10 D2 40 — — one and one 0.2 0.2 B1 90 A4 10 C1 1 J 1 < 1.0 77 7 8 EG EG — A3 A3 90 90 Α4 Α4 10 10 D2 D3 40 40--one-0.2 0.2 A3 A3 90 90 A4 A4 10 10 C1 C1 1 J 15 15 1.0 1.0 1 Λ 79 80 81 EG ZN G1 40 40 A3 A3 A3 90 90 90 Α4 Α4 Α4 10 10 10 D9 D2 D2 40 40 40--0.2 0.2 0.2 A3 A3 A3 90 90 90 A4 A4 A4 10 10 10 C1 C1 C1 15 15 15 1. U 1.0 r? -1.0 1) Types and ratios of each water-based resin inferred when the water-based resin or / and the silicate compound as a whole is replaced with a solid content of f when the nose is 1000 ^ 2) Organic and inorganic The type and ratio of silicon dioxide blended at the time of conversion of solid content by the total weight of the composite film as a whole. 3) The spherical wax blended by the total weight of solid content by the conversion of solid content by the day of ^ 100 Types and ratios of dispersions

-------I-----裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 60- 573062 A7 B7 五、發明說明（子經濟部智慧財產局員工消費合作社印製表21 編號性能備考平板耐性加 X 部耐蝕性塗料黏附性可焊性耐加壓加工性耐摩耗性耐剝離性耐線圈變形性動摩擦係數靜摩擦係數浸潰無浸潰有 1 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.07 0.15 本發明 2 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 3 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇〇 0.15 0.25 本發明 4 ◎ ◎ ◎ ◎ ◎ Δ 〇〇〇 0.20 0.30 比較例 5 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇〇 0.08 .015 本發明 6 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.07 0.12 本發明 7 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 X 0.06 0.10 比較例 8 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.09 0.20 本發明 9 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 10 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇 0.15 0.30 本發明 11 ◎ ◎ ◎ ◎ ◎ X Δ 〇〇 0.20 0.35 比較例 12 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇 0.08 0.20 本發明 13 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.07 0.17 本發明 14 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.15 0.30 本發明 15 ◎ ◎ ◎ ◎ ◎ X X 〇〇 0.20 0.35 比較例 16 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 17 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 18 ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇〇 0.10 0.20 本發明 19 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 20 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 21 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 22 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 23 ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇〇 0.10 0.25 本發明 24 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 25 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 26 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇〇 0.12 0.25 本發明 27 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 28 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇〇 0.20 0.35 本發明 29 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.15 0.30 本發明 30 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 (請先閱讀背面之注意事項再填寫本頁) ▼裝------訂---------· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -61- 573062 A7 B7 五、發明說明（，經濟部智慧財產局員工消費合作社印製表22 編號性能備考平板耐蝕性加工部而于蝕性塗料黏附性可焊性耐加壓加工性耐摩耗性耐剝離性耐線圈變形性動摩擦係數靜摩擦係數浸潰無浸潰有 31 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.15 0.30 本發明 32 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇 0.15 0.30 本發明 33 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇〇 0.12 0.25 本發明 34 〇〇 ◎ 〇 ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 35 Δ Δ 〇 Δ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 36 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇 0.20 0.35 本發明 37 ◎ ◎ ◎ ◎ ◎ 〇 ◎ 〇〇 0.18 0.30 本發明 38 〇〇 ◎ 〇 ◎ ◎ ◎ 〇〇 0.15 0.30 本發明 39 Δ Δ 〇 Δ ◎ ◎ ◎ 〇〇 0.15 0.30 本發明 40 X X ◎ ◎ ◎ X X X 〇 0.08 0.15 比較例 41 〇〇〇〇 ◎ 〇〇〇〇 0.08 0.15 本發明 42 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 43 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇〇 0.10 0.30 本發明 44 ◎ ◎ ◎ 〇 X ◎ ◎ 〇〇 0.25 0.35 比較例 45 X X Δ Δ ◎ X X X 〇 0.08 0.15 比較例 46 〇〇〇〇 ◎ 〇〇〇〇 0.08 0.20 本發明 47 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 48 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇〇 0.10 0.25 本發明 49 ◎ ◎ ◎ 〇 X ◎ ◎ 〇〇 0.25 0.35 比較例 50 ◎ ◎ ◎ ◎ ◎ X X 〇〇 0.2 0.30 比較例 51 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇 0.15 0.25 本發明 52 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.1 0.20 本發明 53 ◎ ◎ ◎ ◎ ◎ X X 〇〇 0.20 0.30 比較例 54 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇 0.15 0.30 本發明 55 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.25 本發明 56 Δ Δ ◎ 〇 ◎ Δ 〇〇〇 0.10 0.20 比較例 57 〇〇 ◎ ◎ ◎ 〇〇〇〇 0.10 0.20 本發明 58 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇 0.10 0.20 本發明 --------1 — I------^--------- η 一 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -62- 573062 A7------- I ----- install -------- order --------- (Please read the precautions on the back before filling this page) 60- 573062 A7 B7 V. Description of the invention (printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Table 21 No. Performance Remarks Flatness resistance plus Part X Corrosion resistance Coating adhesion Solderability Pressure resistance Wear resistance Peel resistance Coil deformation Dynamic friction Coefficient of static friction coefficient impregnation without impregnation: 1 Invention 4 ◎ ◎ ◎ ◎ ◎ △ 〇〇〇0.20 0.30 Comparative Example 5 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.08.015 This invention 6 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.07 0.12 This invention 7 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 × 0.06 0.10 Comparative Example 8 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.09 0.20 The present invention 9 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.10 0.25 The present invention 10 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇0.15 0.30 The present invention 11 ◎ ◎ ◎ ◎ ◎ X Δ 〇〇0.20 0.35 Comparative Example 12 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇〇0.08 0.20 This invention 13 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.07 0.17 This invention 14 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.15 0.30 The present invention 15 ◎ ◎ ◎ ◎ XX 〇〇0.20 0.35 Comparative Example 16 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.10 0.20 The present invention 17 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.20 The present invention 18 ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.20 19 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ 〇0.10 0.20 20 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.20 21 of the present invention ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.10 0.25 The present invention 22 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.25 The present invention 23 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.10 0.25 The present invention 24 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.10 0.25 The present invention 25 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.25 The present invention 26 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.12 0.25 The present invention 27 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.10 0.20 The present invention 28 ◎ ◎ ◎ ◎ ◎ ○ ◎ 〇0.20 0.35 The present invention 29 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.15 0.15 0.30 The present invention 30 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇0.10 0.20 The present invention (please first Read the precautions on the reverse side and fill out this page) ▼ Packing ------ Order --------- · This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -61 -573062 A7 B7 V. Description of the invention (Printed in Table 22 of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, No. Performance Remarks Flat Plate Corrosion Resistance Processing Department and Corrosive Coating Adhesiveness Solderability Pressure Resistance Wear Resistance Peel Resistance Coil deformation resistance Coefficient of dynamic friction Coefficient of static friction Impregnation without impregnation 31 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.15 0.30 The present invention 32 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇0.15 0.30 The present invention 33 ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.12 0.25 The present invention 34 〇〇 ◎ 〇 ◎ ◎ ◎ 〇〇0.10 0.20 The present invention 35 Δ Δ 〇Δ ◎ ◎ ◎ 〇〇0.10 0.20 the present invention 36 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇0.20 0.35 The present invention 37 ◎ ◎ ◎ ◎ ◎ ○ ◎ 〇〇0.18 0.30 The present invention 38 〇 ○ ◎ ◎ ◎ ◎ 〇〇0.15 0.30 The present invention 39 Δ Δ 〇Δ ◎ ◎ ◎ 〇〇0.15 0.30 The present invention 40 XX ◎ ◎ XXX XXX 0.08 0.15 Comparative Example 41 〇〇〇〇〇〇〇〇〇0.08 0.15 The present invention 42 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.20 The present invention 43 ◎ ◎ ◎ 〇〇 ◎ 〇〇0.10 0.30 The present invention 44 ◎ ◎ ◎ ○ X ◎ ◎ 〇〇0.25 0.35 Comparative Example 45 XX Δ Δ ◎ XXX 〇0.08 0.15 Comparative Example 46 〇〇〇〇 ◎ 〇〇〇〇0.08 0.20 This invention 47 ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.25 The present invention 48 ◎ ◎ ◎ 〇〇 ◎ ◎ 〇〇0.10 0.25 The present invention 49 ◎ ◎ ◎ ○ X ◎ ◎ 〇〇0.25 0.35 Comparative Example 50 ◎ ◎ ◎ ◎ XX 〇〇0.2 0.30 Comparative Example 51 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇0.15 0.25 The present invention 52 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.1 0.20 The present invention 53 ◎ ◎ ◎ ◎ XX 〇〇0.20 0.30 Comparative Example 54 ◎ ◎ ◎ ◎ ◎ 〇〇〇〇0.15 0.30 The present invention 55 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ 0.10 0.25 The present invention 56 Δ Δ ◎ ◎ △ △ 〇〇〇0.10 0.20 Example 57 〇〇 ◎ ◎ ◎ 〇〇〇〇〇0.10 0.20 The present invention 58 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇〇0.10 0.20 The present invention -------- 1-I ------ ^ --- ------ η I (Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -62- 573062 A7

五、發明說明（f 表23V. Description of the invention (f Table 23

備考靜摩擦係數 0.20 1.20 1.20 —0.20 飞.20 0.20 ^.20 ^.20 0.25 ^.20 0.20 本發明比較例比較例孓發明本發明 I發明比較例本發明孓發明孓發明本發明 0.25 0.30 0.25 0.25 ~0.25Remarks Static friction coefficient 0.20 1.20 1.20 —0.20 Fly. 20 0.20 ^ .20 ^ .20 0.25 ^ .20 0.20 Comparative Examples of the present invention Comparative Examples 孓 Inventions of the present invention I Comparative Examples of the present invention 孓 Inventions 孓 Inventions of the present invention 0.25 0.30 0.25 0.25 ~ 0.25

本發明孓發明孓發明孓發明孓發明Invention invention invention invention invention invention invention

---^--------^--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本發明第i觀點之表面處理金屬板，係一種耐钱^ 附性、可焊性等各種性能倶佳，進而可維持耐壓磨損性並可改善因捲繞鬆弛所致之線圈毀壞或條狀板材打樁時負載崩潰之問題者，故適用於作為家電、建材及汽車類材料。又，藉由本發明第1觀點之水性有機無機複合塗料製造方法，則可供給市場一種具有良好之耐壓磨損性與線圈變形性之表面處理金屬板。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -63- y/3062--- ^ -------- ^ --------- (Please read the precautions on the back before filling out this page) The Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperatives printed the i-th view of the invention The surface-treated metal plate is a variety of excellent properties such as resistance to ^ adhesion, solderability, etc., which can maintain pressure wear resistance and improve coil damage caused by winding slack or load collapse when piling the strip. For those who have problems, it is suitable for use as home appliances, building materials and automotive materials. In addition, according to the method for producing an aqueous organic-inorganic composite paint according to the first aspect of the present invention, a surface-treated metal plate having good pressure wear resistance and coil deformability can be supplied to the market. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -63- y / 3062

、發明說明（ej 經濟部智慧財產局員工消費合作社印製本發明第2觀點之表面處理金屬板，係一種雜性、黏附!生、可焊性等各種性能俱佳，進而具優異耐壓磨損性盥耐連續滑動磨耗性者，故亦適用於作為家電、建材及汽車類之材料。此外’藉由本發明第2觀點之水性有機無機複合塗料與製造方法，則可供給市場—種具有良好之财壓磨損性與耐連續滑動磨耗性之表面處理金屬板。本發明第3觀點之表面處理金屬板，係一種耐蝕性、黏附丨生可焊性等各種性能倶佳，進而可維持耐壓磨損性，並可改善因捲繞鬆弛所致之線圈毁壞或條狀板材打樁時之負載朋潰之問題，亦可抑制於壓製時潤滑劑自覆膜脫落而引起之黏稠性殘渣產生者，故亦適用於作為家電、建材及汽車類之材料。此外，藉由本發明第3觀點之製造方法，則可供給市場一種具有良好耐壓磨損性與耐線圈變形性之表面處理金屬板。【元件標號對照表】 1···聚烯烴蠟分散體 24··.水性有機無機複合覆膜（D) 2…水性有機無機複合覆膜 3…鍵金屬板 11…潤滑劑（A) 12…潤滑劑（B) 13…水性有機無機複合覆膜 14···鍍金屬板 22…水性有機無機複合覆膜（C)、（C) 23…錢金屬板本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝 *laj— — — — — — — — —、 Explanation of the invention (ej) The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the surface-treated metal plate of the second aspect of the present invention, which is a variety of properties such as heterogeneity, adhesion, solderability, and excellent pressure resistance. Those that are resistant to continuous sliding abrasion resistance are also suitable for use as materials for home appliances, building materials, and automobiles. In addition, 'the water-based organic-inorganic composite coating and manufacturing method of the second aspect of the present invention can be supplied to the market—a kind of A surface-treated metal sheet with abrasion resistance and continuous sliding abrasion resistance. The surface-treated metal sheet according to the third aspect of the present invention is excellent in various properties such as corrosion resistance, adhesion, and solderability, and can maintain pressure-wear resistance. It can improve the problem of coil damage caused by winding looseness or load collapse during piling of strip-shaped plates, and can also suppress the generation of viscous residues caused by the lubricant falling off the film during pressing, so it is also applicable. It is used as a material for home appliances, building materials, and automobiles. In addition, the manufacturing method according to the third aspect of the present invention can provide the market with a good pressure resistance. Surface treated metal sheet with good resistance to coil deformation. [Comparison of component numbers] 1 ··· Polyolefin wax dispersion 24 ··. Water-based organic-inorganic composite film (D) 2… Water-based organic-inorganic composite film 3 ... Key metal plate 11 ... Lubricant (A) 12 ... Lubricant (B) 13 ... Water-based organic-inorganic composite coating 14 ... Metal-plated plate 22 ... Water-based organic-inorganic composite coating (C), (C) 23 ... Money The paper size of the metal plate is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page). * Laj— — — — — — — — —

P -64-P -64-

Claims

573062 ./X aL. 一 ο573062 ./X aL. One ο

▼請專利範園 (請先閲讀背面之注意事項再填寫本頁) 1· 一種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，係具有一 0.3g/m2〜5.0g/m2之水性有機無機複合覆膜者，該水性有機無機複合覆膜係包含有水性樹脂及矽酸鹽化合物之一方或兩方，進而包含有分子量在6〇〇〇〜 15000範圍内之聚烯烴蠟分散體與以固體成分換算時為 5〜35質篁％之膠體二氧化碎者。 -、可| 2.如申清專利範圍第1項之具優異财壓磨損性與耐線圈變形性之表面處理金屬板，其中該聚烯烴蠟分散體係由不含極性基且分子量在6000〜15000範圍内、粒徑為〇·1μηι 〜5·0μηι之聚烯烴蠟分散體，與分子量在6〇〇〇〜15〇〇〇範圍内、酸值在40以下、且粒徑為〇·ι〜5.0μπι之變性聚烯烴蠟分散體中選出之至少1種以上者。 3 ·如申請專利範圍第1項或第2項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其表面之動摩擦係數係在0.07〜0.15之範圍内，而靜摩擦係數係在010以上。 4· 一種水性有機無機複合塗料，係包含有水性樹脂及石夕酸鹽化合物之一方或兩方，進而包含有分子量在6000〜 15000範圍内之聚烯烴蠟分散體與以固體成分換算時為 5〜35質量％之膠體二氧化矽以及水者。 5.如申請專利範圍第4項之水性有機無機複合塗料，其中該聚烯烴蠟分散體係由不含極性基且分子量在6000〜 15000範圍内、粒徑為〇.;^111〜5〇(1111之聚烯烴蠟分散體，與分子量在6000〜15000範圍内、酸值在40以下、且粒徑為Ο.ίμιη〜5·0μπι之變性聚烯烴蠟分散體中選出本紙張尺度適用中國國家標準（CNS) Α4規格（210X 297公釐) -65- 573062 A8 B8 C8 D8 六、申請專利範圍之至少1種以上者。 (請先閲讀背面之注意事項再填寫本頁) 6. —種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，係將以乾態質量換算時為0.3g/m2〜 5_0g/m2之申請專利範圍第4項之塗料塗布於鍍金屬板上後，經烘烤而形成水性有機無機複合覆膜。 7· —種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，係將以乾態質量換算時為〇.3g/m2〜 5.0g/m2之申請專利範圍第5項之塗料塗布於鍍金屬板上後，經烘烤而形成水性有機無機複合覆膜。 8· —種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板，係具有一水性有機無機複合覆膜者，該水性有機無機複合覆膜係包含有水性樹脂及矽酸鹽化合物之一方或兩方，進而包含有以分子量在6〇〇〇〜15000範圍内之聚烯烴蠟分散體構成之潤滑劑（A )，以分子量在1000〜5000範圍内之聚烯烴蠟分散體構成之潤滑劑 (B) ’與以固體成分換鼻時為5〜35質量％之膠體二氧化矽者；且，該水性有機無機複合覆膜係具有〇.3g/m2 〜5.0g/m2 〇 9·如申請專利範圍第8項之具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板，其中該潤滑劑（A )係由不含極性基且分子量在6000〜15000範圍内、粒徑為 Ο.ίμιη〜5·0μιη之聚烯烴蠟分散體，與分子量在6〇〇〇〜 15000範圍内、酸值在40以下、且粒徑為〇1μιη〜5 〇μιη 之變性聚稀經堰分散體中選出之至少1種以上之潤滑本紙張尺度適用中國國家標準（CNS) Α4規格（210 X 297公釐） -66- 573062 A8 B8 C8 —---—--- 六、申請專利範圍 (請先閲讀背面之注意事項再填寫本頁) 劑，而潤滑劑（Ή)係不含極性基且分子量在1〇〇〇〜5〇〇〇範圍内、粒徑為Ο.ίμηι〜5·〇μηι之聚烯烴蠛分散體。 10· —種水性有機無機複合塗料，係包含有水性樹脂及矽酸鹽化合物之一方或兩方，進而包含有以分子量在6〇〇〇〜 15000範圍内之聚烯烴蠟分散體構成之潤滑劑（Α)，以分子量在1000〜5000範圍内之聚烯烴蠟分散體構成之潤滑劑（Β )’與以固體成分換算時為5〜3 5質量％之膠體二氧化矽以及水者。 11 ·如申請專利範圍第10項之水性有機無機複合塗料，其中該潤滑劑（Α)係由不含極性基且分子量在6〇〇〇〜15〇〇〇範圍内、粒徑為Ο.ίμηι〜5·0μηι之聚烯烴蠟分散體，與分子量在6000〜15000範園内、酸值在4〇以下、且粒徑為 Ο.ίμηι〜5·0μηι之變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑，而潤滑劑（Β)係不含極性基且分子量在1000〜5000範圍内、粒徑為〇· 1 〜5.〇pm之聚稀烴蠛分散體。 12. —種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板之製造方法，係將以乾態質量換算時為〇.3g/m2 〜5.0g/m2之申請專利範圍第10項之水性有機無機複合塗料塗布於鍍金屬板上後，經烘烤而形成水性有機無機複合覆膜。 13· —種具優異耐壓磨損性與耐連續滑動磨耗性之表面處理金屬板之製造方法，係將以乾態質量換算時為03g/m2 〜5_0g/m2之申請專利範圍第π項之水性有機無機複合本紙張尺度適用中國國家標準（CNS) A4規格（210X297公釐） -67- 573062 A8 B8 C8 D8 、申請專利範圍塗料塗布於鍍金屬板上後，經烘烤而形成水性有機無機複合覆膜。 (請先閲讀背面之注意事項再填寫本頁) ^ 一種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，係使第一層具有乾態質量為〇.〇5g/m2〜〇.3g/m22 水性有機無機複合覆膜（C )，該水性有機無機複合覆膜（C)係包含有水性樹脂及矽酸鹽化合物之一方或兩方’進而包含有以分子量在6〇〇〇〜15000範圍内之聚烯烴蠟分散體構成之潤滑劑（A)者；、可| 該表面處理金屬板並使第二層具有乾態質量為〇」g/m2〜5.0g/m2之水性有機無機複合覆膜（D)，該水性有機無機複合覆膜（D )係以水性樹脂及矽酸鹽化合物之一方或兩方，進而以固體成分換算時為5〜35質量 %之膠體二氧化矽構成者^ 1 5·如申請專利範圍第14項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該潤滑劑（A )係由不 3極性基且分子量在6000〜15000範圍内、粒徑為01(Im 〜5·0μιη之聚烯烴蠟分散體，與分子量在6〇〇〇〜15〇〇〇範圍内、S文值在40以下、且粒徑為〇· 1 μηι〜5鄭變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑。 16.如申凊專利範圍第14項之具優異耐壓磨損性與耐線圈隻形性之表面處理金屬板，其中該水性有機無機複合覆膜（c)係以將水性樹脂與分子量在6〇〇〇〜15〇⑼範圍内之聚烯烴蠟分散體之潤滑劑（Α),及分子量在1〇〇〇〜 5〇〇〇範圍内之聚烯烴蠟分散體之潤滑劑（Β)混合後之▼ Please patent Fanyuan (please read the precautions on the back before filling this page) 1 · A surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance, which has a 0.3g / m2 ~ 5.0g / m2 For water-based organic-inorganic composite coatings, the water-based organic-inorganic composite coatings include one or both of an aqueous resin and a silicate compound, and further include a polyolefin wax dispersion having a molecular weight in the range of 6000 to 15,000. The body and the colloidal dioxide which is 5 to 35 mass% when converted into solid content. -、可 | 2. The surface-treated metal plate with excellent financial pressure abrasion resistance and coil deformation resistance, as described in item 1 of the scope of the patent application, wherein the polyolefin wax dispersion system is composed of no polar group and has a molecular weight of 6000 to 15000. Polyolefin wax dispersions with particle diameters ranging from 0.1 μm to 5.0 μm in the range, with molecular weights ranging from 6,000 to 150,000, acid values below 40, and particle diameters from 0.00 to 5.0 At least one selected from μm modified polyolefin wax dispersions. 3 · If the surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance in item 1 or 2 of the scope of patent application, the surface dynamic friction coefficient is in the range of 0.07 ~ 0.15, and the static friction coefficient is in the range of 010 or more. 4. A water-based organic-inorganic composite coating, which contains one or both of water-based resin and oxalate compound, and further contains a polyolefin wax dispersion with a molecular weight in the range of 6000 to 15000 and 5 when converted into solid content. ~ 35% by mass of colloidal silica and water. 5. The aqueous organic-inorganic composite coating according to item 4 of the patent application, wherein the polyolefin wax dispersion system comprises no polar group and has a molecular weight in the range of 6000 to 15000 and a particle size of 0.11 to 5〇 (1111 Polyolefin wax dispersion with a molecular weight in the range of 6000 ~ 15000, an acid value of 40 or less, and a modified polyolefin wax dispersion with a particle size of 0. Ιμιη ~ 5 · 0μπι. This paper is selected to apply Chinese national standards. CNS) Α4 specifications (210X 297 mm) -65- 573062 A8 B8 C8 D8 6. At least one of the patent application scopes (Please read the precautions on the back before filling out this page) 6. — A kind with excellent resistance The method for manufacturing a surface-treated metal plate with pressure abrasion resistance and coil deformation resistance is after coating a metal-plated plate with a coating material No. 4 in the patent application range of 0.3 g / m2 to 5_0 g / m2 when converted to dry mass. After baking, the water-based organic-inorganic composite film is formed. 7 · —A method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance, which will be 0.3 g / m2 ~ 5.0g / m2 After the coating of item 5 is coated on a metal plate, it is baked to form a water-based organic-inorganic composite film. 8 · —A surface-treated metal plate with excellent pressure wear resistance and continuous sliding wear resistance. For a water-based organic-inorganic composite coating, the water-based organic-inorganic composite coating includes one or both of an aqueous resin and a silicate compound, and further includes a polyolefin wax having a molecular weight in the range of 6000 to 15,000. Lubricant (A) composed of a dispersion, lubricant (B) composed of a polyolefin wax dispersion having a molecular weight in the range of 1000 to 5,000, and colloidal silicon dioxide having a content of 5 to 35% by mass when replacing solids with a nose Moreover, the water-based organic-inorganic composite film system has a surface-treated metal with excellent pressure wear resistance and continuous sliding wear resistance such as 0.3 g / m2 to 5.0 g / m2. Plate, wherein the lubricant (A) is a polyolefin wax dispersion containing no polar groups and having a molecular weight in the range of 6000 to 15000 and a particle size of 0. Ιμιη to 5.0 μιη, and a molecular weight of 6,000 to 15000. Within the range, the acid value is within At least one or more lubricants selected from denatured poly warp weir dispersions with a particle size of 0 to 1 μm and less than 50 μm, and the paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm)- 66- 573062 A8 B8 C8 —------- 6. Scope of patent application (please read the notes on the back before filling this page), and the lubricant (润滑剂) does not contain polar groups and molecular weight is 1〇. Polyolefin fluorene dispersions having a particle size ranging from 0.01 μm to 5.0 μm in the range of 0.00 to 5000. 10 · —A water-based organic-inorganic composite coating containing one or both of a water-based resin and a silicate compound, and further a lubricant composed of a polyolefin wax dispersion having a molecular weight in the range of 6,000 to 15,000 (A) Lubricant (B) 'composed of a polyolefin wax dispersion having a molecular weight in the range of 1000 to 5000, and colloidal silica and water having a content of 5 to 35% by mass in terms of solid content. 11 · The water-based organic-inorganic composite coating according to item 10 of the patent application range, wherein the lubricant (A) is composed of a polar group and having a molecular weight in the range of 600,000 to 150,000, and a particle size of 0. ίμηι Polyolefin wax dispersion of ~ 5.0 μm and at least 1 selected from denatured polyolefin wax dispersions having a molecular weight of 6000 to 15,000 in the range, an acid value of 40 or less, and a particle size of 0. Ιμηι ~ 5.0 μm More than one kind of lubricant, and the lubricant (B) is a polyhydrocarbon rhenium dispersion that does not contain polar groups and has a molecular weight in the range of 1000 to 5000 and a particle size of 0.1 to 5.0 μm. 12. —A method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and continuous sliding wear resistance, which will be 0.3g / m2 to 5.0g / m2 in terms of dry mass conversion. The water-based organic-inorganic composite coating is coated on a metal plate and then baked to form an water-based organic-inorganic composite coating. 13 · —A method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and continuous sliding wear resistance, which is based on the dry water mass conversion of 03g / m2 to 5_0g / m2 in the scope of the patent application No. π Organic-inorganic composite This paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -67- 573062 A8 B8 C8 D8, the scope of patent application is applied after coating on metal plate, and then baked to form water-based organic-inorganic composite Laminated. (Please read the precautions on the back before filling this page) ^ A surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance. The first layer has a dry mass of 0.05 g / m2 ~ 〇 .3g / m22 water-based organic-inorganic composite coating (C), the water-based organic-inorganic composite coating (C) contains one or both of an aqueous resin and a silicate compound, and further includes a molecular weight of 600,000. Lubricant (A) composed of a polyolefin wax dispersion in the range of ~ 15000; The surface treatment of the metal plate and the second layer with a dry mass of 0 ″ g / m2 ~ 5.0g / m2 Inorganic composite coating (D), the water-based organic-inorganic composite coating (D) is one or both of an aqueous resin and a silicate compound, and further is 5 to 35% by mass of colloidal silica in terms of solid content. Constructor ^ 1 5 · Such as the surface treatment metal plate with excellent pressure wear resistance and coil deformation resistance according to item 14 of the scope of patent application, wherein the lubricant (A) is composed of a non-polar group and has a molecular weight of 6000 to 15000. Polyolefins with a particle size within the range of 01 (Im ~ 5.0 μm) Dispersion and at least one selected from Zheng modified polyolefin wax dispersions having a molecular weight in the range of 6,000 to 150,000, an S value of 40 or less, and a particle size of 0.1 μm to 5 16. Lubricant 16. The surface-treated metal plate with excellent pressure wear resistance and coil shape resistance as described in item 14 of the patent application, wherein the water-based organic-inorganic composite film (c) is a mixture of water-based resin and molecular weight Lubricant (A) for polyolefin wax dispersions in the range of 6,000 to 150,000, and lubricants (B) for polyolefin wax dispersions in the molecular weight range of 10,000 to 50,000. After mixing

-68- 573062 A8 B8 C8 ---- —__Df____ 六、申請專利範圍複合系潤滑劑構成者。 (請先閱讀背面之注意事項再填寫本頁) 17.如申印專利範圍第丨5項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該水性有機無機複合覆膜（c)係以將水性樹脂與分子量在6〇〇〇〜15〇〇〇範圍内之聚烯烴蠟分散體之潤滑劑（A)，及分子量在1〇〇〇〜 5〇〇〇範圍内之聚烯烴蠟分散體之潤滑劑（B)混合後之複合系潤滑劑構成者。 18·如申凊專利範圍第16項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該潤滑劑（A )係由不含極性基且分子量在6〇〇〇〜15000範圍内、粒徑為01μηι 〜5·〇μΐη之聚烯烴蠟分散體，與分子量在6000〜15000範圍内、酸值在40以下、且粒徑為〇.1μηι〜5 〇(1111之變性聚烯烴蠟分散體中選出之至少丨種以上之潤滑劑，而潤滑劑（Β)係不含極性基且分子量在1〇〇〇〜5〇〇〇範圍内、粒徑為Ο.ίμηι〜3·0μιη之聚烯烴蠛分散體。 19.如申請專利範圍第17項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板，其中該潤滑劑（Α)係由不含極性基且分子量在6000〜15000範圍内、粒徑為〇·1μηι 〜5·0μιη之聚烯烴蠟分散體，與分子量在6〇〇〇〜ι5〇〇〇範圍内、酸值在40以下、且粒徑為ο」gm〜變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑，而潤滑劑（B)係不含極性基且分子量在1〇〇〇〜5〇〇〇範圍内、粒徑為Ο.ίμηι〜3·0μιη之聚烯烴蟻分散體。 20·如申請專利範圍第14至19項中任一項之具優異耐壓磨本紙張尺度適用中國國家標準（CNS) Α4規格（210X297公釐） -69- 573062 A8 B8 C8 _______ D8 六、申請專利範圍 (請先閲讀背面之注意事項再填寫本頁) 損性與耐線圈變形性之表面處理金屬板，其表面之動摩擦係數係在0.07〜0.15之範圍内，而靜摩擦係數係在〇1〇以上。 21. —種具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，係於鍍金屬板之上層塗布以乾態質量換算時為0.05g/m2〜0.3g/m2之水性有機無機複合塗料 (E )後，經烘烤而形成第一層，而該水性有機無機複合塗料（E )係以水性樹脂及矽酸鹽化合物之一方或兩方’進而以分子量在6000〜15000範圍内之聚稀烴蠛分月欠體之潤滑劑（A )以及水所構成者；其次，塗布以乾態質量換算時為0.5g/m2〜5.0g/m2之水性有機無機複合塗料（F )後，經烘烤而形成第二層，而該水性有機無機複合塗料（F )係以水性樹脂或/及矽酸鹽化合物、膠體二氧化石夕及水所構成，且膠體二氧化石夕之含量以固體成分換算時為5〜35質量％者。 22. 如申請專利範圍第21項之具耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，其中該潤滑劑（A) 係由不含極性基且分子量在6000〜15000範圍内、粒徑為Ο.ίμηι〜5·0μηι之聚烯烴蠟分散體，與分子量在6000 〜15000範圍内、酸值在40以下、且粒徑為0.1 μηι〜5.Ομηι 之變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑。 23. 如申請專利範圍第21項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，其中該水性有機本紙張尺度適用中國國家標準（CNS) Α4規格（210X297公釐） -70- 573062 A8 B8 C8 D8 申請專利範園 (請先閲讀背面之注意事項再填寫本頁) 無機複合塗料（E )係以將水性樹脂與分子量在6〇〇〇〜 15000範圍内之聚烯烴蠟分散體之潤滑劑（A)，及分子 1在1000〜5000範圍内之聚烯烴蠟分散體之潤滑劑（B) 混合後之複合系潤滑劑，以及水構成者。 24·如申請專利範圍第22項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，其中該水性有機無機複合塗料（E )係以將水性樹脂與分子量在6〇〇〇〜 15000範圍内之聚烯烴蠟分散體之潤滑劑（a),及分子量在1000〜5000範圍内之聚烯烴蠟分散體之潤滑劑（B) 混合後之複合系潤滑劑，以及水構成者。 25·如申請專利範圍第21至24項中任一項之具優異耐壓磨損性與耐線圈變形性之表面處理金屬板之製造方法，其中该潤滑劑（A )係由不含極性基且分子量在6〇〇〇〜 15000範圍内、粒徑為〇4111〜5.〇|11111之聚烯烴蠟分散體’與分子量在6000〜15000範圍内、酸值在4〇以下、且粒徑為0.1 μπι〜5.Ομηι之變性聚烯烴蠟分散體中選出之至少1種以上之潤滑劑，而潤滑劑（Β )係不含極性基且分子量在1000〜5000範圍内、粒徑為〇 1μπι〜3 〇μιη之聚烯烴蠟分散體。本紙張尺度適用中國國家標準（CNS) Α4規格（210X297公釐） -71--68- 573062 A8 B8 C8 ---- —__ Df____ 6. Scope of patent application Compound lubricant composition. (Please read the precautions on the back before filling in this page) 17. If the surface treatment metal plate with excellent pressure and abrasion resistance and coil deformation resistance is in accordance with item 5 of the patent application, the water-based organic-inorganic composite film (C) Lubricant (A) comprising an aqueous resin and a polyolefin wax dispersion having a molecular weight in the range of 6,000 to 15,000, and a molecular weight in the range of 10,000 to 50,000. Compound lubricant composition of polyolefin wax dispersion lubricant (B). 18. The surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance, as described in item 16 of the patent application, wherein the lubricant (A) is made of a polar group and has a molecular weight of 6,000 to 15,000. Polyolefin wax dispersions with particle diameters ranging from 01 μηι to 5.0 μμηη in the range, and denatured polyolefins with molecular weights ranging from 6000 to 15000, acid values below 40, and particle diameters from 0.1 μηι to 5 〇 (1111 At least one or more lubricants selected from the wax dispersion, and the lubricant (B) is free of polar groups and has a molecular weight in the range of 10,000 to 50000 and a particle size of 0.15 μm to 3.0 μm Polyolefin 蠛 dispersion. 19. The surface treated metal plate with excellent pressure abrasion resistance and coil deformation resistance according to item 17 of the patent application scope, wherein the lubricant (A) is composed of a polar group and a molecular weight of Polyolefin wax dispersions with a particle size of 0.001 μm to 5.0 μm in the range of 6000 to 15000, with molecular weights in the range of 600,000 to 5,000, acid values of 40 or less, and particle sizes of ο '' gm ~ At least one lubricating oil selected from denatured polyolefin wax dispersion The lubricant (B) is a polyolefin ant dispersion which does not contain polar groups and has a molecular weight in the range of 1,000 to 50000 and a particle size of 0.18 μm to 3.0 μm. 20. Such as applying for a patent The paper size with excellent pressure resistance of any one of items 14 to 19 applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -69- 573062 A8 B8 C8 _______ D8 VI. Scope of patent application (please read first Note on the back side, please fill in this page again.) For surface-treated metal plates with damage and coil deformation resistance, the surface has a coefficient of dynamic friction in the range of 0.07 to 0.15, and a coefficient of static friction in the range of 010 or more. A method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance, which is coated on the upper layer of a metal-plated plate with an aqueous organic-inorganic composite coating of 0.05 g / m2 to 0.3 g / m2 in terms of dry mass conversion. (E) After baking, a first layer is formed, and the water-based organic-inorganic composite coating (E) is polymerized with one or both of a water-based resin and a silicate compound, and is then polymerized with a molecular weight in the range of 6000 to 15,000. Dilute hydrocarbons Lubricant (A) and water; Secondly, after coating the water-based organic-inorganic composite coating (F) at a dry mass conversion of 0.5 g / m2 to 5.0 g / m2, the second layer is formed by baking. And the water-based organic-inorganic composite coating (F) is composed of a water-based resin or / and a silicate compound, colloidal silica and water, and the content of the colloidal silica is 5 to 35 when the solid content is converted. % By mass. 22. For example, a method for manufacturing a surface-treated metal plate having pressure wear resistance and coil deformation resistance according to item 21 of the scope of patent application, wherein the lubricant (A) is made of a polar group and has a molecular weight of 6000. Polyolefin wax dispersion with a particle size of 0 to 15000 and a particle size of 5.0 μm to a molecular weight of 6000 to 15000, an acid value of 40 or less, and a denatured polymer having a particle size of 0.1 μm to 5.0 μm At least one lubricant selected from olefin wax dispersions. 23. For example, a method for manufacturing a surface-treated metal plate with excellent pressure wear resistance and coil deformation resistance in accordance with item 21 of the scope of patent application, wherein the size of the water-based organic paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ) -70- 573062 A8 B8 C8 D8 Patent Application Park (please read the precautions on the back before filling out this page) Inorganic composite coating (E) is used to polymerize water-based resin with molecular weight in the range of 6000 ~ 15000 Lubricant (A) for olefin wax dispersion, lubricant (B) for polyolefin wax dispersion with molecule 1 in the range of 1000 to 5000, compound lubricant and water composition. 24. The method for manufacturing a surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance, as described in item 22 of the scope of patent application, wherein the water-based organic-inorganic composite coating (E) is based on an aqueous resin and a molecular weight of 60. 〇OO ~ 15000 polyolefin wax dispersion lubricant (a), polyolefin wax dispersion molecular weight of 1000 ~ 5000 lubricant (B) compound lubricant after mixing, and water composition By. 25. A method for manufacturing a surface-treated metal plate having excellent pressure wear resistance and coil deformation resistance according to any one of claims 21 to 24, wherein the lubricant (A) is made of a non-polar group and Polyolefin wax dispersions' with a molecular weight in the range of 6,000 to 15,000 and a particle size of 0411 to 5.00 | 11111 and a molecular weight in the range of 6000 to 15000, an acid value of 40 or less, and a particle size of 0.1 At least one lubricant selected from the denatured polyolefin wax dispersions of μπι to 5.0 μηι, and the lubricant (B) is a polar group with a molecular weight in the range of 1000 to 5000 and a particle size of 〇1 μπι to 3 0 μm of a polyolefin wax dispersion. This paper size applies to China National Standard (CNS) A4 (210X297 mm) -71-