TW568963B - Method for producing polyester fiber suitable for a draw-texturing raw yarn - Google Patents

Method for producing polyester fiber suitable for a draw-texturing raw yarn Download PDF

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TW568963B
TW568963B TW090124044A TW90124044A TW568963B TW 568963 B TW568963 B TW 568963B TW 090124044 A TW090124044 A TW 090124044A TW 90124044 A TW90124044 A TW 90124044A TW 568963 B TW568963 B TW 568963B
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Taiwan
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yarn
processing
false
polyester fiber
polyester
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TW090124044A
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Chinese (zh)
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Takashi Iwade
Takashi Fujii
Masamichi Yamashita
Makoto Nishioji
Takeshi Kikutani
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Toray Eng Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • D01D10/02Heat treatment
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

This invention provides a polyester fiber which has physical properties such as a double refraction Deltan of up to 0.07, an elongation after fracture of at least 80%, and a specific weight of at least 1.35 g/cm<3> and is suitable for a draw-texturing raw yarn, and which is produced by cooling polyester filaments melt-spun from spinnerets to up to a glass transition temperature by a cooling air while filaments are being taken up by a take-up roller at at least 3000 m/min, and by heating them to above a glass transition temperature while they are being wound up from the take-up roller into a package by a winding device.

Description

568963568963

五、發明說明(1) 技術領域 本發明為關於聚酉旨纖維及其製造方法,更詳言之,特 知方、L伸饭掩加工用原絲中所使用之聚酯纖維及其製; 法。 心万 背景技術 简二H检加卫用原絲中所使用之聚_纖維中,廣泛使用 正 ^ 4 分取向絲,partially oriented yarn)的半 ==。此聚酯半延伸絲為經由將熔融狀之聚酯由紡絲管 ° 纺出,並將此紡紗絲條一邊以3 0 0 0m/min以上之高速下 拉=邊以冷卻風予以冷卻固化則可製造。 &amp;由如此兩速紡絲拉取所得之聚酯半延伸絲為斷裂伸度 為38動上、雙折射^為〇.。7以下、比重為未滿!.35g/ cm之物性值。以往、將此聚酯半延伸絲做為延伸假捻加 工用原1之代表品種hd-36i (83dtx-36f)延伸假捻絲予 、 ^ 為以加工速度9〇〇 — l〇〇Om/min,加工張力40- 50c+N ^條件進行延伸假捻加工、取得殘留伸度為約2〇-25% 、、’糸 此類衫鬆加工絲之殘留伸度因為較高至約 20 -2 5%之範圍、故即使使用於織布工程和編織工程之高次 工程中、亦不會發生斷絲、可進行安定的作業。 但是、於更加提高生產性之目的下,令延伸假捻加工速 度上升,120〇m/min以上、且若為了令其高速加工時之張 力不句呈現安定而將加工張力提高至55洲以上,則以上述 物性值之聚酯半延伸絲做為延伸假捻加工用原絲者,僅取 得殘留伸度未滿20%之膨鬆加工鮮、。因為膨鬆加工絲之殘V. Description of the invention (1) TECHNICAL FIELD The present invention relates to a polyester fiber and a manufacturing method thereof, more specifically, a polyester fiber and a polyester fiber used in the raw yarn for processing and processing of the raw silk, L. law. Xinwan Background Technology Among the poly-fibers used in the Jane II H-defense and defense yarns, semi-oriented yarns (partially oriented yarns) are widely used. The polyester semi-stretched yarn is obtained by spinning molten polyester from a spinning tube, and pulling the spinning yarn at a high speed of more than 300 m / min = while cooling and solidifying with cooling air. Can be manufactured. &amp; The polyester semi-stretched yarn obtained by such two-speed spinning and drawing had a breaking elongation of 38 and a birefringence ^ of 0.0. Below 7, the proportion is not full! Physical property value of .35g / cm. In the past, this polyester semi-stretched yarn was used as the representative variety hd-36i (83dtx-36f) of the original false-twisted processing stretch-twisted yarn, and the processing speed was 900-1000 m / min. , The processing tension of 40-50c + N ^ conditions for extended false twist processing, to obtain a residual elongation of about 20-25%, the residual elongation of this type of shirt loose processing yarn because the higher to about 20 -2 5 % Range, so even if used in high-order projects of weaving engineering and knitting engineering, wire breakage does not occur and stable operations can be performed. However, for the purpose of further improving productivity, the extension false twist processing speed is increased to 120 m / min or more, and the processing tension is increased to 55 or more in order to stabilize the tension during high-speed processing. The polyester semi-stretched yarn with the above-mentioned physical property value is used as the raw yarn for the stretch false twist processing, and only the bulk processing freshness with a residual elongation of less than 20% is obtained. Because of the residue of bulk processing silk

568963 五、發明說明(4) — 之芳香族二羧酸及其機能性衍生物、己二酸、癸二酸、琥 拍酸、戊二酸等之脂族二羧酸及其機能性衍生物、環己烷 二羧酸等之脂環族二羧酸及其機能性衍生物等。 又,上述聚酯中共聚所使用之二元醇可列舉二甘醇、丙 二醇、丁二醇、新戊二醇等之脂族二醇、環己烷二甲醇等 之脂環族二元醇、雙酚A、雙酚A之烯化氧加成物等之芳香 族二元醇等。568963 V. Description of the Invention (4) — Aromatic dicarboxylic acids and their functional derivatives, adipic acid, sebacic acid, succinic acid, glutaric acid and other aliphatic dicarboxylic acids and their functional derivatives Cycloaliphatic dicarboxylic acids, such as cyclohexanedicarboxylic acid, and functional derivatives thereof. Examples of the glycol used in the copolymerization of the polyester include aliphatic glycols such as diethylene glycol, propylene glycol, butanediol, neopentyl glycol, and cycloaliphatic diols such as cyclohexanedimethanol. Aromatic diols such as bisphenol A and alkylene oxide adducts of bisphenol A.

本發明之聚S旨纖維為雙折射△ η為〇. 〇 7以上、斷裂伸度 為8 0 %以上,且比重為1 · 3 5 g / c m3以上為其特徵。即,先前 之聚酿半延伸絲雖於複折射率△ η和斷裂伸度為大約相同 之物性值,但因比重為未滿1 · 3 5 g / c m3,故比先前者於纖維 内分子之結晶化度更高,且具有大的抗張力。 因此,例如於延伸假捻加工絲之代表品種 7 5d-36 f( 83d tx-36 f之)情形中,即使令延伸假捻加工速度 提高至先前一般的100〇m/min至1200m/min以上,且令加工 張力由49cN左右之程度提高至55cN以上,亦不會發生斷絲 且可保證安定的延伸假捻加工,並且可令所得膨鬆加工絲 之殘留伸度為2 0 %以上,特別為2 〇〜2 5 %之程度。The polyS fibers of the present invention are characterized by a birefringence Δη of 0.07 or more, an elongation at break of 80% or more, and a specific gravity of 1.35 g / cm3 or more. That is to say, although the previously polymerized semi-stretched yarns have approximately the same physical properties in terms of complex refractive index Δη and elongation at break, the specific gravity is less than 1.35 g / c m3. It has a higher degree of crystallization and has a large tensile strength. Therefore, for example, in the case of 7 5d-36 f (83d tx-36 f), the representative variety of extended false twisted yarn, even if the extension false twisted processing speed is increased to 100 m / min to 1200 m / min or more , And the processing tension is increased from about 49cN to more than 55cN, no breakage will occur and stable extension false twist processing can be guaranteed, and the residual elongation of the resulting bulked processing yarn can be more than 20%, especially It is about 2 to 25%.

如此經由延伸假捻加工速度之高速化而提高生產性,又 經由高張力化抑制張力變動,故可取得高品質的膨鬆加工 絲。更且,因為經由延伸假捻加工所得之膨鬆加工絲的殘 留伸度大,故即使供於織布工程和編織工程之高次工程亦 不會發生斷絲,可進行安定之作業,且可令織布和編織所得 之織編物作成而品質。In this way, productivity is improved by increasing the speed of the stretch false twist processing speed, and tension variation is suppressed by increasing the tension, so that a high-quality bulky yarn can be obtained. In addition, since the residual elongation of the bulky processing yarn obtained through the extended false twist processing is large, even if it is used in the high-order process of the weaving process and the knitting process, the wire break does not occur, and stable operations can be performed, and Weaving and weaving woven fabrics are made and quality.

第8頁 ------- 五、發明說明(10) 亦可令絲條y之複; 持於80%以上。其他^ Λη維持於〇·〇7以下、斷裂伸度維 同於圖1之情況。 W輕3和加熱裝置1 2之作用效果為 本叙明之聚g旨纖維 、 在提高延伸假捡加工 做為延伸假捻加工用原絲,則 加工絲上為優良。 生產性,並且取得品質優良之膨鬆 定,且先前公知之延仲用之延伸假捻加工法並無特別限 圖5為例示將本發明:::法均可適用。 用原絲之延伸假捻加工:置曰纖維應用做為延伸假捻加工 此延伸假捻加工裳f ^ 人土 p 序配置加㈠置62 、ί為於供給輕61與延伸親65之間,依 ^ 、/、、置62、冷部裝置㈢、假捻器64,再於延伸輥 6 5之下游側配置捲取妒 、 摩擦假撿器。 例*於假撿器64使用碟型 由捲裝P將聚酯纖維γ以供給輥61拉出後,以延伸輥65延 2間,以假捻器64予以捻轉,此捻轉為以加熱裝置62和冷卻 裝置6 3予以固定後,於假捻器6 4之下游側解捻則可作成膨 鬆加工絲Y ’ 。此膨鬆加工絲γ,為以捲取裝置6 6予以捲取。 實施例1〜4 1,衣這π _纖平 。 測定各條件所得之聚酯纖維絲條之纖度(d 1 χ)、斷裂伸 使用圖1之聚酯纖維製造裝置,設定紡絲管嘴之吐出孔數 為3 6個、每1吐出孔之聚合物吐出量為1 · 2 g / m i η、加熱裝 置之設定溫度為1 8 0 °C,並分別以牵引輥及捲取裝置以拉弓I 速度不同至3000m/min、3500m/min、4000m/min、45〇〇m/ m i η,製造聚酯纖維ΛPage 8 ------- V. Description of the invention (10) It is also possible to restore the yarn y; hold it above 80%. Other ^ Λη is maintained below 0.07, and the fracture elongation dimension is the same as that in Fig. 1. The effect of W light 3 and heating device 12 is that the polyg fibers intended in this description are used to improve the extended false picking process. As the raw yarn for extended false twist processing, the processed yarn is excellent. Productivity and good quality bulking are obtained, and the previously known extension false twist processing method for extension is not particularly limited. Fig. 5 illustrates the invention ::: method can be applied. Extending false twist processing using raw silk: the fiber should be used as the extension false twist processing. This extension false twist processing is f ^ human soil p sequence configuration plus set 62, ί for the supply of light 61 and extension pro 65, According to ^, / ,, set 62, the cold part device ㈢, the false twister 64, and the downstream side of the extension roller 65 is arranged to take up the jealousy, rub the false picker. Example * After the polyester fiber γ is pulled out from the supply roll 61 by the package P using the dish type at the false picker 64, it is extended by the extension roll 65 and twisted by the false twister 64. This twisting is performed by heating After the device 62 and the cooling device 63 are fixed, the untwisting at the downstream side of the false twister 64 can be used to form a bulk processing yarn Y '. The bulk processing yarn γ is wound by a winding device 66.实施 例 1〜41 1. The π _ fiber is flat. Measure the fineness (d 1 χ) and elongation of the polyester fiber yarns obtained under various conditions. Using the polyester fiber manufacturing apparatus of FIG. 1, the number of spouting holes in the spinning nozzle was set to 36, and the polymerization of each spouting hole was set The output of the object is 1.2 g / mi η, the set temperature of the heating device is 180 ° C, and the pulling speed of the pulling roller and the winding device are different from 3000m / min, 3500m / min, and 4000m / min, 4500m / mi η, manufacture of polyester fiber Λ

第14頁 568963 五、發明說明(11) 度(%)、雙折射Δη,比重(g/cm3)時,取得表卜a之結果 表1 -a 貫施例 拉引速度 m / m i η 纖度 dt x 斷裂伸度 % 雙折射 Δ η 比重 g/cm3 1 3 000 143 132 0,048 1.350 2 3 500 125 111 0.05 7 1.360 3 4000 109 97 0.066 1.369 4 4500 97 84 0.070 1.377 將如上述處理所得之具備本發明規定物性值之四種聚酯 纖維做為延伸假捻加工用原絲,經由圖5所示之延伸假捻加 工裝置,以加工速度1400 m/min,並設定於各加工張力為安 疋之延伸倍率進行延伸假捻加工。其結果示於表丨—b。表 1 -b中,亦合併記載可令各延伸假捻加工安定實施的加工張 力(安定加工張力)。 、 如表1 -b之結杲所闡明般,可知若將具備本發明物性值之 聚酯纖維使用做為延伸假捻加工用原絲,則即使於加工速 度度14 0Om/min之高速度下亦不會發生斷絲,可安定取得殘 留伸度2 0 %以上之膨鬆加工絲。 表1 -b 實施例Page 14 568963 V. Description of the invention (11) Degree (%), birefringence Δη, specific gravity (g / cm3), the results obtained from table a are shown in Table 1 -a pull speed m / mi η fineness dt x elongation at break% birefringence Δ η specific gravity g / cm3 1 3 000 143 132 0,048 1.350 2 3 500 125 111 0.05 7 1.360 3 4000 109 97 0.066 1.369 4 4500 97 84 0.070 1.377 will be processed as described above and have the provisions of the present invention The four types of polyester fibers with physical properties are used as the raw yarn for the extended false twist processing, and the processing speed is 1400 m / min through the extended false twist processing device shown in FIG. 5, and each processing tension is set to an extension ratio of Ang. Extend false twist processing. The results are shown in Tables 丨 -b. In Table 1-b, the processing tension (stable processing tension) that enables each extension false twist processing to be stably performed is also recorded. As explained in Table 1-b, it can be seen that if the polyester fiber having the physical property value of the present invention is used as the raw yarn for stretch false twist processing, even at a high speed of 14Om / min There is no broken wire, and bulky processed yarn with a residual elongation of more than 20% can be obtained stably. Table 1 -b Examples

加工張力 cNProcessing tension cN

殘留伸度 % 15 2 4 0 2 5 6 2 2 2 2 \\312\2d-code\90-12\90124044.ptd 第15頁 568963 五、發明說明(12) 、使用圖4之聚酯纖維製造裝置,設定紡絲管嘴之吐出孔數 為3/個、每1吐出孔之聚合物吐出量為1. 2g/min、應力緩 # U卩之平行氣流速度為1 2 〇 Q m / m i n,加熱裝置之設定溫度為 1 8 0 c,並分別以牽引輥及捲取裝置以拉引速度不同至 4〇〇〇ni/min、4 5 0 0m/min、5〇〇〇m/min,製造聚醋纖維。 ^定各條件所得之聚酯纖維絲條之纖度(dtx)、斷裂伸 度(%)、雙折射Δη、比重(g/cm3)時,取得表2_a之結果。 a 表2 - 實施例 拉引速度 m/min 纖度 dtx 斷裂伸度 % 雙折射 Δ η 比重 g/cm3 5 r 4000 143 120 0.046 1.355 0 η 4500 125 98 0.061 1.360 I 5000 109 87 0.069 1.368 _將★上述處理所得之具備本發明規定物性值之三種聚醋 扒、、隹做為延伸假捻加工用原絲,並以實施例1相同之延伸假 ί加工&amp;條、/件進行延伸假捻加工。其結果示於表2 — b。表2 一 b 二亦合併記載可令各延伸假捻加工安定實施的加工張力 〔女定加工張力)。Residual elongation% 15 2 4 0 2 5 6 2 2 2 2 \\ 312 \ 2d-code \ 90-12 \ 90124044.ptd Page 15 568963 V. Description of the invention (12) Manufactured using polyester fiber as shown in Figure 4 The device sets the number of discharge holes of the spinning nozzle to 3 /, the polymer discharge amount per 1 discharge hole is 1.2 g / min, and the parallel air velocity of the stress relief # U 卩 is 1 2 0 m / min, The set temperature of the heating device is 180 ° C, and the pulling speeds of the traction roller and the winding device are respectively different from 4,000ni / min, 4500m / min, and 50,000m / min. Polyester fiber. When the fineness (dtx), elongation at break (%), birefringence Δη, and specific gravity (g / cm3) of the polyester fiber yarn obtained under each condition are determined, the results in Table 2_a are obtained. a Table 2-Example pulling speed m / min fineness dtx elongation at break% birefringence Δ η specific gravity g / cm3 5 r 4000 143 120 0.046 1.355 0 η 4500 125 98 0.061 1.360 I 5000 109 87 0.069 1.368 _will The three types of polyester vinegars and stalks obtained from the treatment and having the physical properties specified in the present invention were used as the raw yarns for the extended false twist processing, and the extended false twist processing was performed using the same extended false twist processing & strips / pieces as in Example 1. The results are shown in Table 2-b. Table 2 (b) and (b) also collectively record the processing tensions [female fixed processing tensions] that allow stable implementation of each extended false twist process.

五、發明說明(13) ___ 如表2 - b之結果所ω 聚酿纖維使用做為所 度m〇m/min之高速^伸^加八工用原絲,則即使於力口工迷 留伸度2⑽以上之膨鬆加工絲。 斷4’疋取得殘 表2 - b 實施例 5 6 7V. Description of the invention (13) ___ As shown in the result of Table 2-b, the use of ω poly-fermented fiber as the high speed of m0m / min ^ stretching ^ plus eight raw yarns, even if left in the mouth Bulk processing yarn with an elongation of 2⑽ or more.断 4 ’疋 Get residual Table 2-b Example 5 6 7

加工張力 cN 60 62 60 殘留伸度 % 24.9 23.8 25.2 實施 成^ (Γη ^例5〜7中,除了將應力緩和部之平行氣流速度變更 —夂铬η/&quot;11 5外’以實施例5〜7相同條件製造聚醋纖維。測 件所仔之聚酿纖維絲條之纖度(dtX)、斷裂伸度 ° 折射Δη,比重(g/cm3)時,取得表3-a之結果。 表3 -aProcessing tension cN 60 62 60 Residual elongation% 24.9 23.8 25.2 Implemented as ^ (Γη ^ In Examples 5 to 7, except for changing the parallel air flow velocity of the stress relaxation portion-夂 Crη / &quot; 11 5 'in Example 5 Polyester fibers were produced under the same conditions as ~ 7. When the fineness (dtX), elongation at break of the test piece of polyvinyl alcohol fiber yarn, refraction Δη, and specific gravity (g / cm3), the results in Table 3-a were obtained. Table 3 -a

568963 五、發明說明(14) 將如上述處理所得之具備本發明規定物性值之三種聚酯 纖維做為延伸假捻加工用原絲,並以實施例1相同之延伸假 擒加工條件進行延伸假捻加工。其結果示於表3-b。表3-b 中,亦合併記載可令各延伸假捻加工時安定實施的加工張 力(安定加工張力)。 如表3-b之結果所闡明般,可知若將具備本發明物性值之 聚S旨纖維使用做為延伸假捻加工用原絲,則即使於加工速 度1 40 0m/min之高速度下亦不會發明生斷絲,可安定取得殘 留伸度2 0 %以上之膨鬆加工絲。 表3 - b 實施例 加工張力 殘留伸度 cN % 8 62 26.3 9 63 26.2 10 62 26.5 比較例1〜3 使用圖1之聚酯纖維製造裝置中未設置加熱裝置之裝置, ^紡絲管嘴之吐出孔數為36個、每1吐出孔之聚合物吐出 里為1 · 2 g / m i η,並分別以牵引報及捲取裝置以拉引速度不 同至3000m/min 、3500m/min 、4000m/min,製造聚 g旨纖維。 測定各條件所得之聚酯纖維絲條之纖度(dtx)、斷裂伸 度(%)、雙折射△ η、比重(g/ cm3)時,取得表4 _a之結果。568963 V. Description of the invention (14) Three polyester fibers with the physical properties specified in the present invention obtained as described above are used as the raw yarn for the extended false twist processing, and the extended false false processing conditions are used for the extended false false processing. Twist processing. The results are shown in Table 3-b. In Table 3-b, the processing tension (steady processing tension) that can be stably performed during each extension false twist processing is also recorded together. As clarified by the results in Table 3-b, it can be seen that if the poly-S purpose fiber having the physical property values of the present invention is used as a raw yarn for stretch false twist processing, it can be used even at a high speed of 1,400 m / min. It will not invent broken yarns, and can stably obtain bulk processed yarns with a residual elongation of more than 20%. Table 3-b Example processing residual tensile elongation cN% 8 62 26.3 9 63 26.2 10 62 26.5 Comparative Examples 1 to 3 A device without a heating device in the polyester fiber manufacturing device of FIG. 1 was used. The number of ejection holes is 36, and the polymer ejection inside of each ejection hole is 1.2 g / mi η, and the pulling speed and winding device are respectively used to pull the speeds to 3000m / min, 3500m / min, and 4000m / min. min, making polyg fibers. When the fineness (dtx), elongation at break (%), birefringence Δη, and specific gravity (g / cm3) of the polyester fiber yarn obtained under each condition were measured, the results in Table 4_a were obtained.

第18頁 568963 五、發明說明(15) 表4-a 比較例 拉引速度 m / m i η 纖度 dt χ 斷裂伸度 % 雙折射 Δ η 比重 g/cm3 1 3 000 143 135 0.044 1.332 2 3 5 00 125 108 0.056 1.335 3 4000 109 93 0.068 1.338 將如上述處理所得之不具備本發明規定物性值之三種聚 酯纖維做為延伸假捻加工用原絲,並以實施例1相同之延伸 假捻加工條件進行延伸假捻加工。其結果示於表4-b。表 4 - b中,亦合併記載各延伸假捻加工時的加工張力。 如表4 - b之結果所闡明般,可知若將具備本發明物性值之 聚酯纖維使用做為延伸假捻加工用原絲,則若以加工速度 1 4 0 0m/min則頻頻發生斷絲,且無法取得殘留伸度20%以上 之膨鬆加工絲。 表4 - bPage 18 568963 V. Description of the invention (15) Table 4-a Comparative example drawing speed m / mi η Fineness dt χ Elongation at break% Birefringence Δ η Specific gravity g / cm3 1 3 000 143 135 0.044 1.332 2 3 5 00 125 108 0.056 1.335 3 4000 109 93 0.068 1.338 The three polyester fibers obtained as described above that do not have the physical properties specified in the present invention are used as the raw false-twist processing yarn, and the same conditions for the extended false-twist processing as in Example 1 are used. Extend false twist processing. The results are shown in Table 4-b. Table 4-b also shows the processing tension during each false-twisting process. As explained in the results of Table 4-b, it can be seen that if the polyester fiber having the physical property value of the present invention is used as the raw yarn for extended false twist processing, if the processing speed is 14 00 m / min, the filament will frequently break. , And can not obtain bulk processing yarn with a residual elongation of more than 20%. Table 4-b

比較例 加工張力 殘留伸度 cN % 1 60 12.3 2 59 13.6 3 6 1 13.5 第19頁 568963 五、發明說明(16) 如上述,若根據本發明之聚酯纖維,則因為比重為 1. 3 5 g / c m3以上,故即使進行纖維内分子之結晶化、令延伸 假捻加工速度高速化,且加工張力增大,亦具備不會發生斷 絲之抗張力。又,因為比重高,加上雙折射△ η為0 . 0 7以下, 斷裂伸度為8 0 %以上,故可令延伸假捻加工後之膨鬆加工絲 之殘留伸度為2 0 %以上。因此,將此膨鬆加工絲供至織布工 程、編織工程等之高次工程亦不會發生斷絲,可安定作 業。又,因於高次工程中不會斷絲,故可取得高品質的織編 物。Comparative Example Residual Tension of Processing Tension cN% 1 60 12.3 2 59 13.6 3 6 1 13.5 Page 19 568963 V. Description of the Invention (16) As mentioned above, if the polyester fiber according to the present invention has a specific gravity of 1. 3 5 g / c m3 or more, even if the crystallization of the molecules in the fiber, the extension false twist processing speed is increased, and the processing tension is increased, it also has the anti-tension that does not break the yarn. In addition, because the specific gravity is high and the birefringence Δη is 0.07 or less, and the elongation at break is 80% or more, the residual elongation of the bulked yarn after the extended false twist processing can be made to be 20% or more. . Therefore, even if the bulk processing yarn is supplied to higher-order processes such as weaving process and knitting process, the yarn breakage does not occur, and the operation can be stabilized. In addition, since the yarn is not broken in high-level processes, a high-quality knitted fabric can be obtained.

產業上之可利用性 可利用於纖維產業中之聚酯纖維之生產,特別為展開利 用於延伸假捻加工用原絲。 [元件編號之說明] 1 旋轉滑車 2 冷卻裝置 3 牵引輥 3a 、 3b 輥 4 捲取裝置 5 計量泵Industrial Applicability It can be used for the production of polyester fiber in the fiber industry, especially for the development of raw yarn for false twist processing. [Explanation of component number] 1 Rotary pulley 2 Cooling device 3 Traction roller 3a, 3b roller 4 Winding device 5 Metering pump

6 紡絲包 7 紡絲管嘴6 Spinning package 7 Spinning nozzle

7 a 吐出孑L 8 冷卻部本體 9 鼓風機7 a Spit 孑 L 8 Cooling unit body 9 Blower

第20頁 568963 五、發明說明(17) 10 吹出口 11 賦與油劑導管 12 加熱裝置 13 旋轉滑車 14 接觸輥 15 導絲動程機構 20 反射扳 21 鹵素燈 22a、 2 2 b 電極 42 冷卻裝置 48 冷卻部本體 49 鼓風機 50 吹出口 51 應力緩和部 52 氣流用内筒 53 氣流用外筒 54 應力緩和部本體 56 鼓風機 61 供給輥 62 加熱裝置 63 冷卻裝置 64 假检器 65 延伸輥 66 捲取裝置 119 議_讎Page 20 568963 V. Description of the invention (17) 10 Blowout port 11 Oil guide tube 12 Heating device 13 Rotary pulley 14 Contact roller 15 Guide wire travel mechanism 20 Reflector 21 Halogen lamp 22a, 2 2 b Electrode 42 Cooling device 48 Cooling section body 49 Blower 50 Blowout port 51 Stress relief section 52 Inner tube for air flow 53 Outer tube for air flow 54 Stress relaxation section body 56 Blower 61 Supply roller 62 Heating device 63 Cooling device 64 Fake detector 65 Extension roller 66 Winding device 119 Meeting _ 雠

第21頁 568963Page 21 568963

第22頁Page 22

568963 圖式簡單說明 圖1為例示實施本發明聚酯纖維之製造方法之裝置的概 略圖。 圖2為例示圖1裝置中所使用之加熱裝置,且為圖3之B-B 箭視圖。 圖3為圖2之A-A箭視圖。 圖4為例示實施本發明聚酯纖維之製造方法之其他態樣 之概略圖。 圖5為例示延伸假捻裝置之概略圖。568963 Brief description of the drawings Fig. 1 is a schematic diagram illustrating an apparatus for carrying out the method for producing a polyester fiber of the present invention. FIG. 2 illustrates a heating device used in the device of FIG. 1, and is a view taken along the arrow B-B of FIG. 3. Fig. 3 is a view of arrow A-A of Fig. 2. Fig. 4 is a schematic diagram illustrating another aspect of a method for producing a polyester fiber according to the present invention. Fig. 5 is a schematic view illustrating an extension false twisting device.

第23頁Page 23

Claims (1)

568963 _ 案號 90124fUzl568963 _ Case No. 90124fUzl ^ 一種聚酿纖維假捻加工絲之製造方法,其特徵為: 六、申請專利範圍 _ 管嘴所咖出之 =产:下^ r 又 人由刖述牽引輥以捲取裝置捲取成捲裝 (Package)為止之間,於高於玻璃轉移溫度之溫度中加埶 =得雙折射Δη為0·07以下、斷裂伸度為8〇%〜14〇%、比 ^ 1 · 35〜1 · 377g/cm3之物性值的高順向未延伸聚醋纖維, 。人―將該高順向未延伸聚酯纖維作為延伸假捻加工用原 絲,藉由對之以速度12〇〇m/min以上、張力55州以上進行延 伸假捻加工,以形成殘留伸度為2〇〜26· 5%的膨鬆加工絲。 2 ·如申請專f範圍第丨項之聚酯纖維假捻加工絲之製造 方法,其中,由前述熔融紡出之聚酯絲條之單側吹送冷卻風 予以冷卻,並且令前述牽引輥之拉引速度為 3000〜4500m/min 。 3 ·如申請專利範圍第1項之聚酯纖維假捻加工絲之製造 方法,其中,由前述溶融紡出之聚酯絲條之全周圍吹送冷卻 風予以冷卻,再於下游側令冷卻風於平行於行走方向上流 動且賦與應力緩和,一邊令前述牵引輥之拉引速度為 3000〜5000m/min 〇^ A method for manufacturing false-twisted processing yarn of poly-brewed fiber, which is characterized by: 6. Scope of patent application _ Out of the nozzle = production: down ^ r The reel is wound into a roll by a retraction device Before the installation (Package), add 埶 at a temperature higher than the glass transition temperature to obtain a birefringence Δη of 0.07 or less, an elongation at break of 80% to 14%, and a ratio of ^ 1 · 35 to 1 · High forward unstretched polyester fiber with a physical property value of 377g / cm3. Man-This high-direction non-stretched polyester fiber is used as the raw yarn for false-twist processing. The false-twist processing is performed at a speed of 12,000 m / min and a tension of 55 states to form a residual elongation. It is 20 ~ 26 · 5% bulked yarn. 2 · If the method for manufacturing a polyester fiber false twisted processing yarn according to item 丨 of the special application is applied, wherein the cooling side is cooled by blowing cooling air from one side of the polyester yarn melt-spun, and the pulling of the traction roller is performed The speed is 3000 ~ 4500m / min. 3. The manufacturing method of polyester fiber false-twisted processing yarn according to item 1 of the patent application scope, wherein the entire circumference of the polyester yarn produced by the melt spinning is blown with cooling air for cooling, and then the cooling wind is applied to the downstream side. Flow parallel to the direction of travel and relieve stress, while setting the pulling speed of the traction roller to 3000 ~ 5000m / min. C:\ 總檔\90\90124044\90124044(替換)-2.pt 第24頁C: \ master file \ 90 \ 90124044 \ 90124044 (replace)-2.pt page 24
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