TW568892B - Method for producing glass printed with color enamel - Google Patents

Abstract

A method for producing glass printed with color enamel comprises: (a) preparing an enamel coating material with suitable viscosity and concentration; (b) using a calender printer to print the enamel coating material on a roll transfer printing paper; (c) applying a protective adhesive layer and an isolation paper over the roll transfer printing paper; (d) transfer printing the roll transfer printing paper to a glass substrate; and (e) applying a sintering enforcement or bending thermal treatment on the glass substrate.

Description

568892 五、發明說明（1) 【發明領域 本發明係 別有關於將 造方法。 【先前技術 習用彩色 號「玻璃上 包含下列步 紋’並照相 實物底片製 處理：將前 溫耐高溫玻 層，最後方 漆料之玻璃 按，前述發 於待加工之 塗覆順序係 因此，該製 造之缺點， 處理之玻璃 板之缺點。 另一習用彩色瓷釉印刷玻璃製 號「玻璃表面花紋貼合成型製法 份：〔一〕花樣轉印紙製程：製 有關於一種彩色瓷釉印刷玻璃製造方法，其特 陶瓷塗料以轉印紙轉貼至玻璃板之彩色玻璃製 烤漆玻 還原實 驟：步 取景； 成分色 述分色 璃塗料 塗覆底 板加溫 明所揭 玻璃板 先不斷 造過程 此外， 板規格 璃製造 物色紋 驟—、 步驟二 底片， 網版置 層層塗 色層； 烘烤， 示之製上，再 重複塗 複雜、 分色網 亦受限 方法及 之製造 實物照 、製成 再製成 於待加 覆，其 步驟四 使玻璃 造方法 以耐高 覆各色 費時、 版具有 制，其 其塗料， 方法」之 相：選取 分色網板 分色網版 工之玻璃 塗覆順序 、供烤成 漆料完全 之步驟三 溫玻璃塗 層，最後 產量少而 規格限制 具有無法 如公告 製造方 所須之 :將前 ;步驟 板上’ ，係先 型：將 黏附於 、將分 料層層 方塗覆 具有無 ，因而 製造大 第253848 法，其係 實物花 述步驟之 三、上色 再以财南 塗覆各色 塗覆玻璃 玻璃板丨; 色網版ί. 塗覆，其 底色層， 法大量製 所被上色 規格玻璃 造方法，如公告第360599 」，其主要包括兩個部 圖—照相製板—印刷—乾568892 V. Description of the Invention (1) [Field of the Invention] The present invention relates to a method for manufacturing. [Prior art color number "The glass contains the following step patterns' and is processed by photographic actual negatives: the front temperature and high temperature resistant glass layer, and the last lacquered glass are pressed. The aforementioned coating sequence is issued for processing. Therefore, the Disadvantages of manufacture, disadvantages of processed glass plates. Another custom is the use of colored enamel printing glass. "Glass surface pattern and paste synthetic method": [1] Pattern transfer paper. Process: A method for manufacturing a colored enamel printed glass. The special ceramic coating is transferred to the glass plate by the transfer paper to the colored glass baking paint. The glass reduction steps: step framing; the component color description, the color separation glass coating, the base plate, and the glass plate exposed by Wenming. Steps to find color patterns— Step 2 negative film, screen layer coating layer and color coating layer; baking, showing the system, and then repeatedly applying complex, color separation screen is also limited method and manufacturing physical photos, making and then making To be added, the fourth step of the method is to make the glass manufacturing method resistant to high color and time-consuming, the plate is made, and its coating, method. Take the glass coating sequence of the color separation screen and the color separation screen printer, and complete the step of baking the paint. Three-temperature glass coating, the final output is small and the specifications are limited. As required by the manufacturer of the announcement: first; steps On the board, it is the first type: it will be adhered to, and the material layer will be coated on each side without coating. Therefore, the large method 253848 is used. It is the third step of the actual flowering. Coloring and coating with Cainan Glass glass plate; color screen version. Coating, its base color layer, the method of making glass in a large number of manufacturing methods, such as bulletin No. 360599, which mainly includes two parts—photographic board—printing— dry

568892 五、發明說明（2) 燥―轉印紙成品，其主要是先宗 之構圖後，再利用照相製版技玻璃表面附加花樣 印刷作業，先於轉印蠛紙表面塗；成後進行網版 可於其上利用網版套印圖樣色彩，於：=層，即 於顏料上層均勻塗佈一層表面透樹=7 二早，，再 亦 ^ . 也 η树脂’取後施予#條你 業，使表面透明樹脂層硬化而能于^作 可完；花樣轉印紙之製…二= 紙經泡水處理後貼覆於玻璃表面預定；===印 i ’ η ί化樣之顏料與轉印蠟紙分離而能單獨取下蠟 :、隹僅令其花樣著於玻璃表面，而後將玻璃製品置入；i 内進仃加溫定型作業，在加溫過程中，詨 匕 將會逐漸：化揮*，同時花樣顏料乃石更;:固著於玻璃表"旨 面，依此完成玻璃表面花樣之附加。按，前述發明所 該製法之轉印蠟紙表面塗印一層透明樹鹿底# 其上利用網版套印圖樣色彩具有規格限制，因而轉 之玻璃板規格#受限制’纟具有無法t造大規 缺點。 π T久〜 本發明係將前述製造方法加以改良，提供一種彩色瓷釉 印刷玻璃製造方法將陶瓷塗料以輪轉印刷機印於轉印紙 上，再將轉印紙轉貼至玻璃板上，由於轉印紙轉貼至玻璃 板上具有不需不斷重複塗覆各色層及不限轉印紙長度之製 程’本發明具有大量生產及不限玻璃板規格功效。 【發明目的】568892 V. Description of the invention (2) Drying—the finished product of transfer paper, which is mainly composed of the previous pattern, and then uses pattern printing on the glass surface to add pattern printing work, and then the surface of the transfer paper is coated. The screen printing pattern color is used on it: = layer, that is, evenly coating a layer on the surface of the pigment through the tree = 7 morning, and no more ^. Also η resin 'is given to # 条 你 业, so that the surface The transparent resin layer is hardened and can be finished in ^; the pattern transfer paper is made ... 2 = the paper is coated with water on the glass surface to be scheduled; === 印 i 'η The pigment is separated from the transfer wax paper And the wax can be removed separately: 隹 only make the pattern on the glass surface, and then put the glass products; i inside the 仃 heating and setting operation, during the heating process, the dagger will gradually: At the same time, the pattern pigment is stone: fixed on the glass surface, and the glass surface pattern is added accordingly. According to the above-mentioned invention, the surface of the transfer wax paper is coated with a layer of transparent tree deer bottom. The color of the overprint pattern on the screen has a specification limit, so the glass plate specification #restricted 'has the disadvantage that it cannot be made in a large scale. π T long ~ The present invention is to improve the aforementioned manufacturing method, and to provide a method for manufacturing colored enamel printed glass. The ceramic coating is printed on a transfer paper by a rotary printer, and the transfer paper is transferred to a glass plate. The glass plate has a manufacturing process that does not need to repeatedly coat each color layer and unlimited length of the transfer paper. The invention has mass production and unlimited glass plate specifications. [Objective of the invention]

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568892568892

本發明主 法，其將陶 轉貼至玻璃 長度，本發 根據本發 塗料調配至 印刷機印刷 層及隔離紙 將該玻璃板 黏度，使該 紋表面上， 色圖案及花 要目的係提供^種势$ 1 禋夯色究釉印刷玻璃製造方 一尤塗料以轉印紙轉貼至姑逋 ^ ^ 王坂瑪扳面，由於轉印紙 板具有不需不斷重複塗覆各色層及不限轉印紙 明具有大量生產及不限玻璃板規格功效。 明之彩色瓷釉印刷玻璃製造方法，a、將陶瓷 適當黏度及濃度，b、將該陶瓷塗料以輪轉 至捲筒轉印紙，c、在該捲筒轉印紙上保護膠 、’ d、將該捲筒轉印紙轉貼至玻璃板面，及e、 進了燒結。本發明之陶瓷塗料必須調配至適當 陶究塗料不產生沉澱而黏附於輪轉印刷機之印 而該輪轉印刷機可迅速大量印刷出各種不同彩 紋0 &本發明改良公告第253848號及第3 60 599號之彩色玻璃製 仏方法’其主要將公告第25 3848號及第36059 9號之網版印 刷玻璃板面改良為以將青:堯塗料以轉印紙轉貼至玻璃靖断According to the main method of the present invention, the ceramic is transferred to the length of the glass, and the hair is formulated to the printing layer of the printing machine and the release paper according to the hair to make the glass plate viscosity so that the color pattern and flowers on the surface of the texture are provided. Potential $ 1 禋 satin-colored glaze printing glass manufacturer Fang Yiyou coating is reprinted on transfer paper to ^ ^ Wang Banma, because the transfer cardboard has no need to repeatedly coat each color layer and unlimited transfer paper. Mass production and unlimited glass sheet specifications. Ming Zhi colored enamel printing glass manufacturing method, a, appropriate viscosity and concentration of ceramic, b, the ceramic coating is rotated to a roll transfer paper, c, protective glue on the roll transfer paper, 'd, the roll The transfer paper was affixed to the glass plate surface, and e, sintered. The ceramic coating of the present invention must be formulated to a suitable ceramic coating that does not cause sedimentation and adheres to the printing of a rotary printing machine, and the rotary printing machine can quickly print a large number of different color patterns. 0 & Improvement Notice No. 253848 and No. 3 of the Invention 60 599's method of making stained glass' It mainly improves the screen printing glass plate surface of Announcement No. 25 3848 and No. 36059 9 to transfer the green: Yao paint to the glass by transfer paper

以提高印刷效率及可轉印於任何規格之玻離板。 I 【圖式說明】 為了讓本發明之上述和其他目的、特徵、和優點能更為 明顯被了解’下文特舉本發明較佳實施例，並配合所附圖 式，作詳細說明如下。 第1圖：本發明較佳實施例之製程方法流程圖。 【發明說明】 請參照第一圖所示，本發明較佳實施例製造方法主要包 含· a、將陶瓷塗料調配至一適當黏度及濃度，b、將該陶In order to improve the printing efficiency and can be transferred to any specifications of the glass plate. I [Illustration of the Drawings] In order to make the above and other objects, features, and advantages of the present invention more comprehensible, the following describes the preferred embodiments of the present invention in detail with reference to the accompanying drawings. FIG. 1 is a flowchart of a manufacturing method according to a preferred embodiment of the present invention. [Explanation of the invention] Please refer to the first figure. The manufacturing method of the preferred embodiment of the present invention mainly includes: a. Preparing the ceramic coating to an appropriate viscosity and concentration; b.

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瓷塗料以輪轉印刷機印刷至捲筒轉印紙上，c、 捲筒 轉印紙上保護膠層及隔離紙，d、將該捲筒轉印紙^貼= 玻璃板面，及e、將該玻璃板進行燒結。 、 本發明製造方法步驟a係將陶瓷塗料調配至一適當黏度 及濃度，該陶瓷塗料係主要將陶瓷色粉加入有機%容"劑"The porcelain coating is printed on the roll transfer paper by a rotary printing machine, c, the protective adhesive layer and release paper on the roll transfer paper, d, the roll transfer paper ^ paste = the glass plate surface, and e, the glass plate Sintering is performed. In step a of the manufacturing method of the present invention, the ceramic coating is formulated to an appropriate viscosity and concentration. The ceramic coating is mainly a ceramic toner added to an organic solvent.

節油、苯類溶劑···〕調製成一適當黏度，使該陶瓷塗料不 產生沉澱而黏附於輪轉印刷機之印紋表面上，該陶兗色粉 重量百分比則可決定色彩濃度，若該陶瓷塗料内/加入石= 粉在玻璃板面上形成一粗糙面，而該石英粉顆粒大小則可 決定玻璃板面色層之粗糙度。一般陶瓷塗料則具有產生沉 澱及其黏度無法使該陶瓷塗料黏附於輪轉印刷機之印紋表 面上之缺點。Fuel-saving, benzene-based solvents ... Prepared to an appropriate viscosity, so that the ceramic coating does not precipitate and adheres to the printing surface of the rotary printing press. The weight percentage of the ceramic powder can determine the color concentration. In the coating / added stone = powder forms a rough surface on the glass plate surface, and the particle size of the quartz powder can determine the roughness of the color layer of the glass plate surface. Common ceramic coatings have the disadvantages of causing precipitation and their viscosity to prevent the ceramic coating from adhering to the printing surface of the rotary printing press.

本發明製造方法步驟b係將該陶瓷塗料以輪轉印刷機印 刷至捲筒轉印，，由於該輪轉印刷機一次將彩色圖案及花 紋印刷至該捲筒轉印紙以及該捲筒轉印紙具有不限長度，之, 優點，因此，該捲筒轉印紙上可迅速印刷彩色圖案及花， 紋’且該圖案不受規格限制。Step b of the manufacturing method of the present invention is to print the ceramic coating to a roll transfer by a rotary printing machine. Since the rotary printing machine prints color patterns and patterns to the roll transfer paper and the roll transfer paper at one time, The length, the advantages, therefore, the roll transfer paper can be quickly printed with color patterns and flowers, patterns' and the pattern is not limited by specifications.

本發明製造方法步驟c係在該捲筒轉印紙上保護膠層及 隔離紙’該保護膠層將該捲筒轉印紙上彩色圖案及花紋定 型’而該隔離紙則將該彩色圖案及花紋隔離於該捲筒轉印 紙背面’以免该彩色圖案及花紋受損。 本發明製，方法步驟d係將該捲筒轉印紙轉貼至玻璃板 面’將該捲筒轉印紙撕開隔離紙泡水後並將該捲筒轉印紙 貼於該玻璃板面’使該捲筒轉印紙上彩色圖案及花紋黏附Step c of the manufacturing method of the present invention is a protective adhesive layer and a release paper on the roll transfer paper. The protective adhesive layer sets the color pattern and pattern on the roll transfer paper and the release paper isolates the color pattern and pattern. On the back of the roll transfer paper to prevent the color patterns and patterns from being damaged. According to the method of the present invention, the method step d is to transfer the roll transfer paper to the surface of the glass plate 'after tearing the roll transfer paper to isolate the paper soaked in water and attach the roll transfer paper to the surface of the glass plate' to make the roll Color pattern and pattern adhesion on tube transfer paper

568892 五、發明說明（5) - 於該玻璃板面上，此時，該玻璃板面上呈現該彩色圖案及 花紋。 ^ 本發明製造方法步驟e係將該玻璃面板進行燒結，當進 行高溫燒結強化或彎曲熱處理〔5 6 0 °C〜6 2 0 °C〕時，該陶 瓷塗料内有機溶劑及不穩定化學物質完全揮發，而該保護 膠層則同時被熔化後使該陶瓷塗料的花紋及圖案落在該玻 璃板面上’使該玻璃板面上只剩下耐高溫及穩定不變質之 無機色料花紋與玻璃板面燒結成一體並呈現光滑之平面。568892 V. Description of the invention (5)-On the glass plate surface, at this time, the colored pattern and pattern appear on the glass plate surface. ^ Step e of the manufacturing method of the present invention is to sinter the glass panel. When high temperature sintering strengthening or bending heat treatment is performed (5 60 ° C ~ 6 2 ° C), the organic solvents and unstable chemicals in the ceramic coating are completely Volatilize, and the protective glue layer is melted at the same time so that the pattern and pattern of the ceramic coating fall on the glass plate surface, so that only the high-temperature resistant and stable non-deteriorating inorganic pigment pattern and glass remain on the glass plate surface The surface of the board is sintered into one body and presents a smooth flat surface.

若該陶瓷塗料内包含石英粉則該石英粉與玻璃板面在高溫 下燒結成一粗糙面。有關進一步燒結技術内容揭示於我國 第87105319號「彩色烤漆玻璃製造方法及其塗料」發明專 利申請案。 X 本發明係提供一種彩色玻璃製造方法，將陶瓷塗料以轉 印紙轉貼至玻璃板，由於轉印紙轉貼至玻璃板具有不需不 斷重複塗覆各色層及不限轉印紙長度，雖然本發明較，公告。 第2 538 48號多出將該陶瓷塗料以輪轉印刷機印刷至捲筒缚丨::了;) 印紙及將該捲筒轉印紙轉貼至玻璃板面製程，事實上，由〜 於將該陶瓷塗料以輪轉印刷機印刷至捲筒轉印紙上，因 此’該輪轉印刷機一次將各色層彩色圖案及花紋印刷至該 捲筒轉印紙上具有迅速大量印刷之功效，及該捲筒轉印紙 具有不限長度及運輸方便之功效，因此，該捲筒轉印紙上 可迅速印刷彩色圖案及花紋，且該圖案不受規格限制，使 玻璃板面亦不受規格限制，此外，已印刷之捲筒轉印紙具 有方便儲藏，依需要再將該捲筒轉印紙轉貼至玻璃面板上If the ceramic coating contains quartz powder, the quartz powder and the glass plate surface are sintered into a rough surface at a high temperature. The content of further sintering technology was disclosed in China's patent application for invention No. 87105319 "Method for Manufacturing Colored Bake Glass and Its Coating". X The present invention provides a method for manufacturing colored glass. The ceramic coating is transferred to a glass plate by a transfer paper. Since the transfer paper is transferred to the glass plate, it does not need to repeatedly coat each color layer and the length of the transfer paper is not limited. announcement. No. 2 538 No. 48: The process of printing the ceramic coating to the roll with a rotary printing machine is called 丨 :: ;;). The process of printing paper and transferring the roll transfer paper to the glass surface is, in fact, from ~ to the ceramic The coating is printed on the roll transfer paper by a rotary printing machine, so 'the rotary printing machine prints the color patterns and patterns of each color layer on the roll transfer paper at a time, which has the effect of quickly printing a large amount, and the roll transfer paper has no effect. Limited length and convenient transportation. Therefore, color patterns and patterns can be quickly printed on the roll transfer paper, and the pattern is not limited by the specifications, so that the glass plate surface is not limited by the specifications. In addition, the printed rolls are turned. Printing paper has convenient storage, and then transfer the roll transfer paper to the glass panel as needed

568892 五、發明說明（6) 即可，本發明具有彩色玻璃大量生產及不限玻璃板規格功 效。 雖然本發明已以前述較佳具體實施例揭示，然其並非用 以限定本發明，任何熟習此技藝者，在不脫離本發明之精 神和範圍内，當可作各種之更動與修改。因此本發明之保 護範圍當視後附之申請專利範圍所界定者為準。568892 V. Explanation of the invention (6). The invention has mass production of colored glass and unlimited glass plate specifications. Although the present invention has been disclosed in the foregoing preferred embodiments, it is not intended to limit the present invention. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be determined by the scope of the attached patent application.

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Claims (1)

568892 六、申請專利範圍 I ，'... ί I 1、一種彩色玻係包括有下列步驟： 提供適當黏度之一陶瓷塗料，該陶瓷塗料包含數個陶 兗色粉及一有機溶劑； 將該陶曼塗料置於一輪轉印刷機墨槽並印刷至一捲筒 轉印紙之表面以形成各種色彩圖案及花紋； 在該捲筒轉印紙上一保護膠層使該色彩圖案及花紋定 形’再將一隔離紙置於該色彩圖案及花紋上； 將該捲筒轉印紙撕開該隔離紙後泡水，再將該捲筒轉 印紙轉貼至一玻璃板面；及 將該玻璃板進行高溫燒結，該陶瓷塗料内有機溶劑及 _ 不穩定化學物質完全揮發，而該保護膠層則被熔化後 使該陶瓷塗料落在該玻璃板面上，使該玻璃板面上只 剩下耐高溫及穩定不變質之無機色料與玻璃板面燒結 成一體並呈現光滑之平面。 2、 依申請專利範圍第1項之1彩色玻璃製造方法，其中該 有機溶劑係屬松節油。 3、 依申請專利範圍第1項之彩色玻璃製造方法，其中該 有機溶劑係屬苯類溶劑。 4、 依申請專利範圍第1項之彩色玻璃製造方法，其中該 陶究塗料包含一石英粉’該石英粉與破璃板面在南溫 下燒結成一粗糙面。568892 VI. Application for patent scope I, '... ί I 1. A colored glass system includes the following steps: providing a ceramic coating with an appropriate viscosity, the ceramic coating includes a plurality of ceramic tincture powder and an organic solvent; Taumann paint is placed in the ink tank of a rotary printing machine and printed on the surface of a roll transfer paper to form various color patterns and patterns; a protective adhesive layer on the roll transfer paper shapes the color patterns and patterns. A release paper is placed on the color pattern and pattern; the roll transfer paper is torn off the release paper, soaked in water, and then the roll transfer paper is affixed to a glass plate surface; and the glass plate is sintered at high temperature, The organic solvent and unstable chemicals in the ceramic coating are completely volatilized, and the protective glue layer is melted to cause the ceramic coating to fall on the glass plate surface, so that only the high temperature resistance and stability of the glass plate surface remain. The deteriorated inorganic colorant is sintered with the glass plate surface to form a smooth surface. 2. The method for manufacturing stained glass according to item 1 of the scope of patent application, wherein the organic solvent is turpentine. 3. The method for manufacturing stained glass according to item 1 of the scope of patent application, wherein the organic solvent is a benzene solvent. 4. The method for manufacturing stained glass according to item 1 of the scope of patent application, wherein the ceramic coating comprises a quartz powder ', and the quartz powder and the surface of the broken glass plate are sintered to a rough surface at a temperature of South. C:\Program Files\patent\PK6623.ptdC: \ Program Files \ patent \ PK6623.ptd