TW555849B - Smokeless candle - Google Patents

Smokeless candle Download PDF

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Publication number
TW555849B
TW555849B TW089106905A TW89106905A TW555849B TW 555849 B TW555849 B TW 555849B TW 089106905 A TW089106905 A TW 089106905A TW 89106905 A TW89106905 A TW 89106905A TW 555849 B TW555849 B TW 555849B
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Taiwan
Prior art keywords
wax
candle
insect
smokeless
patent application
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TW089106905A
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Chinese (zh)
Inventor
Taizo Noda
Moriji Umeda
Daijiro Ohtani
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Cera Rica Noda Co Ltd
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Priority claimed from JP26095799A external-priority patent/JP3387863B2/en
Application filed by Cera Rica Noda Co Ltd filed Critical Cera Rica Noda Co Ltd
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Publication of TW555849B publication Critical patent/TW555849B/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C5/00Candles
    • C11C5/002Ingredients
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C5/00Candles

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)

Abstract

There is described a smokeless candle which contains insect or Chinese wax, in addition to paraffin wax, to prevent generation of soot, when burning flame of the candle flares. A smokeless candle comprising paraffin wax and insect wax derived from Ericerus pela, as wax components thereof, wherein an amount of said insect wax occupies 5-60% by weight in the wax components.

Description

A7A7

555849 五、發明說明(1 ) 發明背景 1 ·發明範圍 本發明係關於蠟燭,並且更特定言之,係關於無煙虫蔵 燭其燃燒時不會或幾乎不會產生煙灰並且可以含有香料以 享受其燃燒期間的芳香。 2 ·相關技藝 迄今,蜂蠟及日本蠟係作爲製備照明蠟燭的原料,目 前則是主要使用石蠟的石油蠟及其與聚乙烯蠟或硬脂酸的 混合物。 在包括日本型蠟燭的躐燭中,一種稱爲'、無煙〃蠘燭 的產品亦已上市,其顯現極佳的燃燒性質並且在無風的條 件下當然不會有煙灰的產生,但是,當燭火爲風或類似物 所搖曳時,瞬間產生的煙灰仍無法避免,即使其量很少。 至於用以享受其燃燒期間香味的所謂的、、芳香蠟燭〃 ,Japanese Patent 9-188893(A)揭示一種蠟燭其包含混入石 蠟之蠟混合物中作爲主要組份的香料前驅物及作爲附加組 份的聚乙烯蠟及高碳脂肪羧酸,蠟燭燃燒期間,該蠟燭會 因香料前驅物的分解作用而產生香味。近年來,爲因應芳 香療法及因爲蠘燭的光或燭火具有緩和人類心性的效果, 所以含有香料的多種蠟燭業已問世。 如果周遭係維持在無風的條件下,僅由石蠟製成的蠟 燭或者含有石蠟作爲其主要組份的蠟燭係於幾近完美燃燒 的狀態下燃燒並且幾乎不會有煙灰的產生,但是仍具有以 (請先閱讀背面之注意事項再填寫本頁) ---------訂---------線· 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -4 - 經濟部智慧財產局員工消費合作社印製 555849 A7 B7__,_ 五、發明說明(2 ) 下的缺點。 (1 )當燭火爲風或類似物所搖曳時,瞬間產生的煙 灰會使室中的環境變差, (2 )燭火多少會變長因此在安全上產生某些問題並 且總燃燒時間變短, (3 )當燭火熄滅時,強烈且固有的味道(令人不快 的味道)多少會產生,及 (4 )當選用液體香料且其量較高時,蠟的硬度會變 低因此當蠟燭以模塑法製造時蠟燭的構形僅限於棒狀。此 意味蠟應倒至不同構形的玻璃或類似容器中以製得具有不 同於棒狀之構形的蠟燭,此蠟燭產品必須連同容器一倂促 銷。 發明槪述 因此,本發明之主要目的係提供無煙蠘燭其含有石蠟 作爲其蠟組份之一,但是煙灰的產生被顯著地抑制或者煙 灰根本不會產生。 本發明之另一目的係提供無煙蠘燭其燭火較習用蠟燭 者爲短,所以和習用蠟燭相較其總燃燒時間相當長。 本發明之另一目的係提供無煙蠟燭其易於脫模,即使 液體香料以大量混入蠟組份中,由是具有不同構形的蠟燭 可以利用本質上已知的模塑法製得。 本發明之另一目的係提供無煙蠟燭其具有細緻的淡色 調且無不規則的色調因而賦予透明的感覺,而某些市售的 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -5- ---------------------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 555849 A7 _ B7 五、發明說明(3 ) 芳香蠟燭具有重色調,其原因可能爲石蠟對多種著色劑( 更特定言之,液體型著色劑)具有低親和性因此著色劑係 以大量使用以避免芳香蠟燭在色調上產生不規則性。 依據本發明,主要目的係藉無煙蠟燭達成其包含石蠘 及昆蟲蠛或中國蠟作爲其蠟組份。 在依據本發明之無煙蠟燭用的蠟組份中,昆蟲蠟係白 蠟蟲次生幼蟲分泌且附著至Fraxinus chinensis及Li-gustrum lucidum之樹幹及枝葉者,此蠟藉其純化作用而顯現幾近 純白之色調及8 0 - 8 3 °C之相當高的熔點。發明人不經 意地發現將昆蟲蠟納入石蠟中而製得的蠘燭具有以下特性 並因此確立本發明。 (a )煙灰的產生明顯地受到抑制。 (b )燭火短(約1公分其爲石蠟製成之鱲燭者均一 半或以下)因此燃燒時間變長(本發明之基本目的不在於 提供照明蠟燭,而是提供芳香蠟燭,就使用的安全性而言 ,短的燭火非但不是缺點反而是一種優點)。 (c )當燭火熄滅時,石蠟製成之蠟燭所固有的令人 不快的味道不會產生。 (d )即使液體香料構成蠘組份的約1 〇重量%,經 由模塑法熔蠟仍可製得具有良好硬度的蠟燭,由是各鱲燭 在其燃燒期間可以產生不同強度的香味。 (e )蠟的熔融混合物對多種液體著色劑顯現良好的 親和性,其使得具有細緻淡色調且無不規則著色部份並賦 予透明色感的蠟燭得以製成。 本紙張尺度適用中國國家標準(CNS)A4規格(210 297公釐) -------I#--------π---------線 _ (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 555849 A7 __ B7 五、發明說明(4 ) (f )習用蠟燭之燭火的尖端爲尖型當蠟燭燃燒時其 會因上升的氣流而幾乎連續地搖曳但是在依據本發明之蠟 燭的情況中,燭火的尖端稍圓並且整體而言其呈現安定因 而給人溫和或平靜的感覺。 在依據本發明的無煙鱲燭中,昆蟲蠟最好占蠟組份的 5 — 6 0重量%。因爲,當昆蟲蠟占約5重量%時,煙p 產生的頻率即顯著地降低,當燭火被手強迫搖曳及燭火因 搖曳或搖晃而使得煙灰瞬間產生時,產生之煙灰的量極少 ,因爲燭火的長度短了約1公分。請注意市售芳香蠟燭之 燭火的長度爲2公分或以上,如果昆蟲蠟占約6 0重量% 或以上,在模中固化的蠟混合物顯現過高的硬度,當模具 具有細緻或複雜的構形時,蠟燭產品在脫模時可能發生斷 裂或破裂的現象,就製造成本而言此並不適宜。 1 如果香料在芳香蠟燭中的濃度太高,則香料可能會引 起不快的感覺,端視其種類而定。在前述的Japanese Patent 9 - 1 8 8 8 9 3 (A)中,段落編號〇 〇 〇 7中有如下的說明”就蠟 燭中香料前驅物的量而言,前驅物被納入並占0 · 0 1 -20重量%,以〇 · 05 - 10重量%爲更佳,以〇 . 1 - 5重量%爲最佳,雖然其視香料的種類而定”,即建議將 香料的量設定爲相當低並且在實例中,前驅物對蠟組份( 稱爲燃燒物質〃)的量僅爲1重量%。然而,在本發明 之無煙蠟燭的例子中,因爲燭火較短,所以香味的釋出有 被抑制的傾向,因此香料的量必須設定在較高的水準。在 石蠟製成或者不含昆蟲蠘但含有石蠟作爲主要蠟組份之習 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) .—--------^--------- (請先閱讀背面之注意事項再填寫本頁) 555849 A7 ___ B7 五、發明說明(5 ) (請先閱讀背面之注意事項再填寫本頁) 見芳香蠟燭的情況中,當液體香料以大量混入時,其硬度 會降低’因而在脫模時會產生問題。相反地,就本發明之 鱲燭的製造而言,具有8 0 - 8 3 °C之相當高熔點的昆蟲 蠟被納入因而在脫模步驟中不會發生無煙蠘燭的變形。依 據本發明之無煙蠟燭,其在燃燒期間熔化及流動蠟的量小 ,當蠟燭的燃燒完全終結而自然燃盡時,其潰散度小。即 ’在依據本發明之蠟燭的例子中,其外殻部份實質上仍維 持原有的形狀。請注意在石蠟製成之市售芳香蠟燭的例子 中,未燃燒的蠟完全無法保持其原有的形狀。 較佳實施例的詳細說明 本發明將參考試驗例及製造例作進一步的說明。 以下係使用於試驗例及製造例中的原料。 (1 )蠟 (a )石蠟: 熔點爲1 3 5 °F之市售的純化產物。 (b )昆蟲獵· 經濟部智慧財產局員工消費合作社印製555849 V. Description of the invention (1) Background of the invention 1 · Scope of the invention The present invention relates to candles, and more specifically, to smokeless insect candlesticks that do not or hardly produce soot when burned and may contain fragrances to enjoy their use Aroma during burning. 2 · Related skills So far, beeswax and Japanese wax are used as raw materials for lighting candles. At present, petroleum waxes mainly using paraffin and their mixtures with polyethylene wax or stearic acid. Among the Japanese candlesticks, a product called ', smokeless candlestick' has also been launched on the market. It shows excellent burning properties and of course there will be no soot under windless conditions. When fire is swayed by wind or the like, instantaneous soot is unavoidable, even in small quantities. As for the so-called, scented candle 〃, which is used to enjoy the fragrance during its burning, Japanese Patent 9-188893 (A) discloses a candle which contains a fragrance precursor mixed as a main component in a wax mixture of paraffin and an additional component Polyethylene wax and high-carbon fatty carboxylic acid. During the burning of the candle, the candle will generate fragrance due to the decomposition of the precursor of the fragrance. In recent years, in order to respond to aromatherapy and because the light of candlelight or candlelight has a soothing effect on human heart, a variety of candles containing spices have been introduced. If the surrounding system is maintained in a windless condition, a candle made of only paraffin or a candle containing paraffin as its main component will be burned in a nearly perfect condition and there will be almost no soot, but it still has (Please read the precautions on the back before filling this page) --------- Order --------- Line · Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is applicable to China Standard (CNS) A4 specification (210 X 297 mm) -4-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 555849 A7 B7 __, _ V. Disadvantages under Description of Invention (2). (1) When the candlelight is swayed by the wind or the like, the instantaneous soot will make the environment in the room worse, (2) the candlelight will become longer, so there will be some problems in safety and the total burning time will change. Short, (3) When the candle is extinguished, a strong and inherent taste (unpleasant taste) will be produced to some extent, and (4) When a liquid flavor is used and its amount is high, the hardness of the wax will become low, so when When a candle is manufactured by a molding method, the configuration of the candle is limited to a rod shape. This means that the wax should be poured into glass or similar containers of different configurations to make candles with different configurations than rods. This candle product must be sold together with the container. SUMMARY OF THE INVENTION Therefore, the main object of the present invention is to provide a smokeless candle containing paraffin as one of its wax components, but the generation of soot is significantly suppressed or soot is not generated at all. Another object of the present invention is to provide a smokeless candle with a shorter candle flame than a conventional candle, so that its total burning time is considerably longer than a conventional candle. Another object of the present invention is to provide a smokeless candle which can be easily demolded, and even if a liquid fragrance is mixed in a large amount in a wax component, a candle having a different configuration can be produced by a molding method known per se. Another object of the present invention is to provide a smokeless candle which has a delicate light hue and no irregular hue, thus giving a transparent feeling, and some commercially available paper sizes are applicable to China National Standard (CNS) A4 (210 X 297) Mm) -5- --------------------- Order --------- line (Please read the notes on the back before filling in this page ) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 555849 A7 _ B7 V. Description of the Invention (3) The aromatic candles have a heavy color tone, which may be due to the low paraffin wax's effect on various colorants (more specifically, liquid colorants). Affinity is therefore used in large amounts to avoid irregularities in the tone of the aromatic candles. According to the present invention, the main purpose is to achieve a smokeless candle which contains a stone salamander and an insect salamander or Chinese wax as its wax component. In the wax composition for smokeless candles according to the present invention, the secondary wax larvae of the insect wax-type white wax insect are secreted and attached to the trunks and leaves of Fraxinus chinensis and Li-gustrum lucidum. This wax appears almost pure white by its purification Color tone and a very high melting point of 8 0-8 3 ° C. The inventors inadvertently discovered that the candlestick prepared by incorporating insect wax into paraffin wax has the following characteristics and thus established the present invention. (a) The generation of soot is significantly suppressed. (b) The candlelight is short (about 1 centimeter, which is half or less of those made from paraffin wax candles), so the burning time becomes longer (the basic purpose of the present invention is not to provide lighting candles, but to provide aromatic candles. In terms of safety, a short candlelight is not a disadvantage but an advantage). (c) When the candle is extinguished, the unpleasant taste inherent in candles made from paraffin does not occur. (d) Even if the liquid fragrance constitutes about 10% by weight of the rhenium component, the wax can still be made with a good hardness by melting the wax, so that each scented candle can produce a scent with different intensity during its burning. (e) The molten mixture of the wax exhibits good affinity for a variety of liquid colorants, which makes a candle having a fine light tone without irregularly colored portions and imparting a transparent color feeling. This paper size applies to China National Standard (CNS) A4 (210 297 mm) ------- I # -------- π --------- line_ (please first Read the notes on the back and fill in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 555849 A7 __ B7 V. Description of the invention (4) (f) The tip of the candlelight of a conventional candle is pointed when the candle burns Swaying almost continuously due to the rising air currents but in the case of a candle according to the invention, the tip of the candlelight is slightly rounded and overall it presents a sense of calmness or calmness. In the smokeless candle according to the present invention, the insect wax preferably accounts for 5 to 60% by weight of the wax component. Because, when the insect wax accounts for about 5% by weight, the frequency of smoke p is significantly reduced. When the candlelight is forced to sway by hand and the candlelight is caused by the swaying or shaking of the candlelight, the amount of soot generated is very small. Because the length of the candlelight was about 1 cm shorter. Please note that the length of the commercially available scented candle is 2 cm or more. If the insect wax accounts for about 60% by weight or more, the wax mixture cured in the mold shows excessive hardness. When the mold has a fine or complex structure When it is shaped, the candle product may break or crack during demolding, which is not suitable in terms of manufacturing cost. 1 If the concentration of the fragrance in the scented candle is too high, the fragrance may cause unpleasant sensations, depending on the type. In the aforementioned Japanese Patent 9-1 8 8 8 9 3 (A), the paragraph No. 2007 has the following description "In terms of the amount of the spice precursor in the candle, the precursor is included and accounts for 0 · 0 1-20% by weight, more preferably 0.05-10% by weight, and most preferably 0.1-5% by weight, although it depends on the type of fragrance ", that is, it is recommended to set the amount of fragrance to be quite low And in the example, the amount of the precursor to the wax component (referred to as a burning substance 〃) is only 1% by weight. However, in the example of the smokeless candle of the present invention, since the candlelight is short, the release of fragrance tends to be suppressed, and therefore, the amount of fragrance must be set to a higher level. For papers made of paraffin or containing no insect pupae but containing paraffin as the main wax component, the paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm). ---------- ^- -------- (Please read the notes on the back before filling this page) 555849 A7 ___ B7 V. Description of the invention (5) (Please read the notes on the back before filling this page) See the situation of aromatic candles However, when a liquid flavor is mixed in a large amount, its hardness is reduced, and thus a problem may occur during demolding. In contrast, for the manufacture of the candlestick of the present invention, insect wax having a relatively high melting point of 80 to 83 ° C is incorporated so that the smokeless candlestick does not deform during the demolding step. According to the smokeless candle according to the present invention, the amount of wax that melts and flows during the burning is small, and when the burning of the candle is completely ended and naturally burns out, the degree of collapse is small. That is, 'in the example of the candle according to the present invention, its outer shell portion substantially maintains the original shape. Please note that in the example of a commercially available scented candle made of paraffin, the unburned wax was unable to maintain its original shape at all. Detailed Description of the Preferred Embodiments The present invention will be further described with reference to test examples and manufacturing examples. The following materials are used in the test examples and manufacturing examples. (1) Wax (a) Paraffin: A commercially available purified product having a melting point of 1 35 ° F. (b) Insect hunting · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

Kanagawa-ken,Japan.之 Cera Rica Noda Co.,Ltd.販售的純化產物。 (2 )著色劑 (a )紅色著色劑: R - 225 (使用濃度;〇 · 3毫克/毫 升)。 (b )藍色著色劑: -8 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 555849 A7 B7 五、發明說明(6 ) d B — 403 (使用濃度;〇 升)。 )綠色著色劑: G— 202 (使用濃度;〇 升)。 黃色著色劑: 3毫克/毫 3毫克/毫 Y - 0 4 (使用濃度;〇 . i 毫克/毫升 請注意'' R — 2 2 等係用以確認顏料自勺符號 試驗例1 (煙灰產生試驗) 利用圓柱狀模具製得具有不同組成比之石蠟與昆蟲蠟 的多種鱲燭以使蠘燭產品易於脫模。將各個蠘燭點燃荦使 其在無風的狀態下燃燒,將白紙置於蠟燭火焰的鄰近處, 然後以手煽動火焰以強迫燭火搖曳並經由目視檢查煙灰產 生的頻率。結果示於下表1中。 ---------------------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) _ 9 - 555849 A7 B7A purified product sold by Cera Rica Noda Co., Ltd. of Kanagawa-ken, Japan. (2) Colorant (a) Red colorant: R-225 (concentration used; 0.3 mg / mL). (b) Blue colorant: -8-This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 555849 A7 B7 V. Description of the invention (6) d B — 403 (use concentration; 0 liter ). ) Green colorant: G-202 (use concentration; 0 liter). Yellow colorant: 3 mg / milligram 3 mg / millimeter Y-0 4 (Used concentration; 0.1 mg / mL Please note '' R — 2 2 etc. are used to confirm the symbol of the pigment from the spoon Test Example 1 (Soot production test ) A variety of candlesticks with paraffin wax and insect wax with different composition ratios are made using a cylindrical mold to make candlestick products easy to release. Ignite each candlestick to burn it in a windless state, and put white paper in the candle flame. Close to the ground, then incite the flame with your hands to force the candle to sway and visually check the frequency of soot. The results are shown in Table 1 below. ------------------- --Order --------- line (please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) _ 9-555849 A7 B7

五、發明說明( 表 原料(重量% ) 煙灰產生的頻率 石蠟 昆蟲虫鼠 0 10 0 0 0 0 0 0 2 0 8 0 0 0 0 0 0 4 0 6 0 0 0 0 0 0 6 0 4 0 0 0 0 0 8 0 2 0 0 0 0 8 3 17 〇〇 8 5 15 〇〇 8 8 12 〇〇 9 0 10 〇〇 9 3 7 〇 ' 9 5 5 〇 9 7 3 X 10 0 〇 X (請先閱讀背面之注意事項再填寫本頁) # 訂--- 經濟部智慧財產局員工消費合作社印製 在 表 1 中, 〇 〇 〇 〇〇 :在1 0 0 次以 上 的 試 驗 中 未有 煙 灰 的產 生, 〇 〇 〇 〇 :在1 0 〇 次的 試 驗 中 有 1 一 2 次 的 煙灰 產生 y 〇 〇 〇 :在5 0 次 的試 驗 中 有 1 一 2 次 的 煙 灰 產生 9 〇 〇 :在2 5 次 的試 驗 中 有 1 — 2 次 的 煙 灰 本紙張尺度適用中國國家標準(CNS)A4規格(21〇 x 297公爱)-10- !線_释——------------------ 555849 A7 _ B7 五、發明說明(8 ) 產生, 〇 ·在次的試驗中有1〜2次的煙灰產 生,且 X :在每一次或實質上每一次的試驗中均有 煙灰的產生。 考量: 由表1中所示的結果可以淸楚地看出,當製成蠟燭時 ,煙灰產生的頻率會因昆蟲蠟混入石蠟中而顯著地或突然 地降低。顯現效果的低限係小於5重量%並且若將其他因 素考慮在內時其實際上限似乎爲約6 0重量%.。此外,不 經意地發現以下事實,即,在僅包含石鱲作爲其鱲組份之 蠟燭的例子中,當燭火熄滅時,蠟燭固有之強烈且刺裊的 味道會產生,但是當昆蟲蠟混入石蠟中而製成蠟燭時,此 味道不會產生或者極爲微弱。 試驗例2 (脫模能力及蠟燭硬度) 原料鱲以後述之表2中所示的比率取用,將彼置於燒 杯中並以水浴加熱使之熔化。同其時,將蠟燭用的棉蕊浸 於熔融石鱲中,將彼拉出,並使蠘組份固化而製得附著至 支座的浸鱲棉蕊。支座係中央有小的開口的錫盤’浸蠘棉 蕊通過其中並附著至支座。將具有支座的浸蠟棉蕊附著至 實質上具有半球體構形且其頂部有小孔的模具上。在此情 況中,浸蠘棉蕊係插至模具的孔洞中,所以其自由端多少 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -· I I I - II - ^ 11111111 I II--— — — 1 - I - I - I----I____ 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -11 - 555849 A7 _ B7 五、發明說明(9 ) 會穿出孔洞而形成欲製得之蠟燭的發光部份。然後,將熔 融蜂蠟附著至與浸蠟棉蕊及模具孔洞開口接觸的部份並令 蜂蠟固化以使具有支座的浸蠟棉蕊固定至模具。 將玫瑰香料加至該熔融蠟混合物然後將生成的混合物 施以攪拌,將模具倒置並將熔蠟注入倒置的模具中。在此 情況中,熔蠟的注入量係經過設定,所以熔蠘的表面量多 少變得較支座的底面爲高。當注入模具中之熔蠟的表面發 生固化作用時,模具即移至冰箱中(內部溫度:- 5 t ) 以冷卻並使模具中的蠟完全固化。 其後,自冰箱取出模具並將生成的鱲燭脫模以評估其 脫模能力,即蠟燭是否能容易地脫模。結果示於後述的表 2中。 此外,利用J I S K — 2 2 3 5中所述的方法霉測 生成之蠟燭樣品的穿透以檢視其硬度。其結果亦示於以下 的表2中。 --------*------------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) · ] 2 - 555849V. Description of the invention (Table material (% by weight)) Frequency of soot paraffin insect pests 0 10 0 0 0 0 0 0 2 0 8 0 0 0 0 0 0 4 0 6 0 0 0 0 0 0 6 0 4 0 0 0 0 0 8 0 2 0 0 0 8 3 17 〇〇8 5 15 〇〇8 8 12 〇09 0 10 〇〇9 3 7 〇 9 5 5 〇9 7 3 X 10 0 〇X (please first (Please read the notes on the back and fill in this page again.) # ORDER --- The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is printed in Table 1. 〇〇〇〇〇: No soot has been generated in more than 100 tests. 〇〇〇〇〇: 1 to 2 times of soot production in 100 times of tests y 00: In 50 times of test 1 to 2 times of soot production 9 0: 0 to 2 5 times In the test, there are 1-2 times of soot. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (21〇x 297 public love). ------- 555849 A7 _ B7 Fifth, the invention description (8) was produced, and there were 1-2 times in the test. Ash is produced, and X: Soot is produced in every or substantially every test. Consideration: From the results shown in Table 1, it can be clearly seen that the frequency of soot generation when making candles It may decrease significantly or suddenly due to the mixing of insect wax into paraffin wax. The lower limit of the effect is less than 5% by weight and its practical limit seems to be about 60% by weight when other factors are taken into account. In addition, it is inadvertently The fact was found that, in the case of a candle containing only Shizuku as its hafnium component, when the candle was extinguished, the strong and prickly flavor inherent in the candle was produced, but it was made when insect wax was mixed with paraffin In the case of candles, this taste does not occur or is very weak. Test Example 2 (Release Ability and Candle Hardness) The raw materials were taken at the ratios shown in Table 2 described below, placed in a beaker and heated in a water bath. Melt. At the same time, immerse the cotton core for candles in the molten stone concrete, pull out and solidify the concrete components to make the cotton core that is attached to the support. There is a small core in the center of the support. Open tin plate 'impregnated cotton The core passes through and attaches to the support. The wax-impregnated cotton core with the support is attached to a mold that has a substantially hemispherical configuration and a small hole on its top. In this case, the dipped cotton core is inserted into the hole of the mold, so how much is the free end (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-· III-II -^ 11111111 I II -----1-I-I-I ---- I____ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -11-555849 A7 _ B7 V. Description of the invention (9) The hole will be penetrated to form the luminous part of the candle to be made. Then, the molten beeswax is attached to a portion in contact with the wax-impregnated cotton core and the opening of the mold hole, and the beeswax is cured to fix the wax-impregnated cotton core with a support to the mold. Rose fragrance was added to the molten wax mixture and the resulting mixture was stirred, the mold was inverted and the molten wax was poured into the inverted mold. In this case, the injection amount of the molten wax is set, so that the amount of the surface of the molten wax becomes higher than the bottom surface of the support. When the surface of the molten wax injected into the mold solidifies, the mold is moved to the refrigerator (internal temperature:-5 t) to cool and completely solidify the wax in the mold. Thereafter, the mold was taken out of the refrigerator and the resulting candlestick was demolded to evaluate its demolding ability, that is, whether the candle can be demolded easily. The results are shown in Table 2 described later. In addition, the penetration of the resulting candle sample was measured by the method described in J I S K-2 2 3 5 to check its hardness. The results are also shown in Table 2 below. -------- * ------------ Order --------- line (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs The paper size printed by the employee consumer cooperative is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) ·] 2-555849

L7t A C 五、發明說明(1〇 ) ^_2 蠟及香料(重量%〕 脫模能力 穿透(2 5 °C ) 石蠟 昆蟲蠟 香料 4 0 6 0 0 〇 8 . 8 4 0 6 0 6 〇 11.6 4 0 6 0 10 〇 12.8 1〇〇 0 0 Δ 12.1 市售產品A Δ 18.8 市售產品B X 3 1.0 (請先閱讀背面之注意事項再填寫本頁) 螓 經濟部智慧財產局員工消費合作社印製 在表2中, 〇·谷易脫模, △:脫模有些困難,且 X :蠟燭無法自模具中拉出。 , 考量或評估: 藉混入昆蟲蠟製得的蠟混合物具有低穿透及足夠的硬 度而易於實施脫模操作及後續的拔出或拉出操作而製得所 欲的蠟燭產品’即使液體香料係以1 〇重量%的量混至鱲 組份中。含有昆蟲鱲的蠟其脫模能力較石蠟及市售芳香蠟 燭中的蠟組成物者爲佳。 此外,經由其他試驗亦確認如果芳香蠟燭僅使用包含 液體香料的石蠟,且利用脫模法製得,則香料相對於石蠟 的量僅止於約5 - 6重量%,不然,鱲燭的硬度會變得太 低而在欲形成之蠟燭中引發變形或者一部份的蠘會殘留模 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -13- 一-οτ I ϋ .^1 I I ^1 ϋ I ϋ *ϋ I n ϋ I i l^i I n i^i ϋ ϋ . 555849 A7 B7 五、發明說明(11 ) (請先閱讀背面之注意事項再填寫本頁) 具的內表面上,在任一種情況中,所欲的芳香蠟燭產品均 無法製得。意指含有大量液體香料的石蠟並不適合以模塑 法來製造芳香鱲燭因此其應該注入玻璃或陶瓷容器或瓶中 並將彼和容器一同促銷。 試驗例3 (連續燃燒試驗) 製得石蠟與昆蟲蠟間有不同組成比的多種蠟燭(各蠟 燭樣品的重量:2 0克,構形:半球體)。將各鱲燭點燃 並使之連續燃燒以觀察構形隨時間的變化並量測總連續燃 燒時間直到其蕊心燃盡(當蠟燭自然燃盡時,立即將其再 點燃)。蠟的組成比及累積燃燒時間示於下表3中。 m_3 原料(重量%) 累積燃燒時間(分鐘) 石蠘 昆蟲!fe 〇 10 0 2 6 0 2 0 8 0 2 4 0 4 0 6 0 2 3 0 6 0 4 0 19 0 8 0 2 0 17 0 10 0 0 16 0 經濟部智慧財產局員工消費合作社印製 考量: 當蠟燭含有大量的昆蟲蠘時’累積燃燒時間變長。在 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)-14 _ 經濟部智慧財產局員工消費合作社印製 555849 A7 _ B7 五、發明說明(12 ) 不含昆蟲蠟之鱲燭樣品的例子中,當試驗結束時,其代表 熔蠟以小量殘存的狀態並且完全不具原有的形狀,但是, 在含有昆蟲蠟之蠟燭樣品的例子中,其外殼部份傾向在不 引起熔化的情況下殘留,更特定言之,在不含石蠟之鱲燭 樣品的例子中,外殼部份實質上維持其原有的形狀並展現 類似碗的構形。 實例1 秤取石蠟(6 0克)及昆蟲蠟(4 0克),將蠟置於 燒杯中並以水浴加熱使其熔化。同其時,將鱲燭用的棉蕊 浸於熔融石蠘中,然後利用如試驗例2中的方式製得浸蠟 棉蕊。將浸蠟棉蕊切成數段,將各蕊段附著至支座,再將 具有支座的蕊段固定至實質上具有半球體構形的不鏽_模 具上。 將玫瑰香料(3或6克)及紅色著色劑(3 · 2毫升 )或藍色著色劑(6 · 4毫升)加至熔蠟混合物並攪拌之 ,將生成的混合物注入各模具中。將模具移至冰箱中以使 模具中的鱲完全固化然後實施脫模即製得所欲的含有玫瑰 香料之半球體蠘燭(各蠟燭的重量:15克)。 各個蠟燭具有細緻的淡粉色或藍色色調並且無不規則 色調的部份而顯現透明的感覺。 實例2 重覆實例1中所述的流程,但是此處選用薰衣草香料 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)-15- ---------------------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 555849 A7 ~-_ B7 五、發明說明(13) (3或6克)及紫色著色劑(5 · 13毫升,混合 2 · 3 7毫升紅色著色劑及2 · 7 6毫升藍色著色劑而得 ’但是當使用3克香料時,不加入著色劑),並製得所欲 的含有薰衣草香料之蠟燭。生成的蠟燭具有純白色色調或 淡紫色色調。 實例3 重覆實例1中所述的流程,但是此處選用玫瑰或薰衣 草香料(各1 0克)及綠色或黃色著色劑(各3 · 2毫升 ),並製得所欲的含有玫瑰或薰衣草香料之蠟燭。生成的 蠟燭具有淡綠色或淡黃色色調。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -16-L7t AC V. Description of the invention (1〇) ^ _2 Wax and fragrance (wt%) Release ability penetration (25 ° C) Paraffin insect wax fragrance 4 0 6 0 0 8. 8 4 0 6 0 6 0 11.6 4 0 6 0 10 〇12.8 1〇00 0 0 Δ 12.1 Commercially available product A Δ 18.8 Commercially available product BX 3 1.0 (Please read the precautions on the back before filling this page) 消费 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In Table 2, Gu Yi is easy to demold, △: It is difficult to demould, and X: The candle cannot be pulled out of the mould., Consider or evaluate: The wax mixture made by mixing insect wax has low penetration and sufficient It is easy to carry out the demolding operation and subsequent pull-out or pull-out operation to obtain the desired candle product 'even if the liquid fragrance is mixed into the pupa component in an amount of 10% by weight. The wax containing insect pupa is The mold release ability is better than those in paraffin and commercially available aromatic candles. In addition, it has been confirmed through other tests that if the aromatic candle uses only paraffin containing liquid flavors and is produced by the demolding method, the fragrance is better than paraffin. Amount only ends at about 5-6% by weight Otherwise, the hardness of the candlestick will become too low to cause deformation in the candle to be formed, or a part of the candlestick will remain. The paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm)- 13- 一 -οτ I ϋ. ^ 1 II ^ 1 ϋ I ϋ * ϋ I n ϋ I il ^ i I ni ^ i ϋ ϋ. 555849 A7 B7 V. Description of the invention (11) (Please read the precautions on the back first (Please fill in this page again) On the inner surface of the tool, in any case, the desired scented candle product cannot be made. It means that paraffin containing a large amount of liquid flavor is not suitable for molding scented candle by the molding method, so it should be injected Glass or ceramic container or bottle and promote them together with container. Test Example 3 (Continuous Burning Test) Various candles with different composition ratios between paraffin and insect wax were prepared (weight of each candle sample: 20 grams, configuration : Hemisphere). Ignite each candle and burn it continuously to observe the change of the configuration over time and measure the total continuous burning time until its core burns out (when the candle burns out naturally, immediately relight it) The composition ratio and cumulative burning time of the wax are shown in In the following table 3. m_3 Raw material (% by weight) Cumulative burning time (minutes) Stone bug insect! Fe 〇 10 0 2 6 0 2 0 8 0 2 4 0 4 0 6 0 2 3 0 6 0 4 0 19 0 8 0 2 0 17 0 10 0 0 16 0 Print considerations for the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs: When the candle contains a large number of insect pupae, the 'cumulative burning time becomes longer. Applicable to China Paper Standard (CNS) A4 (210 X 297 mm) on this paper scale -14 _ Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperative 555849 A7 _ B7 V. Description of the invention (12) No insect wax In the case of the candle sample, when the test is over, it represents a state where the molten wax remains in a small amount and does not have the original shape at all. However, in the case of the candle sample containing the insect wax, the shell portion tends to not cause It remains in the melted state, and more specifically, in the example of a candlestick sample that does not contain paraffin, the shell portion substantially maintains its original shape and exhibits a bowl-like configuration. Example 1 Paraffin wax (60 g) and insect wax (40 g) were weighed out. The wax was placed in a beaker and heated in a water bath to melt it. At the same time, the cotton stamens for candlesticks were immersed in molten stone slag, and then the cotton dipped wax staves were prepared in the same manner as in Test Example 2. The wax-impregnated cotton core was cut into several sections, each core section was attached to a support, and the core section having the support was fixed to a stainless mold having a substantially hemispherical configuration. Rose perfume (3 or 6 g) and red colorant (3.2 ml) or blue colorant (6.4 ml) were added to the molten wax mixture and stirred, and the resulting mixture was poured into each mold. The mold was moved to a refrigerator so that the urn in the mold was completely cured, and then demolding was performed to obtain a desired hemisphere candle with a rose flavor (the weight of each candle: 15 g). Each candle has a delicate pale pink or blue hue, and there is no irregular hue portion, and it appears transparent. Example 2 The process described in Example 1 was repeated, but the lavender flavor was selected here. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -15- ---------- ----------- Order --------- line (please read the notes on the back before filling this page) 555849 A7 ~ -_ B7 V. Description of the invention (13) (3 Or 6g) and purple colorant (5.31ml, mixed with 2.37ml of red colorant and 2.7.6ml of blue colorant ', but when 3g of fragrance is used, no colorant is added), And make the desired candle containing lavender spices. The resulting candle has a pure white or lilac tint. Example 3 The procedure described in Example 1 was repeated, but rose or lavender flavors (10 g each) and green or yellow colorants (3.2 ml each) were selected here, and the desired rose or lavender flavor was prepared. Candles. The resulting candle has a pale green or yellowish hue. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -16-

Claims (1)

555849 .一 --—.-一 •… -以二 公 ^ & C8 J —J D8 六、申讀專利範圍 一..............-,Λ.:Γί 舰·故· 方丨 /fill L___— 第89106905號專利申請案 中文申請專利範圍修正本 民國92年4月16日修正 1 · 一種無煙蠘燭,其包含作爲蠘組份之石蠟及由白 蠟蟲(万peh)所得之昆蟲蠟,其中,該昆蟲蠟在蠟 組份中的量爲5 — 6 0重量%。 2 ·如申請專利範圍第1項之無煙蠘燭,其中,每 1 0 0克的蠘組份尙包含3 _ 1 0克的香料。 3 ·如申請專利範圍第1項之無煙蠘燭,其中,該繼 燭尙包含著色劑。 4 ·如申請專利範圍第2項之無煙蠊^ _ 厕,其中,該香 料係液體。 ^IT (請先聞讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製555849. 一 --—.- 一 •… -Twenty-two ^ & C8 J —J D8 6. Scope of patent application I ..............-, Λ .: Γί Jian · Fang Fang 丨 / fill L ___— Patent Application No. 89106905 Chinese Patent Application Amendment Amendment April 16, 1992 Amendment 1 · A smokeless candlestick containing paraffin wax as a puppet component and a white wax insect ( 10,000 peh) of the obtained insect wax, wherein the amount of the insect wax in the wax component is 5 to 60% by weight. 2. The smokeless candle of item 1 in the scope of the patent application, wherein each 100 grams of 蠘 component 尙 contains 3 -10 grams of spices. 3. The smokeless candlestick according to item 1 of the patent application scope, wherein the relay candlestick contains a colorant. 4 · Such as the smoke-free toilet ^ _ latrine in the scope of patent application, wherein the fragrance is liquid. ^ IT (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
TW089106905A 1999-09-14 2000-04-13 Smokeless candle TW555849B (en)

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JP26095799A JP3387863B2 (en) 1998-11-20 1999-09-14 Smokeless candle

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MXPA03003910A (en) * 2000-11-02 2003-10-15 Honeywell Int Inc Vegetable-based compositions and articles, and methods of making same.
KR100750205B1 (en) * 2006-05-11 2007-08-17 이란형 A beeswax candle having nature fragrance and method of manufacture thereof
CN102499187A (en) * 2011-11-10 2012-06-20 中国林业科学研究院资源昆虫研究所 Method for alternately breeding wax insects outside cages
KR102023481B1 (en) 2018-04-25 2019-09-20 임승만 Variable Stopper Apparatus For Window

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US3898039A (en) * 1972-06-15 1975-08-05 Tong Joe Lin Article having fumigant containing substrate for diffusion promoting candle
SU840094A1 (en) * 1979-09-17 1981-06-23 Всесоюзный Научно-Исследовательскийи Проектный Институт Химическойпромышленности Candle
US5837763A (en) * 1995-06-07 1998-11-17 Amcol International Corporation Compositions and methods for manufacturing waxes filled with intercalates and exfoliates formed with oligomers and polymers
HU220713B1 (en) * 1998-03-16 2002-04-29 Gábor Ruzsonyi Full valve biocandle with high beewax content
US6106597A (en) * 1998-12-18 2000-08-22 Milliken & Company Wax compositions comprising fatty ester poly(oxyalkylenated) colorants
US6022402A (en) * 1998-12-18 2000-02-08 Stephenson; Eugene Kyle Wax compositions comprising alkenyl succinic anhydride-capped poly (oxyalkylenated) colorants

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EP1085078A3 (en) 2001-04-11
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KR20010029639A (en) 2001-04-06
EP1085078A2 (en) 2001-03-21
KR100652174B1 (en) 2006-11-29
DE60011000T2 (en) 2005-06-09
DE60011000D1 (en) 2004-07-01
CN1166755C (en) 2004-09-15

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