TW520331B - Recording material - Google Patents

Abstract

A recording material is characterized in that it has a substrate and an ink-receiving layer formed thereon, the substrate having a thickness of 38 to 200 μm, the ink-receiving layer containing a particle and a resin and being a porous layer having a thickness of 40 μm to 105 μm, the recording material having a curl value of less than +10 mm, and a recording material is characterized in that the surface strength of ink-absorbing layer is more than 80 gw/cm. The recording material is useful for ink jet printing in oil ink. A picture excellent in sharpness and water-resistance can be obtained. Curling rarely occurs even if it is under a circumstance that the humidity and temperature vary tremendously, and a stabilized recording material is ensured during transportation.

Description

520331 五、 發明說明 ( 1 ) [ 技 術 領 域 ] 本 發 明 係 有 關 一種 適 合 各 種 記 錄 方 式 之 記 錄 材料 〇 詳 言 之 ， 係 有 關 一 種無 論 在任 何 環 境 下 仍 可 安 定 地 連 續 印 刷 之 記 錄 材料 〇 更 詳 言 之 7 係有關 於 適 合 噴 墨 記 錄 方 式 之 記 錄 材料 ， 即 使 用 油 性 油 墨 之噴 墨 記 錄 方 式 中 即 使在 筒 溫 多 濕 及 低 溫 低 濕 下 等 仍 可安 定地 連 續 印 刷 之 記 錄 材料 〇 ( 先 刖 技 術 ) 近 年 來 ， 電 腦 之性 能 提 筒 及 電 腦 之 普 及 且 硬 體 影 印 技 術 急 速 發 展 〇 硬體 影 印 之 記 錄 方 式有 昇 華 影 印 記 錄 方 式 Λ 電 子 影 像 方 式、 噴 mzf 墨 方 式 等 之 方 式係 爲 已 知 〇 藉 由 噴 墨 方 式 之影 印 機 係 白 噴 嘴 朝 向 記 錄 材料 高 速 噴 射 油 墨 液 滴 以 形 成畫 像 方 式 之 影 印 機 〇 該 方 式 之 影 印 機 由 於 易 於彩 色 化 、小 型 化 、 且 印 字 噪 低 y 故 做 爲 辦 公 室 用 或 家 庭 用 等 文字 處 理 機 之 印 刷 終 贿 裝 置 於近年來 急 速 普 及化 〇 另 外， 由 於 接 近 銀 鹽 相 片 之記 錄 品 質 佳 、 溶 液 予 以 大 型 化 ，故 期 待 應 用 於大 型 看 板 海 報 > 電 飾 看 板 等 之 作 成 用 影印 機 等 產 業 範 圍 〇 其 中 ) 亦注 使用 於 白 後 方 照 射 光 予以 鑑 賞 的 電 飾 〇 噴 墨 方 式所使 用的 油 rrpr 墨 爲 水性 染 料油 Em 垂 J 即 在水或 親 水性 溶 劑 之 混 合 溶劑 中 溶 解 各 種 水 溶 性 染 料 且 視 其 所 而 混 合 有 各 種 添 加劑 者 爲 主 流 〇 此 係水性油 墨 可 以 色 調 思牛 明 地 記 錄 ， 易 於調 整 油 tsnj 墨 之 -3. 黏 度 溶 劑 不 易 發 臭 5 就 520331 五、發明說明（2) 安全性而言極爲優異。 以在載體上設有水溶性樹脂者來改善染料油墨之耐水 性、耐候性不佳的缺點方法有各種提案（於日本特開昭 5 - 1 243 3 1號公報）。然而，無法發揮可在野外展示的性 能，且爲防止表面上因紫外線使染料變色的情形故必須 貼附紫外線吸收性積層薄膜，結果會造成成本提高的問 題產生。 爲彌補水性染料油墨之缺點，提案有使水性顏料油墨 即有機顏料、無機顏料分散於水或水與親水性溶劑之混 合溶劑中，且視其所需添加有各種添加劑之油墨。爲使 用水性油墨之記錄時，若印刷後充分乾燥記錄材料時可 得完全的耐水性，近年來急激使用此種。然而，由於使 用水做爲主溶劑，無法提高顏料之濃度，發色性且鮮明 度不佳，易產生噴嘴頭部阻塞等問題。 爲解決此等問題的方法，提案使用油性油墨之噴射方 式。油性油墨爲使油溶性染料、有機顏料、無機顏料等 溶解或分散於鏈烯類、醚類、醇類等溶劑中，與水性染 料油墨、水性顏料油墨比較時，染料、顏料之選擇範圍 可達自廣泛的耐候性、耐水性優異的色材，由於在溶劑 中可以高濃度溶解或分散，可實現高畫像濃度，噴嘴頭 不會有阻塞情形，不會因片板之吸收而引起旋塞情形， 可降低油墨之表面張力，可提高記錄材料中之浸透性等 優點。因此，企求在必須具有高速印刷、高畫質印刷、 高耐候性之範圍內代替水性油墨。該適於油性油墨之記 -4- 五、發明說明（3 ) 錄材料於特開平3 - 1 3 3 68 7號公報中亦有提案。 另外，記錄材料對水性染料油墨即水性顏料油墨而言 可滿足記錄品質者有各種提案。例如，在載體上設有含 顏料與樹脂之多孔質層者、在透明載體上設有不透明的 谷受層（油墨容受層），自記錄有畫像之面與反對面鑑賞 的後端印刷方式（特開昭6 1 - 3 5 2 7 5號），另外提案有爲提 高耐水性、滲色等之性能之各種添加劑。 然而，上述公報中所揭示的記錄材料係爲水性染料或 任何設計做爲水性顏料用者，使用於以油性油墨記錄時 並不一定可得良好的記錄。此係適合水性油墨之記錄材 料的油墨容受層構成材料，由於會吸收油墨中之水故一 般使用水溶性樹脂或吸水性樹脂，惟水溶性樹脂、吸水 性樹脂也不一定爲具溶劑之吸收性能，而水性油墨係油 墨中之染料或顏料具有電荷或因主溶劑爲水之故具有高 表面張力等特性，與油性油墨有差別而有不同的特性。 因此，沒有可使油性油墨之性能爲最大極限的記錄材料 存在。另外’使用吸水性佳之樹脂做爲油墨容受層構成 材料的適合水性油墨之記錄材料，會因濕度變化而使吸 水性樹脂之吸水率變大，樹脂本身會產生體積變化的結 520331 五、發明說明（4) 果，記錄材料會引起捲曲情形’且在高溫多濕下或低溫 低濕下由於捲曲情形，會使記錄材料之處理產生困難， 於畫像連續印刷時印表機內用紙搬送容易性產生問題。 〔發明所欲解決的問題〕 本發明之目的係以提供適合噴墨記錄方式之記錄材 料。尤其是提供適合使用具有下述特性之油性油墨的噴 墨記錄方式之記錄材料爲目的。 1 ·即使在高溫多濕下、低溫低濕下，仍不會產生捲曲情 形、進行安定的處理或搬送，且不會滲透、可得鮮明 記錄，耐水性良好的畫像之記錄材料。 2 ·可作成在野外展示程度之耐水性、尤其是耐水濃度保 持性能優異之記錄物的記錄材料。 3 .使用做爲電飾看板時可得畫像濃度高、發色性優異的 高晝質且耐水性良好的記錄材料，尤其是不僅於電飾看 板點燈時且於熄燈時，皆可得優異畫像之記錄材料。 〔解決問題的手段〕 本發明人等爲使油性油墨之性能發揮至最大極限，再 三進行深入硏究的結果，發現在基材上設有油墨容受層. 之記錄材料，藉由特定上述基材與油墨容受層之厚度， 520331 五、發明說明（5) 且使上述容受層爲多孔質層之構成，於使用油性油墨之 噴墨記錄方式中不會有滲透情形、可予以鮮明地記錄， 同時可得形成耐水性佳的畫像之記錄材料，即使在高溫 多濕下及低溫低濕下等嚴酷的環境條件下仍不易引起捲 曲情形，可得可安定地連續印刷之記錄材料。 於本發明之記錄材料中，做爲油墨容受層中粒子的黏 接材料之樹脂，較佳者係藉由使用非吸水性樹脂以具有 良好的耐水性，另外藉由使多孔質層之厚度在一定的範 圍內可具有對油性油墨而言良好的記錄品質，同時即使 在高溫多濕的環境、低溫低濕環境下因水之吸收、放 出’僅有稍許的體積變化，故可得積層於基材上亦不會 有捲曲情形之記錄材料。 本發明藉由黏接劑之樹脂爲非吸水性熱塑性樹脂，可 形成具優異耐水性之多孔質的油墨容受層，且可抑制記 錄材料之捲曲情形。換言之，記錄材料之捲曲値必須在 + 10mm以下，較佳者爲+8mm以下。 此處之捲曲値爲l〇mm以下係指切出二張20cmX20cm 之記錄材料評估試樣，在台紙上使一張評估試樣置於油 墨容收層側下，另一張則置於油墨容受層側上的狀態 520331 五、發明說明（6) 下，各在 20°C /60%RH、15°C /20%RH、30°C /80%RH 之環境 下放置24小時，在白紙之4角高度上最大値爲l〇mm以 下。此時，油墨容受層側爲內側時經捲曲者爲正値，油 墨容受層側爲外側時經捲曲者爲負値。 若捲曲値大於1 Omm時，噴墨針頭之搬送性不佳，會發 生無法印刷的問題。 另外，在基材上設有油墨容受層之記錄材料中，藉由 印刷全黑色時透過之發色濃度T與反射之發色濃度R 之關係滿足下式，自背面透光予以觀看時或在熄燈的狀 態下觀看時，由於仍呈現鮮明的畫面，故可使用於電飾 用途。 1.20XR ^ T ^ 1.70XR 於上式中透過之發色濃度（T )與反射之發色濃度（R )係使 用馬克倍斯（譯音）濃度劑TR- 927予以測定。而且，全 黑係使用歐林怕斯（譯音）光學工業公司製噴墨印表機 JP- 3 600及純正得油性顏料油墨以半721 dpi型予以 K 100%印刷。 (基材） 該基材之厚度爲38〜200// πι，較佳者爲50〜188// ni。 520331 五、發明說明（7) 若基材之厚度小於3 8 // Π1時基材之剛性不足且油墨容受 層會有稍許膨脹、縮小等之尺寸變化情形，因而引起打 摺或捲曲的惰形，而若大於200 // m時會因油墨容受層之 尺寸變化而使記錄材料變形，不僅會使成本增加且會降 低其柔軟性而造成處理困難。 本發明基材的材質沒有特別的限制，於印刷後使記錄 材料貼附於牆壁等時，以使用看不見底料之不透明基材 較佳，自電飾看板等之背面照射光線時以使用透明性基 材較佳。 透光性基材例如有聚酯系、聚苯乙儲系、聚丙烯、聚 醯胺系、聚碳酸酯、聚原菠烯、維尼龍、丙烯酸系等之 薄膜或片板（以下稱爲片板時亦包含薄膜之意）、玻璃及 此等任意2種以上之貼合者，以耐熱性、柔軟性優異且 透明的聚酯系樹脂片板、薄膜較佳。於聚酯系樹脂中 尤以透明性、強度、油墨容受層之密接性、且成本較低 之聚對苯甲酸乙烯酯（PET )更佳。 使用於電飾看板時，基材以透光性較佳，該透光性基 材之較佳透明度以J I S K 7 1 05爲基準所測定的全光線透 過率爲85%以上。若全光線透過率小於85%時，自印刷畫 像背面照射光線時無法得到畫像十分鮮明的問題。 聚酯系樹脂片板不是僅限於使用習知之聚酯系樹脂片 板，惟於本發明中可使用對苯甲酸、異苯甲酸、萘二羧 酸之芳香族二羧酸或其酯與二乙醇、二乙二醇、1，4 -丁 二醇、辛戊醇等之醇類聚縮合予以製得的聚酯樹脂爲主 520331 五、發明說明（8) 成份之樹脂片板。 本發明中透明性基材所使用的聚酯系樹脂片板係以使 用至少一種上述樹脂以一軸方向拉伸之片板較佳。藉由 拉伸不僅可提高強度且對成本有利。 聚酯系樹脂片板之拉伸方法例如有管狀法拉伸、同時 二軸拉伸、逐次二軸拉伸等，沒有特別的限制，惟就平 面性、尺寸安定性良好、厚度斑點情形少等而言以逐次 二軸拉伸較佳。藉由逐次二軸予以拉伸之具體例如長度 方向在聚酯之玻璃轉移溫度之+0〜+30°C下以2 . 0〜5 . 0 倍輥拉伸，然後在120〜15(TC下以1 · 2〜5 · 0倍之倍率 拉幅器拉伸。另外，於拉伸後在220°C以上進行3〜8%緩 和且熱固定的方法。 本發明之記錄材料所使用的透明性基材可以基層二種 以上之層即複合薄膜。該複合薄膜之製法係爲習知複合 薄膜之製法，沒有特別的限制。然而考慮生產性時，以 使構成各層複合薄膜之原料分別自各押出機押出，且導 入一個塑模中予以積層，製得樹脂混合物之未拉伸片板 後’至少朝一軸拉伸，即藉由共押出法予以積層最佳。 於本發明中對於不透明基材沒有特別的限制，例如有聚 酯系、聚苯乙烯系、聚丙烯、聚醯胺、聚碳酸酯、聚原 疲烯、維尼龍、丙烯酸系等塑膠薄膜或片板或於此等之 材料中混合有無機材料、發泡劑之不透明樹脂薄膜、聚 酯系布、聚酯/棉混合布、棉布、不織布、紙漿、樹脂 含浸紙、鑄模塗覆紙、樹脂塗覆紙、玻璃紙及此等之 -10- 520331 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（） 任意二種以上者，較佳者為耐熱性、柔軟性優異的不透 明聚酯糸合成紙。較佳的不透明度偽全光線透過率為60% 以下。若全光線透過率大於6 0 %時，不透明性不佳且於 阽附於牆壁時會有看見内裏的問題産生。 本發明之不透明基材以非多孔質較佳。可防止油墨浸 透至基材或油墨中浸透溶劑，結果可防止基材強度降低 、印刷後記錄材料重疊、於保存時内部移動的問題。而 且，非多孔質含有即使内部有很多空洞而於外部沒有開 口的材質之意。 聚酯条合成紙係為習知的聚酯合成紙，沒有特別的限 制，於本發明中尤以使如對苯甲酸、異苯甲酸、萘二羧 酸之芳香族二羧酸或其酯與乙二醇、二乙二醇、1，4 -丁 二醇、新戊醇等之醇類聚縮合所製造的在聚酯樹脂内部 形成空洞的不透明薄膜之含有空洞的聚酯条合成紙更佳。 於上述含有空洞的聚酯条合成紙中發現空洞的方法係 以習知的方法，没有特別的限制，惟較佳者為藉由使下 述之在聚酯中混合、熔融有非相溶的熱塑性樹脂、經押 出的為拉伸片板予以至少一軸方向拉伸，在内部形成很 多微細空洞的方法。 -於該空洞形成方法所使用的聚酯中非相溶性熱塑性樹 脂，具體例如聚苯乙烯条樹脂、聚烯烴条樹脂、聚丙烯 酸条樹脂、聚磺酸酯条樹脂、聚碼条樹脂、纖維素条樹 脂等。尤以使用聚苯乙烯条樹脂、聚甲基戊烯、聚丙烯 等之聚烯烴糸樹脂較佳。 -1 1- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂---------線0. 520331 A7 B7 五、發明說明（ 10 脂熔使 樹機機 之出練 脂押混 樹以由 性且藉 塑條先 熱脂預 性樹使 溶各 ， 相合法 非混方 有如的 合例化 混，硬 中板 、 酷片出 聚伸押 在拉以 與為予 酯的後 聚物練 使合混 混融 於，等 ，脂法 法樹方 方性的 的塑化 化熱硬 一彐/ 硬 / 、溶出 出相押 押非融 融加熔 熔添條 機中脂 出酯樹 押聚的 由在得 藉中製 另程散 者工分 練合拌 混聚攪 脂之以 樹酯予 兩聚且 向中 配酯 弱聚 或於 向偽 配脂 無樹 為性 常塑 通熱 ，性 板溶 片相 伸非 拉酯 為聚 的與 得 ， 所且 化而 硬 ❶ 〇 者 造態 製狀 在目 ， 存視佳 態量較 型之ί 的脂 散樹 分性 狀塑 形熱以 種性中 各溶體 等相全 狀非物 絲酯合 或聚混 、 與於 狀的 ， 球合同 圓混不 橢所而 或中量 狀酯洞 球聚空 以 的 - 3520331 V. Description of the invention (1) [Technical Field] The present invention relates to a recording material suitable for various recording methods. Specifically, it relates to a recording material that can be continuously and stably printed in any environment. More detailed No. 7 is a recording material suitable for inkjet recording. Even in the inkjet recording method using oil-based ink, the recording material can be continuously and stably printed even at a cylinder temperature and humidity, low temperature and low humidity. (Advanced technology ) In recent years, the performance of computers and the popularity of computers and the rapid development of hardware photocopying technology. The recording methods of hardware photocopying include sublimation photocopying recording methods Λ electronic image method, spray mzf ink method, etc. are known. High-speed jet of oil from the white nozzle of the inkjet printer to the recording material A photocopier in which droplets form an image. This type of photocopier is easy to colorize, miniaturize, and has low printing noise. Therefore, it has become a popular printing device for word processors such as office and home use in recent years. In addition, due to the high recording quality of close to silver salt photographs and the large size of the solution, it is expected to be used in industries such as photocopying machines for the production of large-scale kanban posters and electrical signboards, etc., among which are also used for white rear irradiation Electric decoration that is appreciated by light. The oil rrpr ink used in the inkjet method is a water-based dye oil Em, which means that various water-soluble dyes are dissolved in a mixed solvent of water or a hydrophilic solvent, and various additives are mixed depending on the type. Mainstream 〇 This series of water-based inks can be recorded in vivid colors, easy to adjust the oil tsnj ink-3. Viscosity solvent is not easy to smell 5 just 520331 Described invention, (2) extremely excellent in terms of safety. Various proposals have been made to improve the shortcomings of water resistance and poor weather resistance of dye inks by using a water-soluble resin on the carrier (Japanese Patent Application Laid-Open No. 5-1 243 31). However, it cannot exhibit the performance that can be displayed in the field, and in order to prevent the dye from being discolored by ultraviolet rays on the surface, it is necessary to attach an ultraviolet absorbing laminated film, which results in a problem of increased cost. In order to make up for the shortcomings of water-based dye inks, water-based pigment inks, that is, organic pigments and inorganic pigments are dispersed in water or a mixed solvent of water and a hydrophilic solvent, and various additives are added as needed. In order to use water-based ink for recording, if the recording material is sufficiently dried after printing, complete water resistance can be obtained, and in recent years, such use has been urged. However, because water is used as the main solvent, the concentration of the pigment cannot be increased, the color developability and brightness are not good, and problems such as clogging of the nozzle head are easy to occur. In order to solve these problems, it is proposed to use an ink jet method. Oil-based inks are used to dissolve or dissolve oil-soluble dyes, organic pigments, inorganic pigments, etc. in solvents such as olefins, ethers, and alcohols. Compared with water-based dye inks and water-based pigment inks, the choice of dyes and pigments can reach Since a wide range of weathering and water-resistant color materials can be dissolved or dispersed in a high concentration in a solvent, a high image density can be achieved, the nozzle head will not be blocked, and the plug will not be caused by the absorption of the plate. It can reduce the surface tension of the ink and improve the permeability of the recording material. Therefore, it is desired to replace water-based inks within a range that requires high-speed printing, high-quality printing, and high weather resistance. The note for oil-based inks -4- V. Description of the Invention (3) The recording materials are also proposed in JP-A-H 3-1 3 3 68 7. Various proposals have been made for recording materials that satisfy the recording quality for aqueous pigment inks, that is, aqueous pigment inks. For example, if a porous layer containing pigment and resin is provided on a carrier, an opaque valley receiving layer (ink receiving layer) is provided on a transparent carrier, and a back-end printing method for recording the appreciation of the image side and the opposite side is used. (Japanese Patent Application Laid-Open No. 6 1-3 5 2 7 5) In addition, various additives have been proposed to improve water resistance and bleeding. However, the recording materials disclosed in the above publications are water-based dyes or anyone designed to be used as a water-based pigment, and when used with oil-based inks, recording may not be good. This is an ink-receiving layer constituting material suitable for recording materials of water-based inks. Water-soluble resins or water-absorbent resins are generally used because they absorb water in the ink, but water-soluble resins and water-absorbent resins are not necessarily solvent-absorbing. Performance, while water-based inks are dyes or pigments that have a charge or have high surface tension because the main solvent is water, which is different from oil-based inks and has different characteristics. Therefore, there is no recording material which can maximize the performance of the oil-based ink. In addition, 'using a water-absorbent resin as a material for the ink-receiving layer as a recording material suitable for water-based inks, the water absorption of the water-absorbent resin will increase due to changes in humidity, and the resin itself will produce a volume change. 520331 V. Invention Explanation (4) As a result, the recording material will cause curling, and it will be difficult to handle the recording material due to curling under high and high humidity or low temperature and low humidity. It is easy to transport the paper in the printer when the image is continuously printed. cause problems. [Problems to be Solved by the Invention] An object of the present invention is to provide a recording material suitable for an inkjet recording method. In particular, it is an object to provide a recording material suitable for an ink jet recording method using an oil-based ink having the following characteristics. 1 · Even under high temperature and humidity, low temperature and low humidity, there is no curling, stable handling or transportation, and it does not penetrate, can obtain sharp records, and is a recording material for portraits with good water resistance. 2 · It can be used as a recording material for recording objects exhibiting a degree of water resistance in the field, especially excellent in water resistance. 3. When used as an electric decoration signboard, a recording material with high image density, excellent color development and high daytime quality and good water resistance can be obtained, especially not only when the electric decoration signboard is turned on but also when it is turned off. Recording materials for portraits. [Means for Solving the Problem] In order to maximize the performance of the oil-based ink, the present inventors repeatedly researched and found that a recording material is provided with an ink-receiving layer on the substrate. By specifying the aforementioned base, The thickness of the material and ink receiving layer, 520331 V. Description of the invention (5) The above-mentioned receiving layer is made of a porous layer, and there will be no penetration in the inkjet recording method using oily ink, which can be clearly At the same time, recording materials that can form portraits with good water resistance can be obtained. Even under severe environmental conditions such as high temperature and humidity and low temperature and low humidity, curling is not easy to cause, and recording materials that can be continuously and stably printed can be obtained. In the recording material of the present invention, as the resin of the adhesive material for the particles in the ink receiving layer, it is preferable to use a non-water-absorbent resin to have good water resistance, and also to make the thickness of the porous layer In a certain range, it can have good recording quality for oil-based inks. At the same time, even in high-temperature and humid environments, low-temperature and low-humidity environments, there is only a slight volume change due to water absorption and release, so it can be laminated in There is also no recording material with curl on the substrate. In the present invention, the resin of the adhesive is a non-water-absorbing thermoplastic resin, which can form a porous ink-receiving layer having excellent water resistance, and can suppress curling of the recording material. In other words, the curl of the recording material must be +10 mm or less, preferably +8 mm or less. Here, the curl is less than 10mm, which means that two 20cm × 20cm evaluation samples of recording material are cut out. One evaluation sample is placed on the paper under the ink receiving layer side, and the other is placed in the ink container. State on the side of the receiving layer 520331 5. In the description of the invention (6), each is left for 24 hours in an environment of 20 ° C / 60% RH, 15 ° C / 20% RH, 30 ° C / 80% RH, and on white paper The maximum height at 4 corners is 10 mm or less. At this time, the curled side is positive when the ink receiving layer side is inside, and the curled side is negative when the ink receiving layer side is outside. If the curl is larger than 10 mm, the transferability of the inkjet needle is not good, and a problem that printing is impossible may occur. In addition, in a recording material provided with an ink-receiving layer on a substrate, the relationship between the transmitted color density T and the reflected color density R when printing in full black satisfies the following formula. When viewed in the light-off state, it can still be used for electrical decoration because it still presents a vivid picture. 1.20XR ^ T ^ 1.70XR In the above formula, the color density (T) and the color density (R) of reflection are measured using the Marks concentration agent TR-927. In addition, the all-black series uses an inkjet printer JP-3 600 manufactured by Olympus Optical Industry Co., Ltd. and a pure oil-based pigment ink is printed at 100% K at half 721 dpi. (Base material) The thickness of the base material is 38 ~ 200 // m, preferably 50 ~ 188 // ni. 520331 V. Description of the invention (7) If the thickness of the base material is less than 3 8 // Π1, the rigidity of the base material is insufficient and the ink receiving layer may have a dimensional change such as a slight expansion or contraction, which may cause a discount or curl inertia. If it is larger than 200 // m, the recording material will be deformed due to the size change of the ink receiving layer, which will not only increase the cost but also reduce its softness, which will cause processing difficulties. The material of the substrate of the present invention is not particularly limited. When the recording material is attached to a wall or the like after printing, it is better to use an opaque substrate that does not see the primer, and to use it when the light is irradiated from the back of an electric decorative signboard or the like. A transparent substrate is preferred. Examples of the light-transmitting substrate include polyester-based, polystyrene-based storage, polypropylene, polyamide-based, polycarbonate, polyortho-spinene, vinylon, acrylic-based films or sheets (hereinafter referred to as sheets) In the case of a plate, it also includes a film), glass, and any two or more of these types, preferably a polyester-based resin sheet or film that is excellent in heat resistance and flexibility and is transparent. Among polyester-based resins, polyethylene terephthalate (PET) is more preferred because of its transparency, strength, adhesion to the ink receiving layer, and lower cost. When used in electrical decoration signboards, the base material has better light transmittance, and the better transparency of the light-transmissive base material is based on J I S K 7 105 as a reference. The total light transmittance is more than 85%. If the total light transmittance is less than 85%, there is a problem that a sharp image cannot be obtained when the light is irradiated from the back of the printed image. The polyester resin sheet is not limited to the conventional polyester resin sheet, but in the present invention, an aromatic dicarboxylic acid of p-benzoic acid, isobenzoic acid, naphthalenedicarboxylic acid or an ester thereof and diethanol can be used. Polyester resin prepared by polycondensation of alcohols such as diethylene glycol, 1,4-butanediol, and octyl alcohol, etc. 520331 5. Resin sheet with ingredients as described in (8) of the invention. The polyester-based resin sheet used for the transparent substrate in the present invention is preferably a sheet that is stretched in one axial direction using at least one of the above-mentioned resins. Stretching not only improves strength but also benefits cost. The stretching method of the polyester resin sheet is, for example, tubular stretching, simultaneous biaxial stretching, sequential biaxial stretching, and the like. There are no particular restrictions, but planarity, good dimensional stability, and few thickness spots. It is preferable to use sequential biaxial stretching. Specific examples of stretching by successive biaxial stretching are, for example, in the longitudinal direction at + 0 ~ + 30 ° C of the glass transition temperature of polyester by 2.0 to 5.0 times rolls, and then at 120 ~ 15 (TC The tenter is stretched at a magnification of 1 · 2 ~ 5 · 0. In addition, a method of 3 ~ 8% relaxation and heat fixing is performed at 220 ° C or higher after stretching. The transparency used in the recording material of the present invention The substrate can be a base film with two or more layers, that is, a composite film. The method of manufacturing the composite film is a conventional composite film manufacturing method, and there is no particular limitation. However, in consideration of productivity, the raw materials constituting each layer of the composite film are separately made from each extruder Extruded, and introduced into a mold and laminated, the unstretched sheet of the resin mixture is prepared to be stretched at least in one axis, that is, laminated by the co-extrusion method. In the present invention, there is no particular opaque substrate. Restrictions, such as polyester-based, polystyrene-based, polypropylene, polyamide, polycarbonate, polyorpene, vinylon, acrylic and other plastic films or sheets or mixed with these materials Opaque tree of inorganic material and foaming agent Lipid film, polyester cloth, polyester / cotton mixed cloth, cotton cloth, non-woven cloth, pulp, resin impregnated paper, mold coated paper, resin coated paper, cellophane and the like-10-520331 Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the consumer cooperative A7 B7 5. Description of the invention () Any two or more, preferably opaque polyester / synthetic paper with excellent heat resistance and softness. The better opacity pseudo total light transmittance is 60% or less If the total light transmittance is more than 60%, the opacity is not good and there is a problem of seeing the inside when it is attached to the wall. The opaque substrate of the present invention is preferably non-porous. It can prevent the ink from penetrating into the substrate. The solvent is impregnated into the material or ink, and as a result, problems such as a decrease in the strength of the substrate, overlapping of recording materials after printing, and internal movement during storage can be prevented. In addition, non-porous material includes a material that does not have openings on the outside even if there are many voids in the inside. The polyester strip synthetic paper is a conventional polyester synthetic paper, which is not particularly limited. In the present invention, aromatic dicarboxylic acids such as p-benzoic acid, isobenzoic acid, and naphthalenedicarboxylic acid are particularly used. Hollow polyester strips containing opaque films formed inside polyester resins by polycondensation of acids or their esters with alcohols such as ethylene glycol, diethylene glycol, 1,4-butanediol, neopentyl alcohol, etc. Synthetic paper is more preferred. The method for finding voids in the above-mentioned polyester strip synthetic paper containing voids is a conventional method and is not particularly limited, but it is preferable to mix and melt the polyester with the following There is a method of immiscible thermoplastic resin, and extruded sheet is stretched at least in one axial direction to form a lot of fine voids in the interior.-Immiscible thermoplastic resin in polyester used in this void forming method, Specific examples include polystyrene strip resin, polyolefin strip resin, polyacrylic strip resin, polysulfonate strip resin, polycode strip resin, cellulose strip resin, etc. Especially polystyrene strip resin and polymethylpentene are used. Polyolefin fluorene resins such as Polypropylene and Polypropylene are preferred. -1 1- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Order --------- line 0. 520331 A7 B7 V. Description of the invention (10 Fat melting makes the tree machine machine to train the fat-mixed tree to freely dissolve each other by the use of plastic strips to heat the fat pre-tree, so that it can be blended in the same way as the unmixed formula. Rigid medium plate, cool film out of polymer, stretched and stretched, and mixed with prepolymer, etc., etc., etc., the method of plasticizing the square plasticity of the fat method is hard and hard /, The dissolving phase and the non-melting and melting and melting melting machine are used to melt the fat ester resin in the machine. The ester is weakly polymerized, or it is usually plastic and heat-suppressing to the pseudo-lipid-free tree, and the non-laminated ester of the lyophilized plate is polyacrylic, and the result is hardened. The state of formation is in sight. The good shape and quantity of the fat dispersing tree traits are shaped and shaped. In the nature of the solution, the various phases of the solution and the like are all non-material silk esters. Round ball contract but do not mix or the amount of the oval-shaped hole ester globulomer to empty of 3 -

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G〜5.0 倍棍拉伸，然後在120〜150 °C下以1.2〜5.0倍之倍率拉 幅器拉伸。另外，於拉伸後在2 2 0 °C以上進行3〜8 %緩和 且熱固定的方法。 請 先 閱 讀 背 面 之 注 意 事 項 再J 寫 本 頁 以 為 各 圍 ，範 佳的 較佳 色較 白 ， 以時 材現 基表 明值 透1 不 、 L VII J 氺 的 a 準 VII 5 基-為 、 設 .接 直 上 材 基 性 明 透 不 或 性 明 透 該 在 由 藉 中 5 明 VII 發 1本 VII 於 使 以 可 亦 rc二 惟 〇 ，態 料形 材的 錄層 記塗 得 底 製置 以設 層間 質之 孔層 多質 之孔 層多 受與 容材 墨基 油在 置用 層 塗 底 構 0 層 性 接 密 的 層 受 容 墨 油 與 材 基 高 提 為 偽 層 塗 底 該 ·111111 線 經濟部智慧財產局員工消費合作社印製 脂此 樹及 酯脂 酸樹 甲胺 基蜜 胺 、 聚脂 、樹 脂条 樹酸 糸烯 酯丙 聚 、 用脂 使樹 可酯 脂酸 樹甲 C 之基等 層胺合 塗酯混 底聚之 成、等 接土化 密領氧 之高 、 質、黑 孔矽炭 多化 、 與氧鋇 高二酸 提有硫 /如 、 性例鋁 滑 C 化 平子氧 善粒 、 改種石 以各沸 中加 / 層添鈣 塗可酸 底的磺 述目 、 上為石 於時滑 力 、 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 B7 五、發明說明（ 12 經濟部智慧財產局員工消費合作社印製 、縮 式幕塗上設 底 m 為料 時， 所丨外 "量 以 脂醛 方簾棍線以 由 ο 做材 "板時 ，u 野 樹甲 覆、逆之予 經 C i 使錄 Μ 看 層 9 耐 為 收 A 胺、 塗式可層式 或料 1 即記 纟飾5 質為可 醯脂 版方、塗方。接材 Μ，之 電1 孔可得 聚樹 凹覆式底覆式直錄 Μ内機 I於於 多率可 、胺 相塗方置塗方上.記 $圍表 Ξ用大 之持式 脂糞 照霧覆設外覆材的ms範印 ί 使若 脂保方 樹鳥 用噴塗中線塗基層^述用 h 且， 樹度錄 5 待 酸并 使、佈程之上性質 ο 上成Inff形之。與濃記 ^苯 常式分工層線明孔 1 在作 。/^情反題子水墨 丙、 通方、膜塗的透多 i 層等料40透 c問粒耐噴 、脂 法覆式成底利非之 A 受板材於滲形的有的之 。 子樹 方塗方之置有或層))40容看錄小生情落含示墨料 粒糸。之漬覆膜設本性受層為墨飾記度産的脱為所油材 機酯子層浸塗薄厚成明容質度油電的厚布足粉層式性錄 無聚粒塗 、刀在膜對透墨孔厚使、質之合不起受下油記 之 、機底式氣，成以在油多之由報品層混度引容以用好 等脂有置方空法於傺為為M層藉海好受在濃會墨料使良 層 鈴樹等設覆、方、者係做纟受。、良容液色際油材以之 J 受 Μ 化糸脂，塗式等式佳明置容〃板具墨溶發之使錄此度 氧烯樹外模方式方較發設1墨5^看得油而生斷由記藉程 、乙物此鑄覆方覆。本層由油10型可若足産切藉的°.示 ii苯合 、塗覆塗置 塗(V~ 大仍 不會於 得上展 -----------------^----訂---------線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 _B7___ 13 五、發明說明（） 耐水濃度保持率（S：)= [(試驗後發色濃度）/(試驗而發色濃度）】xl〇0 (其中試驗偽於進行使試料在水中浸漬1小時後，使用J I S L - 0 8 4 9所記載的摩擦試驗機I I型，反覆5 0次之摩擦試驗 (摩擦子之質量：2 G 0 g、移動距離.· 1 0 0 m m、移動速度： 每分反覆3G次、摩擦用布：日本藥局方型I予以2張重 疊）。於摩擦後輕輕地在流水下洗淨且測定發色濃度。 發色濃度偽使用馬克倍斯濃度計T E - 9 2 7。） 詳細說明時係藉由在油墨容受層使用非吸水性熱塑性 樹脂以使記錄材料之耐水濃度保持率為9 5 %以上，油墨 容受層於印刷後印字部會因與油性油墨相互作用而很少 會有色脱落情形以改良耐水性，且可得對油性油墨而言 具良好記錄品質之記錄材料。而且，藉由使油墨容受層 為多孔質層，即使使用做為油墨吐出量大的大型看板、 海報等作成用印表機之記錄材料時仍可得具良好記錄品 質之記錄材料。若上述記錄材料之耐水濃度保持率小於 95%時，耐水性不充分。 -----------------^----訂---- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 有粒劑者之 、 如有溶佳劑 土 例含機較溶 領 ，中有 。性 高 由液於法水 、 理合覆方親 矽 的混塗的與 化 制之 、燥水。氣 限劑法乾或液二 別溶方以水覆有 待性的予於塗如 有水燥並覆之例 沒親乾液塗脂子 法與以覆、樹粒 方水予塗法與之 之或並之方子料 層水液脂的粒材 質於覆樹劑有成 孔覆塗與溶散構 多塗之子主分層 成上脂粒為中質 形材樹有水液孔 該基與含以合多 在子中為混 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 B7 五、發明說明（ 14 酸酸 硫矽 / / 鋁鈦 化化 氧氧 、二 石、 沸鉾 、 酸 鈣磺 酸、 碩鋅 質酸 重硫 / / 鈣鋅 酸化 磺氣 質、 經黑 、 炭 石、 滑鋅 等醋 0 、 化糸 氧烯 氫乙 、化 鎂氯 酸 、 磺糸 、酸 鋁烯 化丙 氧基 氬甲 、或 鈣酸 酸烯 矽丙 / J 土子 藻粒 矽機 、無 鋁之 龍烯 耐乙 、苯 糸聚 烯 、 乙条 酸烯 条 酸 烯 丙\ 烯 乙 苯 烯 乙 苯 聚 / 糸 酸 烯 丙 二基 丁甲 / 、 烯条 乙烯 苯戊 聚異 糸 氧 甲 / 環 酸 、 烯条 丙素 尿 / 条 酯 酸 磺 聚 / 条 胺 蜜 / 条 酯 丁 酸 烯 丙 基 丙 烯二 酸 甲 苯 / 条 i} 苯 / 糸 酯 酸 甲 基 胺 樹以 之徑 等粒 条之 酯子 聚粒 、等 糸此 酯 子 粒 匕曰The amount of S is based on the amount of time when the cave is empty. The amount of weight is 3 and the weight is better than the%. The amount of weight is soft and soft. The amount of weight is 40. The weight method is 40. Tracing / light weight heat resistance of the specific polymer damage is significantly higher when the need for sexual tracing or sexual privacy. The waist paper in the strong vision part is Cheng Qiyou, the ester content is strong, or the titanium petrochemical slippery oxygen, the two soils have a high degree of example, the aluminum granulation machine is free, the S shell is added with acid and sulfur. / Calcium is better than acidic sulphur particles, organic silicon without oxygen and oxygen, ------------- ^^ pack -----: -------- Order --- ----- · (Please read the precautions on the back before filling out this page) The employee's cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the consumer co-operative society, when printing the fatty tree, the film is made of paper, polyester, and polyester. The film is clear and transparent. -Mu has special features, such as unmade, preparation, etc., and other absorbent lines to prevent external purple, gas materials, wood color adhesion reduction, adding additives can also prevent electricity demand, tincture, white The material addition and photo-mixing of fluorescent materials are better than those of the transparent ones, and the base material is not used for the two-layer transparent layer, which makes it possible to use the materials and papers to record the book. The dimensions of the hollow paper are applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 520331 A7 B7 11 V. Description of the invention (The layer of the substrate is the composite film. The manufacturing method of the laminated film can be the same as that used for the transparent substrate. The stretching method for producing polyester synthetic paper from a resin mixture includes, for example, tubular stretching, simultaneous biaxial stretching, and successive biaxial stretching. However, in terms of planarity, good dimensional stability, and less thickness spots, successive biaxial stretching is preferred. Specific examples of stretching by successive biaxial stretching are, for example, + 0 in the glass transition temperature of polyester in the length direction. Stretched at 2. G to 5.0 times at ~ + 30 ° C, and then stretched at 1.2 to 5.0 times at 120 to 150 ° C. In addition, after stretching at 2 2 0 ° C The above is a method of 3 ~ 8% relaxation and heat fixing. Please read the precautions on the back before J. Write this page for each circle. Fan Jia's better color is whiter. The value is based on the time base. 1 No, L VII J 氺 a quasi VII 5 base-for, set. Directly on the base material is clear or not clear should be borrowed 5 Ming VII issued 1 book VII in order to make it possible to rc two only, state material The recording layer of the profile is coated to set the interlayer quality. The multi-layered porous layer is mostly coated with the base material ink base oil on the application layer. 0 The layer that is densely packed is coated with the base oil ink and the base material as a pseudo layer. This is 111111. The Bureau of Intellectual Property of the Ministry of Economic Affairs Employee Consumer Cooperative Co., Ltd. printed this tree and ester melamine melamine, polyester, resin stripe resin acrylic resin acrylic resin, and resin to make the resin ester resin C C base and other layers of amine coating Ester mixed bottom polymerization, high soil density, high oxygen density, black pores, polysilicon, and sulphur extraction with barium peroxic acid, such as properties, aluminum slip, C, flattened oxygen, and modified seeds The sulphur head of the stone is added in each boiling layer and added with calcium and coated with acid base. The time is the sliding power of the stone. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 520331 A7 B7 5 、 Explanation of the invention (12 When printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the shrink-type curtain is coated with the bottom m as the material. , U Ye Shujia overwhelmed and reversed through C i to record M to see layer 9 A close to an amine coated or layered material of Formula 1 may be referred i.e. Si 5 mass to be decorated aliphatic acyl side plate, coated side. For connecting materials, 1 hole of the electricity can be obtained from the tree-recessed, bottom-covered, direct-recording internal machine I on the multi-coated, amine-coated side and placed on the coated side. Ms. Fan Yin, a faecal shroud covering material, used to coat the base layer with a sprayed midline bird. The tree degree is 5 to be acidified, and the nature of the schedule is to be Inff. Shape it. With Nong Kee ^ Benzene normal division layer line open hole 1 is made. / ^ Love counter-inking Ink C, Tong Fang, film-coated, multi-layered materials, etc. 40 through c Question grain spray-resistant, fat-laminated into the bottom of the right and wrong A Affected by the plate infiltration. Sub-tree Fang Tu Fang's place or layer)) 40 Rong Lu recorded naughty feelings containing ink and grain. The stain coating is based on the nature of the coating layer, which is produced by the ink decoration. The polyester sublayer is dip-coated with a thin thickness to become bright. The thickness of the oil and electricity is thick. The powder layer is recorded without polymer particles. The film is thick enough for the ink penetrating holes, the quality is unacceptable, and the bottom of the machine is air-conditioned, so that the oil is mixed by the newspaper layer to accommodate the volume, and the square method is used to make good use of the fat. In order to take advantage of the sea for the M floor, the thick layer of Suzuki and other decorations, squares, and others are accepted by the thick ink. , Liang Rongye color interstitial oil material is subject to J chemical conversion grease, coating formula Jiaming placement capacity plate with ink dissolve, so that the degree of oxygen olefin outside mold method is set to 1 ink 5 ^ see Obtaining the oil and breaking it is covered by the debit process and the second thing. This layer is made of oil 10, which can be cut if it can be produced in full. Ii Benzene compounding, coating, coating, coating (V ~ large will not be able to show up -------------- --- ^ ---- Order --------- Line (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ) 520331 A7 _B7___ 13 V. Description of the invention () Water resistance concentration retention rate (S :) = [(color concentration after test) / (color concentration after test)] xl0 (where the test is pseudo-tested to make the sample in water After 1 hour of immersion, the friction tester type II described in JISL-0 8 4 9 was used, and the friction test was repeated 50 times (mass of friction: 2 G 0 g, moving distance. · 100 mm, moving speed : Repeated 3G times per minute, rubbing cloth: Japan Pharmacopoeia Form I overlapped with 2 sheets). After rubbing, gently wash under running water and measure the color density. The color density is pseudo-marker TE-9 2 7.) In the detailed description, the non-water-absorbing thermoplastic resin is used in the ink-receiving layer so that the water-resistant concentration retention rate of the recording material is more than 95%. The ink-receiving layer is printed after printing. Due to the interaction with oil-based inks, there is little color peeling to improve water resistance, and a recording material with good recording quality for oil-based inks can be obtained. In addition, by making the ink receiving layer a porous layer, Even when used as recording materials for printers such as large signboards and posters with large ink discharge, recording materials with good recording quality can still be obtained. If the water-resistant concentration retention rate of the above-mentioned recording materials is less than 95%, the water resistance is not Adequate. ----------------- ^ ---- Order ---- (Please read the notes on the back before filling out this page) Employees ’Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs For those who have printed granules, if there is a good solvent, the soil contains organic and relatively soluble collars, and there are some. The sex is high, it is mixed with liquid water, lyophilized and coated with silicone, mixed with chemical, dry water. Gas Restricted agent method: dry or liquid two, dissolved with water, waiting to be applied, if it is dry and covered with water, it is not compatible with dry liquid, fat-liquid method, and coated, bark, and water. The granule material of the liquid and fat in the square material layer has a hole forming coating and a dispersive structure and multiple coating on the tree coating agent. The upper layer of the fat particles is a medium-sized tree with water pores. The base is mixed with the contained polyphenols in the paper. The paper is scaled to the Chinese National Standard (CNS) A4 (210 X 297 mm). 520331 A7 B7 5 、 Explanation of the invention (14 Sulfuric acid sulphuric acid // Aluminium titanated oxygen oxygen, distone, boiling sulphur, calcium acid sulfonic acid, sulphur zinc acid heavy sulfur // Calcium zinc acidified sulphur gas, black, charcoal, slippery Zinc and other vinegars 0, trioxane hydrochloride, magnesium chloride chloric acid, sulfonium chloride, aluminum oxyalkylene propoxy argonium methacrylate, or allyl silicate calcium silicate / J diatom algae silicon machine, aluminum-free dragon Ethylene-Resistant Ethylene, Styrene Polyene, Ethyl Acetate Allyl Ethylene Acetate / Allyl Diethyl Butyrate Acetate / Ethylene Ethylene Phenylisopropyloxymethane / Cyclic Acid, Allyluria / Sulfuric acid polysulfide / Amino honey / Sulfuric acid Butyl allyl acrylic acid Toluene / Stripe Grains, etc.

5 ο 為 者 佳 更 RI 溶 機 有 就 佳 較 子 粒 矽 化 氯二 用 使 以 中 子 粒 之 mo述 A 上 2 於 化 為 氧 徑 二 粒 質 均 晶 平 非 之 成 子 合 粒 之 聚 孔 凝 細 次 具 2 面 以 表 傺 用 性 使 特 以 之 尤 子 ^目 粒 而 矽 收。化 吸佳氧 之較二 劑矽 ^ 為 徑 孔 細 / 且 而 ο 佳 較 者 埃 矽蠟 機石 有著 用附 使上 有面 理表 處在 面純 表單 ο > 者理 質處 改學 經化 面之 表等 為酯 以酸 可鈦 亦機 需有 所 、 其烷 ----K----^---------. (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 魯 密 製 學 化 澤 水 如 例 ο 品 售 0 市 等擇 理選 處可 理子 物粒 之矽 物化 合氧 化二 醇該 或 雷 魯布 西卡 克製 頓藥 製製 \\/ \)/ 音音 譯譯 /V /V 達奇 索羅 山歐 德西 / f )/ V-/ 立日立日 譯譯 /V /V 魯 魯 西西 卡因 U音 亞譯 /(V 西 匡 西 士 富 、 音 7譯 音{ 頓 龍 賽 製 音 譯 法 B幸 -|口 /ί\ 斯 克 音 索 皮 迪 史 雷 古 、 音 亞譯 /fv 西 里 賽 製 頓 傑 0 賽 等 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 經濟部智慧財產局員工消費合作社印製 A7 _B7_ 15 五、發明說明（） 結合粒子之黏接材料俗使用非吸水性熱塑性樹脂。藉 由使用熱塑性樹脂，由於因乾燥工程之加熱而具流動性 ,故可形成歪斜或表面不齊情形很少的層。另外，可使 耐水性、耐候性優異的油性油墨之特徵活化。 結合粒子之黏接材料為非吸水性熱塑性樹脂，以玻璃 轉移溫度為-5 °C〜1 G 0 °C較佳。若玻璃轉移溫度過高時， 乾燥過程之流動性不佳，尤其容易在預先進行乾燥的表 面上造膜，且表面之油墨吸水性不佳。反之，若玻璃轉 移溫度過低時，由於乾燥過程之流動性過佳，容易在基 材側聚集樹脂、且降低表層黏接粒子之樹脂量、降低表 面強度之問題。 做為黏接材料所使用的上述熱塑性樹脂例如有聚丙烯 、聚乙烯、聚氧化乙烯、聚乙二醇、聚乙烯基吡咯烷酮 、聚氯化乙烯、聚酯、聚碩酸酯、烷氧化物、聚胺基甲 酸酯、甲基丙烯酸甲酯、纖維素等，沒有限定。於此等 之中，就與基材之密接性、耐水性、耐候性等尤以使用 聚酯糸熱塑性樹脂較佳。 本發明之非吸水性樹脂俗為對樹脂固體而言不會吸收 1 0 %以上常溫的水之樹脂，較佳者為不會吸收5 %以上之 樹脂。吸水性之評估可以測定使樹脂固體在常溫下浸漬 24小時之體積變化，具體而言俗實質上在非吸水性載體 (例如鋁箔、玻璃等）上塗覆厚度為數+Ain之樹脂層，並 予以乾燥旦測定在1 8 °C之離子交換水中浸漬2 4小時後厚 度變化。 一 1 7 一 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1_ϋ I n -ϋ ·ϋ ϋ ϋ I ·ϋ n n I ϋ ·ϋ ·ϋ n n an in J IV n 1^1 ·Ηϋ —ϋ ϋ ·ϋ 1 1 (請先閱讀背面之注意事項寫本頁) 520331 經濟部智慧財產局員工消費合作社印製 A7 _B7_ 16 五、發明說明（) 本發明中較佳的黏結材料之聚酯条樹脂傺為由二元酸 與醇所形成的可乳化或分散於水中的聚酯樹脂。具體而 言，二元酸偽全部二元酸之5G〜0.5莫耳5!為含磺酸金屬 鹽的二羧酸，此等中至少二種之二羧酸成份與醇成份共 聚合的聚酯共聚物。 上述含有磺酸金屬鹽基之二羧酸例如有磺基對苯甲酸 酯、5-磺基異苯甲酸、4-磺基苯甲酸、4-磺基萘基-2， 7-二羧酸、5[4 -磺基苯氯基]異苯甲酸等之金屬鹽，更 佳者為5 -鈉磺基異苯甲酸、鈉磺基對苯甲酸。此等含磺 酸異苯甲酸鹽之二羧酸對全部二羧酸成份而言為50〜0.5 莫耳％、較佳者為20〜1莫耳％。若大於50莫耳％時，即使 對水之分散性佳，共聚含物之耐水性降低。聚酯共聚物 封水而言之分散性偽視共聚合組成、水溶性有機化合物 之種類及量等而不同，上述含磺酸金屬鹽基之二羧酸成 份之量係在不損及對水之分散性範圍下，愈少愈好。 不含磺酸金屬鹽基之二羧酸可使用芳香族二羧酸、脂 肪族二羧酸、脂環族二羧酸。芳香族二羧酸例如有對苯 甲酸、異苯甲酸、原苯甲酸、2, 6-萘二羧酸等。此等之 芳香族二羧酸以全部二羧酸成份之40莫耳％以上者較佳， 若小於40莫耳％時，聚酯共聚物之機槭強度或耐水性會 降低。脂肪族、脂環族二羧酸例如有琥珀酸、己二酸、 葵二酸、1,3-環戊烷二羧酸、1，2-環己烷二羧酸、1，3-環己烷二羧酸、1，4-環己烷二羧酸等。加入此等之非芳 香族二羧酸成份時，雖可提高黏接性能，惟一般而言會 -1 8 _ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） n ·ϋ n ϋ n n n n ϋ in n fli ϋ n n 一口， n ·ϋ ϋ ϋ ·ϋ (請先閱讀背面之注意事項再填寫本頁) 禮- 520331 A7 B7 五、發明說明（ 17 脂 個 8 - 2 數 碩 用 使 〇 可 佳份 不成 性醇 水的 耐應 或反 度份 強成 之酸 物羧 聚二 共述 酯上 聚與 使 且 物 合 混 之 者 兩 及 淳 ο &物 族 合 環b 指 /Ί 丨醇 酯 聚 6 用 數使 碩可 、需 醇所 族其 肪視 個 2 V-1 數丙 碩3- / 1X 醇 、 族醇 肪二 脂丙 之2- 個1’ 8 / 2 醇 數二 磺乙 有 如 例 醇 族 環 脂 個 醇 醇 古子^? S 酉 戊甲 醇二 己 醇 甲二 烷 己 環 二 烷 己 環5 ο For better Jiari RI dissolving machine, it is better to use silicium chloride for better than grains. Use numerology of neutrons as above 2 to reduce the oxygen pores to two grains. It has 2 sides with surface function, which makes it especially good for you ^ mesh and silicon. Compared with the two doses of silicon that absorbs good oxygen, ^ is fine in diameter and hole, and ο better than the ethene wax machine stone has the use of a surface treatment on the surface in pure form ο > The table of chemical surface is the ester, acid and titanium, and the alkane ---- K ---- ^ ---------. (Please read the precautions on the back before filling in this Page) The Ministry of Economic Affairs ’Intellectual Property Bureau ’s Employees’ Cooperatives printed Lumi ’s chemical chemical water as an example. Ο Product sales 0 City and other optional places. Pharmacy system \\ / \) / transliteration / V / V Dachisoro Odesi / f) / V- / Hitachi Hitachi translation / V / V Lurusicicaine U transliteration / (V Xi Kuang Xi Shi Fu, Yin 7 transliteration {Dun Long game system transliteration B Xing- | kou / ί \ skeletal Sopidi Sregu, Yin Ya translation / fv Sicilian system Dunge 0 match book Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 520331 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7_ 15 V. Invention It is customary to use non-water-absorbing thermoplastic resin as the bonding material for the particles. By using the thermoplastic resin, it can form a layer with few skews or uneven surfaces due to its fluidity due to the heating of the drying process. In addition, Can activate the characteristics of oil-based inks with excellent water resistance and weather resistance. The bonding material for the binding particles is a non-water-absorbing thermoplastic resin, and the glass transition temperature is preferably -5 ° C to 1 G 0 ° C. If the glass transition temperature is When it is too high, the fluidity in the drying process is not good, and it is especially easy to form a film on the surface that has been dried in advance, and the ink absorption of the surface is poor. On the contrary, if the glass transition temperature is too low, the fluidity in the drying process is too high. It is easy to gather resin on the substrate side, and to reduce the amount of resin and surface strength of the adhesion particles on the surface layer. The thermoplastic resins used as the adhesive material include polypropylene, polyethylene, polyethylene oxide, and polyethylene. Ethylene glycol, polyvinylpyrrolidone, polyvinyl chloride, polyester, polysterate, alkoxide, polyurethane, methyl methacrylate, cellulose There is no limitation on pigments. Among these, it is particularly preferable to use polyester / thermoplastic resins in terms of adhesion to the substrate, water resistance, and weather resistance. The non-water-absorbent resin of the present invention is generally used for resin solids. A resin that does not absorb water of more than 10% at room temperature, preferably a resin that does not absorb more than 5%. The evaluation of water absorption can measure the volume change of the resin solid after immersion at room temperature for 24 hours. A non-absorbent carrier (such as aluminum foil, glass, etc.) is substantially coated with a resin layer having a thickness of + Ain, and dried to measure the thickness change after immersion in ion-exchange water at 18 ° C for 24 hours. 1 1 7 A paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1_ϋ I n -ϋ · ϋ ϋ ϋ I · ϋ nn I ϋ · ϋ · ϋ nn an in J IV n 1 ^ 1 · Ηϋ —ϋ ϋ · ϋ 1 1 (Please read the notes on the back to write this page) 520331 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7_ 16 V. Description of the invention () The better bonding material in the present invention The polyester strip resin 傺 is a polyester resin formed by a dibasic acid and an alcohol that can be emulsified or dispersed in water. Specifically, 5G to 0.5 mol of the dibasic pseudo-dibasic acid is a dicarboxylic acid containing a sulfonic acid metal salt, and at least two of these are a polyester copolymerized with a dicarboxylic acid component and an alcohol component. Copolymer. Examples of the dicarboxylic acid containing a sulfonic acid metal salt group include sulfoparaben, 5-sulfoisobenzoic acid, 4-sulfobenzoic acid, and 4-sulfonaphthyl-2, 7-dicarboxylic acid. And 5 [4-sulfophenylchloro] isobenzoic acid, and more preferred are 5-sodium sulfoisobenzoic acid and sodium sulfo-p-benzoic acid. The dicarboxylic acid containing sulfonic acid isobenzoate is 50 to 0.5 mole%, preferably 20 to 1 mole% of the total dicarboxylic acid component. If it is more than 50 mol%, even if the dispersibility to water is good, the water resistance of the copolymer content decreases. The dispersibility of polyester copolymers for water sealing varies depending on the copolymer composition, the type and amount of water-soluble organic compounds, etc. The amount of the dicarboxylic acid component containing the sulfonic acid metal salt group is not harmful to water. In the range of dispersion, the less the better. As the dicarboxylic acid having no metal sulfonic acid group, an aromatic dicarboxylic acid, an aliphatic dicarboxylic acid, and an alicyclic dicarboxylic acid can be used. Examples of the aromatic dicarboxylic acid include p-benzoic acid, isobenzoic acid, orthobenzoic acid, and 2,6-naphthalenedicarboxylic acid. These aromatic dicarboxylic acids are preferably 40 mol% or more of the total dicarboxylic acid components. If the aromatic dicarboxylic acid is less than 40 mol%, the organic maple strength or water resistance of the polyester copolymer may be reduced. Examples of the aliphatic and alicyclic dicarboxylic acids include succinic acid, adipic acid, succinic acid, 1,3-cyclopentanedicarboxylic acid, 1,2-cyclohexanedicarboxylic acid, and 1,3-cyclohexane. Alkanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, and the like. When these non-aromatic dicarboxylic acids are added, although the adhesion performance can be improved, in general it will be -1 8 _ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) n · ϋ n ϋ nnnn ϋ in n fli ϋ nn sip, n · ϋ ϋ 请 · ϋ (Please read the notes on the back before filling this page) E-520331 A7 B7 V. Description of the invention (17 Fat 8-2 digits) The acid carboxypolydicopolyester which is used to make 0 parts of the insoluble alcoholic water resistant or the inverse part strong is used to polymerize and mix the two, and the &com; cyclic compound b means / Ί 丨 Alcohol Polyester 6 can be used as a number of alcohols and alcohols, and its fat is 2 V-1. It is a 3- / 1X alcohol, and it is a 2- and 1 '8/2 alcohol. There are several examples of disulfoethyl alcohols, cycloaliphatic alcohols, alcohols, ^? S, pentamethanol, dihexanol, methane, hexane, and dioxane.

(請先閱讀背面之注意事Z 等 醇 苯 甲二 I 對 例 醇二 族 肪 脂 之 上 以 個 4 數 醇二 丙 化 氧 聚 / 醇二 乙 。化 等氧 享 轻 二有 〇 乙如等 三例醇 、醇二 醇酯甲 二聚亞 乙 ，四 二 且化 為而氧 如 聚 得餾 二 製且使 以應或 予反 、 合接法 縮直化 聚份酯 融成接 熔醇直 之及之 知份合 習成縮 由酸聚 藉羧行 可二進 旨 ί Bn 、ρχ ， 樹上後 性由化 塑藉酯 熱，以 条之予 酯〗一一口 分 聚換水 。去 交聚 酯液 行溶 進由 且藉 醇 ， 甲外 去此 |§。 ,得 應製 反而 份法 成換 醇交 與酯 酯之 甲 合 二縮 之聚 份以 成予 酸後 羧換 等化 此氧 受抗 不入 明加 發需 本所 rllil huN 惟其 ，視 物可 合 ， 聚時 得 合 製縮 以聚 等融 合熔 縮於 聚 〇 由制 藉限 或所 合法 縮方 -丨 --- ▼填寫本頁) 訂， 經濟部智慧財產局員工消費合作社印製 化融 氧熔 聚以 之予 述可 上後 ο 合 劑聚 止或 防時 電合 帶縮 、聚 子融 粒熔 為於 機 ， 無醇 。 、醚合 劑聚聚 滑之共 平等 / 、 醇合 劑乙混 時 層 受 容 墨 油 成 作 為 必於酮 , 解 、 時溶糸 脂脂醚 樹樹醇 有使 、 含 。条 中中醇 液水入 溶於加 的散脂 用分樹 使或將 所中如 劑例 溶 ， 機法 有方 於的 含中 脂劑 樹溶 使機 須有 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 B7 經濟部智慧財產局員工消費合作社印製 18五、發明說明（） ^ 条、脂肪族烴条、芳香族烴条等有機溶劑中且予以加熱 的方法。分散、乳化於水中的方法例如在使樹脂與可使 樹脂溶解的溶劑與水加熱的狀態下持續攪拌的方法、使 樹脂加熱溶解於有機溶劑後將水投入予以分散的方法。 上述之聚酯条樹脂可選自市售品。例如東洋紡績製拜 羅那魯、大日本油墨製法因迪克斯（譯音）等。 熱塑性樹脂與粒子之比例沒有特別的限制，樹脂/粒 子之重量比為1/1.2〜1/10，尤以1/1. 3〜1/2.5較佳。 若粒子之比例過小時，粒子以熱塑性樹脂被覆的比例過 大，不易形成多孔質構造。反之，粒子之比例過大時會 降低本發明4 0〜1 0 5 # οι厚之多孔質層的表面強度。 本發明之多孔質糸内部存在有很多空隙且自表面至内 部連通〇 油墨容受層方可於塗覆時提高其水平、塗覆液之脱泡 等為目的時加入界面活性劑。界面活性劑可以為陽離子 条、陰離子糸、非離子条及非離子性等。然而，較佳者 為聚矽氧烷条或氟糸界面活性劑。聚矽氧烷糸界面活性 劑例如有二甲基聚矽氧烷、胺基矽烷、丙烯基矽烷、乙 烯基苯甲基矽烷、乙烯基苯甲基胺基矽烷、環氧丙基矽 烷、氫硫基矽烷、二甲基矽烷、聚二甲基矽氧烷、聚烷 氧基矽氧烷、氫改性的矽氧烷、乙烯基改性的矽氧烷、 羥基改性的矽氧烷、胺基改性的矽氧烷、羧基改性的矽 氧烷、氫化改性的矽氧烷、環氧基改性的矽氧烷、甲基 丙烯氣基改性的矽氧烷、氫硫基改性的矽氧烷、氟改性 -2 0 - (請先閱讀背面之注意事填寫本頁) --裝 · 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 經濟部智慧財產局員工消費合作社印製 A7 _B7 , 19 五、發明說明（） 的 矽 氣 烷 、 烷 基 改 性 的 矽 氧 烷 、 苯 基 改 性 的 矽 氧 烷 - 氧 化 烯 基 改 性 的 矽 氧 烷 等 〇 氟 条 界 面 活 性 劑 例 如 有 過 氟 烷 基 m 鹽 過 氟 烷 基 磺 酸 醯 胺 過 氣 烷 基 磺 酸 鈉 過 氟 烷 基 鉀 鹽 過 氟 院 基 羧 酸 鹽 、 過 氣 烷 基 磺 酸 鹽 、 過 氟 烷 基 氧 化 乙 烯 加 成 物 過 氟 烷 基 三 甲 基 銨 鹽 、 過 氟 烷 基 胺 基 廣 酸 鹽 S 過 氟 烷 基 磷 酸 酯 過 氟 烷 基 烷 基 化 合 物 過 氟 院 基 烷 基 苯 因 、 過 氣 烷 基 鹵 化 物 等 〇 此 等 界 面 活 性 劑 在 不 極 度 降 低 油 墨 容 受 層 之 油 墨 吸 收 性 能 之 程 度 下 添 加 較 佳 〇 本 發 明 之 油 墨 容 受 層 偽 主 要 在 由 水 所 成 的 溶 劑 中 使 上 述 粒 子 、 及 上 述 玻 璃 轉 移 溫 度 (T g) 為 -5°C 1 0 0 °c之非 吸 水 性 熱 塑 性 樹 脂 乳 化 或 分 散 之 塗 覆 液 塗 覆 於 上 述 至 少 一 面 透 光 性 基 材 後 使 溶 劑 乾 燥 除 丢 予 以 形 成 較 佳 〇 此 時 9 於 上 述 塗 覆 液 中 以 配 合 可 滿 足 下 述 式 1 . 式2 之比 例 的 沸 點 為 1 5 0 °c以上之水溶性高沸點溶劑較佳。 S > T g - 3 0 式1 S < T g + 7 0 式2 (其中， S 偽表示對1 0 0 重 量 份 熱 塑 性 逑 之 而 言 沸 點 1 5 i〇°C 以 上 之 水 溶 性 高 沸 點 溶 劑 之 配 合 比 例 [重量份】，T g俗表 示 熱 塑 性 樹 脂 之 玻 璃 轉 移 溫 度 [°C ]) 此 處 之 厂 水 溶 性 高 沸 點 溶 劑 J 俗 在 水 中 可 以 任 fcb 例 溶 解 沸 點 1 5 0 °c以上之溶劑。 水 溶 性 高 沸 點 溶 劑 之 沸 點 小 於 1 5 丨0。。時， 於油墨容受 層 形 成 時 之 乾 燥 工 程 中 $ 與 溶 劑 —- 起 蒸 發 而 無 法 得 到 充 -2 1- (請先閱讀背面之注意事 裝—— 寫本頁) « - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 五、發明說明（2〇 ) 分的本發明作用。 而且’粒子與樹脂之重量比（A/B)及熱塑性樹脂之Tg 的關係式以下式較佳。 A/B 1.2 式 A/B Tg/ 100 + 0.8 式 A/B Tg/ 100+1 ·9 式 A/B小於1.2時，粒子表面被覆之樹脂量過多，油墨 容受層中多孔質量降低且油墨吸收性不佳。此外，爲另 組合油墨吐出量大的印表機時，式5以A / B S T g / 1 0 0 + 1 . 9 較佳。 熱塑性樹脂之玻璃轉移溫度過高時，於油墨容受層形 成時乾燥過程中熱塑性樹脂之流動性過低，乾燥過程之 造膜性過高而使油墨容受層之被覆粒子的樹脂量增加， 表層之油墨吸收量降低。表層之油墨吸收量降低時，厚 度方向之油墨浸透顯著而成有浸透情形的記錄畫像缺 點。而且，熱塑性樹脂之玻璃轉移溫度過高時，上述高 沸點溶劑之配合比例過多，油墨容受層形成時以乾燥溫 度調整熔融黏度。 此外，上述熱塑性樹脂之玻璃轉移溫度過低時，乾燥 過程之流動性過高，致使油墨容受層之被覆粒子的樹脂 量降低，表層之油墨吸收量增加。另外，過低時產生表 面強度降低的情形。表層之油墨吸收量過高時，藉由在 表層吸收油墨雖易得畫像濃度高之記錄畫像，惟點徑較 設計値小時印刷黑色時會在點間產生出現隙縫的情形。(Please read the note on the back first. Z and other alcohols, such as benzoyl I, and alcohols, are listed on the top of the alcohol two-family fat with four digits of alcohol dipropylated oxypoly / alcohol diethyl. Three examples of alcohols, alcohol glycol esters, methylenediethylene, and dioxin are converted to oxygen, such as polymerization and distillation, and the polycondensation esters that are straightened by the reaction or reaction method are melted into the molten alcohol. And the knowledge of the students is that the acidification of the polymer and the use of the carboxylic acid can be dualized. Bn, ρχ, the posteriority of the tree is transformed by the heat of the ester, and the ester is divided into one bite to change the water. The ester solution is dissolved and the alcohol is removed, and A is removed here. §. It is necessary to make a fractional method to exchange the alcohol and the di-esterified polymer of the ester to form the acid. To resist the indiscriminate addition, we need the rllil huN of the firm. However, depending on the material, it can be combined at the time of fusion. It can be merged with the fusion of fusion, etc. Fusion by the borrowing limit or the legal contraction-丨 --- ▼ Fill in This page) order, printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumer cooperatives melted oxygen fusion can be described later When the anti-bonding agent or polymerization stopper electrical engagement with condensation, and gather in the machine to melt into particles, alcohol-free. Ethyl ether, polyether, polyether, etc., Alcohol admixture, when the ink is contained in the ink layer, is necessary for ketones, and it can dissolve the tallow fatty alcohol tree resin, which can be used. The alcoholic water in the strip is dissolved in the added fat, and it is used to dissolve or dissolve all the ingredients as shown in the example. The method for the dissolving of the medium-containing fat-containing tree must be made according to the Chinese paper standard. CNS) A4 specification (210 X 297 mm) 520331 A7 B7 Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 18th Five, Invention Description () ^, aliphatic hydrocarbon bars, aromatic hydrocarbon bars and other organic solvents and heated Methods. The method of dispersing and emulsifying in water is, for example, a method of continuously stirring the resin and a solvent capable of dissolving the resin and water, and a method of dispersing the resin by heating and dissolving the resin in an organic solvent. The above-mentioned polyester strip resin may be selected from commercially available products. For example, Toyobo Textile's Byronaru, Dainippon Ink, etc. The ratio of the thermoplastic resin to the particles is not particularly limited, and the weight ratio of the resin / particles is 1 / 1.2 to 1/10, particularly preferably 1/1. 3 to 1 / 2.5. When the proportion of the particles is too small, the proportion of the particles coated with the thermoplastic resin is too large, and it is difficult to form a porous structure. Conversely, when the proportion of the particles is too large, the surface strength of the porous layer having a thickness of 40 to 105 according to the present invention will be reduced. The porous concrete of the present invention has a lot of voids inside and communicates from the surface to the inside. The ink receiving layer can be added with a surfactant for the purpose of increasing its level during coating and defoaming of the coating solution. The surfactant may be a cationic bar, an anionic hafnium, a non-ionic bar, a non-ionic bar, and the like. However, preferred are polysiloxane strips or fluorene surfactants. Examples of polysiloxane surfactants include dimethyl polysiloxane, amine silane, acryl silane, vinyl benzyl silane, vinyl benzyl amine silane, epoxy propyl silane, and hydrogen sulfur. Silane, dimethyl silane, polydimethyl siloxane, poly alkoxy siloxane, hydrogen modified siloxane, vinyl modified siloxane, hydroxyl modified siloxane, amine Base modified siloxane, carboxy modified siloxane, hydrogen modified siloxane, epoxy modified siloxane, methacryl modified siloxane, hydrogen thio modified Siloxane and Fluorine Modified -2 0-(Please read the notes on the back and fill in this page first)-Packing · This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 520331 Economy Printed by A7 _B7, 19 of the Intellectual Property Cooperative of the Ministry of Intellectual Property Bureau V. Description of the invention () Silane, alkyl-modified siloxanes, phenyl-modified siloxanes-oxyalkylene-modified silica Fluorine surfactants such as alkanes include perfluoroalkyl m salts perfluoroalkylsulfonic acids Amine perfluoroalkyl sulfonate sodium perfluoroalkyl potassium salt perfluoroalkyl carboxylate, perfluoroalkyl sulfonate, perfluoroalkyl ethylene oxide adduct perfluoroalkyltrimethylammonium salt, Fluoroalkylamino broad salt S Perfluoroalkyl phosphate Perfluoroalkyl alkyl compounds Perfluoroalkyl alkyl benzene, perfluoroalkyl halides, etc. These surfactants do not significantly reduce the ink capacity It is preferable to add it to the extent of the ink absorption performance of the receiving layer. The ink receiving layer of the present invention mainly makes the above particles and the above-mentioned glass transition temperature (T g) in a solvent made of water -5 ° C 1 0 0 ° c non-water-absorbing thermoplastic resin emulsified or dispersed coating liquid is coated on the at least one side of the light-transmitting substrate, and then the solvent is dried and removed to form it. At this time, 9 in the above coating liquid may be mixed with Satisfy the following formula 1. A ratio of 2 is preferably a water-soluble high-boiling-point solvent having a boiling point of 150 ° C or higher. S > T g-3 0 Formula 1 S < T g + 7 0 Formula 2 (where S pseudo represents a water-soluble high boiling point with a boiling point of 1 5 i ° C or more for 100 parts by weight of thermoplastic rhenium The proportion of the solvent [parts by weight], T g is the glass transition temperature of the thermoplastic resin [° C]) The water-soluble, high-boiling point solvent J in the factory can be used in the water. For example, fcb can be dissolved at a boiling point above 150 ° C. Solvent. The boiling point of water-soluble high boiling point solvents is less than 1 5 丨 0. . In the drying process when the ink accommodating layer is formed, the solvent and solvent —- evaporates and cannot be charged-2 1- (Please read the precautions on the back-write this page) «-This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 520331 V. Description of the invention (20) The effect of the invention. Further, the relationship between the weight ratio of particles to the resin (A / B) and the Tg of the thermoplastic resin is preferably the following formula. A / B 1.2 Formula A / B Tg / 100 + 0.8 Formula A / B Tg / 100 + 1 · 9 When Formula A / B is less than 1.2, the amount of resin coated on the particle surface is too much, the porous quality of the ink receiving layer is reduced and the ink Poor absorption. In addition, in the case of a combination printer with a large ink discharge amount, Equation 5 is preferably A / B S T g / 100 + 1.9. When the glass transition temperature of the thermoplastic resin is too high, the fluidity of the thermoplastic resin is too low during the drying process when the ink receiving layer is formed, and the film forming property of the drying process is too high, so that the resin amount of the coated particles of the ink receiving layer is increased. The ink absorption of the surface layer is reduced. When the ink absorption in the surface layer is reduced, the penetrating of the ink in the thickness direction becomes noticeable, and the recorded image is deficient. In addition, when the glass transition temperature of the thermoplastic resin is too high, the blending ratio of the above-mentioned high-boiling-point solvent is excessive, and the melt viscosity is adjusted at a drying temperature when the ink receiving layer is formed. In addition, when the glass transition temperature of the above-mentioned thermoplastic resin is too low, the fluidity in the drying process is too high, so that the resin amount of the coated particles of the ink receiving layer is reduced, and the ink absorption of the surface layer is increased. In addition, if it is too low, the surface strength may decrease. When the ink absorption of the surface layer is too high, it is easy to obtain a recorded image with a high image density by absorbing the ink on the surface layer, but when the dot diameter is smaller than the design time, black gaps may appear between the dots.

-22- 520331 A7 B7 五、發明說明（ 2 1 點之 沸度 高溫 述燥 上乾 ，以 時時 低成 過形 度層 溫受 移容 轉墨 璃油 玻， 之少 脂過 樹例 性比 塑合 熱配 ，之 且劑 而溶 分 或 化 乳 脂 樹 性 塑 熱 時 成 形 層 受 容 墨 油 ο ， 高中 過明 度發 黏本 融於 熔 脂拌 樹it 性續 塑持 熱 下 使態 有狀 如熱 例加 ，在 法劑 方溶 之與 劑劑 溶 溶 的點 成沸 所高 水性 由溶 要水 主述 於上 散與 解 溶 熱 加 中 劑 溶 點 沸 高 性 0 溶等 水法 在方 樹散 性分 塑以 熱予 使劑 ，溶 法加 方添 的後 等 条 酯 5 享 1 酉 為 、 點糸 沸醚 述醇 上 、 ， 条 中醇 明有 發如 本例 於劑 溶 點 沸 高 性 溶 水 之 上 以 °c 醇 乙二 如 例 體 具 (請先閱讀背面之注意事項寫本頁) 裝 乙 醚醚 單單酯 醇醇酸 二 二乙 乙乙基 、 二 乙 醇 、單 二醚醇 乙乙二 聚單乙 、醇二 醇二 、 二乙酯 乙二酸 三 、乙 、醚基 醇甲甲 二 單單 丙醇醇 、二 二 醇乙乙 醚 甲 # 3 ▲D子 酉 I 二基 乙甲 三 2 丙 醚可 丁等 單此 醇 。 二等 *** 三烷 、 咯0 ^ 乙 2 單- 醇二 乙N 三 酉 基 甲 子 粒 之 層 受 容 墨 油 。成 用構 使使 合 ， 混時 上層 以受 種容 二墨 可油 亦述 ，上 用成 使形 獨於 單 訂-- 經濟部智慧財產局員工消費合作社印製 基版 於凹 覆相 塗照 液用 覆使 塗可 之常 散通 分 ， 、 制 解限 溶的 份別 成待 成有 構没 等 ， 脂法 樹方 性的 塑面 熱表 及材 、逆 式可 方 、 覆式 塗方 霧覆 噴塗 , 合 式混 方 、 漬式 浸方 、覆 式塗 方刀 覆氣 塗空 觸 、 接式 、方 式覆 方塗 覆幕 塗簾 飾以 電予 C 於準 法用基 方使為 等，05 式制1 方限 覆的Is 塗別U 部特率 凸有過 、沒透 式度線 方厚光 覆之全 塗層之 棒受料 、容材 式墨錄 方油記 覆述時 塗上板 棍 看-22- 520331 A7 B7 V. Description of the invention (21-point boiling point, high temperature, dry and dry, low temperature, low temperature, low temperature, low temperature, low temperature The plastic heat compounding, and the dissolving agent or the melted milky tree plasticity heats the forming layer when the plastic is heated. The high school super bright tack is melted into the melted fat and mixed with the tree. Hot example, the point where the agent is dissolved and the agent is soluble, and the high water content is boiled by the water to dissolve and dissolve the heat. Bulk dispersing is based on heat preservatives, and the addition of the post-equipment esters 5 in the solvent method enjoys 1 、 as the boiling point of the alcohol on the alcohol, and the alcohol in the strip is obviously as soluble in the boiling point of the agent as in this example. Above the water, ° C alcohol ethylene glycol is used as an example. (Please read the precautions on the back to write this page). Fill with ether ether mono-mono-alcohol alkyd diethylene glycol ethyl, diethanol, mono-diethyl ether alcohol ethylene glycol. Polyethylene glycol, alcohol glycol di, diethyl ethylene diacetate Ethyl alcohol, methyl alcohol monomethyl monopropanol, diethylene glycol ethyl ether methyl # 3 ▲ D 酉 酉 I dimethyl ethyl trimethyl 2 propyl ether cobutane and other mono alcohols. Second class ether trioxane, slightly 0 ^ B2 Mono-Alcohol Diethyl N Tris-methyl base grains contain ink. The composition is used to mix together, and the upper layer is mixed to contain the same amount of ink. It is also used to make the shape unique to the order- -The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the basic version on the concave photocoated coating liquid to make Tu Ke's regular dispersal, and the solution to limit the solution should be structured, etc. Plastic surface heat meter and material, reverse can square, overlay square spray coating, combined mixed square, stain dip square, overlaid square knife air coating air touch, contact, method overlaid curtain The coated curtain is decorated with electricity and C. The base method is used in the quasi-method. The 05-type system is coated with 1-side Is coated. The coated part of the U part has a convex rate, and the transparent coating has a thick and light coating. Ink and square ink recorder with materials and materials

K 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 B7 2 2 五、發明說明（） 測定）以1 5〜6 ϋ %較佳。若全光線透過率大於6 U時，不 透明度不足且做為電飾看板使用時會産生發色性不足的 問題，而若全光線透過率小於1 5 %石油於不透明性過高， 做為電飾看板使用時為印刷部分太黑而無法得到鮮明的 畫像。此外，油墨容受層之厚度過少時油墨吸收容量不 足。基材表面之塗覆液的塗覆量係視所使用的構成成份 種類或配合比例、溶劑等適當地設定，以5 g / in 2〜1 0 0 g / m 2時較佳。另外，本發明之記錄材料的總厚度，在 不會損及本發明作用範圍下沒有持別的限制。 使油墨容受層在基材之一側上形成時，油墨容受層與 反側之基材表面上，視其所需進行各種加工。該加工例 如形成帶電防止層、黏接層、筆記層等。 本發明之記錄材料由於具有上述油墨容受層構成，可 使用於藉由噴墨記錄方式之畫像形成用，尤其是使用於 藉由約性油墨之噴墨記錄方式之畫像形成用。而此藉 由在本發明之記錄材料上形成畫像時，可自非畫像形成 方向照射光，自畫像形成方向視認得電飾看板。 此外，油墨容受層之黏接劑樹脂可添加一些水溶性或 水膨漲性樹脂，其量俗以所配合的黏接劑樹脂對常溫之 樹脂固體而言不會吸水10 %以上較佳。若吸水10 %以上時 ，無法得到本發明之捲曲值、耐水表面強度等。水溶性 或水膨漲性樹脂之配合量以1 5重量％以下較佳，更佳者 為10重量％以下，最佳者為5重量％以下，惟以不配合些 許的黏度調整創者最佳。 - 2 4 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項㈣填寫本頁) I · I I I l· I I I ^ « — — — — — — I— . 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 520331 A7 B7 2 3 五、發明說明（） 油墨容受層中在不損及油墨吸收能力與其他物性之範 圍下亦可添加各種添加劑。例如螢光染料、螢光增白劑 、可塑劑、紫外線吸收劑、顔料分散劑、抑泡劑、消泡 劑、防腐劑等。 設置油墨容受層之方法没有特別的限制，通常可使用 照相凹販塗覆方式、接觸塗覆方式、浸漬方式、噴霧塗 覆方式、簾幕塗覆方式、空氣刀塗覆方式、混合塗覆方 式、可逆輾塗覆方式、棒塗覆方式、凸部塗覆方式等之 方法。 在設有油墨容受層之反面上視其所需方可以進行各種 加工。例如有帶電防止層、黏接層、筆記層等。 (油墨） 對本發明之記錄材料而言所使用的油墨為油性者即可 ，可使用使染料或顔料溶解或分散於溶劑中者。 油性油墨所使用的染料例如有萘醇染料、偶氮染料、 金屬錯鹽染料、陛啉染料、硝基染料、®酲染料、陛亞 胺染料、靛籃染料、亞硝基染料、苯并酲染料、陽磺離 子染料、萘酲染料、萘醯亞胺染料、酞菁藍染料等之油 溶性染料。 油性油墨所使用的顔料例如有鋁粉、青銅粉、炭黑、 氧化鈦、氣化鐵、氣化鋅、氣化鋁白、氧化鐵紅、硫酸 鋇、碩酸鈣、碩酸鎂、黏土、群青、黃鉛、鈷藍、深籃 等之無機顔料，堅牢黃G、堅牢黃1GG、二偶氮黃AAA、 二偶氮黃AAMX、二偶氮黃AAOT、二偶氪黃AAOA、原硝基 -2 5 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） •---------------- (請先閱讀背面之注意事^^填寫本頁) 訂·· 520331 2 4 A7 B7 五、發明說明（ 苯胺橘、二硝基苯胺橘、二偶氮橘、二偶氮橘PMP、烏 爾康橘、甲苯胺红、氯化帕拉紅、萘醇胭脂紅F B、萘醇 紅Μ、艶堅牢紅、萘醇紅2 3、派拉左隆員紅、鋇紅2 B、 鈣紅2 Β、锶紅2 Β、錳紅2 Β、銀力索爾紅、色澱紅C、艶 胭脂紅6 Β、色素猩紅3 Β、色殿黑1 0 Β、安索辛3 Β色澱、 安索辛5Β色澱、若單明6G色澱、曙紅色澱、萘醇紅FGR 、若單明Β色澱、甲基紫色澱、吡吖酮紅k、二噁嗪紫、 維多利亞純籃B0色澱、基本藍5B色澱、基本藍6G色澱、 太菁籃、堅牢籃、鹼藍G調色劑、鹼藍R調色劑、孔雀 藍色澱、反射籃2 G、反射籃R、艶線色澱、鑽石緣硫黃 素色澱、酞菁綠G、綠鈷、酞菁綠Y、苯胺籃、炭黑、日 光螢光顔料、珍珠顔料。 油性油墨所使用的溶劑就對噴嘴頭特性之適合性、安 全性、乾燥性而言選擇各種溶劑，視其所需可使用混合 數種溶劑。該溶劑例如有正己烷、正庚烷、橡膠揮發 油、石油溶劑等之脂肪族烴類，甲苯、二甲苯、溶劑油 請 先 閱 讀 背 面 之 注 意 事 項K This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 520331 A7 B7 2 2 V. Description of the invention () Measurement is preferably from 15 to 6%. If the total light transmittance is greater than 6 U, the opacity is insufficient and it will cause insufficient color development when used as an electric decorative signboard. If the total light transmittance is less than 15%, oil is too opaque and it is used as electricity. The kanban is too dark for the printed part when using it to get a vivid portrait. In addition, when the thickness of the ink receiving layer is too small, the ink absorption capacity is insufficient. The coating amount of the coating liquid on the surface of the substrate is appropriately set depending on the type of the component used, the mixing ratio, the solvent, etc., and it is preferably 5 g / in 2 to 100 g / m 2. In addition, the total thickness of the recording material of the present invention is not limited insofar as it does not impair the scope of the present invention. When the ink receiving layer is formed on one side of the substrate, the ink receiving layer and the surface of the substrate on the opposite side are subjected to various processes as required. This processing is, for example, forming a charge prevention layer, an adhesive layer, a note layer, and the like. Since the recording material of the present invention has the above-mentioned ink-receiving layer structure, it can be used for image formation by the inkjet recording method, especially for image formation by the inkjet recording method of the ink. In this case, when an image is formed on the recording material of the present invention, light can be irradiated from a direction other than the image formation direction, and the electric decoration sign can be visually recognized from the image formation direction. In addition, the adhesive resin of the ink receiving layer may be added with some water-soluble or water-swellable resins. The amount of the adhesive resin used is generally not more than 10% of water absorption for normal temperature resin solids. If the water absorption is 10% or more, the curl value and water-resistant surface strength of the present invention cannot be obtained. The compounding amount of water-soluble or water-swellable resin is preferably 15% by weight or less, more preferably 10% by weight or less, and the most preferable is 5% or less, but it is best to adjust the amount of the viscosity without a slight viscosity adjustment. . -2 4-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the notes on the back first and fill in this page) I · III l · III ^ «— — — — — — I—. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 520331 A7 B7 2 3 V. Description of the invention () The ink receiving layer does not damage the ink absorption capacity and other physical properties Various additives can also be added within the range. For example, fluorescent dyes, fluorescent whitening agents, plasticizers, ultraviolet absorbers, pigment dispersants, foam inhibitors, defoamers, preservatives, and the like. The method for setting the ink receiving layer is not particularly limited. Generally, a photogravure coating method, a contact coating method, a dipping method, a spray coating method, a curtain coating method, an air knife coating method, and a hybrid coating can be used. Method, reversible coating method, rod coating method, convex coating method, and the like. Various processes can be performed on the reverse side provided with the ink-receiving layer as required. For example, there are a charge prevention layer, an adhesive layer, a note layer, and the like. (Ink) The ink used for the recording material of the present invention may be an oily one, and a dye or a pigment may be dissolved or dispersed in a solvent. The dyes used in oil-based inks are, for example, naphthol dyes, azo dyes, metal salt dyes, perylene dyes, nitro dyes, fluorene dyes, fluorene imine dyes, indigo dyes, nitroso dyes, and benzofluorene. Oil-soluble dyes such as dyes, sulfonate dyes, naphthalene fluorene dyes, naphthalene limine dyes, phthalocyanine blue dyes, and the like. Pigments used in oil-based inks include, for example, aluminum powder, bronze powder, carbon black, titanium oxide, vaporized iron, zincized gas, vaporized aluminum white, iron oxide red, barium sulfate, calcium sulphate, magnesium sulphate, clay, Ultraviolet, yellow lead, cobalt blue, deep basket and other inorganic pigments, Fast Yellow G, Fast Yellow 1GG, Diazo Yellow AAA, Diazo Yellow AAMX, Diazo Yellow AAOT, Diazo Yellow AOAA, Protonitro -2 5-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) • ---------------- (Please read the notes on the back first ^^ Fill in this page) Order ... 520331 2 4 A7 B7 V. Description of the invention (aniline orange, dinitroaniline orange, diazo orange, diazo orange PMP, urkan orange, toluidine red, chlorinated para Red, naphthol carmine FB, naphthol red M, sturdy fast red, naphthol red 2 3, Parazomron red, barium red 2 B, calcium red 2 Β, strontium red 2 Β, manganese red 2 Β, Silver Lithol Red, Lake Red C, Carmine Red 6 Β, Pigment Scarlet 3 Β, Sedian Black 1 0 Β, Anthoxin 3 Β Lake, Anthoxin 5B Lake, Ruo Danming 6G Lake , Eosin Lake, Naphthol Red FGR, Ruo Danming B color , Methyl purple lake, pyracridone red k, dioxazine violet, Victoria pure basket B0 lake, basic blue 5B lake, basic blue 6G lake, Taijing basket, fast basket, alkali blue G toner, Alkali Blue R Toner, Peacock Blue Lake, Reflective Basket 2 G, Reflective Basket R, Sineline Lake, Diamond Edge Thioflavin Lake, Phthalocyanine Green G, Green Cobalt, Phthalocyanine Green Y, Aniline Basket, Carbon black, fluorescent fluorescent pigment, pearl pigment. Solvents for oil-based inks are selected from various solvents in terms of the suitability, safety, and dryness of the characteristics of the nozzle head, and several solvents can be mixed according to their needs. This solvent For example, there are aliphatic hydrocarbons such as n-hexane, n-heptane, volatile rubber oil, petroleum solvents, etc. Toluene, xylene, and solvent oil, please read the notes on the back first

頁 訂 由 劑 溶 / 號 3 由 劑 溶 f 號 2 油 劑 溶 f 號 由 劑 溶 經濟部智慧財產局員工消費合作社印製 、二 醇乙 丙 ， 異類 、醇 醇等 丙醇 正己 、環 醇基 乙甲 I f 2 醇 、 甲醇 ， 己 類環 烴 、 族醇 香 Γ癸 芳三 等 、 滿醇 萘 丁 、 正 二乙 、 丙單醚 二 ，乙 、 醇單 醇二醇 二乙二 丙醚乙 、 甲二 醇單 、 二醇醚 乙二甲 聚乙單 、 ，醇 醇醇二 二三乙 乙 ί 二 三醇 、 、之醚 醇等丁 二醇單 乙三醇 二丙二 、 、 乙 醇醇醚 乙 、 基酯 乙酸 單乙 醇基 二 甲 乙 S早 、醇 酯二 酸乙 乙二 醚 、 甲酯-單酸26 醇乙_ 二基 乙丁 、 單 0 醇 丁 二 醇乙 二 、 乙酯 二酸 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 五、發明說明（25) 二乙二醇單乙基乙酸酯、二乙二醇單丁基乙酸酯等之醇 醚〜醇單酯類，醋酸乙酯、醋酸異丙酯、醋酸正丁酯等 之酯類，丙酮、甲基乙酮、甲基異丁酮、環己酮、異佛 爾酮、二丙酮醇等之酮類等。 油性油墨例如以保存安定性、耐摩擦性爲目的時，例 如可添加聚丙烯酸酯、亞麻仁由改性的烷基化物樹脂、 聚苯乙烯、松香系樹脂、轉變苯酚係樹脂、烷基苯酚改 性二甲苯系樹脂等樹脂，且可添加例如可塑劑、石蠟、 乾燥劑、分散劑、增黏劑、凝膠化劑、觸變劑、消泡 劑、抑泡劑、沉澱防止劑、擴張防止劑、乾燥抑制劑、 抗氧化劑、平滑劑、防蟎劑、紫外線吸收劑、消艷劑、 帶電防止劑、安定劑、難燃劑、表面張力調整劑、界面 活性劑、黏度調整劑等之添加劑。 如此所得的記錄材料尤其是使用油性油墨之噴墨記錄 方式中，可予以無滲透、鮮明地記錄，且形成耐水性佳 的畫像。而且，本發明之記錄材料係油墨容受層爲多孔 質層，且亦可使用做爲使用水性油墨之記錄材料。 於本發明中藉由使記錄材料在外徑爲5cm心10cm之筒 上捲成5m〜100m，可容易地設定印表機。 實施例 於下述中以實施例說明本發明，惟本發明不受此等實 施例所限制。而且，實施例之「份」或「％」沒有特別限 制時，係指重量份及重量％。 <評估方法>Page order by agent solution / No. 3 by agent solution f No. 2 Oil agent solution f No. printed by agent consumer cooperative of Intellectual Property Bureau of Ministry of Economic Affairs, glycol ethylene propylene, isopropyl alcohol, isopropyl alcohol, etc. Ethyl alcohol I f 2 alcohol, methanol, hexane cyclic hydrocarbons, alcohol Γ decaryl tertiary, full alcohol naphthalene, n-diethyl ether, propylene monoether diethylene glycol, alcohol monool glycol diethylene glycol diethyl ether Diethylene glycol, glycol ethers, ethylene glycol, polyethylene glycol, alcohols, alcohols, diethylene glycol, triethylene glycol, ether alcohols, butylene glycol monoethylene glycol, dipropylene glycol, ethanol alcohol ether, Ethyl Acetate Monoethanol Methyl Ethyl Ester, Alcohol Ethyl Diethylene Ethyl Ester, Methyl Ester Diethylene Ethyl Ether Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 520331 V. Description of the invention (25) Alcohol ethers such as diethylene glycol monoethyl acetate, diethylene glycol monobutyl acetate, etc. Alcohol monoesters, ethyl acetate, isopropyl acetate, n-butyl acetate, etc. Acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and the like, isophorone, diacetone alcohol, etc. ketones. For oil-based inks, for example, for the purpose of storage stability and abrasion resistance, for example, polyacrylate, linseed modified alkylate resin, polystyrene, rosin-based resin, conversion phenol-based resin, and alkylphenol can be added. Resins such as xylene-based resins, and plasticizers, paraffin waxes, desiccants, dispersants, tackifiers, gelling agents, thixotropic agents, antifoaming agents, antifoaming agents, precipitation inhibitors, and expansion prevention agents can be added. Additives, drying inhibitors, antioxidants, smoothing agents, anti-mite agents, UV absorbers, anti-dazzling agents, antistatic agents, stabilizers, flame retardants, surface tension modifiers, surfactants, viscosity modifiers, etc. . The recording material obtained in this way, in particular, an ink jet recording method using an oil-based ink, can be recorded without bleeding, with sharpness, and can form an image with excellent water resistance. Further, the recording material of the present invention is a porous ink receiving layer, and can also be used as a recording material using an aqueous ink. In the present invention, a printer can be easily set by rolling a recording material on a cylinder having an outer diameter of 5 cm and a diameter of 10 cm to 5 to 100 m. Examples The present invention is illustrated by the following examples, but the present invention is not limited by these examples. In addition, when "part" or "%" in the examples is not particularly limited, it means parts by weight and% by weight. < Evaluation method >

-27- 520331 A7 B7 五、發明說明（26 ) 方 述 下 以 偽 料 材 錄 記 的 作 製 所 例 較 比 及 例 施。 實估 述評 下行 以進 法 像 畫 的 成 形 所 墨 油 性 油 由0 ---V 1—I 質 品 錄 記 之 料 質材 品錄 字記 印 i .1 紅 P ( od色 72次 度二 像 、 解 2 ^一 曰/In 而ml 料24 材為 錄約 記大 對最 用色 使單 使 至 整大 調最 傺丨 量 墨 油 藍 綠-27- 520331 A7 B7 V. Comparison of the examples and implementations of the recordings made with fake materials under the description of the invention (26). The actual evaluation and review of the ink-forming oil in the formation of the progressive image painting from 0 --- V 1-I quality record material quality material record character print i .1 red P (od color 72 times second image , Solution 2 ^ 一 曰 / In and ml material 24 materials are recorded for the most important use of the color to make the most important, the most important 丨 the amount of ink blue and green

噴 I 式機 方表 \)/ 印 墨 噴 頓製 馬丨 迪 恩業 ?τ 學 光 斯 洛帕 耶林 皮歐 之 射 2 噴 ffl // ， ml機 48表 為印 勺 S 墨 油 料 顔 性 S畫’ 用 i ο 捅 6 與 7像Spray I-type machine square table \) / Ink jet printing horse 丨 Dean industry? Τ Xueguang Slopeyepelio shot 2 spray ffl //, ml machine 48 table is printing spoon S ink oil color S draw 'with i ο 捅 6 and 7 like

音 S幸 -iD 股 斯 富 頗 耶 庫 克 在 且 畫 調 片 照 之 像 畫 錄 記音 為譯 /V 做 刷 印 之 料 材 錄 記 自 上 台 觀 視 巨 以 且 準 基 之 述 下 以 光 過 透 由0 光 射 照 面 。 錄像 記畫 非察 平 水 的 題 異 問 優 佳 為異不 極優性 性性色 色色發 發發許 、、稍 明明有 鮮鮮沒 ® 〇 △ 性 2 色質 發品 乏錄 缺記 或之 明 料 鮮材 不錄 : 記 \—/ X i 度 像 解 使 且 2 / 1L 之J 1 湏 質觀 品地 錄同 記相 為 1 定質 設品 量錄 墨記 油與 出 ， 吐外 使P1 除od 6 3 為 (請先閱讀背面之注意事項寫本頁〕 |.:裝 寫太 訂---------- 經濟部智慧財產局員工消費合作社印製 墨 油 料其 材馬 錄米 記用 法 方 驗 試 與 正 1 Η 13像 2-畫 JV錄 製記 丨為 做 刷 古印 質林地 品阿同 錄尼相 記基1) 之恩ί 音 譯 以 斯光 雷過 頓透 耶由 S. § 0 為 克 ， 在光 ， 射 圖照 插面 與錄 像記 畫非 調之 音 譯 下 料視 材目 錄以 記且 自準 上基 台之 丨逑 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 __________ B7 五、發明說明（27) 觀察β ® ··鮮明、發色性極為優異 〇 :鮮明、發色性優異 △:沒有稍許發色性不佳問題的水平 X :不鮮明或缺乏發色性 (1 V ) 錄材料之記錄品質4 (藉由水性染料油墨所形成 的畫像） 使用耶布松（譯音）製Ρ Μ — 7 Q G c及其純正油墨，與上 述試驗方法（1)相同地印刷做為記錄畫像之照片調畫像 與 插 晝 ，且 在 克 庫 耶 頗 富 斯 (譯音） 台 上 白 記 錄 材 料 之 非 記 錄 面 照射 光 9 藉 由 透 過 光 以 下述 之 基 準 且 以 巨 視 觀 察 畫 像 〇 © :鮮 明 、 發 色 性 極 為 優 異 〇 :鮮 明 \ 發 色 性 優 異 △ :没 有 稍 許 發 色 性 不 佳 問題 的 水 平 X :不 鮮 明 或 缺 乏 發 色 性 (請先閱讀背面之注意事_填寫本頁) 丨裝 訂： 經濟部智慧財產局員工消費合作社印製 (V )記錄材料之記錄品質5 使用歐林帕斯光學工業製噴墨印表機πρ_ 3 600及 純正顏料油墨，以半7 20 dp i型印刷做爲記錄畫像之照片 e周畫像與插晝’且在電飾裝置上自非印刷面照射光，以 目視觀察。 ® :鮮明、發色性極為優異 〇：鮮明、發色性優異 △ ··沒有稍許發色性不佳問題的水平 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 五、發明說明（28) X :不鮮明或缺乏發色性 (v i )記錄材料之印自品質6 使用歐林帕斯光學工業（股）製噴墨印表機i〗p_ 3600及 純正顏料油墨，以半720dp 1型印刷做爲記錄畫像之照片 調畫像及插畫，且在電飾裝置上自非印刷面不照射光’ 以目視觀察。 ◎:鮮明、發色性極爲優異 〇：鮮明、發色性優異 △:沒有稍許發色性不佳問題的水平 X :不鮮明或缺乏發色性 (2)厚度 藉由下式求取記錄材料之厚度、由除去油墨容受層後 之厚度求取基材之厚度與油墨容受層之厚度。 (油墨容受層之厚度）=(記錄材料之厚度）- (除去油墨容受層後之厚度） (基材之厚度）=(除去油墨容受層後之厚度） (3 )捲曲値 切取二張20cm X 20cm大小之記錄材料評估用試樣，且 在台紙上將一張評估試樣至於油墨容受層側下、另一 張則至於油墨容受層側上之狀態下，於2(TC /60%RH之 -30- 520331 A7 經濟部智慧財產局員工消費合作社印製 _B7_五、發明說明（29) 環境下放置2 4小時且求取自白紙之4角高度最大值做 為處理前之捲曲值。此時，使油墨容受層為内側、捲 曲者為正值，油墨容受層為外側、捲曲者為負值。同 樣地測定1 5 °C / 6 0 % R Η、3 G °C / 8 0¾ R Η之捲曲值。 (4 )搬送性 使歐林帕斯光學工業製噴墨印表機IJP-360Q及914πιπι 巾 Χ30ιη 捲之記錄材料在 15°C/20；UH、20°C/60%RH、 30°C / 8 0%RH之環境下各放置24小時後，印刷3Gm全黑 部分且可沒有問題地印刷者為〇、噴嘴頭與記錄材料 摩擦且記錄材料壞掉者為X。 (5 )切斷性 以切斷器切斷記錄材料時沒有發生粉落情形者為〇、 有稍許粉落情形者為△、有多量粉落情形者為X。 (6 )基材之至光線透過率 記錄材料所使用的基材，以J I S K - 7 1 G 5為基準測定全 光線透過率 (7 )記錄材料之全光線透過率 有關記錄材料，以J I S K - 7 1 0 5為基準測定全光線透過 率。 (8 )記錄材料之耐水性 有關記錄材料傺在2 3 °C之水中浸漬2 4小時後，以手指 來回擦拭數次，於2 3 °C之環境下自然乾燥2 4小時後以 目視且以下述之基準與沒有浸漬水中者比較。 Ο :沒有差別 -3 1 - (請先閱讀背面之注意事項,填寫本頁'> i 裝 訂--------- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 A7 B7 五、發明說明（30音 S 幸 -iD shares Sifupoye Cook in the picture of the tone of the picture, the sound recording is translated / V The material of the printing is recorded from the stage of the giant and the basis of the description See through the surface with 0 light. The video recordings are based on non-approved questions. The best and the best are the different sexes. The hair color is faint, slightly clear and fresh. 〇 △ Sex 2 There is no record or lack of freshness in the color The material is not recorded: record \ — / X i degree image solution and 2 / 1L of J 1 观 quality view and quality record with the same phase as 1 qualitative set quantity record ink and oil, and spit out P1 except od 6 3 For (Please read the notes on the back first to write this page) | .: Pre-ordering ---------- Printed ink and oil materials by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Usage test and positive 1 Η 13 like 2-painting JV recording 丨 for making ancient printed woodland products A Tongluni Jiji 1) The transliteration of Isaac Lei thunderton Dunya by S. § 0 is gram, non-transliterated transliteration of the photo, radiograph, and video recording. The material list is recorded and recorded on the abutment. 逑 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 520331 A7 __________ B7 V. Description of the invention (27) Observe β ® ·· Brightness and color development Excellent 〇: Brightness and excellent color development △: Level with no slight problem of poor color development X: No sharpness or lack of color development (1 V) Recording quality of recording material 4 (Image formed by water-based dye ink) Using JP-7 QG c made by Jebson (transliteration) and its pure ink, the same as the test method (1) above was printed as a photo-portrait and cut-in for recording portraits, and in Kukuye Pofus ( Transliteration) The light on the non-recording surface of the white recording material on the stage is 9. The transmitted light is used to observe the image based on the following criteria and macroscopic viewing. ○: Brightness and excellent color development. ○: Brightness and excellent color development. △: No slight hair. Level of poor coloring problem X: Not clear or lacking color development (please read the notes on the back _ fill out this page) 丨 Binding: Recording quality of (V) recording materials printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperatives 5 Uses Olympus Optical Industrial Inkjet Printer πρ_ 3 600 and Pure Color Ink, semi 7 20 dp i-type printing the portrait photograph recorded as e circumferential and interpolated day portrait 'and decorated on the electrical device irradiating light from the non-printed surface was visually observed. ®: Brightness and excellent color development 〇: Brightness and excellent color development △ ·· A level with no slight problem of poor color development This paper is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 520331 V. Description of the invention (28) X: No sharpness or lack of color development (vi) The printing quality of the recording material 6 Use inkjet printer made by Olympus Optical Industry Co., Ltd. i_p_ 3600 and pure pigment ink, The semi-720dp type 1 printing was used as the photo adjustment portrait and illustration for recording the portrait, and no light was irradiated from the non-printing side on the electric decoration device. ◎: Brightness and excellent color development. ○: Brightness and excellent color development. △: There is no slight problem of poor color development. X: No sharpness or lack of color development. (2) Thickness. Thickness, the thickness of the substrate and the thickness of the ink receiving layer were obtained from the thickness after removing the ink receiving layer. (Thickness of ink receiving layer) = (thickness of recording material)-(thickness after removing ink receiving layer) (thickness of base material) = (thickness after removing ink receiving layer) (3) Curling and cutting two 20cm X 20cm size recording material evaluation samples, and place one evaluation sample on the ink receiving layer side and the other on the ink receiving layer side at 2 (TC / 60% RH of -30- 520331 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs_B7_ V. Description of the invention (29) Place it in the environment for 2 4 hours and obtain the maximum value of the 4 corner height from the white paper as a treatment The previous curl value. At this time, the ink receiving layer is inside, the curl is positive, the ink receiving layer is outside, and the curl is negative. Similarly, measure 15 ° C / 60% R Η, 3 G ° C / 8 0¾ R 卷曲 curl value. (4) Transportability makes Olympus Optical Industry inkjet printer IJP-360Q and 914πιι towel X30ιη roll recording material at 15 ° C / 20; UH, After being left for 24 hours in an environment of 20 ° C / 60% RH and 30 ° C / 8 0% RH, 3Gm all black parts can be printed without any problem. If the nozzle head rubs against the recording material and the recording material is damaged, it is X. (5) Cut-off property: When the recording material is cut by a cutter, there is no occurrence of powder fall, ○, if there is a slight powder fall, △, there is a large amount The case of powder fall is X. (6) The base material to the light transmittance of the recording material is measured on the basis of JISK-7 1 G 5 (7) The total light transmittance of the recording material is related For recording materials, the total light transmittance was measured based on JISK-7105. (8) Water resistance of the recording materials. Record materials: immersed in water at 2 ° C for 24 hours, then wiped back and forth with your fingers several times. Dry naturally at 2 3 ° C for 24 hours, then compare with those without immersion in water visually and according to the following criteria. 〇: No difference-3 1-(Please read the precautions on the back and fill in this page '> i Binding --------- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 520331 A7 B7 V. Description of the invention (30

準 水 的 題 問 有 沒 在 惟別 ，差 化的 變顯 有明 稍有 △ X 度 .Ε 強 面 表 之 料 材 錄 記 尼 將 偽 料 材 錄 記 穿,?' 有 墨 油絆 ί基 容 容 墨 由 於 覆 阽 帶 } 膠 層製 受丨 tttt- 離 剝 地 〇 緩估 緩評 後以 時予 小準 一 基 置之 放述 下下 境以 環 ， 之帶 °c膠 23察 在 觀 ，視 面目 表以 層 且 受 ，The question of quasi-water is not the same, the difference becomes obvious with a slight △ X degree. Ε The material record of the strong surface is recorded by the fake material,? ' The ink is covered by the tape} The glue system is subject to tttt- stripping off the ground 〇 After the slow evaluation, the time is given to Xiaozhun Yiji, and the bottom circle is described. The tape ° 23 Faces are layered and affected,

〇 △ X 墨容 油墨 之油 料之 材料 錄材 記錄 著記 附許 有稍 沒有 側 側 帶帶 膠 在在 墨 油 之 料 材 錄 記 著 附 面 全 側 帶 膠 在 著 層附層 受層受 容受容 轉 璃音 玻譯 /(\ 之 脂 樹 性 塑 熱 的計 用量 使熱 所型 層描 受掃 容差 墨式 油用 0)使 度 溫 移 馬 魯 耶 金 巴 製 司 公 型 以 5m溫。 使室g) T ， 自 ( )，度 後溫 冷移 急轉 、璃 解玻 溶定 脂測 樹 ， 性溫 塑昇 熱度 的速 用溫 使昇 所之 料分 材/ 錄 記 °c 機 表 印 墨 噴 製 業Η 度學 濃光 色斯 發帕 之林 過歐 透用 1)使 1 iil-n VA {度 黑濃 全斯 型倍 P 克 ο 馬 2 7 用 半使 以 ， ，後 墨燥 油乾 料然 顔自 性時 油小 刷 印 測 及fi定 正 純 § 全 • I,----------^11^·裝---------訂---------^_wi · (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 機 表 印 墨 噴 製 業Η 度學 。濃光 度色斯 濃發帕 過之林 透射歐 之反用 分2)使 部(1 % R ο Τ 1 iilis K {度 黑濃 全斯 型倍 P1克 od馬 2 7 用 半使 以 ， 0 ， 後度 墨燥濃 油乾射 料然反 顔自之 性時分 油小部 正 2 黑 純且全 及，定 00刷測 6 7 3 印 2 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（31 ) (1 3 )耐水濃度保持率 使用歐林帕斯光學工業製噴墨印表機及純正油墨予以 全黑印刷，且在2 0 °C、濕度6 (U之環境下放置2 4小時， 乾燥後測定記錄材料之發色濃度。然後，將記錄材料切 成5 0 m m X 5 0 m m，在水中浸漬一小時後使用J I S L - 0 8 4 9所 記載的摩擦試驗基I I型，來回5 0次進行摩擦試驗。此時 摩擦子之質量為2Q(]g、移動距離為lGGinni、移動速度每 分鐘3 0次來回、摩擦用纱布偽為二張重疊的日本藥局方 形I。於摩擦試驗後輕輕地在流水下洗淨，再於保持於 1 6 0 °C之乾燥器中乾燥3分鐘後測定發色濃度。耐水濃 度保持率偽藉由下式求取。 耐水濃度保持率（％ ) =[(試驗後發色濃度）/(試驗而發色濃度）j X 1 0 0 (1 4 )塗覆量 將記錄材料切成2 0 c m X 2 0 c di之大小且藉由油墨容受層 中除去溶劑前後之重量差，計算、求取油墨容受層之塗 覆量。 塗覆量U/m2 )=[(除去前之重量）-(除去後之重量）] / ( 0 . 2 X 0.2) (1 5 )野外展示性 使上述（1 )所印刷的記錄物質在野外展示一週（其中兩 天為雨天）後，以目視判斷畫像變化，〇為沒有變化、 △為變化但沒有實用上的問題、X為變化且有實用上的 問題。 -33- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------裝--- (請先閱讀背面之注咅心事項Hi寫本頁> · 520331 Α7 Β7 五、發明說明（32) (實施例1 ) <透明基材之調製> 將特性黏度0 . 6 2之具對苯甲酸乙烯酯樹脂（P E T )投入2 軸螺旋押出機，藉由T -塑模在2 9 0 °C熔融押出，且於冷 卻回轉棍中靜電地密接硬化，製得P E T之為拉伸薄膜。 再使該為拉伸薄膜以棍拉伸機，加熱至9 0 °C ( T g + 1 5 °C ) 進行3 . 5倍縱拉伸，再以拉幅器加熱至1 4 Q °C進行3 . 7倍 橫拉伸後，在2 3 5 °C緩和4 %且予以熱處理以製得薄膜。 所得薄膜之厚度為1 0 0 A in ,全光線透過率為9 Q %之聚酯 糸樹脂薄膜。 <粒子分散液、界面活性劑稀釋液之調製> 添加水使粒子（富士西里西亞（譯音））4 5 G成固成份濃 度2 0重量％，使用均混器以5000 r pm分散30分鐘，做成 粒子分散液A。以同量的異丙醇溶解界面活性劑（大日本 油墨製梅卡法克（譯音）F - 1 4 4 D ),另以水予以5倍稀釋 ，作成固成份濃度為10重量％之界面活性劑。 <塗液之作成> 原料及其混合重量比 離子交換水 3 . 7 3份 粒子分散液A 6 8 . 7 8份 熱塑性樹脂 2 6 . 9 7份 (東洋紡績（股）拜羅那魯（譯音）M D 1 1 0 0、固成份濃度 3 0¾) 一 34- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝.----：----訂--------- 經濟部智慧財產局員工消費合作社印製 520331 五、發明說明（33) 螢光增白劑 0 · 1 1份 (千葉特別、化學製Uv i t eEBF250% ) 界面活性劑稀釋液B 0 · 4 1份 使上述材料混合攪拌，作成塗液。 <記錄材料之作成> 在上述 < 基材之調製 > 所得之厚度100//m之基材上使 用微調照相凹版印刷塗覆上述塗液，在1 00°C下通過風 量10m/sec之乾燥區20秒，然後，在160 °C下通過風量 2 0m/sec之乾燥區40秒予以乾燥，製得記錄材料。油墨 容受層之厚度爲55//m。 (實施例2〜1 1 ) 除基材之厚度及油墨容受層之厚度如表1所希外 ^ 實施例1相同地製得記錄材料。 ^ (比較例1〜3 ) · 除使樹脂爲部份皂化聚乙二醇（克拉雷（譯音 ;^ Ρ V A - 217)，基材之厚度、油墨容受層之厚度如表丨 所不外， 與實施例1相同地製得記錄材料。結果如表] 丄所示。 -35- 520331 *A7B7 五、發明說明（34) 經濟部智慧財產局員工消費合作社印製 表1 基材 iWX ("m) 油墨 層厚 度 ("m) 捲曲値(mm) 搬送性 印刷特性 切割 11: 15°C 20% 2QX: 60% 10°(： 80% I5°C 20% 2(Γ(' 60% M)V 80% 丨;丨1跺 1 實施 例1 100 55 -2 一 2 一 2 〇 〇 〇 〇 〇 〇 實施 例2 100 75 -2 -2 一 3 〇 〇 〇 〇 〇 〇 實施 例3 100 100 -2 -2 —4 〇 〇- 〇 〇 〇 〇 實施 例4 50 55 -2 -2 一 4 〇 〇 〇 〇 〇 〇 實施 例5 50 80 -1 一 2 -4 〇 〇 〇 〇 〇 〇 實施 例6 50 100 2 0 0 〇 〇 〇 〇 〇 〇 實施 例7 188 55 0 0 一 1 〇 〇 〇 〇 〇 〇 實施 例8 188 85 -1 0 一 1 〇 〇 〇 〇 〇 〇 實施 例9 188 100 -1 -1 -6 〇 〇 〇 〇 〇 〇 實施 例10 100 45 -2 -2 -2 〇 〇 〇 〇 〇 〇 實施 例11 100 40 一 2 -2 -2 〇 〇 〇 X 〇 〇 比較 例1 100 80 + 90 -21 -120 X X X 〇 〇 〇 比較 例2 100 20 + 15 -2 -13 〇 〇 〇 X X 〇 比較 例3 225 80 + 18 —7 + 16 X X X 〇 〇 〇 -36 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------裝--------訂--- (請先閱讀背面之注意事項再填寫本頁) 520331 A7 B7 五、發明說明（35) (實施例1 2 ) <透明基材之製造> 與實施例1相同地製得透明基材。 <油墨容受層用熱塑性樹脂之製造> 在具備有溫度計、攪拌機之壓熱鍋中加入3 5重量份對 苯甲酸、35重量份異苯甲酸、9重量份5 -磺基異苯甲酸 鈉、2 7重量份乙二醇、4 6重量份新戊醇、0 . 1重量份四 甲氧基酞酸酯，於1 8 0〜2 3 (TC下加熱1 2 0分鐘，進行酯 交換反應。然後，使反應条舁溫至2 5 0 °C，条内壓力為 1〜1 0 ni in H g ,繼續反應6 0分鐘，結果製得共聚合聚酯樹 脂（A 1 )。所得的（A 1 )共聚合聚酯樹脂如表1所示，還原 黏度0 . 4 Q d 1 / g、玻璃轉移溫度6 1 °C、其組成藉由N M R分 析的結果，酸成份#為對苯甲酸4 7 . 0莫耳％、異苯甲酸 46. Q莫耳％、 5 -鈉磺基異苯甲酸7.0莫耳％，二醇成份像 為乙二醇50.0莫耳％、新戊醇50.0莫耳％。同樣地製造如 表1所示之共聚含聚酯樹脂（Α2〜Α4)。 表2 (請先閱讀背面之注意事項^^寫本頁) »!裝 訂---------· 經濟部智慧財產局員工消費合作社印製 A1 A2 A3 A4 對苯甲酸 47 49 50 97.5 異苯甲酸 46 48.5 47.5 5-磺基異苯甲 酸 7 2.5 2.5 2.5 乙二醇 50 40 20 新戊醇 50 二乙二醇 60 30 己二醇 70 丙二醇 78 玻璃轉移溫度 CC) 61 42 5 79 還原黏度(dl/g) 0.40 0.78 0.66 0.34 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） _ 3 7 _ 520331 A7 B7 五、發明說明（36 ) (A1)〜（A4)對水之膨漲度為1%以下。 <油墨容受層用熱塑性樹脂之水分散物作成> ------------I!裝 (請先閱讀背面之注意事項寫本頁> 對1 0 0重量份如表1所示之（A 1 )共聚合聚酯樹脂而言， 加入5 0重量份如表2所示之乙二醇一丁醚（沸點1 7 1 °C ) ,昇溫至1 3 0 °C予以溶解後降溫至8 G °C，且予以攪拌、 添加溫水使成固成份濃度為3 U，製得（A 1 )共聚合聚酯 樹脂之（P 1 >水分散物。同樣地配合如表2所示之溶劑， 製得（A 1〜A 4 )共聚合聚酯樹脂之（P 2〜P 1 4 )水分散物。 表3 水分散物 熱塑性樹脂 水溶性溶劑* 乙二醇一丁 醚(171°C)** 三乙二醇一 丁醚 (271°C)** 二乙二醇 (245°〇** 乙二醇一甲 醚(125。〇** P1 A1 50 0 0 0 P2 A1 35 0 0 15 P3 A1 100 0 0 0 P4 A1 125 0 0 0 P5 A1 0 100 0 0 P6 A1 0 0 100 0 P7 A1 50 50 0 0 P8 A1 100 0 0 50 P9 A2 50 0 ' 0 0 P10 A2 15 0 0 35 P11 A2 100 0 0 0 P12 A3 50 0 0 0 P13 A3 70 0 0 0 P14 A4 50 0 0 0 (注)* :對100重量份熱塑性樹脂而言之重量份 :沸點 經濟部智慧財產局員工消費合作社印製 -38- 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） 520331 Α7 Β7 五、發明說明（37) <油墨容受層形成用之塗液作成> 添加水使粒子（富士西里西亞（股）製賽里西亞45Q)成 固成份濃度為20重量％，且使用均混器以5G0Grpm予以 分散3 0分鐘，作成粒子分散液。而且，以酮量異丙醇稀 釋界面活性劑（大日本油墨（股）製梅卡法克F-142Q)，再 以水稀釋成5倍以作成固成份濃度為1 0重量％之界面活 性劑稀釋液。使用該粒子分散液、界面活性劑稀釋液、 上述（A1)油墨容受層用熱塑性樹脂之水分散物、螢光增 白劑（千葉特別化學製ϋ v i t e X E B F 2 5 (U ),以下述之配合 比例配合，作成油墨容受層形成用之塗液。 離子交換水 3 . 7 3份 粒子分散液 6 8 . 7 8份 (A 1 )油墨容受層用熱塑性樹脂之（P 1 )水分散液 2 6 . 9 7份 界面活性劑稀釋液 0 . 4 1份 螢光增白劑 0 . 1 1份 <油墨容受層之形成（記錄材料之作成）> 在上述之基材上以# 6 0鐵絲棒塗覆上述油墨容受層形 成用塗液，在保持於1 6 0°C之烤箱中加熱3分鐘，乾燥 除去溶劑以製得記錄材料。該記錄材料之全光線透過率 為 30·3%〇 實施例1 3〜2 4、比較例1 除油墨容受層用熱塑性樹脂之水分散物如表4所示外 ，與實施例1 2相同地製得記錄材料。此等記錄材料之全 光線透過率為30. 2〜41.1%。 -39 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 請 先 閱 讀 背 之 注 意 事 項〇 △ X The material of the ink material of the ink recording material is recorded with a little adhesive tape on the side. In the ink material recording material, the entire side is glued on the adhesive layer. Zhuan Yinyin translates / (The amount of the resinous plastic heat of the \ makes the thermal layer type scan the scanning tolerance ink oil 0) to make the temperature shift Maruye Kimba company model to 5m. Make the room g) T, from (), after the temperature is changed, the temperature is shifted sharply, the glass is dissolved and the glass is dissolved to determine the fat, the temperature is quickly increased, the temperature is quickly increased, and the temperature is divided into materials / recorded ° c machine table Inkjet printing industry: the science of lightness, color, light, hair, hair, hair, skin, hair, skin, hair, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, skin, beauty, skin, beauty, beauty, beauty, beauty, hair, skin, hair, skin, hair, skin); Dry oil, dry material, natural appearance, small oil brush printing test and fi calibration, pure§ I, ---------- ^ 11 ^ · install --------- order-- ------- ^ _ wi · (Please read the precautions on the back before filling out this page) Department of Economics, Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Cooperatives, Printing Machines, Tables, Printing, Inkjet Printing, and Industrial Science. Luminosity, chroma, thick hair, opaque forest, transmissive, transmissive points, 2) Caution (1% R ο Τ 1 iilis K {Degree black, full-thickness type P1 g od horse 2 7) Use a half to make, 0, After the ink is dry, the oil is dry and the material is negative. When the oil is small, it is 2 black and pure, and it is 00. 6 7 3 is printed. 2 This paper size is applicable to China National Standard (CNS) A4 specifications ( (210 X 297 mm) 520331 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (31) (1 3) Water resistance concentration retention rate Use Olympus Optical Industrial inkjet printer and pure ink It should be printed in black, and left to stand for 24 hours under the environment of 20 ° C and humidity 6 (U), and then measure the color density of the recording material after drying. Then, cut the recording material into 50 mm X 50 mm. After immersing in water for one hour, the friction test type II described in JISL-0 8 4 9 was used to conduct the friction test 50 times. The friction mass at this time was 2Q () g, the moving distance was 1GGinni, and the moving speed per minute. 30 times back and forth, the rubbing gauze was faked into two overlapping Pharmacopoeia square I. Yu friction test Then, it was washed gently under running water, and then dried in a dryer maintained at 160 ° C for 3 minutes, and then the hair color concentration was measured. The water resistance concentration retention rate was calculated by the following formula. Water resistance concentration retention rate (% ) = [(Color density after test) / (color density after test) j X 1 0 0 (1 4) Coating amount Cut the recording material into a size of 20 cm X 2 0 c di and pass the ink volume The weight difference before and after removing the solvent in the receiving layer, calculate and calculate the coating amount of the ink receiving layer. Coating amount U / m2) = [(weight before removal)-(weight after removal)] / (0. 2 X 0.2) (1 5) Field displayability After the recorded material printed in (1) above was displayed in the field for one week (two of which were rainy days), the image changes were visually judged. 〇 indicates no change, △ indicates change but no Practical problems, X is a change and there are practical problems. -33- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------- -Packing --- (Please read the note on the back Hi to write this page> · 520331 Α7 Β7 V. Description of the invention (32) (Example 1) < Modulation of transparent substrate > With a viscosity of 0.62, a vinyl parabenzoate resin (PET) was put into a 2-axis screw extruder, melted and extruded by a T-mold at 290 ° C, and electrostatically sealed and hardened in a cooling rotating stick. The PET obtained was a stretched film. This film was stretched with a stick stretcher, heated to 90 ° C (T g + 15 ° C) for 3.5 times longitudinal stretching, and then heated with a tenter to 14 Q ° C. After 3.7 times transverse stretching, 4% was relaxed at 2 3 5 ° C and heat treated to obtain a film. The thickness of the obtained film was 100 A in, and the polyester rayon resin film had a total light transmittance of 9 Q%. < Preparation of Particle Dispersion Liquid and Diluent of Surfactant > Add water to make particles (Fuji Silesia) 4 5 G solid content concentration 20% by weight, disperse using a homomixer at 5000 r pm for 30 minutes To make a particle dispersion A. The same amount of isopropyl alcohol was used to dissolve the surfactant (Meikafak F-1 4 4 D made by Dainippon Ink), and it was diluted 5 times with water to make an interface activity with a solid concentration of 10% by weight. Agent. < Preparation of coating liquid > Raw materials and mixed weight ratio of ion exchange water 3. 7 3 parts of particle dispersion liquid A 6 8. 7 8 parts of thermoplastic resin 2 6. 7 7 parts (Toyo Textile Co., Ltd.) (Transliteration) MD 1 1 0 0, solid content concentration 3 0¾) 34- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Packing .---- ： ---- Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 520331 V. Description of the invention (33) Fluorescent whitening agent 0 · 1 1 ( Chiba Special Chemical Co., Ltd. Uv it eEBF 250%) Surfactant Diluent B 0 · 4 1 part The above materials are mixed and stirred to prepare a coating solution. < Preparation of recording material > The fine coating gravure was used to coat the coating solution on the substrate with a thickness of 100 // m obtained from the above-mentioned < Preparation of the substrate >, and the air volume passed at 100 ° C was 10 m / The drying area was sec for 20 seconds, and then dried at 160 ° C for 40 seconds through a drying area with an air volume of 20 m / sec, to obtain a recording material. The thickness of the ink receiving layer was 55 // m. (Examples 2 to 1 1) Except for the thickness of the substrate and the thickness of the ink receiving layer, as shown in Table 1, the recording material was prepared in the same manner as in Example 1. ^ (Comparative Examples 1 to 3) · Except that the resin is partially saponified polyethylene glycol (Claret (translated; ^ VA-217)), the thickness of the substrate and the thickness of the ink receiving layer are as shown in Table 丨A recording material was prepared in the same manner as in Example 1. The results are shown in Table 丄. -35- 520331 * A7B7 V. Description of the invention (34) Printed on Table 1 by iWX (" m) Ink layer thickness (" m) Curl (mm) Transport printing characteristics Cutting 11: 15 ° C 20% 2QX: 60% 10 ° (: 80% I5 ° C 20% 2 (Γ ('60% M) V 80% 丨; 丨 1 Example 1 100 55 -2-2-2 20000 Example 2 100 75 -2-2-3 0000 Example 3 100 100 -2 -2 -4 〇00-〇00〇 Example 4 50 55 -2 -2-40,000 0000 Example 5 50 80 -1-2-40,000 0000 Example 6 50 100 2 0 0 0 0 0 0 0 0 0 0 0 0 7 7 188 55 0 0 1 1 0 0 0 0 0 0 8 8 188 85 -1 0 1 1 0 0 0 0 0 9 9 188 100 -1- 1 -6 〇〇〇 〇 Example 10 100 45 -2 -2 -2 〇00〇〇 Example 11 100 40-2 -2 -2 〇〇X 〇〇 Comparative Example 1 100 80 + 90 -21 -120 XXX 〇〇 〇Comparative Example 2 100 20 + 15 -2 -13 〇〇〇XX 〇Comparative Example 3 225 80 + 18-7 + 16 XXX 〇〇〇-36-This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------------ Installation -------- Order --- (Please read the precautions on the back before filling this page) 520331 A7 B7 V. Description of the invention ( 35) (Example 1 2) < Production of transparent substrate > A transparent substrate was prepared in the same manner as in Example 1. < Production of thermoplastic resin for ink receiving layer > Add 35 parts by weight of p-benzoic acid, 35 parts by weight of isobenzoic acid, 9 parts by weight of sodium 5-sulfoisobenzoate, 27 parts by weight of ethylene glycol, 46 parts by weight of neopentyl alcohol, and 0.1 parts by weight. Parts of tetramethoxyphthalic acid ester were heated at 180 to 23 (TC for 120 minutes to perform a transesterification reaction. Then, the temperature of the reaction bar was raised to 250 ° C, and the pressure in the bar was 1 to 10 ni in H g, and the reaction was continued for 60 minutes, and as a result, a copolymerized polyester resin (A 1) was obtained. The obtained (A 1) copolymerized polyester resin is shown in Table 1. The reduction viscosity was 0.4 Q d 1 / g, the glass transition temperature was 6 1 ° C, and the composition was analyzed by NMR. Benzoic acid 47.0 mole%, isobenzoic acid 46.Q mole%, 5-sodium sulfoisobenzoic acid 7.0 mole%, glycol component like ethylene glycol 50.0 mole%, neopentyl alcohol 50.0 Mole%. Copolymerized polyester-containing resins (A2 to A4) shown in Table 1 were produced in the same manner. Table 2 (Please read the precautions on the back ^^ write this page) »! Binding --------- · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A1 A2 A3 A4 p-benzoic acid 47 49 50 97.5 Isobenzoic acid 46 48.5 47.5 5-sulfoisobenzoic acid 7 2.5 2.5 2.5 Ethylene glycol 50 40 20 Neopentyl alcohol 50 Diethylene glycol 60 30 Hexylene glycol 70 Propylene glycol 78 Glass transition temperature CC) 61 42 5 79 Reduced viscosity (dl / g) 0.40 0.78 0.66 0.34 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) _ 3 7 _ 520 331 A7 B7 V. Description of the invention (36) (A1) ~ (A4) pairs The swelling degree of water is below 1%. < Aqueous dispersion of thermoplastic resin for the ink receiving layer > ------------ I! (Please read the precautions on the back first to write this page)> For 100 parts by weight For the (A 1) copolymerized polyester resin as shown in Table 1, add 50 parts by weight of ethylene glycol monobutyl ether (boiling point 17 1 ° C) as shown in Table 2, and heat up to 130 ° C was dissolved, the temperature was lowered to 8 G ° C, and the mixture was stirred and warm water was added so that the solid content concentration was 3 U to obtain (A 1) copolymerized polyester resin (P 1 > water dispersion.) The solvents shown in Table 2 were used to prepare (P 2 to P 1 4) water dispersions of (A 1 to A 4) copolymerized polyester resins. Table 3 Water dispersion thermoplastic resin water-soluble solvents * ethylene glycol Monobutyl ether (171 ° C) ** Triethylene glycol monobutyl ether (271 ° C) ** Diethylene glycol (245 ° 〇 ** Glycol monomethyl ether (125.〇 ** P1 A1 50 0 0 0 P2 A1 35 0 0 15 P3 A1 100 0 0 0 P4 A1 125 0 0 0 P5 A1 0 100 0 0 P6 A1 0 0 100 0 P7 A1 50 50 0 0 P8 A1 100 0 0 50 P9 A2 50 0 '0 0 P10 A2 15 0 0 35 P11 A2 100 0 0 0 P12 A3 50 0 0 0 P13 A3 70 0 0 0 P14 A4 50 0 0 0 (Note) *: for 100 Parts by weight of thermoplastic resin: Boiling point Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -38- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 520331 Α7 Β7 V. Description of the invention (37) < Preparation of a coating liquid for forming an ink receiving layer > Add water to make particles (Fuji Silesia (Qili) 45Q) made into a solid content concentration of 20% by weight, and use a homomixer at 5G0Grpm Disperse for 30 minutes to prepare a particle dispersion. In addition, dilute the surfactant (Meikafak F-142Q, manufactured by Dainippon Ink Co., Ltd.) with the amount of ketone isopropanol, and dilute it 5 times with water to make a solid. A surfactant diluent with a concentration of 10% by weight. Use the particle dispersion, the surfactant diluent, the aqueous dispersion of the thermoplastic resin for the ink receiving layer (A1), and a fluorescent whitening agent (Chiba Special Chemically made vite XEBF 2 5 (U), in the following mixing ratio, to form a coating liquid for forming ink receiving layer. Ion exchange water 3. 7 3 parts particle dispersion 6 8. 7 8 parts (A 1) Thermoplastic tree for ink receiving layer (P 1) water dispersion liquid 26.97 parts of surfactant diluent 0.4 parts of fluorescent brightener 0.1 parts < formation of ink receiving layer (making of recording material) > The above-mentioned substrate was coated with the above-mentioned coating liquid for forming an ink-receiving layer with a # 60 0 iron wire rod, heated in an oven maintained at 160 ° C. for 3 minutes, and dried to remove the solvent to obtain a recording material. The total light transmittance of this recording material was 30 · 3%. Example 1 3 ~ 2 4. Comparative Example 1 The same as Example 12 except that the water dispersion of the thermoplastic resin for the ink receiving layer is shown in Table 4. Recording material was prepared. 2〜41.1%。 The total light transmittance of these recording materials is 30.2 ~ 41.1%. -39-This paper size is in accordance with the Chinese National Standard (CNS) A4 (210 X 297 mm). Please read the notes at the back first

Η 頁 I 訂 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 520331 A7 B7 五、發明說明（38 ) 實施例2 5、 2 6 除使油墨容受層形成用塗液各以# 3 0、# 7 5之鐵絲棒塗 覆外，與實施例2 0相同地製得記錄材料。該記錄材料之 全光線透過率為52.0%、21. 8%。 比較例4 除使用部分經皂化的具乙二醇（可樂麗（股）P V A - 2 1 7 ) 做為油墨容受層形成用熱塑性樹脂外，與實施例1 2相同 地製得記錄材料。該記錄材料之全光線透過率為3 4 . 5 %。 結果如表4所示。 表4I Page I Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees’ Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economics 520331 A7 B7 V. Description of the Invention (38) Example 2 5 and 2 6 The recording material was prepared in the same manner as in Example 20 except that the liquids were coated with wire rods # 3 0 and # 7 5. The total light transmittance of this recording material was 52.0% and 21.8%. Comparative Example 4 A recording material was obtained in the same manner as in Example 12 except that a partially saponified ethylene glycol (Kuraray PVA-2 1 7) was used as the thermoplastic resin for forming the ink receiving layer. The total light transmittance of the recording material was 34.5%. The results are shown in Table 4. Table 4

油墨容受層 試驗結果 實施例 水分散 Tg 溶劑 記錄 記錄 記錄 表面 耐水 No. 物 °c 量重 量％ 品質 品質 品質 強度 性 1 3 4 12 P1 61 50 〇 Δ X 〇 〇 13 P2 61 35 〇 Δ X 〇 〇 14 P3 61 100 ◎ Δ X 〇 〇 15 P4 61 125 ◎ 〇 Δ 〇 〇 16 P5 61 100 ◎ Δ X 〇 〇 17 P6 61 100 ◎ Δ X 〇 〇 18 P7 61 100 ◎ Δ X 〇 〇 19 P8 61 100 ◎ Δ X 〇 〇 20 P9 42 50 ◎ 〇 Δ 〇 〇 21 P10 42 15 〇 〇 Δ 〇 〇 22 P11 42 100 〇 〇 Δ 〇 〇 23 P12 6 50 ◎ 〇 Δ 〇 〇 24 P13 6 70 〇 〇 Δ X 〇 25 P9 42 50 〇 〇 Δ 〇 〇 26 P9 42 50 〇 〇 Δ 〇 〇 比較例4 — 69 0 〇 Δ ◎ ◎ X -40 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------^^裳-----^----訂---------· (請先閱讀背面之注意事項再填寫本頁) 520331 A7 _B7_ 五、發明說明（39 ) 實施例2 7 <透明基材之調整> 與實施例1相同地製得透明基材。 <塗液之作成> 以下逑之重量混合比作成塗液。 離子交換水 1 G . 5 5份 粒子分散液 6 8 . 3 4份 樹脂分散液 2 G . 7 1份 螢光增白劑 0 . 0 9份 (千葉特別化學製 U v i t e X E B F 2 5 0 % ) 界面活性劑稀釋液 0 . 3 1份 <記錄材料之作成> 在上逑之基材上以# 6 D鐵絲棒塗覆上述塗液，在保持 於1 6 G °C之烤箱中加熱3分鐘，乾燥除去溶劑以製得記 錄材料。該記錄材料之全光線透過率為3 5 . 1 %。 實施例2 8 除以# 3 0塗覆外與實施例2 7相同地製得記錄材料。所 得薄膜之全光線透過率為5 2 . 0 %。 實施例2 9 除以# 7 5塗覆外與實施例2 7相同地製得記錄材料。所 得薄膜之全光線透過率為2 1 . 4 %。 實施例3 0〜3 8 除如表5所示之樹脂種類、粒子與樹脂之重量比外， 與實施例2 7相同地製得記錄材料。所得薄膜之全光線透 -4 1 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注咅？事項寫本頁〕 裝 訂： 經濟部智慧財產局員工消費合作社印製 520331 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（4〇) 過率為28.1〜47.5%。 實施例3 9、4 0 除如表5所示之粒子與樹脂之重量比例外，與實施例 2 7相同地製得記錄材料。所得薄膜之全光線透過率為 3 2.1%. 3 3 . 2 % 〇 比較例5 除使用部分經皂化的具乙二醇（可樂麗（股）PVA-2 17) 做為樹脂外，與實施例2 7相同地製得記錄材料。全光線 透過率為4 2 %。 此等之評估結果如表5。 表5Ink receiving layer test results Example Water-dispersed Tg Solvent records Record surface water-resistant No. matter ° C Amount by weight% Quality Quality Quality Strength 1 3 4 12 P1 61 50 〇ΔX 〇〇13 P2 61 35 〇ΔX 〇 〇14 P3 61 100 ◎ ΔX 〇〇15 P4 61 125 ◎ 〇Δ 〇〇16 P5 61 100 ◎ ΔX 〇〇17 P6 61 100 ◎ ΔX 〇〇18 P7 61 100 ◎ ΔX 〇〇19 P8 61 100 ◎ Δ X 〇〇20 P9 42 50 ◎ 〇Δ 〇〇21 P10 42 15 〇〇Δ 〇〇22 P11 42 100 〇〇Δ 〇〇23 P12 6 50 ◎ 〇Δ 〇〇24 P13 6 70 〇〇Δ X 〇 25 P9 42 50 〇〇Δ 〇〇26 P9 42 50 〇〇Δ 〇〇 Comparative Example 4 — 69 0 〇Δ ◎ ◎ X -40-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) ------------ ^^ Shang ----- ^ ---- Order --------- (Please read the notes on the back before filling this page) 520331 A7 _B7_ V. Description of the invention (39) Example 2 7 < Adjustment of transparent substrate > A transparent substrate was prepared in the same manner as in Example 1. < Preparation of coating liquid > The coating liquid was prepared by the following weight mixing ratio. Ion-exchanged water 1 G. 5 5 parts particle dispersion 6 8. 3 4 parts resin dispersion 2 G. 7 1 part fluorescent brightener 0.09 part (U vite XEBF 2 50% by Chiba Specialty Chemicals) 0.31 part of surfactant diluent < Preparation of recording material > The above coating solution was coated with # 6 D wire rod on the base material of the upper part, and heated in an oven maintained at 16 G ° C for 3 times. After a minute, the solvent was removed by drying to obtain a recording material. The total light transmittance of the recording material was 35.1%. Example 2 8 A recording material was produced in the same manner as in Example 2 7 except that it was coated with # 3 0. The total light transmittance of the obtained film was 52.0%. Example 2 9 A recording material was prepared in the same manner as in Example 2 7 except that it was coated with # 7 5. The total light transmittance of the obtained film was 2 1.4%. Example 3 0 to 3 8 A recording material was prepared in the same manner as in Examples 2 to 7 except that the types of resin and the weight ratio of particles to resin shown in Table 5 were used. Full light transmission of the obtained film-4 1-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back first? Matters write this page) Binding: Intellectual Property Bureau, Ministry of Economic Affairs Printed by employee consumer cooperatives 520331 Printed by employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of invention (40) The overage rate is 28.1 ~ 47.5%. Example 3 9, 4 0 Except for the particles shown in Table 5 and Except for the weight ratio of the resin, a recording material was prepared in the same manner as in Example 27. The total light transmittance of the obtained film was 3 2.1%. 3 3.2% 〇 Comparative Example 5 Except for the partially saponified ethylene glycol ( Kuraray (stock) PVA-2 17) As a resin, a recording material was prepared in the same manner as in Example 27. The total light transmittance was 42%. The results of these evaluations are shown in Table 5. Table 5

實施例 No. 水分散 物 Tg °c 溶劑 量重 量％ 記錄 品質 1 記錄 品質 3 記錄 品質 4 表面 強度 耐水 性 27 P9 42 2.2 ◎ 〇 Δ 〇 〇 28 P9 42 2.2 〇 〇 Δ 〇 〇 29 P9 42 2.2 〇 〇 Δ 〇 〇 30 P9 42 1.7 ◎ 〇 Δ 〇 〇 31 P9 42 1.3 ◎ 〇 Δ 〇 〇 32 P1 61 2.5 ◎ 〇 Δ 〇 〇 33 P1 61 1.7 ◎ Δ △ 〇 〇 34 P1 61 1.5 ◎ X Δ 〇 〇 35 P12 5 1.3 ◎ 〇 〇 〇 〇 36 P12 5 1.7 ◎ 〇 〇 〇 〇 37 P14 79 1.7 ◎ 〇 △ 〇 〇 38 P1 61 1.9 ◎ 〇 △ 〇 〇 39 P1 61 2.2 ◎ △ Δ 〇 〇 40 P9 42 1.6 ◎ 〇 Δ 〇 〇 比較例5 — 69 1.7 〇 〇 ◎ 〇 X -42 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)Example No. Water dispersion Tg ° c Solvent weight% Recording quality 1 Recording quality 3 Recording quality 4 Surface strength Water resistance 27 P9 42 2.2 ◎ 〇Δ 〇〇28 P9 42 2.2 〇〇Δ29 〇〇29 P9 42 2.2 〇 〇Δ 〇〇30 P9 42 1.7 ◎ 〇Δ 〇〇31 P9 42 1.3 ◎ 〇Δ 〇〇32 P1 61 2.5 ◎ 〇Δ 〇〇33 P1 61 1.7 ◎ Δ △ 〇〇34 P1 61 1.5 ◎ X Δ 〇〇35 P12 5 1.3 ◎ 〇〇〇〇〇〇36 P12 5 1.7 ◎ 〇〇〇〇〇〇37 P14 79 1.7 ◎ △ 〇 △ 〇〇38 P1 61 1.9 ◎ △ 〇〇39 P1 61 2.2 ◎ △ △ 〇〇40 P9 42 1.6 ◎ 〇 Δ 〇〇 Comparative Example 5 — 69 1.7 〇〇 ◎ 〇X -42-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

520331 五、發明說明（41) 實施例4 1 <透明基材之調整> 與實施例1相同地製得透明基材。 <塗液準備> 爲塗液作成之準備 添加水使二氧化矽粒子（富士西里西亞製賽里西亞450 ) 成固成份濃度爲25重量％，且使用均混器以5000 r pm予 以分散30分鐘，作成粒子分散液。以同量異丙醇稀釋界 面活性劑（大日本油墨製梅卡法克F-144D)，再以水稀釋成 5倍以作成固成份濃度爲1 〇重量％之界面活性劑稀釋液。 塗液之作成 ， 以下述之重量混合比作成塗液。 離子交換水 6.24份 聚酯系樹脂 30.65份 (東洋紡績（股）拜羅那魯MD1 100、固成份濃度30%) 粒子分散液 6 2 . 5 2份 螢光增白劑 0 . 1 3份 (千葉特殊、化學製UvitexEBF250% 界面活性劑稀釋液 0.46份 <記錄材料之作成> 在上述之基材上以#60鐵絲棒塗覆上述塗液，在保持 於1 60°C之烤箱中加熱3分鐘，製得記錄材料。 實施例4 2 除以鐵絲棒#75外，與實施例41相同地製得記錄材料。 實施例4 3 除使用鐵絲棒#44外，與實施例41相同地製得記錄材料。 實施例25、26 除使用鐵絲#36外，與實施例41相同地製得記錄材料。 -43- 520331 五、發明說明（42) 實施例44 除使用鐵絲# 3 6外，與實施例4 1相同地製得記錄材料。 實施例45 除使用下述之塗液，與實施例4 1相同地製得記錄材料。 離子交換水 5.44份 聚酯系樹脂 26.72份 (東洋紡績（股）拜羅那魯MD 1 1 〇 〇、固成份濃度3 0 % ) 粒子分散液 6 7 · 3 3份 螢光增白劑 〇 · 1 1份 (千葉特殊、化學製Uvi texEBF25% ) 界面活性劑稀釋液 〇 . 40份 實施例46 除使用下述之塗液，與實施例4 1相同地製得記錄材料。 離子交換水 6.74份 聚酯系樹脂 3 3.08份 (東洋紡績（股）拜羅那魯MD 1100、固成分濃度30%) 粒子分散液 5 9 . 5 5份 螢光增白劑 0 . 1 4份 (千葉特別化學製 Uvi t exEBF 250%) 界面活性劑稀釋液 0.50份 結果如表6所示。 表6 實施例 No. 全光線透渦率 發色濃度 記錄 品質 5 記錄 品質 6 基材 記錄 材料 反射 透過 41 90 28 1.41 2.22 〇 〇 42 90 24 1.40 2.34 〇 〇 43 90 35 1.40 2.07 〇 〇 44 90 43 1.43 1.89 〇 〇 45 90 25 1.39 2.30 〇 〇 46 90 32 1.32 2.09 〇 〇 -44- 520331 A7 _B7_ 五、發明說明（43 ) 實施例4 7 <粒子分散液、界面活性劑稀釋液之調製> 添加水使粒子（富士西里西亞製賽里西亞450)成固成 份濃度為2 3重量％，且使用均混器以5 Q G Q r ρ πι予以分散 3 0分鐘，作成粒子分散液A。以同量異丙醇溶解界面活 性劑（大日本油墨製梅卡法克F-144D),再以水稀釋成5 倍以作成固成份濃度為1 G重量％之界面活性劑稀釋液。 <塗液之作成> 塗液之原料與混合重量比如下所逑。 離子交換水 2 0 . 3 4份 熱塑性樹脂 2 4 . 6 5份 (東洋紡績（股）拜羅那魯M D 1 1 G 0、固成份濃度3 0 % ) 粒子分散液A 5 4 . 6 5份 界面活性劑稀釋液B Q.37份 使上述之材料混合攪拌以作成塗液。 <記錄材料之作成> 使用白色聚酯薄膜（東洋紡績（股）製G 2 3 2 3 - 1 0 0 a )做 為基材，在該基材上以# 6 0鐵絲棒塗覆上述塗液，在保 ------------»!裝 (請先閱讀背面之注意事項寫本頁> 訂--------- #· 經濟部智慧財產局員工消費合作社印製 料 材 錄 記 得 製 鐘 分 3 熱 加 中 箱 烧 之 P 8 ο 4 16例 於施 持實 例 施 實 與 外 液 塗 之 水脂 逑 換樹 下 交性 用 子塑 使 離熱 除 C 料 材 錄 記 得 製 地 同 4 2 7 2 4 2 份份 4 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 五、發明說明（44) (東洋紡績（股）拜羅那魯MD 1 5 00 ) 粒子分散液A 50.62份 界面活性劑稀釋液B 0.42份 混合攪拌係與實施例1相同地進行。 實施例49 除使用下述之塗液外，與實施例47相同地製得記錄材 料。 離子交換水 1 9 . 6 1份 熱塑性樹脂 22.19份 (東洋紡績（股）拜羅那魯MD 1 500 ) 粒子分散液A 57 . 87份 界面活性劑稀釋液B 0 . 3 3份 混合攪拌係與實施例1相同地進行。 實施例50 除使用鐵絲棒#40外，與實施例47相同地製得記錄材 料。 實施例5 1 除使用鐵絲棒#75外，與實施例47相同地製得記錄材 料。 比較例6 除使部分經皂化的聚乙烯醇（克拉雷製PVA - 2 1 7 )投入 18t之水中，予以攪拌昇溫至95°C，以100篩網之過濾 器過濾，作成固成份濃度17重量％之溶液（以下稱爲部份 皂化溶解液），使用該物以作成下述組成之塗液，使其 -46- 520331 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（45) 塗覆外，與實施例4 7相同地製得記錄材料。 離子交換水 1 . 4 9份 部分皂化溶解液 4 3 . 4 9份 粒子分散液A 54. 65份 界面活性劑稀釋液B 〇 . 3 7份 而且，混合攪拌偽與實施例4 7相同地進行。 比較例7 。 除使用下述組成之塗液外，與實施例4 7相同地製得記 錄材料。 離子交換水 1 . 4 7份 部分皂化溶解液 3 0 . 4 4份 交聯劑 4 . 4 4份 (住友化學工業製史密麻卡（譯音）M3,固成份濃度 5 0 %稀釋器） 粒子分散液A 5 4 . 6 5份 界面活性劑稀釋液B 0 . 3 7份 而且，混合攪拌傺與實施例4 7相同地進行。 比較例8 除使完全皂化的聚乙烯醇（可樂麗製R S - 1 1 7 )投入1 8 °C 之水中，予以攪拌且昇溫至95°C,以100篩網之過濾器 過濾，作成固成份濃度17重量％之溶液（以下稱為完全皂 化溶解液），使用該物以作成下述組成之塗液，使其塗 覆外，與實施例4 7相同地製得記錄材料。 -47 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------»!裝 (請先閱讀背面之注意事項寫本頁) 訂--------- 520331 A7 B7 五、發明說明（46 ) 離子交換水 1 . 4 9份 完全皂化溶解液 4 3 . 4 9份 粒子分散液A 5 4 . 6 5份 界面活性劑稀釋液B Q . 3 7份 而且，混合攬拌傺與實施例4 7相同進行。 比較例9 除使用下述組成之塗液外，與實施例4 7 離子交換水 1 0 . 1 0份 完全皂化溶解液 3 0 . 4 4份 交聯劑 4 . 4 4份 (住友化學工業製史密麻卡Μ 3，固成份濃度5 0 %稀釋器） 粒子分散液A 5 4 . 6 5份 界面活性劑稀釋液B 〇 . 3 7份 而且，混合攪拌俗與實施例4 7相同地進行。 記錄材料之評估結果如表7所示。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 表7 塗覆量(g/m2) 發色濃度 耐水濃度保 持率(％) 野外展示性 處理前 處理後 實施例47 34 1.41 1.49 106 〇 實施例48 33 1.32 1.38 105 〇 實施例49 33 1.39 1.34 96 〇 實施例50 24 1.44 1.49 103 〇 實施例51 41 1.39 1.39 100 〇 比較例6 36 1.34 0.40 30 X 比較例7 34 1.32 1.02 77 X 比較例8 35 1.36 0.52 38 X 比較例9 33 1.33 1.12 84 Δ -48 - 線- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 520331 五、發明說明（47) 如此所得的記錄材料，尤其是使用由性油墨之噴墨記 錄方式中不會有滲透情形、可以鮮明地記錄，括耐水性 極佳。此外，即使溼度、溫度等激烈改變的環境下，很 少會有捲曲情形、可確保安定的記錄材料搬送性、不會 因印字噴頭之接觸而產生問題。 而且’使用做爲電飾看板時，在電飾看板點燈時或熄 燈時會有優異的畫像，可提供高畫質記錄之記錄材料。520331 V. Description of the invention (41) Example 4 1 < Adjustment of transparent substrate > A transparent substrate was prepared in the same manner as in Example 1. < Preparation of coating solution > Preparation of the coating solution was prepared by adding water so that the silica particles (Fuji Silesia 450) had a solid content concentration of 25% by weight, and dispersed using a homomixer at 5000 r pm In 30 minutes, a particle dispersion was prepared. Dilute the surfactant with the same amount of isopropanol (Meikafak F-144D made by Dainippon Ink), and then dilute it 5 times with water to make a surfactant diluent with a solid concentration of 10% by weight. The coating liquid was prepared at the following weight mixing ratio. 6.24 parts of ion-exchanged water 30.65 parts of polyester resin (Toyobo Industries Co., Ltd. Bayrona MD 1 100, solid content concentration 30%) Particle dispersion 6 2. 5 2 parts Fluorescent brightener 0.1 3 parts ( 0.46 parts of Chiba Specialty and Chemicals UvitexEBF 250% diluent of surfactant < Preparation of recording material > The coating solution was coated with a # 60 iron wire rod on the above substrate, and heated in an oven maintained at 160 ° C A recording material was prepared in 3 minutes. Example 4 2 A recording material was prepared in the same manner as in Example 41 except that the wire rod # 75 was used. Example 4 3 was prepared in the same manner as in Example 41 except that the wire rod # 44 was used. Recording materials were obtained. Examples 25 and 26 were prepared in the same manner as in Example 41 except that iron wire # 36 was used. -43- 520331 V. Description of the Invention (42) Example 44 Except using iron wire # 3 6 and Example 4 1 A recording material was prepared in the same manner. Example 45 A recording material was prepared in the same manner as in Example 4 1 except that the following coating solution was used. Ion exchanged water 5.44 parts of a polyester resin 26.72 parts (Toyobo Industries Ltd. ) Bayronal MD 1 1 00, solid content concentration 30%) Particle dispersion liquid 6 7 · 3 parts of fluorescent whitening agent · 11 parts (Chiba Specialty, chemically manufactured Uvi texEBF 25%), diluent of surfactant, 40 parts, Example 46, same as Example 41 except that the following coating solution was used Recording materials were prepared: 6.74 parts of ion-exchanged water, 3 3.08 parts of polyester-based resin (Toyobo Industries Co., Ltd. Bayronaru MD 1100, solid content concentration 30%) Particle dispersion 5 9. 5 5 parts fluorescent whitening 0.14 parts (Ubite exEBF 250% manufactured by Chiba Specialty Chemicals) 0.50 parts of the diluent of the surfactant is shown in Table 6. Table 6 Example No. Full-light vortex transmittance color concentration Recording quality 5 Recording quality 6 Reflective transmission of substrate recording material 41 90 28 1.41 2.22 〇〇42 90 24 1.40 2.34 〇43 90 35 1.40 2.07 〇〇44 90 43 1.43 1.89 〇〇45 90 25 1.39 2.30 〇〇46 90 32 1.32 2.09 〇- 44- 520331 A7 _B7_ V. Explanation of the invention (43) Example 4 7 < Preparation of particle dispersion and diluent of surfactant > Water was added to make particles (Fuji Silesia 450 Silesia 450) into a solid component concentration of 2 3% by weight and using a homomixer at 5 QGQ r ρ π was dispersed for 30 minutes to prepare a particle dispersion liquid A. The same amount of isopropyl alcohol was used to dissolve the surfactant (Meikafak F-144D manufactured by Dainippon Ink), and then diluted 5 times with water to make a diluent of surfactant with a solid content concentration of 1 G% by weight. < Preparation of coating liquid > The raw materials and mixing weight of the coating liquid are as follows. Ion-exchanged water 2 0. 3 4 parts thermoplastic resin 2 4. 6 5 parts (Toyo Industries Co., Ltd. Bayronaru MD 1 1 G 0, solid content concentration 30%) Particle dispersion A 5 4. 6 5 parts Q. 37 parts of surfactant diluent B. The above materials were mixed and stirred to prepare a coating solution. < Production of recording material > A white polyester film (G 2 3 2 3-1 0 0 a manufactured by Toyobo Corporation) was used as a base material, and the above was coated with a # 6 0 iron wire rod on the base material. Coating liquid, in the ------------ »! Equipment (please read the precautions on the back to write this page > order --------- # · Intellectual Property Bureau of the Ministry of Economic Affairs Record of materials printed by employees' consumer cooperatives. Minutes are made in minutes. 3 P8 ο 4 in the middle of the box. 4 cases were treated with water and grease coated with external liquid. C. Records of materials are the same as 4 2 7 2 4 2 copies. 4 The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 520331 5. Description of the invention (44) (Toyobo Textile Co., Ltd.) Bayonalu MD 1 5 00) Particle Dispersion A 50.62 parts Surfactant Diluent B 0.42 parts Mixing and stirring is performed in the same manner as in Example 1. Example 49 was the same as in Example 47 except that the following coating liquid was used. A recording material was prepared in the same way. Ion-exchanged water 19.96 1 part thermoplastic resin 22.19 parts (Toyobo Industries Ltd. Bayronaru MD 1 500) Particle fraction Powder A 57. 87 parts of surfactant diluent B 0. 3 and 3 parts were mixed and stirred in the same manner as in Example 1. Example 50 A recording material was prepared in the same manner as in Example 47 except that an iron wire rod # 40 was used. Example 5 1 A recording material was prepared in the same manner as in Example 47 except that an iron wire rod # 75 was used. Comparative Example 6 A saponified polyvinyl alcohol (PVA-2 1 7 manufactured by Claret) was put into 18t of water. The solution was stirred and heated to 95 ° C, and filtered through a 100-mesh filter to prepare a solution with a solid concentration of 17% by weight (hereinafter referred to as a partially saponified dissolution solution), and this material was used to prepare a coating solution with the following composition. Printed on -46- 520331 A7 B7 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of Invention (45) Except for coating, a recording material was prepared in the same manner as in Example 4 7. Ion exchanged water 1.4 9 parts Saponification solution 4 3. 4 9 parts Particle Dispersion A 54. 65 parts Surfactant Diluent B 0.3 7 parts Further, mixing and stirring were performed in the same manner as in Examples 4 and 7. Comparative Example 7 except that the following was used A recording material was obtained in the same manner as in Examples 4 to 7 except for the coating liquid of the composition. Ion-exchanged water 1. 4 7 parts partially saponified solution 30. 4 4 parts cross-linking agent 4. 4 4 parts (Smith Mika (transliteration) M3 manufactured by Sumitomo Chemical Industry, solid content concentration 50% diluent ) Particle Dispersion Liquid A 5 4.5. 5 parts of Surfactant Diluent B 0.37 parts. Mixing and stirring were carried out in the same manner as in Example 47. Comparative Example 8 A completely saponified polyvinyl alcohol (RS-1 1 made by Kuraray) was put into water at 18 ° C, stirred and heated to 95 ° C, and filtered through a 100-mesh filter to make a solid component. A solution having a concentration of 17% by weight (hereinafter referred to as a completely saponified dissolving solution) was used to prepare a coating liquid having the following composition, except that it was coated, and a recording material was prepared in the same manner as in Examples 4 to 7. -47-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------ »! (Please read the precautions on the back and write this page first) Order --------- 520331 A7 B7 V. Description of the invention (46) Ion-exchanged water 1. 4 9 parts of completely saponified solution 4 3. 4 9 parts of particle dispersion A 5 4. 6 5 parts of surfactant The dilution liquid BQ. 37 was performed in the same manner as in Example 47. Comparative Example 9 Except that a coating liquid having the following composition was used, it was the same as in Example 4 7 Ion-exchanged water 10. 10 parts of a completely saponified dissolving solution 30. 4 4 parts of a cross-linking agent 4.4. 4 parts (manufactured by Sumitomo Chemical Industries) Smith Mika M 3, solid content concentration 50% diluent) Particle Dispersion A 5 4. 65 parts of Surfactant Diluent B 0.3 7 parts, and mixing and stirring were performed in the same manner as in Example 4 7 . The evaluation results of the recorded materials are shown in Table 7. (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 7 Coated amount (g / m2) Hair color concentration Water resistance concentration retention rate (%) After field display treatment Example 47 34 1.41 1.49 106 〇 Example 48 33 1.32 1.38 105 〇 Example 49 33 1.39 1.34 96 〇 Example 50 24 1.44 1.49 103 〇 Example 51 41 1.39 1.39 100 〇 Comparative Example 6 36 1.34 0.40 30 X Comparative Example 7 34 1.32 1.02 77 X Comparative Example 8 35 1.36 0.52 38 X Comparative Example 9 33 1.33 1.12 84 Δ -48-Line-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 520331 V. Invention Explanation (47) The recording material obtained in this way, especially in the inkjet recording method using organic inks, can be recorded vividly, including excellent water resistance. In addition, even in environments where humidity and temperature change drastically, curling rarely occurs, ensuring stable transportability of the recording material, and no problems caused by contact with the print head. Furthermore, when used as an electric signboard, it has an excellent image when the electric signboard is turned on or off, and it can provide high-quality recording recording materials.

-49 --49-

Claims (1)

六、申請專利範圍 第8 9 1 0 7 8 9 7號「記錄材料」專利案 (91年11月29日修正) A申請專利範圍： 1.一種記錄材料’其爲基材上設有由同一組成物組成之 油墨容受層的紀錄材料’其特徵爲該基材之厚度爲38 至200 //m，該油墨容受層由厚度爲4〇//m至1〇5 从m之含有粒子與非吸水性樹脂的多孔質層所組成， 且記錄材料之捲曲度爲以下。 2 · —種記錄材料’其爲透明基材上設有由同一組成物組 成之油墨容受層的記錄材料，其特徵爲該基材之厚度 爲’3 8//m至200#m，該油墨容受層由厚度爲4〇//m至 1 05 // m之含有粒子與非吸水性樹脂的多孔質層所組 成’且印刷全黑色時光透過之發色濃度T與反射之發 色濃度R的關係滿足下式（1 ) 20XR ^ T ^ 1 · 7〇xR............... ( 1 )。 3 . —種記錄材料，其爲基材上設有由同一組成物組成之 油墨容受層之記錄材料，其特徵爲該油墨容受層爲由 厚度爲4 0 // m至1 〇 5 // m之含有粒子與非吸水性樹脂 的多孔質層所組成，且耐水濃度保持率爲9 5%以上。 4 .如申請專利範圍第1至3項中任一項之記錄材料，其 中該非吸水性樹脂爲Tg爲-5°C至100°C之熱塑性樹 脂° 5 .如申請專利範圍第4項之記錄材料，其中該熱塑性樹 520331 六、申請專利範圍 脂爲聚酯系熱塑性樹脂。 6 ·如申請專利範圍第1至3項中任一項之記錄材料，其 中該基材爲聚醋系樹脂所組成。 7 .如申請專利範圍第1至3項中任一項之記錄材料，其 中爲該粒子爲聚矽氧烷粒子。 8 .如申請專利範圍第7項之記錄材料，其中該聚矽烷氧 粒子之二次凝集粒子的平均粒徑爲0 . 1 # m至3 0 # m， 且細孔徑爲10 A至2000A。 9 .如申請專利範圍第4項之記錄材料，其中該非吸水性 之熱塑性樹脂與粒子的比例爲，樹脂/粒子之重量比 爲 1/1.2 至 1/10。 1 〇 .如申請專利範圍第4項之記錄材料，其中該粒子（A ) 與非吸水性之熱塑性樹脂（B )的重量比例（A / B )及熱塑 性樹脂（B )之Tg的關係滿足下式（2 )及（3 ) A/B ^ 1 . 2....................................... (2) Tg/100 + 0.8 S A/B S Tg/100 + 1.9...(3)。 1 1 . 一種記錄材料之製法，其爲將粒子及非吸水性熱塑 性樹脂乳化或分散於主要由水構成之溶劑中構成塗 液，塗布於基材的至少一面後，乾燥去除溶劑，形成 油墨容受層，而設有該油墨容受層之如申請專利範圍 第1至3項任一項之記錄材料之製造方法，其特徵爲 該塗液中沸點1 50°C以上之水溶性高沸點溶劑滿足下 式（4) 520331 六、申請專利範圍 Tg - 30 ^ S ^ Tg + 70.....................( (式中，S表爲對沸點1 5(TC以上之水溶性高沸點 之熱塑性樹脂1 00重量份的混配比例[重量份] 表爲熱塑性樹脂之玻璃轉移溫度 PC ])。 4) 溶劑 ，TgSixth, the scope of application for patent No. 8 9 1 0 7 8 9 7 "recording material" patent case (amended on November 29, 91) A scope of application for patent: 1. A recording material 'which is provided on the substrate by the same The recording material of the ink-receiving layer composed of the composition is characterized in that the thickness of the substrate is 38 to 200 // m, and the ink-receiving layer is composed of particles having a thickness of 40 // m to 105 from m. It is composed of a porous layer with a non-water-absorbent resin, and the degree of curl of the recording material is as follows. 2 · —A kind of recording material 'which is a recording material provided with an ink receiving layer composed of the same composition on a transparent substrate, which is characterized in that the thickness of the substrate is' 3 8 // m to 200 # m. The ink receiving layer is composed of a porous layer containing particles and a non-water-absorbent resin having a thickness of 4 // m to 1 05 // m ', and the color density T of light transmission and the color density of reflection when printed in full black The relationship of R satisfies the following formula (1) 20XR ^ T ^ 1 · 7〇xR ......... (1). 3. A recording material, which is a recording material provided with an ink receiving layer composed of the same composition on a substrate, characterized in that the ink receiving layer has a thickness of 4 0 // m to 1 0 5 / / m is composed of a porous layer containing particles and a non-water-absorbent resin, and has a water resistance concentration retention rate of 95% or more. 4. The recording material according to any one of items 1 to 3 in the scope of patent application, wherein the non-water-absorbent resin is a thermoplastic resin having a Tg of -5 ° C to 100 ° C. 5. The record in item 4 of the scope of patent application Materials, of which the thermoplastic tree 520331 6. The scope of the patent application is polyester-based thermoplastic resin. 6. The recording material according to any one of claims 1 to 3, wherein the substrate is composed of a polyester resin. 7. The recording material according to any one of the claims 1 to 3, wherein the particles are polysiloxane particles. 8. The recording material according to item 7 of the scope of patent application, wherein the average particle diameter of the secondary agglomerated particles of the polysilane oxide particles is 0.1 #m to 3 0 #m, and the pore diameter is 10 A to 2000A. 9. The recording material according to item 4 of the scope of patent application, wherein the ratio of the non-water-absorbing thermoplastic resin to particles is a resin / particle weight ratio of 1 / 1.2 to 1/10. 10. The recording material according to item 4 of the scope of patent application, wherein the relationship between the weight ratio (A / B) of the particles (A) and the non-water-absorbing thermoplastic resin (B) and the Tg of the thermoplastic resin (B) satisfies the following Equations (2) and (3) A / B ^ 1. 2 ... .... (2) Tg / 100 + 0.8 SA / BS Tg / 100 + 1.9 ... (3). 1 1. A method for producing a recording material, comprising emulsifying or dispersing particles and a non-water-absorbent thermoplastic resin in a solvent mainly composed of water to form a coating liquid, applying the coating liquid to at least one side of a substrate, and drying and removing the solvent to form an ink container. A method for manufacturing a recording material such as any one of claims 1 to 3 provided with the ink receiving layer provided with the ink receiving layer, which is characterized by a water-soluble high boiling point solvent having a boiling point of 150 ° C or higher in the coating liquid. Satisfy the following formula (4) 520331 VI. Patent application scope Tg-30 ^ S ^ Tg + 70 ..... ((In the formula, S table is For boiling point 15 (100 parts by weight of water-soluble high-boiling thermoplastic resin above TC [parts by weight] Table shows the glass transition temperature of the thermoplastic resin PC]). 4) Solvent, Tg