TW510915B - Carbon black aggregate - Google Patents

Abstract

A carbon black aggregate having a surface hardness of from 70 to 2000 g and having a covering, wherein the density σ (g/cc) of the carbon black aggregate is at least σ = 8.190x10<SP>-3</SP>D - 3.824x10<SP>-3</SP>L + 0.516 and at most σ = 3.265x10<SP>-3</SP>D - 3.334x10<SP>-3</SP>L + 1.173 wherein D is the arithmetic mean primary particle size (nm) of carbon black by an electron microscope, and L is the DBP (dibutyl phthalate) oil absorption (ml/100 g).

Description

5ρί0915 A7 B7 經濟部中央標準局負工消費合作社印製 五、發明説明（彳） 發明說明 本發明係關於一種形式的碳黑集料，其在運送或儲存 時較不易粉碎或破裂，或在使用時較不易產生環境污染， 且在媒劑中有極佳的分散性。 碳黑在工業上廣泛地作爲色料使用，使油墨、塗料物 質、樹脂等具有黑色，或作爲以輪胎爲代表之橡膠的強化 物質，歷史記載上，根據揭示在中國Kan年代之文獻記 錄，碳黑剛開始是從松煙的煙灰製造，隨後的製造方法有 美國Me. Nutt在1 8 9 2年發展的槽碳黑法及Phillips在 1 9 4 2年的爐法，從此碳黑的產量有明顯地改進，且控 制粒子大小及粒子結構長度之技術顯示有明顯地進展。 反之，關於碳黑的形式，未曾有適當地改進，工業上 使用的碳黑形式限於粉末產品、辗轉粒化產品或片狀產品 ，此種形式的缺點是在例如粉狀產品之情形下，無法避免 飛揚或環境污染，或鬆密度太低以致運送成本很高，在輾 轉粒化產品之情形下，可以降低飛揚，但是當其作爲墨 或塗料物質使用時，容易有分散性不良之問題，換句話說 ,在碳黑工業上，咸信降低環境汙染及改進分散性彼此之 間有矛盾之關係 關於粉狀色料，過去通常有數種嘗試方法以改進在媒 劑中的分散性，例如JP—A—51—1530或JP— A — 52 — 103422提出經由將色料、樹脂、塑化劑 等分散在溶劑中，隨後冷凍乾燥而製備有良好分散性之色 料，另外，JP—A—57—49664提出一種方法其 (請先閲讀背面之注意事項5ρί0915 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (彳) Description of the invention The invention relates to a form of carbon black aggregate that is less likely to be crushed or broken during transportation or storage, or is in use It is less prone to environmental pollution and has excellent dispersibility in the vehicle. Carbon black is widely used industrially as a coloring material to make inks, coating materials, resins and other materials black, or as a reinforcing material for rubbers typified by tires. Historically, according to documents disclosed in the Kan era in China, carbon Black was first manufactured from pine soot. The subsequent manufacturing methods include the slot carbon black method developed by Me. Nutt in the United States in 1982 and the furnace method in Phillips in 1982. Since then, the production of carbon black has been significant. Improvements, and techniques for controlling particle size and particle structure length have shown significant progress. On the contrary, the form of carbon black has not been properly improved. The form of carbon black used in industry is limited to powder products, rolled granulated products or flake products. The disadvantage of this form is that in the case of powder products, for example, Avoid flying or environmental pollution, or the bulk density is too low so the transportation cost is high. In the case of rolling granulated products, flying can be reduced, but when it is used as ink or coating material, it is easy to have poor dispersion. In other words, in the carbon black industry, Xianxin has a contradictory relationship between reducing environmental pollution and improving dispersibility. Regarding powdered pigments, there have been several attempts in the past to improve the dispersibility in vehicles, such as JP— A-51-1530 or JP-A-52-103422 proposed to disperse colorants, resins, plasticizers, etc. in a solvent and then freeze-dry to prepare colorants with good dispersibility. In addition, JP-A-57 —49664 propose a method which (please read the precautions on the back first

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本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -4- 5i0915 經濟部中央標準局員工消费合作社印製 A7 ______B7 五、發明説明（3 ) 之原因尙不淸楚，其不僅適於處理且在媒劑中有極佳的分 散性，但是咸信碳黑粒子中的空氣被均勻地去除，使得碳 黑粒子均勻地聚集，實質上沒有不規則的密度，所以也可 改進在媒劑中的分散性。 以下將詳細地說明本發明。 碳黑集料 本發明碳黑集料之表面硬度至少爲70克，表面硬度 較宜高於內部硬度，在此，硬度係根據ASTM D — 2240的規定，用彈簧型態的硬度計（SHORE A )測量的値。 表面硬度是經由上述的方法測量碳黑集料表面所得的 値，內部硬度爲深入碳黑集料表面至少5毫米部份之硬度 ,內部硬度可得自將碳黑集料切開並用上述方法測量切面 之硬度。 測量硬度之位置沒有特別的限制，可在適於測量集料 之平均訊息之位置進行測量，在變動大的情形下，可在數 個位置進行測量，並取其平均値，例如在當集料爲平行四 邊形之情形下，可以在六個面的中間位置測量硬度値，並 計算其平均値，在當集料爲圓柱體之情形下，可在頂端及 底端兩個圓柱面的中間位置測量硬度値，並計算其平均値 〇 在本發明中，碳黑集料爲其中有多數的主要碳黑粒子 聚集，其體積足夠大而能用A STM D — 2240的方 (請先閲讀背面之注意事項This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -4- 5i0915 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 ______B7 V. The reason for the invention (3) is not unreasonable. It is suitable for processing and has excellent dispersibility in the vehicle, but the air in the salt black carbon black particles is uniformly removed, so that the carbon black particles are uniformly aggregated, and there is substantially no irregular density, so it can also be improved in the medium. Dispersibility in the agent. The present invention will be described in detail below. Carbon black aggregate The surface hardness of the carbon black aggregate of the present invention is at least 70 grams, and the surface hardness is preferably higher than the internal hardness. Here, the hardness is based on ASTM D-2240, using a spring-type hardness tester (SHORE A ) Measured plutonium. The surface hardness is obtained by measuring the surface of the carbon black aggregate through the above method. The internal hardness is a hardness at least 5 mm deep into the surface of the carbon black aggregate. The internal hardness can be obtained by cutting the carbon black aggregate and measuring the cut surface using the above method. Of hardness. There is no particular limitation on the position for measuring hardness. It can be measured at a position suitable for measuring the average information of the aggregate. In the case of large fluctuations, it can be measured at several positions and the average value can be taken. For example, when the aggregate is In the case of a parallelogram, the hardness 値 can be measured at the middle position of the six faces and the average 计算 can be calculated. When the aggregate is a cylinder, it can be measured at the middle position of the two cylindrical faces at the top and bottom. The hardness is 値, and the average value is calculated. In the present invention, the carbon black aggregate is the majority of the main carbon black particles, and its volume is large enough to use the square of A STM D-2240 (please read the note on the back first) matter

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 5i0915 A7 B7 經濟部中央標準局員工消費合作社印裝 五、發明説明（4 ) 法測量其硬度，因爲習知的粒狀產物或片狀產物比本發明 之集料小很多，彼等習知產物之硬度無法用ASTM D -2240的方法測量，據此，本發明集料足夠大而使集 料之性質與習知的粉狀產物、粒狀產物或片狀產物差異很 大，因此，可以解決關於習知產物的許多問題。 如果碳黑集料之硬度低於70克，集料的處理過程中 很容易發生粉化或破碎，在運送過程中使集料容易分解， 因此沒有適當的強度供使用，碳黑集料之表面硬度並沒有 特別的限制，’只要其至少爲7 0克，且較宜爲1 0 0至 2，000克，更宜爲200至1，500克，最適宜爲 300至800克，在此範圍內，在媒劑中的分散性特佳 ,當其作爲油墨或塗料物質的色料時，可以很容易地分散 ，當其供製備橡膠組成物使用時，其係經由Banbury混合機 等的強力混合，其中分散性很少成爲問題，且可以接受較 高的硬度而沒有問題，據此，決定於特定的用途而可適當 地選擇硬度。 本發明之碳黑集料可爲其中表面硬度高於內部硬度， 更宜爲表面硬度是內部硬度的1·05至1·50倍，在 內部硬度變動之情形下，選用表層下方5毫米位置之硬度 〇 使用的碳黑沒有特定的限制，例如可以使用燈黑、乙 炔黑或爐黑，普遍使用之爐黑可以製成具有小的粒子大小 及小的結構，且當供不同的有色組成物使用時，其可提供 極佳的特性，此咸信歸因於在其表面官能基之特性，換句 (請先閲讀背面之注意事項 —-- 本頁) %τThis paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 5i0915 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (4) The hardness is measured because of the conventional granular product The flaky product is much smaller than the aggregate of the present invention, and the hardness of their conventional products cannot be measured by the method of ASTM D-2240. According to this, the aggregate of the present invention is large enough to make the properties of the aggregate and the conventional powdery The products, granular products, or flake products vary widely, and therefore many problems with conventional products can be solved. If the hardness of the carbon black aggregate is less than 70 grams, it is easy to pulverize or break during the processing of the aggregate, and it is easy to decompose the aggregate during transportation. Therefore, there is no proper strength for the use. The hardness is not particularly limited, as long as it is at least 70 grams, and more preferably 100 to 2,000 grams, more preferably 200 to 1,500 grams, and most preferably 300 to 800 grams, in this range. In addition, it has excellent dispersibility in the vehicle. When it is used as a colorant for inks or coating materials, it can be easily dispersed. When it is used to prepare rubber compositions, it is strongly mixed through a Banbury mixer or the like Among them, dispersibility is rarely a problem, and higher hardness can be accepted without problems. Accordingly, the hardness can be appropriately selected depending on the specific application. The carbon black aggregate of the present invention may be one in which the surface hardness is higher than the internal hardness, and more preferably, the surface hardness is 1.05 to 1.50 times the internal hardness. In the case where the internal hardness varies, a position 5 mm below the surface layer is selected. There is no specific limitation on the carbon black used. For example, lamp black, acetylene black, or furnace black can be used. The commonly used furnace black can be made with small particle size and small structure, and when used for different colored compositions. At the same time, it can provide excellent characteristics, this letter is attributed to the characteristics of the functional groups on its surface, in other words (please read the precautions on the back first --- this page)% τ

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 540915 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（5 ) 話說，其有粉碎及飛揚之嚴重問題，據此，從工業眼光來 看，本發明使用此爐黑有實質上的重要性。 此碳黑集料之製法沒有特別的限制，但是，爲了得到 有最佳硬度之碳黑集料，較宜使用的方法是將碳黑放在合 適的模具中並經由壓力使其聚集，碳黑集料之製法沒有特 別的限制，只要其可產生內部硬度低且表面硬度高之集料 ，但是，本發明之集料可以很容易地製備，例如經由下列 方法，換句話說，將碳黑塡入可滑動的模具中，並在每分 鐘至少0.Γ kg f/cm2的壓製率下壓製，較宜在每 分鐘1至500 kg f/cm2下聚集碳黑，其中表面的 硬度將會高且內部的硬度將會低，因此可以很容易地得到 本發明之碳黑集料。 至於壓製所使用的設備，可以使用多種壓模機器包括 水壓式機器集空壓式機器。 在此，裝入碳黑之可滑動模具的物質沒有特別的限制 ，可以使用不同金屬、陶瓷及樹脂製成的模具，聚集碳黑 之壓力較宜直接來自實體的模具，例如在碳黑是用環繞在 碳黑周圍的氣體壓製時，例如在JP—A-6— 1 2 2 1 1 1中，很難形成具有適當表面硬度之如同本發 明的碳黑集料。 本發明碳黑集料之大小並沒有特別的限制，其可在硬 度可用ASTM D — 2 240規定的方法下測量之範圍 內，集料之體積特別適宜爲至少約1立方公分，如果集料 的體積小於1立方公分，集料本身容易分散，因此導致環 (請先閲讀背面之注意事項This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 540915 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy From an industrial perspective, the use of this furnace black in the present invention is of substantial importance. There is no particular limitation on the method of producing this carbon black aggregate, but in order to obtain a carbon black aggregate with the best hardness, the more suitable method is to place the carbon black in a suitable mold and aggregate it by pressure. The method of making the aggregate is not particularly limited as long as it can produce aggregates with low internal hardness and high surface hardness, but the aggregates of the present invention can be easily prepared, for example, by the following method, in other words, carbon black Into a slidable mold and press at a compression rate of at least 0. Γ kg f / cm2 per minute, it is more suitable to collect carbon black at 1 to 500 kg f / cm2 per minute, where the surface hardness will be high and The internal hardness will be low, so that the carbon black aggregate of the present invention can be easily obtained. As for the equipment used for the pressing, a variety of compression molding machines can be used, including hydraulic compression machines. Here, there are no particular restrictions on the material into which the carbon black slidable mold is inserted. Molds made of different metals, ceramics, and resins can be used. The pressure for collecting carbon black is preferably directly from the solid mold. For example, in the case of carbon black, When the gas surrounding the carbon black is pressed, for example, in JP-A-6-1 2 2 1 1 1, it is difficult to form a carbon black aggregate having an appropriate surface hardness like the present invention. The size of the carbon black aggregate of the present invention is not particularly limited, and it can be measured within the range specified by ASTM D-2 240. The volume of the aggregate is particularly suitable to be at least about 1 cubic centimeter. The volume is less than 1 cubic centimeter, the aggregate itself is easy to disperse, so the ring (please read the precautions on the back first)

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 510915 經濟部中央標準局員工消費合作社印製 A7 ______B7__五、發明説明（7 ) 時，可使用有凸起之模具，使得可以形成有凹洞之碳黑集 料。 另一方面，可以形成所謂的切線之凹面，當將集料放 入混合槽時可改進分解，也就是說當碳黑與媒劑混合時， 可改進其分散性，簡化分散步驟，免除秤重的勞力或改進 秤重之效率，例如經由提供梯形的規則凹面/凸面圖案， 可以輕易地將碳黑集料分開成各塊狀。 將碳黑集料製成球體、圓柱體或八面體或更多面體之 形狀、五邊或更多邊之柱體，可將此集料製成具有極佳的 軋碾性質，而其運送將很容易，特別是當其製成規則的六 邊形柱體時，有極佳的軋碾性質，同時當數個此種集料堆 積時，有極佳的穩定性，而且，可選擇不同的形狀，使得 可促進運送或放入加料斗、槽等，本發明之碳黑集料有適 當的硬度，據此，在正常處理過程中，不會有裂開或破碎 之損傷或由於封套破裂或甚至當掉落、投擲或堆積也不會 造成環境污染，且其可輕易地形成不同所需的形狀且可保 持該形狀，反之，製備含不同碳黑之組成物時，此集料可 形成具有極佳的性質，使得可用習知的混合方法輕易地將 其分散及混合，在使用此碳黑的所有情形下可同時明顯地 改進操作效率。 據此，本發明之碳黑集料，可選擇視需要的形狀供使 用。 而且，製造本發明之碳黑集料時，除了碳黑以外可摻 混樹脂或其他不同的添加劑，在此情形下，此添加劑的用 (請先閲讀背面之注意事項This paper size applies to China National Standard (CNS) A4 (210X297 mm) 510915 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 ______B7__ V. In the description of the invention (7), a convex mold can be used to make A carbon black aggregate with a cavity formed. On the other hand, a so-called tangent concave surface can be formed. When the aggregate is placed in the mixing tank, the decomposition can be improved, that is, when the carbon black is mixed with the vehicle, the dispersibility can be improved, the dispersing step can be simplified, and the weighing can be avoided. Labor or improve the efficiency of weighing, such as by providing a trapezoidal regular concave / convex pattern, the carbon black aggregate can be easily divided into blocks. The carbon black aggregate is made into the shape of a sphere, a cylinder, an octahedron or more, and a cylinder with five or more sides. This aggregate can be made into excellent rolling properties. It is very easy, especially when it is made into regular hexagonal cylinders, it has excellent rolling properties, and at the same time, it has excellent stability when several such aggregates are stacked. The shape makes it easy to transport or put into the hopper, trough, etc. The carbon black aggregate of the present invention has appropriate hardness. According to this, during normal processing, there will be no cracking or crushing damage, or due to the rupture of the envelope or Even when dropped, thrown, or piled up, it will not cause environmental pollution, and it can easily be formed into different shapes and can maintain the shape. On the contrary, when preparing a composition containing different carbon blacks, this aggregate can be formed to have Its excellent properties make it easy to disperse and mix it by conventional mixing methods, and it can significantly improve the operating efficiency in all cases where this carbon black is used. Based on this, the carbon black aggregate of the present invention can be used in a desired shape. In addition, when manufacturing the carbon black aggregate of the present invention, resins or other different additives may be blended in addition to carbon black. In this case, the use of this additive (please read the precautions on the back first)

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -10- 510915 A7 B7 五、發明説明（12 ) 折疊包封、真空包封或塗膜之間沒有空隙，如果用此方法 在包封集料後，經由上述物理力量形成裂縫，即使在集料 產生裂縫後此膜有助於其保持形狀的性質，可促進堆積供 輸送或儲存。特別適宜經由真空包封、收縮包封或塗上具 有形成膜的性質之可固化液體，形成一種與碳黑集料緊密 貼合之封套，防止模製產物表面品質的惡化例如氧化、改 進強度、增加處理效率、降低運送與儲存的成本、並促進 封套之形成，塗膜的方法沒有特別的限制，但可使用例如 噴霧、空氣塗料機、葉片塗料機、桿塗料機、刀片塗料機 或浸漬塗料機的方法。 特別針對保護表面並保持碳黑集料形狀之目的，可預 先用熱收縮性的物質套封集料，然後加熱使其與封套緊密 貼合，但是通常可用非熱收縮性的物質套封集料，決定於 特定之目的，可用多孔物質或布套封集料。 使用熱收縮性物質經由熱收縮包封形成封套之方法， 可以輕易地達到使碳黑與封套緊密地貼合，並改進形狀保 持之性質，反之，在熱收縮過程中，封套上可形成微細的 孔洞而惡化，決定於特定之應用或使用模式，較宜塗上液 體樹脂將這些孔洞套封，用膜封閉這些孔洞或提供雙層包 封，從完全防止汙染的角度來看，將孔洞封閉使實質上防 止碳黑的洩出。 套封的程度沒有特別的限制，可根據特定的用途、運 送或儲存環境而適當地選擇，例如，通常用不同的膜形成 +脂、紙等套封，但是套封並不限於這些典型的實例，且 C 'ί , .·ί· /i ./ A · 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）_ 15This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -10- 510915 A7 B7 V. Description of the invention (12) There is no gap between the folding encapsulation, vacuum encapsulation or coating film. After encapsulating the aggregate, cracks are formed by the above-mentioned physical force. Even after the aggregate has cracked, the film helps to maintain its shape and can promote accumulation for transportation or storage. It is particularly suitable for vacuum-encapsulating, shrink-encapsulating, or coating a curable liquid with film-forming properties to form an envelope that closely adheres to the carbon black aggregate to prevent deterioration of the surface quality of the molded product such as oxidation, improved strength, There is no particular limitation on the method of coating film to increase the processing efficiency, reduce the cost of transportation and storage, and promote the formation of envelopes, but spraying, air coating machines, blade coating machines, rod coating machines, blade coating machines, or dip coatings can be used. Machine approach. Particularly for the purpose of protecting the surface and maintaining the shape of the carbon black aggregate, the aggregate can be enveloped with a heat-shrinkable substance in advance, and then heated to closely fit the envelope, but the aggregate can be enveloped with a non-heat-shrinkable substance. Depending on the specific purpose, the aggregate can be sealed with a porous substance or cloth. The method of using a heat-shrinkable substance to form an envelope through heat shrink encapsulation can easily achieve that the carbon black and the envelope are closely adhered to each other, and the shape retention property is improved. Conversely, during the heat-shrinking process, the envelope can form a fine The deterioration of the holes depends on the specific application or use mode. It is better to coat the holes with a liquid resin, seal the holes with a film or provide a double-layer encapsulation. From the perspective of completely preventing contamination, the holes are closed. The leakage of carbon black is substantially prevented. The degree of encapsulation is not particularly limited, and can be appropriately selected according to the specific use, transportation or storage environment. For example, different types of films are usually used to form envelopes such as grease, paper, etc., but the envelopes are not limited to these typical examples. , And C 'ί,. · Ί · / i ./ A · This paper size applies to China National Standard (CNS) A4 (210X297 mm) _ 15

經濟部中央標隼局員工消費合作社印製 (請先閲讀背面之注意事項 -- 本頁)Printed by the Employees' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs (Please read the note on the back-this page)

510915 經濟部中央標準局貝工消費合作社印製 A7 ____ B7五、發明説明（14 ) 全將使用者與碳黑隔離，且可達到完全預防其使用時由於 飛揚造成之環境污染，具體地說，經由使用可溶解或混溶 於油墨、塗料、樹脂或橡膠中的含碳黑的組成物之物質（ 以下稱爲”可溶性物質”）套封後，可在不將封套去除下將 套封的集料投入混合槽內，可以使用碳黑之微細粉末而不 會產生環境污染，且此在操作效率的觀點上也非常需要， 而且，可有效地防止碳黑集料載運送過程中破裂。 在此，”可溶性”表示實質上的溶解，但是不限於完全 溶解至沒有固體存在之程度，而是可含有微細的固體，只 要此物質可均勻地混合並達到不會對所要的含碳黑之組成 物性質有負面效應之程度，而且，”可混溶”表示此物質可 在外觀上達到混溶之狀態。 而且，可因而改進運送過程之處理效率，當本發明之 碳黑集料有適當的強度時，可使用多種方法將其套封，所 得套封的碳黑集料具有進一步改進之強度，所以不會破裂 ，可輕易地在與碳黑集料緊密貼合下形成封套，且封套的 厚度也可視需要調整，因此，經由適當地選擇封套的物質 ，可以很容易地改進強度或衝擊吸收性質，且可有效地預 防碳黑集料在運送過程中破裂。 而且，碳黑部份之密度足夠高，可以實質上降低運_ /.〆' 及儲存之成本，地進行去除粒子間的空氣，所以在 媒劑中的分散性特佳，例如，經由將粉末包封在袋子內的 方法，隨後進行去除空氣，很難有效地去除粒子間的空氣 並使碳黑粒子彼此連接至形成碳黑集料的程度，換句話說 (請先閲讀背面之注意事項 — 本頁) 訂510915 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 ____ B7 V. Description of the invention (14) All users are isolated from carbon black and can completely prevent environmental pollution caused by flying when they are used, specifically, By encapsulating a carbon black-containing composition that is soluble or miscible in inks, coatings, resins, or rubbers (hereinafter referred to as "soluble substances"), the envelope can be collected without removing the envelope. When the materials are put into the mixing tank, the fine powder of carbon black can be used without causing environmental pollution, and this is also very necessary from the viewpoint of operating efficiency, and it can effectively prevent the carbon black aggregate from being broken during the loading process. Here, "solubility" means substantial dissolution, but is not limited to complete dissolution to the extent that no solids are present, but may contain fine solids as long as this substance can be mixed uniformly to the extent that it does not affect the desired carbon black. The nature of the composition has a negative effect, and "miscible" means that the substance can be miscible in appearance. Moreover, the processing efficiency in the transportation process can be improved accordingly. When the carbon black aggregate of the present invention has appropriate strength, it can be enveloped by using various methods. The obtained enveloped carbon black aggregate has further improved strength, so It will rupture, and the envelope can be easily formed under close contact with the carbon black aggregate, and the thickness of the envelope can be adjusted as needed. Therefore, by properly selecting the material of the envelope, the strength or impact absorption properties can be easily improved, and It can effectively prevent the carbon black aggregate from cracking during transportation. In addition, the density of the carbon black part is sufficiently high to substantially reduce the cost of transportation and storage, and to remove the air between the particles, so the dispersibility in the vehicle is particularly good, for example, by mixing powder The method of encapsulating in the bag, followed by removing the air, is difficult to effectively remove the air between the particles and connect the carbon black particles to each other to the extent that the carbon black aggregate is formed, in other words (please read the precautions on the back first— (This page)

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •17- 510915 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（15 ) ，在抽真空時，真空系統容易吸進粉末，因此無法適當地 將空氣抽出，而且，在此方法下，經由大氣空氣進行壓製 ,無法進行降低至適當的體積，且此仍然不適用於消除鬆 散的狀態，而且，即使將整個袋子進行壓製，沒有適當的 壓力施加在碳黑上，因此很灘製成保持特定形狀之集料， 據此，迄今仍然沒有包封的碳黑模製產物，尤其是提供極 佳性質者，然而，本發明之碳黑集料可輕易地用上述的方 法製造。 在本發明中，封套內的碳黑爲特定集料之形式，因此 可解決下列問題，換句話說，首先即使是使用以可溶性物 質製成的包封袋包封，且碳黑是以在袋子包封下混合時， 如果碳黑沒有形成本發明之集料，當其投入容器內供製備 例如油墨或塗料時，樹脂膜將溶解並從包封袋釋放出碳黑 粉末，此粉末本身與液體的相容性不良，因此粉末容易經 由在製造設備中提供的攪拌風扇或排氣機而飛揚，因此導 致環境污染。其次，碳黑粉末有低的鬆密度，當在含空氣 狀態下用樹脂膜包封時，不適於運送或儲存。第三，含空 氣的微細粉末之碳黑很難分散在油墨、塗料的淸漆或熔化 的樹脂或橡膠中，使用本發明之碳黑集料，可以解決這些 問題。 封套的物質沒有特別的限制，可以使用例如聚苯乙烯 、或醇酸樹脂例如脂族酸改良之醇酸樹脂、松香改良之醇 酸樹脂、亞麻子油改良之醇酸樹脂、脫水蓖麻油改良之醇 酸樹脂、大豆油改良之醇酸樹脂、酞酸醇酸樹脂或苯乙烯 (請先閲讀背面之注意事項 本頁)This paper size applies to China National Standard (CNS) A4 (210X297 mm) • 17- 510915 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (15), the vacuum system is easy to suck Into the powder, so the air cannot be properly drawn out, and in this method, pressing through atmospheric air can not be reduced to an appropriate volume, and this is still not suitable for eliminating the loose state, and even if the entire bag is Pressing, without proper pressure on the carbon black, is therefore made of aggregates that maintain a specific shape. Accordingly, there is still no encapsulated carbon black molded product, especially those that provide excellent properties. However, the present The carbon black aggregate of the present invention can be easily manufactured by the method described above. In the present invention, the carbon black in the envelope is in the form of a specific aggregate, so the following problems can be solved. In other words, firstly, even if it is encapsulated with an encapsulation bag made of a soluble substance, the carbon black is encapsulated in a bag. When mixed under encapsulation, if the carbon black does not form the aggregate of the present invention, when it is put into a container for preparing, for example, ink or coating, the resin film will dissolve and release the carbon black powder from the encapsulation bag. The powder itself and the liquid The powder has a poor compatibility, so that the powder is liable to fly up through a stirring fan or an exhauster provided in the manufacturing equipment, thereby causing environmental pollution. Secondly, carbon black powder has a low bulk density and is not suitable for transportation or storage when it is encapsulated with a resin film in an air-containing state. Thirdly, it is difficult to disperse carbon black containing fine powder of air in the ink or paint varnish or molten resin or rubber. These problems can be solved by using the carbon black aggregate of the present invention. The material of the envelope is not particularly limited, and for example, polystyrene, or an alkyd resin such as an aliphatic acid-modified alkyd resin, a rosin-modified alkyd resin, a linseed oil-modified alkyd resin, and a dehydrated castor oil-modified resin can be used. Alkyd resin, soybean oil modified alkyd resin, phthalic acid alkyd resin or styrene (Please read the precautions on the back page first)

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 510915 A7 B7 經濟部中央標準局員工消費合作社印装 五、發明説明（16 ) 改良之醇酸樹脂；可以使用例如胺基一醇酸樹脂如尿素-蜜胺樹脂、尿素樹脂、蜜胺樹脂或苯胍胺樹脂；可以使用 例如聚酯樹脂或環氧樹脂例如環氧-酚型樹脂、環氧-胺 基樹脂、環氧-胺樹脂、環氧-醯胺樹脂、環氧樹脂酯或 環氧-異氰酸鹽樹脂；可以使用例如聚胺酯樹脂或矽酮樹 脂例如醇酸改良之矽酮樹脂、環氧改良之矽酮樹脂或酚改 良之矽酮樹脂；可以使用例如二甲苯樹脂例如偏二甲苯-甲醛樹脂、酚改良的二甲苯樹脂、松香改良的酚型樹脂、 脂族酸改良的酚型樹脂、1 0 0%酚型樹脂、改良的酚型 樹脂或酚型樹脂；可以使用例如丙烯酸樹脂例如硝基纖維 素改良的丙烯酸樹脂、纖維素醋酸酯丁酸改良的丙烯酸樹 脂、醇酸改良的丙烯酸樹脂、聚丙烯酸醯胺、聚丙烯酸、 聚丙烯酸酯、聚丙烯腈、聚丙烯腈酯、聚苯乙烯、聚偏丙 烯醯胺、聚偏丙烯酸、聚偏丙烯酸酯或聚偏丙烯腈；可以 使用例如醋酸乙烯酯樹脂、氯乙烯樹脂、或聚烯烴；可以 使用例如聚乙烯例如氯化聚乙烯、氯磺酸化聚乙烯、高分 子量聚乙烯、低分子量聚乙烯、高密度聚乙烯、中密度聚 乙烯、低密度聚甲撐、超低密度聚乙烯或低分子量聚乙烯 均聚物型態，或聚丙烯例如氯化聚丙烯或低分子量聚丙烯 :可以使用例如聚胺酯樹脂、氯乙烯樹脂、丁醛樹脂、偏 二氯乙烯樹脂、或膠乳樹脂例如天然橡膠、SBR橡膠、 丁基橡膠、氯丁二烯、氯丁橡膠、氫氯化橡膠或環化橡膠 ;可以使用例如松香樹脂例如膠松香、木松香、妥爾油松 香、松香改良的順丁烯二酸樹脂、苯乙烯改良的順丁烯二 (請先閲請背面之注意事項 -- wURc本頁) 訂This paper size applies to China National Standard (CNS) A4 (210X297 mm) 510915 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (16) Improved alkyd resin; for example, amine monool Acid resin such as urea-melamine resin, urea resin, melamine resin or benzoguanamine resin; for example, polyester resin or epoxy resin such as epoxy-phenol type resin, epoxy-amine-based resin, epoxy-amine Resin, epoxy-amidamine resin, epoxy resin, or epoxy-isocyanate resin; for example, polyurethane resin or silicone resin such as alkyd-modified silicone resin, epoxy-modified silicone resin, or phenol can be used Modified silicone resin; for example, xylene resin such as metaxylene-formaldehyde resin, phenol modified xylene resin, rosin modified phenol resin, aliphatic acid modified phenol resin, 100% phenol resin Improved phenolic resin or phenolic resin; for example, acrylic resins such as nitrocellulose modified acrylic resins, cellulose acetate butyric acid modified acrylic resins, alkyd modified resins can be used. Acrylic resin, polyacrylamide, polyacrylic acid, polyacrylic acid, polyacrylonitrile, polyacrylonitrile, polystyrene, polyacrylamide, polyacrylic acid, polyacrylic acid, or polyacrylonitrile; can be used For example, vinyl acetate resin, vinyl chloride resin, or polyolefin; for example, polyethylene such as chlorinated polyethylene, chlorosulfonated polyethylene, high molecular weight polyethylene, low molecular weight polyethylene, high density polyethylene, medium density polyethylene can be used. , Low density polyethylene, ultra low density polyethylene or low molecular weight polyethylene homopolymer type, or polypropylene such as chlorinated polypropylene or low molecular weight polypropylene: for example, polyurethane resin, vinyl chloride resin, butyraldehyde resin can be used , Vinylidene chloride resin, or latex resin such as natural rubber, SBR rubber, butyl rubber, chloroprene, neoprene, hydrochloride rubber or cyclized rubber; for example, rosin resin such as gum rosin, wood rosin can be used , Tall oil rosin, rosin-modified maleic acid resin, styrene-modified maleic acid (please read the precautions on the back first-wUR c this page)

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -19- 510915 經濟部中央標準局員工消費合作社印装 A7 B7____五、發明説明（18 ) 胺樹脂、丁二烯樹脂、聚對苯二甲酸丁二酯、石油樹脂、 硬歷青、改良的醇酸樹脂、蟲膠、噠瑪酯、澱粉、糖化物 、或液晶聚合物。可以使用例如水溶性樹脂、聚乙烯醇、 聚環氧乙烷、糊精、聚丙烯酸鈉、聚丙烯醯胺、明膠、殼 糖、酪素、骨膠原、蛋白、海草、卡洛鈉（carageenan)、 精胺酸鈉、瓊脂、黃原膠或普藍（pluran)。 至於共聚物，可以使用例如下列樹脂，換句話說，可 以使用例如低分子量聚乙烯/丙烯酸共聚物、低分子量聚 乙烯/醋酸乙烯酯共聚物、乙烯/醋酸乙烯醋共聚物、甲 基丙烯基醚/順丁烯二酸共聚物、乙烯/丙烯酸乙酯共聚 物、乙烯/甲基丙烯酸無規聚合物、乙烯/丙烯酸共聚物 、乙烯/丙烯酸乙烯酯共聚物、乙烯/氯乙烯共聚物、氯 乙烯/醋酸乙烯酯共聚物、乙烯/醋酸乙烯酯/氯乙烯接 枝樹脂、乙烯/乙烯醇共聚物、羧乙烯基共聚物、聚甲醛 、N-乙烯基吡咯啶酮/醋酸乙烯酯共聚物、或甲基乙烯 基醚/醋酸乙烯酯共聚物。 其他方面，當製備照相底片的背面紙、感光物質脂包 封紙或黑色紙例如黑色棉屑紙時，可用紙塗覆碳黑集料。 可溶性物質 特別適宜的封套物質，可以使用上述不同合成樹脂之 可溶性物質，更特定地說，對於應用至塗料時，可以使用 例如超低密度聚乙烯、孅、聚苯乙烯、醇酸樹脂例i卩酞醇 酸樹脂或苯乙烯改良之醇酸樹脂、胺基一醇酸樹脂例如脲 (請先閲讀背面之注意事項This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -19- 510915 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7____ V. Description of the invention (18) Amine resin, butadiene resin, polymer Butyl terephthalate, petroleum resin, hard green, modified alkyd resin, shellac, pyridate, starch, saccharide, or liquid crystal polymer. For example, water-soluble resin, polyvinyl alcohol, polyethylene oxide, dextrin, sodium polyacrylate, polyacrylamide, gelatin, chitosan, casein, collagen, protein, seaweed, carageenan can be used , Sodium arginine, agar, xanthan gum, or pluran. As for the copolymer, for example, the following resins can be used, in other words, for example, low molecular weight polyethylene / acrylic acid copolymer, low molecular weight polyethylene / vinyl acetate copolymer, ethylene / vinyl acetate copolymer, methacrylic ether / Maleic acid copolymer, ethylene / ethyl acrylate copolymer, ethylene / methacrylic random polymer, ethylene / acrylic acid copolymer, ethylene / vinyl acrylate copolymer, ethylene / vinyl chloride copolymer, vinyl chloride / Vinyl acetate copolymer, ethylene / vinyl acetate / vinyl chloride graft resin, ethylene / vinyl alcohol copolymer, carboxyvinyl copolymer, polyoxymethylene, N-vinyl pyrrolidone / vinyl acetate copolymer, or Methyl vinyl ether / vinyl acetate copolymer. In other aspects, carbon black aggregates may be coated with paper when preparing the backing paper of a photographic film, photosensitive material-encapsulating paper, or black paper such as black cotton paper. As a particularly suitable envelope material for soluble materials, the above-mentioned soluble materials of different synthetic resins can be used. More specifically, when applied to coatings, for example, ultra-low density polyethylene, rhenium, polystyrene, and alkyd resin can be used. Phthalic acid resin or styrene modified alkyd resin, amino monoalkyd resin such as urea (Please read the precautions on the back first

本頁) 訂 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） -21- 510915 A7 B7 五、發明説明（19 ) (請先閲讀背面之注意事項 -訂(This page) Order This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) -21- 510915 A7 B7 V. Description of the invention (19) (Please read the precautions on the back-order

經濟部中央標準局員工消費合作社印裝 -蜜胺樹脂、脲樹脂、蜜胺樹脂或苯胍胺樹脂、聚酯樹脂 、環氧樹脂例如環氧-酚樹脂、環氧-胺基樹脂、環氧-胺樹脂、環氧-醯胺樹脂、環氧樹脂酯或環氧-異氰酸酯 樹脂、聚胺酯樹脂、矽酮樹脂例如醇酸改良的矽酮樹脂、 環氧改良的矽酮樹脂或酚改良的矽酮樹脂、二甲苯樹脂例 如偏二甲苯一甲醛樹脂、酚改良的二甲苯樹脂、松香改良 的酚型樹脂、脂肪酸改良的酚型樹脂、醋酸乙烯酯樹脂、 氯乙烯樹脂、丙烯酸樹脂例如硝基纖維素改良的丙烯酸樹 脂、纖維素醋酸酯丁酸酯改良的丙烯酸樹脂或醇酸改良的 丙烯酸樹脂、膠乳例如SBR樹脂、丁基樹脂、氯丁二烯 或氯丁橡膠、松香樹脂例如膠松香、木松香或妥爾油松香 、或水溶性樹脂例如聚乙烯醇、聚環氧乙烷、羧甲基纖維 素、羥丙基甲基纖維素、羥乙基纖維素、糊精、甲基乙烯 基醚/順丁烯二酸共聚物、聚丙烯酸鈉、聚丙烯醯胺、明 膠、殼糖、蟲膠、酪素、骨膠原、蛋白、海草、卡洛鈉、 精胺酸鈉、瓊脂、黃原膠或普藍。對於應用至油墨時，可 以使用例如松香樹脂例如膠松香、木松香或妥爾油松香、 酚型樹脂例如1 0 0%酚型樹脂或改良的酚型樹脂、改良 之醇酸樹脂例如脂肪酸改良之醇酸樹脂、松香改良之醇酸 樹脂、亞麻油改良之醇酸樹脂、脫水蓖麻油改良之醇酸樹 脂或大豆油改良之醇酸樹脂、石油樹脂、松香-順丁烯二 酸樹脂、環化橡膠、酪素、蟲膠、松香改良的順丁烯二酸 樹脂、硝基纖維素、聚醯胺樹脂、氯化聚丙烯、聚胺酯樹 脂、環氧樹脂、丙烯酸樹脂、聚氯乙烯、氯乙烯一醋酸乙 本紙張尺度適用中國國家標準（CNS ) A4現格（ 210X297公釐） •22- 510915 經濟部中央標隼局員工消费合作社印製 A7 _ __ B7_五、發明説明（20 ) 烯酯共聚物、丁醛樹脂、偏二氯乙烯樹脂、聚烯烴例如低 分子量聚乙烯、低密度聚乙烯、高密度聚乙烯、超低密度 聚乙烯、孅、低分子量聚乙烯均聚物、低分子量聚乙烯/ 丙烯酸共聚物、低分子量聚乙烯/醋酸乙烯酯共聚物、或 低分子量聚丙烯。 對於應用至將樹脂染色時，較宜使用一種樹脂其即使 當塗覆或混合需要染色的樹脂時，對其性質例如強度或良 好的外觀沒有負面之效應，特定地說，可以使用例如 ABS樹脂或丙烯酸樹脂例如聚丙烯醯胺、聚丙烯酸、聚 丙烯酸酯、聚丙腈、聚丙腈酯、苯乙烯、聚甲基丙烯醯胺 或聚甲基丙腈。可以使用離子交聯聚合物、氯化聚醚、香 豆酮-茚樹脂、再生纖維素或石油樹脂。至於纖維素衍生 物，可以使用例如鹼纖維素、纖維素酯、纖維素醋酸酯、 纖維素醋酸酯丁酸酯、纖維素黃原酸酯、纖維素硝酸酯、 纖維素醚、羧甲基纖維素、纖維素醚酯、甲基纖維素、乙 基纖維素、乙基羥乙基纖維素、羥丙基纖維素、羥乙基纖 維素或賽璐珞。至於氟樹脂，可以使用例如FEP、聚氯 三氟乙烯、聚四氟乙烯、聚偏二氟乙烯或聚氟乙烯。至於 聚醯胺，可以使用例如脂族聚醯胺，例如尼龍1 1、尼龍 1 2、尼龍6、尼龍6 λ1 0、尼龍6 1 2或尼龍6 d 6、聚 苯二醯對苯二胺、聚醯胺醯亞胺或聚醯胺酸。可以使用聚 烯丙酸酯、聚對苯二甲酸乙二酯、聚偏二氯乙烯或聚氯乙 烯。至於聚烯烴，可以使用聚乙烯例如氯化聚乙烯、氯碾 化聚乙烯、高分子量聚乙烯、低分子量聚乙烯、高密度聚 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） (請先閲讀背面之注意事項 — 本頁)Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-melamine resin, urea resin, melamine resin or benzoguanamine resin, polyester resin, epoxy resin such as epoxy-phenol resin, epoxy-amine resin, epoxy resin -Amine resin, epoxy-amidamine resin, epoxy resin or epoxy-isocyanate resin, polyurethane resin, silicone resin such as alkyd modified silicone resin, epoxy modified silicone resin or phenol modified silicone Resin, xylene resin such as metaxylene-formaldehyde resin, phenol-modified xylene resin, rosin-modified phenol resin, fatty acid-modified phenol resin, vinyl acetate resin, vinyl chloride resin, acrylic resin such as nitrocellulose Modified acrylic resin, cellulose acetate butyrate modified acrylic resin or alkyd modified acrylic resin, latex such as SBR resin, butyl resin, chloroprene or neoprene, rosin resin such as gum rosin, wood rosin Or tall oil rosin, or water-soluble resins such as polyvinyl alcohol, polyethylene oxide, carboxymethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, Sperm, methyl vinyl ether / maleic acid copolymer, sodium polyacrylate, polyacrylamide, gelatin, shell sugar, shellac, casein, collagen, protein, seaweed, carlo sodium, arginine Sodium, agar, xanthan gum, or blue. For application to inks, for example, rosin resins such as gum rosin, wood rosin or tall oil rosin, phenolic resins such as 100% phenolic resin or modified phenolic resin, modified alkyd resins such as fatty acid modified Alkyd resin, rosin modified alkyd resin, linseed oil modified alkyd resin, dehydrated castor oil modified alkyd resin or soybean oil modified alkyd resin, petroleum resin, rosin-maleic acid resin, cyclization Rubber, casein, shellac, rosin-modified maleic acid resin, nitrocellulose, polyamide resin, chlorinated polypropylene, polyurethane resin, epoxy resin, acrylic resin, polyvinyl chloride, vinyl chloride Ethyl Acetate Paper Standard Applies Chinese National Standard (CNS) A4 Appearance (210X297 mm) • 22- 510915 Printed by the Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs A7 Materials, butyraldehyde resin, vinylidene chloride resin, polyolefins such as low molecular weight polyethylene, low density polyethylene, high density polyethylene, ultra low density polyethylene, rhenium, low molecular weight polyethylene Homopolymer, low molecular weight polyethylene / acrylic acid copolymer, low molecular weight polyethylene / vinyl acetate copolymers, or low molecular weight polypropylene. For the application to dyeing a resin, it is preferable to use a resin that has no negative effect on its properties such as strength or good appearance even when the resin to be dyed is applied or mixed, and in particular, ABS resin or The acrylic resin is, for example, polyacrylamide, polyacrylic acid, polyacrylate, polyacrylonitrile, polyacrylonitrile, styrene, polymethacrylamide, or polymethylpropionitrile. Ionic crosslinked polymers, chlorinated polyethers, coumarone-indene resins, regenerated cellulose or petroleum resins can be used. As the cellulose derivative, for example, alkali cellulose, cellulose ester, cellulose acetate, cellulose acetate butyrate, cellulose xanthate, cellulose nitrate, cellulose ether, carboxymethyl fiber can be used Cellulose, cellulose ether ester, methyl cellulose, ethyl cellulose, ethyl hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose or celluloid. As for the fluororesin, for example, FEP, polyvinyl chloride trifluoroethylene, polytetrafluoroethylene, polyvinylidene fluoride, or polyvinyl fluoride can be used. As for polyamide, for example, aliphatic polyamide can be used, such as nylon 11, 1, nylon 1, 2, nylon 6, nylon 6 λ10, nylon 6 1 2, or nylon 6 d 6, polyphenylene terephthalamide, Polyamidamine or imine. Polyacrylates, polyethylene terephthalate, polyvinylidene chloride, or polyvinyl chloride can be used. As for polyolefin, polyethylene such as chlorinated polyethylene, chlorinated polyethylene, high molecular weight polyethylene, low molecular weight polyethylene, and high-density polyethylene can be used. The size of the paper is applicable to China National Standard (CNS) A4 specification (210X297 mm). (Please read the note on the back-this page first)

-、1T-, 1T

-23 - 510915 A7 B7 經濟部中央標準局員工消費合作社印褽 五、發明説明（21 ) 乙烯、中密度聚乙烯、低密度聚乙烯、超低密度聚乙烯或 LLDPE、聚丁烯例如聚異丁烯、或聚丙烯。可以使用 例如聚碳酸酯、聚苯乙烯或聚碩例如聚醚碩或聚碩醯胺。 可以使用例如聚乙烯醇或聚乙烯酯例如聚肉桂酸乙烯酯、 聚醋酸乙烯酯、聚丙酸乙烯酯、聚硬脂酸乙烯酯、聚丁酸 乙烯酯、聚乙烯甲醛或聚乙烯吡咯啶酮。可以使用聚乙烯 醚例如聚異丁基乙烯基醚或聚甲基乙烯基醚、聚苯醚、聚 對苯二甲酸丁二酯、聚丙烯、聚甲基苯乙烯或聚甲烯。可 以使用例如聚環氧乙烷、聚硬脂酸乙烯酯、氫氯酸橡膠、 環化橡膠、***膠、古巴膠、聚胺酯樹脂、鄰苯二甲酸 二烯丙酯、脲樹脂、蜜胺樹脂、聚胺酯樹脂、丁二烯樹脂 、聚對苯二甲酸丁二酯、松香樹脂、石油樹脂、硬瀝青、 醇酸樹脂.、改良的醇酸樹脂、蟲膠、達馬樹脂、松香改良 的順丁烯二酸樹脂、苯乙烯改良的順丁烯二酸樹脂、硝基 纖維素、酪素、澱粉、糖化物、ABS樹脂或液晶聚合物 〇 而且可以使用共聚物例如乙烯/醋酸乙烯酯共聚物、 乙烯/丙烯酸乙酯共聚物、乙烯/甲基丙烯酸無規聚合物 、乙烯/丙烯酸共聚物、乙烯/丙烯酸乙烯酯共聚物、乙 烯/氯乙烯共聚物、乙烯/醋酸乙烯酯/氯乙烯接枝樹脂 、乙烯/乙嫌醇共聚物、羧乙烯基共聚物、聚申醛、N— 乙烯基吡咯啶酮/醋酸乙烯酯共聚物、或甲基乙烯基醚/ 醋酸乙烯酯共聚物。 至於熱固性樹脂，可以使用胺基樹脂例如苯胺樹脂、 (請先閱讀背面之注意事項 •Jf—丨 本頁) -訂'-23-510915 A7 B7 Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China. 5. Description of Invention (21) Ethylene, medium density polyethylene, low density polyethylene, ultra low density polyethylene or LLDPE, polybutenes such as polyisobutylene, Or polypropylene. For example, polycarbonate, polystyrene, or polyethylene such as polyether or polyethylene. For example, polyvinyl alcohol or polyvinyl ester such as polyvinyl cinnamate, polyvinyl acetate, polyvinyl propionate, polyvinyl stearate, polyvinyl butyrate, polyvinyl formaldehyde or polyvinyl pyrrolidone can be used. Polyethylene ethers such as polyisobutyl vinyl ether or polymethyl vinyl ether, polyphenylene ether, polybutylene terephthalate, polypropylene, polymethylstyrene or polymethylene can be used. For example, polyethylene oxide, polyvinyl stearate, hydrochloric acid rubber, cyclized rubber, gum arabic, Cuban gum, polyurethane resin, diallyl phthalate, urea resin, melamine resin, Polyurethane resin, butadiene resin, polybutylene terephthalate, rosin resin, petroleum resin, hard pitch, alkyd resin, modified alkyd resin, shellac, dama resin, modified rosin-modified butadiene Diacid resin, styrene-modified maleic acid resin, nitrocellulose, casein, starch, saccharide, ABS resin or liquid crystal polymer. Also copolymers such as ethylene / vinyl acetate copolymer, ethylene / Ethyl acrylate copolymer, ethylene / methacrylic random polymer, ethylene / acrylic acid copolymer, ethylene / vinyl acrylate copolymer, ethylene / vinyl chloride copolymer, ethylene / vinyl acetate / vinyl chloride graft resin, Ethylene / ethanol copolymer, carboxyvinyl copolymer, polyaldehyde, N-vinylpyrrolidone / vinyl acetate copolymer, or methyl vinyl ether / vinyl acetate copolymer. As for the thermosetting resin, you can use amine-based resins such as aniline resin, (Please read the precautions on the back first • Jf— 丨 this page)-Order '

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）_ 24 510915 經濟部中央標準局員工消費合作社印裝 A7 B7五、發明説明（23 ) 可以使用例如聚乙烯醇或聚乙烯酯例如聚肉桂酸乙烯酯、 聚醋酸乙烯酯、聚丙酸乙烯酯、聚硬脂酸乙烯酯、聚丁酸 乙烯酯、聚乙烯甲醛或聚乙烯吡咯啶酮。可以使用聚乙烯 醚例如聚異丁基乙烯基醚或聚甲基乙烯基醚、聚苯醚、聚 對苯二甲酸丁二酯、聚丙烯、聚甲基苯乙烯或聚甲烯。可 以使用聚環氧乙烷、聚硬脂酸乙烯酯、氫氯酸橡膠、環化 橡膠、***膠、古巴膠、聚胺酯樹脂、鄰苯二甲酸二烯 丙酯、脲樹脂、蜜胺樹脂、聚胺酯樹脂、丁二烯樹脂、聚 對苯二甲酸丁二酯、松香樹脂、石油樹脂、硬瀝青、醇酸 樹脂、改良的醇酸樹脂、蟲膠、達馬樹脂、松香改良的順 丁烯二酸樹脂、苯乙烯改良的順丁烯二酸樹脂、硝基纖維 素、酪素、澱粉、糖化物、ABS樹脂或液晶聚合物。 而且可以使用共聚物例如乙烯/醋酸乙烯酯共聚物、 乙烯/丙烯酸乙酯共聚物、乙烯/甲基丙烯酸無規聚合物 、乙烯/丙烯酸共聚物、乙烯/丙烯酸乙烯酯共聚物、乙 烯/氯乙烯共聚物、乙烯/醋酸乙烯酯/氯乙烯接枝樹脂 、乙烯/乙烯醇共聚物、羧乙烯基共聚物、聚甲醛、N-乙烯基吡咯啶酮/醋酸乙烯酯共聚物、或甲基乙烯基醚/ 醋酸乙烯酯共聚物。 至於熱固性樹脂，可以使用例如胺基樹脂例如苯胺樹 脂、脲樹脂、聚碩醯胺或三聚氰胺樹脂、烯丙基樹脂例如 CR-39或酞酸二烯丙酯、醇酸樹脂、環氧樹脂、矽酮 樹脂或乙烯酯樹脂。可以使用酚型樹脂，例如酚醛樹脂或 偏苯二酚樹脂、不飽和的聚酯樹脂或呋喃樹脂。而且可以 (請先閱讀背面之注意事項This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) _ 24 510915 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 5. Invention Description (23) For example, polyvinyl alcohol or polyvinyl ester can be used, for example Polyvinyl cinnamate, polyvinyl acetate, polyvinyl propionate, polyvinyl stearate, polyvinyl butyrate, polyvinyl formaldehyde or polyvinyl pyrrolidone. Polyethylene ethers such as polyisobutyl vinyl ether or polymethyl vinyl ether, polyphenylene ether, polybutylene terephthalate, polypropylene, polymethylstyrene or polymethylene can be used. Polyethylene oxide, polyvinyl stearate, hydrochloric acid rubber, cyclized rubber, gum arabic, Cuban gum, polyurethane resin, diallyl phthalate, urea resin, melamine resin, polyurethane can be used Resin, butadiene resin, polybutylene terephthalate, rosin resin, petroleum resin, hard pitch, alkyd resin, modified alkyd resin, shellac, dama resin, rosin modified maleic acid Resin, styrene-modified maleic acid resin, nitrocellulose, casein, starch, saccharide, ABS resin or liquid crystal polymer. Also copolymers such as ethylene / vinyl acetate copolymer, ethylene / ethyl acrylate copolymer, ethylene / methacrylic random polymer, ethylene / acrylic acid copolymer, ethylene / vinyl acrylate copolymer, ethylene / vinyl chloride Copolymer, ethylene / vinyl acetate / vinyl chloride graft resin, ethylene / vinyl alcohol copolymer, carboxyvinyl copolymer, polyoxymethylene, N-vinyl pyrrolidone / vinyl acetate copolymer, or methyl vinyl Ether / vinyl acetate copolymer. As for the thermosetting resin, for example, an amine-based resin such as aniline resin, urea resin, polyethylene terephthalamide or melamine resin, allyl resin such as CR-39 or diallyl phthalate, alkyd resin, epoxy resin, silicon can be used. Ketone resin or vinyl ester resin. A phenol type resin such as a phenol resin or a resorcinol resin, an unsaturated polyester resin, or a furan resin may be used. And you can (Please read the notes on the back first

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •26- 510915 A7 B7 五、發明説明（24) (請先閲讀背面之注意事項 使用這些樹脂之混合物，或樹脂中摻混不同的添加劑。 用超低密度之聚乙烯套封 在特別適宜的具體實施例中，列舉用特定的聚乙烯套 封上述之碳黑集料。 訂This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) • 26- 510915 A7 B7 V. Description of the invention (24) (Please read the notes on the back first to use a mixture of these resins, or the resins are mixed differently The use of ultra-low-density polyethylene jackets In a particularly suitable embodiment, the above-mentioned carbon black aggregates are listed with specific polyethylene jackets.

經濟部中央標準局員工消費合作社印裝 換句話說，其包封是由密度最高爲〇 . 9 0 0克/立 方公分的聚乙烯組成，更適宜最高爲0·880克/立方 公分，聚乙烯通常包括高壓法的低密度聚乙烯、高密度聚 乙烯、低密度聚乙烯及直鏈低密度聚乙烯，這些聚乙烯之 密度在高壓法的低密度聚乙烯之情形下爲0.91至 0 · 9 3克/立方公分，在高密度聚乙烯之情形下爲 0 · 94至0 · 97克/立方公分，在直鏈低密度窣乙烯 之情形下爲0·91至0.93克/立方公分，這些習知 的聚乙烯具有高結晶性且通常作爲多種試劑或食品之容器 ，但是，頃經由本案發明者的硏究發現很難將其溶解在油 墨或塗料所使用的媒劑中，反之，上述特定的超低密度聚 乙烯爲一種聚乙烯，其密度比此種習知的聚乙烯更低，且 經由最近幾年處媒劑數之發展而可在工業量下大量生產， 此種超低密度聚乙烯可在高溫下製造投影片膜，可降低套 封時的密封溫度，且可增加拉力，本案發明者硏究此超低 密度聚乙烯在不同溶劑中的溶解度，並很訝異地發現其在 油墨或塗料中的溶解度非常高，根據本發明，係在顏料上 套封此超低密度聚乙烯的膜，其可加入供製備油墨或塗料 的爐中，不需將此聚乙烯封套撕開，因此可提供可非常有 本紙張尺度適用中國國家標準（CNS &gt; A4規格（210X297公釐） •27- 510915 經濟部中央標準局員工消费合作社印製 A7 _ B7五、發明説明（25 ) 效可防止環境污染之顏料。 在本發明中使用的超低密度聚乙烯，可經由例如所謂 的金屬觸媒或Kaminsky觸媒製備，使用此觸媒時，聚合反 應的活性部位爲單獨一種，與習知的Ziegler-Natu觸媒比較 ,可以容易地控制聚合物之分子量或聚合物結構例如接枝 ，結果是可合成超低密度之聚乙烯。 將如此所得的聚乙烯加工而形成可作爲封套材料之膜 的方法沒有特別的限制，例如，可以使用膨脹膜塑法或T -模模塑法，而且，膜的厚度沒有特別的限制，只要其有 適當的強度可包封顏料及供運送，且通常使用厚度爲10 至1 0 0微米之膜。 當聚乙烯形成膜時，必要時可摻混抗結塊劑、泥釉劑 、抗氧化劑或中和劑。 如果上述超低密度聚乙烯單獨用於套封時，有最大的 溶解度，且即使在低溫下，其可容易地溶解在多種媒劑中 而不會有沈澱的問題，但是，決定於特定之目的或使用模 式，其可摻混其他套封物質而一起使用，例如，其可與含 乙烯-醋酸乙烯醋共聚物爲主要成份之樹脂成份共同擠壓 而形成疊層，所以在橫面方向有收縮的性質，因此可促進 顏料之收縮包封，或EVA可與超低密度之聚乙烯混合， 可增加膜製備過程中的熔化張力。 在封套或二次包封上，可以印刷（包括打字）任何所 要的指示，封套材料或二次包封材料可預先印刷，並用此 印刷後的材料套封碳黑集料，反之，可在封套或二次包封 (請先閲讀背面之注意事項Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics In other words, its packaging is composed of polyethylene with a density of 0.90 g / cm3, more preferably 0.880 g / cm3, polyethylene. Usually includes high-pressure low-density polyethylene, high-density polyethylene, low-density polyethylene, and linear low-density polyethylene. The density of these polyethylenes is 0.91 to 0.93 in the case of high-pressure low-density polyethylene. G / cm3, from 0.94 to 0.997 g / cm in the case of high-density polyethylene and 0.91 to 0.93 g / cm3 in the case of linear low-density fluorene Polyethylene has high crystallinity and is usually used as a container for a variety of reagents or foods. However, it has been found by the inventors of this case that it is difficult to dissolve it in the vehicle used for inks or coatings. Low density polyethylene is a kind of polyethylene, which has a lower density than this conventional polyethylene, and can be mass-produced in industrial quantities through the development of the number of agents in recent years. This ultra-low density polyethylene can be In high The manufacture of the projection film can reduce the sealing temperature during encapsulation and increase the tensile force. The inventor of this case investigated the solubility of this ultra-low density polyethylene in different solvents and was surprised to find that it was used in inks or coatings. The solubility is very high. According to the present invention, the ultra-low-density polyethylene film is enveloped on a pigment. It can be added to a furnace for preparing inks or coatings. This polyethylene envelope does not need to be torn apart, so it can provide Very much this paper size applies Chinese national standard (CNS &gt; A4 size (210X297 mm) • 27- 510915 Printed by A7 _ B7 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of invention (25) Pigment: The ultra-low density polyethylene used in the present invention can be prepared through, for example, a so-called metal catalyst or Kaminsky catalyst, and when using this catalyst, the active site of the polymerization reaction is a single kind, and the conventional Ziegler-Natu Compared with the catalyst, the molecular weight of the polymer or the polymer structure such as grafting can be easily controlled, and as a result, an ultra-low density polyethylene can be synthesized. The method for forming the film that can be used as the envelope material is not particularly limited. For example, the expansion film molding method or the T-die molding method can be used, and the thickness of the film is not particularly limited as long as it has a suitable strength and can be wrapped. Seal pigments and deliver, and usually use a film with a thickness of 10 to 100 microns. When polyethylene is formed into a film, if necessary, anti-caking agents, mud glazes, antioxidants or neutralizers can be blended. If the above Ultra-low-density polyethylene has the highest solubility when used alone for encapsulation, and can be easily dissolved in a variety of vehicles without precipitation problems even at low temperatures, but it depends on the specific purpose or use Mode, which can be mixed with other encapsulating substances and used together, for example, it can be extruded together with resin components containing ethylene-vinyl acetate copolymer as the main component to form a laminate, so it has a shrinkage property in the transverse direction Therefore, it can promote the shrinkage and encapsulation of pigments, or EVA can be mixed with ultra-low density polyethylene, which can increase the melt tension during film preparation. On the envelope or secondary encapsulation, you can print (including typing) any desired instructions. The envelope material or secondary encapsulation material can be pre-printed and the carbon black aggregate is enveloped with this printed material. Otherwise, it can be printed on the envelope. Or secondary encapsulation (please read the precautions on the back first)

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -28- 510915 A7 ______B7 五、發明説明（26) 施加至碳黑集料後再印染，例如，可以使用油墨噴嘴印染 機、油墨輥、熱印染機、蓋印機或雷射印染機，可以貼上 印染的標籤，本發明之碳黑集料具有適當的強度，可以容 易地進行印染或標示，例如可標示色線、商標名稱、產物 型態、製造商名稱、內容物重量、批號、條碼、說明、商 標、顏色顯示或標記供商業上分類。 而且，辨別本發明碳黑集料之產品類型較宜經由改變 包封材料之顏色、黏貼供習知碳黑的紙袋使用之色帶、在 封套上加上設計圖案或不規則樣式，關於上述印染之色料 或分辨產品類型之物質例如標籤，可根據碳黑之特定目的 選擇適當的材料及用量，使得其加入不會產生問題。 經濟部中央標隼局員工消費合作社印装 而且，封套或二次包封可有打開的功能，打開的功能 係指可以不用工具例如刀子或切割器就可將封套或二次包 封打開，並從封套或二次包封中取出碳黑，特定地說，可 舉例的一種系統是其中如同香煙包封之情形，在包封或封 套內***開封帶，所以在要打開的時候，拉此帶子就可將 封套或包封打開；一種打孔眼的系統其中使用打孔眼的膜 套封或包封，所以在要打開的時候，可沿著孔眼將膜撕開 :一種刻痕的系統其中在套封或包封時，使膜有V形的刻 痕，所以在要打開的時候，可沿著V形的刻痕將膜撕開； 一種標籤系統其中在要打開的時候，拉標籤使膜撕開並打 開；或一種舌板系統其中在枕形包封中，將外加的舌板部 份放在縱向密封部位，所以在要打開的時候，可拉舌板而 打開。對於收縮包封的打開，以膠帶系統、標籤系統或打 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -29· 510915 A7 _________B7____ 五、發明説明（27) 孔眼的系統較佳，打開的位置可在任何部位，只要可以很 容易地取出碳黑集料，但是在標籤系統中，以側面較佳， 其不會受到例如堆積的影響。 封套內的碳黑，即本發明之碳黑集料，可爲單獨的碳 黑集料，或爲碳黑與有機化合物預先混合之集料，在此， 有機化合物的典型實例包括單體或其聚合物、表面活性劑 及油，但是，此有機化合物並不僅限於這些特定實例，尤 其是可在含碳黑的組成物例如樹脂組成物、橡膠組成物、 塗料組成物或油墨中，預先混合添加劑，將此添加成份混 合至碳黑的方法並沒有特別的限制，但是，不要用例如在 橡膠組成物中的捏合，經由混合將成份壓製並進行從固體 變成液體之相變化，因爲如此將很難形成碳黑集料，有機 化合物對碳黑之混合比例適宜爲有機化合物最多是5 0重 量％,較宜爲最多是20重量％,更宜爲最多是10重量 %，如果有機化合物的量太多，尤其是當有機化合物爲液 體時，與碳黑之混合物容易爲液態或類似黏土，很難製成 具有特定形狀之碳黑集料。 經濟部中央標準局員工消費合作社印装 顏料之套封 多種顏料可用上述密度最高爲0 · 9 0 0克/立方公 分的聚乙烯套封，這些顔料並沒有特別的限制，例如，可 以使用氧化鈦（R —型）、氧化鈦（Α —型）、氧化鋅、 硫化鋅、鋅鋇白、白鉛、硫酸鉛、鹼性硫酸鉛、燈黑、乙 炔黑、碳黑、石墨、骨黑、氧化鐵鉛、銻鉛、鎘鉛、鉬鉛 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） -30 - 510915 A7 B7 五、發明説明（28) 、銀硃、鉛丹、次氯化銅、鉻黃（帶紅色的）、鉻黃（帶 黃色的）、鎘黃、鋅黃、緦黃、鋇黃、一氧化鉛、赭石、 黃氧化鐵、T一赤鐵礦、琥珀、黃土、基尼綠、氧化鉻、 鈷綠、酞花青綠、鐵藍、群青青、鈷藍、酞花青藍鋅粉、 鋁粉、金粉、硫酸鋇、碳酸鋇、碳酸蓋、石灰、碳酸寒、 石膏、氧化鋁白、高嶺黏土、雲母、滑石、氧化矽、矽藻 土、合成鑽石、永久紅4R、視紅、頭黃1 0G、重氮黃 、酒紅10B、甲苯胺紫醬、孔雀藍、尼龍粉、或聚乙烯 粉。 而且，也可使用經多種氧化劑或表面處理劑處理後的 這些顏料。 通常，當顏料的大小不超過1 〇 〇微米時，飛揚將是 • \ 一個嚴重的問題，在本發明中，顏料的大小沒有特別的限 制，但是本發明對於大小不超過1 〇 〇微米的顏料特別有 效，經由本發明改進工作環境之效應很明顯。 在本發明中，情形需要時也可使用經由壓模法製成的 壓模產品例如顏料，包封模塑產品時，處理包封的顏料將 很容易，並可降低儲存及運送之成本，而且，決定於顏料 的型態及用途，經由壓模法將模塑的產品脫氣，因而可改 進媒劑之濕化性，並使其容易分散，至於供壓模法使用之 模具，可以使用任何材料製成的模具，只要其有適當的強 度可耐受模塑時施加的壓力，特定地說，可以使用例如金 屬、陶瓷或樹脂製成的模具。 模具的大小沒有特別的限制，但是實際上較宜將顏料 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）This paper size applies Chinese National Standard (CNS) A4 specification (210X297mm) -28- 510915 A7 ______B7 V. Description of the invention (26) Printing and dyeing after applying to carbon black aggregate, for example, ink nozzle printing machine, ink can be used The roller, thermal printing machine, stamping machine or laser printing machine can be affixed with a label for printing and dyeing. The carbon black aggregate of the present invention has appropriate strength and can be easily printed or labeled, such as color lines and trademark names. , Product type, manufacturer name, content weight, batch number, bar code, description, trademark, color display or mark for commercial classification. Moreover, it is better to identify the product type of the carbon black aggregate of the present invention by changing the color of the encapsulating material, pasting the ribbon for the conventional carbon black paper bag, and adding a design pattern or an irregular pattern to the envelope. For colorants or materials that distinguish product types such as labels, appropriate materials and amounts can be selected according to the specific purpose of carbon black, so that its addition will not cause problems. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Moreover, the envelope or secondary envelope may have the function of opening. The function of opening means that the envelope or secondary envelope can be opened without tools such as a knife or cutter, and Take out carbon black from the envelope or secondary encapsulation. In particular, a system that can be exemplified is the case where an unsealing tape is inserted into the envelope or envelope, as in the case of cigarette encapsulation, so when it is about to be opened, pull the tape The envelope or encapsulation can be opened; a perforated system uses a perforated membrane envelope or encapsulation, so when it is to be opened, the membrane can be torn apart along the perforations: a scoring system where When encapsulating or encapsulating, the film has a V-shaped score, so when it is to be opened, the film can be torn along the V-shaped score; a label system in which when the label is to be opened, the label is pulled The membrane is torn and opened; or a tongue plate system in which the additional tongue plate portion is placed in the longitudinal sealing portion in a pillow-shaped encapsulation, so when it is to be opened, the tongue plate can be opened to open. For the opening of the shrink-wrap, the Chinese national standard (CNS) A4 specification (210X297 mm) is applied to the tape system, label system or paper size. -29 · 510915 A7 _________B7____ 5. Description of the invention (27) The eyelet system is better The open position can be anywhere, as long as the carbon black aggregate can be easily taken out, but in the label system, the side is better, it will not be affected by, for example, accumulation. The carbon black in the envelope, that is, the carbon black aggregate of the present invention, may be a single carbon black aggregate or an aggregate of carbon black and an organic compound in advance. Here, typical examples of organic compounds include monomers or Polymers, surfactants, and oils, but the organic compound is not limited to these specific examples, and in particular, additives may be premixed in a carbon black-containing composition such as a resin composition, a rubber composition, a coating composition, or an ink The method of mixing this added ingredient to carbon black is not particularly limited, but do not use, for example, kneading in a rubber composition, press the ingredients through mixing and change the phase from solid to liquid, because it will be difficult The carbon black aggregate is formed. The mixing ratio of the organic compound to the carbon black is preferably at most 50% by weight, more preferably at most 20% by weight, and more preferably at most 10% by weight. If the amount of the organic compound is too large, , Especially when the organic compound is liquid, the mixture with carbon black is easily liquid or similar to clay, and it is difficult to make a carbon black aggregate with a specific shapeA variety of pigments can be encapsulated in the printed pigments of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. The above-mentioned polyethylene envelopes with a density of up to 0.90 g / cm3 can be used. These pigments are not particularly limited. For example, titanium oxide can be used. (R-type), titanium oxide (Α-type), zinc oxide, zinc sulfide, zinc barium white, white lead, lead sulfate, alkaline lead sulfate, lamp black, acetylene black, carbon black, graphite, bone black, oxidation Iron-lead, antimony-lead, cadmium-lead, molybdenum-lead The paper standards are applicable to the Chinese National Standard (CNS) A4 specifications (210 × 297 mm) -30-510915 A7 B7 V. Description of the invention (28), Yin Zhu, Lead Dan, hypochlorous Copper, chrome yellow (red), chrome yellow (yellow), cadmium yellow, zinc yellow, ochre yellow, barium yellow, lead monoxide, vermiculite, yellow iron oxide, T-hematite, amber, loess , Gini green, chromium oxide, cobalt green, phthalocyanine green, iron blue, ultramarine blue, cobalt blue, phthalocyanine blue zinc powder, aluminum powder, gold powder, barium sulfate, barium carbonate, carbonate cap, lime, carbonate, gypsum , Alumina white, kaolin clay, mica, talc, silica , Diatomaceous earth, synthetic diamond, permanent red 4R, visual red, head yellow 10G, diazo yellow, wine red 10B, toluidine purée, peacock blue, nylon powder, or polyethylene powder. Moreover, these pigments treated with various oxidizing agents or surface treatment agents can also be used. In general, when the size of the pigment does not exceed 1000 microns, flying will be a serious problem. In the present invention, the size of the pigment is not particularly limited, but the present invention is for pigments whose size does not exceed 1000 microns. Particularly effective, the effect of improving the working environment through the present invention is obvious. In the present invention, it is also possible to use a compression molded product such as a pigment produced by a compression molding method when necessary. When encapsulating a molded product, it is easy to handle the encapsulated pigment and reduce the cost of storage and transportation, and Depending on the type and use of the pigment, the molded product is degassed through the compression molding method, so the wettability of the agent can be improved and it is easily dispersed. As for the mold used for the compression molding method, any A mold made of a material may be, for example, a mold made of metal, ceramic, or resin as long as it has a proper strength to withstand the pressure applied during molding. There is no particular limitation on the size of the mold, but in fact it is better to apply the pigment. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm)

經濟部中央標準局貝工消費合作社印製 (請先閲讀背面之注意事項 本頁)Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on this page)

經濟部中央標準局員工消费合作社印裝 510915 A7 B7 _ 五、發明説明（29) 模塑成至少1立方公分之大小，較宜至少爲1 〇 〇立方公 分，隨後再包封，如果體積太小，將不容易處理。 用於壓製的壓塑機可以使用任何的壓塑機，只要其可 完成壓塑，例如水壓機械式壓塑機、水壓手動式壓塑機、 機械式壓塑機或空壓型壓塑機。 模具的形狀沒有特別的限制，且決定於模製產物之所 要形狀，可爲具有三角或其他多邊形截面之管柱，從模具 的處理、所得顏料模製產物之包封集包封的顏料之處理效 率之觀點，較適宜特別是正方形或平行四邊形。 壓模時施加的壓力較宜爲2至500 kg f/平方 公分，更宜爲5至400 kg f/平方公分，而且用聚 乙烯膜包封模製產物後，可施加超音波或震動使膜內的模 製產物有裂縫，因而進一步改進顏料之分散性。 本發明顏料之包封方法沒有特別的限制，如前所述， 可經由壓製法將顏料預先膜塑成某種形狀，經由收縮包封 、真空包封等將模製產物緊密地包封，此爲簡單且極佳的 模式，所得包封的顏料很容易處理，當然還可使用其他方 法，例如其中用上述聚乙烯製備的包封袋，並將顏料包封 在袋中。 而且，顏料可結合多種添加劑，尤其是可包封有飛揚 及汙染問題之粉狀添加劑，在本發明中包封的形式沒有特 別的限制，只要其可將顏料與外界隔離至所要的程度並可 預防飛揚及汙染問題。 密度最高爲0 · 9 0 0克/立方公分之上述聚乙烯膜 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） &quot; -32 - (請先閲讀背面之注意事項再本頁) 訂 510915 A7 B7_ 五、發明説明（3〇) 可溶解在多種供油墨或塗料之溶劑中，使用時沒有任何問 題，據此，經由將本發明包封的顏料與溶劑或與溶劑及樹 脂成份混合，可製備多種油墨組成物或塗料組成物。Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 510915 A7 B7 _ V. Description of the invention (29) Molded to a size of at least 1 cubic centimeter, preferably at least 100 cubic centimeters, and then encapsulated, if the volume is too small Will not be easy to handle. As the compression molding machine, any compression molding machine can be used as long as it can complete compression molding, such as a hydraulic mechanical compression molding machine, a hydraulic manual compression molding machine, a mechanical compression molding machine, or an air compression molding. machine. The shape of the mold is not particularly limited and depends on the desired shape of the molded product. It can be a pipe column with a triangular or other polygonal cross-section, from the treatment of the mold, the treatment of the pigment encapsulated by the encapsulation set of the obtained pigment molded product From the viewpoint of efficiency, a square or a parallelogram is particularly suitable. The pressure applied during the die is preferably 2 to 500 kg f / cm 2, more preferably 5 to 400 kg f / cm 2, and after the molded product is encapsulated with a polyethylene film, ultrasonic or vibration can be applied to make the film The molded product inside is cracked, thereby further improving the dispersibility of the pigment. The method for encapsulating the pigment of the present invention is not particularly limited. As mentioned above, the pigment can be pre-molded into a certain shape by pressing, and the molded product can be tightly encapsulated by shrink encapsulation, vacuum encapsulation, etc. For a simple and excellent model, the resulting encapsulated pigment is easy to handle, and of course other methods can also be used, such as an encapsulation bag made of the polyethylene described above and encapsulating the pigment in the bag. Moreover, pigments can be combined with a variety of additives, especially powdery additives that can be encapsulated with flying and pollution problems. In the present invention, the form of encapsulation is not particularly limited, as long as it can isolate the pigment from the outside world to a desired degree and can Prevent flying and pollution problems. The above polyethylene film with a density of up to 0.90 g / cm3 is suitable for the Chinese paper standard (CNS) A4 (210X297 mm). &Quot; -32-(Please read the precautions on the back before this page) ) Order 510915 A7 B7_ V. Description of the invention (30) It can be dissolved in a variety of solvents for inks or coatings without any problems during use. According to this, the pigment and solvent or solvent and resin components encapsulated by the present invention are used. By mixing, various ink compositions or coating compositions can be prepared.

EVA 當本發明之碳黑集料供油墨使用時，較宜使用If列作 爲封套，換句話說，用至少含一種乙烯/醋酸乙酯共聚物 (以下稱爲” EVA”）之可溶解在油墨中的物質包封集料 〇 至於EVA,醋酸乙酯的含量較宜爲5至25重量％ ,更宜爲10至20重量％，如果醋酸乙酯的含量低於5 重量％, EVA傾向於很難溶解在油墨中，因此無法使用 ，反之，如果醋酸乙酯的含量高於25重量％，膜傾向於 很難加工，且膜容易進行結塊，使得很難作爲油墨基質物 質的包封。 經濟部中央標隼局貝工消費合作社印裝 在可溶解在油墨中的物質之EVA含量沒有特別的限 制，但是較宜爲至少6 0重量％，特別適宜爲至少7 0重 量％，在此範圍中，製備油墨組成物時與溶劑之不混溶性 及作爲封套物質之性質間的平衡最佳· E VA以外的可溶解在油墨中的物質爲可存在於油墨 組成物中且不會有任何問題之物質，且此物質可混溶或溶 解在油墨的媒劑中，特定地說，可以使用松香樹脂例如膠 松香、木松香或多爾油松香，酚型樹脂例如1 0 0 %酚型 樹脂或改良的酚型樹脂，改良的醇酸樹脂例如脂肪酸改良 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） -33 - 510915 A7 ____B7 _ 五、發明説明（32) 在本發明中使用，因爲其與粉狀產物比較，不易飛揚或造 成環境污染，並有高的鬆密度及良好的分散性。 至於固體媒劑，可以使用硬瀝青、聚四氟乙烯（” Teflon” ，商標名稱）、蠟或聚乙烯蠟，各成份例如顏料、 添加劑及媒劑，可一起或分開塗覆，當然，必要時可塗覆 其中一部分。 如上所述的本發明碳黑集料，可適用於使用碳黑的任 何用途。 製備橡膠組成物 如上所述的本發明碳黑集料，可添加至橡膠成份中， 經濟部中央標準局員工消費^.作社印裝 隨後混合及分散後得到含碳黑的橡膠組成物，在此，混合 及分散方法沒有特別的限制，且可以使用習知的方法，本 發明的碳黑集料可以使用從供模塑使用的模具取出時的大 小，或者是分解成直徑爲0 . 1毫米至1公分的大小，因 此其大小將低於捏合機入口的大小，並因此可添加至捏合 機內，即使當使用分解的產物時，可以得到分散性之改進 及低的滯後損失效應，在此，分解方法沒有特別的限制， 例如，可以使用切變碾磨型碾磨機例如切磨機、旋轉粉碎 機或切變輥磨機，其中在碾碎過程中，粒子的密度依需要 將不會增加。 經由適當地選擇套封材料，本發明的碳黑集料可在不 需要將封套除去下分散在媒劑中，如上所述，可以改進工 作環境，並可實質上改進工作效率，但是，當然也有可能 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -35- 510915 A7 、______Β7 _____ 五、發明説明（34) 得到橡膠組成物，在此所使用的捏合機可爲普遍用在橡膠 捏合的習知機器，例如批次系統開放型之開放式煉膠機、 及批次系統密閉型之Banbury型混合機，至於連續輥型，可 使用例如單輥擠壓機或雙輥擠壓機，至於連續性轉子型， 可使用例如單輥捏合機，至於連續性轉子型，可使用例如 雙輥捏合機。 製備油墨組成物 如上所述的本發明碳黑集料，可用於製備油墨，此油 墨可以獲得極佳的黑色及色調。 在此情形下，可用習知的方法但是使用本發明的碳黑 集料作爲油墨之顏料。 .具體地說，可用習知的方法在作爲媒劑的淸漆中摻混 上述的碳黑集料，而且，分散步驟沒有特別的限制，可以 使用習知的方法但是使用本發明的碳黑集料。 經濟部中央標準局員工消費合作社印製 使用的淸漆（媒劑）沒有特別的限制，只要其可供油 墨使用，例如，對於供印刷使用的淸漆，例如供石印使用 的松香改良之酚型樹脂、醇酸樹脂及乾性油之混合物；對 於供凸版印刷使用的淸漆，例如含天然樹脂如硬瀝青或松 香、天然樹脂如松香改良的酚型樹脂、順丁烯二酸樹脂、 石油樹脂、醇酸樹脂、酯膠、植物油例如亞麻子油或桐油 、及礦物油例如墨油或溶劑油之混合物：對於供旋轉壓模 油墨使用的淸漆，例如含樹脂如硬瀝青、松香改良的酚型 樹脂、松香酯樹脂、順丁烯二酸樹脂或醇酸樹脂、乾性油 本紙張尺度適用中國國家標準（CNS &gt; A4規格{ 210X297公釐） -37 - 510915 A7 B7 經濟部中央標準局員工消費合作社印裝 五、發明説明（35) 例如亞麻子油或桐油及礦物油例如墨油、油墨溶劑、紡錘 油或機油之混合物；對於供凹版印刷油墨使用的淸漆，例 如含樹脂如松香改良的樹脂、順丁烯二酸樹脂或硬瀝青、 及溶劑例如甲苯、正己烷或環己烷之混合物；對於供水性 凹版印刷油墨使用的淸漆，例如含樹脂如聚乙烯醇或澱粉 及多種醇類的混合物；對於供橡膠版輪轉印刷油墨使用的 淸漆，例如含樹脂如松香改良的順丁烯二酸樹脂、苯乙烯 丙烯酸樹脂、苯乙烯順丁烯二酸樹脂、苯乙烯甲基丙烯酸 樹脂、丙烯酸酯丙烯酸樹脂或甲基丙烯酸酯丙烯酸樹脂、 及溶劑例如乙二醇、醇、酯或脂族烴之混合物；而且對於 供網版印刷油墨使用的淸漆，例如含樹脂如丙烯酸樹脂、 氯乙烯-醋酸乙烯酯共聚物、聚酯樹脂、纖維素樹脂、環 氧樹脂、蜜胺樹脂、多種多元醇類、醇酸樹脂或多種丙烯 酸酯、及溶劑例如多種醇類、多種醚類、多種酮類、多種 芳族烴類、多種脂族烴類或多種鹵素型態的溶劑、含烷屬 烴爲主要成份之溶劑、含髿烴爲主要成份之溶劑、或含礦 物油爲主要成份之溶劑的混合物。 本發明可以使用的墨沒有特別的限制，且可爲例如油 性基質的墨、樹脂型態的墨、亞麻子油墨、蠟墨、顏料墨 、凸版印刷墨例如新聞墨、旋轉壓印墨或半噸塊墨、石印 墨例如膠版墨、乾性膠版墨或珂羅版墨、凹版印刷墨例如 彫刻凹版印刷墨、凹版印刷墨、’快乾墨、光澤墨、抗吸收 墨、熱固化墨、蒸氣固化墨、壓力固化墨、塑料溶膠墨、 平衡墨、冷固化墨或拉賽（raset)墨，或其他例如橡膠板 (請先閲讀背面之注意事項 -- 本頁)EVA When the carbon black aggregate of the present invention is used for ink, it is more suitable to use the If column as an envelope, in other words, to dissolve in ink containing at least one ethylene / ethyl acetate copolymer (hereinafter referred to as "EVA") As for EVA, the content of ethyl acetate is more preferably 5 to 25% by weight, more preferably 10 to 20% by weight. If the content of ethyl acetate is less than 5% by weight, EVA tends to be very It is difficult to dissolve in the ink, so it cannot be used. On the contrary, if the content of ethyl acetate is more than 25% by weight, the film tends to be difficult to process, and the film is easy to agglomerate, making it difficult to encapsulate the material as an ink matrix. There is no particular limitation on the EVA content of the substance that can be dissolved in the ink printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, but it is preferably at least 60% by weight, and particularly preferably at least 70% by weight, in this range. In the preparation of the ink composition, the balance between the immiscibility with the solvent and the properties as an envelope substance is the best. · Other than E VA, the substances that can be dissolved in the ink can exist in the ink composition without any problems. It can be miscible or dissolved in the vehicle of the ink. In particular, rosin resin such as gum rosin, wood rosin or Dall oil rosin can be used, phenol resin such as 100% phenol resin or Improved phenolic resin, modified alkyd resin such as fatty acid. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -33-510915 A7 ____B7 _ V. Description of the invention (32) Used in the present invention Because it is not easy to fly or cause environmental pollution compared with powder products, it has high bulk density and good dispersibility. As for the solid vehicle, hard asphalt, polytetrafluoroethylene ("Teflon", trade name), wax or polyethylene wax can be used, and various components such as pigments, additives and vehicles can be applied together or separately. Of course, if necessary, Part of it can be applied. The carbon black aggregate of the present invention as described above is applicable to any application using carbon black. Preparation of rubber composition The carbon black aggregate of the present invention as described above can be added to the rubber component and consumed by employees of the Central Standards Bureau of the Ministry of Economic Affairs ^. Printed by the company and then mixed and dispersed to obtain a rubber composition containing carbon black. Here, the mixing and dispersing method is not particularly limited, and a conventional method can be used. The carbon black aggregate of the present invention can be used in the size when it is taken out from a mold for molding, or it can be decomposed into a diameter of 0.1 mm. To 1 cm, so its size will be lower than the size of the kneader inlet, and therefore it can be added to the kneader, even when using the decomposed product, it can get improved dispersion and low hysteresis loss effect, here The decomposition method is not particularly limited. For example, a shear-milling mill such as a cutter mill, a rotary crusher, or a shear roller mill may be used. In the crushing process, the particle density will not increase. By appropriately selecting the sleeve material, the carbon black aggregate of the present invention can be dispersed in a vehicle without removing the sleeve. As described above, the working environment can be improved and the working efficiency can be substantially improved, but of course there are also It is possible that this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -35- 510915 A7, ______ Β7 _____ V. Description of the invention (34) The rubber composition is obtained. The kneader used here can be widely used in Conventional machines for rubber kneading, such as an open batch mixer with an open batch system and a closed-type Banbury mixer with a batch system, as for the continuous roll type, for example, a single roll extruder or a double roll extruder can be used. As the continuous rotor type, for example, a single-roll kneader can be used, and as for the continuous rotor type, for example, a two-roll kneader can be used. Preparation of ink composition The carbon black aggregate of the present invention as described above can be used for preparing ink, and this ink can obtain excellent black and color tone. In this case, a conventional method can be used but the carbon black aggregate of the present invention is used as the pigment of the ink. Specifically, the above-mentioned carbon black aggregate can be blended into the lacquer as a vehicle by a conventional method, and the dispersing step is not particularly limited. A conventional method can be used but the carbon black aggregate of the present invention can be used. material. There is no special restriction on the lacquer (medium) used for printing by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, as long as it can be used for inks. For example, for lacquers used for printing, such as rosin modified phenols for lithography Mixtures of resins, alkyd resins, and dry oils; for lacquers for letterpress printing, for example, natural resins such as hard pitch or rosin, natural resins such as rosin-modified phenolic resins, maleic acid resins, petroleum resins, Mixtures of alkyd resins, ester gums, vegetable oils such as linseed oil or tung oil, and mineral oils such as ink or solvent oil: for varnishes for rotary stamping inks, such as resin-containing types such as hard asphalt, rosin modified phenol type Resin, rosin ester resin, maleic acid resin or alkyd resin, dry oil The paper size applies to Chinese national standards (CNS &gt; A4 specifications {210X297 mm) -37-510915 A7 B7 Employees of the Central Bureau of Standards, Ministry of Economic Affairs Cooperative print 5. Description of the invention (35) For example, a mixture of linseed oil or tung oil and mineral oil such as ink, ink solvent, spindle oil or motor oil For varnishes for gravure printing inks, such as mixtures containing resins such as rosin-modified resins, maleic acid resins or hard pitches, and solvents such as toluene, n-hexane or cyclohexane; for water-supply gravure printing Varnishes used in inks, such as resins containing polyvinyl alcohol or starch and a mixture of various alcohols; for varnishes used in rubber plate rotary printing inks, such as resins such as rosin-modified maleic acid resin, styrene Mixtures of acrylic resins, styrene maleic acid resins, styrene methacrylic resins, acrylate acrylic resins or methacrylate acrylic resins, and solvents such as ethylene glycol, alcohols, esters or aliphatic hydrocarbons; and Varnishes for screen printing inks, such as resin-containing resins such as acrylic resins, vinyl chloride-vinyl acetate copolymers, polyester resins, cellulose resins, epoxy resins, melamine resins, various polyols, alkyd resins Or multiple acrylates and solvents such as multiple alcohols, multiple ethers, multiple ketones, multiple aromatic hydrocarbons, multiple aliphatic hydrocarbons More halogens patterns solvent, paraffinic solvent containing the main ingredient, a hydrocarbon solvent containing Suo main ingredient, or containing mineral oil as main ingredient a mixture of solvents. The ink that can be used in the present invention is not particularly limited, and may be, for example, an ink of an oily base, a resin-type ink, a linseed ink, a wax ink, a pigment ink, a letterpress printing ink such as a news ink, a rotary imprint ink, or a half ton Block inks, lithographic inks such as offset inks, dry offset inks or colo inks, gravure printing inks such as engraved gravure inks, gravure inks, 'quick-drying inks, glossy inks, anti-absorption inks, heat-curable inks, vapor-curable ink , Pressure-cured ink, plastisol, balanced ink, cold-cured ink or raset ink, or other such as rubber sheet (please read the precautions on the back-this page)

Γ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） • 38 510915 A7 B7___ 五、發明説明（36) 墨、苯胺墨、錫板印刷墨、塑膠膜用墨、絲網墨、水溶性 油墨、印度墨例如中國墨或黑色書寫液、製備色紙的顏料 墨，供本發明油墨使用的顏料可用於製備任何一種這些油 墨。 將本發明碳黑集料分散在媒劑中的方法沒有特別的限 制，其可以從模塑的模具中取出的大小使用，或者是壓碎 成0 · 1毫米至1公分的直徑，使其顆粒小於捏合機的入 口，然後加入捏合機中分散，即使當使用壓碎的產物也可 得到黑色的改進。 在此，壓碎的方法沒有特別的限制，但是較宜使用切 變形式的壓碎機例如切磨機、旋轉壓碎機或切變輥磨機， 其中在壓碎過程至中，顆粒的密度不會增加。 而且，供本發明油墨使用的顏料可在不將封套除去下 分散在媒劑中，經由適當地選擇包封的材料，如上所述可 以改善工作環境並實質上改進操作效率，但是當然也可將 封套除去，在此情形下，包封材料的選擇範圍將更廣闊， 雖然需要增加幾個操作步驟。 經濟部中央標準局員工消費合作社印裝 對於經由本發明的顏料製備水溶性油墨，可以使用製 備水溶性油墨的習知方法，不需要有任何特殊的改變就可 製造油墨，例如可用於水溶性油墨之淸漆，可以使用可溶 於鹼的樹脂例如松香順丁烯二酸樹脂、苯乙烯丙烯酸樹脂 、苯乙烯順丁烯二酸樹脂、苯乙烯甲基丙烯酸樹脂、丙烯 酸酯丙烯酸樹脂或甲基丙烯酸酯丙烯酸樹脂，水溶膠型樹 脂例如苯乙烯順丁烯二酸樹脂、苯乙烯丙烯酸樹脂、α — 本紙張尺度適用中國國家標準（CNS ) Α4規格{ 210X297公釐） •39- 510915 A7 B7 五、發明説明（37) 甲基苯乙烯丙烯酸樹脂、丙烯酸酯丙烯酸樹脂或甲基丙烯 酸酯丙烯酸樹脂，乳液型樹脂例如苯乙烯樹脂、苯乙烯丙 烯酸酯樹脂、丙烯酸酯共聚物樹脂或甲基丙烯酸酯共聚物 樹脂。 而且，決定於特定的用途，可以添加例如分散劑、乾 燥阻延劑、抗靜電劑、去泡沫劑或吸氧劑。 此淸漆、添加劑及包括碳黑之顏料可以在特定用途的 粒子大小下分散，經由習知的分散機器例如球磨機、砂磨 機、磨碎機、'籃式磨機或輥磨機而得到水溶性油墨。 而且，在包含必須避免粗粒子的應用中，例如在供油 墨噴嘴的油墨情形下，製備油墨後必須經由例如離心分離 法將粗的粒子去除。 製備樹脂組成物 經濟部中央標準局員工消費合作社印製 可以使用如上所述的本發明碳黑集料得到樹脂組成物 ，具體地說，將本發明之碳黑集料與樹脂成份混合，情形 必要時將混合物捏合，在此，可以使用供橡膠使用之捏合 機，一種普遍作爲生產橡膠使用之捏合機，例如批次系統 開放型的軋混機、批次系統密閉型的Banbury型混合機、連 續輥型的單輥捏合擠壓機或雙輥捏合擠壓機、連續轉子型 的單軸捏合機、連續轉子型的雙軸捏合機，在製備樹脂組 成物中，可預先製備母體批次物，或可直接經由捏合製備 樹脂組成物。 將本發明之碳黑集料分散在樹脂成份中的方法沒有特 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -40 - 510915 A7 B7 五、發明説明（39) 適用於習知的樹脂組成物，例如有色的樹脂、電子照相的 色劑、人造纖維之紡絲物質或密封劑。 在此，”有色的樹脂”係指其中添加碳黑而具有與樹 脂本身的顏色不同之樹脂，其目的是例如使樹脂有（1 ) 裝飾的效應供改進商業價値之目的，（2)利用顏料的紫 外線吸收功能的防止紫外線之保護效應，（3)利用導電 性之抗靜電效應或（4 )強化效應。 ”電子照相的色劑”爲一種供影印機、印表機或傳真 機使用的色劑，其中經由電子照相而形成影像，色劑中含 熱塑性黏合劑樹脂、顏料（碳黑）及電荷控制劑，其中普 遍使用聚集粒子大小爲5至20微米的碳黑，黏合劑樹脂 是由80重量％的色劑成份組成，且其通常使用聚乙烯樹 脂、甲基丙烯酸樹脂或其共聚物、聚酯或環氧型樹脂，碳 黑的添加量通常爲約1 0重量％。 ”人造纖維之紡絲物質”係指供染色儲備溶液使用之 紡絲物質，此方法是將染料添加至供人造纖維（化學纖維 、合成纖維）的紡絲儲備溶液中，使此儲備溶液進行紡絲 而得到有色的纖維，至於纖維，通常使用黏膠人造絲、醋 酯纖維、丙烯酸纖維、尼龍、聚酯纖維或聚丙烯纖維，通 常經由三種方法進行紡絲，也就是熔紡、濕紡及乾紡，使 用四種形式的色劑，也就是主粉劑、糊劑、高濃度染色配 料及顏料九粒，最近，爲了降低碳黑汙染之目的，在許多 情形下傾向於使用高濃度染色配料，關於碳黑的型態，在 許多情形下使用經常使用中等類型的碳黑，有色的纖維可 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項 wWk本頁)Γ This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) • 38 510915 A7 B7___ V. Description of the invention (36) Ink, aniline ink, tin printing ink, plastic film ink, silk screen ink, water soluble Base ink, Indian ink such as Chinese ink or black writing liquid, pigment ink for preparing colored paper, and pigment for ink of the present invention can be used for preparing any of these inks. The method for dispersing the carbon black aggregate of the present invention in a vehicle is not particularly limited, and it can be used in a size taken out from a molding mold, or it can be crushed to a diameter of 0. 1 mm to 1 cm to make the particles Smaller than the entrance of the kneader and then added to the kneader to disperse, even when crushed products are used, an improvement in black can be obtained. Here, the crushing method is not particularly limited, but it is preferable to use a shearing type crusher such as a cutter mill, a rotary crusher, or a shear roll mill, in which the density of particles during the crushing process is No increase. Moreover, the pigment for the ink of the present invention can be dispersed in a vehicle without removing the envelope, and by appropriately selecting the encapsulating material, as described above, the working environment can be improved and the operating efficiency can be substantially improved, but of course, the The envelope is removed. In this case, the choice of encapsulation material will be wider, although several additional steps will be required. For the printing of water-soluble inks by the pigment of the present invention, the conventional method for preparing water-soluble inks can be used for the production of water-soluble inks by the pigment of the present invention, and inks can be manufactured without any special changes, such as water-soluble inks. As the base paint, an alkali-soluble resin such as rosin maleic acid resin, styrene acrylic resin, styrene maleic acid resin, styrene methacrylic resin, acrylate acrylic resin, or methacrylic acid can be used. Ester acrylic resin, hydrosol-type resin such as styrene maleic acid resin, styrene acrylic resin, α — This paper size applies Chinese National Standard (CNS) A4 specification {210X297 mm) • 39- 510915 A7 B7 V. Description of the invention (37) methacrylic acid acrylic resin, acrylate acrylic resin or methacrylic acid acrylic resin, emulsion resin such as styrene resin, styrene acrylate resin, acrylate copolymer resin or methacrylate copolymer Resin. Furthermore, depending on the specific application, for example, a dispersant, a drying retarder, an antistatic agent, a defoaming agent, or an oxygen absorbent may be added. The paint, additives, and pigments including carbon black can be dispersed at a particle size for a specific purpose, and water-soluble through a conventional dispersing machine such as a ball mill, a sand mill, a mill, a 'basket mill, or a roll mill. Sexual ink. Furthermore, in applications containing coarse particles that must be avoided, such as in the case of inks from ink supply nozzles, the coarse particles must be removed after the ink is prepared, for example, by centrifugation. Preparation of resin composition Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs The resin composition can be obtained by using the carbon black aggregate of the present invention as described above. Specifically, the carbon black aggregate of the present invention is mixed with the resin component, which is necessary. The mixture is kneaded at this time. Here, a kneader for rubber can be used, a kneader generally used for the production of rubber, such as a batch system open type rolling mixer, a batch system closed type Banbury mixer, continuous The roll type single-roll kneading extruder or double-roll kneading extruder, continuous-rotor single-shaft kneader, and continuous-rotor double-shaft kneader can be used to prepare the parent batch in the preparation of the resin composition. Alternatively, the resin composition can be prepared directly by kneading. The method for dispersing the carbon black aggregate in the resin composition of the present invention does not have a special paper size applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -40-510915 A7 B7 V. Description of the invention (39) Known resin compositions are, for example, colored resins, electrophotographic toners, rayon spinning materials or sealants. Here, "colored resin" refers to a resin to which carbon black is added and has a color different from that of the resin itself. The purpose is, for example, to make the resin have (1) the effect of decoration for the purpose of improving commercial value, (2) the use of pigments The UV-absorbing function prevents UV-protective effects, (3) the use of conductive antistatic effects or (4) the strengthening effect. "Electrophotographic toner" is a toner for use in photocopiers, printers or facsimiles, in which an image is formed by electrophotography. The toner contains a thermoplastic binder resin, pigment (carbon black) and a charge control agent. Among them, carbon black with an aggregate particle size of 5 to 20 microns is commonly used, and the binder resin is composed of 80% by weight of a toner component, and usually a polyethylene resin, a methacrylic resin or a copolymer thereof, a polyester or The epoxy resin, carbon black is usually added in an amount of about 10% by weight. "Spinning substance of artificial fiber" refers to the spinning substance for dyeing stock solution. This method is to add dye to the spinning stock solution for artificial fiber (chemical fiber, synthetic fiber), and make this stock solution to be spun. As for the fibers, colored fibers are usually obtained. As for the fibers, viscose rayon, acetate fiber, acrylic fiber, nylon, polyester fiber, or polypropylene fiber are usually used. Spinning is usually performed by three methods, that is, melt spinning, wet spinning, and Dry spinning, using four forms of toner, that is, main powder, paste, high-concentration dyeing ingredients and nine pigments. Recently, in order to reduce carbon black pollution, in many cases tend to use high-concentration dyeing ingredients, Regarding the type of carbon black, in many cases, medium-type carbon black is often used, and colored fibers can be used in accordance with Chinese National Standard (CNS) A4 specifications (210X297 mm). (Please read the precautions on the back first wWk (This page)

Γ 經濟部中央標準局員工消費合作社印裝 42· 510915 A7 B7 五、發明説明（40) 用於例如工作服、學校制服、泳衣、運動裝、雨傘用布、 襪子、地毯、帳棚及魚網。 ”密封劑”係指供密封例如車窗玻璃之密封劑或鋼板 之黏合劑。 上述的樹脂組成物僅作爲本發明適用的樹脂組成物之 實例，本發明可適用的樹脂組成物不限於這些實例，可擴 展至涵蓋廣泛的範圍。 製備塗料 上述的碳黑集料可作爲顏料供製備塗料，對於製備塗 料，可以使用習知的方法但是使用上述的碳黑集料作爲顏 料，具體地說，將本發明之碳黑集料與淸漆及樹脂成份混 合。 經濟部中央標準局員工消費合作社印装 在此所使用的淸漆（媒劑）沒有特別的限制，只要其 可供塗料使用，例如，其可爲乾性油、改良的乾性油、天 然樹脂或瀝青供油質的塗料，蟲膠供醇系的塗料，硝基纖 維素、乙醯基纖維素、丙烯酸樹脂、酚醛樹脂或樹脂改良 的酚醛樹脂供纖維素衍生物之塗料，氧化油改良的醇酸樹 脂、改良的醇酸樹脂、丁縮醛化胺基醇酸樹脂、胺基醇酸 樹脂、聚醋酸乙烯酯、聚氯乙烯、氯化橡膠、苯乙烯一丁 二烯樹脂、熱固性丙烯酸樹脂、環氧樹脂、布飽和的聚酯 、聚異氰酸酯樹脂、矽酮及醇酸樹脂、或丁基鈦酸鹽供合 成樹脂塗料，聚醋酸乙烯酯、聚苯乙烯一丁二烯或聚丙烯 酸化合物供合成乳漆，酚醛聚縮合物、醚化蜜胺樹脂或胺 本紙張尺度適用中國國家標準（CNS ) A4規格(210X297公釐） -43 - 510915 A7 _________B7 __ 五、發明説明（41 ) 中和化醇酸樹脂供水溶性烤漆，蛋白質·澱粉·精胺酸聚乙 烯醇或羧甲基纖維素供水溶性塗料，中性高級酚或中性酚 醛樹脂可用於日本真漆。 溶劑也沒有特別的限制，並可使用習知的溶劑，例如 甲苯、二甲苯、甲基乙基酮、甲基異丁基酮或水，而且可 以使用多種添加劑。 這些成份可爲習知的混合比例，具體地說，通常淸漆 (非揮發性成份）是20至40重量％，添加劑爲數個重 量％，且碳黑是0.5至5重量％。 塗料也沒有特別的限制，例如根據以塗膜的主要成份 分類，其可爲例如油漆、琺瑯油、酚型樹脂塗料、順丁烯 二酸塗料、醇酸樹脂塗料、胺基醇酸樹脂塗料、脲樹脂塗 料、醇系塗料、真漆、乙烯基樹脂塗料、丙醯基樹脂塗料 、聚酯樹脂塗料、環氧樹脂塗料、聚醯胺酯樹脂塗料、矽 酮樹脂塗料、乳液樹脂塗料或水溶性樹脂塗料。 經濟部中央標準局員工消費合作社印製 如此得到的塗料之用途沒有特別的限制，例如，其可 作爲磁帶之背塗層，在此情形下，碳黑必須有例如導電、 遮光及賦予表面不規則化之性質，可根據所需的用途而適 當地選擇碳黑，至於淸漆，特別適宜使用醯胺酯型的淸漆 〇 將本發明碳黑集料分散在淸漆中的方法沒有特別的限 制，其可以從模塑的模具中取出的大小使用，或者是壓碎 成0 · 1毫米至1公分的直徑，.使其顆粒小於捏合機的入 口，然後加入捏合機中分散，即使當使用壓碎的產物也可 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） ~ 一 * 44麵 510915 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明（42) 得到黑色的改進。 在此，壓碎的方法沒有特別的限制，但是較宜使用切 變形式的壓碎機例如切磨機、旋轉壓碎機或切變輥磨機， 其中在壓碎過程至中，顆粒的密度不會增加。 而且，供本發明塗料使用的顏料可在不將封套除去下 分散在媒劑中，經由適當地選擇包封的材料，如上所述可 以改善工作環境並實質上改進操作效率，但是當然也可將 封套除去，在此情形下，包封材料的選擇範圍將更廣闊， 雖然需要增加幾個操作步驟· 經由本發明之碳黑集料改進例如黑色性質的機制尙不 淸楚，但使可作下列假設，換句話說將碳黑分散在淸漆中 的機制，可視爲”從固體一氣體界面至固體一液體界面之 取代步驟，也就是說，從空氣-顏料界面至顏料-分散介 質界面，且在所得的固體一液體分散系統中，在顏料與分 散介質見面間的作用及顏料的固體界面本質扮演主要的角 色” （” Most Pigment Application Technique&quot;, Kabushiki Kaisha CMC出版，1 37頁），據此，在本發明塗料之顏 料中，碳黑粒子間的空氣經由壓模而除氣，且咸信可促進 從固體-氣體界面至固體-液體界面之取代，在任何情形 下，經由使用本發明塗料之顏料，可以得到非常獨特的效 應，例如改進碳黑作爲顏料之處理效率、防止操作過程中 飛揚造成的環境污染、及降低儲存及運送之成本，同時可 實質上改進所得塗料之分散性、黑色及光澤。 以下，將參照實例進一步說明本發明，但是，必須知 (請先閲讀背面之注意事項Γ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 42 · 510915 A7 B7 V. Description of the invention (40) It is used in, for example, work clothes, school uniforms, swimwear, sportswear, umbrella cloth, socks, carpets, tents and fishnets. "Sealant" means a sealant such as a window glass or an adhesive for steel plates. The above-mentioned resin composition is merely an example of a resin composition to which the present invention is applicable, and the resin composition to which the present invention is applicable is not limited to these examples, and can be extended to cover a wide range. Preparation of Coatings The above carbon black aggregates can be used as pigments for preparing coatings. For the preparation of coatings, conventional methods can be used but the above carbon black aggregates are used as pigments. Specifically, the carbon black aggregates of the present invention and Lacquer and resin ingredients are mixed. There is no special restriction on the lacquer (medicine) used for printing by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, as long as it can be used for coatings, for example, it can be dry oil, modified dry oil, natural resin or asphalt Oil-based coatings, shellac alcohol-based coatings, nitrocellulose, ethyl cellulose, acrylic resins, phenolic resins, or resin-modified phenolic resins, coatings for cellulose derivatives, and oxidized oil-modified alkyds Resin, modified alkyd resin, butyralized amino alkyd resin, amino alkyd resin, polyvinyl acetate, polyvinyl chloride, chlorinated rubber, styrene-butadiene resin, thermosetting acrylic resin, ring Oxygen resin, cloth saturated polyester, polyisocyanate resin, silicone and alkyd resin, or butyl titanate for synthetic resin coatings, polyvinyl acetate, polystyrene monobutadiene or polyacrylic acid compounds for synthetic milk Lacquer, phenolic polycondensate, etherified melamine resin or amine The paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) -43-510915 A7 _________B7 __ V. Invention In Ming (41) and a supply of water-soluble alkyd resin paint, starch-protein-arginine polyvinyl alcohol or carboxymethyl cellulose for a water-soluble paint, neutral or neutral phenol advanced phenolic resins can be used Japanese lacquer. The solvent is also not particularly limited, and conventional solvents such as toluene, xylene, methyl ethyl ketone, methyl isobutyl ketone, or water can be used, and various additives can be used. These ingredients may be a conventional blending ratio. Specifically, varnishes (non-volatile ingredients) are usually 20 to 40% by weight, additives are several% by weight, and carbon black is 0.5 to 5% by weight. The coating is also not particularly limited. For example, it can be classified according to the main components of the coating film. It can be, for example, paint, enamel oil, phenol resin coating, maleic acid coating, alkyd resin coating, amino alkyd resin coating, Urea resin paint, alcohol paint, real paint, vinyl resin paint, acrylic resin paint, polyester resin paint, epoxy resin paint, polyurethane resin paint, silicone resin paint, emulsion resin paint or water-soluble Resin coating. There is no particular limitation on the use of the coatings thus obtained by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. For example, it can be used as a back coating for magnetic tapes. In this case, the carbon black must have, for example, conductivity, shading, and irregularities on the surface. Carbon black can be appropriately selected according to the required application. As for lacquers, it is particularly suitable to use amine ester type lacquers. The method for dispersing the carbon black aggregate in the lacquers is not particularly limited. It can be used in the size taken out from the molding mold, or crushed to a diameter of 0. 1 mm to 1 cm to make the particles smaller than the entrance of the kneader and then dispersed in the kneader, even when using the press The crushed product can also be in accordance with Chinese National Standards (CNS) A4 specifications (210X297 mm) on this paper size. One * 44 sides 510915 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 5. Invention Description (42) Improve. Here, the crushing method is not particularly limited, but it is preferable to use a shearing type crusher such as a cutter mill, a rotary crusher, or a shear roll mill, in which the density of particles during the crushing process is No increase. Furthermore, the pigments used in the coatings of the present invention can be dispersed in a vehicle without removing the envelope, and by appropriately selecting the materials to be encapsulated, as described above, the working environment can be improved and the operating efficiency can be substantially improved, but of course, the The envelope is removed. In this case, the range of choice of the encapsulating material will be wider. Although it is necessary to add several operating steps. The mechanism of improving the black property through the carbon black aggregate of the present invention is not negligible, but it can be used as follows. Suppose, in other words, the mechanism of dispersing carbon black in the lacquer can be regarded as "the replacement step from the solid-gas interface to the solid-liquid interface, that is, from the air-pigment interface to the pigment-dispersion medium interface, and In the resulting solid-liquid dispersion system, the role between the pigment and the dispersion medium and the nature of the solid interface of the pigment play a major role "(" Most Pigment Application Technique &quot;, published by Kabushiki Kaisha CMC, page 1 37), based on which In the pigment of the coating material of the present invention, the air between the carbon black particles is degassed through the stamper, and the salt is believed to promote the The replacement of the -gas interface to the solid-liquid interface, in any case, by using the pigment of the coating of the present invention, very unique effects can be obtained, such as improving the processing efficiency of carbon black as a pigment, and preventing environmental pollution caused by flying during operation. , And reduce the cost of storage and transportation, while at the same time can substantially improve the dispersibility, black and gloss of the resulting coating. In the following, the present invention will be further explained with reference to examples, but you must know (please read the precautions on the back first)

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本紙張尺度適用中國國家標準（CNS ) A4规格·（ 210X297公釐） -45- 510915 A7 B7 五、發明説明（43) 道本發明不論如何都不能限定在這些特定的實例。 (請先閱讀背面之注意事項 旬射的碳黑集料應用至油墨或塗料 所給的實例中，表面硬度至少爲70克的碳黑用可溶 解在油墨或塗料中使用的溶劑之膜包封。 實例1 (1 )在溶劑中的溶解度測試1 Γ 將五種樹脂，也就是由Dow Chemical Co,，Ltd.製造 的超低密度聚乙烯”£08200”（密度：0.870 克/立方公分，以下稱爲” PE (A)” ）、由Nippon Polychem K.K.製造的超低密度聚乙烯” Kernel” （密度： 0 · 8 8 0克/立方公分，以下稱爲” P E ( B ) ” ）、 由Nippon Polychem Κ·Κ·製造的乙烯一醋酸乙烯酯共聚物 ” Novatec EVA, LV440” （醋酸乙酯含量：15重量％,This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) -45- 510915 A7 B7 V. Description of the invention (43) The present invention is not limited to these specific examples in any way. (Please read the precautions on the back first. In the example given by the application of carbon black aggregate to inks or coatings, carbon black with a surface hardness of at least 70 grams is encapsulated with a film that can dissolve in solvents used in inks or coatings. Example 1 (1) Solubility test in a solvent 1 Γ Five resins, namely ultra-low density polyethylene manufactured by Dow Chemical Co ,, Ltd. "£ 08200" (density: 0.870 g / cm3, below) "PE (A)"), ultra-low density polyethylene "Kernel" (density: 0.88 g / cm3, hereinafter referred to as "PE (B)") manufactured by Nippon Polychem KK, and Nippon Polychem K · K · ethylene-vinyl acetate copolymer "Novatec EVA, LV440" (ethyl acetate content: 15% by weight,

經濟部中央標準局員工消费合作社印製 密度：0·940克/立方公分，以下稱爲” EVA” ） 、由Nippon Polychem Κ·Κ·製造的低密度聚乙烯” L Η 100Ν” （密度：0.921克/立方公分，以下稱爲 ” P E ( C ) ” ）、及由Nippon Polychem Κ·Κ·製造的高 密度聚乙烯” ΗΒ430” （密度：0.958克/立方 公分，以下稱爲” PE (D)” ），形成厚度爲30微米 的膜，並從各膜中切割出0·2克的樣品，將20克由 Nippon Oil Co·, Ltd·製造供印刷油墨使用的溶劑” No. 6 Solvent”加入容量爲1 〇 〇毫升的五個Erlenmeyer燒瓶中 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ^ -46 - 510915 A7 ________B7_____— 五、發明説明（44) ，並分別將上述五種類型的膜放入Erlenmeyer燒瓶中，將 Erlenmeyer燒瓶放入水浴中，並將水浴的溫度設定至40 °C,進行攪拌1小時使膜溶解在Erlenmeyer燒瓶中，五種 型態的膜沒有一種溶解，然後將溫度設定至4 5 °C並進行 攪拌1小時，在相同方法下進行檢査，PE (A)溶解但 其他沒有溶解，進一步重複類似的操作以確定溶解的溫度 ,PE(B)在55t溶解，EVA在65°C溶解，但是 PE (C)及PE (D)即使在80°C也沒有溶解。 結果列在表1。 (請先閲讀背面之注意事項 訂Low-density polyethylene "L Η 100N" (density: 0.921) manufactured by Nippon Polychem K · K · G / cm3, hereinafter referred to as "PE (C)"), and high-density polyethylene made by Nippon Polychem KK · "B430" (density: 0.958 g / cm3, hereinafter referred to as "PE (D) "), Forming a film with a thickness of 30 microns, and cutting a 0.2 g sample from each film, adding 20 g of a solvent for printing inks manufactured by Nippon Oil Co., Ltd." No. 6 Solvent " The size of the paper in five Erlenmeyer flasks with a capacity of 100 ml is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ^ -46-510915 A7 ________B7_____ — V. Description of the invention (44), and the above five This type of membrane was placed in an Erlenmeyer flask, the Erlenmeyer flask was placed in a water bath, and the temperature of the water bath was set to 40 ° C, and stirred for 1 hour to dissolve the membrane in the Erlenmeyer flask. None of the five types of membrane was soluble. , Then set the temperature to 4 5 ° C and stir for 1 hour, check in the same method, PE (A) is dissolved but others are not dissolved, repeat the similar operation to determine the temperature of dissolution, PE (B) at 55t Dissolve. EVA dissolves at 65 ° C, but PE (C) and PE (D) do not dissolve even at 80 ° C. The results are listed in Table 1. (Please read the precautions on the back first

經濟部中央標準局員工消費合作社印裝 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -47· 510915 A7 B7 五、發明説明（45) 表1聚乙烯膜（油墨）的溶解溫度 品牌 PE(A) PE(B) EVA PE(C) PE(D) 密度 0.870 0.880 0.940 0.921 0.958 (克/立方公分） 4(TC 不溶解 不溶解 不溶解 不溶解 不溶解 45t 溶解 不溶解 不溶解 不溶解 不溶解 50°C 不溶解 不溶解 不溶解 不溶解 55°C 溶解 不溶解 不溶解· 不溶解 60°C ·· 不溶解 不溶解 不溶解 65〇C 溶解 不溶解 不溶解 70°C 不溶解 不溶解 75t 不溶解 不溶解 8(TC 不溶解 不溶解 (請先閲讀背面之注意事項The paper size of the printed papers of the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 (210X297 mm) -47 · 510915 A7 B7 V. Description of the invention (45) Table 1 Dissolution of polyethylene film (ink) Temperature brand PE (A) PE (B) EVA PE (C) PE (D) Density 0.870 0.880 0.940 0.921 0.958 (g / cm3) 4 (TC Insoluble, insoluble, insoluble, insoluble, insoluble, 45t, dissolved, insoluble, insoluble Insoluble and insoluble 50 ° C Insoluble and insoluble Insoluble and insoluble 55 ° C Insoluble and insoluble Insoluble and insoluble 60 ° C Insoluble and insoluble 65 ° C Insoluble and insoluble 70 ° C Insoluble Insoluble 75t Insoluble and insoluble 8 (TC Insoluble and insoluble (Please read the precautions on the back first

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(2)在溶劑中的溶解度測試2 進行上述操作（1 )的相同操作，但是用由Oishi Sangyo K.K.製造的 P S 膜” Styrofan” （密度： 經濟部中央標準局貝工消費合作社印裂 1.050克/立方公分，厚度：31微米）代替 E V A r u p 4型測試，並用Kansai Paint K.K.製造供塗料 使用的溶劑” Thinner No· 3 for Baking Coating Material&quot; 代替&quot;No. 6 Solvent&quot;, PE (A)及 PS 在 40 °C 溶解， PE (B)在 50 °C 溶解，但是 PE (C)及 PE (D) 即使在7 0 °C也沒有溶解，結果列在表2。 -48- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 510915 A7 _ ______B7 五、發明説明（46) 表2聚乙烯膜（塗料）的溶解溫度 品牌 ΡΕ(Α) ΡΕ(Β) PS PE(C) PE(D) 密度 0.870 0.880 1.050 0.921 0.958 (克/立方公分） 40°C 溶解 不溶解 溶解 不溶解 不溶解 45〇C 不溶解 不溶解 不溶解 50t 溶解 不溶解 不溶解 55〇C 不溶解 不溶解 60eC 、 不溶解 不溶解 65eC 不溶解 不溶解 7(TC 不溶解 不溶解 (3 : &gt;製備測試樣本 在碳鋼模具中1 (內部空間1 ! 5 0毫米X 1 5 0毫米， 高度：3 6 0毫米） ，加入 1 公斤由Mitsubishi Cheihical Corporation製造的碳黑” ΜΑ 7 ”（粒子大小： 2 4毫微 米，D Β Ρ油吸收： 6 5毫升/ 1 0 0克碳黑，鬆密度： (請先閲讀背面之注意事 訂(2) Solubility test in a solvent 2 The same operation as in the above operation (1) was performed, but using a PS film "Styrofan" (density: Central Standards Bureau, Ministry of Economic Affairs, Shellfish Consumer Cooperative, India, 1.050 g / cm) Cubic centimeter, thickness: 31 microns) instead of EVA rup 4 type test, and use Kansai Paint KK to manufacture solvents for coatings "Thinner No. 3 for Baking Coating Material" instead of "No. 6 Solvent", PE (A) and PS It dissolves at 40 ° C, PE (B) dissolves at 50 ° C, but PE (C) and PE (D) do not dissolve even at 70 ° C. The results are shown in Table 2. -48- This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 510915 A7 _ ______B7 V. Description of the invention (46) Table 2 Dissolution temperature of polyethylene film (coating) Brand PE (Α) PE (B) PS PE (C) PE ( D) Density 0.870 0.880 1.050 0.921 0.958 (g / cm3) 40 ° C dissolved insoluble dissolved insoluble insoluble 45 ° C insoluble insoluble insoluble 50t dissolved insoluble insoluble 55 ° C insoluble insoluble 60eC, Insoluble and insoluble 65eC Insoluble and insoluble 7 (TC Insoluble and insoluble (3: &gt; Preparation of test specimens in a carbon steel mold 1 (internal space 1! 50 mm X 150 mm, height: 360 mm ), Add 1 kg of carbon black "ΜΑ 7" manufactured by Mitsubishi Cheihical Corporation (particle size: 24 nm, D Β oil absorption: 65 ml / 100 g carbon black, bulk density: (Please read first Note on the back

經濟部中央標準局員工消費合作社印製 0 · 1 9 0克/立方公分），並裝設由Yuken K.K.製造的 水壓機，在1分鐘內將碳黑壓製成壓力爲2kgf/平 方公分，使聚集而得到具有預先決定形狀之碳黑集料，集 料之密度（經由質量除以體積所得的値）爲0 · 5 6 5克 /立方公分，將所得的碳黑集料沿著壓軸經由電磨鋸切割 成兩等分的樣品，一個樣品用於測量硬度，另一個樣品用 於測量粉碎比例與最初分散性及供製備油墨。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -49- 510915 A7 B7____ 五、發明説明（48) 分散性指數之方法。 在約1.8升不銹鋼容器中（直徑：11公分，高度 % :18 · 5 公分），加入 480 克REDUCTUS # 2 2 0 (由Kyodo Sekiyu製造）及120克碳黑集料，將 TK AUTO HOMOMIXER SL10A (由 Tokushu Rika Kogyo製 造）攪拌器（四葉，各葉直徑：4·5公分）***在不銹 鋼容器底部上方2公分處，使攪拌器在5000 r pm 下操作並進行攪拌1小時，取樣50克的混合物，並用 325篩目（開口：46微米）的不銹鋼網過濾，過濾後 ，在網上灑約2 0 0毫升的輕油淸洗，使此網在1 5 0°C 的乾燥箱中乾燥1小時，然後將網從乾燥箱中取出並冷卻 ，然後測量網的重量，從所測量的重量中扣除預先測量的 網最初重量，得到殘留在網上的碳黑重量（A克），用下 列公式計算網的殘留。 油墨網殘留（％) = (Αχ600/(50 χ·120 ))X 1 0 0 油墨網殘留爲0 · 3重量％，此表示有良好的分散性 (7)製備熱收縮包封 從上述碳黑集料切割出1 1 4克的碳黑集料並用膨脹 模塑法形成的厚度爲3 0微米的PE (Β)膜包封，隨後 在1 8 0°C下熱密封2秒，將包封在膜內的碳黑集料放入 由Nissan Kiko K.K.製造且設定在1 5 0°C的收縮通道（ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (0.190 g / cm3) and installed a hydraulic press made by Yuken KK to press the carbon black into a pressure of 2 kgf / cm2 in 1 minute. A carbon black aggregate having a predetermined shape was obtained. The density of the aggregate (the 値 obtained by dividing the mass by the volume) was 0 · 5 6 5 g / cm³. The obtained carbon black aggregate was passed along an axis through an electric mill saw. Cut into two halved samples, one for hardness and the other for pulverization ratio and initial dispersibility, and for ink preparation. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -49- 510915 A7 B7____ 5. Description of the invention (48) Dispersion index method. In a 1.8-liter stainless steel container (diameter: 11 cm, height%: 18 · 5 cm), add 480 g of REDUCTUS # 2 2 0 (manufactured by Kyodo Sekiyu) and 120 g of carbon black aggregate, and add TK AUTO HOMOMIXER SL10A ( (Made by Tokushu Rika Kogyo) a stirrer (four leaves, each leaf diameter: 4.5 cm) is inserted 2 cm above the bottom of the stainless steel container, the stirrer is operated at 5000 r pm and stirred for 1 hour, and 50 grams of the mixture is sampled , And filtered with a 325 mesh (opening: 46 microns) stainless steel mesh. After filtering, sprinkle about 200 ml of light oil on the mesh and rinse, and dry the mesh in a drying box at 150 ° C for 1 hour. , Then take the net out of the drying box and cool it, then measure the weight of the net, subtract the pre-measured initial net weight from the measured weight to get the weight of carbon black (A gram) remaining on the net, and use the following formula Remnants of the net. Ink net residue (%) = (Αχ600 / (50 χ · 120)) X 1 0 0 Ink net residue is 0.3% by weight, which indicates good dispersibility (7) Preparation of heat shrinkable encapsulation from the above carbon black The aggregate was cut out of 114 grams of carbon black aggregate and was encapsulated by a 30 micron thick PE (B) film formed by an expansion molding method, and then heat-sealed at 180 ° C for 2 seconds. The carbon black aggregate in the film is placed in a shrink channel made by Nissan Kiko KK and set at 150 ° C (This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the back Precautions

本I·) 訂 經濟部中央標準局員工消費合作社印装 -51 - 510915 f A7 _— B7 五、發明説明（49) 型號：” NS—450” ），使碳黑集料進行收縮包封， 用手觸摸包封後的碳黑集料，手上沒有沾染。 (8 )製備油墨 將3 8 0克由Showa Varnish K.K.製造的淸漆” M S —8 〇 0 ”、2 0 克由 Showa Varnish Κ·Κ·製造的淸漆” Fl〇4” 及 57 克由 Nippon Sekiyu Κ·Κ·製造的” Ν 〇 · 6 Solvent”秤重並加入容器內（直徑：11公 分，高度：18 · 5 公分），用Tokushu Rika Kogyo Κ·Κ. 製造的均勻混合機（型號：” ΤΚ AUTO HOMOMIXER SL· 10A” ）在5000 rpm下攪拌此淸漆1小時，得到供 商業化膠版油墨的淸漆，將容器加熱至使淸漆的溫度爲 8 〇 °C，將1 1 4克上述收縮包封的碳黑集料添加至如上 所述製備供商業化膠版油墨的淸漆中，隨後在5 〇 〇 〇 r p m下攪拌1 2 0分鐘而得到油墨。 此時，沒有發生碳黑的飛揚。 經濟部中央標準局員工消費合作社印装 (9 )捏合 如此製備的油墨，用Asada Tekkosho K.K.製造的軋製 機（型號：” BR — 500” ）捏合，其中用粉碎計測量 沒有分散的塊狀之大小，確定其不超過1 0微米，需要使 油墨通過軋製機四次直到沒有分散的塊狀之大小不超過 10微米，使此油墨熟化1周，然後作爲測試的油墨使用 本紙韻用中國國家標f (⑽赠（21〇雜羡） 經濟部中央標準局貝工消費合作社印製 510915 A7 B7 五、發明説明（50) (1 0 )收縮測試 取樣0 · 6立方公分的此熟化油墨並放在由Toyo Seiki .K.K.製造的膠版印刷機中，在此印刷機中加入A 4大小 的碎木紙並印刷，使油墨自然乾燥，然後用Suga Shikenki K.K.製造的S Μ顏色電腦測量L値而測量印刷表面之色差 ，結果L値（亮度）爲27 · 6, L値與使用沒有模塑或 包封的粉狀碳黑” MA 7”製備之油墨（實例比較7)相 等。 油墨的L値（亮度）係根據揭示在J I S Z -8730 - 1980 (色差表示法）的Hunters色差， 實例2 . 進行實例1的相同步驟，但是將模塑壓力改變爲 2 2.2 kg f/平方公分，模製產物之密度爲 0·598克/立方公分，表面硬度爲622克，且內部 硬度爲497克。 而且，用實例1的相同方法測量粉碎比例及網殘留， 粉碎比例爲1·2重量％，且網殘留爲12·3重量％, 因此兩種値都很好。 用實例1的相同方法包封此碳黑集料，並製備油墨， 在油墨之製備中，沒有觀察到飛揚，使油墨通過軋製機三 次，而且在收縮測試的結果，L値爲2 7 · 5,此値與實 例比較7相等。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項寫本頁)This I ·) is ordered to be printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs -51-510915 f A7 _ — B7 V. Description of the invention (49) Model: "NS-450"), so that the carbon black aggregate is shrink-encapsulated, The encapsulated carbon black aggregate was touched by hand, and there was no contamination on the hand. (8) Preparation of ink: 380 g of lacquer "MS-0" manufactured by Showa Varnish KK, 20 g of lacquer "Fle4" manufactured by Showa Varnish KK and 57 g of Nippon "N 〇 · 6 Solvent" manufactured by Sekiyu K · K · was weighed and put into a container (diameter: 11 cm, height: 18 · 5 cm), and a homomixer manufactured by Tokushu Rika Kogyo Κ · Κ. (Model: ΤΚ AUTO HOMOMIXER SL · 10A ") The lacquer was stirred at 5000 rpm for 1 hour to obtain a lacquer for commercial offset inks. The container was heated to a temperature of 80 ° C, and 1 1 4 g The above-mentioned shrink-encapsulated carbon black aggregate was added to a varnish prepared for a commercial offset ink as described above, and then stirred at 5000 rpm for 120 minutes to obtain an ink. At this time, no flying of carbon black occurred. (9) The ink prepared in this way was kneaded by a consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, and kneaded with a rolling mill (model: "BR-500") manufactured by Asada Tekkosho KK. The size is determined to be no more than 10 microns. It is necessary to pass the ink through the rolling machine four times until the size of the dispersed block does not exceed 10 microns. This ink is matured for 1 week, and then used as the test ink. Standard f (Gift gift (21〇 miscellaneous)) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, 510915 A7 B7 V. Description of the invention (50) (1 0) Shrinkage test samples of this cured ink of 0.6 cm3 and placed In an offset printing press manufactured by Toyo Seiki .KK, A 4 size shredded wood paper was added to this press and printed, the ink was allowed to dry naturally, and then L 値 was measured using an SM color computer manufactured by Suga Shikenki KK. The color difference of the printing surface, the result was L 値 (brightness) of 27 · 6, and L 値 was equal to the ink (Example 7) prepared using powdered carbon black "MA 7" without molding or encapsulation. L of the ink値 (brightness) is based on the Hunters color difference disclosed in JISZ -8730-1980 (color difference notation), Example 2. The same steps as in Example 1 were performed, but the molding pressure was changed to 2 2.2 kg f / cm², the molded product The density was 0.598 g / cm3, the surface hardness was 622 g, and the internal hardness was 497 g. Moreover, the crushing ratio and the mesh residue were measured in the same manner as in Example 1, and the crushing ratio was 1.2 weight%, and the mesh The residual was 12.3% by weight, so both types of fluorene were good. The carbon black aggregate was encapsulated in the same manner as in Example 1 and an ink was prepared. In the preparation of the ink, no flying was observed, and the ink was passed through rolling. Machine three times, and the results of the shrinkage test, L 値 is 2 7 · 5, which is equal to the example comparison 7. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the note on the back first Matters written on this page)

510915 經濟部中央標準局員工消費合作社印装 A7 B7五、發明説明（51) 實例3 進行實例1的相同步驟，但是將模塑壓力改變爲 4 4.4 kg f/平方公分，模製產物之密度爲 0.656克/立方公分，表面硬度爲686克，且內部 硬度爲6 1 7克。 而且，用實例1的相同方法測量粉碎比例及網殘留， 粉碎比例爲0·4重量％，且網殘留爲20·6重量％, 因此兩種値都很好。 用實例1的相同方法包封此碳黑集料，並製備油墨， 在油墨之製備中，沒有觀察到飛揚，使油墨通過軋製機兩 次，而且在收縮測試的結果，L値爲27·3,此値與實 例比較7相等。 實例4 在SUS304模具中（內部大小：70毫米x70 毫米，高度：70毫米），加入0 · 1公斤由Mitsubishi Chemical Corporation製造的碳黑” Μ A 7 ” ，並裝設由 Yuken K.K.製造的水壓機，在1分鐘內將碳黑壓製成壓力 爲408 · 2 kg f/平方公分，使聚集而得到具有預 先決定形狀之碳黑集料，集料之密度（經由質量除以體積 所得的値）爲0·844克/立方公分。 而且，用實例1的相同方法測量硬度、粉碎比例及網 殘留，表面硬度爲1 * 270克，且內部硬度爲 (請先閲讀背面之注意事項 -- 本頁) 訂510915 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (51) Example 3 The same steps as in Example 1 were performed, but the molding pressure was changed to 4 4.4 kg f / cm². The density of the molded product was 0.656 g / cm3, the surface hardness is 686 g, and the internal hardness is 6 17 g. Furthermore, the pulverization ratio and the net residue were measured in the same manner as in Example 1. The pulverization ratio was 0.4% by weight and the net residue was 20.6% by weight, so both types of fluorene were good. This carbon black aggregate was encapsulated in the same manner as in Example 1 and an ink was prepared. In the preparation of the ink, no flying was observed, the ink was passed through the rolling mill twice, and in the result of the shrinkage test, L 値 was 27 · 3, this 値 is equal to 7 compared with the example. Example 4 In a SUS304 mold (internal size: 70 mm x 70 mm, height: 70 mm), 0.1 kg of carbon black "M A 7" manufactured by Mitsubishi Chemical Corporation was added, and a hydraulic press manufactured by Yuken KK was installed. The carbon black is pressed into a pressure of 408 · 2 kg f / cm 2 within 1 minute, and the carbon black aggregate having a predetermined shape is obtained by aggregation. The density of the aggregate (値 obtained by dividing mass by volume) is 0. · 844 g / cm3. Moreover, the hardness, crushing ratio and net residue were measured by the same method as in Example 1. The surface hardness was 1 * 270 grams, and the internal hardness was (Please read the precautions on the back first-this page).

本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐） •54- 510915 A7 B7 五、發明説明（52) 1，219克，粉碎比例爲0 · 2重量％，且網殘留爲 51·2重量％,因此粉碎比例好在低的範圍，硬度及網 殘留稍微偏高但是在沒有問題之範圍。 用實例1的相同方法包封此碳黑集料，並製備油墨， 在油墨之製備中，沒有觀察到飛揚，使油墨通過軋製機三 次，而且在收縮測試的結果，L値爲27 . 2,此値與實 例比較7相等。 實例5 ‘ 在1 0 0重量組份由Nippon Polychem K.K.製造的 EVA中，加入〇 · 3 0重量組份的脂肪酸醯胺、 0.90重量組份的氧化矽及0.075重量組份的氫氧 化鈣，隨後膨脹模塑而得到膜（厚度：30微米）。 用實例.1的相词步驟製備碳黑集料，但是將模塑壓力 改變爲7 · 4 kg f/平方公分，模製產物之密度爲 0 · 5 6 6克/立方公分。 經濟部中央標準局貝工消費合作社印装 用實例1的相同方法測量硬度、粉碎比例及網殘留， 表面硬度爲1 2 1克，內部硬度爲8 5克，粉碎比例爲 16.5重量％，且網殘留爲2·2重量％，粉碎比例及 網殘留都良好。 從實例2的碳黑集料切割114克並用上述膜包封β 根據實例1的相同方法用此包封的碳黑集料製備油墨 ，在油墨之製備中，沒有觀察到飛揚，使油墨通過軋製機 三次，而且在收縮測試的結果，L値爲27·5,此値與 本紙張尺度適用中國國家標準（CMS ) A4規格（2〗0X297公釐） • 55- 510915 A7 B7_ 五、發明説明（53) 實例比較7相等，而且在製備包封的碳黑集料本身或使用 其之油墨，沒有觀察到飛揚或環境污染。 實例6 將0·30重量組份的脂肪酸醯胺、0·90重量組 份的氧化矽及0·075重量組份的氫氧化鈣添加至40 重量％由Hercules Co·, Ltd.製造的乙基纖維素” N — 50 ”摻混60重量％EVA的樹脂組成物中，隨後膨脹模塑 而得到膜（厚度：3 0微米）。 用實例2的相同方法製備油墨，但是用此膜包封碳黑 集料。 在收縮測試的結果，L値爲2 7 · 5 ,此値與實例比 較7相等，而且在製備包封的碳黑集料本身或使用其之油 墨，沒有觀察到飛揚或環境污染。 實例7 經濟部中央標準局員工消費合作社印装 用實例2的相同方法製備包封的碳黑集料，但是用 PE (A)膜代替PE (B)膜包封，並使用此碳黑集料 製備油墨。 在收縮測試的結果，L値爲27.5,此値與實例比 較7相等，而且在製備包封的碳黑集料本身或使用其之油 墨，沒有觀察到飛揚或環境污染。 實例8 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) •56- 510915 A7 B7___ 五、發明説明（54) 用實例1的相同方法製備油墨，但是用Mitsubishi Chemical Corporation製造的碳黑” # 4 5 ” （粒子大小： 24毫微米，DBP油吸收：53毫升/100克碳黑， 鬆密度：0·270克/立方公分）代替MA7,膜塑產 物之密度爲0·565克/立方公分。 碳黑集料之表面硬度爲78克，內部硬度爲63克， 粉碎比例爲24·5重量％，且網殘留爲15·2重量％ ,粉碎比例稍高但仍在沒有問題之範圍內。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE(B)包封的碳黑（#45)集料製備油墨，在製備 包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚或 環境污染。 實例9 用實例2的相同方法製備油墨，但是用Mitsubishi Chemical Corporation 製造的碳黑” #4 5” 代替ΜΑ 7, 膜塑產物之密度爲0 · 6 9 2克/立方公分。 經濟部中央標準局員工消费合作社印装 碳黑集料之表面硬度爲6 2 3克，內部硬度爲4 3 7 克，粉碎比例爲1 · 2重量％，且網殘留爲1 8 . 1重量 % ,粉碎比例及網殘留都良好。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (Β)包封的碳黑（#45)集料製備油墨，在製備 包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚或 環境污染。 本紙張尺度適用中國國家標準（CNS ) Α4規格·（ 210X297公釐） •57- 510915 A7 __B7____ 五、發明説明（ 實例1 0 用實例3的相同方法製備油墨，但是用Mitsubishi Chemical Corporation 製造的碳黑 #45 代替ΜΑ 7 ’ 膜塑產物之密度爲0.771克/立方公分° 碳黑集料之表面硬度爲7 0 8克，內部硬度爲5 5 2 克，粉碎比例爲0·3重量％，且網殘留爲30·4重量 %,粉碎比例及網殘留都良好。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE(Β)包封的碳黑（#45)集料製備油墨，在製備 包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚或 環境污染。 實例1 1 用實例2的相同方法製備油墨，但是用Mitsubishi Chemical Corporation 製造的碳黑” #45” 代替 MA7, 膜塑產物之密度爲1 · 0 2 4克/立方公分。 經濟部中央標準局員工消费合作社印装 碳黑集料之表面硬度爲1，2 8 0克，內部硬度爲 1，211克，粉碎比例爲0 · 1重量％，且網殘留爲 8 8 · 9重量％，網殘留稍高但仍在沒有問題之範圍內。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (B)包封的碳黑（#4 5)集料製備油墨，在製備 包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚或 環境污染。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -58- 510915 經濟部中央標隼局員工消費合作社印裝 A7 _ B7五、發明説明（56) 實例1 2 用實例9的相同方法製備油墨，但是用PE (A)膜 代替P E ( B )膜包封，用實例1的相同方法測量硬度、 粉碎比例及網殘留。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (A)包封的碳黑（#45)集料製備油墨，在製備 包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚或 環境污染。' 實例1 3 用實例1的相同方法製備油墨，但是用Mitsubishi Chemical Corporation製造的碳黑” # 9 9 0 ” （粒子大小 :16毫微米，DBP 油吸收：113毫升/100克 碳黑，鬆密度：0 · 08 1克/立方公分）代替Μ A 7, 膜塑產物之密度爲0·241克/立方公分。 碳黑集料之表面硬度爲78克，內部硬度爲60克， 粉碎比例爲24.5重量％，且網殘留爲15·2重量％ ，粉碎比例稍高但仍在沒有問題之範圍內。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (B)包封的碳黑（#990)集料製備油墨，在製 備包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚 或環境污染。 (請先閲讀背面之注意事項This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) • 54- 510915 A7 B7 V. Description of the invention (52) 1,219 g, crushing ratio is 0 · 2% by weight, and net residue is 51.2% by weight. Therefore, the pulverization ratio is preferably in a low range, and the hardness and net residue are slightly higher, but in a range without problems. This carbon black aggregate was encapsulated in the same manner as in Example 1 and an ink was prepared. In the preparation of the ink, no flying was observed, and the ink was passed through the rolling mill three times. As a result of the shrinkage test, L 値 was 27.2. This 値 is equal to 7 in the example comparison. Example 5 'To 100 parts by weight of EVA manufactured by Nippon Polychem KK, 0.3 parts by weight of fatty acid ammonium, 0.90 parts by weight of silica and 0.075 parts by weight of calcium hydroxide were added, and then Film was obtained by expansion molding (thickness: 30 microns). The carbon black aggregate was prepared using the phase step of Example.1, but the molding pressure was changed to 7.4 kg f / cm2, and the density of the molded product was 0.556 g / cm3. Printed by the Central Standards Bureau of the Ministry of Economic Affairs of Shellfish Consumer Cooperatives using the same method as in Example 1 to measure the hardness, pulverization ratio, and mesh residue. The surface hardness was 121 grams, the internal hardness was 85 grams, the crushing ratio was 16.5% by weight, and the mesh residue It was 2.2% by weight, and the pulverization ratio and net residue were good. 114 g of the carbon black aggregate of Example 2 was cut and β was encapsulated with the above-mentioned film. An ink was prepared from this encapsulated carbon black aggregate according to the same method as in Example 1. In the preparation of the ink, no flying was observed, and the ink was passed through a rolling mill. The machine was made three times, and the result of the shrinkage test was L 値 27 · 5. This paper and the paper size apply the Chinese National Standard (CMS) A4 specification (2〗 0 × 297 mm) • 55- 510915 A7 B7_ V. Description of the invention (53) Example comparison 7 is equal, and no flying or environmental pollution was observed in the preparation of the encapsulated carbon black aggregate itself or its ink. Example 6 Fatty acid ammonium of 0.30 parts by weight, silica of 0.90 parts by weight, and calcium hydroxide of 0.075 parts by weight were added to 40% by weight of ethyl manufactured by Hercules Co., Ltd. Cellulose "N-50" was blended with a resin composition of 60% by weight of EVA, followed by expansion molding to obtain a film (thickness: 30 microns). An ink was prepared in the same manner as in Example 2 except that the carbon black aggregate was encapsulated with this film. In the results of the shrinkage test, L 値 is 2 7 · 5, which is equivalent to Example 7 and no flying or environmental pollution was observed in the preparation of the encapsulated carbon black aggregate itself or its ink. Example 7 The printed carbon black aggregate was prepared in the same manner as in Example 2 by the consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, except that the PE (A) film was used instead of the PE (B) film to encapsulate the carbon black aggregate. Ink. As a result of the shrinkage test, L 値 was 27.5, which was equivalent to Example 7 and no flying or environmental pollution was observed in the preparation of the encapsulated carbon black aggregate itself or its ink. Example 8 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) • 56- 510915 A7 B7___ V. Description of the invention (54) The ink was prepared by the same method as in Example 1, but using carbon black manufactured by Mitsubishi Chemical Corporation ”# 4 5” (particle size: 24 nm, DBP oil absorption: 53 ml / 100 g carbon black, bulk density: 0.270 g / cm 3) instead of MA7, the density of the membrane plastic product is 0.565 g / Cubic centimeters. The carbon black aggregate has a surface hardness of 78 grams, an internal hardness of 63 grams, a crushing ratio of 24.5% by weight, and a net residue of 15.2% by weight. The crushing ratio is slightly higher but still within the range without problems. To check the flying of the ink, the ink was prepared with PE (B) -encapsulated carbon black (# 45) aggregate according to the same method as in Example 1. In preparing the encapsulated carbon black aggregate itself or using its ink, no Observed flying or environmental pollution. Example 9 An ink was prepared in the same manner as in Example 2 except that carbon black "# 4 5" manufactured by Mitsubishi Chemical Corporation was used instead of MAA 7, and the density of the film-molded product was 0.62 g / cm3. The surface hardness of the printed carbon black aggregate of the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is 6 2 3 grams, the internal hardness is 4 3 7 grams, the crushing ratio is 1.2 weight%, and the net residue is 18.1 weight% , Crushing ratio and net residue are good. Inspecting the flying during the manufacture of the ink, the ink was prepared by using the PE (Β) -encapsulated carbon black (# 45) aggregate according to the same method as in Example 1. In preparing the encapsulated carbon black aggregate itself or using its ink, no Observed flying or environmental pollution. This paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210X297 mm) • 57-510915 A7 __B7____ 5. Description of the invention (Example 10) The ink was prepared in the same manner as in Example 3, but carbon black manufactured by Mitsubishi Chemical Corporation # 45 instead of ΜΑ 7 'The density of the film plastic product is 0.771 g / cm 3 ° The surface hardness of the carbon black aggregate is 708 g, the internal hardness is 5 5 2 g, and the crushing ratio is 0.3% by weight. The residue was 30 · 4% by weight, and the pulverization ratio and the net residue were good. To check the flying of the ink, the ink was prepared by using the carbon black (# 45) aggregate encapsulated by PE (Β) according to the same method as in Example 1. Preparation of the encapsulated carbon black aggregate itself or use of its ink, no flying or environmental pollution was observed. Example 1 1 An ink was prepared in the same manner as in Example 2, but using carbon black "# 45" manufactured by Mitsubishi Chemical Corporation instead of MA7 The density of the film-plastic product is 1.024 g / cm3. The surface hardness of the printed carbon black aggregate printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is 1,280 grams, and the internal hardness is 1,211 grams. powder The crushing ratio was 0 · 1% by weight and the net residue was 8 8 · 9% by weight. The net residue was slightly higher but still within the range without problems. Checking the flying during the manufacture of the ink was performed in the same way as in Example 1 using PE ( B) Encapsulated carbon black (# 4 5) aggregate preparation ink. No flying or environmental pollution was observed in the preparation of the encapsulated carbon black aggregate itself or its ink. The paper dimensions are in accordance with Chinese national standards (CNS ) A4 size (210X297 mm) -58- 510915 Printed by A7 _ B7 of the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (56) Example 1 2 Ink was prepared in the same manner as in Example 9, but using PE (A ) Film instead of PE (B) film encapsulation, the hardness, pulverization ratio and net residue were measured in the same way as in Example 1. Checking the flying during ink manufacturing was based on the same method used in Example 1 to encapsulate carbon black with PE (A) (# 45) Aggregate-prepared ink. No flying or environmental pollution was observed in the preparation of the encapsulated carbon black aggregate itself or the ink using it. 'Example 1 3 An ink was prepared in the same manner as in Example 1, but using Mitsubishi Chemical Corporation-made carbon black ”# 9 9 0” (Particle size: 16 nm, DBP oil absorption: 113 ml / 100 g of carbon black, bulk density: 0 · 08 1 g / cm 3) instead of M A 7, the density of the film plastic product is 0 · 241g / cm3. The surface hardness of the carbon black aggregate is 78g, the internal hardness is 60g, the crushing ratio is 24.5% by weight, and the net residue is 15.2% by weight. The crushing ratio is slightly higher but there is still no problem. Within range. To check the flying of the ink, the ink was prepared by using the PE (B) encapsulated carbon black (# 990) aggregate according to the same method as in Example 1. In preparing the encapsulated carbon black aggregate itself or using its ink, no Observed flying or environmental pollution. (Please read the notes on the back first

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -59· 510915 A7 B7 57 五、發明説明（ 實例1 4 用實例2的相同方法製備油墨，但是用Mitsubishi Chemical Corporation 製造的碳黑” # 9 9 0” 代替 MA7 ，膜塑產物之密度爲0·430克/立方公分。This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297mm) -59 · 510915 A7 B7 57 V. Description of the Invention (Example 1 4 Ink was prepared in the same way as in Example 2, but using carbon black manufactured by Mitsubishi Chemical Corporation ”# 9 9 0” instead of MA7, the density of the film plastic product is 0.430 g / cm3.

碳黑集料之表面硬度爲5 9 2克，內部硬度爲4 3 7 克，粉碎比例爲1·1重量％，且網殘留爲18·1重量 %,粉碎比例及網殘留都良好。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (B)包封的碳黑（#9 9 0)集料製備油墨，在製 備包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚 或環境污染。 訂 實例1 5 用實例3的相同方法製備油墨，但是用Mitsubishi themical Corporation 製造的碳黑” #9 9 0” 代替 MA7 ，膜塑產物之密度爲0·485克/立方公分。 經濟部中央標準局貝工消费合作社印裝 碳黑集料之表面硬度爲6 3 7克，內部硬度爲5 5 2 克，粉碎比例爲0·2重量％，且網殘留爲30.4重量 %,粉碎比例及網殘留都良好。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (B)包封的碳黑（#9 9 0)集料製備油墨，在製 備包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚 或環境污染。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •60 510915 經濟部中央標準局負工消费合作社印装 A7 B7五、發明説明（58) 實例1 Θ 用實例4的相同方法製備油墨，但是用Mitsubishi Chemical Corporation 製造的碳黑” #9 9 0” 代替 MA7 ，膜塑產物之密度爲0 · 6 6 2克/立方公分。 碳黑集料之表面硬度爲1，350克，內部硬度爲 1，270克，粉碎比例爲0 · 1重量％，且網殘留爲 76.3重量％，網殘留稍高但仍在沒有問題之範圍內。 檢査油墨製造時的飛揚，是根據實例1的相同方法用 PE (B)包封的碳黑（#990)集料製備油墨，在製 備包封的碳黑集料本身或使用其之油墨，沒有觀察到飛揚 或環境污染。 實例1 7 (1 )製備碳黑集料 將 0 · 5 公斤由 Mitsubishi Chemical Corporation 製造 的碳黑” #2650” （粒子大小：13毫微米，DBP 油吸收：78毫升/100克碳黑，鬆密度：〇 · 077 克/立方公分）放入碳鋼模具中（內部大小：1 5 0毫米 X 1 5 0毫米，高度：3 6 0毫米），並裝設由Yuken K· Κ·製造的水壓機，施加22 · 2 kg f /平方公分的壓 力進行壓塑而得到碳黑集料，測量所得集料之密度並發現 爲0.491克/立方公分。 (2 )製備熱收縮包封 (請先閲讀背面之注意事項The carbon black aggregate had a surface hardness of 592 g, an internal hardness of 4 37 g, a crushing ratio of 1.1% by weight, and a net residue of 18 · 1% by weight. The crushing ratio and net residue were good. To check the flying of the ink, the ink was prepared with PE (B) encapsulated carbon black (# 9 9 0) aggregate according to the same method as in Example 1. The encapsulated carbon black aggregate itself or its ink was used No flying or environmental pollution was observed. Example 15 An ink was prepared in the same manner as in Example 3, except that carbon black "# 9 9 0" manufactured by Mitsubishi themical Corporation was used instead of MA7, and the density of the film-plastic product was 0.485 g / cm3. The surface hardness of the carbon black aggregate printed by the Shell Standard Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is 637 grams, the internal hardness is 552 grams, the crushing ratio is 0.2% by weight, and the net residue is 30.4% by weight. Proportion and net residue are good. To check the flying of the ink, the ink was prepared with PE (B) encapsulated carbon black (# 9 9 0) aggregate according to the same method as in Example 1. The encapsulated carbon black aggregate itself or its ink was used No flying or environmental pollution was observed. This paper size applies to China National Standard (CNS) A4 (210X297 mm) • 60 510915 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives A7 B7 V. Description of the invention (58) Example 1 Θ Prepared by the same method as Example 4 Ink, but carbon black "# 9 9 0" manufactured by Mitsubishi Chemical Corporation was used instead of MA7, and the density of the film-plastic product was 0.62 g / cm3. The carbon black aggregate has a surface hardness of 1,350 grams, an internal hardness of 1,270 grams, a crushing ratio of 0.1% by weight, and a net residue of 76.3% by weight. The net residue is slightly higher but still within the range without problems. . To check the flying of the ink, the ink was prepared by using the PE (B) encapsulated carbon black (# 990) aggregate according to the same method as in Example 1. In preparing the encapsulated carbon black aggregate itself or using its ink, no Observed flying or environmental pollution. Example 1 7 (1) Preparation of carbon black aggregate 0.5 kg of carbon black "# 2650" manufactured by Mitsubishi Chemical Corporation (particle size: 13 nm, DBP oil absorption: 78 ml / 100 g carbon black, bulk density : 0 · 077 g / cm3) into a carbon steel mold (internal size: 150 mm X 150 mm, height: 360 mm), and equipped with a hydraulic press made by Yuken K · K ·, A carbon black aggregate was obtained by compression-molding by applying a pressure of 22.2 kgf / cm2, and the density of the obtained aggregate was measured and found to be 0.491 g / cm3. (2) Preparation of heat shrinkable encapsulation (Please read the precautions on the back first

本頁) 訂 r 本紙張尺度適用中國國家標準（CNS ) A4規格·（ 210X297公釐） -61· 510915 A7 B7__ 五、發明説明（59) 根據實例1的相同方法用PE(B)製備5公分x5 公分之聚乙烯袋。 從上述碳黑集料切割3克的碳黑集料並放入上述聚乙 烯袋中，然後將袋密封。 (3 )製備塗料 將9 0克由Tokyo Glass Κ·Κ·製造且直徑爲2 · 5至 3·5毫米之玻璃珠添加至140毫升的低溫瓶中，然後 將1 6克由K’ansai Paint Κ·Κ·製造的蜜胺醇酸樹脂淸漆（ Amylak 1 0 2 6 )、1 0 克由 Kansai Paint Κ·Κ·製造的 Amylak Thinner、及上述碳黑集料添加至低溫瓶中。 將此低溫瓶放在由Red Devil Co.製造的單一型塗料搖 動器內並搖動1 5分鐘，使此黑色的淸漆冷卻至室溫，大 小在0至5 0微米範圍之沒有分散的塊狀碳黑用Kabushiki Kaisha Kamishima Seisakusho 製造的粉碎計（型號： R 1 1 1 0 )測量，粉碎計的測量結果爲7微米。 經濟部中央標準局員工消费合作社印聚 而且，將5 0克” Amylak 1026 Clear”放入此低溫瓶 中，隨後經由塗料搖動器混合10分鐘而得到黑色塗料。 (4 )評估黑色 取樣一部分的黑色塗料（約1立方公分）並放在由 Fuji Film Co·，Ltd.製造的 PET 腠上（Trancee G，厚度 :1 8 0微米），並用由Toyo . Seiki Κ·Κ·製造的桿塗料器 (No · 24)拉伸，使此 PET 膜在由 Ikeda Rika Κ.Κ. 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） -62· 510915 A7 B7 五、發明説明（60) 製造的空氣循環乾燥器中（Automatic Drying Oven SS· 200N)在 1 2 0°C 下烘烤 2 0 分鐘，經由 Nippon Denshoku K.K.製造的色差計（Spectro Color Meter SE-2000 )測量 如此烘烤的黑色塗膜之L値，L値爲4·22,此L値與 使用沒有模塑或包封的粉狀碳黑” #2650”製備之塗 料相等。 實例1 8 用實例Γ 7的相同方法製備塗料，但是在賓例1 7中 的包封膜從PE (B)改變爲由Oishi Sangyo K.K.製造的 P S 〇 粉碎計値爲8微米，且塗膜的L値爲4.23,此L 値與使用沒有模.塑或包封的粉狀碳黑” # 2 6 5 0 ”製備 之塗料相等。 塗膜的L値（亮度）係根據揭示在JIS Z-8730 - 1980 (色差表示法）的Hunter’s色差。 經濟部中央標準局頁工消费合作社印裝 實例比較1 將 0 · 5 公斤由 Mitsubishi Chemical Corporation 製造 的碳黑” MA7”放入不銹鋼有角的容器中（1 5公分x 1 5公分X 1 2公分高度）並均勻調整上層表面（高度： 11·5公分），將有角的容器放在含直徑爲30公分且 高度爲35公分並在其上層部位具有吸氣口、壓力再恢復 口及壓力計之圓柱形粉末接受部份之密閉容器中，然後， 本紙張尺度適用中國國家標準（CNS ) A4規格&lt; 210X297公釐） -63- 510915 經濟部中央標準局員工消费合作社印装 A7 B7_.五、發明説明（61) 將粉末接受部份密阱，從吸氣口抽出內部空氣歷時1分鐘 ，將內部壓力降低至不高於1毫米汞柱，然後，將壓力再 恢復口打開使空氣從外部進入，使內部壓力在約〇 . 5秒 內恢復至大氣壓力。 如此，得到長度爲13.0公分、寬度爲12.8公 分且高度約7公分塊狀形式之碳黑集料，用風壓吹塊狀物 的頂部使有實質上的不規則，切出一部分此集料，測量其 密度並發現爲0 · 3 2 1克/立方公分，關於此塊狀物， 經由實例1的相同方法測量其硬度及粉碎比例，表面硬度 低於5 6克（低於可測量之最低値），內部硬度爲9 3克 ，粉碎比例爲42 · 3重量％，且油墨網殘留爲〇 .3重 量％，據此，粉碎比例太高而不適於使用。 嘗試用實例1的相同方法包封此碳黑集料，在此處理 過程中，集料破裂並粉碎且汙染環境。 根據實例1的相同方法，用此包封的碳黑集料製備油 墨，在油墨的製備過程中產生飛揚，至於收縮測試之結果 ,L値爲27·7,此値與實例1至7的値實質上相同。 實例比較2 根據實例比較1的相同方法製備碳黑集料，但是用由 Mitsubishi Chemical Corporation 製造的碳黑 ” # 4 5 ” 代 替實例比較1中的” MA7” ，其密度爲0 · 4 5 0克/ 立方公分，經由實例1敘述的方法測量此集料之硬度、粉 碎比例及網殘留，結果是表面硬度低於5 6克（低於可測 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項(This page) Order r This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm)-61 · 510915 A7 B7__ V. Description of the invention (59) PE (B) was prepared in 5 cm according to the same method as in Example 1. x5 cm polyethylene bag. From the above carbon black aggregate, 3 g of the carbon black aggregate was cut and put into the above polyethylene bag, and then the bag was sealed. (3) Preparation of a coating 90 g of glass beads manufactured by Tokyo Glass K.K. and having a diameter of 2.5 to 3.5 mm were added to a 140 ml low-temperature bottle, and 16 g of K'ansai Paint Melamine alkyd resin varnish (Amylak 1 0 2 6) manufactured by K.K., 10 g of Amylak Thinner manufactured by Kansai Paint K.K., and the above carbon black aggregate were added to a cryogenic bottle. The cryogenic bottle was placed in a single type paint shaker manufactured by Red Devil Co. and shaken for 15 minutes to cool the black lacquer to room temperature, with a size of 0 to 50 micrometers without dispersion. The carbon black was measured with a pulverizer (model: R 1 1 1 0) manufactured by Kabushiki Kaisha Kamishima Seisakusho, and the measurement result of the pulverizer was 7 microns. In addition, 50 grams of "Amylak 1026 Clear" was put into this cryogenic bottle and mixed with a paint shaker for 10 minutes to obtain a black paint. (4) Evaluate a portion of the black paint (approximately 1 cubic centimeter) of the black sample and place it on a PET roll made by Fuji Film Co., Ltd. (Trancee G, thickness: 180 microns), and use Toyo. Seiki KK · K · The rod applicator (No. 24) is made to stretch, so that this PET film is made by Ikeda Rika Κ.Κ. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -62 · 510915 A7 B7 V. Description of the invention (60) Air circulation dryer (Automatic Drying Oven SS 200N) manufactured at 120 ° C for 20 minutes, and passed through the Nippon Denshoku KK (Spectro Color Meter SE- 2000) The L 値 of the black coating film thus baked was measured. The L · was 4.22, which was equal to the paint prepared using powdered carbon black "# 2650" which was not molded or encapsulated. Example 18 A coating was prepared in the same manner as in Example Γ7, but the encapsulating film in Binary Example 17 was changed from PE (B) to PS manufactured by Oishi Sangyo KK. The pulverizer was 8 microns, and The L 値 is 4.23, which is equivalent to the paint prepared using powdered carbon black “# 2 6 5 0” without mold, plastic or encapsulation. The L 値 (brightness) of the coating film is based on the Hunter's color difference disclosed in JIS Z-8730-1980 (color difference expression). Comparison of printing examples of pager consumer cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 1 Put 0.5 kg of carbon black "MA7" manufactured by Mitsubishi Chemical Corporation into a stainless steel angled container (15 cm x 1 5 cm x 1 2 cm Height) and evenly adjust the upper surface (height: 11.5 cm), place the angled container with a diameter of 30 cm and a height of 35 cm and have an air inlet, a pressure recovery port and a pressure gauge on the upper part The cylindrical powder is received in a part of a closed container. Then, this paper size applies the Chinese National Standard (CNS) A4 specification &lt; 210X297 mm. 、 Explanation of the invention (61) The powder receives a part of the trap, and the internal air is drawn out from the suction port for 1 minute, and the internal pressure is reduced to not higher than 1 mm Hg. Then, the pressure recovery port is opened to allow the air from the outside Enter, so that the internal pressure returns to atmospheric pressure in about 0.5 seconds. In this way, a carbon black aggregate having a length of 13.0 cm, a width of 12.8 cm, and a height of about 7 cm was obtained, and the top of the block was blown with wind to make it substantially irregular, and a part of the aggregate was cut out. The density was measured and found to be 0 · 3 2 1 g / cm 3. Regarding this block, the hardness and pulverization ratio were measured by the same method as in Example 1. The surface hardness was lower than 56 g (lower than the minimum measurable value). ), The internal hardness is 93 grams, the crushing ratio is 42 · 3% by weight, and the ink screen residue is 0.3% by weight. Therefore, the crushing ratio is too high to be suitable for use. An attempt was made to encapsulate this carbon black aggregate in the same manner as in Example 1. During this process, the aggregate broke and pulverized and polluted the environment. According to the same method as in Example 1, ink was prepared by using the encapsulated carbon black aggregate, and flying occurred during the preparation of the ink. As for the result of the shrinkage test, L 値 was 27 · 7, which is the same as that of Examples 1 to 7 値Substantially the same. Example Comparative 2 A carbon black aggregate was prepared according to the same method as that of Example Comparative 1, except that the carbon black "# 4 5" manufactured by Mitsubishi Chemical Corporation was used instead of "MA7" in Example Comparative 1, and its density was 0.45 gram. / Cubic centimeter, the hardness, crushing ratio and net residue of this aggregate were measured by the method described in Example 1, and the surface hardness was lower than 56 g (below the measurable paper size, the Chinese National Standard (CNS) A4 specification applies) 210X297 mm) (Please read the notes on the back first

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-64- 510915 A7 _B7_ 五、發明説明（62) 量之最低値），內部硬度爲85克，粉碎比例爲47 · 5 重量％,且油墨網殘留爲12·5重量％。 嘗試用實例1的相同方法包封此碳黑集料，在此處理 過程中，集料破裂並粉碎且汙染環境。 根據實例1的相同方法，用此包封的碳黑集料製備油 墨，在油墨的製備過程中產生飛揚。 實例比較3 根據實例比較1的相同方法製備碳黑集料，但是用由 Mitsubishi Chemical Corporation 製造的碳黑” #9 9 0” 代替實例比較1中的” MA7” ，其密度爲0 · 2 1 2克 /立方公分，經由實例1敘述的方法測量此集料之硬度、 粉碎比例及網殘留，結果是表面硬度爲6 0克，內部硬度 爲86克，粉碎比例爲41·7重量％，且油墨網殘留爲 0 · 7重量％。 嘗試用實例1的相同方法包封此碳黑集料，在此處理 過程中，集料破裂並粉碎且汙染環境。 經濟部中央標準局負工消費合作社印裝 根據實例1的相同方法，用此包封的碳黑集料製備油 墨，在油墨的製備過程中產生飛揚。 實例比較4 從PE(B)膜切割兩片5公分xlO公分的大小， 將此兩片重疊放在一起，將三側邊密封而得到一個袋子， 製備數個此EVA袋子，在各袋子中加入由Mitsubishi 本纸張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） -65· 510915 經濟部中央標準局員工消費合作社印繁 A7 B7五、發明説明（63) Chemical Corporation製造作爲油墨顏料使用的碳黑” MA 7” （粒子大小：24毫微米，DBP油吸收：65毫升 /100克碳黑，鬆密度：0·190克/立方公分）， 將各EVA袋子的剩下一邊熱封而得到用E VA膜包封的 碳黑之碳黑包封，用袋子包封碳黑的時候，碳黑散落並汙 染環境。 用粉碎計確定製備的油墨中非分散結塊之大小，使油 墨通過軋製機，結果是，油墨通過三軋製機使大小不超過 10微米所需的次數爲六次。 使用此油墨，根據實例1的相同方法進行印刷，測量 印刷表面之L値，L値爲2 7 · 7。 實例比較5 根據實例比較4的相同方法製備商業化的膠版印刷油 墨，但是用經由乾性粒化” MA7”製備的” MA7B” (鬆密度：0 · 384克/立方公分）代替” MA7” ， 包封粒化碳黑的時候，從碳黑產生飛揚，根據實例比較4 的相同方法製備油墨，油墨通過軋製機使大小不超過1 0 微米所需的次數爲五次，在油墨的製備過程中，沒有觀察 到飛揚，使用此油墨所得的印刷表面之L 値爲27·5 (請先閲讀背面之注意事項 # I 本頁) 訂--64- 510915 A7 _B7_ 5. The description of the invention (62) is the lowest amount 値), the internal hardness is 85 grams, the crushing ratio is 47 · 5% by weight, and the ink screen residue is 12.5% by weight. An attempt was made to encapsulate this carbon black aggregate in the same manner as in Example 1. During this process, the aggregate broke and pulverized and polluted the environment. According to the same method as in Example 1, an ink was prepared by using the encapsulated carbon black aggregate, and flying was generated during the ink preparation process. Example Comparative 3 A carbon black aggregate was prepared according to the same method as that of Example Comparative 1, except that the carbon black "# 9 9 0" manufactured by Mitsubishi Chemical Corporation was used instead of "MA7" in Example Comparative 1, and its density was 0 · 2 1 2 G / cm3, the hardness, crushing ratio and net residue of this aggregate were measured by the method described in Example 1. As a result, the surface hardness was 60 g, the internal hardness was 86 g, the crushing ratio was 41.7% by weight, and the ink The net residue was 0.7% by weight. An attempt was made to encapsulate this carbon black aggregate in the same manner as in Example 1. During this process, the aggregate broke and pulverized and polluted the environment. Printing by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives According to the same method as in Example 1, ink was prepared using this encapsulated carbon black aggregate, which caused flying during the ink preparation process. Example comparison 4 Cut two pieces of 5 cm x 10 cm from a PE (B) film, put the two pieces on top of each other, seal the three sides to obtain a bag, prepare several EVA bags, and add them to each bag Made by Mitsubishi This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) -65 · 510915 Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, Yinfan A7 B7 V. Description of invention (63) Made by Chemical Corporation for use as ink pigment Carbon black "MA 7" (particle size: 24 nm, DBP oil absorption: 65 ml / 100 g carbon black, bulk density: 0.190 g / cm3), heat seal the remaining side of each EVA bag and The carbon black was obtained by encapsulating the carbon black with an E VA film. When the carbon black was encapsulated with a bag, the carbon black was scattered and polluted the environment. The size of the non-dispersed agglomerates in the prepared ink was determined by a pulverizer, and the ink was passed through a rolling mill. As a result, the number of times required for the ink to pass through the three rolling mills to make the size not more than 10 m was six. Using this ink, printing was performed according to the same method as in Example 1, and L 値 of the printed surface was measured, and L 値 was 2 7 · 7. Example Comparison 5 A commercial offset printing ink was prepared according to the same method as in Example Comparison 4, except that "MA7B" (bulk density: 0 · 384 g / cm3) prepared by dry granulation "MA7" was used instead of "MA7". When pelletizing carbon black, fly from carbon black is produced. The ink is prepared according to the same method as in Example 4. The ink is passed through a rolling mill to make the size no more than 10 microns. The number of times required is five. During the ink preparation process, No flying was observed, and the L L of the printing surface obtained using this ink was 27 · 5 (please read the note on the back first # I this page) Order-

實例比較6 根據實例2的相同方法製備油墨，但是用實例2製造 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -66· 510915 A7 ____·__B7____ 五、發明説明（64) 的”碳黑集料”（鬆密度：〇·598克/立方公分）代 替實例2包封的碳黑集料，在油墨的製備過程中，碳黑散 落並汙染工作環境。 根據實例1的相同方法使油墨通過軋製機，油墨通過 軋製機使大小不超過10微米所需的次數爲三次，而且根 據實例1的相同方法測量印刷表面之L値，L値爲 2 7.5。 實例比較7 根據實例1的相同方法製備油墨，但是用”碳黑MA 7粉末”（鬆密度：0.190克/立方公分）代替實例 1包封的碳黑集料，在油墨的製備過程中，碳黑散落並汙 染工作環境。 根據實例1的相同方法使油墨通過軋製機，油墨通過 軋製機使大小不超過10微米所需的次數爲六次，而且根 據實例1的相同方法測量印刷表面之L値，L値爲 2 7. 8 〇 經濟部中央標準局員工消费合作社印裝 從實例1至1 8及實例比較1至7的比較，明顯地經 由使用可溶解的膜包封表面硬度至少爲7 0克之碳黑集料 ，並用其製備油墨或塗料時，可以在不汙染環境下製備油 墨或塗料，除此之外，很訝異地在製備油墨時可減少油墨 通過軋製機的次數且不會降低製備的油墨之品質。 將包封的碳黑集料應用至有色的樹脂 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）. •67- 510915 Α7 Β7 經濟部中央標準局員工消費合作社印装 五、發明説明（65) 實例1 9及2 0與實例比較8至1 1說明經由使用可 與樹脂混溶的膜包封碳黑集料，並用其製備有色的樹脂時 ，可防止汙染工作環境。 實例1 9 (1)製備碳黑集料 將 1 公斤由 Mitsubishi Chemical Corporation 製造的碳 黑#45 (粒子大小：24毫微米，DBP油吸收：53 毫升/10σ克碳黑，鬆密度：0·270克/立方公分 )放入由Yuken Κ·Κ·製造的碳鋼模具中（內部大小： 150毫米xl50毫米，高度：360毫米），並裝設 由Yuken Κ.Κ.製造的20噸水壓機，施加40 k g f / 平方公分的壓力進行壓塑而得到碳黑集料，測量所得集料 之密度並發現爲0·761克/立方公分。 (2 )包封 從上述碳黑集料切下77·66克的碳黑集料，並放 入由 Kyowa Kikai Κ·Κ·製造的Universal Sealer (型號：&quot; T 一 6 0 0” ）中，其中裝上厚度爲1 6微米的雙軸拉伸 聚乙烯膜，在1 8 0°C下進行熱封2秒，將包封在聚乙烯 膜之此碳黑集料放入由Kyowa Kikai K.K.製造且設定在 1 5 0的 Universal Shrink Tunnel (型號：” N S — 450”）中，使膜熱收縮10秒。 (請先閱讀背面之注意事項Example comparison 6 The ink was prepared according to the same method as in Example 2, but the paper used in Example 2 was produced in accordance with China National Standard (CNS) A4 (210X297 mm) -66 · 510915 A7 ____ · __B7 ____ V. Description of the Invention (64) "Carbon black aggregate" (bulk density: 0.598 g / cm3) instead of the carbon black aggregate encapsulated in Example 2. During the preparation of the ink, the carbon black was scattered and polluted the working environment. The same method as in Example 1 was used to pass the ink through the rolling mill, and the number of times required for the ink to pass through the rolling machine to not exceed 10 microns was three times, and the L 表面 on the printed surface was measured according to the same method as in Example 1, and L 値 was 2 7.5 . Comparative Example 7 An ink was prepared according to the same method as in Example 1, but "carbon black MA 7 powder" (bulk density: 0.190 g / cm3) was used instead of the carbon black aggregate encapsulated in Example 1. During the ink preparation process, carbon Black strays and pollutes the work environment. According to the same method of Example 1, the ink was passed through the rolling machine, and the number of times required for the ink to pass through the rolling machine to not exceed 10 micrometers was six times, and the printing surface L 値 was measured according to the same method of Example 1, and L 値 was 2 7.8 The comparison of examples from 1 to 18 and the comparison of examples 1 to 7 by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economics clearly shows that carbon black aggregates with a surface hardness of at least 70 g are encapsulated with a soluble film. In addition, when using it to prepare inks or coatings, inks or coatings can be prepared without polluting the environment. In addition, it is surprisingly possible to reduce the number of times the ink passes through the rolling machine without reducing the prepared ink. quality. Apply the encapsulated carbon black aggregate to the colored resin. The paper size is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). • 67- 510915 Α7 Β7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Explanation (65) Examples 19 and 20 are compared with Examples 8 to 11. 1 illustrates that when a carbon black aggregate is encapsulated with a resin-miscible film and used to prepare a colored resin, pollution to the working environment can be prevented. Example 1 9 (1) Preparation of carbon black aggregate 1 kg of carbon black # 45 (particle size: 24 nm, DBP oil absorption: 53 ml / 10 sigma carbon black, bulk density: 0.2270, manufactured by Mitsubishi Chemical Corporation) G / cm3) into a carbon steel mold (internal size: 150 mm x 150 mm, height: 360 mm) made by Yuken KK · K, and installed a 20-ton hydraulic press made by Yuken KK. A carbon black aggregate was obtained by compression molding at a pressure of 40 kgf / cm2, and the density of the obtained aggregate was measured and found to be 0.7761 g / cm3. (2) Encapsulating 77.66 grams of carbon black aggregate cut from the above carbon black aggregate and placing it in a Universal Sealer (model: &quot; T-6 0 0 ") manufactured by Kyowa Kikai KK In it, a biaxially stretched polyethylene film with a thickness of 16 micrometers was installed, and heat-sealed at 180 ° C for 2 seconds. The carbon black aggregate encapsulated in the polyethylene film was placed in Kyowa Kikai KK Manufactured and set in a 150 Universal Shrink Tunnel (model: "NS — 450"), and heat shrinks the film for 10 seconds. (Please read the precautions on the back first

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X^7公釐） -68 - 510915 A7 B7 經濟部中央標準局員工消費合作社印装 五、發明説明（66) (3)製備有色的樹脂 在由 Toyo SeikiSeisakusho Κ·Κ·製造的 Banbury 混合 機（型號：B — 2 5 0 )中加入1 1 4 ·2 1克由Mitsubis hi Chemical Corporation 製造的 A B S 樹脂（5111116叉5八1^-C)、1 · 1 4克由Chiba-Geigy AG製造的抗老化劑（ Irganox 1010)、1 · 1 4克硬脂酸鈣及上段敘述之包封的 碳黑集料，將混合物溫度設定在16 5°C,進行捏合1. 2 分鐘而得到碳黑濃度爲4 0重量％之母體批次物。 在2.5克此40重量％的母體批次物中，加入 9 7 · 5 克由 Mitsubishi Chemical Corporation 製造的 A B S 樹脂（Toughlex 450),用 Yasuda Seiki Seisakusho K.K.製造且設定在1 5 0°C的雙輥軋製機（型號1 9 1 一 TM)使混合物捏合1〇分鐘而得到有色的樹脂樣品。 將有色的樹脂樣品形成厚度爲0·3毫米之薄層，從 其中切下3 X 3毫米之樣品，將玻璃片放在設定爲2 4 0 °C的加熱板上，將3x3毫米之切割樣品放在玻璃片上並 在其上面放另一玻璃片而形成三明治化，加壓1〇分鐘使 樣品拉伸。 (4 )測量分散性 關於拉伸的樣品，用 Mitsubishi Chemical Corporation 製造的影像處理設備（MKS I PS — 1 〇〇〇)計算直 徑至少爲7微米之粒子的面積，從檢査範圍的面積及粒子 大小至少爲7微米的粒子總面積，根據下列公·式計算分散 (請先閲讀背面之注意事項 -- 本瓦)This paper size is applicable to Chinese National Standard (CNS) A4 (210X ^ 7mm) -68-510915 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (66) To a Banbury mixer (model: B — 2 50) manufactured by Toyo Seiki Seisakusho K · K · was added 1 1 4 · 2 1 g of ABS resin (5111116 fork 5 八 1 ^ -C) manufactured by Mitsubis hi Chemical Corporation, 1.4 grams of an anti-aging agent (Irganox 1010) manufactured by Chiba-Geigy AG, 1.4 grams of calcium stearate and the encapsulated carbon black aggregate described in the previous paragraph, set the temperature of the mixture at 16 5 ° C Kneading was performed for 1.2 minutes to obtain a mother batch having a carbon black concentration of 40% by weight. To 2.5 g of this 40% by weight parent batch, 97.5 g of ABS resin (Toughlex 450) manufactured by Mitsubishi Chemical Corporation was added, and a double roll made of Yasuda Seiki Seisakusho KK and set at 150 ° C A rolling machine (model 191-TM) kneaded the mixture for 10 minutes to obtain a colored resin sample. The colored resin sample was formed into a thin layer with a thickness of 0.3 mm, and a 3 X 3 mm sample was cut from it. A glass piece was placed on a heating plate set at 240 ° C, and a 3 x 3 mm cut sample was cut. Place on a glass sheet and place another glass sheet on top of it to form a sandwich. Press for 10 minutes to stretch the sample. (4) Measure the dispersibility. For stretched samples, the area of particles with a diameter of at least 7 microns was calculated using image processing equipment (MKS I PS — 1000) manufactured by Mitsubishi Chemical Corporation. From the area of the inspection range and the particle size The total area of the particles is at least 7 microns, and the dispersion is calculated according to the following formula (please read the precautions on the back-Benwa)

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本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） -69- 510915 A7 B7 經濟部中央標準局員工消費合作社印裝 五、發明説明（67) 指數。 分散指數=粗粒子總面積/檢査範圍的面積X100000 結果是分散指數爲1 3 3 6,其結果列在表3。 實例2 0 (1 )製備碳黑集料 根據實例19的方法製備碳黑集料。 (2 )包封 從上述碳黑集料切下69·44克的碳黑集料，並放 入由Kyowa Kikai Κ·Κ·製造的Universal Sealer (型號：·’ T一600” ）中，其中裝上厚度爲16微米的雙軸拉伸 聚乙烯膜，在1 8 0°C下進行熱封2秒，將包封在聚乙烯 膜之此碳黑集料放入由Kyowa Kikai K.K.製造且設定在 1 5 0 °C 的 Universal Shrink Tunnel (型號：” N S — 450 ” ）中，使膜熱收縮10秒。 % (3)製備有色的樹脂 在由Toyo Seiki Seisakusho Κ·Κ·製造的Banbury 混合 機（型號·· B — 2 5 0 )中加入1 0 1 · 4 9克由 Mitsubishi Chemical Corporation製造的低密度聚乙Μ樹脂 (LF440HA)、0.87 克由 Chiba-Geigy AG 製造 的抗老化劑（Irganox 1010)、.1 · 3 9克硬脂酸鈣及上段 敘述之包封的碳黑集料，將混合物溫度設定在1 1 5°C, (請先閲讀背面之注意事項再 -mk— 本頁) 訂This paper size applies to China National Standard (CNS) A4 specifications (210 × 297 mm) -69- 510915 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Dispersion index = total area of coarse particles / area of inspection range X100000 The result is that the dispersion index is 1 3 3 6, and the results are shown in Table 3. Example 2 0 (1) Preparation of carbon black aggregate A carbon black aggregate was prepared according to the method of Example 19. (2) Encapsulating 69.44 grams of carbon black aggregate cut from the above carbon black aggregate and placing it in a Universal Sealer (model: 'T-600 ") manufactured by Kyowa Kikai KK ·, where A biaxially stretched polyethylene film with a thickness of 16 μm was mounted, and heat-sealed at 180 ° C. for 2 seconds. The carbon black aggregate encapsulated in the polyethylene film was placed in a set made by Kyowa Kikai KK The film was heat-shrinked in a Universal Shrink Tunnel (model: "NS — 450") at 150 ° C for 10 seconds.% (3) Preparation of colored resin in a Banbury mixer manufactured by Toyo Seiki Seisakusho KK (Model ·· B — 2 5 0) 1 0 1 · 4 9 g of low density polyethylene resin (LF440HA) manufactured by Mitsubishi Chemical Corporation, 0.87 g of anti-aging agent (Irganox 1010 manufactured by Chiba-Geigy AG) ), .1 · 39 grams of calcium stearate and the encapsulated carbon black aggregate described in the previous paragraph, set the mixture temperature to 115 ° C, (Please read the precautions on the back before -mk— this page) Order

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •70- 510915 A7 B7 經濟部中央標準局貝工消费合作社印裝 五、發明説明（68) 進行捏合7分鐘而得到碳黑濃度爲4 0重量％之母體批次 物。 在1·5克此40重量％的母體批次物中，加入 5 8 · 3 克由Mitsubishi Chemical Corporation 製造的低密 度聚乙稀樹脂（F 1 20)，用 Yasuda Seiki Seisakusho Κ·Κ·製造且設定在1 30°C的雙輥軋製機（型號1 9 1 一 TM)使混合物捏合1〇分鐘而得到有色的樹脂樣品。 將有色的樹脂樣品形成厚度爲0·3毫米之薄層，從 其中切下3x3毫米之樣品，將玻璃片放在設定爲2 4 0 °C的加熱板上，將3x3毫米之切割樣品放在玻璃片上並 在其上面放另一玻璃片而形成三明治化，加壓1 〇分鐘使 樣品拉伸。 ^ (4)測量分散性 根據實例19的方法進行測量。 結果是分散指數爲3 3 4,其結果列在表4。 實例比較8 進行根據實例1 9的相同操作，但是使用由Mitsubishi Chemical Corporation製造且沒有模塑或包封的碳黑乾性 粒化產物” #45B” （粒子大小：24毫微米，DBP 吸收：53毫升/100克碳黑，鬆密度：0 · 481克 /立方公分）。 結果是分散指數爲1 * 739。 (請先閲讀背面之注意事項This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) • 70- 510915 A7 B7 Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (68) The carbon black concentration is obtained by kneading for 7 minutes It is 40% by weight of the parent batch. To 1.5 grams of this 40% by weight parent batch, 5 8 · 3 grams of a low density polyethylene resin (F 1 20) manufactured by Mitsubishi Chemical Corporation was added, manufactured by Yasuda Seiki Seisakusho KK · K · and The mixture was kneaded for 10 minutes in a two-roll mill (model 1 911-TM) set at 130 ° C to obtain a colored resin sample. The colored resin sample was formed into a thin layer with a thickness of 0.3 mm, and a 3 x 3 mm sample was cut from it. A glass piece was placed on a heating plate set at 240 ° C, and a 3 x 3 mm cut sample was placed A glass sheet was placed on top of the glass sheet to form a sandwich, and the sample was stretched by pressing for 10 minutes. ^ (4) Measurement of dispersion The measurement was performed according to the method of Example 19. As a result, the dispersion index was 3 3 4, and the results are shown in Table 4. Example Comparative 8 The same operation as in Example 19 was performed, but using a carbon black dry granulated product "# 45B" (particle size: 24 nm, DBP absorption: 53 ml) manufactured by Mitsubishi Chemical Corporation and not molded or encapsulated / 100g carbon black, bulk density: 0 · 481g / cm3). The result is a dispersion index of 1 * 739. (Please read the notes on the back first

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本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 510915 A7 _________ B7 _ 五、發明説明（69) 而且，在秤重碳黑之乾性粒化產物時，粒化產物所含 的微細粉末散落並汙染工作環境，其結果列在表3。 實例比較9 進行根據實例19的相同操作，但是使用沒有包封的 碳黑模塑產物。 結果是分散指數爲1，3 8 0,與起始的原料粉末比 較，使用碳黑模塑產物可實質上降低粉末散落，但是與實 例19使用之包封的碳黑模塑產物比較，環境污染的預防 並不適宜，其結果列在表3 · 表3實例及實例比較 碳黑 分散指數 環境污染 實例19 包封的碳黑集料 1,336 沒有 實例比較8 碳黑的乾性粒化產物 1,739 嚴重汙染 實例比較9 碳黑集料 1,380 輕微汙染 經濟部中央標準局員工消费合作社印«. 實例比較1 0 進行根據實例2 0的相同操作，但是使用由Mitsubishi Chemical Corporation製造且沒有模塑或包封的碳黑乾性 粒化產物” # 4 5 B ” （粒子大小：2 4毫微米，D B P 吸收：53毫升/100克碳黑，鬆密度：0 · 481克 /立方公分）。 結果是分散指數爲5 3 3，而且，在秤重碳黑之乾性 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •72· 510915 A7 ___ B7 五、發明説明（7〇) 粒化產物時，粒化產物所含的微細粉末散落並汙染工作環 境，其結果列在表4。 實例比較1 1 進行根據實例20的相同操作，但是使用沒有包封的 碳黑模塑產物。 結果是分散指數爲346,與起始的原料粉末比較， 使用碳黑模塑產物可實質上降低粉末散落，但是與實例 20使用之包封的碳黑模塑產物比較，環境污染的預防並 不適宜，其結果列在表4。 (請先閲讀背面之注意事項This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) 510915 A7 _________ B7 _ V. Description of the invention (69) Moreover, when weighing the dry granulated product of heavy carbon black, the granulated product contains The fine powder was scattered and polluted the working environment. The results are shown in Table 3. Example Comparative 9 The same operation as in Example 19 was performed, but an unencapsulated carbon black molded product was used. As a result, the dispersion index was 1, 3 0. Compared with the starting raw material powder, the use of the carbon black molding product can substantially reduce powder scattering, but compared with the encapsulated carbon black molding product used in Example 19, environmental pollution The prevention is not suitable, and the results are listed in Table 3 Comparison 9 Carbon black aggregate 1,380 Lightly polluted by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economy «Example comparison 1 0 The same operation as in Example 20 was performed, but using carbon black manufactured by Mitsubishi Chemical Corporation and not molded or encapsulated Dry granulated product "# 4 5 B" (particle size: 24 nm, DBP absorption: 53 ml / 100 g of carbon black, bulk density: 0 · 481 g / cm 3). As a result, the dispersion index is 5 3 3, and the paper size of the heavy carbon black is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm) • 72 · 510915 A7 ___ B7 V. Description of the invention (7〇 ) When granulating the product, the fine powder contained in the granulated product was scattered and polluted the working environment. The results are shown in Table 4. Comparative Example 1 1 The same operation as in Example 20 was performed, but a carbon black molded product was used without encapsulation. The result was a dispersion index of 346. Compared with the starting material powder, the use of carbon black molding products could substantially reduce powder scattering, but compared with the encapsulated carbon black molding products used in Example 20, the prevention of environmental pollution was not It is suitable, and the result is shown in Table 4. (Please read the notes on the back first

本頁) 表4 « 碳黑 分散指數 環境污染 實例20 包封的碳黑集料 334 沒有 實例比較10 碳黑的乾性粒化產物 533 嚴重汙染 實例比較11 碳黑集料 346 輕微汙染 訂(This page) Table 4 «Carbon Black Dispersion Index Environmental Pollution Example 20 Encapsulated Carbon Black Aggregate 334 None Example Comparison 10 Dry Granulated Product of Carbon Black 533 Severe Pollution Example Comparison 11 Carbon Black Aggregate 346 Light Pollution Order

經濟部中央標準局員工消費合作社印製 如同實例1 9及實例比較8及9用AB S樹脂包封的 碳黑集料及如同實例2 0及實例比較1 0及1 1用聚乙烯 包封的碳黑集料，具有極佳的分散性且有極佳的預防環境 污染的效應。 I 包封的碳黑集料應用至橡膠 實例21與實例比較12及13說明經由使用包封的 本紙張尺度適用中國國家標準（CNS ) A4規格(2】0X297公釐） 510915 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（71 ) 碳黑集料製備橡膠時，可防止環境汙染。 實例2 1 (1 )製備碳黑集料 將 5 0 0 克由 Mitsubishi Chemical Corporation 製造的 碳黑” D I A — I ” （非粒化產物）（粒子大小：2 4毫 微米，DBP油吸收：114毫升/100克碳黑，鬆密 度：0 · 169克/立方公分）放入由Yuken Κ·Κ·製造的 碳鋼（SS 400)模具中（內部大小：150毫米X 1 5 0毫米，高度：3 6 0毫米），並裝設由Yuken Κ.Κ. 製造的20噸水壓機，施加88 · 9 kg f/平方公分 的壓力進行壓塑而得到碳黑集料，測量所得集料之密度並 發現爲0·522克/立方公分。 (2 )包封 從上述碳黑集料放入由Kyowa Kikai K.K.製造的 Universal Sealer (型號：” T 一 600” ）中，其中裝上 厚度爲2 0微米的聚乙烯膜，在1 5 0°C下進行熱封2秒 ，將包封在聚乙烯膜之此碳黑集料放入由Kyowa Kikai K.K. 製造且設定在1 5 0°C的Universal Shrink Tunnel (型號 :” NS—450” ）中，使膜熱收縮10秒。 (3 )捏合橡膠 用Banbury混合機及開口軋製機將此包封的碳黑集料 (請先閲讀背面之注意事項Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs as in Example 19 and Comparative Examples 8 and 9 carbon black aggregates encapsulated with AB S resin and as in Example 20 and Comparative Examples 10 and 11 1 Carbon encapsulated with polyethylene Black aggregate, with excellent dispersibility and excellent effect of preventing environmental pollution. I Encapsulated carbon black aggregate applied to rubber Example 21 Comparison with examples 12 and 13 Explains that by using the paper size of the envelope, the Chinese National Standard (CNS) A4 specification (2) 0X297 mm is applied 510915 A7 B7 Central Printed by the Consumer Cooperatives of the Bureau of Standards V. Description of Invention (71) Carbon black aggregates can prevent environmental pollution when preparing rubber. Example 2 1 (1) Preparation of Carbon Black Aggregate 500 g of carbon black "DIA—I" (non-granulated product) manufactured by Mitsubishi Chemical Corporation (particle size: 24 nm, DBP oil absorption: 114 ml / 100g of carbon black, bulk density: 0 · 169g / cubic centimeter) into a carbon steel (SS 400) mold made by Yuken KK · (internal size: 150 mm X 150 mm, height: 3 60 mm), and equipped with a 20-ton hydraulic press manufactured by Yuken KK., Pressurized with a pressure of 88.9 kg f / cm 2 to obtain a carbon black aggregate. The density of the obtained aggregate was measured and found to be 0.522 g / cm3. (2) Encapsulating the above carbon black aggregate into a Universal Sealer (model: "T-600") manufactured by Kyowa Kikai KK, in which a polyethylene film with a thickness of 20 micrometers is mounted, at 150 ° Heat-seal for 2 seconds at C. Place this carbon black aggregate encapsulated in a polyethylene film into a Universal Shrink Tunnel (model: "NS-450") manufactured by Kyowa Kikai KK and set at 150 ° C. , The film was thermally contracted for 10 seconds. (3) Kneading rubber The carbon black aggregate encapsulated with a Banbury mixer and open-roller (please read the precautions on the back first)

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •74· 510915 A7 ______B7 五、發明説明（72) 與下列成份混合而得到橡膠組成物。 天然橡膠（&quot;SMR-L&quot;) 100重量組份 包封的碳黑集料 50重量組份 鈴白 5重量組份 硬脂酸 3重量組份 防老化劑（&quot;Santoflex 13&quot;, 1重量組份 Monsanto Co·製造） 硫 2重量組份 硫化促進劑（Nokseler CZ, 0.7重量組份 Ouchi Shinko K.K.製造） (請先閲讀背面之注意事項This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) • 74 · 510915 A7 ______B7 5. Description of the invention (72) The rubber composition is obtained by mixing with the following ingredients. Natural rubber (&quot; SMR-L &quot;) 100 weight component encapsulated carbon black aggregate 50 weight component suzuki 5 weight component stearic acid 3 weight component anti-aging agent (&quot; Santoflex 13 &quot;, 1 weight Component by Monsanto Co · Sulfur 2 weight component vulcanization accelerator (Nokseler CZ, 0.7 weight component by Ouchi Shinko KK) (Please read the precautions on the back first

本頁) 、-ιτ 在橡膠組成物之製造過程中，沒有觀察到因爲碳黑散 落而造成的環境污染。This page), -ιτ In the manufacturing process of rubber composition, no environmental pollution caused by the scattering of carbon black was observed.

(4 )橡膠測試 經濟部中央標準局員工消費合作社印製 此橡膠組成物在1 6 0 °C下進行平板硫化而得到硫化 的橡膠測試樣品，用下列測試方法進行不同的測試，並測 量其物理性質。 在下列情形下，使用Kabushiki Kaisha Rheology製造 之&quot;DVE Rheospectrer&quot;測量功耗因數（t a ηδ)。 靜態變形：10%;動態變形（振幅）：2%;頻率 ·· 1 0 Η ζ ;測量溫度：6 0 t 在下列情形下使用由Kabushiki Kaisha Kamishima 本紙張尺度適用中國國家標準（CNS ) Α4規格(210Χ297公釐） •75- 經濟部中央標準局員工消費合作社印装 510915 A7 B7 五、發明説明（73)(4) Rubber testing. The Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed this rubber composition to undergo flat plate vulcanization at 160 ° C to obtain vulcanized rubber test samples. Use the following test methods to perform different tests and measure their physical properties. nature. In the following cases, "DVE Rheospectrer" manufactured by Kabushiki Kaisha Rheology was used to measure the power consumption factor (t a ηδ). Static deformation: 10%; Dynamic deformation (amplitude): 2%; Frequency ·· 1 0 Η ζ; Measurement temperature: 6 0 t Use in the following cases by Kabushiki Kaisha Kamishima This paper standard applies to Chinese National Standard (CNS) Α4 specifications (210 × 297 mm) • 75- Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 510915 A7 B7 V. Description of Invention (73)

Seisakusho製造的 Good Rich Flexometer 測量熱積聚' 測量溫度：35 °C;負荷：24磅：測試時間：25 分鐘 根據測量碳黑分散性的方法，也就是ASTM D2 6 6 3 — B方法（計算聚集物的方法），測量橡膠中 強化粒子之分散性（D%),換句話說，用Sledge型切薄片 機（Leitz Co.製造）將硫化橡膠切成薄膜，然後，用光學 顯微鏡測量摻混物中至少5微米強化粒子（碳黑）聚集物 所佔據的總面積，從添加至摻混物的強化粒子之總截面積 (計算値）得到大小不超過5微米之強化粒子的百分比並 作爲分散性（D % )。 結果是，在60 °C的功耗因數爲0 · 139,熱積聚 爲31 · 0°C且D%爲99 · 2%,其結果總結在表5。 實例比較1 2 進行根據實例21的相同方法測試橡膠，但是將碳黑 改成由 Mitsubishi Chemical Corporation 製造的 ” DIA — I” （濕性粒化產物）（鬆密度：0.351克/立方公 分）。 結果是，在60 °C的功耗因數爲0 . 152,熱積聚 爲35 · 0°C且D%爲95 · 4%,而且在秤重碳黑之粒 化產物時，粒化產物所含的微細粉末散落並汙染環境。 實例比較1 3 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）The Good Rich Flexometer manufactured by Seisakusho measures heat accumulation 'Measurement temperature: 35 ° C; Load: 24 lbs: Test time: 25 minutes According to the method for measuring the dispersion of carbon black, which is ASTM D2 6 6 3 — B method (calculate aggregates Method), measuring the dispersion (D%) of the reinforced particles in the rubber, in other words, cutting the vulcanized rubber into a thin film using a Sledge type slicer (manufactured by Leitz Co.), and then measuring at least the blend with an optical microscope The total area occupied by aggregates of 5 micron reinforced particles (carbon black), the percentage of reinforced particles up to 5 microns in size obtained from the total cross-sectional area of reinforced particles added to the blend (calculated 値) and used as dispersibility (D %). As a result, the power dissipation factor at 60 ° C was 0 · 139, the heat accumulation was 31 · 0 ° C, and D% was 99 · 2%. The results are summarized in Table 5. Comparative Example 1 2 The rubber was tested in the same manner as in Example 21, except that carbon black was changed to "DIA-I" (wet granulated product) manufactured by Mitsubishi Chemical Corporation (bulk density: 0.351 g / cm3). The result is a power consumption factor of 0.152 at 60 ° C, a thermal buildup of 35.0 ° C, and a D% of 95.4%, and when the granulated product of heavy carbon black is weighed, the granulated product contains The fine powder is scattered and pollutes the environment. Comparison of Examples 1 3 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm)

-76- 510915 A7 __Β7 _ 五、發明説明（74) 進行根據實例13的相同操作，但是使用沒有包封的 碳黑集料。 結果是，在60 t的功耗因數爲0 · 140，熱積聚 爲31 · 4 °C且D%爲99 . 1%,與起始的原料粉末比 較，使用碳黑集料可實質上降低飛揚，但是與實例21使 用之包封的碳黑集料比較，環境污染的預防並不適宜，其 結果列在表5。 表5 功耗因熱積聚分散指數（D環境污染 塾_ %) _ 實例2 1 1.39 31.0 99.2 沒有 實例比較12 1.52 35.0 95.4 嚴重汙染 實例比較13 . 1.40 31.4 99.1 輕微汙染 經濟部中央標準局員工消费合作社印裝 從實例21及實例比較12及13的比較，用包封的 碳黑集料降低環境污染的效應非常明顯，而且實例2 1顯 示有高的分散性，雖然其鬆密度高於實例比較12的事實 有裂縫的碳黑集料改進分散性 實例2 2及2 3與實例比較1 4及1 5說明經由預先 使包封的碳黑集料有裂縫，不只可防止環境汙染，還可有 高的分散性。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •77- 510915 A7 B7 經濟部中央標準局員工消費合作社印装 五、發明説明（75) 實例2 2 (1 )製備碳黑集料 將 0 · 5 公斤由 Mitsubishi Chemical Corporation 製造 的碳黑” MA7” （粒子大小：24毫微米，DBP油吸 收：65毫升/100克碳黑，鬆密度：〇·190克/ 立方公分）放入由Yuken Κ·Κ·製造的碳鋼模具中（內部大 小：150毫米xl50毫米，高度：350毫米），並 裝設由YukeiT Κ.Κ.製造的水壓機，施加2 2 · 2 k g f /平方公分的壓力進行壓塑而得到碳黑集料，測量所得集 料之密度並發現爲0 · 5 9 8克/立方公分，從此集料， 切割成30克的八塊。 (2)製備熱收縮包封 從上述碳黑集料放入由Kyowa Kikai Κ·Κ·製造的 Universal Sealer (型號：” T 一 6 〇 0 ” ）中，其中加入 由Mitsubishi Chemical Corporation製造的乙嫌一醋酸乙嫌 酯共聚物（以戲稱爲EVA)(型號：LV540,醋酸 乙烯酯含量：2 0重量％)並經吹模成厚度爲3 0微米， 在1 8 0°C下進行熱封2秒，將包封在EVA膜之此碳黑 模塑產物放入由Kyowa Kikai K.K.製造且設定在1 5 0 °C 的 Universal Shrink Tunnel (型號NS — 450” ） 中，使膜熱收縮10秒，在相同的方法下，將其餘7塊包 封。 (請先閱讀背面之注意事項-76- 510915 A7 __Β7 _ V. Description of the Invention (74) The same operation as in Example 13 was performed, but an unencapsulated carbon black aggregate was used. As a result, at 60 t, the power consumption factor is 0 · 140, the heat accumulation is 3 · 4 ° C, and the D% is 99.1%. Compared with the original raw material powder, the use of carbon black aggregates can substantially reduce flying. However, compared with the encapsulated carbon black aggregate used in Example 21, the prevention of environmental pollution is not appropriate. The results are shown in Table 5. Table 5 Dispersion index of power consumption due to heat accumulation (D environmental pollution 塾 _%) _ Example 2 1 1.39 31.0 99.2 No example comparison 12 1.52 35.0 95.4 Example of severe pollution 13. 1.40 31.4 99.1 Slightly polluted employee consumer cooperative of Central Standards Bureau of Ministry of Economic Affairs Printing From the comparison of Example 21 and Example Comparisons 12 and 13, the effect of using the encapsulated carbon black aggregate to reduce environmental pollution is very obvious, and Example 21 shows high dispersibility, although its bulk density is higher than that of Example Comparison 12. The fact that cracked carbon black aggregates improve the dispersibility Examples 2 2 and 2 3 compared with the examples 1 4 and 15 show that by making the encapsulated carbon black aggregates crack in advance, not only can prevent environmental pollution, but also have high Dispersibility. This paper size applies to China National Standard (CNS) A4 (210X297 mm) • 77- 510915 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (75) Example 2 2 (1) Preparation of carbon black set 0.5 kg of carbon black "MA7" manufactured by Mitsubishi Chemical Corporation (particle size: 24 nm, DBP oil absorption: 65 ml / 100 g of carbon black, bulk density: 0.190 g / cm3) A carbon steel mold (internal size: 150 mm x 150 mm, height: 350 mm) made by Yuken Κ · Κ ·, and a hydraulic press made by YukaiT KK.K. The carbon black aggregate was obtained by compression molding under pressure, and the density of the obtained aggregate was measured and found to be 0.598 g / cm3. From this aggregate, it was cut into eight pieces of 30 g. (2) Preparation of heat-shrinkable encapsulation From the carbon black aggregate described above, a Universal Sealer (model: "T-600") manufactured by Kyowa Kikai K.K. was added, and ethyl acetate manufactured by Mitsubishi Chemical Corporation was added thereto. Ethyl acetate copolymer (henceforth referred to as EVA) (model: LV540, vinyl acetate content: 20% by weight) and blow-molded to a thickness of 30 microns, heat-sealed at 180 ° C 2 This carbon black molded product enclosed in an EVA film was placed in a Universal Shrink Tunnel (model NS — 450 ”) manufactured by Kyowa Kikai KK and set at 150 ° C, and the film was thermally contracted for 10 seconds, Encapsulate the remaining 7 pieces in the same way. (Please read the notes on the back first

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 78 510915 A7 B7 五、發明説明（76) (3) 使碳黑集料有裂縫 使八個包封的碳黑集料通過由Kabushiki Kaisha Ishikawa Tekko製造的加壓滾筒，沒有觀察到EVA袋子 的損壞或破裂，雖然外觀有部份破壞但仍保持封閉的形式 〇 (4) 測量油墨的最初分散性 根據實例1 (4)的相同方法，但是將” REDUCTUS #220 ” 改成 No· 6 Solvent ( Nisseki 製造）， 並將溶劑加熱至7 0°C,用上述碳黑集料（3 0克/集料 )之四個集料進行測量，油墨之網殘留爲3 · 6重量％。 (5 )觀察環境污染 在均勻混合機的旋轉過程中，沒有觀察到碳黑之散落 ，且沒有發生環境污染。 經濟部中央標準局員工消費合作社印装 (6 )測量碳黑的大小 爲了確定裂縫之***，將剩下四個集料之袋子打開， 測量平均粒子大小並發現爲1 7 · 3毫米。 實例2 3 根據實例2 2的相同方法製備有裂縫的碳黑集料，但 是使用Fuji Air Tools製造的連接至削片軟木塞空氣鎚之振 本紙張尺度適用中國國家標準（CNS ) A4規格（ 210X297公釐） •79- 510915 經濟部中央標隼局食工消費合作社印装 A7 _____B7 ___五、發明説明（77) 動板1 5公分X 1 5公分代替實例2 2的加壓滾筒，使其 與包封的碳黑集料接觸10秒而產生裂縫，袋子沒有破裂 ，且沒有改變外觀，根據實例2 2的相同方法製備樣品， 並測量網殘留及粒子大小，油墨的網殘留爲2·5重量％ ，而且在油墨的製備過程中，沒有觀察到環境污染，平均 粒子大小爲11.2毫米。 實例比較1 4 根據實例22的相同方法測量油墨的網殘留，但是使 用包封在EVA膜製成的袋子內的粉狀碳黑” MA 7”，結 果是，網殘留爲4.0重量％，而且在測量油墨的網殘留 時，EVA膜破裂，一部分碳黑散落並汙染環境。 實例比較1 5 根據實例2 2的相同方法測量油墨的網殘留，但是沒 有使碳黑產生裂縫，沒有觀察到環境污染，但是網殘留高 於實例22及23。 如實例2 2及2 3與實例比較1 4及1 5所顯示，經 由預先使碳黑集料有裂縫可得到更高的分散性。 不同的包封方法 實例24至29經由不同的套封或包封方法，與實例 比較16至20進行比較，說明防止環境污染之效應，爲 了確定效應，將實例比較1 9與實例2 1比較，且實例比 (請先閲讀背面之注意事項This paper size is in accordance with China National Standard (CNS) A4 (210X297 mm) 78 510915 A7 B7 V. Description of the invention (76) (3) Make the carbon black aggregate cracks and allow eight encapsulated carbon black aggregates to pass through. Kabushiki Kaisha Ishikawa Tekko's pressurized roller, no damage or cracking of the EVA bag was observed, and although the appearance was partially damaged, it remained in a closed form. (4) The initial dispersion of the ink was measured according to the same as in Example 1 (4) Method, but changing "REDUCTUS # 220" to No. 6 Solvent (manufactured by Nisseki), and heating the solvent to 70 ° C, using the four aggregates of the carbon black aggregate (30 g / aggregate) The net residue of the ink was measured to be 3.6% by weight. (5) Observation of environmental pollution During the rotation of the homomixer, no scattering of carbon black was observed, and no environmental pollution occurred. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (6) Measuring the size of carbon black In order to determine the cracking of the cracks, the remaining four aggregate bags were opened, the average particle size was measured and found to be 17 · 3 mm. Example 2 3 A cracked carbon black aggregate was prepared according to the same method as in Example 2 2 except that the vibration of the paper hammer connected to the chipped cork air hammer manufactured by Fuji Air Tools was adapted to the Chinese National Standard (CNS) A4 specification (210X297). (Mm) • 79- 510915 Printed by the Food and Beverage Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 _____B7 ___ V. Description of the invention (77) Moving plate 1 5 cm X 1 5 cm instead of the pressure roller of Example 2 2 After contacting the encapsulated carbon black aggregate for 10 seconds, cracks occurred, and the bag did not break, and the appearance was not changed. Samples were prepared according to the same method as in Example 22, and the net residue and particle size were measured. % By weight, and no environmental pollution was observed during the preparation of the ink, with an average particle size of 11.2 mm. Comparative Example 1 4 The net residue of the ink was measured according to the same method as in Example 22, but using a powdery carbon black “MA 7” enclosed in a bag made of an EVA film. As a result, the net residue was 4.0% by weight, and When measuring the net residue of the ink, the EVA film was cracked, and a part of the carbon black was scattered and polluted the environment. Comparative Example 15 The net residue of the ink was measured according to the same method as in Example 22, but no carbon black was cracked, no environmental pollution was observed, but the net residue was higher than that of Examples 22 and 23. As shown in Examples 2 2 and 2 3 and Examples 14 and 15 in comparison, higher dispersibility can be obtained by cracking the carbon black aggregate in advance. Examples 24 to 29 of different encapsulation methods are compared with example comparisons 16 to 20 through different encapsulation or encapsulation methods, illustrating the effect of preventing environmental pollution. To determine the effect, compare example comparison 19 with example 21, And examples than (Please read the precautions on the back first

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本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •80- 510915 A7 B7 五、發明説明（78) 較2 0與實例1 9比較。 實例2 4 (1 )製備碳黑集料 根據實例19的相同方法製備碳黑集料，（品牌： #45,模塑產物之密度：〇·761克/立方公分）' (2 )製備包封 將上述碳黑集料放在Kohoku Seiko K.K.製造之外包封 紙包封機上（型號：KW201),其中裝上Nichigo Film Κ·Κ·製造厚度爲3 0微米並浮凸處理的聚乙烯基醇膜（“ Hyceron Η”），進行包封，至於包封的方法係使用焦糖包 封法，模的結合是使用Nippon Gosei K.K.製造的聚乙烯基 醇黏著劑進行❶ (3 )結果 用聚乙烯基醇膜包封碳黑集料，使其與外部緊密接觸 並保持其形狀，碳黑不會從袋子漏出，沒有發生環境污染 實例2 5 (1 )製備碳黑集料 根據實例2 4的相同方法製備碳黑集料。 本紙張尺度適用中國國家標準（CNS ) A4規格&lt;2丨0X297公釐） (請先閲讀背面之注意事項This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) • 80- 510915 A7 B7 V. Description of the invention (78) Compare 20 with Example 19. Example 2 4 (1) Preparation of carbon black aggregate A carbon black aggregate was prepared according to the same method as in Example 19, (brand: # 45, density of the molded product: 0.7761 g / cm3) '(2) Preparation of encapsulation The above carbon black aggregate was placed on an outer wrapping paper encapsulation machine (model: KW201) manufactured by Kohoku Seiko KK, with Nichigo Film KK · K made of 30 micron thick embossed polyvinyl alcohol Film ("Hyceron Η") for encapsulation. As for the encapsulation method, the caramel encapsulation method is used, and the mold is combined with a polyvinyl alcohol adhesive manufactured by Nippon Gosei KK. (3) As a result, polyethylene is used. Alcohol film encapsulates the carbon black aggregate so that it is in close contact with the outside and maintains its shape. The carbon black does not leak out of the bag and no environmental pollution occurs. Example 2 5 (1) Preparation of carbon black aggregate is the same as in Example 2 4 Method to prepare carbon black aggregate. This paper size applies to China National Standard (CNS) A4 specifications &lt; 2 丨 0X297 mm) (Please read the precautions on the back first

經濟部中央標準局員工消费合作社印製 本頁)(Printed by Staff Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs)

510915 A7 ___B7 五、發明説明（79) (2 )製備枕型包封 將上述碳黑集料放在Kyowa Kikai Κ·Κ·製造之Universal Sealer 上（型號·· βΤ — 6 0 0 &quot;),其中裝上 Nichigo Film Κ·Κ·製造厚度爲3 0微米並浮凸處理的聚乙烯基醇膜 (μ Hyceron Η”），在18 0t下2秒將三個邊熱封·進行 碳黑集料的枕型包封。 (3 )結果 用聚乙烯基醇膜包封碳黑集料，使其與外部緊密接觸 並保持其形狀，碳黑不會從袋子漏出，沒有發生環境污染 (請先閱讀背面之注意事項510915 A7 ___B7 V. Description of the invention (79) (2) Preparation of pillow-type encapsulation The carbon black aggregate is placed on a Universal Sealer (model · · βΤ — 6 0 0 &quot;) made by Kyowa Kikai KK · K, It was installed with Nichigo Film K · K ·, a 30-micron-thick embossed polyvinyl alcohol film (μ Hyceron on), and heat-sealed the three sides at 180 ° t for 2 seconds. (3) As a result, the carbon black aggregate was encapsulated with a polyvinyl alcohol film to make it in close contact with the outside and maintain its shape. Carbon black would not leak out of the bag and no environmental pollution occurred (please read first Notes on the back

本頁) -訂 實例2 6 (1 )製備碳黑集料 根據實例5的相同方法製備碳黑集料。This page)-Order Example 2 6 (1) Preparation of carbon black aggregate A carbon black aggregate was prepared according to the same method as in Example 5.

(2)製備熱收縮包封 經濟部中央標率局員工消費合作社印装 從上述碳黑集料切割出114克的碳黑集料，放在 Kyowa Kikai Κ·Κ·製造之 Universal Sealer 上（型號：“T 一 6 0 0 ”），其中裝上 Mitsubishi Chemical Corporation 製 造的乙烯醋酸乙醯酯共聚物（“EVA”）（產品編號： LV440,醋酸乙烯酯含量：15重量％),厚度爲 3 0微米並用吹塑法製備，在1 8 0°C下熱密封2秒，將 包封在“ E V A ”膜內的碳黑集料放入由Kyowa Kikai K.K. •本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） • 82- 510915 A7 B7 五、發明説明（8〇) 製造且設定在1 5 的之Universal Shrink Tunnel (型號 :” NS-450” ），使膜熱收縮10秒，碳黑不會從 袋子漏出，沒有發生環境污染。 (3 )製備油墨 根據實例5的相同方法製備油墨，但是用上述碳黑集 料作爲碳黑使用，在油墨的製備過程中，沒有發現碳黑飛 揚或環境污染。 (4)用三輥軋製機評估分散性 用實例1敘述的方法評估分散性，結果是，第一次測 量結果的最大粒子大小爲18微米，第二次測量結果爲 15微米，且第三次測量結果爲7微米。 實例2 7 (1)製備碳黑集料 根據實例5的相同方法製備碳黑集料。 經濟部中央標隼局員工消費合作社印装 (2 )塗覆 將2 0 0克由Harima Kasei Κ·Κ·製造的松香樹脂（商 標：” Hartol R — X ”，軟化點：7 9 t )放入容量爲 5 0 0毫升的不銹鋼燒杯中，將此燒杯浸漬在由BUCHI K. K.製造且設定在1 6 0t的的油鍋（型號：“4 7 1 ”）使 松香樹脂熔化。 本紙張尺度適用中國國家標準（CNS &gt; A4規格（210X297公釐) ~ 一 510915 A7 B7 五、發明説明（81 ) 從上述碳黑集料切割出114克塊狀形式的碳黑集料 ，並用刷子塗上熔化的松香樹脂，用手觸摸表面塗上松香 樹脂的碳黑集料，手上沒有沾染碳黑。 (3 )製備油墨 根據實例5的相同方法製備油墨，在油墨的製備過程 中，沒有發現碳黑飛揚或環境污染。 (4)用三輥軋製機評估分散性 用實例1敘述的方法評估分散性，結果是，第一次測 量結果的最大粒子大小爲19微米，第二次測量結果爲 14微米，且第三次測量結果爲7微米。 實例2 8 (1 )製備碳黑集料 經濟部中央標隼局負工消費合作社印装 將 2 公斤由 Mitsubishi Chemical Corporation 製造的碳 黑”#2650”（粒子大小：13毫微米，DBP油吸收 :73毫升/100克碳黑，鬆密度：0·077克/立 方公分）放入由Yuken K.K.製造的碳鋼模具中（內部大小 :350毫米X350毫米，高度：500毫米），並裝 設由Yuken K.K.製造的2 0噸水壓機，施加2 · 0 k g f /平方公分的壓力進行壓塑而得到碳黑集料，測量 所得集料之密度並發現爲0 · 2 6 6克/立方公分。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） •84· 510915 A7 __________ B7_________ 五、發明説明（82) (2 )塗覆 將2 0 0克由Hadma Kasei Κ·Κ.製造的松香樹脂（商 標：” Hartol R — X”，軟化點：79乞）放入容量爲 5 0 〇毫升的不銹鋼燒杯中，將此燒杯浸漬在由BUCHI K. K·製造且設定在1 60 t的的油鍋（型號：^47 1”）使 多爾松香熔化。 從上述碳黑集料切割出3克的碳黑集料，並用刷子塗 上熔化的多爾松香樹脂，用手觸摸表面塗上松香樹脂的碳 黑集料，手上沒有沾染碳黑。 (3 )製備塗料 將9 0克由Tokyo Glass K.K.製造且直徑爲2 · 5至 3 · 5毫米之玻璃珠添加至14 0毫升的低溫瓶中，然後 將1 6克由Kansai Paint K.K.製造的蜜胺醇酸樹脂淸漆（ Amylak 1026 )、10 克由 Kansai Paint Κ·Κ·製造的 Amylak Thinner、及上述碳黑集料添加至低溫瓶中。 經濟部中央標準局員工消费合作社印裝 將此低溫瓶放在由Red Devil Co.製造的單一型塗料搖 動器內（RC — 5000A)並搖動15分鐘，使此黑色 的淸漆冷卻至室溫，大小在0至5 0微米範圍之沒有分散 的塊狀碳黑用 Kabushiki Kaisha Kamishima Seisakusho 製造 的粉碎計（型號：R 1 1 1 0 )測量，粉碎計的測量結果 爲7微米。 而且，將5 0克” Amylak 1026 Clear”放入此低溫瓶 中，隨後經由塗料搖動器混合10分鐘而得到黑色塗料。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X29*7公釐）~ •85- 510915 A7 _______B7 _____ 五、發明説明（83) (4)評估黑色 取樣一部分的黑色塗料（約1立方公分）並放在由 Fuji Film Co·, Ltd.製造的 PET 膜上（Trancee G，厚度 ·· 180微米），並用由Toyo Seiki K.K.製造的桿塗料器 (No · 24)拉伸，使此 PET 膜在由 Ikeda Rika Κ·Κ· 製造並設定在1 2 0°C的空氣循環乾燥器中（Automatic Drying Oven SS — 200N)烘烤 20 分鐘，經由 Nippon Densh’oku Κ·Κ·製造的色差計（Spectro Colo】· Meter SE — 2000)測量如此烘烤的黑色塗膜之L値· L値 爲 4 · 2 3 〇 在塗料的製備過程中，沒有發現碳黑飛揚或環境污染 實例2 9 (1 )製備碳黑集料 根據實例2 6的相同方法製備碳黑集料。 (2 )製備熱收縮包封 從上述碳黑集料切割出3克的碳黑集料，放在Kyowa Kikai Κ·Κ·製造之 Universal Sealer上（型號·· “ T 一 6 0 0 ” ),其中裝上厚度爲16微米且雙軸拉伸的聚乙烯膜，在 1 8 0°C下熱密封2秒，將包封在聚乙烯膜內的碳黑集料 放入由Kyowa Kikai K.K.製造且設定在1 5 0°C的之 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項(2) Preparation of heat-shrinkable encapsulation. The consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed 114 grams of carbon black aggregate cut from the carbon black aggregate and placed it on the Universal Sealer (model number manufactured by Kyowa Kikai KK). : "T-6 0 0"), which is filled with ethylene ethyl acetate copolymer ("EVA") manufactured by Mitsubishi Chemical Corporation (product number: LV440, vinyl acetate content: 15% by weight), and the thickness is 30 The micron is prepared by blow molding, heat-sealed at 180 ° C for 2 seconds, and the carbon black aggregate encapsulated in the "EVA" film is put into Kyowa Kikai KK. • This paper size is applicable to Chinese National Standards (CNS) A4 specification (210X297 mm) • 82- 510915 A7 B7 V. Description of the invention (80) Universal Shrink Tunnel (model: "NS-450") manufactured and set at 1 to make the film heat shrink for 10 seconds, carbon Black does not leak out of the bag and no environmental pollution occurs. (3) Preparation of ink An ink was prepared according to the same method as in Example 5, but using the above carbon black aggregate as the carbon black, no carbon black flying or environmental pollution was found during the preparation of the ink. (4) Evaluation of dispersibility using a three-roll rolling mill The dispersibility was evaluated by the method described in Example 1. As a result, the maximum particle size of the first measurement result was 18 microns, the second measurement result was 15 microns, and the third The measurement results were 7 microns. Example 2 7 (1) Preparation of carbon black aggregate A carbon black aggregate was prepared according to the same method as in Example 5. Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs (2) Coat 200 grams of rosin resin (trademark: "Hartol R — X", softening point: 7 9 t) manufactured by Harima Kasei KK Into a stainless steel beaker with a capacity of 500 ml, this beaker was immersed in an oil pan (model: "4 7 1") manufactured by BUCHI KK and set at 160 t to melt the rosin resin. This paper size applies to Chinese national standards (CNS &gt; A4 size (210X297 mm) ~ 510915 A7 B7 V. Description of the invention (81) 114 g of carbon black aggregate in block form is cut from the above carbon black aggregate and used together The brush was coated with molten rosin resin, and the carbon black aggregate coated with rosin resin was touched on the surface by hand, and the carbon black was not contaminated on the hand. (3) Preparation of ink The ink was prepared according to the same method as in Example 5. No flying carbon black or environmental pollution was found. (4) Evaluation of dispersibility using a three-roll rolling mill The dispersibility was evaluated by the method described in Example 1. As a result, the maximum particle size of the first measurement was 19 microns, and the second time The measurement result was 14 micrometers, and the third measurement result was 7 micrometers. Example 2 8 (1) Preparation of Carbon Black Aggregate The Ministry of Economic Affairs, Central Standards Bureau, Negative Work Consumer Cooperative, printed 2 kg of carbon black manufactured by Mitsubishi Chemical Corporation "# 2650" (particle size: 13 nm, DBP oil absorption: 73 ml / 100 g carbon black, bulk density: 0.077 g / cm3) was placed in a carbon steel mold made by Yuken KK (internal size: 3 50 mm X 350 mm, height: 500 mm), and a 20-ton hydraulic press manufactured by Yuken KK was installed to apply compression at a pressure of 2.0 kgf / cm² to obtain a carbon black aggregate, and the density of the obtained aggregate was measured. It was found to be 0 · 26 6g / cm3. This paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm) • 84 · 510915 A7 __________ B7_________ 5. Description of the invention (82) (2) 2000 grams of rosin resin (trademark: “Hartol R — X”, softening point: 79 μg) manufactured by Hadma Kasei KK · K. Was put into a stainless steel beaker with a capacity of 500 ml, and the beaker was immersed in An oil pan (model: ^ 47 1 ”) manufactured by BUCHI K.K. and set at 1 60 t melts the dol rosin. From the above carbon black aggregate, 3 g of the carbon black aggregate is cut and applied with a brush. Melted Dole Rosin Resin, the carbon black aggregate coated with rosin resin on the surface is touched by hand, and the carbon black is not contaminated on the hand. (3) Preparation of coating 90 grams of Tokyo Glass KK made with a diameter of 2.5 to 3 · 5 mm glass beads are added to a 140 ml cryogenic bottle, After 16 g of a melamine alkyd paint Qing manufactured by Kansai Paint K.K. of (Amylak 1026), 10 g of added by Amylak Thinner, and said carbon black aggregate Kansai Paint Κ · Κ · manufactured to cryovial. The Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs printed this cold bottle in a single paint shaker (RC — 5000A) manufactured by Red Devil Co. and shaken for 15 minutes to cool the black paint to room temperature. The non-dispersed bulk carbon black having a size in the range of 0 to 50 micrometers was measured with a pulverizer (model: R 1 1 1 0) manufactured by Kabushiki Kaisha Kamishima Seisakusho. The measurement result of the pulverizer was 7 micrometers. Furthermore, 50 g of "Amylak 1026 Clear" was put into this cryogenic bottle, and then mixed through a paint shaker for 10 minutes to obtain a black paint. This paper size is in accordance with Chinese National Standard (CNS) A4 (210X29 * 7mm) ~ • 85- 510915 A7 _______B7 _____ V. Description of the invention (83) (4) Evaluate the black paint for the black sample (about 1 cubic centimeter) And placed on a PET film (Trancee G, 180 mm in thickness) made by Fuji Film Co., Ltd. and stretched with a rod applicator (No. 24) made by Toyo Seiki KK, so that this PET film was Manufactured by Ikeda Rika K · K · and set in an air circulation dryer (Automatic Drying Oven SS — 200N) at 120 ° C for 20 minutes and passed through a Nippon Densh'oku K · K · color difference meter (Spectro Colo] · Meter SE — 2000) Measured the L 値 · L 値 of the black coating film thus baked to 4 · 2 3 〇 No carbon black flying or environmental pollution was found during the preparation of the coating. Example 2 9 (1) Preparation Carbon black aggregate A carbon black aggregate was prepared according to the same method as in Example 26. (2) Preparation of heat-shrinkable encapsulation 3 g of carbon black aggregate cut from the above carbon black aggregate and placed on a Universal Sealer (model "· T-6 0 0") manufactured by Kyowa Kikai KK · K, A 16-micron-thick biaxially stretched polyethylene film was mounted thereon, and heat-sealed at 180 ° C for 2 seconds. The carbon black aggregate encapsulated in the polyethylene film was put into a product made by Kyowa Kikai KK and The paper size set at 150 ° C applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back first

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經濟部中央標準局貝工消費合作社印裝 -86 - 510915 A7 £7____ 五、發明説明（84)Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs -86-510915 A7 £ 7 ____ 5. Description of the Invention (84)

Universal Shrink Tunnel (型號：”NS - 450”），使 膜熱收縮1 0秒。 (3 )製備塗料 根據實例25 (3)的相同方法，但是使用上述步驟 (2 )的碳黑集料，測量大小在0至5 0微米範圍之沒有 分散的塊狀碳黑，粉碎計的測量結果爲7微米。 而且，將5 0克” Amylak 1026 Clear”放入此低溫瓶 中，隨後經由塗料搖動器混合10分鐘而得到黑色塗料。 (4 )評估黑色 根據實例17的相同方法進行測量，L値爲4.78 實例比較1 6 進行根據實例2 9的相同操作，但是使用Mitsubishi Chemical Corporation製造的碳黑粉末” ΜΑ 7”代替實例 2 9所使用的碳黑集料，經由粉碎計測量的値爲8 . 0微 米，且黑色塗料的L値爲4.83。 在測量預先決定的量時，碳黑粉末散落並汙染環境。 實例比較1 7 進行根據實例2 6的相同操作，但是使用沒有包封的 碳黑集料。 本紙張尺度適用中國國家標準（CNS ) Α4規格·（ 210Χ297公釐） (請先閲讀背面之注意事項Universal Shrink Tunnel (model: "NS-450"), which heat shrinks the film for 10 seconds. (3) Preparation of coatings According to the same method as in Example 25 (3), but using the carbon black aggregate of the above step (2), the non-dispersed lumped carbon black with a size in the range of 0 to 50 micrometers was measured, and the pulverizer measurement The result was 7 microns. Furthermore, 50 g of "Amylak 1026 Clear" was put into this cryogenic bottle, and then mixed through a paint shaker for 10 minutes to obtain a black paint. (4) Evaluation of black The measurement was performed according to the same method as in Example 17, and L 値 was 4.78. Example Comparison 16 The same operation as in Example 2 9 was performed, but a carbon black powder "ΜΑ 7" manufactured by Mitsubishi Chemical Corporation was used instead of Example 2 9 The carbon black aggregate used had a 値 measured through a pulverizer of 8.0 microns, and the L 値 of the black paint was 4.83. When a predetermined amount is measured, the carbon black powder is scattered and pollutes the environment. Example comparison 17 The same operation as in Example 2 6 was performed, but an unencapsulated carbon black aggregate was used. This paper size applies to Chinese National Standard (CNS) Α4 specifications · (210 × 297 mm) (Please read the precautions on the back first

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經濟部中央標準局員工消費合作社印裝 -87- 510915 A7 —B7 五、發明説明（85) 結果是，油墨通過三輥軋製機使非分散結塊的大小不 超過10微米所需的次數爲三次，而且非分散結塊的大小 爲7·5微米，與起始的原料粉末比較，使用碳黑集料可 實質上降低飛揚，但是與實例2 6及2 7使用之塗覆的碳 黑集料比較，環境污染的預防並不適宜。 實例比較1 8 進行根據實例2 9的相同操作，但是使用沒有包封的 碳黑集料。· 結果是，製備的塗料之黑色也就是色差計的L値爲 4.25。 與起始的原料粉末比較，使用碳黑集料可實質上降低 飛揚，但是與實例29使用之包封的碳黑集料比較，環境 污染的預防並不適宜。 實例比較1 9 進行根據實例2 1的相同操作，但是使用沒有包封的 經濟部中央標準局員工消費合作社印裝 碳黑集料。 結果是，在60 °C的功耗因數爲0 . 141,熱積聚 爲3 1 . 2°C且D%爲99 . 1%,與起始的原料粉末比 較，使用碳黑集料可實質上降低飛揚，但是與實例21使 用之包封的碳黑集料比較，環境污染的預防並不適宜。 實例比較2 0 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -88 - 510915 I ^ , s A7 1 丨___B7___ 五、發明説明（2 ) 中將水溶性聚合物添加至色料中而得到稠漿並將此稠漿噴 霧乾燥，但是這些方法含有缺點，其處理成本高且很難在 工業上大量進行處理，而且，防止散落或飛揚的效應不佳 另外，JP — A - 2 — 142858 或 JP — A - 3 —1 9 3 3 1 2 9揭示經由碾壓機之碳黑壓縮一粒化作用 而有起始分散性經改進之碳黑，但是，使用時的飛揚沒有 足夠地改進，而且高鬆密度之改進也不恰當。Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-87- 510915 A7 —B7 V. Description of the invention (85) As a result, the number of times that the ink needs to pass through the three-roll rolling mill to make the size of the non-dispersed agglomerates not more than 10 microns is Three times, and the size of the non-dispersed agglomerates is 7.5 micrometers. Compared with the original raw material powder, the use of carbon black aggregates can substantially reduce flying, but the coated carbon black aggregates used in Examples 2 6 and 27 It is not suitable to prevent environmental pollution. Example comparison 18 The same operation as in Example 2 9 was performed, but an unencapsulated carbon black aggregate was used. · As a result, the black of the prepared paint, that is, the L 値 of the colorimeter was 4.25. Compared with the starting raw material powder, the use of carbon black aggregates can substantially reduce flying, but compared with the encapsulated carbon black aggregates used in Example 29, the prevention of environmental pollution is not appropriate. Example comparison 19 The same operation as in Example 21 was performed, but the carbon black aggregate was printed using an unencapsulated Ministry of Economic Affairs Central Standard Bureau employee consumer cooperative. The result is a power consumption factor of 0.141 at 60 ° C, a thermal buildup of 3 1.2 ° C, and a D% of 99.1%. Compared with the starting raw material powder, the use of carbon black aggregates can substantially Fly is reduced, but environmental pollution prevention is not appropriate compared to the encapsulated carbon black aggregate used in Example 21. Comparison of Examples 2 0 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -88-510915 I ^, s A7 1 丨 ___B7___ 5. In the description of the invention (2), add water-soluble polymer to the color The thick slurry is obtained from the material and the thick slurry is spray-dried. However, these methods have disadvantages, their processing cost is high and it is difficult to handle a large amount in the industry, and the effect of preventing scattering or flying is not good. In addition, JP — A- 2 — 142858 or JP — A-3 — 1 9 3 3 1 2 9 reveals that the carbon black is compressed and pelletized by a compactor to improve the initial dispersibility of the carbon black, but the flying when used is not enough Improvement, and the improvement of high bulk density is not appropriate.

J P — A (請先閱讀背面之注意事項再填寫本頁) 6 — 1 2 2 1 1 1揭示將碳黑粉末塡入密 閉的模製容器中，將容器內的壓力降低後，使容器內的壓 力恢復至大氣壓力而使碳黑有特定之形狀，但是經由減壓 而可運用之壓力最大不會超過1大氣壓力，因此碳黑的模 製產物非常軟，模製產物的邊緣很容易破碎，或模製產物 在運送或儲存時很容易粉碎，因此，這種方法並不適用於 工業化操作。 部 中 A i?. )] .T 消 fr 合 鑑於上述之問題，本案發明者進行深入的硏究並發現 將碳黑形成具有某種特定硬度之碳黑集料或將碳黑形成一 種集料其中表面的硬度與內部的硬度有特定的關係，可以 抑制粉碎，且令人訝異地，可進一步改進其在媒劑中的分 散性，並將產物製成適於使用，而且還發現將此碳黑集料 包封後，可以完全防止使用時的環境污染，本發明係基於 這些發現，也就是說，本發明係基於表面硬度至少爲70 克的碳黑集料或類似物等。 爲何本發明之碳黑集料具有適當的硬度並能防止飛揚 本纸ίΜΙ度適扣屮^國家標丰（CNS ) Λ4規格（210 X 297公浚） -5 - 510915 I A7 ;..U.__ 一 B7 五、發明説明（6 ) 境污染，即使是集料具有所述之硬度。 集料之形狀並沒有特別的限制且可爲視需要之形狀， 例如平行四邊體、立方體、圓柱體、或球體形，決定於特 定之目的及使用的特定模具。 *此碳黑集料可能有孔洞及/或凹洞，在此，孔洞的大 小及形狀沒有特別的限制，且可根據特定目的而適當地選 擇，具體地說，例如基於將多個碳黑集料連接之目的，將 連接介質例如線、繩索或鏈穿過各集料之孔洞，以便在運 送或儲存時防止堆積的集料碰撞時，孔洞必須是可讓連接 介質從其中穿過，反之，基於容易分解集料並使其分散在 供例如油墨或塗料的媒劑之目的而形成的孔洞，此種孔洞 適宜相當大，反之，經由形成孔洞或凹洞，可促進碳黑集 料之重量調整，在此情形下，可經由管狀刀片之穿孔設備 形成孔洞，使得可從管狀刀片之截面積輕易地測定作爲孔 洞移除之碳黑量，據此，經由形成所需數目之孔洞，可以 輕易地進行微細調整碳黑之量.。 凹洞的大小及形狀同樣也沒有特定的限制，凹洞只要 其可形成凹痕就可被接受，例如，可在碳黑及量上有效地 形成凹面或凸面，使得一集料之凹面可吻合另一集料之凸 面，所以當大量集料堆積時，可以有效地防止堆積集料之 碰撞，經由提供不同的凹面或凸面，其可用於辨認碳黑型 態之方法。 提供此種孔洞或凹面之方法沒有特定之限制，例如某 種特定形狀之碳黑集料可用例如切刀彫刻，或當模製集料 本纸張尺度適州屮闽國家標枣（CNS ) Λ4規格（2丨OX2()7公漦） -9 - (請先閱讀背面之注意事項再填寫本頁)JP — A (Please read the precautions on the back before filling out this page) 6 — 1 2 2 1 1 1 Reveals that carbon black powder is poured into a closed molding container, and the pressure in the container is reduced. The pressure is restored to atmospheric pressure so that the carbon black has a specific shape, but the pressure that can be applied through decompression will not exceed a maximum of 1 atmospheric pressure. Therefore, the molded product of carbon black is very soft, and the edges of the molded product are easily broken. Or, the molded product is easily pulverized during transportation or storage, so this method is not suitable for industrial operation. In view of the above problems, the inventors of this case conducted in-depth research and found that carbon black is formed into a carbon black aggregate with a certain hardness or carbon black is formed into an aggregate. Among them, the hardness of the surface has a specific relationship with the hardness of the interior, which can suppress pulverization, and surprisingly, it can further improve its dispersibility in the vehicle and make the product suitable for use. After the carbon black aggregate is encapsulated, environmental pollution during use can be completely prevented. The present invention is based on these findings, that is, the present invention is based on a carbon black aggregate or the like having a surface hardness of at least 70 g. Why does the carbon black aggregate of the present invention have appropriate hardness and can prevent flying of the paper? The national standard (CNS) Λ4 specification (210 X 297 public dredging) -5-510915 I A7; .. U. __ 一 B7 V. Description of the Invention (6) Environmental pollution, even if the aggregate has the stated hardness. The shape of the aggregate is not particularly limited and can be as desired, such as a parallelogram, cube, cylinder, or sphere, depending on the specific purpose and the specific mold used. * This carbon black aggregate may have pores and / or recesses. Here, the size and shape of the pores are not particularly limited, and may be appropriately selected according to the specific purpose. Specifically, for example, based on collecting a plurality of carbon blacks. The purpose of material connection is to pass a connection medium such as a wire, rope or chain through the holes of each aggregate, in order to prevent the stacked aggregates from colliding during transportation or storage, the holes must allow the connection medium to pass through, and vice versa, The pores formed based on the purpose of easily decomposing the aggregate and dispersing it in a medium such as ink or coating, such pores are suitable to be quite large. Conversely, the formation of pores or recesses can promote the weight adjustment of the carbon black aggregate In this case, holes can be formed through the perforating equipment of the tubular blade, so that the amount of carbon black removed as a hole can be easily determined from the cross-sectional area of the tubular blade, and accordingly, by forming the required number of holes, it is possible to easily Finely adjust the amount of carbon black. The size and shape of the pits are also not limited. The pits are acceptable as long as they can form dents. For example, it can effectively form a concave or convex surface in carbon black and volume, so that the concave surface of an aggregate can match The convex surface of another aggregate, so when a large number of aggregates are stacked, it can effectively prevent the collision of the stacked aggregates. By providing different concave or convex surfaces, it can be used to identify the type of carbon black. There are no specific restrictions on the method of providing such holes or concave surfaces. For example, a carbon black aggregate of a specific shape can be engraved with a knife, for example, or when the aggregate is molded. Specifications (2 丨 OX2 () 7mm) -9-(Please read the precautions on the back before filling this page)

510915 I D，. A7 B7 五、發明説明（8 ) (讀先閱讀背面之注意事項再填寫本頁) 量通常最多是5重量％，較宜最多是3重量％，此添加的 時間沒有特定的限制，但是例如當將碳黑粉加入模具時， 隨後經由壓製，在上述的方法下，如果集料中摻混此類添 加劑，進行壓製時，操作方法很簡單。 碳黑集料之密度（也就是將集料之重量除以集料之體 積所得的値）沒有特定的限制，但是，密度σ (克/立方公 分）特別適宜在下列範圍內： 至少 a = 8.190xl0'3D-3.8 24xl0*3L + 0.516 且最大 σ = 3.265x1 0*3D-3.334xl0'3L+1.173 更宜至少 a = 8.6 8 6xl0*3D-4.031xl0*3L + 0.5 43 且最大 σ = 3. 123x10'3D-3. 18 9x10'3L+1.07 2 在此範圍內，此集料有極佳的處理效率，且在製備油 墨、塗料等時有極佳的分散性，且所得的塗料、油墨等的 黑色特佳。 在各上述公式中，D爲碳黑在電子顯微鏡下之算術平 均粒子大小（毫微米），也就是說用下列方法所得的値。 換句話說，將碳黑放入氯仿中並施加2 0 0 KHz 的超音波2 0分鐘使其分散，然後將分散的樣品放在支架 膜上，用穿透式電子顯微鏡照相此膜，經由在相片上的直 徑及照相的倍數計算粒子大小，此操作重複進行約 家標枣(CNS ) Λ4 規格（210X297 公漦) -11 - 510915 A7 B7 五、發明説明（9 ) 1，5 0 0次，取這些値的算術平均値作爲粒子大小。 (請先閱讀背面之注意事項再填寫本頁) L爲D B P油吸收（毫升/ 1 〇 〇克），根據j j s K 6 2 2 1 — 1 9 8 2的方法測量。 有裂縫形成之碳黑集料 在本發明中，特別適宜在上述集料中有裂縫形成，因 此可增進集料與分散介質之接觸面積，促進液體成份在粉 末中的穿透及均勻分佈，當製備不同顏色的組成物時，例 如當粉末成份分散在液體介質，例如用於製備油墨或塗料 之液體淸漆或熔化的橡膠樹脂.時，咸信可得到本發明之效 應，換句話說，咸信液體成份將從在集料上形成的裂縫穿 透，或雖然集料在包封下有數種形狀，當放入液體成份時 ，封套將裂開或與液體成份混合，且內容物也就是集料將 分解並分散，於是可改進分散性。 裂縫的程度可用下列測量方法測量粒子的大小而定義 ，換句話說，根據J IS K— 6221，將100克有 裂縫形成之模製粉末產物放在直徑爲2 0 0毫米之篩網上 ，並搖動1分鐘，經由搖動機器施加衝擊，結果在Rosin-Rammlar圖上作圖，以平均直徑作爲平均粒子大小。 如此測量的平均粒子大小較宜爲0 . 1至5 0毫米， 更宜爲0 · 2至3 0毫米，如果平均粒子大小低於〇 · 1 毫米，將容易喪失模製時防止飛揚之效應，因此很容易產 生飛揚，反之，如果平均粒子大小高於5 0毫米，液體成 份例如淸漆或熔化的聚合物穿透至集料的中心部位需要很 木紙认尺度这州屮1¾國家標率（CNS ) /\4規格（210X297公釐） -12 - 510915 A7 B7 五、發明説明（1〇) 長的時間，因此很難得到高的分散性，從上述測量裂縫程 度的方法，明顯地知道本發明之裂縫不只包括其中在封套 的情形，存在的集料完全分成數份，還包括其中所謂的，，裂 縫”存在單一的連續體上，因此其相當於可用上述測量方法 將集料分成多個粒子之裂縫。 在本發明中，裂縫之施加方法沒有特別的限制，可以 使用例如施加震動在集料上的方法、壓製集料而形成裂縫 的方法、彎曲集料而形成裂縫的方法。 f請先閱讀背面之注意事項再填寫本頁j 衣. 'ή\ 部 I ' _了 ·;/] 包封 在本發明中，將上述碳黑集料包封，包封的材料沒有 特別的限制，只要其可將碳黑集料包封，但是，較宜使用 即使其溶解或混合在與集料或所要產物爲含碳黑之組成物 例如油墨、塗料、樹脂或橡膠混合的溶劑中時也不會產生 任何問題之成份，選擇此類物質時，可在不將封套去除下 將包封的集料與其他成份混合，製備含碳黑的組成物，因 此可完全抑制飛揚的產生，在此”包封”係指將碳黑集料包妾 而與外界隔離，可實質上防止碳黑的散落或飛揚，其中包 括不僅用一層物質包封，例如包裹、收縮包封或真空包封 ，還包括用塗膜包封，其形成係塗上可形成膜的成份，例 如可固化的液態物質，如樹脂組成物，通常，較宜使用由 聚合物例如樹脂製成的樹脂膜，因爲當裂縫施加在集料時 ，其強度及彎曲性可以耐受所施加的力，其在含碳黑的組 成物例如油墨、塗料、樹脂或橡膠中具有溶解性，且容易 丁 、-口 本紙张尺度·適用中网國家標卑（CNS ) Λ4規格（210X297公嫠） .13 - ii 'ή\ 部 屮 Jk il j' -Τ f 510915 . A 7 _______________________B7 五、發明説明（11) 進行包封，例如對於應用在油墨上時，可以使用例如乙烯 /醋酸乙烯酯共聚物（以下稱爲EVA)、乙基纖維素、 酚型樹脂、醇酸樹脂、丙烯酸樹脂、聚醯胺樹脂、或超低 密度的聚乙烯，對於應用在塗料上時，可以使用例如 E V A、聚苯乙烯或超低密度的聚乙烯，在水溶性油 墨或水溶性塗料的領域中，可以使用例如聚乙烯醇或聚環 氧乙烷，對於應用在樹脂上時，可以使用例如聚苯乙烯、 EVA、或聚乙烯，對於應用在橡膠上時，可以使用例如 聚乙烯或EVA,可依據特定之應用而選擇適當的材料。 爲了使用此樹脂作爲包封膜，可摻混預先決定量之添 加物，例如，爲了避免膜本身的結塊，可摻混低於5重量 %的無機塡充劑例如氧化矽或滑石作爲防止結塊劑，或低 於1重量％的滑動劑，低於〇 · 5重量％的抗氧化劑或低 於0 · 1重量％的中和劑，而且根據情形需要可以加入可 溶於油墨、塗料、樹脂或橡膠中的聚合物。 在本發明中，包封的方法沒有特別的限制，可以使用 枕型的包封，例如垂直枕型包封或水平枕型包封，膜包封 例如收縮包封、真空包封、拉·伸包封、表皮包封或折疊包 封，盒子包封例如外包封紙包封、紙盒包封或多份包封， 透明塑料包封或外表包封，而且，可在碳黑集料的表面用 例如噴霧、空氣塗料機、葉片塗料機、桿塗料機、刀片塗 料機或浸漬塗料機的方法形成塗膜，而且此塗膜可作爲包 封使用，較宜在碳黑集料形成後，用一種方法包封使膜與集 料緊密接觸，使得集料與包封例如收縮包封、枕型包封、 (請先閱讀背面之注意事項再填寫本頁)510915 ID, A7 B7 V. Description of the invention (8) (Read the precautions on the back before filling this page) The amount is usually at most 5% by weight, preferably at most 3% by weight. There is no specific limitation on the time of addition. However, for example, when carbon black powder is added to a mold and then pressed, under the method described above, if such additives are blended in the aggregate, the operation method is simple. The density of the carbon black aggregate (that is, 所得 obtained by dividing the weight of the aggregate by the volume of the aggregate) is not particularly limited, but the density σ (g / cm3) is particularly suitable in the following range: at least a = 8.190 xl0'3D-3.8 24xl0 * 3L + 0.516 and maximum σ = 3.265x1 0 * 3D-3.334xl0'3L + 1.173 More preferably at least a = 8.6 8 6xl0 * 3D-4.031xl0 * 3L + 0.5 43 and maximum σ = 3. 123x10'3D-3. 18 9x10'3L + 1.07 2 In this range, this aggregate has excellent processing efficiency, and has excellent dispersibility when preparing inks, coatings, etc., and the resulting coatings, inks, etc. Black is particularly good. In each of the above formulas, D is the arithmetic average particle size (nanometer) of carbon black under an electron microscope, that is, 値 obtained by the following method. In other words, carbon black was placed in chloroform and a 200 KHz ultrasonic wave was applied for 20 minutes to disperse it. Then the dispersed sample was placed on a support film, and the film was photographed with a transmission electron microscope. The diameter on the photo and the multiple of the photo are used to calculate the particle size. This operation is repeated about the standard Chinese date (CNS) Λ4 specification (210X297 gong) -11-510915 A7 B7 V. Description of the invention (9) 1,500 times, Take the arithmetic mean of these 値 as the particle size. (Please read the notes on the back before filling in this page) L is D B P oil absorption (ml / 100 g), measured according to the method of j j s K 6 2 2 1-1 9 8 2. Carbon black aggregate with crack formation In the present invention, it is particularly suitable for the formation of cracks in the aggregate, so it can increase the contact area between the aggregate and the dispersion medium, and promote the penetration and uniform distribution of liquid components in the powder. When the composition of different colors is prepared, for example, when the powder component is dispersed in a liquid medium, such as a liquid varnish or a molten rubber resin used for preparing inks or coatings, the effect of the present invention can be obtained, in other words, salty It is believed that the liquid component will penetrate through the cracks formed on the aggregate, or although the aggregate has several shapes under the encapsulation, when the liquid component is placed, the envelope will crack or mix with the liquid component, and the content is also the aggregate. The material will disintegrate and disperse, thus improving dispersibility. The degree of cracks can be defined by measuring the size of the particles with the following measurement methods. In other words, according to J IS K-6221, 100 grams of cracked molded powder product is placed on a sieve with a diameter of 200 mm, and After shaking for 1 minute and applying an impact via a shaking machine, the results were plotted on a Rosin-Rammlar chart, with the average diameter as the average particle size. The average particle size measured in this way is preferably 0.1 to 50 mm, more preferably 0.2 to 30 mm. If the average particle size is less than 0.1 mm, the effect of preventing flying when molding is easily lost, Therefore, it is easy to produce flying. On the contrary, if the average particle size is greater than 50 mm, the penetration of liquid components such as lacquer or molten polymer to the center of the aggregate requires a very hard paper. This state 屮 1¾ national standard ( CNS) / \ 4 specifications (210X297 mm) -12-510915 A7 B7 V. Description of the invention (10) Long time, so it is difficult to obtain high dispersion. From the above method of measuring the degree of cracks, it is obvious that The cracks of the invention include not only the case where the aggregate is completely divided into several parts, but also the so-called, cracks, which exist on a single continuum, so it is equivalent to using the above measurement method to divide the aggregate into multiple Particle cracks. In the present invention, the method of applying cracks is not particularly limited, and for example, a method of applying vibration to the aggregate, a method of pressing the aggregate to form cracks, and a bending aggregate can be used. Method to form cracks. F Please read the precautions on the back before filling in this page j clothing. 'Ή \ 部 I' _ 了 ·; /] Encapsulated in the present invention, the above carbon black aggregate is encapsulated, The encapsulating material is not particularly limited as long as it can encapsulate the carbon black aggregate, however, it is preferable to use it even if it is dissolved or mixed with the aggregate or the desired product is a carbon black-containing composition such as ink, coating, resin Or rubber mixed solvents will not cause any problems. When selecting such materials, the encapsulated aggregate can be mixed with other ingredients without removing the envelope to prepare a carbon black-containing composition. Completely suppress the occurrence of flying, here "encapsulation" refers to enclosing carbon black aggregate and isolating it from the outside, which can substantially prevent the scattering or flying of carbon black, including not only encapsulating with a layer of material, such as wrapping, shrinking Encapsulation or vacuum encapsulation also includes encapsulation with a coating film, which is formed by coating a film-forming component, such as a curable liquid substance, such as a resin composition. Generally, it is preferable to use a polymer such as a resin. Resin film due to When cracks are applied to the aggregate, its strength and bendability can withstand the applied force. It has solubility in carbon black-containing compositions such as inks, coatings, resins, or rubbers, and is easy to dangle. Dimensions · Applicable to China National Standards (CNS) Λ4 specifications (210X297). 13-ii 'price \ 部 屮 Jk il j' -T f 510915. A 7 _______________________B7 V. Description of the invention (11) Encapsulation, For example, when applied to inks, for example, ethylene / vinyl acetate copolymer (hereinafter referred to as EVA), ethyl cellulose, phenol resin, alkyd resin, acrylic resin, polyamide resin, or ultra-low density can be used. For the application of polyethylene, for example, EVA, polystyrene, or ultra-low density polyethylene can be used. In the field of water-soluble ink or water-soluble coating, for example, polyvinyl alcohol or polyethylene oxide can be used. For applications such as polystyrene, EVA, or polyethylene for resins, for example, polyethylene or EVA can be used for rubber applications, depending on the application When the material. In order to use this resin as an encapsulation film, a predetermined amount of additives can be blended, for example, to avoid agglomeration of the film itself, less than 5% by weight of an inorganic filler such as silica or talc can be blended as an anti-caking agent. Block, or less than 1% by weight of sliding agent, less than 0.5% by weight of antioxidants or less than 0.1% by weight of neutralizers, and can be added to soluble in ink, coatings, resins as needed Or polymers in rubber. In the present invention, the method of encapsulation is not particularly limited, and pillow-type encapsulation can be used, such as vertical pillow-type encapsulation, or horizontal pillow-type encapsulation, and film encapsulation such as shrink encapsulation, vacuum encapsulation, and stretching. Encapsulation, skin encapsulation or folding encapsulation, box encapsulation such as outer paper encapsulation, carton encapsulation or multiple encapsulation, transparent plastic encapsulation or surface encapsulation, and can be used on the surface of carbon black aggregate The coating film is formed by a method such as spray, air coating machine, blade coating machine, rod coating machine, blade coating machine or dip coating machine, and the coating film can be used as an encapsulation. It is more suitable to use after the carbon black aggregate is formed. One method of encapsulation is to bring the film into close contact with the aggregate, making the aggregate and encapsulation such as shrink encapsulation, pillow encapsulation, (please read the precautions on the back before filling this page)

本紙张尺度述川十阄國家標準（CNS ) Λ4規格（210X 297公缝） -14 - 部 又;J 消 f η 510915 ^ Α7 Β7 五、發明説明（13) 可使用不同的物質例如多孔性物質，而且不需要套封整個| 集料的表面，同樣地，不需要使封套與集料緊密貼合，封 套的厚度沒有特別的限制，通常爲5至5 0 0微米，用-層物質套封時，其厚度較宜爲10至50微米，且使用胃 固化的物質套封時，其厚度較宜爲5 0至1 0 〇微米，但 是，厚度並不僅限於此範圍，只要封套可達到所要之目的 即可。 在塗膜之情形下，可將塗料溶解在溶劑或熱熔化物中 ，使得液化的物質可用於塗覆碳黑集料。 決定於特定之目的及工作環境等，包封並不需要密封 且可有適當的形式。 而且，有封套之上述碳黑集料可另外再包封（以下有 時稱爲二次包封），例如，多個包封後的碳黑集料可包在 一起，使得可實質上降低運送成本，或者是，當經由將在 下文中說明之可溶性物質在碳黑集料上形成封套時，如果 此封套沾染泥土或灰塵，且在沒有將此封套去除下將集料 投入混合槽中，所得含碳黑的組成物例如油墨或塗料，將 含有此泥土或灰塵，據此，決定於應用或使用模式，此二 次包封有其效應，此表示二次包封使用之物質沒有特別的 限制，且可使用習知的多種包封方法，具體地說，拉伸包 封例如板式拉伸包封或板式收縮包封、或收縮包封爲典型 之實例。 如上所述將碳黑集料套封後，可防止飛揚造成之環境 污染，此問題在使用碳黑時很容易發生，換句話說，可完 (讀先閱讀背面之注意事項再镇寫本頁) 訂 本纸张尺度述川屮0國家標準（CNS ) Λ4規格（210X 297公釐） -16- 510915 附件A: 第86116063號專利申請案 中文說明書修正頁$國部年4月修正|齑補亦j 五、發明説明（17 ) 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 酸樹脂；可以使用例如纖維素例如鹼纖維素、纖維素酯、 纖維素醋酸酯、纖維素醋酸酯丁酸酯、纖維素黃原酸酯、 纖維素硝酸酯、纖維素醚、羧甲基纖維素、纖維素醚酯、 甲基繊維素、乙基纖維素、乙基經基乙基纖維素、雜某丙 基纖維素、羥基乙基纖維素、再生纖維素、賽璐珞或硝基 纖維素；可以使用例如聚乙烯酯例如聚乙烯醇、聚乙烯肉 桂酸酯、聚乙烯醋酸酯、聚乙烯丙酸酯、聚乙烯硬脂酸酯 、聚乙烯丁酸酯、聚乙烯甲醛或聚乙烯吡略啶酮；可以使 用例如聚乙烯醚例如聚異丁基乙烯醚或聚甲基乙烯醚；可 以使用例如聚硕例如聚***硕或聚硕醯胺；可以使用例如 氟樹脂例如FEP、聚氯三氟乙烯、聚四氟乙烯、聚偏二 氟乙烯或聚氟乙烯；至於聚醯胺，可以使用例如脂族聚醯 胺例如尼龍1 1、尼龍1 2、尼龍6、尼龍6，1 0、尼 龍6，12或尼龍6，6、聚苯二醯對苯二胺、聚醯胺醯 亞胺或聚醯胺；至於胺基樹脂，可以使用例如苯胺樹脂、 脲樹脂、聚砚醯胺或三聚氰胺樹脂；至於烯丙基樹脂，可 以使用例如C R - 3 9或酞酸二烯丙酯；至於酚型樹脂， 可以使用例如酚醛樹脂或偏苯二酚樹脂。 至於其他樹脂，可以使用例如聚烯丙酸酯、聚對苯二 甲酸乙二酯、聚偏二氯乙烯、聚氯乙烯、聚碳酸酯、 A B S樹脂、離子交聯聚合物、氯化聚醚、香豆酮-茚樹 脂、聚苯醚、聚對苯二甲酸丁二酯、聚甲基苯乙烯、聚甲 烯、不飽和的聚酯樹脂、呋喃樹脂、聚硬脂酸乙烯酯、阿 拉伯膠、古巴膠、鄰苯二甲酸二烯丙酯、脲樹脂、三聚氰 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇Χ297公釐）The dimensions of this paper are described in the Sichuan Tenth National Standard (CNS) Λ4 specification (210X 297 cm) -14-Ministry of the Ministry; J f f η 510915 ^ Α7 Β7 V. Description of the invention (13) Different substances such as porous substances can be used Also, the entire surface of the aggregate does not need to be enveloped. Similarly, the envelope and the aggregate do not need to be closely adhered. The thickness of the envelope is not particularly limited, usually 5 to 500 microns. The thickness is preferably 10 to 50 micrometers, and the thickness is preferably 50 to 100 micrometers when the stomach is solidified. However, the thickness is not limited to this range, as long as the envelope can achieve the desired Just the purpose. In the case of a coating film, the coating can be dissolved in a solvent or a hot melt, so that the liquefied substance can be used to coat the carbon black aggregate. Depending on the specific purpose, working environment, etc., the encapsulation does not need to be sealed and may have an appropriate form. Moreover, the above-mentioned carbon black aggregate with a cover can be additionally encapsulated (hereinafter sometimes referred to as secondary encapsulation). For example, multiple encapsulated carbon black aggregates can be wrapped together, which can substantially reduce transportation. Cost, or, when forming an envelope on a carbon black aggregate via a soluble substance described below, if the envelope is contaminated with dirt or dust and the aggregate is put into a mixing tank without removing the envelope, the resulting Compositions of carbon black, such as inks or coatings, will contain this dirt or dust. According to this, depending on the application or mode of use, this secondary encapsulation has its effect. This means that the substances used for secondary encapsulation are not particularly limited. Various conventional encapsulation methods can be used. Specifically, stretch encapsulation such as plate stretch encapsulation or plate shrink encapsulation, or shrink encapsulation is a typical example. After encapsulating the carbon black aggregate as described above, the environmental pollution caused by flying can be prevented. This problem is easy to occur when using carbon black. In other words, it can be completed (read the precautions on the back before writing this page) ) The size of the paper is described in the Sichuan National Standard 0 (CNS) Λ4 specification (210X 297 mm) -16- 510915 Attachment A: Amendment Page of the Chinese Specification for Patent Application No. 86116063 j V. Description of the invention (17) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) Acid resin; you can use cellulose such as alkali cellulose, cellulose ester, cellulose Acetate, cellulose acetate butyrate, cellulose xanthate, cellulose nitrate, cellulose ether, carboxymethyl cellulose, cellulose ether ester, methylphenidin, ethyl cellulose, ethyl Ethyl cellulose, heteropropyl cellulose, hydroxyethyl cellulose, regenerated cellulose, celluloid or nitrocellulose; for example, polyvinyl esters such as polyvinyl alcohol, polyvinyl cinnamate, polyethylene Acetate Polyvinyl propionate, polyethylene stearate, polyvinyl butyrate, polyvinyl formaldehyde or polyvinyl pyridone; for example, polyvinyl ethers such as polyisobutyl vinyl ether or polymethyl vinyl ether can be used; For example, polyethylene, such as polyether, or polyethylene, can be used; for example, fluororesins, such as FEP, polychlorotrifluoroethylene, polytetrafluoroethylene, polyvinylidene fluoride, or polyvinyl fluoride, can be used; Use, for example, aliphatic polyamines such as nylon 11, nylon 12, nylon 6, nylon 6,10, nylon 6,12 or nylon 6,6, polyphenylene diphenyl-p-phenylenediamine, polyamidamine, imine Or polyamide; for amine-based resins, for example, aniline resin, urea resin, polyamide, or melamine resin; for allyl resins, for example, CR-3 9 or diallyl phthalate; for phenol As the resin, for example, a phenol resin or a resorcinol resin can be used. As for the other resins, for example, polyallylate, polyethylene terephthalate, polyvinylidene chloride, polyvinyl chloride, polycarbonate, ABS resin, ionomer, chlorinated polyether, Coumarone-indene resin, polyphenylene ether, polybutylene terephthalate, polymethylstyrene, polymethene, unsaturated polyester resin, furan resin, polyvinyl stearate, gum arabic, Cuban gum, diallyl phthalate, urea resin, and melamine paper are in accordance with Chinese National Standard (CNS) A4 specifications (21 × 297 mm)

510915 A7 B7 五、發明説明（22 ) 脲樹脂、聚硕醯胺或三聚氰胺樹脂、烯丙基樹脂例如C R - 3 9或酞酸二烯丙酯、醇酸樹脂、環氧樹脂、矽酮樹脂 或乙烯酯樹脂。可以使用酚型樹脂，例如酚醛樹脂或偏苯 二酚樹脂、不飽和的聚酯樹脂或呋喃樹脂。 對於應用至橡膠，可以使用例如A B S樹脂或丙烯酸 樹脂例如聚丙烯醯胺、聚丙烯酸、聚丙烯酸酯、聚丙腈、 聚丙腈酯、苯乙烯、聚甲基丙烯醯胺、聚甲基丙烯酸、聚 甲基丙烯酸酯或聚甲基丙腈。可以使用離子交聯聚合物例 如氯化聚醚、香豆酮-茚樹脂、再生纖維素或石油樹脂。 至於纖維素衍生物，可以使用例如鹼纖維素、纖維素酯、 纖維素醋酸酯、纖維素醋酸酯丁酸酯、纖維素黃原酸酯、 纖維素硝酸酯、纖維素醚、羧甲基纖維素、纖維素醚酯、 甲基纖維素、乙基纖維素、乙基羥乙基纖維素、羥丙基纖 維素、羥乙基纖維素或賽璐珞。至於氟樹脂，可以使用例 如FEP、聚氯三氟乙烯、聚四氟乙烯、聚偏二氟乙烯或 聚氟乙烯。至於聚醯胺，可以使用例如脂族聚醯胺，例如 尼龍1 1、尼龍1 2、尼龍6、尼龍6，1 0、尼龍6， 1 2或尼龍6，6、聚苯二醯對苯二胺、聚醯胺醯亞胺或 聚醯胺酸。可以使用聚烯丙酸酯、聚對苯二甲酸乙二酯、 聚偏二氯乙烯或聚氯乙烯。至於聚烯烴，可以使用聚乙烯 例如氯化聚乙烯、氯硕化聚乙烯、高分子量聚乙烯、低分 子量聚乙烯、高密度聚乙烯、中密度聚乙烯、低密度聚乙 烯或LLDPE、聚丁烯例如聚異丁烯、或聚丙烯。可以使用 例如聚碳酸酯、聚苯乙烯或聚硕例如聚醚硕或聚硕醯胺。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 4 經濟部中央標準局員工消費合作社印製 -25- 510915 A7 _______W〇 Z 1 一 B7 五、發明説明（31) (諳先閱讀背面之注意事項再填寫本頁) 的醇酸樹脂、松香改良的醇酸樹脂、亞麻油改良的醇酸樹 脂、脫水蓖麻油改良的醇酸樹脂或大豆油改良的醇酸樹脂 ，石油樹脂、松香-順丁烯二酸樹脂、環化橡膠、酪素、 蟲膠、松香改良的順丁烯二酸樹脂、硝基纖維素、聚醯胺 樹脂、氯化聚丙烯、聚胺酯樹脂、環氧樹脂、丙烯酸樹脂 、氯乙烯樹脂、氯乙烯-醋酸乙烯酯共聚物、丁醛樹脂、 偏二氯乙烯樹脂，或聚烯烴例如低分子量聚乙烯、低密度 聚乙烯、高密度聚乙烯、低分子量聚乙烯均聚物、低分子 量聚乙烯/丙烯酸共聚物、低分子量聚乙烯/醋酸乙烯酯 共聚物或低分子量丙烯。 在可溶解的物質中，必要時可摻混多種合適的添加劑 ，例如，對於預防結塊劑防止膜本身的結塊，可以添加低 於5重量％的無機塡充劑例如氧化矽或滑石，或者是低於 1重量％的滑動劑、低於〇 · 5重量％的抗氧化劑或低於 0 . 1重量％的中和劑，而且，必要時可加入低於40重 量％可溶解在油墨中的聚合物例如乙基纖維素。 至於添加劑，可以使用例如分散劑、抗氧化劑、抗乾 燥劑、黏性控制劑、調色劑、反應劑、濕化劑、去泡沬劑 、抗真菌劑、抗剝皮劑、皺縮劑、顏色中斷預防劑、及抗 偏移劑例如澱粉，使用的添加劑種類及量可根據包封產物 例如油墨、塗料、有色樹脂或橡膠之特定用途而適當地選 擇，此色料或添加劑之形式可.爲粉狀、乾輾轉粒化的產物 、濕粒化產物、經由例如輥壓縮機之壓製產物、或壓模產 物，尤其是經由合適的模塑壓力或脫氣之模塑產物，適於 尺度这州中®國家標準（CNS ) Λ4规格（210X 297公尨) 510915510915 A7 B7 V. Description of the invention (22) Urea resin, polysulfonamide or melamine resin, allyl resin such as CR-3 9 or diallyl phthalate, alkyd resin, epoxy resin, silicone resin or Vinyl ester resin. A phenol type resin such as a phenol resin or a hydroquinone resin, an unsaturated polyester resin or a furan resin can be used. For application to rubber, for example, ABS resin or acrylic resin such as polyacrylamide, polyacrylic acid, polyacrylate, polyacrylonitrile, polyacrylonitrile, styrene, polymethacrylamide, polymethacrylic acid, polymethylmethacrylate Acrylate or polymethylpropionitrile. Ionic crosslinked polymers such as chlorinated polyethers, coumarone-indene resins, regenerated cellulose or petroleum resins can be used. As the cellulose derivative, for example, alkali cellulose, cellulose ester, cellulose acetate, cellulose acetate butyrate, cellulose xanthate, cellulose nitrate, cellulose ether, carboxymethyl fiber can be used Cellulose, cellulose ether ester, methyl cellulose, ethyl cellulose, ethyl hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose or celluloid. As for the fluororesin, for example, FEP, polyvinyl chloride trifluoroethylene, polytetrafluoroethylene, polyvinylidene fluoride, or polyvinyl fluoride can be used. As for polyamide, for example, aliphatic polyamide can be used, such as nylon 11, nylon 1, 2, nylon 6, nylon 6, 10, nylon 6, 12 or nylon 6, 6, polyphenylene terephthalate. Amines, polyamides, imines or polyamic acids. Polyacrylates, polyethylene terephthalate, polyvinylidene chloride or polyvinyl chloride can be used. As the polyolefin, polyethylene such as chlorinated polyethylene, chlorinated polyethylene, high molecular weight polyethylene, low molecular weight polyethylene, high density polyethylene, medium density polyethylene, low density polyethylene or LLDPE, polybutene For example, polyisobutylene, or polypropylene. For example, polycarbonate, polystyrene, or polyethylene such as polyether or polyethylene. This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling out this page) 4 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics -25- 510915 A7 _______ W〇Z 1 A B7 V. Description of the invention (31) (谙 Please read the notes on the back before filling in this page) alkyd resin, rosin modified alkyd resin, linseed oil modified alkyd resin, dehydrated castor oil modified alkyd resin Or soybean oil modified alkyd resin, petroleum resin, rosin-maleic acid resin, cyclized rubber, casein, shellac, rosin modified maleic acid resin, nitrocellulose, polyamide resin , Chlorinated polypropylene, polyurethane resin, epoxy resin, acrylic resin, vinyl chloride resin, vinyl chloride-vinyl acetate copolymer, butyraldehyde resin, vinylidene chloride resin, or polyolefin such as low molecular weight polyethylene, low density Polyethylene, high density polyethylene, low molecular weight polyethylene homopolymer, low molecular weight polyethylene / acrylic copolymer, low molecular weight polyethylene / vinyl acetate copolymer, or low molecular weight acrylic . In the dissolvable substance, various suitable additives may be blended if necessary. For example, for the anti-caking agent to prevent the film from agglomerating, less than 5% by weight of an inorganic filler such as silica or talc may be added, or It is less than 1% by weight of a sliding agent, less than 0.5% by weight of an antioxidant, or less than 0.1% by weight of a neutralizer, and, if necessary, less than 40% by weight of a soluble in ink can be added. A polymer such as ethyl cellulose. As the additive, for example, a dispersant, an antioxidant, an anti-drying agent, a viscosity control agent, a toner, a reactant, a wetting agent, a defoaming tincture, an antifungal agent, an anti-skinning agent, a shrinkage agent, Color break prevention agents, and anti-offset agents such as starch, the type and amount of additives used can be appropriately selected according to the specific application of the encapsulated products such as inks, coatings, colored resins or rubbers, the form of this colorant or additive can be. It is a powdery, dry-granulated product, wet-granulated product, a pressed product such as a roller compressor, or a compression molded product, especially a molded product that is subjected to a suitable molding pressure or deaeration. State® National Standard (CNS) Λ4 Specification (210X 297 cm) 510915

il -T 消 f- 合 印 V A7 B7 五、發明説明（33) 在將封套除去下使用集料，在此情形下，套封材質的選擇 範圍將更廣闊，雖然需要增加幾個工作步驟。 在本發明中使用的橡膠成份沒有特別的限制，其可爲 至少一種的天然橡膠及合成橡膠，此種橡膠成份係添加至 上述的壓塑碳黑中，其後混合及分散而得到橡膠組成物， 在此，每1 0 0重量組份的橡膠中，碳黑的摻混量較宜爲 3 0至1 5 0重量組份，如此可得到小損失係數或產生小 量熱的橡膠。 使用的橡膠在此沒有特別的限制，例如可以使用合成 橡膠例如苯乙烯丁二烯橡膠（S BR)、丁二烯橡膠（ BR)、異戊間二烯（IR)、氯丁二烯（CR)、腈丁 二烯橡膠（NBR)、異丁儲·異戊間二烯（I I R )、乙 烯丙烯橡膠（EPM)、矽酮橡膠、氟橡膠、氯磺化聚乙 烯（CSM)、氯化聚乙烯（CM)、聚硫橡膠、聚胺酯 橡膠（AU)、丙烯酸橡膠（ACM)、表氯醇橡膠（ ECO)、環氧丙烷橡膠（P〇）、乙烯一醋酸乙烯酯共 聚物（EVA)、液體橡膠、聚嫌硫或亞硝基橡膠、天然 橡膠、或上述橡膠之混合物。而且，必要時可摻混硬化劑 、交聯劑、硬化加速劑、硬化助加速劑、活化劑、分散劑 、硬化阻延劑、防老化劑、增強劑或碳黑以外之塡充劑、 軟化劑、塑化劑、黏著劑、色料、固化劑、發泡劑、潤滑 劑、溶劑、表面活性劑、乳化劑、安定劑、濕化劑、黏稠 劑、凝固劑、膠化劑、乳劑、抗靜電劑、或去泡沬劑。 本發明之碳黑集料添加至上述的橡膠成份中，捏合後 (請先閱讀背面之注意事項再填寫本頁)il -T elimination f-combination V A7 B7 V. Description of the invention (33) The aggregate is used with the envelope removed. In this case, the choice of envelope material will be wider, although several work steps will need to be added. The rubber component used in the present invention is not particularly limited, and it may be at least one of natural rubber and synthetic rubber. This rubber component is added to the above-mentioned compression-molded carbon black, and then mixed and dispersed to obtain a rubber composition. Here, the blending amount of carbon black per 100 weight components of rubber is more preferably 30 to 150 weight components, so a rubber with a small loss coefficient or a small amount of heat can be obtained. The rubber used is not particularly limited, and for example, synthetic rubber such as styrene butadiene rubber (S BR), butadiene rubber (BR), isoprene (IR), and chloroprene (CR ), Nitrile Butadiene Rubber (NBR), Isobutadiene · Isoprene (IIR), Ethylene Propylene Rubber (EPM), Silicone Rubber, Viton, Chlorosulfonated Polyethylene (CSM), Chlorinated Polymer Ethylene (CM), polysulfide rubber, polyurethane rubber (AU), acrylic rubber (ACM), epichlorohydrin rubber (ECO), propylene oxide rubber (Po), ethylene-vinyl acetate copolymer (EVA), liquid Rubber, polysulfide or nitroso rubber, natural rubber, or a mixture of the above. Furthermore, if necessary, a hardener, a cross-linking agent, a hardening accelerator, a hardening accelerator, an activator, a dispersant, a hardening retarder, an anti-aging agent, a reinforcing agent, or an filler other than carbon black may be blended, and softened. Agents, plasticizers, adhesives, colorants, curing agents, foaming agents, lubricants, solvents, surfactants, emulsifiers, stabilizers, wetting agents, thickeners, coagulants, gelling agents, emulsions, Antistatic agent or defoaming tincture. The carbon black aggregate of the present invention is added to the above rubber component, and after kneading (please read the precautions on the back before filling this page)

木纸张尺度適州屮ft]國家標苹（CNS ) Λ4規格（21〇 χ2()7公楚 -36 510915Wood paper scale Shizhou 屮 ft] National Standard Apple (CNS) Λ4 Specification (21〇 χ2 () 7 Gongchu -36 510915

A7 B7 五、發明説明（38) (請先閱讀背面之注意事項再填寫本頁) 別的限制，可以使用從供模塑使用的模具取出時的大小， 或者是粉碎成直徑爲0 · 1毫米至1公分的大小，使其大 小低於捏合機入口的大小，然後將其添加至捏合機內分散 ，即使當使用粉碎的產物時，可以得到改進黑色及光澤的 效應，在此，粉碎方法沒有特別的限制，但是較宜使用切 變型的粉碎機例如切磨機、旋轉粉碎機或切變輥磨機，其 中在碾碎過程中，粒子的密度不會增加。 而且，經由適當地選擇套封材料，本發明的碳黑集料 可在不需要將封套除去下分散在媒劑中，如上所述，可以 改進工作環境，並可實質上改進工作效率，但是，當然也 有可能在將封套除去下使用集料，在此情形下，套封材質 的選擇範圍將更廣闊，雖然需要增加幾個工作步驟。 而且，除了上述碳黑集料及樹脂成份外，情形需要時 可視需要添加硬脂酸鈣、鐵安定劑、抗氧化劑及其他添加 劑。 &amp;'·'';ί&quot;中*^ c ΛΜ 這些成份之混合比例，在製備母體批次物的情形下， 作爲顏料之碳黑較宜爲30至60重量％,添加物爲數個 重量％，且其餘爲樹脂成份，如此製備的母體批次物可添 加至熔化的樹脂中，使碳黑的濃度爲數個重量％，反之， 在經由直接摻混而製備樹脂組成物之情形下，碳黑較宜爲 〇· 1至5重量％，添加物爲數個重量％,且其餘爲樹脂 成份。 如上所述，本發明之碳黑集料可用於製備樹脂組成物 ，本發明適用之樹脂組成物沒有特別的限制，且本發明可 尺度適川屮段國家標準（CNS )八4规格（210X 297公釐） -41 - 510915A7 B7 V. Description of the invention (38) (Please read the precautions on the back before filling in this page) Other restrictions, you can use the size when taken out of the mold for molding, or crushed to a diameter of 0 · 1 mm To 1 cm, make it smaller than the entrance of the kneader, and then add it to the kneader to disperse. Even when using the pulverized product, the effect of improving black and gloss can be obtained. Here, the pulverization method does not have It is particularly limited, but it is preferable to use a shear type pulverizer such as a cutter mill, a rotary pulverizer, or a shear roll mill, in which the particle density does not increase during the crushing process. Furthermore, the carbon black aggregate of the present invention can be dispersed in a vehicle without removing the envelope by appropriately selecting the envelope material. As described above, the working environment can be improved, and the work efficiency can be substantially improved. Of course, it is also possible to use aggregates after removing the envelope. In this case, the choice of envelope material will be wider, although several work steps need to be added. In addition, in addition to the carbon black aggregate and resin components described above, calcium stearate, iron stabilizers, antioxidants, and other additives may be added as necessary. &amp; '·' '; ί &quot; Medium * ^ c ΛΜ The mixing ratio of these ingredients is preferably 30 to 60% by weight as the pigment carbon black in the case of preparing the parent batch, and the additives are several weights %, And the remainder is the resin component. The mother batch prepared in this way can be added to the molten resin so that the concentration of carbon black is several weight%. Conversely, in the case of preparing a resin composition by direct blending, The carbon black is more preferably from 0.1 to 5% by weight, the additives are several% by weight, and the remainder is a resin component. As described above, the carbon black aggregate of the present invention can be used to prepare a resin composition, and the resin composition to which the present invention is applicable is not particularly limited, and the present invention can be adapted to the National Standard (CNS) 8-4 (210X 297) of the Sichuan Basin Section Mm) -41-510915

五、發明説明（47) (4 )測量硬度 測量其中一個從集料等份分離樣品之表面與切面（內 部）硬度，使用由 Kabushiki Kaisha Kamishima Seisakusho 製造的彈簧型硬度計（型號HD 一 1 〇 3N)，集料的頂 面及側面各測量三次，以6個點的平均値作爲表面硬度， 結果其表面硬度爲9 0克，切面（內部）的硬度測量三次 ，並以平均値作爲內部硬度，內部硬度爲61克。 (5 )測量粉碎比例 用下列方法測量粉碎比例。 根據J IS K— 6221,精確秤重25 土 〇· 0 1克（W)的碳黑集料，並放入直徑爲2 0 0毫米 且開口爲1毫米的篩網中，將此篩網連接容器及蓋子，根 據JIS K — 6221的搖動機搖動篩網20秒同時施 以震動，使容器與搖動機分離，精確秤重容器中的碳黑重 量至準確度爲〇 · 0 1克，此値作爲搖動後的重量（WR) ,用下列公式計算粉碎比例。 粉碎比例（％) = (Wr/W) xl〇〇 W r = 5 · 3 0克且粉碎比例爲2 1 . 2 %。 產生微量的粉碎，但其仍在沒有問題的範圍內。 (6 )測量油墨的最初分散性 以下將說明測量油墨網殘留作爲碳黑在製備油墨中的 -50- (請先閱讀背面之注意事項再填寫本頁) 1m氏张尺度述州屮阄國家標枣（CNS ) Λ4現格（2丨0X 297公漦）V. Description of the invention (47) (4) Measuring hardness To measure the hardness of the surface and cut surface (internal) of one sample from the aggregate aliquot, use a spring-type hardness tester (model HD-1 〇3N manufactured by Kabushiki Kaisha Kamishima Seisakusho) ), The top and side of the aggregate are measured three times each, and the average hardness of 6 points is used as the surface hardness. As a result, the surface hardness is 90 grams, the hardness of the cut surface (inner) is measured three times, and the average hardness is used as the internal hardness. The internal hardness is 61 grams. (5) Measurement of pulverization ratio The pulverization ratio was measured by the following method. According to J IS K-6221, a carbon black aggregate weighing 25 soil 0.01 g (W) was accurately weighed and placed in a sieve with a diameter of 200 mm and an opening of 1 mm. This sieve was connected The container and lid are shaken by the shaker according to JIS K-6221 for 20 seconds and shaken at the same time to separate the container from the shaker. The carbon black in the container is accurately weighed to an accuracy of 0.01 grams. This 値As the weight (WR) after shaking, the crushing ratio was calculated using the following formula. Crushing ratio (%) = (Wr / W) x 100 W r = 5.30 g and the crushing ratio was 2 1.2%. A small amount of pulverization occurred, but it was still within a range without problems. (6) The initial dispersibility of the measuring ink The following will explain the measurement of the ink web residue as carbon black in the preparation of -50- (Please read the precautions on the back before filling this page) 1m scale Zhangzhou State Standard Jujube (CNS) Λ4 appears (2 丨 0X 297 male)

、- Λ:, 部 屮 -失 r'j η j &gt;7ί A 510915 z &gt;· ί A? __—-—…:」__B7__ 五、發明説明（86) 進行根據實例1 9的枏同操作，但是使用沒有包封的 碳黑集料。 結果是，分散指數爲1，3 8 0，與起始的原料粉末 比較，使用碳黑集料可實質上降低飛揚，但是與實例1 9 使用之包封的碳黑集料比較，環境污染的預防並不適宜。 如同實例2 4至2 9所顯示，經由使用可溶解的物質 之不同包封方法，也可預防碳黑之環境污染。 實例3 0 根據實例1的相同方法製備包封之碳黑集料，但將實 例1 (7)中所用PE (B)膜換成PE (C)膜而作爲 熱收縮包封。 此包封之碳黑集料不會漏出碳黑而污染環境。此包封 之碳黑集料在PE (C)膜移除後，根據實例1的相同方 法製備油墨。在製備油墨中，.因爲碳黑爲模製過，所以幾 乎沒有觀察到環境的污染，雖然雙手有些被污染的現象。 網殘留幾乎等於實例1者。 實例3 1 根據實例2的相同方法製備包封之碳黑集料，但將實 例2中所用PE (B)膜換成PE (C)膜。 此包封之碳黑集料不會漏出碳黑而污染環境。此包封 之碳黑集料在P E ( C )膜移除後，根據實例1的相同方 法製備油墨。在製備油墨中，因爲碳黑爲模製過，所以幾 (讀先閲讀背面之注意事項再填寫本頁) 裝· 本纸张尺度述州屮阄國家標準（C、NS ) Λ4規格（210X 297公1 ) -89- 510915 B7. !〇„ A7 B7 五、發明説明（87) 乎沒有觀察到環境的污染，雖然雙手有些被污染的現象。 網殘留幾乎等於實例2者。實例3 3 根據實例3的相同方法製備包封之碳黑集料，但將實 例3中所用PE(B)膜換成PE(C)膜。 此包封之碳黑集料不會漏出碳黑而污染環境。此包封 .之碳黑集料在P E ( C )膜移除後，根據實例1的相同方 法製備油墨。在製備油墨中，因爲碳黑爲模製過，所以幾 乎沒有觀察到環境的污染，雖然雙手有些被污染的現象。 網殘留幾乎等於實例3者。 本發明之效應 本發明提供一種碳黑集料，其在運送或儲存時不會有 實質上的飛揚或破裂，當其作爲油墨或塗料使用時有極佳 的分散性，本發明爲一個劃時代的發明，與習知的粒化產 物比較，本發明碳黑集料的鬆密度有實質上的改進，構成 與碳黑相關的成本主要部份之運送及儲存成本，可以大幅 降低。 使用本發明的碳黑集料製備油墨時，可在油墨的製備 中實質上降低處理時間或通過分散機的次數，與使用習知 產物例如粉狀或粒化產物所製備者比較，所得的油墨在基 本油墨性能（黑色級光澤）上並非劣級品。 而且當使用本發明的碳黑集料製備塗料時，不需要任 (請先閱讀背面之注意事項再填寫本頁)、-Λ :, Ministry 屮-失 r'j η j &gt; 7ί A 510915 z &gt; · ί A? __—-—…: ”__ B7__ 5. Description of the invention (86) Perform the same operation according to Example 1-9 , But use unencapsulated carbon black aggregate. As a result, the dispersion index was 1, 3 0. Compared with the starting raw material powder, the use of carbon black aggregates could substantially reduce flying, but compared with the encapsulated carbon black aggregates used in Example 19, the environmental pollution Prevention is not appropriate. As shown in Examples 24 to 29, the environmental pollution of carbon black can also be prevented through different encapsulation methods using soluble substances. Example 30 An encapsulated carbon black aggregate was prepared in the same manner as in Example 1, except that the PE (B) film used in Example 1 (7) was replaced with a PE (C) film as a heat shrinkable envelope. The encapsulated carbon black aggregate will not leak carbon black and pollute the environment. After the encapsulated carbon black aggregate was removed from the PE (C) film, an ink was prepared according to the same method as in Example 1. In the preparation of ink, since carbon black was molded, almost no environmental pollution was observed, although some hands were contaminated. The net residue is almost equal to that of Example 1. Example 3 1 An encapsulated carbon black aggregate was prepared in the same manner as in Example 2 except that the PE (B) film used in Example 2 was replaced with a PE (C) film. The encapsulated carbon black aggregate will not leak carbon black and pollute the environment. After the encapsulated carbon black aggregate was removed from the PE (C) film, an ink was prepared according to the same method as in Example 1. In the preparation of ink, because carbon black is molded, so read (read the precautions on the back first and then fill out this page). The size of this paper states the state standard (C, NS) Λ4 specification (210X 297) 1) -89- 510915 B7.! 〇 A7 B7 V. Explanation of the invention (87) There is almost no environmental pollution observed, although some hands are polluted. The net residue is almost equal to that of Example 2. Example 3 3 According to the example The same method was used to prepare the encapsulated carbon black aggregate, but the PE (B) film used in Example 3 was replaced with a PE (C) film. This encapsulated carbon black aggregate did not leak out carbon black and pollute the environment. After the encapsulation of the carbon black aggregate was removed from the PE (C) film, an ink was prepared according to the same method as in Example 1. In the preparation of the ink, because carbon black was molded, almost no environmental pollution was observed, although Some hands are contaminated. The net residue is almost equal to that in Example 3. The effect of the present invention The present invention provides a carbon black aggregate that does not have substantial flying or cracking during transportation or storage. When it is used as ink or The coating has excellent dispersibility when used. The present invention is a The invention of the era, compared with the conventional granulated product, the bulk density of the carbon black aggregate of the present invention has a substantial improvement, and the transportation and storage costs that constitute the main part of the cost related to carbon black can be greatly reduced. When the carbon black aggregate of the present invention is used to prepare an ink, the processing time or the number of times of passing the disperser can be substantially reduced in the preparation of the ink. Compared with those prepared using conventional products such as powder or granulated products, the obtained ink is basically The ink performance (black gloss) is not inferior. And when using the carbon black aggregate of the present invention to prepare coatings, you don't need to do it (please read the precautions on the back before filling this page)

L 、!' 丁 木纸张尺度適丨丨1 t阀國家標準（CNS ) Λ4规格（210 X 2()7公嫠） -90 - 510915 ! ' * ；^ A 7 ____ϋ__ 五、發明説明（88) (讀先閱讀背面之注意事項再填寫本頁) 何特殊的處理或任何昂貴的機器就可增加塗料之黑色，當 使用本發明的碳黑集料製備樹脂組成物時，可製備有色的 樹脂其中碳黑有高的分散性。 使用本發明的碳黑集料製備橡膠組成物時，可顯示高 的分散性、低功耗因數及低熱積聚，除此之外，經由調整 碳黑集料之密度可控制這些性質之平衡。 要得到本發明之碳黑集料，不需要使用以傳統技術粒 化碳黑所需使用的大量能源或大型設備，換句話說，本發 明的碳黑集料可普遍使用並可用相當小的投資生產，而且 ，碳黑爲非常小的粉碎比例之集料形式且經包封，可以實 質上抑制因爲飛揚造成的汙染，尤其是用可溶性的物質包 封時，可以將飛揚造成的汙染實質上降低至零，因而明顯 地改進工作環境。 Μ 、，i yr. 部 中 夾 冬 又:j '；/i f Μ (丨， 本紙ίΜΙ度違州屮阄囤家標準（CNS ) Λ4规格（21 〇 X 2()&quot;7公釐）L ，! 'Dingmu paper is suitable 丨 丨 1 t valve national standard (CNS) Λ4 specification (210 X 2 () 7mm7) -90-510915!' *; ^ A 7 ____ ϋ__ V. Description of the invention (88) (Read the precautions on the back before you fill in this page) Any special treatment or any expensive machine can increase the blackness of the coating. When the carbon black aggregate of the present invention is used to prepare the resin composition, a colored resin can be prepared. Carbon black has high dispersibility. When the carbon black aggregate of the present invention is used to prepare a rubber composition, it can exhibit high dispersibility, low power consumption factor, and low heat accumulation. In addition, the balance of these properties can be controlled by adjusting the density of the carbon black aggregate. To obtain the carbon black aggregate of the present invention, it is not necessary to use a large amount of energy or large equipment required to granulate the carbon black by the conventional technology. In other words, the carbon black aggregate of the present invention can be universally used and a relatively small investment In addition, carbon black is an aggregate with a very small crushing ratio and is encapsulated, which can substantially suppress the pollution caused by flying, especially when it is encapsulated with a soluble substance, which can substantially reduce the pollution caused by flying. To zero, thus significantly improving the working environment. Μ ,, i yr. In the middle of the winter: j '; / i f Μ (丨, this paper ίΜΙ degree violates the state standard of the domestic store (CNS) Λ4 specification (21 〇 2 () &quot; 7 mm)

Claims (1)

510915 8 88 8 ABCD Γ ii亦 一蒼二南 -ΛΠ* 、：. -0 -D -一Λ 六、申請專利範圍 附件A :第861 1 6063號專利申請案 中文申請專利範圍修正本 民國91年8月30日修正 1·一種碳黑集料，其表面硬度爲70至2000克 且具有封套， 其中碳黑集料之密度σ(克/立方公分）至少是 〇 = 8.190xl(T3D-3.824xl(r3L + 0.516 且最大是 a = 3.265xl〇'3D-3.3 34xl〇-3L+1.173 其中D爲碳黑在電子顯微鏡下之算術平均粒子大小（毫微 米）且 L 爲 DBP (萘酸二丁酯，dibutyl phthalate )油吸 收（毫升/ 1 0 0克）， 該封套是由選自下列的可溶解物質製成：聚烯烴、聚乙烯 -乙酸乙烯酯共聚物、纖維素衍生物、以及聚苯乙烯。 2 ·如申請專利範圍第1項之碳黑集料，其表面硬度 爲300至800克。 3 ·如申請專利範圍第1項之碳黑集料，其表面硬度 高於內部硬度。 4 ·如申請專利範圍第1項之碳黑集料，其中碳黑集 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------------ (請先閱讀背面之注意事項再填寫本頁) *1T 經濟部智慧財產局員工消費合作社印製 510915 A8 B8 C8 D8 六、申請專利範圍 料含有裂縫。 5 .如申請專利範圍第1項之碳黑集料，係用於製造 油墨組成物。 6 .如申請專利範圍第1項之碳黑集料，係用於製造 塗料組成物。 7 .如申請專利範圍第1項之碳黑集料，係用於製造 樹脂組成物。 8 .如申請專利範圍第1項之碳黑集料，係用於製造 橡膠組成物。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -2-510915 8 88 8 ABCD Γ ii is also Cang Ernan-ΛΠ * ,: -0 -D-一 Λ 6. Scope of Patent Application Annex A: Patent Application No. 861 1 6063 Chinese Application for Patent Scope Amendment 1991 Amendment on August 30 1. A carbon black aggregate with a surface hardness of 70 to 2000 grams and an envelope, wherein the density σ (g / cm3) of the carbon black aggregate is at least 0 = 8.190xl (T3D-3.824xl (r3L + 0.516 and maximum a = 3.265xl0'3D-3.3 34xl0-3L + 1.173 where D is the arithmetic mean particle size of carbon black under the electron microscope (nm) and L is DBP (dibutyl naphthalate (Dibutyl phthalate) oil absorption (ml / 100 g), the envelope is made of a soluble substance selected from the group consisting of polyolefins, polyethylene-vinyl acetate copolymers, cellulose derivatives, and polystyrene 2 · If the carbon black aggregate in the scope of patent application No. 1 has a surface hardness of 300 to 800 g. 3 · If the carbon black aggregate in the scope of patent application No. 1 has a surface hardness higher than the internal hardness. 4 · For example, the carbon black aggregate in the first patent application scope, in which the carbon black aggregate paper rule Applicable to China National Standard (CNS) A4 specification (210X297 mm) ------------ (Please read the precautions on the back before filling this page) * 1T Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printed 510915 A8 B8 C8 D8 6. The material in the scope of patent application contains cracks. 5. The carbon black aggregate such as in the scope of patent application No. 1 is used to make ink compositions. 6. The carbon in scope of patent application No. 1 The black aggregate is used for manufacturing coating composition. 7. The carbon black aggregate such as in the first patent application scope is used for manufacturing resin composition. 8. The carbon black aggregate in the first patent application scope, It is used to make rubber composition. (Please read the notes on the back before filling out this page) Printed on the paper by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The paper size is applicable to China National Standard (CNS) A4 (210X297 mm) -2 -