TW500775B - Dye mixtures comprising water-soluble fiber-reactive azo dyes - Google Patents

Abstract

Described are dye mixtures comprising yellow dyes of the formulae indicated and defined in claim 1, which are useful for dyeing hydroxyl- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton and filament viscose, and wool and also synthetic polyamide fibers.

Description

500775 A7 __ B7_五、發明說明（1 ) 本發明係有關纖維反應性偶氮染料之技術範疇。 日本專利申請案公告He i - 1 一 170 661揭 示一種黃色染色單偶氮基染料，其具有乙烯基硕系列之纖 維反應性基團，但其具有特定之應用缺陷。 就個別染料而言，染料混合物提供具有良好得色量之 染料，即相對於所使用之染料量其色度極高之染料，因爲 該染料混合，物之著色性質，亦因爲其染料特性，諸如良好 > 之親和性及高固色率之故。使用兩種染料之混合物所得之 得色量通常係爲個別染料之得色量的平均値。兩種染料之 混合物的得色量因此低於具有較大得色量性質之個別染料 的得色量。 本發明因而提出一種染料混合物，其提供具有遠優於 該染料混合物中個別染料之染色得色量之平均値的得色量 之染色。此種協合效應本身亦顯示於使得本發明混合物部 分之提弁特性較該混合物中個別染料改善。 ‘ 本發明因此提出一種染料混合物，其包含一或多種諸 經濟部智慧財產局員工消費合作社印製 義 定以 而， 示種 列三 所或 下種 以兩 自如 選諸 ’ 種 佳多 爲或 \一彐= 一 種 I 2 及 或， 1料 以染 ， 之 種 } 三 1 或C \}彐| 一 ^ίν 兩通 如於500775 A7 __ B7_ V. Description of the invention (1) The present invention relates to the technical category of fiber-reactive azo dyes. Japanese Patent Application Publication He i-1 1 170 661 discloses a yellow dyed monoazo-based dye having a fiber-reactive group of vinyl series, but it has specific application defects. For individual dyes, dye mixtures provide dyes with good color yield, that is, dyes with extremely high chroma relative to the amount of dye used, because of the dye mixing, the coloring properties of the material, and because of its dye characteristics, such as Good > affinity and high fixing rate. The color yield obtained by using a mixture of two dyes is usually the average color yield of the individual dyes. The yield of a mixture of two dyes is therefore lower than the yield of an individual dye with a greater yield property. The present invention therefore proposes a dye mixture that provides dyeing having an average dye yield that is much better than the dye yield of individual dyes in the dye blend. Such a synergistic effect itself is also shown in that the enhancement properties of the mixture part of the present invention are improved compared to individual dyes in the mixture. 'The present invention therefore proposes a dye mixture, which contains one or more printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs.彐 = one kind of I 2 and or, one material is dyed, the kind of} three 1 or C \} 彐 | 一 ^ ίν The two links are like

IX 料係 5 染比 6 之耳： > 莫 5 2 之 3 C } 至 式 2 5 通 C 3 於等： 義料 5 定染 6 而或 示料 列染 所對 下 } 以 1 5 ο 自 C 2 4 選等至： ’ 料 5 ο 佳染 2 6 爲或··而 種料 5 ， 2 染 7 佳 或，爲爲 4 至 5 以 佳 更 ο 適 度 尺 張 紙 本 I公 97 2 X 1(210 格 I規 Α4 S) Ν (C 準 標 (請先閱讀背面之注意事項再填寫本頁)IX material 5 ears of dyeing ratio 6: > Mo 5 2 3 C} to formula 2 5 pass C 3 is equal to: material 5 will be dyed 6 or the material is dyed in the same place} with 1 5 ο from C 2 4 Select until: 'material 5 ο Jia dye 2 6 is or ... and seed material 5, 2 dye 7 is good or better, it is 4 to 5 and better. Moderate rule paper on paper I male 97 2 X 1 (Class 210 I, Α4 S) Ν (C standard (Please read the precautions on the back before filling this page)

I Α7I Α7

η OH丨η OH 丨

N II N \>-R7N II N \ > -R7

N丨NN 丨 N

9 ,R (S〇3M)m (2) 經濟部智慧財產局員工消費合作社印製 此等通式中： M 係爲氫或鹼金屬，諸如鈉、鉀或鋰； γ1係爲乙烯基或乙基，其/5 -位置經鹼可去除之取代基 所取代，例如氯、硫酸根絡基、硫式硫酸根絡基、磷 酸根絡基、具有2至5個碳原子之烷醯氧基諸如乙醯 ·、. 氧基及磺基苯甲醯氧基，以乙烯基、石一氯乙基或/5 -疏酸根絡乙基爲佳’而乙嫌基或石—硫酸根‘絡乙基 更佳； Υ2具有Υ1之定義之一； R1係爲氫、氯、具有1至4個碳原子之烷基諸如乙基或 尤其是甲基、具有1至4個碳原子之烷氧基諸如乙氧 基或尤其是甲氧基、羧基或磺基，以氫、甲基或甲氧 基爲佳，尤其是氫； R 2係爲氫、具有1至4個碳原子之烷基諸如乙基或尤其 是甲基、具有1至4個碳原子之烷氧基諸如乙氧基或 尤其是甲氧基，以氫、甲基或甲氧基爲佳，而尤其是 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -5- (請先閱讀背面之注意事項再填寫本頁) w/ /) w/ /) A79, R (S〇3M) m (2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs in these general formulas: M is hydrogen or alkali metal, such as sodium, potassium or lithium; γ1 is vinyl or ethyl Group, whose / 5-position is substituted with a base-removable substituent such as chlorine, sulfate complex, thiosulfate complex, phosphate complex, alkoxyl group having 2 to 5 carbon atoms such as Acetyl ·, .oxy and sulfobenzyloxy, preferably vinyl, stone monochloroethyl or / 5-phosphatoethyl, and ethyl or sulphate-ethyl More preferably; Υ2 has one of the definitions of Υ1; R1 is hydrogen, chlorine, alkyl having 1 to 4 carbon atoms such as ethyl or especially methyl, alkoxy having 1 to 4 carbon atoms such as ethyl Oxygen or especially methoxy, carboxyl or sulfo, preferably hydrogen, methyl or methoxy, especially hydrogen; R 2 is hydrogen, alkyl having 1 to 4 carbon atoms such as ethyl or Especially methyl, alkoxy groups having 1 to 4 carbon atoms, such as ethoxy or especially methoxy, preferably hydrogen, methyl or methoxy, and especially this paper size applies to China National Standard (CNS) A4 Specification (210 X 297 mm) -5- (Please read the precautions on the back before filling this page) w / /) w / /) A7

五、發明說明（3 ) 氫； R '具有1至4個碳原子之烷基諸如乙基或尤其 胃'具有1至4個碳原子之烷氧基諸如乙氧基或 尤其是甲氧基、或磺基，以氫、甲基或甲氧基爲佳， 或尤其是磺基，且R3以位於—NH — CO — R基之對 位爲佳； R •係爲胺，基或具有1至6個碳原子之烷基，以具有1至 3{@碳原子爲佳，諸如乙基或尤其是甲基，其中該烷 基可經取代，例如經羥基、磺基、羧基、硫酸根絡基 、磷酸根絡基或—s 0 2 — Y 3基所取代，其中Y 3係 具有γι之定義之一； R4係爲氫、氯、具有1至4個碳原子之烷基諸如乙基或 尤:其是甲基、具有1至4個碳原子之烷氧基諸如乙氧 基或尤其是甲氧基、或磺基，以氫、甲基或甲氧基爲 佳，'尤其是氫； . R5係爲氫、具有1至4個碳原子之烷基諸如乙基或尤其 是甲基、具有1至4個碳原子之烷氧基諸如乙氧基或 尤其是甲氧基，以氫、甲基或甲氧基爲佳，尤其是氫 R6係爲氫、具有1至4個碳原子之烷基諸如乙基或尤其 是甲基、具有1至4個碳原子之烷氧基諸如乙氧基或 尤其是甲氧基、或磺基，以氫、甲基、甲氧基或磺基 爲佳，尤其是氫； η 係爲零或1 ; 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) -5. Description of the invention (3) Hydrogen; R 'alkyl having 1 to 4 carbon atoms such as ethyl or especially gastric' alkoxy having 1 to 4 carbon atoms such as ethoxy or especially methoxy, Or sulfo, preferably hydrogen, methyl or methoxy, or especially sulfo, and R3 is preferably in the para position of —NH — CO — R group; R is an amine group, or has 1 to An alkyl group of 6 carbon atoms, preferably having 1 to 3 {@carbon atoms, such as ethyl or especially methyl, wherein the alkyl group may be substituted, for example, by hydroxyl, sulfo, carboxyl, sulfate , Phosphate or —s 0 2 — Y 3 groups, where Y 3 is one of the definitions of γι; R4 is hydrogen, chlorine, alkyl groups having 1 to 4 carbon atoms such as ethyl or especially : It is a methyl group, an alkoxy group having 1 to 4 carbon atoms such as an ethoxy group or especially a methoxy group, or a sulfo group, preferably hydrogen, a methyl group or a methoxy group, 'especially hydrogen;. R5 is hydrogen, an alkyl group having 1 to 4 carbon atoms such as ethyl or especially methyl, an alkoxy group having 1 to 4 carbon atoms such as ethoxy or especially methoxy, and hydrogen, methyl Base or Oxygen is preferred, especially hydrogen R6 is hydrogen, alkyl having 1 to 4 carbon atoms such as ethyl or especially methyl, alkoxy having 1 to 4 carbon atoms such as ethoxy or especially Methoxy or sulfo, preferably hydrogen, methyl, methoxy or sulfo, especially hydrogen; η is zero or 1; this paper size applies to Chinese National Standard (CNS) A4 (210 X 297) Mm) (Please read the notes on the back before filling out this page)-

訂---------線J 經濟部智慧財產局員工消費合作社印製 -6- 500775 Α7 Β7 五、發明說明（4 ) R 7係爲甲基或羧基； R8係爲氫、具有1至4個碳原子之烷基諸如乙基或尤其 是甲基、具有1至4個碳原子之烷氧基諸如乙氧基或 尤其是甲氧基、或氯，以甲基或氯爲佳，尤其是氫； R9係爲氫、具有1至4個碳原子之烷基諸如乙基或尤其 是甲基、具有1至4個碳原子之烷氧基諸如乙氧基或 .尤其是·甲氧基、或氯，以氫爲佳； m 係爲零、1或2，以1或2爲佳，尤其是1 (當m爲 * 零時，此基團係爲氫）； 該Y1— SO 2 —及Y2— S〇2 —基團係鍵結於苯環，個別 與偶氮基及該一 NH — C〇一基團成間位及尤其是對 位； 該—NH - C0 -基團係鍵結於式（2)中之苯環，與該 偶氮基成間位及較佳之對位。 前述通式及以下通式中，通式中之個別組分不‘論是具 有相同或不同之名稱，皆可具有定義下之意義，彼此相同 或相異。 ''磺基〃、 ''硫代硫酸根絡基〃、''羧基〃、 ''磷酸 根絡基〃及''硫酸根絡基〃不僅包括酸形式，亦包括個別 基團之鹽形式。是故，磺基係爲對應於通式- s 〇3基團’ 硫代硫酸根絡基係對應於通式- S - S〇3 Μ之基團，羧基 係爲對應於通式- C 0〇Μ之基團，磷酸根絡基係爲對應 於通式-〇Ρ 〇 3 Μ 2之基團，而硫酸根絡基係爲對應於通 式一〇S〇3Μ之基個，其中每個Μ皆如前定義。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） <請先閱讀背面之注意事項再填寫本頁) -Order --------- Line J Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-6-500775 Α7 Β7 V. Description of the invention (4) R 7 is methyl or carboxy; R8 is hydrogen and has Alkyl groups of 1 to 4 carbon atoms such as ethyl or especially methyl, alkoxy groups of 1 to 4 carbon atoms such as ethoxy or especially methoxy, or chlorine, preferably methyl or chlorine , Especially hydrogen; R9 is hydrogen, an alkyl group having 1 to 4 carbon atoms such as ethyl or especially methyl, an alkoxy group having 1 to 4 carbon atoms such as ethoxy or. Oxygen or chlorine, preferably hydrogen; m is zero, 1 or 2, preferably 1 or 2, especially 1 (when m is * zero, this group is hydrogen); the Y1-SO The 2- and Y2-S02- groups are bonded to the benzene ring, and each forms an m-position and especially a para-position with the azo group and the one NH-C0- group; the -NH-C0- group It is bound to the benzene ring in formula (2), and forms a meta position and a preferred para position with the azo group. In the foregoing general formula and the following general formulas, the individual components in the general formula do not have the same or different names, and they may have the meanings as defined, and they may be the same or different from each other. '' Sulfo〃, '' `` thiosulfate〃 '', `` carboxy〃, '' `` phosphate 络, '' and `` sulfate 络 '' include not only the acid form but also the salt form of individual groups. Therefore, the sulfo group is a group corresponding to the general formula-s 〇 3 'thiosulfate complex group is a group corresponding to the general formula-S-S 03 M, and the carboxyl group is corresponding to the general formula-C 0 The group of 0M, the phosphate complex is a group corresponding to the general formula -〇 〇 3 Μ 2 and the sulfate complex is a group corresponding to the general formula 10S 3M, each of which M is defined as before. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) < Please read the precautions on the back before filling this page)-

訂---------線U 經濟部智慧財產局員工消費合作社印製 500775 A7 B7 五、發明說明（5) 通式（1 )及（2 )之染料係眾所周知，而描述於例 如歐洲專利申請案公告第〇 0 7 3 4 8 1號、英國專 利編號1 1 2 4 3 8 8及德國專利編號 1 2 8 2 213 及 1 206 1〇7 中。 本發明染料混合物中通式（1 )染料中之一，需特別 強調其中γ 1 一 S〇2 一基係與偶氮基成間位，尤其是對位 ，Y 1係爲乙烯基或較佳之/3 -硫酸根絡乙基，R 1及R 2 個別係爲氫、甲基或甲氧基，以氫爲佳，R3係爲磺基，而 鍵\結於苯環與一 NH — CO — R基團成對位，且R係爲甲 基。 本發明染料混合物中，通式（2 )之染料中，較佳者 中η係爲零’ Y 2 - S 0 2 -基係位於偶氮基之間位或對位 ，R4係爲氫、甲基、或甲氧基，R5係爲氫或甲基，R8 及R 9皆爲氫，而m係爲1，此磺基以鍵結於苯環與該D比d坐 酮環之氮原子成對位於位置爲佳；其中較佳者係爲·通式（ 2 )之單偶氮基染料，其中R4及R5皆爲氫，而Y2-S〇2 -基係與偶氮基成對位。 此外，本發明混合物中通式（2 )之單偶氮基染料尤 其有關其中η係爲1 ，R4及r5皆爲氫，Y2 一 s〇2 —基 團與—NH — C〇一基團成間位或較佳之對位，且Y2係爲 乙烯基或/3 -硫酸根絡乙基，以/3 -硫酸根絡乙基爲佳， 該- N Η - C 0 -基係與該偶氮基成間位或較佳之對位， R 6係爲氫，R 8及R 9皆爲氫，且m係爲1 ，而此磺基較 佳係鍵結於苯環與該吡唑酮環之氮原子成對位之位置上。 (請先閱讀背面之注意事項再填寫本頁) - 經濟部智慧財產局員工消費合作社印製 訂---------線 丨丨---一1---.1------------, 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -8 - 500775 A7 B7 五、發明說明（6) 通式（1 )之染料可具有Y1定義範圍內之不同纖維反 應性一 S〇2 — Y1基團，尤其是具有相同發色團（而通式 (2 )染料之Y2及Y3亦相同）。更佳之染料混合物可 含有具有相同發色團而對應於通式（1 )之染料，及/或 具有相同發色團而對應於通式（2 )之染料，其中該纖維 反應性基團一 SO 2 — Y1 (或一s〇2 — Y2及一s〇2 — Υ3 Λ於一方面係爲乙烯磺醯基，而另一方面係爲冷一氯乙 基磺醯基或Θ -硫式硫酸根絡乙磺醯基或較佳之Θ -硫酸 根'铬乙磺醯基。當該染料混合物含有部分具有乙烯磺醯基 之個別染料時，該具有乙烯磺醯基之個別染料的比例以個 別染料發色團計係高達約3 0莫耳百分比。 對應於通式（3 a )及（3b)之基團Order --------- Line U Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 500775 A7 B7 V. Description of the invention (5) The dyes of the general formulae (1) and (2) are well known and described in, for example, European Patent Application Publication No. 2007 3 4 81, British Patent No. 1 12 4 38 8 and German Patent Nos. 1 2 8 2 213 and 1 206 1 07. In the dye mixture of the present invention, one of the dyes of the general formula (1) needs to be particularly emphasized, in which the γ 1 -S02-based system is in meta position with the azo group, especially the para position, and the Y 1 system is vinyl or better / 3-Sulfate complex ethyl, R 1 and R 2 are each hydrogen, methyl or methoxy, preferably hydrogen, R3 is sulfo, and the bond between the benzene ring and a NH — CO — R The groups are in para position and R is methyl. Among the dye mixtures of the present invention, among the dyes of the general formula (2), the η system is preferably zero. The Y 2 -S 0 2-group is located between the azo group or the para position, and R 4 is hydrogen and methyl. Group, or methoxy group, R5 is hydrogen or methyl, R8 and R9 are both hydrogen, and m is 1, this sulfo group is bonded to the benzene ring and the nitrogen atom of the ketone ring. The pair is preferably in a position; the more preferred is a monoazo-based dye of the general formula (2), where R4 and R5 are both hydrogen, and the Y2-S02-group is in a para-position with the azo group. In addition, the monoazo dyes of the general formula (2) in the mixtures of the present invention are particularly relevant in which the η system is 1, R4 and r5 are both hydrogen, and the Y2 -s02- group and the -NH-C0-group form Meta or better para-position, and Y2 is vinyl or / 3-sulfate complex ethyl, preferably / 3-sulfate complex ethyl, the -N Η-C 0-group is related to the azo The group forms a meta position or a preferred para position, R 6 is hydrogen, R 8 and R 9 are both hydrogen, and m is 1, and the sulfo group is preferably bonded to the nitrogen of the benzene ring and the pyrazolone ring. Atoms are in pairs. (Please read the notes on the back before filling out this page)-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs --------- line 丨 丨 --- 一 1 ---. 1 ---- --------, The size of this paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) -8-500 775 A7 B7 V. Description of the invention (6) Dye of general formula (1) may have Different fiber reactivity-S02-Y1 groups within the definition of Y1, especially have the same chromophore (and Y2 and Y3 of the dye of general formula (2) are also the same). More preferred dye mixtures may contain dyes having the same chromophore and corresponding to the general formula (1), and / or dyes having the same chromophore and corresponding to the general formula (2), wherein the fiber reactive group is SO 2 — Y1 (or one s〇2 —Y2 and one s〇2 — Υ3 Λ on the one hand is ethylenesulfonyl, and on the other hand is cold monochloroethylsulfonyl or Θ-thiosulfate Ethylsulfonyl or preferably Θ-sulfate'chromethionsulfenyl. When the dye mixture contains individual dyes partially having ethylenesulfonyl, the proportion of the individual dyes having ethylenesulfonyl is based on individual dyes. The chromophore is up to about 30 mole percentages. Groups corresponding to the general formulae (3a) and (3b)

----I------,-- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 其係存在於染料（1 )及（2 )中，係爲例如3 —（冷一 硫酸根絡乙磺醯基）苯基、4 -（ /5 -硫酸根絡乙磺醯基 )苯基、2 -甲基—5 —(石一硫酸根絡乙磺醯基）苯基 、2 —甲氧基一 5 — （沒一硫酸根絡乙磺醯基）苯基、4 —甲基一 3 -（Θ —硫酸根絡乙磺醯基）苯基、2，5 — 二甲基一 4 一—硫酸根絡乙磺醯基）苯基、2 ，6 — 二甲基一 4 一 （/3 —硫酸根絡乙磺醯基）苯基、2 —甲氧 基一 4 一 —硫酸根絡乙磺醯基）苯基、4 一甲氧基一---- I ------,-(Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, which are in dyes (1) and (2) It is, for example, 3- (cold monosulfate ethanesulfonyl) phenyl, 4-(/ 5-sulfate ethanesulfonyl) phenyl, 2-methyl-5— (stone monosulfate Ethylsulfonyl) phenyl, 2-methoxy-5 ((monosulfate, ethylsulfonyl) phenyl), 4-methyl-1,3- (Θ-sulfate, ethylsulfonyl) phenyl , 2,5 —dimethyl-4 4-sulfoethanesulfonylsulfonyl) phenyl, 2,6-dimethyl-4 4-(/ 3sulfatesulfonylsulfonyl) phenyl, 2 — Methoxy-1, 4-mono-sulfoethanesulfonyl) phenyl, 4-monomethoxy-1

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -9- 500775 A7 __ _B7 __ 五、發明說明（7 ) 5 — (/? -硫酸根絡乙磺醯基）苯基、2 -甲基一 4 一-硫酸根絡乙磺醯基）苯基 甲氧基一 5 —一硫酸根絡乙磺醯基）苯 二甲氧基一 4 一—硫酸根絡乙磺醯基） 基一 4 一-硫酸根絡乙磺醯基）苯基， /5 -硫酸根絡乙磺醯基）苯基，及其衍生物 硫酸根絡乙礒醯基係由乙烯磺醯基或/3 —硫 磺醯基或Θ -氯乙基磺醯基所置換。 '本發明染料混合物可使用習用方式製備 地混合個別染料，通常或爲染料粉末或顆粒 成溶液或爲個別染料之水溶液的形式，可另 劑，或藉著化學合成於單鍋反應中製備，例 批料中使用個別染料之重氮成分及偶聯成分 爲熟習此技藝者所熟知。例如，於一可能方 種諸如兩種或三種通式（4 a )之苯胺化合 諸如兩種或三種通式（4 b )之苯胺化合物 甲氧基一5 — 、2，4 一二 基、2，5 -苯基及2 -磺 尤其是4 一（ ，其中該/3 — 式硫酸根絡乙 ，例如機械性 形式或其初合 外包括習用輔 如於相同反應 。該合成法係 法中，一或多 物及一‘或多種 -----I--;丨皿丨ί—丨·丨丨 (請先閱讀背面之注意事項再填寫本頁) 訂· 線· 經濟部智慧財產局員工消費合作社印製This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -9- 500775 A7 __ _B7 __ V. Description of the invention (7) 5 — (/?-Sulfoxyethanesulfonyl) phenyl , 2-methyl-1, 4-mono-sulfate ethanesulfonyl) phenylmethoxy-1, 5-monosulfate ethanesulfonyl) benzenedimethoxy-1, 4-monosulfate ethanesulfonyl ) Group 1-4-monosulfoethanesulfonyl) phenyl, / 5 -sulfolanthethanesulfonyl) phenyl, and its derivatives Sulfonylacetamidine is composed of ethylenesulfonyl or / 3-Sulfuryl or Θ -chloroethylsulfonyl. 'The dye mixture of the present invention can be prepared by mixing individual dyes in a conventional manner, usually in the form of dye powder or granules in solution or in the form of an aqueous solution of individual dyes. The use of diazo components and coupling components of individual dyes in batches is well known to those skilled in the art. For example, an aniline such as two or three general formulas (4a) is combined with a aniline compound such as two or three general formulas (4b) in one possible way: methoxy-5, 2, 2, 4-diyl, 2 , 5-Phenyl and 2-Sulfur, especially 4-((wherein, the / 3-form sulfate ion B, for example, the mechanical form or its initial combination, including the conventional supplements are complementary to the same reaction. In the synthetic method, One or more things and one's or more ----- I--; 丨 Ware 丨 ί-- 丨 · 丨 丨 (Please read the notes on the back before filling this page) Order · Line · Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives

(4a)(4a)

NH, (4 b) 其中該式之個別組分各如前定義，係於相同反應批料中 -10- 本紙用中國國家標準（CNS)A4規格（210 X 297公复） 500775 A7 _______B7_ 五、發明說明（8 ) 於一或多種諸如兩種或三種通式（5 a )之化合物及一或 多種諸如兩種或三種通式（5 b )之化合物存在下NH, (4 b) where the individual components of the formula are as defined above and belong to the same reaction batch-10- This paper uses the Chinese National Standard (CNS) A4 specification (210 X 297 public) 500775 A7 _______B7_ V. Description of the invention (8) in the presence of one or more compounds such as two or three formulas (5 a) and one or more compounds such as two or three formulas (5 b)

(請先閱讀背面之注意事項再填寫本頁) - 訂---------線 其中式中之個別組分係各如前定義，各於對應之分率下， 於習用方式下，例如於鹽酸或硫酸介質中藉著亞硝酸，例 如於低於2 · 5之p Η下及於介於一 5 °C及+ 1 0 °C間之 溫度下’一起進行重氮化，形成之重氮鏺化合物於調整至 弱酸至中性p Η之後，依習用方式與化合物（5 a )及{ 5 b ) f禺聯’例如於介於〇及3 〇 π間之溫度下，.以介於 1 0及2 0。(：間爲佳，及介於3及7 · 5間之ρ Η下，以 介於4 · 5及6 . 5間爲佳。 經濟部智慧財產局員工消費合作社印製 #發明染料混合物可爲單體或液體（溶解）之製備形 式°於@體形式下，其通常包括習用於水溶性（尤其是纖 維反應性）染料之電解質鹽類，諸如氯化鈉、氯化鉀、及 硫酸鈉’可另外包含習用於市售染料之輔劑，諸如可將水 溶液中之ρ Η設定於3及7之間的緩衝劑，諸如乙酸鈉、 檸檬酸鈉、硼酸鈉、碳酸氫鈉、磷酸二氫鈉及磷酸氫二鈉 '染色_劑、防塵劑及少量乾燥劑；若其爲液體、水溶液 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）_ 1 1 · 500775 經濟部智慧財產局員工洎費合作社印製 A7 B7 五、發明說明（9) (包括習用於印染漿之增稠劑），則其亦可包括確定該配 製劑具有長壽命之物質，例如防黴劑。 於固體形式下’本發明染料混合物通常係爲粉碎或顆 粒配製劑，包括電解質鹽類，含有或不含一或多種前述輔 劑。該配製劑中之染料混合物分率以該配製劑計係爲1 〇 至8 0重量百分比。緩衝劑物質總量以該配製劑計通常高 達5.重量百分比。若本發明染料混合物係爲水溶液形式， 則以該水溶液計，此等水溶液之染料總含量係高達約5 〇 重量百分比’例如介於5及5 0重量百分比之間，而此等 水溶液之電解質鹽含量係低於1 〇重量百分比；該水溶液 (液體配製劑）可包括前述緩衝劑物質，通常高達5重量 百分比，以高達2重量百分比爲佳。 本發明經化學方式產製之染料混合物自其合成溶液之 分離可藉一般已知方法進行，例如藉著電解質例如氯化鈉 或氯化鉀而由反應介質沉澱，或藉著蒸發或噴霧乾·燥該反 應溶液，此情況下，此反應溶液可添加緩衝劑物質。 本發明染料混合物可包括其他纖維反應性染料，其係 用以調整該染料混合物之色光，用量高達5重量百分比。 此等、、調整色光染料〃可藉著習用混合添加，或可於相同 反應批料中’與前述本發明染料混合物之合成一起化學性 地製備’或當該調整色光染料之成分中一或多種與式（工 )及（2 )之染料成分相同時則摻入該染料混合物中。 本發明染料混合物具有有效之應用性質。其可用以染 色或印染含有羥基及/或含有羧醯胺基之材料，例如片 本紙張尺度適用中國國家標準（CNS)A4規格（2】0 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)(Please read the notes on the back before filling this page)-Order --------- The individual components in the formula are defined as above, each under the corresponding fraction, and in the conventional mode For example, by nitrous acid in hydrochloric acid or sulfuric acid medium, for example, diazotization at a temperature of p p lower than 2.5 and at a temperature between -5 ° C and + 10 ° C, forming After the diazonium compound is adjusted to a weak acid to a neutral p, the compound (5a) and {5b) f are coupled according to a conventional manner, for example, at a temperature between 0 and 3 0π. Between 1 0 and 2 0. (: The room is better, and the range between 3 and 7 · 5 is better, and the room is better than 4. 5 and 6. 5 Monomeric or liquid (dissolved) forms of preparation ° Under the @body form, it usually includes electrolyte salts commonly used in water-soluble (especially fiber-reactive) dyes such as sodium chloride, potassium chloride, and sodium sulfate ' Additional adjuvants commonly used in commercially available dyes, such as buffers that can set ρ Η in aqueous solutions between 3 and 7, such as sodium acetate, sodium citrate, sodium borate, sodium bicarbonate, sodium dihydrogen phosphate And disodium hydrogen phosphate 'staining agent, dustproof agent and a small amount of desiccant; if it is a liquid or aqueous solution, the paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) _ 1 1 · 500775 Ministry of Economic Affairs wisdom A7 B7 printed by the staff of the Property Agency Cooperative Fifth, the invention description (9) (including thickeners used in printing and dyeing paste), it can also include substances that determine that the formulation has a long life, such as antifungal agents. In solid form, the dye mixture of the present invention is Often a pulverized or granular formulation, including electrolyte salts, with or without one or more of the aforementioned adjuvants. The dye mixture fraction in the formulation is 10 to 80 weight percent based on the formulation. Buffer The total amount of agent material is usually up to 5. weight percent based on the formulation. If the dye mixture of the present invention is in the form of an aqueous solution, the total dye content of these aqueous solutions is up to about 50 weight percent based on the aqueous solution, such as between 5 and 50 weight percent, and the electrolyte salt content of these aqueous solutions is less than 10 weight percent; the aqueous solution (liquid formulation) may include the aforementioned buffer substances, usually up to 5 weight percent and up to 2 weight percent The separation of the chemically produced dye mixture of the present invention from its synthetic solution can be performed by generally known methods, such as precipitation from a reaction medium by an electrolyte such as sodium chloride or potassium chloride, or by evaporation or The reaction solution is spray-dried and dried, and in this case, a buffer substance may be added to the reaction solution. The dye mixture of the present invention may include other fibers Reactive dyes are used to adjust the shade of the dye mixture, and the amount is up to 5 weight percent. These dyes can be added by conventional mixing, or can be used in the same reaction batch as the dyes of the present invention. The synthesis of the mixture is chemically prepared together 'or incorporated into the dye mixture when one or more of the components of the shade-adjusting dye are the same as the dye ingredients of formulae (Engineering) and (2). The dye mixture of the present invention is effective Application properties. It can be used to dye or print materials containing hydroxyl groups and / or carboxyamido groups. For example, the size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (2) 0 X 297 mm. (Please read the back first (Notes for filling in this page)

-12- 500775 A7 B7 五、發明說明（10) (請先閱讀背面之注意事項再填寫本頁) 結構，諸如紙及皮或薄膜，例如包含聚醯亞胺，或整體， 例如聚醯亞胺及聚胺基甲酸乙酯，但特別是用以染色或印 染纖維形式之此等材料。相同地，本發明染料混合物之合 成中所得之溶液可視需要於添加緩衝劑物質之後，且視需 要於濃縮或稀釋之後，直接作爲供染色用之液體配製劑。 本發明因此亦提出本發明染料混合物之用途，其係用 以染色或印染此等材料，或以習用方式染色或印染此等材 料之方法’其係使用本發明染料混合物或其個別成分（染 料），個別同時使用著色劑。該材料以使用纖維材料形式 爲佳’尤其是紡織纖維形式，諸如機織織物或紗，如絞紗 或筒捲紗形式。 經濟部智慧財產局員工消費合作社印製 含羥基之材料係爲天然或合成來源，例如纖維素纖維 材料或其再生產物及聚乙烯醇。纖維素纖維材料以棉爲佳 ’但亦可爲其他植物纖維，諸如亞麻、***、黃麻及芋麻 纖維；苒生纖維素纖維有例如黏膠短纖維及黏膠纖‘絲，及 經化學改質之纖維素纖維，諸如經胺化之纖維素纖維或例 如P CT專利申請案公告第*w〇 9 6/3 7 6 4 1及 W〇9 6 / 3 7 6 4 2所述之纖維，及歐洲專利申請案公 告編號0 538 785及〇 692 559所述之 纖維。 含羧之材料係爲例如合成及天然聚醯胺及聚胺基甲酸 乙酯’尤其是纖維形式’例如羊毛及其他動物毛、絲、皮 、耐綸一 6，6、耐綸—6、耐綸一 1 1及耐綸—4。 本發明染料混合物可藉著水溶性染料尤其是纖維反應 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -13- 500775 A7 B7 五、發明說明（ii) (請先閱讀背面之注意事項再填寫本頁) 性染料已知之應用技術施加且固定於前述物質，尤其是所 述之纖維材料上。其特徵爲優越之顏色提升性，因此可用 以提供特別有利於工業化之深色澤，尤其是當與其他染料 使用於三原色染色時，亦提供例如深棕色。適當之組合係 具有一或兩個乙烯碼系列纖維反應性基之習用染料，或具 有單氯三井/乙烯硕系列組合之纖維反應性基團的染料。 例如，·其於纖維素纖維上，藉著盡染法，自小浴比及 大浴比’例如5 ·· 1至1 〇 〇 : 1之染液對於產品比例， 經濟部智慧財產局員工消費合作社印製 以‘ 7 ·· 1至3 0 : 1爲佳，使用各種酸鍵結劑例如碳酸鈉 及氫氧化鈉及視情況使用之中性鹽諸如氯化鈉或硫酸鈉， 產生具有較個別染料改善之極佳得色量的染色。以自溫度 介於4 0及1 0 5 °C間之溫度下之水浴施加爲佳，視情況 於高達1 3 0°C之溫度下於超大氣壓下進行，以3 0至 9 5 °C爲佳，尤其是4 5至6 5 °C，視情況存在習用染色 輔劑。一種可能之方法係將該物質導入含有鹼之染‘浴中， 該浴緩緩加熱至所需之染色溫度，於該溫度完成該染色過 程；亦可由視情況含有碳酸鈉之染浴開始，稍後於該染色 過程中添加氫氧化鈉溶液於該染浴中。 視情況在達到實際染色溫度之前，不添加加速該染料 之盡染的中性鹽於該染浴中。本發明混合物特別適合使用 於盡染法’於由4 5至6 5 °C之較佳溫度範圍內，根據 ®automet 方法（參照例如 E P — A — 0 1 2 6 0 4 2 及EP — A — 〇 2 5 9 319)而於該染浴中而漸次 地量入氫氧化鈉溶液。特別可使用於該盡染法之染料混合 本紙張尺度適用中國國家標準（CNS)A4規格（2】〇χ 297公釐） -14- 500775 A7 經濟部智慧財產局員工消費合作社印製 B7____五、發明說明（12) 物係包含通式（2)之染料，其中n係爲1。 · 習用軋染法同樣於纖維素纖維上提供優越之得色量， 及極佳之顏色提升。該染料混合物以於含有例如碳酸鈉及 氫氧化鈉溶液之鹼軋染液體中施加於該材料爲佳，該染料 藉著於高溫例如高達6 0°C下卷染而變成固定於該材料上 ’但以根據冷軋卷堆染色法而於室溫下進行爲佳。然而， 染料於該材料上之固定亦可以連續方式進行，例如使用軋 -烘-軋-汽蒸法，藉汽蒸或使用乾熱以習用方式進行。 尤’其是含有通式（2 )之染料的本發明染料混合物，其中 η係爲零，有利於此等軋染方法。 相同地，纖維素纖維所習用之印染法，可於單相下進 行，例如使用包含碳酸氫鈉或某些其他酸鍵結劑之印漿印 染，之後於1 0 0至1 0 3°C下汽蒸，或於雙相下進行， 例如使用中性或弱酸性印漿印染，而藉著使經印染之材料 通經包舍電解質之熱鹼浴或使用包含電解質之熱軋噪液進 行過度乳染，之後使經處理之材料進行卷染，或後續汽蒸 或後續使用乾熱處理，產生具有淸晰之輪廓及乾淨之白色 背景的強染色。該印染之外觀不因固色條件之變化而大幅 改變。 當根據習用熱固色方法藉乾熱固色時，使用1 2 0至 2〇0°C之熱空氣。除了 1 〇 1至1 〇 3°C之習用蒸汽之 外，亦可使用過熱蒸汽，及高達1 6 0°C溫度之高壓蒸汽 〇 影響本發明染料混合物於纖維素纖維上之固色的酸鍵 (請先閱讀背面之注意事項再填寫本頁) 夢-12- 500775 A7 B7 V. Description of the invention (10) (Please read the notes on the back before filling this page) Structure, such as paper and leather or film, for example, containing polyimide, or the whole, such as polyimide And polyurethanes, but especially these materials in the form of dyed or printed fibers. Similarly, the solution obtained in the synthesis of the dye mixture of the present invention may be directly used as a liquid formulation for dyeing after adding a buffer substance, and optionally after concentrating or diluting, if necessary. The invention therefore also proposes the use of the dye mixture of the invention, which is a method for dyeing or printing these materials, or dyeing or printing these materials in a customary manner, 'which uses the dye mixture of the invention or its individual ingredients (dye) , Individual use of colorants. The material is preferably in the form of a fibrous material ', especially in the form of textile fibers, such as woven fabrics or yarns, such as skeins or bobbins. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Materials containing hydroxyl groups are of natural or synthetic origin, such as cellulose fiber materials or their regenerated products and polyvinyl alcohol. Cellulose fiber materials are preferably cotton, but they can also be other plant fibers, such as flax, hemp, jute, and taro fibers; virgin cellulose fibers such as viscose staple fibers and viscose fibers, and chemical Modified cellulose fibers, such as the aminated cellulose fibers or the fibers described in, for example, PCT Patent Application Publication Nos. * WO9 6/3 7 6 4 1 and WO 9 6/3 7 6 4 2 , And the fibers described in European Patent Application Publication Nos. 0 538 785 and 0692 559. Carboxyl-containing materials are, for example, synthetic and natural polyamides and polyurethanes, especially in the form of fibers, such as wool and other animal hair, silk, leather, nylon-6, nylon-6, nylon-resistant Nylon-1 1 and Nylon-4. The dye mixture of the present invention can be reacted by water-soluble dyes, especially fibers. The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -13- 500775 A7 B7 V. Description of the invention (ii) (Please read first Note on the back, please fill in this page again.) The known application technology of sex dyes is applied and fixed to the aforementioned materials, especially the fiber materials mentioned. It is characterized by superior color liftability, so it can be used to provide a dark color that is particularly conducive to industrialization, especially when used with other dyes in three primary color dyeing, and also provides, for example, dark brown. A suitable combination is a conventional dye having one or two vinyl code series fiber-reactive groups, or a dye having a single-chlorine Mitsui / ethylene master series fiber-reactive group combination. For example, on the cellulose fiber, by the exhaust dyeing method, the ratio of the dyeing solution to the product from the small bath ratio to the large bath ratio, such as 5 · 1 to 100: 1, is consumed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs. Cooperatives print with '7 ·· 1 to 3 0: 1 preferably, using various acid bonding agents such as sodium carbonate and sodium hydroxide and optionally using neutral salts such as sodium chloride or sodium sulfate, resulting in more individual Dyes improve dyeing with excellent yield. It is best to apply from a water bath at a temperature between 40 and 105 ° C. Depending on the situation, it can be performed at a temperature of up to 130 ° C under superatmospheric pressure, with 30 to 95 ° C as Good, especially 4 5 to 65 ° C, customary dyeing adjuvants are available as appropriate. One possible method is to introduce the substance into a dyeing bath containing alkali, which is slowly heated to the required dyeing temperature, and the dyeing process is completed at this temperature; it may also be started from a dyeing bath containing sodium carbonate, as appropriate. Later in the dyeing process, sodium hydroxide solution was added to the dyeing bath. Optionally, a neutral salt that accelerates the exhaustion of the dye is not added to the dye bath until the actual dyeing temperature is reached. The mixture according to the invention is particularly suitable for use in the exhaustion method 'in the preferred temperature range from 45 to 65 ° C, according to the ® automet method (see for example EP — A — 0 1 2 6 0 4 2 and EP — A — 〇 2 5 9 319) And in this dyeing bath, gradually measure the sodium hydroxide solution. In particular, the dyes used in the exhaustion method can be mixed with the paper standard of China National Standard (CNS) A4 (2) 〇χ 297 mm -14- 500775 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7____5 2. Description of the invention (12) The system includes dyes of the general formula (2), where n is 1. · The conventional padding method also provides superior color yield and excellent color improvement on cellulose fibers. The dye mixture is preferably applied to the material in an alkali padding liquid containing, for example, sodium carbonate and sodium hydroxide solution. The dye becomes fixed on the material by dyeing at high temperatures, such as up to 60 ° C. ' However, it is preferably performed at room temperature according to the cold rolled coil dyeing method. However, the fixing of the dye to the material can also be performed in a continuous manner, for example, using a roll-bake-roll-steam method, by steaming or using dry heat in a conventional manner. In particular, it is a dye mixture of the present invention containing a dye of the general formula (2) in which η is zero, which is advantageous for these pad dyeing methods. Similarly, the conventional printing and dyeing method for cellulose fibers can be performed in a single phase, such as printing with a printing paste containing sodium bicarbonate or some other acid bonding agent, and then at 100 to 103 ° C. Steaming, or in a two-phase process, such as printing with a neutral or weakly acidic printing paste, and passing the dyed material through a hot alkali bath enclosing the electrolyte or using a hot rolling noise solution containing the electrolyte for excessive milking After dyeing, the treated material is subjected to volume dyeing, or subsequent steaming or subsequent dry heat treatment, to produce a strong dyeing with a clear outline and a clean white background. The appearance of the printing and dyeing does not change greatly due to changes in fixing conditions. When borrowing dry heat fixation according to the conventional thermal fixation method, use hot air at 120 to 200 ° C. In addition to customary steam from 101 to 103 ° C, superheated steam and high-pressure steam at temperatures up to 160 ° C can also be used. Acid bonds that affect the fixation of the dye mixture of the present invention on cellulose fibers (Please read the notes on the back before filling this page) Dream

訂------------線J 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -15- 500775 A7 B7____ 五、發明說明（13) (請先閱讀背面之注意事項再填寫本頁) 結劑係包括例如水溶性鹼金屬及相同鹼土金屬之無機或有 機酸的鹼性鹽或於加熱下釋出鹼的化合物，及鹼金屬矽酸 鹽。特別適當者係爲鹼金屬氫氧化物及弱至中性無機或有 機酸之鹼金屬鹽，較佳之鹼金屬化合物係爲鈉及鉀化合物 。該酸鍵結劑係包括例如氫氧化鈉、氫氧化鉀、碳酸鈉、 碳酸氫鈉、碳酸鉀、甲酸鈉、磷酸二氫鈉、磷酸氫二鈉、 三氧乙酸鈉，、磷酸三鈉或水玻璃或其混合物，諸如例如氫 氧化鈉溶液與水玻璃之混合物。 * 本發明染料混合物較著稱的是其藉染色或印染施加於 纖維素纖維材料上時的高得色率。藉著淋洗去除未固色之 染料部分而於習用後處理之後所得之纖維素染色係具有優 越之耐溼牢度，尤其是因爲該未固色染料部分因其於冷水 中之良好溶解度而可輕易地洗除。 可使甩本發明染料混合物得到之染色及印染具有明亮 之色澤/尤其是於纖維素纖維材料上之染色及印染·具有極 佳之耐光牢度，尤其是極佳之耐溼牢度，諸如耐洗、耐磨 、耐水、耐海水、耐交染及耐酸及耐鹼汗漬牢度性質，及 良好之耐褶撊、耐熱壓燙及耐摩擦牢度。 經濟部智慧財產局員工消費合作社印製 此外，本發明染料混合物亦可使用於木材之纖維反應 性染色。而且，已給予不氈合或低氈合整理之木材（對照 例如 H.Rath，Lehrbuch der Textilchemie，Springer-Verlag ，第 3版（1972)，第295 — 299頁，尤其是使用Order ------------ Line J This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -15- 500775 A7 B7____ V. Description of the invention (13) (please first Read the notes on the back and fill in this page again.) Binders include, for example, water-soluble alkali metals and basic salts of inorganic or organic acids of the same alkaline earth metal or compounds that release bases under heating, and alkali metal silicates. Particularly suitable are alkali metal hydroxides and alkali metal salts of weak to neutral inorganic or organic acids. Preferred alkali metal compounds are sodium and potassium compounds. The acid-binding agent includes, for example, sodium hydroxide, potassium hydroxide, sodium carbonate, sodium bicarbonate, potassium carbonate, sodium formate, sodium dihydrogen phosphate, disodium hydrogen phosphate, sodium trioxoacetate, trisodium phosphate, or water glass. Or a mixture thereof, such as, for example, a mixture of a sodium hydroxide solution and water glass. * The dye mixture of the present invention is better known for its high color yield when applied to cellulose fiber materials by dyeing or printing. The cellulose dyeing system obtained after conventional post-treatment by removing the unfixed dye portion by leaching has superior wet fastness, especially because the unfixed dye portion can be dissolved due to its good solubility in cold water. Wash off easily. The dyeing and printing and dyeing obtained by throwing away the dye mixture of the present invention can have a bright color / especially on cellulose fiber materials. It has excellent light fastness, especially excellent wet fastness, such as Washing, abrasion resistance, water resistance, seawater resistance, cross dye resistance, acid and alkali resistance, fastness properties, and good fold resistance, heat resistance and friction fastness. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In addition, the dye mixture of the present invention can also be used for reactive dyeing of wood fibers. Moreover, unfinished or low-felt finished wood has been given (cf. for example H. Rath, Lehrbuch der Textilchemie, Springer-Verlag, 3rd edition (1972), pp. 295-299, especially

Hercosett 方法（第 29 8 頁）；J. S oc.Dy ers and Cο 1 ouri sts 1 972,93-99及1 975,33-44)可於極佳牢度性質下進行染色。木 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -16 - 500775 A7 B7____ 五、發明說明（14) 材上之染色方法係以習用方式由酸性介質進行。例如，乙 酸及/或硫酸銨或乙酸及乙酸銨或乙酸鈉可添加於染浴， 以得到所需之P Η。爲了得到可接受之染色標準，建議添 加習用勻色劑，例如以氰尿醯氯與3倍莫耳量之胺基苯磺 酸及/或胺基萘磺酸之反應產物計，或以例示硬脂胺與氧 化乙烯之反應產物計。例如，本發明染料混合物以先由 Ρ Η約3 · ·5至5 · 5之酸性染浴於ρ Η控制下進行盡染 法爲佳，之後隨著染色時間之終止，ρ Η移入中性，或許 爲翕達8 · 5之弱鹼性——尤其是極深之染色，以使本發 明染料混合物之染料與纖維間產生完全反應性鍵結。同時 ，該染料非反應性鍵結之部分。 經濟部智慧財產局員工消費合作社印製 ----.---；----— —丨 (請先閱讀背面之注意事項再填寫本頁) --線· 本發明所描述之方法亦應用於在包含其他天然取醯胺 或合成聚醯胺及聚胺基甲酸乙酯之纖維材料上產生染色。 欲染色之材料通常係導入溫度約4 0 °C之染浴中，於其中 攪拌一段時間’染浴隨之調至所需之弱酸性ρ Η，‘以弱乙 酸爲佳’實際染色係於6 0及9 8 °C間之溫度下進行。然 而，該染色亦可於高達1 〇 6°C之溫度下於鍋爐或密封之 染色裝置中進行。因爲本發明染料混合物之水溶性極佳， 故其亦可使用於習用連續染色方法。本發明染料混合物之 顏色強度極高。 本發明染料混合物將前述材料（以纖維材料爲佳）染 成具有極佳之牢度性質及低光致變色性之黃色。 以下貫施例係用以說明本發明。除非另有陳述，否則 份數及百分比係以重量計。重量百分比相對於體積份數係 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -17- 500775 A7 _____B7____ 五、發明說明（l5) 爲公斤對公升。實施例以化學式描述述之化合物通常係以 其鹽形式製備及單離，以鈉或鉀鹽爲佳，而以鹽形式使用 於染色。以下實施例所述之起始化合物，尤其是表例，可 同樣以游離酸形式或其鹽形式使用於該合成中，以鹼金屬 鹽爲佳，諸如鈉鹽或鉀鹽。 實施.例1 ， 1 0 0 0份含有1 5 0份下述式（A )之水溶液諸如 此 '染料之合成溶液，及1 0 0 0份含有1 5 0份下式（B )所示之水溶液諸如此染料之合成溶液 !.! i — 丨 if! (請先閱讀背面之注意事項再填寫本頁)Hercosett method (p. 298); J. S oc. Dy ers and Co 1 ours st 1 972,93-99 and 1 975,33-44) can be dyed with excellent fastness properties. The size of the wood paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -16-500775 A7 B7____ V. Description of the invention (14) The dyeing method on the wood is performed by acid media in a customary way. For example, acetic acid and / or ammonium sulfate or acetic acid and ammonium acetate or sodium acetate can be added to the dye bath to obtain the desired PP. In order to obtain acceptable dyeing standards, it is recommended to add custom leveling agents, for example, based on the reaction product of cyanuric chloride and 3 times the molar amount of aminobenzenesulfonic acid and / or aminonaphthalenesulfonic acid. Based on the reaction product of aliphatic amine and ethylene oxide. For example, in the dye mixture of the present invention, it is better to first perform an exhaust dyeing method under the control of ρ 由 from an acidic dyeing bath of ρ 3 about 3 · · 5 to 5 · 5. Then, as the dyeing time ends, ρ Η moves to neutral. Possibly weak alkaline of Trent 8.5-especially extremely deep dyeing, so as to produce a fully reactive bond between the dye and the fiber of the dye mixture of the present invention. At the same time, the dye is non-reactively bonded. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ----.---; ------ 丨 (Please read the precautions on the back before filling out this page) --- The method described in this invention is also It is used to produce dyeing on fiber materials containing other natural polyamides or synthetic polyamides and polyurethanes. The material to be dyed is usually introduced into a dyeing bath at a temperature of about 40 ° C, and stirred in it for a while. The dyeing bath is then adjusted to the desired weak acidity ρ 以, and "weak acetic acid is preferred". The actual dyeing system is at 6 Performed at temperatures between 0 and 98 ° C. However, the dyeing can also be performed in a boiler or a sealed dyeing apparatus at a temperature of up to 106 ° C. Because the dye mixture of the present invention has excellent water solubility, it can also be used in conventional continuous dyeing methods. The color intensity of the dye mixture of the present invention is extremely high. The dye mixture of the present invention dyes the aforementioned materials (preferably fibrous materials) to a yellow color having excellent fastness properties and low photochromic properties. The following examples are provided to illustrate the present invention. Unless stated otherwise, parts and percentages are by weight. The weight percentage relative to the volume fraction is based on the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -17- 500775 A7 _____B7____ 5. Description of the invention (l5) is kilograms per liter. The compounds described in the formulae of the examples are usually prepared and isolated in the form of their salts, preferably sodium or potassium salts, and are used in the form of salts for dyeing. The starting compounds described in the following examples, especially the table examples, can also be used in the synthesis in the form of free acids or salts, preferably alkali metal salts, such as sodium or potassium salts. Example 1. 100 parts containing 150 parts of an aqueous solution of the following formula (A) such as a synthetic solution of this dye, and 1000 parts containing 150 parts of the following formula (B) Aqueous solution such as the synthetic solution of this dye!.! I — 丨 if! (Please read the precautions on the back before filling this page)

CH^OSO.M ㈧ --線.CH ^ OSO.M ㈧-line.

OHOH

so3m (B) SO： I CH. r ch2-oso3m N = N— 經濟部智慧財產局員二涓費/0作社印製so3m (B) SO: I CH. r ch2-oso3m N = N—The fee of the Intellectual Property Bureau of the Ministry of Economy

ΚΛ C〇〇M (其中M係如前定義，以鈉爲佳）彼此混合。本發明染料 混合物以習用方式自結合溶液單離，染料（A )對染料< B )之莫耳混合比係爲5 8 ·· 4 2 ，例如使該染料溶液噴 霧乾燥。形成之本發明染料混合物含有來自合成之電解質 本紙張尺度適用中國國家標準（CNS〉A4規格（210 X 297公釐） 18- 500775 A7 B7 五、發明說明（16) 鹽類，諸如氯化鈉及硫酸鈉，具有極佳之染色性質，且當 藉著習用於纖維反性染料之盡染法施加於纖維素纖維材 料諸如棉或再生纖維素纖維上時，提供例如深而均勻之黃 色染色。 實施例2 .1 Ο Ο Ό份含有5 9份實施例1之式（A )之水溶液 諸如此染料之合成溶液.，與5 0 0份含有6 3 · 5份下式 (C )所示之水溶液諸如此染料之合成溶液 (請先閱讀背面之注意事項再填寫本頁)KΛCOm (wherein M is as defined above, preferably sodium) is mixed with each other. The dye mixture of the present invention is isolated from the binding solution in a conventional manner, and the molar mixing ratio of the dye (A) to the dye < B) is 5 8 ·· 4 2. For example, the dye solution is spray-dried. The formed dye mixture of the present invention contains synthetic electrolytes. The paper size is applicable to Chinese national standards (CNS> A4 specification (210 X 297 mm) 18- 500775 A7 B7 V. Description of the invention (16) Salts such as sodium chloride and Sodium sulfate has excellent dyeing properties, and when applied to cellulosic fibrous materials such as cotton or regenerated cellulose fibers by exhaustion methods conventionally used for fiber-reactive dyes, provides, for example, deep and uniform yellow dyeing. Example 2. 1 0 0 0 parts containing 5 9 parts of the aqueous solution of the formula (A) such as the synthetic solution of the dye in Example 1, and 500 parts containing 6 3 · 5 parts of the aqueous solution represented by the following formula (C) Synthetic solutions such as this dye (please read the precautions on the back before filling this page)

N = NN = N

S03M (C) 經濟部智慧財產局員工消費合作社印製 (其中Μ係如前定義，以鈉爲佳）混合，於兩合成溶液結 合之後，本發明染料混合物以習用方式諸如噴霧乾燥該染 料溶液而單離。形成之本發明染料混合物含有來自合成之 電解質鹽類諸如氯化鈉及硫酸鈉，染料（A )對染料（Β )之莫耳混合比係爲5 0 : 5 0，具有極佳之染色性質， 且當藉著習用於纖維反應性染料之冷軋卷堆染色法施加於 纖維素纖維材料諸如棉或再生纖維素纖維上時，提供例如 深而均勻之黃色染色。 -19- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 500775S03M (C) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (where M is as defined above, preferably sodium) and mixed. After the two synthetic solutions are combined, the dye mixture of the present invention is conventionally used, such as spray drying the dye solution. Single. The formed dye mixture of the present invention contains synthetic electrolyte salts such as sodium chloride and sodium sulfate, and the molar mixing ratio of the dye (A) to the dye (B) is 50:50, which has excellent dyeing properties. And when applied to a cellulosic fiber material such as cotton or regenerated cellulose fiber by a cold-rolled stack dyeing method conventionally used for fiber-reactive dyes, deep and uniform yellow dyeing is provided, for example. -19- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 500775

五、發明說明（17 ) 實施例3至1 9 以下表例係插述其他本發明染料绲合物，包含通式（ Y )及（z )之染料 1 ' D1 - N = N « K1 ⑺ D2 雄 N = N _ K2 (Z) 其組份係列不於各表例中。可根據本發明之方法製備，或 藉著混合個別染料或其溶液或化學性地借助其起始成分， 通式D1 - NH2及D2 - NH2之重氮成分，及通式 Η - K1及Η — K2之偶聯成分。 本發明染料混合物具有極佳之施用性質，當藉著技藝 界習用之染色及印染法施加時，以習用於纖維反應性染料 之施加及固色方法爲佳，於所述之材料（尤其是纖維素纖 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 之料 性染 升兩 提爲 色係 顏例 之比 好値 良數。 及之+° 質錄bl 性記'口 色所百 固上耳 佳欄莫 極 R 以 有M， 具 。 比 供染合 提印混 上及耳 } 色莫 料染之 材色此 維黃彼 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐）-20 - -n · (n n n n n n n 一 .cfj( n n -ϋ n n n IK I n , 500775 A7 B7 五、發明說明（I8) 經濟部智慧財產局員工消費合作社印製 MR ⑺:(z) 50:50 45:55 61:39 ! |52:48 ；55:45 | CN1 Μ 1-(4'-磺基苯基)-3-甲基吡唑-5-酮-4-基 H4'-磺基苯基)各羧基吡. 5-P-4-S 同上 1-(4'-磺基苯基)-3-甲基吡嗤-5.-4-基 i—苯基各甲基吡哩-5-酮-4-基 斑 t δί 翻 NO 1 t ¥稍 糊 浒 m m m Κ3 垮爾 3裝 擗 i m m κ) 鎏 嗥秘1 垮爾 V 糊 氍 数 ^ S 稍_ Ilf ϋ 旺· Ν3 Α銮 K3 m 綴 灌 祕擀 ΓΠ_ η _ u ^ 3繫 良料⑺ Κ1 2-乙醯胺基-5-磺基-4-胺苯基 同上 L .... 同上 ;同上 ί 同上 ......i K] 逡 i _ 4舊 同上 同上 同上 同上 >< 寸 r- -------\--II----------訂—I------線U (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -21 - 500775 Α7Β7 五、發明說明（19) 經濟部智慧財產局員工消費合作社印製 ^ Β 名. cn 〇〇 ζ} E〇 CNI δ cn 爾 齡 1摊i 黌i s Μ 1~1 IT) 晅 i CO ί 擀 1湖 -ί s Μ t—( 1： 叫 n i & 1 CO Ϊ 擀 1 _ f计 s ffi 二 ιΛ S m N3 m 彩 m 祕资: 稍 M 稍 s 塵 ，慳 丨Κ) 銮 1 寸 m N3 m 韜 Μ I i i 城1 CN Μ 浒 i 翻 繼 K] 銮 | « V糊 4 ^ n ϋ 1 擀 懲 涯‘ 稍 νΛ νΛ 觀 s i to ή s _ S ή m g 1 11 裝械I in 1 « WH m 士娜*ΠΗΙ 浒 m i τιτζ ϋ i杯 i rnm Μ κ稍 m S寸 iR- H： 1： m a鏗 a _ ..............i 丄] H： IE ϋ： ϋ ϋ： >< ω oo ON 〇 r"""H m 寸 ----‘---^---1 I · I I (請先閱讀背面之注意事項再填寫本頁) .線· 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） - 22- 500775 A7 B7 五、發明說明（2〇) 經濟部智慧財產局員工消費合作社印製 μ 0 ^ Β C^i 〇〇 VO όί Os CN ΙΕ 叵 # i 睡 CO m 擗 f摊1 V i V E r«H 11 1： S 叵 ϋ IE 11 Ξ P 伴 懲 1 Μ糊 I CET5 ή 祕 & ιΛ s _ 讎稍 bO ^ csi ^ i 銮ϋ 2¾ , % tt 2 i v應城1 m: 1： t.............i [1 1： 免灑 V ii ^ n3 湖銮 祕彩}1 氍t A握《 苳觀 m ^ f S _ 穴i齡 .渾備 3资塵 塵 w ϋ ^ N3 祕擊f fr經t A懷_ >< ω wn 卜 oo 〇\ ----.--J--—1 I --I (請先閱讀背面之注意事項再填寫本頁) 訂！ 線· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -23-V. Description of the invention (17) Examples 3 to 19 The following table examples are inserts of other dye dye compounds of the present invention, including dyes of the general formulae (Y) and (z) 1 'D1-N = N «K1 ⑺ D2 Male N = N _ K2 (Z) The component series is not in the table examples. It can be prepared according to the method of the present invention, or by mixing individual dyes or their solutions or chemically relying on their starting ingredients, diazo components of the general formula D1-NH2 and D2-NH2, and general formulas Η-K1 and Η — K2 coupling component. The dye mixture of the present invention has excellent application properties. When applied by the dyeing and printing methods customary in the art world, the application and fixing methods of fiber-reactive dyes are preferred. The materials (especially fibers) Plain fiber (please read the precautions on the back before filling this page) The material dyeing printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs is mentioned as a better color ratio. ++ bl sex notes' color of Baigu upper ear Jialan Moji R to have M, with. than for dyeing and printing and mixing on the ear} color material dyed this color yellow paper paper size applicable to China Standard (CNS) A4 specification (210 x 297 mm) -20--n · (nnnnnnn a.cfj (nn -ϋ nnn IK I n, 500775 A7 B7) V. Description of the invention (I8) Employees ’Intellectual Property Bureau, Ministry of Economic Affairs Cooperative printed MR ⑺: (z) 50:50 45:55 61:39! | 52:48; 55:45 | CN1 Μ 1- (4'-sulfophenyl) -3-methylpyrazole-5 -Keto-4-yl H4'-sulfophenyl) each carboxypyridine. 5-P-4-S Ibid. 1- (4'-sulfophenyl) -3-methylpyridine-5.-4- Phenyl i-phenylmethylpyrazol-5-one -4- 基 斑 t δί Turn over NO 1 t ¥ Slightly 浒 mmm Κ3 尔尔 3 装 擗 imm κ) Secret 1 尔 ー ル V 氍 ^^ S slightly_ Ilf ϋ ϋ · Ν3 Α 銮 K3 m Secret ΓΠ_ η _ u ^ 3 series of good ingredients ⑺ Κ1 2-ethylamido-5-sulfo-4-aminephenyl Ibid. I ... Ibid; Ibid. Ibid ... i K]逡 i _ 4 old ibid ibid ibid > < inch r- ------- \-II ---------- order --I ------ line U (please Please read the notes on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -21-500775 Α7Β7 V. Description of the invention (19) Employee Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Printed ^ Β name. Cn 〇〇ζ} E〇CNI δ cn Erling 1 booth i 黉 is Μ 1 ~ 1 IT) 晅 i CO ί 11 湖 -ί s Μ t— (1: called ni & 1 CO Ϊ 1 1 _ f meter s 2 m Λ S m N3 m color m Secret funds: slightly M slightly s dust, 悭 丨 Κ) 銮 1 inch m N3 m TaoM I ii city 1 CN Μ 浒 i succession K]銮 | «V 44 ^ n ϋ 1 Roll over the punishment '' ν ν ν Λ si to ή s _ S ή mg 1 11 Equipment I in 1 «WH m Shi Na * ΠΗΙ 浒 mi τιτζ ϋ i cup i rnm Μ κ slightly m S inch iR- H: 1: ma 铿 a _............ ..i 丄] H: IE ϋ: ϋ ϋ: > < ω oo ON 〇r " " " H m inch ----'--- ^ --- 1 I · II (Please read first Note on the back page, please fill in this page again). Line · This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm)-22- 500775 A7 B7 V. Description of Invention (2) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the employee's consumer cooperative μ 0 ^ Β C ^ i 〇〇VO ό Os CN ΙΕ 叵 # i Sleep CO m 擗 f booth 1 V i VE r «H 11 1: S 叵 ϋ IE 11 Ξ P with punishment 1 Μ paste I CET5 Price & ampΛ s _ 雠 slightly bO ^ csi ^ i 銮 ϋ 2¾,% tt 2 iv Yingcheng 1 m: 1: t ............. i [1 1: Free spray V ii ^ n3 Lake 銮 secret color} 1 氍 t A grip "苳 观 m ^ f S _ acupoint i age. Complete 3 resources dust w ϋ ^ N3 secret hit f fr Jing t A Huai_ > < ω wn oo oo 〇 \ ----.-- J --— 1 I --I (Please read the notes on the back before filling this page) Order! Line · This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -23-

Claims (1)

申請專利範圍 附件一（A): 弟88116634號專利申請案 中文申請專利範圍修正本 民國90年9 1、一種染料混合物，其包含一或多種選自以 示而定義於通式（1 )之染料，及一或多種選自以 示而定義於通式（2)之染料，染料或染料等（1 料或染料等（2 )之莫耳比係爲7 ⑴ R6 •N = N—^ J, | •、 (2) 其中： 經濟部智慧財產局員工消費合作社印製 C请先閲讀背希之注意事項存填寫本頁) 月修正 T所列 下所列 )對染 7 5 至Attachment 1 (A) to the scope of the patent application: The patent application No. 88116634 is amended in Chinese. The scope of the patent application in the Republic of China is 90 years. 1. A dye mixture containing one or more dyes selected from the group defined by the general formula (1). , And one or more selected from the dyes, dyes, or dyes defined in the general formula (2) as shown (the mole ratio of the material or dye (2) is 7 ⑴ R6 • N = N— ^ J, •, (2) Among them: Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. C Please read the precautions and fill in this page first.) Monthly amendments listed under T) NH-CO-NH-CO- Μ 係爲氣或驗金屬， Υ 1係爲乙烯基或乙基，其/3 -位置經鹼可去除之取代基 所取代； Υ2具有Υ1之定義之一； R 1係爲氫、氯、具有1至4個碳原子之烷基、具有1至 4個碳原子之烷氧基、羧基或磺基； R2係爲氫、具有1至4個碳原子之烷基或<具有1至4個 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 500775 A8 B8 C8 D8 六、申請專利範圍 碳原子之烷氧基； (請先聞讀背面之注意事項再填寫本頁) R3係爲氫、具有1至4個碳原子之烷基、具有1至4個 碳原子之烷氧基或磺基； R 係爲胺基或具有1至6個碳原子而可經取代之烷基； R4係爲氫、氯、具有1至4個碳原子之烷基、具有1至 4個碳原子之烷氧基、或磺基； R5係爲氫、具有1至4個碳原子之烷基或具有1至4個 碳原子之烷氧基； R6係爲氫、具有1至4個碳原子之烷基、具有1至4個 碳原子之烷氧基、或磺基； η 係爲零或1 ; R 7係爲甲基或羧基； R8係爲氫、具有1至4個碳原子之烷基、具有1至4個 碳原子之烷氧基或氯； R9係爲氫、具有.1至4個碳原子之烷基、具有1至4個 碳原子之烷氧基或氯； m 係爲零、1或2 (當m爲零時，此基團係爲氫）。 經濟部智慧財產局員工消費合作社印製 2、 如申請專利範圍第1項之染料混合物，其中R 1及 R 2皆爲氫。 3、 如申請專利範圍第1項之染料混合物，其中R係 爲甲基。 4、 如申請專利範圍第1項之染料混合物，其中R 3係 爲磺基，且位於一 N Η — C〇一 R基之對位。 5、 如申請專利範圍第1項之染料混合物，其中R 4及 本紙張尺度逋用中國國家標準（CNS ) Α4規格（210Χ297公釐）-2 - 500775 A8 B8 C8 D8 六、申請專利範圍 R 5皆爲氫。 6、 如申請專利範圍第1項之染料混合物，其中r 8及 R9皆爲氣’且m係爲1。 7、 如申請專利範圍第1項之染料混合物，其中^係 爲零。 8、 如申請專利範圍第1項之染料混合物，其中^係 爲1，而R 6係爲氫。 9、 如申請專利範圍第1項之染料混合物，其中 Υ 1 — S〇2 —及Υ 2 — S 0 2 —基團係鍵結於苯環，個別與 偶氮基及一 NH — C Η -基成對位。 1 0、如申請專利範圍第1項之染料混合物，其中γ 1 及Υ 2個別係爲乙烯基、/5 -氯乙基或/3 一硫酸根絡乙基。 1 1、如申請專利範圍第1項之染料混合物，其中於 通式（1 )之染料中，該Υ1 - S〇2 —基團係與該偶氮基 成間位或對位，Y 1係爲Θ -硫酸根絡乙基，R 1及R 2皆 爲氫，R係爲甲基，且R 3係鍵結於苯環，與該 L-------—— (請先閎讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 Η 1 Ν 式 Υ 通 I 於 中 其 物 合 混 。料 基 3染 磺1 頁 係 I 且1 ，第 立 圍 對請 成利 基專 R 請 | 申 ο 如 中 料 染L 之 ο ) S 基 爲 係 4 R ， 位 零對 爲或 係位 η 間 數成 匕曰 .二、1 ί 基 式氮 學偶 ft ^ 該係 係 R 基 ， 磺 基此 氧 ’ 甲 1—1 或爲 基係 甲III 、 且 氫， 基 甲 或 氬 爲 係 環 苯 於 結 鍵 氫原 爲0 皆之 9 .環 R Μ 画 及唑 8 吼 與 R 位 對 成 子 IX 中 其 物 合 混 染 之 項 2 IX 第 圍 範 利 專 請 串 如 本紙張尺度適用中國國家揉準（CNS ) A4規格（210X297公釐） -3 - 500775 Α8 Β8 C8 D8 申請專利範圍 R4及R5皆爲氫，而γ2 一 S〇 基團係與偶氮基成對位 1 4、如申請專利範圍第i項之染料混合物，其中於 通式（2 )之染料中，化學式指數^係爲1 ，R 4及R 5皆 爲氫，Y2 — s〇2—基團係與—nh — C〇一基團成對位 ’ Υ 係爲/3 —硫酸根絡乙基’該一 νη—CO —基團係與 偶氮基成對位，R 6、R 8及R 9各爲氫，m係爲1 磺基係鍵結於苯環，與吡唑酮之氮原子成對位。 1 5、如申請專利範圍第1項之染料混合物，其包含 式（A)之染料及式（B)之染料 ’ . so3m 而此 (請先閎讀背面之注意事項再填寫本頁)Μ is gas or metal detection, Υ 1 is vinyl or ethyl, its / 3-position is replaced by a base-removable substituent; Υ 2 has one of the definitions of Υ 1; R 1 is hydrogen, chlorine, has An alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, a carboxyl group or a sulfo group; R2 is hydrogen, an alkyl group of 1 to 4 carbon atoms, or < 1 to 4 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 500775 A8 B8 C8 D8 VI. Alkoxy group of carbon atom for patent application; (Please read the precautions on the back before filling this page) R3 series Is hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkoxy group or sulfo group having 1 to 4 carbon atoms; R is an amine group or an alkyl group which may be substituted with 1 to 6 carbon atoms; R4 is hydrogen, chlorine, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, or sulfo; R5 is hydrogen, alkyl having 1 to 4 carbon atoms, or An alkoxy group having 1 to 4 carbon atoms; R6 is hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a sulfo group; η is zero or 1; R 7 is methyl or carboxyl; R8 is hydrogen, alkyl having 1 to 4 carbon atoms, alkoxy or chlorine having 1 to 4 carbon atoms; R9 is hydrogen , An alkyl group having .1 to 4 carbon atoms, an alkoxy group or chlorine having 1 to 4 carbon atoms; m is zero, 1 or 2 (when m is zero, this group is hydrogen). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 2. If the dye mixture in the first scope of the patent application, R 1 and R 2 are hydrogen. 3. For the dye mixture of item 1 of the patent application, where R is methyl. 4. The dye mixture according to item 1 of the scope of patent application, in which R 3 is a sulfo group and is located in the para-position of a N Η —C0-R group. 5. For the dye mixture in item 1 of the scope of patent application, in which R 4 and this paper size are in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm)-2-500775 A8 B8 C8 D8 6. Application scope of patent R 5 All are hydrogen. 6. For the dye mixture of item 1 of the patent application scope, wherein r 8 and R 9 are both gas' and m is 1. 7. For the dye mixture of item 1 of the patent application, where ^ is zero. 8. For the dye mixture of item 1 in the scope of patent application, where ^ is 1 and R 6 is hydrogen. 9. For example, the dye mixture of item 1 in the scope of the patent application, in which the Υ 1 — S〇 2 — and Υ 2 — S 0 2 — groups are bonded to the benzene ring, and are individually linked to the azo group and a NH — C Η- Base pairs. 10. The dye mixture according to item 1 of the scope of patent application, wherein γ 1 and 个别 2 are each vinyl, / 5-chloroethyl or / 3 monosulfoethyl. 1 1. The dye mixture according to item 1 of the scope of patent application, wherein in the dye of the general formula (1), the Υ1-S〇2- group is meta- or para-position with the azo group, and Y 1 is Θ-Sulfate ethyl, R 1 and R 2 are both hydrogen, R is methyl, and R 3 is bonded to the benzene ring, and this L -------—— (Please read first Note on the back, please fill out this page again) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Η 1 Ν 通 I I mix things together. The material base 3 is dyed 1 and the page is I and 1. The rivet pair should be a niche special R. Please apply as in the material dyeing of L.) The S base is 4 R and the bit-zero pair is or the position η. The number is two. 1 、 Basic nitrogen couple ft ^ This system is R group, sulfo this oxygen 'A 1-1 or is a base A III, and hydrogen, the base or argon is a ring benzene in The bonding hydrogen is 0 and 9. The ring R Μ painting and azole 8 and the R-position pair IX are mixed and dyed items of IX 2 IX Fan Li special please string as the paper size is applicable to Chinese countries. (CNS) A4 specifications (210X297 mm) -3-500775 A8 B8 C8 D8 The scope of patent applications R4 and R5 are both hydrogen, and the γ2-S0 group is in para-position with the azo group. The dye mixture of item i, wherein in the dye of the general formula (2), the chemical formula index ^ is 1, R 4 and R 5 are both hydrogen, Y 2 —s〇2—group system and —nh — C 0 1 group The group is in the para-position 'Υ system is / 3-sulfate complex ethyl' The one νη-CO- group is in para-position with the azo group, R 6, R 8 and R 9 Each is hydrogen, m is 1 and sulfo is bonded to a benzene ring and is in para-position with the nitrogen atom of pyrazolone. 15. If the dye mixture in item 1 of the scope of patent application includes dyes of formula (A) and dyes of formula (B) '. So3m and this (please read the precautions on the back before filling this page) NH-CONH-CO ㈧ 經濟部智慧財產局員工消費合作社印製印 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs OHOH S〇3M COOM (B) 其中M係如申請專利範圍第1項之定義。 1 6、如申請專利範圍第1項之染料混合物，其包含 式（A y之染料及式(C )之染料 本紙張尺度適用中國國家標準（CNS ) A4規格（2ί〇Χ297公釐） -4 · 500775 A8 B8 C8 D8 六、申請專利範圍 so； I CH, -N 2 N- so3m NH, ㈧ NH - C〇· CH3 CHv〇S〇iMS〇3M COOM (B) where M is as defined in item 1 of the scope of patent application. 16. If the dye mixture in item 1 of the scope of patent application includes dyes of formula (A y and dyes of formula (C)), the size of the paper is applicable to China National Standard (CNS) A4 (2ί〇 × 297 mm) -4 500775 A8 B8 C8 D8 6. Application for patent scope so; I CH, -N 2 N- so3m NH, ㈧ NH-C〇 · CH3 CHv〇S〇iM __ ------ΛΨ ! (碕先閎讀背面之注意事項再填寫本頁〕 其中M係如申請專利範圍第1項之定義。 1 7、如申請專利範圍第1至1 6項中任一項之染料 混合物，其中通式（1 )之染料或染料等及通式（2 )之 染料或染料等之莫耳混合比係爲6 0 : 4 0至4 0 : 6 〇 〇 1 8、如申請專利範圍第1項之染料混合物，其係用 以染色含羥基-及/或羧醯胺基之材料’尤其是纖維材料 〇 1 9、如申請專利範圍第1 8項之染料混合物，其中 該染色係進行如下，即將該染料混合物施加於材料上，並 藉由加熱或使用鹼劑或使用兩者而使其固定於該材料上。 、π 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X：297公釐） -5 -__ ------ ΛΨ! (碕 Read the notes on the reverse side before filling out this page) where M is as defined in item 1 of the scope of patent application. 1 7. As in items 1 to 16 of the scope of patent application The dye mixture according to any one, wherein the molar mixing ratio of the dyes or the dyes of the general formula (1) and the dyes or the dyes of the general formula (2) is 60:40 to 40: 6 00 8 For example, the dye mixture of item 1 in the scope of patent application is used to dye materials containing hydroxyl- and / or carboxyamido groups, especially fiber materials. The dyeing process is as follows, that is, the dye mixture is applied to the material, and it is fixed to the material by heating or using an alkali agent or both. Π Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Paper size applies to China National Standard (CNS) A4 (210X: 297 mm) -5-