TW499446B - Curable composition for planarized film, and planarized film - Google Patents
Curable composition for planarized film, and planarized film Download PDFInfo
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- TW499446B TW499446B TW089110994A TW89110994A TW499446B TW 499446 B TW499446 B TW 499446B TW 089110994 A TW089110994 A TW 089110994A TW 89110994 A TW89110994 A TW 89110994A TW 499446 B TW499446 B TW 499446B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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Abstract
Description
499446 A7 ____ B7五、發明説明（1 ) 本發明係關於平坦化膜用硬化性組成物以及平坦化膜 。更詳細而言，係關於作爲欲形成使用於液晶顯示元件（ L C D )用彩色濾器以及電荷結合元件（C C D )用彩色 濾器的保護膜之材料時可使用較適當的平坦化膜用硬性化 組成物及平坦化膜。 經濟部智慧財產局員工消費合作社印製 先前技術 L C D 或 C 溶劑、酸或鹼溶 濺塗膜形成配線 下。因此，欲預 對於這些處理具 面上。 此保護膜被 層，或保護膜上 爲平滑且強韌者 光性者、經長時 具有優良的耐水 。作爲形成滿足 開平5 — 7 8 4 C D等放射線裝置裡， 液等的顯示元件的浸漬 電極層時，元件表面會 防經由此處理所造成的 有耐性之薄膜所成的保 要求爲，形成該保護膜 所形成的層面其具有高 、具有透明性者、具有 間不會引起著色、變黃 性、耐溶劑性、耐酸性 這些各種特性的保護膜 5 3號公報所揭示的含 其製造步驟中進行 處理，又，經由飛 局部性曝曬於高溫 元件惡化或損傷， 護膜設置於元件表 時必須對基體或下 接著性者、膜自身 較高耐熱性以及耐 、白化等變質者、 以及耐鹼性等性能 之材料，已知有特 具有環氧丙基之聚 合物之熱硬化性組成物。 對於此熱硬化性組成物，例如有經如下述而形成保護 膜。 首先，形成保護膜必須於基體的表面上塗佈熱硬化性 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-4 - 請 先 閱 讀 背 面 之 注 意 事 項 再-I 填 ♦·' 499446 A7 B7 五、發明説明（2 ) 組成物。其次進行經塗佈的熱硬化性組成物的預先焙烤， 其後經本焙烤形成保護膜。 另一方面，對於超扭轉絲狀液晶（S T N )方式的彩 色液晶顯示元件，與扭轉絲狀液晶（T N )方式的液晶顯 示元件作比較，晶胞間隔的均一性極爲重要。因此，作爲 使用於S T N方式的彩色液晶顯示元件的基板，其表面被 要求爲較高平坦性者。其理由爲因爲使用較低表面的平坦 性的基板時，所得之液晶顯示元件會顯示斑點。 又，採用動態定址方式等的新型驅動方式時，可得到 比過去的S T N方式者更爲高的顯示速度，隨之由晶胞間 隔必須更爲薄且更高均一性的事看來，使用於此液晶顯示 元件的基板上，其表面被要求爲極高的平坦性。 然而，對於例如形成彩色濾器所形成的基板而言，其 表面因彩色濾器而會形成凹凸現象。因此，使用過去的熱 硬化性組成物，於彩色濾器形成的表面上形成保護膜時， 對於該熱硬化性組成物的塗佈步驟以及欲焙烤步驟而言， 雖可形成較高表面平坦性的塗膜，但對於本焙烤步驟而言 ，因於比較高的溫度下處理，故熱硬化性組成物的塗膜會 成流動化，該塗膜的表面會因彩色濾器的凹凸而變形’故 難以得到表面平坦性高的硬化膜。 本發明係提供一種平坦化膜用硬化性組成物以及平坦 化膜，其依據上述所成者，其目的爲即使表面的平坦性較 低的基體，該基體上可形成平坦性較高的硬化膜’且可形 成具有表面硬度高、耐熱性、耐酸性、耐鹼性等各種優良 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐）-5 - 請 先 閲 讀 背 之 注 意 事 項 再 資 經濟部智慧財產局員工消費合作社印製 499446 A7 B7 五、發明説明（3 ) 的耐性之硬化膜。 (請先閲讀背面之注意事項再填寫束fo 本發明的其他目的以及優點由下述說明可淸楚明瞭。 所謂本發明’本發明的上述目的及優點，第1爲含有 (A )下述式（1 ) 式中’ R1表示爲氫原子或碳數爲1至5的烷基、R2 表示爲氫原子或碳數爲1至2的烷基，m表示爲1至8的 整數。 —ch2-chrM- L〇CmH2m—1。严 具有上述所表示的構造單位對整個重複單位而言爲 2 0莫耳％以上含於聚合物或共聚物， (B ) ( A )成分以外的環氧基樹脂，以及 (C )因熱或放射線產生酸的化合物 爲特徵之平坦化膜用硬化性組成物以及其所得之平坦 膜而達成。 經濟部智慧財產局員工消費合作社印製 本發明的硬化性組成物因含有由環氧基化合物以及熱 或放射線產生酸的化合物，可經由加熱或放射線照射而使 其硬化。因此，本焙烤進行前，藉硬化性組成物的塗膜之 低溫加熱或放射線照射，使該塗膜表面硬化，而可防止因 本焙烤的塗膜流動化，其結果可形成表面的平坦性較高的 硬化膜。 以下則對本發明的硬化組成物作詳細的說明。 本紙張尺度適用中國國家標準（ CNS ) A4規格（210X 297公釐）-6 - 499446 Α7 Β7 五、發明説明（4 ) 本發明的硬化組成物係含有，含以特定比例的特定構 造單位之聚合物或共聚物（以下，稱「特定聚合物」。） 的成分（A)、與作爲環氧樹脂的成分（b)、與因熱或 放射線而產生酸的化合物（C )所成者。 〈成分（A )〉 作爲成分（A )所使用的特定聚合物係含有上述式（ 1 )所表示的構造單位所成者。 對於上述式（1 )而言，m爲1至8，1至4的整數 爲佳。又，R1表示爲氫原子或碳數爲1至5的烷基。此烷 基可爲直鏈或支鏈任一皆可。作爲其具體例子可舉出甲基 、乙基、η —丙基、異丙基、n —丁基、異丁基、s e c —丁基、t e r t — 丁基以及n -戊基。且，r2爲氫原子 、甲基或乙基。 欲導入式（1 )所表示的構造單位所使用的單量體（ 以下稱「特定單量體」。）的下述式（2) ch2=chr1 R2499446 A7 ____ B7 V. Description of the Invention (1) The present invention relates to a curable composition for a flattening film and a flattening film. In more detail, when it is intended to form a protective film for a color filter for a liquid crystal display device (LCD) and a color filter for a charge-coupled device (CCD), a more suitable hardening composition for a flattening film can be used. And flattening film. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Prior art L C D or C Solvent, acid or alkali solution Spattered coating film forms wiring. Therefore, I would like to predict the specific aspects of these treatments. This protective film is smooth, strong, or light-resistant, and has excellent water resistance over time. When forming an impregnated electrode layer that satisfies display elements such as Kaiping 5 — 7 8 4 CD and liquid display devices, the surface of the element is protected against the resistance caused by this process. The layer formed by the film is a protective film that has high and transparent properties, and does not cause coloring, yellowing, solvent resistance, and acid resistance, among other characteristics. It is performed in the manufacturing process disclosed in JP 3 3 Treatment, and through localized exposure to high-temperature components to deteriorate or damage, the protective film must be placed on the surface of the component or the substrate, the film itself has higher heat resistance and resistance to deterioration, such as whitening, and alkali resistance As a material having the same properties, a thermosetting composition having a polymer having a glycidyl group is known. For this thermosetting composition, a protective film is formed, for example, as described below. First of all, to form a protective film, the surface of the substrate must be coated with thermosetting. The paper size applies Chinese National Standard (CNS) A4 (210X297 mm) -4-Please read the precautions on the back before -I fill in ♦ · ' 499446 A7 B7 V. Description of the invention (2) Composition. Next, pre-baking of the applied thermosetting composition is performed, and thereafter, the baking is performed to form a protective film. On the other hand, for a color liquid crystal display device of the super twisted filament liquid crystal (S T N) method, compared with a liquid crystal display device of the twisted filament liquid crystal (T N) method, the uniformity of the cell interval is extremely important. Therefore, as a substrate for a color liquid crystal display element using the STN method, a surface having a high flatness is required. The reason is that when a flat substrate having a relatively low surface is used, the resulting liquid crystal display element may exhibit speckles. In addition, when a new driving method such as a dynamic addressing method is used, a display speed higher than that of the conventional STN method can be obtained, and in accordance with the fact that the cell interval must be thinner and more uniform, it is used in The surface of the substrate of this liquid crystal display element is required to have extremely high flatness. However, for a substrate formed by, for example, forming a color filter, the surface may be uneven due to the color filter. Therefore, when using a conventional thermosetting composition to form a protective film on a surface formed by a color filter, the coating step and the baking step of the thermosetting composition can form a high surface flatness. The coating film, but in this baking step, the coating film of the thermosetting composition is fluidized because it is processed at a relatively high temperature, and the surface of the coating film is deformed by the unevenness of the color filter. A cured film having a high surface flatness was obtained. The present invention provides a hardening composition for a flattening film and a flattening film. According to the above, the purpose is to form a hardened film with a high flatness even on a substrate having a low flatness on the surface. 'And can form a variety of excellent surface hardness, heat resistance, acid resistance, alkali resistance, etc. This paper size applies Chinese National Standards (CNS) A4 specifications (210X297 mm)-5-Please read the precautions before back Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 499446 A7 B7 5. The hardened film of the invention description (3). (Please read the precautions on the back before filling in the fo. Other objects and advantages of the present invention will be clear from the following description. The so-called "objectives and advantages of the present invention", the first is the following formula containing (A) (1) where R1 is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, R2 is a hydrogen atom or an alkyl group having 1 to 2 carbon atoms, and m is an integer of 1 to 8. —ch2- chrM- L〇CmH2m-1. Strictly having the structural unit indicated above is 20 mol% or more for the entire repeating unit. It is contained in the polymer or copolymer, and epoxy resin other than (B) (A) component. And (C) A hardening composition for a flattening film characterized by a compound that generates an acid due to heat or radiation and a flat film obtained therefrom. The employee's cooperative of the Intellectual Property Bureau of the Ministry of Economy printed the hardening composition of the present invention Because it contains epoxy compounds and compounds that generate acid from heat or radiation, they can be hardened by heating or radiation. Therefore, before the baking, the coating film of the hardenable composition is heated at low temperature or radiated by radiation. The coating film surface It can prevent the coating film from fluidizing due to the baking, and as a result, a hardened film with a high flatness of the surface can be formed. The hardened composition of the present invention will be described in detail below. This paper size applies the Chinese national standard (CNS ) A4 specification (210X 297 mm)-6-499446 A7 B7 V. Description of the invention (4) The hardened composition of the present invention contains a polymer or copolymer (hereinafter referred to as "" "Specific polymer".) The component (A), the component (b) as an epoxy resin, and the compound (C) that generates an acid due to heat or radiation. <Component (A)> as the component (A The specific polymer used includes the structural unit represented by the above formula (1). For the above formula (1), m is preferably an integer of 1 to 8, and an integer of 1 to 4 is preferred. R1 represents Is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. The alkyl group may be either straight or branched. Specific examples include methyl, ethyl, η-propyl, and isopropyl. , N-butyl, isobutyl, sec-butyl, tert-butyl, and n -Pentyl. R2 is a hydrogen atom, a methyl group, or an ethyl group. To introduce a singular body (hereinafter referred to as a "specific singular body") used in the structural unit represented by the formula (1) ( 2) ch2 = chr1 R2
I COOCmH2m— CsT~/CH2 ο 式中，R1、R2以及m的定義與上述式（1 )相同。 作爲上述式（2 )所表示的單量體，例如可舉出（甲基） 丙烯酸環氧丙基、α -乙基丙烯酸環氧丙基、n 一丙 基丙烯酸環氧丙基、α - η - 丁基丙烯酸環氧丙基、（甲 基）丙烯酸—3 ，4 —環氧丁基、（甲基）丙烯酸—4， 5 —環氧戊基、（甲基）丙烯酸一 6 ，7 —環氧己基、（ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）-7 - (請先閱讀背面之注意事項再填寫本資) •裝· 訂 經濟部智慧財產局員工消f合作社印製 499446 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（5 ) 甲基）丙烯酸一 6 ，7 —環氧戊基、（甲基）丙烯酸甲基 環氧丙基。其中，特別以（甲基）丙烯酸環氧丙基爲佳。 這些單量體可單獨或2種以上組合使用。 作爲成分（A )所使用的特定聚合物亦可僅如上述式 (1 )所表示的構造單位所成的聚合物。可含有比例爲 7 〇莫耳％以下爲佳、較佳爲5至6 0莫耳％ 、特佳爲 2 0至5 0莫耳％的式（1 )所表示的構造單位以外之構 造單位。 作爲欲導入式（1 )所表示的構造單位以外的構造單 位之單量體（以下成「其他單量體」。）例如可舉出（甲 基）丙烯酸甲基、（甲基）丙烯酸乙基、（甲基）丙烯酸 丁基、（甲基）丙烯酸一2—乙基己基、（甲基）丙烯酸 苯基、（甲基）丙烯酸環己基、（甲基）丙烯酸三環〔 5 . 2 · 1 · 0 2 ’ 6〕癸烷—8 -基（該技術領域中以（ 甲基）丙烯酸二環戊基之慣用名詞）、（甲基）丙烯基二 環戊基氧基乙基、（甲基）丙烯基異冰片基等的（甲基） 丙烯基酯；苯乙烯、α —甲基苯乙烯、p —甲基苯乙烯、 乙烯基萘等的乙烯基芳香族系化合物、苯基馬來酸酐縮亞 胺、環己基馬來酸酐縮亞胺、Τ基馬來酸酐縮亞胺、Ν -琥珀銑酵亞胺基- 3 -馬來酸酐縮亞胺苯甲酸酯、Ν -琥 珀銑酵亞胺基- 4 -馬來酸酐縮亞胺丁酸酯、Ν -琥珀銑 酵亞胺基- 6 -馬來酸酐縮亞胺己酸酯、Ν 一琥珀銑酵亞 胺基一 3 一馬來酸酐縮亞胺丙酸酯、Ν -（ 9 一吖啶基） 馬來酸酐縮亞胺等的馬來酸酐縮亞胺化合物。這些單量體 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐)~ I-------1Τ (請先閲讀背面之注意事項再填寫本'r) 裝 訂 4 499446 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（6 ) 可單獨或2種以上組合使用。 作爲成分（A )使用的特定聚合物之分子量，經由塗 佈所得之硬化性組成物之溶液，表面可形成平坦的塗膜即 可無特別限制，因應所形成塗膜之厚度，硬化性組成物的 溶液之塗佈條件、目的等作適宜的選擇，但通常聚苯乙烯 換算重量平均分子量爲3，000至300，000的範 圍爲佳，3，000至100，000的範圍較佳。 又，作爲成分（A )，使用具有式（1 )所表示構造 單位與其之外的構造單位之特定聚合物時，該聚合物可爲 特定單量體與其他單量體的隨機共聚物，以及異分子共聚 物的任一種皆可，而以隨機共聚物爲佳。 〈成分（B )〉 作爲成分（A )以外的環氧樹脂，可使用例如雙酚A 型環氧樹脂、雙酚F型環氧樹脂、酚漆用酚醛環氧樹脂、 甲酚漆用酚醛環氧樹脂。這些販賣品皆可獲得。 例如可舉出，作爲雙酚A型環氧樹脂，有埃皮科特1001、同 10 02、同 1003、同 1004、同 1007、同 1〇〇9、同 1010、同 828 (以上， 油化shell環氧股份有限公司製、作爲雙酚f型環氧樹脂有 埃皮科特8 0 7、同8 3 4 (以上，油化shell環氧股份有 限公司製）作爲酚基漆用酚醛型環氧樹脂、有埃皮科特 1 5 2、同1 5 4、同1 5 7 Η 6 5 (以上，油化shell環 氧股份有限公司製）EPPN201、同202 (以上， 本紙張尺度適用中國國家標準（（^5)八4規格（210\297公釐）-9- ---------mjp 裝-- (請先閲讀背面之注意事項再·填寫本I-) 、-t d 499446 A7I COOCmH2m— CsT ~ / CH2 ο In the formula, the definitions of R1, R2, and m are the same as the formula (1). Examples of the singular body represented by the formula (2) include (meth) acrylic acid glycidyl group, α-ethylacrylic acid glycidyl group, n-propylacrylic acid glycidyl group, and α-η -Glycidyl butyl acrylate, (meth) acrylic acid 3-4, epoxy butyl, (meth) acrylic acid -4, 5-epoxyamyl, (meth) acrylic acid -6, 7-ring Oxyhexyl, (This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -7-(Please read the precautions on the back before filling in the capital)) Printed by the cooperative 499446 Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5) Methacrylic acid-6,7-epoxyamyl, (meth) acrylic acid methyl propyl. Among them, particularly preferred is glycidyl (meth) acrylate. These singular bodies can be used individually or in combination of 2 or more types. The specific polymer used as the component (A) may be a polymer formed of only a structural unit represented by the formula (1). It may contain a structural unit other than the structural unit represented by formula (1), which is preferably 70 mol% or less, more preferably 5 to 60 mol%, and particularly preferably 20 to 50 mol%. As a singular body (hereinafter referred to as "other singular body") to be introduced into a structural unit other than the structural unit represented by formula (1), for example, methyl (meth) acrylate and ethyl (meth) acrylate may be mentioned. , Butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, phenyl (meth) acrylate, cyclohexyl (meth) acrylate, tricyclo (meth) acrylate [5.2.1] 0 2 '6] decane-8-yl (commonly used in this technical field as dicyclopentyl (meth) acrylate), (meth) propenyl dicyclopentyloxyethyl, (methyl ) (Meth) acrylic esters such as propenyl isobornyl; vinyl aromatic compounds such as styrene, α-methylstyrene, p-methylstyrene, vinylnaphthalene, and phenylmaleic anhydride Imine, cyclohexylmaleic anhydride imine, T-based maleimide imine, N-succinic acid imino-3-maleic acid imide benzoate, N-amber acid Amino-4-maleic anhydride imidobutyrate, N-succinyl imino-6-maleic anhydride imidohexanoate, Maleic anhydride imine compounds such as Ν-amber milled imine- 3 -maleic anhydride imine propionate, N-(9 -acridyl) maleic anhydride imine, and the like. These single-volume paper sizes are applicable to China National Standard (CNS) A4 specifications (210 × 297 mm) ~ I ------- 1T (Please read the notes on the back before filling in this' r) Binding 4 499446 Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative A7 B7 V. Description of invention (6) Can be used alone or in combination of two or more. The molecular weight of the specific polymer used as the component (A) is not particularly limited as long as a flat coating film can be formed on the surface of the hardening composition solution obtained by coating. Depending on the thickness of the formed coating film, the hardening composition The coating conditions, purpose, etc. of the solution are appropriately selected, but usually the weight average molecular weight in terms of polystyrene is preferably in the range of 3,000 to 300,000, and more preferably in the range of 3,000 to 100,000. When a specific polymer having a structural unit represented by the formula (1) and structural units other than the specific polymer is used as the component (A), the polymer may be a random copolymer of a specific unit and other units, and Any of the hetero-molecular copolymers is acceptable, and random copolymers are preferred. <Component (B)> As the epoxy resin other than the component (A), for example, bisphenol A type epoxy resin, bisphenol F type epoxy resin, phenolic epoxy resin for phenol paint, and phenolic ring for cresol paint can be used. Oxygen resin. These items are available. For example, as the bisphenol A type epoxy resin, there are Epicote 1001, the same 10 02, the same 1003, the same 1004, the same 1007, the same 1009, the same 1010, and the 828 (above, oily Shell Epoxy Co., Ltd., as the bisphenol f-type epoxy resin, Epicote 8 0 7 and the same 8 3 4 (above, made by Petrochemical Shell Epoxy Co., Ltd.) as a phenolic ring for phenolic paint Oxygen resin, Epcot 1 5 2, same as 1 5 4, same as 1 5 7 Η 6 5 (above, made by Petrochemical Shell Epoxy Co., Ltd.) EPPN201, same as 202 (above, this paper size applies to China) Standard ((^ 5) 8 4 specifications (210 \ 297mm) -9- --------- mjp pack-(Please read the precautions on the back before filling in this I-), -td 499446 A7
五、發明説明（7 ) 曰本化藥股份有限公司，作爲用酚漆用酚醛型環氧樹脂、 EOCN — 1〇2、 E〇CN— l〇3S、 EOCN 〜 1〇4S、 EOCN-1020. E〇CN—l〇25、 EOCN — 1 0 2 7 (以上日本化藥股份有限公司製）、 埃皮科特1 8 0 S 7 5 (油化s h e 11環氧股份有限公司製） 其他’作爲環式脂肪族環氫樹脂有C Y 1 7 5、 CY177、CY179(W1，CIBA— GEIGY A.G 製）、ERL - 4234、ERl-4299、ERL - 4221、ERL — 4206 (以上 ’ u · C · C公司製），showdain 509 (昭和電工股份 有限公司製）、Adaruliat CY — 182、同 CY —V. Description of the invention (7) Saipan Chemical Co., Ltd., as a phenolic epoxy resin for phenol paint, EOCN — 102, E〇CN — 103S, EOCN ~ 104S, EOCN-1020. E〇CN—l025, EOCN — 1 0 2 7 (manufactured by Nippon Kayaku Co., Ltd.), Epcot 1 8 0 S 7 5 (manufactured by Petrochemical She 11 Epoxy Co., Ltd.), etc. Cyclic aliphatic cyclohydrogen resins include CY 1 7 5, CY177, CY179 (W1, manufactured by CIBA—GEIGY AG), ERL-4234, ERl-4299, ERL-4221, and ERL-4206 (above 'u · C · C companies System), showdain 509 (manufactured by Showa Denko Corporation), Adaruliat CY — 182, same as CY —
192、同 CY— 184 (以上，CIBA — GEIGY A.G製），埃皮庫隆200、同400(以上，大曰本 1 n k工業股份有限公司製），埃皮科特8 7 1、同 8 7 2、E P 1 〇 3 2 Η 6 0 (以上，油化Shell環氧股份 有限公司製）、ED— 5661、ED— 5662 (以上 ’賽拉尼斯coating股份有限公司製），作爲脂肪族聚環氧 丙基醚有埃皮科特1 9 0 P、同1 9 1 P (以上，油化 shell環氧股份有限公司製）epolight 1 0 〇 M F (共榮 社油脂化學工業股份有限公司製），epiol Τ Μ P (日本油脂股份有限公司製）。 其中較佳者爲，可舉出雙酚Α型環氧樹脂，酚漆用酚 醛聚氧樹脂以及甲酚漆用酚醛聚氧樹脂。192, same as CY-184 (above, made by CIBA—GEIGY AG), Epicolon 200, same as 400 (above, made by Daikoku 1 nk Industrial Co., Ltd.), Epicote 8 7 1, same as 8 7 2. EP 1 〇3 2 Η 60 (above, manufactured by Petrochemical Shell Epoxy Co., Ltd.), ED-5661, ED-5662 (above manufactured by Celanese Coating Co., Ltd.), as aliphatic polyepoxy The propyl ethers are Epicote 1 900 P, the same as 19 1 P (above, manufactured by Petrochemical Shell Epoxy Co., Ltd.) epilight 1 0 MF (produced by Kyoeisha Oil Chemical Industry Co., Ltd.), epiol ΤΜ P (manufactured by Japan Oil Co., Ltd.). Among them, preferred are bisphenol A-type epoxy resins, phenolic polyoxy resins for phenol paints, and phenolic polyoxy resins for cresol paints.
環氧樹脂（B )的使用比例，每1 0 〇重量份的（A 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）-1〇 - ---I-----〔 (請先閱讀背面之注意事項再_填寫本齊) •裝· 訂 經濟部智慧財產局員工消費合作社印製 499446 經濟部智慧財產局員工消費合作社印製 A7 __B7五、發明説明（8 ) )成分，較佳爲1至2 0 0重量份，更佳爲3至1 0 0重 量份。 且，雖前述的（A )亦爲環氧樹脂，但上述（B )成 分的環氧樹脂與（A )成分比較時其爲低分子量體，對於 平坦化的提升效果上有差異。 〈成分（C )〉 作爲因熱產生酸的化合物，例如可使用鎏鹽、苯并噻 唑鐵鹽、銨鹽、鱗鹽等的鑰鹽可使用。 其中，鎏鹽以及苯并噻唑鑰鹽爲佳。 作爲上述鎏鹽的具體例子可舉出，4 -乙醯苯基二甲 基鎏六氟銻酸鹽、4 -乙醯氧基苯基二甲基鎏六氟伸酸鹽 、二甲基- 4 -（苄基氧基羰基氧基）苯基鎏六氟銻酸鹽 、二甲基一 4 一（苯醯氧基）苯基鎏六氟銻酸鹽、二甲基 一 4 一（苯醯氧基）苯基鎏六氟伸酸鹽、二甲基一 3 -氯 -4 -乙醯氧基苯基鎏六氟銻酸鹽等烷基鎏鹽；苄基一 4 -羥苯基甲基鎏六氟銻酸鹽、苄基- 4 -羥苯基甲基鎏六 氟磷酸鹽、.4 -乙醯氧基聯苯基甲基鎏六氟銻酸鹽、苄基 一 4 一甲氧基苯基甲基鎏六氟銻酸鹽、苄基一 2 —甲基一 4 一羥基苯基甲基鎏六氟銻酸鹽、芣基一 3 -氯一 4 一經 基苯基甲基鎏六氟砷酸鹽、4 -甲氧基苄基一 4 一經基苯 基甲基鎏六氟磷酸鹽等芣基鎏鹽： 二苄基一 4 一羥基苯基鎏六氟銻酸鹽、二苄基一 4 一 羥基苯基鎏六氟磷酸鹽、4 -乙醯氧基苯基二苄基璧六氟 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-11 - (請先閱讀背面之注意事項再填寫本齊) 499446 A7 _ B7五、發明説明（9 ) 銻酸鹽、二T基- 4 一甲氧基苯基鎏六氟銻酸鹽、二T基 一 3 —氯一4 —羥基苯基鎏六氟砷酸鹽、二苄基一 3 —甲 基一 4 一羥基一 5 - t e r t — 丁基苯基鎏六氟銻酸鹽、 苄基- 4 -甲氧基τ基- 4 -羥基苯基鎏六氟磷酸鹽等二 苄基鎏鹽； p 一氯化芣基—4 -羥基苯基甲基鎏六氟銻酸鹽、P -硝基苄基- 4 -羥基苯基甲基鎏六氟銻酸鹽、P -氯化 苄基-4 -羥基苯基甲基鎏六氟磷酸鹽、P -硝基苄基-3 —甲基一 4 一羥基苯基甲基鎏六氟銻酸鹽、3 ，5 —二 氯T基- 4 -羥基苯基甲基鎏六氟銻酸鹽、〇 -氯化苄基 一 3 -氯一 4 一羥基苯基甲基鎏六氟銻酸鹽；以及 下述式（1)至（7)所示的鎏鹽。 (請先閲讀背面之注意事項再填寫本貧) 3 (1) 經濟部智慧財產局員工消費合作社印製 H0 ch3cooThe proportion of epoxy resin (B) used per 100 weight parts (A paper size applies to China National Standard (CNS) A4 specifications (210X 297 mm)-10---- I ----- [(Please read the notes on the back before _filling in this book) • Binding and printing Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 499446 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 __B7 V. Description of Invention (8)) The component is preferably 1 to 200 parts by weight, and more preferably 3 to 100 parts by weight. In addition, although the aforementioned (A) is also an epoxy resin, the epoxy resin of the aforementioned (B) component is a low-molecular-weight body when compared with the component (A), and there is a difference in the improvement effect of planarization. <Component (C)> As a compound that generates an acid due to heat, for example, a key salt such as a sulfonium salt, a benzothiazole iron salt, an ammonium salt, and a scale salt can be used. Among them, sulfonium salts and benzothiazole key salts are preferred. Specific examples of the above-mentioned phosphonium salt include 4-ethylammonium phenyldimethylfluorene hexafluoroantimonate, 4-ethylammonyloxyphenyldimethylfluorene hexafluoroantimonate, and dimethyl-4 -(Benzyloxycarbonyloxy) phenylfluorene hexafluoroantimonate, dimethyl-1 4-phenyl (phenylfluorenyloxy) phenylfluorene hexafluoroantimonate, dimethyl-4 4- (phenylfluorenyloxy) Alkyl) phosphonium salts such as phenylsulfonium hexafluoro ethanate, dimethyl- 3-chloro-4 -ethoxyfluorenyl hexafluoroantimonate; benzyl 4-hydroxyphenylmethyl fluorene Hexafluoroantimonate, benzyl-4 -hydroxyphenylmethylfluorene hexafluorophosphate, .4-ethylacetoxybiphenylmethylfluorene hexafluoroantimonate, benzyl-4 -methoxybenzene Methylmethylfluorene hexafluoroantimonate, benzyl-2-methyl-4 4-hydroxyphenylmethylfluorene hexafluoroantimonate, fluorenyl-3 -chloro-4, trimethylphenylmethylfluorene hexafluoroarsenic Acid salt, 4-methoxybenzyl-4, trimethyl phenylmethyl, hexafluorophosphate, and other fluorenyl salts: dibenzyl-4, hydroxyphenyl, hexafluoroantimonate, dibenzyl-4 Monohydroxyphenylphosphonium hexafluorophosphate, 4-Ethyloxyphenyldibenzylhexafluoride paper ruler Applicable to China National Standard (CNS) A4 specification (210X297mm) -11-(Please read the notes on the back before filling in this book) 499446 A7 _ B7 V. Description of the invention (9) Antimonate, Di-T-based-4 Monomethoxyphenyl fluorene hexafluoroantimonate, di-T-yl-3-chloro-4 4-hydroxyphenyl fluorene hexafluoroarsenate, dibenzyl-3-methyl-4 4-hydroxy-5-tert — Dibenzylsulfonium salts such as butylphenylphosphonium hexafluoroantimonate, benzyl-4 -methoxyτyl-4 -hydroxyphenylphosphonium hexafluorophosphate; p-fluorenyl-4-hydroxybenzene Methylmethylfluorene hexafluoroantimonate, P-nitrobenzyl-4-hydroxyphenylmethylfluorene hexafluoroantimonate, P-benzyl chloride-4 -hydroxyphenylmethylfluorene hexafluorophosphate , P-nitrobenzyl-3-methyl-4 monohydroxyphenylmethylfluorene hexafluoroantimonate, 3,5-dichloroTyl-4 4-hydroxyphenylmethylfluorene hexafluoroantimonate, O-benzyl chloride 3-chloro-4 4-hydroxyphenylmethylphosphonium hexafluoroantimonate; and phosphonium salts represented by the following formulae (1) to (7). (Please read the notes on the back before filling out this poverty) 3 (1) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs H0 ch3coo
cf3co3* CF3S03- CF3S03' ch3 cf3so3- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-12 - (2) (3) (4) (5) (6)499446 經濟部智慧財產局員工消費合作社印製 五、發明説明（1〇 )cf3co3 * CF3S03- CF3S03 'ch3 cf3so3- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -12-(2) (3) (4) (5) (6) 499446 Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumer Cooperatives V. Invention Description (10)
HOHO
cf3so3"cf3so3 "
HO 普C普 ch3HO Pu C Pu ch3
cf3s(V (7) 作爲上述苯并噻唑鑰鹽的具體例子可舉出3 - f ^ $ 并基噻唑鑰鹽六氟銻酸鹽、3 -苄基苯并基噻唑 磷酸鹽、3 -苄基苯并基噻唑鐵鹽六氟硼酸鹽、3 — 一甲氧基苄基）苯并噻唑鑰六氟銻酸鹽、3 -苄基一 2厂 甲基硫基苯并噻唑鐵六氟銻酸鹽、3 -苄基一 5 -氣 并噻唑鑰六氟銻酸鹽等的T基苯并基噻唑鐵鹽。 其中，4 一乙醯氧基苯基二甲基鎏六氟砷酸鹽、 - 4 -羧基苯基甲基鎏六氟銻酸鹽、4 一乙醯氧基苯基$ 基甲基鎏六氟銻酸鹽、二苄基- 4 -羧基苯基鎏六氟鍊@ 鹽、4 -乙醯氧基苯基苄基鎏六氟銻酸鹽、3 —苄基苯并1 基噻唑鏺鹽六氟銻酸鹽等較佳。作爲這些的販賣品可舉出 S unend S I — 6 0L 、同 S I— 80L 、同 S 1 — 100L、同 SI—L85、同 SI — L110、同 SI 一 L145 、同 S I — L147 、同 S I — L150 、问 S I — L 1 6 0 (三新化學工業（株）製）等。 這些因熱產生酸的化合物，作爲因放射線產生酸的化 合物亦具有功能性。 這些化合物中可單獨或2種以上組合使用。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-13 - (請先閱讀背面之注意事項存填寫本頁) 499446 A7 __ B7 _五、發明説明（11 ) 又，作爲因放射線產生酸的化合物，例如可使用三氯 化甲基- S -三吖嗪類、二芳基碘鎗鹽類、三芳基鎏鹽類cf3s (V (7) As specific examples of the benzothiazole key salt, 3-f ^ $ benzothiazole key salt hexafluoroantimonate, 3-benzylbenzothiazole phosphate, 3-benzyl Benzylthiazole iron salt hexafluoroborate, 3-monomethoxybenzyl) benzothiazole key hexafluoroantimonate, 3-benzyl-2 plant methylthiobenzothiazole iron hexafluoroantimonate , T-benzobenzothiazole iron salts such as 3-benzyl-5-gasthiathiazolium hexafluoroantimonate and the like. Among them, 4-ethylacetoxyphenyldimethylfluorene hexafluoroarsenate, -4-carboxyphenylmethylfluorene hexafluoroantimonate, 4-ethylacetoxyphenyl $ methylhexafluorene Antimonate, Dibenzyl-4 -carboxyphenylphenyl hexafluoro chain @ salt, 4-Ethyloxyphenylbenzyl hexafluoroantimonate, 3-Benzylbenzo 1 thiazolium salt hexafluoro Antimonate and the like are preferred. Examples of these sales items include Sund SI — 60L, the same SI — 80L, the same S — 100L, the same SI — L85, the same SI — L110, the same SI — L145, the same SI — L147, and the same SI — L150. Ask SI — L 1 6 0 (manufactured by Sanxin Chemical Industry Co., Ltd.). These compounds which generate acid due to heat are also functional as compounds which generate acid due to radiation. These compounds can be used individually or in combination of 2 or more types. This paper size applies the Chinese National Standard (CNS) A4 specification (210X297mm) -13-(Please read the precautions on the back and fill in this page) 499446 A7 __ B7 _V. Description of the invention (11) Acid-generating compounds such as trichloromethyl-S-triazine, diaryl iodonium salts, and triarylsulfonium salts can be used.
作爲上述的三氯化甲基- S 4 6 -三氯化 6 -三氯化 —氯化苯）—雙（4， 、2 -（ 3 -氯化苯） —三吖嗪類、2 — ( 2 甲基）一 s —三吖嗪類 ，6 —三氯化甲基）一 苯）—雙（4，6 -三 一雙（4 甲基） 甲基） 經濟部智慧財產局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本Ifo -裝· 訂 . 出三 —S -三吖嗪類、2 -苯基 (4 嗪類 一 s 氯化 (4 氧基 s —三吖嗪類、2 6 —三氯化甲 一雙（4，6 一氯化苯）一 基）一 一三氯化甲 s —三吖 雙（4 2 — （ 4 一甲氧基 S 一 吖嗪類 ，6 —三 苯）一雙 (3 —甲 氯化甲 2 —甲氧基苯）一雙（4, (4 一甲基硫代 吖嗪類、2 甲基）一 s —三吖嗪類 4，6 —二 硫代苯）一 2 -（ 4 -三吖嗪類 氯化甲基） 雙（4，6 甲氧基萘） 一 s — 一三氯 -雙（ 基）一 6 -三 苯）-(3 - 三吖嗪 化甲基 4 ， 6 s —三 類 氯化甲基）一 s —三 雙（4，6 -甲基硫代苯） 類、2 — 2 — )一 —二 2 —（3 —甲基硫代苯）一雙 氯化甲基）一 s —三吖 一三氯化甲 雙（4 6 嗪類 基）一 甲氧基一 /3 —巢醇）一 三吖嗪類、2 —（ 3 — 一三氯化甲基）—s - 2 -（ s —三 ，6 — —β — 2 —甲 雙（4 甲氧基 三吖嗪類、2 — 吖嗪類 三氯化 巢醇） 吖嗪 化甲基）(4，6 基硫代苯 、2〜（ 甲基）一 -雙（4 〜甲氧基 氯化 雙（ 甲基 類、 一 s 4 s 一 一 β 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐）_ 14 yc 44 9 49 A7 B7 五、發明説明（12 ) —巢醇）—雙（4，6 —三氯化甲基）一 s —三吖嗪類、 2 — ( 3 ，4，5 —三甲氧基一/3 —巢醇）一雙（4 ，6 —三氯化甲基）一 s —三吖嗪類、2 — (4 —甲基硫基一 冷一巢醇一雙（4 ，6 —三氯化甲基）一s —三吖嗪類、 2 — (3 —甲基硫基一沒一巢醇一雙（4，6 —三氯化甲 基）一s —三吖嗪類、2 — (2 —甲基硫基一/3 —巢醇一 雙（4，6 —三氯化甲基）一 s —三吖嗪類、2 —胡椒基 一雙（4，6 —三氯化甲基）一 s —三吖嗪類、2 —〔 2 一（呋喃一 2 —基）乙烯基〕一雙（4，6 —三氯化甲基 )一 s —三吖嗪類、2 —〔2 —（5 —甲基呋喃一2 —基 請 先 閲 讀 背 之 注 I· )乙烯基〕一雙（4，6 —三氯化甲基）一 、2 —〔2 —（4 —甲基咲喃一 2 —基）乙 4，6 —三氯化甲基）一 s —三吖嗪類等。 作爲上述的二芳基碘鑰鹽類 氟硼酸酯、聯苯碘鏺六氟磷酸鹽 聯苯碘鑰三氟甲烷硫酸鹽、聯苯 鐵 P —甲苯硫酸鹽、4 一甲氧 經濟部智慧財產局員工消費合作社印製 ，例如可舉 、聯苯碘鏺 碘鏺三氟乙 基苯基苯基 氟磷酸鹽、 氧基苯基苯 碘鑰三氟乙 鹽、4 -甲氧基苯基苯基碘鏺六 基苯基碘鑰六氟砷酸鹽、4 -甲 烷硫酸鹽、4 一甲氧基苯基苯基 氧基苯基苯基碘鏺- p -甲苯硫酸鹽、雙 -丁基苯基）碘鑰四氟硼酸鹽、 苯基）碘鏺六氟砷酸鹽、雙（4 雙（4 一 t —t e r t s —三吖嗪類 烯基〕一雙（ 出聯苯碘鏺四 六氟砷酸鹽、 酸鹽、聯苯碘 碘鏺四氟硼酸 4 一甲氧基苯 基碘鏺三氟甲 酸鹽、4 —甲 4 — t e r t e r t -丁基 一丁基苯基） 碘鏺三氟甲烷硫酸鹽、雙（4 一 t e r t —丁基苯基 本紙張尺度適用中國國家標準（CNS ) A4規格（2iOX297公釐）-15 - 499446 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（13 ) 鏺三氟乙酸鹽、雙（4一 t e r t - 丁基苯基）碘鑰一 P 一甲苯硫酸鹽等。 作爲上述的三芳基鎏鹽類，例如有舉出三芳基鎏四氟 硼酸鹽、二芳基鎏四氟硼酸鹽、三芳基鎏六氟磷酸鹽、三 芳基鎏六氟砷酸鹽、三芳基鎏三氟甲烷硫酸鹽、三芳基鎏 三氟乙酸鹽、三芳基鎏一 P —甲苯硫酸鹽、4 一甲氧基苯 基二苯基鎏四氟硼酸鹽、4 -甲氧基苯基二苯基鎏六氟磷 酸鹽、4 -甲氧基苯基二苯基鎏六氟砷酸鹽、4 一甲氧基 苯基二苯基鎏三氟甲烷硫酸鹽、4 一甲氧基苯基二苯基鎏 三氟乙酸鹽、4 一甲氧基苯基二苯基鎏一 p 一甲苯硫酸鹽 、4 一苯基硫基苯基二苯基鎏四氟硼酸鹽、4 一苯基硫基 苯基一苯基鎏六氟磷酸鹽、4 -苯基硫基苯基二苯基鎏六 氟砷酸鹽、4 -苯基硫基苯基二苯基鎏三氟甲烷硫酸鹽、 4 -苯基硫基苯基二苯基鎏三氟乙酸鹽、4 一苯基硫基苯 基二苯基鎏一 p —甲苯硫酸鹽等。 這些化合物中，作爲三氯化甲基一 s -三吖嗪類，有 2 — (3 —氯化苯基）一雙（4，6 -三氯化甲基）一 s —三α丫嗪、2 —（ 4 一氯化苯基）一雙（4，6 —三氯化 甲基）一 s —三吖嗪、2 — （4 一甲基硫基苯基）一雙（ 4，6 —三氯化甲基）一 s —三吖嗪、2 — (4 —甲氧基 一 /3 —巢醇）一雙（4，6 —三氯化甲基）一s —三吖嗪 、2 —〔2 —(呋喃—2 —基）乙烯基〕一雙（4，6 — 二氣化甲基）一 s —三n、/ fl秦類、2 —〔 2 —（ 5 —甲基口夫 喃一 2 —基）乙烯基〕—雙（4，6 —三氯化甲基）一 s (請先閲讀背面之注意事項再填寫本牙V ) 裝· 訂 4 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-16 - 499446 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（14 ) 一三D丫嗪類、2 —〔2 —（4 一二乙基胺基一 2 -甲基苯 基）乙烯基〕一雙（4，6 —三氯化甲基）一 s —三吖嗪 或2 —（4 —甲氧基萘基）一雙（4 ，6 —三氯化甲基） 一 s —三吖嗪； 作爲二芳基碘鏺鹽類，例如可舉出聯苯碘鏺三氟甲烷 硫酸鹽、聯苯碘鏺三氟乙酸鹽、4 一甲氧基苯基苯基碘鐵 三氟甲烷硫酸鹽或4 -甲氧基苯基苯基碘鐵三氟乙酸鹽； 作爲三芳基鎏鹽類，例如可舉出三芳基鎏三氟甲烷硫 酸鹽、三芳基鎏三氟乙酸鹽、4 -甲氧基苯基二苯基鎏三 氟甲烷硫酸鹽、4 -甲氧基苯基二苯基鎏三氟乙酸鹽、4 -苯基硫基苯基二苯基鎏三氟甲烷硫酸鹽、或4 -苯基硫 基苯基二苯基鎏三氟乙酸鹽等分別爲較佳者。 因熱或放射線產生酸的化合物（C )之使用比例，對 於1 0 0重量份的（A)成分而言，較佳爲〇 . 〇 1至 20重量份，更佳爲0.2至10重量份。 (C )成分爲的使用比例對1 〇 〇重量份的（A )而 言，若未滿0 · 0 1重量份時，因加熱或接受放射線而產 生酸的量較少，故（A )成分以及（B )成分的交聯便十 分難以進行，所得硬化膜之耐熱性、平坦化性、耐藥品性 、與基板的密著性有下降的現象。另一方面，（c )成分 的使用比例爲對1 0 0重量份的（A )成分而言，超過 2 0重量份時膜容易產生粗糙現象。 〈其他成分〉 1Γ (請先閲讀背面之注意事項再填寫本貢) -裝 、π d 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-17 - 499446 A7 B7 五、發明説明（15 ) (請先閲讀背面之注意事項再填寫本貫) 對於本發明的硬化性組成物而言，上述的成分（A ) 、成分（B )以及成分（C )以外，因應必須作爲其他成 分例如可含有有機矽烷偶合劑、硬化補助劑、硬化促進劑 、界面活性劑、紫外線吸收劑。 〈有機矽烷偶合劑〉 有機矽烷偶合劑係欲提升硬化膜與必須形成之基體間 的密著性所使用者，有使用含有具羧基、甲基丙烯醯基、 異氰酸酯、環氧基等反應性取代基（官能基）的官能基之 院氧基矽烷化合物。 作爲此含有官能基的烷氧基矽烷化合物，例如可舉出 三甲氧基甲矽烷基安息香酸、r -甲基丙烯醯氧基丙基三 甲氧基矽烷、乙烯三乙醯氧基、乙烯三甲氧基矽烷、r -異氰酸根丙基三乙氧基矽烷、r -環氧丙氧基丙基三甲氧 基矽烷、/3 -（3 ，4 —環氧基環己基）乙基三甲氧基砍 烷、r -環氧丙氧基丙基二乙氧基矽烷等。這些可單獨或 2種以上組合使用。 經濟部智慧財產局員工消費合作社印製 有機矽烷偶合劑的使用比例對1 〇 〇重量份的成分（ A)而言爲100重量份以下爲佳，較佳爲〇 · 1至 1 0 0重量份、特佳爲1至4 0重量份。當有機矽烷偶合 劑的使用比例低於0 · 1時，有對硬化膜與必須形成的基 體之間的密著性效果並不充分的情況。另一方面，有機砂 烷偶合劑的使用比例超過1 〇 〇重量份時’會有所得的硬 化膜之耐鹼性、耐溶劑性會降低之現象。 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）-18 - 499446 經濟部智慧財產局員工消費合作社印製 A7 ____B7五、發明説明（16 ) 〔硬化補助劑〕 所謂硬化補助劑即，作爲成分（A )所使用的特定聚 合體以及作爲環氧基樹脂（B )的硬化劑而發揮其作用。 這些硬化劑僅使用於，因成分（C )的熱或放射線產生酸 的化合物所引起的硬化下交聯並不充足時。作有相關的硬 化補助劑可適當地使用多電子價羧酸無水物或多電子價羧 酸。 作爲多電子價羧酸無水物的具體例子，可舉出無水衣 康酸、無水琥珀酸、無水檸康酸、無水十二碳烯酸、無水 三苯胺基甲酸、無水馬來酸、無水六氫苯二酸、無水甲基 四氫苯二酸、無水安眠酸的脂肪族二羧酸無水物；1 ，2 ，3，4 一丁基四羧酸二無水物；無水苯二酸、無水均苯 四甲酸、無水三苯六甲酸、無水二苯甲酮四羧酸的芳香族 多電子價羧酸三苯六甲酸酯的含酯基酸無水物。其中芳香 族多電子價羧酸無水物、特別爲無水三苯六甲酸可得到耐 熱性較高的硬化膜。 又，作爲多電子價羧酸之具體例子，琥珀酸、戊二酸 、己二酸、丁烷四羧酸、馬來酸、衣康酸等的脂肪族多電 子價羧酸；六氫苯二酸' 1 ，2 -環己烷羧酸、1 ，2， 4 -環己烷三羧酸、環戊烷四羧酸等的脂肪族多電子價羧 酸、苯二酸、異苯二酸、對苯二甲酸、三苯四甲酸、均苯 四甲酸、1 ，2，5，8 —萘基四羧酸等的芳香族多電子 價羧酸。其中由硬化組成物的反應性、形成硬化膜的耐熱 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂 -1¾ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-19 - 499446 A7 B7 五、發明説明（17 ) 丨生等觀點’芳香族多電子價殘酸爲較適當。 (請先閱讀背面之注意事項再填寫本頁) 這些多電子價羧酸無水物或多電子價羧酸可單獨或2 種以上組合使用。 硬化補助劑的使用比例，對1 〇 〇重量份的成分（A )而言爲1至4 0重量份爲佳，較佳爲5至2 0重量份。 〔硬化促進劑〕 硬化促進劑係使用於促進（A )成分以及（B )成分 與硬化補助劑即硬化劑的反應上者，一般使用具含有2級 氮原子或3級氮原子的雜環構造之化合物。 經濟部智慧財產局員工消費合作社印製 作爲此化合物的具體例子，可舉出吡咯、咪唑、吡啶 、吡嗪、嘧啶、吲哚、吲唑、苯并咪唑或三聚異氰酸或這 些的衍生物。其中以2 —甲基咪唑、2 —乙基一4 —甲基 咪唑、2 -十七烷基咪唑、4 一甲基一 2 —苯基咪唑、1 一苄基一2 —甲基咪唑、2 —乙基一 4 一甲基一 1 一（2’ —氰基乙基）咪D坐、2 —乙基—4 一甲基一 1—〔2’—（ 3 ”，5 ” 一二胺基三嗪基）乙基〕咪唑、苯并咪唑等的咪唑 衍生物爲佳，最佳爲2 -乙基一 4 一甲基咪唑、4 一甲基 一2—苯基咪唑、1一苄基一2-甲基咪唑。 這些化合物可單獨或2種以上組合作爲硬化促進劑使 用。 硬化促進劑的使用比例對1 0 0重量份的成分（A ) 而言，以0·01至10重量份爲佳，較佳爲〇·05至 5重量份。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-20 - 499446 A7 B7 五、發明説明（18 ) _ 〔界面活性劑〕 (請先閱讀背面之注意事項再填寫本貢) 作爲界面活性劑，使用氟素系界面活性劑以及聚矽氧 烷系界面活性劑爲佳。 作爲氟素系界面活性劑，較佳使用至少於末端、主鏈 以及支鏈的某部位具有氟化烷基或氟化亞烷基之化合物。 其具體例子可舉出1 ，1，2，2 -四氟辛基（1 ，1 ， 2 ’ 2 —四氟丙基）醚、1 ，1 ，2 ，2 —四氟辛基己基 _、八乙二烯二（1 ，1 ，2 ，2 —四氟丁基）醚、六乙 二烯（1 ，1 ，2 ，2 ，3 ’ 3 —六氟戊基）醚、八丙二 烯二（1，1 ，2，2 —四氟丁基）醚、六丙二烯二（1 ’ 1 ，2 ，2 ，3 ，3 -六氟戊基）醚、全氟月桂基磺酸 經濟部智慧財產局員工消費合作社印製 納、1 ’ 1 ，2，2’8’8，9 ，9 ，10，10 —十 氟十二烷、1 ，1 ，2，2，3，3 -六氟癸烷、氟烷基 苯磺酸鈉、氟烷基氧基***、雙甘油四碳、碘化氟烷基銨 、氟烷基聚氧***、全氟烷基聚氧乙醇、全氟烷基烷氧酸 、氟素系烷基酯。又，作爲這些販賣品，B Μ - 1 0 0 0 、ΒΜ— 11〇〇(以上，BM Chemie 公司製）， megafack F142D，同 F172、同 F173、同 F183、同 F178、同 F191、同 F471 (以上 ，大日本i n k化學工業股份有限公司製）、furolardF C 一 170C、FC-171、FC-430、FC-4 3 1 (以上，住友3 Μ股份有限公司製）。 又作爲聚矽氧烷系界面活性劑’例如可舉出Τ 〇 r e 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-21 · 499446 經濟部智慧財產局員工消費合作社印製 A7 ____B7__五、發明説明（19 ) 聚矽氧烷 DC3PA、同 DC7PA、同 SH11PA、 同 SH21PA、同 SH28PA、同 SH29PA、同 SH30PA、同 FS — 1265 — 300 (以上，東 ledouconing聚石夕氧院股份有限公司製）、丁 S F — 4 4 40、TSF-4300、TSF — 4445、 TSF - 4446、TSF — 44 6 〇、TSF — 4 4 5 2 (以上，東芝聚矽氧烷股份有限公司製）商品名 。這些界面活性劑可單獨或2種以上組合使用。 界面活性劑的使用比例以其種類或構成硬化性組成物 的各成分之種類或比例而不同，對1 0 0重量份的成分（ A)而言爲0至100重量份爲佳，較佳爲0·0001 至5重量份的範圍。 本發明的硬化組成物，將上述成分（A )、成分（B )以及因應必要含有之其他成分均一地混合而調製出，一 般將各成分溶解於有機溶劑中作爲組成物溶液而調製。 欲調製此組成物溶液所使用的有機溶劑，僅可將各成 分均一地溶解且不與各成分反應者即可並無特別限制。一 般而言，作爲較易形成塗膜者，例如可舉出乙二醇單甲基 醚、乙二醇單乙基醚的乙二醇醚類；甲基溶纖劑乙酸鹽、 乙基溶纖劑乙酸鹽、乙二醇單丁基醚乙酸鹽的乙二醇烷基 醚乙酸鹽類；二乙二醇單甲基醚、二乙二醇單乙基醚、二 乙二醇二甲基醚、二乙二醇二乙基醚、的二乙二醇類；丙 二醇甲基醚乙酸鹽、丙二醇乙基醚乙酸鹽、丙二醇丙基醚 乙酸鹽的丙二醇烷基醚乙酸鹽類；甲苯、二甲苯的芳香族 (請先閱讀背面之注意事項再填寫本貧) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-22 - 499446 A7 B7 五、發明説明（20 ) 烴基；甲基乙基酮、環己酮、4 —羥基一 4 一甲基—2 -戊酮的酮類；2 -羥基丙酮酸乙基、2 -羥基一 2 -甲基 丙酮酸乙基、乙氧基乙酸乙基、羥基乙酸乙基、2 -羥基 一 3 —甲基丁酸甲基、3 —甲氧基丙酸乙基、3 —甲氧基 丙酸乙基、3 —乙氧基丙酸甲基、3 —乙氧基丙酸乙基、 乙酸乙基、乙酸丁基、乳酸甲基、乳酸乙基的酯類。這些 溶劑中，可單獨或2種類以上組合使用。 對組成物溶液的硬化性組成物的濃度並無特別限制， 可因應使用目的可適當選擇，固體成分的濃度以1至6 0 重量％爲佳，較佳爲5至4 0重量％ 。 因使用本發明的硬化組成物，例如可形成下述的硬化 膜。 即，將調整後組成物溶液，塗抹於必須形成硬化膜的 基體表面上，因進行預先焙烤而除去溶劑形成硬化性組成 物的塗膜，或預先焙烤後的塗膜再照射放射線，使得塗膜 的表面硬化，其後經由進行主焙烤步驟形成硬化膜。 以上作爲組成物溶液的塗佈方法，特別無限制，例如 可採用噴霧法、滾筒塗佈法、旋轉塗佈法等各種方法。 預先焙烤的條件，依組成物溶液的各成分種類、使用 比例等不同而不同，以6 0至1 2 0 t下約〇 . 5至2 0 分鐘爲佳。 又，主焙烤條件較佳爲1 5 0至2 5 0 °C下約〇 · 2 至2 . 0小時爲佳。 又，預先焙烤以及主焙烤各別可以1階段或2階段以 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-23 - nr (請先閱讀背面之注意事項再填寫本貧) -裝· 訂 經濟部智慧財產局員工消費合作社印製 499446 A7 _____B7 五、發明説明（21 ) 上的步驟組合進行。 本發明的硬化性組成物中，作爲成份（A ) 、( B ) (請先閱讀背面之注意事項再填寫本r) 的環氧化合物以及作爲成分（C )含有因熱或放射線產生 酸的化合物，故可經由塗膜的加熱或放射線的照射使得表 面硬化。因此，塗佈硬化性組成物進行預備焙烤，或形成 硬化性組成物的塗膜後，因塗膜經放射線照射使該塗膜的 表面硬化，對主焙烤可防止塗膜表面的流動，其結果，可 形成表面平坦性較高之硬化膜。 又，本發明的硬化性組成物所形成的硬化膜，由以下 的實施例顯示，其具有優良的各種物理性質，例如使用 L C D用彩色濾器以及C C D用彩色濾器作爲保護膜極爲 佳。 以下，由實施例詳細說明本發明，但本發明不受此實 施例所限制。實施例中「％」若無特別限制則表示「重量 °/〇 」° 合成例1 (聚合物（A 1 )的合成） 經濟部智慧財產局員工消費合作社印製 8 0重量份的環氧丙基甲基丙烯酸酯以及2 0重量份 的苯乙烯，添加於2 0 0重量份的丙二醇單甲基醚乙酸鹽 中混合，添加4 · 0重量份的偶氮二異丁腈（A I B N ) 後，於9 5 °C下進行3小時的聚合反應，得到聚合物（ A 1 )濃度3 2 %的聚合物溶液。 共聚物（A 1 )的聚苯乙烯換算之重量平均分子量（ M w )爲 4，〇 〇 〇。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-24 - 499446 Α7 Β7 五、發明説明（22 ) 合成例2 (聚合物（A 2 )的合成） (請先閎讀背面之注意事項再填寫本頁) 5 0重量份的環氧丙基甲基丙烯酸酯以及5 0重量份 的二環戊基甲基丙烯酸酯，添加於2 0 0重量份的丙二醇 單甲基醚乙酸鹽中混合，添加4 · 0重量份的偶氮二異丁 腈（A I B N )後，於9 5 °C下進行3小時的聚合反應， 得到聚合物（A 2 )濃度3 2 %的聚合物溶液。 共聚物（A2)的聚苯乙烯換算之重量平均分子量（ ^1〜）爲5，000。 合成例3 (聚合物（A3)的合成） 6 0重量份的環氧丙基甲基丙烯酸酯、3 0重量份的 苯乙烯以及1 〇重量份的甲基甲基丙烯酸酯，添加於 2 0 0重量份的丙二醇單甲基醚乙酸鹽中混合，添加 4 · 0重量份的偶氮二異丁腈（A I B N )後，於9 5 °C 下進行3小時的聚合反應，得到聚合物（A 3 )濃度3 2 %的聚合物溶液。 經濟部智慧財產局員工消費合作社印製 共聚物（A2 )的聚苯乙烯換算之重量平均分子量（ M w )爲 4，0 0 0 〇 實施例1硬化性組成物。 硬化性組成物的調製 含有如上述合成例1所合成的聚合物（A 1 )之聚合 物溶液（相當於1 0 0 0重量份（固體部份）的聚合物（ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐）-25 - 499446 A7 B7 五、發明説明（23 ) (請先閲讀背面之注意事項再填寫本買) A 1 ))以1 〇 〇重量份的丙二醇單甲基醚乙酸鹽稀釋後 ’作爲成分（B)添加20重量份的埃皮科特828 (二 酚A型環氧樹脂、油化s h e 1 1環氧股份有限公司製） 、作爲成分（C )添加2重量份的4 一乙醯苯基二甲基鎏 鹽六氟化銻酸鹽、作爲有機矽烷偶合劑添加6重量份的τ -環氧丙氧基丙基二乙氧基矽烷、作爲硬化促進劑添加 〇· 1重量份的2 —乙基一 4 一甲基咪唑、以及作爲界面 活性劑添加0 · 0 1重量份的megafak F172(氟素係界 面活性劑、大日本i n k化學工業股份有限公司製），充 分攪拌後得到硬化性組成物。 玻璃基板上將上述的硬化性組成物（S 1 )欲成膜厚 度爲2 // m而使用旋轉塗佈器塗佈，以熱板上8 0 °C下3 分鐘的條件進行預先焙烤形成塗膜。再將此形成的塗膜於 淨化烤箱中進行2 5 0 °C 1小時的主焙烤步驟，而形成平 坦化膜。 平坦化膜（Π )的形成 經濟部智慧財產局員工消費合作社印製 於玻璃基板上以J s R顏料係顏色遮蔽（R · G · B )形成具有條紋狀的紅、藍、綠三色的彩色濾器（條紋寬 爲1 0 0 ί/m)之基板。此具有彩色濾器的玻璃基板表面 上之凹凸，使用表面凹凸計a — s t e p ( tencol公司製 )測定爲1 · 0 // m。 此形成彩色濾器的玻璃基板上，如上述平坦化膜（I )的形成步驟相同，經硬化性組成物的塗佈、預先焙烤、 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-26 - 499446 A7 ________B7_ 五、發明説明（24 ) 以及主焙烤而形成平坦化膜（Π )。 (請先閲讀背面之注意事項真填寫本贫) 平坦化膜的評估 密著性 JIS K—5400(1900)8.5的附著性 試驗中以8 · 5 · 2的方格帶子法，於上述平坦化膜（I )以及平坦化膜（Π )的以切刀形成1 〇 〇方格子而進行 附著性試驗。此時，未剝離殘留的格子數如表i所示。 平坦化膜（I )的密著性爲密著性（I )、平坦化膜 (π )的密著性爲密著性（π )。 J I S κ — 5 4〇0 ( 1 9〇〇）8 · 4的鉛筆刮 擦試驗中，8 · 5 · 1的試驗法爲準，對上述所形成的平 坦化膜（I )進行鉛筆刮擦試驗，實施平坦化膜的表面硬 度之評估。結果如表1所示。 耐酸性 經濟部智慧財產局員工消費合作社印製 如上述所形成的平坦化膜（I )所形成的剝離基板， 於HC Ι/FeC 12·Η2〇/水=2/1/1重量比水 溶液中於4 5 °C浸漬1 5分鐘後，由觀察平坦化膜的外觀 變化進行保護膜的耐酸性之評估。此時，外觀無變化者爲 耐酸性良好（〇），而外觀已剝落且白化者爲耐酸性不良 (X ) 〇 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）-27 - 499446 A7 B7 五、發明説明（25 ) 耐驗性 (請先閲讀背面之注意事項再填寫本贫) 上述平坦化膜（I )所形成的剝離基板，浸漬於5重 量％氫氧化鈉水溶液中於3 0 °C下浸漬3 0分鐘後，藉由 觀察平坦化膜的外觀變化對保護膜的耐酸性進行評估。此 時，外觀無變化者爲耐鹼性良好（〇），而外觀已剝落且 白化者爲耐酸性不良（X)。 耐熱變色性 對上述平坦化膜（I )所形成的玻璃基板，測定對波 長4 0 0至7 0 0 nm的透過光譜。再將此玻璃基板於淨 化烤箱中以2 5 0 °C下加熱6 0分鐘後，再測定對波長 4〇0至7 0 0 nm的透過光譜。調查加熱前後的4 0 0 n m透過光譜之變化，評估耐熱變色性。加熱前後的 4 0 0 nm透過光譜之變化率如表1所示。 平坦化性 上述平坦化膜（Π )的表面凹凸，以表面凹凸計α - 經濟部智慧財產局員工消費合作社印製 s t e ρ測定。以下式爲準計算出之平坦化率如表.]_所示 〇 平坦化率=平坦化膜（Π )的表面凹凸/保護膜塗佈 前的彩色濾器之表面凹凸X 1 〇 〇 實施例2 對於實施例1 ，除作爲成分（B )的埃皮科特8 2 8 本紙張尺度適用中國國家標準（ CNS ) A4規格（210X297公釐）-28 - 499446 經濟部智慧財產局員工消費合作社印製 五、發明説明（26 ) 添加量爲4 0重量份之外其他與實施例i相同方法實施， 得到硬化性組成物（S 2 )。 又，對實施例1中，取代硬化性組成物（s 1 )使用 上述硬化性組成物（S 2 )’其他則與實施例1相同形成 平坦化膜（"以及平坦化膜（π )，進行評估。結果如 表1所示。 實施例3 對實施例1作爲成分（Β )的埃皮科特8 2 8以埃皮 科特1 5 2取代外，其他則與實施例丨相同方法實施，得 到硬化性組成物（S 3 )。 又’對實施例1而言，除取代硬化性組成物（S 1 ) 使用上述硬化性組成物（S 3 )之外，其他與實施例1相 同方法進行，形成平坦化膜（I )以及平坦化膜（η ), 進行評估。結果如表1所示。 實施例4 硬化性組成物的調製 對實施例1而言’取代含有聚合物（A 1 )的溶液， 使用含前述合成例2所合成的聚合物（a 2 )的溶液，作 爲成分（C )使用2重量份的4 -乙醯苯基甲基鎏鹽六氟 鍊酸鹽’其他與實施例1相同方法進行，得到硬化性組成 物（S 4 ) 〇 本紙張尺度適用中國國豕標準（CNS ) A4規格（21〇 X 297公釐;）-29 _ (請先閱讀背面之注意事項再填寫本頁) 裝·As the above-mentioned trichloromethyl-S 4 6 -trichloride 6 -trichloride-benzene chloride) -bis (4,, 2-(3-chlorobenzene) -triazine, 2-( 2 Methyl) -s-triazine, 6-trichloromethyl) -benzene) -bis (4,6-tris-bis (4 methyl) methyl) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Please read the precautions on the back before filling out this Ifo-bound. Binding. Three-S-triazine, 2-phenyl (4-azine-s chloride (4-oxys-triazine) , 2 6 —methyl trichloride, bis (4,6 monochlorinated benzene), one group) —one trichloride, s—triazine (4 2 — (4 -methoxyl S, azine), 6 —Triphenyl) —Bis (3-methyl chloride—2-methoxybenzene) —Bis (4, (4-methylthioazine, 2 methyl) —s—Triazine 4,6 —Dithiobenzene)-2-(4 -triazine-based methyl chloride) bis (4,6methoxynaphthalene) -s —-trichloro-bis (yl) -6-triphenyl)-( 3-Triazinated methyl 4, 6 s-three types of chlorinated methyl)-s-tris (4, 6-methylthio) ), 2-2-)-2-2-(3-methylthiobenzene)-dichloromethyl)-s-triazine-trichloromethanebis (4 6 azinyl)-methoxy 1- / 3-nestanol) -triazine, 2- (3-monotrichloromethyl) -s- 2- (s-tri, 6 --- β- 2-methylbis (4 methoxy Triazine, 2-azine trichlorinated nested alcohol) Azazinated methyl) (4,6-based thiobenzene, 2 ~ (methyl) mono-bis (4 ~ methoxychlorobis ( Methyl type, one s 4 s one one β This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) _ 14 yc 44 9 49 A7 B7 V. Description of the invention (12) —Nestanol) —Double ( 4,6-trichloromethyl) -s-triazine, 2- (3,4,5-trimethoxy-1 / 3-nestanol) -bis (4,6-trichloromethyl) One s-triazine, 2- (4-methylsulfanyl, one cold-cold alcohol, one bis (4,6-trichloromethyl), one s-triazine, 2- (3-methyl Thio-mono-n-alcohol-bis (4,6-trichloromethyl) -s-triazine, 2- (2-Methylthio- / 3-Nestanol-bis (4,6-trichloromethyl) -s-triazine, 2-piperazine-bis (4,6-trichloromethyl) ) -S-triazine, 2- [2- (furan-2-yl) vinyl] -bis (4,6-trichloromethyl) -s-triazine, 2- [2 — (5-methylfuran-2-yl, please read the note I ·) Vinyl] -bis (4,6-trichloromethyl) -1,2- [2— (4-methylfuran-1 2-yl) ethyl 4,6-trichloromethyl) -s-triazine and the like. As the above-mentioned diaryl iodide key salt type fluoroborate, biphenyl iodonium hexafluorophosphate biphenyl iodokey trifluoromethane sulfate, biphenyl iron P-toluene sulfate, 4-monomethoxy intellectual property Printed by the Bureau ’s Consumer Cooperative, for example, Biphenyl Iodine, Iodine, Trifluoroethylphenylphenylfluorophosphate, Oxyphenylphenyliodotrifluoroethyl salt, 4-methoxyphenylphenyl Iodopyrene hexaphenylphenyl iodofluorohexafluoroarsenate, 4-methane sulfate, 4-monomethoxyphenylphenyloxyphenylphenyl iodonium-p-toluene sulfate, bis-butylphenyl ) Iodine tetrafluoroborate, phenyl) iodofluorene hexafluoroarsenate, bis (4-bis (4-tts-triazine alkenyl)] bis (biphenyl iodofluorene tetrahexafluoroarsinate Salt, acid salt, biphenyliodoiodonium tetrafluoroborate 4 monomethoxyphenyliodonium trifluoroformate, 4-methyl 4-tertert-butyl monobutylphenyl) iodonium trifluoromethane sulfate And bis (4-tert-butylphenyl) This paper is sized for the Chinese National Standard (CNS) A4 (2iOX297 mm) -15-499446 A7 B7 Printed by the Bureau ’s Consumer Cooperatives 5. Description of the Invention (13) Trifluoroacetate, bis (4-tert-butylphenyl) iodo-P-toluene sulfate, etc. As the above-mentioned triarylphosphonium salts, for example, Examples include triarylsulfonium tetrafluoroborate, diarylsulfonium tetrafluoroborate, triarylsulfonium hexafluorophosphate, triarylsulfonium hexafluoroarsenate, triarylsulfonium trifluoromethane sulfate, triarylsulfonium Fluoroacetate, triarylfluorene-P-toluene sulfate, 4-monomethoxyphenyldiphenylfluorene tetrafluoroborate, 4-methoxyphenyldiphenylfluorene hexafluorophosphate, 4-methoxy Phenylphenyldiphenylsulfonium hexafluoroarsenate, 4-monomethoxyphenyldiphenylsulfonium trifluoromethane sulfate, 4-monomethoxyphenyldiphenylsulfonium trifluoroacetate, 4-monomethoxy Phenylphenyldiphenylphosphonium-p-toluene sulfate, 4-phenylphenylthiophenyldiphenylphosphonium tetrafluoroborate, 4-phenylphenylthiophenyl-phenylfluorene hexafluorophosphate, 4- Phenylthiophenyldiphenylsulfonium hexafluoroarsenate, 4-phenylthiophenyldiphenylsulfonium trifluoromethane sulfate, 4-phenylthiophenyldiphenylsulfonium Fluoroacetate, 4-phenylthiophenyldiphenylphosphonium-p-toluene sulfate, etc. Among these compounds, as trichloromethyl-s-triazine, there are 2- (3-chloro Phenyl) -bis (4,6-trichloromethyl) -s-tri-alpha-pyrazine, 2- (4-monochlorophenyl) -bis (4,6-trichloromethyl) -s- Triazine, 2- (4-methylthiophenyl) -bis (4,6-trichloromethyl) -s-triazine, 2- (4-methoxyl / 3-nestanol ) One pair of (4,6-trichloromethyl) one s-triazine, 2- [2- (furan-2-yl) vinyl] one pair of (4,6-digasified methyl) one s —Tri-n, / fl Qin, 2 — [2 — (5-methylhuffan-2-yl) vinyl] —bis (4,6-trichloromethyl) -s (please read first Note on the back then fill in the teeth V) Binding · Order 4 This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) -16-499446 Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives printed A7 B7 V. Invention Explanation (14) a tri-D-pyrazine, 2-[2 (4-diethylamino-2-methylphenyl) vinyl] -bis (4,6-trichloromethyl) -s-triazine or 2- (4-methoxynaphthyl) One bis (4,6-trichloromethyl) and one s-triazine; Examples of the diaryliodonium salts include biphenyliodonium trifluoromethane sulfate and biphenyliodonium trifluoroacetic acid Salt, 4-monomethoxyphenylphenyliodotrifluoromethanesulfate or 4-methoxyphenylphenyliodotrifluorotrifluoroacetate; examples of triarylsulfonium salts include triarylsulfonium Fluoromethane sulfate, triarylfluorene trifluoroacetate, 4-methoxyphenyldiphenylfluorene trifluoromethane sulfate, 4-methoxyphenyldiphenylfluorene trifluoroacetate, 4-phenyl Thiophenyldiphenylsulfonium trifluoromethane sulfate, 4-phenylthiophenyldiphenylsulfonium trifluoroacetate, and the like are each preferred. The use ratio of the compound (C) which generates an acid due to heat or radiation is preferably from 0.01 to 20 parts by weight, more preferably from 0.2 to 10 parts by weight, with respect to 100 parts by weight of the component (A). (C) The use ratio of the component is 100 parts by weight of (A). If it is less than 0.01 parts by weight, the amount of acid generated by heating or receiving radiation is small, so the component (A) And (B) crosslinking of the component becomes very difficult, and the heat resistance, planarization, chemical resistance, and adhesion to the substrate of the obtained cured film are reduced. On the other hand, the use ratio of the (c) component is 100 parts by weight of the (A) component. When the amount exceeds 20 parts by weight, the film is liable to cause a roughening phenomenon. 〈Other ingredients〉 1Γ (Please read the precautions on the back before filling in this tribute)-Packing, π d This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) -17-499446 A7 B7 V. Description of the invention (15) (Please read the precautions on the back before filling in this document.) For the curable composition of the present invention, the components (A), (B), and (C) above must be used as other components. For example, it may contain an organic silane coupling agent, a hardening aid, a hardening accelerator, a surfactant, and an ultraviolet absorber. 〈Organic Silane Coupling Agent〉 The organic silane coupling agent is intended for users who want to improve the adhesion between the cured film and the substrate that must be formed. There are reactive substitutions that use carboxyl groups, methacryl groups, isocyanates, and epoxy groups. The functional group is a functional silane compound. Examples of the functional group-containing alkoxysilane compound include trimethoxysilyl benzoic acid, r-methacryloxypropyltrimethoxysilane, ethylene triethoxyl, and ethylene trimethoxyl. Silane, r-isocyanatopropyltriethoxysilane, r-glycidoxypropyltrimethoxysilane, / 3- (3,4-epoxycyclohexyl) ethyltrimethoxy Alkane, r-glycidoxypropyldiethoxysilane and the like. These can be used alone or in combination of two or more. The use ratio of the organic silane coupling agent printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is preferably 100 parts by weight or less, more preferably 0.1 to 100 parts by weight, based on 1,000 parts by weight of the component (A). Especially preferred is 1 to 40 parts by weight. When the use ratio of the organosilane coupling agent is less than 0.1, the adhesion effect between the cured film and the substrate to be formed may be insufficient. On the other hand, when the use ratio of the organosarane coupling agent exceeds 1,000 parts by weight, the alkali resistance and solvent resistance of the resulting hardened film may decrease. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -18-499446 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ____B7 V. Description of the invention (16) [Hardening subsidy] The so-called hardening subsidy That is, the specific polymer used as the component (A) and the curing agent of the epoxy resin (B) exert their functions. These hardeners are used only when the crosslinking under hardening is not sufficient due to the heat generated by the component (C) or a compound that generates an acid. As the related hardening aid, a polyelectron carboxylic acid anhydride or a polyelectron carboxylic acid can be suitably used. Specific examples of the polyvalent carboxylic acid anhydrous include anhydrous itaconic acid, anhydrous succinic acid, anhydrous citraconic acid, anhydrous dodecenoic acid, anhydrous triphenylaminocarboxylic acid, anhydrous maleic acid, and anhydrous hexahydrogen. Anhydrous aliphatic dicarboxylic acid of phthalic acid, anhydrous methyltetrahydrophthalic acid, anhydrous hypnotic acid; 1,2,3,4 monobutyltetracarboxylic acid dianhydride; anhydrous phthalic acid, anhydrous homobenzene An ester-based acid anhydride of an aromatic multi-electron carboxylic acid trimelate with tetracarboxylic acid, anhydrous triphenylhexacarboxylic acid, and anhydrous benzophenone tetracarboxylic acid. Among them, an aromatic polyelectron carboxylic acid anhydrous, particularly anhydrous triphenylhexanoic acid, can obtain a cured film having high heat resistance. Further, as specific examples of the polyelectron carboxylic acid, aliphatic polyelectron carboxylic acids such as succinic acid, glutaric acid, adipic acid, butanetetracarboxylic acid, maleic acid, itaconic acid, and the like; hexahydrobenzene dicarboxylic acid; Acid '1,2-cyclohexanecarboxylic acid, 1,2,4-cyclohexanetricarboxylic acid, cyclopentanetetracarboxylic acid, etc., aliphatic polyelectron carboxylic acid, phthalic acid, isophthalic acid, Aromatic multivalent carboxylic acids such as terephthalic acid, triphenyltetracarboxylic acid, pyromellitic acid, 1,2,5,8-naphthyltetracarboxylic acid and the like. Among them, the reactivity of the hardened composition and the heat resistance of the hardened film (please read the precautions on the back before filling out this page). Binding-1¾ This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm)- 19-499446 A7 B7 V. Description of the invention (17) The viewpoints such as "aromatic polyelectron residual acid" are more appropriate. (Please read the notes on the back before filling out this page) These polyelectron carboxylic acid anhydrous or polyelectron carboxylic acid can be used alone or in combination of two or more. The use ratio of the hardening auxiliary is preferably 1 to 40 parts by weight, and more preferably 5 to 20 parts by weight, based on 1,000 parts by weight of the component (A). [Hardening Accelerator] The hardening accelerator is used to promote the reaction between the component (A) and the component (B) and the hardening aid, that is, a hardening agent. Generally, a heterocyclic structure having a second-order nitrogen atom or a third-order nitrogen atom is used. Of compounds. Specific examples of this compound printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy include pyrrole, imidazole, pyridine, pyrazine, pyrimidine, indole, indazole, benzimidazole, or trimeric isocyanate or derivatives of these Thing. Among them, 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-heptadecylimidazole, 4-methyl-2-phenylimidazole, 1-benzyl-2-methylimidazole, 2 —Ethyl-4, methyl-1, 1- (2′-cyanoethyl) imide, 2-ethyl-4, 4-methyl-1, [2 ′ — (3 ”, 5”, diamino) Triazinyl) ethyl] imidazole, benzimidazole and other imidazole derivatives are preferred, and the most preferred are 2-ethyl-4-methylimidazole, 4-methyl-2-phenylimidazole, 1-benzyl- 2-methylimidazole. These compounds can be used alone or in combination of two or more as a hardening accelerator. The use ratio of the hardening accelerator to 100 parts by weight of the component (A) is preferably from 0.01 to 10 parts by weight, and more preferably from 0.05 to 5 parts by weight. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -20-499446 A7 B7 V. Description of the invention (18) _ [Interactive agent] (Please read the precautions on the back before filling in this tribute) as As the surfactant, a fluorine-based surfactant and a polysiloxane-based surfactant are preferably used. As the fluorine-based surfactant, a compound having a fluorinated alkyl group or a fluorinated alkylene group at least at a terminal, a main chain, and a branch of a branched chain is preferably used. Specific examples thereof include 1,1,2,2-tetrafluorooctyl (1,1,2,2-'tetrafluoropropyl) ether, 1,1,2,2-tetrafluorooctylhexyl-, octa Ethylenedi (1,1,2,2-tetrafluorobutyl) ether, hexaethylenediene (1,1,2,2,3,3-'hexafluoropentyl) ether, octadiene di ( 1,1,2,2-tetrafluorobutyl) ether, hexapropadiene di (1'1,2,2,3,3-hexafluoropentyl) ether, perfluorolaurylsulfonic acid, intellectual property Printed by the Consumer Cooperatives of the Bureau, 1 '1, 2, 2' 8 '8, 9, 9, 10, 10-decafluorododecane, 1, 1, 2, 2, 3, 3-hexafluorodecane , Sodium fluoroalkylbenzene sulfonate, fluoroalkyloxyether, diglycerol tetracarbon, fluoroalkylammonium iodide, fluoroalkyl polyoxyether, perfluoroalkyl polyoxyethanol, perfluoroalkyl alkoxy acid Fluorine-based alkyl esters. In addition, as these sales items, B M-1 0 0, B M-1 100 (above, manufactured by BM Chemie), megafack F142D, F172, F173, F183, F178, F191, F471 ( Above, manufactured by Dainippon Ink Chemical Industry Co., Ltd.), furolard FC-170C, FC-171, FC-430, FC-4 31 (above, manufactured by Sumitomo 3M Co., Ltd.). As a polysiloxane-based surfactant, for example, TO ore can be used. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -21 · 499446. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. A7 ____B7__V. Description of the invention (19) Polysiloxane DC3PA, same as DC7PA, same as SH11PA, same as SH21PA, same as SH28PA, same as SH29PA, same as SH30PA, and same as FS — 1265 — 300 (above, East ledouconing Polystone Oxygen Institute shares Co., Ltd.), Ding SF — 4 4 40, TSF-4300, TSF — 4445, TSF-4446, TSF — 44 6 〇, TSF — 4 4 5 2 (above, manufactured by Toshiba Polysiloxane Co., Ltd.) name. These surfactants can be used alone or in combination of two or more. The use ratio of the surfactant varies depending on the kind or the type or ratio of each component constituting the curable composition, and it is preferably 0 to 100 parts by weight for 100 parts by weight of the component (A), and more preferably A range of 0 · 0001 to 5 parts by weight. The hardened composition of the present invention is prepared by uniformly mixing the above-mentioned component (A), component (B), and other components contained as necessary, and generally each component is dissolved in an organic solvent as a composition solution. The organic solvent used to prepare the composition solution is not particularly limited as long as it can dissolve each component uniformly and does not react with each component. Generally, as those who are more likely to form a coating film, for example, ethylene glycol monomethyl ether and ethylene glycol monoethyl ether glycol ethers; methyl cellosolve acetate, ethyl cellosolve Agent acetates, ethylene glycol alkyl ether acetates of ethylene glycol monobutyl ether acetate; diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol dimethyl ether , Diethylene glycol diethyl ether, diethylene glycol; propylene glycol methyl ether acetate, propylene glycol ethyl ether acetate, propylene glycol alkyl ether acetate of propylene glycol propyl ether acetate; toluene, xylene Aromatic (please read the notes on the back before filling in the poverty) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -22-499446 A7 B7 V. Description of the invention (20) Hydrocarbon group; methyl Ketones of ethyl ketone, cyclohexanone, 4-hydroxy-4 4-methyl-2-pentanone; ethyl 2-hydroxypyruvate, ethyl 2-hydroxy-2-methylpyruvate, ethoxyacetic acid Ethyl, ethyl glycolate, 2-hydroxy-3-methylbutyrate methyl, ethyl 3-methoxypropionate, 3-methoxypropionic acid Yl, 3 - methyl ethoxypropionate, 3 - ethoxy-propionic acid ethyl ester, ethyl acetate, butyl acetate, methyl lactate, ethyl lactate. These solvents may be used alone or in combination of two or more kinds. The concentration of the curable composition of the composition solution is not particularly limited, and may be appropriately selected according to the purpose of use. The concentration of the solid content is preferably 1 to 60% by weight, and more preferably 5 to 40% by weight. By using the cured composition of the present invention, for example, the following cured film can be formed. That is, the adjusted composition solution is applied to the surface of a substrate on which a hardened film must be formed, and the solvent is removed by pre-baking to form a hardened composition coating film, or the pre-baked coating film is irradiated with radiation to make the coating film The surface is hardened, and then a hardened film is formed by performing a main baking step. The coating method of the composition solution is not particularly limited, and various methods such as a spray method, a roll coating method, and a spin coating method can be used. The pre-baking conditions vary depending on the type of each component of the composition solution, the use ratio, etc., and it is preferably about 0.5 to 20 minutes at 60 to 120 t. The main baking conditions are preferably about 0.2 to 2.0 hours at 150 to 250 ° C. In addition, the pre-baking and main baking can be performed in one or two stages according to the Chinese National Standard (CNS) A4 specification (210X297 mm) -23-nr (please read the precautions on the back before filling in the poverty) -Binding and printing printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 499446 A7 _____B7 5. The steps of the invention description (21) are combined. In the curable composition of the present invention, the epoxy compound as the component (A), (B) (please read the precautions on the back before filling this r) and the compound containing the acid generated by heat or radiation as the component (C) Therefore, the surface can be hardened by heating of the coating film or irradiation of radiation. Therefore, after the hardening composition is applied for pre-baking, or the coating film of the hardening composition is formed, the surface of the coating film is hardened by radiation irradiation, and the main baking can prevent the flow of the coating film surface. As a result, , Can form a hardened film with higher surface flatness. The cured film formed by the curable composition of the present invention has excellent physical properties, as shown in the following examples. For example, the use of a color filter for LC and a color filter for CC is excellent as a protective film. Hereinafter, the present invention will be described in detail by examples, but the present invention is not limited by the examples. In the examples, "%" means "weight ° / 〇" unless otherwise specified. Synthesis Example 1 (Synthesis of Polymer (A 1)) 80 parts by weight of propylene oxide printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Methyl methacrylate and 20 parts by weight of styrene were added to 200 parts by weight of propylene glycol monomethyl ether acetate and mixed, and 4.0 parts by weight of azobisisobutyronitrile (AIBN) was added. Polymerization was performed at 95 ° C for 3 hours to obtain a polymer solution having a polymer (A1) concentration of 32%. The polystyrene equivalent weight average molecular weight (M w) of the copolymer (A 1) was 4,000. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -24-499446 A7 B7 V. Description of the invention (22) Synthesis example 2 (synthesis of polymer (A 2)) (Please read the first Please fill in this page again.) 50 parts by weight of glycidyl methacrylate and 50 parts by weight of dicyclopentyl methacrylate are added to 200 parts by weight of propylene glycol monomethyl ether acetate. After mixing, 4.0. Parts by weight of azobisisobutyronitrile (AIBN) was added, and then a polymerization reaction was performed at 95 ° C for 3 hours to obtain a polymer solution having a polymer (A2) concentration of 32%. The polystyrene equivalent weight average molecular weight (^ 1 ~) of the copolymer (A2) was 5,000. Synthesis Example 3 (Synthesis of Polymer (A3)) 60 parts by weight of glycidyl methacrylate, 30 parts by weight of styrene, and 10 parts by weight of methmethacrylate were added to 20 0 parts by weight of propylene glycol monomethyl ether acetate was mixed, 4.0. Parts by weight of azobisisobutyronitrile (AIBN) was added, and then a polymerization reaction was performed at 95 ° C for 3 hours to obtain a polymer (A 3) A polymer solution with a concentration of 32%. The polystyrene-equivalent weight average molecular weight (M w) of the copolymer (A2) printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is 4,000,000. Example 1 A hardening composition. Preparation of hardenable composition A polymer solution containing the polymer (A 1) synthesized as described in Synthesis Example 1 above (equivalent to 100 parts by weight (solid portion) of the polymer (this paper size applies Chinese national standards) (CNS) A4 specification (210X297 mm) -25-499446 A7 B7 V. Description of the invention (23) (Please read the precautions on the back before filling out this purchase) A 1)) 100 parts by weight of propylene glycol monomethyl After diethyl ether acetate is diluted, 20 parts by weight of Epicote 828 (diphenol A epoxy resin, manufactured by Sinopec Epoxy Co., Ltd.) as a component (B), and added as a component (C) 2 parts by weight of 4-ethylammonium phenyl dimethyl sulfonium salt hexafluoric antimonate, 6 parts by weight of τ-glycidoxypropyldiethoxysilane added as an organosilane coupling agent, and hardening acceleration 0.1 parts by weight of 2-ethyl-4-methylimidazole and 0.1 parts by weight of megafak F172 (fluorine-based surfactant, Dainippon Ink Chemical Industry Co., Ltd.) are added as a surfactant. (Manufactured), and hardened composition was obtained after sufficient stirring. The above-mentioned curable composition (S 1) was coated on a glass substrate with a thickness of 2 // m using a spin coater, and pre-baked at 80 ° C for 3 minutes to form a coating. membrane. The formed coating film was then subjected to a main baking step at 250 ° C for 1 hour in a purification oven to form a flat film. Formation of a flattening film (Π) Printed on a glass substrate by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and masked with J s R pigment-based colors (R · G · B) to form stripes with red, blue, and green colors. Substrate with color filter (stripe width of 1 0 0 ί / m). The unevenness on the surface of this glass substrate having a color filter was measured using a surface unevenness meter a-s t e p (manufactured by Tencol Corporation) to be 1 · 0 // m. On the glass substrate forming the color filter, the steps of forming the flattening film (I) are the same as above, and the hardening composition is applied, pre-baked, and the paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) ) -26-499446 A7 ________B7_ 5. Description of the invention (24) and main baking to form a flattening film (Π). (Please read the precautions on the back to fill in this question first.) Evaluation of adhesion of flattened film JIS K-5400 (1900) 8.5 Adhesion test using the 8 · 5 · 2 grid tape method to flatten the above The film (I) and the flattened film (Π) were formed into square grids with a cutter to perform an adhesion test. At this time, the number of grids remaining without peeling is shown in Table i. The adhesion of the planarization film (I) is adhesion (I), and the adhesion of the planarization film (π) is adhesion (π). In the pencil scratch test of JIS κ-5400 (1900) 8 · 4, the test method of 8 · 5 · 1 shall prevail. The pencil-scratch test is performed on the flattened film (I) formed as described above. The evaluation of the surface hardness of the flattened film was performed. The results are shown in Table 1. The peeling substrate formed by the flattened film (I) formed as described above is printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Acid-resistant Economy in the HC Ι / FeC 12 · Η20 / water = 2/1/1 weight ratio aqueous solution After immersion at 45 ° C for 15 minutes, the appearance of the flattened film was observed to evaluate the acid resistance of the protective film. At this time, those with no change in appearance are good acid resistance (〇), and those with peeled appearance and whitening are poor acid resistance (X) 〇 This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -27 -499446 A7 B7 V. Description of the invention (25) Resistance (please read the precautions on the reverse side before filling in this document) The peeling substrate formed by the flattening film (I) is immersed in a 5% by weight sodium hydroxide aqueous solution After being immersed at 30 ° C for 30 minutes, the acid resistance of the protective film was evaluated by observing the appearance change of the flattened film. At this time, those who have no change in appearance are considered to have good alkali resistance (0), while those whose appearance has been peeled off and whitened are considered to have poor acid resistance (X). Heat discoloration resistance A transmission spectrum of a wavelength of 400 to 700 nm was measured on a glass substrate formed of the planarizing film (I). This glass substrate was heated in a cleaning oven at 250 ° C for 60 minutes, and then a transmission spectrum of a wavelength of 400 to 700 nm was measured. The change of the transmission spectrum of 400 nm before and after the heating was investigated to evaluate the heat discoloration resistance. The change rate of the 400 nm transmission spectrum before and after heating is shown in Table 1. Planarity The surface unevenness of the flattening film (Π) was measured as the surface unevenness α-printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The flattening rate calculated based on the following formula is shown in the table.] _ Flattening rate = surface unevenness of the flattened film (Π) / surface unevenness of the color filter before the protective film coating X 1 〇 Example 2 For Example 1, except for Epicote 8 2 8 as the component (B), this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -28-499446 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (26) Except for the addition amount of 40 parts by weight, the same method as in Example i was carried out to obtain a hardenable composition (S 2). In addition, in Example 1, the above-mentioned curable composition (S 2) was used instead of the curable composition (s 1). Otherwise, a planarizing film (" and a planarizing film (π)) were formed in the same manner as in Example 1. Evaluation was performed. The results are shown in Table 1. Example 3 The same method as in Example 丨 was performed except that Epicote 8 2 8 was replaced with Epicote 1 5 2 as the component (B) in Example 1. A hardenable composition (S 3) is obtained. In the same manner as in Example 1, except that the hardenable composition (S 3) is used instead of the hardenable composition (S 1), The flattening film (I) and the flattening film (η) were formed and evaluated. The results are shown in Table 1. Example 4 Preparation of a hardenable composition For Example 1, the polymer was substituted with (A 1 ), A solution containing the polymer (a 2) synthesized in Synthesis Example 2 was used, and as a component (C), 2 parts by weight of 4-ethylammonylmethylphosphonium salt hexafluorochain acid salt was used. Example 1 was performed in the same manner to obtain a hardenable composition (S 4). Hog Standard (CNS) A4 size (21〇 X 297 mm;) --29 _ (Please read the Notes on the back to fill out this page) installed ·
、1T 4 499446 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（27 ) 平坦化膜（I)的形成 玻璃基板上將上述硬化性組成物（S 4 )欲成膜厚度 爲2 //m使用旋轉塗佈器塗佈，以熱板上8 0°C下3分鐘 的條件進行預先焙烤形成塗膜。再將此形成的塗膜使用露 光機Canon PLA 501F(Canon股份有限公司製），將g h i 線（波長4 3 6 n m、4 0 5 n m、3 6 5 n m的強度比 =2·7:2·5:4·8)以i線換算的200 m J / c m 2之露光量照射。其後，形成塗膜的基板於淨化 烤箱中於2 5 0 °C下進行1小時的主焙烤步驟，而形成平 坦化膜。 平坦化膜（E )的形成 於玻璃基板上以J S R顏料係顏色遮蔽（R · G · b )形成具有條紋狀的紅、藍、綠三色的彩色濾器（條紋寬 爲1 〇 〇 /zm)之基板。此具有著色層的玻璃基板表面之 凹凸，使用表面凹凸計α - step(tencol公司製）測定爲 1 ·〇 # m 〇 此形成著色層的玻璃基板上，如上述平坦化膜（ί ) 的形成步驟相同，經硬化性組成物的塗佈、預先焙烤、光 照射以及主焙烤而形成平坦化膜（Π )。 平坦化膜的評價 使用上述所形成的平坦化膜（I )以及平坦化膜（π )’與實施例1相同方法進行平坦化膜的評估。其評估結 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公慶)~ΓβπΤ -- (請先閱讀背面之注意事項再填寫本I) -裝· 訂 -4 499446 A7 B7 五、發明説明（28 ) 果如表1所示。 實施例5 (請先閲讀背面之注意事項再·填寫本贤) 對於實施例1取代含有聚合物（A 1 )的溶液使用含 有前述合成例（3 )合成的聚合物（A 3 )的溶液，作爲 成分（C )使用2重量份的3 一苄基苯并基噻唑鑰鹽六氟 銻酸鹽’其他與實施例1相同得到硬化性組成物（s 5 ) 〇 又’對於實施例1取代硬化性組成物（S 1 )使用上 述硬化性組成物（S 5 )其他與實施例1相同形成平坦化 膜（I )以及平坦化膜（II )，進行評估結果如表1所示 〇 實施例6 將2 0重量份的無水扁苯三酸溶解於二甘醇二甲醚（ 二乙二醇二甲基醚），調製出濃度30重量％的無水扁苯 三酸的二甘醇二甲醚溶液中所成之硬化劑溶液。 經濟部智慧財產局員工消費合作社印製 前述實施例2所調製出的硬化性組成物（S 2 )中添 加上述硬化劑溶液後混合，調製成硬化性組成物（S 6 ) 〇 又，對於實施例1，取代硬化性組成物（S 1 )使用 上述硬化性組成物（S 6 )，其他與實施例1相同形成平 坦化膜（I )以及平坦化膜（Π )，進行評估。結果如表 1所示。 本紙張尺度適用中國國家標準（CNS ) A4規格（210x297公釐）-31 - 499446 A7 ----；__^B7_ 五、發明説明（29 ) 比較例 對於實施例1而言，未添加（C )成分以外與實施例 1相同調製成硬化性組成物（R i )。 .又，對實施例1而言，取代硬化性組成物（s i )使 用上述硬化性組成物（R 1 )其他與實施例i相同形成平 坦化膜（I )以及平坦化膜（π )，進行評估。結果如表 1所示。 表1 經濟部智慧財產局員工消費合作社印製 \ 密著性 表面 耐酸 耐鹼 耐熱變 平坦化率 (%) \ (I) (II) 硬度 性 性 色性（％) 實施例 1 100/100 100/100 4H 〇 〇 2 __— 24 實施例 2 100/100 100/100 5H 〇 〇 2 '^^^、 10 實施例 3 100/100 100/100 5H 〇 0 2 20 實施例 4 100/100 100/100 3〜4H 〇 〇 3 '---- 16 實施例 5 100/100 100/100 5H 〇 〇 2 21 實施例 6 100/100 100/100 4 Η 〇 〇 2 -——. 22 比較例 100/100 100/100 4Η 〇 〇 3 '---- 45 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）· 32 - 499446 A 7 B7 五、發明説明（3〇 ) 本發明的硬化性組成物而言，即使如上述表面平坦性 較低的基體，該基體上可形成平坦性較高之硬化膜，而且 可形成具有表面硬度高、耐熱性、耐酸性、耐鹼性等各種 耐性之優點的硬化膜。 (請先閲讀背面之注意事項再试寫本實) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）-33 -1T 4 499446 A7 B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (27) Formation of the flattening film (I) The above-mentioned hardening composition (S 4) is to be formed into a film thickness of 2 // m Coating with a spin coater, and baking in advance at 80 ° C for 3 minutes on a hot plate to form a coating film. Then, the formed coating film was exposed to light using Canon PLA 501F (manufactured by Canon Co., Ltd.), and the intensity ratio of the ghi lines (wavelengths 4 3 6 nm, 40 5 nm, 3 6 5 nm = 2 · 7: 2 · 5: 4 · 8) Exposure to 200 m J / cm 2 of dew light in i-line conversion. Thereafter, the substrate on which the coating film is formed is subjected to a main baking step in a purification oven at 250 ° C for 1 hour to form a flattened film. The flattening film (E) is formed on a glass substrate with a JSR pigment-based color mask (R · G · b) to form a stripe-shaped red, blue, and green color filter (stripe width of 100 / zm) The substrate. The unevenness on the surface of the glass substrate having the colored layer was measured using a surface unevenness meter α-step (manufactured by Tencol Corporation) to be 1 · 〇 # m 〇 On the glass substrate on which the colored layer was formed, the flattening film (ί) was formed as described above. The steps are the same, and a flattening film (Π) is formed by coating, curing in advance, light irradiation, and main baking of the curable composition. Evaluation of Planarization Film The evaluation of the planarization film was performed in the same manner as in Example 1 using the planarization film (I) and the planarization film (π) 'formed as described above. The paper size of the evaluation results is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 public holiday) ~ ΓβπΤ-(Please read the precautions on the back before filling in this I)-Binding · Book-4 499446 A7 B7 V. Description of the invention (28) The results are shown in Table 1. Example 5 (Please read the precautions on the back before filling in this sect.) For the solution containing polymer (A 1) in Example 1 instead of the solution containing polymer (A 3) synthesized in Synthesis Example (3), As the component (C), 2 parts by weight of 3-monobenzylbenzothiazole key salt hexafluoroantimonate was used. 'Others were the same as in Example 1 to obtain a hardening composition (s 5). The hardening composition (S 1) was used to form the flattening film (I) and the flattening film (II) in the same manner as in Example 1 except that the hardening composition (S 5) was used. The evaluation results are shown in Table 1. Example 6 Dissolve 20 parts by weight of anhydrous trimellitic acid in diglyme (diethylene glycol dimethyl ether) to prepare a solution of 30% by weight of anhydrous trimellitic acid in diglyme Hardener solution formed in the. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the hardening composition (S 2) prepared in the above Example 2 and added the hardening agent solution and mixed to prepare a hardening composition (S 6). In Example 1, the above-mentioned curable composition (S 6) was used in place of the curable composition (S 1), and the planarization film (I) and the planarization film (Π) were formed in the same manner as in Example 1 and evaluated. The results are shown in Table 1. This paper size applies the Chinese National Standard (CNS) A4 specification (210x297 mm) -31-499446 A7 ----; __ ^ B7_ V. Description of the invention (29) Comparative Example For Example 1, no addition (C Except for the components), a curable composition (R i) was prepared in the same manner as in Example 1. In Example 1, instead of the hardenable composition (si), the above-mentioned hardenable composition (R1) was used, and the planarization film (I) and the planarization film (π) were formed in the same manner as in Example i. Evaluation. The results are shown in Table 1. Table 1 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs \ Adhesive surface Acid and alkali resistance Heat resistance flattening rate (%) \ (I) (II) Hardness and color (%) Example 1 100/100 100 / 100 4H 〇〇2 __- 24 Example 2 100/100 100/100 5H 〇〇2 '^^^, 10 Example 3 100/100 100/100 5H 〇 2 20 Example 4 100/100 100 / 100 3 ~ 4H 〇〇3 '---- 16 Example 5 100/100 100/100 5H 〇〇2 21 Example 6 100/100 100/100 4 Η〇〇2 -——. 22 Comparative Example 100 / 100 100/100 4Η 〇〇3 '---- 45 This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) · 32-499446 A 7 B7 V. Description of the invention (3〇) The hardening of the present invention In terms of the composition, even if the substrate has a low surface flatness as described above, a hardened film with higher flatness can be formed on the substrate, and various resistances such as high surface hardness, heat resistance, acid resistance, and alkali resistance can be formed. Advantages of hardened film. (Please read the precautions on the back before trying to write the actual document.) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -33-
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| JP11158967A JP2000344866A (en) | 1999-06-07 | 1999-06-07 | Curable composition for flattened film, and flattened film |
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| JP2003128957A (en) * | 2001-10-25 | 2003-05-08 | Jsr Corp | Curable composition for forming protective film, method for forming protective film and protective film |
| KR100954044B1 (en) | 2002-05-14 | 2010-04-20 | 제이에스알 가부시끼가이샤 | Resin Composition and Protective Film |
| KR100789589B1 (en) * | 2005-01-25 | 2007-12-28 | 주식회사 엘지화학 | Thermally curable resin composition with extended storage stability and good adhesive property |
| KR100777582B1 (en) * | 2005-12-01 | 2007-11-28 | 주식회사 엘지화학 | Composition for preparing thermosetting resin, thermosetting resin prepared by the same, and thermosetting resin composition comprising the same |
| CN101896537B (en) | 2007-12-10 | 2012-10-24 | 株式会社钟化 | Alkali-developable curable composition, insulating thin film using the same, and thin film transistor |
| WO2009104643A1 (en) * | 2008-02-20 | 2009-08-27 | 日産化学工業株式会社 | Photocurable film-forming composition and method of forming a photocurable film |
| KR102165728B1 (en) | 2014-07-24 | 2020-10-14 | 닛산 가가쿠 가부시키가이샤 | Resin composition for forming color filter underlayer film |
| TWI675907B (en) | 2015-01-21 | 2019-11-01 | 日商Ｊｓｒ股份有限公司 | Solid imaging device |
| US10774237B2 (en) | 2015-10-13 | 2020-09-15 | Nissan Chemical Industries, Ltd. | Thermosetting resin composition |
| JP6623839B2 (en) * | 2016-02-29 | 2019-12-25 | 日産化学株式会社 | Resin composition for forming flattening film |
| CN113631586A (en) | 2019-03-29 | 2021-11-09 | 日产化学株式会社 | Low-temperature curable resin composition |
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| JPS5819325A (en) * | 1981-07-27 | 1983-02-04 | Sakamoto Yakuhin Kogyo Kk | Heat-resistant epoxy resin composition |
| KR920007757B1 (en) * | 1987-10-13 | 1992-09-17 | 미쓰이 세끼유 가가꾸 고오고오 가부시끼가이샤 | Epoxy resin process for its production and process for producing epoxy foam |
| KR930011004B1 (en) * | 1990-10-26 | 1993-11-19 | 삼성전자 주식회사 | Position control method of robot |
| JP3074850B2 (en) * | 1991-09-20 | 2000-08-07 | ジェイエスアール株式会社 | Protective film material |
| JP3321858B2 (en) * | 1992-11-25 | 2002-09-09 | ジェイエスアール株式会社 | Thermosetting resin composition |
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| JP2000344866A (en) | 2000-12-12 |
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