TW498056B - Method for treating waste water by oxygen-containing water reflux type biological active carbon and device therefore - Google Patents
Method for treating waste water by oxygen-containing water reflux type biological active carbon and device therefore Download PDFInfo
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- TW498056B TW498056B TW089100672A TW89100672A TW498056B TW 498056 B TW498056 B TW 498056B TW 089100672 A TW089100672 A TW 089100672A TW 89100672 A TW89100672 A TW 89100672A TW 498056 B TW498056 B TW 498056B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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498056 五、發明說明α) 產業上利用領域 本發明係關於利用一組生物活性碳單元結合一組供氧 單元的廢水處理方法及裝置,其間處理的廢水在放流之前 利用泵浦將供氧單元之含氧水迴流至生物活性竣單元,以 提供活性碳上微生物足夠之氧氣,達到去除水/廢水中之 污染質如COD,B0D及TKN等。其應用範圍可涵蓋廢水之二 級處理、高級處理、飲用水去除氨氮、三自甲烷等致癌前 驅物之高級處理,本發明亦可與臭氧系統併用,作進一步 之處理。 習知技術 為使廢(污)水處理效果達到最終水質淨化之目標,在 傳統的生物處理系統後端銜接活性石炭吸附單元,以將殘留 之污染質如COD、BOD、TKN等去除,是目前廣為一般環工 技藝習用者,但傳統上所使用的活性碳吸附單元將可能因 吸附飽合而無法發揮去除污染質之功用,故必須廢棄更新 或再生活性碳’以維持原有功能,不僅增加操作人力及費 用,且廢棄後的活性碳更需另行處理而增加處理負擔。近 年來已發展一種生物活性碳處理技術,即在活性碳上植入 適當量之微生物,使其不僅保有傳統活性碳之吸附能力 外’更能發揮生物分解去除之功能,研究顯示,對於同樣 濃度之有機廢水,採用生物性碳可延滯活性碳吸附飽合之 時間達5 - 1 0倍左右(依廢水種類及濃度而定)。由此證明生 物活性碳在廢(污)水高級處理上有極大之應用空間。而為 了讓活性碳上之微生物能有效分解進流水中之污染質,供498056 V. Description of the invention α) Field of industrial utilization The present invention relates to a method and a device for treating wastewater using a group of biological activated carbon units and a group of oxygen supply units, and the treated wastewater is pumped to the oxygen supply unit before being discharged. Oxygen-containing water is returned to the biologically active unit to provide sufficient oxygen to the microorganisms on the activated carbon to remove pollutants such as COD, BOD, and TKN from water / wastewater. Its application scope can include secondary treatment of wastewater, advanced treatment, advanced treatment of carcinogenic precursors such as ammonia nitrogen removal from drinking water, and tri-methane. The invention can also be used in combination with the ozone system for further treatment. In order to achieve the goal of final water purification by the conventional technology, the active carbon adsorption unit is connected to the back end of the traditional biological treatment system to remove residual pollutants such as COD, BOD, TKN, etc. It is widely used by general environmental engineering practitioners, but the activated carbon adsorption unit traditionally used may not perform the function of removing pollutants due to adsorption and saturation. Therefore, it must be discarded to renew or regenerate activated carbon to maintain its original function. The operation manpower and cost are increased, and the waste activated carbon needs to be treated separately, which increases the processing burden. In recent years, a biological activated carbon treatment technology has been developed, that is, an appropriate amount of microorganisms are implanted on the activated carbon so that it not only retains the adsorption capacity of traditional activated carbon, but also exerts the function of biological decomposition and removal. Studies have shown that for the same concentration For organic wastewater, the use of biological carbon can delay the adsorption and saturation of activated carbon by about 5 to 10 times (depending on the type and concentration of wastewater). This proves that biological activated carbon has great application space in advanced treatment of waste (sewage) water. In order to allow microorganisms on activated carbon to effectively decompose the pollutants in the flowing water,
第5頁 498056 五、發明說明(2) 應足夠之氧氣量是必需之條件。而在室溫情況下,水中之 飽合f氧量約為8 mg/L,亦即如果在傳統固定床式之生物 活,,系統中,僅讓污水流過生物活性碳床,在無額外供 應氧氣情況下,生物作用所能去除之c〇D濃度,最高僅能、 達8mg/L,該系統除應用在極低濃度之淨水處理外,應用 空間極有限。若某廢水進流濃度達(:〇1) 2〇〇mg/L,則必須 重復,理達十二次以上’方能將污染值逐次降解至民國八 十t i放流水標準C0D i〇0mg/L以丁,此將使反應槽之體 積a j 3曰力Z ,不敷實際需求。為改進此缺點,較習用之方 /套疋以連績曝氣之方式維持生物活性碳塔槽内之溶氧量, 以染質之去除率。此外為了獲得充足之溶氧量及使 活***攪動(流體化)以增加與有機質及氧氣之接觸,必須 提供足夠動能的進氣’但劇烈之氣動將產生較大剪力,而 使,性碳顆粒因磨擦導致碎裂而流失,故需經常補充,且 造$放流水中懸浮微粒(SS)濃度偏高。另一方面在此種流 ΐίΐ二生物:舌性碳處理系統中,活性碳之填充率無法太 仏 勹】保符疋桎度之污染質去除率, Ϊ 上之活性碳總量,®此勢必導致反應槽 總體積增大,而且反應槽必須維持一定以上之高度 二以設置沉澱槽’否則流動化之活性碳將漂曹:。 j積之=增大及高度之必須增冑,皆將使整體工程費用 批咼,此為極大之不利點。 本發明為克服生物活性石炭系統在應用上所面臨之上述 缺點,而採含氧水迴流方式,於傳統之生物活性碳反應槽 498056 五、發明說明(3) 除另設置一「供氧槽」外,亦設置一迴流裝置,對進流廢 (污)水提供大量之空氣,以便進入生物活性碳槽中可供應 微生物賴以分解污染質之足夠氧氣,而依進流水中之污染 質濃度,可設定迴流再曝氣之流量比例,以確保處理效 果。此外本發明係以迴流水帶動活性碳床之流動除可提供 足夠之氧氣量以供生物分解外,同時亦避免直接供應氧氣 因劇烈之氣動造成活性碳磨擦而導致碎裂之問題,也因此 不必擔心因碎裂的活性碳顆粒之漂流而須建造體積龐大或 高度極高之反應槽的缺點,而更符合經濟效益。 本發明之目的 本發明之主要目的乃在於提供一種生物活性碳新技 術,以改善上述習知技術之缺點,使本技術可較習知技術 應用於水/廢水處理能更有效及更具經濟價值。其目的有 1.提高處理效率:利用含氧水迴流方式,增加水中溶氧 量,以提高污染質之去除效率,2 ·減少活性碳之磨耗:利 用含氧水迴流自活性碳床底部流入向上至頂部流出,使活 性碳層輕微膨化,減少顆粒間之磨擦及磨耗,3.無需設置 前處理設施:因活性碳床為膨化狀態,顆粒間孔隙不致被 懸浮性固體物堵塞,可允許僅經沉澱池處理後之水/廢水 直接流入,無需設置前過濾處理設施,4.降低單元設置高 度:採用含氧水迴流方式供應氧氣及膨化活性碳層,非為 利用氣昇管式,故單元高度可以降低,5.增加活性碳填充 率:非以氣昇管方式揚昇活性碳,故可增加填充率至Page 5 498056 V. Description of the invention (2) A sufficient amount of oxygen is a necessary condition. At room temperature, the saturated oxygen content in water is about 8 mg / L, that is, if the biological activity of the traditional fixed bed type, the system only allows sewage to flow through the biological activated carbon bed. In the case of oxygen supply, the maximum concentration of coD that can be removed by biological action can only reach 8mg / L. This system has a limited application space except for the application of very low concentration of purified water treatment. If the inflow concentration of a certain wastewater reaches (: 〇1) 200mg / L, it must be repeated, and it must be repeated more than twelve times before the pollution value can be successively degraded to the standard of 80 ti release water of the Republic of China. L is small, which will make the volume aj of the reaction tank a force Z, which is insufficient for actual needs. In order to improve this shortcoming, the more commonly used formula / sleeve is used to maintain the dissolved oxygen content in the biological activated carbon tower tank by continuous aeration, in order to remove the chromatin. In addition, in order to obtain a sufficient amount of dissolved oxygen and agitate (fluidize) the active slave to increase the contact with organic matter and oxygen, it is necessary to provide sufficient kinetic energy for the intake air. The particles are lost due to friction caused by friction, so they need to be replenished frequently, and the concentration of suspended particles (SS) in the release water is relatively high. On the other hand, in this kind of biological organism: tongue-type carbon treatment system, the filling rate of activated carbon cannot be too high] the removal rate of pollutants that guarantees the degree of protection, the total amount of activated carbon on Ϊ, this is bound to As a result, the total volume of the reaction tank is increased, and the reaction tank must be maintained at a certain height or higher to set up a precipitation tank. Otherwise, the fluidized activated carbon will drift. The product of j = increase and height must be increased, which will cause the overall engineering costs to be approved, which is a great disadvantage. In order to overcome the above-mentioned shortcomings encountered in the application of the bioactive charcoal system, the present invention adopts an oxygen-containing water reflux method in a traditional bioactive carbon reaction tank 498056. V. Description of the invention (3) In addition to an "oxygen supply tank" In addition, a reflux device is also provided to provide a large amount of air to the influent waste (sewage) water so that it can enter the biological activated carbon tank to supply sufficient oxygen for the microorganisms to break down the pollutants, and depending on the concentration of the pollutants in the flowing water, The flow ratio of reflux and aeration can be set to ensure the treatment effect. In addition, the present invention drives the flow of activated carbon bed with reflux water. In addition to providing sufficient oxygen for biodegradation, it also avoids the problem of direct supply of oxygen caused by the aerodynamic friction of activated carbon caused by the abrasion. Worrying about the disadvantage of having to build a large or extremely high reaction tank due to the drifting of the broken activated carbon particles, which is more economical. OBJECTS OF THE INVENTION The main purpose of the present invention is to provide a new biological activated carbon technology to improve the shortcomings of the above-mentioned conventional technologies, so that this technology can be more effective and economical than conventional technologies for water / wastewater treatment. . The objectives are: 1. To improve the treatment efficiency: use the oxygen-containing water reflux method to increase the amount of dissolved oxygen in the water to improve the removal efficiency of the pollutants; 2. reduce the wear of activated carbon: use oxygen-containing water reflux to flow from the bottom of the activated carbon bed upward It flows out to the top to make the activated carbon layer slightly swell, reducing friction and abrasion between particles. 3. No pre-treatment facilities are needed: Because the activated carbon bed is in an expanded state, the pores between the particles are not blocked by suspended solids. The water / wastewater treated by the sedimentation tank flows directly without the need to set up a pre-filtration treatment facility. 4. Reduce the height of the unit: Oxygen-containing water is used to supply oxygen and puffed activated carbon layers. It is not a gas riser, so the unit height Can be reduced, 5. Increase the activated carbon filling rate: the activated carbon is not lifted by means of a gas riser, so the filling rate can be increased to
498056 五、發明說明(4) 6 0%。 發明的技術手段 為達到上述目的,依本發明内容而完成的一含氧水迴 流式生物活性碳的廢水處理方法包含下列步驟: a) 將待處理廢水導入一供氧槽以空氣或其它含氧氣 體於其中進行曝氣,而增加水中含氧量; b) 將步驟a)獲得的氧氣增濃廢水導入一内含生物活 性石炭床的反應槽的底部,於是膨化該生物活性碳床,並於 該反應槽的上部產生一處理過廢水; c ) 將該處理過廢水的一部份於過濾後放流,及將另 一部份迴流至該供氧槽内與該待處理廢水同時進行曝氣。 依本發明内容而完成的另一種含氧水迴流式生物活性 碳的廢水處理方法,其包含下列步驟: a) 將待處理廢水導入一内含生物活性碳床的反應槽 的上部並與該反應槽内的處理水混合; b ) 從步驟a )的反應槽的上部取出該混合水,並導入 一供氧槽以空氣或其它含氧氣體於其中進行曝氣,而增加 水中含氧量; c ) 將步驟b)獲得的氧氣增濃處理水的一部份於過濾 後放流,而另一部份迴流至導入該反應槽的底部,於是膨 化該生物活性碳床。 於本發明方法中該放流水的流量與進流的待處理廢水 的流量實質上相等而被維持於一穩定操作狀態。498056 V. Description of the invention (4) 60%. Technical means of the invention In order to achieve the above-mentioned object, an oxygen-containing water reflux type biological activated carbon wastewater treatment method completed according to the present invention includes the following steps: a) introducing waste water to be treated into an oxygen supply tank with air or other oxygen-containing gas The gas is aerated therein to increase the oxygen content in the water; b) the oxygen-enriched wastewater obtained in step a) is introduced into the bottom of a reaction tank containing a bioactive charcoal bed, so the bioactive carbon bed is expanded, and A treated wastewater is generated in the upper part of the reaction tank; c) a part of the treated wastewater is discharged after filtering, and the other part is returned to the oxygen supply tank and aerated simultaneously with the wastewater to be treated. Another method for treating wastewater containing oxygen-containing water-return type biologically active carbon completed according to the present invention includes the following steps: a) introducing the waste water to be treated into the upper part of a reaction tank containing a biologically active carbon bed and reacting with the reaction Mix the treated water in the tank; b) take out the mixed water from the upper part of the reaction tank in step a) and introduce it into an oxygen supply tank to aerate it with air or other oxygen-containing gas to increase the oxygen content in the water; c ) Part of the oxygen-enriched water obtained in step b) is discharged after filtering, and the other part is refluxed to the bottom of the reaction tank, and the biological activated carbon bed is expanded. In the method of the present invention, the flow rate of the discharged water is substantially equal to the flow rate of the incoming wastewater to be treated, and is maintained in a stable operation state.
第8頁 498056 五、發明說明(5) 於本發明方法中該 流量的比例可视待處理 於8 - 30倍。 於本發明方法中該 碳係被支撐於〜距該反 該迴流係由一介於該反 入該反應槽。 一適用於本發明的 理裝置,包含二組單元 一組為供氧單元;及一 元:包含一桶槽作為一 設置均 於該支 氧槽及 入該供 内的液 位於該 該 式,分 單元的 溢流機 由該生 配管、支撐材及 撐材及集水溢流 一曝氣機構,該 氧槽内部;其中 體導出並使其流 供乳槽内的被曝 生物活性碳單元 別為(1)併構式 供氧槽相連,即 構的二單元共壁 物活性碳單元順 處需設置一阻流板,以 倒流至該生物活性碳單天 迴流的流量與進流的待處理廢水的 廢水的水質而加予調整,一般約介 内含生物活性碳床的反應槽的活性 應槽的底部一段距離的位置上,且 應槽的底部及該支撐位置之間被導 含氧水迴流式生物活性碳的廢水處 ’其中一組·為生物活性碳單元,另 迴流機構’其中該生物活性碳單 反應槽,槽内部由其底部依序間隔 集水溢流機構’一活性碳可被放置 機構之間;該供氧單元:包含一供 曝氣機構將一空氣或一含氧氣體導 该集水溢流機構將一位於該反應槽 入該供氧槽内,及該迴流機構將一 氣液體供應給該反應槽的均配管。 與曝氣單元間’可有兩種連接方 :生物活性碳單元的e — λ $ — p 兀的反應槽及曝氣 兩卓彳朱共壁方-^ 處,於接近該集水 %,開δ又適當孔洞 利流入該曝氣單元,^奢水能 阻止該供氧單元内 兮開孔 元;或⑺分離^生物Λ孔洞 生物活性碳單Page 8 498056 V. Description of the invention (5) The proportion of the flow rate in the method of the present invention can be treated as 8 to 30 times. In the method of the present invention, the carbon system is supported at a distance from the reaction and the reflux system is interposed between the reaction and the reaction tank. A physical device suitable for the present invention includes two groups of units, one of which is an oxygen supply unit; and one unit: a barrel tank is provided as an installation both in the branch oxygen tank and the liquid entering the supply is located in the type, the subunit The overflow machine is an aeration mechanism that overflows the raw piping, support material and support material, and water collection, inside the oxygen tank; the body is led out and flows to the milk tank. The exposed biological activated carbon unit is (1 ) The parallel-type oxygen supply tank is connected, that is, a two-unit co-walled activated carbon unit needs to be provided with a baffle plate in order to flow back to the biological activated carbon single-day reflux flow and the inflow wastewater to be treated The quality of the water is adjusted. Generally, the activity of the reaction tank containing the biological activated carbon bed is located at a distance from the bottom of the reaction tank, and the bottom of the tank and the supporting position are guided by oxygen-containing water returning organisms. One of the activated carbon waste water is a biological activated carbon unit, and the other is a reflux mechanism. The biological activated carbon is a single reaction tank, and the inside of the tank is sequentially spaced by a water collection overflow mechanism. An activated carbon can be placed on the mechanism. between The oxygen supply unit includes an aeration mechanism to guide an air or an oxygen-containing gas to the water collection overflow mechanism, a reaction tank located in the oxygen supply tank, and a reflux mechanism to supply a gas liquid to the reaction The pipes are uniformly piped. There can be two types of connections between the “aeration unit” and the “a — λ $ — p” reaction tank of the biological activated carbon unit and the aquarium and the aquarium. Appropriate holes flow into the aeration unit, and the extra water can prevent the open cells in the oxygen supply unit; or separate the biological activated carbon from the holes
第9頁 498056 五、發明說明(6) 元的反應槽 物活性破早 氣單元的供 該供氧槽内 位於該反應 情形下被導 適用於 一組散氣頭 其中該鼓風 該散氣頭並 槽内的沉水 適用於 部與該均配 型或沉水式 較佳地 理裝置可進 排出的放流 及曝氣單元 元的反應槽 氧槽,使一 ,較佳地該 槽内的液體 出並流入該 本發明的該 及設於該供 機或空氣壓 分散進入該 式曝氣機。 本發明的該 管的迴流管 泵浦。 ,本發明的 一步包含 水。 的供氧槽分 壁近該集水 位於該反應 曝氣單元低 由該集水溢 供氧槽内。 曝氣機構可 氧槽外的— 縮機將一空 供氧槽内; 開設置,以〜& 溢流機構處遠 、生 槽内的液體導+、,二* τ出亚流入 於該活性碳單元,於是 流機構處在不需動力的 包含設於該供氧槽内的 鼓風機或空氣壓縮機, 氣或一含氧氣體供應給 亦可採用一值於該供氧 k机機構可包含一連通該供氧槽内 路及叹於該迴流管路上的一陸上 s氧X瘦流式生物活性碳的廢水處 過濾機氺、^ , u ^不過濾由該供氧槽或反應槽 圖示之簡單說明: 圖一 A及B分別為本發明之八^ 、 廢水處理方法的第一及第二實二氧水迴流式生物活性碳的 圖二為適用於本發明第〜命,的机私圖。 活性碳的廢水處理裝置(併構式^施例的含氧水迴流式生物 圖二A為沿圖二中A —A線的^的俯視示意圖。 1崎面示意圖。Page 9 498056 V. Description of the invention (6) The reaction tank is active. The early air unit is broken. The oxygen supply tank is located in the reaction case and is guided to a group of diffuser heads. The submerged water in the parallel tank is suitable for the oxygen tank of the reaction tank that can be discharged into and discharged from the uniformly matched or submerged preferred geographical device, so that one, preferably, the liquid in the tank is discharged. It flows into the aerator of the invention and is provided in the feeder or dispersed by air pressure. The return pipe of the tube of the present invention is pumped. A step of the invention comprises water. The partition wall of the oxygen supply tank is near the water collection tank and is located in the reaction aeration unit. The oxygen supply tank overflows from the water collection tank. The aeration mechanism can be outside the oxygen tank — the shrinking machine will empty an oxygen supply tank; open the installation, and the overflow mechanism is remote and the liquid in the raw tank is guided +, and two * τ outflow into the activated carbon Unit, so the flow mechanism is located in the oxygen supply tank without the need for power, and the air or an oxygen-containing gas is also supplied to the oxygen supply machine. The internal circuit of the oxygen supply tank and the waste water filter at the land s oxygen X thin-flow biological activated carbon sighed on the return pipeline 氺, ^, u ^ do not filter the oxygen supply tank or the reaction tank as shown in the diagram Description: Figures A and B are the first and second solid dioxide recirculating biological activated carbon of the wastewater treatment method of the present invention, respectively, and Figure 2 is a private diagram applicable to the first and second inventions of the present invention. Activated carbon wastewater treatment device (combined structure ^ example of oxygen-containing water reflux type organism) Figure 2A is a schematic plan view taken along the line A-A in Figure 2. Figure 1 is a schematic view of the surface.
498056 五、發明說明(7) 圖三為適用於本發明第二實施例的含氧水迴流式生物 活性碳的廢水處理裝置(分離式)的俯視示意圖。 圖三A為沿圖三中A - A線的斷面示意圖。 主要元件的圖號說明 1.供氧槽 2 .生物活性碳反應槽 3. 迴流泵浦 4. 鼓風機 5. 散氣頭 6. 均配管 7 .集水溢流堰/渠 8 ·阻流板(併構式);迴流水管(分離式) 9.支撐材層 1 0 .活性碳層 1 1.進流管 1 2.出流管 1 3.廢棄活性碳排出管 14.空氣管 1 5 .含氧水迴流管 1 6,1 7 ·排水閥 較佳具體實施例的詳細說明 1.含氧水迴流式生物活性碳處理裝置(併構式)498056 V. Description of the invention (7) FIG. 3 is a schematic top view of a wastewater treatment device (separate type) of an oxygen-containing water recirculation type biological activated carbon suitable for the second embodiment of the present invention. Fig. 3A is a schematic sectional view taken along line A-A in Fig. 3. Description of drawing numbers of main components 1. Oxygen supply tank 2. Biological activated carbon reaction tank 3. Backflow pump 4. Air blower 5. Diffuser 6. Equal piping 7. Water collecting overflow weir / ditch 8 Parallel structure); Return water pipe (separate type) 9. Support material layer 1 0. Activated carbon layer 1 1. Inflow pipe 1 2. Outflow pipe 1 3. Waste activated carbon discharge pipe 14. Air pipe 1 5. Included Oxygen water return pipe 1, 6, 7 · Detailed description of the preferred embodiment of the drain valve 1. Oxygen water return type biological activated carbon treatment device (parallel structure)
第11頁Page 11
爹考圖一 A及圖二所-, 性碳處理裝置處理 不’本务明含氧水迴流式生物活 槽1,由鼓風機4提^空^自^^自進流管11流入供氧 夠之氧氣溶於水中,自j虱碩5進入供氧槽1,供應足 流泵浦3經含氧水迴槽内含有充分氧氣之水/廢水以迴 底部均配管β均句k == 至生物活性碳反應槽2,經由 化,水/廢水中所含=:二向士經支撐材層將活性碳膨 於水中之微生物,\乳 八亂將^供給活性碳顆粒上或懸浮 中之有機污染物,迴治刀旦除吸附於活性碳顆粒内或水 但活性碳顆粒不致户=7,二里需予以控制使活性碳膨脹, 後,少部份排出,^山,=理水經集水溢流堰/渠7收集 卜出 !出流管1 2至過、声嬸留-r 土 一 μ 中),濾除懸浮固體物德妨、、六1〜濾枝早兀(未不於圖 再迴流至供氧槽丄,自μ = ’大部份則經兩槽中間開孔 扞俞it、牛鲈 ^ , 政乳頭5獲得溶氧補充後,再繼續進 :Γ 隔牆處設置-阻流板8,…進? 、1【生::可a r、:、廢水倒流污染已處理水。已吸附飽和之 由廢棄活性碳排出管13排出,廢棄量應由實 定‘生物活性碳去除污染物量所需氧氣多S,可由;= 所提供之氧氣量及含氧水迴流率來調整,供氧槽 / 活性碳反應槽2若需排空存水,可分別由排水閥“或": 之。 々 2 ·含氧水迴流式生物活性碳處理裝置(分離式) 參考圖B及圖二所示,本發明含氧水迴流式生物活 性礙處理裝置處理程序為,水/廢水自進流管丨丨流入生物As shown in Figure 1A and Figure 2, the carbon treatment device does not process the oxygen-containing water reflux biological living tank 1, which is lifted by the blower 4 ^ ^ from ^^ into the oxygen supply pipe 11 The oxygen is dissolved in water, and it enters the oxygen supply tank 1 from J Liaoshuo 5 and supplies foot pump 3 to the water / wastewater containing sufficient oxygen in the oxygen tank to return to the bottom. Activated carbon reaction tank 2, through chemical conversion, contained in water / wastewater =: Micro-organisms that swell activated carbon in water through the support material layer, and feed the organic pollution on activated carbon particles or in suspension In addition to adsorption of activated carbon particles or water, but activated carbon particles do not cause households = 7, Erli needs to be controlled to expand the activated carbon, and then a small part is discharged. Collect the overflow weir / ditch 7! Outflow pipe 12 to, sound retention -r soil 1μ), filter suspended solids Dexuan, 6 1 ~ filter branches early (not return to the oxygen supply tank as shown in the figure, since μ = 'Most of them pass through the middle hole of the two slots to defend Yuit and beef perch ^, after the government nipple 5 has been supplemented with dissolved oxygen, proceed further: Γ set at the partition wall-baffle plate 8, ...? Health :: ar,:, Wastewater backflow pollutes the treated water. The adsorbed and saturated waste is discharged from the waste activated carbon discharge pipe 13, and the amount of waste should be determined by the amount of oxygen required to remove the amount of pollutants from the biological activated carbon. The amount of oxygen provided and the reflux rate of oxygenated water are adjusted. If the oxygen supply tank / activated carbon reaction tank 2 needs to drain the stored water, they can be drained by the drain valve "or" respectively: 之 2 · Oxygenated water reflux type Biological activated carbon treatment device (separate type) Referring to FIG. B and FIG. 2, the treatment procedure of the oxygen-containing water reflux type biological activity hindering treatment device of the present invention is that water / wastewater flows from the inflow pipe into the organism
498〇56 發明説明(9) 潘性敏反應^另由政風機4提供空氣自散氣頭5進入供 氧槽1 ’ i、應足约之氧氣落於水中,該槽内含有充分氧氣 之水/ ’: 7以迴流泵浦3經含氧水迴流管i 5抽至生物活性碳 反應槽:由底部均配管6均句水流後,向上經支^ 、4科漆於k击 中所含之氧氣將^ i、給活性碳顆 粒上或微生物,用以分解去除吸附於活性碳 顆粒内或水中之有機污染物,迴流水流量需予以控制使活 /渠7收亦ί ”自進流官1 1流入槽2之水/廢水混合,經兩槽 中間迴1 ^8再迴流至供氧槽1,自散氣頭5獲得溶氧補充 後,再繼續進行前述步驟,少部份水則於供氧槽上方出流 管12流出,再經過壚機單元(未示於圖中),濾除懸浮固體 物後放流。^吸附飽和之活性碳可由廢棄活性碳排出管】3 2出二,Ϊ $應由實驗決定,生物活性碳去除污染物量所 需氧氣多寡’可由鼓風機所提供之氧氣量及含氧水迴流率 來調整’供氧槽1或生物活性碳反應槽2若需排空存水,可 分別由排水閥1 6或1 7為之。 (實驗例) 本發明曾針對造紙廠廢水、養豬場廢水及農藥廠廢水 進行測試,該等廢水皆已經過原廢水處理廠生物處理,廢 水中易為微生物所分解之污染質大都已去除,若欲以習知 生物技術再做進一少之處理,殊不容易,經以本發明測 試,處理水皆可符合政府最新標準8 7年放流水標準,成效 498056 五、發明說明(ίο) 良好。 實驗例1.造紙廠廢水 實驗裝置規模:6 M3模型廠 處理廢水量:3 5 Μ 3 / D 進流水性質:二級生物處理水 二級生物處理水COD濃度:120〜150mg/L 生物活性碳處理水COD濃度:<100mg/L 運轉時間:1年 迴流的流量與進流的二級生物處理水的流量的比例介 於1 0 - 2 0倍。 於供氧槽的水中溶氧量及放流水的溶氧量分別為6 - 7 mg/L 及0· 5-1 mg/L 。 實驗例2 .養豬場廢水 實驗裝置規模:2 0 0L模型廠 處理廢水量:1. 5M3/D 進流水性質:二級生物處理水 二級生物處理水C0D濃度:250〜350mg/L 生物活性碳處理水C 0 D濃度:< 2 5 0 m g / L 運轉時間:3個月 迴流的流量與進流的二級生物處理水的流量的比例介 於1 0 - 2 G倍。 於供氧槽的水中溶氧量及放流水的溶氧量分別為6 - 7498〇56 Description of the invention (9) Pan Xingmin reaction ^ Another air provided by the government fan 4 from the air diffuser 5 into the oxygen supply tank 1 'i, the oxygen should be enough in the water, the tank contains water with sufficient oxygen / ': 7 is pumped back to the pump 3 through the oxygen-containing water return pipe i 5 to the biological activated carbon reaction tank: from the bottom of the piping 6 jun sentence water flow, and upwards through the branch ^, 4 Division lacquer hit the oxygen contained in k Apply ^ i to the activated carbon particles or microorganisms to decompose and remove the organic pollutants adsorbed in the activated carbon particles or water. The return water flow needs to be controlled so that the live / drain 7 can also be collected. The water / wastewater flowing into the tank 2 is returned to the oxygen supply tank 1 through the middle of the two tanks and then returned to the oxygen supply tank 1. After the dissolved oxygen is obtained from the gas diffusion head 5, the above steps are continued. A small part of the water is supplied in the oxygen supply. The outflow pipe 12 above the tank flows out, and then passes through the grate unit (not shown in the figure) to filter out suspended solids and release. ^ Saturated activated carbon can be discharged from the waste activated carbon discharge pipe] 3 2 out of 2, Ϊ $ 应It is determined by experiments that the amount of oxygen required for the removal of pollutants by biological activated carbon can be provided by the oxygen provided by the blower. The amount of oxygen and the reflux rate of oxygen-containing water are used to adjust the 'oxygen supply tank 1 or biological activated carbon reaction tank 2 to drain the stored water, which can be done by the drain valve 16 or 17 respectively. (Experimental Examples) The present invention has been directed to papermaking Tests are conducted on plant wastewater, pig farm wastewater and pesticide factory wastewater. These wastewaters have been biologically treated in the original wastewater treatment plant. Most of the pollutants in the wastewater that are easily decomposed by microorganisms have been removed. If you want to do it with conventional biotechnology, It is not easy to treat even a small amount of water. After testing with the present invention, the treated water can meet the latest government standards for 87 years of drainage water, and the results are 498056. 5. Description of the invention (() Experiment example 1. Paper mill wastewater experimental device Scale: 6 M3 model plant wastewater treatment capacity: 3 5 Μ 3 / D inflow water properties: secondary biological treatment water COD concentration of secondary biological treatment water: 120 ~ 150mg / L biological activated carbon treatment water COD concentration: < 100mg / L Running time: The ratio of the flow rate of the return flow to the flow rate of the inflow secondary biological treatment water is between 1 and 20 times in 1 year. The dissolved oxygen in the water of the oxygen supply tank and the dissolved oxygen in the discharged water are 6 -7 mg / L and 0. 5-1 mg / L. Test example 2. Experimental scale of pig farm wastewater: 200 0L Model plant wastewater treatment capacity: 1.5M3 / D Inflow water properties: secondary biological treatment water COD concentration of secondary biological treatment water: 250 ~ 350mg / L biological activity Carbon treated water C 0 D concentration: < 2 50 mg / L Operating time: The ratio of the reflux flow rate to the inflow secondary biologically treated water flow rate in 3 months is between 10 and 2 G times. The amount of dissolved oxygen in the tank water and the amount of dissolved oxygen in the draining water are 6-7
498056 五、發明說明(11) m g / L 及 0 · 5 - 1 m g / L。 實驗例3 ·農藥廠廢水 實驗裝置規模:3· 4M3實廠 處理廢水量:35M3/D 進流水性質:二級生物處理水 二級生物處理水C0D濃度:150〜200 mg/L 生物活性碳處理水COD濃度:<100mg/L 運轉時間:1年 迴流的流量與進流的二級生物處理水的流量的比例介 於1 0 - 2 0倍。 於供氧槽的水中溶氧量及放流水的溶氧量分別為7 一 8 mg/L 及0· 5-1 mg/L。 由上述3實驗例可知,本發明對於二級生物處理水所 含有機性污染物可去除至政府民國8 7年放流水標準’其 COD去除率約為20〜50%。 因此與習知技術比較,本發明之進步功效可歸納如 下: 1 ·利用含氧水迴流方式,增加水中溶氧,提高污染質 之去除效率,一般COD去除濃度可達50〜100mg/L,C0D去除 率可達20〜50%。 2 ·因(1 )本發明採用活性碳層膨化方式,不必設置前 過濾設施,(2)本發明採用含氧水迴流方式使活性碳層顆498056 V. Description of the invention (11) m g / L and 0 · 5-1 m g / L. Experimental example 3 · Pesticide plant wastewater experimental device scale: 3.4M3 actual plant wastewater treatment capacity: 35M3 / D Inflow water properties: secondary biological treatment water Secondary biological treatment water COD concentration: 150 ~ 200 mg / L biological activated carbon treatment COD concentration of water: <100mg / L Operating time: The ratio of the flow rate of the return flow to the flow rate of the inflow secondary biological treatment water in 1 year is between 10 and 20 times. The amount of dissolved oxygen in the water of the oxygen supply tank and the amount of dissolved oxygen in the bleed water were 7 to 8 mg / L and 0. 5-1 mg / L, respectively. From the above three experimental examples, it can be known that the organic pollutants contained in the secondary biologically treated water of the present invention can be removed to the government's 1987 standard for draining water ', and its COD removal rate is about 20-50%. Therefore, compared with the conventional technology, the improved effects of the present invention can be summarized as follows: 1 · Using the oxygen-containing water reflux method to increase the dissolved oxygen in the water and improve the removal efficiency of pollutants, the general COD removal concentration can reach 50 ~ 100mg / L, COD The removal rate can reach 20 ~ 50%. 2 · Because (1) the present invention adopts an activated carbon layer puffing method, there is no need to set up a front filtering facility, (2) the present invention uses an oxygen-containing water reflux method to make the activated carbon layer particles
第15頁 498056 五、發明說明(12) 粒呈懸浮狀態,而非為採用氣昇式,可降低單元高度, (3 )活性礙填充率可達6 0 %,縮小反應槽體積,故可較習知 技術降低工程設置費。 3.本發明採用迴流方式膨化活性碳層,減少顆粒間之 磨擦及損耗,可減少活性碳補充量,降低營運成本。 綜上所述,本發明確實能符合專利要件,爰依法提出 申請。Page 15 498056 V. Description of the invention (12) The particles are in a suspended state instead of the air-lift type, which can reduce the height of the unit. (3) The filling rate of the activity barrier can reach 60%, and the volume of the reaction tank can be reduced. Know-how reduces project setup costs. 3. The present invention adopts a reflow method to expand the activated carbon layer, reduce friction and loss between particles, reduce the amount of activated carbon replenishment, and reduce operating costs. To sum up, the present invention can indeed meet the patent requirements, and the application is filed according to law.
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CN111792778A (en) * | 2019-04-05 | 2020-10-20 | 西门子能源公司 | Method and system for reducing total carbon consumption in producing low chemical oxygen demand process streams |
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