TW482680B

TW482680B - Semipermanent acid hairdye composition for aerosol

Info

Publication number: TW482680B
Application number: TW85115237A
Authority: TW
Inventors: Nozomi Nagashima; Yutaka Shibata; Toru Yoshihara
Original assignee: Kao Corp
Priority date: 1995-12-23
Filing date: 1996-12-10
Publication date: 2002-04-11
Also published as: JPH09175961A; DE19653496A1; JP3480165B2; DE19653496B4

Abstract

A semipermanent acid hairdye composition for aerosol is disclosed, comprising a semipermanent acid hairdye stock solution containing an acid dye and a propellant, packed in an aerosol container and sprayed out in the state of foam in use, wherein said composition is defoamed so as to give a foam density of at least 0.1 g/ml at 25 DEG C under 1 atm within 10 seconds from spraying, and a semipermanent acid hairdye aerosol product wherein the semipermanent acid hairdye composition for aerosol is packed in an aerosol container provided with an applicator is disclosed.

Description

482680 A7 —___ B7 五、發明説明（1) 發明的領域本發明係有關氣溶膠噴射用酸性半永久染髮毛料組八物。詳而言之’其係有關優異染色性質的氣溶膠噴射用酸性半永久染髮毛料組合物，其顯示染色步騾中沒有流辨或滴落，稍為弄髒頭皮等且可容易地施用。發明背景已經廣泛地使用酸性半永久染髮毛料，藉此頭髮藉由酸性染料的滲透至其中而染色，商品名，例如， Manicure。因為包含滲透加速劑（例如，苯甲醇等）和酸性染料一起，這些酸性半永久染髮毛料之進入頭髮的滲透作用和染色性質是優異的。然而，他們也有強烈弄髒皮膚的缺點。再者，習知的酸性半永久染髮毛料具有相當低的黏度’低黏度引起染色的步騾中酸性半永久染髮毛料流掛和滴落土顽皮或額上之另外缺點。結果，發生頭皮或額被酸性半永久染髮毛料弄髒且之後不易清潔之問題。經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 為了要避免上文提及的問題，已建議藉由將增稠劑加至其中以提高酸性半永久染髮毛料的黏度來使防止酸性半永久染髮毛料流掛和滴落在額，頭皮等上。然而，在此情形中，不能夠充份地避免酸性半永久染髮毛料的流掛和滴落且，相反地，造成酸性半永久染髮毛料的施用性能由於提高的黏度而變壞，因此引起非均勾染色的額外問題。因此，已建議用於改良酸性半永久染髮毛料組合物施用至頭髮上之性能而防止任何在皮膚（例如，頭皮，额等）上的污垢，其包括摻合酸性半永久染髮毛料組合物及發泡劑 -4 - 本紙張尺度適用中國國家榡CNS)八4規格（2—10x297公董） ΗΟΖΟδυ 經濟部中央標準局員工消費合作杜印製 Α7 五、發明説明（2) 和推進劑，將所獲得的組八舲4 、。卞厂且口物包裝於氣溶膠容器中，從氣溶膠容器噴出且有好的形Μ，趣、 #的形狀滯留 <泡沫狀態的組合物及然後將酸性半永久染髻革刹_ 、Α 又未友毛科的泡沫施用在髮毛上[JP-A-61- 210023， JP-A-7-3369Q 签.土 πη 、 29寺，（使用於本文之” JP-A”乙詞意為"未審查公開之日本專利中請案，，）]。在該情形中，建議使用裝備有直接連接其上之頭梳類型施用器的氣溶膠容器以利施用步驟（mu七38660 ;使用於本文中，，jp_A_ U”乙詞表示”未審查公開日本實用新案申請案"）。在S泡沫酸性半永久染髮毛料組合物中，流掛和滴落在颈皮和韻上可凡全被抑制。然而，由於泡沫的良好形狀滞留而其具有大的體積比。結果，當酸性半永久染髮毛料組合物施用在頭髮上時，如與該等習知非泡沫酸性半永久染髮毛料組合物比較時，組合物對頭髮的浴比完全地降低，叩引起染色性質被嚴重惡化的問題。如上所述，該等氣溶膠類型酸性半永久染髮毛料組合物在目前之階段是方便施用且完全不弄髒皮膚（頭皮等），但在染色性質上仍不足夠。發明概述本發明的一個目的為解決在習知技藝中遭遇之上述問題。亦即，本發明的目的為改良氣溶膠類型酸性半永久染髮毛料組合物的染色性質，該組合物不弄髒頭皮等且具有良好的施用性能。本發明之發明人頃發現當酸性半永久染髮毛料組合物 (其由包含酸性染料和推進劑之酸性半永久染髮毛料保存本紙張尺度適财SS家鮮（CMS ) Α4規格（21GX 297公釐 — L,I------缠衣------、玎------0 (請先閲讀背面之注意事項再填寫本頁) 482680 五、發明説明（3) 液組成）從氣溶膠容器喑 .,,, 态貧出於泡沫的狀態時，藉由將該組合物肩泡致使從噴出起—今 σ (請先閲讀背面之注意事項再填寫本頁} W电、Λ、九# 义時間内增加泡沫密度而可提高酸性半水久染髮毛料保在、、户 n ^ 因此明顯改良而沒有使祐旧α 本巴改具可更她用性能變壞，因此完成本發明。因此，本發明提供_綠# 、種乳落膠噴射用酸性半永久染# 料組合物，其係由包今酴#、干N人木3c毛 ^ 、匕口馱性染料和推進劑之酸性半永久染髮毛料保存液所組成，白4士、、、匕衣於在氣溶膠容器中且使用時以。心末的m出’其特徵在於該組合物被消泡以使於 C ' 1個大驗下從噴霧起1。秒内產生至少的(M克/亳升之泡沫密度。升詳細說明現在，於下文中將更詳細說明本發明。本發明的氣溶膠噴射用酸性半永久染髮毛料組合物具有其泡 >冬金度不增加直到发/Ak ^ | » ^ _L. ^ j具攸谷崙中以泡沫的狀態噴出和然後消泡的趨向。因此，可提高酸性半永久染髮毛料保存液對頭髮的浴比，及可顯著地改良染色性質。此情況中，組合物應於以使在25。〇、i個大氣壓下自喷霧起1〇秒内產生至少0.1克/毫升’較佳0.2克，毫升或以上之泡沫密度的經濟部中央標準局員工消費合作社印製万式消泡。當噴霧10秒之後泡沫密度小於〇丨克/毫升時，僅達到頭髮的酸性半永久染髮毛料保存液的低浴比且因此染色性質惡化。在其以髮刷或手塗在頭髮上期間因為其保持某程度之泡 t (一般，從噴霧起幾秒内），所以本發明的氣溶膠噴射用酸性半永久染髮毛料組合物施用性能沒有嚴重變壞。 -6 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 482680 A7 ___ B7 五、發明説明（^ ~ ^-- 一~ 現在，說明構成本發明的酸性半永久垫干水又木髮毛料組合物之酸性半永久染髮毛料保存液。 (請先閲讀背面之注意事項再填寫本頁) 欲使用於本發明之酸性半永久染髮羊料卞N人术I乇村保存液包含酸性染色。為了加速酸性染料滲透至頭髮中以使改良染色性質，除滲透加速劑之外，保存液進一步包含一酸性成分藉此保存液的工作p Η值被控制在2到5之範園（酸性染料的工作pH值）。當酸性半永久染髮毛料保存液具有太低的黏度（布汝克菲式黏度計，30 °C)時，組合物從氣溶膠容器噴出，不易形成泡沫，且因此施用性能變壞。另一方面，當其黏度太高時，組合物不易從氣溶膠容器以泡沫的狀態噴出。因此，其黏度較佳於1，000到50,000 cs範圍，2,000到40,000 CS仍較佳。黏度可藉由添加例如，增稠劑適當地調整，該增稠劑如後所述。經濟部中央標隼局員工消費合作杜印製本發明中所用的酸性染料沒有特別地限制，只要它是一種習用於染髮毛料者。其實例包括紅色2號（C.I. 16185)，紅色3 號（C.I. 45430)，紅色 102 號（C.I. 16255 )，紅色 104 號 (C.I· 45410)，紅色 105 號（C.I. 45440)，紅色 1〇6 號（C.I. 45100)，黃色 4 號（C.I. 19140)，黃色 5 號（C.I· 15985)，綠色 3 號（C.I· 42053 )，藍色 1 號（C.I. 42090)，藍色 2 號（C.I. 73015)，紅色 201 號（C.I· 15850)，紅色 227 號（C.I. 17200)，紅色 230 號（C.I. 45380)，紅色 231 號（C.I. 45410)，紅色 232 號（C.I. 45440)，橘色 205 號（C.I. 15510)，橘色 207 號（C.I. 45425 )，黃色 202 號（C.I· -7- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 482680 第“η5237號專利申請案 i修正士中文說明書修正頁⑼年2月）s j補充 ΐ、發明説明（5~) "~— 45350)，黃色 203 號（C.I· 47005 )，綠色 201 號（C.I· 61570) ’ 綠色 204 號（CJ· 59040)，綠色 205 號（C.I. 42095 )，藍色 202 號（C.I. 42052)，藍色 203 號（C.I. 42052)，藍色 205 號（C.I. 42090)，棕色 201 號（C.I. 20170) ’ 紅色 401 號（C.I. 45190)，紅色 502 號（C.I. 16155)，紅色 503 號（C.I· 16150)，紅色 504 號（C.I. 14700) ’ 紅色 506 號（C.I. 15620)，橘色 402 號（C.I. 14600)，黃色 402 號（C.I. 18950)，黃色 403 號（C.I. 10316)，黃色 406 號（C.I· 13065 )，黃色 407 號（C.I. 18820)，綠色 401 號（C.I. 10020)，綠色 402 號（C.I· 42085)，紫色 401 號（C.I. 60730)和碳黑 401 號（C.I. 20470) 〇在保存液中該酸性染料的含量較佳於〇.〇丨到3重量％之範圍’仍較佳為0.1到2重量0/〇。使用於發明中滲透加速劑的較佳實例包括式（1 )表示的芳族醇和以式（2 )表示的N -烷基吡咯啶酮。482680 A7 —___ B7 V. Description of the Invention (1) Field of the Invention The present invention relates to eight groups of acidic semi-permanent hair dyeing hair materials for aerosol spraying. More specifically, it relates to an acidic semi-permanent hair dyeing hair composition for aerosol spraying with excellent dyeing properties, which shows no flow or dripping in the dyeing step, slightly stains the scalp, etc., and can be easily applied. BACKGROUND OF THE INVENTION Acidic semi-permanent hair dyes have been widely used, whereby hair is dyed by the penetration of acid dyes into it, under the trade name, Manicure, for example. Because it contains penetration accelerators (for example, benzyl alcohol, etc.) together with acid dyes, these acidic semi-permanent hair dyes have excellent penetration and dyeing properties into the hair. However, they also have the disadvantage of strongly staining the skin. Furthermore, the conventional acidic semi-permanent hair dyed wool has a relatively low viscosity. The low viscosity causes the acidic semi-permanent hair dyed wool in the dyeing step to sag and drip the soil to be naughty or have other disadvantages on the forehead. As a result, a problem occurs that the scalp or forehead is stained with acidic semi-permanent hair dyed hair and it is not easy to clean afterwards. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) In order to avoid the problems mentioned above, it has been suggested to increase the acidity of semi-permanent hair dyeing wool by adding thickeners to it Viscosity to prevent acidic semi-permanent hair dye from hanging and dripping on the forehead, scalp, etc. However, in this case, the sag and dripping of the acidic semi-permanent hair-dyeing hair cannot be fully prevented and, conversely, the application performance of the acid semi-permanent hair-dyeing hair is deteriorated due to the increased viscosity, thereby causing uneven dyeing Extra question. Therefore, it has been proposed to improve the performance of the acidic semi-permanent hair dyeing hair composition to the hair and prevent any dirt on the skin (eg, the scalp, forehead, etc.), which includes blending the acidic semi-permanent hair dyeing hair composition and a foaming agent. -4-This paper size applies to China's National Standards (CNS) 8-4 (2-10x297 public directors) ΗΟΖΟδυ Staff printing cooperation of the Central Standards Bureau of the Ministry of Economic Affairs Du printed Α7 V. Description of the invention (2) and propellant, Group eight 舲 4 ,. The plant is packed in an aerosol container, sprayed from the aerosol container and has a good shape M, interesting, # shape retention < foamed composition and then acidic semi-permanent dyeing leather brake _, Α and Weiyou Maoke's foam is applied to hair [JP-A-61- 210023, JP-A-7-3369Q signed. Soil πη, 29 temples, (used in this article "JP-A" means "quot" Unexamined published Japanese patent applications ,,))]. In this case, it is recommended to use an aerosol container equipped with a comb-type applicator directly connected to it to facilitate the application step (mu 7386660; as used herein, jp_A_U "means" unexamined and published in Japan. " New application "). In the S foam acidic semi-permanent hair dyeing hair composition, sagging and dripping on the neck skin and rhyme can be suppressed. However, the foam has a large volume ratio due to its good shape retention. As a result, when the acidic semi-permanent hair dyeing hair composition is applied to the hair, as compared with the conventional non-foam acidic semi-permanent hair dyeing hair composition, the bath ratio of the composition to the hair is completely reduced, and the dyeing properties are seriously deteriorated. The problem. As mentioned above, these aerosol-type acidic semi-permanent hair dyeing hair composition are convenient to apply at the present stage and do not stain the skin (scalp, etc.) at all, but they are still insufficient in dyeing properties. SUMMARY OF THE INVENTION An object of the present invention is to solve the above problems encountered in the conventional art. That is, the object of the present invention is to improve the dyeing properties of an aerosol-type acidic semi-permanent hair dyeing hair composition which does not stain the scalp and the like and has good application performance. The inventors of the present invention have discovered that when an acidic semi-permanent hair dyeing hair composition (which is composed of an acidic semi-permanent hair dyeing hair containing an acid dye and a propellant, the paper size is suitable for SS Home Fresh (CMS) A4 specification (21GX 297 mm — L, I ------ wrapping ------, 玎 ------ 0 (Please read the notes on the back before filling this page) 482680 V. Description of the invention (3) Liquid composition) Sol container 喑. ,,, When the state of leanness is in a state of foam, the composition should be foamed from the shoulder by spraying out—now σ (Please read the precautions on the back before filling out this page) W 电、 Λ 、九# Increasing the foam density in the right time can increase the acidic half-water long-term dyeing hair. Keep, and household n ^ Therefore, it has been significantly improved without deteriorating the performance of the old α bumba, so the present invention has been completed. The present invention provides _green #, an acidic semi-permanent dyeing material composition for emulsion gel spraying, which consists of acid semi-permanent hair dyeing including Bao Jin 酴 #, dry N human wood 3c hair, dagger dye and propellant It is made of wool preservation solution. The white coat, white coat, and white coat are used in an aerosol container and used when The end of the heart is characterized by the fact that the composition is defoamed so that a foam density of at least (Mg / liter) is produced within 1 second from the spray at C'1 test. The detailed description is now Hereinafter, the present invention will be described in more detail. The acidic semi-permanent hair dyeing hair composition for aerosol spraying of the present invention has its foam > the winter gold degree does not increase until the hair / Ak ^ | »^ _L. ^ J 有尤谷伦It tends to spray out in a foamed state and then defoam. Therefore, the bath ratio of the acidic semi-permanent hair dyeing hair preservation solution to the hair can be increased, and the dyeing properties can be significantly improved. In this case, the composition should be adjusted to 25. 〇 At 10 atmospheres from the spray at i atmospheric pressure, at least 0.1 g / ml 'preferably 0.2 g, ml or more foam density is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Consumer Cooperatives to print million-type defoaming. When spraying When the foam density is less than 0 g / ml after 10 seconds, only the low bath ratio of the acidic semi-permanent dyed hair preservation solution of the hair is reached and therefore the dyeing properties are deteriorated. It is maintained to some extent during its application to the hair with a brush or hand. Bubble t ( Generally, within a few seconds from spraying), the application performance of the acidic semi-permanent hair dyeing hair composition for aerosol spraying of the present invention has not been seriously deteriorated. -6-This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 male) (Central) 482680 A7 ___ B7 V. Description of the invention (^ ~ ^-I ~ Now, the acidic semi-permanent hair dye preservation solution that constitutes the acidic semi-permanent pad dry water and wood hair composition of the present invention will be described. (Please read the back Note: Please fill in this page again.) The acidic semi-permanent hair dye sheep's feed to be used in the present invention (N Human Techniques I) Village preservation solution contains acid dyeing. In order to accelerate the penetration of acid dyes into the hair to improve the dyeing properties, in addition to the penetration accelerator, the preservation solution further contains an acidic component so that the working p value of the preservation solution is controlled to a range of 2 to 5. Working pH). When the acidic semi-permanent hair dyeing hair preservation solution has too low a viscosity (Brookfield viscometer, 30 ° C), the composition is sprayed from the aerosol container, it is difficult to form a foam, and therefore the application performance is deteriorated. On the other hand, when the viscosity is too high, the composition is not easily ejected from the aerosol container in a foamed state. Therefore, its viscosity is better in the range of 1,000 to 50,000 cs, and 2,000 to 40,000 CS is still better. The viscosity can be appropriately adjusted by adding, for example, a thickener, which will be described later. Printed by the staff of the Central Bureau of Standards of the Ministry of Economic Affairs for consumer co-operation. The acid dye used in the present invention is not particularly limited as long as it is a type used to dye hair. Examples include Red No. 2 (CI 16185), Red No. 3 (CI 45430), Red No. 102 (CI 16255), Red No. 104 (CI · 45410), Red No. 105 (CI 45440), Red No. 106 ( CI 45100), Yellow No. 4 (CI 19140), Yellow No. 5 (CI · 15985), Green No. 3 (CI · 42053), Blue No. 1 (CI 42090), Blue No. 2 (CI 73015), Red 201 (CI · 15850), Red 227 (CI 17200), Red 230 (CI 45380), Red 231 (CI 45410), Red 232 (CI 45440), Orange 205 (CI 15510), Orange No. 207 (CI 45425), Yellow No. 202 (CI · -7- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 482680 No. η5237 Patent Application i Amendment Chinese Manual Amendment Page Leap Year February) sj added ΐ, description of the invention (5 ~) " ~-45350), yellow 203 (CI · 47005), green 201 (CI · 61570) 'green 204 (CJ · 59040), green 205 (CI 42095), Blue No. 202 (CI 42052), Blue No. 203 (CI 42052) Blue 205 (CI 42090), Brown 201 (CI 20170) 'Red 401 (CI 45190), Red 502 (CI 16155), Red 503 (CI · 16150), Red 504 (CI 14700)' Red 506 (CI 15620), orange 402 (CI 14600), yellow 402 (CI 18950), yellow 403 (CI 10316), yellow 406 (CI · 13065), yellow 407 (CI 18820), Green No. 401 (CI 10020), Green No. 402 (CI · 42085), Purple No. 401 (CI 60730) and Carbon Black No. 401 (CI 20470) 〇The content of the acid dye in the preservation solution is better than 0.00. The range 'to 3% by weight' is still preferably 0.1 to 2% by weight. Preferred examples of the penetration accelerator used in the invention include an aromatic alcohol represented by the formula (1) and an N-alkylpyrrolidone represented by the formula (2).

Z Ί (ί) R1Z Ί (ί) R1

Υ— (0 C Hg C Η) p 〇 ΗΥ— (0 C Hg C Η) p 〇 Η

R 2 (2 -8 本紙張尺度適用中國國家標準(CNS) Α4規格（210 X 297公釐） 482680 A7 B7 五、發明説明（6) 在式（1 )中，R 1表示氫原子，低級烷基（例如，甲基）或低級坑氧基（例如，甲氧基）；γ表示伸垸基（例如，伸甲基）仲缔基（例如，伸乙婦）或早一键，Z表示氯原子或輕基；及P和q分別表示〇到5之整數。在式（2)中，R2表示垸基（例如，甲基，辛基）。式（1 )芳族醇的較佳實例包括苯甲醇，桂醯基醇，苯乙醇，對-茴香醇，對-甲芊基醇，苯氧基乙醇，苄氧基異丙酉手和2 -卞氧基乙醇、。式（2 ) N -技基晚p各淀S同的較佳實例包括N-甲基吡咯啶酮，n -乙基吡咯啶酮和N -辛基基，比洛淀酉同。當保存液中該滲透加速劑的含量太小時，沒有達到充份的染色特性質。另一方面，當其含量太大時，不能夠再改良该等效果。因此，其含量較佳於3到2 0重量％之範圍，仍較佳為5到1 5重量％。經濟部中央標準局員工消費合作社印製 __2___r---- -- (請先閲讀背面之注意事項再填寫本頁) 、^1 因為髮毛具有離子緩衝能力，所以較佳選擇弱酸作為欲使用於本發明中之酸。弱酸之實例包括檸檬酸，幾乙酸，琥珀酸，酒石酸，乳酸，乙酸，反-丁烯二酸，韻果酸，乙醯丙酸’丁酸，戊酸，草酸，順-丁浠二酸，扁桃酸和磷酸。在這情況中，其較佳為該弱酸和其鹽（例如，納鹽，却鹽’銨鹽）一起使用以藉此賦予保存液緩衝能力。保存液包含於以使產生至少0.01克當量/升，較佳〇〇2 克當量/升或以上之酸濃度的量，以緩衝能力表示。如上所述，其較佳為本發明之酸性半永久染髮毛料保存液包含黏度控制劑，藉此保存液的黏度調整至丨〇〇〇到 -9- 482680 A7 B7 五、發明説明（7) 50,000(布汝克菲式黏度計，3〇°C)以使允許組合物之喷霧於泡朱狀悲和在噴霧之後立刻消泡，藉此增加泡沫密度。作為黏度控制劑’其較佳使用水溶性聚合物。其實例包括天然膠（例如，三仙膠，瓜爾膠膠）和其改質物，纖維素衍生物（例如，爽乙基纖維素，甲基纖維素，瘦甲基纖維素），每g fe付生物（例如，海藻酸納，丙二醇海讓酸g旨）和合成聚合物（例如，聚乙烯醇，聚乙烯吡咯啶酮，聚乙二醇）。在這些材料中，特佳為使用天然膠，其改質物或纖維素衍生物。孩等水溶性聚合物可單獨或以其二個或以上的混合物使用。其在保存液中之含量視保存液意欲具有的黏度而適當地決定。經濟部中央標準局員工消費合作社印製 --Γ-->------ (請先閲讀背面之注意事項再填寫本頁) 訂為了控制泡沫安定性，其較佳地酸性半永久染髮毛料保存液進一步地包含泡沫安定劑。作為泡沫安定劑，較佳使用界面活性劑。界面活性劑的實例包括聚氧乙撐烷基醚，聚氧乙撐聚氧丙撐烷基醚，聚氧乙撐-第二·烷基醚，烷基 =油基醚，烷基異戊四醇甘油基醚，烷基硫酸鹽，聚氧乙撐烷基硫酸鹽，烷基磺酸鹽，聚醚改質之聚矽酮和烷基磷鉍2在該等材料中，特佳為使用聚氧乙撐烷基醚，聚氧乙袼第一-烷基醚，烷基甘油基醚，烷基異戊四醇甘油基醚或聚醚改質之聚矽酮。該等泡沫安定劑可單獨或以其二個或以上的混合物使用。當作為保存液的泡沫安定劑之界面活性劑的含量太小時，泡沐無法在噴霧的步驟中形成。另_方面，當其含量 -10- 482680 A7 B7 五、發明説明（8) 太大時’泡沐過度地安定且不能很快地消泡。因此，其各量較佳於0.1到5重量％之範圍，仍佳為〇 3到3重量％。為了加速酸性染料和滲透加速劑的溶解，其較佳為酸性半永久染髮毛料保存液進一步地包含公知的低級醇和低級多元醇，低級醇之實例包括乙醇，異丙醇，正丙醇和正丁醇。低級多元醇的實例包括乙二醇，丙二醇，異戊二醇， 1，3 -丁二醇，甘油，二甘醇單***，二甘醇二***和乙二醇單***。如果需要的話，酸性半永久染髮毛料保存液可進一步包含各種一般使用於化爿女品之添加劑例如油性成分（例如，鍵燒烴油，羊毛脂，聚矽酮，高級脂肪酸，高級醇），保護頭髮的成分，殺細菌劑，頭髮生長刺激劑，頭髮滋養品，防腐劑，抗頭皮屑劑，u V吸收劑，香料等。除上述用於酸性半永久染髮毛料的成分外，本發明之酸性半永久染髮毛料組合物包含推進劑。推進劑的實例包括液化石油氣（例如，丙烷，丁烷，異戊烷），甲醚和氟里昂 (Freon)氣體（例如，HCFC123，HFC134a，HFCl52a)。經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 當推進劑的含量太小時，泡沫不易被形成和，此外，保存液不易噴出。另一方面，太大含量的推進劑不再改良效果。因此推進劑較佳含量於0 1到2 〇重量份之範圍，1到i 5 重量份仍佳’每1〇〇重量份之酸性半永久染髮毛料保存液。本發明的酸性半永久染髮毛料組合物可以習知方法產生。例如’包含酸性染料和其他成分之酸性半永久染髮毛料保存液和推進劑一起包裝在氣溶膠容器中。在這情況 -11 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公着) "" ~~"" 五、發明説明（9) 2乱，谷膠谷益提供施用器（頭梳，刷等）是較好的以利施槿特佳為該施用器具有齒寬度寬於其間隔的頭梳 η孔浴膠噴射用酸性半永久染髮毛料組合物從該齒釋出（JP-A-U-6-38660)。為了進一步更詳細說明本發明，給予下列實例。 t例1到4和fck _例1和2 ，在白知方法中製備如表丨所示組合物之氣溶膠噴射用酸性半永久染髮毛料保存液。表 (重量％) 比較例 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製實例成分 1 2 3 4 1 2 乙醇 15.0 10.0 15.0 15.0 15.0 15.0 1,3_ 丁二醇 - 10.0 - 5.0 晒甘油 - - 5.0 • #苯甲醇 5.0 - 5.0 3.0 5.0 5.0 爷氧基乙醇 - 5.0 - 3.0 麵 • 、N-甲基吡哈途酮 5.0 - 8.0 - 5.0 5.0 /檸檬酸 3.0 5.0 - - 3.0 3.0 乳酸 - 3.0 - - - 磷酸 _ _ - 3.0 - - 羥基乙酸 - - - 2.0 - _ NaOH水溶液 - 足以產生pH 3之量 - -12- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） Α7 _____Β7 五、發明説明（1C) 異硬脂基季戊四醇甘油基醚 - 0.1 2.0 - - 6.0 井硬脂基甘油基酸 0.1 一 - 1.0 0.1 0.1 聚氧乙撐(23)月桂基醚 - - - 0.05 - 1.0 聚醚改質之聚矽酮1 0.5 0.5 0.6 0.05 0.5 - 三仙樹膠 1.0 1.5 1.0 1.5 0.3 1.0 碳黑401號 0.03 0.03 0.03 0.03 0.03 0.03 橘色205號 0.06 0.06 0.06 0.06 0.06 0.06 黏度(CS) 20000 25000 20000 20000 800 20000 緩衝能力(克當量/升） 0.014 0.024 0.013 0.025 0.014 0.014 1 ·· Silicone SH3 775 (由 Toray工業公司製造）丨..,--------- (請先閲讀背面之注意事項再填寫本頁) 9 0重量份之每個如此所得的保存液包裝至裝備有氣溶膠噴霧閥之聚對酞酸乙酯（PET)容器中。進一步地，將9重量份溶化石油氣和1重量份甲醚包裝至其中。如此獲得包裝在氣溶膠容器的酸性半永久染髮毛料組合物。如此獲得的組合物依下列標準測試泡沫密度和染色性質。 (泡沫密度測試）實例1到4和比較實例1和2的酸性半永久染髮毛料組合物各於25 °C、1大氣壓下從氣溶膠容器噴霧到玻璃容器〇〇〇毫升）中。在靜置1 0秒之後，過量的泡沫以匙狀取走，及稱重100毫升體積之泡沫’如此決定泡沫密度（克/毫升）。如此獲得的資料依照下列各項標準評估。 1估泡沫密唐標進 A :泡沫密度為〇. 1克/毫升或以上。 -13- 本紙張尺度適财關家料（CNS ) Α4· ( 210、/297公廣1 — 訂 4 經濟部中夬標準局員工消費合作社印製 482680 第85Π5237號專利申請案中文說明書修正頁(91年2月）R 2 (2 -8 This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 482680 A7 B7 V. Description of the invention (6) In formula (1), R 1 represents a hydrogen atom, a lower alkane (For example, methyl) or lower alkoxy (for example, methoxy); γ represents a fluorenyl group (for example, a methyl group), a secondary group (for example, ethene), or a bond, and Z represents chloro An atom or a light group; and P and q each represent an integer of 0 to 5. In formula (2), R2 represents a fluorenyl group (eg, methyl, octyl). Preferred examples of the aromatic alcohol of formula (1) include Benzyl alcohol, lauryl alcohol, phenethyl alcohol, p-anisyl alcohol, p-formyl alcohol, phenoxyethanol, benzyloxyisopropyl alcohol and 2-methoxyethanol, formula (2) N- Preferable examples of the technical bases include N-methylpyrrolidone, n-ethylpyrrolidone, and N-octyl, which is the same as that of Biloxidine. When the permeation accelerator in the preservation solution is When the content is too small, sufficient dyeing properties are not achieved. On the other hand, when the content is too large, these effects cannot be further improved. Therefore, the content is preferably in the range of 3 to 20% by weight. , It is still preferably 5 to 15% by weight. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs __2 ___ r -----(Please read the precautions on the back before filling this page), ^ 1 because the hair has ions Weak acid is preferably selected as the acid to be used in the present invention. Examples of the weak acid include citric acid, polyacetic acid, succinic acid, tartaric acid, lactic acid, acetic acid, trans-butenedioic acid, rhodopic acid, acetic acid Propionate'butyric acid, valeric acid, oxalic acid, cis-succinic acid, mandelic acid and phosphoric acid. In this case, it is preferred that the weak acid is together with its salt (eg, sodium salt, but salt 'ammonium salt) Used to thereby impart a buffering capacity to the preservation solution. The preservation solution is contained in an amount such that an acid concentration of at least 0.01 g equivalent / liter, preferably 0.02 g equivalent / liter or more, is expressed as the buffering capacity. As described above, It is preferably that the acidic semi-permanent hair dyeing hair preservation solution of the present invention contains a viscosity control agent, whereby the viscosity of the preservation solution is adjusted to 丨 00 to -9- 482680 A7 B7 V. Description of the invention (7) 50,000 (Brookfield Viscometer, 30 ° C) to allow composition The spray is applied to the foam and the foam is defoamed immediately after spraying, thereby increasing the foam density. As a viscosity control agent, it is preferable to use a water-soluble polymer. Examples thereof include natural rubber (for example, Sanxian gum, guar Gum) and its modified products, cellulose derivatives (for example, ethylcellulose, methylcellulose, lean methylcellulose), per g of fe (for example, sodium alginate, propylene glycol, and seawater acid g) Purpose) and synthetic polymers (for example, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol). Among these materials, it is particularly preferable to use natural rubber, its modified product or cellulose derivative. Children are water-soluble The polymer may be used alone or as a mixture of two or more thereof. Its content in the preservation solution is appropriately determined depending on the intended viscosity of the preservation solution. Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs --Γ-> ------ (Please read the precautions on the back before filling out this page) Ordered to control the foam stability, it is preferably acidic semi-permanent hair dyeing The wool preservative further contains a foam stabilizer. As the foam stabilizer, a surfactant is preferably used. Examples of the surfactant include polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene-second alkyl ether, alkyl = oleyl ether, alkyl isoprene Alcohol glyceryl ethers, alkyl sulfates, polyoxyethylene alkyl sulfates, alkyl sulfonates, polyether modified silicones and alkyl phosphorus bismuth Oxyethylene alkyl ether, polyoxyethyl fluorene first-alkyl ether, alkyl glyceryl ether, alkyl isopentaerythritol glyceryl ether or polyether modified silicone. These foam stabilizers may be used alone or in a mixture of two or more thereof. When the content of the surfactant of the foam stabilizer as a preservation solution is too small, the foam cannot be formed in the spraying step. On the other hand, when its content is -10- 482680 A7 B7 V. Description of the invention (8) is too large, the foam is excessively stable and cannot be quickly defoamed. Therefore, the respective amounts are preferably in the range of 0.1 to 5% by weight, and still more preferably 0.3 to 3% by weight. In order to accelerate the dissolution of the acid dye and the penetration accelerator, it is preferably an acidic semi-permanent hair dyeing hair preservation solution further containing a well-known lower alcohol and a lower polyol. Examples of the lower alcohol include ethanol, isopropanol, n-propanol, and n-butanol. Examples of the lower polyol include ethylene glycol, propylene glycol, isoamyl glycol, 1,3-butanediol, glycerol, diethylene glycol monoethyl ether, diethylene glycol diethyl ether, and ethylene glycol monoethyl ether. If necessary, the acidic semi-permanent hair dye preservation solution may further include various additives commonly used in chemical products such as oily ingredients (for example, kerosene hydrocarbon oil, lanolin, silicone, higher fatty acids, higher alcohols) to protect the hair Ingredients, bactericides, hair growth stimulants, hair tonics, preservatives, anti-dandruff agents, UV absorbers, fragrances and more. In addition to the above-mentioned ingredients for acidic semi-permanent hair coloring hair, the acidic semi-permanent hair coloring hair composition of the present invention contains a propellant. Examples of propellants include liquefied petroleum gas (for example, propane, butane, isopentane), methyl ether, and Freon gas (for example, HCFC123, HFC134a, HFCl52a). Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). When the propellant content is too small, bubbles will not be easily formed and the preservation solution will not be easily sprayed. On the other hand, too much propellant no longer improves the effect. Therefore, the content of the propellant is preferably in the range of 0.01 to 20 parts by weight, and 1 to 5 parts by weight is still good 'per 100 parts by weight of the acidic semi-permanent hair dyeing hair preservation solution. The acidic semi-permanent hair dyeing hair composition of the present invention can be produced by a conventional method. For example, an acidic semi-permanent hair dye preservation solution containing an acid dye and other ingredients is packaged in an aerosol container together with a propellant. In this case-11-This paper size applies Chinese National Standard (CNS) A4 specification (210X297) " " ~~ " " V. Description of the invention (9) 2 Mess, Gujiao Guyi provides applicator (Hair comb, brush, etc.) is better. The applicator has a head comb with a tooth width wider than its interval. The pore bath gel spray acid semi-permanent hair dye composition is released from the teeth (JP -AU-6-38660). To further illustrate the present invention in more detail, the following examples are given. t Examples 1 to 4 and fck _ Examples 1 and 2, in a method known in the art, an acidic semi-permanent hair coloring hair preservation solution for aerosol spraying of the composition shown in Table 丨 was prepared. Table (% by weight) Comparative example (please read the notes on the back before filling this page) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1 2 3 4 1 2 Ethanol 15.0 10.0 15.0 15.0 15.0 15.0 1, 3_ Ding Er Alcohol-10.0-5.0 Sun glycerol--5.0 • #Benzyl alcohol 5.0-5.0 3.0 5.0 5.0 Ethyl alcohol-5.0-3.0 Noodles,, N-methylpyrrolidone 5.0-8.0-5.0 5.0 / Citric acid 3.0 5.0 --3.0 3.0 Lactic acid-3.0---Phosphoric acid _ _-3.0--Glycolic acid---2.0-_ NaOH aqueous solution-sufficient to produce pH 3--12- This paper size applies to China National Standard (CNS) A4 specifications (210X 297mm) Α7 _____ Β7 V. Description of the invention (1C) Isostearyl pentaerythritol glyceryl ether-0.1 2.0--6.0 Well stearyl glyceryl acid 0.1-1.0 1.0 0.1 Polyoxyethylene (23) Laurel Base ether---0.05-1.0 polyether modified silicone 1 0.5 0.5 0.6 0.05 0.5-Sanxian gum 1.0 1.5 1.0 1.5 0.3 1.0 carbon black 401 0.03 0.03 0.03 0.03 0.03 0.03 0.03 orange 205 0.06 0.06 0.06 0.06 0.06 0.06 Viscosity (CS) 20000 25000 20000 20000 800 20 000 Cushioning capacity (gram equivalent / liter) 0.014 0.024 0.013 0.025 0.014 0.014 1 ·· Silicone SH3 775 (manufactured by Toray Industries) 丨 .., --------- (Please read the precautions on the back before (Fill in this page) 90 parts by weight of each of the thus obtained preservation solutions are packed into a polyethylene terephthalate (PET) container equipped with an aerosol spray valve. Further, 9 parts by weight of molten petroleum gas and 1 part by weight of methyl ether were packed therein. Thus was obtained an acidic semi-permanent hair dyeing hair composition packed in an aerosol container. The composition thus obtained was tested for foam density and dyeing properties according to the following criteria. (Foam density test) The acidic semi-permanent hair dyeing hair composition of Examples 1 to 4 and Comparative Examples 1 and 2 were each sprayed from an aerosol container to a glass container (200 ml, at 25 ° C, 1 atmosphere). After standing for 10 seconds, the excess foam was removed with a spoon and a 100 ml volume of foam was weighed to determine the foam density (g / ml). The information thus obtained was evaluated in accordance with the following criteria. 1 Estimation of foam density Tang A: foam density is 0.1 g / ml or more. -13- This paper is suitable for financial data (CNS) Α4 · (210, / 297 Gongguang 1 — Order 4 Printed 482680 No. 85Π5237 Chinese Specification for Amendment of Patent Application (Chinese version of the Patent Application No. 85Π5237) February 91)

五、發明説明（11 ) B :泡沫密度小於0.1克/毫升。 (染色性質測試）實例1到4和比較實例1和2的酸性半永久染髮毛料組合物各從氣溶膠容器嘴出，於多高爾夫球大小之量，然後塗敷在稱重洗滌和以清水沖洗。如此染色之髮的顏色與色差計 (CR200，由Minolta照相機公司製造）測量和決定與未染色白色髮的色差（△£)。結果顯示在表2(其中較高的ae代表比較好的染色性質。表 2 實例比較例評估項目 1 2 3 4 1 2 泡沫密度 A A A A B B 染色性質(ΔΕ) 50 53 51 56 36 32 從表2的結果明顯可知，實例1至4的組合物各具有〇·ΐ克 / i升或ス上的泡’未密度和好的染色性質。對照下，比較實例\的> 組合物具有低黏度，及比較實例2的組；物產生非苇不fe足的/包沫，和比較實例丨和2的組合物具有少於〇. 1克 /毫升的泡沫密度和差的染色性質。實例5到I和|較實彳在習知万法中製備如表3所示組合物之氣溶膠喷射用酸性半永久染髮毛料保存液。V. Description of the invention (11) B: Foam density is less than 0.1 g / ml. (Dyeing property test) The acidic semi-permanent hair dyeing wool composition of Examples 1 to 4 and Comparative Examples 1 and 2 each came out of the aerosol container in a golf ball-sized amount, and was then applied to a weight wash and rinsed with water. The color and color difference meter (CR200, manufactured by Minolta Camera Co., Ltd.) of the dyed hair thus measured and determined the color difference (Δ £) from the uncolored white hair. The results are shown in Table 2 (where higher ae represents better dyeing properties. Table 2 Examples Comparative Examples Evaluation Items 1 2 3 4 1 2 Foam density AAAABB Dyeing properties (ΔΕ) 50 53 51 56 36 32 Results from Table 2 Obviously, the compositions of Examples 1 to 4 each have a density of 0.1 gram / liter or a bubble density on the surface and good dyeing properties. In comparison, Comparative Example > The composition has a low viscosity and a comparison The group of Example 2 produced a non-sufficient / foamed foam, and the compositions of Comparative Examples 1 and 2 had a foam density of less than 0.1 g / ml and poor dyeing properties. Examples 5 to I and | More practically, in the conventional method, an acidic semi-permanent hair dye preservation solution for aerosol spraying of the composition shown in Table 3 was prepared.

482680 A7 B7 五、發明説明（1每實例 (重量％) 比較例成分 7 3 乙醇 10.0 10.0 15.0 15.0 1，3-丁二醇 5.0 5.0 5.0 5.0 苯甲醇 5.0 5.0 5.0 3.0 苄氧基乙醇 3.0 3.0 3.0 3.0 檸檬酸 1.0 5.0 - - 乳酸 5.0 - 3.0 3.0 Na〇H水溶液 -足以產生pH 3之量 - 異硬脂基季戊四醇甘油基醚 - - 2.0 - 聚氧乙撐(9)-第二-十四基醚 1.0 2.0 - 1.0 聚醚改質之聚矽酮1 0.1 0.3 0.3 - 羥乙基纖維素 1.0 1.0 1.0 - 碳黑401號 0.03 0.03 0.03 0.03 橘色205號 0.06 0.06 0.06 0.06 黏度(CS) 20000 20000 20000 <100 緩衝能力(克當量/升） 0.030 0.025 0.015 0.015 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 9 0重量份之每個如此所得的保存液包裝至裝備有氣溶膠噴霧閥之PET容器内。進一步地，將8.5重量份液化石油氣和1.5重量份甲醚包裝至其中。如此獲得包裝在氣溶膠容器的酸性半永久染髮毛料組合物。如此獲得的组合物藉由與 -15- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） A7482680 A7 B7 V. Description of the invention (1 per example (% by weight) Comparative Example Ingredient 7 3 Ethanol 10.0 10.0 15.0 15.0 1,3-butanediol 5.0 5.0 5.0 5.0 Benzyl alcohol 5.0 5.0 5.0 3.0 Benzyloxyethanol 3.0 3.0 3.0 3.0 Citric acid 1.0 5.0--Lactic acid 5.0-3.0 3.0 NaOH solution-sufficient to produce pH 3-isostearyl pentaerythritol glyceryl ether--2.0-polyoxyethylene (9)-second-tetradecyl ether 1.0 2.0-1.0 Polyether modified silicone 1 0.1 0.3 0.3-Hydroxyethyl cellulose 1.0 1.0 1.0-Carbon black 401 0.03 0.03 0.03 0.03 Orange 205 0.06 0.06 0.06 0.06 Viscosity (CS) 20000 20000 20000 < 100 buffering capacity (gram equivalent / liter) 0.030 0.025 0.015 0.015 (Please read the precautions on the back before filling out this page) Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs printed 90 parts by weight of each of the thus obtained preservation solution packaging Into a PET container equipped with an aerosol spray valve. Further, 8.5 parts by weight of liquefied petroleum gas and 1.5 parts by weight of methyl ether were packaged therein. Thus, an acidic semi-permanent hair dyeing hair composition packed in an aerosol container was obtained. Composition obtained by this paper and -15- scale applicable to Chinese National Standard (CNS) A4 size (210X 297 mm) A7

五、發明説明（評估項目泡沫密度染色性質(ΛΕ) 見例1相同方去測試泡沫密度和染色性質。結果顯示在表4 中。 Μ：__4 _實例 __比較例 5 6 丄_3 A A a Β 5〇 53 51 36 從表4的結果明顯可知，實例5至7的組合物各具有〇丨克 / 4升或以上的泡沫密度和好的染色性質。對照下，比較具例3的組合物具有_太低的黏度，和因此丨〇秒之後具有小於0.1克/晕升的泡沫密度和差的染色性質。實例8和比較例4 在習知方法中製備如表5所示組合物之氣溶膠噴射用酸性半永久染髮毛料保存液。使用實例1相同方法噴霧丨〇秒之後評估每種產品的泡沫密度。結果顯示在表5中。 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X297公釐） 482680 A7 B7 五、發明説明（yV. Description of the invention (Evaluation item Foam density dyeing properties (ΛΕ) See the same method as in Example 1 to test the foam density and dyeing properties. The results are shown in Table 4. Μ: __4 _ Examples __ Comparative Example 5 6 6_3 AA a Β 5503 53 36 From the results in Table 4, it is clear that the compositions of Examples 5 to 7 each have a foam density of 0 g / 4 liter or more and good dyeing properties. In comparison, the composition of Example 3 was compared Has a too low viscosity, and therefore has a foam density of less than 0.1 g / halo and poor dyeing properties after 10 seconds. Example 8 and Comparative Example 4 Gases of the composition shown in Table 5 were prepared in a conventional manner. Acid spray semi-permanent hair dye preservation solution for sol spraying. The foam density of each product was evaluated after spraying using the same method as in Example 1. The results are shown in Table 5. (Please read the precautions on the back before filling this page) Ministry of Economy Printed by the Central Bureau of Standards Consumer Cooperatives The paper size is applicable to the Chinese National Standard (CNS) A4 (21 × 297 mm) 482680 A7 B7 V. Description of the invention (y

A 實例 (重量％) 比較例 _§_ _1_ 15.0 15.0 8.0 8.0 1.0 1.0 5.0 5.0 (請先閲讀背面之注意事項再填寫本頁) 成色乙醇爷氧基乙辟檸檬酸乳酸A Example (% by weight) Comparative example _§_ _1_ 15.0 15.0 8.0 8.0 1.0 1.0 5.0 5.0 (Please read the precautions on the back before filling out this page) Condition Ethanol Ethyl Ethyl Citric Acid Lactic Acid

-足以產生pH 3之量異硬脂基季戊四醇甘油基醚 1.0 1.0 ***聚氧乙撐(9>第二十四基醚 1.0 1.0 聚醚改質之聚矽酮中1 0.1 0.3 三仙樹膠 1.5 0.1 碳黑401號 0.03 0.03 橘色205號 0.06 0.06 黏度(CS) 20000 600 緩衝容量(克當量/升） 0.025 0.025 泡沫密度 A B-An amount of isostearyl pentaerythritol glyceryl ether 1.0 1.0 sufficient to produce pH 3 1.0 ether polyoxyethylene (9 > twenty-fourthyl ether 1.0 1.0 polyether modified silicone 1 0.1 0.3 Sanxian gum 1.5 0.1 Carbon Black No. 401 0.03 0.03 Orange No. 205 0.06 0.06 Viscosity (CS) 20000 600 Buffer capacity (gram equivalent / liter) 0.025 0.025 Foam density AB

NaOH水溶液經濟部中央標準局員工消費合作社印製 9 0重量份之每個如此所得的保存液包裝至裝備有氣溶膠賣務閥之P E T容器内。進一步地，將8 5重量扮液化石油氣和1.5重量份甲醚包裝至其中。如此獲得包裝在氣溶膠容器的酸性半永久染髮毛料組合物。然後將頭梳類型施用器直接地連接到氣溶膠容器。實例8和比較例4的酸性半永久染髮毛料組合物及市售酸 -17- 本紙張尺度適用中國國家標準（CNS )八4規格（210 X297公釐） A7 B7 五、發明説明（1令陡丰水久朱髮毛料（凝膠），龙 m , . ^ , ，、乙衣在管中和以所附刷子施用，由3位具有2〇%比例之白 I M ^ Μ 3 π、邑項髮的評審員使用。評估該寺所侍Κ施用方便性,，，"用量,，，，, 垢”和"不顯眼的白色頭髮，，。結 ^ m ^ rb A L i ""果頒示在表0中。在每個詞估項目中，0代表，，良好”，八代八表普通，，和X代表”差”。評審員 A B JC 註解樣品實例8 比較4 市售塗敷的方便性_ — 皮膚上白色頭髮之污垢的顯著性 0*1 30克 0*2 0*3 Δ*4 16克 0*5 χ*6 χ*7 --. χ*8 χ*9 (請先閲讀背面之注意事項再填寫本頁)NaOH aqueous solution Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs each 90 parts by weight of each of the thus-obtained preservation solutions were packaged in a PET container equipped with an aerosol sales valve. Further, 85 weight parts of liquefied petroleum gas and 1.5 weight parts of methyl ether were packed therein. Thus, an acidic semi-permanent hair dyeing hair composition packed in an aerosol container was obtained. A head comb type applicator was then connected directly to the aerosol container. Example 8 and Comparative Example 4 Acidic semi-permanent hair dyeing hair composition and commercially available acid -17- This paper size applies to China National Standard (CNS) 8 4 specifications (210 X297 mm) A7 B7 V. Description of the invention (1 order abruptly Shuijiu Zhuhair wool (gel), Long m,. ^, ,, Yiyi in the tube and applied with the attached brush, made by 3 persons with white IM ^ Μ 3 π, 20% in proportion Assessors use. Evaluate the convenience of the temple's service, ",", "dosage,", "," "and inconspicuous white hair." Results ^ m ^ rb AL i " " Shown in Table 0. In each word evaluation item, 0 represents, good, "eight generations and eight tables are normal, and X represents" bad ". Reviewer AB JC Annotation Sample Example 8 Comparison 4 Convenience of commercial coating Sex_ — Significance of white hair dirt on the skin 0 * 1 30g 0 * 2 0 * 3 Δ * 4 16g 0 * 5 χ * 6 χ * 7-. Χ * 8 χ * 9 (Please read first (Notes on the back then fill out this page)

，1T 經濟部中央標準局員工消費合作社印製 *2 *3 * 4 *5 *6 氺7 ^㈣單手使用’非常地可散佈的泡泳，短應時間。皮膚上沒有污垢。全部頭髮之小顯著白色頭髮。容易地以單手使用，乾且相4 乾五祖糙的泡沫極不與頭髮處，垂流和滴落弄髒手。皮膚上沒有污垢。稍為染色，顯著白色的頭髮。以與兩隻手使用，差的凝膠覆蓋性，不平順的塗敷。弄髒額頭和頭皮。非均勾染色，顯著白色頭髮。 -18- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） i# A7 B7 五、發明説明（1今從表6的結果明顯可知，實例8的組合物在使用泡沫密度和數量是適合的，可容易地施用’沒有造成皮膚等上ςς 垢等且使白色頭髮不顯眼。比較貫例4的組合物在丨〇秒之後具有低泡沫密度。因此，泡沫是乾的，粗糙和頭髮稍相容。再者，組合物不易消泡且因此僅使用於小量，不能使白色頭髮足夠地不顯眼。市售的產品具有差的凝膠的覆蓋性和非均勻染色。也具有嚴重地污染皮膚等。發明的效果本發明可改良酸性半永久染髮毛料組合物的染色性質而展現良好施用效能。 II. #1— (請先閲讀背面之注意事項再填寫本頁) 訂經濟部中央標準局員工消費合作社印製 -19- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2!〇X297公楚）, 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs * 2 * 3 * 4 * 5 * 6 氺 7 ^ ㈣ One-handed use ‘very dispersible bubble swimming, short response time. No dirt on the skin. Small hair with significant white hair. Easy to use with one hand, dry and dry. The five ancestors' rough foam is extremely close to the hair, and drooping and dripping will stain your hands. No dirt on the skin. Slightly dyed, noticeably white hair. For use with both hands, poor gel coverage, uneven application. Soils forehead and scalp. Non-uniform dyeing, markedly white hair. -18- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) i # A7 B7 V. Description of the invention (1 It is clear from the results in Table 6 that the composition of Example 8 is using foam density and quantity It is suitable and can be easily applied 'without causing stains on the skin, etc. and making white hair inconspicuous. The composition of Comparative Example 4 has a low foam density after 10 seconds. Therefore, the foam is dry, rough and The hair is slightly compatible. Furthermore, the composition is not easy to defoam and is therefore only used in small amounts and cannot make white hair sufficiently inconspicuous. Commercially available products have poor gel coverage and non-uniform dyeing. They also have severe It can contaminate the skin, etc. Effect of the invention The present invention can improve the dyeing properties of the acidic semi-permanent hair dyeing hair composition and exhibit good application performance. II. # 1— (Please read the notes on the back before filling this page) Set the central standard of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives -19- This paper size applies to the Chinese National Standard (CNS) Α4 specification (2.0 × 297)

Claims

! 8£ 1 1 5 2 3 7號專利申請案A8 甲又申請專利範圍修正本(9丨年2月）言篇申請專利範圍 • 種氣溶膠嘴射用酸性半永久染毛料組合物，其包括一種含有酸性染料之酸性半永久染毛料原液及推進劑，充填在氣溶膠容器中供泡狀噴出使用，其特徵在於：上述酸性染料原液中含有選自紅色3號、1 0 4號、1 〇 6號及 227號、黃色4號、5號、203號、403號、綠色3號及 401號、藍色1號、橙色205號、褐色2〇1號、紫色4〇1 號、黑色401號之酸性染料〇.〇i〜3重量％、選自苄氧基乙醇、+醇、N -曱基ρ比洛淀酮之滲透加速劑3〜20重量 %及作為泡沫安定劑之自分子中含有氧乙撐或兩個以上罗空基之燒基酸系非離子界面活性劑、聚醚改質碎酮類選出的一種以上之界面活性劑〇 · 1〜5重量％，且在使用時以泡沫的狀態噴出後，在2 5 °C、1大氣壓下自嘴出起！〇秒内以至少〇· 1克/毫升的泡沫密度之方式被消泡。 2·根據申請專利範圍第1項之氣溶膠噴射用酸性半永久染毛料組合物，其中該酸性半永久染髮毛料原液之枯度為 1，000 到 50,000 cs 〇 3.根據申請專利範圍第1或2項的氣溶膠喷射用酸性半永久染髮毛料組合物，其中該酸性半永久染毛料原液之酸漢度（以緩衝能力表示）為至少0.01克當量/升。 4·根據申請專利範圍第1或2項的氣溶膠噴射用酸性半永久染髮毛料組合物，其中該酸性半永久染毛料原液包含作為黏度控制劑的選自天然膠類或其改質物、纖維素衍生 .物、海藻酸衍生物、合成聚合物之水溶性聚合物。本纸張尺度適用中國國家標準(CNS) A4規格(210X297公釐）8 £ 1 1 5 2 3 7 Patent Application A8 A Patent Application Scope Amendment (February 9 丨 February) Text Application Patent Scope • An acidic semi-permanent wool dyeing composition for aerosol mouth spray, including a An acidic semi-permanent wool dyeing stock solution and a propellant containing an acid dye are filled in an aerosol container for bubble-like ejection, and are characterized in that the acid dye stock solution contains red 3, 104, and 106. And the acidity of 227, yellow 4, 5, 203, 403, green 3 and 401, blue 1, orange 205, brown 201, purple 401, black 401 Dye 〇i ~ 3% by weight, permeation accelerator selected from benzyloxyethanol, + alcohol, N-fluorenyl p-bilolidene, 3 ~ 20% by weight, and oxyethyl in the molecule as a foam stabilizer 1 or more surfactants selected from the group consisting of two or more rosinyl-based non-ionic surfactants, polyether modified ketones, and the like. 1 to 5% by weight, and in a foam state when used After spraying out, start from the mouth at 25 ° C and 1 atmosphere! Defoamed with a foam density of at least 0.1 g / ml within 0 seconds. 2. The acidic semi-permanent hair dyeing composition for aerosol spraying according to item 1 of the scope of the patent application, wherein the acidity of the acidic semi-permanent hair dyeing stock solution has a dryness of 1,000 to 50,000 cs. 0. According to the scope of the patent application, item 1 or 2 Acidic semi-permanent hair dyeing hair composition for aerosol spraying, wherein the acidity (expressed as buffering capacity) of the acidic semi-permanent hair dyeing stock solution is at least 0.01 gram equivalent / liter. 4.Acid aerosol spraying acidic semi-permanent hair dyeing hair composition according to item 1 or 2 of the scope of the applied patent, wherein the acidic semi-permanent hair dyeing stock solution contains as a viscosity control agent selected from natural gums or modified products thereof, cellulose-derived. Polymers, alginic acid derivatives, water-soluble polymers of synthetic polymers. This paper size applies to China National Standard (CNS) A4 (210X297 mm)