Claims (1)
42669 8 ^ 2633twf.doc/〇〇5 Λ7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（ί ) 本發明是有關於一種抗靜電環氧樹脂及其製造方 法’且特別是有關於一種具有長效性之抗靜電環氧樹脂及 其製法。本發明係利用含烷氧基醚類之胺基（Amine，NH2) 化合物和含環氧基（Epoxy)之化合物反應而生成者。 習知賦予高分子抗靜電性者多係屬於一種添加劑，傳 統多爲利用低分子量四級胺鹽類或添加導電性碳黑等來增 加其抗靜電性，如：美國專利第5，128,473號以及日本專 利第349,053號。添加低分子量四級胺鹽者易因四級胺鹽 之遷移而流失，且放置時間久時在高分子表面易有潮濕的 現象而影響其使用之性質，而若添加過量時，易影響高分 子之物性；而摻有導電碳黑者，除會有脫碳之困擾外，亦 限制其顏色之範圍，且與高分子有相容性之問題。 另一類習知之抗靜電劑爲將有機矽化合物摻混在高分 子中或塗佈在高分子表面，以達導電性需求。此類有機矽 高分子因不易和其他高分子相容，故以塗佈者居多，如： 美國專利第5,008,328號以及第4,584,342號專利。由於此 類產品通常以添加方式加入，其抗靜電之持久性及耐擦拭 水洗性在實際應用上均有不足之處。 另外有將聚氧乙院（Polyethylene Oxide; PEO)添加 於高分子中，以使之具有導電性者，如美國專利第 5,356,959、4,931，506、5,262,460、5,051，475 號等。雖然 聚氧乙烷具有的反應性官能基OH可與高分子反應，而使 導電持久性及耐水洗性等獲得改善，但是因爲其反應性慢 且反應時間長，所以需要在高溫環境下以促進其反應。然 4 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS〉A4規格（210X297公楚) a D Ό ο a D Ό ο 經濟部中央標準局員工消費合作社印聚 2633twf.doc/005 A / B7^_—_ 五、發明説明（2) 而，高溫卻會造成高分子的裂解而影響其品質。 因此，本發明的目的就是在提供一種具高反應性官能 基之長效型抗靜電環氧樹脂’以改善上述習知技藝之缺 點。 根據本發明的目的，提出一種長效型之抗靜電環氧樹 脂，其主要含有之分子結構如下所示： OH 0H 〒2 ^CH2-ChhRi---C,+~CH2-N^- R4 Rs CJH CjH 或 十 N-R3—N —C H 2~C H-R i—C H-C H2-)- 其中，&爲分子量約介於44〜2000 (g/mole)之間的芳香 烴基鏈段、脂肪烴基鏈段、含鹵素取代基之芳香烴基鏈段 或含鹵素取代基之脂肪烴基鏈段；而I與R3爲分子量約 介於550〜6000 ( g/mole )之間的含院氧基醜類 (Polyoxyalkylene 或 Polyoxyethylene)鏈段，其結構爲： 其中R。爲含有2或3個碳原子之烴基，η爲10〜45之整數： 1與R5爲擇自由氫、甲基或R,所組成之族群。 本發明之抗靜電環氧樹脂係由含有反應性單胺官能基 化合物H2N-R2、或雙胺官能基化合物R4，HN-R3-NH-R5、 或同時含單胺官能基與雙胺官能基之化合物與具有反應性 之含環氧官能基化合物反應而成。其中，含環氧官能基化 合物的結構爲： i>-Ri-<S 其中，K可爲分子量介於44〜2〇〇〇 (g/mole)之間的芳香 _ 5 本紙張尺度關中關家縣（CNS ) ( 21GX 297公^7 (請先閱讀背面之注意事項再填寫本頁) ，1T 經濟部中央標準局負工消費合作社印裝 4266 9 8 4 2633 twf.doc/005 八7 B7 五、發明説明（> ) 烴基鏈段、脂肪烴基鏈段、含鹵素取代基之芳香烴基鏈段 或含鹵素取代基之脂肪烴基鏈段；而含胺基化合物之r2 與R3爲含有烷氧基醚類之鏈段，其分子量約介於550〜6000 (g/mole)之間，且心與R3之結構爲： 十 R〇-〇^ 其中R。爲2或3個碳原子之烴基，η爲10〜45之整數；R4 與R5爲擇自由氫、甲基或R,所組成之族群。 根據本發明的目的，提出一種抗靜電環氧樹脂之製造 方法，包括：將含烷氧基醚類之胺基化合物與含環氧官能 基之化合物’依適當之比例放入反應器中，其中較佳之比 例爲當量數比値約爲I/2〜2。並徐徐加溫攪拌，在溫度 30〜180°C下’使含胺基之化合物與含環氧官能基之化合物 反應而生成含反應官能基之抗靜電環氧樹脂。 本發明之特徵之一是所使用的胺基化合物與環氧基化 合物的反應性大，且抗靜電環氧樹脂之製造方法非常簡 單，因此可以應用之產業相當廣泛，例如可應用在樹脂、 塑膠加工、特用化學品、塗料以及電子資訊等產業上，因 此本發明之抗靜電環氧樹脂係一種高附加價値之產品。 本發明之特徵之二是本發明之抗靜電環氧樹脂係屬於 反應型，因此不會有習知之低分子量四級胺鹽的遷移流失 及影響高分子基材性質的缺點，而且可以有效地改善習知 技藝中因爲加入導電碳黑而產生之脫碳、顔色限制以及與 高分子間之相容性不佳等問題。 6 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公i ) (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作杜印製 426698^ 2633twf.doc/0〇5 五、發明説明（V ) 本發明之特徵之三是本發明之抗靜電環氧樹脂因爲具 有反應性官能基，因此具有耐久性與長效性’且表面特性 佳。 爲讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂’下文特舉較佳實施例’作詳細說明如下： 圖表之簡單說明： 表1係繪示依照本發明實施例之不同含胺化合物與環 氧化合物所製得之抗靜電環氧樹脂組成’及其抗靜電性 質。 實施例 本發明之抗靜電環氧樹脂係由含有胺基之化合物，包 括單胺官能基化合物H2N-R2、或雙胺官能基化合物r4-hn-r3-nh-r5或同時含單胺官能基與雙胺官能基之化合物 與具有反應性之含環氧官能基化合物反應而成。其中，含 環氧官能基化合物的結構爲： 其中，Rl可爲分子量介於44〜2000 (g/mole)之間的芳香 烴基鏈段、脂肪烴基鏈段、含鹵素取代基之芳香烴基鏈段 或含鹵素取代基之脂肪烴基鏈段；而含胺基化合物之R2 與R3爲含有烷氧基醚類之鏈段，其分子量約介於550-6000 (g/mole)之間，且R2與R3之結構爲： 其中爲2或3個碳原子之烴基，η爲10〜45之整數；R4 7 本紙張尺度適用中國國家標準（CNS ) Λ4規格（2!OX297公釐） (請先聞讀背面之注意事項再填寫本頁)42669 8 ^ 2633twf.doc / 〇〇5 Λ7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention (ί) The present invention relates to an antistatic epoxy resin and a method for manufacturing the same, and is particularly related to An antistatic epoxy resin with long-lasting properties and a preparation method thereof. The present invention is produced by reacting an amine (Amine, NH2) compound containing an alkoxy ether and an epoxy group (Epoxy) -containing compound. Many people who are known to impart antistatic properties to polymers belong to an additive. Traditionally, low molecular weight quaternary amine salts or conductive carbon black are used to increase their antistatic properties, such as US Patent No. 5,128,473 and Japanese Patent No. 349,053. Adding low molecular weight quaternary amine salt is easy to be lost due to the migration of quaternary amine salt, and when it is left for a long time, it is prone to wet on the polymer surface and affect its use properties, and if it is added in excess, it will easily affect the polymer. In addition to the conductive carbon black, in addition to the problem of decarburization, the color range is also limited, and it has compatibility problems with polymers. Another type of conventional antistatic agent is to mix an organosilicon compound in a polymer or coat it on a polymer surface to meet the conductivity requirement. Since these organic silicon polymers are not easily compatible with other polymers, they are mostly coated by, for example, US Patent Nos. 5,008,328 and 4,584,342. Since such products are usually added in an additive manner, their antistatic durability and resistance to wiping and washing are deficient in practical applications. In addition, Polyethylene Oxide (PEO) is added to the polymer to make it conductive, such as US Patent Nos. 5,356,959, 4,931,506, 5,262,460, 5,051,475 and the like. Although the reactive functional group OH of polyoxyethane can react with polymers to improve the conductive durability and washing resistance, but because of its slow reactivity and long reaction time, it needs to be promoted under high temperature environment. Its response. Ran 4 (Please read the notes on the back before filling this page) This paper size applies to Chinese national standards (CNS> A4 specification (210X297)) a D Ό ο a D Ό ο Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 2633twf.doc / 005 A / B7 ^ _—_ 5. Description of the invention (2) However, high temperature will cause the polymer to be cracked and affect its quality. Therefore, the object of the present invention is to provide a functional group with high reactivity. In order to improve the shortcomings of the above-mentioned conventional techniques, a long-acting antistatic epoxy resin is proposed. According to the purpose of the present invention, a long-acting antistatic epoxy resin is mainly composed of the following molecular structure: OH 0H 〒 2 ^ CH2-ChhRi --- C, + ~ CH2-N ^-R4 Rs CJH CjH or ten N-R3—N —CH 2 ~ C HR i—C HC H2-)-where & is a molecular weight approximation Aromatic hydrocarbon-based segment, aliphatic hydrocarbon-based segment, aromatic hydrocarbon-based segment containing halogen substituent or aliphatic hydrocarbon-based segment containing halogen substituent between 44 ~ 2000 (g / mole); and I and R3 are about molecular weight Polyoxyalkylene or Pol between 550 ~ 6000 (g / mole) yoxyethylene) segment, its structure is: where R. It is a hydrocarbon group containing 2 or 3 carbon atoms, η is an integer of 10 to 45: 1 and R5 are a group consisting of optional hydrogen, methyl or R. The antistatic epoxy resin of the present invention is composed of a reactive monoamine functional compound H2N-R2, or a diamine functional compound R4, HN-R3-NH-R5, or both a monoamine functional group and a diamine functional group. The compound is reacted with a reactive epoxy functional group-containing compound. Among them, the structure of the epoxy functional group-containing compound is: i > -Ri- < S, where K may be an aromatic having a molecular weight between 44 and 2000 (g / mole). Home County (CNS) (21GX 297 public ^ 7 (please read the precautions on the back before filling out this page), 1T printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4266 9 8 4 2633 twf.doc / 005 8 7 B7 V. Explanation of the invention (>) Hydrocarbyl segment, aliphatic hydrocarbyl segment, aromatic hydrocarbyl segment containing halogen substituent or aliphatic hydrocarbyl segment containing halogen substituent; and r2 and R3 of amine-containing compound are alkoxy-containing The segment of the ether group has a molecular weight of about 550 ~ 6000 (g / mole), and the structure of the core and R3 is: ten R0-〇 ^ where R. is a hydrocarbon group of 2 or 3 carbon atoms, η is an integer from 10 to 45; R4 and R5 are a group consisting of selected hydrogen, methyl, or R. According to the purpose of the present invention, a method for manufacturing an antistatic epoxy resin is provided, which includes: containing an alkoxy group The amine compound of the ether type and the compound containing the epoxy functional group are put into the reactor in an appropriate ratio, wherein The preferred ratio is equivalent number ratio 値 is about I / 2 ~ 2. Stir slowly and warm, and at a temperature of 30 ~ 180 ° C, 'react the amine-containing compound with the epoxy-functional compound to form a reactive function. An antistatic epoxy resin based on the invention. One of the characteristics of the present invention is that the used amine compound has high reactivity with epoxy compounds, and the manufacturing method of the antistatic epoxy resin is very simple, so it can be used in a wide range of industries. For example, it can be used in the industries of resin, plastic processing, special chemicals, coatings, and electronic information. Therefore, the antistatic epoxy resin of the present invention is a product with a high added price. The second feature of the present invention is that of the present invention. Antistatic epoxy resin is a reactive type, so it does not have the disadvantages of migration and loss of the conventional low molecular weight quaternary amine salt and affect the properties of the polymer substrate, and it can effectively improve the conventional technology because conductive carbon black is added. Problems such as decarburization, color limitation, and poor compatibility with polymers. 6 This paper size applies to China National Standard (CNS) A4 specifications (210X297 Company i) (Please read the notes on the back before filling this page) Order the consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Du printed 426698 ^ 2633twf.doc / 0〇 5. Description of the invention (V) Three characteristics of the invention Because the antistatic epoxy resin of the present invention has reactive functional groups, it has durability and long-lasting properties, and has good surface characteristics. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, In the following, the preferred embodiment is described in detail as follows: A brief description of the chart: Table 1 shows the composition of the antistatic epoxy resin prepared by different amine-containing compounds and epoxy compounds according to the embodiments of the present invention and its composition. Antistatic properties. Examples The antistatic epoxy resin of the present invention is a compound containing an amine group, including a monoamine functional compound H2N-R2, or a diamine functional compound r4-hn-r3-nh-r5 or a monoamine functional group. The compound with a diamine functional group is reacted with a reactive epoxy functional group-containing compound. The structure of the epoxy functional group-containing compound is: wherein R1 can be an aromatic hydrocarbon-based segment, an aliphatic hydrocarbon-based segment, or a halogen-containing aromatic hydrocarbon-containing segment having a molecular weight between 44 and 2000 (g / mole). Or halogenated substituent-containing aliphatic hydrocarbon-based segments; and amine-containing compounds R2 and R3 are segments containing alkoxy ethers, the molecular weight of which is between about 550-6000 (g / mole), and R2 and The structure of R3 is: where is a hydrocarbon group of 2 or 3 carbon atoms, η is an integer from 10 to 45; R4 7 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (2! OX297 mm) (Please read first (Notes on the back then fill out this page)
本發明之雜之三是本發明之祕電環麟顧爲具有 反應性官絲，耻具有歌性與長錄，且表面特性佳。 爲讓本發明之上述和其他目的、特徵、和優點能更明顯 易懂’下文特舉較佳實施例，作詳細説明如下： 圖表之簡單説明： 表2係繪示依照本發明實施例之不同含胺基化合物與環 氧化合)紛所製得之抗靜電環氧樹脂組成，及其抗靜電性質。 實施例 本發明之抗靜電環氧樹脂係由含有胺基之化合物，包括 單胺官能基化合物H2N-R2，或雙胺官能基化合物R^HN-Rr NH-R5，或同時含單胺官能基與雙胺官能基之化合物與具有 反應性之含環氧官能基化合物反應而成。其中，含環氧官能 基化合物的結構爲： 其中，及!可爲分子量介於44〜2000(g/mole)之間的芳香烴基鏈 段、脂肪烴基鏈段、含鹵素取代基之芳香烴基鏈段或含鹵素 取代基之脂肪烴基鏈段。商業上可得之含環氯官能某化合物 如長春人造樹脂公司之BE-188，其化皋式如下： -------^----)裝-----—訂：------^ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消费合作社印製 ch3 ch3 och2chch2 Y CH, cn, 、〇/ n=0〜0.2 ;或如Shell公司之Edkote 1007，其化輋式如下： CH I CH, I C\ OC^CHCHj^OC-^~ och3chch; CH, CH, 一 7 -（修正頁） 私紙張尺度逋用中國國家揉準（CNS ) A4洗格（210X297公釐） 83, 3,10,000 經濟部中央標隼局貝工消费合作社印製 426698. ， 2633twf.d〇c/〇〇^ Λ7 B7 ___ 五、發明説明（Γ) 與r5爲擇自由氫' 甲基或K所組成之族群；而含胺基化 合物與含環氧官能基化合物的較佳比例爲1/2〜2;較佳的 反應溫度約爲30°C〜180°C左右。此外，在反應中亦可以 另外添加低分子量含胺基化合物，以增加其交鏈度或其他 物性。適當之含胺基化合物如乙醇胺（Monoethanol amine，MEA) ’ Huntsman 公司之 EDR148、D230、D400 ' T403，乙二胺（Ethylene diamine )、己二胺（Hexamethylene diamine)、苯二胺（Phenylene diamine)等。爲詳細說明 本發明之製造抗靜電環氧樹脂之方法，以下特舉出十二個 達成本發明實施例的例子，以作爲解析之用，然並非用以 限制本發明之範圍。 例一 將長春公司所製造的含環氧基之化合物BE-188 (重量 平均分子量爲380，環氧當量爲85〜195)約42wt% 、 Huntsman公司所製造的含胺基之化合物EDR148 (重量平 均分子量爲148，胺當量爲37)約3.3wt%以及ED2001 (重量平均分子量爲2000，胺當量爲500)約54.7wt%置 入反應瓶中。然後在約爲30〜180°C的溫度中進行反應約 1〜4小時，即可獲得抗靜電環氧樹脂，其表面電阻約爲10〃 Ω /口。 例二 將長春公司所製造的含環氧基之化合物BE-188約 60wt%與Huntsman公司所製造的含胺基之化合物D-230 C重量平均分子量爲230，胺當量爲57_5)約15wt%以 __ 8 本紙張尺度適用中國國家標隼（CNS )六以見格 { 210'乂2们公釐） (請先閱讀背面之注意事項再填寫本頁) 、1T 426698 I修正補克 本奶. 1>月外日丨 B7 五、發明説明（5 經濟部中央橾準局員工消费合作社印策 n= 10.5〜12.5。而含胺基化合物之112與113爲含有烷氧基醚類 之鍵段，其分子量約介於550〜6000(g/mole)之間，且R2與1之 結構爲： -^R〇-〇-^· 其中R〇爲2或3個碳原子之烴基，η爲10〜45之數；R4與R5爲擇 自由氫、甲基或&所組成之族群；而含胺基化合物與含環氧 官能基化合物的較佳比例爲1/2〜2 ;較佳的反應溫度約爲30°C 〜180°C左右。此外，在反應中亦可以另外添加低分子量含胺 基化合物，以增加其交鏈度或其他物性。適當之含胺基化合 物如乙醇胺(Monoethanol amine, MEA)，Huntsman 公司之 EDR148、ED2001、D230、D400、ED6000、Μ 2070、乙二 胺(Ethylene diamine)、己二胺(Hexamethylene diamine)、苯二 胺(Phenylene diamine)等，其中 EDR148之化犖式如下： HjNCI^CI^O - Cl^Ci^O - CH^H^ -NH, ED2001之化學式如下： 严 〒H3 CH3 y 二40,5 x+z=2.5 D230之化學式如下： 邱 CHCH^OCH^Hf CH3 CH3 NHj :2-3 1!------' J裝------訂：--LI-辣 (請先閱讀背面之注意事項再填寫本頁) —8 -(修正頁） 木紙張尺度適用中國國家標準（CNS ) A4規格（2IOX297公釐） 83. 3.10,000 426698 o' 五、發明説明（ D400之化舉古十下. i^N CHCHj-f-OC： CH3 ch3 NH2 x=5-6 經濟部中央梯準局負工消費合作社印製 ED6000之化皋或如下： M2070之化聲 <‘·τγ : CH3〇-^ ΟΗ,ΟΗ,Ο ^C^CHO C^CHNii, 以上化合物皆由Huntsman公司購得。 爲詳細説明本發明之環氧樹脂，以下特舉出十二個達成本發 明實施例的例子，然並非用以限制本發明之範園。 例一 將長春公司所製造的含環氧基之化合物BE-188(重量平均 分子量爲380 ’環乳當量爲85〜195)約42wt%、Huntsman公司 所製造的含胺基之化合物EDR148(重量平均分子量爲148，胺 當量爲37)约3.3wt%以及ED2001(重量平均分子量爲2000，胺 當量爲500)約54,7wt°/〇置入反應瓶中。然後在約爲3〇~18〇1〇的 溫度中進行反應約1〜4小時，即可獲得抗靜電環氧樹脂，其 表面電阻約爲1082Ω〇。 例二 將長春公司所製造的含環氧基之化合物ΒΕ-188約60wt% 與Huntsman公司所製造的舍胺基之化合物D-230(重量平均分 子量爲230，胺當量爲57.5)約15wt%以 一 9 —(修正頁） 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇χ297公釐） 83. 3.10,000 i I —I— W裝 H .~^訂. 踩 (請先閲讀背面之注$項再填寫本頁) 4 2 6 6 9 8 2633twf .doc/005 Λ7 B7 五、發明説明（厶） 及ED2001約2Swt。/。置入反應瓶中。然後在約爲30〜180 °C的溫度中進行反應約1〜4小時，即可獲得抗靜電環氧樹 月旨，其表面電阻約爲10ι°_4Ω/口。 例三 將含環氧基之化合物TBBADE ( Tetra-Bromo Bisphenol A Diglycidyl Ether ;分子量 656，環氧當量 328 ) 約61.9wt%與Huntsman公司所製造的含胺基之化合物 ED2001約23.7wt%以及D-400 (重量平均分子量爲400， 胺當量爲100)約14.4wt%置入反應瓶中。然後在約爲 30〜180°C的溫度中進行反應約1〜4小時，即可獲得抗靜電 環氧樹脂，其表面電阻約爲109 5 Ω/口。 例四 將Shell公司製造的含環氧基之化合物Epikote 1007(重 量平均分子量2900，環氧當量1750〜2100)約53wt%與 Huntsman公司所製造的含胺基之化合物ED2001約35wt% 以及D-230約12wt%置入反應瓶中。然後在約爲30〜18〇 °C的溫度中進行反應約1〜4小時，即可獲得抗靜電環氧樹 脂，其表面電阻約爲109 5 Ω/口。 例五 將長春公司製造的含環氧基之化合物ΒΕ-188約42.7% 與Huntsman公司所製造的含胺基之化合物ED2001約 50wt%以及D-230約7.3wt%置入反應瓶中。然後在約爲 30〜180°C的溫度中進行反應約1〜4小時，即可獲得抗靜電 環氧樹脂，其表面電阻約爲1〇〃Ω/口。 (請先閲讀背面之注意事項再填ίϊ5本頁) 、1T 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準{ CNS ) Α4規格（2]ΟΧ 297公釐） 4 2669 8, 2633twf.doc/005 Λ7 B7 五、發明説明（^ ) 例六 將含環氧基之化合物BDDE (Butane Diol Diglycidyl Ether;分子量 2〇2 ’ 環氧當量 100)約 38.5wt% 與 Huntsman 公司所製造的含胺基之化合物ED2001約51.2wt%以及 D-4〇〇約l〇.3wt%置入反應瓶中。然後在約爲30〜180°c 的溫度中進行反應約1〜4小時，即可獲得抗靜電環氧樹脂， 其表面電阻約爲1〇8+5Ω/口。 _七 將含環氧基之化合物DGE (Diglycidyl Ether ;分子量 130，環氧當量65)約32wt°/〇與Huntsman公司所製造的 含胺基之化合物ED2001約63.7wt%以及D-400約4.3wt% 置入反應瓶中。然後在約爲30〜180°C的溫度中進行反應約 1〜4小時，即可獲得抗靜電環氧樹脂，其表面電阻約爲ι〇*_ι Ω/口。 例八 將長春公司所製造的含環氧基之化合物BE-188約 31wt%與Huntsman公司所製造的含胺基之化合物ED6000 (重量平均分子量6000，環氧當量1500)約62wt%以及 D-230約7wt%置入反應瓶中。然後在約爲30〜180°C的温 度中進行反應約1〜4小時，即可獲得抗靜電環氧樹脂，其 表面電阻約爲109·4Ω/口。 例九 將長春公司所製造的含環氧基之化合物BE-188約 llwt%、Huntsman公司所製造的含胺基之化合物ED6000 10 本紙張尺度適用中國國家椟車（CNS ) A4規格（210X 297公f ) T------------.5?^t— I (請先閲讀背面之注意事項再填寫本頁) 訂 濟 部 中 A 標 準 局 員 工 消 費 合 經濟部中史標準局員工消費合作社印製 426698 Λ 2633twf.doc/005 五、發明説明（汉） 約89wt%置入反應瓶中。然後在約爲30〜18〇°C的溫度中 進行反應約1〜4小時，即可獲得抗靜電環氧樹脂’其表面 電阻約爲1〇9ΜΩ/口。 例十 將長春公司所製造的含環氧基之化合物ΒΕ-188約 26wt%與Huntsman公司所製造的含胺基之化合物D-230 約4wt%以及M-2070 (重量平均分子量爲2000，胺當量爲 1000)約70wt%置入反應瓶中。然後在約爲3〇〜180°C的 溫度中進行反應約卜4小時，即可獲得抗靜電環氧樹脂， 其表面電阻約爲1〇7+7Ω/口。 例-- 將長春公司所製造的含環氧基之化合物ΒΕ-188約 40·5\νΐ%與Huntsman公司所製造的含胺基之化合物Μ-2070約50wt%以及D_230約9.5wt%置入反應瓶中。然 後在約爲30〜180°C的溫度中進行反應約1〜4小時，即可 獲得抗靜電環氧樹脂，其表面電阻約爲1〇81Ω/口。 將長春公司所製造的含環氧基之化合物ΒΕ-188約 76wt%與Huntsman公司所製造的含胺基之化合物Μ-2070 約 12wt% 以及 MEA (Monoethanol Amine)約 12wt%置 入反應瓶中。然後在約爲30〜180°C的溫度中進行反應約 1〜4小時，即可獲得抗靜電環氧樹脂，其表面電阻約爲101<3_5 Ω/口。 表1係繪示依照本發明例一至例十二其反應物之組成 (請先閲讀背面之注意事項再填寫本頁)The third aspect of the present invention is that the secret electric ring of the present invention is a reactive silk, which has singing and long recording, and has good surface characteristics. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, the following describes specific preferred embodiments as follows: A brief description of the chart: Table 2 shows the differences according to the embodiments of the present invention. Composition of antistatic epoxy resin prepared by amine-containing compound and epoxidation), and its antistatic properties. Examples The antistatic epoxy resin of the present invention is a compound containing an amine group, including a monoamine functional compound H2N-R2, or a diamine functional compound R ^ HN-Rr NH-R5, or a monoamine functional group. The compound with a diamine functional group is reacted with a reactive epoxy functional group-containing compound. Among them, the structure of the epoxy functional group-containing compound is: where, and! May be an aromatic hydrocarbon-based segment, an aliphatic hydrocarbon-based segment, or a halogen-containing aromatic hydrocarbon-containing chain having a molecular weight between 44 and 2000 (g / mole). Segment or an aliphatic hydrocarbon segment containing a halogen substituent. A commercially available compound containing a cyclic chlorine function, such as BE-188 from Changchun Synthetic Resin Company, has the following chemical formula: ------- ^ ----) Packing ------- Order:- ----- ^ (Please read the notes on the back before filling out this page) Printed by the Shell Standard Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ch3 ch3 och2chch2 Y CH, cn, 〇 / n = 0 ~ 0.2; or as Shell The company's Edkote 1007, its chemical formula is as follows: CH I CH, IC \ OC ^ CHCHj ^ OC- ^ ~ och3chch; CH, CH, 1 7-(revised page) Private paper scale, using China National Standards (CNS) A4 Xiege (210X297 mm) 83, 3,10,000 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 426698. ， 2633twf.d〇c / 〇〇 ^ Λ7 B7 ___ V. Description of Invention (Γ) and r5 are Select the group consisting of free hydrogen 'methyl or K; and the preferred ratio of the amine-containing compound to the epoxy-functional compound is 1/2 ~ 2; the preferred reaction temperature is about 30 ° C ~ 180 ° C about. In addition, a low-molecular-weight amine-containing compound may be added during the reaction to increase the degree of cross-linking or other physical properties. Suitable amine-containing compounds such as Monoethanol amine (MEA) 'Huntsman's EDR148, D230, D400' T403, Ethylene diamine, Hexamethylene diamine, Phenylene diamine, etc. . In order to explain the method of manufacturing the antistatic epoxy resin of the present invention in detail, twelve examples of the embodiments of the present invention are given below for analysis purpose, but not intended to limit the scope of the present invention. Example 1: About 42% by weight of epoxy-containing compound BE-188 (weight average molecular weight: 380, epoxy equivalent: 85 ~ 195) manufactured by Changchun Company, Huntsman Company's amine-containing compound EDR148 (weight average A molecular weight of 148 and an amine equivalent of 37) were placed in the reaction flask at about 3.3 wt% and an ED2001 (weight average molecular weight of 2000 and amine equivalent of 500) of about 54.7 wt%. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 10〃 Ω / mouth. Example 2 The weight-average molecular weight of the epoxy-containing compound BE-188 manufactured by Changchun Company is about 60% by weight and the amino group-containing compound D-230 C manufactured by Huntsman Company is 230, and the amine equivalent is 57_5. __ 8 This paper size applies to China National Standards (CNS) Liu Yijian (210 '乂 2 mm) (please read the precautions on the back before filling this page), 1T 426698 I amended to supplement the milk. 1 > Outer Day 丨 B7 V. Description of the invention (5 Employee policy of the Central Consumers' Association of the Ministry of Economic Affairs, Consumer Cooperatives n = 10.5 ~ 12.5. And 112 and 113 of amine-containing compounds are bond segments containing alkoxy ethers. Its molecular weight is between 550 ~ 6000 (g / mole), and the structure of R2 and 1 is:-^ R〇-〇- ^ · where R0 is a hydrocarbon group of 2 or 3 carbon atoms, η is 10 ~ The number of 45; R4 and R5 are a group consisting of free hydrogen, methyl or &; the preferred ratio of the amine-containing compound to the epoxy-functional compound is 1/2 to 2; the preferred reaction temperature About 30 ° C ~ 180 ° C. In addition, low molecular weight amine-containing compounds can be added in the reaction to increase the degree of cross-linking. Other physical properties. Suitable amine-containing compounds such as Monoethanol amine (MEA), Huntsman's EDR148, ED2001, D230, D400, ED6000, M 2070, Ethylene diamine, Hexamethylene diamine, Phenylene diamine, etc., where the chemical formula of EDR148 is as follows: HjNCI ^ CI ^ O-Cl ^ Ci ^ O-CH ^ H ^ -NH, the chemical formula of ED2001 is as follows: Yan H3 CH3 y 2 40,5 The chemical formula of x + z = 2.5 D230 is as follows: Qiu CHCH ^ OCH ^ Hf CH3 CH3 NHj: 2-3 1! ------ 'J Pack ------ Order: --LI-Spicy (please first Read the notes on the reverse side and fill in this page) — 8-(correction page) Chinese paper standard (CNS) A4 size (2IOX297 mm) is applicable for wood and paper scales 83. 3.10,000 426698 o 'V. Description of invention (D400) Ten examples from ancient times. I ^ N CHCHj-f-OC: CH3 ch3 NH2 x = 5-6 The print of ED6000 printed by the Consumers ’Cooperatives of the Central Government of the Ministry of Economic Affairs or below is as follows: The sound of M2070 < '· τγ : CH3〇- ^ ΟΗ, ΟΗ, Ο ^ C ^ CHO C ^ CHNii, the above compounds were purchased from Huntsman. In order to explain the epoxy resin of the present invention in detail, twelve examples of the present invention are given below, but they are not intended to limit the scope of the present invention. Example 1: Approximately 42% by weight of epoxy-containing compound BE-188 (weight average molecular weight: 380 'cyclic milk equivalent: 85 ~ 195) manufactured by Changchun Company, and amine group-containing compound EDR148 (weight average manufactured by Huntsman) The molecular weight was 148, the amine equivalent was 37), about 3.3 wt%, and ED2001 (the weight average molecular weight was 2000, the amine equivalent was 500) was placed in the reaction flask at about 5,7 wt ° /. Then, the reaction is performed at a temperature of about 30 to 180,100 for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 1,082 Ω. Example Two: About 60% by weight of the epoxy-containing compound Β-188 manufactured by Changchun Company and D-230 (the weight average molecular weight is 230 and the amine equivalent weight is 57.5) manufactured by Huntsman Company are about 15% by weight. A 9 — (correction page) This paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 83. 3.10,000 i I —I— W installed H. ~ ^ Order. Step (please read the back first) Please fill in this page for the $ item) 4 2 6 6 9 8 2633twf .doc / 005 Λ7 B7 V. Description of the invention (厶) and ED2001 about 2Swt. /. Place into reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy tree can be obtained, and its surface resistance is about 10ι ° _4Ω / mouth. Example 3 The epoxy-containing compound TBBADE (Tetra-Bromo Bisphenol A Diglycidyl Ether; molecular weight 656, epoxy equivalent 328) is about 61.9 wt% and the amino group-containing compound ED2001 manufactured by Huntsman Company is about 23.7 wt% and D- Approximately 14.4 wt% of 400 (weight average molecular weight of 400 and amine equivalent of 100) was placed in a reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 1095 Ω / mouth. Example 4 Epoxyte 1007 (weight-average molecular weight 2900, epoxy equivalent 1750 ~ 2100) about 53% by weight of epoxy-containing compound manufactured by Shell Company and about 35% by weight of ED2001-containing compound manufactured by Huntsman and D-230 About 12 wt% was placed in a reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 1095 Ω / mouth. Example 5 Approximately 42.7% of the epoxy-containing compound Β-188 manufactured by Changchun Company and about 50% by weight of the amine group-containing compound ED2001 manufactured by Huntsman Company and about 7.3% by weight of D-230 were placed in a reaction bottle. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained with a surface resistance of about 10 Ω / mouth. (Please read the precautions on the back before filling in this page), 1T Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs This paper is printed in accordance with Chinese National Standards {CNS Α4 Specification (2) 0 × 297 mm) 4 2669 8, 2633twf.doc / 005 Λ7 B7 V. Description of the invention (^) Example 6 The epoxy-containing compound BDDE (Butane Diol Diglycidyl Ether; molecular weight 202 'epoxy equivalent 100) is about 38.5wt%, manufactured by Huntsman Approximately 51.2 wt% of the amine group-containing compound ED2001 and about 10.3 wt% of D-4 00 were placed in a reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 108 + 5Ω / mouth. _ Seven will be epoxy-containing compound DGE (Diglycidyl Ether; molecular weight 130, epoxy equivalent 65) about 32wt ° / 0 and Huntsman's amine-containing compound ED2001 about 63.7 wt% and D-400 about 4.3 wt % Into the reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about ι0 * _ι Ω / mouth. Example 8: About 31% by weight of epoxy-containing compound BE-188 manufactured by Changchun Company and about 62% by weight of ED6000 (weight-average molecular weight 6000, epoxy equivalent 1500) and D-230 manufactured by Huntsman Company. About 7 wt% was placed in a reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained with a surface resistance of about 109.4 Ω / mouth. Example 9: About 11% by weight of epoxy-containing compound BE-188 manufactured by Changchun Company and amine-containing compound ED6000 manufactured by Huntsman Company 10 The paper size is applicable to the Chinese National Car (CNS) A4 specification (210X 297) f) T ------------. 5? ^ t— I (Please read the notes on the back before filling out this page) A Standard Bureau of the Ministry of Economic Affairs, Staff Standards and Standards of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives 426698 Λ 2633twf.doc / 005 V. Description of the Invention (Chinese) About 89wt% was placed in a reaction bottle. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin 'can be obtained, and its surface resistance is about 109 MΩ / mouth. Example 10: About 26% by weight of epoxy-containing compound Β-188 manufactured by Changchun Company and about 4% by weight of amine-containing compound D-230 manufactured by Huntsman Company and M-2070 (weight average molecular weight is 2000, amine equivalent 1000) into the reaction flask. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 107 + 7Ω / port. Example-Put about 40 · 5 \ νΐ% of epoxy-containing compound Β-188 manufactured by Changchun company and about 50% by weight of amine group-containing compound M-2070 manufactured by Huntsman company and about 9.5% by weight of D_230 Reaction bottle. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained with a surface resistance of about 1081 Ω / port. About 76% by weight of the epoxy-containing compound Β-188 manufactured by Changchun Company, about 12% by weight of the amine group-containing compound M-2070 manufactured by Huntsman Company, and about 12% by weight of MEA (Monoethanol Amine) were placed in a reaction bottle. Then, the reaction is performed at a temperature of about 30 to 180 ° C for about 1 to 4 hours, and an antistatic epoxy resin can be obtained, and its surface resistance is about 101 < 3_5 Ω / mouth. Table 1 shows the composition of the reactants according to Examples 1 to 12 of the present invention (please read the precautions on the back before filling this page)
本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公漦） 經濟部中央標準局員工消費合作杜印製 Gefi 9 8 . 2633twf.doc/0〇5 ^7 ___ B7 __ 五、發明説明（^ ) 與各例所得之抗靜電環氧樹脂之抗靜電性的比較。由表中 所示，例一至例十二所得之表面電阻約在107·7〜1〇ι°·5Ω/口 之間，顯示例一至例十二所得之環氧樹脂具極佳之抗靜電 效果。 根據以上所述本發明之長效型抗靜電環氧樹脂其主要 之知子結構爲 ？H OH f^2 ^CH2-CH-Ri—CH-CH2-N^- R4 Rs CJH CJH 或 R3"HnI —C H2—C H—R i—C H_C H2 子 其中’ R,爲分子量約介於44〜2000 (g/mole)之間的芳香 @基鏈段、脂肪烴基鏈段、含鹵素取代基之芳香烴基鏈段 或含鹵素取代基之脂肪烴基鏈段；而r2與r3爲分子量約 介於550〜6000 (g/mole)之間的含烷氧基醚類鏈段，其結 構爲： 七 其中Rt)爲含有2或3個碳原子之烴基，η爲10〜45之整數； 心與R5爲擇自由氫、甲基或心所組成之族群。 依照本發明實施例所述本發明之特徵之一是所使用的 月安基化合物與環氧基化合物的反應性大，且抗靜電環氧樹 脂之製造方法非常簡單，因此可以應用之產業相當廣泛， 例如可應用在樹脂、塑膠加工、特用化學品、塗料以及電 子資訊產品等產業上，因此本發明之抗靜電環氧樹脂是一 種高附加價値之產品。 本發日月之特徵之二是本發明之抗靜電環氧樹脂係屬於 _____ 12 尺度現格（21()x 297公楚)- ---------5r水-----Ί 订 ------). (請先閱讀背面之注意事項再填寫本頁) 4 266 9 8 Μ 2633twf. doc/005 Λ7 五、發明説明（β ) 反應型，因此不會有習知之低分子量四級胺鹽的遷移流失 及影響高分子基材性質的缺點，而且可以有效地改善習知 技藝中因爲加入導電碳黑而產生之脫碳、顏色限制以及與 高分子間之相容性不佳等問題。 本發明之特徵之三是本發明之抗靜電環氧樹脂因爲具 有反應性官能基，因此具有耐久性與長效性，且表面特性 佳。 雖然本發明已以較佳實施例揭露如上’然其並非用以 限定本發明，任何熟習此技藝者，在不脫離本發明之精神 和範圍內，當可作各種之更動與潤飾，因此本發明之保護 範圍當視後附之申請專利範圍所界定者爲準。 (請先閲讀背面之注意事項再填寫本頁) ,¾. 經濟部中央標準局員工消費合作杜印袋 本紙張尺度適用中國國家揉準（CNS ) A4規格（210X297公t ) 426698 ， Λ7 B7 五、發明説明（/ί ) ( Ω / □) DJ> 頭 m {cv Φ 0 HI麵 m fcv Π1> # WDR14S· §2001·* WDio·* D-230+ D-400+ M-2070e MWA* BE-lsoo TBWADE Epikote WDDW DGW 河m潘 (wt% ) 經濟部中央標準局員工消費合作杜印裂 10® M0S M05 M0。Μ0®·Μ0®」10® Μ0〒Μ0。」10- Μ0Π 10Ξ」 54.7 25.0 23·7 35.0 50·0 51.2 63·7..... - - - - - - -62.0009.0 - , --15.0 - 12.0 7·3 - - 7.0 - 4.0 9.5 _ - - 14.4 - - 10.3 4.3..... - - - , , - - - -70.0 50.0 12.0 ...........12.0 3.3 払2·0 60.0 61·9 53.0 S.7 300,5 32.0 31.0 11.0 26b έ.5 76.0 窗 鸢鸢鸢鸢鸢 S 渣鸢鸢鸢 鸢 ιί1ίΒ5:>4=:>Α + + ——hlll 姍一脚淛洚陛筇蹯_繃雜纖龉N-諱m^KmBlillsf爾 (請先閱讀背面之注意事項再填舄本頁) "衣 _ 、1T 本紙張尺廋適用中國國家標準（CNS ) Λ4規格（2Κ)Χ297公釐） dl 經濟部肀央棵準局員工消費合作社印家 Δ?^^9 8 , 附件三 AS BS 4 266 9 金·，外.認 修正日期：88年12月20日 必申蠢利赛® 1 L w〜 第8710829〇號專利申請案 申請專利範園修正本 1. 一種含烷氣基醚類鏈段之環氧樹脂，其具有如下(犬TM. (式m之分子結構: T 丫 丨 -e CH2 - CH-R, - CH - CH;-Ni— (式 I) ^ ^ ?H ?H -tN-I^-N-CH.-CH-^-CH-CI^-)— (式H)， 其中： 爲分手量介於44〜2000g/mole之間之若杏娣甚絲 段、脂肪烴基鏈段、含函素取代基之芳香烴基鏈段或含 鹵素取代基之脂肪烴基鏈段其中之一； R2與r3爲含烷氧基醚類鏈段，該含烷氧基醚猶鍅與 之結構爲十Rn-Oir，其中R〇爲含有2或3個碳原子之烴 基，η爲10-45之教;以及 R4與R5爲擇自由氫、甲基及Ri所組成之族群其中之 。 9如申請專釗篇.圊第1項所述之含烷氧基醚類鍅蔚夕琿 氧樹脂，其中尺2與&的分子量均介於550〜60⑽(g/mole)之 間0 浪逋用中國困家梯準(CNS ) A4規格（210X297公釐> ---..------系------：-訂 J (請先閲讀.背面之注意事項再填寫表頁) 426698, ABCD 、申請專利範圍 3.如申請專利範圍第1續所沭泛会忱氬某醚類键段之環 氧樹脂，係由含胺基化合物與含環氧官能基化合物反應而 成。 1如申請專利範園第乏項所述之含烷氣基醚類鏈段之環 氧樹脂，其中該含胺基化合物與該含環氧官能基化合物之 當量比値爲1/2至2。 1如申請專利範圍第2項所述之含烷氳基醚類#段之璜 氣樹脂，其中該含胺基化合物包括具有反應性單胺官能基 化合物，其結構爲： h2n-r2 达如申請專利範圍第2項所述之含烷氣甚赫顱铋is· 氣街脂，其中該含胺基化合物包括具有反應性雙胺官能基 化合物，其結構爲： R4_HN_R3—NH—Rs1如申請專利範園第i項所述之含烷氳甚酴鉬辞 氣樹脂，其中該含胺基化合物爲含有單胺官能基迅金趣與 雙胺官能基化合物之混合物。 也如申請專利範園第2項所述之金 氧街脂，其中該含環氧官能基化合物的結構爲： 中围闺家棣準 (CNS ) A4iMS· ( 210X297公釐） (請先閱請背面之.-意事項再填寫本頁} -υψ til n ^ *1 n ίΊ ^ /Ί n n n n 1 ) —一--I I ;II----This paper size applies to China National Standard (CNS) A4 (210X297 cm), printed by Gefei 9 8. 2633twf.doc / 0〇 ^ _ _ B7 __ 5. Description of the invention (^ ) Comparison with the antistatic properties of the antistatic epoxy resin obtained in each case. As shown in the table, the surface resistances obtained in Examples 1 to 12 are about 107 · 7 ~ 10 ̊ · 5Ω / mouth, showing that the epoxy resins obtained in Examples 1 to 12 have excellent antistatic effects. . According to the above, the main substructure of the long-acting antistatic epoxy resin of the present invention is? H OH f ^ 2 ^ CH2-CH-Ri-CH-CH2-N ^-R4 Rs CJH CJH or R3 " HnI —C H2—CH—R i—C H_C H2 where 'R' is a molecular weight of about 44 ~ 2000 (g / mole) aromatic @ based segment, aliphatic hydrocarbon segment, aromatic hydrocarbon segment containing halogen substituent or aliphatic hydrocarbon segment containing halogen substituent; and r2 and r3 have molecular weights between about The alkoxy ether-containing segment between 550 ~ 6000 (g / mole), its structure is: Seven of which Rt) is a hydrocarbon group containing 2 or 3 carbon atoms, and η is an integer of 10 ~ 45; heart and R5 Choose a group of free hydrogen, methyl, or heart. One of the characteristics of the present invention according to the embodiments of the present invention is that the used moonyl compound has high reactivity with epoxy compounds, and the manufacturing method of antistatic epoxy resin is very simple, so the industry that can be applied is quite wide For example, it can be applied to industries such as resin, plastic processing, special chemicals, coatings, and electronic information products. Therefore, the antistatic epoxy resin of the present invention is a product with high added cost. The second feature of the sun and the moon is that the antistatic epoxy resin of the present invention belongs to _____ 12 scales (21 () x 297 Gongchu)---------- 5r water ---- -Ί Order ------). (Please read the notes on the back before filling out this page) 4 266 9 8 Μ 2633twf. Doc / 005 Λ7 V. Description of the invention (β) Reactive type, so there will be no practice It is known that the migration and loss of low molecular weight quaternary amine salts and the disadvantages affecting the properties of polymer substrates can effectively improve the decarburization, color limitation and compatibility with polymers caused by the addition of conductive carbon black in conventional techniques. Sexual problems. The third characteristic of the present invention is that the antistatic epoxy resin of the present invention has durability and long-lasting properties, and has excellent surface characteristics because it has a reactive functional group. Although the present invention has been disclosed in the preferred embodiment as above, it is not intended to limit the present invention. Any person skilled in the art can make various changes and decorations without departing from the spirit and scope of the present invention. Therefore, the present invention The scope of protection shall be determined by the scope of the attached patent application. (Please read the precautions on the back before filling out this page), ¾. The consumer ’s cooperation with the Central Bureau of Standards of the Ministry of Economic Affairs, the printed paper size of this paper is applicable to China National Standards (CNS) A4 (210X297g) 426698, Λ7 B7 5 Description of the invention (/ ί) (Ω / □) DJ > head m {cv Φ 0 HI face m fcv Π1 ># WDR14S · §2001 · * WDio · * D-230 + D-400 + M-2070e MWA * BE -lsoo TBWADE Epikote WDDW DGW Hempan (wt%) Staff Consumer Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs Du Yinhe 10® M0S M05 M0. M0® · M0® "10® M0〒Μ0. `` 10- Μ0Π 10Ξ '' 54.7 25.0 23 · 7 35.0 50 · 0 51.2 63 · 7 .....-------62.0009.0-, --15.0-12.0 7 · 3--7.0-4.0 9.5 _--14.4--10.3 4.3 .....---,,----70.0 50.0 12.0 ........... 12.0 3.3 払 2 · 0 60.0 61 · 9 53.0 S.7 300,5 32.0 31.0 11.0 26b. 5 76.0 Window kite kite kite S squaring kite kite 1 ίΒ5: > 4 =: > Α + + —— hlll shank zhe _ _ zhang miscellaneous fiber龉 N- 讳 m ^ KmBlillsfer (Please read the precautions on the back before filling this page) " 衣 _ 、 1T This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (2KK) × 297mm) dl Economy Ministry of Health, Central Bureau of Quasi-Bureau, Consumer Consumption Cooperative, India Δ? ^^ 9 8, Attachment 3 AS BS 4 266 9 Gold, outside. Revision date: December 20, 88, must apply for Stupid Race® 1 L w ~ Patent No. 87108290, patent application, amendments to the patent park 1. An epoxy resin containing an alkanoyl ether segment, which has the following (canine TM. (Molecular structure of the formula m: T Ya 丨 -e CH2- CH-R,-CH-CH; -Ni— (Formula I) ^ ^? H? H -tN-I ^ -N-CH.-CH-^-CH-CI ^-) — ( H), of which: the Rhodium apricotii silk segment, the aliphatic hydrocarbon-based segment, the aromatic hydrocarbon-based segment containing a functional element substituent or the halogen-containing aliphatic hydrocarbon segment containing a breakup amount between 44 and 2000 g / mole One of them; R2 and r3 are alkoxyether-containing segments, and the alkoxyether-containing structure is ten Rn-Oir, where R0 is a hydrocarbon group containing 2 or 3 carbon atoms, and η is The teachings of 10-45; and R4 and R5 are selected from the group consisting of hydrogen, methyl, and Ri. 9 As described in the application section. 专 alkoxy ether-containing ethers described in item 1 Oxygen resin, in which the molecular weights of ruler 2 and & are between 550 ~ 60⑽ (g / mole). 0 逋 逋 uses the Chinese Standard for Household Standards (CNS) A4 (210X297 mm) ---..- ----- Department ------ ：-Order J (please read first. Please fill in the sheet on the back) 426698, ABCD, patent application scope 3. If you apply for the first patent application scope The epoxy resin of an ether bond segment is formed by the reaction of an amine-containing compound and an epoxy-functional compound. 1 The epoxy resin containing an alkanoyl ether segment as described in Item No. 1 of the applied patent garden, wherein the equivalent ratio 値 of the amine group-containing compound to the epoxy functional group-containing compound is 1/2 to 2. 1 The gas-containing resin containing alkyl sulfonyl ethers as described in item 2 of the scope of patent application, wherein the amine-containing compound includes a compound having a reactive monoamine functional group, and its structure is: h2n-r2 The alkane-containing Shichi cranibismuth is · gas street lipid according to item 2, wherein the amine-containing compound includes a compound having a reactive diamine functional group, and its structure is: R4_HN_R3—NH—Rs1 The alkane-containing molybdenum moisturizing gas resin as described in item i, wherein the amine-containing compound is a mixture containing a monoamine functional group and a diamine functional compound. It is also as described in the patent application Fanyuan No.2, the structure of the epoxy functional group-containing compound is: Zhong Wei Gui Jia Jun Zhuan (CNS) A4iMS · (210X297 mm) (please read first please On the back.-Issue matters, please fill out this page} -υψ til n ^ * 1 n ίΊ ^ / Ί nnnn 1) — 一 --II; II ----