--4 254 2 6； A7 B7 經濟部中夬標隼局員工消費合作社印製 五、發明説明（1) 本發明俗關於一種持久型清香劑組成物，更詳而言之 ，傲關於一種特別適合汽車用的清香劑組成物，具有緩慢 釋放番氣之效果。 目前汽車上用的空氣清香劑之内容物絶大多數為液態 或凝膠態，故其産品必須要有容器如玻璃瓶或是塑膠外殼 包裝且，且一般僳經雙面膠帶黏附於汽車内裝上才能使用 c此習用産品之缺點為：1)因其用雙面膠帶黏且其髏積又 大，行駛中容@溢出（液體）污染車内的内装，雙面膠帶又 會破壊儀表板；2)此兩種形態（液態及凝膠態）雖有其揮發 快速的優點，但相對在持久性上（使用時間）就很短。近幾 年來，市面上出現一種新産品，其體積小可夾在汽車冷氣 出風口的葉片上，且其内容物為固體也無污染之疑慮。但 是此産品因其體積小而内容物亦少，造成其持久性短。目 前市面上所銷售之此類産品（包括進口産品）皆有此缺點。 為了要達成”體積小，效果好，持久性佳”的要求，理 論上必須要讓極小體積的載體吸附最多的香精，且必須要 能控制其揮發速度，如此才能逹成此目標。經過長期的載 體實驗，發現很多材質皆有相同問題，可吸附大量香精. 但無法控制其揮發時間，即在短時間内就揮發完。只有一 類材質是相反，即塑膠類（聚合物），其組成為高分子結構 ,香精非常不容易加入，但是一旦加入後就可保持”半永 久性”的效果。理論上其困難之處在於：1)塑膠類的熔解溫 度皆很高，而溫度越高，對香精的破鹿力越強；2)塑腰類 皆為高密度分子結構，讓香精分子進入的空間並不大。針 —3 — 本紙張尺度適用中國國家標準（CNS > A4規格（210X297公釐） (請先聞讀背面之注意事項再填寫本頁) 425426 A7 B7 _五、發明説明（2 ) 對此兩點本案發明人開始找熔點”較”低的塑膠材質，理論 上熔點越低其分子密度也應越低。最後確認用PVC粉當主 要原料，再加其他一些必須之原料（見配方表），試出其吸 收香精之臨界點，再利用塑膠高分子使香精可被慢慢釋放 出來，而來完成前述之效果。此製品經實驗後發現可在汽 車内使用60天以上，若在小空間使用如衣楠、抽屜、皮包 …·等等，其壽命更逾賽年以上. 本發明之清香劑組成物包括總重量為100%的以下成分 經濟部中央標準局貝工消費合作杜印製 聚氣乙燃（PVC)粉 20-25% 碩酸鈣 20-25% DINP (苯二甲酸二異壬酯） 20-25% 硬脂酸 0.1-0.5% 香精油 25-35% 其中上述硝酸鈣條充當作填充劑， DINP偽當作可塑劑 ，硬酯酸的作用為讓押出之産品表面光滑細緻，亦具有讓 整個配方原料在高溫之下保持安定的效用，而香精油為高 濃度香精油，賦予成品香味。 本發明之清番劑組成物較佳包括以重量百分率計的以 下成分： 聚氣乙烯（PVC)粉 22.72% 磺酸鈣 22.72% DINP (苯二甲酸二異壬酿） 22.35% 硬脂酸 0.27% — 4 — 本紙張尺度適用中國國家標準（CNS ) A4規格（2彳OX297公釐） 經濟部中央標準局貝工消費合作社印製 4254 2 6 ΑΊ Α7 一一__Β7_ 五、發明説明（3) 香精油 31.94% 鸾例： 以上述較佳組成的比率將聚氣乙嫌、确酸縛、DINP及 硬脂酸混合一起及搜拌均勻，然後以所示比率添加香精油 而得到一混合物。於m拌下將所得混合物送入螺旋押出機 之料管内。押出機料管溫度為110-115TC,加熱時間為約 為3分鐘。所得半成品由押出機押出後，待其冷卻後，再 以粉碎機粉碎，然用將混料後的半成品送進另一螺旋押出 機之料管内，並將螺旋押出機之料管設定於125-130=0之 間，加熱時間約4分鐘。立即將所押出的物品冷卻（水浴） ，以加速物品的固化及減少香精油的揮發損失。最後以切 刀切割物品成所欲之大小。此製诰流程大致如附圖1中所 示。 試驗： 將圓柱型齒輪狀的成品（7克，香精油含量為2.236克） 夾於汽車冷氣出風口（溫度平均8。0 ,記錄每日揮發的重 量及將累積重（即當日揮發置加上之前的揮發暈），結果示 於以下實驗數據中。並以之作圖，如附圖2及3所示。 圖式説明： _______- 5 -_ 一本紙張尺度適用中國國家標準（CMS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) *?τ 經濟部中央橾準局員工消費合作社印製 A7 B7 五、發明説明（4 ) 實驗數攄 天 揮發m 累積重 1 0.04 0.04 2 0.0399 0.0799 3 0.0389 0.1188 4 0.0379 0.1567 5 0.0375 0.1942 6 0.0374 0.2316 7 0.0373 0.2689 8 0.0372 0.3061 9 0.0371 0.3432 10 ◦.037 0,3802 11 0.0368 0.417 12 0.0366 0,4536 13 0.0364 0.49 14 0.0362 0.5262 15 0,036 0.5622 16 0.0358 0.598 17 0.0354 0.6334 18 0.0352 0.6686 19 0.0348 0.7034 20 0.0344 0.7378 21 0.034 0.7718 22 0.0338 0.8056 23 0.0336 0,8392 24 0.0334 0.8726 25 0.033 0.9056 26 0·0328 0.9384 27 0.0325 0.9709 28 0.0321 1.003 29 0.0318 1.0348 30 0.0312 !Ό66 31 0.0305 1.0965 32 0.029 1.1255 33 0.0285 1.154 34 0·028 [182 35 0.0275 1.2095 36 0,027 1.2365 37 0.0266 1.2631 38 0.0264 1.2895 39 0.025 1.3145 40 0.024 1,3385 41 0.023 1.3615 天 揮發皇 累賴重 42 0.022 ί.3835 43 0.0213 1.4048 44 0.0215 1.4263 45 0.0196 1.4459 46 0.0194 1.4653 47 0.0185 1.4838 48 0.018 1.5018 49 0.0175 1.5193 50 0.017 1.5363 51 0,016 1.5523 52 0.015 1.5673 53 0,014 1.5813 54 0.012 1.5933 55 0.01 1.6033 56 0.009 1.6123 57 0.008 1.6203 58 0.007 1.6273 59 0.006 1.6333 60 0.005 1.6383 61 0.004 1.6423 62 0.003 1.6453 63 0.001 1.6463 64 0 1.6463 (請先Η讀背面之注意事項再填寫本頁) 訂 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨0Χ 297公釐） _B7 五、發明説明（5 ) 圖1偽本發明之持久型清香劑組成物的製造流程方 塊圖。 圖2像本發明之持久型清香劑組成物使用時的累積 重與時間的關俗。 圖3條本發明之持久型淸香劑組成物使用時的惲發 置與時間的關條。 (請先聞讀背面之注意事項再填寫本頁} .訂 經濟部中央標隼局負工消費合作社印製 中國國家標準(CNS) ( 210X297^t )--4 254 2 6; A7 B7 Printed by the Consumers' Cooperative of the China National Standards Administration of the Ministry of Economic Affairs. 5. Description of the invention (1) The invention is about a long-lasting fragrance composition, more specifically, about a special A deodorant composition suitable for automobiles, which has the effect of slowly releasing breath. At present, the contents of air deodorants used in automobiles are mostly liquid or gel. Therefore, their products must be packed in containers such as glass bottles or plastic shells, and generally adhered to the interior of the car with double-sided tape. The disadvantages of using this conventional product are: 1) Because it is adhered with double-sided tape and its cross-section is large, the driving capacity @ overflow (liquid) pollutes the interior of the car, and the double-sided tape will break the dashboard; 2) Although these two forms (liquid and gel) have the advantage of rapid volatility, they are relatively short-lasting (use time). In recent years, a new product has appeared on the market. Its small size can be clamped on the blades of car air-conditioning air outlets, and its contents are solid and there is no concern about pollution. However, because of its small size and small contents, this product has short durability. Such products (including imported products) currently on the market have this disadvantage. In order to achieve the requirements of "small volume, good effect, and good durability", in theory, it is necessary to allow a very small volume of carrier to absorb the most flavors, and it must be able to control its volatilization rate, so as to achieve this goal. After long-term carrier experiments, it was found that many materials have the same problem and can absorb a large amount of flavor. However, the volatilization time cannot be controlled, that is, the volatilization is completed in a short time. Only one type of material is the opposite, namely plastics (polymers), whose composition is a polymer structure. Flavors are very difficult to add, but once added, they can maintain the "semi-permanent" effect. The theoretical difficulties are: 1) the melting temperature of plastics is very high, and the higher the temperature, the stronger the deer breaking power of the fragrance; 2) the plastic waist are high-density molecular structure, allowing the fragrance molecules to enter Not much space. Pin — 3 — This paper size is in accordance with Chinese national standards (CNS > A4 size (210X297 mm) (Please read the precautions on the back before filling out this page) 425426 A7 B7 _V. Description of the invention (2) The inventor of this case started to find plastic materials with a lower melting point. In theory, the lower the melting point, the lower the molecular density. Finally, confirm that PVC powder is used as the main raw material, and then add other necessary raw materials (see the formula table). Try to find out the critical point of absorbing fragrance, and then use plastic polymer to make the fragrance slowly release to complete the aforementioned effect. This product was found to be able to be used in a car for more than 60 days after experiments. If used in a small space Such as Yi Nan, drawers, leather bags, etc., its life span is more than the race year. The fragrance composition of the present invention includes the following ingredients with a total weight of 100%. Ethylene (PVC) powder 20-25% Calcium sulfonate 20-25% DINP (diisononyl phthalate) 20-25% Stearic acid 0.1-0.5% Essential oil 25-35% The above calcium nitrate strips serve as As filler, DINP pseudo-plasticizer The function of stearic acid is to make the surface of the extruded product smooth and fine, and it also has the effect of keeping the entire formula raw materials stable under high temperature, and the essential oil is a high-concentration essential oil, which gives the finished product a fragrance. The material preferably includes the following ingredients in weight percentage: Polyethylene (PVC) powder 22.72% calcium sulfonate 22.72% DINP (diisononyl phthalate) 22.35% stearic acid 0.27% — 4 — This paper is applicable to the standard China National Standard (CNS) A4 specification (2 彳 OX297 mm) Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy 4254 2 6 ΑΊ Α7 一 __Β7_ V. Description of the invention (3) Essential oil 31.94% Example: Take The above preferred composition ratio is to mix polygas, acetic acid, DINP and stearic acid together and mix well, and then add essential oils at the ratio shown to obtain a mixture. The resulting mixture is sent under mixing Inside the material tube of the screw extruder. The temperature of the material tube of the extruder is 110-115TC, and the heating time is about 3 minutes. After the semi-finished product obtained is extruded by the extruder, it is cooled, and then pulverized by a pulverizer, then Feed the mixed semi-finished product into the material pipe of another screw extruder, and set the material pipe of the screw extruder between 125-130 = 0, and the heating time is about 4 minutes. Cool the extruded items immediately (water bath ) To accelerate the solidification of the article and reduce the volatilization loss of the essential oil. Finally, the article is cut with a cutter to the desired size. The process of making this product is roughly as shown in Figure 1. Test: The cylindrical gear-shaped finished product ( 7 grams, essential oil content is 2.236 grams) clipped to the car air-conditioning air outlet (temperature average 8.0, record the weight of daily volatility and the cumulative weight (that is, the volatility of the day plus the previous volatility), the results are shown below Experimental data. And use it for drawing, as shown in Figures 2 and 3. Schematic description: _______- 5 -_ A paper size is applicable to the Chinese National Standard (CMS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) *? Τ Staff of the Central Bureau of Standards, Ministry of Economic Affairs Printed by the consumer cooperative A7 B7 V. Description of the invention (4) The number of experiments per day volatile m Cumulative weight 1 0.04 0.04 2 0.0399 0.0799 3 0.0389 0.1188 4 0.0379 0.1567 5 0.0375 0.1942 6 0.0374 0.2316 7 0.0373 0.2689 8 0.0372 0.3061 9 0.0371 0.3432 10 ◦ .037 0,3802 11 0.0368 0.417 12 0.0366 0,4536 13 0.0364 0.49 14 0.0362 0.5262 15 0,036 0.5622 16 0.0358 0.598 17 0.0354 0.6334 18 0.0352 0.6686 19 0.0348 0.7034 20 0.0344 0.7378 21 0.034 0.7718 22 0.0338 0.8056 23 0.0336 0,8392 24 0.0334 0.8726 25 0.033 0.9056 26 0.32832 0.9384 27 0.0325 0.9709 28 0.0321 1.003 29 0.0318 1.0348 30 0.0312! Ό 66 31 0.0305 1.0965 32 0.029 1.1255 33 0.0285 1.154 34 0 · 028 [182 35 0.0275 1.2095 36 0,027 1.2365 37 0.0266 1.2631 38 0.0264 1.2895 39 0.025 1.3145 40 0.024 1,3385 41 0.023 1.3615 days Fatty weight 42 0.022 ί. 3835 43 0.0213 1.4048 44 0.0215 1.4263 45 0.0196 1.4459 46 0.0194 1.4653 47 0.0185 1.4838 48 0.018 1.5018 49 0.0175 1.5193 50 0.017 1.5363 51 0,016 1.5523 52 0.015 1.5673 53 0,014 1.5813 54 0.012 1.5933 55 0.01 1.6033 56 0.009 1.6123 57 0.008 1.6203 58 0.007 1.6273 59 0.006 1.6333 60 0.005 1.6383 61 0.004 1.6423 62 0.003 1.6453 63 0.001 1.6463 64 0 1.6463 (Please read the notes on the back before filling out this page) The paper size of the paper is applicable to Chinese national standards (CNS ) A4 specification (2 丨 0 × 297 mm) _B7 V. Description of the invention (5) Figure 1 is a block diagram of the manufacturing process of the long-lasting fragrance composition of the present invention. Fig. 2 is a graph showing the relationship between cumulative weight and time when the long-lasting fragrance composition of the present invention is used. Fig. 3 is a graph showing the relationship between the time and the time when the permanent fragrance composition of the present invention is used. (Please read the notes on the back before filling out this page}. Order printed by the Central Standards Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperatives China National Standard (CNS) (210X297 ^ t)