TW416986B

TW416986B - Liquid bleaching agent composition with enhanced viscosity

Info

Publication number: TW416986B
Application number: TW86111382A
Authority: TW
Inventors: Nobuyuki Ogura; Kazuyoshi Ozaki; Muneo Aoyanagi
Original assignee: Kao Corp
Priority date: 1996-09-06
Filing date: 1997-08-08
Publication date: 2001-01-01
Also published as: CN1121486C; CN1176302A; ID17239A

Abstract

A liquid bleaching agent composition of enhanced viscosity is disclosed which excels in storage stability and suffers only a sparing change in viscosity due to changes in temperature. The present liquid bleaching agent composition contains peroxide, a thickener, and a surfactant and manifests a viscosity in the range of 10 to 1,000 mPa's at 30 DEG C. It is characterized in that the thickener is a compound containing a polyoxyalkylene chain and an alkyl or alkenyl group in the molecular unit thereof and having a molecular weight of not less than 600 and the gravimetric ratio of the polyoxyalkylene chain to the alkyl or alkenyl group in the molecule thereof is larger than 2, namely (polyoxyalkylene chain)/(alkyl group or alkenyl group)>2.

Description

A7 B7 經濟部中央標準局員工消費合作杜印裂 416S86 五、發明説明（1 ) 發明背景發明範園：本發明係關於強化黏度之一種液體漂白劑組合物及更特定1之係關於獲得優良之儲存安定性及遭受因溫度改變而產生之僅微小之黏度改變之強化黏度之一種液體漂白劑組合物。先前技藝之説明：漂白劑係分類爲兩種類型，即以氯爲主之漂白劑及以氧爲主之漂白劑。以氯爲主之漂白劑係僅僅可使用於有限種類之纖維上，不能使用於有顏色或有圖案之織品上，及由於特別之氣味而受到拒絕。因此，於最近年代以氧爲主之漂白劑，其不具有此等缺點，已顯著地推廣。於以氧爲主之漂白劑中，過碳酸鈉及過硼酸鈉係以粉末狀漂白劑使用及過氧化氫係以一種液體以氧爲主之漂白劑使用。以容易使用之觀點，液體漂白劑組合物係較佳於其他類型之漂白劑組合物。當一種液體漂白劑係使用於漂白衣服時，其時常係直接置於洗衣機中。然而，當其直接塗佈於污斑時，其顯示高漂白效應。由於一般之液體以氧爲主之漂白劍具有低黏度 ’因此當其塗佈於鱗衣服上之污斑時於其漆造入此污斑之前其自污斑移動。因此，以使用之方便之觀點，此種應用之方式係成問題的。於此種情形下，已需要經由強化黏度而改良之液體漂白劑。作爲強化液體漂白劑之黏度之方法，世界智慧財權組織 ___ -4- 本紙適用中國國家標準（CNS) A4規—格（21GX297公楚）—~~— ------ (請先閱讀背面之注意事項再填寫本頁}A7 B7 Consumption cooperation between employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du Yinhe 416S86 V. Description of the invention (1) Background of the invention Fan Yuan: The present invention is a liquid bleach composition for strengthening viscosity and more specifically 1 for obtaining excellent A liquid bleach composition that is stable in storage and is subject to enhanced viscosity with only minor viscosity changes due to temperature changes. Explanation of previous techniques: Bleaching agents are classified into two types, namely chlorine-based bleaching agents and oxygen-based bleaching agents. Chlorine-based bleaching agents can only be used on a limited number of fibers, they cannot be used on colored or patterned fabrics, and they are rejected due to their special odor. Therefore, oxygen-based bleaching agents, which do not have these disadvantages in recent years, have been significantly promoted. Among the oxygen-based bleaches, sodium percarbonate and sodium perborate are used as powder bleaches and hydrogen peroxide is used as a liquid oxygen-based bleach. From the standpoint of ease of use, liquid bleach compositions are preferred over other types of bleach compositions. When a liquid bleach is used to bleach clothes, it is often placed directly in the washing machine. However, when it is directly applied to the stain, it shows a high bleaching effect. Because the general liquid oxygen-based bleaching sword has a low viscosity ′, when it is applied to a stain on scale clothes, it moves from the stain before the paint is made into the stain. Therefore, from the standpoint of ease of use, such an application is problematic. In such cases, a liquid bleach improved by enhanced viscosity has been required. As a method to strengthen the viscosity of liquid bleaching agents, the World Intellectual Property Organization ___ -4- This paper applies the Chinese National Standard (CNS) A4 Regulations-Standard (21GX297 Gongchu) — ~~ — ------ (Please read first Note on the back then fill out this page}

A7 B7 416S86 五、發明説明（2 ) 專利9 4 /1 14 7 4揭示依賴兩種非離子界面活性劑之使用之一種方法’及美國專利-A 4900469揭示依賴—種脂肪酸之組合之一種方法。然而，當應用此等方法於酸液體漂白劑時 ’由於相關之漂白劑.因溫度改變而遭受顯著之黏度改變，因此此等方法引發漂白劑實際上僅困難地使用之問題。曰本專利- A-2-300300揭示一種酸濃縮之液體成分，其使用一種不飽和幾酸與一種烯烴不炮和單體之共聚物作爲一種增稠劑。此種増稠劑之使用不但引發液體成份由於溫度改變而遭受顯著之黏度改變之問題，而且引發增稠劑，當應用於其中包含一種漂白活化劑諸如於日本專利_A_6_ 494 87中揭示者之一種液體漂白劑組合物時，加速漂白活化劑之分解之問題。此外，採用多醣諸如黃酸樹膠及聚半乳甘露糖及纖維素衍生物諸如羧甲纖維素作爲增稠劑係可想像的。然而’此等增稠劑具有當儲時彼等引發過氧化氫之分解之問題。發明摘述因此，本發明之一項目的係提供強化黏度之一種液體漂白劑組合物’其消除上述之先前技藝之缺點 '擅長於儲存安定性、及遭受因溫度改變而產生之僅微小之黏度改變。本發明人等，於勤勉之研究之後，已發現上述之目的係經由組合一種特定之聚氧伸烷基衍生物作爲一種增稠劑而達成，及已達成本發明。特定言之，本發明係針對強化黏度之一種液體漂白劑組合物，其包含過氧化氫、一種增稠劑、及一種界面活性劑 -5 私紙張从適用中國國家標準（CNS ) Α4^_ ( 21〇x297公衆 (請先閱讀背面之注意事項再填寫本買) 經濟部中央標準局貝工消費合作社印製 L-i~l·；-------->l、w------Q------„——r A7 B7 416S86 五、發明説明（3 ) 及於30°C顯示於1〇至1，〇〇〇毫帕秒（厘泊（cp))之範園内之黏度，其特徵爲增稠劑係於其之分予單位中包含一種聚氧伸競基鏈及一種基或一種缔基及具有不小於6〇〇之分子量及於其之分子中聚氧伸烷基鏈比烷基或烯基之重量比例係大於2 (即（聚氧伸烷基鏈）/ (烷基或烯基）> 2)之一種化合物。本發明亦係針對一種方法，其包含將於前述段節中提及之增稠劑（於標題"申請專利範圍"之部分中述及申請專利範園第1項及於以下***本文中）加入包含過氧化氫及一種界面活性劑並於30 °C顯示於1 〇至1，000毫帕秒之範圍内之黏度之一種液體漂白劑組合物中’因而限制組合物回應於自20 C至30 C之溫度改變而發生〇6〇或以下（較佳地〇5〇或β下）之黏度改變比率，如根據下列式計算。 |黏度(30 °C)-黏度(20 °C)1 ~~+黏度(3Γ@ 根據本發明，可提供強化黏度之一種液體漂白劑組合物 ’其獲得優良之儲存安定性及遭受因溫度改變而產生之僅微小之黏度改變〇較佳具體實施例之説明以下將關於一種較佳具體實施例較詳細地説明本發明。 —本發明<液體漂白劑組合物包含過氧化氫作爲一種主要成分。過氡化氫之含量較佳地係於以重量計1至1 〇 %之範圍内’更佳地於以重量計1至6 0/〇之範圍内。使用一種化合物作爲於本發明中之增稠劑，其於其之； _ο裝 .^ Iΐτ-------U (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印裂A7 B7 416S86 V. Description of the invention (2) Patent 9 4/1 14 7 4 discloses a method relying on the use of two non-ionic surfactants' and US Patent-A 4900469 discloses a method relying on a combination of a fatty acid. However, when these methods are applied to acid liquid bleaching agents, due to the related bleaching agents, they undergo significant viscosity changes due to temperature changes, so these methods raise the problem that bleaching agents are practically only difficult to use. The Japanese patent-A-2-300300 discloses an acid-concentrated liquid component which uses a copolymer of an unsaturated polyacid and an olefinic monomer and a monomer as a thickener. The use of such thickeners not only causes the liquid components to suffer significant viscosity changes due to temperature changes, but also causes thickeners, when applied to include a bleach activator such as disclosed in Japanese Patent _A_6_494 87 In a liquid bleach composition, the problem of accelerated decomposition of the bleach activator. In addition, it is conceivable to use polysaccharides such as xanthan gum and polygalactomannose and cellulose derivatives such as carmellose as thickeners. However, these thickeners have the problem that they cause decomposition of hydrogen peroxide when stored. SUMMARY OF THE INVENTION Accordingly, one of the items of the present invention is to provide a liquid bleaching composition that enhances viscosity, which eliminates the shortcomings of the prior art described above, and is good at storage stability and suffers from only small viscosity due to temperature changes. change. After diligent research, the present inventors have found that the above-mentioned object is achieved by combining a specific polyoxyalkylene derivative as a thickener, and has reached the present invention. In particular, the present invention is directed to a liquid bleach composition for enhancing viscosity, which comprises hydrogen peroxide, a thickener, and a surfactant-5. Private paper is applicable from China National Standard (CNS) Α4 ^ _ ( 21〇x297 public (please read the precautions on the back before filling in this purchase) Li ~ l · printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs; -------- > l, w ---- --Q ------ „—— r A7 B7 416S86 V. Description of the invention (3) and display at 30 ° C in the range of 10 to 1,000 milliPascal Seconds (centipoise (cp)) The viscosity in the garden is characterized in that the thickener contains a polyoxyl stretching chain and a group or an allyl group in its unit and has a molecular weight of not less than 600 and polyoxygen in its molecule. A weight ratio of an alkylene chain to an alkyl group or an alkenyl group is greater than 2 (that is, (polyoxyalkylene chain) / (alkyl or alkenyl) > 2). The present invention is also directed to a method, It contains the thickener that will be mentioned in the previous paragraph (referred to in the section entitled "Scope of Patent Application" in the section entitled "Patent Application" and inserted below (Text) Adding a liquid bleach composition containing hydrogen peroxide and a surfactant and exhibiting a viscosity in the range of 10 to 1,000 milliPascal seconds at 30 ° C, thus limiting the composition's response from 20 The temperature change from C to 30 C results in a viscosity change ratio of 060 or less (preferably at 050 or β), as calculated according to the following formula: | Viscosity (30 ° C)-Viscosity (20 ° C) 1 ~~ + viscosity (3Γ @ According to the present invention, a liquid bleach composition capable of providing enhanced viscosity is obtained which has excellent storage stability and suffers only slight viscosity changes due to temperature changes. Preferred embodiments Explanation The following will describe the present invention in more detail with respect to a preferred embodiment.-The present invention < liquid bleach composition contains hydrogen peroxide as a main ingredient. The content of hydrogen peroxide is preferably based on weight In the range of 1 to 10%, it is more preferable to be in the range of 1 to 60/0 by weight. A compound is used as the thickener in the present invention, and _ο 装. ^ Iΐτ ------- U (Please read the notes on the back first (Please fill in this page again)

416SS6 at ------ B7 五、發明説明（4 ) ~~ ~ -一~ 子單位中包含一種聚氧伸烷基鏈及一種烷基或一種烯基，具有超過600之分子量，較佳地於1〇〇〇至3〇〇〇〇之範園内，及滿足於其之分子中聚氧伸烷基鏈比烷基或烯基之重量比例係大於.2之條件，即表示：（聚氧伸烷基鏈）/(烷基或烯基）[於後文中此商數將簡短地稱爲"E"] >2，較佳地e > 5。倘若增稠劑之分子量係小於600，則增稠劑將不獲得適合之黏度。倘若E之大小係不大於2，則增稠劑將亦不獲得適合之黏度。作爲本説明書之增稠劑之較佳實例’可引用由式（1)代表之化合物。 R1 - X - (C2H40)„ - (c〇)p - R2 ⑴ 經濟部中央標準局員工消費合作社印製 • 1^1 IT s I I n nby I , , 霸澤 ί請先聞讀背面之注意事項再填寫本頁} iw 其中R1代表具有10至20個碳原子之一種線性或分枝之烷基或晞基；R2代表Η或具有10皇2 〇個碳原子之一種線性或分枝之熄基或烯基；及X代表-Ο-、-COO-、-NR3-、或-CONR3-，其中以代表h，具有個碳原子之一種烷基、喪燒基、或聚氧仲貌基；p係〇或1，其限制條件爲當 R2係Η時p係〇 ;及η係於20至5〇〇之範圍内之一平均數目’其限制條件爲選擇R1、R2、及η以使分予量及於分子中之聚氧伸烷基鏈比烷基或烯基之重量比例可係於以上指疋之相關範圍之内。於由式（1)代表之此等化合物中，其中Rl係具有10至20 個碳原子之一種燒基、r2係Η或具有10至20個碳原子之一種燒*基、X代表或_COO-、及11係於至500 (特定本紙張尺度逍用中國國家榡準（as) Α4^_ (21〇><297公釐) 經濟部中央標準局貝工消費合作社印聚 416SS6 A7 _____ B7 五、發明説明（5 ) 言之30至300)之範圍之内之數目者，係較佳的。作爲本發明之增稠劑之其他實例’可5丨用由式（1’）代表之雙環氧化物與醇之加成產物之化合物。 R1-X-(C2H4〇)a-Y-[(C2H40)b-X- R1], (1，）其中R1及X係相同於以上定義者；a及b係彼此相同或相異，係20至500之平均數0 ; q係〇至3之數目；及γ代表經由開環而自雙環氧化物衍生之一種基。作爲經由開環而自雙環氧化物衍生由於式（Γ)中之γ代表之基之特定實例，可引用丁烷雙環氧化物、己烷雙環氧化物及乙烯基環己烯雙環氧化物。於由式（Γ)代表之此等化合物中，其中R1係具有10至20 個碳原子之一種烷基，X代表-0-或-COO-，γ代表自丁烷雙環氧化物、己烷雙環氧化物或乙烯基環己烯雙環氧化物經由其之開環而衍生之一種基，a及b係彼此相同或相異、係30至500 (特定言之30至300)之平均數目，及q係1 或2者，係較佳的。作爲於本發明中使用之增稠劑之特定實例，可引用 EM ANON 3115(商標，花王公司（Kao Corporation)之產物）（聚氧伸乙基單硬脂酸酯，分子量：825 ， E=2.1)、 EMANON 3130 (聚氧伸乙基單硬脂酸酯，分子量：1,500 ’ E=5.8)、EMANON 3170 (聚氧伸乙基單硬脂酸酯，分子量：3,300，E=13)、EMAN0N 3199 (聚氧伸乙基單硬脂酸酯，分子量：7,000，E=27) ' EMANON 11 12 (聚氧伸乙基單月桂酸酯，分子量：640，E=3.5 0)、EM ANON 1210 ( -8 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） „Γ|~；---©裝-----:—訂；------% (請先聞讀背面之注意事項再填寫本頁) A7 B7 418886 五、發明説明（6 ) 聚氧伸乙基單月桂酸酯，分子量：810 ， Ε=4·5)、 ΕΜΑΝΟΝ 3299 (聚氧伸乙基二硬脂酸酯，分子量：8,500 ,E=17)、EMULGEN 2200 (商標，花王公司之產物）（聚氧伸乙基鯨蠟基醚，分子量：7,〇〇〇，E=31)、EMULGEN220 (聚氧伸乙基鯨蠟基醚，分子量：800，Ε=3·5)及EMULGEN 3200 (聚氧伸乙基硬脂基醚，分子量：6,000 ，Ε=24)、 VISSURF S (商標，花王公司之產物）（EMULGEN 3200與乙烯基環己晞雙環氧化物之加成產物，分子量：1〇,〇〇〇至 20,000，E>30)、VISSURF CT (EMULGEN 2200 與乙晞基環己晞雙環氧化物之加成產物，分子量：20,000至30,000 ，Ε>30)° 以上提及之本發明之組合物之增稠劑係於分子中具有聚氧伸烷基鏈及烷基或烯基，以使加成至烷基或烯基之聚氧伸烷基具有大數目之莫耳之一種聚氧伸烷基加成物。當儲存組合物時，增铜劑抑制過氧化鼠之分解及因此使組合物能擅長於儲存安定性及減緩由於溫度改變而產生之黏度改變0 增稠劑可係於以重量計〇〇 1至1 〇 %，較佳地以重量計 0.1至10 %，及更佳地以重量計〇 · 1至5 %，之範圍内之數量組合於本發明之液體漂白劑組合物中。本發明之液體漂白劑組合物包含一種界面活性劑作爲一種主要成分。於本發明中使用之界面活性劑較佳地係選自包括陰離子界面活性劑、陽離子界面活性劑及非離子界面活性劑之至少一種。 9 * 尺度逋用中國國家標準（CNS ) Α4规格（210X297公釐 ,~|l· ；雙 Ί1Τ'------Q (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局男Η消費合作衽印製 A7 B7 416S86 五、發明説明（7 ) (請先閱讀背面之注意事項再填寫本頁) 作爲於本發明中使用之陰離子界面活性劑.之特定之實例，可引用烷基苯磺酸鹽類、烷基或烯基醚硫酸酯鹽類、燒基或晞基硫酸酯鹽類、α-烯烴磺酸鹽類、飽和或不飽和之脂肪酸鹽類、Ν-醯基胺基酸類型界面活性劑、烷基或烯基酿羧酸鹽類、胺基酸類型界面活性劑、及坑基或歸基磷酸酯鹽類。於彼等中，具有8至22個碳原子之烷基之烷基苯磺酸鹽類係特別較佳的。作爲於本發明中使用之陽離子界面活性劑之實例，由式 (4 )代表之化合物係較佳的。 r8 R6—N-R9 · B' (4) 其中R6、R7、R8及R9之至少一種代表具有6至20個碳原子之一種烷基或烯基及其餘每種代表具有1至3個碳原子之一種烷基或羥烷基；及f代表一種有機或無機陰離子。作爲由式（4)代表之化合物之實例，可引用下列化合物。416SS6 at ------ B7 V. Description of the invention (4) ~~ ~ -One ~ The subunit contains a polyoxyalkylene chain and an alkyl group or an alkenyl group, and has a molecular weight of more than 600, preferably It is located within the range of 10,000 to 3,000, and the condition that the weight ratio of the polyoxyalkylene chain to the alkyl or alkenyl group in the molecule is greater than .2 means that: (poly Oxyalkylene chain) / (alkyl or alkenyl) [hereinafter this quotient will be referred to as " E "] > 2, preferably e > 5. If the molecular weight of the thickener is less than 600, the thickener will not obtain a suitable viscosity. If the size of E is not greater than 2, the thickener will also not obtain a suitable viscosity. As a preferred example of the thickener in this specification, a compound represented by the formula (1) can be cited. R1-X-(C2H40) „-(c〇) p-R2 印 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs • 1 ^ 1 IT s II n nby I,, Ba Ze Please read the notes on the back first Fill out this page again} iw where R1 represents a linear or branched alkyl or fluorenyl group with 10 to 20 carbon atoms; R2 represents fluorene or a linear or branched sulfanyl group with 10 to 20 carbon atoms Or alkenyl; and X represents -0-, -COO-, -NR3-, or -CONR3-, wherein h represents an alkyl group having a carbon atom, a benzyl group, or a polyoxy secondary group; p Is 0 or 1, and the restriction is that p is 0 when R2 is Η; and η is an average number in the range of 20 to 500 ', and the restriction is that R1, R2, and η are selected so that The amount and the weight ratio of the polyoxyalkylene chain to the alkyl or alkenyl group in the molecule may be within the relevant range of the above-mentioned 疋. Among these compounds represented by formula (1), R1 has A calcined group of 10 to 20 carbon atoms, r2 is fluorene or a calcined group of 10 to 20 carbon atoms, X represents or _COO-, and 11 is up to 500 (specific paper size is not used in China Furniture standard (as) Α4 ^ _ (21〇 > < 297mm) The Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative Co., Ltd. 416SS6 A7 _____ B7 V. Description of Invention (5) (30 to 300) The number within the range is preferred. As another example of the thickener of the present invention, a compound of the addition product of a diepoxide and an alcohol represented by formula (1 ') can be used. R1-X- (C2H4〇) aY-[(C2H40) bX- R1], (1,) where R1 and X are the same as defined above; a and b are the same or different from each other, and are an average of 20 to 500 0; q And γ represents a radical derived from a biepoxide via ring opening. As a specific example of a radical derived from a biepoxide via ring opening due to the base represented by γ in formula (Γ), reference may be made Butane diepoxide, hexane diepoxide, and vinyl cyclohexene diepoxide. Among these compounds represented by the formula (Γ), R1 is an alkyl group having 10 to 20 carbon atoms, X Represents -0- or -COO-, γ represents the opening through butane diepoxide, hexane diepoxide or vinyl cyclohexene diepoxide. As a derived base, a and b are the same or different from each other, an average number of 30 to 500 (specifically 30 to 300), and q is 1 or 2, which are preferable. As used in the present invention Specific examples of the thickener used include EM ANON 3115 (trademark, a product of Kao Corporation) (polyoxyethylene ethylstearate, molecular weight: 825, E = 2.1), EMANON 3130 ( Polyoxyethylene monostearate, molecular weight: 1,500 'E = 5.8), EMANON 3170 (Polyoxyethylene monostearate, molecular weight: 3,300, E = 13), EMAN0N 3199 (polyoxyethylene) Base monostearate, molecular weight: 7,000, E = 27) 'EMANON 11 12 (Polyoxyethylene ethyl laurate, molecular weight: 640, E = 3.5 0), EM ANON 1210 (-8-paper size Applicable to China National Standard (CNS) A4 specification (210X297mm) „Γ | ~; --- © installed -----:-order; ------% (Please read the precautions on the back before reading (Fill in this page) A7 B7 418886 V. Description of the invention (6) Polyoxyethylene monolaurate, molecular weight: 810, Ε = 4.5.), ΕΜΑΝΝΝ 3299 (polyoxyethylene distearate, molecular : 8,500, E = 17), EMULGEN 2200 (trademark, product of Kao Corporation) (polyoxyethylene cetyl ether, molecular weight: 7,000, E = 31), EMULGEN220 (polyoxyethylene cetyl whale) Wax-based ether, molecular weight: 800, E = 3.5, and EMULGEN 3200 (polyoxyethylene ethyl stearyl ether, molecular weight: 6,000, E = 24), VISSURF S (trademark, product of Kao Corporation) (EMULGEN 3200) Addition product with vinylcyclohexamethylene diepoxide, molecular weight: 10,000 to 20,000, E > 30), VISSURF CT (EMULGEN 2200 and addition product of ethylcyclohexamethylene diepoxide, Molecular weight: 20,000 to 30,000, E > 30) ° The thickener of the composition of the present invention mentioned above has a polyoxyalkylene chain and an alkyl or alkenyl group in the molecule so that the addition to the alkyl or Alkenyl polyoxyalkylene has a large number of moles of a polyoxyalkylene adduct. When the composition is stored, the copper thickener inhibits the decomposition of peroxide rats and therefore enables the composition to excel at storage stability and slow down viscosity changes due to temperature changes. 0 Thickeners can be tied to An amount in the range of 10%, preferably 0.1 to 10% by weight, and more preferably 0.1 to 5% by weight, is combined in the liquid bleach composition of the present invention. The liquid bleach composition of the present invention contains a surfactant as a main ingredient. The surfactant used in the present invention is preferably at least one selected from the group consisting of an anionic surfactant, a cationic surfactant, and a nonionic surfactant. 9 * The scale adopts the Chinese National Standard (CNS) Α4 specification (210X297 mm, ~ | l ·; double Ί1Τ '-------- Q (Please read the precautions on the back before filling this page) Central Standard of the Ministry of Economic Affairs A7 B7 416S86 printed by the Bureau of the People's Republic of China 5. Description of the invention (7) (Please read the notes on the back before filling this page) As a specific example of the anionic surfactant used in the present invention, it can be cited Alkylbenzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or fluorenyl sulfates, α-olefin sulfonates, saturated or unsaturated fatty acid salts, N-fluorenyl Amino acid type surfactants, alkyl or alkenyl carboxylates, amino acid type surfactants, and pit or phosphonate salts. Among them, they have 8 to 22 carbon atoms. Alkyl alkylbenzene sulfonates are particularly preferred. As examples of the cationic surfactant used in the present invention, compounds represented by formula (4) are preferred. R8 R6—N-R9 B '(4) where at least one of R6, R7, R8 and R9 represents an alkyl or olefin having 6 to 20 carbon atoms And each representative of the remaining one alkyl or hydroxyalkyl group having 1-3 carbon atoms; and f represents an organic or inorganic anion as examples of representatives of compounds of the formula (4), the following compounds may be cited.

ChH2h+1-^H5-C2H5OS03- 一3_ ch3 . 經濟部中央標準局員工消費合作社印製ChH2h + 1- ^ H5-C2H5OS03- One 3_ ch3. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

I -10 本紙張尺度適用中國國家標準（CNS > A4规格（210X297公釐） 418SS6 A7 B7 五、發明説明（8 )I -10 This paper size applies to Chinese national standards (CNS > A4 size (210X297 mm) 418SS6 A7 B7 V. Description of invention (8)

CgH2g+i\^ CdH2d+〆 xh3 C2H40H 對甲苯磺酸陰離子鯉濟部中央樣準局員工消費合作衽印製其中h、g '及d係彼此相同或相異，係6至2〇之〆數目。作爲於本發明中使用之非離予界面活性劑之實例，可引用由式（2)代表之化合物。 R4-X-(AO)m.2 (2) 其中R4代表具有ό至22個碳原子之_種線性或分枝之烷基或浠基或用具有1至1 8個碳原子之—種線性或分枝之烷基視需要經取代之一種芳基；X係相同於以上定義；Α代表具有2或3個碳原子之一種線性或分枝之伸烷基；m個a 可係彼此相同或相異的；Z代表η或具有1至3個碳原子之一種烷基；及m係3至19之一平均數目。於式（2)中，R4較佳地係具有8至1 8個碳原子之一種烷基及X係-0- «>當A基代表伸乙基或伸丙基（較佳地分枝之伸丙基）時，彼等可係一種嵌段聚合者或一種無規聚合者。於本發明中使用之非離子界面活性劑之實例係表示於表 1中。 -11 衣紙張尺度適用中國國家標準（CNS )从規格（21〇x297公釐 ----„------裝--r 一, c (請先閱讀背面之注$項再填寫本頁) 416SB6 五、發明説明（9 )CgH2g + i \ ^ CdH2d + 〆 xh3 C2H40H p-toluenesulfonic acid anion Printed by the staff of the Central Bureau of Standards of the Ministry of Economics and Consumers, where h, g ', and d are the same or different from each other, and are the numbers of 6 to 20. As an example of the non-ionizing surfactant used in the present invention, a compound represented by the formula (2) can be cited. R4-X- (AO) m.2 (2) where R4 represents a linear or branched alkyl or fluorenyl group having between 6 and 22 carbon atoms or a linear having 1 to 18 carbon atoms Or an optionally substituted aryl group; X is the same as defined above; A represents a linear or branched alkylene group having 2 or 3 carbon atoms; m a may be the same as each other or Are different; Z represents η or an alkyl group having 1 to 3 carbon atoms; and m is an average number of 3 to 19. In the formula (2), R4 is preferably an alkyl group having 8 to 18 carbon atoms and X is 0-0 «> when the A group represents an ethylidene group or a propylidene group (preferably branched) In the case of propylene), they may be a block polymerizer or a random polymerizer. Examples of nonionic surfactants used in the present invention are shown in Table 1. -11 The size of the paper is applicable to the Chinese National Standard (CNS) from the specification (21 × 297 mm ---- -------- install --r a, c (please read the note $ on the back before filling in this Page) 416SB6 V. Description of Invention (9)

央標準 h 員工合作社印製表1 _. ♦雜子界面活性劑’ R4-X-(么0)m二多 R4 X___ A m ---—* - Z JV -c2h4- 1 to 19 rL '一 H ^ 1 0 Al2 1 C , -- -O- -C2H4- 3 to 19 丨一 H • 0- -c2h4- % to 19 一--— H 4-^^29 -0- -c2h4- 3 to 19 --------- H ("I 1 Ο M -5 7 -0 " -c2h4- 3 to 19 H C i 〇 H 7 1 -c2h4- ch3 Ci2h25 -0- -c2h4- ^ to 19 ^----1 --- cm c14h29 -0- -C2H4- -¾ to 19 ^ _ CH, C 16H3 3 -0- -C2H4- q to 19 CH, CiaH„ -0- -C2H4- 3 to 19 —·ί^^ CH, 於本發明之液體漂白劑組合物中，界面活性劑係以於以重量計0.1至5 0 %，較佳地以重量計0 · 5至3 0 %，及更佳地以重量計1至20 %，之範圍内之數量組合。液體漂白劑组合物係經由以重量計超過0.1 %之數量組合界面活性劑於其中而使其能獲得完全令人滿意之清潔性質。爲了避免增加组合物之黏度，界面活性劑之數量較佳係以重量計5 〇 %或以下。當必要時’本發明之液體漂白劑組合物可於其中組合一種漂白活性劑。 -12- 本紙張尺度適用中國國家鱗（CNS ) M規格（2似公褒） 416986 A7 B7 五、發明説明（10Central Standard h Employee Cooperative Printed Table 1 _. ♦ Heterosurfactant 'R4-X-(? 0) m Dito R4 X___ A m ---— *-Z JV -c2h4- 1 to 19 rL' 一H ^ 1 0 Al2 1 C,--O- -C2H4- 3 to 19 丨 a H • 0- -c2h4-% to 19 one --- H 4-^^ 29 -0- -c2h4- 3 to 19 --------- H (" I 1 Ο M -5 7 -0 " -c2h4- 3 to 19 HC i 〇H 7 1 -c2h4- ch3 Ci2h25 -0- -c2h4- ^ to 19 ^ ---- 1 --- cm c14h29 -0- -C2H4- -¾ to 19 ^ _ CH, C 16H3 3 -0- -C2H4- q to 19 CH, CiaH „-0- -C2H4- 3 to 19 — · ^^ CH, In the liquid bleach composition of the present invention, the surfactant is 0.1 to 50% by weight, preferably 0.5 to 30% by weight, and more preferably The amount is within a range of 1 to 20% by weight. The liquid bleach composition is obtained by combining surfactants in an amount of more than 0.1% by weight so that it can obtain completely satisfactory cleaning properties. In order to avoid increasing the viscosity of the composition, the amount of the surfactant is preferably 50% or less by weight. When necessary, the liquid bleaching of the present invention Wherein the composition may be in a combination of one kind of bleach activators. This paper -12- applies the Chinese national scale Scale (CNS) M size (2 might well praise) 416986 A7 B7 five described (10 invention

作爲於本發明中使用之漂白活化劑之實例’可引用由式 (3)代表之化合物。 W r5coo-As an example of the bleach activator used in the present invention, a compound represented by the formula (3) can be cited. W r5coo-

(3) 其中R5代表具有5至19個碳原子之一種線性或分枝之烷基或晞基；W代表-S03M或-COOM ;及]VI代表Η或一種有機或無機陽離子。作爲由式（3)代表之化合物之具體實例，可引用下列化合物0(3) wherein R5 represents a linear or branched alkyl or fluorenyl group having 5 to 19 carbon atoms; W represents -S03M or -COOM; and] VI represents fluorene or an organic or inorganic cation. As specific examples of the compound represented by the formula (3), the following compounds can be cited:

QHnCOOQHnCOO

-S〇3Na C7H15COO- -S〇3Na I----r-----裝-- (請先閱讀背面之注意事項再填寫本頁) 訂-S〇3Na C7H15COO- -S〇3Na I ---- r ----- pack-(Please read the precautions on the back before filling this page) Order

C9H19COOC9H19COO

S03NaS03Na

C11H23COOC11H23COO

S〇3Na 經濟部中央橾準局員工消費合作杜印製S〇3Na Consumption Co-operation by Employees of the Central Government Bureau of the Ministry of Economic Affairs

C13H27COOC13H27COO

C17H35COO.C17H35COO.

S〇3NaS〇3Na

S03NaS03Na

C15H31COOC15H31COO

SOsNa -13 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 41BS86 A7 B7 五、發明説明（11SOsNa -13 This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) 41BS86 A7 B7 V. Description of invention (11

C5H11COOC5H11COO

COONa C7H15COOCOONa C7H15COO

COONa C9H19COO-COONa C9H19COO-

COONa CnH23COOCOONa CnH23COO

COONaCOONa

C13H27COOC13H27COO

COONa C15H31C00-COONa C15H31C00-

COONaCOONa

C17H35COOC17H35COO

COONa C5HnC00- COOH C7H15COO-COONa C5HnC00- COOH C7H15COO-

COOH iCOOH i

C9H19COOC9H19COO

COOH C11H23COO-COOH C11H23COO-

COOH ,ί '#裝 -1訂^ . W (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 c13h27c〇oCOOH, ί '# 装 -1 定 ^. W (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs c13h27c〇o

COOH C15H31CO〇-COOH C15H31CO〇-

COOHCOOH

CnH35COOCnH35COO

COOH -14 本紙張尺度適用中國國家標率（CNS ) A4規格（210 X 297公釐） 418S86 A7 B7 白活化劑之數五、發明説明（12 組合於本發明之液體漂白劑組合物中之猫量較佳係於以重量計0>1至1〇0/〇之範園内。此外’本發明之液體漂白劑組合物可於其中組隔劑。可引用下列作爲錯隔劑之實例：鲭 ⑴基於磷酸之化合物諸如植酸或其之驗金屬鹽烷醇胺鹽類；〈 (2) 乙烷-1,1-二磷酸、乙烷三磷酸、ι_羥基亞乙基_ ι，ι-二磷酸、及其之衍生物，磷酸類諸如乙烷羥基三磷酸、乙晚-1，2-二羧基{2-二磷酸及甲燒羥基騰酸或其之驗金屬鹽類或其之燒醇胺鹽類； (3) 膦酸基羧酸類（phosphonocarboxylic acids)諸如 2_膦酸基丁烷-1，2-二甲酸' 1-膦酸基丁烷-2,3,4-三甲酸、及…甲基膦酸基琥珀酸或其之鹼金屬鹽類或其之烷醇胺鹽類； (4) 胺基酸類諸如天門冬胺酸、麩胺酸、及甘胺酸或其之鹼金屬鹽類或其之烷醇胺鹽類； (5) 胺基多乙酸諸如氮基三乙酸、亞胺基二乙酸、伸乙二胺四乙酸、二伸乙三胺五乙酸、乙二醇醚二胺四乙酸、幾乙基亞胺基二乙酸、三伸乙基四胺六乙酸、及金龜胺酸或其之鹼金屬鹽類或其之烷醇胺鹽類； (6) 有機酸諸如氧化二乙酸、氧基二琥珀酸、羧基子基氧基號拍酸、檸檬酸、乳酸、酒石酸、草酸、蘋果酸、葡萄庚酸、羧基甲基琥珀酸、及羧基甲基酒石酸或其之鹼金屬鹽類或其之烷醇胺鹽類； (7) 由沸石A代表之銘碎酸之驗金屬鹽類或燒醇胺鹽類；及 -15 本紙張尺度適用中國國家標準（CNS ) A4规格（2丨Ο X 297公釐） f諳先埤讀背面、意寧項再填寫本頁} 經濟部中央標準局員工消費合作社印製 S裝-----_—-ir-:-------------COOH -14 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 418S86 A7 B7 Number of white activators 5. Description of the invention (12 Cats combined in the liquid bleach composition of the present invention The amount is preferably within the range of 0 to 1/100/00 by weight. In addition, the liquid bleach composition of the present invention may be used as a spacer. The following can be cited as an example of the spacer: mackerel Phosphoric acid-based compounds such as phytic acid or its metal salt alkanolamine salts; <(2) ethane-1,1-diphosphate, ethanetriphosphate, ι_hydroxyethylene_ι, ι-di Phosphoric acid, and its derivatives, phosphoric acids such as ethane hydroxytriphosphate, aceto-1,2-dicarboxy {2-diphosphate and methylalcoholic acid or their metal salts or their alcohol amines Salts; (3) Phosphonocarboxylic acids such as 2-phosphonobutane-1,2-dicarboxylic acid '1-phosphonobutane-2,3,4-tricarboxylic acid, and ... Methylphosphonic acid succinic acid or its alkali metal salts or its alkanolamine salts; (4) amino acids such as aspartic acid, glutamic acid, and glycine or their Alkali metal salts or their alkanolamine salts; (5) Amino polyacetic acids such as nitrogen triacetic acid, iminodiacetic acid, ethylenediaminetetraacetic acid, ethylenediaminetripentaacetic acid, ethylene glycol Etherdiaminetetraacetic acid, chinethyliminodiacetic acid, triethylenetetraaminehexaacetic acid, and chelamine acid or its alkali metal salts or its alkanolamine salts; (6) organic acids such as Oxidized diacetic acid, oxydisuccinic acid, carboxyloxyoxy acid, citric acid, lactic acid, tartaric acid, oxalic acid, malic acid, grape heptanoic acid, carboxymethylsuccinic acid, and carboxymethyltartaric acid or its base Metal salts or their alkanolamine salts; (7) Metal salt or burned alcohol amine salts of incisive acid represented by zeolite A; and -15 The paper size applies to Chinese National Standard (CNS) A4 specifications (2 丨〇 X 297 mm) f 谙 Read the back and the item “I-Ning” before filling out this page} Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ------------ ir-: --- ----------

416S86 ---- 五、發明説明（13 ) (8)胺基聚（亞甲基磷酸）或其之鹼金屬鹽類或其之烷醇胺鹽類、或聚乙烯聚胺聚（亞甲基磷酸）或其之鹼金屬鹽類或烷醇胺鹽類。％於以上引用之此等錯隔劑中，較佳地使用選自包括以上提及之（2)、（5)、（6)、及（7)之化合物之至少—種化合物及更佳地使用選自包括以上提及之（2)之化合物之至少一種化合物。以本發明之液體漂白劑组合物爲基準，组合之錯隔劑之數量係於以重量計0.0005至5 %(較佳地以重量計〇〇1至夏 %)之範固内。除了以上提及之成分以外，本發明之液體漂白劑組合物於其中可組合任何之熟知之添加劑。可使用，例如，增滌劑如水溶性之無機增滌劑諸如硫酸鹽、碳酸鹽、碳酸氫鹽、砂酸鹽、及磷酸鹽。可使用鎂鹽諸如硫酸鎂、矽酸鎂、氣化鎂、梦氟化鎂、氧化鎂及氫氧化鎂及矽酸鹽諸如梦酸鈉作爲過氧化物或過氧化氫加成物之安定劑。液體漂白劑組合物，當必要時，可於其中另外包含避免再污染之一種藥劑，諸如，例如，羧甲纖維素、聚乙烯基吡咯啶酮，或聚乙二醇。本發明之液體漂白劑組合物基本上具有以上提及之主要成分及另外以上提及溶解或分散於水中之選用之成分。爲了於低溫度安定化溶液，改良自一種冷凍狀態，恢復之能力 '或防止溶液於高溫度分離之目的，於其中可组合一種增溶劑。可引用由甲苯磺酸鹽類及二甲苯磺酸鹽類代表之 -16 私紙張尺度適用巾關家辟（CNS )八4遞_ ( 21()><297公楚 !---@ 裝 (請先聞讀背面之注意事項再填寫本頁) -訂 —:)脉 _ 經濟部中央標準局員工消費合作社印製 A7 B7 416S86 五、發明説明（14 短鏈烷基苯磺酸鹽類及由乙醇、乙二醇、丙二醇、己二醇、及丙三醇代表之醇類及多糾類’作爲増溶劑之實例。以組合物爲基準，增溶劑可係以於以重量計〇至3〇%之範圍内之數量组合於本發明之液體漂白劑組合物中。本發明之液體漂白劑組合物可於其中另外組合各種化合物諸如，例如，以過氧化氫之—種安定劑知曉之磷酸、巴比妥酸、尿酸'乙醯胺苯、由氧化喳啉代表之胺基多羧酸及乙氧乙醯胺苯及DL-α-生育酚、五倍子酸衍生物、丁基化之羥基苯基甲基醚（BHA)、及2,6_二_第三_丁基_4_甲基酚 (BHT)。添加之安定劑之數量雖然隨著過氡化氫之濃度而可變動，但是以本發明之組合物之數量爲基準，通常係於以重量計0至5 %(較佳地以重量計〇〇1至3 %)之範圍内。此外，本發明之液體漂白劑組合物可另外包含任何之各種熟知之物質諸如，例如，由苯基丙胺酸、組胺酸、離胺酸、甲狀腺素及甲硫胺酸代表之胺基酸類及胺基酸鹽類；由羥基亞胺基二乙酸代表之胺基或亞胺基化合物；及丙缔腈與至少一種可與丙烯腈共聚合之含第四銨基之單體之共聚物作爲避免變色之一種藥劑。偶然地，光學異構物係^ 在於胺基酸中。本發明之效應係與此等光學異構物無關。因此，容許本發明之液體漂白劑組合物使用化學合成之基酸。爲了強化對於白色纖維之漂白效應之目的，本發明之液體漂白劑組合物可於其中組合一種螢光增白劑。添加之螢光增白劑之數量係於以重量計〇至5 %之範園内。可引用 17 私纸張尺度適用中國國家標準（CNS ) A4規格（210χ297公楚） Iί I—-7---® 裝-----丨訂"------Q (諳先聞讀背面之注意事項再填寫本頁) 經濟部中央標率局員工消費合作社印製416S86 ---- V. Description of the invention (13) (8) Amine poly (methylene phosphate) or its alkali metal salts or its alkanolamine salts, or polyethylene polyamine poly (methylene Phosphoric acid) or its alkali metal salts or alkanolamine salts. % Among these spacers cited above, it is preferable to use at least one compound selected from the compounds including (2), (5), (6), and (7) mentioned above and more preferably At least one compound selected from the compounds including the above-mentioned (2) is used. Based on the liquid bleach composition of the present invention, the amount of the spacers combined is within the range of 0.0005 to 5% by weight (preferably 0.001 to summer% by weight). In addition to the above-mentioned ingredients, the liquid bleach composition of the present invention may be combined with any well-known additives therein. There can be used, for example, a detergent such as a water-soluble inorganic detergent such as sulfate, carbonate, bicarbonate, oxalate, and phosphate. Magnesium salts such as magnesium sulfate, magnesium silicate, magnesium gasification, magnesium magnesium fluoride, magnesium oxide and magnesium hydroxide, and silicates such as sodium dreamate can be used as stabilizers for peroxides or hydrogen peroxide adducts. The liquid bleach composition may, if necessary, additionally contain an agent to prevent recontamination, such as, for example, carmellose, polyvinylpyrrolidone, or polyethylene glycol. The liquid bleach composition of the present invention basically has the above-mentioned main ingredients and additionally the above-mentioned optional ingredients dissolved or dispersed in water. In order to stabilize the solution at a low temperature, improve the ability to recover from a frozen state, or prevent the solution from separating at a high temperature, a solubilizer can be combined therein. Can be cited as represented by toluene sulfonates and xylene sulfonates. -16 Private paper size applicable towels Guan Jiapi (CNS) 8 4 delivery_ (21 () > < 297 公楚! --- @ (Please read the precautions on the back before filling out this page) -Order— :) Pulse _ Printed by A7 B7 416S86, Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy And alcohols and polyphenols represented by ethanol, ethylene glycol, propylene glycol, hexanediol, and glycerol as examples of hydrazone solvents. Based on the composition, the solubilizer may be based on 0 to The amount in the range of 30% is combined in the liquid bleach composition of the present invention. The liquid bleach composition of the present invention may further be combined therein with various compounds such as, for example, known as a stabilizer of hydrogen peroxide Phosphoric acid, barbituric acid, uric acid 'acetamidobenzene, amine polycarboxylic acids and ethoxyacetamidobenzene and DL-α-tocopherol, gallic acid derivatives, butylated hydroxyl groups Phenyl methyl ether (BHA), and 2,6_di_third_butyl_4_methylphenol (BHT). Among the added stabilizers Although the amount varies with the concentration of hydrogen peroxide, it is usually based on the amount of the composition of the present invention, and is usually 0 to 5% by weight (preferably 0.01 to 3% by weight). In addition, the liquid bleach composition of the present invention may additionally contain any of a variety of well-known substances such as, for example, represented by phenylalanine, histamine, lysine, thyroxine, and methionine Amino acids and amino acid salts; amine or imine compounds represented by hydroxyimino diacetic acid; and acrylonitrile and at least one monomer containing a fourth ammonium group which can be copolymerized with acrylonitrile Copolymers are used as an agent to avoid discoloration. Occasionally, the optical isomers are in amino acids. The effect of the present invention is not related to these optical isomers. Therefore, the liquid bleach composition of the present invention is allowed to be used Chemically synthesized base acid. For the purpose of enhancing the bleaching effect on white fibers, the liquid bleaching composition of the present invention may be combined with a fluorescent whitening agent. The amount of the fluorescent whitening agent added is based on weight 〇 to 5% In the park, 17 private paper sizes can be cited. Applicable to China National Standard (CNS) A4 specification (210 × 297). I I—-7 --- ® Packing ----- 丨 Order " ------ Q ( (闻 Please read the notes on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

經濟部中央樣準局員工消費合作社印I 4169S6 A7 ______________B7 五、發明説明（15 )Printed by the Consumer Procurement Cooperative of the Central Sample Bureau of the Ministry of Economic Affairs I 4169S6 A7 ______________B7 V. Description of Invention (15)

Tin0pal CBS (商標，汽巴嘉基公司（Ciba Geigy)之產品）、 Tin〇PalSWN、及色指數螢光增白劑28、4〇、“及^作爲螢光增白劑之實例。本發明之液體漂白劑組合物可於其中另外組合著色劑諸如染料及顏料及輔助之添加劑諸如殺菌劑、紫外線吸收劑及無機電解質（例如、NaCl、Na2S04、及CaCl2)，各別地於以重量計0至2 %之近似範園之内。染料較佳地係具有於酸性溶液中抿抗過氧化氫之能力之酸染料。 ©對於強化&白容量之目的係必要時，本發明之組合物可於其中另外组合任何之熟知之酵素諸如，例如，纖維素酶、澱粉酶、蛋白酶、或脂酶。自於過氧化氫之存在下儲存安定性之觀點看，本發明之液體漂白劑組合物較佳地具有維持於6或以下（較佳地3.5 或以下）之pH値。pH値之調節較佳地係經由使用—種無機酸諸如硫酸或鱗酸或一種有機酸諸如甲苯績酸或笨績酸、經由添加錯隔劑或以上提及於一種酸之形式之陰離子界面活性劑、或視需要經由使用一種苛性鹼諸如氳氧化納或氫氧化鉀而達成。以本發明之液體漂白劑組合物漂白衣服可係經由直接地塗佈組合物於衣服、容許其靜置於衣服上歷時1〇至3〇分鐘、然後經由用水清洗而將其自衣服移除或經由製備組合物於自來水中之水溶液及將衣服沈浸於水溶液中而達成。本發明之液體漂白劑組合物可係與習用之衣服級清潔劑混合使用。 -18 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項存填寫本頁)Tin0pal CBS (trademark, product of Ciba Geigy), TinOPalSWN, and color index fluorescent whitening agents 28, 40, "and ^ are examples of fluorescent whitening agents. The liquid bleach composition may further be combined therein with colorants such as dyes and pigments and auxiliary additives such as fungicides, ultraviolet absorbers, and inorganic electrolytes (eg, NaCl, Na2S04, and CaCl2), individually from 0 to Within the range of 2%. The dye is preferably an acid dye having the ability to resist hydrogen peroxide in an acidic solution. © For the purpose of strengthening & white capacity, the composition of the present invention can be used in Among them, any well-known enzyme such as, for example, cellulase, amylase, protease, or lipase is further combined. From the viewpoint of storage stability in the presence of hydrogen peroxide, the liquid bleach composition of the present invention is preferred. The ground has a pH 値 maintained at 6 or lower (preferably 3.5 or lower). The pH 値 is preferably adjusted by using an inorganic acid such as sulfuric acid or phosphonic acid or an organic acid such as toluene or stupid. Achieved by adding a spacer or an anionic surfactant mentioned above in the form of an acid, or if necessary by using a caustic such as sodium hydroxide or potassium hydroxide. Bleaching with the liquid bleach composition of the present invention The clothes may be by directly applying the composition to the clothes, allowing them to rest on the clothes for 10 to 30 minutes, and then removing them from the clothes by washing with water or by preparing an aqueous solution of the composition in tap water and This is achieved by immersing clothes in an aqueous solution. The liquid bleach composition of the present invention can be mixed with conventional clothes-grade cleaners. -18-This paper size applies to China National Standard (CNS) A4 (210X297 mm) ( (Please read the precautions on the back and fill in this page)

經濟部中央標準局貝工消費合作社印製 416886 5 五、發明説明（16 ) 實例現在以實例敘述本發明。本發明係不受限於此等實例° 實例1至12及比較實例1至9 : 於表2及3中指示之液體漂白劑組合物係經由使用過氧化氫、於工作實例中之下列增稠劑（b-Ι)至（b_6)或於比較實例中之下列增稠劑（b，-l)至（b，-5)、下列漂白活化劑（d-Ι)至 (d-2)、及下列錯隔劑（e-Ι)而製備。 •增稠劑 EMANON 3 170 (由花王公司製造） (聚氧伸乙基單硬脂酸酯，分子量： 3,300 ，E = 13) (b-1) ΕΜΑΝ0Ν 3199 (由花王公司製造） (聚氧伸乙基單硬脂酸酯，分子量： 7,000 ，E=27) (b；2) EMANON 1112 (由花王公司製造） (聚氧伸乙基單月桂酸酯，分子量： 640， E=3.5) (b-3) EMULGEN 2200 (由花王公司製造） (聚氧伸乙基鯨蠟基醚，分子量：7: ;000， E=3 1) (b-4) VISSURF S (由花王公司製造） (b-5) (EMULGEN 3200與乙烯基環己烯雙環氧化物之加成產物，分子量·· 10,000 JL 20,000，E>30) VISSURF CT (由花王公司製造） (b.6) (EMULGEN 2200與乙烯基環己烯雙環氧化物之加成產物，分子量：20,000 至 30,000，E>30) 〇 CARBOPOL ETD 2691 (b'-l) (由BF固德里奇公司（BF Goodrich Co.)製造） -19- 本紙張尺度適用中國國家標準（CNS ) A4规格（210Χ：Ϊ97公釐） — l· —---@裝丨- (讀先閱讀背面之注意事項再填寫本頁) 訂 416SS6 A7 B7 五、發明説明（17 (以聚丙晞酸爲主之聚合物）黃酸樹膠硬脂醇與10莫耳之環氧乙烷（E0)之加成物 (分子量：710，E=1.8) 乙醇與11莫耳之EO之加成物 (分子量：530，Ε=17·3) 聚乙二醇 (分子量：8,000，Ε=0) •界面活惟劑烷基（於烷基中含12個碳原子）苯磺酸鹽硫酸Ν-十四基-Ν,Ν-二甲基-Ν-乙基銨 c12h25〇(c2h4〇)4-h c12h25〇(c2h4〇)8-h •漂白活化劑 (b'-2) (b'-3) (b'-4) (b'-5) (^-1)(c，2) (c-3) (c-4)Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 416886 5 V. Description of the Invention (16) Examples The invention will now be described with examples. The present invention is not limited to these examples. Examples 1 to 12 and Comparative Examples 1 to 9: The liquid bleach compositions indicated in Tables 2 and 3 were thickened by using hydrogen peroxide as follows in the working examples. Agents (b-1) to (b-6) or the following thickeners (b, -l) to (b, -5), the following bleach activators (d-1) to (d-2), And the following spacers (e-1). • Thickener EMANON 3 170 (manufactured by Kao Corporation) (Polyoxyethylene ethylstearate, molecular weight: 3,300, E = 13) (b-1) ΕΜΑΝΝ 3199 (manufactured by Kao Corporation) (Polyoxygen) Ethyl monostearate, molecular weight: 7,000, E = 27) (b; 2) EMANON 1112 (manufactured by Kao Corporation) (polyoxyethylene ethyl laurate, molecular weight: 640, E = 3.5) (b -3) EMULGEN 2200 (manufactured by Kao Corporation) (polyoxyethylene cetyl ether, molecular weight: 7:; 000, E = 3 1) (b-4) VISSURF S (manufactured by Kao Corporation) (b- 5) (Addition product of EMULGEN 3200 and vinyl cyclohexene diepoxide, molecular weight · 10,000 JL 20,000, E > 30) VISSURF CT (manufactured by Kao Corporation) (b.6) (EMULGEN 2200 and vinyl ring Addition product of hexene diepoxide, molecular weight: 20,000 to 30,000, E > 30) CARBOPOL ETD 2691 (b'-l) (manufactured by BF Goodrich Co.) -19- Standards are applicable to China National Standard (CNS) A4 specifications (210 ×: Ϊ97 mm) — l · —--- @ 装丨-(Read the precautions on the back before filling this page) 416SS6 A7 B7 V. Description of the invention (17 (Polyacrylic acid-based polymer) adduct of xanthan gum stearyl alcohol and 10 mol ethylene oxide (E0) (molecular weight: 710, E = 1.8 ) Addition of ethanol and 11 moles of EO (Molecular weight: 530, E = 17 · 3) Polyethylene glycol (Molecular weight: 8,000, E = 0) • Interfacial active agent alkyl (containing 12 in the alkyl group) Carbon atoms) besylate sulfate N-tetradecyl-N, N-dimethyl-N-ethylammonium c12h25〇 (c2h4〇) 4-h c12h25〇 (c2h4〇) 8-h • bleach activator (b'-2) (b'-3) (b'-4) (b'-5) (^ -1) (c, 2) (c-3) (c-4)

CsHnCOOCsHnCOO

S03Na (d-1) 11. 'Π3 裝 -1 訂 ^ ^ )^, (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製〇πίΪ23〇00S03Na (d-1) 11. 'Π3 Pack -1 Order ^ ^) ^, (Please read the notes on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 〇πίΪ23〇00

S03Na (d-2) •錯隔劑 1-羥基亞乙基-1,1-二膦酸 (由日本孟山都公司（Japan Monsanto K.K.)製造及以 ”Diquest 2010"之商標名稱銷售）（e-1) -20- 本紙張尺度適用中國國家標準（CNS ) A4规格（2丨0X297公釐） 418886 A7 B7 五、發明説明（18 ) 最後獲得之液體漂白劑組合物係經由下列方法而試驗過氧化氫之安定性及黏度。結果係於表2及3中表示。 <測定過氧化氫之安定性之方法> 一種指定之液體漂白劑組合物，於在表2及3中表示之條件下儲存之前及之後，係用一種標準N過錳酸水溶液滴定，以測定有效氧。過氧化氫之安定性係根據下列式計算。過氧化氫之安定悻（％ ) (於儲存後之有效氧） (於儲存前之有效氧） 100 <測定黏度之方法> 一種指定之液體漂白劑組合物係經由使用一種黏度計（由東京計量器公司（Tokyo Keiki K.K.)製造及以"類型B"之產品號碼銷售）而測定於10°〇、20°(：、及30°(：之黏度。由於自20 °C至30 °C之溫度改變而產生之黏度改變之比率係根據下列式計算。結果係於表2及3中表示。 |黏度(30。0 -黏度(20。〇| 黏度(30 °C) J---------Q 裝-- (請先聞讀背面之注意事項再填寫本頁) 訂經濟部中央標準局員工消費合作社印製 -21 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 416S86 A7 B7 五、發明説明（19 經濟部中央摇準局員工消費合作社印装 fN< 實例. ： 1· 1 ο 1 o oo K o 1—( o 餘額 CN Ο m 〇〇0 99.9 CN rn m cn m ^0 o o ο o o 寸 o o 餘額〇 CN ο in 〇〇〇 I 99.9 I 寸寸 o 寸 o o 1-H o 寸〇 - 1—( o 餘額 in Cn| Ο to 〇〇〇〇\ 〇\ σ\ ,481 | 452 411 o ^—i o in *n o o <N t-H o 餘額 ο CN Ο 〇〇〇 99.9 | 280 256 235 0.09 <N to CN ' 0 1 < o 寸 o 餘額 ο tn 〇〇〇 99.9 v〇 cs in Ο in 寸 o o cst o o (N ΐ-Η o 餘額 2.0 ο 〇 QC [99.9 | CN oo c<\ o 氫氧化氫 ¥-H r 1 b-2 cn 1 Xi b-4 1 Xi CN 1 1 ϋ CN 1 O 1 1 O 寸 r O 1 1 χί Ψ—H 1 1 去離子水 * 溫度（°c) 濕度（％) 過氧化氫之安定性（％) 10 Ό 20 °C 3 0 °C 黏度¢20 °C)| 〇 Π： CL 黏度（毫帕秒） 1 黏度(30 儲存之條件 1 黏度(30 °C) 鲱 W 41 審 ( f&iT -Jtp ) -22- 本紙張尺度適用中國國家標準（CNS ) A4規格UIOX 297公釐了 (請先聞讀背面之注意事項再填寫本頁)S03Na (d-2) • Separator 1-hydroxyethylene-1,1-diphosphonic acid (manufactured by Japan Monsanto KK and sold under the trademark name "Diquest 2010 ") (e-1 ) -20- This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) 418886 A7 B7 V. Description of the invention (18) The final liquid bleach composition obtained was tested for hydrogen peroxide by the following method The stability and viscosity. The results are shown in Tables 2 and 3. < Method for measuring the stability of hydrogen peroxide > A specified liquid bleach composition is stored under the conditions shown in Tables 2 and 3. Before and after, it was titrated with a standard N permanganic acid aqueous solution to determine the available oxygen. The stability of hydrogen peroxide was calculated according to the following formula. The stability of hydrogen peroxide (%) (available oxygen after storage) ( Available oxygen before storage) 100 < Method for measuring viscosity > A specified liquid bleach composition is prepared by using a viscometer (manufactured by Tokyo Keiki KK) and " type B " Product number sales The viscosity measured at 10 °, 20 ° (:, and 30 ° (:). The ratio of viscosity change due to temperature change from 20 ° C to 30 ° C is calculated according to the following formula. The results are shown in Table 2. And 3. | Viscosity (30.0-Viscosity (20.〇 | Viscosity (30 ° C) J --------- Q Pack-(Please read the precautions on the back before filling in this Page) Order printed by the Central Consumers ’Cooperative of the Ministry of Economic Affairs -21-This paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm) 416S86 A7 B7 V. Description of Invention Cooperative printed fN < Example .: 1 · 1 ο 1 o oo K o 1— (o balance CN 〇 m 〇〇0 99.9 CN rn m cn m ^ 0 oo ο oo inch oo balance 〇CN ο in 〇〇〇I 99.9 I inch inch o inch oo 1-H o inch 〇- 1— (o balance in Cn | 〇 to 〇〇〇〇 \ 〇 \ σ \, 481 | 452 411 o ^ —io in * noo < N tH o balance ο CN 〇〇〇〇99.9 | 280 256 235 0.09 < N to CN '0 1 < o inch o balance ο tn 〇〇〇99.9 v〇cs in Ο i n inch oo cst oo (N ΐ-Η o balance 2.0 ο 〇QC [99.9 | CN oo c < \ o hydrogen hydroxide ¥ -H r 1 b-2 cn 1 Xi b-4 1 Xi CN 1 1 ϋ CN 1 O 1 1 O inch r O 1 1 χ— 1—H 1 1 deionized water * temperature (° c) humidity (%) stability of hydrogen peroxide (%) 10 Ό 20 ° C 3 0 ° C viscosity ¢ 20 ° C) | 〇Π: CL viscosity (mPas) 1 Viscosity (30 Storage conditions 1 Viscosity (30 ° C) Herring W 41 Examination (f & iT -Jtp) -22- This paper size applies to Chinese national standards (CNS ) A4 size UIOX 297mm (Please read the precautions on the back before filling in this page)

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本紙張尺度逋用中國國家標準（CNS ) A4规格（21〇X2.97公釐） 416S86 at B7 五、發明説明（21 ) π ΟΙ 1.0 ΓΟThe size of this paper adopts Chinese National Standard (CNS) A4 specification (21.0 × 2.97 mm) 416S86 at B7 V. Description of invention (21) π ΟΙ 1.0 ΓΟ

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93.CO 000 50 2,5 漆趙 0.1 1.0 〇〇·0 1.0 2_o 本紙張尺度適用中國國家標準（CNS ) Α4规格（210 X 297公釐） 25- 416S86 A7 B7 五、發明説明（23 ) 餑谇(30。8 |龄碎(30 DC)-齡碎(20 DC) ft 0 邀命芽 \/ 14 H® % 300 200 lori 銨淖(％) 如费^^ rt— . d丨2 d_l c-4- flll c-to! b-λ α·ί,·:ϊ5ι b.~3 b-6 b-593.CO 000 50 2,5 Qi Zhao 0.1 1.0 〇 · 0 1.0 2_o This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 25- 416S86 A7 B7 V. Description of the invention (23) 饽谇 (30. 8 | Age-breaking (30 DC)-Age-breaking (20 DC) ft 0 Inviting buds // 14 H®% 300 200 lori Ammonium hydrazone (%) as fee ^^ rt—. D 丨 2 d_l c -4- flll c-to! B-λ α · ί, ·: ϊ5ι b. ~ 3 b-6 b-5

II IUb IL 請先閲讀，背之注意事項再頁 0.62 13 100 900.3 000 50 2.5 傘数 0.1 P5 0_5 0-87 15 28 32 92‘1 000 50 2.5 #湓 0:1 P5 0,5 10 71 7 19 31 92」 80 50 3.5 .1 經濟部中夬標準局員工消費合作社印製 0.15 20 39 90.2 000 50 2.5 傘盌 -.1 0.5 P5 本紙張尺度適用中國國家操準（CNS > A4規格（210X297公釐） -26- 416886五、發明説明（ A7 B7 24 註）* : pH値係用N硫酸調節。自表2及3之結果清礎地注意到，本發明之液體漂白劑組合物顯示由於溫度改變而產生之僅小之黏度改變，而比較實例之液體漂白劑组合物未顯示強化黏度之訊息或顯示由於溫度改變而產生之顯著之黏度改變。亦注意到，本發明之液體漂白劑組合物顯示完美之過氧化氫安定性，而於比較實例中使用之增稠劑分解過氧化氫。 (請先閎讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -27- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）II IUb IL Please read it first, note on the back 0.62 13 100 900.3 000 50 2.5 Number of umbrellas 0.1 P5 0_5 0-87 15 28 32 92'1 000 50 2.5 # 湓 0: 1 P5 0,5 10 71 7 19 31 92 "80 50 3.5 .1 Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 0.15 20 39 90.2 000 50 2.5 Umbrella bowl -.1 0.5 P5 This paper size is applicable to China National Standards (CNS > A4 size (210X297) (%) -26-416886 V. Description of the invention (A7 B7 24 Note) *: The pH is adjusted with N sulfuric acid. From the results of Tables 2 and 3, it is clearly noted that the liquid bleach composition of the present invention shows The change resulted in only a small change in viscosity, while the liquid bleach composition of the comparative example did not show a message of enhanced viscosity or showed a significant change in viscosity due to a change in temperature. It was also noted that the liquid bleach composition of the present invention It shows perfect hydrogen peroxide stability, and the thickener used in the comparative example decomposes hydrogen peroxide. (Please read the notes on the back before filling this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-27 -This paper is of suitable size Use Chinese National Standard (CNS) A4 specification (210 X 297 mm)

Claims

A8 B8 C8 弟8611:382號專利申請案申請專利範圍修正本(88年I2月）丄申請專利範圍A8 B8 C8 Patent Application No. 8611: 382 Amendment to the scope of patent application (I-88 in February) 范围 Scope of patent application

4 本 416986 "^irr f具有強化黏度之液體漂白劑組合物，其包含1〜i 〇重量％之過氧化氫、0.01〜10重量％之增稠劑及.0.1〜 5〇重量％之選自包括陰離子界面活性劑' 陽離子界面活性劑及非離子界面活性劑之至少一種之界面活性劑，其於3 0 C顯示於1 〇至1，〇〇〇毫帕抄之範圍内之黏度，其特徵為該增稠劑係由下式（1)或（1，）所示之聚氧化乙烯化合物： R1 - X - (C2H40)n - (CO)p - R2 (1) 其中R代表具有1 〇至2 0個碳原子之一種線性或分枝之晚基或缔基；R2代表Η或具有1〇至20個碳原子之線性或分枝之燒基或烯基；X代表_〇_、-COO-、-NR3-、或 -CONR3- ’其中R3代表Η，具有1至3個碳原子之烷基、經烷基或聚氧伸烷基；ρ係〇或i，其限制條件為當 R2係Η時p係〇 ; η係20至500之平均數目，其限制條件為選擇R1、R2、及η以使分子量及於分子中之該聚氧伸fe基鏈相對烷基或烯基之重量比可於以上指定之相關範園之内； RI-X-(C2H40)a-Y-[(C2H4〇)b-X. R1],, (Γ) 式中，R1及X係相同於以上定義者；a及b係彼此相同或相異，係20至500之平均數目；q係〇至3之數目；及Y代表經由開環而自雙環氧化物獲得之一種基。 2.根據申請專利範圍第丨項之組合物，其中於3 〇 t之該黏度係於1 0至5 0 0毫帕秒之範圍内。 3 ·根據申請專利範圍第丨項之組合物，其中該界面活性劑 —?—„-----------訂. (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標隼局貞工消費合作社印¾4 of this 416986 " ^ irr f liquid bleaching composition with enhanced viscosity, which contains 1 to 10% by weight of hydrogen peroxide, 0.01 to 10% by weight of thickener and .0.1 to 50% by weight of the choice A surfactant including at least one of an anionic surfactant, a cationic surfactant and a non-ionic surfactant, which exhibits a viscosity at 30 C in the range of 10 to 1,000 mPascals, which It is characterized in that the thickener is a polyethylene oxide compound represented by the following formula (1) or (1,): R1-X-(C2H40) n-(CO) p-R2 (1) wherein R represents 1 〇 A linear or branched late or alkenyl group of 20 to 20 carbon atoms; R2 represents fluorene or a linear or branched alkyl or alkenyl group having 10 to 20 carbon atoms; X represents _〇_,- COO-, -NR3-, or -CONR3- 'where R3 represents Η, an alkyl group having 1 to 3 carbon atoms, an alkyl group or a polyoxyalkylene group; ρ is 0 or i, and the limitation is that when R2 In the case of p, 0 is an average number; η is an average number of 20 to 500, and the limiting condition is that R1, R2, and η are selected so that the molecular weight and the polyoxygen chain in the molecule are extended. The weight ratio to alkyl or alkenyl can be within the range specified above; RI-X- (C2H40) aY-[(C2H4〇) bX. R1] ,, (Γ) where R1 and X are The same as defined above; a and b are the same or different from each other and are an average number of 20 to 500; q is a number of 0 to 3; and Y represents a radical obtained from a bisepoxide via ring opening. 2. The composition according to item 丨 of the patent application range, wherein the viscosity at 300 t is in the range of 10 to 500 mPas. 3 · The composition according to item 丨 of the scope of patent application, in which the surfactant-?-"------------ order. (Please read the precautions on the back before filling this page) Economy Printed by Zhengong Consumer Cooperative of the Ministry of Standards of the People's Republic of China ¾

> 16B86申請專利範圍 A8 B8 C8 D8 係由式(2)代表之非離子界面活性劑： 4 R "X^A0)m_z (2) 其中R代.表具有6至22個碳原子.之線性或分枝之烷基或烯基或視需要經具有}至【8個碳原子之線性或分枝之烷基取代3之芳基；X代表·〇_ <〇〇 nr3、或wo服L ’其中a K表具有i至3個碳原子之烷基羥烷基或聚氧伸烷基，A代表具有2或3個碳原子之線性或分枝之伸 k·基，m個A可彼此相同或相異；z代表H或具有i至 3個碳原子之烷基；及m代表3至19之平均數目。 ‘根據申叫專利範圍第丨項之組合物，其另外包含一種漂白活化劑。 5.根據申請專利範圍第4項之組合物，其中該漂白活化劑係由式（3)代表之一種化合物：輕濟部中夫接準局IΗ消費合作社印製其中R5代表具有5至1 9個碳原子之線性或分枝之烷基或烯基；W代表_s〇3M或-COOM ;及Μ代表η或有機或無機陽離子。 6 ·根據申請專利範圍第1項之組合物，其另外包含一種錯隔劑。 . 7·根據申請專利範圍第1項之組合物，其中黏度隨著自20 C至30 t：之溫度以0_60或以下之比率改變，如根據下列式： -2 私紙張从適用中固國) A娜（210Χ297ϋ) (請先閲讀背面之注意事項再填寫本頁}> 16B86 patent application range A8 B8 C8 D8 is a non-ionic surfactant represented by formula (2): 4 R " X ^ A0) m_z (2) where R represents. The table has 6 to 22 carbon atoms. Linear or branched alkyl or alkenyl groups or aryl groups substituted with a linear or branched alkyl group having} to [8 carbon atoms as necessary; 3 represents X; 〇_ < 〇〇nr3, or wo L 'where a K represents an alkylhydroxyalkyl or polyoxyalkylene group having i to 3 carbon atoms, A represents a linear or branched elongation k · group having 2 or 3 carbon atoms, and m A may be Are the same or different from each other; z represents H or an alkyl group having i to 3 carbon atoms; and m represents an average number of 3 to 19. ‘The composition according to claim 1 of the claim, further comprising a whitening activator. 5. The composition according to item 4 of the scope of patent application, wherein the bleach activator is a compound represented by formula (3): printed by Zhongfu Access Bureau of the Ministry of Light Industry, IΗConsumer Cooperative, where R5 represents 5 to 19 A linear or branched alkyl or alkenyl group of one carbon atom; W represents _s03M or -COOM; and M represents η or an organic or inorganic cation. 6-The composition according to item 1 of the patent application scope, further comprising a spacer. 7. Composition according to item 1 of the scope of patent application, wherein the viscosity changes with the temperature from 20 C to 30 t: the ratio of 0-60 or less, such as according to the following formula: -2 private paper from the applicable solid state A 娜（210Χ297ϋ) (Please read the notes on the back before filling in this page}

ΰ 6 41 ABCD r、申請專利乾圍 I黏度(30 °C)-黏度(20 °C)| 黏度(30 °C) 計算。 8. —種經由將根據申請專利範圍第卜項之增稠劑加入液體漂白劑中而將包含過氧化氫及界面活性劑且於3 0 °C顯示於1 0至1，000毫帕秒之範圍内之黏度的组合物其溫度自20 °C至30 °C之黏度變化率限制至0.60或以下（（如根據下列式計算）之方法：丨黏度(30 °C)-黏度(20 °C)丨黏度(30 °C) _ (請先聞讀背面之注意事項再填寫本頁) 訂經濟部中央標隼局一®:工消費合作社印裝 -3- 本紙張尺度逋用中國國家揉準（CNS ) Α4规格（21〇Χ297公釐） A8 B8 C8 弟8611:382號專利申請案申請專利範圍修正本(88年I2月）丄申請專利範圍41 6 41 ABCD r, patent application dry circumference I viscosity (30 ° C)-viscosity (20 ° C) | viscosity (30 ° C) calculation. 8. A method comprising adding a thickening agent according to Item B of the scope of the patent application to a liquid bleaching agent, containing hydrogen peroxide and a surfactant, and displaying it at 30 ° C between 10 and 1,000 mPas The viscosity of the composition within the range of the temperature from 20 ° C to 30 ° C viscosity change rate is limited to 0.60 or below (as calculated according to the following formula): 丨 viscosity (30 ° C)-viscosity (20 ° C ) 丨 Viscosity (30 ° C) _ (Please read the precautions on the back before filling in this page) Order the Central Bureau of Standards of the Ministry of Economic Affairs ®: Printing by Industrial and Consumer Cooperatives (CNS) A4 Specification (21〇 × 297 mm) A8 B8 C8 Patent Application No. 8611: 382 Amendment to Patent Application Scope (I Feb. 88) 范围 Application for Patent Scope

4 本 416986 "^irr f具有強化黏度之液體漂白劑組合物，其包含1〜i 〇重量％之過氧化氫、0.01〜10重量％之增稠劑及.0.1〜 5〇重量％之選自包括陰離子界面活性劑' 陽離子界面活性劑及非離子界面活性劑之至少一種之界面活性劑，其於3 0 C顯示於1 〇至1，〇〇〇毫帕抄之範圍内之黏度，其特徵為該增稠劑係由下式（1)或（1，）所示之聚氧化乙烯化合物： R1 - X - (C2H40)n - (CO)p - R2 (1) 其中R代表具有1 〇至2 0個碳原子之一種線性或分枝之晚基或缔基；R2代表Η或具有1〇至20個碳原子之線性或分枝之燒基或烯基；X代表_〇_、-COO-、-NR3-、或 -CONR3- ’其中R3代表Η，具有1至3個碳原子之烷基、經烷基或聚氧伸烷基；ρ係〇或i，其限制條件為當 R2係Η時p係〇 ; η係20至500之平均數目，其限制條件為選擇R1、R2、及η以使分子量及於分子中之該聚氧伸fe基鏈相對烷基或烯基之重量比可於以上指定之相關範園之内； RI-X-(C2H40)a-Y-[(C2H4〇)b-X. R1],, (Γ) 式中，R1及X係相同於以上定義者；a及b係彼此相同或相異，係20至500之平均數目；q係〇至3之數目；及Y代表經由開環而自雙環氧化物獲得之一種基。 2.根據申請專利範圍第丨項之組合物，其中於3 〇 t之該黏度係於1 0至5 0 0毫帕秒之範圍内。 3 ·根據申請專利範圍第丨項之組合物，其中該界面活性劑 —?—„-----------訂. (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標隼局貞工消費合作社印¾4 of this 416986 " ^ irr f liquid bleaching composition with enhanced viscosity, which contains 1 to 10% by weight of hydrogen peroxide, 0.01 to 10% by weight of thickener and .0.1 to 50% by weight of the choice A surfactant including at least one of an anionic surfactant, a cationic surfactant and a non-ionic surfactant, which exhibits a viscosity at 30 C in the range of 10 to 1,000 mPascals, which It is characterized in that the thickener is a polyethylene oxide compound represented by the following formula (1) or (1,): R1-X-(C2H40) n-(CO) p-R2 (1) wherein R represents 1 〇 A linear or branched late or alkenyl group of 20 to 20 carbon atoms; R2 represents fluorene or a linear or branched alkyl or alkenyl group having 10 to 20 carbon atoms; X represents _〇_,- COO-, -NR3-, or -CONR3- 'where R3 represents Η, an alkyl group having 1 to 3 carbon atoms, an alkyl group or a polyoxyalkylene group; ρ is 0 or i, and the limitation is that when R2 In the case of p, 0 is an average number; η is an average number of 20 to 500, and the limiting condition is that R1, R2, and η are selected so that the molecular weight and the polyoxygenated fe-based chain in the molecule The weight ratio to alkyl or alkenyl can be within the range specified above; RI-X- (C2H40) aY-[(C2H4〇) bX. R1] ,, (Γ) where R1 and X are The same as defined above; a and b are the same or different from each other and are an average number of 20 to 500; q is a number of 0 to 3; and Y represents a radical obtained from a bisepoxide via ring opening. 2. The composition according to item 丨 of the patent application range, wherein the viscosity at 300 t is in the range of 10 to 500 mPas. 3 · The composition according to item 丨 of the scope of patent application, in which the surfactant-?-"------------ order. (Please read the precautions on the back before filling this page) Economy Printed by Zhengong Consumer Cooperative of the Ministry of Standards of the People's Republic of China ¾