TW413700B - Method of establishing a vegetation base comprising a water-resistant aggregated structure, and a waterproof, anti-erosion agent - Google Patents

Method of establishing a vegetation base comprising a water-resistant aggregated structure, and a waterproof, anti-erosion agent Download PDF

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Publication number
TW413700B
TW413700B TW085109030A TW85109030A TW413700B TW 413700 B TW413700 B TW 413700B TW 085109030 A TW085109030 A TW 085109030A TW 85109030 A TW85109030 A TW 85109030A TW 413700 B TW413700 B TW 413700B
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TW
Taiwan
Prior art keywords
water
component
mud
mixing
erosion
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TW085109030A
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Chinese (zh)
Inventor
Noriyuki Sasahara
Kimiyasu Kuranuki
Shinzo Kaida
Original Assignee
Saiko Kk
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Publication of TW413700B publication Critical patent/TW413700B/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/14Soil-conditioning materials or soil-stabilising materials containing organic compounds only
    • C09K17/18Prepolymers; Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2103/00Civil engineering use

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

A method to establish a vegetation base comprising a water-resistant aggregated structure is provided, the vegetation base protecting a face of slope from an erosion and collapse for a long period of time, and being suitable for protecting the environment and for growing plants. The resulting vegetation base recovers greenery on the sloped bared ground in mountains or around dams, or the face of a slope bared as a result of development construction. A waterproof, anti-erosion agent used for such an object is also provided. A waterproof, anti-erosion agent of the present invention consists of an amphiphatic material comprising hydrophilic portions and hydrophobic portions, the ratio of an equivalent weight of hydrophilic functionality of said hydrophilic portions and that of hydrophobic functionality of said hydrophobic portions is 20:80 to 80:20. A method of the present invention comprises the steps of mixing and agitating a waterproof, anti-erosive agent with a muddy vegetation base material, resulting from mixing a vegetation base material comprising solid particles such as clay with water in a mixing tank, pumping said muddy vegetation material to an outlet, introducing a solution of a polymeric anionic polyacrylic amide coagulant into an agitation vessel, which is attached to a tip of said outlet, mixing and agitating these three components in the agitation vessel, and spraying said muddy base material onto the surface of application while effecting a coagulating reaction of said muddy material.

Description

413700 Λ7 -- - B7 五、發明説明(1 ) — ~ 本發明係關於一種造成綠化基盤的方法及其目的所使 用之耐浸水性侵蝕防止劑。本發明更詳而言之係關於一於 含有黏土、於〉尼等固體粒子之綠化基盤材與木混合而得到 之泥狀綠化基材上,使一含有親水性部分與疏水性部分之 兩親和性材科所構成的对浸水性侵敍防止劑進行混合而暫 時成為泥狀之基材’施工時與團粒劑(凝集劑)混合,一面 使產生團粒反應一面吹出,以造成安定之生育基盤,即綠 化基然之造成法及其目的所使用之耐浸水性侵蝕防止劑。 經濟部中央標準局員工消費合作社印製 ---------^--;-----,1T -·· (請先閱讀背面之注意事項再填寫本頁) 對於在災害或開發工事等所發生之山腹裸地斜面或法 面等的綠化困難地,以綠化復原作為目的,為使植物可生 育之表土再生,乃產生喷上植生基材之工事。從降雨等之 知蚀以至保證山腹裸地斜面或法面,保持景觀之目的,·為 綠化所作植生基材之噴塗所引起的生育基盤之造成工事中 ’ 一般係使客土、有機、肥料、侵蝕防止劑、植物種子等 與水混合而具有流動性之泥土中,以嗔塗喷嘴混合一調配 有高分手凝集劑或無機凝集劑之水溶液,一面使泥狀化之 水進行疏水’一面以安定之形態喷在山壁的方法已被廣泛 實施。於此等工法中係以防止所造成之生育基盤之侵蝕作 為目的’而使發芽或初期生育的旺盛草本類能在早期繁茂 生長之方法。但’對於植生條件之惡劣岩盤或硬質土法面 等進行施工時,一般,由喷塗造成之生育基盤厚度為3〜1〇 cm左右’故基盤内之肥料成分會被繁茂生長之草本類在 早期消耗掉,現地周邊植物之侵入所引起的植物遷移在開 始前1〜2年已衰退,再度呈裸地化。 本紙張尺度適用中國國家梂準(CNS ) Α4規格(2丨〇Χ;297公發) 413700 Λ7413700 Λ7--B7 V. Description of the invention (1)-The present invention relates to a method for creating a green substrate and an anti-soaking water-resistant corrosion inhibitor used for the purpose. More specifically, the present invention relates to a mud-like green substrate obtained by mixing a green base material containing clay, solid particles such as clay, and other green particles with wood, so that a hydrophilic portion and a hydrophobic portion are compatible. The base material composition is composed of a water-repellent invasion preventive agent mixed to temporarily become a mud-like substrate. 'When mixing, it is mixed with an agglomerating agent (agglomerating agent) to blow out while reacting to generate agglomerates, thereby creating a stable growth base. That is, the greening-based method and the purpose of the water-resistant erosion prevention agent. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs --------- ^-; -----, 1T-(Please read the precautions on the back before filling this page) Development of construction sites, such as slopes of bare hillsides, slopes, or French land, where greening is difficult. The purpose of greening restoration is to regenerate plant fertile topsoil, which is a process of spraying vegetation substrates. From the erosion of rainfall and other issues to the maintenance of bare slopes or slopes on the mountainside, to maintain the landscape, the construction of fertility substrates caused by the spraying of vegetative substrates for greening is generally used in the construction of guest soil, organic, fertilizer, Erosion inhibitors, plant seeds, etc. are mixed with water and have fluidity. Mix the solution with a high-strength agglutinating agent or inorganic agglutinating agent with a coating nozzle, and stabilize the water while making the muddy water hydrophobic. This method of spraying on the mountain wall has been widely implemented. In these methods, the purpose is to prevent the erosion of the fertility substrate caused by it ', so that the germinated or early-growing vigorous herbs can flourish in the early stages. However, 'for the construction of harsh rock disks or hard soil surfaces with vegetative conditions, in general, the thickness of the fertility substrate caused by spraying is about 3 to 10 cm', so the fertilizer components in the substrate will be lushly grown by herbs. Consumed at an early stage, the plant migration caused by the invasion of the surrounding plants has declined 1 to 2 years before the start, and it has become bare again. This paper size applies to China National Standards (CNS) Α4 specifications (2 丨 〇 ×; 297) 413700 Λ7

五'發明説明(2 ) I ί I 裳 . 訂 J - - (請先閱讀背面之注意事項再填寫本頁) 因此,最近出現從施工當初即使肥料成分报少之貧瘠 地亦成立》此木本類與習知所使用之草本類比較,發芽或 初期生育遲綴’導入之植物在施工播種不適期時,所造成 之生s基盤有時係干覆蓋一年以上植物而繼續以直接露出 的狀態。如此所造成之生育基盤因長期間露出,故必須更 進一步強化綠化基盤之对侵蚀性。 為防止此綠化基盤之侵餘,以往,主要乃使用柏油乳 劑等與基盤材混合的方法,藉由柏油之接著及被膜效果可 防止生育基盤之侵蝕。但,此柏油係數千種以上之化合物 的集合體,要個別取出實有困難,一般對石蠟、環烧煙等 之飽和物、芳香族成分、樹腊及瀝育等之組成進行分析, 均呈疏水性。因此,以提高綠化基盤之耐侵蝕性作為目的 而大量混合,則形成綠化基盤本體具有撥水性(疏水性), 因妨礙降雨水等之吸收,故綠化基盤係乾燥、進而造成植 物生育之結果。 為維持生態系,乃期待周邊植物之侵入,而不混入種 子之自然植生誘導工法或導入發芽或初期生育遲緩之木本 經濟部中央標隼局貝工消費合作社中装 植物作為目的時’ X,於河川或水霸頂水法面等所造成之 綠化基盤,係必須是一種能夠承受長期間之降雨或成浸水 狀態,同時,在侵入之植物種子或綠化基盤中所混合之植 物種子的發芽或生育不受阻礙的士壤構造者,向綠化基盤 吸水、脫权財等«河輕$,故不料來自綠化基 盤之有害物質的產生β 使用習知之侵食防止劑的綠化基盤存在如下問題··遇 本紙張尺度適用中國 413700 Λ7 —----------β7 五、發明説明(3 ) ―― 到長期間料或降雨,齡呈泡敎㈣,㈣絲性會極 端劣化。又,習知綠化基盤之侵㈣止財會對植物生育 帶來或多或少之不良的影響。因此,極吩望—種對綠化基 盤賦與充分耐水性、對植物生育無不良影響、對環境亦具 有安全之耐水性的綠化基盤之造成法及侵蝕防止劑。 於土壞團粒中,可看到從耕作等人為性造成者乃至自 然營造經長年累月形成之森林褐色土壤的形態,即有分布 廣泛範圍之狀態者。就耕地而言,一般符合作物收穫之周 期,依情況耕耘,故所造成之團粒安定性未必需要,但, 本發明在於針對災害或開發行為等發生之裸地或法面的生 育基盤’施工時直接以所造成之狀態無須一切管理而放置 著乃現狀。因此’針對不間斷地供給植物生育必要之水分 或養分與空氣給植物的根所產生的生育基盤之構造,亦即 土壤團粒乃必須長期間維持。 若觀察堆積於自然界急峻的山腹斜面之表土,係以很 薄層堆積於岩石或硬質土的上層,不會侵蝕或崩落而安定 地附著。成長於此之植物的根極有助於表土之安定係肯定 的’但認為’不太有助於受降雨水等侵蝕之土壤微細粒子 亦即黏土的侵蚀防止》防止此黏土粒子之侵蚀係有助於生 經濟部中央標準局貝工消费合作社印^ 存於此之植物或小動物等屍骸所產生的有機或腐殖與黏土 1¾ 、 粒子經以降雨水等作為媒介而結合成之面粒構造。 為造成一忠實地再呈現自然界長年累月進行之機溝且 適於植物生育之生育基盤的方法,已記載於有關本案申請 人之特公昭第64-2734號及特公平第2-26932號公報中。此 前案發明之方法係以具有高凝集能之陽離子性高分子凝集 劑之作用來置換 自然界小動物的屍骸或有機物等所產生 本紙張尺度適用中國國家楳準(CNS ) Λ4規格(210X297公#—) 413700 Λ7 ___ Πί 五、發明説明(4 ) 之高凝集作用。預先準備之黏性土壤及有機堆肥與水混合 而得到之泥狀生育基盤材再與凝集劑於施工時分別以泵浦 壓送,在噴嘴之前端以特殊方法進行混合,使一面產生團 粒反應一面吹出,造成形成團粒構造之生育基盤。此前案 發明之方法即為目前廣泛施工之方法,但,如前述般若遇 到長期間降雨成浸水’則呈泡漲之狀態,耐侵蝕性食劣化 0 因此’有關再度堆積於自然界之表土的本性及形成機 構,經熟視、研究之結果,乃著眼於小動物之屍骸係殘存 著多少的油脂成分亦即疏水性要素,此乃吸附於黏土粒子 且以具有適度疏水性之狀態藉由與腐殖亦即線狀有機高分 子之结合形成團粒化。土壤團粒之崩壞係有如下情形:從 外部之機械衝擊所造成的,以及土壤本身之乾濕引起重複 t澗收縮所造成的;而於施工後長期間放置之斜面或法面 上所造成之生育基盤’乃以後者崩壞成為要因占多數β使 土壌團粒之乾濕情況緩和者乃吸附於黏土粒子之疏水要素 亦即油脂成分,誠然,係具有充分平衡之親水性與疏水性 兩性質的兩親媒性材料。 經濟部中央榡準局負工消費合作社印51 I n 11 J I ! ί ϋ I - ' (讀先閱11背而之注項再填寫本頁) 本發明之綠化基盤的造成法,其特徵在於:使用具有 充分平衡之疏水性與親水性的兩親媒性耐浸水性侵蝕防止 劑,俾綠化基盤具有埘侵蝕性且促進植物之生育。 本發明之方法係於一含有粘土、齡泥等固體粒子之綠 化基盤材料與水混合而得到之泥狀綠化基材上,攪拌混合 一由上述兩親媒性材料所構成之耐浸水性侵钮防止劑後, 以泵浦將此泥狀材朝吐出口壓送,並將陰離子型高分子凝 集劑水溶液導入預先安裝於前述吐出口的攪拌筒内,此等 本紙張尺度適用中國國家標準(CMS ) A4規格(21GX297公楚) 413700 Λ7 ------- -H7 五、發明説明(5 ) 3者在前述欖拌筒内混合攪拌,立即使前述泥狀材進行團 粒反應’並同時吹向施工面之步驟。進而,於前述方法中 ’為使圏粒構造之結持力更強固,當高分子凝集劑水溶液 導入攪拌筒内的同時,宜將空氣導入該攪拌筒内。 可用於上述方法之本發明耐浸水性侵蝕防止劑係含有 親水性部分與疏水性部分,且由此等親水性部分之親水基 與疏水性部分之疏水基的當量比乃20/80〜80/20的兩親媒 性材科所構成。於較佳態樣中,此侵蝕防止劑係由每1個 羧基碳數6〜24之脂肪酸疏水性成分(A)、及、每1個羧基 破數6〜24之脂肪酸之鹼金屬鹽、胺鹽或銨鹽之親水性成 份(B)所構成的,進而更佳係,親水性成分可為每丨個 羧基碳數6〜24之脂肪酸的烷醇胺鹽或銨鹽》 經濟部中央橾準局員工消費合作社印製 本發明之侵餘防止劑的疏水性成分(A)可舉例如破數 6〜24之1價脂肪酸及每1個羧基碳數6〜24之聚合脂肪酸, 此等之具體例可舉出:天然之1價高級脂肪酸(例如己酸、 辛酸、月桂醃、肉豆蔻酸、棕櫊酸、硬脂酸、花生四烯酸 、山备酸、二十四酸等之飽和脂肪酸、肉豆蔻烯酸、棕櫚 稀酸 '油酸、反油酸、界子酸、亞油酸' Hiragonic acid 、亞麻酸等之不飽和酸、大豆油脂肪酸、松漿油脂肪酸、 棕櫚油脂肪酸、椰子油脂肪酸等之天然油脂經處理所得到 之脂肪酸混合物、藏麻油脂肪酸等之含羥基脂肪酸)以及 聚合脂肪酸(例如油酸、亞油酸之C18的不飽和脂肪酸、 乾性油脂肪酸成半乾性油脂肪酸及此等各脂肪酸之低級單 醇酯經二分子聚合者為主成分之二聚酸)。其中較佳者係 9 --------;I β--------訂 (務先聞讀^'面之注意事項再填寫本黃) 本纸張尺度適用中國國家揉车(CNS ) Α4规格(210X29?公釐) 413700 經濟部中央標準局—工消費合作社印家 Λ7 Ρ1·7 五、發明説明(6 ) 月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、亞油酸、亞 麻酸、二聚酸及椰子油脂肪酸 '棕櫊脂肪酸、牛脂肪酸等 之每1個羧基c12〜c24的脂肪酸或脂肪酸混合物。親水性 成分(B)中之脂肪酸亦可舉例與上述疏水性成分(A)所例示 者同樣,較佳者亦相同。 於親水性成分(B)中,鹼金屬可舉例鈉 '鉀、鋰等, 胺舉例如單乙醇胺、二乙醇胺、三乙醇胺等之烷醇胺、烷 基(ί^〜<:4)胺。成分(B)宜為烷醇胺鹽及銨鹽。 若例示本發明之耐浸水性侵蝕防止劑之製造,亦可混 合成分(Α)與成分(Β) ’或使用鹼金屬化合物、胺、銨水溶 液等來部分中和成分(Α)而使一部分形成成分(Β)。混合之 方法中,成分(Β)亦可使用與成分(Α)相同之脂肪酸鹽4行 混合,或’使用異種之脂肪酸鹽與成分(Α)混合。成分(Α) 與成分(Β)之羧基當量比(Α)/(Β)—般為20/80〜80/20、宜 為 30/70〜60/40。 本發明之耐浸水性侵蝕防止劑亦可直接使用含有成分 (Α)與成分(Β)者’亦可使用水、無活性有機液體、乳化劑 等作為水性懸濁液或水性乳化液。製造水性懸濁液或水性 乳化液之方法無特別限定,例如①預先將成分(Α)及成分(β) 投入調配槽或容器中後,成分(Α)在常溫為液體時,直接 攪拌,在常溫為固體時加溫溶融後,攪拌,同時加入乳化 劑、水等而製造漁濁液的方法;0預先將水、乳化劑等投 入調配槽或容器中,然後一面攪拌成分(Α)及成分(Β)—面 加入而製造懸濁的方法。 本紙張尺度適用中國國家標準(CNS ) Λ4規格(2丨0 X 297公楚) (請先閱攻背面之注意事項再填寫本頁〕 -訂 經濟部中央棣準局員工消費合作社印製 413700 Λ7 _-____Η 7 五、發明説明(7 ) , 於本發明中,成為從降雨或浸水保護對象之綠化基盤 可舉例:對於岩盤或硬質土法面等綠化困難地,以長久綠 化復元為目的,而從施工當初即有計劃性導入發芽或初期 生育遲緩之肥料木等的木本類之情形,或,為衍生出由周 邊植物之侵入而產生之自然植生,而從當初不混入種子 之無種子客土上’以及極度要求耐浸水性之年間平均1 5〇 日以上浸水的水霸頂水法面或增水時頂水河川之堤防上, 所施工的綠化基盤等。 本發明之耐浸水性侵蝕防止劑於綠化基盤内的添加量 ,係依成為對象之綠化基盤全材料的種類或組成或綠化基 盤之施工場所而異’無特別限定’但對於綠化基盤材之合 計為1〜100 kg/m3、較佳係5〜50 kg/m3。添加量不足丨kg/m3 時,綠化基盤於短期間内會受降雨或浸水侵蝕,即使超過 100kg/m3效果上亦無特別提高,不經濟。 本發明方法之綠化基盤造成工事’係於附有挽拌機之 調配裝置等中,首先投入客土、堆肥、植物種子、水等之 綠化基盤材料,然後添加本發明之耐水性侵蝕防止劑,授 拌混合後,將其與預先準備好之陰離子型聚丙烯醯胺系高 分子凝集劑水溶液分別以泵浦壓送至吹出喷嘴,在喷嘴内 混合,而使之附著安定於崩壞地斜面或法面。 於以本發明之方法所施工之綠化基盤中,附著於土粒 表面之成分(A)及成份(B)乃充分平衡地賦與疏水性與親水 性在土粒子中’故可賦與綠化基盤適度的保水性、通水,陡 ,且,對於降雨成浸水具有成為安定基盤的作用β ---------裝--^-----訂 - - (讀先閱讀.背面之注意事項再填寫本頁)Five 'invention description (2) I ί I Sang. Order J--(Please read the precautions on the back before filling out this page) Therefore, recently, even from the beginning of the construction, even the barren land with a small amount of fertilizer content has been established. Compared with the herbs used in the past, when the plants introduced with germination or early growth delay are introduced during the unsuitable period of construction and sowing, the raw s substrate may sometimes be covered with plants for more than one year and continue to be exposed directly. . Since the fertility substrate exposed in this way is exposed for a long period of time, it is necessary to further strengthen the erosiveness of the greening substrate. In order to prevent the invasion of this greening substrate, in the past, the method of mixing with the substrate material such as asphalt emulsion was mainly used. The adhesion of the asphalt and the coating effect can prevent the erosion of the fertility substrate. However, it is difficult to take out the aggregate of more than one thousand compounds with an asphalt coefficient. Generally, the composition of saturated compounds such as paraffin, ring-burning tobacco, aromatic components, wax, and leaching are all hydrophobic. Sex. Therefore, if a large amount of mixing is carried out for the purpose of improving the erosion resistance of the greening substrate, the greening substrate body has water repellency (hydrophobicity), and the absorption of rainwater and the like is hindered. Therefore, the greening substrate system is dry, which results in plant growth. In order to maintain the ecosystem, the invasion of surrounding plants is expected, and natural plant growth induction methods that do not mix with seeds or the introduction of germination or early growth retardation of the Woody Ministry of Economic Affairs Central Standardization Bureau Shellfish Consumer Cooperative Co., Ltd. for the purpose of loading plants' X, The greening substrate caused by rivers or water tops, etc. must be able to withstand long-term rainfall or flooding, and at the same time, the germination or plant seeds mixed in the invading plant seeds or greening substrates Those who are not obstructed by fertility of the soil structure absorb water, deprivation of wealth, etc. to the greening substrate, so it is expected that harmful substances from the greening substrate will be generated. Β The greening substrate using the conventional anti-eating agent has the following problems. This paper scale is applicable to China 413700 Λ7 ------------ β7 V. Description of the invention (3) —— In the long period of time, the material will be immersed in age or rain, and the silk will be extremely deteriorated. In addition, it is known that the invasion and financial control of greening bases will have more or less adverse effects on plant growth. Therefore, it is highly hoped that a greening substrate that provides sufficient water resistance to the greening substrate, has no adverse effects on plant growth, and has a water resistance that is safe to the environment, and a method for preventing erosion. In the soil granules, you can see the man-made causes such as farming, and even the natural formation of forest brown soil formed over many years, that is, people with a wide range of states. As far as cultivated land is concerned, it generally conforms to the crop harvesting cycle and cultivates according to the situation, so the stability of the resulting pellets may not be necessary. However, the present invention is aimed at the bare land or the legal growth fertility substrate when the disaster or development behavior occurs. It is the status quo that it is placed directly without any management. Therefore, the structure of the growth substrate produced by continuously supplying plants with necessary water or nutrients and air for plant growth, that is, the soil aggregates must be maintained for a long period of time. If you observe the topsoil piled up on the sloping mountainside slopes in nature, it is deposited in a very thin layer on the upper layer of rock or hard soil, and it will adhere securely without erosion or chipping. The roots of the plants that grow here contribute affirmatively to the stability of the topsoil. However, it is believed that the soil fine particles that are eroded by rainfall and so on, that is, the erosion prevention of clay, help prevent the erosion of this clay particle. Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Health and Economics ^ Organic or humus and clay 1¾ produced by the corpses of plants or small animals stored here, particles of noodle structure formed by using rainwater as a medium. In order to create a faithful reappearance of the ditch that has been going on in nature for many years and is suitable for plant growth, it has been described in Japanese Patent Publication No. 64-2734 and Japanese Patent Publication No. 2-26932. The method invented in the previous case is to replace the corpse or organic matter of small animals in nature with the action of a cationic polymer agglutinant with high agglutination energy. The paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X297 公 # —) 413700 Λ7 ___ Πί 5. Description of invention (4) High agglutination. The viscous soil and the organic compost prepared in advance are mixed with water and the mud-like fertility-based disc material is pumped with the agglutinant during construction and mixed by a special method at the front end of the nozzle to cause agglomeration reaction on one side. Blowing out, resulting in the formation of fertility bases of agglomerate structures. The method invented in the previous case is the current method of extensive construction. However, as mentioned above, if it encounters long-term rainfall and soaks in water, it will be in a state of swelling, and the erosion resistance will deteriorate. Therefore, it is related to the nature of topsoil which has accumulated in nature again. And the formation mechanism, the results of familiarity and research are focused on how much oily components, that is, hydrophobic elements, remain in the corpse of small animals, which is adsorbed on clay particles and has a moderately hydrophobic state through humus That is, the combination of linear organic polymers forms agglomerates. The collapse of soil particles is caused by mechanical shock from the outside, and caused by repeated t 涧 shrinkage caused by the soil's dryness and wetness; and caused by the inclined surface or normal surface placed for a long time after construction. The "fertility substrate" is the latter that collapses to cause the majority of β to ease the wet and dry conditions of the soil granules. It is the hydrophobic element that is adsorbed on the clay particles, that is, the oil component. Of course, it has a well-balanced hydrophilicity and hydrophobicity. Amphiphilic material. Printed on 51 I n 11 JI! 负-I-'(read the note below and read this page before filling out this page) The method for creating the green base of the present invention is characterized by: The amphiphilic greening substrate is 埘 erosive and promotes the growth of plants by using amphiphilic immersion water-resistant erosion inhibitors with a sufficient balance of hydrophobicity and hydrophilicity. The method of the present invention is based on mixing a greening base material containing solid particles such as clay, aging mud, and water with a mud-like greening substrate, and mixing and mixing a water-resistant invasion button made of the amphiphilic material. After the preventive agent, the mud-like material is pumped to the discharge port by a pump, and an anionic polymer coagulant aqueous solution is introduced into a stirring cylinder installed in the discharge port in advance. These paper standards are applicable to Chinese national standards (CMS ) A4 specification (21GX297 Gongchu) 413700 Λ7 ------- -H7 V. Description of the invention (5) The three are mixed and stirred in the aforementioned mixing bowl to immediately cause the aforementioned mud-like material to undergo agglomeration reaction and simultaneously blow Steps to the construction surface. Furthermore, in the aforementioned method, 'in order to make the holding force of the crumb structure stronger, when the polymer coagulant aqueous solution is introduced into the stirring drum, air is preferably introduced into the stirring drum. The water-repellent erosion-proofing agent of the present invention which can be used in the above method contains a hydrophilic part and a hydrophobic part, and the equivalent ratio of the hydrophilic group of the hydrophilic part to the hydrophobic group of the hydrophobic part is 20/80 ~ 80 / 20 amphipathic materials. In a preferred embodiment, the erosion preventing agent is composed of a fatty acid hydrophobic component (A) having a carbon number of 6 to 24 per carboxyl group, and an alkali metal salt and an amine of a fatty acid having a number of 6 to 24 per 1 carboxyl group. Salt or ammonium salt composed of the hydrophilic component (B), and more preferably, the hydrophilic component may be an alkanolamine or ammonium salt of a fatty acid having 6 to 24 carboxyl carbon atoms. The hydrophobic component (A) of the anti-overrunner of the present invention printed by the bureau employee consumer cooperative can be, for example, a monovalent fatty acid with a number of 6 to 24 and a polymerized fatty acid with a number of 6 to 24 per carboxyl carbon. Examples include: natural monovalent higher fatty acids (such as hexanoic acid, caprylic acid, laurel pickling, myristic acid, palmitic acid, stearic acid, arachidonic acid, behenic acid, behenic acid, etc.) , Unsaturated acids such as myristic acid, palmitic acid, oleic acid, oleic acid, bound acid, linoleic acid, Hiragonic acid, linolenic acid, soybean oil fatty acid, pine oil fatty acid, palm oil fatty acid, coconut Fatty acid mixtures obtained from the treatment of natural oils such as oil fatty acids, Tibetan hemp Oil-containing fatty acids such as hydroxy fatty acids) and polymeric fatty acids (such as oleic acid, C18 unsaturated fatty acids, dry oil fatty acids into semi-dry oil fatty acids, and the lower monoalcohol esters of each of these fatty acids are polymerized by two molecules: Dimer acid of main component). The better one is 9 --------; I β -------- order (please read the notes of ^ 'side first, then fill in this book) This paper size is applicable to Chinese countries Vehicle (CNS) Α4 specification (210X29? Mm) 413700 Central Standards Bureau of the Ministry of Economic Affairs—Industrial and Consumer Cooperatives Co., Ltd. Λ7 P1 · 7 5. Description of the invention (6) Lauric acid, myristic acid, palmitic acid, stearic acid, oil Fatty acids or fatty acid mixtures of each carboxyl group, such as acids, linoleic acid, linolenic acid, dimer acid, coconut oil fatty acids, palmitic fatty acids, bovine fatty acids, and the like. Examples of the fatty acid in the hydrophilic component (B) may be the same as those exemplified for the above-mentioned hydrophobic component (A), and preferably the same. In the hydrophilic component (B), examples of the alkali metal include sodium, potassium, lithium, and the like. Examples of the amine include alkanolamines and alkyl (4) amines such as monoethanolamine, diethanolamine, and triethanolamine. Ingredient (B) is preferably an alkanolamine salt and an ammonium salt. If the production of the water-impermeant corrosion inhibitor of the present invention is exemplified, the component (A) and the component (B) may be mixed, or an alkali metal compound, an amine, an aqueous solution of ammonium, or the like may be used to partially neutralize the component (A) to form a portion. Ingredient (B). In the mixing method, the component (B) may be mixed in four lines using the same fatty acid salt as the component (A), or a different type of fatty acid salt may be mixed with the component (A). The carboxy equivalent ratio (A) / (B) of the component (A) and the component (B) is generally 20/80 to 80/20, and preferably 30/70 to 60/40. As the anti-soaking water erosion inhibitor of the present invention, those containing the component (A) and the component (B) may be used as they are. Alternatively, water, an inactive organic liquid, an emulsifier, or the like may be used as an aqueous suspension or an aqueous emulsion. The method for producing an aqueous suspension or an aqueous emulsion is not particularly limited. For example, ① After the component (A) and the component (β) are put into a mixing tank or container in advance, when the component (A) is liquid at normal temperature, directly stir it. When the solid is at room temperature, it is heated and melted, stirred, and added with emulsifier, water, etc. to produce fish turbid liquid; 0 Water, emulsifier, etc. are put into a mixing tank or container in advance, and then the ingredients (A) and ingredients are stirred (B)-A method of adding suspension to produce suspension. This paper size applies the Chinese National Standard (CNS) Λ4 specification (2 丨 0 X 297). (Please read the precautions on the back before filling out this page.)-Order printed by the Central Consumers' Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 413700 Λ7 _-____ Η 7 V. Description of the Invention (7) In the present invention, the greening substrate that is the object of protection from rainfall or water infiltration can be exemplified: for the difficult greening such as rock plate or hard soil surface, for the purpose of long-term green restoration, and From the time of construction, woody species such as fertile wood that has germinated or had early growth retardation have been planned to be introduced, or, in order to derive natural vegetation that is generated by the invasion of surrounding plants, and from the seedless customers who did not mix the seeds at the beginning On the soil 'and on the surface of the water dam top surface or the embankment of the top water river when the water is increased for an average of more than 150 days, the green substrate is constructed, etc. The water resistance erosion of the present invention The amount of the preventive agent added to the greening substrate depends on the type or composition of the entire greening substrate of the target or the construction site of the greening substrate. 'No special restrictions' but for greening The total base material is 1 ~ 100 kg / m3, preferably 5 ~ 50 kg / m3. When the amount is less than 丨 kg / m3, the greening base plate will be eroded by rain or water in a short period of time, even if it exceeds 100kg / m3. There is no special improvement, and it is not economical. The greening base of the method of the present invention is fortified with a mixing device equipped with a mixing machine, etc. First, the greening base materials such as guest soil, compost, plant seeds, and water are added, and then added. After the water-resistant erosion preventing agent of the present invention is mixed and mixed, it is pumped to a blow-out nozzle with an anionic polyacrylamide-based polymer coagulant aqueous solution prepared in advance, and mixed in the nozzle so that The adhesion is stabilized on the inclined or inclined surface of the broken ground. In the greening substrate constructed by the method of the present invention, the components (A) and (B) attached to the surface of the soil particles are fully balanced to impart hydrophobicity and hydrophilicity. Nature in the soil particles' so it can give the greening substrate a moderate water retention, water flow, steep, and for rain and water infiltration has the role of a stable substrate β --------- install-^- --- Order--(Read first. Read on the back (Please fill this page again)

413700 經濟部中央標準局員工消費合作社印装 Λ7 1}7 五、發明説明(8 ) [實施例] 以下’以實施例說明本發明,但,本發明不限於此》 實施例中之份及%係重量份及重量%。 實施例1 部分中和棕櫊酸’於附有攪拌機之不銹鋼製調配槽中 ,使相對於全羧基0.3當量鈉鹽之棕櫚酸的鈉鹽10份、水88 份及作為乳化劑之聚乙二醇型非離子界面活性劑2份經充 分攪拌調配而使之分散,得到本發明之侵蝕防止劑。對於 此,為確認侵蝕防止性能,混合一由埴土壤60份、樹皮堆 ’ 肥39份及植物性織維1份所構成的植生基盤材1〇〇份、草種 (weeping love grass)0.01份、草種(ereeping red feScue)0‘01 份及水100份而得到綠化基盤材。對於此綠化基盤材〇. 1 ,添加混合本發明之侵蝕防止劑5kg,得到綠化基盤用之 泥狀基材。進而混合溶解陰離子型之聚丙烯醯胺系高分子 凝集劑0.01份與水10份所得到之高分子凝集劑水溶液10 kg 作為補助劑,而加入於泥狀基材中經充分攪拌混合,可得 到一充分使土粒子等圍粒構造化之綠化基盤。從其中採取 0,05 m3而作成10 cm厚的供試體,以日照乾燥約7日。然 後,供試體於隔日浸泡於水中,調查綠化基盤因浸水所引 起之侵蝕狀態或有無崩壞與種子之發芽及生育狀態。將結 果表示於表1中。 實施例2 部分中和棕櫚酸’於附有攪拌機之不銹鋼製調配槽中 ,相對於全羧基0.6當量二乙醇胺鹽之棕櫚酸的二乙醇胺 本紙張尺度適用中圉國家標準(CNS)A4規格(2I〇X297公t ) . 12 ! in _____ I n - I — _ 丁 i 1111 - Λ <- (錆先閱讀背*之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印簟 413700 Λ7 _______B7 五、發明説明(9 ) "~^~~; —-- 逢12份、水84份、作為乳化劑之聚丙稀酸鈉水溶液乙份及 聚乙二醇型界面活性劑乙份經充分挽掉混合而得到本發明 之侵蝕防止劑。為進行性能測定,對於實施例丨所使用之 綠化基盤材0.1 m3,混合添加本發明之侵蝕防止劑〇 5 kg ,得到泥狀基材》進而於實施例丨所使用的高分子凝集劑 水溶液相對於泥狀基材0.1 m3添加混合丨〇 kg,得到一充分 使土粒子等團粒構造化之綠化基盤。從其中’採取0 05 m3 而與實施例1同樣地作成供試體,進行性能測定。將其結 果表示於表1中。 實施例3 使一混合有油酸50%與亞油酸50%之不飽和脂肪酸混 合物部分中和,於附有攪拌機之不銹鋼製調配槽中,使相 對於羧基0.5當量鉀鹽之油酸與亞油酸混合物之鉀鹽25份 、水72份、作為乳化劑之聚丙烯酸鈉水溶液乙份及聚乙二 醇型界面活性劑I份經充分攪拌混合而得到本發明之侵钱 防止劑。為進行性能測定,對於實施例1所使用之綠化基 盤材0.1 m3 ’混合添加本發明之侵蝕防止劑2.5kg,得到泥 狀基材。進而於實施例1所使用的高分子凝集劑水溶液相 對於泥狀基材0.1 m3添加混合丨〇 leg,得到一充分使土粒子 等團粒構造化之綠化基盤。從其中,採取0.05 m3而與實 施例1同樣地作成供試體,進行性能測定。將其結果表示 於衷1中。 實施例4 使一含有月桂酸、肉豆蔻酸、辛酸等之椰子油脂肪酸 本紙悵尺度適用中國國家標準(CNS ) Λ4規格(210X 297公t } - 13 1 (諳先閱換背面之注項再填寫本頁) .裝· 413700 Λ 7 ------___ 五、發明説明(10 ) . 部分中和,於附有攪拌機之不銹鋼製調配槽中,使相對於 全羧基0.4當量銨鹽之椰子油脂肪酸的銨鹽15份、水83份 及作為乳化劑之聚丙稀酸鈉水溶液2份經充分攪拌混合而 得到本發明之侵蝕防止劑。為進行性能測定,對於實施例 1所使用之綠化基盤材〇. 1 m3 ’混合添加本發明之侵蚀防 止劑2.5 kg ’得到泥狀基材。進而於實施例1所使用的高分 子凝集劑水溶液相對於泥狀基材0.1 m3添加混合1〇 kg,得 到一充分使土粒子等困粒構造化之綠化基盤。從其中,採 取0.05 m3而與實施例1同樣地作成供試體,進行性能測定 。將其結果表示於表1中。 實施例5 經濟部令央標隼局員工消費合作社印製 ---------袭--ϊ-----訂 * (薄先閱讀If·面之注意事項再填寫本頁) 使一含有硬脂酸、棕櫚酸等之牛脂肪酸部分中和;於 一附有攪拌機之不銹鋼製調配槽中,使相對於全羧基0.7 當量三乙醇胺鹽之牛脂酸的三乙醇胺鹽2〇份、水76份及作 為乳化劑之聚丙烯酸鈉水溶液4份,經充分攪拌混合而得 到本發明之侵蝕防止劑。為進行性能測定,對於實施例j 所使用之綠化基盤材〇. 1 m3 ,混合添加本發明之侵蚀防止 劑2.5 kg *得到泥狀基材。進而於實施例1所使用的高分 子凝集劑水溶液相對於泥狀基材0Jm3添加混合1〇 kg, 得到一充分使土粒子等團粒構造化之綠化基盤。從其中, 採取0.05 m3而與實施例丨同樣地作成供試體,進行性能測 定。將其結果表示於表1中。 比較例1 4 相對於殖蠓土 60份、樹皮堆肥39份及植物性纖維1份 14 413700 Λ7 B7 五、發明説明(11 ) . 所構成的椬生基盤材100份,在草種(creeping red fescue) 0_01份、草種(weeping love gracs)0.〇l 份及水 loo份中,混 合目前所使用之瀝青系侵蝕防止劑0,05份(相對於植生基 盤材100份,且為提高财侵餘性之目的,此份量乃為一般 之1 _5倍)而得到綠化基盤用之泥狀基材6進而使陰離子型 之聚丙婦酿胺系高分子凝集劑〇·〇1份與水份混合混解而 得到之高分子凝集劑水溶液丨〇 kg作為補助劑,加入泥狀 基材中充分攪拌混合,得到一充分使土粒子等團粒構造化 之綠化基盤。從其中採取0.05 m3而作成10 cm厚之供試體 ,以日照乾燥約7日,然後,供試體於隔日浸泡於水中, 調查綠化基盤因浸水所引起的侵蝕狀態或有無崩壞與種子 之發芽及生育狀態》將結果表示於表1中β · 比較例2 經濟部中央標準局負工消費合作社印製 11 I . J 5 11 ~ 訂 · (铕先閱後背面之注意Ϋ項再填寫本頁) 依據特開平4-93419號公報說明書中記載的實施例-, 於Si03濃度30%矽酸溶膠30份中加入NaCl 1.2份而混合之 ’進而加入水及硫酸形成一呈PH6,5之全量50份矽酸溶膠 水分散液,放置於室溫下使之凝膠化,得/j一習知技術之 侵蝕防止劑。為測定其性能,相對於埴$土 100份、草種 (creeping red fescue)0.01 份及草種(weeping love grass)0.01 份混合者100份,混加混合習知技術之侵蝕防止劑50份, 得到〇·1 m3之綠化基盤。從其中採取0_05 m3而作成10 cm 厚的供試體,以日照乾燥約7日。然後,供試體於隔曰浸 泡於水中,調查綠化基盤因浸水所引起之侵蝕狀態或有無 崩壞與種子之發芽及生育狀態。將結果表示於表1中。 本紙張尺度適用中圑國家標準(CNS ) A4坑格(210Χ29Ί公釐) · 15,- 413700 Λ7 __B7 五、發明説明(丨2 ) 表1 崩壞之有無 (30曰經過後) 種子之發芽狀態 (發芽率) 發芽後之生育狀態 (30曰經過後) 1 安定 90% 良好 2 安定 90% 良好 實 施3 安定 90% 良好 例 4 安定 90% 良好 5 安定 90% 良好 比 較 安定 3 5% 不良 80%崩壞 50% 不良 (銪先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局貝工消費合作社印製 [發明之效果] 形成本發明之耐水性團粒構造的綠化基盤造成法及耐 浸水性侵蝕防止劑可發揮以下之效果。 (1) 以脂肪酸、脂肪酸鹽為成分之前述耐浸水性侵蝕防止 劑混合於泥狀化的綠化基材後,再與凝集劑水溶液混合成 團粒化,只使泥狀基材中所含有的土粒子帶電不安定化, 故可促進泥狀基材之團粒化。 (2) 以利用有脂肪酸特有之疏水性的前述耐浸水性侵蝕防 止劑,使經被膜之土粒子團粒化,俾可抑制長時間之降雨 或浸水所引起的黏土粒子豐潤,且可防止綠化基盤因豐軟 化所造成的耐侵蝕性劣化。 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公釐) -16 - 413700 Λ7 ----- 扪____ 五、發明説明(13 ) (3) 可促進植物之生育 使用於本發明之綠化基盤的耐浸水性侵蝕防止劑,因 係以脂肪酸與脂肪酸鹽為成分者,故可對綠化基盤充分平 衡地賦與疏水性及親水性,綠化基盤因保有保水性及通水 性之相互矛盾機能,故可促進綠化基盤中之植物種子的發 芽、生育》 (4) 安全性高 使用於本發明之綠化基盤的耐浸水性侵蝕防止劑係由 脂肪酸所構成,故生物分解性優異、安全性高。 I - - - - I I I 士衣 —嘗ί I--訂 · (兔先閱讀"*面之注意事項再填寫本頁) 經濟部中央標準局舅Η消費合作社印裂 本紙張尺度適用中國國家標準(CNS ) A4規格(2!0Χ^97公潑)413700 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 1} 7 V. Description of the Invention (8) [Examples] The following examples are used to illustrate the present invention, but the present invention is not limited to this. Based on parts by weight and% by weight. Example 1 Partially neutralize palmitic acid 'in a stainless steel blending tank with a mixer, so that 10 parts of sodium salt of palmitic acid with 0.3 equivalent of sodium salt to all carboxyl groups, 88 parts of water, and polyethylene glycol as an emulsifier Two parts of the alcohol-type non-ionic surfactant were fully mixed and dispersed to obtain the erosion preventing agent of the present invention. In this regard, in order to confirm the erosion prevention performance, 100 parts of a plant-based disc material consisting of 60 parts of loquat soil, 39 parts of bark pile 'fertilizer and 1 part of plant-based weave were mixed, and 0.01 part of weeping love grass. , 0'01 parts of grass seed (ereeping red feScue) and 100 parts of water to obtain green base material. To this greening substrate 0.1, 5 kg of the erosion preventing agent of the present invention was added and mixed to obtain a mud-like substrate for the greening substrate. Furthermore, by mixing and dissolving 0.01 part of anionic polyacrylamide polymer coagulant with 10 parts of water, 10 kg of polymer coagulant aqueous solution obtained as an auxiliary agent, and adding it to the mud-like substrate, and thoroughly mixing, can obtain A greening base that fully structures the surrounding particles such as soil particles. From it, 0,05 m3 was taken to make a 10 cm thick test body, and it was dried in sunlight for about 7 days. Then, the test subjects were immersed in water every other day to investigate the erosion status or the collapse and seed germination and growth status of the greening substrate caused by the immersion in water. The results are shown in Table 1. Example 2 Partially neutralized palmitic acid 'in a stainless steel blending tank equipped with a stirrer. Diethanolamine palmitic acid diethanolamine with 0.6 equivalents of the total carboxyl group of diethanolamine salt. This paper applies the Chinese National Standard (CNS) A4 specification (2I). 〇X297 公 t). 12! In _____ I n-I — _ Ding 1111-Λ <-(锖 Please read the notes on the back first before filling in this page) Staff Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 413700 Λ7 _______B7 V. Description of the invention (9) " ~ ^ ~~; --- 12 parts, 84 parts of water, one part of an aqueous sodium polyacrylate solution as an emulsifier and one part of a polyethylene glycol surfactant The mixing is eliminated to obtain the erosion preventing agent of the present invention. In order to measure the performance, for the green substrate material used in Example 丨, 0.1 m3, the erosion preventing agent of the present invention was added and mixed with 0.5 kg to obtain a mud-like substrate. Further, the polymer coagulant aqueous solution used in Example 丨 was relatively 0.1 kg of mud-like base material was added and mixed, and 0 kg was added to obtain a greening base plate that sufficiently structured the soil particles and the like. From this, 0 05 m3 was taken, and a test specimen was prepared in the same manner as in Example 1 and its performance was measured. The results are shown in Table 1. Example 3 A partially unsaturated fatty acid mixture mixed with 50% oleic acid and 50% linoleic acid was partially neutralized, and in a mixing tank made of stainless steel with a stirrer, oleic acid and 25 parts of potassium salt of oleic acid mixture, 72 parts of water, 1 part of sodium polyacrylate aqueous solution as emulsifier and 1 part of polyethylene glycol type surfactant are thoroughly stirred and mixed to obtain the anti-money preventive agent of the present invention. In order to measure the performance, 2.5 kg of the corrosion inhibitor of the present invention was added to 0.1 m3 'of the greenery-based disk material used in Example 1 to obtain a mud-like substrate. Furthermore, 0.1 m3 of the polymer coagulant aqueous solution used in Example 1 was added and mixed with 0.1 m3 of the mud-like substrate to obtain a greening substrate that sufficiently structured the soil particles and the like. From this, 0.05 m3 was taken, and a test specimen was prepared in the same manner as in Example 1 and the performance was measured. The results are shown in Table 1. Example 4 A paper of coconut oil fatty acids containing lauric acid, myristic acid, caprylic acid, etc. was applied to Chinese paper standard (CNS) Λ4 specification (210X 297 g t)-13 1 Fill in this page). Packing · 413700 Λ 7 ------___ 5. Description of the invention (10). Partially neutralize it in a stainless steel mixing tank with a stirrer so that it is 0.4 equivalents of ammonium salt relative to the total carboxyl group. 15 parts of ammonium salt of coconut oil fatty acid, 83 parts of water, and 2 parts of aqueous sodium polyacrylate solution as emulsifier were thoroughly stirred and mixed to obtain the erosion preventing agent of the present invention. For performance measurement, the greening used in Example 1 was performed. Base material 0.1 m3 '2.5 kg of the erosion inhibitor of the present invention was added and mixed to obtain a mud-like substrate. Furthermore, the polymer coagulant aqueous solution used in Example 1 was added to and mixed with 0.1 m3 of the mud-like substrate 10 kg. A greening substrate was obtained which fully structured the soil particles such as soil particles. From this, 0.05 m3 was taken to prepare a test body in the same manner as in Example 1 and the performance was measured. The results are shown in Table 1. Example 5 Order of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives ------------------------- Order * (Thin first read the precautions of If and noodles before filling out this page) Make one containing stearic acid, palmitic acid Partially neutralize bovine fatty acids; in a stainless steel mixing tank with a stirrer, make 20 parts of triethanolamine salt of tallow acid, 76 parts of water and emulsifier as a emulsifier with 0.7 equivalents of tricarboxyamine relative to the total carboxyl group. 4 parts of an aqueous sodium acrylate solution were thoroughly stirred and mixed to obtain the erosion preventing agent of the present invention. In order to measure the performance, for the green base plate used in Example j, 0.1 m3, 2.5 kg of the erosion preventing agent of the present invention was added and mixed * A mud-like substrate was obtained. Further, 10 kg of the polymer coagulant aqueous solution used in Example 1 was added and mixed with respect to the mud-like substrate 0 Jm3 to obtain a greening substrate that sufficiently structured the soil particles and other aggregates. 0.05 m3, a test specimen was prepared in the same manner as in Example 丨 and performance measurements were performed. The results are shown in Table 1. Comparative Example 1 4 60 parts of arable soil, 39 parts of bark compost, and 1 part of plant fiber 14 413700 Λ7 B7 V. Description of the invention (11 ). 100 parts of hyaluronic base material is composed of 0 ~ 01 parts of creeping red fescue, 0. 01 parts of weeding love gracs and 10 parts of water, mixed with the currently used asphalt based erosion prevention 0,05 parts of agent (relative to 100 parts of plant-based disc material, and for the purpose of improving financial surplus, this amount is generally 1 to 5 times) to obtain a mud-like substrate 6 for greening substrates, thereby making the anionic type Polypropylene amine-based polymer coagulant 0.001 part of polymer coagulant aqueous solution obtained by mixing and dissolving with water as a supplement, added to the mud-like substrate and stirred well to obtain a sufficient soil A greening base structured by particles and other aggregates. From it, 0.05 m3 was taken to make a 10 cm thick test body, and it was dried for about 7 days in sunlight. Then, the test body was immersed in water every other day to investigate the erosion status of the greening substrate caused by water immersion or whether it was damaged and the seeds were damaged. The results are shown in Table 1. β Comparative Example 2 Printed by the Central Laboratories of the Ministry of Economic Affairs and the Consumer Cooperatives 11 I. J 5 11 ~ Order · (铕 Please read the notes on the back and fill in this section before filling in this Page) According to the example described in the specification of Japanese Patent Application Laid-Open No. 4-93419, 1.2 parts of NaCl was added and mixed with 30 parts of 30% silicic acid sol with 30% Si03 concentration, and then water and sulfuric acid were added to form a total amount of pH 6,5. 50 parts of a silicic acid sol aqueous dispersion was allowed to gel at room temperature to obtain an erosion preventive agent of a conventional technique. In order to determine its performance, 100 parts of the mixture of 100 parts of soil, 0.01 parts of creeping red fescue and 0.01 parts of weeping love grass are mixed, and 50 parts of the erosion prevention agent of the conventional technology is added. A greening substrate of 0.1 m3 was obtained. From it, 0_05 m3 was taken to make a 10 cm thick test body, and it was dried in sunlight for about 7 days. Then, the test subject was immersed in water every other day to investigate the erosion state or the breakage of the greening substrate caused by the water immersion and the germination and growth state of the seeds. The results are shown in Table 1. This paper size applies to the Chinese National Standard (CNS) A4 pit (210 × 29Ίmm) · 15,-413700 Λ7 __B7 V. Description of the invention (丨 2) Table 1 The presence or absence of collapse (after the 30th passage) Seed germination status (Germination rate) Fertility state after germination (after 30 days) 1 stability 90% good 2 stability 90% good implementation 3 stability 90% good example 4 stability 90% good 5 stability 90% good stability 3 5% bad 80% Broken 50% Defective (铕 Please read the notes on the back before filling this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives [Effects of the Invention] Greening substrate forming method and water resistance forming the water-resistant pellet structure of the present invention The water-repellent erosion preventing agent has the following effects. (1) The aforementioned impregnated water-resistant erosion inhibitor containing fatty acids and fatty acid salts as ingredients is mixed with a mud-like green substrate, and then mixed with an aggregating agent aqueous solution to form granules, so that only the soil contained in the mud-like substrate is used. The particles become unstable when charged, so they can promote the agglomeration of the mud-like substrate. (2) Using the aforementioned hydrophobic water-resistant erosion-preventive agent, which is peculiar to the fatty acid, makes the coated soil particles agglomerate, which can suppress the enrichment of clay particles caused by long-term rainfall or water infiltration, and can prevent greening of the substrate. Deterioration of erosion resistance due to softening. This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) -16-413700 Λ7 ----- 扪 ____ 5. Description of the invention (13) (3) It can promote the growth of plants. The anti-soaking and water-resistant erosion preventive agent of the greening substrate is composed of fatty acids and fatty acid salts, so it can fully impart hydrophobicity and hydrophilicity to the greening substrate. The greening substrate has contradictory functions of water retention and water permeability. Therefore, it can promote the germination and growth of plant seeds in greening substrates. "(4) High safety The anti-soaking water erosion preventing agent used in the greening substrates of the present invention is composed of fatty acids, so it has excellent biodegradability and high safety. . I----III Shiyi—Taste I—Order · (Rabbit first reads " * Notes on the side before filling out this page) The Central Standards Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives printed this paper to apply Chinese national standards (CNS) A4 specifications (2! 0 × ^ 97 male splash)

Claims (1)

^ 4 月 3 炫ii委員明示’本究妗正後是否變更原實質内容 經濟部中央標率局属工消费合作社印裂 六、申請專利範圍 第85109030號專利再審查案申請專利範圍修正本 修正日期:88年3月 1· 一種造成綠化基盤之方法,其係含有以下步驟: (1) 於混練槽内將含有黏土、淤泥等之固體粒子的綠化 基盤材與水混合而形成泥狀綠化基材; (2) 將兩親媒性材料所構成之耐浸水性侵蝕,防止劑添加 於前述泥狀綠化基材中,並混合攪拌,而形成泥狀 材; (3) 將前述泥狀材以泵浦壓送至吐出口,並導入預先安 裝於前述吐出口之攪拌筒内; (4) 將陰離子型之聚丙烯醯胺系高分子凝集劑水溶液導 入前述攪拌筒内;及 (5) 將步驟(3)導入之含有泥狀綠化基材及耐浸水性侵蝕 防止劑的前述泥狀材與步驟(4)導入之陰離子型之聚 丙烯醯胺系高分子凝集劑水溶液,於前述攪拌筒内 混合攪拌而得之混合物*立即進行團粒反應並同時 喷吹至施工面; 又,前述耐浸水性侵蝕防止劑係由以下所構成: .每1個羧基碳數7-17個之脂肪酸的疏水性成分(A)、及 每1個羧基碳數7-17個之脂肪酸的鹼金屬鹽、胺鹽或銨 鹽的親水性成分(B),且成分(A)與成分(B)之羧基當量 比為 20/80-80/20 » 2.如申請專利範圍第1項之方法,其中親水性成分(B)為 每1個羧基碳數7-Π個之脂肪酸的烷醇胺鹽或銨鹽。 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨〇 χ 297公釐) ^ W------訂--------線 « % (紫先.的讀背面之注意事項再填寫本S ) 18^ April 3 Hyunii member stated clearly whether to change the original substance after the Ministry of Economic Affairs ’Central Standards Bureau was affiliated to the Industrial and Consumer Cooperatives. VI. Application for Patent Scope No. 85109030 Patent Reexamination Application Scope of Application for Amendment of this Patent Amendment Date : March 1988 1. A method for creating a green substrate, which includes the following steps: (1) mixing a green substrate material containing solid particles such as clay and silt with water in a mixing tank to form a mud-like green substrate ; (2) Adding the water-resistant erosion resistance composed of the amphiphilic material, the preventive agent is added to the aforementioned muddy green substrate, and mixed and stirred to form a mud-like material; (3) the aforementioned mud-like material is pumped The pump pressure is sent to the discharge port, and is introduced into the stirring cylinder previously installed in the discharge port; (4) an anionic polyacrylamide-based polymer coagulant aqueous solution is introduced into the foregoing stirring cylinder; and (5) the step ( 3) The above-mentioned mud-like material containing the mud-like greening base material and the anti-soaking water erosion inhibitor and the anionic polyacrylamide-based polymer coagulant aqueous solution introduced in step (4) are placed in the agitating cylinder. The mixture obtained by internal mixing and stirring * immediately undergoes agglomeration reaction and is simultaneously sprayed to the construction surface; In addition, the aforesaid anti-soaking water erosion prevention agent is composed of the following:. Hydrophobicity of fatty acids of 7-17 per carboxyl carbon The hydrophilic component (B) of the sexual component (A) and the alkali metal salt, amine salt or ammonium salt of a fatty acid having 7 to 17 carboxyl carbon atoms, and the carboxyl equivalent of the component (A) and the component (B) The ratio is 20 / 80-80 / 20 »2. The method according to item 1 of the patent application range, wherein the hydrophilic component (B) is an alkanolamine salt or an ammonium salt of a fatty acid having 7 to Π carbon atoms per carboxyl group. . The size of this paper applies the Chinese National Standard (CNS) A4 specification (2 丨 〇χ 297mm) ^ W ------ Order -------- Line «% (Note on the back of Zi Xian. Matters refill this S) 18 ^ 4 月 3 炫ii委員明示’本究妗正後是否變更原實質内容 經濟部中央標率局属工消费合作社印裂 六、申請專利範圍 第85109030號專利再審查案申請專利範圍修正本 修正日期:88年3月 1· 一種造成綠化基盤之方法,其係含有以下步驟: (1) 於混練槽内將含有黏土、淤泥等之固體粒子的綠化 基盤材與水混合而形成泥狀綠化基材; (2) 將兩親媒性材料所構成之耐浸水性侵蝕,防止劑添加 於前述泥狀綠化基材中,並混合攪拌,而形成泥狀 材; (3) 將前述泥狀材以泵浦壓送至吐出口,並導入預先安 裝於前述吐出口之攪拌筒内; (4) 將陰離子型之聚丙烯醯胺系高分子凝集劑水溶液導 入前述攪拌筒内;及 (5) 將步驟(3)導入之含有泥狀綠化基材及耐浸水性侵蝕 防止劑的前述泥狀材與步驟(4)導入之陰離子型之聚 丙烯醯胺系高分子凝集劑水溶液,於前述攪拌筒内 混合攪拌而得之混合物*立即進行團粒反應並同時 喷吹至施工面; 又,前述耐浸水性侵蝕防止劑係由以下所構成: .每1個羧基碳數7-17個之脂肪酸的疏水性成分(A)、及 每1個羧基碳數7-17個之脂肪酸的鹼金屬鹽、胺鹽或銨 鹽的親水性成分(B),且成分(A)與成分(B)之羧基當量 比為 20/80-80/20 » 2.如申請專利範圍第1項之方法,其中親水性成分(B)為 每1個羧基碳數7-Π個之脂肪酸的烷醇胺鹽或銨鹽。 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨〇 χ 297公釐) ^ W------訂--------線 « % (紫先.的讀背面之注意事項再填寫本S ) 18 413700 λ8 Β8 C8 _____D8 六、申請專利範圍 ~~.一— - 3.如申請專利範圍第1項之方法’其中於步驟4將前述高 分子凝集劑水溶液導入前述攪拌筒内之同時,並將空 氣導入前述攪拌筒内》 4‘一種对浸水性侵蝕防止劑,係由以下所構成:每丨個羧 基破數7-17個之脂肪酸的疏水性成分(A)、及每1個羧 基碳數7-17個之脂肪酸的鹼金屬鹽、胺鹽或銨鹽的親 水性成分(B) ’且成分(A)與成分(b)之羧基當量比為 20/80-80/20 « 5.如申請專利範圍第4項之耐浸水性侵蝕防止劑,其中親 水性成分(B)為每1個羧基碳數7-17個之脂肪酸的烷醇 胺鹽或銨鹽。 經濟部中央標準局貝工消費合作社印製 本紙張1適用中國國家標準(CNS ) Α4·(加X297公釐) 19^ April 3 Hyunii member stated clearly whether to change the original substance after the Ministry of Economic Affairs ’Central Standards Bureau was affiliated to the Industrial and Consumer Cooperatives. VI. Application for Patent Scope No. 85109030 Patent Reexamination Application Scope of Application for Amendment of this Patent Amendment Date : March 1988 1. A method for creating a green substrate, which includes the following steps: (1) mixing a green substrate material containing solid particles such as clay and silt with water in a mixing tank to form a mud-like green substrate ; (2) Adding the water-resistant erosion resistance composed of the amphiphilic material, the preventive agent is added to the aforementioned muddy green substrate, and mixed and stirred to form a mud-like material; (3) the aforementioned mud-like material is pumped The pump pressure is sent to the discharge port, and is introduced into the stirring cylinder previously installed in the discharge port; (4) an anionic polyacrylamide-based polymer coagulant aqueous solution is introduced into the foregoing stirring cylinder; and (5) the step ( 3) The above-mentioned mud-like material containing the mud-like greening base material and the anti-soaking water erosion inhibitor and the anionic polyacrylamide-based polymer coagulant aqueous solution introduced in step (4) are placed in the agitating cylinder. The mixture obtained by internal mixing and stirring * immediately undergoes agglomeration reaction and is simultaneously sprayed to the construction surface; In addition, the aforesaid anti-soaking water erosion prevention agent is composed of the following:. Hydrophobicity of fatty acids of 7-17 per carboxyl carbon The hydrophilic component (B) of the sexual component (A) and the alkali metal salt, amine salt or ammonium salt of a fatty acid having 7 to 17 carboxyl carbon atoms, and the carboxyl equivalent of the component (A) and the component (B) The ratio is 20 / 80-80 / 20 »2. The method according to item 1 of the patent application range, wherein the hydrophilic component (B) is an alkanolamine salt or an ammonium salt of a fatty acid having 7 to Π carbon atoms per carboxyl group. . The size of this paper applies the Chinese National Standard (CNS) A4 specification (2 丨 〇χ 297mm) ^ W ------ Order -------- Line «% (Note on the back of Zi Xian. Please fill in this S) 18 413700 λ8 Β8 C8 _____D8 VI. Application scope of patents ~~. I—-3. Method of applying for the scope of patent application No. 1 'wherein the aforementioned polymer coagulant aqueous solution is introduced into the aforementioned agitating cylinder in step 4 At the same time, the air is introduced into the agitating cylinder. 4'A water-repellent corrosion inhibitor is composed of the following: a hydrophobic component (A) of a fatty acid having 7-17 broken carboxyl groups, and The hydrophilic component (B) 'of alkali metal salt, amine salt or ammonium salt of fatty acid having 7-17 carboxyl carbons per 1 and the carboxyl equivalent ratio of component (A) to component (b) is 20 / 80-80 / 20 «5. The impregnating agent for preventing water intrusion according to item 4 of the patent application scope, wherein the hydrophilic component (B) is an alkanolamine salt or an ammonium salt of a fatty acid having 7-17 carboxylic carbons per carboxyl group. Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This paper 1 complies with Chinese National Standards (CNS) Α4 · (plus X297 mm) 19
TW085109030A 1995-01-17 1996-07-24 Method of establishing a vegetation base comprising a water-resistant aggregated structure, and a waterproof, anti-erosion agent TW413700B (en)

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