TW402634B - Detergent composition - Google Patents

Abstract

A detergent composition in powder is offered excellent in detergency and prevention of solid soil redeposition. This composition contains an inorganic phosphate, a copolymer of acrylic acid and maleic acid, polyethylene glycol and Glauber's salt each at a specific content together with a surfactant and an alkali.

Description

ui\TYPE\MFy\JKP-2.DOC\4 丨1-·丨 結晶矽酸鹽 秒酸納 蘇打粉 STPP 〇 1' 聚丙歸酸 AA-MA共聚物 LAS 成份(Wt%) OJ 1—i 14.9 S 1 Ο <_·=- U) c: 1—* 14.9 M s 1 ο Im oo K3 〇-> υ； 1—1 \〇 to \〇 o •LA 1 ο Ln U) Ui )—* )—* •Ό C\ o U\ 1 ο Ui U) C； 1—* 8.76 0.07 1 ο·〇7 Ui LO 1—1 o 12.1 ] 1 σ> 00 e: 1—1 14.9 >-—1 o Lh 1 Ο *Ui K) Lh H—* 比較例 LO Ui ·: 1—* 14.9 〇 LAI 1 1 to LO l/l c; 1—-» 14.9 1 1 Ο Ui U) OO c; 1—^ 14.9 〇 Im ο Lai 1 私 LO 1 1—* ON •s 1 s >2 卡K盏(、v+、v^+b ) Λ-i 5贫洄芩衅宣一沙斗外嫜jf芪韙令j 5羧命赛。私淬迹奔今沣迹崦桊聆拉妄碲窆沣昂禽令了洄钋芩沐2卡-私奇 >^迹據0%^薄^。 五 、發明説明（ A7 B7' 發明之技術領域 本發明係關於布料之㈣清潔劑组合物。 先前技藝 效能之一償螯合劑，促劑 使冷物及其他清潔劑組份分散之高分子量化合物驗， 清潔劑组份作用之—係抑❹垢自布料移除時之再 積。呈現此作用之組份之實例包含三聚鱗酸納、聚酸 及聚乙二醇。至於使用此等組 -、 去心担-、人 刀夂先則技藝I實例，所？| 用者局揭W U.S.P.NO.觀693中之，，具有改善之物理 質及於冷水中之溶解度之清潔劑組合物,,（含界面活性劑， 三嶙酸納聚乙二醇及聚丙晞酸）。然而，此等組合物在 抑制固體污物再沈積之效能上不足。 發明之揭示 本發明者曾進行密集之研究以解決上述之問題。結果， 發現上狀問題可藉由將無機磷酸鹽，聚乙二醇，丙晞酸 經濟部中央標準局員工消費合作社印製 及馬來酸（共聚物’及Glauber’s鹽依特定比例捧合，再添 加界面活性劑及鹼於其中解決。 、 據此，本發明提供含15至3〇 wt%之無機轉酸鹽、〇仍 至2 〇 Wt%之丙烯酸及馬來酸之共聚物，0.05至2.0加％之 聚乙二醇m〇wt%之Glauber，s鹽，界面活性劑及鹼 之粉末狀清潔劑组合物。 換言之，本發明係針對包括界面活性劑及鹼之清潔劑组 -4 _ 本紙張尺度適财國國家) M規格（別幻97公楚） 經濟部中央標準局員工消費合作社印製ui \ TYPE \ MFy \ JKP-2.DOC \ 4 丨 1- · 丨 Crystalline Silicate Sodium Acid Soda Powder STPP 〇1 'Polyaluminum AA-MA Copolymer LAS Composition (Wt%) OJ 1—i 14.9 S 1 Ο < _ · =-U) c: 1— * 14.9 M s 1 ο Im oo K3 〇- >υ; 1—1 \ 〇to \ 〇o • LA 1 ο Ln U) Ui) — * ) — * • Ό C \ o U \ 1 ο Ui U) C; 1— * 8.76 0.07 1 ο · 〇7 Ui LO 1-1 o 12.1] 1 σ > 00 e: 1-1 14.9 >-1 o Lh 1 Ο * Ui K) Lh H— * Comparative Example LO Ui ·: 1— * 14.9 〇LAI 1 1 to LO l / lc; 1—- »14.9 1 1 Ο Ui U) OO c; 1— ^ 14.9 〇Im ο Lai 1 Private LO 1 1— * ON • s 1 s > 2 cards K (, v +, v ^ + b) Λ-i 5 poor provocation Xuan a sand bucket outside jf Qi 韪 令 j 5 Carboxy. The private traces of this time, the traces of the dead, the fascination, and the frightened birds, made the Mu 2 Cards-Private Qi > ^ Track data 0% ^ thin ^. V. Description of the invention (A7 B7 ') Technical Field of the Invention The present invention relates to a cloth cleaner composition. One of the prior art performances is chelating agent, accelerator, which disperses cold matter and other detergent components. The role of the detergent component is to prevent the build-up of scale when it is removed from the cloth. Examples of components exhibiting this effect include sodium trimeric phosphonate, polyacid, and polyethylene glycol. As for the use of these groups- , To worry about, the first example of the skill of the knife, so? | User Bureau Reveal W USPNO. 693, which has a cleaner composition with improved physical properties and solubility in cold water ,, (Contains a surfactant, sodium polyethylene glycol triacetate, and polypropionic acid.) However, these compositions are insufficient in their ability to inhibit the redeposition of solid dirt. Disclosure of the Invention The inventors have conducted intensive research to The above problems were solved. As a result, it was found that the above problems can be printed by the inorganic phosphate, polyethylene glycol, and the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs and the maleic acid (copolymer 'and Glauber's salt according to specific Proportionality, Add surfactant and alkali to solve it. Based on this, the present invention provides copolymers of acrylic acid and maleic acid containing 15 to 30 wt% of inorganic transacids, 0 to 20 Wt% of acrylic acid and maleic acid, 0.05 to 2.0 Powder cleaner composition with Glauber, s salt, surfactant and alkali added with polyethylene glycol at 0% by weight. In other words, the present invention is directed to a detergent group including surfactant and alkali-4 _ This Paper scale is suitable for countries with rich countries) M specification (Biemag 97), printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

Mmu B7 五、發明説明（2 ) 合物，其特點爲尚包括15至30 wt%之無機磷酸鹽，0.05 至2.0 wt%之丙烯酸及馬來酸之共聚物，〇·〇5至2.0 wt%之 聚乙二醇及15至40 wt%之Glauber’s鹽或硫酸鈉。 較好本發明之清潔劑組合物尚含有〇j至5 wt%之結晶 砍酸鹽，當其在20 X：下以〇.1 wt%之速率分散於去離子水 中時，可提供11或以上之最大値pH値，且此驗性度需要 5氅升之HC1 0· 1 N水溶液，以使上述1公升水性分散液之 PH値降低至10。 本發明之清潔劑組合物較好含10至40 wt%之界面活性 劑及10至3 0 wt%之驗。 較好無機磷酸鹽爲三聚磷酸鹽，正磷酸鹽或焦磷酸鹽， 且鹽之平衡離子爲鹼金屬。 丙烯酸及馬來酸共聚物之特殊實例包含丙烯酸/馬來酸 共聚物，丙烯酸/馬來酸酐共聚物及其部份鹽。 依本發明，含有界面活性劑，驗，無機磷酸鹽及 Glauber's鹽之含▲粦清潔劑係藉由添加丙晞酸及馬來酸之共 聚物及聚乙二醇於其中改善。 發明之詳細敘述 本發明中所用無機磷酸鹽之較佳實例除三聚磷酸鹽外， 爲正磷酸鹽與焦磷酸鹽。全部磷酸鹽中之三聚磷酸鈉之適 當含量至少爲80 wt%，同時正鱗酸及焦嶙酸之含量分別爲 1至5 wt%及2至5 wt% (含量：以無水物質爲準）。至於 平衡離子，較好者爲鹼金屬，且更好者爲鈉及/或鉀。清 潔劑组合物中之無機磷酸鹽含量爲15至3〇 wt%，較好爲 -5- 本紙張尺度顧中國CNS) A视格（21GX297公楚）~~—- —~ (讀先閱讀背面之注意事項再填寫本頁)Mmu B7 5. Description of the invention (2) The compound is characterized by including 15 to 30 wt% of inorganic phosphate, 0.05 to 2.0 wt% of copolymer of acrylic acid and maleic acid, 0.05 to 2.0 wt% Polyethylene glycol and 15 to 40 wt% of Glauber's salt or sodium sulfate. Preferably, the detergent composition of the present invention still contains 0 to 5 wt% of crystalline cholate salt. When it is dispersed in deionized water at a rate of 0.1 wt% at 20X :, it can provide 11 or more The maximum pH is 値, and this test requires 5 liters of HC1 0 · 1 N aqueous solution to reduce the pH 上述 of the above 1 liter aqueous dispersion to 10. The detergent composition of the present invention preferably contains 10 to 40% by weight of a surfactant and 10 to 30% by weight. Preferably, the inorganic phosphate is tripolyphosphate, orthophosphate or pyrophosphate, and the counter ion of the salt is an alkali metal. Specific examples of acrylic acid and maleic acid copolymers include acrylic acid / maleic acid copolymers, acrylic acid / maleic anhydride copolymers, and partial salts thereof. According to the present invention, the cleaning agent containing surfactant, inorganic phosphate and Glauber's salt is improved by adding a copolymer of malonic acid and maleic acid and polyethylene glycol therein. DETAILED DESCRIPTION OF THE INVENTION Preferred examples of the inorganic phosphate used in the present invention are, besides tripolyphosphate, orthophosphate and pyrophosphate. The appropriate content of sodium tripolyphosphate in all phosphates is at least 80 wt%, and the content of ortho-scale acid and pyrogallic acid are 1 to 5 wt% and 2 to 5 wt%, respectively (content: based on anhydrous substance) . As for the counter ion, an alkali metal is preferred, and sodium and / or potassium is more preferred. The content of inorganic phosphate in the detergent composition is 15 to 30% by weight, preferably -5- The paper size is based on China CNS) A Vision (21GX297) Chu (Read the first read on the back) (Notes for filling in this page)

經濟部中央標準局員工消費合作社印製 CNS ) Α4規格（210X297公釐） 402634 at -------B7 五、發明説明（3 ) ' ' 17至25 wt% (含量：以無水物質爲準）。 除多螯合作用外，本發明所用丙埽酸及馬來酸之共聚 .物當呈現使固體淳物粒子自衣物分散於洗滌槽中之作用， 且另一作用爲抑制此等粒子再沈積（再成垢）於布料之上。 針對此目的較好摻合分子量爲數百至數十萬，且以下式（ι) 代表之共聚物。通常，此共聚物係以無規聚合製備。 '(Zi)m-(Z2)n--(m+2n)M ⑴ 上式中，Z!代表丙烯酸原始之單體單元；Z2爲馬來酸或 馬來酸酐原始之另一單體單元；m&n係可提供分子量 (m+n)爲數百至十萬之數目，且比率m:n爲8:2至5:5 ;且 Μ爲Na，K , NH4或Η。此共聚物可爲部份鹽之形式。 一分子中之諸Μ爲Na，Κ或ΝΗ4與Η之混合物。 清潔劑组合物中之式（1)之共聚物含量爲〇 〇5至2加％。 此聚合物之分子量較好在2〇〇至1〇〇,〇〇〇之間。 較好本發明中所用聚乙二醇爲平均分子量爲5,000至 15,000者。組合物中之聚乙二醇含量爲〇 至2加％，且 較好爲0.1至1.0 Wt%。 本發明中所用之Giauber's鹽（其爲硫酸鈉之俗名）具有提 升洗滌槽鹽強度之作用，且如其他鹼一樣，在乾燥後形成 清潔劑粒子之骨架。較好，组合物中Glauber's鹽之含量爲 15至40 Wt%，且較好爲18至35 wt% (含量：以無水物質 爲準）。 本發明中’組合物之清潔力可藉由添加結晶矽酸鹽進— 步改吾。本發明中所用結晶矽酸鹽係於20 °C下依0.1 wt0/。 本紙張尺度適用中 (請先鬩讀背面之注意事項再填寫本頁}Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China (CNS) A4 specification (210X297 mm) 402634 at ------- B7 V. Description of the invention (3) '' 17 to 25 wt% (content: based on anhydrous substance as quasi). In addition to multi-chelation, the copolymerization of propionic acid and maleic acid used in the present invention has the effect of dispersing solid particles from the laundry in the washing tank, and another function is to inhibit the redeposition of these particles ( Then scale) on the fabric. For this purpose, it is preferable to blend a copolymer having a molecular weight of several hundreds to several hundreds of thousands and represented by the following formula (ι). Generally, this copolymer is prepared by random polymerization. '(Zi) m- (Z2) n-(m + 2n) M ⑴ In the above formula, Z! Represents the original monomer unit of acrylic acid; Z2 is another monomer unit of maleic acid or maleic anhydride; m & n series can provide numbers with a molecular weight (m + n) of several hundreds to 100,000, and the ratio m: n is 8: 2 to 5: 5; and M is Na, K, NH4 or fluorene. This copolymer may be in the form of a partial salt. M in one molecule is a mixture of Na, K or NH4 and hydrazone. The content of the copolymer of formula (1) in the detergent composition is from 0.05 to 2 plus%. The molecular weight of this polymer is preferably between 2000 and 100,000. The polyethylene glycol used in the present invention is preferably one having an average molecular weight of 5,000 to 15,000. The polyethylene glycol content in the composition is 0 to 2 plus%, and preferably 0.1 to 1.0 Wt%. The Giauber's salt (which is the common name of sodium sulfate) used in the present invention has the effect of increasing the strength of the salt in the washing tank, and, like other alkalis, forms the skeleton of the detergent particles after drying. Preferably, the content of Glauber's salt in the composition is 15 to 40 Wt%, and preferably 18 to 35 wt% (content: based on anhydrous substance). The cleaning power of the composition of the present invention can be further improved by adding crystalline silicate. The crystalline silicate used in the present invention is 0.1 wt0 / at 20 ° C. This paper size is applicable (Please read the precautions on the back before filling this page}

經濟部中央標準局員工消費合作社印製 40^634 at --— _______ B7 五、發明説明（4 ) 之速率分散於去離子水中時，可得到i 1或以上之最大pH 値者’且需要5毫升之HC1 〇. 1 N水溶液之極佳鹼度’使1 升之上述水性分散液之pH値降低至1 〇。此種結晶梦酸鹽 與結晶鋁矽酸鹽不同。 結晶ί夕酸鹽特別好之實例爲具有下列組合物者： x(M20).y(Si02).2(]y[em0n)-w(H20) (Π) 其中Μ代表週期表中ja族之元素，最好爲Κ及/或 Na ; Me代表選自週期表中na，Hb，IIIa，IVa及VIII 族中之一種或多種元素，較好爲Mg及/或Ca ; y/x爲0.5 至 2.6 ; z/x 爲 0_01 至 〇 9 ; w 爲 〇 至 2〇 ;且 n/m 爲 〇_5 至 2.0。 以一般式（II)表示之結晶碎酸鹽可以參照JP-A 7-89712製 成。 而且，具下列組合物之結晶秒酸鹽可適當的使用： M20.xi(Si02).y'(H20) (ΠΙ) 其中Μ代表鹼金屬，最好爲κ及/或Na ; x'爲1,5至 2.6 ;且y'爲0至20，最好實質上爲0。 一般式（III)之結晶矽酸鹽係敘述於JP-A 60-227895號， Phys. Chem. Glasses. 7, 127-138 (1996), Z. Kristallogr., 129 第 396-404 頁（1969)，等等中。而且，如"Na-SKS-6TM”（δ-40 ^ 634 at --- _______ B7 printed by the Central Consumers Bureau of the Ministry of Economy B7 V. Description of the invention (4) When the rate is dispersed in deionized water, a maximum pH of 1 or above can be obtained, and 5 is required The excellent alkalinity of milliliters of HC1 0.1 N aqueous solution lowered the pH of 1 liter of the above-mentioned aqueous dispersion to 10. This crystalline dream salt is different from crystalline aluminosilicate. A particularly good example of a crystalline salt is one having the following composition: x (M20) .y (Si02) .2 (] y [em0n) -w (H20) (Π) where M represents a member of the ja group in the periodic table Element, preferably K and / or Na; Me represents one or more elements selected from the group consisting of na, Hb, IIIa, IVa and VIII of the periodic table, preferably Mg and / or Ca; y / x is 0.5 to 2.6; z / x is 0_01 to 〇9; w is 0 to 20; and n / m is 0_5 to 2.0. The crystalline crushed acid salt represented by the general formula (II) can be prepared by referring to JP-A 7-89712. Moreover, a crystalline second salt having the following composition can be suitably used: M20.xi (Si02) .y '(H20) (ΠΙ) where M represents an alkali metal, preferably κ and / or Na; x' is 1 , 5 to 2.6; and y 'is 0 to 20, preferably substantially 0. The crystalline silicate of general formula (III) is described in JP-A 60-227895, Phys. Chem. Glasses. 7, 127-138 (1996), Z. Kristallogr., 129 pages 396-404 (1969) , And so on. Moreover, such as " Na-SKS-6TM "(δ-

Na2Si2〇5)(Hoechst AG)之粉狀或粒狀產物均可使用。本發明 中，結晶矽酸鹽之較佳用量爲0至5 wt%，較好爲組合物 中之 0.1 至 5 wt°/〇。 至於本發明中使用之界面活性劑，爲含有陰離子性界面 -7- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) ' ~ ' (諳先閩讀背面之注意事項再填寫本頁)Na2Si205) (Hoechst AG) can be used in powder or granular form. In the present invention, the preferred amount of crystalline silicate is 0 to 5 wt%, and preferably 0.1 to 5 wt ° / 0 in the composition. As for the surfactant used in the present invention, it contains an anionic interface. 7- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) '~' (谙 Please read the precautions on the back before filling in this page)

402634 A7 B7 五、 發明説明（ 活性劑當作主要成份者。本發明中 +货Λ甲特別好者爲使用烷基鏈 平具有12至14個碳原子之亩鍅 * 繾心基丰•鹽，或具有12 至18個碳原子之硫酸燒醋。黾$人承f7 -·於千衡離子，較好爲鹼金 屬，且更好爲鈉及/或卸。除此外，其可含有小量之由牛 油或椰子生成之脂肪酸鹽。 本發明中，陰離子界面活性劑之含量爲1〇至4〇 wt% ’，較好爲 15 至 30 wt%。 10 至於本發明中所用之鹼，除上述之結晶矽酸鹽及無機磷 酸鹽外，較好添加―般已知之驗。此驗之實例包含驗金屬 碳酸鹽，如一般稱爲密灰或輕灰之碳酸鈉，及無定形鹼金 屬矽酸鹽，如JIS No. 1，Νο· 2及N〇. 3。此等無機鹼可有 效地在清潔劑乾燥步驟中形成顆粒骨架，且因此確保得到 相對硬且高流動之清潔劑。组合物中鹼之含量較好爲 至30 wt%，且更好爲15至25 wt%。 經濟部中央操準局員工消費合作社印製 知 基 離 及 機 或 咯 活 乙 酶 除上述成份外，本發明之清潔劑组合物可含有公開已 比例之公開已知成份，例如，界面活性劑，如聚氧伸乙 燒基醚之非離子界面活性劑，陽離子界面活性劑及兩性 子界面活性劑之多價螯合劑如稱爲沛石之結晶銘秒酸鹽 JP_A 7-89712及JP-A 60-227895中敘述之結晶矽酸鹽；有 多價螯合劑如乙二胺四乙酸（EDTA )及擰檬酸鹽；分散劑 顏色轉移抑制劑，如羧基甲基纖維素（CMC);聚乙烯吡 烷酮（PVP)及聚乙烯醇（pvA);漂白劑如過碳酸鋼；漂白 化劑如JP-A 6-316700中所述之有機過酸前驅物及四乙醯 二胺（TAED);酶如朊酶，纖維素酶，澱粉酶及脂肪酶 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X297公釐） 五 402634 ---、發明説明（6 A7 B7 經濟部中央榇準局員工消費合作社印製 :疋劑如·化合物及亞疏酸鈉；聯苯基«類之榮光劑染 料；矽酮’氧化矽類等等之消泡劑；&amp;氧化劑；藍化劑； 及香料。更特別地是JP_A 8-218〇93中所述者可用作上、狀、 添加劑。 k &lt; 清潔劑組合物可以以公開已知之方法製成。適當之製造 條件可由熟習本技藝者，依组合物輕易地選定。 ° 本發明 &lt; 組合物具有高的清潔力，及再者，抑制固體污 物再沈積之極佳效能。 a [進行本發明之模式] 實例1及2及比較例1至4 由2〇公斤之LAS，〇.5公斤之AA-MA共聚物，〇 5公 斤（聚乙二醇，20公斤之三聚磷酸鈉，10公斤之矽酸鈉 nS N〇. 2，14_9克之蘇打粉，20公斤之Glauber's鹽及0.3 公斤之螢光劑染料製備因成份爲6〇%之水性漿料。漿料噴 霧乾燥後，所得之粉末飼入垂直掺合機中。再添加3公斤 沸石，1.5公斤之結晶矽酸鹽及丨公斤之酶後，混合摻合 物，因此得到如表i中所示之實例1之粉末狀清潔劑組合 物（鬆岔度：0.35克/升），平均粒徑：4〇〇微米）。依相同 方式製備實例2及比較例1至4之组合物。 因此製得之各組合物以下列方法進行清潔力試驗及抗再 沈積試驗。表1列出結果。 〈清潔力試驗&gt; (人造污垢布料之製備） 以下列组合物之人造污垢溶液人工污染布料。污損係藉 9- Μ氏張尺度適财目ϋ家標準（CNS ) Α4規格（210X297公董） (請先聞讀背面之注意事項再填寫本頁)402634 A7 B7 V. Description of the invention (The active agent is regarded as the main component. The one + + Λ in the present invention is particularly good for the use of alkyl chain flat acres with 12 to 14 carbon atoms 鍅 * 缱 心 基丰 • 盐, Or sulfuric acid burning vinegar with 12 to 18 carbon atoms. 黾 ren f7-is a thousand ions, preferably an alkali metal, and more preferably sodium and / or unloaded. In addition, it may contain a small amount of Fatty acid salt produced from tallow or coconut. In the present invention, the content of the anionic surfactant is 10 to 40 wt%, preferably 15 to 30 wt%. 10 As for the base used in the present invention, except for the above In addition to the crystalline silicate and inorganic phosphate, it is better to add-generally known tests. Examples of this test include metal carbonates, such as sodium carbonate commonly known as dense or light gray, and amorphous alkali metal silicate. Salts, such as JIS No. 1, No. 2 and No. 3. These inorganic bases are effective in forming a granular skeleton in the cleaning agent drying step, and thus ensure that a relatively hard and highly flowing cleaning agent is obtained. In the composition The content of alkali is preferably up to 30 wt%, and more preferably 15 to 25 wt%. In addition to the above ingredients, the cleansing composition of the present invention may be printed by employees' consumer cooperatives. In addition to the above-mentioned ingredients, the detergent composition of the present invention may contain publicly known ingredients in published proportions, for example, a surfactant such as polyoxyethylene Non-ionic surfactants based on ethers, polyvalent chelating agents of cationic surfactants and amphoteric surfactants, such as the crystals described in pesite's crystalline succinates JP_A 7-89712 and JP-A 60-227895 Silicates; sequestrants such as ethylenediaminetetraacetic acid (EDTA) and citrate; dispersant color transfer inhibitors, such as carboxymethyl cellulose (CMC); polyvinylpyrrolidone (PVP) and Polyvinyl alcohol (pvA); bleaching agents such as percarbonate steel; bleaching agents such as organic peracid precursors and tetraethylphosphonium diamine (TAED) as described in JP-A 6-316700; enzymes such as enzymes, cellulose Enzymes, amylases and lipases This paper is in accordance with Chinese National Standards (CNS) A4 specifications (21 × 297 mm) 5 402634 ---, Description of the invention (6 A7 B7 Printed by the Consumers' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs: Tinctures such as compounds and sodium sulfite; glory of biphenyls Deodorants; silicone 'silica-based defoamers, etc .; &oxidants; bluening agents; and perfumes. More specifically, those described in JP_A 8-218009 can be used as top, shape, and additives. k &lt; Detergent compositions can be made by publicly known methods. Appropriate manufacturing conditions can be easily selected by those skilled in the art based on the composition. ° The composition of the present invention &lt; has high cleaning power, and, Excellent performance in inhibiting solid redeposition. A [Mode for carrying out the present invention] Examples 1 and 2 and Comparative Examples 1 to 4 20 kg of LAS, 0.5 kg of AA-MA copolymer, 0.5 kg (Polyethylene glycol, 20 kg of sodium tripolyphosphate, 10 kg of sodium silicate nS N 0.2, 14-9 g of soda powder, 20 kg of Glauber's salt, and 0.3 kg of fluorescein dye preparation factor is 60. % Of aqueous slurry. After the slurry was spray-dried, the resulting powder was fed into a vertical blender. After further adding 3 kg of zeolite, 1.5 kg of crystalline silicate and 丨 kg of enzyme, the blend was mixed, so that the powdered detergent composition of Example 1 as shown in Table i (looseness: 0.35 g) was obtained. / Liter), average particle size: 400 microns). The compositions of Example 2 and Comparative Examples 1 to 4 were prepared in the same manner. Each of the thus prepared compositions was subjected to a cleaning power test and an anti-redeposition test by the following methods. Table 1 lists the results. <Cleaning power test> (Preparation of artificial dirt cloth) The cloth was artificially contaminated with an artificial dirt solution of the following composition. The defacement is based on the 9-M scale standard (CNS) A4 specification (210X297), (please read the precautions on the back before filling this page)

----------衣-------,—訂-----_-----------------III 經濟部中央標準局員工消費合作社印製 402634_b7__ 五、發明説明（7 ) 由使用凹版滚筒塗佈器，塗佈速率爲1.0米/分下之能力爲 58立方公分/平方米，以人造污垢溶液印刷布料進行，且 再於100 °C下烘乾1分鐘。至於布料，所用者爲襯衫料棉 布 2003 (由 Tanigashira Shoten 製造）〇 [人造污染溶液之組合物] 月桂酸 0.44 wt% 十四燒酸 3.09 wt% 十五烷酸 2.3 1 wt% 十六燒酸 6.18 wt% 十七垸酸 0.44 wt% 硬脂酸 1.57 wt% 油酸 7.75 wt% 三油酸 13.06 wt% 十六酸正十 六院酉旨 2.18 wt% 角鯊烯 6.53 wt% 蛋卵磷脂， 液晶形式 1.94 wt% 紅色污垢（Kanuma) 8.11 wt% 碳黑 0.01 wt% 自來水 其餘 (洗滌條件及評估法） 將五片人工污染之布料（〗0公分X 10公分）置於1升欲 評估之清潔劑水溶液中），且在下列條件下以丁6巧-0-Tometer，100 rpm.下洗條。 -10- 本紙張尺度適用中國國家標準（CNS )、Α·4規格（210X297公釐） (諳先閱讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 402634 A7 R7 五、發明説明（8 ) 洗膝條件 洗滌時間 10分鐘 清潔劑濃度 0.133% 水硬度 5° DH 水溫 25 °C 沖洗 自來水5分鐘 清潔力係藉由以自比色計（由Shimadzu公司製造）。測量 洗條前後起始布料及污染布料於550微毫米下之反射，且 依下式計算清潔力（％)評估。清潔力係以五布料片之數據 平均値表示。 清潔力（％)二 洗滌後之反射—洗滌前之反射 X 100 起始布料之反射—洗滌前之反射 &lt;抗再沈積試驗&gt; 至於布料， 所用者爲襯衫用棉布2003 (由Tanigashira Shoten 製造）。 以市售清潔劑Attack™ (由Kao公司製造） 洗滌後，將此布料切割成片（1()公分X 10公分）。將2 5 克紅色污垢（Kamrnia)加於欲評估之清潔劑之1升水溶液 中，烘乾且經 150網目篩整理。接著將上述五片布料置於 其中，且在下列條件下以100 rprn之Terg-0-Tometer洗滌。 (諳先閱讀背面之注意事項再填寫本頁) 訂. S. -11- 本紙張尺度適用中國國家鱗（CNS ) A4規格（210X297公A ) 402634---------- Cloths -------,-Order -----_----------------- III Central Bureau of Standards, Ministry of Economic Affairs Printed by the employee consumer cooperative 402634_b7__ V. Description of the invention (7) By using a gravure roller coater, the coating rate is 58 cubic centimeters per square meter at a coating rate of 1.0 m / min, and the fabric is printed with artificial dirt solution, and then Dry at 100 ° C for 1 minute. As for the cloth, a shirt material cotton 2003 (manufactured by Tanigashira Shoten) was used. [Composition of artificial pollution solution] Lauric acid 0.44 wt% Tetradecanoic acid 3.09 wt% Pentadecanoic acid 2.3 1 wt% Hexadecanoic acid 6.18 wt% heptadecanoic acid 0.44 wt% stearic acid 1.57 wt% oleic acid 7.75 wt% trioleic acid 13.06 wt% n-hexadecanoic acid decree 2.18 wt% squalene 6.53 wt% egg lecithin, liquid crystal form 1.94 wt% red dirt (Kanuma) 8.11 wt% carbon black 0.01 wt% rest of the tap water (washing conditions and evaluation method) Put five pieces of artificially contaminated cloth (〖0 cm x 10 cm) in 1 liter of aqueous detergent solution to be evaluated Medium), and the strips were washed with Ding-6-0-Tometer, 100 rpm under the following conditions. -10- This paper size applies to Chinese National Standards (CNS), A · 4 size (210X297 mm) (谙 Please read the notes on the back before filling this page) Order printed by the Central Consumers Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 402634 A7 R7 V. Description of the invention (8) Knee-washing condition Washing time 10 minutes Detergent concentration 0.133% Water hardness 5 ° DH Water temperature 25 ° C Washing tap water for 5 minutes The cleaning power is based on self-colorimeter (manufactured by Shimadzu). The reflections of the starting cloth and the soiled cloth before and after washing were measured at 550 micrometers, and the cleaning power (%) was evaluated according to the following formula. The cleaning power is expressed by the average 値 of the data of the five cloth pieces. Cleaning power (%) 2 Reflection after washing-Reflection before washing X 100 Reflection of starting cloth-Reflection before washing &lt; Resedimentation test &gt; As for the cloth, a cotton cloth for shirts 2003 (manufactured by Tanigashira Shoten) ). After washing with a commercially available detergent, Attack ™ (manufactured by Kao), the cloth was cut into pieces (1 () cm x 10 cm). 25 grams of red dirt (Kamrnia) was added to a 1 liter aqueous solution of the cleaning agent to be evaluated, dried and processed through a 150 mesh screen. The above five pieces of cloth were then placed therein, and washed with a Terg-0-Tometer at 100 rprn under the following conditions. (谙 Please read the precautions on the back before filling this page) Order. S. -11- This paper size applies to China National Scale (CNS) A4 specification (210X297 male A) 402634

五、發明説明p 洗滌條件 洗滌時間 清潔劑濃度 水硬度 水溫 沖洗 抗再沈積比係以自比色計（由Shimadzu公司製造）測量茂 染前之起始布料及洗滌後之布料在55〇微毫米下之反射評 估’且依下式計算抗再沈積比（％)。抗再沈積比係以五布 料片之數據平均表示。 洗滌後之反射 10分鐘 0.133% 5° DH 25 V 自來水5分鐘 抗再沈積比（％) X 1〇〇 起始布料之反射 ---------裝------——訂『1 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -12- 一---- 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇χ Μ?公釐） 402634五、發明説明（10 ) Μ -13- 經濟部中央標準局員工消費合作社印製 抗再沈積比(％) 清潔力％ 香料 螢光染料 Glauber’s 鹽 結晶矽酸鹽 珍酸納 蘇打粉 STPP \ 聚乙二醇 聚丙烯酸 AA-MA共聚物 LAS 成份(wt%) 00 ° 00 2 δ LO C： 1~~&gt; 14.9 Μ P 1 〇 Im 1—^ 〇\ 00 00 £ S Η-* K) Κ» U) 一 14.9 〇 1 o U\ to 00 〇 U) 〇 U) h-i UJ 一 to ο U\ 1 o Im On 00 〇 •U) 〇 ίο OJ U) ►—λ 〇\ ο 1 S 私 〇〇 00 〇 U) δ Η-Λ U) u： 1—i 8.76 0.07 1 0.07 NJ Οι 00 S £ U) C： 12.1 〇 1—i '^o I σ\ ίο 00 •S S 1—* — 14.9 H-* o Ui ! s K) 比較例 00 δ S H-* U) LM 14.9 s 1 1 o to 00 〇 U) •S l·-* U) U\ c; 14.9 t I s U) δ 00 S •s H-* U) a 14.9 o KJ\ 〇 u\ 1 (請先閩讀背面之注意事項再填寫本頁) ,1V. Description of the invention p Washing conditions Washing time Detergent concentration Water hardness Water temperature Rinse resistance Redeposition ratio is measured with a colorimeter (manufactured by Shimadzu) The initial cloth before dyeing and the cloth after washing are 55 micrometers Evaluation of reflection in millimeters' and calculated anti-redeposition ratio (%) according to the following formula. The anti-redeposition ratio is represented by the average of the data of five cloth pieces. Reflection after washing for 10 minutes 0.133% 5 ° DH 25 V Tap water for 5 minutes Anti-redeposition ratio (%) X 100 Reflection of the starting cloth ------------------------- Order "1 (Please read the notes on the back before filling in this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs -12- 一 ---- This paper size applies to the Chinese National Standard (CNS) A4 specification (21〇χ Μ? Mm) 402634 V. Description of the invention (10) Μ -13- Anti-redeposition ratio (%) printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (%) Cleaning power% Spice fluorescent dye Glauber's Salt Crystal Silicate Soda powder STPP \ Polyethylene glycol polyacrylic acid AA-MA copolymer LAS composition (wt%) 00 ° 00 2 δ LO C: 1 ~~ &gt; 14.9 Μ P 1 〇Im 1— ^ 〇 \ 00 00 £ S Η -* K) Κ »U)-14.9 〇1 o U \ to 00 〇U) 〇U) hi UJ-to ο U \ 1 o Im On 00 〇 • U) 〇ίο OJ U) ►—λ 〇 \ ο 1 S private 〇0000 〇U) δ Η-Λ U) u: 1—i 8.76 0.07 1 0.07 NJ 〇 00 S £ U) C: 12.1 〇1—i '^ o I σ \ ίο 00 • SS 1— * — 14.9 H- * o Ui! S K) Comparative Example 00 δ S H- * U) LM 14.9 s 1 1 o to 00 〇U) • S l ·-* U) U \ c; 14.9 t I s U) δ 00 S • s H- * U) a 14.9 o KJ \ 〇u \ 1 (Please read the precautions on the back before filling this page), 1

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 402634 A7 經濟部中央標準局員工消費合作社印製 B7五、發明説明（11 ) 附註： LAS :直鏈-燒基（Ci 2)苯績酸鈉。 AA-MA共聚物：平均M. W.爲70,000之丙烯酸/馬來酸（莫 耳比7/3 )共聚物之鈉鹽。 聚丙晞酸：平均M. W.爲6,000之聚丙烯酸鈉。 聚乙二醇：平均分子量爲7,000。 STPP :三聚磷酸鈉。 石夕酸納：碎酸鋼JIS No. 2。 結晶矽酸鈉：組合物 M2O'1.8SiO2O.02MO(M:Na，K· K/Na=0.03, M*=Ca, Mg, Mg/Ca=0.01) ° 離子交換能力：290 CaCO3mg/g，平均粒徑：30微米 [結晶矽酸鹽以一般式（II)代表]。 沸石：組合物M20'Al203'2Si02 2H20，平均粒徑4微米，離 子交換能力：290 CaC03 mg/g。 酶：脫酶（Savinase 12.0TW ，由 Novo Nordisk 製造），脂肪 酶（Lipolase 100T ，由 Novo Nordisk 製造），纖維素酶 (Celluzyme 0.1T ，由 Novo Nordisk 製造），澱粉酶 (Termamyl 60T ，由 Novo Nordisk 製造），以重量比 2:1:1:1 混合。 螢光劑染料：TinopalCBS (由 Ciba-Geigy 製造）/whitexSA (由Sumitomo化學股份有限公司製造），重量比爲1/1 下混合。 -14- (請先閱讀背面之注意事項再填寫本頁) D裝_ .訂 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐） ui\TYPE\MFy\JKP-2.DOC\4 丨1-·丨 結晶矽酸鹽 秒酸納 蘇打粉 STPP 〇 1' 聚丙歸酸 AA-MA共聚物 LAS 成份(Wt%) OJ 1—i 14.9 S 1 Ο &lt;_·=- U) c: 1—* 14.9 M s 1 ο Im oo K3 〇-&gt; υ； 1—1 \〇 to \〇 o •LA 1 ο Ln U) Ui )—* )—* •Ό C\ o U\ 1 ο Ui U) C； 1—* 8.76 0.07 1 ο·〇7 Ui LO 1—1 o 12.1 ] 1 σ&gt; 00 e: 1—1 14.9 &gt;-—1 o Lh 1 Ο *Ui K) Lh H—* 比較例 LO Ui ·: 1—* 14.9 〇 LAI 1 1 to LO l/l c; 1—-» 14.9 1 1 Ο Ui U) OO c; 1—^ 14.9 〇 Im ο Lai 1 私 LO 1 1—* ON •s 1 s &gt;2 卡K盏(、v+、v^+b ) Λ-i 5贫洄芩衅宣一沙斗外嫜jf芪韙令j 5羧命赛。私淬迹奔今沣迹崦桊聆拉妄碲窆沣昂禽令了洄钋芩沐2卡-私奇 &gt;^迹據0%^薄^。 c:\TYPE\MFY\JK’p--DOCU —Ml 抗再沈積比(％) 清潔力％ 香料 螢光染料 敬 Glauber's 鹽 oo o oo o U) ο *U) )—l 00 00 o U) ο OJ )—1 K) Μ g 00 o U) ο u&gt; &gt;—* G\ oo o ίο ο L〇 I—i ON 00 oo o Lo ο U) 1—-A 客 oo oo o L) ο U) 1—-l Μ G\ 00 00 o OJ ο OJ 1—i 1—ι &lt;1 oo o Lo ο ίο )—* σ\ vo &lt;1 1—^ oo o L〇 ο Lo Μ G\ vo oo o Lo ο L〇 |&gt;&gt;a_k Μ 2 oo o 1&gt;j ο L〇 1—* 38.5This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) 402634 A7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs B7 V. Invention Description (11) Remarks: LAS: Straight Chain-Burning Base (Ci 2) Sodium benzoate. AA-MA copolymer: Sodium salt of acrylic acid / maleic acid (mole ratio 7/3) copolymer with an average M.W. of 70,000. Polyacrylic acid: an average M.W. of 6,000 sodium polyacrylate. Polyethylene glycol: The average molecular weight is 7,000. STPP: Sodium tripolyphosphate. Sodium oxalate: broken acid steel JIS No. 2. Crystalline sodium silicate: Composition M2O'1.8SiO2O.02MO (M: Na, K · K / Na = 0.03, M * = Ca, Mg, Mg / Ca = 0.01) ° Ion exchange capacity: 290 CaCO3mg / g, average Particle size: 30 microns [crystalline silicate is represented by general formula (II)]. Zeolite: Composition M20'Al203'2Si02 2H20, average particle size 4 microns, ion exchange capacity: 290 CaC03 mg / g. Enzymes: Deenzyme (Savinase 12.0TW, manufactured by Novo Nordisk), lipase (Lipolase 100T, manufactured by Novo Nordisk), cellulase (Celluzyme 0.1T, manufactured by Novo Nordisk), amylase (Termamyl 60T, manufactured by Novo Nordisk) (Manufactured), mixed in a weight ratio of 2: 1: 1: 1. Fluorescent dye: TinopalCBS (manufactured by Ciba-Geigy) / whitexSA (manufactured by Sumitomo Chemical Co., Ltd.), mixed at a weight ratio of 1/1. -14- (Please read the precautions on the back before filling this page) D Pack _. The size of the paper used for the order is applicable to China National Standard (CNS) A4 (2 丨 0X297 mm) ui \ TYPE \ MFy \ JKP-2. DOC \ 4 丨 1- · 丨 Crystalline Silicic Acid Sodium Soda Powder STPP 〇1 'Polyacrylic acid AA-MA copolymer LAS Composition (Wt%) OJ 1—i 14.9 S 1 〇 &lt; _ · =-U ) c: 1— * 14.9 M s 1 ο Im oo K3 〇- &gt;υ; 1—1 \ 〇to \ 〇o • LA 1 ο Ln U) Ui) — *) — * • Ό C \ o U \ 1 ο Ui U) C; 1— * 8.76 0.07 1 ο · 〇7 Ui LO 1-1 o 12.1] 1 σ &gt; 00 e: 1-1 14.9 &gt;-1 o Lh 1 〇 * Ui K) Lh H — * Comparative Example LO Ui ·: 1— * 14.9 〇LAI 1 1 to LO l / lc; 1—- »14.9 1 1 〇 Ui U) OO c; 1— ^ 14.9 〇Im ο Lai 1 Private LO 1 1— * ON • s 1 s &gt; 2 cards K (, v +, v ^ + b) Λ-i 5 poor provocation Xuan Yi Sha Dou 嫜 jf 韪 韪 j j 5 carboxyl match. The private traces of this time, the traces of the dead, the fascination, and the frightened birds, made the Mu 2 Cards-Private Qi &gt; ^ Track data 0% ^ thin ^. c: \ TYPE \ MFY \ JK'p--DOCU —Ml Anti-redeposition ratio (%) Cleansing power% Spice Fluorescent Dye Glauber's salt oo o oo o U) ο * U)) —l 00 00 o U) ο OJ) —1 K) Μ g 00 o U) ο u &gt; &gt; — * G \ oo o ίο ο L〇I—i ON 00 oo o Lo ο U) 1—A guest oo oo o L) ο U) 1—l Μ G \ 00 00 o OJ ο OJ 1—i 1—ι &lt; 1 oo o Lo ο ίο) — * σ \ vo &lt; 1 1— ^ oo o L〇ο Lo Μ G \ vo oo o Lo ο L〇 | &gt; &gt; a_k Μ 2 oo o 1 &gt; j ο L〇1— * 38.5

Claims (1)

^ # Μ a^ # Μ a ^包括界面活性劑及鹼之粉末狀清潔劑組合物，其 包括15至30 wt%之無機磷酸鹽，0_05至2.0 wi%工两 烯酸與馬來酸之共聚物，〇.〇5至2.0 wt%之聚乙一醇及 15至40 wt%之Glauber's鹽或硫酸鈉，其中該無機磷酸 鹽為三聚磷酸鹽，原磷酸鹽或焦磷酸鹽，JL鹽之平衡 離子為鹼金屬。 2·根據申請專利範園第1項之組合物’尚包括〇.1至.5 wt°〆。之結晶矽酸鹽，當以〇 ；! wt%之速率分散於20 °C 下之去離子水中時可提供丨丨或更高之pH值’且此驗 性度需要至少5毫升之〇. 1 n HC1水溶液，使1升之上 述水性分散液之pH值降低至1〇。 3.根據申請專利範園第1項之組合物，其含有10至40 wt%之該界面活性劑，及1〇至3〇 wt%之該鹼。 4·根據申請專利範圍第1項之組合物，其中該丙烯酸及 馬來酸之共聚物為丙浠酸/馬來酸共聚物，两晞酸馬來 酸奸共聚物或其部份趟。 .1'请先—閱讀背面之注意事項再填寫本頁) (裝· 訂 經濟部中央標準局員工消費合作社印製 本..氏張尺度適用十國國家標準（CNS ) M餘（2ΐ〇χ297公 ^ # Μ a^ A powdered detergent composition including a surfactant and an alkali, which includes 15 to 30 wt% of inorganic phosphate, 0_05 to 2.0 wi% of a copolymer of oxydiene and maleic acid, and 0.05 to 2.0 wt% of polyethylene glycol and 15 to 40 wt% of Glauber's salt or sodium sulfate, wherein the inorganic phosphate is a tripolyphosphate, orthophosphate or pyrophosphate, and the counter ion of the JL salt is an alkali metal. 2. The composition according to item 1 of the patent application park further comprises 0.1 to 0.5 wt.%. The crystalline silicate can provide a pH value of 丨 丨 or higher when dispersed in deionized water at 20 ° C at a rate of 0; wt%, and this test requires at least 5 ml of 0.1 n HC1 aqueous solution to reduce the pH of 1 liter of the above-mentioned aqueous dispersion to 10. 3. The composition according to item 1 of the patent application park, which contains 10 to 40 wt% of the surfactant and 10 to 30 wt% of the base. 4. The composition according to item 1 of the scope of the patent application, wherein the copolymer of acrylic acid and maleic acid is propionic acid / maleic acid copolymer, maleic acid dimaleic acid copolymer or a part thereof. .1'Please first—read the notes on the back before filling out this page) (Binding and binding the printed version of the Staff Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs .. The Zhang scale is applicable to ten national standards (CNS) M and more (2ΐ〇χ297 Public ^ # Μ a ^包括界面活性劑及鹼之粉末狀清潔劑組合物，其 包括15至30 wt%之無機磷酸鹽，0_05至2.0 wi%工两 烯酸與馬來酸之共聚物，〇.〇5至2.0 wt%之聚乙一醇及 15至40 wt%之Glauber's鹽或硫酸鈉，其中該無機磷酸 鹽為三聚磷酸鹽，原磷酸鹽或焦磷酸鹽，JL鹽之平衡 離子為鹼金屬。 2·根據申請專利範園第1項之組合物’尚包括〇.1至.5 wt°〆。之結晶矽酸鹽，當以〇 ；! wt%之速率分散於20 °C 下之去離子水中時可提供丨丨或更高之pH值’且此驗 性度需要至少5毫升之〇. 1 n HC1水溶液，使1升之上 述水性分散液之pH值降低至1〇。 3.根據申請專利範園第1項之組合物，其含有10至40 wt%之該界面活性劑，及1〇至3〇 wt%之該鹼。 4·根據申請專利範圍第1項之組合物，其中該丙烯酸及 馬來酸之共聚物為丙浠酸/馬來酸共聚物，两晞酸馬來 酸奸共聚物或其部份趟。 .1'请先—閱讀背面之注意事項再填寫本頁) (裝· 訂 經濟部中央標準局員工消費合作社印製 本..氏張尺度適用十國國家標準（CNS ) M餘（2ΐ〇χ297公^ A powdered detergent composition including a surfactant and an alkali, which includes 15 to 30 wt% of inorganic phosphate, 0_05 to 2.0 wi% of a copolymer of oxydiene and maleic acid, and 0.05 to 2.0 wt% of polyethylene glycol and 15 to 40 wt% of Glauber's salt or sodium sulfate, wherein the inorganic phosphate is a tripolyphosphate, orthophosphate or pyrophosphate, and the counter ion of the JL salt is an alkali metal. 2. The composition according to item 1 of the patent application park further comprises 0.1 to 0.5 wt.%. The crystalline silicate can provide a pH value of 丨 丨 or higher when dispersed in deionized water at 20 ° C at a rate of 0; wt%, and this test requires at least 5 ml of 0.1 n HC1 aqueous solution to reduce the pH of 1 liter of the above-mentioned aqueous dispersion to 10. 3. The composition according to item 1 of the patent application park, which contains 10 to 40 wt% of the surfactant and 10 to 30 wt% of the base. 4. The composition according to item 1 of the scope of the patent application, wherein the copolymer of acrylic acid and maleic acid is propionic acid / maleic acid copolymer, maleic acid dimaleic acid copolymer or a part thereof. .1'Please first—read the notes on the back before filling out this page) (Binding and binding the printed version of the Staff Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs .. The Zhang scale is applicable to ten national standards (CNS) M and more (2ΐ〇χ297 public