TW401306B

TW401306B - Cosmetic compositions

Info

Publication number: TW401306B
Application number: TW83109792A
Authority: TW
Inventors: Gillian Scott Briggs; Teresa-Barbara Crook; Karen Fish; George Endel Deckner
Original assignee: Procter & Gamble
Priority date: 1993-08-06
Filing date: 1994-10-22
Publication date: 2000-08-11
Also published as: JPH09501176A; EP0717627A1; EP0717627A4; WO1995004537A1; CZ34796A3; AU673623B2; CN1130875A; AU7520694A; GB9316323D0; CA2168425A1

Abstract

A cosmetic composition in the form of an emulsion, gel or lotion comprising an aqueous/alcoholic solution of an acidic anti-acne active and a pyrrolidone-based complexing agent therefor, wherein the aqueous/alcoholic solution has a pH of less than pKa + 1, where pKa is the logarithmic acidity constant for the fully protonated anti-acne active. The cosmetic composition exhibits anti-acne effectiveness and product and colour stability.

Description

五、發明説明（ Α7 Β7 發明領城本發明係有關化粧组合物且更特別者，有闞具有抗痤瘡活#及配方和顔色安定性的著色打底化粧组合物。吸_明贫君· 打底組合色調和質地底組合物來抗曰光，風化粧姐合颸縮粉或無美阚專利的方法，其確油等之姐 ’煤:答M，物可Μ塗在面部和身體的其他部份K平均皮慮並遮蓋凹洞，缺陷，细線條等。此外，也用打濕濶皮虜，平衡皮虜的油水平及提供保護Μ對和粗礪環境等的不利影響。物通常可為液體或乳霜懋浮液，乳液，凝膠，水油和蝴姐合物等形式。第3, 444,291號揭示一棰填充和掩飾皮膚腔洞係用含65至75份重量的微晶蠟和約25至35份的合物塗在皮虜上。該組合物包含色料，較佳者例如，匹配使用者皮膚顔色的DIC紅色17號等先閱讀背 St 之注項再填本頁經濟部中央揉準局貝工消費合作社印製美國專利第4,486,405號提及可散佈，流動和無脂的化粧覆蓋組合物。該組合物的特徴為含有第一和第二種大致相同濃度的烷氧化界面活性劑。美國專利第4, 804.532號述及使用比先前技藝姐合物遠較為澹度的结晶氧化矽之面部化粧粉。該粉在用為腮或面部塗被時，據稱對於皮濟跛紋，線條和孔洞具有遮蓋效用。該組合物為色料相與稀釋劑相的混合物。其色料相係經由將结晶氧化矽和色料摻合而形成的。將所得色料相與本紙張尺度適用中國國家揉牟（CMS M4规格（210X297公釐） 40ί30δ A7 B7 五、發明説明（基本t.由珍珠母合即形成該姐合美國專利第3 , 晳的打底姐合物其特徴為含有珍霜似珍珠效果，係由珍珠母物質美國專利第4, •其包含用於彼氧化矽混合物和密混合物。該姐件。亦即，據稱料與珍珠母劑的 Nakamura e t 第 XIV 屆 I.F.S. 化矽和聚二甲基 Μ提供打底效果較的化粧打底姐矽和聚二甲基矽物質，如滑石和物。 978 , 207號提及之用途。該姐合珠母物質•例如亦即，明亮的表所提供。 659,562號揭示等的黏合劑，及約5至95重量％合物據稱可保持可“防跛”。該混合物。 al .,在 1 986 年 * C.C.會議報告複矽氧烷的新穎化 *其將跛紋可視合物。該驢紋可氣烷的新_利用V. Description of the invention (Α7 Β7 发明领城 The invention relates to a cosmetic composition and more particularly, there is a coloring base makeup composition with anti-acne activity # and formula and color stability. Suction_ 明 poor 君 · 打The combination of the base color and the texture of the bottom composition to resist light, wind, makeup, or shrinking powder, or a patent-free method, its oil and other sisters' coal: A M, the material can be painted on the face and other parts of the body Part K evenly considers and covers pits, defects, thin lines, etc. In addition, the skin is also moistened with moisture to balance the oil level of the skin and provide protection against the adverse effects of rough and rough environments. It is in the form of liquid or cream 懋 float, emulsion, gel, water oil and butterfly compound etc. No. 3, 444,291 discloses a microcrystalline wax containing 65 to 75 parts by weight for filling and masking the skin cavity. And about 25 to 35 parts of the composition is coated on the skin. The composition contains colorants, preferably, for example, DIC Red No. 17 to match the skin color of the user, etc. Read the notes on the back of St and fill in this page. Central Patent Office Printed U.S. Patent for Shellfish Consumer Cooperative No. 4,486,405 refers to a dispersible, flowing, and non-fat cosmetic covering composition. The composition is characterized by containing the first and second alkoxylated surfactants at approximately the same concentration. US Patent No. 4,804.532 describes Facial makeup powder using crystalline silica, which is much more daunting than previous techniques. This powder, when applied as a cheek or face coating, is said to have a covering effect on skin texture, lines and holes. The composition It is a mixture of a colorant phase and a diluent phase. The colorant phase is formed by blending crystalline silica and a colorant. The obtained colorant phase and the paper size are applicable to the Chinese national standard (CMS M4 specification (210X297) (Mm) 40ί30δ A7 B7 V. Description of the invention (Basic t. Formed by mother-of-pearl. US Patent No. 3, a clear primer composition. It is specially formulated to contain frost-like pearl effect. It is made of mother-of-pearl material. U.S. Patent No. 4, • It contains a silicon oxide mixture and a dense mixture. The sister piece. That is, Nakamura et XIV IFS Silicone and Polydimethyl M are said to provide a primer with pearl mother agent The effect of the make-up primer is silicon and polydimethyl silicon substances, such as talc, and the use mentioned in No. 978, 207. This sister blends with mother-of-pearl material. For example, that is, provided by the bright watch. No. 659,562 revealed And other adhesives, and about 5 to 95% by weight of the compound is said to remain "anti-pimple". The mixture. Al., At the 1986 * CC Conference report on the novelty of polysiloxanes * which will scratch Visible compound. The new_use

雲母所形成的稀釋劑相混具有相當高濃度珍珠母物物為一種ffi縮粉组合物，雲母，和摻合油，可提供覼。該打底姐合物的顏色一種化粧用化粧品姐合物含5至95重量％的细粉狀细粉吠聚乙烯嫌維等的緊其所塗佈皮虜部位的均匀 ’562專利的姐合物包含色巴塞降納（Barcelona)的印本中提及利用球體狀氧粧姐合物。該姐合據稱可度的減低程度大於其所比見度的減砝係由球體氧化所Μ進的光學椹細效果iS 先 » 讀背之注The diluent formed by mica is mixed with a relatively high concentration of mother-of-pearl material, which is a ffi powdered composition, mica, and blended oils to provide rhenium. The color of the primer composition is a cosmetic composition containing 5 to 95% by weight of a fine powder and a fine powder, such as polyethylene, and the uniformity of the skin area to be coated. The object contains a printed version of Barcelona, which mentions the use of a spherical oxygen makeup compound. This sister is said to be able to reduce the degree of greater than the visibility of the weight reduction is the optical slimming effect iS by the sphere oxidation first »read back note

I 裝訂經濟部中央椹準局員工消費合作社印製化酮等的砂劑式，性形素活液色面乳的界水被物包塗聚油烷共種氧烯一矽氧示聚聚揭用 I 號含烷 2包氧 72中矽 3,其機 14,有 5’物二第合聚利姐和專粧相。舅化水的美用，成粧相。本紙張尺度逍用中國國家標準（CNS ) A4規格（21〇χ297公釐） 401308 A7 B7 五、發明説明（油包水乳液形式的打底物是热知者，可提供良好的覆蓋和良奸的皮It感甭，著飾和表覼。同時*有需要提出一棰具有局部抗痤瘡活性的打底姐合物。有許多化合物是已知在局部塗佈於皮It時具有抗痤瘡性質者。一種常用的具有抗痤瘡活性之角質分解劑為柳酸。彻酸實質地不溶於水，難κ將其滲入乳液组合物的水相中。不過，要將柳酸從乳液打底姐合物的含色素油相艙送出彻酸時可能會因為柳酸與色素*特別是氧化赖類型的色素*之間的交互作用而導致姐合物褪色。所Μ，有需要將柳酸以可溶形式從水相中蝓送出。聚乙烯基吡咯烷_是已知可在各種姐合物中用為增溶/ 複合劑者。 -先閱背 Λ 之注I Binding of the Ministry of Economic Affairs, the Central Provincial Bureau of Staff's Consumer Cooperative Co., Ltd. printed a lotion of ketones, etc., and the boundary layer of the hydrating active liquid color facial milk was coated with polyoleane, co-oxyalkylene, and siloxane. I use alkane 2 containing oxygen 72 in silicon 3, and its machine 14, there is a 5 'thing two di Lili and special makeup. The beauty of hydrating water becomes a makeup look. This paper is based on the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 401308 A7 B7 V. Description of the invention (The substrate in the form of a water-in-oil emulsion is a keen reader, which can provide good coverage and good adultery. Peel It feels embarrassing, decorative and cosmetic. At the same time * there is a need to propose a primer compound with local anti-acne activity. There are many compounds that are known to have anti-acne properties when topically applied to Peel It. A commonly used keratolytic agent with anti-acne activity is salicylic acid. Thoracic acid is substantially insoluble in water, making it difficult for κ to penetrate into the aqueous phase of the emulsion composition. However, salicylic acid must be removed from the base of the emulsion. Pigment-containing oil phase capsules may cause discoloration due to the interaction between salicylic acid and pigments *, especially oxidized pigments * when sending out citric acid. Therefore, it is necessary to remove salicylic acid from soluble form. It is sent out in the water phase. Polyvinylpyrrolidine is known to be used as a solubilizer / composite in various compounds. -Please read the note below

I 頁 GB-A-2,041 經濟部中夹揉準局負工消费合作社印装劑組合基吡咯 m合物酸/撺指的完物。由於高穠度物，其烷酮輔也可含樺酸锞金質子酸性抗的自由出值下Μ質子要目的合物。 —項主 β粧姐 ,963揭示一種用清潔油性皮虜的含水清潔中含有肌胺酸Ν-醯基酯的水溶性黷·聚乙烯增溶劑*與蛋白質及/或蛋白質水解物。該有柳酸作為角質分解劑•及媛衝器•如搏權等。不過•其中未揭示含有以如本發明所特化形式的增溶酸性抗痤瘡活性劑之化粧姐合痤瘡劑在低出時最有效（此時，溶液中含有酸）|因此有需要將該藥劑在其明顯存在％化形式從水相轤送出。因此之故，本發明的為提出在低cH值含有抗痤瘡活性物水溶液的本紙張尺度適用中國國家樣準（CNS ) Α4规格（210Χ297公釐）經濟部中央揉準局負工消费合作社印製 A7 B7 五、發明説明（4,）本發明的另一目的為提出具有改良抗痤瘡活性和安定性的化粧姐合物。本發明的另一目的為具有改良顔色安定性和色素/抗痤瘡活件物相容性的水包油或油包水乳液形式之化粧組合物根據本發明的一部份，提出乳液，凝膠或洗疲等形式的化粧组合物，其包含酸性抗痤瘡活性物的水/酵溶液及用於彼等的吡咯烷酮基質複合劑，且其中該水/酵溶液具有低於約pKaM的pH值，此處pKa為完全質子化抗痤瘡活性物的酸度常數對數值》本發明化粧姐合物提供抗痤瘡效率加上改良的產品和顔色安定性。根撺本發明的另一部份*提出油包水或水包油乳液形式的化粧姐合物，其中包含溶油水相中的酸性抗痤瘡活性物及分敢於油相中的色素或色素混合物。除非另外指出，否則所有的水平和比例皆為Μ缌姐合物重最計算者。鏈長度和烷氧化程度也皆Μ重量平均基礎表出。發明 > 洚钿銳明本發明一部份的化粧姐合物包含酸性抗痤癒活性物的水 /醇溶液，及吡咯烷嗣基質複合劑。該姐合物為乳液，凝本紙張尺度逋用申國國家標準（CNS ) A4規格（210X297公釐） I ~j 装----：---^訂---1--"械 (請先閱讀背面之注意事項再填寫本頁) ΙΓΓ____I_____ 401306 A7 B7 五、發明説明（嘐或洗本發水/醇，視黃，丙嗣用於和千二瘡活性佳者為該抗液等形式。明該第一部份的第一種必活性物的包括檷酸，乙醇酸選自柳酸。該抗痤 10¾ ，較，以的醇為選物等之中約20¾之周溫（25 質子化的中，最後抗痤瘡活性物，乳酸佳者為為柳酸 U至約約3¾ ° ，例如較適用其混合約U至佳者在為完全實施例要成份為當抗痤瘡其衍生物合物等。活性物較，更佳者計的約0 . 約0 . 5 X至酵溶液内之溶液· 二醇，和較佳者為物溶液較處 pKa+1 。於較佳溶液。可酸和其衍酸，類黃本發明姐酸，及其物的含量約0 . 1 至痤瘡活性酵，二醇，二丙二在本發明該最後水 pH侑為低活性物之 pH值為小数對數值 A為完全 U為該平衡用於本發明的適生物，干二酸和酮，及上述之混合物中的抗痤瘡混合物等之中者為Μ組合物重量約5S；，更佳者為物係溶解在水或和多元酵為基質酵，丁二酵，己姐合物中的含最 /酵抗痤瘡活性於約P K a + 1 ，此酸性常數對數值於約P K a。係參考下列平衡 Η" + Ηπ-ιA 質子化的酸，η 該酸對懕於失去的酸常數為先閱背 Λ 之注意事項再填 % 本頁裝訂 '银經濟部中央標準局貝工消费合作社印製自乙醇者。酵水平。 t：)的抗摔瘡溶液的酸常其中H„ 數目J· 如此式予Μ定義者 =Η„Α 為完全質子化酸中的質子一個質子的共轭驗。本紙張尺度適用中國國家橾準（CNS ) Α4规格（210X297公釐）經濟部中央搮準局負工消费合作社印製 401S06 A7 ____B7_ 五、發明説明u，）Page I GB-A-2,041 The Ministry of Economic Affairs has completed the printing of the quasi-bureau's work co-operative consumer cooperatives. The combination of pyrrole m-compound acid / fluorene refers to the finished product. Due to its high alkalinity, its alkanones can also contain osmium betulinate, gold protons, acidic resistance, and free M-protons. —Project owner β makeup sister, 963 discloses a water-based cleanser for cleaning oily skin with water-soluble 聚乙烯 · polyethylene solubilizer * containing sarcosinate N-methyl ester and protein and / or protein hydrolysate. It has salicylic acid as a keratolytic agent, and a yuan punch, such as right to fight. However • It is not disclosed that a cosmetic acne agent containing a solubilizing acidic anti-acne active agent in a form specialized according to the present invention is most effective when it is low (in this case, the solution contains an acid) | so there is a need for the agent In its apparent presence in% form it is sent out from the water phase. For this reason, the paper of this invention proposes to apply the Chinese National Standard (CNS) A4 specification (210 × 297 mm) to the paper size of the paper containing the anti-acne active solution at a low cH value. A7 B7 V. Description of the invention (4,) Another object of the present invention is to propose a cosmetic composition with improved anti-acne activity and stability. Another object of the present invention is a cosmetic composition in the form of an oil-in-water or water-in-oil emulsion with improved color stability and compatibility of pigments / anti-acne actives. According to a part of the present invention, a lotion, gel is proposed. Or a wash-up cosmetic composition, comprising a water / fermentation solution of an acidic anti-acne active and a pyrrolidone matrix complex for them, and wherein the water / fermentation solution has a pH value lower than about pKaM, where The pKa is the logarithm of the acidity constant of the fully protonated anti-acne active. The cosmetic composition of the present invention provides anti-acne efficiency plus improved product and color stability. According to another part of the present invention *, a cosmetic composition in the form of a water-in-oil or oil-in-water emulsion is proposed, which contains an acidic anti-acne active substance in an oil-soluble water phase and a pigment or a pigment mixture in the oil phase. Unless otherwise indicated, all levels and ratios are calculated by the M.sub. Chain length and degree of alkoxylation are also shown on a weight average basis. Invention > Tong Ruiming A part of the cosmetic composition of the present invention comprises a water / alcohol solution of an acidic anti-acne healing agent, and a pyrrolidine base compound. The sister compound is an emulsion, and the paper size of the paper is in accordance with the national standard of China (CNS) A4 (210X297 mm). I ~ j Packing ----: --- ^ Order --- 1-" (Please read the precautions on the back before filling in this page) ΙΓΓ ____ I_____ 401306 A7 B7 V. Description of the invention (嘐 or shampoo / alcohol, retinol, propylamidine, and those with good activity for septic sore are the anti-fluids, etc. Form. The first necessary active substance of the first part includes gallic acid and glycolic acid selected from salicylic acid. The anti-acne 10¾, compared with about 20¾ of the week temperature (25 In the protonated, the last anti-acne active, lactic acid is preferably salicylic acid U to about 3¾ °, for example, it is more suitable to mix about U to good. In the complete example, the main ingredient is when the anti-acne derivative is combined. The active substance is better than about 0. About 0.5 X to the solution · diol in the fermentation solution, and the better one is pKa + 1 compared to the better solution. It is the better solution. Acid And its derivatized acids, flavonoids of the present invention, and its content of about 0.1 to acne active enzymes, glycols, dipropylene glycol At the end of the present invention, the pH of the water is low, the pH value is a logarithmic logarithmic value, A is completely U, and the balance is suitable for the suitable organisms, dry diacids and ketones of the present invention, and the anti-acne mixture in the above mixture. Among them, the weight of the M composition is about 5S; more preferably, the system is dissolved in water or mixed with multiple enzymes as matrix fermentation, succinate, and citrullin containing the most active / anti-acne activity in about PK a. + 1, the logarithmic value of this acidity constant is about PK a. Refer to the following equilibrium Η " + Ηπ-ιA Protonated acid, η The acid constant for the acid is lost. Please read the precautions of Λ before filling in the% Page binding 'Silver printed by ethanol from the Central Standards Bureau Shellfish Consumer Cooperative of the Ministry of Economic Affairs. Fermentation level. T :) The acid of the anti-fall sore solution is often H „Number J · This formula is defined by M = Η„ Α is Conjugation test of one proton in a fully protonated acid. This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) Printed by 401S06 A7 __B7_ __B7_ by the Central Government Standards Bureau of the Ministry of Economic Affairs Description u,)

Kn = [HnA] [Η + ][Ηη.!Α] 而 pKa = loglO^n 基於本說明書之目的，將酸常數定義在25t；和零離子強度。文獻值是取自可能之處（參看Stability Constants of Metal-Ion Complexes, Special Publication Ho. 25, The Chemical Society, Iondon)；於有疑問時，是用玻璃雷檷M窜位测定測定之。本發明所用酸性抗痤瘡活性物的pK a值較佳者是在約1 到約6的範圍，更佳者約1到約4 . 5 ，特別者約1 . 5至約 4. 0之範圍。最後水/酵抗痤瘡活性物溶液的pH較佳者是在約1至約 7 ，更佳者約2至約5 ，特別者約2至約4之範圍內。於飫於約5 Μ下的pH值時，該水相較佳者不含酸不稞性物種，例如丙烯酸/丙烯酸乙酯共聚物和聚甲基丙烯酸甘油酯等° 本發明第一部份姐合物的第二種必需成份為吡咯烷酮基質複合劑。吡咯烷酮基質複合劑是從_助該抗痤瘡活性物的增溶之顴點J於本發明者。本發明所用吡咯烷酮基質複合劑較佳者為選自聚乙烯基吡咯烷_複合劑或“吖4烷基聚乙烯基吡咯烷酮禊合劑等之中，其具有約1500至約1,500,000 ’ 較徉者約3000至約70 0,000 ，更佳者約5000至約100 ,000 本纸張尺度逍用中國困家椟準（CNS ) Λ4说格（2丨0X297公釐）；-W裝--------訂------械卜請_先«讀背面之注意事項再填寫本頁) 401306 A7 _ B7_ 五、發明説明（7,) 範閛内之分子最（黏度平均）。適用的吡咯烷醑基質複合劑例子為聚乙烯基吡咯烷酮（PVP、或povidore)和丁基化聚乙烯*吡咯烷酮。最適用於本發明的吡咯烷酮基質複合劑為聚乙烯基吡咯烷酮複合劑。PVP在市面上可得自BASF ，其商品名為Luviskol (RTM)。較適於本發明的PVP複合劑為1(^丨51<〇11(17，其具有約9,000之黏度平均分子量° 可用本發明用的其他吡咯烷萌系複合劑包括Ci-Cw烷基或珲垸基吡咯烷_ ，例如月桂基吡咯烷酮。該吡咯烷酮基質複合劑在本發明姐合物中的含量水平為姐合物重最的約0.U至約10X ，較佳者約〇·1Χ至約5X。抗痤瘡活性物：吡咯烷_基質複合劑的重量比例係在約罕約1:〗0，較佳者約5:1至約1:5 。本發明較佳實施例另外包含約0.01¾至約5重量％ *可在低於或等於對應酸pKa值的pH值下溶解於水中的酸或其鹽，例如，選自擰樺酸，硼酸，和鹽*及其混合物等的酸。這些物質可在本發明中從幫肋抗痤瘡活性物的增溶之覼點與該吡咯烷酮基質複合劑配合使用。從該親點來看•特別較佳者為檸樺酸納鹽。於較佳實施例中，該酸或其鹽在25 t的溶解水平為至少5S! w/ν»。經濟部中央標準局貝工消费合作杜印製本發明姐合物可為乳液U/ο或ο/w)，凝穋或洗液形式，不過JSM圭者為油包水轧液形式，其中，於較佳實胞例中，其油相包含著揮發性矽酮和非揮發性矽酮的混合物。該矽酮油的含最為約1至約5 0重量％。適用的揮發性矽酮油包栝環吠和埭梨揮發性聚有機基矽氧烷（本文所用"揮發性 -!〇本紙張尺度適用中國國家揉準（CNS ) A4规格（210X297公釐） 40130 ο Α7 Β7 五、發明説明（8 詞指的是在周圍條件下具有可測得的蒸氣壓之1^質° 經濟部中央梂準局負工消费合作社印装各種揮發性矽酮的說明可參看Todd, et al*， MVolatile Silicone Fluids for Cosmetics", 91 Cosmetics and Toiletries 27-32 (1976)° 較佳的瓖狀矽嗣包含具有約3至約9個矽原子’較佳者· 具有約4至約5個矽原子之聚二甲基矽氧烷。較佳的線型矽酮油包栝具有約3至約9個矽原子的聚二甲基砂氧院° 線型揮發性矽酮通常具有在25C下低於約5厘史的黏度’ 而瑁状物刖具有低於約1〇厘史的黏度。可用於本發明的砂嗣油例子包栝：Dow Corning 344， Dow COrning 21330’ Dow Corning 345,和 Dow Dorning 200 (皆為 the Dow Corning Corporation 所製者）；Silicone 7207 和 Silicone 7158 (the Union Carbide Corporation的產〇〇 >;SF:202 (General Electric的產品）及 SWS-03314 (Stauffer Chemical的產品）等。通用的非揮發性矽酮較佳者具有在25t的平均黏度值為約 1,000 至約 2,000,000 mm2.s-1* 更佳者為約 1〇,〇〇〇至約1,800,000 mm2.s-1 ，甚至更佳者為約100,000至約 1,500,000 bb^.s-1。不過，也可Μ使用較低黏度的非揮發性矽JR調理劑。黏度可Μ利用如Dow Corning Corporate Test Method CTM 0004, July 20, 1 970 中所述的玻璃毛细管黏度計來測量。供本發明所用的適當非揮發性矽酮流體包栝聚烷基矽氧烷，聚芳基矽氧烷，聚烷基芳基矽氧烷* •ί 閱讀背之泣Kn = [HnA] [Η +] [Ηη.! Α] and pKa = loglO ^ n For the purposes of this specification, the acid constant is defined at 25t; and zero ion strength. Literature values are taken from where possible (see Stability Constants of Metal-Ion Complexes, Special Publication Ho. 25, The Chemical Society, Iondon); when in doubt, they are measured using glass thunder M shift measurement. The pK a value of the acidic anti-acne active used in the present invention is preferably in the range of about 1 to about 6, more preferably in the range of about 1 to about 4.5, and particularly in the range of about 1.5 to about 4.0. The pH of the final water / fermentation anti-acne active solution is preferably in the range of about 1 to about 7, more preferably about 2 to about 5, and particularly about 2 to about 4. At a pH value of about 5 μM, the aqueous phase is preferably free of acid-unstable species, such as acrylic acid / ethyl acrylate copolymer and polyglyceryl methacrylate, etc. The second essential component of the compound is a pyrrolidone matrix complex. The pyrrolidone matrix complex was developed by the present inventors to assist the solubilization of the anti-acne active substance. The pyrrolidone matrix complexing agent used in the present invention is preferably selected from the group consisting of a polyvinylpyrrolidine complexing agent or an "acryl 4 alkyl polyvinylpyrrolidone coupler", which has a range of about 1500 to about 1,500,000 ', which is about 3000. To about 70 0,000, more preferably about 5,000 to about 100,000. This paper size is free to use in China (CNS) Λ4 grid (2 丨 0X297 mm); -W pack ------- -Order ------ Please refer to __ «Read the precautions on the reverse side before filling out this page) 401306 A7 _ B7_ V. Description of the invention (7,) The molecules in the range (the average viscosity). Pyrrole applicable Examples of alkane-based matrix composites are polyvinylpyrrolidone (PVP, or povidore) and butylated polyethylene * pyrrolidone. The pyrrolidone-based composite compound most suitable for the present invention is polyvinylpyrrolidone composite. PVP is commercially available Since BASF, its trade name is Luviskol (RTM). A more suitable PVP compound for the present invention is 1 (^ 丨 51 < 〇11 (17, which has a viscosity average molecular weight of about 9,000 °.) Other pyrrolidines that can be used in the present invention Germination complexes include Ci-Cw alkyl or fluorenylpyrrolidine, such as laurylpyridine The content level of the pyrrolidone matrix composite in the sister compound of the present invention is about 0. U to about 10X, preferably about 0.1 × to about 5X. The anti-acne actives: The weight ratio of the pyrrolidine-matrix complexing agent is about 1 to about 0, preferably about 5: 1 to about 1: 5. The preferred embodiment of the present invention further comprises about 0.01¾ to about 5% by weight * may An acid or a salt thereof dissolved in water at a pH value lower than or equal to the corresponding acid pKa, for example, an acid selected from the group consisting of betulinic acid, boric acid, and salts * and mixtures thereof, etc. These materials may be used in the present invention from The solubilizing point of the rib anti-acne actives is used in combination with the pyrrolidone matrix compound. From the point of view • Particularly preferred is sodium citrate beetate. In a preferred embodiment, the acid or its The dissolution level of the salt at 25 t is at least 5S! W / ν ». The printed materials of the present invention can be emulsion U / ο or ο / w), gelatin or lotion. Form, but JSM is in the form of water-in-oil rolling fluid, in which, in the preferred case, its oil phase contains volatile silicone and non-volatile A mixture of ketones. The silicone oil contains up to about 1 to about 50% by weight. Suitable volatile silicone oils include cyclopentadiene and pyrene volatile polyorganosiloxane (as used herein " volatile- ! 〇 This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 40130 ο Α7 Β7 V. Description of the invention (8 words refer to 1 ^ mass of measurable vapor pressure under ambient conditions ° For instructions on printing various volatile silicones in the Consumers' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, please refer to Todd, et al *, MVolatile Silicone Fluids for Cosmetics ", 91 Cosmetics and Toiletries 27-32 (1976) ° Silica gel includes a polydimethylsiloxane having about 3 to about 9 silicon atoms, and a polydimethylsiloxane having about 4 to about 5 silicon atoms. Preferred linear silicone oils include polydimethylsiloxanes with about 3 to about 9 silicon atoms. Linear volatile silicones typically have a viscosity of less than about 5 centimeters at 25C. Rhenium has a viscosity below about 10%. Examples of sanding oils that can be used in the present invention include: Dow Corning 344, Dow COrning 21330 'Dow Corning 345, and Dow Dorning 200 (all manufactured by the Dow Corning Corporation); Silicone 7207 and Silicone 7158 (the Union Carbide Corporation) 〇〇 > SF: 202 (product of General Electric) and SWS-03314 (product of Stauffer Chemical), etc. General non-volatile silicone preferably has an average viscosity value of about 1,000 to about 25t 2,000,000 mm2.s-1 * more preferably about 10,000 to about 1,800,000 mm2.s-1, even more preferably about 100,000 to about 1,500,000 bb ^ .s-1. However, it can also be used Lower viscosity non-volatile silicon JR conditioner. Viscosity can be measured using a glass capillary viscometer as described in Dow Corning Corporate Test Method CTM 0004, July 20, 1 970. Suitable non-volatile for use in the present invention Silicone fluids include polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes

I 装订 I ' 11 - 本紙張又度適用t國國家揉準（CNS ) A4規格（210X297公釐） 401306 A7 B7 五、發明説明（9,）具有胺官能取代基的聚矽氧烷，聚醚矽氧烷共聚物’及上述之混合物等。可用於本發明中的矽氧烷可Μ用任何數目的部份聘予Μ封端，包括，例如，甲基，羥基，環氧乙烷，瑁氧丙烷，胺基和羧基等。不過，也可以用具有皮虜調理件質的其他矽酮流體。可Μ用於本發明中的非揮發性聚烷基矽氧烷流體包括，例如，聚二甲基矽氧烷。這類矽氧综有，例如，可得自 the General Electric Company 的 Viscasil RTM)系列和得自 Dow Corning 的 the Dow Corning 200系列。較佳者，其在25t的黏度範圈為約l〇 1«1112.5_1至約100,00〇1111112.5_1。可以使用的聚院基芳基砂氧烷流艚也包括*例如，聚甲基苯基矽氧烷。這類矽氧烷可為，例如，得自 the General Electric Company的 SF 1075甲基苯基流體或得自Dow Corning的556化粧品级流髑。可Μ使用的聚醚矽氧烷共聚物包括，例如•聚環氧丙烷改質二甲基聚矽氧烷（如，Dow Corning DC-1248)，不過，也可Μ使用環氧乙烷或環氧乙烷/環氧丙烷混合物。揭示適當矽酮流體的參考文獻包括Green的US-A-2,826,551 ， 1976年 6 月 22 日核發給 Drakoff 的 US-A- 3.964,500; Pader的 USA-4,364,837 ;及 Woolston的 GB-A-849,433 等。此外，1984年 Petrarch Systems Inc. 發行J4) ”Silcione Compounds”提出一份通用矽嗣流體的充分（但並未完全）之表列。可供本發明所用的較佳非揮發性矽酮包括含有至少一個聚二有機基矽氧烷節段和至少一個聚氧烯節段的聚二有機 -12 本紙張尺度適用中國國家橾準（CNS ) A4規格（210X297公釐） -請先 W 讀背之注裝訂經濟部中央橾準局貝工消费合作社印製 401306 A7 B7 五、發明説明（10，）蓽矽氧烷-聚氧烯共聚物，該聚二有機基矽氧烷節段基本上包含I Binding I '11-This paper is again suitable for National Standards (CNS) A4 (210X297 mm) 401306 A7 B7 V. Description of the invention (9,) Polysiloxanes with polyfunctional amines and polyethers Siloxane copolymer 'and mixtures thereof. Siloxanes that can be used in the present invention can be terminated with any number of moieties, including, for example, methyl, hydroxy, ethylene oxide, oxypropane, amine, and carboxyl groups. However, other silicone fluids with Pilot conditioning can be used. Non-volatile polyalkylsiloxane fluids that can be used in the present invention include, for example, polydimethylsiloxane. This type of silicon oxide is comprehensive, for example, the Viscasil RTM series available from the General Electric Company and the Dow Corning 200 series available from Dow Corning. Preferably, its viscosity range at 25t is about 10 1 «1112.5_1 to about 100,000 0111112.5_1. Polyaryl aryl sands that can be used. Oxygen flow also includes * for example, polymethylphenylsiloxane. Such siloxanes can be, for example, SF 1075 methylphenyl fluid from the General Electric Company or 556 Cosmetic Grade Fluid from Dow Corning. Polyethersiloxane copolymers that can be used include, for example, • polypropylene oxide modified dimethylpolysiloxane (eg, Dow Corning DC-1248), but ethylene oxide or cyclic Ethylene oxide / propylene oxide mixture. References revealing suitable silicone fluids include US-A-2,826,551 by Green, US-A-3.964,500 issued to Drakoff on June 22, 1976; USA-4,364,837 by Pader; GB-A-849,433 by Woolston, etc. . In addition, in 1984, Petrarch Systems Inc. issued J4) "Silcione Compounds" to present a sufficient (but not complete) list of general purpose silicon fluids. Preferred non-volatile silicones that can be used in the present invention include polydiorganic-12 containing at least one polydiorganosiloxane segment and at least one polyoxyalkylene segment. ) A4 size (210X297mm)-Please read the note first and print it. 401306 A7 B7, printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperative. 5. Description of the invention (10,) 荜 Siloxane-polyoxyene copolymer The polydiorganosiloxane segment basically contains

RbSi0(4-bj/2 石夕氣烷單位，式中b具有約0至約3之值（包括0和3)，於該共聚物的所有矽氧烷軍位中每髑矽平均有約2個R基，目.R表選自甲基，乙基，乙烯基，苯基和將該聚氧烯節段键结到該聚二有機基矽氧烷節段的二價基等之中的基* 金部R基中至少有約9 5«為甲基；且該聚氧烷節段具有至少約1000的平均分子量且包含約〇至約50莫耳％的聚氧丙烯單位和約50至約100莫耳％的聚氧乙烯單位，該聚氧烯節段的至少一個末端部份係鐽结到該聚二有櫬基矽氧烷節段者，而未鐽结到該聚二有機基矽氧烷節段的該聚氧烯節段所具任何终端部份則加上一终端基；該共聚物中的聚二有機棊矽氧烷節段對聚氧烯節段之重量比例值為約2至約 8 。這揷聚合物載於US-A-4,268,499之中。 . 最遘用於本發明中的聚二有櫬基矽氧烷-聚氧烯共聚物為具有下示通式者： CH3 CH3 CH3 CH3 經濟部+央梂準局負工消费合作杜印裝 I. I I ! H3C Si 〇 (Si-0— (Si-〇) -si- CH3 CH3 ch3 c3h6 ch3 Ο (〇2Κ4〇)a(C^KgO) -13 - 本紙張尺度適用t國國家標準（CNS ) A4規格（210X297公釐） 401306 A7 B7RbSi0 (4-bj / 2 Shixane unit, where b has a value of about 0 to about 3 (including 0 and 3), and there is an average of about 2 per silicon in all the siloxane positions of the copolymer R groups, and the R table is selected from the group consisting of methyl, ethyl, vinyl, phenyl, and the divalent group that bonds the polyoxyene segment to the polydiorganosiloxane segment. At least about 9 5 «in the gold group R group is a methyl group; and the polyoxane segment has an average molecular weight of at least about 1000 and contains about 0 to about 50 mole% of polyoxypropylene units and about 50 to About 100 mol% of polyoxyethylene units, at least one terminal portion of the polyoxyene segment is bound to the polydifluorenylsiloxane segment, but not to the polydiorgano A terminal group is added to any terminal part of the polyoxyene segment of the siloxane segment; the weight ratio of the polydiorganofluorene siloxane segment to the polyoxyene segment in the copolymer is About 2 to about 8. This polymer is contained in US-A-4,268,499. The polydifluorenylsiloxane-polyoxyene copolymer most preferably used in the present invention is one having the general formula shown below : CH3 CH3 CH3 CH3 Ministry of Economic Affairs + Industrial and Consumer Consumption Cooperation of the Central Bureau of Standards and Duty Printing I. II! H3C Si 〇 (Si-0— (Si-〇) -si- CH3 CH3 ch3 c3h6 ch3 〇 (〇2Κ4〇) a (C ^ KgO)- 13-This paper size is applicable to the national standard (CNS) A4 specification (210X297 mm) 401306 A7 B7

五、發明説明（U 經濟部中央標準局—工消费合作社印製式：中X和y係選擇段之重最比例值為 0 . 5至約1 ;且R為，如甲棊，乙基，烷氧基，如甲氧基 ;芳氧基*如苯氧醯氧基•如乙醢氧如二甲胺基等之中該共聚物中諸節物所含聚二有機基佳地為約2.5至約適用的共聚物在 Gfisohafsbereich 名為Be丨s丨1 (RTM) House, Victoria 的 Abi1 (RTM)。特 6031 , Ab i1 (RTH) 矽酮為CTFA命名為 copolyol)者0 矽油相較佳地佳者約5«至約15SK 本發明姐合物的物。本發明濕潤劑得使聚二有機基矽氧烷節段對聚氧烯節約2至約8 ;a:(a + b)的荑耳比例為約鐽终端基，特別是選自氫；羥基；烷基丙基，丁基，苯甲基；芳基，如苯基；，乙氧基，丙氧基，丁氧基；苯甲氧基基；烯氧基，如乙烯氧基和烯丙氧基；基，丙烯醯氧基和丙醣氧基；及胺基，者0 段的數目和平均分子量皆為可使該共聚矽氧烷節段對聚氧烯節段的重量比例較 4.0 〇市面上可得自Wacker-Chemit GmbH， S, Postfach D-8000 Munich 22’ 商 no ;及得自 Th. Goldschmidt Ltd. Tego Road, Ruislip, Middlesex, HA4 OYL 別適用於本發明者為Belsil (RTM) B88183和DC3225C 。較通用於本發明的二甲基矽酮共多元酵（dinethU(5ne 含有以姐合物重量計約23!至約25!S ’更的非揮發性矽酮。一高度較佳成份為濕潤劑或濕潤劑混合或濕潤劑混合物的含量為姐合物重量的 14 本紙張尺度適用中逋國家橾準（CNS ) Α4規格（210X297公嫠）先閱背 A 之注裝訂 A7 B7 401306 五、發明説明（12 ) 約0.U至約30X ，較佳者為約5«至 1 0¾:至約20¾ 。缠用的濕濶謂為選甘油酯潤滑劑之中者•其在2 5 t：的 1.100,000 cps ;在 25C 的比重為谙為5.0至5.5;结合水含量為33至最為5至20%。該濕潤劑可Μ至少部份地摻加到形成多相水包油包濕潤劑分散液。合物基礎計約0.1Χ至約10!Κ* 更佳的濕濶劑。該濕潤劑可以用與粒吠料的混合物或摻加在其内的形式導具有所欲性質的聚甲基丙烯酸甘 Chemical Corporation^ 註冊商檷品。其中 Μ 編為” L u b r a j e 1 D V ” . ” ” I, u b r a j e I C G ” 等的” L u b「a j e 1 s ” 埴些註冊商標下銷售的膠凝劑含有其他適用的濕潤劑包括山梨糖酵酵，己二酵，烷氧化葡萄糖衍生物 E-20，己三酵，和葡萄糖醚，及上約25；«* 且更佳者為約自甘油和聚甲基丙烯酸黏度為300 , 000至 1至1 . 2克/毫升；其p Η 58¾ ; 且，其自由水含油包水乳液的油相中Μ 該油相較佳地含有Μ姐者約0 . 1至約3重量％親油性或疏水性載體物到油相内。油酷潤滑劑有Guardian ” L u b r a j e 1 ”銷售的產 Lubrajel MS"和較適用於本發明中。在約1 χ丙二酵。，泛酵，丙二醇，丁二，例 2如 Glucam (RTM) 述之混合物等。腺也可先閎背 it 之注經濟部中央橾準局WC工消费合作杜印製。醇劑泛濶D-濕自為選作% 中可相劑3’ 水潤-3 内濕)] ffiJ?* 加泛丙 W 羥基羥汀ar 西rp 泛酸 . 米 0蓋基甲二胺釀酵泛王蜂鈣酸泛潘生 , 維継合乙綜醯和泛糖 ’ 乳胺醯乙泛基’ 疏酵醯哆泛吡 5 1 本紙張尺度適用中國國家標準（CNS ) M规格（2丨0><297公釐） 40130 ο Α7 Β7 五、發明説明（ 13 素B等較適 1,2,3-本發明中的包栝具光散射锇，群照化粧合物。本發用於本丙三酵明較佳色素可有低顏劑等。青Μ * 組合物經濟部令央標準局負工消费合作社印家明姐合優良的整髑相一部份，提出含溶解在水相或色素混合物打底姐合物功能為遮蔽皮機藥劑，亦即 Dictionary ，砂嗣處理過的钛，S 土，水氧化样等部可色素，如用硫遇的雲母）。發明的濕潤劑為甘油。化學上，甘油為且為商業產品。實施例包含色素或色素混含物。適用於本發為無機物及/或有機物。此外，色素一詞亦色或光澤的物質，例如，無光修飾劑，以及通用色素的例子有氧化鐵，醯基穀胺酸氧化 D&C染料，胭脂紅，及上述之混合物等，依的類型，如打底或腮紅等，通常採用色素混物的一項特點為該色素和抗痤提活性物具有容性和顔色安定性。依此，根據本發明的另油包水或水包油乳液形式的化粧组合物，包中的酸性抗痤瘡活性物及分散在油相中的色素〇也包括至少一種無光修飾劑。無光修飾劑的 «Τ缺陷和減少油光。這種化粧品可接受的無 * 載於 C T F A C 〇 s m e t ί c I n g r e d i e n t 第三版之中者，如氧化矽，水合氧化矽，經氧化矽珠粒，雲母，滑石，聚乙烯，二氧化輝石，高嶺土，白堊，矽藻土，活性白土， Μ使用。特別可用為無光修飾劑者為低光澤酸鋇塗被過的钛酸化雲母（用二氧化钛塗被於可用為無光修飾劑的無機成份中’以低光 -16 - 本紙》適用中國國家梂準（CNS )八峨^ ( 21〇χ297公爱） .請先閱背面之注V. Description of the invention (U Central Bureau of Standards, Ministry of Economic Affairs-Industrial and Consumer Cooperative Cooperative Printing System: The ratio of the weight of the X and y series selected segments is 0.5 to about 1; and R is, for example, formazan, ethyl, Alkoxy, such as methoxy; aryloxy *, such as phenoxyfluorenyloxy; such as acetaminox, such as dimethylamino; etc. The polydiorganic group contained in the copolymers in the copolymer is preferably about 2.5 Applicable copolymers at about Gfisohafsbereich are named Be 丨 s 丨 1 (RTM) House, Victoria's Abi1 (RTM). Special 6031, Ab i1 (RTH) silicone is named CTFA as copolyol) 0 Silicone oil phase is preferred The best is about 5 «to about 15SK. The humectant of the present invention can save the polydiorganosiloxane segment to the polyoxyene by 2 to about 8; the a: (a + b) ratio of the ear is about 鐽 terminal group, especially selected from hydrogen; hydroxyl; Alkylpropyl, butyl, benzyl; aryl, such as phenyl;, ethoxy, propoxy, butoxy; benzyloxy; alkenyloxy, such as vinyloxy and allyloxy Groups; groups, allyloxy and trisoxy groups; and amine groups, where the number of 0 segments and the average molecular weight are both such that the weight ratio of the copolysiloxane segment to the polyoxyene segment is more than 4.0. Available from Wacker-Chemit GmbH, S, Postfach D-8000 Munich 22 'Shang No; and from Th. Goldschmidt Ltd. Tego Road, Ruislip, Middlesex, HA4 OYL Not suitable for the inventor is Belsil (RTM) B88183 And DC3225C. Compared to the dimethyl silicone copolyenzyme (dinethU (5ne) which is generally used in the present invention, it contains more non-volatile silicone than about 23! To about 25! S by weight of the compound. A highly preferred ingredient is a wetting agent The content of the humectant mixture or humectant mixture is 14% of the weight of the sister compound. The paper size is applicable to the Chinese National Standards (CNS) A4 specifications (210X297). Please read the back binding A7 B7 401306 5. Description of the invention (12) about 0. U to about 30X, preferably about 5 «to 10 0 :: to about 20 ¾. The wet weave used is said to be one of the selected glyceride lubricants. It is 1.100 at 2 5 t: 10,000 cps; the specific gravity at 25C is 5.0 to 5.5; the combined water content is 33 to 5 to 20%. The humectant can be added at least partially to form a heterogeneous oil-in-water-in-humidant dispersion Based on the composition basis, about 0.1 × to about 10! K * better wet liniment. The humectant can be used in the form of or mixed with granule bark to guide polymethacrylic acid with desired properties. Chem Chemical Corporation ^ Registered counterfeit products. Among them, M code is "L ubraje 1 DV". "" I, ubraje I CG ", etc." Lub "aje 1 s". The gelling agents sold under some registered trademarks contain other suitable humectants including sorbase, adipase, alkoxylated glucose derivative E-20, and adipokine. And glucose ether, and above about 25; «* and more preferably from about glycerol and polymethacrylic acid having a viscosity of 300,000 to 1 to 1.2 g / ml; its p Η 58¾; and, its free water In the oil phase of the water-in-oil emulsion, the oil phase preferably contains about 0.1 to about 3% by weight of a lipophilic or hydrophobic carrier into the oil phase. The lubricants include Guardian ”Lubraje 1 "Produced by Lubrajel MS " and is more suitable for use in the present invention. At about 1 x malonase. Pantothenic acid, propylene glycol, butane, Example 2 such as the mixture described in Glucam (RTM). it Note Produced by WC Industrial and Consumer Cooperation of the Ministry of Economic Affairs of the Central Government Bureau of Commerce and Industry. Du Alcohol D-wet is selected as% Medium Phase Agent 3 'Moisturizing-3 Internal Wet)] ffiJ? * Add pan-propyl W Hydroxyhydroxytin ar xi rp pantothenic acid. Rice 0 gaky methyldiamine fermented pan-king calcic acid pan-panson, vitamin B Comprehensive and pansugar 'Lactamine 醯 Ethyl ubiquinyl' lysozyme ubiquitin 5 1 This paper size applies to Chinese National Standard (CNS) M specifications (2 丨 0 > < 297 mm) 40130 ο Α7 Β7 V. Description of the invention (13 prime B and the like are suitable for 1, 2, 3, and the package in the present invention has a light-scattering compound, and a group photo cosmetic composition. The preferred pigments used in this application for glycerol may be low-fat agents. Qing M * Composition of the Ministry of Economic Affairs, the Central Standards Bureau, Off-line Consumer Cooperative, Yin Jiaming, together with the excellent tidy phase, proposed to contain the function of dissolving in the water phase or the pigment mixture as a primer to hide the skin medicament. Also known as Dictionary, sand-treated titanium, S soil, water oxidation samples and other pigments, such as mica encountered with sulfur). The humectant of the invention is glycerin. Chemically, glycerol is a commercial product. Examples include pigments or pigment blends. Applicable to this invention is inorganic and / or organic. In addition, the term pigment is also colored or shiny, for example, matte modifiers, and examples of general pigments are iron oxide, glutamic acid oxidized D & C dye, carmine, and mixtures thereof, etc., according to Types, such as primers or blushers, usually use a pigment mixture. One characteristic of the pigment is that the pigment and anti-acne active are capacitive and color stable. Accordingly, the cosmetic composition in the form of another water-in-oil or oil-in-water emulsion according to the present invention, the acidic anti-acne active substance in the package and the pigment dispersed in the oil phase, also include at least one matte modifier. Matting modifiers «T defects and reducing shine. Acceptable for this cosmetic * are contained in the third edition of CTFAC 〇smet ί c I ngredient, such as silica, hydrated silica, silica beads, mica, talc, polyethylene, pyroxene dioxide, kaolin , Chalk, diatomaceous earth, activated clay, Μ used. Particularly suitable for matte modifiers are low-gloss barium acid-coated titanated mica (coated with titanium dioxide in inorganic ingredients that can be used as matte modifiers. 'Low-light-16-This paper' applies to Chinese national standards (CNS) Ba'e ^ (21〇χ297 公爱). Please read the note on the back first

I 妾裝訂 401306 A7 B7 五、發明説明（U ) 經濟部中央揉準局員工消费合作杜印«. 澤色素及上述光敗射样者約化矽粒色素，較佳決定於色素混化鈦a 從濕，較逋例如胺卵磷BS 烷）處本發者含有約5至本發或甲基合物較地分散件聚合 *滑石的混合劑的物 5至約子等。的缌濃者為約選用於合物。更佳者涠化，用於本基酸，和酯油琿過的明姐合約30至約70，明化粧丙烯酸，同時佳者為在其整物可為，聚乙物等為質可槪 50微米度可為 1至約打底化較佳的，約5 皮膚感發明的如離胺等予Μ 色素。物的其約95 * 更佳者姐合物酯共聚幫肋提共聚物髑a包具有約烯，水合氧化矽*高嶺土，二氧化鈦特別較適用箸。適合用於本發明作為括地描述為具有高達約100微米，較的粒度之球形無機物質，例如球形氧總姐合物重量的約0.1至約25重量％ 10重量％，其正確瀰度在某些程度上粧或腮紅之中Μ達到所欲色調的特殊姐合物含有約2至約20重量％的二氧至約1 0重量％的二氧化鈦。 *皮虜外觀和乳液相容性等覬點來看色素為經處理過的色素。色素可Κ用酸；矽酮，月桂醯•膠原|聚乙烯* 處理。更適用的色素為矽酮（聚矽氧餘部份為去離更佳者約40至約20至約60重也可Κ包含粒物。該共聚物供有效的濕潤乳膠形式，有在該共聚物乳 50至500 »較子水。該約80重量量％的水狀交聯疏特別可用效益。該至少一種膠之内。佳者100 姐合物 %的油相。水性丙 Μ減低交聯疏活性成另夕卜，至300 較佳為相|和烯酸酷閃光並水性聚份均勻該疏水米2/克先閱背面之注I 妾 Binding 401306 A7 B7 V. Description of the invention (U) The consumption cooperation of employees of the Central Bureau of the Ministry of Economic Affairs, Du Yin «. From the wet, more concentrated (such as amine lecithin BS alkane), the hairdresser contains about 5 to about 50% of the hair or methyl compound dispersion dispersion polymerized * talc mixture and so on. The strontium is selected for the compound. It is better to use it for the base acid, and the contract with the ester oil Mingjie sister 30 to about 70, make-up acrylic, meanwhile it is better to use it in the whole thing, polyethylene, etc. The micron degree may be from 1 to about 10, preferably about 5 for priming pigments such as lysine, etc., which are skin-sensitive inventions. Its properties are about 95 * better, sister compound, ester copolymerization, ribate copolymer, 髑 a package, with about olefin, hydrated silica * kaolin, titanium dioxide is particularly suitable for 箸. Suitable for use in the present invention as described in general terms as spherical inorganic substances having a relatively large particle size of up to about 100 microns, such as about 0.1 to about 25% by weight and 10% by weight of the total weight of the spherical oxygen compound. To a certain extent, the special composition for achieving a desired hue in makeup or blush contains about 2 to about 20% by weight of dioxygen to about 10% by weight of titanium dioxide. * From the point of view of skin appearance and emulsion compatibility, pigments are treated pigments. Pigments can be treated with acid; silicone, laurel • collagen | polyethylene *. A more suitable pigment is silicone (the rest of the polysiloxane is about 40 to about 20 to about 60 weights, which can be better off. Particles can also be included. The copolymer is provided in an effective wet latex form. Milk 50 to 500 »Comparison water. The about 80% by weight of water-like cross-linking agent is particularly useful. The at least one gum is within. The best 100% compound oil phase. Water-based propylene reduces cross-linking Reducing activity becomes another matter, preferably to 300 phase | and enoic acid cool flash and water-based polymer uniformity The hydrophobic rice 2 / g

I -17 本紙張尺度適用中國困家橾準（CNS ) A4規格（210X297公釐） A7 B7 401306 五、發明説明（15.) 的表而積（N 2 - B E T ) 該交聯最％目.較份可為一劑，加濕末形式，乳膠*其在約20到 Μ及尺寸聚物閹塊可用於描述為經佳者具有式的活性成自由潦物質。該疏水性聚佳者是揍或多揷皮劑•和防該粉末為中包含平 100微米在約20 0 凝集賵等本發明作交聯的“ 包覆和分物。該·乳動性個別聚合物具 a其内吸合物在本加在外部釀相容性晒劑等或粒子的組均直徑小平均直徑至 1 , 200 收著活性發明的用含矽酮油油，皮虜其混合物合糸统。於約一微範圍内的微米平均狀粒子。至約10重該活性成劑•潤滑材料為粉 ***形成子，尺寸子黏聚物的稠合鈷為活性成份載體的後吸收”疏水性聚散在其內的可為固膠為粒狀形式旦於固體粒子。該乳膠有下示構造式：粉末物質可Μ廣義地合物孔膠。該粉末較體•液體或氣體等形装載活性物質時，構可包含預定量的活性成份之孔洞量為約0 . 1 相之中者。相容性濕潤。該聚合物該粉末粒子米的單位粒稠合單位粒直徑範圍内請 *先閱讀背面之注I -17 The size of this paper is applicable to Chinese Standards (CNS) A4 (210X297 mm) A7 B7 401306 V. Table of the invention description (15.) (N 2-BET) The cross-linking is the most important. The portion may be in a single dose, in the form of a humidified, latex * which is in the range of about 20 to M and the size of the polymer block can be used to describe the active compound as a free compound. The hydrophobic polymer is osmium or multi-skinning agent, and the powder is a "coating and fraction" which is cross-linked by the present invention, which includes agglomerates of about 100 micrometers at about 20 0. The milky individuality The polymer has a mixture of internal absorbing materials and externally-compatible additives such as sunscreen or particles. The average diameter of the particles is small and the average diameter is 1,200. The active invention contains a silicone-containing oil, and a mixture of pimples. Combined system. Micron-like particles in the range of about one micron. Up to about 10 weights of the active agent • Lubricating material is a powder system former, and the fused cobalt of the dimensional cohesive polymer is the post-absorption of the active ingredient carrier " Hydrophobic aggregates dispersed therein may be solid gels in a granular form rather than solid particles. The latex has the following structural formula: The powder material can be used to form a porous gel. When the powder is filled with an active substance in the form of a liquid, a gas, or the like, the amount of pores that can contain a predetermined amount of the active ingredient is about 0.1 phase. Wet compatibility. The polymer, the powder particles, the unit particles of rice, and the unit diameter of condensed units. Please read the note on the back first.

I 裝訂經濟部中央橾準局貝工消费合作社印製 8 ti 本紙張尺度適用中國國家操準（CNS ) A4规格（210X297公釐） 401306 A7 B7 五、發明説明（1& ) CK-I Binding Printed by Shelley Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs 8 ti This paper size is applicable to China National Standards (CNS) A4 (210X297 mm) 401306 A7 B7 V. Description of Invention (1 &) CK-

CH— C CH： 'C ·CH— C CH: 'C ·

CH 2 C-0 c»o 〇 0 ，請先閱背 Λ 之注 CH- R, ! I 0 ! i C-0 i ic—— R1CH 2 C-0 c »o 〇 0, please read the note of Λ CH- R,! I 0! I C-0 i ic—— R1

YY

I 旁Next to I

CH 3CH 3

X 經濟部中央揉準局工消费合作社印製式中X對y的比例為8 0 : 2 0，R '為-C H 2 C Η 2 -且R ”為 (CHs!)! 1CH3 0 疏水性聚合物為高度交騍聚合物，更恃別者高度交聯的聚甲基丙烯酸醋共聚物。該物質為美國•密西根州，米蘭 (Mi dj_ and)的 the Dow Corning Corporation 所製並 Μ 註冊商標？01^了1^?(111^)銷售。其為超輕的自由流動性白粉目該粒子能夠吸收高水平的親脂性液體和某些親水性液體，同時仍然保持自由流動粉末特性。該粉末結構係由單位 19 - 本紙張尺度適用中國國家標準（CNS ) Α4规格（210Χ297公釐） 401306 A7 B7 五、發明説明（17 ) 粒子小於黏聚物鬆凝樂物所流聘，轧活性物成，其中覆到聚合聚合物的度為lh而，螺條或甘油。較一微米散地集構成者液，分對聚合包括將物粉内可密封被吸附雙维摻佳者· 的乳膠稠合蔟成約2 0 0 。該聚合物散液或溶化物粉的吸附活性物加到。低黏度流容器内*然掉。也可Μ 合器等。較濕潤劑：載成20至100微米至約1200微米尺粉能夠包含多達固體。可Μ用不锈網混粉末並用匙均匀體可Κ經由將流後將該物質鼓轉採用更精巧的摻通用於本發明中體重量比例為約的黏聚物且該寸的巨粒子或四倍其重量的合鉢和匙來完地將活性物包體加到装著該到達到一稠密合設備，例如的活性成份為 1 : 4至約3 : 1 -請先閱背面之注裝經濟部中央揉準局負工消费合作杜印製另有適用為高密度交 Microsponges 5647 ° 物粒子形式，具有約0. 平方米/克之表面積。水平的濕涠劑。本發明姐合物也可以為為約0.0U至約10« 別者為約0.02¾至約0. 4000jPa . S，更佳者至 50,000 mPa.S的黏度（聯聚甲基丙烯酸酯共聚物者為其為大膀為球形的交聯疏水性聚合 01至約0.05微米的孔徑及200-300 同樣地，其較佳者也是裝載著上述含有親水性膠凝劑，其水平較佳者，更佳者為約0.02X至約2!«，且特 5¾。該膠凝劑較佳者具有至少約少約10,000 «^3.5且特別者至少 % 水溶液，2 0 t：，B r ο 〇 k f i e 1 d R V T ) 適合的親水性膠凝劑可概括地描述為水溶性或膠體狀水 20 - 本紙張ΛΑϋ用家料（CNS ) A4^ ( 21GX297公釐）訂 401308 A7 B7 五、發明説明。8,) 溶件聚合物，包括嫌維素醚（如，羥乙基缴維素，甲基纖維素，羥丙基甲基纖維素），聚乙烯醇， P〇lyciuartern{um-10，苦阿爾膝（guar gum)，經丙基苦阿爾核及.黃爾膠（xanthan gum)等.。適用的親水性膠凝劑包括B.F. Goodrich Company所售在許冊商標為Carbopol樹脂之下的丙烯酸/丙烯酸乙醋共聚物和羧乙烯基聚合物。這些樹脂基本上係用丙烯酸與 0.75J：至2.00SK交聯劑，如多烯丙基蔗糖或多烯丙基季戊四酵等交聯所得膠體樣水溶性聚烯聚醚交聯聚合物。其例子包栝：C a r b ο ρ ο 1 934，C a r b ο ρ ο 1 940，Carbopol 9 50 * C a r b ο p 〇 1 980，Carbopol 951 和 Carbopol ,981 等 ° Carbopol 934為丙烯酸與約1¾，每蔗糖分子平均具有約 5.8烯丙基的蔗糖多烯丙基链經交聯而得之水溶性聚合物。另外，適用於本發明者為可在商品名為Carbopol 1382 ’ Carbopo丨1342和Penu len TR-1等之下得到的具有兩親媒性件質的經疏水改質交聯丙烯酸聚合物（CTFA名稱：丙稀酸酯/丙烯酸10 -3 0烷基酯交錯聚合物）。聚烯聚醚交 #丙烯_聚合物和疏水改質交聯丙烯酸聚合物的姐合也適用於本發明中。適用於本發明的其他膠凝劑為油凝膠，例如三基硬脂和羥基硬脂酸鋁鎂。本發明所用膠凝劑特別可用i提供在常溫和增溫下的優異安定性特性。適合用於中和本發明所用含酸基親水性膠凝劑的中和劑包栝氣氧化納，氫氧化钾，氫氧化銨，一乙醇胺，二乙酵胺和三乙酵胺。 -21 -A4洗格（210x297公釐） (請_先閱讀背面之注意事項再填寫本頁) 裝經濟部t央搮準局負工消费合作社印裂本纸張尺度適用中國國家樣準（CNS ) 401306 5 經濟部中央棵筚局貝工消费合作社印製五、發明説明（19 ) 本發明化粧組合物可另外包含濶滑劑。適合本發明組合物所用的潤滑劑包括選自碾油，植物油和動物油，脂肪和蠟，脂肪酸酯，脂肪醇’烷二醇和聚烷二醇醚和酯，脂肪酹，與h述之混合物等之中的天然和合成油。適合用於本發明的潤滑劑包括，例如，視需要經羥基取代的不飽和脂肪酸及其酯，Ca-C3〇飽和脂肪酸的醅，如肉豆蔻酸異丙醏，棕擱酸鲸蠟酯及肉豆蔻酸辛酯十二烷酯（Wickenol 142)，蜜蠅，飽和及不飽和脂肪酵，如二十二垸酵和鲸蠟酵；烴，如磺油，石蟠脂和角鯊烷；脂肪酸山梨糖酵醋（參看US-A-3988255，1976年10月 26日核發给Seiden者）’羊毛脂和羊毛脂衍生物，如羊毛賄醇，乙氧化，羥基化和乙醯化羊毛脂；膽固酵及其衍生物；動物和植物甘油三酸酯，例如，杏仁油，花生油，麥芽油，亞麻仁油，荷荷芭油（j 〇 j 〇 b a 〇 il)，Μ及杏果•核桃，棕糊堅果，乳番*芝麻仁及菜仔等的油，杜松油，玉米油，桃果油，m粟子油，松油，蓖麻油，大豆油，鰐梨油，紅花油，椰子油，榛子油，橄攬油，葡萄子油’及葵花油等，Μ及二體酸和三膊酸的Ci -c24酯，例如，二體酸二異丙酯，蘋果·酸二異硬脂酯，二體酸二異硬脂酯和三體酸三異硬脂酯等。較准的潤滑劑為選自烴，如異十六烷，礦油，石蠟脂和角鯊烷等；羊毛脂醇，和硬腊醇等之中者。這些潤滑劑可獨立地使用或混合使用，且其在本發明组合物中的含量可為缌姐合物重量的約U到約30% ,且較佳者約5到約15重 -22 - 本纸張尺度適用中國國家標準（CNS ) A4規丨〇><297公釐 -請先閔讀背面之注 i t 訂 40130 A7 _____B7_ 五、發明説明（2。）最％〇本發明组合物也可κ含有另外的物質*例如·香料；填充料，如尼龍，防晒劑，防腐劑，電解質，如氛化納；蛋白質，抗氧化劑，绀合劑及適當的油包水乳化劑等。本發明化粧驵合物的另一選用成份為一或多種紫外光吸收劑。常稱為防晒劑的紫外光吸收劑之濃度可為Μ姐合物總重最計之約1至約12重量％。更佳者，該UV吸收劑在姐合物中的漘度可為約4至約6重量％。於通合本發明所用的紫外光吸收_中·以二苯甲酮-3*辛基二甲基ΡΑΒΑ (Padimate 0)及其混合物等為等別較通用者。另一逋用但較逋用於本發明的成份為一或多種加添的甜合_，其含最較佳者為Μ組合物缌重量計之約0.02至約 0.10重最％。較佳者，該钳合劑的濃度為Μ姐合物缌重量計之約0.03至約0.07重量％。於可加在本發明姐合物内的紺合劑中包栝EDTA四納鹽。打底姐合物的另一選用但較佳成份為一或多種防腐劑。打底组合物中的防腐劑澹度為以該姐合物總重量計之約 0.0 5至約0.8窜最％，較佳者為約0.1至約0.3重量％。適用於本發明的防腐劑包括笨甲酸納和對羥基苯甲酸丙酷，及其混合物等。經濟部中央標隼局貝工消费合作杜印製 (If先閱讀背面之注意事項再填寫本頁) 本潑明化粧組合物可為打底，腮紅•掩飾*壓縮粉等，較伟者為打底和掩飾。提出下而的表Μ閫明本發明化粧組合物。 -23 - 本紙浪尺度適用中國國家標準（CNS ) Α4规格（210X2S»7公釐） 401306 五、發明説明（n ) A7 B7 寅施例 I II Wt Wt A % % 泰酸館蛾酷 2.00 0.0 環甲矽酮 8.57 12.25 環甲矽酮/二甲矽酮共多元醇(90:10) 17.16 20.0 Propylparaben 0.75 0.75 (33%) in laureth-7 ΐ：甲矽酮流體 2.0 0.0 二苯甲酮-3 0.0 0.0 丙二醇二癸酸酯/二辛酸酯 0.0 0.0 B. 二氧化鈦 (水合鋁，環脂酸）處理過的二氧化鈦 8.25 6,0 III IV V VI VII Wt Wt Wt Wt Wt % % % % % 0.0 0.0 0.0 0.0 2.0 12.25 15.0 12.0 8.57 8.57 20.0 5.0 8.0 10.0 17.16 0.0 0.75 0.0 0.75 0.75 2.0 3.0 5.0 10.0 0.0 0.0 0.0 0.0 2.0 0.0 0.0 5.0 0.0 10.0 0.0 1.5 6.0 8.0 20.0 8.25 (請免閱讀背面之注項再填寫本頁) 經濟部中央櫺準局貝工消费合作社印衷X The ratio of X to y in the printed format of the Central Ministry of Economic Affairs and Consumer Cooperatives is 8 0: 2 0, R 'is -CH 2 C Η 2-, and R "is (CHs!)! 1CH3 0 Hydrophobic Polymerization This material is a highly cross-linked polymer, let alone a highly cross-linked polymethacrylic acid vinegar copolymer. This material is manufactured by the Dow Corning Corporation and registered trademark of Milan, Michigan, USA (Mi dj_ and). ? 01 ^ 1 ^? (111 ^) for sale. It is an ultra-light free-flowing white powder. The particles are capable of absorbing high levels of lipophilic liquids and certain hydrophilic liquids, while still maintaining the characteristics of a free-flowing powder. The powder The structure is composed of unit 19-this paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) 401306 A7 B7 V. Description of the invention (17) The particles are smaller than those of the polymer loose aggregate, and the active material is rolled. In which, the degree of covering the polymer is lh, and the ribbon or glycerin. Compared with one micron, the constituent liquid is collected, and the pairwise polymerization includes the latex condensation of the powder that can be sealed and adsorbed by the two-dimensional blender.蔟成约 2 0 0. The polymer is dispersed or dissolved The active substance of the powder is added to it. It is dropped in the low-viscosity flow container. It can also be a mixer, etc. Wetting agent: powder containing 20 to 100 microns to about 1200 microns ruler can contain up to solids. Can be used The stainless steel net mixes the powder and uses a spoon to homogenize the body. After passing the stream, the substance can be transferred to a more delicate blend for use in the present invention. The bowl and spoon are used to finish adding the active substance package to the device that contains the active ingredient. For example, the active ingredient is from 1: 4 to about 3: 1-please read the note on the back of the center and knead The quasi-office consumer cooperation du print is also suitable for high-density microsponges 5647 ° particle form, with a surface area of about 0. square meters / gram. Horizontal wet tincture. The sister compound of the present invention can also be about 0.0 U to about 10 «others about 0.02¾ to about 0.4 000jPa. S, more preferably viscosities of 50,000 mPa.S (for crosslinked polymethacrylate copolymers, it is a spherical crosslinked hydrophobic Polymeric pore size from 01 to about 0.05 microns and 200-300 The preferred one is also loaded with the above-mentioned hydrophilic gelling agent, and the level is better, more preferably about 0.02X to about 2! «, And special 5¾. The preferred gelling agent has at least about less About 10,000 ^^ 3.5 and especially at least% aqueous solution, 20 t :, B r ο 〇kfie 1 d RVT) Suitable hydrophilic gelling agents can be described generally as water-soluble or colloidal water 20-This paper is used for ΛΑϋ Household materials (CNS) A4 ^ (21GX297 mm) Order 401308 A7 B7 5. Description of the invention. 8,) Solvent polymers, including steroids (eg, hydroxyethyl fulvicin, methylcellulose, hydroxypropylmethylcellulose), polyvinyl alcohol, Polyciuartern {um-10, bitter Guar gum, guar gum and xanthan gum, etc. Suitable hydrophilic gelling agents include acrylic / ethyl acrylate copolymers and carboxyvinyl polymers sold under the trademark Carbopol resin sold by the B.F. Goodrich Company. These resins are basically colloid-like water-soluble polyene polyether crosslinked polymers obtained by crosslinking with acrylic acid and 0.75J: to 2.00SK crosslinking agents such as polyallyl sucrose or polyallyl pentaerythritol. Examples include: Carbor ο ρ ο 1 934, Carbor ο ρ ο 1 940, Carbopol 9 50 * Carbor ο p 〇1 980, Carbopol 951 and Carbopol, 981 etc. Carbopol 934 is acrylic acid with about 1¾, each A water-soluble polymer obtained by crosslinking a sucrose polyallyl chain having an allyl group of about 5.8 allyl on average. In addition, suitable for the present inventors are hydrophobically modified crosslinked acrylic polymers (CTFA names) with amphiphilic media available under the trade names Carbopol 1382 'Carbopo 丨 1342 and Penu len TR-1, etc. : Acrylic / acrylic acid 10-3 0 alkyl ester staggered polymer). Polyene polyether cross-linked polymers and hydrophobically modified cross-linked acrylic polymers are also suitable for use in the present invention. Other gelling agents suitable for use in the present invention are oleogels, such as tristearate and magnesium aluminum hydroxystearate. The gelling agent used in the present invention is particularly useful for providing excellent stability characteristics at normal temperature and increased temperature. Neutralizers suitable for neutralizing acid-group-containing hydrophilic gelling agents used in the present invention include sodium oxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethylenamine, and triethylenamine. -21 -A4 Washing (210x297mm) (Please read the notes on the back before filling this page) Installed by the Ministry of Economic Affairs and the Central Bureau of Standards, the Consumers' Cooperatives printed this paper. The paper size is applicable to the Chinese National Standard (CNS ) 401306 5 Printed by the Shellfish Consumer Cooperative of the Central Keji Bureau of the Ministry of Economic Affairs 5. Description of the invention (19) The cosmetic composition of the present invention may further include a smoothing agent. Suitable lubricants for use in the composition of the present invention include those selected from the group consisting of mill oil, vegetable and animal oils, fats and waxes, fatty acid esters, fatty alcohols, alkylene glycols and polyalkylene glycol ethers and esters, fatty acids, mixtures thereof, and the like Among natural and synthetic oils. Lubricants suitable for use in the present invention include, for example, unsaturated fatty acids substituted with hydroxyl groups and esters thereof as required, Ca-C30 saturated fatty acids such as isopropyl myristate, cetyl palmitate, and meat Octyl myristate dodecyl ester (Wickenol 142), honey flies, saturated and unsaturated fatty enzymes, such as sarcozyme and cetyl oxidase; hydrocarbons, such as sulphur oil, petrolatum and squalane; fatty acid sorbose Fermented vinegar (see US-A-3988255, issued to Seiden on October 26, 1976) 'lanolin and lanolin derivatives, such as lanolin, ethoxylated, hydroxylated, and acetylated lanolin; cholesterase And its derivatives; animal and plant triglycerides, such as almond oil, peanut oil, malt oil, linseed oil, jojoba oil (j 〇j 〇ba 〇il), M and apricot fruit • walnut, brown Oils such as nut paste, milk pan * sesame kernels and vegetable seeds, juniper oil, corn oil, peach fruit oil, m corn oil, pine oil, castor oil, soybean oil, avocado oil, safflower oil, coconut oil, hazelnut oil , Olive oil, grape seed oil ', sunflower oil, etc., Ci and c24 esters of M and dibasic acid and trisaccharic acid E.g., diisopropyl dimer acid, apples, diisostearyl, diisostearyl dimer, and tris trisomy isostearyl acrylate. The more accurate lubricants are selected from hydrocarbons such as isohexadecane, mineral oil, paraffin grease and squalane; lanolin alcohol, and stearyl alcohol. These lubricants can be used independently or in combination, and their content in the composition of the present invention can be about U to about 30% by weight of the compound, and preferably about 5 to about 15 weight-22- The paper size applies the Chinese National Standard (CNS) A4 regulations. 丨 < 297 mm-please read the note on the back of the book to order 40130 A7 _____B7_ 5. Description of the invention (2.) The most% 〇 The composition of the present invention also It may contain additional substances * such as fragrances; fillers such as nylon, sunscreens, preservatives, electrolytes such as fume sodium; proteins, antioxidants, couplers, and suitable water-in-oil emulsifiers. Another optional ingredient of the cosmetic blend of the present invention is one or more ultraviolet light absorbers. The concentration of the ultraviolet light absorber, often referred to as a sunscreen agent, may be from about 1 to about 12% by weight based on the total weight of the M compound. More preferably, the degree of the UV absorber in the sister compound may be about 4 to about 6% by weight. In the ultraviolet light absorption used in the present invention, benzophenone-3 * octyl dimethyl PABA (Padimate 0) and mixtures thereof are used as equivalents. Another but more useful ingredient for use in the present invention is one or more added sweeteners, which most preferably comprise from about 0.02 to about 0.10 weight percent based on the weight of the M composition. Preferably, the concentration of the clamping agent is from about 0.03 to about 0.07% by weight based on the weight of the compound. Tetra sodium salt of EDTA is contained in a coupler which can be added to the sister compound of the present invention. Another preferred but preferred ingredient of the primer composition is one or more preservatives. The degree of preservative in the primer composition is about 0.05 to about 0.8% by weight based on the total weight of the sister compound, and preferably about 0.1 to about 0.3% by weight. Preservatives suitable for use in the present invention include sodium benzoate and propylparaben, and mixtures thereof. Printed by Shellfish Consumer Cooperation Department of the Central Bureau of Standards of the Ministry of Economic Affairs (If you read the precautions on the back before filling out this page) The splashing makeup composition can be used as a primer, blusher • masking * compressed powder, etc. Base and cover up. The following table is presented to illustrate the cosmetic composition of the present invention. -23-Chinese paper standard (CNS) A4 specification (210X2S »7 mm) applies to this paper. 401306 V. Description of the invention (n) A7 B7 Example I II Wt Wt A%% Thai acid museum moth 2.00 0.0 ring Silicone 8.57 12.25 Cyclosilicone / Dimethicone copolyol (90:10) 17.16 20.0 Propylparaben 0.75 0.75 (33%) in laureth-7 ΐ: Silicone fluid 2.0 0.0 Benzophenone-3 0.0 0.0 Propylene glycol dicaprate / dicaprylate 0.0 0.0 B. Titanium dioxide (hydrated aluminum, cycloaliphatic acid) Titanium dioxide treated 8.25 6,0 III IV V VI VII Wt Wt Wt Wt Wt%%%%% 0.0 0.0 0.0 0.0 2.0 12.25 15.0 12.0 8.57 8.57 20.0 5.0 8.0 10.0 17.16 0.0 0.75 0.0 0.75 0.75 2.0 3.0 5.0 10.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 10.0 0.0 1.5 6.0 8.0 20.0 8.25 (please skip reading the notes on the back and fill in this page) Central Cooperative Bureau of the Ministry of Economic Affairs

鈦酸化雲母滑石氧化矽尼龍本纸張尺度適用中國困家標窣（CNS > A4规格（2丨OX297公釐） 401306 /五、發明説明（2’2 ) 經濟部中央標準局員工消費合作社印製寅施例 I II III rv V VI VII· Wt Wt Wt Wt Wt Wt Wt % . % % % % % % C. 環甲矽酮/二甲矽酮共多元醇(90:10) 1.85 1.5 1.85 5.0 1.0 1.0 1.85 D. 黃色氧化鐵 1.2 1.2 0.6 0.4 1.2 1.2 1.2 紅色氧化鐵 0.49 0.6 0.6 0.49 0.49 0.2 0.6 黑色氧化鐵 0.16 0.1 0.24 0.1 0.1 0.24 0.24 群青藍 0.0 0.0 0.0 0.1 0.0 0.0 0.0 環甲矽酮 0.0 0.0 0.0 0.0 0.68 0.0 0.0 E. 合成蠟 0.1 0.5 0.5 0.1 0.0 0.0 O.C 二十二烷酸花生酯 0.3 0.0 0.0 0.3 0.5 0.3 0.3 硬脂酸 0.0 0.0 0.0 0.0 0.0 0.0 2.5 棕櫚酸 0.0 0.0 0.0 0.0 0.0 2.5 0.0 氧化砂（spheron 6.0 0.0 6.0 0.0 0.0 0.0 0.0 P1500) F. 一三羥硬脂 0.3 0.3 1.5 1.5 0.0 0.0 0.0 環甲矽酮 1.0 4.0 0.0 0.0 4.0 4.0 4.0 蜜蟠 1.5 1.2 0.0 0.0 1.3 0.0 0.0 Abil WED9 0.0 3.0 0.0 0.0 0.0 0.0 0.0 (請先閲讀背面之注意事項再填寫本頁) L____ 本紙张尺皮適用中國國家標準（CN&) 210X297公釐） 4殳1306 A7 - B7 經濟部中央標準局貝工消费合作杜印製五、發明説明（23 ) • 1 1 I 寅施例 I II III IV V VI VII 1 1 I Wt Wt Wt Wt Wt Wt Wt 1 G. % % % % % % % •請先 1 巴西酸乙烯酯 0.05 0.0 0.0 · 0.0 0.0 0.05 0.05 閲讀背 1 1 I BHT H. 0.05 0.0 0.0 0.0 0.0 0.05 0.05 之注意事項 1 1 1 去離子水 — —----- ——to 100-- ---—— — —-----— 再填 / V V, 乙醇 6 5.5 4.0 7 6.0 8.0 6.0 寫本 ά 柳酸 1 1 1 2 2 2 0.0 頁 1 壬二酸 0.0 0.0 0.0 0.0 0.0 0.0 5 1 I 丙二醇 2.37 2.37 1.37 2.37 0.0 2.37 0.0 1 .1 二丙二醇 6.0 5.0 6.5 7.00 8.0 6.0 5.0 1 1 | 氯化鈉 0.5 0.5 0.5 0.5 0.5 0.5 1.0 \ 訂甘油 4.5 5.0 10.0 5.0 5.0 10.0 15.0 1 EDTA四鈉 0.05 0.05 0.05 0.1 0.1 0.1 0.01 1 1 三乙醇胺 0.0 0.0 0.0 0.0 0.0 0.0 0.75 1 I 尿囊素 0.0 0.0 0.1 0.0 0.0 0.0 0.0 1 防晒劑 0.0 0.0 0.0 0.2 0.2 0.0 0.0 * ’辣聚乙烯基吡咯烷酮- (Luvi skoi K17) 1 2 1.5 1 1 1 1 1 | 檸檬酸鈉 0.3 0.3 0.0 0.2 0.4 0.3 0.4 1 | 四硼酸瘀 0.0 0.0 0.1 0.4 0.0 0.2 0.0 1 I 水相pH值 2.9 2.8 2.9 3.2 3.0 2.9 3.1 * 1 1 Ί 1 I. 去離子水： 0.0 0.0 « 0.0 26 - 0.0 10.0 0.0 0.0 1 1 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）經濟部中夬標準局員工消费合作杜印裝 401306 A7 ______B7 五、發明説明（24 ) 黄施例 I II III IV V VI VII Wt Wt Wt Wt Wt w[ •請先 u 1 % % % % % % % 1 T 1 I J ♦ _ 1 0.0 0.0 0.0 .2.0 0.0 0.0 0.0 背 1 1 0.0 0.0 0.0 0.08 0.0 0.0 0.0 之注 1 I 黃菌膠意重 1 I 項 1 I K. 再 T.· _ 精油 0.0 0.0 0.0 0.20 0.0 0.0 0.0 填 U 0.0 0.25 0.0 0.20 0.0 0.0 0.0 本裝香油頁 S^o 1 I 維生素A 0.0 0.05 0.0 0.0 0.0 0.0 0.0 1 I 棕櫚酸酯 1 -| - L. 葸薈膠 0.0 0.0 3.0 0.0 0.0 0.0 0.0 1 .1 訂洋甘菊萃取物 0.0 0.0 0.1 0.0 0.0 0.0 0.0 1 1 1 来含約丨油的丙二醇 1 1 ! • ! ▲ 1 I 表_中所列各種成份已分成數組，根據下面所述程序，將 1 1 1 I 各姐的構成份先混合後，才加到其他組的成份内。 m I • _ 於第一步驟中，將 A相的成份混合物用剪切混合器攪拌 1 1 約5分鐘到均匀為出。在高速剪切混合之下，將B相的物塞 1 -27 - 本紙張尺度逋用中國國家標準（CNS ) A4规格（210X297公釐） ^〇jl3〇6 A7 B7 五、發明説明（2&) 曹逐漸地加到A中並將該枇料混合2 0分鐘直到分散為止。接著，將C相的成份，然後D相成份慢慢地加到A相和 R相的混合物中並用高剪切混合到分散為止。於此時，加人氧化矽並分散到混合物内。將所得枇料加熱到90 C後，加入E相成份。將容器冷卻到5 5 Τ並加入預混合好的F相。將該批料混合到均勻為止。之後，將混合物冷卻到30Ό ·再加入G相。將Η相的所有成份混合到完全溶解而製備成Η相預混料。於3010下，將Η相預混料Κ高剪切加到該批料混合物内，但要確定表面上沒有超最的水。然後將混合物研磨15分 _。最後，將I，，丨，Κ，和L等相加入作為稀釋劑。所得化枏姐合物即可進行包装。誌等宵施例的化粧詡合物展規出抗痤瘡活性及改良的調配物和顏色安定性。 • - IJI.--Γ-------'Τ 裝----1---r-訂 -,ιν J (_先閎讀背面之注意事項再填寫本頁) 經濟部中央揉準局貝工消t合作社印製 8 2 本紙張適用中國困家樣準（cns )从祕（2丨。χ297公羡）The titanated mica talc oxidized silicon nylon is suitable for the standard of Chinese papers (CNS > A4 size (2 丨 OX297 mm) 401306 / V. Description of the invention (2'2) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System Example I II III rv V VI VII · Wt Wt Wt Wt Wt Wt Wt%.%%%%%% C. Cyclosiloxane / Dimethicone Copolyol (90:10) 1.85 1.5 1.85 5.0 1.0 1.0 1.85 D. yellow iron oxide 1.2 1.2 0.6 0.4 1.2 1.2 1.2 red iron oxide 0.49 0.6 0.6 0.49 0.49 0.2 0.6 black iron oxide 0.16 0.1 0.24 0.1 0.1 0.24 0.24 ultramarine blue 0.0 0.0 0.0 0.1 0.0 0.0 0.0 cyclomethicone 0.0 0.0 0.0 0.0 0.68 0.0 0.0 E. Synthetic wax 0.1 0.5 0.5 0.1 0.0 0.0 OC Peanutyl dodecanoate 0.3 0.0 0.0 0.3 0.5 0.3 0.3 Stearic acid 0.0 0.0 0.0 0.0 0.0 0.0 2.5 Palmitic acid 0.0 0.0 0.0 0.0 0.0 2.5 0.0 Oxidation Sand (spheron 6.0 0.0 6.0 0.0 0.0 0.0 0.0 P1500) F. Tristearyl 0.3 0.3 1.5 1.5 0.0 0.0 0.0 Cyclosilicone 1.0 4.0 0.0 0.0 4.0 4.0 4.0 Honey Melon 1.5 1.2 0.0 0.0 1.3 0.0 0.0 Abil WED9 0.0 3.0 0.0 0.0 0.0 0.0 0.0 (please first Read the notes on the back and fill in this page again.) L____ This paper ruler applies the Chinese National Standard (CN &) 210X297 mm) 4 殳 1306 A7-B7 Printed by Shellfisher Consumer Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs 23) • 1 1 I. Example I II III IV V VI VII 1 1 I Wt Wt Wt Wt Wt Wt Wt 1 G.%%%%%%% • Please first 1 vinyl brasilate 0.05 0.0 0.0 · 0.0 0.0 0.05 0.05 Reading back 1 1 I BHT H. 0.05 0.0 0.0 0.0 0.0 0.05 0.05 Notes 1 1 1 Deionized water — —----- ——to 100-- ---—— — —---- --- Refill / VV, ethanol 6 5.5 4.0 7 6.0 8.0 6.0 Copybooks Salicylic acid 1 1 1 2 2 2 0.0 Page 1 Azelaic acid 0.0 0.0 0.0 0.0 0.0 0.0 5 1 I Propylene glycol 2.37 2.37 1.37 2.37 0.0 2.37 0.0 1. 1 Dipropylene glycol 6.0 5.0 6.5 7.00 8.0 6.0 5.0 1 1 | Sodium chloride 0.5 0.5 0.5 0.5 0.5 0.5 1.0 \ Order glycerin 4.5 5.0 10.0 5.0 5.0 10.0 15.0 1 EDTA tetrasodium 0.05 0.05 0.05 0.1 0.1 0.1 0.01 1 1 Triethanolamine 0.0 0.0 0.0 0.0 0.0 0.0 0.75 1 I Allantoin 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 1 Sunscreen 0. 0 0.0 0.0 0.2 0.2 0.0 0.0 * 'Spicy polyvinylpyrrolidone-(Luvi skoi K17) 1 2 1.5 1 1 1 1 1 | Sodium citrate 0.3 0.3 0.0 0.2 0.4 0.3 0.4 1 | Tetraborate stasis 0.0 0.0 0.1 0.4 0.0 0.2 0.0 1 I pH value of the water phase 2.9 2.8 2.9 3.2 3.0 2.9 3.1 * 1 1 Ί 1 I. Deionized water: 0.0 0.0 «0.0 26-0.0 10.0 0.0 0.0 1 1 1 1 1 This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) Consumer cooperation of the China Standards Bureau of the Ministry of Economic Affairs Du printed 401306 A7 ______B7 V. Description of the invention (24) Yellow Example I II III IV V VI VII Wt Wt Wt Wt Wt w [[Please first u 1%%%%%%%% 1 T 1 IJ ♦ _ 1 0.0 0.0 0.0 .2.0 0.0 0.0 0.0 Back 1 1 0.0 0.0 0.0 0.08 0.0 0.0 0.0 Note 1 I Xanthan gum intended 1 I Item 1 I K. Re T. · _ Essential oil 0.0 0.0 0.0 0.20 0.0 0.0 0.0 Fill in U 0.0 0.25 0.0 0.20 0.0 0.0 0.0 This sesame oil sheet S ^ o 1 I Vitamin A 0.0 0.05 0.0 0.0 0.0 0.0 0.0 1 I Palmitate 1-|-L. Tincture Gel 0.0 0.0 3.0 0.0 0.0 0.0 0.0 1 .1 Order Chamomile Extract 0.0 0.0 0.1 0.0 0.0 0.0 0.0 1 1 1 to contain about 1 propylene glycol 1 1! •! ▲ 1 I The various ingredients listed in Table _ have been divided into arrays. According to the procedure described below, each 1 1 1 I Sister's ingredients are mixed before adding to other ingredients. m I • _ In the first step, the component mixture of phase A is stirred with a shear mixer for 1 1 for about 5 minutes until uniform. Under high-speed shear mixing, plug the B-phase material 1 -27-This paper size uses Chinese National Standard (CNS) A4 (210X297 mm) ^ 〇j3〇6 A7 B7 V. Description of the invention (2 & ) Cao was gradually added to A and the mixture was mixed for 20 minutes until dispersed. Next, the components of the C phase and then the D phase are slowly added to the mixture of the A and R phases and mixed with high shear until dispersed. At this time, silica was added and dispersed into the mixture. After heating the obtained tartar to 90 C, the phase E component was added. Cool the container to 5 5 T and add premixed Phase F. The batch is mixed until homogeneous. After that, the mixture was cooled to 30 [deg.] F. G phase was added again. Mix all the ingredients of the mash phase to completely dissolve to prepare a mash phase premix. At 3010, add the high-shear phase premix K to the batch mixture, but make sure that there is no super water on the surface. The mixture was then ground for 15 minutes. Finally, phases I ,, 丨, K, and L were added as diluents. The resulting chemical compound is ready for packaging. The cosmetic compound of the Zhi et al. Example demonstrates anti-acne activity and improved formulation and color stability. •-IJI .-- Γ ------- 'Τ equipment ---- 1 --- r-order-, ιν J (__Please read the notes on the back before filling in this page) Central Ministry of Economic Affairs Printed by the Zhun Bureau Bei Gong Xiao T Cooperative 8 2 This paper is suitable for Chinese families (cns) Cong Mi (2 丨. Χ297 public envy)

Claims

蓽A3 ΐ 0Q7.32號專轺自辑案樹_ 請專利範圍修£本年fi月） *V A8 B8 C8 卫8 * _2 六、申請專利範圍 2 . 3. 5 . 6 . 公告本 ^6. |l^r J U!荜 A3 ΐ 0Q7.32 self-editing case tree _ Please revise the scope of the patent (fi this month) * V A8 B8 C8 Wei 8 * _2 6. The scope of patent application 2. 3. 5. 6.. Bulletin ^ 6 . | l ^ r JU!

經濟部中央梯準局貝工消費合作社印装 8 . 一種轧液、凝膝或洗液形式的化自0.5¾到3¾之水楊酸或重量0.5 合物和重蚤自〇 · U到5¾之吡咯烷該水/酵溶液具有低於P K a +〗的質子化的抗痤瘡活性物所具酸性根據申請專利範圍第1項之化粧銅基質複合劑為聚乙烯基吡咯烷根撺申請專利範圍第1項之化粧 0.0 1重最％至5電量％的榨樣酸根撺申請專利範圍第1項之化粧詨形式。 . 根撺申請專利範圍第4項之化粧 % g 50重最％矽嗣油，選自揮發，及其混合物。根撺申請專利範圍第5項之化粧沾齲油係選自具有在2 5 下低於機基矽氧烷及在2 5 t下黏度低於砂氧掠。梢撺申謓專利範圍第6項之化粧矽顳油係選自具有3至9個矽if 矽原子的環狀聚二甲基矽氧烷及埭型聚二甲基矽氧烷。根撺申請專利範圍第7項之化粧钱’矽_油包含具有至少一個聚二粧組合物，其選自簠量到3 3；之壬二酸或此等混嗣基質複合劑*且其中 pH值，此處pKa為完全常數之對數值。组合物*其中該吡咯综酮複合劑。組合物，其另包含或其鹽。姐合物》其為油包水乳姐合物，其包含1重最性矽嗣，非揮發性矽酮姐合物，其中該揮發性 1011史黏度之環狀聚有 5厘史的線型聚有機基姐合物，其中該揮發性子，較佳具有4至5個具有3至9涸矽原子的姐合物*其中該非揮發有機基矽氧烷節段和至裝—---5---τ ------·Λ (請t閲讀背面之注意事項再4,寫本頁) 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）蓽A3 ΐ 0Q7.32號專轺自辑案樹_ 請專利範圍修£本年fi月） *V A8 B8 C8 卫8 * _2 六、申請專利範圍 2 . 3. 5 . 6 . 公告本 ^6. |l^r J U!Printed by Shellfish Consumer Cooperatives, Central Stairway Bureau, Ministry of Economic Affairs 8. A salicylic acid or a 0.5 weight compound and a heavy flea from 0.5 U to 5¾ in the form of rolling solution, knee gel or lotion Pyrrolidine The water / fermentation solution has a lower acidity than protonated anti-acne actives below PK a +. The cosmetic copper matrix compound according to item 1 of the patent application scope is polyvinylpyrrolidine. 1 item of makeup 0.0 1 weight% to 5% of the amount of squeezed acid root 撺 applied for the scope of the patent application of the first item of makeup 詨 form. . Makeup according to item 4 of the patent application.% G 50% by weight silicone oil, selected from volatile and mixtures thereof. The makeup according to item 5 of the patent application scope is based on a caries oil selected from those having a viscosity lower than organosilane at 25 and a viscosity lower than sand at 25 t. The makeup of the 6th patent in the patent application Silicone temporal oil is selected from cyclic polydimethylsiloxane and tritium polydimethylsiloxane having 3 to 9 silicon if silicon atoms. According to item 7 of the patent application scope, the cosmetic oil 'silicone oil' contains at least one polydimethicone composition selected from the amount of melamine to 3 3; azelaic acid or these mixed matrix composites * and wherein pH Value, where pKa is the logarithm of the complete constant. Composition * wherein the pyrroconone compound. A composition further comprising or a salt thereof. "Sister compound" It is a water-in-oil emulsion sister compound, which contains 1 weight of the most sexual silicone, a non-volatile silicone sister compound, in which the volatile 1011-historical viscosity of the ring-shaped polymer is 5% history linear polymer Organic-based sister compounds, in which the volatile protons, preferably have 4 to 5 sister compounds having 3 to 9 涸 silicon atoms * wherein the non-volatile organic-based siloxane segments and toss ---- 5-- -τ ------ · Λ (Please read the notes on the back again and write this page again) This paper size is applicable to China National Standard (CNS) A4 specifications (210X297 mm) 荜 A3 ΐ 0Q7.32 Special self-editing case tree _ Please revise the scope of the patent (fi-month of this year) * V A8 B8 C8 Wei 8 * _2 6. Scope of patent application 2. 3. 5. 6.. Bulletin ^ 6. | L ^ r JU!

經濟部中央梯準局貝工消費合作社印装 8 . 一種轧液、凝膝或洗液形式的化自0.5¾到3¾之水楊酸或重量0.5 合物和重蚤自〇 · U到5¾之吡咯烷該水/酵溶液具有低於P K a +〗的質子化的抗痤瘡活性物所具酸性根據申請專利範圍第1項之化粧銅基質複合劑為聚乙烯基吡咯烷根撺申請專利範圍第1項之化粧 0.0 1重最％至5電量％的榨樣酸根撺申請專利範圍第1項之化粧詨形式。 . 根撺申請專利範圍第4項之化粧 % g 50重最％矽嗣油，選自揮發，及其混合物。根撺申請專利範圍第5項之化粧沾齲油係選自具有在2 5 下低於機基矽氧烷及在2 5 t下黏度低於砂氧掠。梢撺申謓專利範圍第6項之化粧矽顳油係選自具有3至9個矽if 矽原子的環狀聚二甲基矽氧烷及埭型聚二甲基矽氧烷。根撺申請專利範圍第7項之化粧钱’矽_油包含具有至少一個聚二粧組合物，其選自簠量到3 3；之壬二酸或此等混嗣基質複合劑*且其中 pH值，此處pKa為完全常數之對數值。组合物*其中該吡咯综酮複合劑。組合物，其另包含或其鹽。姐合物》其為油包水乳姐合物，其包含1重最性矽嗣，非揮發性矽酮姐合物，其中該揮發性 1011史黏度之環狀聚有 5厘史的線型聚有機基姐合物，其中該揮發性子，較佳具有4至5個具有3至9涸矽原子的姐合物*其中該非揮發有機基矽氧烷節段和至裝—---5---τ ------·Λ (請t閲讀背面之注意事項再4,寫本頁) 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 401306 A8 B8 C8 D8 六、申請專利範圍少一個聚氧烯節段之聚二有機基矽氧烷-聚氧烯共聚物 9 . 10. 根機共根重 11 .根 12 13 14 15 經濟部中央標準局貞工消費合作社印袈 16 1，合根為根包性根物根雪 m 根水勻. 據申請專利範圍第8項之化粧姐合物，其中該聚二有基矽氧烷-聚氧烯共聚物為二甲矽嗣（diuethicone} 多元醇。捸申請專利範圍第1項之化粧姐合物，其另包含0. i 最％至30重量％的濕潤劑。撺申請專利範圍第1 〇項之化粧姐合物，其中該濕潤劑選自甘油，及在251：的黏度為300.000至 1 0 0，0 0 0 c p s的聚甲基丙烯酸甘油酯潤滑劑，及其渴物。據申請專利範圍第11項之化粧组合物，其中該濕潤劑甘油。撺申請專利範圍第5項之化粧組合物，其中該矽網油含Μ组合物重鼉計2¾至25¾ ，較佳5¾至15S；之非揮發矽飼。撺申請專利範圍第1 〇項之化粧姐合物，其包含以组合重量計5¾至25¾的濕潤劑。撺申請專利範圍第1項之化粧組合物，其另包含〇. i 量％呈10重最％的交聯疏水性丙烯酸醸或甲基丙烯酸共聚物。撺申請專利範圍第1 5項之化粧姐合物，其中該交聯疏性共聚物為乳膠髟式，巨其中至少一檟活性成汾係均地分散並包覆在該共聚物格子之內，該活性成份係選請先聞讀背之注頁裝訂 Λ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） Α8 68 C8 D8 431306 々、申請專利範圍自皮麻相容性油，皮濟相容性濕潤劑，潤滑劑，加濕劑及防晒劑。 17 .根撺申請專利範圍第1 β項之化粧姐合物，其中該活性成份係選自濕潤劑，較佳為甘油。 1 8 .根撺申請專利範圍第1項之化粧组合物，其另包含1重量％至15重量％的潤滑劑，其為天然或合成油，選自礦油，植物油和動物油，脂防和撖，脂防酸酯*脂肪醇，烷二醇，聚烷二醇醚和酯，脂肪酸，及其混合物。 1 9 .根撺申請專利範圍第1 8項之化粧组合物，其中該潤滑劑係選自棕撋酸異丙酯，異硬脂酸異丙酯，順丁烯二酸二辛酯，丙二醇二（癸酸酯）./丙二醇二（辛酸酯），甘油三（癸酸酯）/甘油三（辛酸酯），角鯊烷，礦油，異壬酸鲸蠟硬脂酯，羊毛脂醇，及其混合物。 2 0 .根撺申請專利範圍第1項之化粧姐合物，其中該油相含有Μ姐合物為基計算〇 · 1至1 〇重量％，較佳0. 1至3重量％的濕潤劑。 21 .根撺申請專利範圍第1項之化粧姐合物，其包含30至 95重最％，較伟40至30窜鼂％的油相，及5至70重量％，較佳20至60重最％的水相。 2 2 .根撺申請專利範圍第1項之化粧姐合物，其另包含一或多楫紫外光吸收劑。本纸張尺度逋用中國國家梯準（CNS ) Α4規格（210Χ297公釐） I — (請先聞讀背面之注^·項再&寫本頁) -丨訂_ 經濟部中央標準局貝工消費合作社印褽Printed by Shellfish Consumer Cooperatives, Central Stairway Bureau, Ministry of Economic Affairs 8. A salicylic acid or a 0.5 weight compound and a heavy flea from 0.5 U to 5¾ in the form of rolling solution, knee gel or lotion Pyrrolidine The water / fermentation solution has a lower acidity than protonated anti-acne actives below PK a +. The cosmetic copper matrix compound according to item 1 of the patent application scope is polyvinylpyrrolidine. 1 item of makeup 0.0 1 weight% to 5% of the amount of squeezed acid root 撺 applied for the scope of the patent application of the first item of makeup 詨 form. . Makeup according to item 4 of the patent application.% G 50% by weight silicone oil, selected from volatile and mixtures thereof. The makeup according to item 5 of the patent application scope is based on a caries oil selected from those having a viscosity lower than organosilane at 25 and a viscosity lower than sand at 25 t. The makeup of the 6th patent in the patent application Silicone temporal oil is selected from cyclic polydimethylsiloxane and tritium polydimethylsiloxane having 3 to 9 silicon if silicon atoms. According to item 7 of the patent application scope, the cosmetic oil 'silicone oil' contains at least one polydimethicone composition selected from the amount of melamine to 3 3; azelaic acid or these mixed matrix composites * and wherein pH Value, where pKa is the logarithm of the complete constant. Composition * wherein the pyrroconone compound. A composition further comprising or a salt thereof. "Sister compound" It is a water-in-oil emulsion sister compound, which contains 1 weight of the most sexual silicone, a non-volatile silicone sister compound, in which the volatile 1011-historical viscosity of the ring-shaped polymer is 5% history linear polymer Organic-based sister compounds, in which the volatile protons, preferably have 4 to 5 sister compounds having 3 to 9 涸 silicon atoms * wherein the non-volatile organic-based siloxane segments and toss ---- 5-- -τ ------ · Λ (please read the notes on the back again and write this page again) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 401306 A8 B8 C8 D8 The scope of the patent application is a polydiorganosiloxane-polyoxyene copolymer with one less polyoxyene segment. 9. Root weights total root weight 11. Roots 12 13 14 15 Printed by Zhengong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs袈 16 1, the roots are root-encrusted roots, roots, snow, and roots. The roots are evenly distributed. According to the cosmetic composition of the patent application No. 8, the polydisiloxane and polyoxyalkylene copolymer is dimethylsilicon. (Diuethicone) Polyol. 化妆 Cosmetic composition of the scope of patent application No. 1 which further comprises 0.1 to 30% by weight撺 Wetting agent of the patent application No. 10, wherein the humectant is selected from the group consisting of glycerin and polyglyceryl methacrylate with a viscosity at 251: 300.000 to 1 0,0 0 0 cps Lubricants, and their thirsty. The cosmetic composition according to item 11 of the patent application, wherein the moisturizer is glycerin. 化妆 The cosmetic composition according to item 5 of the patent application, wherein the silicone oil contains the M composition by weight. 2¾ to 25¾, preferably 5¾ to 15S; non-volatile silicon feed. 撺 Cosmetic composition for patent application No. 10, which contains humectants from 5¾ to 25¾ by combination weight. 撺 Applicability for patent No. 1 A cosmetic composition, further comprising 0.1% by weight of 10% by weight of a cross-linked hydrophobic acrylic acid methacrylate or methacrylic acid copolymer. 撺 a cosmetic composition of claim 15 in the patent application, wherein the crosslinking The hydrophobic copolymer is of latex type, at least one of which is active is dispersed and coated in the copolymer lattice, and the active ingredient is selected. Please read the back page for binding. Λ This paper size Applicable Chinese national standards ( CNS) A4 specification (210X297 mm) A8 68 C8 D8 431306 々, the scope of patent application is dermal compatible oil, dermatologically compatible wetting agent, lubricant, humidifier and sunscreen. 17. Root application The cosmetic composition of item 1 β of the patent scope, wherein the active ingredient is selected from a humectant, preferably glycerin. 18. The cosmetic composition of item 1 of the patent scope, which further comprises 1% by weight to 15% by weight lubricant, which is a natural or synthetic oil, selected from mineral oils, vegetable oils and animal oils, fat control and antiseptic, fatty control esters * fatty alcohols, alkanediols, polyalkylene glycol ethers and esters, fatty acids, And its mixture. 19. The cosmetic composition according to item 18 of the scope of patent application, wherein the lubricant is selected from the group consisting of isopropyl palmitate, isopropyl isostearate, dioctyl maleate, and propylene glycol di (Decanoate) ./ propylene glycol di (caprylate), triglyceride (caprate) / triglyceride (caprylate), squalane, mineral oil, cetyl isanononanoate, lanolin alcohol , And its mixtures. 2 0. The makeup composition according to item 1 of the scope of patent application, wherein the oil phase contains M composition based on 0.1 to 10% by weight, preferably 0.1 to 3% by weight of wetting agent. . 21. The makeup compound according to item 1 of the scope of patent application, which contains 30 to 95% by weight, 40% to 30% of oil phase, and 5 to 70% by weight, preferably 20 to 60% by weight. Most percent of the water phase. 22. The makeup composition according to item 1 of the patent application scope, which further comprises one or more ultraviolet light absorbers. This paper uses the Chinese National Standard (CNS) Α4 size (210 × 297 mm) I — (Please read the note on the back ^ · Item and then write this page)-丨 Order_ Central Standards Bureau of the Ministry of Economic Affairs Industrial and Consumer Cooperatives