TW393397B - Polymer coated multilayer material and its production processes - Google Patents
Polymer coated multilayer material and its production processes Download PDFInfo
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五、發明説明（ A7 B7 '、 >. L * /' 、年Ά丄ϋ · rV. Description of the invention (A7 B7 ', >. L * /', year Ά 丄 ϋ · r
經濟、郅中央標準局貝工消費合作杜印製 本發明係爲〜種有聚合物塗層的多層 多層材料的方法。這種多層材料是由一種 一 ί收= 類薄膜構成’薄膜上並塗:有二層聚合The economy, the central standard bureau, shellfish consumer cooperation, Du printed. The present invention is a method of multi-layer multi-layer material with polymer coating. This multilayer material is composed of a thin film and a thin film.
Hi屬熱^膠黏材料塗層，吸顏料塗層及/或吸油墨 科適於製成飛機模型製造及單人飛機/超 輕土飛機的機架上所需的大面積張拉薄膜。它也可以 影印紙使用，以-般的影印機即可在這種多層材料上&印 =形，文字。也可以用來製作耐風雨的自轉籤、姑紙 或用於其它類似用途。 彩色的聚酯類薄膜（如：聚對苯二甲酸乙二醇酯）基於 其物理及化學特性，適於製成飛機模型所需的 枯 薄膜乃吾人習知的事實。此外，這種薄膜的耐風雨 熱性都很好，若在其上塗一層吸顏料或吸油墨的塗層，還 可當作影印紙使用，以一般的影印機即可在薄膜上印出文 字及圖形。一般的作法是在透明的衆酯類薄膜上加上一層 可感熱、塗有顏料（或經過染色）的聚合物膠粘層。另一種 常見的作法是，衆酯類薄膜上有一層塗有顏料的熱固聚合 物層及兩層熱塑聚合物層（其中一層作爲膠粘層，另 作爲熱固聚合物層與薄膜之間的聯給層）。這種作法的缺 點是所製成的薄膜重量太重。另一種用來包裹模型飛機木 一層作爲熱固聚合物層與薄膜之間的聯給層）。這種作法 製機架的材料，是以經過樹脂浸漬的聚酯編織成的纖維性 I--------—裝---^---»~訂-----線 (請先閲讀背面之注意事項再填寫本頁) 本紙铢尺度適用中國國家標準（CNS ) A4規格（210'〆297公釐） 五、發明説明（ A7 B7 '、 >. L * /' 、年Ά丄ϋ · rHi is a coating of thermal adhesive material, pigment-absorbing coating, and / or ink-absorbing. It is suitable for making large-area tensile films required for aircraft model manufacturing and single-person / ultra-light earth aircraft frames. It can also be used on photocopier paper. A -like photocopier can print & print on this multilayer material. It can also be used to make weatherproof auto-signs, guillotines, or other similar applications. Colored polyester films (such as polyethylene terephthalate) are based on their physical and chemical properties and are suitable for making dry films required for aircraft models. In addition, this film has good weather and heat resistance. If it is coated with a pigment or ink-absorbing coating, it can also be used as photocopying paper. With ordinary photocopiers, text and graphics can be printed on the film. . A common practice is to add a heat-sensitive, pigmented (or dyed) polymer adhesive layer to a transparent polyester film. Another common practice is to use a thermosetting polymer layer coated with pigment and two thermoplastic polymer layers (one of which is used as an adhesive layer, and the other is between the thermosetting polymer layer and the film. Connection layer). The disadvantage of this method is that the film produced is too heavy. The other layer is used to wrap the model aircraft wood as a tie layer between the thermosetting polymer layer and the film). The material of the frame made by this method is fibrous I woven with polyester impregnated with resin. I ---------- install --- ^ --- »~ order ----- thread ( Please read the notes on the back before filling in this page) Baht scale of this paper applies Chinese National Standard (CNS) A4 specification (210'〆297 mm) V. Description of invention (A7 B7 ', >. L * /', year Ά 丄 ϋ · r
經濟、郅中央標準局貝工消費合作杜印製 本發明係爲〜種有聚合物塗層的多層 多層材料的方法。這種多層材料是由一種 一 ί收= 類薄膜構成’薄膜上並塗:有二層聚合The economy, the central standard bureau, shellfish consumer cooperation, Du printed. The present invention is a method of multi-layer multi-layer material with polymer coating. This multilayer material is composed of a thin film and a thin film.
Hi屬熱^膠黏材料塗層，吸顏料塗層及/或吸油墨 科適於製成飛機模型製造及單人飛機/超 輕土飛機的機架上所需的大面積張拉薄膜。它也可以 影印紙使用，以-般的影印機即可在這種多層材料上&印 =形，文字。也可以用來製作耐風雨的自轉籤、姑紙 或用於其它類似用途。 彩色的聚酯類薄膜（如：聚對苯二甲酸乙二醇酯）基於 其物理及化學特性，適於製成飛機模型所需的 枯 薄膜乃吾人習知的事實。此外，這種薄膜的耐風雨 熱性都很好，若在其上塗一層吸顏料或吸油墨的塗層，還 可當作影印紙使用，以一般的影印機即可在薄膜上印出文 字及圖形。一般的作法是在透明的衆酯類薄膜上加上一層 可感熱、塗有顏料（或經過染色）的聚合物膠粘層。另一種 常見的作法是，衆酯類薄膜上有一層塗有顏料的熱固聚合 物層及兩層熱塑聚合物層（其中一層作爲膠粘層，另 作爲熱固聚合物層與薄膜之間的聯給層）。這種作法的缺 點是所製成的薄膜重量太重。另一種用來包裹模型飛機木 一層作爲熱固聚合物層與薄膜之間的聯給層）。這種作法 製機架的材料，是以經過樹脂浸漬的聚酯編織成的纖維性 I--------—裝---^---»~訂-----線 (請先閲讀背面之注意事項再填寫本頁) 本紙铢尺度適用中國國家標準（CNS ) A4規格（210'〆297公釐）Hi is a coating of thermal adhesive material, pigment-absorbing coating, and / or ink-absorbing. It is suitable for making large-area tensile films required for aircraft model manufacturing and single-person / ultra-light earth aircraft frames. It can also be used on photocopier paper. A -like photocopier can print & print on this multilayer material. It can also be used to make weatherproof auto-signs, guillotines, or other similar applications. Colored polyester films (such as polyethylene terephthalate) are based on their physical and chemical properties and are suitable for making dry films required for aircraft models. In addition, this film has good weather and heat resistance. If it is coated with a pigment or ink-absorbing coating, it can also be used as photocopying paper. With ordinary photocopiers, text and graphics can be printed on the film. . A common practice is to add a heat-sensitive, pigmented (or dyed) polymer adhesive layer to a transparent polyester film. Another common practice is to use a thermosetting polymer layer coated with pigment and two thermoplastic polymer layers (one of which is used as an adhesive layer, and the other is between the thermosetting polymer layer and the film. Connection layer). The disadvantage of this method is that the film produced is too heavy. The other layer is used to wrap the model aircraft wood as a tie layer between the thermosetting polymer layer and the film). The material of the frame made by this method is fibrous I woven with polyester impregnated with resin. I ---------- install --- ^ --- »~ order ----- thread ( Please read the notes on the back before filling out this page) The baht scale of this paper applies the Chinese National Standard (CNS) A4 specification (210'〆297 mm)
五、發明説明（ 經濟部中央標準局員工消費合作社印装 色（供心用的樹脂溶液應先以顏料及/或有機色素染 這類方法的缺點很多，例 - 著力並不可靠◊此外，以這類方式製成的張拉材^材料粘I 視覺感受到使用條件和加給人的運 定的品質。由於_料的熱塑性，=角 張拉«時，會架角落及棱角處:r一更正表面材料時，都會二，:= 二j系轭的硬化劑(如：異氰酸鹽〉會與熱塑聚合物 層^化學反應，反應過程中會放出氣髏（如：二氧化碳、 小蒸氣），而在顏料層上造成微小的細孔。 一般的吸顏料層是由雙環烷基一，lM2_c 基一、或芳香族一丙烯酯酯、及不超過20%的極化單體或 N，N 一烴基一單烷基胺一烷基一丙烯酸酯所構成。此外， 常用的還有：聚合物化的Di〇H卜丙烯酸醋添加共重合 化的乙基單體及共重合化的乙烯基酯，甲基丙烯酸酯及/ 或苯乙烯製成的溶液。另一種方式是以水溶性聚合物加上 大小在Ι-ISU之間的聚合物微粒及抗靜電劑 : 私溶性吸顏料層。也有人以乙祕2。_4。％(克\成^^ 策合衆乙烯醇缩醛製成顏料固定層，適於作爲塗在聚酯類 -_- 4 ____ 之 注 事 再 i 1 L___ 本紙張尺度適用中國國家榡準（CNS ) 格（21〇X297公釐V. Description of the invention (Central Bureau of Standards, Ministry of Economic Affairs, Consumer Co-operative Printing Color (Resin solution for heart should first be dyed with pigments and / or organic pigments. The disadvantages of this method are many, for example-the focus is not reliable. In addition, Tensile materials made in this way ^ Material sticky I Visually feel the conditions of use and the quality given to people. Due to the thermoplasticity of the material, = corner tensioning «, the corners and edges of the frame: r-Correct the surface When materials are used, the hardeners of two = series j conjugates (such as isocyanate) will chemically react with the thermoplastic polymer layer, and gas cross-sections (such as carbon dioxide and small vapors) will be released during the reaction. And the pigment layer causes tiny pores. The general pigment-absorbing layer is composed of bicycloalkyl-1, lM2_c group-1, or aromatic monoacrylate ester, and no more than 20% of polar monomer or N, N- Hydrocarbon-monoalkylamine-alkyl-acrylate. In addition, commonly used are: polymerized DiOH, acrylic acid vinegar, co-reformed ethyl monomer, and co-reformed vinyl ester. Acrylate and / or styrene solution. One way is to use a water-soluble polymer plus polymer particles between I-ISU and an antistatic agent: a privately soluble pigment-absorbing layer. Some people also use Yimi 2._4.% (G \ 成 ^^ Polyvinyl acetal is used to make a fixed layer of pigment, which is suitable as a note on polyester -_- 4 ____ i 1 L___ This paper size is applicable to China National Standard (CNS) standard (21 × 297 mm)
五、發明説明（ 經濟部中央標準局員工消費合作社印装 色（供心用的樹脂溶液應先以顏料及/或有機色素染 這類方法的缺點很多，例 - 著力並不可靠◊此外，以這類方式製成的張拉材^材料粘I 視覺感受到使用條件和加給人的運 定的品質。由於_料的熱塑性，=角 張拉«時，會架角落及棱角處:r一更正表面材料時，都會二，:= 二j系轭的硬化劑(如：異氰酸鹽〉會與熱塑聚合物 層^化學反應，反應過程中會放出氣髏（如：二氧化碳、 小蒸氣），而在顏料層上造成微小的細孔。 一般的吸顏料層是由雙環烷基一，lM2_c 基一、或芳香族一丙烯酯酯、及不超過20%的極化單體或 N，N 一烴基一單烷基胺一烷基一丙烯酸酯所構成。此外， 常用的還有：聚合物化的Di〇H卜丙烯酸醋添加共重合 化的乙基單體及共重合化的乙烯基酯，甲基丙烯酸酯及/ 或苯乙烯製成的溶液。另一種方式是以水溶性聚合物加上 大小在Ι-ISU之間的聚合物微粒及抗靜電劑 : 私溶性吸顏料層。也有人以乙祕2。_4。％(克\成^^ 策合衆乙烯醇缩醛製成顏料固定層，適於作爲塗在聚酯類 -_- 4 ____ 之 注 事 再 i 1 L___ 本紙張尺度適用中國國家榡準（CNS ) 格（21〇X297公釐V. Description of the invention (Central Bureau of Standards, Ministry of Economic Affairs, Consumer Co-operative Printing Color (Resin solution for heart should first be dyed with pigments and / or organic pigments. The disadvantages of this method are many, for example-the focus is not reliable. In addition, the Tensile materials made in this way ^ Material sticky I Visually feel the conditions of use and the quality given to people. Due to the thermoplasticity of the material, = corner tensioning «, the corners and edges of the frame: r-Correct the surface When materials are used, the hardeners of two = series j conjugates (such as isocyanate) will chemically react with the thermoplastic polymer layer, and gas cross-sections (such as carbon dioxide and small vapors) will be released during the reaction. And the pigment layer causes tiny pores. The general pigment-absorbing layer is composed of bicycloalkyl-1, lM2_c group-1, or aromatic monoacrylate ester, and no more than 20% of polar monomer or N, N- Hydrocarbon-monoalkylamine-alkyl-acrylate. In addition, commonly used are: polymerized DiOH, acrylic acid vinegar, co-reformed ethyl monomer, and co-reformed vinyl ester. Acrylate and / or styrene solution. One way is to use a water-soluble polymer plus polymer particles between I-ISU and an antistatic agent: a privately soluble pigment-absorbing layer. Some people also use Yimi 2._4.% (G \ 成 ^^ Polyvinyl acetal is used to make a fixed layer of pigment, which is suitable as a note on polyester -_- 4 ____ i 1 L___ This paper size is applicable to China National Standard (CNS) standard (21 × 297 mm)
五、發明説明（） 經濟部中央標準局員工消費合作社印製 薄膜上的透明顏料塗層，如 :Melinex 薄膜或 Hostaphan 薄膜等含有非離子或離子成分的水溶性纖維化聚合物的薄 膜。還有以乙烯呲咯烷酮、聚酯微粒、共衆酯微粒、2-6-C環氧烷微粒、衆乙烯醇微粒及惰性微粒製成聚酯類薄膜 的吸油墨塗層。也有人將聚乙烯、聚丙烯及聚碳酸酯製的 薄膜塗上一層由氣乙烯一醋酸乙烯酯一共聚合樹脂形成的 乳劑/色散劑製的吸墨水塗層。這些製品通常都添加了可 防止阻塞現象的膠質氧化矽◊上述產品的一個共同缺點 是，雖然以聚酯類薄膜作爲原材料製成的飛機模型用拉張 薄膜具有抗風雨性及抗斷裂性強的優點，但其張拉面積及 載重性仍有一定的限度，所以在許多方面的應用（如用於 單人飛機）受到限制。 塗有吸墨水塗層的薄膜呈透明至乳白色之間，因此影 印出來的底色會偏黑。由於透明性的降低，會使其影印件 失去部分（或完全失去）使用性。 本發明的目的，在於改善以聚對苯二甲酸乙二醇酯爲 原材料製成的可感熱、具有收縮能力的彩色薄膜的使用 性。本發明用於薄膜上的聚合物塗層一方面可以改善熱固 性顏料塗層的表面性質，提高薄膜的抗斷裂能力，降低薄 膜的單位面積重量，另一方面同時在薄膜上塗上顏料塗層 和膠粘材料還可以擴大薄膜的應用範園。本發明尚包括使 薄膜適用於複印技術的塗層方式。 本發明揭示的方法，可以達到上述目的，採用本發明 ___L___ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I I I —裝 n ^~訂 線 (請先閲讀背面之注意事項再填寫本頁)5. Description of the invention () Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. Transparent pigment coatings on films, such as Melinex film or Hostaphan film, which contain non-ionic or ionic components of water-soluble fibrous polymers. There are also ink-absorbing coatings made of polyester films made of vinylpyrrolidone, polyester particles, copolyester particles, 2-6-C alkylene oxide particles, vinyl alcohol particles, and inert particles. Films made of polyethylene, polypropylene, and polycarbonate have also been coated with an ink-receptive coating made of an emulsion / dispersion agent formed of a gas ethylene-vinyl acetate-copolymer resin. These products are usually added with colloidal silica to prevent clogging. A common disadvantage of the above products is that although the stretch film for aircraft models made of polyester film as a raw material has weather resistance and fracture resistance. Advantages, but its tensile area and load capacity are still limited, so its application in many aspects (such as for single-person aircraft) is limited. The film with the ink-absorbing coating is transparent to milky white, so the background color of the copy will be black. The reduced transparency can result in partial (or total loss) usability of the photocopy. The object of the present invention is to improve the usability of a heat-sensitive, color-shrinkable color film made of polyethylene terephthalate. The polymer coating used on the film can improve the surface properties of the thermosetting pigment coating on the one hand, improve the fracture resistance of the film, and reduce the weight per unit area of the film, and on the other hand, apply a pigment coating and glue on the film. Adhesive materials can also expand the application range of films. The invention also includes coating methods that make films suitable for use in copying technology. The method disclosed by the present invention can achieve the above-mentioned purpose. Using the present invention ___L___ This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) III — Install n ^ ~ order the thread (please read the precautions on the back first) (Fill in this page)
五、發明説明（） 經濟部中央標準局員工消費合作社印製 薄膜上的透明顏料塗層，如 :Melinex 薄膜或 Hostaphan 薄膜等含有非離子或離子成分的水溶性纖維化聚合物的薄 膜。還有以乙烯呲咯烷酮、聚酯微粒、共衆酯微粒、2-6-C環氧烷微粒、衆乙烯醇微粒及惰性微粒製成聚酯類薄膜 的吸油墨塗層。也有人將聚乙烯、聚丙烯及聚碳酸酯製的 薄膜塗上一層由氣乙烯一醋酸乙烯酯一共聚合樹脂形成的 乳劑/色散劑製的吸墨水塗層。這些製品通常都添加了可 防止阻塞現象的膠質氧化矽◊上述產品的一個共同缺點 是，雖然以聚酯類薄膜作爲原材料製成的飛機模型用拉張 薄膜具有抗風雨性及抗斷裂性強的優點，但其張拉面積及 載重性仍有一定的限度，所以在許多方面的應用（如用於 單人飛機）受到限制。 塗有吸墨水塗層的薄膜呈透明至乳白色之間，因此影 印出來的底色會偏黑。由於透明性的降低，會使其影印件 失去部分（或完全失去）使用性。 本發明的目的，在於改善以聚對苯二甲酸乙二醇酯爲 原材料製成的可感熱、具有收縮能力的彩色薄膜的使用 性。本發明用於薄膜上的聚合物塗層一方面可以改善熱固 性顏料塗層的表面性質，提高薄膜的抗斷裂能力，降低薄 膜的單位面積重量，另一方面同時在薄膜上塗上顏料塗層 和膠粘材料還可以擴大薄膜的應用範園。本發明尚包括使 薄膜適用於複印技術的塗層方式。 本發明揭示的方法，可以達到上述目的，採用本發明 ___L___ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I I I —裝 n ^~訂 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央榡率局員工消費合作.社印製 A7 B7 _ 五、發明説明（） 的方法可以製造出一種多層材料，這種材料不使用熱塑性 膠辛占材料層作爲經染色的熱固層與聚對苯二甲酸乙二醇酯 做的薄膜之間的聯結層，此外，再以本發明揭示方法（事 先以纖維網或織布塗覆薄膜）提高其抗斷裂能力。 本發明的多層材料的加工性、抗風雨能力及抗斷裂能 力皆較一般材料高。尤其是薄膜經過所謂的電暈前處理（以 電子衝擊進行物理及化學處理）後表面會變得粗糙、起毛， 使聚合物層與薄膜之間的結合力大幅提高◊但要達到這種 效果’先決條件是聚合物層做好後要立刻接受電暈處理， 不能延搁。 將彩色顏料及/或發螢光的顏料及/或有機色素加入含 有羥基（最好還有位於末端的氫氧基）的聚氨基甲酸酯及低 分子量線性聚異氰酸鹽構成的反應混合劑中，作爲橫向交 聯劑，可使聚合物層被染上十分均句的顏色《本發明使用 一種錫的有機化合物作爲催化劑，可使聚合的時間縮短至 48小時左右（不使用催化劑則需數日之久）。 膠粘層是以習知的傳遞方式塗在薄膜上，即將以聚丙 歸酸醋爲主要成分的膠粘材料的溶液塗在矽紙上，待溶劑 揮發後加壓、加熱貼於薄膜上。 ' 本發明的方法亦可爲薄膜加上一層透明的吸顏科層及 /或吸油墨層（最好是以聚乙烯醇縮醛製成）。此層的質量 爲2-8g/m2(薄膜面積）。這種薄膜可在一般影印機上a作 影印紙使用，影印出來的圖文資料具有絶佳的透光性:這 ----------装-----1訂-----線 (請先閱讀背面之注意事項再填寫本頁) i張尺度適用中國國家標準（CNS 21〇χ6297公羡） --- 經濟部中央榡率局員工消費合作.社印製 A7 B7 _ 五、發明説明（） 的方法可以製造出一種多層材料，這種材料不使用熱塑性 膠辛占材料層作爲經染色的熱固層與聚對苯二甲酸乙二醇酯 做的薄膜之間的聯結層，此外，再以本發明揭示方法（事 先以纖維網或織布塗覆薄膜）提高其抗斷裂能力。 本發明的多層材料的加工性、抗風雨能力及抗斷裂能 力皆較一般材料高。尤其是薄膜經過所謂的電暈前處理（以 電子衝擊進行物理及化學處理）後表面會變得粗糙、起毛， 使聚合物層與薄膜之間的結合力大幅提高◊但要達到這種 效果’先決條件是聚合物層做好後要立刻接受電暈處理， 不能延搁。 將彩色顏料及/或發螢光的顏料及/或有機色素加入含 有羥基（最好還有位於末端的氫氧基）的聚氨基甲酸酯及低 分子量線性聚異氰酸鹽構成的反應混合劑中，作爲橫向交 聯劑，可使聚合物層被染上十分均句的顏色《本發明使用 一種錫的有機化合物作爲催化劑，可使聚合的時間縮短至 48小時左右（不使用催化劑則需數日之久）。 膠粘層是以習知的傳遞方式塗在薄膜上，即將以聚丙 歸酸醋爲主要成分的膠粘材料的溶液塗在矽紙上，待溶劑 揮發後加壓、加熱貼於薄膜上。 ' 本發明的方法亦可爲薄膜加上一層透明的吸顏科層及 /或吸油墨層（最好是以聚乙烯醇縮醛製成）。此層的質量 爲2-8g/m2(薄膜面積）。這種薄膜可在一般影印機上a作 影印紙使用，影印出來的圖文資料具有絶佳的透光性:這 ----------装-----1訂-----線 (請先閱讀背面之注意事項再填寫本頁) i張尺度適用中國國家標準（CNS 21〇χ6297公羡） --- A7 B75. Description of the invention () Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. Transparent pigment coatings on films, such as Melinex film or Hostaphan film, which contain non-ionic or ionic components of water-soluble fibrous polymers. There are also ink-absorbing coatings made of polyester films made of vinylpyrrolidone, polyester particles, copolyester particles, 2-6-C alkylene oxide particles, vinyl alcohol particles, and inert particles. Films made of polyethylene, polypropylene, and polycarbonate have also been coated with an ink-receptive coating made of an emulsion / dispersion agent formed of a gas ethylene-vinyl acetate-copolymer resin. These products are usually added with colloidal silica to prevent clogging. A common disadvantage of the above products is that although the stretch film for aircraft models made of polyester film as a raw material has weather resistance and fracture resistance. Advantages, but its tensile area and load capacity are still limited, so its application in many aspects (such as for single-person aircraft) is limited. The film with the ink-absorbing coating is transparent to milky white, so the background color of the copy will be black. The reduced transparency can result in partial (or total loss) usability of the photocopy. The object of the present invention is to improve the usability of a heat-sensitive, color-shrinkable color film made of polyethylene terephthalate. The polymer coating used on the film can improve the surface properties of the thermosetting pigment coating on the one hand, improve the fracture resistance of the film, and reduce the weight per unit area of the film, and on the other hand, apply a pigment coating and glue on the film. Adhesive materials can also expand the application range of films. The invention also includes coating methods that make films suitable for use in copying technology. The method disclosed by the present invention can achieve the above-mentioned purpose. Using the present invention ___L___ This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) III — Install n ^ ~ order the thread (please read the precautions on the back first) (Fill in this page) The Consumer Co-operation of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs. The company printed A7 B7 _ V. The method of invention () can be used to make a multi-layer material. This material does not use thermoplastic rubber as the dyed material layer. The bonding layer between the thermosetting layer and the film made of polyethylene terephthalate. In addition, the method disclosed in the present invention (coating the film with a fiber web or a woven fabric in advance) is used to improve its fracture resistance. The multilayer material of the present invention has higher workability, weather resistance, and fracture resistance than ordinary materials. Especially after the so-called corona pretreatment (physical and chemical treatment with electronic impact), the surface of the film will become rough and fluffy, which will greatly improve the bonding force between the polymer layer and the film. But to achieve this effect ' The prerequisite is that the polymer layer should be corona treated immediately after it is prepared, and cannot be postponed. A reaction mixture of colored pigments and / or fluorescent pigments and / or organic pigments added to a polyurethane containing a hydroxyl group (preferably a terminal hydroxyl group) and a low molecular weight linear polyisocyanate Among the agents, as a cross-linking agent, the polymer layer can be dyed with a very uniform color. "The invention uses a tin organic compound as a catalyst, which can shorten the polymerization time to about 48 hours. Days). The adhesive layer is applied to the film by a conventional transmission method, that is, a solution of an adhesive material mainly composed of polypropylene acetic acid vinegar is applied to silicon paper, and the solvent is volatilized, and the film is heated and pasted on the film. '' The method of the present invention can also add a film with a transparent absorbing layer and / or ink absorbing layer (preferably made of polyvinyl acetal). The mass of this layer is 2-8g / m2 (film area). This film can be used as a photocopying paper on a general photocopier, and the photographic data printed out have excellent light transmission: this ------------ install ----- 1 order --- --- line (please read the notes on the back before filling this page) i-scale is applicable to Chinese national standards (CNS 21〇χ6297 public envy) --- the central government bureau of the Ministry of Economic Affairs consumer cooperation. Printed by A7 B7 _ V. Description of the invention The method () can produce a multilayer material. This material does not use the thermoplastic rubber as the material layer as the dyed thermosetting layer and the film made of polyethylene terephthalate. In addition, the method disclosed in the present invention (the film is coated with a fiber web or a woven fabric in advance) is used to improve its resistance to fracture. The multilayer material of the present invention has higher workability, weather resistance, and fracture resistance than ordinary materials. Especially after the so-called corona pretreatment (physical and chemical treatment with electronic impact), the surface of the film will become rough and fluffy, which will greatly improve the bonding force between the polymer layer and the film. But to achieve this effect ' The prerequisite is that the polymer layer should be corona treated immediately after it is prepared, and cannot be postponed. A reaction mixture of colored pigments and / or fluorescent pigments and / or organic pigments added to a polyurethane containing a hydroxyl group (preferably a terminal hydroxyl group) and a low molecular weight linear polyisocyanate Among the agents, as a cross-linking agent, the polymer layer can be dyed with a very uniform color. "The invention uses a tin organic compound as a catalyst, which can shorten the polymerization time to about 48 hours. Days). The adhesive layer is applied to the film by a conventional transmission method, that is, a solution of an adhesive material mainly composed of polypropylene acetic acid vinegar is applied to silicon paper, and the solvent is volatilized, and the film is heated and pasted on the film. '' The method of the present invention can also add a transparent facial absorption layer and / or ink absorption layer (preferably made of polyvinyl acetal) to the film. The mass of this layer is 2-8g / m2 (film area). This film can be used as a photocopying paper on a general photocopier, and the photographic data printed out have excellent light transmission: this ------------ install ----- 1 order --- --- line (please read the notes on the back before filling this page) i-scale is applicable to Chinese national standard (CNS 21〇χ6297 public envy) --- A7 B7
經濟部中央樣準局員工消費合作杜印製 五、發明説明（ 種薄膜也十分適於用來製作宣傳品’因爲它的整個聚合物 層顏色都十分均勻（前段已提及），且其熱固性亦使其具有 甚佳的抗風雨性。 爲了儘可能縮小吸顏料層及/或吸油墨層所謂的「薄 膜阻塞效應」，故在此層添加ο·5，的抗阻塞效應齊卜 例如，可以膠質氧㈣作·阻缺應劑，或是在水溶性 色散中加人澱粉（枝過3%)作爲餘塞效躺。若使此 層具有感光能力’更可擴大薄膜的應用範固。 本發明提出的方法，亦包括在薄膜上加設一層厚度< 的金屬層，（最好是使用鋁及/或鉻金屬），此金屬層位 於聚合物層的背面。這個措施可使薄膜的單位面積重量大 爲降低。在彩色透明的薄膜上塗上一層金屬廣，可使薄膜 仍然顯現相同的色彩，但變爲不透光。與其它製造彩色不 透光薄膜的方法相較，本發明的方式可使薄膜的單位重量 降低25—3〇%，而不影響其物理及化學性質。 本發明的另一項目的是提出一種製造多層材料的方 法。本發明所揭示的就是這種製造方法。採用這種方法可 製造出品質穩定的多層材料。這種方法包括在薄膜上塗有 聚合物層及膠粘材料的那一面上，塗上一層反應層（如： 吸顏料層及/或吸油墨層），必要時，尚可在此反應層内添 知適當的抗阻塞效應劑，以避免出現所謂的薄膜阻塞敫 隐。在本發明的製造方法中，爲了避免及/或降低薄膜在 袞筒上滾動因磨擦生成的靜電充電效應，故使薄膜流經電 ϋ- —κ ϋ I n tn n I f ui I I I i n n τ I n ϋ ml I I^ (請先聞讀背面之注^h項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 B7Production cooperation of employees of the Central Bureau of the Ministry of Economic Affairs of the People's Republic of China. 5.Invention (A kind of film is also very suitable for making promotional materials' because its entire polymer layer color is very uniform (mentioned in the previous paragraph), and its thermosetting It also has excellent weather resistance. In order to minimize the so-called "thin film blocking effect" of the pigment-absorbing layer and / or ink-absorbing layer, the anti-blocking effect of ο · 5 is added to this layer. For example, you can Colloidal oxygen acts as a deficient agent, or it can be added with water-soluble dispersion of human starch (over 3% of branches) as a stopper effect. If this layer has photosensitivity, it can expand the application scope of the film. The method proposed by the invention also includes adding a metal layer with a thickness < (preferably using aluminum and / or chrome metal) on the film, and the metal layer is located on the back of the polymer layer. This measure can make the unit of the film The area weight is greatly reduced. Coating a layer of metal on the color transparent film can make the film still appear the same color, but become opaque. Compared with other methods of manufacturing a color opaque film, the present invention The method can reduce the unit weight of the film by 25-30%, without affecting its physical and chemical properties. Another item of the present invention is to propose a method for manufacturing a multilayer material. What is disclosed in the present invention is this manufacturing method. This method can produce multi-layer materials with stable quality. This method includes applying a reaction layer (such as pigment-absorbing layer and / or ink-absorbing layer) on the side of the film coated with the polymer layer and the adhesive material. ), If necessary, an appropriate anti-blocking effect agent may be added to this reaction layer to avoid the so-called film blocking concealment. In the manufacturing method of the present invention, in order to avoid and / or reduce the film on the drum Due to the electrostatic charging effect generated by friction, the film is caused to flow through the battery κ-κ ϋ I n tn n I f ui III inn τ I n ϋ ml II ^ (Please read the note ^ h on the back before filling in this (Page) This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7
經濟部中央樣準局員工消費合作杜印製 五、發明説明（ 種薄膜也十分適於用來製作宣傳品’因爲它的整個聚合物 層顏色都十分均勻（前段已提及），且其熱固性亦使其具有 甚佳的抗風雨性。 爲了儘可能縮小吸顏料層及/或吸油墨層所謂的「薄 膜阻塞效應」，故在此層添加ο·5，的抗阻塞效應齊卜 例如，可以膠質氧㈣作·阻缺應劑，或是在水溶性 色散中加人澱粉（枝過3%)作爲餘塞效躺。若使此 層具有感光能力’更可擴大薄膜的應用範固。 本發明提出的方法，亦包括在薄膜上加設一層厚度< 的金屬層，（最好是使用鋁及/或鉻金屬），此金屬層位 於聚合物層的背面。這個措施可使薄膜的單位面積重量大 爲降低。在彩色透明的薄膜上塗上一層金屬廣，可使薄膜 仍然顯現相同的色彩，但變爲不透光。與其它製造彩色不 透光薄膜的方法相較，本發明的方式可使薄膜的單位重量 降低25—3〇%，而不影響其物理及化學性質。 本發明的另一項目的是提出一種製造多層材料的方 法。本發明所揭示的就是這種製造方法。採用這種方法可 製造出品質穩定的多層材料。這種方法包括在薄膜上塗有 聚合物層及膠粘材料的那一面上，塗上一層反應層（如： 吸顏料層及/或吸油墨層），必要時，尚可在此反應層内添 知適當的抗阻塞效應劑，以避免出現所謂的薄膜阻塞敫 隐。在本發明的製造方法中，爲了避免及/或降低薄膜在 袞筒上滾動因磨擦生成的靜電充電效應，故使薄膜流經電 ϋ- —κ ϋ I n tn n I f ui I I I i n n τ I n ϋ ml I I^ (請先聞讀背面之注^h項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 五、發明説明（） 離棒，以便放出靜電。另一種方法是在眞空蒸發程序中爲 薄膜塗上一層金屬層。 底下配合圖形及實施例，詳細解説本發明的特點： 圖式説明： ，圖一係爲本發明之有衆合物塗層的多層材料之製造方 法流程示意圖。 圖號説明： 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 10製造多層材料的裝置 11薄膜 12備用滚筒 13導引滾筒 14導引滾筒 15電暈裝貴 l5a表面處理裝置 16屬（15)的導引滾筒 17導引滾筒 18導引滾筒 19導引滾筒 20橡膠滾筒 21汲取滚筒 22具有刮板的刮板滾 23盛裝聚合物塗覆料的槽 _；_8_ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 五、發明説明（） 離棒，以便放出靜電。另一種方法是在眞空蒸發程序中爲 薄膜塗上一層金屬層。 底下配合圖形及實施例，詳細解説本發明的特點： 圖式説明： ，圖一係爲本發明之有衆合物塗層的多層材料之製造方 法流程示意圖。 圖號説明： 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 10製造多層材料的裝置 11薄膜 12備用滚筒 13導引滾筒 14導引滾筒 15電暈裝貴 l5a表面處理裝置 16屬（15)的導引滾筒 17導引滾筒 18導引滾筒 19導引滾筒 20橡膠滾筒 21汲取滚筒 22具有刮板的刮板滾 23盛裝聚合物塗覆料的槽 _；_8_ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）Production cooperation of employees of the Central Bureau of the Ministry of Economic Affairs of the People's Republic of China. 5.Invention (A kind of film is also very suitable for making promotional materials' because its entire polymer layer color is very uniform (mentioned in the previous paragraph), and its thermosetting It also has excellent weather resistance. In order to minimize the so-called "thin film blocking effect" of the pigment-absorbing layer and / or ink-absorbing layer, the anti-blocking effect of ο · 5 is added to this layer. For example, you can Colloidal oxygen acts as a deficient agent, or it can be added with water-soluble dispersion of human starch (over 3% of branches) as a stopper effect. If this layer has photosensitivity, it can expand the application scope of the film. The method proposed by the invention also includes adding a metal layer with a thickness < (preferably using aluminum and / or chrome metal) on the film, and the metal layer is located on the back of the polymer layer. This measure can make the unit of the film The area weight is greatly reduced. Coating a layer of metal on the color transparent film can make the film still appear the same color, but become opaque. Compared with other methods of manufacturing a color opaque film, the present invention The method can reduce the unit weight of the film by 25-30%, without affecting its physical and chemical properties. Another item of the present invention is to propose a method for manufacturing a multilayer material. What is disclosed in the present invention is this manufacturing method. This method can produce multi-layer materials with stable quality. This method includes applying a reaction layer (such as pigment-absorbing layer and / or ink-absorbing layer) on the side of the film coated with the polymer layer and the adhesive material. ), If necessary, an appropriate anti-blocking effect agent may be added to this reaction layer to avoid the so-called film blocking concealment. In the manufacturing method of the present invention, in order to avoid and / or reduce the film on the drum Due to the electrostatic charging effect generated by friction, the film is caused to flow through the battery κ-κ ϋ I n tn n I f ui III inn τ I n ϋ ml II ^ (Please read the note ^ h on the back before filling in this Page) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 5. Description of the invention () Isolate the rod to discharge static electricity. Another method is to coat the film with a metal layer in the evaporation process The following figures and examples are used to explain the features of the present invention in detail: Schematic description: Figure 1 is a schematic flow chart of the method for manufacturing a multilayer material with a coating of the present invention. Figure Number Description: Central Bureau of Standards, Ministry of Economic Affairs Printed by employee consumer cooperatives (please read the precautions on the back before filling out this page) 10 Device for manufacturing multi-layer materials 11 Film 12 Backup roller 13 Guide roller 14 Guide roller 15 Corona mounted expensive 15a Surface treatment device 16 gen (15 ) Guide roller 17 Guide roller 18 Guide roller 19 Guide roller 20 Rubber roller 21 Drum roller 22 Squeegee roller with a scraper 23 Tank for polymer coating _; _8_ This paper size applies to Chinese national standards (CNS) A4 specification (210X297 mm) 5. Description of the invention () Isolate the rod to discharge static electricity. Another method is to coat the film with a metal layer during a vacuum evaporation process. The following figures and examples are used to explain the features of the present invention in detail: Schematic description: Figure 1 is a schematic flow chart of the method for manufacturing a multilayer material with a coating of the present invention. Drawing number description: Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 10 Device for manufacturing multi-layer materials 11 Film 12 Backup roller 13 Guide roller 14 Guide roller 15 Corona equipment Your 15a surface treatment device 16 belongs to (15) of the guide roller 17, guide roller 18, guide roller 19, guide roller 20, rubber roller 21, drawing roller 22, a squeegee roller 23 with a squeegee, and a groove for polymer coating. _8_ This paper size applies to China National Standard (CNS) A4 specification (210X297 mm)
B7 五、發明説明（） 24有塗覆層的薄膜 25電離棒 25a電離棒 26電離棒 26a電離棒 27導引滚筒 28乾燥管道 29輸入開口 3 0輸出開口 31屬（28)的導引滾筒 32供氣 33加熱器 34螺旋線燈絲 35排氣 36導引滾筒 37塗覆裝貴 38可被加熱的鋼製滚筒 經濟部中央標準局貝工消費合作社印袋 (請先閱讀背面之注意事項再填寫本頁) 39橡膠滾筒 4〇繞有經塗覆的薄膜或纖維網的滾筒 40a薄膜帶 41冷卻滾筒 42導引滾筒 43導引滾筒 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇Χ297公釐）B7 V. Description of the invention (24) 24 coated film 25 ionization rod 25a ionization rod 26 ionization rod 26a ionization rod 27 guide roller 28 drying duct 29 input opening 3 0 output opening 31 belonging to (28) guide roller 32 Air supply 33 Heater 34 Spiral filament 35 Exhaust 36 Guide roller 37 Coating expensive 38 Steel rollers that can be heated 38 Printed bags by the Central Standards Bureau of the Ministry of Economic Affairs Shellfish Consumer Cooperatives (please read the precautions on the back before filling (This page) 39 Rubber roller 40. Roller 40a with a coated film or fiber web 40a Film belt 41 Cooling roller 42 Guide roller 43 Guide roller This paper size is applicable to China National Standard (CNS) A4 specification (21〇 × 297 Mm)
B7 五、發明説明（） 24有塗覆層的薄膜 25電離棒 25a電離棒 26電離棒 26a電離棒 27導引滚筒 28乾燥管道 29輸入開口 3 0輸出開口 31屬（28)的導引滾筒 32供氣 33加熱器 34螺旋線燈絲 35排氣 36導引滾筒 37塗覆裝貴 38可被加熱的鋼製滚筒 經濟部中央標準局貝工消費合作社印袋 (請先閱讀背面之注意事項再填寫本頁) 39橡膠滾筒 4〇繞有經塗覆的薄膜或纖維網的滾筒 40a薄膜帶 41冷卻滾筒 42導引滾筒 43導引滾筒 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇Χ297公釐）B7 V. Description of the invention (24) 24 coated film 25 ionization rod 25a ionization rod 26 ionization rod 26a ionization rod 27 guide roller 28 drying duct 29 input opening 3 0 output opening 31 belonging to (28) guide roller 32 Air supply 33 Heater 34 Spiral filament 35 Exhaust 36 Guide roller 37 Coating expensive 38 Steel rollers that can be heated 38 Printed bags by the Central Standards Bureau of the Ministry of Economic Affairs Shellfish Consumer Cooperatives (This page) 39 Rubber roller 40. Roller 40a with a coated film or fiber web 40a Film belt 41 Cooling roller 42 Guide roller 43 Guide roller This paper size is applicable to China National Standard (CNS) A4 specification (21〇 × 297 Mm)
A Α7 Β7 五、發明説明（） 44導引滾筒 45電離棒 45a電離棒 46電離棒 電離棒 4 7捲繞成品用的捲緩滾筒 48運輸設備 A . 參閲圖（一）係爲本發明有聚合物塗層的多層材料之製 造方法流程示意圖。其中，由備用滾筒（〗2)連續不斷釋出 的衆乙烯醇縮醛製的薄膜（11)，經由導引滾筒（13、14)進 入裝置（1S)内（亦即所謂的電暈裝置），此裝置内有一滾筒 (ie)。薄膜（11)在滾筒（I6)上捲動時，會經過薄膜表面處 理裝置（I5)，接受表面處理，處理的時間依聚滾筒（16)的 周長及旋轉速度而定。電暈裝置（〗5)在整個製造過程中可 以視需要而接通或是關閉。薄膜（11)經過電暈處理後，經 由導引滾筒（17、IS、I9)被導引至由一個橡膠滾筒（2〇) 及一個鍍鉻的鋼製滾筒（21)組成的滾筒組。滾筒（21)在槽 (23)内滚動，作爲汲取滾筒使用。槽（23)内裝有（彩色的） 聚合物混和液，這些聚合物混合液經由一個帶有刮板（圖 中未繪出）的刮板滾筒（22)被帶到滾筒（21)上。 接著，帶有（彩色）塗層的薄膜（24)經過電離棒（25、 10_ 本紙張尺度適用中國國家標準（CNS〉Α4^ ( 2丨0><297公I ) ~裝---〕--1訂-----線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製A Α7 Β7 V. Description of the invention (44) Guiding drum 45 Ionizing rod 45a Ionizing rod 46 Ionizing rod 46 Ionizing rod 4 7 Rolling roller 48 transporting device A for winding the finished product. See Figure (1) for the invention Process flow diagram of manufacturing method of polymer-coated multilayer material. Among them, the film (11) made of vinyl acetal continuously released by the backup roller (〗 2) enters the device (1S) through the guide rollers (13, 14) (also known as a corona device). There is a roller (ie) in this device. When the film (11) is rolled on the roller (I6), it will pass through the film surface processing device (I5) and receive the surface treatment. The processing time depends on the circumference of the polymer roller (16) and the rotation speed. The corona device (〗 5) can be turned on or off as needed during the entire manufacturing process. After the film (11) is corona treated, it is guided by a guide roller (17, IS, I9) to a roller group consisting of a rubber roller (20) and a chrome-plated steel roller (21). The drum (21) rolls in the groove (23) and is used as a drawing drum. The tank (23) contains (colored) polymer mixtures, and these polymer mixtures are brought to the drum (21) via a doctor blade roller (22) with a doctor blade (not shown). Next, the film (24) with (color) coating is passed through an ionization rod (25, 10_ This paper size applies to Chinese national standards (CNS> Α4 ^ (2 丨 0 > < 297 公 I) ~ pack ---] --1 order ----- line (please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs
A Α7 Β7 五、發明説明（） 44導引滾筒 45電離棒 45a電離棒 46電離棒 電離棒 4 7捲繞成品用的捲緩滾筒 48運輸設備 A . 參閲圖（一）係爲本發明有聚合物塗層的多層材料之製 造方法流程示意圖。其中，由備用滾筒（〗2)連續不斷釋出 的衆乙烯醇縮醛製的薄膜（11)，經由導引滾筒（13、14)進 入裝置（1S)内（亦即所謂的電暈裝置），此裝置内有一滾筒 (ie)。薄膜（11)在滾筒（I6)上捲動時，會經過薄膜表面處 理裝置（I5)，接受表面處理，處理的時間依聚滾筒（16)的 周長及旋轉速度而定。電暈裝置（〗5)在整個製造過程中可 以視需要而接通或是關閉。薄膜（11)經過電暈處理後，經 由導引滾筒（17、IS、I9)被導引至由一個橡膠滾筒（2〇) 及一個鍍鉻的鋼製滾筒（21)組成的滾筒組。滾筒（21)在槽 (23)内滚動，作爲汲取滾筒使用。槽（23)内裝有（彩色的） 聚合物混和液，這些聚合物混合液經由一個帶有刮板（圖 中未繪出）的刮板滾筒（22)被帶到滾筒（21)上。 接著，帶有（彩色）塗層的薄膜（24)經過電離棒（25、 10_ 本紙張尺度適用中國國家標準（CNS〉Α4^ ( 2丨0><297公I ) ~裝---〕--1訂-----線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 經濟部中央標準局員工消费合作社印裝 五、發明説明（） 25a及26、Ma)以去除或減少在滾筒上磨擦生成的靜電。 薄膜（11、24)經滚筒系統（27、31及36)通過一個具有輸 入開口（29)及一個輸出開口（3〇)的乾燥管道（28)，將薄膜 上的溶劑（如：甲苯）蒸發掉。乾燥管道（28)内會有熱空氣 吹入，其方式是：供氣（32)經過加熱器（33)上的螺旋線燈 絲（34)被加熱至事先設定的溫度，再進入乾燥管道中。排 氣（35)應離開整個製造系統，不要循環利用。薄膜（n、24) 的乾燥是在逆流過程（32、.35、48)中完成。 接著，薄膜經由滾筒系統（38、41、42、43及44)被 導引至捲繞滾筒（47)，其中，滾筒（41)上裝有一個圏中未 繪出的冷卻裝置，可降低薄膜的溫度，避免薄膜粘在一起， 或在轉動過程中被卡住。爲了消除及/或降低薄膜上的靜 電充電效應，故使薄膜（11、24)再次通過平行設置的一組 電離棒（45、45a 及 46、46a)。 B . 將上述流程A略加修改，可使單面矽化紙（n)自備用 滾筒（I2)中捲出，送至橡膠滾筒（2〇)，使薄膜（11)在此塗 上膠粘材料◊此時，槽（23)應承裝適量的膠粘材料（圖中 未緣出）’此膠粘材料即經由刮板滚筒（Μ〉及汲取滾筒（21) 陂送至薄膜（11)上。在本操作過程中沒有用到電暈裝置 (15)。藉由調整汲取滾筒（U)對橡膠滚筒（2〇)的擠壓力， 午可控制膠粘材料在薄膜上的塗覆量。接著，輿方法A一 本紙張尺度通用中國國家標準（CNS ) A4規格（210X297公釐） I^-------—裝------Ί 訂-----線 (請先閲讀背面之注項再填寫本頁} 經濟部中央標準局員工消费合作社印裝 五、發明説明（） 25a及26、Ma)以去除或減少在滾筒上磨擦生成的靜電。 薄膜（11、24)經滚筒系統（27、31及36)通過一個具有輸 入開口（29)及一個輸出開口（3〇)的乾燥管道（28)，將薄膜 上的溶劑（如：甲苯）蒸發掉。乾燥管道（28)内會有熱空氣 吹入，其方式是：供氣（32)經過加熱器（33)上的螺旋線燈 絲（34)被加熱至事先設定的溫度，再進入乾燥管道中。排 氣（35)應離開整個製造系統，不要循環利用。薄膜（n、24) 的乾燥是在逆流過程（32、.35、48)中完成。 接著，薄膜經由滾筒系統（38、41、42、43及44)被 導引至捲繞滾筒（47)，其中，滾筒（41)上裝有一個圏中未 繪出的冷卻裝置，可降低薄膜的溫度，避免薄膜粘在一起， 或在轉動過程中被卡住。爲了消除及/或降低薄膜上的靜 電充電效應，故使薄膜（11、24)再次通過平行設置的一組 電離棒（45、45a 及 46、46a)。 B . 將上述流程A略加修改，可使單面矽化紙（n)自備用 滾筒（I2)中捲出，送至橡膠滾筒（2〇)，使薄膜（11)在此塗 上膠粘材料◊此時，槽（23)應承裝適量的膠粘材料（圖中 未緣出）’此膠粘材料即經由刮板滚筒（Μ〉及汲取滾筒（21) 陂送至薄膜（11)上。在本操作過程中沒有用到電暈裝置 (15)。藉由調整汲取滾筒（U)對橡膠滚筒（2〇)的擠壓力， 午可控制膠粘材料在薄膜上的塗覆量。接著，輿方法A一 本紙張尺度通用中國國家標準（CNS ) A4規格（210X297公釐） I^-------—裝------Ί 訂-----線 (請先閲讀背面之注項再填寫本頁} 經濟部中央標準局員工消費合作杜印製 A7 B7 五、發明説明（） 樣，被塗上膠粘材料的薄膜（11)經過乾燥管道（28)被弄乾 後，被導引至塗覆裝置（37 )(在方法A中並未用到這種塗 覆裝置）塗覆裝置（37)由一個可被加熱的鋼製滾筒（38)及 一個硬橡膠滾筒（39)構成。薄膜（11)由這兩個滾筒（38,39) 之間的間隙通過，與此同時，一道經方法A杂色的薄膜帶 (4〇a)會由退捲装置U0)捲出並通過塗覆裝置（37)。經由 滾筒（38、39)的壓力及可加熱鏑製滾筒（38)的高溫，會使 附在矽紙上的膠粘材料被移至彩色薄膜上。以這種方式製 成的多層材料經冷卻滾筒U1)冷卻後，再經導引滾筒 (42、43、44)被送至捲繞滚筒（47)。與方法A相同，本 方法亦透過電離棒（25、25a、26、26a、45、45a、46、46a) 消除磨擦造成的靜電。 C . 與上述流程A及B相似，在流程中，可將適當的混合 液注入槽（23)内，以便在薄膜上塗覆一層反應層（如：吸 顏料層及/或吸油墨層）。這個塗覆動作應於薄膜（11、24) 被塗上膠粘材料後便直接進行。 D . 爲了提高力學性能，尤其是抗斷裂的強度，可將薄膜 (11)與聚酯纖維網或織物聯連在一起。這個步驟應在流程 A中將薄膜塗覆上熱固性顏料層之前進行。在此方法中， _;_12 _ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）A Α7 Β7 V. Description of the invention (44) Guiding drum 45 Ionizing rod 45a Ionizing rod 46 Ionizing rod 46 Ionizing rod 4 7 Rolling roller 48 transporting device A for winding the finished product. See Figure (1) for the invention Process flow diagram of manufacturing method of polymer-coated multilayer material. Among them, the film (11) made of vinyl acetal continuously released by the backup roller (〗 2) enters the device (1S) through the guide rollers (13, 14) (also known as a corona device). There is a roller (ie) in this device. When the film (11) is rolled on the roller (I6), it will pass through the film surface processing device (I5) and receive the surface treatment. The processing time depends on the circumference of the polymer roller (16) and the rotation speed. The corona device (〗 5) can be turned on or off as needed during the entire manufacturing process. After the film (11) is corona treated, it is guided by a guide roller (17, IS, I9) to a roller group consisting of a rubber roller (20) and a chrome-plated steel roller (21). The drum (21) rolls in the groove (23) and is used as a drawing drum. The tank (23) contains (colored) polymer mixtures, and these polymer mixtures are brought to the drum (21) via a doctor blade roller (22) with a doctor blade (not shown). Next, the film (24) with (color) coating is passed through an ionization rod (25, 10_ This paper size applies to Chinese national standards (CNS> Α4 ^ (2 丨 0 > < 297 公 I) ~ pack ---] --1 order ----- line (please read the notes on the back before filling out this page) Printed by the Consumers 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs And 26, Ma) to remove or reduce the static electricity generated by friction on the drum. The film (11, 24) passes through the drum system (27, 31, and 36) through an input opening (29) and an output opening (30). Dry the pipe (28) to evaporate the solvent (such as toluene) from the film. Hot air will be blown into the drying pipe (28). The method is: the air supply (32) passes through the spiral on the heater (33). The filament (34) is heated to a preset temperature and then enters the drying duct. The exhaust gas (35) should leave the entire manufacturing system and not be recycled. The drying of the films (n, 24) is in a countercurrent process (32 ,. 35, 48). Next, the film passes through the roller system (38, 41, 42, 43, and 44). It is guided to the winding drum (47), where a cooling device (not shown in the figure) is installed on the drum (41), which can reduce the temperature of the film, prevent the film from sticking together, or get stuck during rotation. In order to eliminate and / or reduce the electrostatic charging effect on the film, the film (11, 24) is again passed through a set of ionization rods (45, 45a and 46, 46a) arranged in parallel. B. The above process A is slightly modified The single-sided siliconized paper (n) can be rolled out from the spare roller (I2) and sent to the rubber roller (20), so that the film (11) is coated with adhesive material. At this time, the groove (23) An appropriate amount of adhesive material (not shown in the figure) should be loaded. 'This adhesive material is sent to the film (11) via the scraper roller (M>) and the extraction roller (21). It is not used during this operation. Corona device (15). By adjusting the pressing force of the extraction roller (U) against the rubber roller (20), the coating amount of the adhesive material on the film can be controlled at noon. Next, method A is a paper size Common Chinese National Standard (CNS) A4 specification (210X297 mm) I ^ --------- installation ------ Ί order ----- line (please read first Please fill in this page again on the page above} Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China. The drum system (27, 31, and 36) evaporates the solvent (such as toluene) on the film through a drying pipe (28) having an input opening (29) and an output opening (30). The drying pipe (28) There will be hot air blowing in, the method is: the air supply (32) is heated to the preset temperature through the spiral filament (34) on the heater (33), and then enters the drying duct. The exhaust (35) should leave the entire manufacturing system and not be recycled. Films (n, 24) are dried in a countercurrent process (32, .35, 48). Then, the film is guided to the winding drum (47) through the roller system (38, 41, 42, 43, and 44). The roller (41) is equipped with a cooling device (not shown) to reduce the film. Temperature to prevent the films from sticking together or getting stuck during rotation. In order to eliminate and / or reduce the electrostatic charging effect on the film, the film (11, 24) is again passed through a set of ionization rods (45, 45a and 46, 46a) arranged in parallel. B. Modify the above process A slightly, so that the single-sided siliconized paper (n) can be rolled out from the spare roller (I2) and sent to the rubber roller (20), so that the film (11) is coated with adhesive here. Material ◊ At this time, the groove (23) should hold an appropriate amount of adhesive material (not shown in the figure). This adhesive material is sent to the film (11) through the scraper roller (M> and the extraction roller (21)). The corona device (15) is not used during this operation. By adjusting the pressing force of the drawing roller (U) against the rubber roller (20), the coating amount of the adhesive material on the film can be controlled at noon. Next, method A—a paper size common Chinese National Standard (CNS) A4 specification (210X297 mm) I ^ ----------------------------- Order --- line (please Read the note on the back before filling out this page} Consumption Cooperation by Employees of the Central Standards Bureau of the Ministry of Economic Affairs, printed A7 B7 5. Description of the invention () Sample, the film coated with adhesive material (11) is passed through a drying pipe (28). After drying, it is guided to the coating device (37) (this coating device is not used in method A). The coating device (37) consists of a steel drum (38) which can be heated and a It consists of a rubber roller (39). The film (11) passes through the gap between the two rollers (38, 39), and at the same time, a film strip (4〇a) colored by method A is passed by the unwinding device. U0) is rolled out and passed through the coating device (37). The pressure of the rollers (38, 39) and the high temperature of the heating roll (38) can cause the adhesive material attached to the silicon paper to be transferred to the colored film The multi-layer material produced in this way is cooled by the cooling drum U1) and then sent to the winding drum (47) through the guide drum (42, 43, 44). As in Method A, this method also eliminates static electricity caused by friction through ionization rods (25, 25a, 26, 26a, 45, 45a, 46, 46a). C. Similar to the above processes A and B, in the process, an appropriate mixed solution can be injected into the tank (23) to apply a reaction layer (such as a pigment-absorbing layer and / or an ink-absorbing layer) on the film. This coating operation should be performed directly after the film (11, 24) is coated with the adhesive material. D. In order to improve the mechanical properties, especially the breaking strength, the film (11) can be connected with polyester fiber net or fabric. This step should be performed before coating the film with a thermosetting pigment layer in process A. In this method, _; _ 12 _ This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm)
Ii— —————— I裝"~ 11 -I n 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 A7 B7 五、發明説明（） 樣，被塗上膠粘材料的薄膜（11)經過乾燥管道（28)被弄乾 後，被導引至塗覆裝置（37 )(在方法A中並未用到這種塗 覆裝置）塗覆裝置（37)由一個可被加熱的鋼製滾筒（38)及 一個硬橡膠滾筒（39)構成。薄膜（11)由這兩個滾筒（38,39) 之間的間隙通過，與此同時，一道經方法A杂色的薄膜帶 (4〇a)會由退捲装置U0)捲出並通過塗覆裝置（37)。經由 滾筒（38、39)的壓力及可加熱鏑製滾筒（38)的高溫，會使 附在矽紙上的膠粘材料被移至彩色薄膜上。以這種方式製 成的多層材料經冷卻滾筒U1)冷卻後，再經導引滾筒 (42、43、44)被送至捲繞滚筒（47)。與方法A相同，本 方法亦透過電離棒（25、25a、26、26a、45、45a、46、46a) 消除磨擦造成的靜電。 C . 與上述流程A及B相似，在流程中，可將適當的混合 液注入槽（23)内，以便在薄膜上塗覆一層反應層（如：吸 顏料層及/或吸油墨層）。這個塗覆動作應於薄膜（11、24) 被塗上膠粘材料後便直接進行。 D . 爲了提高力學性能，尤其是抗斷裂的強度，可將薄膜 (11)與聚酯纖維網或織物聯連在一起。這個步驟應在流程 A中將薄膜塗覆上熱固性顏料層之前進行。在此方法中， _;_12 _ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）Ii—— —————— I equipment " ~ 11 -I n line (please read the precautions on the back before filling this page) Employees' cooperation of the Central Standards Bureau of the Ministry of Economy Du printed A7 B7 V. Description of the invention () In this way, the film (11) coated with the adhesive material is dried through the drying pipe (28) and then guided to the coating device (37) (the coating device is not used in the method A). The covering device (37) is composed of a heatable steel roller (38) and a hard rubber roller (39). The film (11) is passed through the gap between the two rollers (38, 39). At the same time, a film strip (4〇a) colored by method A will be unwound by the unwinding device U0) and passed through the coating. Covering device (37). The pressure from the rollers (38, 39) and the high temperature of the heatable roll (38) will cause the adhesive material attached to the silicon paper to be transferred to the colored film. The multilayer material produced in this way is cooled by the cooling drum U1) and then sent to the winding drum (47) through the guide drum (42, 43, 44). As in Method A, this method also eliminates static electricity caused by friction through ionization rods (25, 25a, 26, 26a, 45, 45a, 46, 46a). C. Similar to the above processes A and B, in the process, an appropriate mixed solution can be injected into the tank (23) to apply a reaction layer (such as a pigment-absorbing layer and / or an ink-absorbing layer) on the film. This coating operation should be performed directly after the film (11, 24) is coated with the adhesive material. D. In order to improve the mechanical properties, especially the breaking strength, the film (11) can be connected with polyester fiber net or fabric. This step should be performed before coating the film with a thermosetting pigment layer in process A. In this method, _; _ 12 _ This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm)
Ii— —————— I裝"~ 11 -I n 線 (請先閲讀背面之注意事項再填寫本頁)Ii— —————— I install " ~ 11 -I n cable (Please read the precautions on the back before filling this page)
A7 B7 u,._.......... 將膠黏材料注入槽（23)内。塗上膠粘材料後的薄膜（11、24) 乾，後’進入塗復裳置（37)，塗覆上纖維網或纖物（40a)， 接著再進行熱固性顏料層的塗覆。 採用以前面麴似的流程可爲厚度在l〇U以内的聚乙 歸醇縮路製的薄膜，以眞空蒸發方法（囷中未繪出）塗覆上 一層厚度<1α的鍺層，此處的蒸發步驟要在48小時的硬 化時間過後才能進行。 本發明的所有步驟都可在同一套裝置上完成。這些步 綠有些可在一個單一的操作流程中一氣呵成，有些步騍則 必須先更換槽内的塗覆材料再逐一完成。 實施例1 將重量百分比爲10-15%、末端帶有氫氧基、ΟΗ數 的聚氨基甲酸乙酯聚合物溶解於含水量<0.1%的甲苯中。 在此溶液中加入重量百分比爲12-15%的彩色顏料（如：二 氧化鈦、螢光性顏料及/或有機色素），將溶液染色。在此 溶液中加入低克分子數的聚異氰酸鹽（重量百分比不超過 1%)及有機錫的化合物（重量百分比不超過〇.〇 5%)作爲催 化劑。此彩色溶液的濕重爲l2-3〇g/nf (視所用顏料而定， 如以二氧化鈦爲顏料，則濕重爲Mg/m2 EMBEDEquat ion·3 □錯誤！物件無法用編輯功能變數代碼來建立。lg)。將甲苯裝在DIN 燒杯内，以4mm喷嘴，流出時間最多90秒的方式稀釋此 * f 3 _ — 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐） I^-------—裝---~--Ί 訂-----線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作衽印製A7 B7 u, ._.......... Inject the adhesive material into the groove (23). The film (11, 24) after being coated with the adhesive material is dried, and after that, it enters the coating fabric (37), is coated with a fibrous web or fabric (40a), and then is coated with a thermosetting pigment layer. A thin film made of polyethylene glycol with a thickness of less than 10U is used in the previous process, and a germanium layer with a thickness of <1α is coated by a vacuum evaporation method (not shown in the figure). The evaporation step can only be performed after the hardening time of 48 hours has elapsed. All steps of the invention can be performed on the same device. Some of these steps can be done in a single operation, and some steps must be completed by changing the coating material in the tank. Example 1 A polyurethane polymer having a weight percentage of 10-15%, a hydroxyl group at the terminal, and a number of Η is dissolved in toluene having a water content of <0.1%. Add 12-15% color pigments (such as titanium dioxide, fluorescent pigments and / or organic pigments) to this solution to dye the solution. To this solution, low-molecular weight polyisocyanate (not more than 1% by weight) and organotin compounds (not more than 0.005% by weight) were added as catalysts. The wet weight of this color solution is l2-30g / nf (depending on the pigment used, if titanium dioxide is used as the pigment, the wet weight is Mg / m2 EMBEDEquat ion · 3 □ Error! The object cannot be created with the editing function variable code .Lg). Fill toluene in a DIN beaker, dilute it with a 4mm nozzle and a maximum outflow time of 90 seconds. * F 3 _ — This paper size applies to China National Standard (CNS) A4 (2 丨 0X297 mm) I ^ --- ------ install --- ~ --Ί order ----- line (Please read the notes on the back before filling this page)
A7 B7 u,._.......... 將膠黏材料注入槽（23)内。塗上膠粘材料後的薄膜（11、24) 乾，後’進入塗復裳置（37)，塗覆上纖維網或纖物（40a)， 接著再進行熱固性顏料層的塗覆。 採用以前面麴似的流程可爲厚度在l〇U以内的聚乙 歸醇縮路製的薄膜，以眞空蒸發方法（囷中未繪出）塗覆上 一層厚度<1α的鍺層，此處的蒸發步驟要在48小時的硬 化時間過後才能進行。 本發明的所有步驟都可在同一套裝置上完成。這些步 綠有些可在一個單一的操作流程中一氣呵成，有些步騍則 必須先更換槽内的塗覆材料再逐一完成。 實施例1 將重量百分比爲10-15%、末端帶有氫氧基、ΟΗ數 的聚氨基甲酸乙酯聚合物溶解於含水量<0.1%的甲苯中。 在此溶液中加入重量百分比爲12-15%的彩色顏料（如：二 氧化鈦、螢光性顏料及/或有機色素），將溶液染色。在此 溶液中加入低克分子數的聚異氰酸鹽（重量百分比不超過 1%)及有機錫的化合物（重量百分比不超過〇.〇 5%)作爲催 化劑。此彩色溶液的濕重爲l2-3〇g/nf (視所用顏料而定， 如以二氧化鈦爲顏料，則濕重爲Mg/m2 EMBEDEquat ion·3 □錯誤！物件無法用編輯功能變數代碼來建立。lg)。將甲苯裝在DIN 燒杯内，以4mm喷嘴，流出時間最多90秒的方式稀釋此 * f 3 _ — 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐） I^-------—裝---~--Ί 訂-----線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作衽印製 經濟部中央標隼局員工消費合作社印製 紙i· 2敖 A7 B7_ ' 五、發明説明（） 彩色溶液。接著將此溶液以機器經由一般的塗覆系統塗覆 在經電暈前處理的聚乙烯醇縮酯所製成的薄膜（PETP薄膜) 上，此PETP薄膜在縱向和橫向上的收縮能力皆爲5%左右。 爲了保持PETP薄膜的收縮能力，最高只能以的溫度 使彩色溶液乾燥。在乾燥過程中，同時將薄膜固定住。乾 燥後的塗層塗覆量爲l5_3〇g/m2 PETP薄膜。將薄膜置於 室溫下（不要超過35·〇48小時後，再塗上一層塗覆量爲 21g/n|2 EMBED Equation. 3 □錯誤丨物件無法用編輯功能變數 代碼來建立》lg的膠粘材料。此處所用的膠粘材料是以聚 丙烯酸酯爲主要成分，先將此膠粘材料的溶液塗在矽紙 上’待其溶劑蒸發後再加壓、加熱，使其與pETp薄膜結 合在一起，待冷卻後此膠粘材料即與熱固性彩色層結合在 一起。此時不要將矽紙拿掉，以保護塗覆層在送到消費者 手上之前不致受到刮傷或爲塵埃所沾污。 實施例2 實施步驟與例1相同。當薄膜塗覆上膠粘材料後，直 接在薄膜正面塗上吸顏料層及/或吸油墨層。此處應以甲 苯（裝在DIN燒杯内、4min喷嘴、流出時間16秒）將溶在 甲苯中的聚醋酸乙烯酯加以稀釋，再以80— 85eC的高溫 將溶劑蒸發掉。塗覆量爲2-8g(乾重）/#薄膜。 實施例3 實施步驟同例2，其吸顏料層及/或吸油墨層添加了 0·5-5%的膠質二氧化矽，以防土薄膜阻塞效應的出現。二 __：__—_14__-___ 本紙張尺度適用中國國家樣準（CNS ) Μ規格（210X297公釐〉 ----------裝-----Τ—訂------線 (請先閲讀背面之注$項再填寫本頁) 經濟部中央標隼局員工消費合作社印製 紙i· 2敖 A7 B7_ ' 五、發明説明（） 彩色溶液。接著將此溶液以機器經由一般的塗覆系統塗覆 在經電暈前處理的聚乙烯醇縮酯所製成的薄膜（PETP薄膜) 上，此PETP薄膜在縱向和橫向上的收縮能力皆爲5%左右。 爲了保持PETP薄膜的收縮能力，最高只能以的溫度 使彩色溶液乾燥。在乾燥過程中，同時將薄膜固定住。乾 燥後的塗層塗覆量爲l5_3〇g/m2 PETP薄膜。將薄膜置於 室溫下（不要超過35·〇48小時後，再塗上一層塗覆量爲 21g/n|2 EMBED Equation. 3 □錯誤丨物件無法用編輯功能變數 代碼來建立》lg的膠粘材料。此處所用的膠粘材料是以聚 丙烯酸酯爲主要成分，先將此膠粘材料的溶液塗在矽紙 上’待其溶劑蒸發後再加壓、加熱，使其與pETp薄膜結 合在一起，待冷卻後此膠粘材料即與熱固性彩色層結合在 一起。此時不要將矽紙拿掉，以保護塗覆層在送到消費者 手上之前不致受到刮傷或爲塵埃所沾污。 實施例2 實施步驟與例1相同。當薄膜塗覆上膠粘材料後，直 接在薄膜正面塗上吸顏料層及/或吸油墨層。此處應以甲 苯（裝在DIN燒杯内、4min喷嘴、流出時間16秒）將溶在 甲苯中的聚醋酸乙烯酯加以稀釋，再以80— 85eC的高溫 將溶劑蒸發掉。塗覆量爲2-8g(乾重）/#薄膜。 實施例3 實施步驟同例2，其吸顏料層及/或吸油墨層添加了 0·5-5%的膠質二氧化矽，以防土薄膜阻塞效應的出現。二 __：__—_14__-___ 本紙張尺度適用中國國家樣準（CNS ) Μ規格（210X297公釐〉 ----------裝-----Τ—訂------線 (請先閲讀背面之注$項再填寫本頁) ga 4.21A7 B7 u, ._.......... Inject the adhesive material into the groove (23). The film (11, 24) after being coated with the adhesive material is dried, and after that, it enters the coating fabric (37), is coated with a fibrous web or fabric (40a), and then is coated with a thermosetting pigment layer. A thin film made of polyethylene glycol with a thickness of less than 10U is used in the previous process, and a germanium layer with a thickness of <1α is coated by a vacuum evaporation method (not shown in the figure). The evaporation step can only be performed after the hardening time of 48 hours has elapsed. All steps of the invention can be performed on the same device. Some of these steps can be done in a single operation, and some steps must be completed by changing the coating material in the tank. Example 1 A polyurethane polymer having a weight percentage of 10-15%, a hydroxyl group at the terminal, and a number of Η is dissolved in toluene having a water content of <0.1%. Add 12-15% color pigments (such as titanium dioxide, fluorescent pigments and / or organic pigments) to this solution to dye the solution. To this solution, low-molecular weight polyisocyanate (not more than 1% by weight) and organotin compounds (not more than 0.005% by weight) were added as catalysts. The wet weight of this color solution is l2-30g / nf (depending on the pigment used, if titanium dioxide is used as the pigment, the wet weight is Mg / m2 EMBEDEquat ion · 3 □ Error! The object cannot be created with the editing function variable code .Lg). Fill toluene in a DIN beaker, dilute it with a 4mm nozzle and a maximum outflow time of 90 seconds. * F 3 _ — This paper size applies to China National Standard (CNS) A4 (2 丨 0X297 mm) I ^ --- ------ install --- ~ --Ί order ----- line (please read the notes on the back before filling out this page) Central Bureau of Standards of the Ministry of Economy Bureau employee consumer cooperative printed paper i · 2 Ao A7 B7_ 'V. Description of the invention () Color solution. This solution is then machine-coated on a film (PETP film) made of corona pretreated polyvinyl acetal by a general coating system. The shrinkage ability of this PETP film in the longitudinal and transverse directions is About 5%. In order to maintain the shrinking ability of the PETP film, the color solution can only be dried at a maximum temperature. During the drying process, the film is fixed at the same time. The coating amount after drying was 15-30 g / m2 PETP film. Place the film at room temperature (do not exceed 35 · 48 hours, and then apply a layer with a coating amount of 21g / n | 2 EMBED Equation. 3 □ Error 丨 The object cannot be edited with the editing function variable code to create "lg gel" Adhesive material. The adhesive material used here is polyacrylate as the main component. First, apply a solution of this adhesive material on silicon paper. 'After the solvent evaporates, pressurize and heat it to combine it with the pETp film. Together, the adhesive material is combined with the thermoset color layer after cooling. At this time, do not remove the silicon paper to protect the coating layer from being scratched or contaminated by dust before it is delivered to the consumer. Example 2 The implementation steps are the same as in Example 1. After the film is coated with an adhesive material, a pigment-absorbing layer and / or an ink-absorbing layer is directly coated on the front side of the film. Here, toluene (packed in a DIN beaker, 4 minutes) Nozzle, outflow time 16 seconds) Dilute polyvinyl acetate dissolved in toluene, and then evaporate the solvent at a high temperature of 80-85eC. The coating amount is 2-8g (dry weight) / # film. Example 3 The implementation steps are the same as in Example 2. The pigment absorption layer and / or 0.5 ~ 5% colloidal silica is added to the ink layer to prevent the blocking effect of the soil film. Two__: __—_ 14 __-___ This paper size applies to China National Standard (CNS) M specifications (210X297) Li> ---------- installation ----- T-order ------ line (please read the note $ on the back before filling out this page) Staff Consumption of Central Bureau of Standards, Ministry of Economic Affairs Cooperative printed paper i · 2ao A7 B7_ 'V. Description of the invention () Color solution. Then this solution is machine-coated with a film made of corona pretreated polyvinyl acetal (PETP film), the shrinking ability of this PETP film in the longitudinal and transverse directions is about 5%. In order to maintain the shrinking ability of the PETP film, the color solution can only be dried at a maximum temperature. During the drying process, the film is simultaneously Fix it. The coating amount of the coating after drying is 15-30 g / m2 PETP film. Place the film at room temperature (do not exceed 35 · 48 hours, and then apply a coating of 21 g / n | 2 EMBED Equation. 3 □ Error 丨 The object cannot be created with the editing function variable code. Lg adhesive material. The one used here Adhesive material uses polyacrylate as the main component. First apply the solution of this adhesive material on silicon paper. 'After its solvent evaporates, pressurize and heat it to combine it with the pETp film. After cooling, this adhesive The material is combined with the thermoset color layer. At this time, do not remove the silicon paper to protect the coating layer from being scratched or contaminated by dust before being sent to the consumer. Example 2 Implementation steps and examples 1 the same. After the film is coated with the adhesive material, directly apply the pigment-absorbing layer and / or ink-absorbing layer on the front side of the film. Here, toluene (packed in a DIN beaker, 4min nozzle, and outflow time 16 seconds) Polyvinyl acetate dissolved in toluene was diluted, and the solvent was evaporated at a high temperature of 80-85eC. The coating amount is 2-8g (dry weight) / # film. Example 3 The implementation steps are the same as in Example 2. The pigment-absorbing layer and / or ink-absorbing layer are added with 0.5-5% colloidal silica to prevent the blocking effect of the soil film. Two __: __—_ 14 __-___ This paper size is applicable to China National Standard (CNS) M specifications (210X297 mm) ---------- installation ----- T-order ---- --Line (please read the note on the back before filling this page) ga 4.21
五、發明説明（ 經濟部中央榡率局員工消費合作、社印袋 氧化梦的添〜是藉絲盤進行的。 兔施例4 前，ίί 2例1的步裸，但PETP薄膜在塗上塗覆廣之 、9纖維網聯結’以提高且力學性能（★、立异抗 斷裂強度）。鬼τ胜她他地捉间，、刀学性此（尤其疋抗 種溶於甲纖維網塗覆在膽薄膜上，應使用一 成分二液在2二，科(以氣氨基甲酸梅爲主要 此溶液與重行加工處理前三十分鐘，將 鹽的玄液相巧人爲 NC()含量約U·5%的聚異氰酸 室溫^放署口。在8〇亡的溫度下使溶劑蒸發◊接著在 液及膠粘材科8塗丄:薄::實施例1的方法依次將彩色溶 免施例5 抑塔實施例1的步骤’但以—種可感熱的膠轱材料為 先使用的膠枯材料，塗在薄膜的聚合物塗層上。這毛 =感熱的膠叫料係由以甲苯爲溶劑的線性結構的含氫| ^的衆氨基甲酸較合物（〇H數如的溶液構成。所塗| ^膠枯材料量（乾重）爲2H5g/nf薄膜。以8G_1()(rc的通 f使溶劑蒸發。與實施例1相同，採用轉移方法將可感索 的膠枯材料塗覆錄合物塗層上。 '” 复施例6 重覆實施例1的步騍，但以眞空蒸發方法將厚度<liU 的銘層塗覆於厚度5_l〇U的彩色透明PETP薄膜上。接著 以傳送方法將一層可感熱的聚氨基甲酸酯膠粘材料塗層塗 —^-- (請先閲读背面之注意事項存填寫本頁) —订 tiiiiiT^NS ) AAW^r ( 2\〇^29V^¥) ga 4.21V. Description of the invention (The consumption cooperation of employees of the Central Government Bureau of the Ministry of Economic Affairs and the oxidized dreams of the social printing bags are carried out by silk reels. Before the Example 4 of the rabbit, the step 2 of Example 1 was bare, but the PETP film was applied on the coating. Covering wide, 9 fiber webs are connected to improve and mechanical properties (★, innovative breaking strength). Ghost τ is better than others, this is the school of science (especially the resistance is soluble in nail fiber web coating) On the bile film, one component and two liquids should be used in two two, two (2), ketone (mainly gas urethane), and this solution should be processed 30 minutes before reprocessing. • 5% polyisocyanate at room temperature. The solvent was evaporated. The solvent was evaporated at a temperature of 80 ° C. Then, it was applied to the liquid and adhesive material department 8: Thin: The method of Example 1 was used to sequentially color dissolve. Exempt from Example 5 The steps of Example 1 of Suppressing Tower, but a kind of heat-sensitive rubber material is used as the rubber material, which is coated on the polymer coating of the film. This wool = heat-sensitive rubber material is made of The linear structure of hydrogen-containing urethanes with toluene as the solvent is composed of a solution with a number of 0H. The amount of coating material The dry weight) is a 2H5g / nf film. The solvent is evaporated with a flux of 8G_1 () (rc.) The same as in Example 1, a susceptible gum material is coated on the recording material coating layer by a transfer method. "" Repeat Example 6 The steps of Example 1 were repeated, but the coating layer with a thickness of < liU was applied to a color transparent PETP film with a thickness of 5-10 U by a vacuum evaporation method. Then, a layer of heat-sensitive polymer was transferred by a transport method. Coating of urethane adhesive material — ^-(Please read the precautions on the back and fill in this page first) —Order tiiiiiT ^ NS) AAW ^ r (2 \ 〇 ^ 29V ^ ¥) ga 4.21
五、發明説明（ 經濟部中央榡率局員工消費合作、社印袋 氧化梦的添〜是藉絲盤進行的。 兔施例4 前，ίί 2例1的步裸，但PETP薄膜在塗上塗覆廣之 、9纖維網聯結’以提高且力學性能（★、立异抗 斷裂強度）。鬼τ胜她他地捉间，、刀学性此（尤其疋抗 種溶於甲纖維網塗覆在膽薄膜上，應使用一 成分二液在2二，科(以氣氨基甲酸梅爲主要 此溶液與重行加工處理前三十分鐘，將 鹽的玄液相巧人爲 NC()含量約U·5%的聚異氰酸 室溫^放署口。在8〇亡的溫度下使溶劑蒸發◊接著在 液及膠粘材科8塗丄:薄::實施例1的方法依次將彩色溶 免施例5 抑塔實施例1的步骤’但以—種可感熱的膠轱材料為 先使用的膠枯材料，塗在薄膜的聚合物塗層上。這毛 =感熱的膠叫料係由以甲苯爲溶劑的線性結構的含氫| ^的衆氨基甲酸較合物（〇H數如的溶液構成。所塗| ^膠枯材料量（乾重）爲2H5g/nf薄膜。以8G_1()(rc的通 f使溶劑蒸發。與實施例1相同，採用轉移方法將可感索 的膠枯材料塗覆錄合物塗層上。 '” 复施例6 重覆實施例1的步騍，但以眞空蒸發方法將厚度<liU 的銘層塗覆於厚度5_l〇U的彩色透明PETP薄膜上。接著 以傳送方法將一層可感熱的聚氨基甲酸酯膠粘材料塗層塗 —^-- (請先閲读背面之注意事項存填寫本頁) —订 tiiiiiT^NS ) AAW^r ( 2\〇^29V^¥) A7 _B7_ '___ 五、發明説明（） 覆在此薄膜上。膠·枯材料的製作方式爲··將〇H數、重 量百分比I2 — I5%的聚氨基甲酸酯聚合物溶液與甲苯及丁 酮的混合液，按9 : 1的比例混合而成。 除了採用聚氨基甲酸酯膠枯材料外，亦可以採用以聚 丙烯酸酯爲主要成分的膠粘材料。 I I裝 - 訂 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 _B7_ '___ 五、發明説明（） 覆在此薄膜上。膠·枯材料的製作方式爲··將〇H數、重 量百分比I2 — I5%的聚氨基甲酸酯聚合物溶液與甲苯及丁 酮的混合液，按9 : 1的比例混合而成。 除了採用聚氨基甲酸酯膠枯材料外，亦可以採用以聚 丙烯酸酯爲主要成分的膠粘材料。 I I裝 - 訂 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）V. Description of the invention (The consumption cooperation of employees of the Central Government Bureau of the Ministry of Economic Affairs and the oxidized dreams of the social printing bags are carried out by silk reels. Before the Example 4 of the rabbit, the step 2 of Example 1 was bare, but the PETP film was applied on the coating. Covering wide, 9 fiber webs are connected to improve and mechanical properties (★, innovative breaking strength). Ghost τ is better than others, this is the school of science (especially the resistance is soluble in nail fiber web coating) On the bile film, one component and two liquids should be used in two two, two (2), ketone (mainly gas urethane), and this solution should be processed 30 minutes before reprocessing. • 5% polyisocyanate at room temperature. The solvent was evaporated. The solvent was evaporated at a temperature of 80 ° C. Then, it was applied to the liquid and adhesive material department 8: Thin: The method of Example 1 was used to sequentially color dissolve. Exempt from Example 5 The steps of Example 1 of Suppressing Tower, but a kind of heat-sensitive rubber material is used as the rubber material, which is coated on the polymer coating of the film. This wool = heat-sensitive rubber material is made of The linear structure of hydrogen-containing urethanes with toluene as the solvent is composed of a solution with a number of 0H. The amount of coating material The dry weight) is a 2H5g / nf film. The solvent is evaporated with a flux of 8G_1 () (rc.) The same as in Example 1, a susceptible gum material is coated on the recording material coating layer by a transfer method. "" Repeat Example 6 The steps of Example 1 were repeated, but the coating layer with a thickness of < liU was applied to a color transparent PETP film with a thickness of 5-10 U by a vacuum evaporation method. Then, a layer of heat-sensitive polymer was transferred by a transport method. Coating of urethane adhesive material — ^-(Please read the precautions on the back and fill in this page first) —Order tiiiiiT ^ NS) AAW ^ r (2 \ 〇 ^ 29V ^ ¥) A7 _B7_ '___ V. Description of the invention () Covered on this film. The production method of glue and dry material is: a mixed solution of OH number and weight percentage I2-I5% of polyurethane polymer solution and toluene and methyl ethyl ketone , Mixed in a ratio of 9: 1. In addition to using polyurethane rubber material, you can also use polyacrylate as the main component of the adhesive material. II Packing-Thread (Please read the note on the back first Please fill in this page again for details) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This paper is applicable to China Standard (CNS) A4 specification (210X297 mm) A7 _B7_ '___ V. Description of the invention () Coated on this film. The production method of glue and dry material is: 〇H number, weight percentage I2 — I5% polymer The urethane polymer solution is mixed with toluene and methyl ethyl ketone in a ratio of 9: 1. In addition to the polyurethane gum material, it is also possible to use a polyacrylate as the main component. Packing II. Binding (please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This paper is sized for China National Standard (CNS) A4 (210X297 mm)
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW86100241A TW393397B (en) | 1997-01-11 | 1997-01-11 | Polymer coated multilayer material and its production processes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW86100241A TW393397B (en) | 1997-01-11 | 1997-01-11 | Polymer coated multilayer material and its production processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW393397B true TW393397B (en) | 2000-06-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW86100241A TW393397B (en) | 1997-01-11 | 1997-01-11 | Polymer coated multilayer material and its production processes |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TW393397B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8021729B2 (en) | 2007-10-25 | 2011-09-20 | Hon Hai Precision Industry Co., Ltd. | Housing and surface treating method for making the same |
-
1997
- 1997-01-11 TW TW86100241A patent/TW393397B/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8021729B2 (en) | 2007-10-25 | 2011-09-20 | Hon Hai Precision Industry Co., Ltd. | Housing and surface treating method for making the same |
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