TW296331B - - Google Patents

Description

經濟部中央標準局SK工消費合作社印奴 A6 B6 五、發明説明（1 ) 本發明係在可用以對抗單子葉及雙子葉雜草& f乍牧 護劑0 EP-A-0，342，569，EP—A-0，342，568 及 ΕΡ-Α-0，388，771 揭 示可用以控制廣範圍單子葉及雙子葉雜草之雜環經取代苯 氧基磺酿基脲。它們可用爲土壤作用除草劑以及葉部使用 且對單子葉作物植物（諸如，穀類，玉米及高梁之單子葉 作物植物具有高度選擇性。 EP — A— 0，4 9 4，9 8 8 及£卩一八— 0 ，4 8 0 ，3 0 6揭示在控制穀類及稻子中之重要問題 雜草具有協乘改良效力之活性物質混合物。 但是，若僅使用上述混合物，則在穀類以及玉米和稻 子中之一系列經濟上高度重要性之單子葉雜草，例如，看 麥娘（Alopecurus myosuroides)，燕麥（Avenafatua) ，稗(Echinochloa crus-galli)，粟(Setaria virid-is)不能以最適當之方式控制。 令人驚訝的是現在由生化實驗可辨認出除草活性物質 ，其當綜合上述各別化合物使用時，就對抗雜草之效率而 言具有顯著的協乘性質，因而優於EP — A — 0 ，4 9 4 ，9 8 8中掲示之二相混合物。 本發明係關於除草劑，其包含有效數量之 A )通式（I )所示化合物或其鹽類： 本纸張尺度適用中國國家標準（CMS)甲4規格（210 X 297公货） -4 - 82.3. 40,000 ------------,---「-------裝------.玎----^ % (請先閲讀背面之注意事項再蜞寫本頁) A6 B6 五、發明説明（2 )The Ministry of Economic Affairs, Central Bureau of Standards, SK Industrial and Consumer Cooperative Inno A6 B6 V. Description of the invention (1) The present invention can be used to fight against monocotyledonous and dicotyledonous weeds & f Chamu pastoral 0 EP-A-0, 342, 569, EP-A-0, 342, 568 and EP-A-0, 388, 771 disclose heterocyclic substituted phenoxy sulfonylurea which can be used to control a wide range of monocotyledonous and dicotyledonous weeds. They can be used as soil-acting herbicides and leaves and are highly selective for monocotyledonous crop plants (such as cereals, corn and sorghum monocotyledonous crop plants. EP — A— 0, 4 9 4, 9 8 8 and £卩 一 八 — 0, 4 8 0, 3 0 6 reveals the important problem in the control of cereals and rice. Weeds are active substance mixtures with synergistic improvement effect. However, if only the above mixtures are used, in cereals and corn and rice One of the series of economically important monocotyledonous weeds, for example, see Alopecurus (Alopecurus myosuroides), oats (Avenafatua), barnyard grass (Echinochloa crus-galli), millet (Setaria virid-is) It is surprising that the herbicidal active substances can now be identified by biochemical experiments. When used in combination with the above compounds, they have significant synergistic properties in terms of efficiency against weeds and are therefore superior to EP-A — Two-phase mixture shown in 0, 4 9 4 and 9 8 8. The present invention relates to herbicides, which contain an effective amount of A) a compound represented by the general formula (I) or its salts: this paper Applicable to China National Standard (CMS) A 4 specifications (210 X 297 public goods) -4-82.3. 40,000 ------------, --- `` ------- installed- -----. 玎 ---- ^% (Please read the precautions on the back before writing this page) A6 B6 5. Description of the invention (2)

(請先閲讀背面之注意事項再場寫本頁) R 1(Please read the notes on the back before writing this page) R 1

_/ Y R_ / Y R

^~y-oso2NH-c-N 式中： a 1 ) R1示乙氧基，丙氧基或異丙氧基以及 R2 示鹵原子，N〇2，CF3，CN，Ci 一 C4 — 焼基’ Cl_C4 一院氧基’ Cl— C4 一院基硫 基或（Cl— C4 一垸氧基）裁基 以及 η 示0，1，2或3，或者 a 2 ) R1示任意不飽和Ci— C8 —烷氧基（其經鹵原子 經濟部中央標準局負工消費合作社印5衣 取代），任意不飽和Ci—Cs —烷氧基，通式 (Ci — C6 —院基）—S -，（Ci— Ce —院 基）—SO —，（Ci— C6 —院基）'一 S〇2 —，（Ci 一 C6 —院基）一0 — c〇一， N〇2，CN所示基團或苯基，還有C2— c8 一烯氧基或-炔氧基，以及 R2示飽和或不飽和Cl— c8-烷基，苯基，苯氧 基* Cl — C4 —院氧基，Cl 一 C4 一院基硫基 ，（Ci—Ci 一烷氧基）羰基，所有上述R2 之基團可經鹵原子，CT—C4 一烷氧基或Ci — C4 —烷基硫基取代，或者示鹵原子，N〇2 ，Ct— C4 一烷基磺醯基或—亞磺醯基，以及 η 示Q，l，2或3，或者 82.3. 40,000 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 經濟部中央標準局員工消费合作社印製 A6 B6 五、發明説明（3 ) a3 ) R1 ^r：Ci_C8 —焼氧基，以及 R2不C2—C8 —嫌基或—块基’苯基或苯氧基， 其中，所有上述R2之基團係未經取代或經齒 原子，Ci — C4 —焼氧基或一院硫基取代，或 者tkC 1— C 4 一焼基磁酿基或一焼基亞礎酿基 ，以及 η 示1，2或3，或者 a4 ) R1在苯基之2 -位置之每一情況下示鹵原子，甲 氧基，乙基或丙基， R2示苯基之6 —位置上的（C^—C4 一烷氧基） 羰基，以及 η 示1 ， 以及，在所有31) — a4)之情況下， R 3 示氫原子，飽和或不飽和匚！— C8 —烷基或Ci- C 4 —院氧基， R4和R5各別示氫原子，鹵原子，CT—C4一烷基，Ci —C4 —院氧基和Cl 一 C4 一院基硫基，前述後三 基團係未經取代或經鹵原子，Ci-Cd —烷氧基或 C 1 一 C 4 一院基硫基取代’ Y 示0或S，以及 E 示C Η或N， 以及 Β ) —，二或更多種選自下列之化合物： Β1) 3，7 —二氯基喹啉—8 -羧酸及其鹽類（喹 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） '6 - 82.3. 40,000 ------------j---'-------裝 訂 -.-J (請先閲讀背面之注意事項再堉寫本頁) 2ο^όόΐ Α6 Β6^ ~ y-oso2NH-cN where: a 1) R1 shows ethoxy, propoxy or isopropoxy and R2 shows halogen atom, N〇2, CF3, CN, Ci — C4 — alkoxy group Cl_C4 Institutional oxygen 'Cl—C4 monoinstitutional thio group or (Cl—C4—alkyloxy) radical and η shows 0, 1, 2 or 3, or a 2) R1 shows any unsaturated Ci—C8 —alkoxy Base (which is replaced by the halogenated consumer cooperative cooperative printing 5 clothing of the Central Standards Bureau of the Ministry of Economics of Halogen), any unsaturated Ci—Cs —alkoxy, general formula (Ci — C6 —hospital base) —S —, (Ci— Ce —Hospital) —SO—, (Ci—C6—Hospital) ′ — S〇2—, (Ci—C6—Hospital) —0—c〇 一, N〇2, CN or the phenyl group , And C2-c8 monoalkenyloxy or -alkynyloxy, and R2 shows saturated or unsaturated Cl-c8-alkyl, phenyl, phenoxy * Cl-C4-homooxy, Cl-C4 uniho Thio group, (Ci-Ci-alkoxy) carbonyl group, all of the above R2 groups may be substituted with halogen atom, CT-C4-monoalkoxy group or Ci-C4-alkylthio group, or show halogen atom, N 〇2, Ct-C4 monoalkylsulfonyl or -sulfinyl , And η shows Q, l, 2 or 3, or 82.3. 40,000 The paper size applies to China National Standards (CNS) A 4 specifications (210 X 297 mm) A6 B6 printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Description of the invention (3) a3) R1 ^ r: Ci_C8-alkoxy group, and R2 is not C2-C8-aryl group or-block group phenyl or phenoxy group, wherein all the above R2 groups are unsubstituted Or via a tooth atom, Ci — C4 — haloxy or a thiol group, or tkC 1 — C 4-yoke magnetic or yoke subbase, and η shows 1, 2 or 3, or a4) R1 shows a halogen atom in each case of the 2-position of phenyl, methoxy, ethyl or propyl, R2 shows the (C ^ -C4 monoalkoxy) carbonyl group at the 6-position of phenyl , And η shows 1, and, in all cases 31) to a4), R 3 shows a hydrogen atom, saturated or unsaturated! — C8 —alkyl or Ci- C 4 —homooxy, R4 and R5 each represent a hydrogen atom, a halogen atom, CT—C4 monoalkyl, Ci —C4 —homooxy and Cl —C4 monohomothio , The aforesaid last three groups are unsubstituted or substituted with halogen atoms, Ci-Cd-alkoxy or C 1 -C 4 -academic thio substituted Y 'shows 0 or S, and E shows C Η or N, and Β) —, two or more compounds selected from the following: Β1) 3,7-dichloroquinoline-8-carboxylic acid and its salts (Quin paper size is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) '6-82.3. 40,000 ------------ j ---'------- binding -.- J (Please read the notes on the back first Rewrite this page) 2ο ^ όόΐ Α6 Β6

N-C0SCH,CH 五、發明説明（4 ) 克羅拉（quinchlorac)， 1 ) B2)N —(乙硫基羰基）氮雜草烷（azepane)( 莫里那特（molinate))， { B 2 B 3 )硫代胺甲酸S — 4 —氯苄基二乙酯（塞歐本卡 爾(thiobencarb))， (請先閲讀背面之注意事項再塡寫本頁)N-C0SCH, CH V. Description of the invention (4) quinchlorac, 1) B2) N— (ethylthiocarbonyl) azepane (molinate), {B 2 B 3) Thiocarbamic acid S — 4-chlorobenzyl diethyl ester (thiobencarb), (please read the precautions on the back before writing this page)

ClCl

ch2s-co-n(c2h5)2 (B3) 經濟部中央標準局員工消費合作社印製ch2s-co-n (c2h5) 2 (B3) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

5 ,coch2c B4 ) N— (丁氧基甲基）一2 —氯基一N — （2 ， 6 —二乙基苯基）乙醯胺（布它克羅（butac· h 1 〇 r ))， r u5, coch2c B4) N— (butoxymethyl) -2-chloro-1-N— (2,6-diethylphenyl) acetamide (butacrrol (butac · h 1 〇r)) , Ru

'CH2-0-CH2CH2CH2CH B5 ) N— ( 2 —丙氧基乙基）一2 —氯基一N —( 2 ，6_二乙基苯基）乙醯胺（普呔克羅（p- 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公坌） 82.3. 40,000 r μ'CH2-0-CH2CH2CH2CH B5) N— (2 — Propoxyethyl) — 2-chloro-N — (2, 6_ diethylphenyl) acetamide (Promethol (p-ben The paper scale is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 82.3. 40,000 r μ

XOCH^CI oh2ch2o(ch2)2ch A6 B6 五、發明説明（5 ) reti lachlor ))， (B5) B6) 3 ，5 —雙（甲硫基羰基）一2 —二氟甲基一 4— ( 2 —甲基丙基）一6 —三氟甲基吡啶（ M〇N — 7 2 0 0 ，二硫吡（dithiopyr))， (請先閲讀背面之注意事項再填寫本頁)XOCH ^ CI oh2ch2o (ch2) 2ch A6 B6 V. Description of the invention (5) reti lachlor)), (B5) B6) 3, 5-bis (methylthiocarbonyl) -2-difluoromethyl-4- (2 —Methylpropyl) -6-trifluoromethylpyridine (M〇N — 7 2 0 0, dithiopyr (dithiopyr)), (please read the precautions on the back before filling this page)

CHCH

•ch3 -CO-SCH CF〇H (B 6 B7) 2 -（1 ，3_苯並U塞唑—2-基連氧基）一 N —甲基乙醯替苯胺，（美吩那西特（11^€611-a c e t ))， as、 CH , I Λ •och2conc6h (B7 —裝- i 經濟部中央標準局員工消費合作社印製 B8 ) 2 —〔 4— ( 6 —氯基苯並噁唑—2 -基連氧 基）苯氧基〕丙酸乙酯，（吩諾拉普一乙基（ fenoxaprop-ethyl )， 本紙張又度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 82.3. 40,000 五、發明説明（• ch3 -CO-SCH CF〇H (B 6 B7) 2-(1,3_benzoU sezo-2-yl-linked oxygen) -N-methyl acetophenanilide, (Mephenacitide (11 ^ € 611-acet)), as, CH, I Λ • och2conc6h (B7-installed-i Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs B8) 2 — [4-(6-chlorobenzoxazole —2-Benzyloxy) phenoxy] ethyl propionate, (fenoxaprop-ethyl), this paper is also applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 %) 82.3. 40,000 V. Description of invention (

CH A6 B6 •N i v I '''yo—r y—o-ch-cooc2h5 (B8 ·〇 \m/ B9 ) N— ( 2-苯基丙—2 —基硫羰基）哌啶（ MY — 9 3，待美 D 比瑞特（dimepiperate))，CH A6 B6 • N iv I '' 'yo-ry—o-ch-cooc2h5 (B8 · 〇 \ m / B9) N— (2-phenylprop-2-ylthiocarbonyl) piperidine (MY—9 3 , To be beautiful D biruite (dimepiperate)),

c(ch3)2-s-co -ο (B9 ) B1 0)甲苯一 4 一磺酸一4 一（2 ，4 —二氯基苯 醯基）_1 ，3 —二甲基吡唑一 5 —酯（吡 哩拉那特（pyraz.olynate)，卩比哩列特（p-yrazolate ))， 0 C I cc (ch3) 2-s-co -ο (B9) B1 0) toluene-4 monosulfonic acid-4 4- (2,4-dichlorophenylacryl) _1,3-dimethylpyrazole-5- Ester (pyraz.olynate, p-yrazolate), 0 CI c

CH (B1 0) (請先M讀背面之注意事項再填寫本頁) 丨裝. 經濟部中央標準局員工消費合作社印3衣 B 1 1 ) 2 —〔4— (2 ，4 —二氯基苯醯基）—1 ，3 —二甲基吡唑一 5 _基連氧基〕苯乙酮 (D比哩西吩（pyrazoxyfen))， 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 82.3. 40,000 2〇ύόό1 Α6 Β6CH (B1 0) (please read the precautions on the back before filling in this page) 丨 Packed. Printed 3 clothes B 1 1) 2 — [4— (2, 4 — dichloro-based Phenacryl) -1,3-dimethylpyrazole-5-pyridine] acetophenone (Dpyrazoxyfen), this paper scale is applicable to China National Standard (CNS) A4 specifications ( 210 X 297 mm) 82.3. 40,000 2〇ύόό1 Α6 Β6

ch3 五、發明説明（ch3 V. Description of invention (

B1 2) 2 —〔4_ (2 ，4 —二氯基—間一甲苯醯 基）—1 ，3 —二甲基吡唑一5 —基連氧基 〕一 4 > 一甲基苯乙酮（苯並吩那普（1)611-ζ 〇 f e n a p )) ， 0 Cl CH, (請先閲讀背面之注意事項再項寫本頁)B1 2) 2 — [4_ (2,4-dichloro-m-tolylyl) -1,3-dimethylpyrazole-5-yl-linked oxy] -4> monomethylacetophenone (Benzenophen (1) 611-ζ 〇fenap)), 0 Cl CH, (please read the precautions on the back before writing this page)

B1 3) 2 — (2 —某氧基）丙醯替苯胺（那普尼里 得(naproanilide))，B1 3) 2 — (2-oxo) propylanilide (naproanilide),

C 經濟部中央標準局員工消費合作社印製C Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

BB

4 6 基be 醯丨 胺基 丨磺甲 - 基 I ^ 醯柔 一 甲 啶酸 嘧苯 基甲 氧| 甲鄰 2 匕曰 甲呋 胺舒 基苯 m 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） -10 - 82.3. 40,000 A6 B64 6 base be amide 丨 amino sulfonyl-yl I ^ acetamido-methyl pyrimidyl methoxy methoxy | methyl o 2 2 d ketuo form furfuryl sulphenyl benzene m This paper scale is applicable to China National Standard (CNS) A 4 Specifications (210 X 297 mm) -10-82.3. 40,000 A6 B6

五、發明説明（8 ) .COOCH αV. Description of the invention (8) .COOCH α

0II0II

0 C H CH,-SO,-NH-C-NH-0 C H CH, -SO, -NH-C-NH-

N- " V (B 1 4 )N- " V (B 1 4)

0 C H0 C H

B )5— (4 ，6_二甲氧基嘧啶—2_基胺甲 醯基磺胺醯基）一 1 —甲基吡唑一4 _羧酸 甲醋（ϋ比哩舒呋柔一乙基（pyrazosulfuron -ethyl))，B) 5— (4,6_dimethoxypyrimidine-2-ylaminomethasulfonamide) -1—methylpyrazole-4_carboxylic acid methyl ester (Pyrazosulfuron -ethyl)),

CH 0 C Η 0CH 0 C Η 0

so2-nh-c (B1 5) (請先閲讀背面之注意事項再填寫本頁) i裝· B 1 )1- (4 ，6 — 二甲氧基一1 ，3 ，5 -三 瞭一2 —基）一3 —〔 2 — ( 2 —甲氧基乙 氧基）苯基磺醯基〕脲（西諾舒呋柔（cin-osulfuron ))，so2-nh-c (B1 5) (Please read the precautions on the back before filling in this page) i installed · B 1) 1- (4, 6 — dimethoxy-1, 3, 5-Trinity 2 — Group) a 3 — [2-(2-methoxyethoxy) phenylsulfonyl] urea (cin-osulfuron (cin-osulfuron)),

0CH,CHo0CH OCH0CH, CHo0CH OCH

(B16) 訂. r^· 經濟部中央標準局g工消費合作社印製 B17)乙烷磺酸一2 ，3 —二氫一3 ，3 —二甲基 苯並呋喃一 5 —酯（苯呋瑞特（卜611丨11^5&-t e ))， 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公坌〉 11 82.3. 40,000 A6 B6(B16) Order. R ^ · Printed by the Ministry of Economic Affairs, Central Bureau of Standards, Gonggong Consumer Cooperatives B17) Ethane sulfonic acid-2,3-dihydromono-3,3-dimethylbenzofuran-5-ester (benzofuran)瑞特 （卜 611 丨 11 ^ 5 & -te)), the paper size is in accordance with the Chinese National Standard (CNS) A 4 specifications (210 X 297 public)> 11 82.3. 40,000 A6 B6

B1 8) 2 —溴基一3 ，3 —二甲基一N - (1—甲 基_ 1 一苯基乙基）丁醯胺（溴布太得（b-B1 8) 2-Bromo-3,3-Dimethyl-N- (1-Methyl_1-Phenylethyl) butyramide (Brombutide (b-

B1 9) 1— （1_甲基一 1 一本基乙基）一3 —對 -甲苯基脲（達若因（dyraron)，達慕若因 (daimuron))， C ΗB1 9) 1— (1-Methyl-1, 1-benzylethyl) -3-P-tolylurea (dyraron, daimuron), C Η

0II -C-NH-C-NH CH τ0II -C-NH-C-NH CH τ

B 1 9 ) ----------------「-------裝------TT----「.Λ (請先閲讀背面之注意事項再塡寫本頁) B 2 0 ) N 2 - ( 1 ， 2 甲基丙基）一N4_乙基 經濟部中央標準局員工消費合作社印製 (B 2 0 6 -甲硫基一1 ，3 ，5 —三嗪—2 ，4 二胺（待美梭美摧（dimethametryn))， ch3 Η 3 C H-CH-CH(CH3)B 1 9) ---------------- `` ------------- TT ---- `` .Λ (Please read the notes on the back first Matters to be written on this page) B 2 0) N 2-(1, 2 Methylpropyl)-N4_ethyl Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (B 2 0 6-Methylthio-1, 3,5-triazine-2,4 diamine (to be dimethametryn), ch3 Η 3 C H-CH-CH (CH3)

T iTT iT

NH-CH,CH B21) 1 ，2_二甲基丙基（乙基）硫代胺甲酸 本紙張尺度適用中國國家標準（CNS〉甲4規格（210 X 297 ;釐） 12 82.3. 40,000 Α6 Β6 五、發明説明（IQ) S —苯甲酯（依斯普卡巴（esprocarb))， 0NH-CH, CH B21) 1, 2, 2-dimethylpropyl (ethyl) thiocarbamic acid This paper scale is applicable to the Chinese National Standard (CNS> A 4 specifications (210 X 297; PCT) 12 82.3. 40,000 Α6 Β6 Fifth, the description of the invention (IQ) S-benzyl ester (esprocarb), 0

CH2*S — C — NCH2 * S — C — N

II < c (B21 )II < c (B21)

CH-CH-CH B 2 2 ) 6 —甲氧基一2 —吡啶基（甲基）硫代胺甲 酸一 0 - 3 -第三丁基苯酯（吡日布太卡巴 (pyributicarb,TSH— 8 8 8 ) > ,c(ch3) (請先閲讀背面之注意事項再塡寫本頁)CH-CH-CH B 2 2) 6-Methoxy-2-pyridyl (methyl) thiocarbamic acid mono 0-3-tert-butylphenyl ester (pyributicarb, TSH-8) 8 8) >, c (ch3) (Please read the notes on the back before writing this page)

ch3 H3C〇y^N N-C-0 Sch3 H3C〇y ^ N N-C-0 S

B 2 2 ) c2hB 2 2) c2h

c2h 經濟部中央標準局員工消費合作社印*'衣 ：C = B 2 3 ) (Z) — N_ 丁一 2_烯氧基甲基一 2—氯 —2 — ，6 — -二乙基乙醯替苯胺（布坦那 克羅（butenachlor，KH - 2 1 8 )，c2h Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs *: Clothing = C = B 2 3) (Z) — N_ butan-2-enoxymethyl-2-chloro-2-, 6-diethylacetyl Aniline (butenachlor, KH-2 1 8),

,C0CH,C I B 2 3 ), C0CH, C I B 2 3)

H B 2 4 )二硫代磷酸_S — 2 _甲基哌啶基羰基甲酯 ，0，〇 —二丙酯（哌吡若福斯（p i p e Γ ο p -h o s ))， 本紙张尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 13 82.3. 40,000 五、發明説明（Π)HB 2 4) Dithiophosphoric acid _S — 2 _ methyl piperidinylcarbonyl methyl ester, 0, 〇- dipropyl ester (pipe pyrofos (pipe Γ ο p -hos)), the paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) 13 82.3. 40,000 V. Description of invention (Π)

0II0II

〇II A6 B6 N-C-CH2-S-P(OCH2CH2CH3)2 (B 2 4) CH3 B 2 5 )二硫代磷酸—S — 4 _氯基—N —異丙基苯 胺基甲醯基甲酯，Ο，0 —二甲酯（阿尼羅 福斯（anilofos))，〇II A6 B6 NC-CH2-SP (OCH2CH2CH3) 2 (B 2 4) CH3 B 2 5) dithiophosphoric acid-S-4 _ chloro-N-isopropylanilinyl methyl methyl, Ο, 0-Dimethyl ester (anilofos (anilofos)),

c Ic I

II II N-C-CH2-S-P(OCHj) I ch(ch3)2 (B25) B 2 6 ) (1RS，2SR，4SR)-1，4 -環 氧基—對—置一 2 —基2 —甲基苯甲基醚（ 西美喜里恩（cinmethylin))， C H . CH ,0 CH ch(ch3)2 0II II NC-CH2-SP (OCHj) I ch (ch3) 2 (B25) B 2 6) (1RS, 2SR, 4SR) -1,4-epoxy-p-set--2-yl-2-methyl Benzyl ether (cinmethylin), CH. CH, 0 CH ch (ch3) 2 0

(B 2 6 B2 7 ) N— ( 3，4 一二氯基苯基）丙醯胺（普潘 尼爾（propanil))， (請先閲讀背面之注意事項再塡寫本頁) 經濟部中央標準局員工消費合作社印製(B 2 6 B2 7) N— (3,4 dichlorophenyl) propionamide (propanil), (please read the precautions on the back before writing this page) Central Ministry of Economic Affairs Printed by the Bureau of Standards and Staff Consumer Cooperative

NHCOCH^CH (B27 ) B 2 8 )依唑舒呋柔（iraazosulfuron，TH — 9 1 3 82.3. 40,000 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） A6 B6 五、發明説明（12)NHCOCH ^ CH (B27) B 2 8) irazozosulfuron (iraazosulfuron, TH — 9 1 3 82.3. 40,000) This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) A6 B6 5. Description of the invention (12)

,Ν^ X I, Ν ^ X I

0II0II

OCH so2-nh-c-nhOCH so2-nh-c-nh

(B 2 8 )(B 2 8)

OCH B2 9 ) α —氯基一N— ( 3 —甲氧基一2— _嗯基 )甲基一2 ** ，6 > —二甲基乙醯替苯胺（ N S K - 8 5 0 )， (請先閲讀背面之注意事項再埙寫本頁)OCH B2 9) α —Chloro-N— (3 —Methoxy-2 -—_ umyl) methyl-1 2 **, 6 > —Dimethylacetanilide (NSK-8 5 0), (Please read the notes on the back before writing this page)

L B3 0) 4 —乙氧基苯一2 一 替苯胺（H W — 5 2 二氫基氯基醯 丨裝. Β 3 1 ) 1—二乙基胺甲醯基一3— (2 ，4 ，6- 三甲基苯基磺醯基）一 1 ，2 ，4 —***（ 訂_ C Η - 9 0 0 )，L B3 0) 4 —ethoxybenzene-2-substituted aniline (HW — 5 2 dihydrochlorochloro amide). Β 3 1) 1-diethylamine methyl acetyl 3-— (2,4, 6-trimethylphenylsulfonyl) -1,2,4-triazole (order_C Η-9 0 0),

SOSO

'N C〇H c2h Β 3 1 ) 經濟部中央標準局員工消費合作社印製'N C〇H c2h Β 3 1) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

0 II0 II

CH.-NH-C-NH-C-CH.-NH-C-NH-C-

Β3 2 ) 3— (2 —氯基苯基甲基）_1 — (1 —甲 基一1—苯基乙基）脲（JC— 9 4 0 )以 及， CH3 CH (B 3 2 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公货） 15 - 82.3. 40,000 A6 B6 五、發明説明（13) B 3 3 ) 2 - ( 2 -氯基 甲烷磺醯基苯醯基）Β3 2) 3— (2-chlorophenylmethyl) _1 — (1 —methyl-1-phenylethyl) urea (JC— 9 4 0) and, CH3 CH (B 3 2 This paper size is applicable China National Standard (CNS) A4 specifications (210 X 297 public goods) 15-82.3. 40,000 A6 B6 V. Description of the invention (13) B 3 3) 2-(2 -chloromethanesulfonyl phenyl phenyl acetyl)

環己烷一1 ，3 —二酮（ICIA 0 0 5 1Cyclohexane-1,3-dione (ICIA 0 0 5 1

SO,CH (B 3 3 烴濟部中央標準局貝工消費合作社印製 但是，有效含量之A綜合選自B1—B9 ，B1 4 — B1 6或B 2 8之唯一化合物B的除草劑除外。 化合物A(通式（I)化合物）已揭示於前面述及之 德國專利申請案中。 化合物B 1 ) — B 2 7 )係揭示於’The Pesticide Manual^ , British Crop Protection Council, 9th Ed. 1991; see Bl) 'quinchlorac^ , P· 749; B2) ^inoli-nate" , P· 5 9 4; B3) ' thiobencarb " , p. 815; B4) butachlor’，p. 106; B5) preti lachor , p . 6 9 9, B6) 'dithiopy〆，p. 321; B7) 'mefenacet’，p. 544 ;B 8 ) ' f e η o x a p r o p '，p . 3 7 4 ; B 9 ) ' d i m e p i p e r a t 〆， p. 289; BIO) ' pyrazo1ynate^ , P- 733; Bll) 'pyraz-oxyfen/r , p. 736; B12) 'bcnzofenap , p . 6 7; B13) ' naproani 1 ide^ , p. 610; B14) ' beηzosu1furοn - met-h y 1 ’，p . 6 2 ; B 1 5 ) ' p y r a z o s u 1 f u r ο n - e t h y 广，p _ 7 3 5 ;B16) ' ciηosu 1 furοn^ , p. 174; B17) ' benfuresate 58: B18) broraobutide Q 7 · R1Q、 '•'Haim- —裝------ir----!/ (請先M讀背面之注意事項再填寫本頁) 本紙张尺度適用中國國家標準（CNS)甲4规格（210 X 297公坌） 16 82.3. 40,000 ^οΰόόΐ Α6 _ Β6___ 五、發明説明（Η) (請先閲讀背面之注意事項再填寫本頁) u r ο η ' , ρ . 2 2 1 ; Β 2 Ο )、d i m e t h a m e t r y η ' , ρ . 2 9 1 ; Β 2 1 )esprocarb^ , ρ. 3 3 8, Β 2 2) ' pyributicarb^ ,. Ρ. 741; Β23) 'butenachior' , ρ. 108; Β24) 'piperophos ,ρ. 688; Β25) ^ a η i 1 ο f ο s ^ , ρ. 36; Β26) 'cininet-hylin^ , ρ. 173; Β27) 'propanil^ (SΤAM) , ρ 7150 化合物Β28)、依唑舒呋柔、（ΤΗ— 913)係 揭示於專利申請案ΕΡ — Α—0，2 3 8，0 7 0中。 化合物Β 2 9 )已知係爲NSK — 8 5 0且已由 Μ. Ogasawara et al.揭示於 'Weed Research’ ，（東京） ，：L989，131 — 137 頁。 化合物B 3 0 )已知係爲H W — 5· 2且已由N . I c h i -zen et a 1.揭不於 'Weed Research'，（東京）， 1990，261-267 頁。 化合物Β 3 1 )已知係爲CH— 9 0 0且已揭示於 EP — 332 ，133 中。 化合物B 3 2 )已知係爲J C — 9 4 0且已揭示於 J — 6 0 0 8 7 254 中 〇‘ 經濟部中央標準居员工消費合作社印製 最令人感興趣之本發明除草劑係爲包含上述通式（I )化合物或其鹽類之除草劑： a 1 ) R1示乙氧基，丙氧基或異丙氧基，以及 R2位於6 -位置上且具有上述意義，以及 η 示0或1，或者 a2 ) R1示任意不飽和Ci_C4 一烷氧基（其係經鹵原 子取代）’ Cl — C 4 —院氧基，Cl _ C 4 一焼 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） -17 ~ 82.3. 40,000 經濟部中央標準局負工消費合作社印製 A6 B6 五、發明説明（15) 硫基或一亞磺醢基或一磺醯基，（Ci— C4-烷氧基）羰基，N〇2，CN或苯基：還有C2 —C5 —烯氧基或（：2 — C4 —炔氧基，以及 R2 不 Cl— C4 —燒基，C2—C5 嫌基，（Cl_ c4 一烷氧基）羰基，Ci— C4 一烷氧基或Cl —c4 —烷硫基，其可各如上述取代，或鹵原 子，以及 η 示0或1，或者 as )Ri示甲氧基，乙基或丙基，以及 R2示6 —甲氧基羰基或6 -乙氧基羰基，以及 π 示1 ，以及 在所有ai) — & 3)之情況下， R 3 示氫原子，Cl — C4 一烷基，尤其是氫原子或甲基 R4和R5示鹵原子，Ca— C4 —烷基，Ci— C4 —烷氧基 或c i 一 c 4 一烷基硫基，前述後面3個基團係未經 取代或者經鹵原子，Ca-Cd —烷氧基或Ci— C4 ''烷基硫基取代， γ 示0或S，尤其是0， E 示CH或N，尤其是CH〇 類似地，飽和或不飽和烷基或烷氧基係爲直鏈或支鏈 焼基或焼氧基，鹵原子係爲F，Cj?，Br或I ，宜爲F 和C卜 通式（I )化合物可形成其內之一S〇2— NH —基 本紙張尺度適用中國國家標準（CNS)肀4规格（210 X 297公釐） 82.3. 40,000 -裝------訂---- (請先閱讀背面之注意事項再塡寫本頁) A6 B6 五、發明説明（16) 團之氫原子爲農業上適當之陽離子取代的鹽類。這些鹽類 通常係爲金屬鹽類，尤其是鹼金屬鹽，鹼土金屬鹽，任意 經烷化之銨鹽或有機胺鹽。 在上述化合物A和B通式中未詳細示出立體化學。若 其可能產生立體異構物，則通式涵括所有幾何異構物’對 掌異構物及非對映立體異構物及其混合物。化合物B 8 ) 涵括，尤其是，D -吩諾拉普-乙基（其係爲較理想的） 0 較理想之除草劑係包含通式A 1 ，A 2和A 3所示之 一或多種化合物作爲化合物A，其通式如下：SO, CH (B 3 3 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Hydrocarbon Economy. However, the effective content of A is selected from the herbicides of the only compound B comprehensively selected from B1 to B9, B1 4 to B1 6 or B 2 8. Compound A (compound of general formula (I)) has been disclosed in the aforementioned German patent application. Compound B 1) — B 2 7) is disclosed in 'The Pesticide Manual ^, British Crop Protection Council, 9th Ed. 1991 ; see Bl) 'quinchlorac ^, P · 749; B2) ^ inoli-nate ", P · 5 9 4; B3)' thiobencarb ", p. 815; B4) butachlor ', p. 106; B5) preti lachor , p. 6 9 9, B6) 'dithiopy〆, p. 321; B7)' mefenacet ', p. 544; B 8)' fe η oxaprop ', p. 3 7 4; B 9)' dimepiperat 〆, p .289; BIO) 'pyrazo1ynate ^, P- 733; Bll)' pyraz-oxyfen / r, p. 736; B12) 'bcnzofenap, p. 6 7; B13)' naproani 1 ide ^, p. 610; B14) 'beηzosu1furοn-met-h y 1', p. 6 2; B 1 5) 'pyrazosu 1 fur ο n-ethy wide, p _ 7 3 5; B16)' ciηosu 1 furοn ^, p. 174; B17) ' benfuresate 58: B18) broraobutide Q 7 · R1Q, '•' Haim- —installed ------ ir ----! / (Please read the notes on the back before M fill in this page) This paper standard is applicable to China National Standard (CNS) A 4 Specifications (210 X 297 gong) 16 82.3. 40,000 ^ οΰόόΐ Α6 _ Β6 ___ V. Description of invention (Η) (Please read the precautions on the back before filling this page) ur ο η ', ρ. 2 2 1; Β 2 Ο), dimethametry η ', ρ. 2 9 1; Β 2 1) esprocarb ^, ρ. 3 3 8, Β 2 2)' pyributicarb ^,. Ρ. 741; Β23) 'butenachior', ρ. 108; Β24 ) 'piperophos, ρ. 688; Β25) ^ a η i 1 ο f ο s ^, ρ. 36; Β26)' cininet-hylin ^, ρ. 173; Β27) 'propanil ^ (SΤAM), ρ 7150 compound Β28 ), Eczosulfurol, (ΤΗ-913) is disclosed in the patent application EP-Α-0, 2 3 8, 0 7 0. Compound B 2 9) is known to be NSK-8850 and has been disclosed by M. Ogasawara et al. In 'Weed Research', (Tokyo): L989, pages 131-137. Compound B 3 0) is known to be H W — 5.2 and has been disclosed by N. I c h i -zen et a 1. 'Weed Research', (Tokyo), 1990, pages 261-267. Compound B 3 1) is known to be CH-900 and has been disclosed in EP-332, 133. Compound B 3 2) The known system is JC-9 4 0 and it has been disclosed in J-6 0 0 8 7 254. The most interesting herbicide system of the present invention is printed by the Central Standard Residence Consumer Cooperative of the Ministry of Economic Affairs. Is a herbicide containing the compound of the above general formula (I) or a salt thereof: a 1) R1 represents ethoxy, propoxy or isopropoxy, and R2 is located at the 6-position and has the above meaning, and η represents 0 or 1, or a2) R1 means any unsaturated Ci_C4 monoalkoxy group (which is substituted by halogen atom) 'Cl — C 4 —homooxy group, Cl _ C 4 — the standard of this paper is applicable to China National Standard (CNS ) A4 specifications (210 X 297 mm) -17 ~ 82.3. 40,000 Printed A6 B6 by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention (15) Sulfur or a sulfinyl or a sulfonyl group , (Ci-C4-alkoxy) carbonyl, N〇2, CN or phenyl: there are C2-C5-alkenyloxy or (: 2-C4-alkynyloxy, and R2 is not Cl-C4-alkyl , C2-C5 alkoxy, (Cl_c4-alkoxy) carbonyl, Ci-C4-alkoxy or Cl-c4-alkylthio, which can be substituted as described above, or halogen And η represents 0 or 1, or as) Ri represents methoxy, ethyl or propyl, and R2 represents 6-methoxycarbonyl or 6-ethoxycarbonyl, and π represents 1, and in all ai ) — &Amp; 3), R 3 represents a hydrogen atom, Cl — C4 monoalkyl, especially a hydrogen atom or methyl R4 and R5 represent a halogen atom, Ca— C4 —alkyl, Ci— C4 —alkoxy Group or ci-c 4 -alkylthio group, the last three groups above are unsubstituted or substituted by halogen atom, Ca-Cd-alkoxy or Ci-C4 ”alkylthio group, γ shows 0 or S, especially 0, E represents CH or N, especially CH. Similarly, a saturated or unsaturated alkyl or alkoxy system is a linear or branched alkyl group or an alkoxy group, and a halogen atom system is F, Cj ?, Br or I, preferably F and C. Compounds of general formula (I) can form one of them. S〇2—NH — The basic paper scale is applicable to the Chinese National Standard (CNS) Y4 specification (210 X 297 mm) 82.3. 40,000-Installed -------- Ordered (please read the precautions on the back before writing this page) A6 B6 5. Description of the invention (16) The hydrogen atom of the group is replaced by an appropriate cation in agriculture Salt. These salts are usually metal salts, especially alkali metal salts, alkaline earth metal salts, any alkylated ammonium salts or organic amine salts. The stereochemistry is not shown in detail in the general formulae of compounds A and B above. If it is possible to produce stereoisomers, the general formula encompasses all geometric isomers' diisomers and diastereoisomers and mixtures thereof. Compound B 8) includes, in particular, D-phenolap-ethyl (which is more desirable) 0 The more desirable herbicides include one of the general formulas A 1, A 2 and A 3 or A variety of compounds as compound A, its general formula is as follows:

OC,HOC, H

OCH (請先閲讀背面之注意事項再塡寫本頁) -0S0,-NH-C0-NH —(7 (A1 ) 丁OCH (Please read the notes on the back before writing this page) -0S0, -NH-C0-NH — (7 (A1) Ding

OCHOCH

OCH(CH3)2 OSO,-NH-CO-NHOCH (CH3) 2 OSO, -NH-CO-NH

OCHOCH

(A2 經濟部中央標準局員工消費合作社印製(A2 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

OCHOCH

(A3 )(A3)

OCHOCH

OCH oso2-nh-co-nh—OCH oso2-nh-co-nh—

CO-OCH, OCH 可提及之所申請專利的活性物質混合物之特定實例係 如下所列，但其並非用以限制本發明之範圍： A 1 +吡唑列特+美吩那西特 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） _ 19 ** 82.3. 40,000 A6 B6 五、發明説明（17) #+吡唑列特+美吩那西特+達若因 #+吡唑列特+美吩那西特+待美梭美摧 '+吡唑列特+依斯普卡巴 #+吡唑列特+依斯普卡巴+達若因 # +吡唑列特+依斯普卡巴+待美梭美摧 #+吡唑列特+苯卩塞卡巴 #+吡唑列特+苯卩塞卡巴+達若因 #+吡唑列特+苯卩塞卡巴+待美梭美摧 #+吡唑列特+待美吡瑞特 #+吡唑列特+待美吡瑞特+達若因 A 1 +吡唑列特+待美吡瑞特+待美梭美摧 " +吡唑列特+ T S Η 888 〃 +吡唑列特+ T S Η 8 8 8 +達若因 # +吡唑列特+TSH 888+待美梭美摧 # + D 比哩列特 + τη ο 1 i n a t e # +吡唑列特+ m ο 1 i n a t e +達若因 " +吡唑列特+ m 〇 1 i n a t e +待美梭美摧 # +Dtt哩列特 + pretilachlor ' +吡唑列特+ p r e t i 1 a c h 1 o r +達若因 # +吡唑列特+ p r e t i 1 a c h 1 o r +待美梭美摧 ' +吡唑列特+ b u t a c h 1 o r " +吡唑列特+ b u t a c h丨o r +達若因 " +吡唑列特+ b u t a c h 1 g r +待美梭美摧 ' +吡唑列特+ N S K 850 (請先閲讀背面之注意事項再填寫本頁) -裝. 訂· 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 20 82.3. 40,000 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明（18) # +吡唑列特+NSK 850+達若因 # +吡唑列特+NSK 8 5 0+待美梭美摧 # +吡唑列特+ K Η 2 1 8 # +吡唑列特+ΚΗ218+達若因 # +吡唑列特+ΚΗ218+待美梭美摧 # +吡唑列特+ C Η 9 0 0 # +吡唑列特+ C Η 9 0 0 +達若因 " +吡唑列特+ C Η 9 0 0 +待美梭美摧 "+吡唑列特+吩諾拉普一乙基 "+吡唑列特+吩諾拉普一乙基+達若因 A 1 +吡唑列特+吩諾拉普一乙基+待美梭美摧 # +吡唑列特+二硫吡 # +吡唑列特+二硫吡+達若因 <+吡唑列特+二硫吡+待美梭美摧 #+吡唑列特+阿尼羅福斯 '+吡唑列特+阿尼羅福斯+達若因 <+吡唑列特+阿尼羅福斯+待美梭美摧 #+苯呋瑞特+美吩那西特 # +苯呋瑞特+美吩那西特+達若因 #+苯呋瑞特+美吩那西特+待美梭美摧 " +苯呋瑞特+依斯普卡巴 〃+苯呋瑞特+依斯普卡巴+達若因 " +苯呋瑞特+依斯普卡巴+待美梭美摧 #+苯呋瑞特+苯卩塞卡巴 (請先閏讀背面之注意事項再瑣寫本頁) .裝. 訂 本紙張又度適用中國國家標準（CN’S)甲4规格（210 X 297公釐） 21 82.3. 40,000 經濟部中央標準局員工消費合作社印製 Α6 _Β6_ 五、發明説明（19) " +苯呋瑞特+苯睡卡巴+達若因 " +苯呋瑞特+苯_卡巴+待美梭美摧 ， +苯呋瑞特+待美吡瑞特 " +苯呋瑞特+待美吡瑞特+達若因 " +苯呋瑞特+待美吡瑞特+待美梭美摧 " +苯呋瑞特+TSH 888 " +苯呋瑞特+TSH 888+達若因 H +苯呋瑞特+TSH 888+待美梭美摧 " +苯呋瑞特+莫里那特 ” +苯呋瑞特+莫里那特+達若因 A 1 +苯呋瑞特+莫里那特+待美梭美摧 嫌 +苯呋瑞特+普呔克羅 H +苯呋瑞特+普呔克羅+達若因 κ +苯呋瑞特+普呔克羅+待美梭美摧 ” +苯呋瑞特+布它克羅 歸 +苯呋瑞特+布它克羅+達若因 " +苯呋瑞特+布它克羅+待美梭美摧 " +苯呋瑞特+NSK 850 " +苯呋瑞特+NSK 850+達若因 Μ +苯呋瑞特+NSK 850+待美梭美摧 ， +苯呋瑞特+ΚΗ218 ” +苯呋瑞特+ΚΗ218+達若因 " +苯呋瑞特+ΚΗ218+待美梭美摧 " +苯呋瑞特+CH9 0 0 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） '22 - 82.3. 40,000 (請先閲讀背面之注意事項再塡寫本頁) .裝. 訂· A6 B6 五、發明説明（2Q) 經濟部中央標準局員工消費合作社印製 23 - +苯呋瑞特+CH9 0 M +苯呋瑞特+CH9 0 • +苯呋瑞特+吩諾拉普 • +苯呋瑞特+吩諾拉普 • +苯呋瑞特+吩諾拉普 • +苯呋瑞特+二硫吡 _ +苯呋瑞特+二硫卩比+ • +苯呋瑞特+二硫卩比+ " +苯呋瑞特+阿尼羅福 " +苯呋瑞特+阿尼羅福 A 1 +苯呋瑞特+阿尼羅福 本發明之除草劑具有對 葉及雙子葉有害植物的傑出 有效作用於從根莖，砧木或 控制的多年生雜草。在本文 前或萌芽後方法施用均可。 用本發明除草劑控制之某些 實例而非列舉以供用爲某些 除草劑有效作用之雜草 之燕麥屬，毒麥屬，看麥娘 粟屬以及一年生莎草屬，和 屬，狗牙根屬，白茅屬和高 在雙子葉雜草之例子中 本紙張尺度適用中國國家標準（CN’S)甲4規格（210 X 297 〇 +達若因 0 +待美梭美摧 —乙基 —乙基+達若因 一乙基+待美梭美摧 達若因 待美梭美摧 斯 斯+達若因 斯+待美梭美摧 抗廣大範圍經濟上重要的單子 除草活性。活性物質混合物亦 其他多年生器官產生芽且難以 中，物質係利用種植前，萌芽 更詳細而言，所提及的是可利 代表性單子葉及雙子葉雜草系 種類之限制範圍。 種類實例係爲單子葉植物範圍 屬，草蘆屬，稗屬，馬唐屬， 在多年生雜草範圍內之小麥草 梁屬與多年生莎草屬。 ，作用範圍擴及，諸如，豬殃 82.3. 40,000 (請先閲讀背面之注意事項再塡寫本頁) i裝. 訂· 經濟部中央標準局貝工消費合作社印製 A6 B6_ 五、發明説明（21) 殃屬，堇菜屬，水苦賛屬，野芝麻屬，繁縷屬，莞屬，白 芥靥，牽牛屬，加密列花屬，苗麻屬及一年生許花屬，及 多年生雜草例子中之三色璇花屬，薊屬，酸模屬和艾屬。 本發明之活性物質混合物對在稻子成長之特定條件下 產生之雜草（例如，慈姑屬，水澤瀉屬，荸薺屬，莞屬及 莎草屬）同樣產生優異的控制作用。 經濟上重要之單子葉雜草（例如，看麥娘（Alopecu-rus myosuroides)，燕麥（Avena fatua)，稗（Echin-ochlcia crus-galli)及粟（Setaria uiridis))係在玉 米及稻子成長之特定條件下受控制。 若本發明之除草劑係在萌芽前施於土壤表面，則可完 全抑制雜草幼苗萌生，或者雜草長至子葉階段即停止成長 ，且在3—4週之後完全死掉。 若活性物質混合物係利用萌芽後方法施加至植物之綠 色部份，則在處理後極短時間內雜草植物明顯地停止成長 而保持在施加該劑時之成長階段，或者在某一時間內迅速 死亡，因此，依此方式，有害於作物植物之雜草競爭作用 因施用本發明之新穎除草劑而在極早階段且以持續方式消 除。 雖然本發明之除草劑對單子葉及雙子葉雜草具有傑出 的除草活性，但經濟上重要作物之作物植物（例如，小麥 ，大麥，裸麥，稻子及玉米）欲僅受到可予忽略程度之傷 害或者一點都不受到傷害。基於這些理由，此等除草劑是 極適供選擇性控制農業用途之種植中不想要植物的成長。 本紙張尺度適用中國@家標準（CNS)甲4规格（210 X 297公货） '24 * 82.3. 40,000 (請先閲讀背面之注意事項再填寫本頁) —裝· 訂. 經濟部中央標準局興工消費合作社印5衣 A6 _____B6_ 五、發明説明（22) 本發明之活性物質混合物可獲致超乎各成份之加成作 用預期値的除草活性。此一較高之活性使得各活性物質之 施用比値可以大大降低◊此外，混合物之作用期間可經加 長或者據發現作用速率提高。本發明活性物質混合物之有 利性質在當實際控制雜草時是相當有利於使用者的，因爲 它們可更經濟，或者更迅速地，或者以更緩釋之方式控制 雜草而使獲致較高產量之作物植物。 此外，吾人已發現本發明之活性物質混合物具有顯著 的安全劑或解毒劑作用，亦即，用於作物植物（諸如，稻 子）中之活性物質的植物毒性二度作用係經減低或完全避 免。安全劑達若因（化合物B19)和JC 一 940 (化 合物B 3 2 )是最令人感興趣的。 A : B混合比値可在廣闊限制範圍內變化而原則上， 在二成份混合物之情況下是介於2 : 1 — 1 : 2 0 0間， 因此，在三成份或四成份混合物（活性物質A以及二或三 種活性物質B)之情況下係介於2:1:1，或2 :1: 1:1 至 1:200:200，或 1:200:200: 2 0 0之間。混合比値之選擇係依混合物中之成份，雜草 之發展階段，雜草範圍及氣候條件而定。 混合比値1 : 1 — 1 : 1 〇 〇 (在二成份混合物之情 況下），以及介於1:1:1，或1:1:1:1至1: 100:100，或 1:100 :100:100 (在三 成份或四成份混合物之情況下）爲較理想。活性物質混合 物中除草劑A之施用比値宜介於1 〇和1 0 0 g/h a之 本紙張尺度適用中國國家標準（CMS)甲4规格（210 X 297公釐) -25 - 82.3. 40,000 (請先閲讀背面之注意事項再填寫本頁) 丨裝. 訂. 2〇(ό^ό1 經濟部中央標準局兵工消費合作社印製 Α6 Β6 五、發明説明（23) 間，而B之施用比値係介於0 · 0 2和4 . Okg/ha之 間。 最適當之重量比値可以系統試驗法（systematic trials) 決定 。當使用達若因作爲安全劑時， 適當之重量比 値係爲 1 : 0 · 1 — 1 : 50 ，宜爲 1 : 1 — 1 : 30 ， 尤其是 1:10 — 1:30。 本發明之活性物質混合物可以二成份之混合組成物形 態存在，其再依傳統方式，於用水稀釋後施用，或爲用水 共同稀釋分別調製之各成份的所謂槽式混合物（tank mixers) 。 化合物 A 或 B 或其混合物可 以多種方式而依現行 生化和/或物化參數調配。因此，下列可能性是爲適當之 組成物：可濕化粉（\V P )，水溶性粉末（S P )，水溶 性濃縮體，可乳化濃縮體（E C )，水溶液（S L )，乳 液（E W )，諸如，油在水中型及水在油中型乳液，可噴 灑粉未或乳液，以油或水爲底質之分散液，懸浮濃縮體（ S C )，（超乳液），油相容性溶液，膠囊懸浮液（C S )，撒佈粉劑，包種劑，土壤施用或撒播用顆粒，微顆粒 ，噴灑顆粒，包覆顆粒及吸附顆粒形態之顆粒（G R )， 水溶液顆粒（S G )，水分散性顆粒（W G ) ，U L V組 成物，微膠囊或蜡。 這些各種類組成物原則上係屬已知且揭示於，例如： Winnacker-Kiichler, Chemische Technologies C Chemical Technology〕，Volume 7, C . Hauser Verlag M u -nich, 4th Ed. 1986; van Valkenburg, 'Pesticides F- 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公；ϊ ) " 26 _ 82.3. 40,000 (請先閲讀背面之注意事項再塡寫本頁) 丨裝· 訂· 經濟部中央標準局员工消費合作社印製 A6 B6 五、發明説明（24) 〇rmu 1 atiοns^ , Marcel Dekker Η. Y., 2nd Ed. 1 972 -73; K. Martens, 'Spray Drying Handbook^ , 3rd Ed. 1979, G. Goodwin Ltd. London0 所需調配組成物（諸如，惰性物質，界面活性劑，溶 劑及其他添加劑）同樣係屬已知且揭示於，例如：Watkins, 'Handbook of Insecticide Dust Diluents and C-arriers^ , 2nd Ed., Darland Books, Caldwell N.J.; H . v . 0 1 p h e n, 'Introduction to Clay Colloid Chemist r y * ,2nd Ed., J. Wiley Sons, N.Y., Marsden, ' Solvents Guide’ ， 2nd Ed., Interscience, N.Y. 1950 ;McCutcheon’s, ' Detergents and Emulsifiers A η n u-a 1 ^ , MC Publ. Gorp., Ridgewood N.J.; Sisley and Wood, Encyclopedia of Surface Active Agents', Chera. Publ. Co, Inc., Η. Y. 1964; Schonfeldt, Gre-nzf 1 achenaktive fithy1enoxidaddukte^ (Surface-active Ethylene Oxide Adducts) , Wiss. Ver 1 agsgese 11. ,Stuttgart 1 976; W i η n a c k e r - Kli c h 1 e r , Chemische Technologies (Chemical Technology) , Volume 7, G. Hauser Verlag Munich, 4th Ed. 19860 亦可根據這些組成物製備與其他殺害蟲活性物質（諸 如，其他除草劑，殺黴菌劑或殺昆蟲劑）之混合物，例如 ，已混合（readymix)或槽式混合（tank mix)形態。 可濕化粉末係爲可均句分散於水中之組成物且其除了 活性物質之外還包含離子性和/或非離子性界面活性劑（ 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） -27 ~ 82.3· 40,000 (請先閱f面之注意事項再塡寫本頁) 丨裝· 訂 A6 B6 五、發明説明（25) 潤濕劑，分散劑），例如，聚連氧乙基化烷基酚，聚連氧 乙基化脂肪醇或脂肪胺，脂肪醇聚乙二醇醚硫酸鹽，烷基 礎酸鹽，烷基苯磺酸鹽，木質磺酸鈉，2，2，一二棻基 甲烷一6，6 — -二磺酸鈉，二丁基棻磺酸鈉或油基甲基 牛磺酸鈉，以及稀釋劑或惰性物質。爲了製備可濕化粉末 ，除草活性物質經精細碾磨，例如，在傳統裝置（諸如， 植式磨機，吹式磨機及空氣噴射式磨機）中碾磨，同時或 者隨後和調配輔助劑混合。 可乳化濃縮體係由溶解活性物質於有機溶劑（例如， 丁醇，環己酮，二甲基甲醯胺，二甲苯或較高沸點之芳烴 或烴類，或有機溶劑之混合物）中，且加入一或多種離子 性和/或非離子性界面活性劑（乳化劑）而製成。例如， 下列各者可被用爲乳化劑：烷基芳基磺酸鈣，諸如，十二 烷基苯磺酸鈣，或非離子性乳化劑，諸如，脂肪酸聚乙二 醇酯，烷基芳基聚乙二醇醚，脂肪醇聚乙二醇醚，聚環氧 丙烷/環氧乙烷縮合產物，烷基聚醚，山梨糖醇酐脂肪酸 醋，聚連氧伸乙基山梨糖醇酐脂肪酸酯或聚連氧伸乙基山 梨糖醇酯。 撒佈粉劑係由碾磨活性物質及微細分離之固態物質（ 例如，滑石粉，天然粘土，諸如，高嶺土，膨脹土及葉错 石，或矽藻土）而製成。 懸浮濃縮體可以水或油爲底質。它們可由，例如，利 用商售珠磨機濕式碾磨，且若適當的話，加入，例如，在 其他形態組成物之情況中已述及之界面活性劑。 (請先閲讀背面之注意事項再填寫本頁) i裝- 訂. 經濟部中央標準局貝工消費合作社印製 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公釐） 28 - 82.3. 40,〇〇〇 A6 B6 五、發明説明（26) (請先閲讀背面之注意事項再項寫本頁) 乳液（例如，油在水中型乳液（E W ))可由，例如 ，利用撹拌器，膠體磨機和/或靜電混合器，使用水性有 機溶劑，以及，若適當的話，例如，在其他形態組成物之 情況下已述及之界面活性劑製成。 顆粒可由噴灑活性物質至吸附性，粒化惰性物質上而 製成或者塗布活性物質濃縮體至載體（諸如，砂子，高嶺 土或粒化惰性物質（利用膠粘劑，例如，聚乙烯醇，聚丙 嫌酸鈉或礦物油）上而製成。適當活性物質亦可依製備肥 料顆粒之傳統方式粒化，若需要的話，製爲和肥料之混合 物0 原則上，水可分散性顆粒係由傳統方法（諸如，噴霧 乾燥，流體床粒化，碟式粒化，利用高速混合器混合及不 含固態惰性物質之擠壓而製成。 原則上，農業化學組成物包含0 . 1 — 9 9重量％， 尤其是2 — 9 5重量％活性物質A或B。 組成物中之活性物質A和B濃度可不相同。 在可濕化粉末中，例如，活性物質濃度約爲1 0 — 經濟部中央標準局8工消費合作社印製 9 5重量％，至1 0 0重量％之其餘成份係由傳統調配成 份所組成。在可乳化濃縮體之情況下，活性物質濃度可爲 約1一 8 5重量％，宜爲5 - 8 0重量％。撒佈粉劑形態 之組成物包含約1 _ 2 5重量％，大多數爲5 — 2 0重量 %活性物質，可噴灑溶液包含約0 · 2 — 2 5重量％，宜 爲2 — 2 0重量％活性物質。在顆粒（諸如，水可分散性 顆粒）之情況下，活性物質含量部份係依活性化合物是爲 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公釐） 29 82.3. 40,000 經濟部中央標準局貝工消費合作社印製 A6 B6__ 五、發明説明（27) 液態或固態形態以及使用何種粒化輔助劑及塡料而定。原 則上，水可分散性顆粒包含1 〇 — 9 0重量％活性物質。 此外，上述活性物質組成物若適當的話還包含膠粘劑 ，潤濕劑，分散劑，乳化劑，滲透劑，防腐劑，抗冷凍劑 ，溶劑，塡料，載體，色科，抗起泡劑，蒸發抑制劑及 pH —和粘度調節劑（其在每一例子中均係傳統的）。 使用時，商售形態之組成物（若適當的話），依傳統 方式，例如，用水（在可濕化粉末，可乳化濃縮體，分散 液及水可分散性顆粒之情況下）稀釋。撒佈粉劑，土壤施 用或撒播形態組成物以及可噴灑溶液傳統上在使用前未再 使用任何其他惰性物質稀釋。. 通式（I )化合物之所需施用比値依外在條件（諸如 ，溫度，濕度及所用除草劑本質而變。 以下實例係供說明本發明： A ·調配實例 a )撒佈粉劑係由混合1 0重量份數本發明之活性物 質混合物以及9 0重量份數滑石粉（作爲惰性物質）且於 槌式磨機中碾碎混合物而製成。 b )可濕化粉末（其易於分散於水中）係由混合2 5 重量份數之活性物質A + B，6 4重量份數包含石英之高 嶺土（作爲惰性物質），1 0重量份數木質磺酸鉀及1重 量份數油基甲基牛磺酸鈉（作爲潤濕劑和分散劑）且於尖 碟式磨機中碾磨混合物而製成。 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） _ 30 _ 82.3. 40,000 (請先閲讀背面之注意事項再填寫本頁) •裝_ 訂. 經濟部中央標準局8工消費合作社印製 A6 B6_______ 五、發明説明（28) C)分散性濃縮體（其可輕易分散於水中）可由混合 2 0重量份數烷基酚聚乙二醇醚（©Triton X 207) ，3 重量份數異十三烷醇聚乙二醇醚（8 EO)及71重量 份數石蜡性礦物油（沸點範圍，例如，約2 5 5至高於 2 7 7 °C)且於球磨機中碾磨混合物至細度小於5微米而 製成。 d) 可乳化濃縮體係由15重量份數活性物質A+B ，7 5重量份數環己酮（作爲溶劑）及1 〇重量份數連氧 乙基化壬基酚（作爲乳化劑）而製成。 e) 水可分散性顆粒係由混合 7 5重量份數活性物質A + B， 1 0重量份數木質磺酸鈣， 5重量份數月桂基硫酸鈉， 3重量份數聚乙烯醇，以及 7重量份數高嶺土， 在尖碟式磨機中碾磨混合物及在流體床中，藉由噴灑水（ 作爲粒化液體）以粒化粉末而製成。 f )水可分散性顆粒亦由均化及預先碾碎（在膠體磨 機中）： 2 5重量份數活性物質A + B， 5重量份數2 ，2 / —二某基甲烷—6 ’ 6 二磺酸 鈉， 2重量份數油基甲基牛磺酸鈉，. 1重量份數聚乙二醇， 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公釐） -31 _ 82.3. 40,000 ---------------「-------裝------ΤΓ---- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局R工消費合作社印製 A6 B6 五、發明説明（29) 1 7重量份數碳酸鈣，以及 5 0重量份數水， 其後，在珠磨機中碾磨混合物且於噴灑塔中，利用單一物 質噴嘴霧化及乾燥所得懸浮液而製成。 g )可濕化粉末係由混合3重量份數活性物質A， 3 0重量份數活性物質B，3重量份數木質磺酸鈉，6 3 重量份數包含石英之高嶺土及1重量份數二辛基磺基琥珀 酸鈉，再碾磨混合物而製成。 h )顆粒係由混合 0 ·1重量份數活性物質A， 1 · 5重量份數活性物質B， 0 · 5重量份數新克醇（neochol)， 3 5 重量份數膨潤土及 6 2 . 9重量份數滑石粉， 在尖碟式磨機中碾磨混合物且於流體床中粒化粉末而製成 生化實例： 1 ·對雜草之萌芽前作用： 單子葉及雙子葉雜草植物之種子或塊莖部份植入直徑 9公分之塑膠缽內的壤質砂土中且覆以土壤。在稻子栽培 中發現之雜草在漬水土壤中成長，缽中塡入水而使其數量 爲高出土壤表面或泛濫幾毫米。本發明之活性物質混合物 本纸張尺度適用中國國家標準（CNS)甲4规格（210 X 297公釐） _ 32 - 82.3. 40,000 (請先閲讀背面之注意事項再填寫本頁) -丨裝_ 訂. • 17^. 經濟部中央標準局8工消費合作社印製 A6 ____B6 五、發明説明（30) (可濕化粉末或乳液濃縮體），以及對照試驗用之對應經 調配各別活性物質再以6 0 0 — 8 0 0升水/h a (經換 算）之施用比値，在不同劑量比値下以水性懸浮液或乳液 形態施加至土壤覆蓋表面上，或者，在稻子之例子中，傾 入灌漑水中。 處理之後，將各缽放在溫室中且保持在雜草之優良成 長條件下。在測試植物已於3 — 4週之測試期間後萌芽之 後，以肉眼評估對植物之傷害或對萌芽之負作用（和未經 處理對照組比較）。本發明之除草劑對廣範圍之草本科雜 草及雙子葉雜草具有優異的萌芽前除草作用。 在所4有情況下獲得化合物之理論及實測活性値差異。 混合物之理論活性値（其可依理論預測）係由S.R. Col b-y公式決定：Calculation of synergistic and antagonistic responses of herbicide combinations, Weeds 15，20-22 頁（1967) 〇 在二成份混合物之情況下，此一公式係爲：CO-OCH, OCH can mention the specific examples of the patented active substance mixture listed below, but it is not used to limit the scope of the present invention: A 1 + pyrazolate + mephenacitide paper The scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) _ 19 ** 82.3. 40,000 A6 B6 V. Description of the invention (17) # + pyrazolate + Mephenacitide + Daryne # + Pyrazolide + Mephenacitide + Pomezolide + Pyrazolide + Isprokaba # + Pyrazolide + Isprokaba + Darroin # + Pyrazolide + Isipababa + Pomexamate # + Pyrazolide + Benzocelcarba # + Pyrazolide + Penzocelka + Darroine # + Pyrazolide + Penzocelkab + Pai Mezomethrin # + pyrazolate + Pomeziride # + Pyrazolide + Pomeziride + Darroin A 1 + Pyrazolate + Pomeziride + Pomezine湯 " + pyrazolate + TS Η 888 〃 + pyrazolate + TS Η 8 8 8 + daruoin # + pyrazolate + TSH 888+ 待 美 索 美 灭 # + D Bimilet + τη ο 1 inate # + pyrazolate + m ο 1 inate + darone " + pyrazolate + m 〇1 inate + Mesometa ## + Dtt Milet + pretilachlor '+ pyrazolide + preti 1 ach 1 or + daruoin # + pyrazolide + preti 1 ach 1 or + to be mesomethadone + pyrazole Leter + butach 1 or " + pyrazolate + butach 丨 or + daruo " + pyrazolate + butach 1 gr + to be mesomethadone + pyrazolate + NSK 850 (please first Read the precautions on the back and then fill out this page)-Binding. Order · Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size is applicable to China National Standards (CNS) Grade 4 (210 X 297 mm) 20 82.3. 40,000 Economy A6 B6 printed by the Employees ’Consumer Cooperative of the Central Standards Bureau of the Ministry of Education V. Description of the invention (18) # + Pyrazolide + NSK 850 + Daruin # + Pyrazolide + NSK 8 5 0+ 待 美 索 美 灭 # + Pyrazolide + K Η 2 1 8 # + Pyrazolide + ΚΗ218 + 达 若因 # + Pyrazolide + ΚΗ218 + 待 美 索 美 灭 # + Pyrazolide + C Η 9 0 0 # + Pyrazole Leter + C Η 9 0 0 + Darroin " + pyrazolate + C Η 9 0 0 + Tomemethoxazole " + pyrazolate + fenolap monoethyl " + pyridine Zoletide + phenolap monoethyl + da Ruoin A 1 + pyrazolate + phenolap monoethyl + tometazole # + pyrazolide + dithiopyr # + pyrazolide + dithiopyr + darone < + Pyrazolide + dithiopyridine + Tolmethoxazole # + Pyrazolide + Anirofus + Pyrilide + Anirofus + Darroin < + Pyrazolide + Anilofos + to be mesmerized # + benfurate + mephenacitide # + benfurate + mephenacit + darone # + benfurate + mephenacil Special + Tomomethoxime " + Benfurate + Ispucarba + Benfurate + Ispucarba + Darroin " + Benfurate + Ispucarba + Tomezo Meizhuang # + Benfurate + Benzoxacaba (please read the precautions on the back before writing this page). Packed. The printed paper is also applicable to China ’s National Standard (CN'S) Grade 4 (210 X 297 Mm) 21 82.3. 40,000 Printed Α6 _Β6_ by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (19) " + benzofurate + benzene sleeping carba + daruoin " + benzofurate + benzene _Kaba + Pomezolate, + Benfurate + Pomepirate " + Penfurate + Pomepirate + Darroin " + Benfurate + Pomepirate + Pomezolide " + Benfurate + TSH 888 " + Benfurate + TSH 888 + Darroin H + Benfurate + TSH 888 + Pomezolate " + Benfurate + Molinate ”+ Benfurate + Molinate + Darin A 1 + Benfurate + Molinate + Pomezide Detoxification + Benfurate + Promethol H + Benfurate + Promethol + Daroine κ + Benfurate + Promethol + Pomegranate ”+ Benfurate + Butacrostat + benfurate + butacrot + daruoin " + benfurate + butacro + bemetamethol " + benfurate + NSK 850 " + Benfurate + NSK 850 + Darroin M + Benfurate + NSK 850 + Pomezide, + Benfurate + ΚΗ218 ”+ Benfurate + ΚΗ218 + Darin " + Benzene Furret + ΚΗ218 + Pomezine + quot; + Benfurate + CH9 0 0 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) '22-82.3. 40,000 (please first Read the precautions on the back and then write this page). Packing. Ordering · A6 B6 V. Description of Invention (2Q) Printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs 23-+ Benfurate + CH9 0 M + Benfurate + CH9 0 • + Benfurate + Fenopram • + Benfurate + Fenoprap • + Benfurate + Fenoprate Lapp • + Benfurate + Dithiopyridine + + Benfurate + Disulfide ratio + • + Benfurate + disulfide ratio + " + Benfurate + Anilofol " + Benfurate + Anirofol A 1 + Benfurate + Anirofol The herbicide of the present invention has an outstanding and effective effect on harmful plants of leaves and dicotyledons from roots, rootstocks or controlled perennial weeds. The method can be applied before or after germination. Some examples of weed control by the herbicides of the present invention are not listed as oats, weeds, trichosporium and annual sedge, and genus bermudagrass for weeds that are effective for certain herbicides. In the case of dicotyledonous weeds, the paper scales are in accordance with the Chinese National Standard (CN'S) A 4 specifications (210 X 297 〇 + daryne 0 + to be mesomethine-ethyl-ethyl + da Rhythm monoethyl + Domethomethoxazole Dynomyx Methomethoxone + Daromethoxazole + Domethomethoxazole is resistant to a broad range of economically important monad herbicidal activities. The active substance mixture is also used in other perennial organs It is difficult to produce buds, the material system is used before planting, germinating in more detail, the mentioned is the limited range of representative monocotyledonous and dicotyledonous weeds. The example of species is the monocotyledonous genus, Phragmites, barnyardgrass, crabgrass, wheatgrass genus and perennial sedge within the perennial weed range., The scope of action is extended, such as pigs 82.3. 40,000 (please read the precautions on the back first (Write this page) i installed. · A6 B6_ printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (21) The genus Viola, the viola, the genus, the sesame, the stellaria, the genus, the white mustard Citrus spp., M. spp., And Perennial spp., As well as perennial weeds. Tricolor genus, thistle, sorrel, and genus Artemisia. The active substance mixture of the present invention is suitable for the growth of rice under specific conditions The resulting weeds (e.g. Citrus, Mizusawa, Water Chestnut, Guania and Cyperus) also produce excellent control effects. Economically important monocotyledonous weeds (e.g. Alopecu-rus myosuroides ), Oats (Avena fatua), barnyardgrass (Echin-ochlcia crus-galli) and millet (Setaria uiridis) are controlled under specific conditions for the growth of corn and rice. If the herbicide of the present invention is applied to the soil before germination On the surface, the weed seedlings can be completely inhibited from growing, or the weeds will stop growing when they reach the cotyledon stage, and they will die completely after 3-4 weeks. If the active substance mixture is applied to the green part of the plant by post-emergence method , Weed plants obviously stop growing within a very short time after treatment and remain at the growth stage when the agent is applied, or die quickly within a certain period of time, therefore, in this way, weeds that are harmful to crop plants The effect is eliminated at an extremely early stage and in a sustained manner by applying the novel herbicide of the present invention. Although the herbicide of the present invention has excellent herbicidal activity against monocotyledonous and dicotyledonous weeds, crop plants of economically important crops (eg , Wheat, barley, rye, rice and corn) want to suffer only negligible harm or not at all. For these reasons, these herbicides are extremely suitable for selective control of agricultural use. The growth of plants. This paper scale is applicable to China @ 家 标准 （CNS) A4 specifications (210 X 297 public goods) '24 * 82.3. 40,000 (please read the precautions on the back before filling out this page) — binding · order. Central Bureau of Standards, Ministry of Economic Affairs Xinggong Consumer Cooperative Printed 5 Clothing A6 _____B6_ V. Description of the invention (22) The active substance mixture of the present invention can achieve herbicidal activity exceeding the expected value of the additive effect of each ingredient. This higher activity allows the application ratio of each active substance to be greatly reduced ◊ In addition, the period of action of the mixture can be lengthened or it is found that the rate of action is increased. The advantageous properties of the active substance mixtures according to the invention are quite user-friendly when weeds are actually controlled, because they can control weeds more economically, or more quickly, or in a more slow-release manner, resulting in higher yields Crop plants. In addition, we have found that the active substance mixture of the present invention has a significant safener or antidote effect, that is, the second-degree phytotoxic effect of active substances used in crop plants (such as rice) is reduced or completely avoided. The safeners darone (compound B19) and JC-940 (compound B 3 2) are the most interesting. A: The mixing ratio of B can be changed within a wide range of limits. In principle, in the case of a two-component mixture, it is between 2: 1 and 1: 200. Therefore, in a three-component or four-component mixture (active substance A and two or three active substances B) in the case of 2: 1: 1, or 2: 1: 1: 1 to 1: 200: 200, or 1: 200: 200: 200. The choice of mixing ratio depends on the ingredients in the mixture, the stage of weed development, the range of weeds and the climatic conditions. Mixing ratio 1: 1 to 1: 1 (in the case of a two-component mixture), and between 1: 1: 1, or 1: 1: 1: 1 to 1: 100: 100, or 1: 100 : 100: 100 (in the case of a three-component or four-component mixture) is ideal. The application ratio of the herbicide A in the active substance mixture should be between 10 and 100 g / ha. This paper scale is applicable to the Chinese National Standard (CMS) A 4 specifications (210 X 297 mm) -25-82.3. 40,000 (Please read the precautions on the back before filling in this page) 丨 Install. Order. 2〇 (ό ^ ό1 Printed by the Ordnance Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Α6 Β6 V. Description of the invention (23), and the application of B The ratio is between 0 · 02 and 4. Okg / ha. The most suitable weight ratio can be determined by systematic trials. When using darone as a safety agent, the appropriate weight ratio is It is 1: 0 · 1 — 1: 50, preferably 1: 1 — 1: 30, especially 1: 10 — 1: 30. The active substance mixture of the present invention can exist in the form of a mixed composition of two components, and then depends on Traditionally, it is applied after dilution with water, or so-called tank mixers for diluting the separately prepared components together with water. Compound A or B or their mixtures can be formulated in a variety of ways according to current biochemical and / or physicochemical parameters. Therefore, the following possibilities are for the appropriate group Substances: Wettable powder (\ VP), water-soluble powder (SP), water-soluble concentrate, emulsifiable concentrate (EC), aqueous solution (SL), emulsion (EW), such as oil-in-water and water-in Medium oil emulsion, sprayable powder or emulsion, dispersion liquid based on oil or water, suspension concentrate (SC), (super emulsion), oil compatible solution, capsule suspension (CS), spreading powder , Seeding agent, particles for soil application or spreading, micro particles, spray particles, coated particles and particles in the form of coated particles (GR), aqueous solution particles (SG), water-dispersible particles (WG), ULV composition, micro Capsules or waxes. These various types of compositions are known in principle and are disclosed, for example: Winnacker-Kiichler, Chemische Technologies C Chemical Technology], Volume 7, C. Hauser Verlag Mu-nich, 4th Ed. 1986; van Valkenburg, 'Pesticides F- This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 g; ϊ) " 26 _ 82.3. 40,000 (please read the precautions on the back before writing this page) 丨· Order · Central Standard of the Ministry of Economic Affairs A6 B6 printed by the quasi-bureau employee consumer cooperative V. Description of invention (24) 〇rmu 1 atiοns ^, Marcel Dekker Η. Y., 2nd Ed. 1 972 -73; K. Martens, 'Spray Drying Handbook ^, 3rd Ed. 1979, G. Goodwin Ltd. London0 The required compounding components (such as inert substances, surfactants, solvents and other additives) are also known and disclosed, for example: Watkins, 'Handbook of Insecticide Dust Diluents and C- arriers ^, 2nd Ed., Darland Books, Caldwell NJ; H. v. 0 1 phen, 'Introduction to Clay Colloid Chemist ry *, 2nd Ed., J. Wiley Sons, NY, Marsden,' Solvents Guide ', 2nd Ed ., Interscience, NY 1950; McCutcheon's, 'Detergents and Emulsifiers A η n ua 1 ^, MC Publ. Gorp., Ridgewood NJ; Sisley and Wood, Encyclopedia of Surface Active Agents', Chera. Publ. Co, Inc., Η Y. 1964; Schonfeldt, Gre-nzf 1 achenaktive fithy1enoxidaddukte ^ (Surface-active Ethylene Oxide Adducts), Wiss. Ver 1 agsgese 11., Stuttgart 1 976; W i η nacker-Kli ch 1 er, Chemische Technologies (Chemical Technology), Volume 7, G. Hauser Verlag Munich, 4th Ed. 19860 According to these compositions, mixtures with other pesticidal active substances (such as other herbicides, fungicides or insecticides) can also be prepared, for example, Mixed (readymix) or tank mix (tank mix) form. Wettable powder is a composition that can be uniformly dispersed in water and contains ionic and / or nonionic surfactants in addition to the active substance (This paper scale applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm) -27 ~ 82.3 · 40,000 (Please read the precautions on page f before writing this page) 丨 Install · Order A6 B6 V. Description of the invention (25) Wetting agent, dispersant), for example, Polyoxyethylated alkylphenol, polyoxyethylated fatty alcohol or fatty amine, fatty alcohol polyglycol ether sulfate, alkyl basic acid salt, alkylbenzene sulfonate, sodium lignosulfonate, 2 , 2, 1,2-dimethyl methane-6,6- sodium disulfonate, dibutyl sodium sulfonate or sodium oleyl methyl taurine, as well as diluents or inert substances. For the preparation of wettable powders, the herbicidal active substances are finely milled, for example, in conventional devices (such as plant mills, blow mills and air jet mills), with or simultaneously with the preparation of auxiliary agents mixing. The emulsifiable concentration system consists of dissolving the active substance in an organic solvent (eg, butanol, cyclohexanone, dimethylformamide, xylene or higher boiling aromatics or hydrocarbons, or a mixture of organic solvents) and adding It is made of one or more ionic and / or nonionic surfactants (emulsifiers). For example, the following can be used as emulsifiers: calcium alkylarylsulfonates, such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acid polyethylene glycol esters, alkylaromatic Base polyglycol ether, fatty alcohol polyglycol ether, polypropylene oxide / ethylene oxide condensation product, alkyl polyether, sorbitan fatty acid vinegar, polybenzoxyethyl sorbitan fat Ester or polydoxyethyl sorbitol ester. Sprinkling powders are made by grinding active substances and finely divided solid substances (for example, talc, natural clays, such as kaolin, expansive soils, and pyrophyllite, or diatomaceous earth). Suspension concentrate can be based on water or oil. They can be, for example, wet-milled with a commercially available bead mill, and if appropriate, added with, for example, the surfactants already mentioned in the case of other morphological compositions. (Please read the precautions on the back and then fill out this page) i Packed-Ordered. The paper printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) Grade 4 (210 X 297 mm) -82.3. 40, 〇〇〇A6 B6 V. Description of the invention (26) (please read the precautions on the back before writing this page) Emulsion (for example, oil-in-water emulsion (EW)) can be used, for example, by mixing It is made with an organic solvent, a colloid mill and / or an electrostatic mixer, using an aqueous organic solvent, and, if appropriate, for example, in the case of other morphological compositions. The granules can be made by spraying the active substance onto an adsorbent, granulated inert substance or coating the active substance concentrate onto a carrier (such as sand, kaolin or granulated inert substance (using an adhesive, for example, polyvinyl alcohol, sodium polyacrylate) Or mineral oil). The appropriate active substance can also be granulated according to the traditional method of preparing fertilizer granules, if necessary, as a mixture with fertilizers. In principle, water-dispersible granules are produced by traditional methods (such as, Spray drying, fluid bed granulation, dish granulation, made by mixing with high speed mixer and extrusion without solid inert material. In principle, the agricultural chemical composition contains 0.1-99.9% by weight, especially 2-9 95% by weight of active substances A or B. The concentration of active substances A and B in the composition may be different. In wettable powders, for example, the concentration of active substances is about 10—Consumer of Central Bureau of Standards of the Ministry of Economic Affairs 95% by weight printed by the cooperative, and the remaining ingredients up to 100% by weight are composed of traditionally formulated ingredients. In the case of emulsifiable concentrates, the active substance concentration can be about 1 8 5 wt%, preferably 5-80 wt%. The composition in the form of a dusting powder contains about 1 _ 2 5 wt%, most of which is 5-20 wt% active substance, and the sprayable solution contains about 0.2 — 25% by weight, preferably 2-20% by weight of active substance. In the case of granules (such as water-dispersible granules), the active substance content is partly based on the active compound and is based on the paper standard. China National Standards (CNS) A4 specifications (210 X 297 mm) 29 82.3. 40,000 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A6 B6__ 5. Description of the invention (27) Liquid or solid form and which granulation aids and It depends on the material. In principle, the water-dispersible granules contain 10 to 90% by weight of active substance. In addition, the above-mentioned active substance composition also contains adhesives, wetting agents, dispersing agents, emulsifying agents, penetrating agents if appropriate , Preservatives, anti-freezing agents, solvents, substrates, carriers, Seco, anti-foaming agents, evaporation inhibitors and pH- and viscosity modifiers (which are traditional in each case). The composition of the sales form Substances (if appropriate), according to traditional methods, for example, dilution with water (in the case of wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules). Spreading powder, soil application or spreading form composition The substances and sprayable solutions have traditionally not been diluted with any other inert substances before use .. The required application ratio of the compound of general formula (I) will vary depending on external conditions (such as temperature, humidity and the nature of the herbicide used. The following examples are provided to illustrate the present invention: A. Compounding Example a) Spreading powder consists of mixing 10 parts by weight of the active substance mixture of the present invention and 90 parts by weight of talc powder (as an inert substance) in a hammer mill It is made by crushing the mixture. b) Wettable powder (which is easy to disperse in water) consists of mixing 25 parts by weight of active substance A + B, 64 parts by weight of kaolin containing quartz (as an inert substance), 10 parts by weight of wood sulfonate Potassium acid and 1 part by weight of sodium oleyl methyl taurine (as wetting agent and dispersing agent) are made by grinding the mixture in a sharp disk mill. The size of this paper is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) _ 30 _ 82.3. 40,000 (please read the precautions on the back before filling in this page) • Binding _ Order. Central Bureau of Standards 8 A6 B6_______ printed by the Industrial and Consumer Cooperatives V. Description of the invention (28) C) The dispersible concentrate (which can be easily dispersed in water) can be mixed with 20 parts by weight of alkylphenol polyethylene glycol ether (© Triton X 207), 3 parts by weight of isotridecyl alcohol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling point range, for example, about 2 5 5 to higher than 2 7 7 ° C) and milled in a ball mill Grind the mixture to a fineness of less than 5 microns. d) The emulsifiable concentration system is made of 15 parts by weight of active substance A + B, 75 parts by weight of cyclohexanone (as solvent) and 10 parts by weight of oxyethylated nonylphenol (as emulsifier) to make. e) The water-dispersible particles consist of mixing 7 5 parts by weight of active substance A + B, 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol, and 7 Parts of kaolin are made by grinding the mixture in a sharp disk mill and in a fluid bed by granulating the powder by spraying water (as a granulating liquid). f) The water-dispersible particles are also homogenized and pre-crushed (in a colloid mill): 2 5 parts by weight of active substance A + B, 5 parts by weight of 2, 2 /-dimethane-6 ' 6 Sodium disulfonate, 2 parts by weight sodium oleyl methyl taurine, .1 parts by weight polyethylene glycol, the paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm)- 31 _ 82.3. 40,000 --------------- `` ------- installed ------ ΤΓ ---- (Please read the notes on the back before filling in This page) A6 B6 printed by R Industry and Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (29) 17 parts by weight of calcium carbonate and 50 parts by weight of water, after which, the mixture is milled in a bead mill And in the spray tower, it is made by atomizing and drying the resulting suspension using a single substance nozzle. G) Wettable powder consists of mixing 3 parts by weight of active substance A, 30 parts by weight of active substance B, 3 parts by weight Several sodium lignosulfonates, 6 3 parts by weight of kaolin containing quartz and 1 part by weight of sodium dioctyl sulfosuccinate, and then grind the mixture. H) The particles are made by mixing 0.1 part by weight of active Thing A, 1 · 5 parts by weight of active substance B, 0 · 5 parts by weight of neochol, 3 5 parts by weight of bentonite and 6 2 9 parts by weight of talc, milled in a sharp disc mill Grind the mixture and granulate the powder in a fluid bed to make a biochemical example: 1 · Pre-emergence effect on weeds: The seeds or tubers of monocotyledonous and dicotyledonous weed plants are implanted in a plastic bowl with a diameter of 9 cm Loamy sandy soil covered with soil. Weeds found in rice cultivation grow in waterlogged soil, and water is added to the bowl to increase the quantity to a few millimeters above the surface of the soil or flooded. The active substance mixture of the present invention The paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) _ 32-82.3. 40,000 (please read the precautions on the back before filling in this page)-丨 install_ order. • 17 ^. Economy A6 ____B6 printed by the Ministry of Central Standards Administration, Industrial and Consumer Cooperatives V. Description of the invention (30) (wettable powder or emulsion concentrate), and the corresponding active substances used in the control test are then mixed with 6 0 0 — 8 0 0 liters of water / ha (converted) application ratio, in different agents Apply it as an aqueous suspension or emulsion to the soil-covered surface, or, in the case of rice, pour it into irrigation water. After treatment, place each pot in the greenhouse and keep it under good growth conditions for weeds After the test plant has germinated after a test period of 3-4 weeks, visually evaluate the damage to the plant or the negative effect on germination (compared to the untreated control group). The herbicide of the present invention has a broad range of grass Undergraduate weeds and dicotyledonous weeds have an excellent pre-emergence weeding effect. In all cases, the theoretical and measured activity values of the compounds obtained are different. The theoretical activity value of the mixture (which can be predicted by theory) is determined by the SR Col by formula: Calculation of synergistic and antagonistic responses of herbicide combinations, Weeds 15, pages 20-22 (1967). In the case of a two-component mixture, this A formula is:

X · Y E = X + Y-- 100 以及，因此，三種除草活性物質之混合物的公式係爲： ίγ ·Υ4.γ ·7 + Υ Ζ5 (Χ·Υ Ζ ) 式中： 本纸張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） '33 ~ 82.3. 40,000 (請先Μ讀背面之注意事項再填寫本頁) 丨裝· 訂‘ J· 經濟部中央標準局員工消費合作社印製 A6 B6____ 五、發明説明（31) x =除草劑A在X kg/ha施用比値下之傷害％; Y =除草劑B在y kg/ha施用比値下之傷害％; Z =除草劑B在z kg/ha施用比値下之傷害％: E=除草劑A+B(或A+B+C)在x+y (或x+y + z ) kg/h a下之預期傷害。 若實際傷害値大於預期傷害値，則混合物之作用是超 力口成的，亦即，具有協乘作用。 本發明之活性物質混合物具有大於使用Colby公式’ 根據僅單獨使用時之各成份的觀察作用預估之除草活性° 因此，活性物質混合物具有協乘作用。 2 ·對雜草之萌芽後作用 將單子葉及雙子葉雜草之種子或塊莖部份植入塑膠缽 中之壤質砂土中，用土壤覆蓋且於優異成長條件下之溫室 中成長。稻子栽培中所見之雜草在缽內成長，缽中之土壤 表面用水泛濫至2公分深度，再於測試期間成長。 本發明之活性物質混合物（其調製成可濕化粉末或乳 液濃縮體），以及，在對照試驗中，對應之經調配各成份 物質以3 0 0 — 6 0 0升水/h a (經換算）之施用比値 ，在不同劑量比値下噴灑至植物之綠色部份上，以及，在 保持植物於溫室中，最適當成長條件下約3 — 4週以後， 用肉眼評估組成物之作用（和未經處理之對照組相比較） 。在稻子栽培中可發現之雜草情況下，活性物質係直接加 至灌漑水（類似所謂之顆粒使用方式）或者噴灑至植物上 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） ~ 34 ~ 82.3. 40,000 -裝------訂----「} (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局R工消費合作社印製 A6 B6 五、發明説明（32) 及灌漑水內。 本發明之除草劑亦具有對廣範圍上重要之禾本科雜草 及雙子葉雜草之優異萌芽後除草活性。Cq 1 by分析證明本 發明之除草劑作用是協乘性的。 實例1 : 稻子和稗在塑膠缽中，在溫室條件（溫度=2 8/ 1 8 °C白天/黑夜；6 0 — 8 0%相對大氣濕度）下成長 Ο 在植物萌芽後，各缽中泛濫水至約2公分深。在整個 測試期間內維持此一水値。當稗已達1.5葉階段時，藉 由傾倒已由最後產物製成之水性懸浮液或乳液形態的本發 明活性物質混合物至泛濫缽內之水中而處理植物。 處理後約3週，測試B利用肉眼評估植物傷害（和未 經處理之對照組比較）。 表1示出在每一例子中之相關數據（重複二次之平均 値）。 結果清楚證明混合物之各成份協乘性作用於稗上而不 減低稻子對各成份之耐受性。 ---------------一—-------裝------訂 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)甲4规格（210 X 297公發） -35 - 82.3. 40,000 A6 B6 五、發明説明（33) 表1 :本發明之活性物質混合物的除草活性及選擇性 產物 (實例號碼） 劑量比値 (kg of a . i . / h a ) 除草作用（％ ) ORSA ECCR A 1 0.005 10 1 5 B5 0.025 0 65 B32 0 . 1 0 0 B 1 8 0.3 0 0 B33 0.006 0 0 B 1 7 0.02 0 5 B25 0.015 0 4 0 A1+B32+B5 0.005+0.1+0.025 0 8 5 ( 7 0 ) A 1 + B 1 8 + B5 0.005+0.3+0.025 0 78(70) A 1 +B33 + B5 0.005+0.006+0.025 0 8 0 ( 7 0 ) A 1 +B 1 7 + B25 0.005+0.002+0.015 0 88(52) 經濟部中央標準局員工消費合作社印製 <請先閲讀背面之注意事項再塡寫本頁) 縮寫代號0 R S A =稻子 ECCR=稗 ()二利用C 〇丨b y公式計算出之預期値 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 36 82.3. 40,000 2 jbddi A6 B6 五、發明説明（34) 實例2 : 莎草及慈姑（在日本之稻子栽培中的二種重要雜草） 類似實例1之方式成長。當莎草達到1 · 5葉階段及慈姑 達1 —葉階段時使用本發明之混合物處理。 在此一試驗中，水量調節至高於土壤表面3公分。在 處理後3 8天評估試驗結果。 表2列出對應數據。 ------------：---「 -------裝------#---- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印制衣 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公货） 37 82.3. 40,000 A6 B6 i、發明説明（35) :本發明活性物質混合物之除草活性 產物 (實例號碼） 〜--- 劑量比値 (kg of a . i ./ha) 除草作用（％ ) CYSE SAPY A1 0.010 35 85 B5 0.225 35 85 B7 -------- 0 . 525 80 0 B10 0.600 10 60 Β18 0 . 600 70 10 Β19 0.750 40 0 Β25 0.150 75 0 Α1+Β19+Β5 ——. 0.01+0.60+0.225 75(42) - Α1+Β10+Β7 ---- 0 . 0 1 + 0 . 6 0 + 0 . 5 25 95(88) - Α1+Β19+Β25 —— 0.01 + 0 . 75 + 0 . 15 90(90) 90(85) Α1+Β18+Β5 ---- 0 . 0 1 + 0 . 75 + 0.525 90(92) 90(85) Α1+Β17+Β25 --- 0 . 0 1 + 0 . 6 0 + 0 . 2 2 5 85(80) - 縮寫代號CYSE =莎草 SAPY =慈姑 ()=由Colby公式計算出之預期値 本紙張尺度適用中酉國家標準（CNS)甲4規格（210 X 297公釐）-38 " (請先閲讀背面之注意事項再填窝本頁) 丨裝， 訂. 馨部中4-wfX消費合作社印製 82.3. 40,000 A6 B6 五、發明説明（36) 實例3:稻子中之安全劑作用 二批稻子植物（2 -葉階段）在溫室內之缽（ 〇 · 0 lm3 )中成長。爲了測定每一種活性物質，或每 一活性物質混合物，每者重複進行3次，亦即，表中之數 據係爲得自3個不相關測定之平均値。種植3天以後，本 發明之活性物質混合物及對應之經調配各別活性成份係以 1Omi噴灑混合物之形態施用。植物係以土壤表面爲2 公分深之水泛濫的方式成長。活性物質之實際使用濃度示 於下表中。根及芽之重量係在施用後2 5天測定且以相對 於未經處理對照組之重量（1 0 0%)表示。 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 82.3. 40,000 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） A6 B6 五、發明説明（37) 稻子中之安全劑作用（種植深度0 · 5 cm) 經濟部中央標準局員工消費合作社印製 化合物 施用比値 成長 〔％〕 (g of a . i ./10a) 芽 根 A1 + 6 82 61 A 1 + B 1 9 6 + 30 98 92 A1+B19 6 + 60 100 100 A1+B19 6 + 120 100 98 A1+B19 12 67 52 A1+B19 12 + 30 9 1 90 A1+B19 12 + 60 98 98 A 1 + B 1 9 12+120 10 0 98 B 1 9 120 10 0 100 未經處理 10 0 100 之控制組 在未經處理之對照組中，1 4 · 8 g芽及 6 · 2 g根等於1 0 0 %。 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 82.3. 40,000 (請先《讀背面之注意事項再塡寫本頁) 丨裝· •11· A6 B6 五、發明説明（38) 稻子內之安全劑作用（種植深度2 · 0 cm) 經濟部中央標準局員工消費合作社印製 化合物 施用比値 (g of a . i . /10a) 成長 芽 〔％〕 根 Α1 6 99 69 A 1 + Β 1 9 6 + 30 100 92 A1+B19 6 + 60 100 97 A1+B19 6 + 120 100 100 A 1 12 98 64 A 1 + B 1 9 12 + 30 100 96 A1+B19 12 + 60 100 98 A1+B19 12+120 100 100 B 1 9 120 100 10 0 未經處理 之對照組 l〇〇g l〇〇g 在未經處理之對照組中，1 7 · 4 g芽及 8 · lg根等於10 0%。 (請先閲讀背面之注意事項再填寫本頁) 丨裝· .,β . 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） 41 82.3. 40,000 A6 B6 五、發明説明（39) 實例4 :稻子中之達若因協乘作用 稗，莞，慈姑，莎草及荸薺之種子或塊莖部份種入塑 膠缽（0 · 08c πί)中，用土覆蓋且於溫室中，優異成 長條件下成長。本發明之活性物質混合物以及對應之經調 配各別活性物質以包含可濕化粉末之懸浮液形態，在稗已 形成葉子（0 _葉階段）施用。在各缽中，土壤表面係用 水泛濫至3公分深。在施用後2 8天測定新生重量（f r e -sh weigh)。表中所示數據等於經處理植物對未經處理對 照組之新生重量比値。 ------------------------裝------訂 (請先閲讀背面之注意事項再塡寫本頁) 經濟部中央標準局貝工消费合作社印製 本纸張尺度適用中國國家標準（CNS)甲4規格（210 X 297公货） -42 - 82.3. 40,000 A6 B6 五、發明説明（40) 化合物 施用比値 (g of a.i./10a) 未經處理對照之％(新生重量） ECHR SCPJU SAGPY CYPSE EL0KU A 3 28 3 6 15 0 A+B19 3+30 26 0 4 14 0 A+B19 3+60 20 0 5 11 0 A+B19 3+120 25 0 6 10 0 B19 120 47 15 100 100 45 未經處理 100 100 100 100 100 (請先閱讀背面之注意事項再蜞寫本頁) 丨裝. 縮寫代號： ECHR =稗 SCPJU =莞 SAGPY=慈姑 CYPSE =莎草 EL0KU =荸薺 在未經處理之對照組中， 1) 71.0 g ECHR 等於 100% 成長 2) 4.6 g SCPJU 等於 100% 成長 3) 5.8 g SAGPY等於10⑽成長 4) 43.0 g CYPSE 等於 100% 成長 5) 8.1 g EL0KU等於〗00%成長 本紙張尺度適用中國國家標準（CNS)甲4規格（210 X 297公釐） -43 ' 82.3.40 000 訂. 經濟部中央標準局貝工消費合作社印製 #48719~~修正 年月曰Λ 、 84」ε η q ^ j 公告本 附件三：第82103143號專利申請案 中文補充數據 稻田用除草劑對一些雜草之除草活性間交互作用之評估 雨久花X · YE = X + Y-- 100 and, therefore, the formula of the mixture of three herbicidal active substances is: ίγ · Υ4.γ · 7 + Υ ZO5 (Χ · Υ ZO) Where: The paper size is applicable to China National Standard (CNS) Grade A 4 (210 X 297 mm) '33 ~ 82.3. 40,000 (please read the precautions on the back before filling out this page) 丨 Installation · Order 'J · Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Printed A6 B6____ V. Description of the invention (31) x =% damage of herbicide A under X kg / ha application ratio; Y =% damage of herbicide B under y kg / ha application ratio; Z = weeding Injury% of the application rate of agent B at z kg / ha: E = expected injury of herbicide A + B (or A + B + C) at x + y (or x + y + z) kg / ha. If the actual damage value is greater than the expected damage value, the effect of the mixture is superfluous, that is, it has a synergistic effect. The active substance mixture of the present invention has a herbicidal activity greater than that estimated using the Colby formula based on the observation effect of each component when used alone. Therefore, the active substance mixture has a synergistic effect. 2. Post-emergence effect on weeds Seeds or tubers of monocotyledonous and dicotyledonous weeds are planted in loamy sand in a plastic bowl, covered with soil and grown in a greenhouse under excellent growth conditions. The weeds seen in rice cultivation grew in the pot, and the soil surface in the pot was flooded with water to a depth of 2 cm, and then grown during the test. The active substance mixture of the present invention (which is prepared as a wettable powder or emulsion concentrate), and, in the control test, the corresponding ingredients are adjusted to 300-600 liters of water / ha (converted) Apply the ratio, spray it onto the green part of the plant at different dose ratios, and after maintaining the plant in the greenhouse under the most suitable growth conditions for about 3-4 weeks, visually assess the effect of the composition (and not Compared with the treated control group). In the case of weeds that can be found in rice cultivation, the active substance is added directly to irrigation water (similar to the so-called granule usage) or sprayed onto the plant. This paper scale applies the Chinese National Standard (CNS) A 4 specification (210 X 297 Mm) ~ 34 ~ 82.3. 40,000-installed ------ ordered ---- "} (please read the notes on the back before filling out this page) Printed A6 B6 by R Industrial and Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs 5. Description of the invention (32) and irrigation water. The herbicide of the present invention also has excellent post-emergence herbicidal activity for a wide range of grass weeds and dicotyledonous weeds. Cq 1 by analysis proves that the herbicides of the present invention The effect of the agent is synergistic. Example 1: Rice and barnyardgrass grow in a plastic bowl under greenhouse conditions (temperature = 28/18 ° C day / night; 60 to 80% relative atmospheric humidity). After the plants germinated, water was flooded to a depth of about 2 cm in each bowl. This water value was maintained throughout the test period. When the barnyardgrass reached the 1.5-leaf stage, by pouring the aqueous suspension or emulsion made from the final product Form of the active substance mixture of the present invention into the flooding bowl Plants are treated in water. About 3 weeks after treatment, Test B uses the naked eye to assess plant damage (compared to the untreated control group). Table 1 shows the relevant data in each example (average value repeated twice). The results clearly prove that the synergy of the ingredients of the mixture acts on the barnyardgrass without reducing the tolerance of the rice to the ingredients. --------------- 一 ----------- Binding --- Order (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 public issue) -35-82.3. 40,000 A6 B6 5 Description of the invention (33) Table 1: Herbicidal activity and selective products of the active substance mixture of the present invention (example number) Dose ratio (kg of a. I. / Ha) Herbicidal effect (%) ORSA ECCR A 1 0.005 10 1 5 B5 0.025 0 65 B32 0. 1 0 0 B 1 8 0.3 0 0 B33 0.006 0 0 B 1 7 0.02 0 5 B25 0.015 0 4 0 A1 + B32 + B5 0.005 + 0.1 + 0.025 0 8 5 (7 0) A 1 + B 1 8 + B5 0.005 + 0.3 + 0.025 0 78 (70) A 1 + B33 + B5 0.005 + 0.006 + 0.025 0 8 0 (7 0) A 1 + B 1 7 + B25 0.005 + 0.002 + 0.015 0 88 (52) Central Standard of the Ministry of Economic Affairs Printed by the Bureau Staff Consumer Cooperative; please read the precautions on the back before writing this page) Abbreviation code 0 RSA = rice ECCR = barnyard (2) The expected value calculated by using the C 〇by formula is applicable to the country of China Standard (CNS) A4 specifications (210 X 297 mm) 36 82.3. 40,000 2 jbddi A6 B6 5. Description of the invention (34) Example 2: Sedge and Cigu (two important weeds in rice cultivation in Japan) It grows in a similar way to Example 1. When the sedges reach the 1.5-leaf stage and the Ciguda 1-leaf stage, the mixture of the present invention is used for treatment. In this experiment, the water volume was adjusted to 3 cm above the soil surface. The test results were evaluated 38 days after treatment. Table 2 lists the corresponding data. ------------: --- "------- 装 ------ # ---- (Please read the notes on the back before filling this page) Economy Ministry of Central Standards Bureau employee consumer cooperatives printed clothing paper standards apply China National Standards (CNS) A 4 specifications (210 X 297 public goods) 37 82.3. 40,000 A6 B6 i, invention description (35): the active substance mixture of the present invention Herbicidal active product (example number) ~ --- dose ratio (kg of a. I ./ha) herbicidal effect (%) CYSE SAPY A1 0.010 35 85 B5 0.225 35 85 B7 -------- 0. 525 80 0 B10 0.600 10 60 Β18 0 .600 70 10 Β19 0.750 40 0 Β25 0.150 75 0 Α1 + Β19 + Β5 ----. 0.01 + 0.60 + 0.225 75 (42)-Α1 + Β10 + Β7 ---- 0. 0 1 + 0. 6 0 + 0. 5 25 95 (88)-Α1 + Β19 + Β25 —— 0.01 + 0.75 + 0.15 15 (90) 90 (85) Α1 + Β18 + Β5 ---- 0. 0 1 + 0. 75 + 0.525 90 (92) 90 (85) Α1 + Β17 + Β25 --- 0. 0 1 + 0. 6 0 + 0. 2 2 5 85 (80)-abbreviated code CYSE = Cyperus SAPY = Ci Gu () = the expected value calculated by the Colby formula. The paper size is applicable to the Zhongyou National Standard (CNS) A 4 specification (210 X 297 mm) -38 " (please read first Note on the back and fill the nest page) 丨 Installed and ordered. Printed by Xinbuzhong 4-wfX Consumer Cooperative 82.3. 40,000 A6 B6 5. Description of the invention (36) Example 3: The role of safeners in rice Two batches of rice plants (2-leaf stage) grow in a bowl (〇 · 0 lm3) in the greenhouse. In order to measure each active substance, or each active substance mixture, each is repeated 3 times, that is, the data in the table is The average value obtained from 3 uncorrelated measurements. After 3 days of planting, the active substance mixture of the present invention and the corresponding formulated active ingredients are applied in the form of a spray mixture of 1 Omi. The plant is based on the surface of the soil at a depth of 2 cm It grows in the manner of flooding. The actual concentration of active substance is shown in the table below. The weight of roots and shoots is measured 25 days after application and is expressed relative to the weight of the untreated control group (100%). (Please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 82.3. 40,000 This paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) A6 B6 V. Description of the invention (37) The role of safeners in rice (planting depth 0. 5 cm) Application compound growth rate of compound printed by employees ’cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (%) (g of a. I ./10a) Bud Root A1 + 6 82 61 A 1 + B 1 9 6 + 30 98 92 A1 + B19 6 + 60 100 100 A1 + B19 6 + 120 100 98 A1 + B19 12 67 52 A1 + B19 12 + 30 9 1 90 A1 + B19 12 + 60 98 98 A 1 + B 1 9 12 + 120 10 0 98 B 1 9 120 10 0 100 untreated 10 0 100 control group In the untreated control group, 1 4 · 8 g shoots and 6 · 2 g root is equal to 100%. The size of this paper is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 82.3. 40,000 (please read the precautions on the back and then write this page) 丨 installed • 11 · A6 B6 V. Description of the invention (38) The role of safeners in rice (planting depth 2 · 0 cm) The compound application ratio (g of a. I. / 10a) of the compound printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 69 A 1 + Β 1 9 6 + 30 100 92 A1 + B19 6 + 60 100 97 A1 + B19 6 + 120 100 100 A 1 12 98 64 A 1 + B 1 9 12 + 30 100 96 A1 + B19 12 + 60 100 98 A1 + B19 12 + 120 100 100 B 1 9 120 100 10 0 untreated control group 100gl〇〇g in the untreated control group, 17.4g shoots and 8.lg root It is equal to 100%. (Please read the precautions on the back before filling in this page) 丨 Package ·., Β. This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 41 82.3. 40,000 A6 B6 V. Description of the invention (39) Example 4: Seeds or tubers of barnyard, guan, ci gu, sedge, and water chestnut in the rice daring for synergy, planted in a plastic bowl (0.08c πί), covered with soil and in a greenhouse, Grow under excellent growth conditions. The active substance mixture of the present invention and the corresponding formulated respective active substances are applied in the form of a suspension containing wettable powders in the leaves of barnyardgrass (0_leaf stage). In each bowl, the soil surface was flooded with water to a depth of 3 cm. The fresh weight (fre-sh weigh) was measured 28 days after application. The data shown in the table is equal to the new weight ratio of treated plants to untreated controls. ------------------------ Installed ----- Ordered (please read the notes on the back before writing this page) Central Standard of the Ministry of Economic Affairs The size of the paper printed by the Bureau Cooperative Consumer Cooperative applies to the Chinese National Standard (CNS) A4 specifications (210 X 297 public goods) -42-82.3. 40,000 A6 B6 V. Description of the invention (40) Compound application ratio (g of ai / 10a)% of untreated control (new weight) ECHR SCPJU SAGPY CYPSE EL0KU A 3 28 3 6 15 0 A + B19 3 + 30 26 0 4 14 0 A + B19 3 + 60 20 0 5 11 0 A + B19 3 + 120 25 0 6 10 0 B19 120 47 15 100 100 45 untreated 100 100 100 100 100 (please read the precautions on the back before writing this page) 丨 installed. Abbreviation code: ECHR = barnacle SCPJU = smile SAGPY = Tsang CYPSE = Cyperus EL0KU = Water Chestnut in the untreated control group, 1) 71.0 g ECHR equals 100% growth 2) 4.6 g SCPJU equals 100% growth 3) 5.8 g SAGPY equals 10 ⑽ growth 4) 43.0 g CYPSE Equal to 100% growth 5) 8.1 g EL0KU equal to〗 00% growth This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) -43 '82.3.40 000. The Ministry of Economic Affairs Central Standards Bureau Bei Gong Printed by the Consumer Cooperative # 48719 ~~ Amendment date Λ, 84 ″ ε η q ^ j Announcement of this Annex III: Chinese supplementary data of Patent Application No. 82103143 Interaction between the herbicides for paddy field herbicides on some weeds Evaluate Yu Jiuhua

化合物 劑量比值 除草作用 g of a.i./ha % A1 0,125 0 0,25 0 B17 75 40 150 40 A1 + 17 0,125 + 75 40 0,125 + 150 80 B32 750 20 A1 + B32 0,125 + 750 40 B33 12,5 20 25 60 A1 + B33 0,125 + 25 80 0,5 + 12,5 40 B18 300 20 A1 + B18 0,125 + 300 40 BIO + 900 60 A1 + BIO 0,25 + 900 BO AD02237 1 I.Compound dose ratio herbicidal effect g of ai / ha% A1 0,125 0 0,25 0 B17 75 40 150 40 A1 + 17 0,125 + 75 40 0,125 + 150 80 B32 750 20 A1 + B32 0,125 + 750 40 B33 12,5 20 25 60 A1 + B33 0,125 + 25 80 0,5 + 12,5 40 B18 300 20 A1 + B18 0,125 + 300 40 BIO + 900 60 A1 + BIO 0,25 + 900 BO AD02237 1 I.

X92/069TW I. AD02237 化合物 劑量比值 除草作用 g of a.i./ha % A1 5 0 10 20 20 50 B19 50 20 A1 + B19 5+50 40 10 + 50 60 B18 50 10 A1 + B18 5+50 50 10 + 50 60 B17 150 0 A1 + B17 5 + 150 20 10 + 150 60 20+150 80 慈姑 化合物 劑量比值 除草作用 g of a.i./ha % A1 0,5 33 1 27 B18 600 40 A1 + B18 0,5 + 600 80 1+600 73 B19 375 0 750 0 A1 + B19 0,5 + 375 . 40 0,5 + 750 40 1 + 375 40 AD02237X92 / 069TW I. AD02237 Compound dose ratio herbicidal effect g of ai / ha% A1 5 0 10 20 20 50 B19 50 20 A1 + B19 5 + 50 40 10 + 50 60 B18 50 10 A1 + B18 5 + 50 50 10 + 50 60 B17 150 0 A1 + B17 5 + 150 20 10 + 150 60 20 + 150 80 Cigu compound dose ratio herbicidal effect g of ai / ha% A1 0,5 33 1 27 B18 600 40 A1 + B18 0,5 + 600 80 1 + 600 73 B19 375 0 750 0 A1 + B19 0,5 + 375. 40 0,5 + 750 40 1 + 375 40 AD02237

II :/ λ 組合物對作物安金性（經移植之稻子）的評估 化合物 A.i. of g/ha 新生重童 (%未處理之）芽 Α1 24 84 Β10 1800 84 A1 + Β10 24+1800 107 Α1 48 83 Β32 '"· 3000 82 A1 + Β32 48+3000 89 Al. + Β17 + Β25 24 + 450 + 450 46 A1 + Β17 + Β25 + Β19 24 + 450 + 450 + 225 45 + 300 54 + 450 60 Al + Β25 + Β17 24 + 450 + 450 39 Al + Β25 + Β17 + Β19 24 + 450 + 450 + 225 73 + 450 70 Al + Β25 + Β17 48 + 900 + 900 28 Al + Β25 + Β17 + Β19 48 + 900 + 900 + 450 41 + 900 55 Α1 24 76 Al + Β32 24+150 87 + 300 85 + 450 94 Α1 48 89 Al + Β32 48+1200 94 Al + Β17 + Β25 24 + 375 + 450 61 Al + Β17 + Β25 + Β19 24 + 375 + 450 + 225 66 + 300 79 + 450 80 Al + Β17 + Β25 48 + 900 + 900 42 Al + Β17 + Β25 + Β19 48 + 900 + 900 + 300 43 + 600 46 + 900 51 AD02237 4II: / λ Composition evaluation of crop safety (transplanted rice) Compound Ai of g / ha Newborn (% untreated) bud A1 24 84 Β10 1800 84 A1 + Β10 24 + 1800 107 Α1 48 83 Β32 '" 3000 82 A1 + Β32 48 + 3000 89 Al. + Β17 + Β25 24 + 450 + 450 46 A1 + Β17 + Β25 + Β19 24 + 450 + 450 + 225 45 + 300 54 + 450 60 Al + Β25 + Β17 24 + 450 + 450 39 Al + Β25 + Β17 + Β19 24 + 450 + 450 + 225 73 + 450 70 Al + Β25 + Β17 48 + 900 + 900 28 Al + Β25 + Β17 + Β19 48 + 900 + 900 + 450 41 + 900 55 Α1 24 76 Al + Β32 24 + 150 87 + 300 85 + 450 94 Α1 48 89 Al + Β32 48 + 1200 94 Al + Β17 + Β25 24 + 375 + 450 61 Al + Β17 + Β25 + Β19 24 + 375 + 450 + 225 66 + 300 79 + 450 80 Al + Β17 + Β25 48 + 900 + 900 42 Al + Β17 + Β25 + Β19 48 + 900 + 900 + 300 43 + 600 46 + 900 51 AD02237 4

Claims (1)

、申請專利範圍 附件二A : 第82103143號專利申請案 中文申請專利範圔修正本 民國85年2月修正 1 . 一種除草劑，其包含作爲活性物質之有效數量之 A )—或多種式A 1 ，A 2及A 3化合物或其鹽類： OC2H5 OCH t —oso2-nh-co-nh —(/ 0 C Η (請先閲讀背面之注意事項再填寫本頁) 〇ch(ch3)2 \__/~〇S〇2-MH- OCH 3 CO -NH (A2 OCH OCH OCH 與 B )—，二或更多種選自下列之化合物綜合在一起： B 10)甲苯—4 —磺酸-4- (2 ，4 —二氯基苯 醯基）—1 ，3 -二甲基吡唑一 5 —酯（吡 唑拉那特（pyrazolynate)，吡唑列特（〇-yrazolate))， 本紙張尺度適用中國國家橾準（CNS )八4規格（210 X 297公釐） 訂、 Appendix II to the scope of patent application: Amendment of the Chinese patent application No. 82103143 in the Chinese patent application. Amendment in February 1985. Amendment 1. A herbicide containing an effective amount of A as an active substance) —or multiple formulas A 1 , A 2 and A 3 compounds or their salts: OC2H5 OCH t —oso2-nh-co-nh — (/ 0 C Η (please read the precautions on the back before filling this page) 〇ch (ch3) 2 \ __ / ~ 〇S〇2-MH- OCH 3 CO -NH (A2 OCH OCH OCH and B) —, two or more compounds selected from the following are combined together: B 10) Toluene—4-sulfonic acid-4- (2,4-Dichlorophenylphenyl) -1,3-dimethylpyrazole-5-ester (pyrazolynate, pyrazolate), the paper size Applicable to China National Standard (CNS) 84 specifications (210 X 297 mm) -NH-CO-NH —(/ 經濟部中央梯準局男工消費合作社印製 申請專利範圍 ο c Α8 Βδ C8 D8 c-NH-CO-NH — (/ Printed by the Men ’s Workers ’Consumer Cooperative of the Central Ladder and Accreditation Bureau of the Ministry of Economics Scope of Patent Application ο c Α8 Βδ C8 D8 c B 1 0 ) B17)乙烷磺酸一2 ，3 —二氫一3 ，3 —二甲基 苯並呋喃—5 —酯（苯呋瑞特（5611丨111633-t e )) -0 h5c2_o2s-oB 1 0) B17) Ethane sulfonic acid 2, 3-dihydro 3, 3-dimethyl benzofuran-5-ester (benfurate (56111 丨 111633-t e)) -0 h5c2_o2s-o B 1 7 ) B18) 2 —溴基一3 ，3 —二甲基一 N- (1—甲 基一 1 —苯基乙基）丁醯胺（溴布太得（1)-romobut i de ) ) 1 r η 〇 Β <" C Η , .3 II I I 3 C-NH-C-CH-C-CH C Η CH ---------{ 私------訂------^ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 Β19) 1— (1-甲基一1—苯基乙基）一3 —對 —甲苯基脲（達若因（dymron)，達慕若因 (da i muron ))， c Η 0II C-NH-C-NH I C H ,B 1 7) B18) 2-bromo-3,3-dimethyl-N- (1-methyl-1-phenylethyl) butyramide (bromobutazone (1) -romobut i de) ) 1 r η 〇Β < " C Η, .3 II II 3 C-NH-C-CH-C-CH C Η CH --------- {私 ------ 定------ ^ (Please read the precautions on the back before filling in this page) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Β19) 1— (1-Methyl-1-Phenylethyl) -3— P-tolylurea (dymron, da i muron), c Η 0II C-NH-C-NH ICH, B 2 5 )二硫代磷酸—s — 4-氯基一 N -異丙基苯 本紙張尺度逋用中國國家揉準（CNS〉A4規格（2l'OX 297公釐） -2 - 六、申請專利範圍 A8 B8 C8 D8 胺基甲醯基甲酯，◦，〇 —二甲酯（阿尼羅 福斯（anilofos))， s 1 οI! II N-C-CH2-5-P(〇CH3) 0 2 5 ) ch(ch3)2 B32) 3— (2—氛基苯基甲基）一1— (1—甲 基一 1—苯基乙基）脲（JC — 940)以 及， 〇 CH, CHCl II \ 一 .CH,-NH-C-NH-CB 2 5) Dithiophosphoric acid — s — 4-chloro-N-isopropyl benzene on paper scale using Chinese National Standard (CNS> A4 specification (2l'OX 297 mm) -2-VI. Application Patent scope A8 B8 C8 D8 Aminomethyl methacrylate, ◦, 〇-dimethyl (anilofos (anilofos)), s 1 οI! II NC-CH2-5-P (〇CH3) 0 2 5) ch (ch3) 2 B32) 3- (2-aminophenylmethyl) -1- (1-methyl-1-phenylethyl) urea (JC-940) and, 〇CH, CHCl II \ One.CH, -NH-C-NH-C -〇 (B 3 2 B33) 2 — (2 —氯基_4_甲烷磺醯基苯醯基） 環己烷一1，3 —二酮（ICIA — 0 0 5 1 )， --------1-衣------訂 J-----{ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 0-〇 (B 3 2 B33) 2 — (2 —chloro_4_methanesulfonyl phenyl acetoyl) cyclohexane-1,3-dione (ICIA — 0 0 5 1), ----- --- 1-Cloth ------ Subscribe J ----- {(Please read the precautions on the back before filling out this page) Printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs 0 S 0. CH B 3 3 ) 2 .如申請專利範圍第1項之除草劑，其包含〇 . 1 一 9 9重量％活性物質A和B以及傳統調配輔助劑。 3 .如申請專利範圍第1項之除草劑，其包含重量比 值介於2 : 1和1 : 2 0 0之間（在雙相混合物之情況下 本紙张尺度適用中國國家標準（CNS ) A4規格（21ΌΧ297公釐） -3 - 經濟部中央橾準局負工消費合作社印製 as C8 D8 六、申請專利範圍 )，及介於2:1:1和1:200:200之間（在三 相混合物之情況下）的活性物質。 4 .如申請專利範圍第3項之除草劑，其包含重量比 值介於1:1和1:100之間（在雙相混合物之情況下 )，及介於1 : 1 : 1和1 : 100 : 100之間（在三 相混合物之情況下）的活性物質。 5 .—種控制不想要植物之方法，其包括施加除草有 效數量之如申請專利範圔第1項中之除草劑至這些植物或 它們成長之區域上。 6 ·如申請專利範圍第5項之方法，其中，有用植物 之作物中的除草係經控制。 7 .如申請專利範圍第6項之方法，其中，有用植物 之作物是來自包括小麥，大麥，裸麥，稻子及玉米之族團 〇 8 .如申請專利範圍第1項之除草劑，其係用以控制 有用植物之作物中的雜草。 9 . 一種用以保護作物植物對抗除草劑之植物毒性二 級作用之方法’係使用如申請專利範圍第1項中所定義之 式B 1 〇 ’ B 1 9及/或B32化合物β 1 0 .如申請專利範圍第9項之方法，其係可用以保 護作物植物對抗如申請專利範圍第1項中所定義之除草劑 A1 ’Α2或A3之植物毒性二級作用^ 1 ：L .如申請專利範圍第9項之方法，其中係使用式 B 1 9或B 3 2之化合物* 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ' -4 - --------人 衣------訂------{ (請先閱讀背面之注意事項再填寫本頁) A8 B8 C8 D8 、申請專利範圍 1 2 .如申請專利範圍第1項之除草劑，其中，在A 類化合物和達若因（dymr〇n)之混合物中的重量比值係爲 1 : . 1 - 1 : 5 0。 1 3 ·如申請專利範圍第1 2項之除草劑，其中該重 量比值爲1 : 1一1 : 30。 1 4 .如申請專利範圍第1 3項之除草劑，其中該重 量比值爲1:10-1:30 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度逋用中國國家標準（CNS ) A4規格（210X297公釐）S 0. CH B 3 3) 2. The herbicide as claimed in item 1 of the patent application, which contains 0.1-99.9% by weight of active substances A and B and traditional formulation adjuvants. 3. Herbicides as claimed in item 1 of the patent application, which contain weight ratios between 2: 1 and 1: 200 (in the case of biphasic mixtures, this paper scale applies the Chinese National Standard (CNS) A4 specifications (21ΌΧ297mm) -3-Printed as C8 D8 by the Negative Work Consumer Cooperative of the Central Department of Economics of the Ministry of Economic Affairs 6. The scope of patent application), and between 2: 1: 1 and 1: 200: 200 (in three phases) In the case of mixtures). 4. The herbicide as claimed in item 3 of the patent application, which contains a weight ratio between 1: 1 and 1: 100 (in the case of a biphasic mixture), and between 1: 1 and 1: 100 : Active substances between 100 (in the case of a three-phase mixture). 5. A method of controlling undesirable plants, which includes applying a herbicidally effective amount of the herbicide as described in item 1 of the patent application to these plants or areas where they grow. 6. The method as claimed in item 5 of the patent application, wherein the weeding in crops of useful plants is controlled. 7. The method as claimed in item 6 of the patent scope, wherein the crops of useful plants are from the clan group including wheat, barley, rye, rice and corn. 8. The herbicide as claimed in item 1 of the patent scope is Used to control weeds in crops of useful plants. 9. A method for protecting crop plants against the secondary effects of phytotoxicity of herbicides 'is the use of compounds B 1 0' B 1 9 and / or B32 compound β 1 0 as defined in item 1 of the patent application. If the method of claim 9 is applied, it can be used to protect crop plants against the phytotoxic secondary effects of the herbicides A1 'Α2 or A3 as defined in item 1 of the patent application. ^ 1: L. If applying for a patent The method of item 9 of the scope, in which the compound of formula B 1 9 or B 3 2 is used * This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) '-4--------- Men's clothing ------ order ------ {(please read the precautions on the back before filling in this page) A8 B8 C8 D8 、 Apply for patent scope 1 2. If applying for the herbicide in item 1 of the patent scope , Wherein, the weight ratio in the mixture of the Class A compound and dymrone (dymr〇n) is 1: 1: 1-1:50. 1 3 · For example, the herbicide in item 12 of the patent application scope, in which the weight ratio is 1: 1 to 1:30. 1 4 .For example, the herbicide in the scope of patent application item 13, where the weight ratio is 1: 10-1: 30 (please read the precautions on the back before filling this page) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs This paper scale uses the Chinese National Standard (CNS) A4 specification (210X297mm)